U.S. patent number 3,568,685 [Application Number 04/721,158] was granted by the patent office on 1971-03-09 for treating human, animal and synthetic hair with a water-proofing composition.
Invention is credited to Howard L. Scott.
United States Patent |
3,568,685 |
Scott |
March 9, 1971 |
TREATING HUMAN, ANIMAL AND SYNTHETIC HAIR WITH A WATER-PROOFING
COMPOSITION
Abstract
A method for treating fibers such as synthetic or natural hair,
whereby synthetic fibers can be made to have the appearance of
human hair and whereby human hair can be straightened, which
comprises applying to the hair a composition containing about 1--50
percent by volume of a substantive water-repellent agent, and about
10--80 percent by volume of a substantive hardening and adhesive
agent. A slipping agent, such as a fluoro resin, and en emollient,
such as lanolin, is also preferably included.
Inventors: |
Scott; Howard L. (Philadelphia,
PA) |
Family
ID: |
24896786 |
Appl.
No.: |
04/721,158 |
Filed: |
April 15, 1968 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
Issue Date |
|
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386730 |
Jul 31, 1964 |
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Current U.S.
Class: |
132/206; 8/127.5;
8/127.6; 8/115.6; 8/127.51; 424/70.11; 424/70.16; 424/70.17 |
Current CPC
Class: |
A61K
8/8123 (20130101); A61K 8/42 (20130101); A61K
8/411 (20130101); A61K 8/86 (20130101); A61K
8/41 (20130101); A61K 8/8152 (20130101); A61Q
5/06 (20130101); A61K 8/26 (20130101); A61K
8/19 (20130101); A61K 8/8158 (20130101) |
Current International
Class: |
A61K
8/42 (20060101); A61K 8/72 (20060101); A61K
8/36 (20060101); A61K 8/81 (20060101); A61K
8/41 (20060101); A61K 8/86 (20060101); A61K
8/19 (20060101); A61K 8/26 (20060101); A61K
8/30 (20060101); A61Q 5/06 (20060101); A61k
007/10 (); D06m 003/10 (); D06m 003/40 () |
Field of
Search: |
;424/154,71 ;132/7
;8/127.5,127.51,128,115.6 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Friedman; Stanley J.
Assistant Examiner: Clarke; Vera C.
Parent Case Text
This is a continuation-in-part of application Ser. No. 386,730,
filed Jul. 31, 1964; which application is now abandoned.
Claims
I claim:
1. A composition for treating natural and synthetic hair consisting
essentially of about 1--50 percent by volume of a water-repellent
agent consisting of (a) a wax-polymer emulsion wherein the ratio of
wax to polymer is about 3:1, the polymer being a copolymer which
consists of (1) about 15--90 percent by weight of an amino group
containing comonomer having the structure: ##SPC2##
where R.sub.1 and R.sub.2 are selected from the group consisting of
lower alkyl and cycloalkyl that include R.sub.1, R.sub.2, and
R.sub.3 is selected from the group consisting of H and CH.sub.3,
and ( 2) 10--85 percent by weight of a comonomer having the
structure:
CH.sub.2=C-Y
where X is a member of the group selected from H and CH.sub.3 and Y
is a member selected from the polar group consisting of nitrile,
aliphatic acyloxy having from 1--18 carbon atoms and alkoxycarbonyl
having from 1--18 carbon atoms, said copolymer having an intrinsic
viscosity in benzene at 30.degree. C. of from 0.04--0.5; and (b)
about 10--80 percent by volume of a hardening agent selected from
the group consisting of (1) p,p'-methylenedianiline, (2) a
copolymer obtained by polymerizing a mixture of 0.5--25 percent of
itaconic acid, 3--40 percent of at least one polymerizable compound
selected from the group consisting of acrylonitrile, alkyl esters
of acrylic and methacrylic acids having from 1 to 18 carbon atoms
in the alkyl group, phenyl methacrylate, cyclohexyl methacrylate,
p-cyclohexylphenyl methacrylate, methacrylonitrile, methyl vinyl
ketone, and vinyl chloride, and 35--96.5 percent of vinylidene
chloride, the proportions being selected to total 100 percent, (3)
water-insoluble copolymers formed by the emulsion copolymerization
of 0.5--6 percent by weight of either N-methylolacrylamide,
N-methylolmethacrylamide or mixtures thereof with 0.5--25 percent
by weight of either acrylamide or methacrylamide and having a
molecular weight of 100,000 to 10,000,000, and (4) copolymers of
acrylonitrile and styrene wherein a 50 percent solution has a
viscosity of SX (Gardner-Holdt at 25.degree. C.).
