U.S. patent number 3,577,885 [Application Number 04/846,285] was granted by the patent office on 1971-05-11 for paper coating composition.
This patent grant is currently assigned to Phillips Petroleum Company. Invention is credited to Johnny L. Wells.
United States Patent |
3,577,885 |
Wells |
May 11, 1971 |
PAPER COATING COMPOSITION
Abstract
A method for detecting coating transfer from a coated film which
involves incorporating a fluorescent, ultraviolet light-detachable
material in the coating, applying the coating to one surface of the
film and subsequently scanning a surface of the film to detect the
presence of the fluorescent material.
Inventors: |
Wells; Johnny L. (Bartlesville,
OK) |
Assignee: |
Phillips Petroleum Company
(N/A)
|
Family
ID: |
25297443 |
Appl.
No.: |
04/846,285 |
Filed: |
July 30, 1969 |
Current U.S.
Class: |
73/150R; 250/304;
250/459.1; 73/159; 250/362 |
Current CPC
Class: |
G01N
21/64 (20130101) |
Current International
Class: |
G01N
21/64 (20060101); G01n 019/04 (); G01n
021/52 () |
Field of
Search: |
;73/150,159 ;250/71 (T)/
;250/71 (Inquired)/ |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Swisher; S. Clement
Claims
I claim:
1. A method for detecting the transfer of a coating from a coated
surface of a film which comprises incorporating in the coating a
fluorescent, ultraviolet light-detectable material and scanning a
surface of the film with ultraviolet light means to detect the
presence of the fluorescent material.
2. The method of claim 1 in which the coated surface is scanned to
detect transfer by nonuniformity of the coating.
3. The method of claim 1 in which the surface to which transfer is
made is scanned to detect the presence of the coating.
4. The method of claim 1 in which the fluorescent compound is
incorporated in the coating in an amount from about 0.001 to about
0.003 percent by weight of the coating.
5. The method of claim 1 in which the ultraviolet light detection
means is adapted to indicate that portion of the film at which
transfer of the coating is detected.
6. The method of claim 1 in which the coating is applied to a sheet
of paper, the transfer being made to the matte surface of the
paper.
7. The method of claim 1 in which the coating comprises silicone
applied to the surface of a paper in the form of a solution.
8. The method of claim 1 in which a fluorescent, ultraviolet
light-detectable material is incorporated in a silicone solution
applied as a coating to the surface of the paper.
Description
This invention relates to detection of the transfer of coating
compositions.
In one of its more specific aspects, this invention relates to
silicone coating compositions used for coating release paper.
In the manufacture of coated surfaces, and in particular of certain
types of papers, one of the surfaces of the paper is coated for a
specific purpose, for example, to facilitate the implantation of an
image in a subsequent printing process. Since such paper is
generally stored in rolls in which the coated surface is brought
into contact with the noncoated, or matte, surface of the sheet, it
frequently happens that on extended storage some of the coating of
the coated surface adheres to the noncoated surface. Upon the
unwinding of the roll, a defective coated surface results. Such
transfer is difficult to detect and frequently considerable amounts
of paper are processed before the transfer is determined. The
method of this invention is directed to the solution of that
problem.
According to the method of this invention there is provided a
process for detecting coating transfer from a coated film which
comprises coating one surface of the film with a composition
comprising a fluorescent, ultraviolet light-detectable material and
subsequently scanning a surface of the film with ultraviolet light
detection means to detect the presence of the fluorescent
material.
In one of its embodiments, this invention contemplates the coating
of one surface of the film and the scanning of the surface of the
film from which transfer is made to detect transfer by
nonuniformity of the residual coating.
In another of its embodiments, this invention contemplates scanning
the surface of the film to which transfer is made to detect the
presence of the fluorescent material.
Accordingly, it is an object of this invention to provide a method
for insuring the production of a surface-processable paper.
It is another object of this invention to provide a method of
eliminating the processing of defectively coated paper.
These and other objects of this invention will become apparent from
the following description.
The method of this invention applies to all types of paper which
are surface coated on at least one surface and is similarly
applicable to paper coated on two surfaces.
The method of this invention also applies to all types of paper to
which an extraneous material is applied, whether such extraneous
material acts as a coating or is incorporated in the body of the
paper, the presence or uniformity of which material it is desired
to determine. One such coating to which the method of this
invention is particularly applicable is a silicone coating applied
in the form of a solution.
The method of this invention similarly applies to all conventional
methods of coating papers, however conducted, which do not destroy
the effect of the fluorescent compounds upon their addition to the
coating solution or in the application of the solution to the
paper. The method of this invention contemplates the addition of
any of the conventional fluorescent compounds detectable by light,
or related means, to the coatings employed. Such fluorescent
compounds include fluorescein, riboflavin, anthracene, rhodamine B
and Tinopal*
While this invention is explained in the terms of coating
compounds, it is, as mentioned above, applicable to any extraneous
materials which are applied to paper.
One, or more, of the detectable fluorescent compounds is
incorporated in the coating by direct addition thereto in amounts
from about 0.001 to about 0.003 percent by weight of either the
coating itself or of the finished solution. Incorporation can be
made under any conditions which promote uniform dispersal of the
fluorescent component in the final solution. The application of the
fluorescent compound-containing solution to the paper is made in
the usual manner.
In the application of this invention, a fluorescent composition
detecting means, such as an ultraviolet light source, is positioned
to scan that surface of the paper to which the coating containing
the fluorescent composition can be expected to be transferred and
such transfer determined. Alternately, the detecting means can be
positioned to scan the original coated surface and adapted to
respond to the irregularity of the fluorescent composition on the
surface. There can be interrelated with the detecting means any
number of systems which respond to the presence or to the lack of
the fluorescent material; for example, such a system can emit a
detectable alarm indicating the location of the surface concerned,
and can be adapted to imprint on the surface of the paper at that
point to which the detection means responds.
One can select a light source of a wide range in conjunction with
the nature of the fluorescent material employed. Similarly, one can
select an ultraviolet-active agent differing from those optical
brighteners which are sometimes added to whiten paper. The detector
response is then adjusted to the particular wave length emitted by
the fluorescent material whose presence requires detection.
In one application of the method of this invention, a
silicone-coated release paper was prepared employing an
organopolysiloxane well known in the art in which an ultraviolet
tracer material, Tinopal SFG, was incorporated to the extent of
about 0.002 weight percent of the finished solution. Coating of the
paper and curing techniques were conventional and the coating was
subsequently monitored on a continuous basis.
The paper was put through a Scan-A-Web unit, a unit equipped with
ultraviolet light having a wave length of 2,537 A and available
from Kensington Scientific Corporation, Oakland California, the
matte surface being oriented to the light source. Release of the
fluorescent component to the matte side of the paper was easily
detected visually.
It will be appreciated that the method of this invention can be
employed to determine not only coating transfer but also uniformity
of coating, both upon application of the coating and after curing
and storage. It will be further evident that the method of this
invention can be employed in applying any solutions of any nature
to any films on which uniformity of deposition or retention is
desired to be determined.
* * * * *