U.S. patent number 3,577,026 [Application Number 04/836,088] was granted by the patent office on 1971-05-04 for method for producing ions utilizing a charge-transfer collision.
Invention is credited to Willy Haeberli.
United States Patent |
3,577,026 |
Haeberli |
May 4, 1971 |
**Please see images for:
( Certificate of Correction ) ** |
METHOD FOR PRODUCING IONS UTILIZING A CHARGE-TRANSFER COLLISION
Abstract
Ionization of a first beam of polarized neutral atoms is
accomplished by a charge-transfer collision with a second beam of
atoms.
Inventors: |
Haeberli; Willy (Madison,
WI) |
Assignee: |
|
Family
ID: |
25271211 |
Appl.
No.: |
04/836,088 |
Filed: |
June 24, 1969 |
Current U.S.
Class: |
250/424; 313/230;
250/493.1; 976/DIG.438 |
Current CPC
Class: |
G21K
1/16 (20130101) |
Current International
Class: |
G21K
1/00 (20060101); G21K 1/16 (20060101); H01j
027/00 () |
Field of
Search: |
;313/63,230 ;250/84 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Lake; Roy
Assistant Examiner: Demeo; Palmer C.
Claims
I claim:
1. A method for ionizing a first beam of polarized neutral atoms
comprising generating a second beam of atoms and effecting a
charge-transfer collision between said first polarized atomic beam
and said second atomic beam to ionize said polarized atoms.
2. The method according to claim 1 wherein said second beam
generation and charge-transfer collision comprises generating a
magnetic field and generating and transmitting said second beam to
intercept said first beam at a velocity relative thereto to effect
a charge-transfer collision therewith in said magnetic field.
3. The method according to claim 1 wherein said second beam
generation and charge-transfer collision comprises generating said
second atomic beam at a predetermined velocity, transmitting said
second atomic beam collinear with said first polarized atomic beam
in a direction opposite thereto to effect a charge transfer
therewith in a partial vacuum to ionize said polarized atoms, and
extracting said ionized polarized atoms.
4. The method according to claim 3 wherein said charge transfer
between said first and second atomic beams is effected in a
magnetic field parallel to the direction of said polarized atomic
beam.
5. The method according to claim 1 wherein said second beam
generation and charge-transfer collision comprises generating a
second beam of neutral cesium atoms at a velocity relative said
first beam atoms of approximately 2.times.10.sup.7
centimeters/second, transmitting said second beam to collide with
said first beam atoms and effect a charge transfer therewith in a
partial vacuum to ionize atoms of said first beam, maintaining a
magnetic field in the region of said charge-transfer collision, and
extracting from said charge-transfer collision region polarized
ionized atoms.
6. The method according to claim 1 wherein said second beam
generation and charge-transfer collision comprises generating a
second beam of either hydrogen or deuterium atoms at a velocity
relative said first beam atoms of approximately 4.times.10.sup.7
centimeters/second, transmitting said second beam to collide with
said first beam atoms and effect a charge transfer therewith in a
partial vacuum to ionize atoms of said first beam, maintaining a
magnetic field in the region of said charge-transfer collision, and
extracting from said charge-transfer collision region polarized
ionized atoms.
7. The method according to claim 1 wherein said first beam
comprises neutral atoms of hydrogen and said second atomic beam
generation and charge-transfer collision comprises generating a
magnetic field, generating in a partial vacuum at a predetermined
velocity a second beam of either lithium or cesium atoms to effect
a charge-transfer collision with said first beam in said magnetic
field and form polarized ionized hydrogen atoms, and extracting
said polarized ionized hydrogen atoms.
8. The method according to claim 7 wherein said cesium atoms of
said second beam are neutral cesium atoms generated to provide a
relative velocity between the atoms of said first and second beams
of approximately 2.times.10.sup.7 centimeters/second.
9. The method according to claim 1 wherein said first beam
comprises neutral atoms of hydrogen and said second atomic beam
generation and charge-transfer collision comprises generating a
magnetic field, generating in a partial vacuum at a predetermined
velocity a second beam of either deuterium or hydrogen atoms to
effect a charge-transfer collision with said first polarized atomic
beam in said magnetic field and form polarized ionized hydrogen
atoms, and extracting said polarized ionized hydrogen atoms.
10. The method according to claim 9 wherein either of said
deuterium or hydrogen atoms of said second beam are ionized atoms
generated to provide a relative velocity between the atoms of said
first and second beams of approximately 2.times.10.sup.7
centimeters/second.