2. The composition of claim 1 also containing about 0.1--10 percent
by volume of a slipping agent, said slipping agent being a member
of the group consisting of polytetrafluoroethylene having a
molecular weight of between about 1,000,000 and about 10,000,000
and vinylidene fluoride polymer having a molecular weight of
between about 300,000 and 600,000.
3. The composition of claim 2 also containing about 25--60 percent
by volume of an emolient which is substantive to the hair.
4. A method of treating natural and synthetic hair which comprises
coating the hair fibers with the composition of claim 1 and then
heating the coated fibers to a temperature at which the composition
thermally sets.
5. A method of treating natural and synthetic hair which comprises
coating the hair fibers with the composition of claim 2 and then
heating the coated fibers to a temperature at which the composition
thermally sets.
6. A method of treating natural and synthetic hair which comprises
coating the hair fibers with the composition of claim 3 and then
heating the coated fibers to a temperature at which the composition
thermally sets.
Description
This invention relates to the treatment of fibers such as synthetic
or natural hair, and it particularly relates to the treatment of
synthetic fibers to give the appearance of human hair, as well as
to the straightening of so-called "kinky" hair, especially human
hair.
It has long been known to straighten kinky or curly hair by
applying tension to the individual strands simultaneously with heat
or pressure. However, after the strands have been straightened, any
accumulation of moisture on the strands overcomes the straightening
effects and causes the strands to resume their natural curl. This
has always posed a large problem because moisture accumulates on
the hair as the result of natural perspiration, especially during
physical exertion, or even by condensation from the air itself,
especially in warm, humid weather. It also interferes with such
activities as swimming, or even bathing.
Various attempts have, heretofore, been made to overcome the above
problems by subjecting the hair to chemical treatments with sodium
hydroxide, potash, lye and other caustics. However, these
treatments prevented the hair from curling only because they so
reduced the body of the hair and, therefore, so weakened the hair
that it did not have the strength to revert back to its normal
curl. Obviously, such treatments often resulted in impairment of
the growth of the hair or even in loss of the hair. Furthermore,
because of the very caustic nature of these chemicals, only one
having professional skill could effectively use the treatment, and
even then, the utmost care had to be taken to avoid burning of the
scalp, blinding of the eyes or other similar injuries.
The expense and danger of using caustic chemicals resulted in many
people affected with the problem resorting to the so-called "hot
comb" straightening method. This involved the use of a hot comb
used in conjunction with petroleum jelly or lard as a lubricant.
The hair then had to be plaited to keep it in place. This method
gave the hair an unattractive "corn row" appearance. Others would
"hot comb" the hair two or three times a week without lubricants.
This latter method, although avoiding the so-called "corn row"
appearance, subjected the hair to such constant mistreatment that
it often resulted in the ultimate destruction of the hair and
impairment of its subsequent growth.
It is also possible to use the present composition to give the
appearance of human hair to synthetic fibers such as polyesters and
polyamides. Nylon fibers are particularly well adapted to this
process.
One object of the present invention is to provide a composition
which is suitable both for treating human or animal hair to
straighten the hair and for treating synthetic fibers to simulate
the appearance of hair.
Another object of the present invention is to treat the hair with a
waterproofing composition at the same time that the hair is being
straightened whereby the hair, after it is straightened, is not
subject to the effects of moisture and, therefore, retains its
straight properties.
Another object of the present invention is to provide a method of
straightening hair which, although it provides a straightening
effect of substantial duration, obviates the use of caustic
chemical agents or undesirable lubricants.
Another object of the present invention is to provide a method of
straightening hair and retaining the hair in such straightened
condition for substantial periods of time without the necessity of
using professional skill and care.
Other objects of the present invention will be apparent from the
specification and claims herein.
In accordance with the present invention, when human hair is to be
straightened, the hair is coated with a treating composition, and
the coated strands of hair are then subjected to straightening
tension and heat, as by means of a heated comb or the like.
The treating composition consists of about 1-- 50 percent of a
water-repellent agent, about 10-- 80 percent of a hardening and
adhesive agent, about 0.1-- 10 percent of a slipping agent and
about 25-- 60 percent of an emollient, these percentages all being
by volume. In addition, a small amount of any desired perfume may
be added.