11. The method according to claim 1 wherein said first beam
comprises neutral atoms of either lithium, cesium, or deuterium and
said second atomic beam generation and charge-transfer collision
comprises generating a magnetic field, generating in a partial
vacuum at a predetermined velocity a second beam of either lithium
or cesium atoms to effect a charge-transfer collision with said
first polarized atomic beam in said magnetic field and form
polarized ionized atoms, and extracting said polarized ionized
atoms.
12. The method according to claim 1 wherein said first beam
comprises neutral atoms of either lithium, cesium, or deuterium and
said second atomic beam generation and charge-transfer collision
comprises generating a magnetic field, generating in a partial
vacuum at a predetermined velocity a second beam of either
deuterium or hydrogen atoms to effect a charge-transfer collision
with said first polarized atomic beam in said magnetic field and
form polarized ionized atoms, and extracting said polarized ionized
atoms.
Description
CONTRACTUAL ORIGIN OF THE INVENTION
The invention described herein was made in the course of, or under,
a contract with the UNITED STATES ATOMIC ENERGY COMMISSION.
BACKGROUND OF THE INVENTION
This invention relates to polarized ions and more particularly to a
method for producing polarized ions utilizing a charge-transfer
collision.
Polarized ion beams are used in particle accelerators to strike
targets of interest. They are presently produced by polarizing
atoms in the beam and then ionizing the polarized atoms. Ionization
to produce polarized positive-ion beams is generally effected in
the manner of either the strong field ionization method disclosed
by Glavish and Collins, Proceedings of the 2nd International
Symposium on Polarization Phenomena or Nucleons, Editors: Huber and
Schopper, Birkhauser Verlag Basel und Stuttgart, page 86, or by
weak field ionization as disclosed by Rudin et al., "Helvetica
Physica Acta," Volume 34, page 58, 1961. With these methods, a beam
of polarized positive ions approximately 1 microampere in intensity
is produced. If polarized negative ions are required as for Tandem
accelerators and some cyclotrons, such ions are presently produced
by accelerating the aforedescribed positive-ion beam and passing it
through a suitable foil or gas. This method results in a polarized
negative-ion beam which is relatively weak in intensity,
approximately 0.01 microampere.
Accordingly, it is one object of the present invention to provide
an improved method of ionizing polarized atoms.
It is another object of the present invention to provide a
polarized ion beam of greater intensity than heretofore.
It is another object of the present invention to provide a method
for directly converting polarized atoms to polarized negative
ions.
It is another object of the present invention to provide a
polarized negative ion beam having an intensity of 1
microampere.
It is another object of the present invention to provide a
polarized positive-ion beam having an intensity of 10
microamperes.
Other objects of the present invention will become more apparent as
the detailed description proceeds.
SUMMARY OF THE INVENTION
In general, the method of the present invention comprises effecting
a charge-transfer collision between a first beam of polarized
neutral atoms to be ionized and a generated second beam of atoms
whereby the polarized atoms in said first beam are ionized.
BRIEF DESCRIPTION OF THE DRAWING
Further understanding of the present invention may best by obtained
by consideration of the accompanying drawings wherein:
FIG. 1 is a schematic diagram of an apparatus for practicing the
method of the present invention.
FIG. 2 is a schematic diagram of an alternate apparatus for the
practice of the method of the present invention.
As previously described, in the production of polarized ions
neutral atoms are formed into a beam and polarized. These polarized
neutral atoms are subsequently ionized. In the present invention,
the direct conversion of the neutral polarized atoms to polarized
negative ions is effected by a charge-transfer collision with a
second atomic beam, which collision may be described by the general
equation
X.sup.0 + Z.sup.0 -- X.sup..sup.- + Z.sup..sup.+ .
This equation is illustrative of a charge-transfer collision
between neutral polarized atoms X.sup.0 and a generated beam of
neutral atoms Z.sup.0 to produce polarized negative ions
X.sup..sup.- and positive ions Z.sup..sup.+. Further understanding
of this general relationship to produce polarized negative ions may
be achieved by considering a particular case wherein polarized
neutral hydrogen atoms are converted to polarized negative hydrogen
ions by a charge-transfer collision with neutral cesium atoms,
which relationship may be described by
H.sup.0 +Cs.sup.0 -- H.sup..sup.- + Cs.sup..sup.+.
In this charge-transfer collision to effect the polarized negative
hydro hydrogen ions, the relative velocity of the neutral cesium
atoms with respect to the neutral hydrogen atoms must be such as to
effect a charge transfer upon collision. For maximum ion intensity
production, the relative velocity V between the neutral cesium and
polarized hydrogen atoms should be approximately 2.times.10.sup.7
cm./sec.
The method of the charge-transfer collision may be achieved
utilizing the apparatus shown in FIG. 1. A neutral cesium atomic
beam 10 is produced at a predetermined velocity by the conventional
technique of passing a positive cesium ion beam through a cesium
vapor cell (not shown) to neutralize the ions in the beam. The
neutral cesium atomic beam 10 is then transmitted collinear with
the polarized neutral hydrogen atomic beam 14 to effect an
interaction therewith in the interior 16 of a solenoid 18 which is
coaxial with the apparatus producing the polarized hydrogen beam
14. The solenoid 18 has a winding 20 disposed thereabout which,
when excited, produces a magnetic field B within the solenoid
parallel to and in the direction of the polarized hydrogen atomic
beam 14. This magnetic field B maintains and defines the spin
alignment direction of the polarized hydrogen atoms. As previously
described, the neutral cesium atoms are generated and injected into
the interior 16 of the solenoid 18 with a velocity sufficient to
effect a charge-transfer collision with the polarized neutral
hydrogen atoms of atomic beam 14. For the case of hydrogen and
cesium, the relative velocity therebetween should be
2.times.10.sup.7 cm./sec. to achieve maximum ionization intensity
output. In the charge-transfer collision between the neutral cesium
atoms and the polarized neutral hydrogen atoms, the cesium atom
gives up an electron which is acquired by the hydrogen atom,
thereby producing polarized negative hydrogen ions in the
interaction region within the interior 16 of solenoid 18.
An electrode 22 having a positive potential thereon extracts the
polarized negative hydrogen ions from the interior 16 of solenoid
18. Subsequently, electrode 24 and grid 26 act to form a focus lens
28 and focus the extracted polarized negative hydrogen ions into a
beam 29. The focused polarized negative hydrogen ions are then
reflected by an electrostatic mirror 30 comprising two grids 32 and
34 for use in the accelerator.
It will be appreciated that the aforedescribed method is
accomplished in a partial vacuum. With a partial vacuum of
10.sup..sup.-7 mm. Hg., a magnetic field B of approximately 1
kilogauss in the interaction region of the interior 16 of solenoid
18, a relative velocity V between the neutral cesium and polarized
hydrogen atoms of 2.times.10.sup.7 cm./sec. and electrode and grid
biases as follows, an output polarized negative hydrogen ion beam
intensity of 1 microampere may be achieved.
Electrode 22 +100 volts
Electrode 24 +1600 volts
Grid 26 +5000 volts
Grid 32 +5000 volts (same potential as grid 26)
Grid 34 electrical ground.
It is not intended that the aforedescribed hydrogen-cesium reaction
be a limitation on the general equation
X.sup.0 + Z.sup.0 -- X.sup..sup.- + Z.sup..sup.+.
It is to be understood that material other than hydrogen and cesium
may be substituted in this general equation to effect the
production by charge-transfer collision of polarized negative ions
of high intensity. For example, polarized neutral lithium or
deuterium atoms may be substituted for the polarized neutral
hydrogen atoms in the aforedescribed example to produce polarized
negative lithium or deuterium ions. Further neutral lithium,
deuterium or hydrogen atoms may be substituted for the neutral
cesium atoms to act as an electron donor.
The charge-transfer collision method of the present invention may
further be described by the general equation
X.sup.0 + Z.sup..sup.- -- X.sup..sup.- + Z.sup.0.
This equation is illustrative of a charge-transfer collision
between neutral polarized atoms X.sup.0 and a generated beam of
negative ions Z.sup..sup.- to produce polarized negative ions
X.sup..sup.- and neutral atoms Z.sup.0. Further understanding of
this general relationship to produce polarized negative ions may be
achieved by considering a particular case wherein polarized neutral
hydrogen atoms are converted to polarized negative hydrogen ions by
charge-transfer collision with negative deuterium ions. The
relationship may be described by
H.sup.0 + D.sup..sup.- -- H.sup..sup.- + D.sup.0.
In this charge-transfer collision to effect the polarized negative
hydrogen ions, the relative velocity of the negative deuterium ions
with respect to the neutral hydrogen atoms must be such as to
effect a charge transfer upon collision. For maximum polarized ion
intensity production, the relative velocity V between the neutral
polarized hydrogen atoms and negative deuterium ions should be
approximately 4.times.10.sup.7 cm./sec. This charge-transfer
collision may be achieved utilizing the apparatus shown in FIG. 2.
The apparatus of FIG. 2 is the same as the apparatus of FIG. 1
except that the negative-ion beam enters the interaction region 16
from the same direction as the polarized neutral atom beam. In the
embodiment of FIG. 2, the negative-deuterium-ion beam 40 enters the
interaction region 16 after being reflected by an electrostatic
mirror 42 comprising grids 44 and 46 maintained at potentials of
approximately -2000 volts and electrical ground, respectively. The
neutral polarized hydrogen atom beam 14 is not affected by the
mirror 42 and also enters the interaction region 16 wherein a
charge-transfer collision is effected between the neutral hydrogen
atoms and negative deuterium ions. The remaining operation of the
apparatus of FIG. 2 is the same as that of FIG. 1. The negative
deuterium ions may be produced by conventional DC arc source
techniques. Further, it will be appreciated that other materials
may be substituted to produce polarized negative ions for the
practice of the charge-transfer collision according to the general
formula
X.sup.0 + Z.sup..sup.- -- X.sup..sup.- + Z.sup.0.
For example, neutral lithium or deuterium atoms may be substituted
for the neutral hydrogen atoms to produce polarized negative
lithium or deuterium ions. Further, negative lithium or hydrogen
ions may be substituted for the negative deuterium ions as an
electron donor. When negative hydrogen ions are substituted for
negative deuterium ions, the same approximate relative velocity of
4.times.10.sup.7 cm./sec. is maintained with respect to the
polarized neutral hydrogen ions.
The charge-transfer collision method of the present invention may
be further expressed by a third general equation
X.sup.0 + Z.sup..sup.+ -- X.sup..sup.+ + Z.sup..sup.+ +e.
This equation is illustrative of a charge-transfer collision
between neutral polarized atoms X.sup.0 and a generated beam of
positive ions to produce polarized positive ions X.sup..sup.+ and
positive ions Z.sup..sup.+ and free electrons. This general
relationship may be specifically illustrated by the process
H.sup.0 + D.sup..sup.+-- H.sup..sup.+ + D.sup..sup.+ +e.
In this case, polarized neutral hydrogen atoms are converted to
polarized positive hydrogen ions by charge-transfer collision with
positive deuterium ions. This process may be carried out by the
aforedescribed and illustrated apparatus of FIG. 2 with the
polarity of the various grid and electrode biases adjusted to
effect extraction of polarized positive hydrogen ions. As for the
aforedescribed embodiments, the relative velocity between the
polarized neutral hydrogen atoms and the positive deuterium ions
must be sufficient to effect a charge-transfer collision. For the
specific example utilizing polarized neutral hydrogen atoms and
positive deuterium ions, a relative velocity of 4.times.10.sup.8
cm./sec. will achieve maximum polarized positive hydrogen ion
intensity output (approximately 10 microamperes). It will also be
appreciated that the third general charge-transfer collision
relationship X.sup.0 + Z.sup..sup.+ -- X.sup..sup.+ + Z.sup..sup.+
+e may be effective using materials other than those recited in the
specific example and is not to be limited thereto. For example,
polarized neutral lithium, cesium or deuterium atoms can be
substituted for the polarized neutral hydrogen atoms to produce
polarized positive lithium, cesium or deuterium ions. Further,
positive hydrogen, lithium or cesium ions can be substituted for
the positive deuterium ions.
It will be appreciated that, in the practice of the present
invention according to the aforedescribed methods, it is not
requisite that the atomic beams effecting the charge-transfer
collision be collinear. The present invention is operable with
apparatus wherein the atomic beams have other relative propagation
directions. For example, the beams may be oriented to cross at
right angles with the resultant charge-exchange collision still
being accomplished. Further, where the present invention is applied
to ionization in a weak field then the magnetic field in the
interaction region need not be parallel to either atomic beam but
may be oriented at will.
Persons skilled in the art will, of course, readily adapt the
general teachings of the invention to embodiments far different
from the embodiments illustrated. Accordingly, the scope of the
protection afforded the invention should not be limited to the
particular embodiment illustrated in the drawings and described
above but should be determined only in accordance with the appended
claims.
The embodiments of the invention in which an exclusive property or
privilege is claimed are defined as follows:
* * * * *