The water-repellent agent utilized herein is preferably an aqueous
paraffin wax-polymer emulsion wherein the ratio of wax:polymer is
about 3:1. The polymer preferably used is a copolymer such as
disclosed in U.S. Pat No. 3,026,250 and consists of 15-- 90 percent
by weight of an amino group containing comonomer having the
structure: ##SPC1##
where R.sub.1 and R.sub.2 are selected from the group consisting of
lower alkyl and cycloalkyl that include R.sub.1 and R.sub.2, and
R.sub.3 is selected from the group consisting of H and CH.sub.3;
and 10-- 85 percent by weight of a comonomer having the
structure:
CH.sub.2=C-Y
where X is a member of the group selected from H and CH.sub.3 and Y
is a member selected from the polar group consisting of nitrile,
acyloxy having from 1-- 18 carbon atoms and alkoxycarbonyl having
from 1-- 18 carbon atoms.
Of particular preference is the copolymer of diethylaminoethyl
methacrylate and octadecyl methacrylate.
Other products that may be used as the waterproofing or
water-repellent agent are such commercially available products as
"Zonyl RP" (DuPont), which is an anionic fluoro compound having a
density at 77.degree. F. of 8.85 lb/gal., a viscosity at 77.degree.
F. of 10 centipoises, a pH of 7.0 and complete solubility in water.
Also "Nalan RF" and "Nalan RD" (DuPont), "Zelcon SL" (DuPont),
"Zepel" (DuPont) and other similar water-dispersible products, as,
for example, "Scotchgard" (Minnesota Mining & Manufacturing
Co.).
Among the hardening agents which may be used are:
p,p'-methylenedianiline and various acrylic, acrylonitrile and
methacrylic copolymers. One such copolymer which is particularly
adapted to this invention is a copolymer obtained by polymerizing a
mixture of about 0.5-- 25 percent by weight of itaconic acid, 3-- 4
percent by weight of at least one member of the group consisting of
acrylonitrile, alkyl esters of acrylic and methacrylic acids having
from 1 to 18 carbon atoms in the alkyl group, phenyl methacrylate,
cyclohexyl methacrylate, p-cyclohexylphenyl methacrylate,
methacrylonitrile, methyl vinyl ketone and vinyl chloride, and 35--
96.5 percent by weight of vinylidene chloride. This product is
disclosed and claimed in U.S. Pat. No. 2,570,478 and will be
hereinafter referred to as "acrylic-modified vinylidene chloride
polymer."
Other copolymers include the water-insoluble copolymers obtained by
emulsion copolymerization of N-methylolacrylamide or
N-methylolmethacrylamide or mixtures thereof with acrylamide or
methacrylamide. These copolymers are disclosed in U.S. Pat. No.
3,157,562 and are sold by Rohm & Haas under the respective
trade names "Rhoplex HA-12" and "Rhoplex HA-16." Similar products
produced by Rohm & Haas under the trade names "Rhoplex 201" and
"Rhoplex X-52," the latter disclosed in U.S. Pat. No. 2,754,280,
may also be used.
Also utilizable are the copolymers of acrylonitrile and styrene
produced by Pennsylvania Industrial Chemical Corp. under the trade
name "Piccoflex" and "Arolon 363" (Archer Daniels Midland Co.), a
solution of a water-soluble, oxidizing resin containing about 50
percent by weight solids, having a viscosity of SX (Gardner-Holdt
at 25.degree. C.) and a pH of between 6.9 and 7.3 at 25.degree.
C.
The slipping agent may be any one of a number of fluoro resins.
Among these resins is a product produced by DuPont under the name
of "Teflon P-TFE." This product, as used herein, is a
polytetrafluoroethylene having a molecular weight of between about
1,000,000 to 10,000,000, and a viscosity greater than 10.sup. 10
poises at 380.degree. C. Also utilizable is a vinylidene fluoride
resin, produced by Pennsalt Chemicals Corporation under the name
"Kynar." is a high molecular weight polymer having a molecular
weight of between about 300,000 and 6,00,000 and having the
structure:
-CH.sub.2-CF.sub.2-CH.sub.2-CF.sub.2-CH.sub.2-CF.sub.2-
All of the compositions embodying the present invention may be
prepared by mixing the desired proportions of all the components
together at room temperature and pressure until a homogeneous,
viscous, greaselike cream is obtained.
The following examples are illustrative of the present
invention.
EXAMPLE 1
To a solution of 300 parts of 2-diethylaminoethyl methacrylate and
700 parts of octadecyl methacrylate in 1000 parts of molten
paraffin wax, maintained at 75.degree. C., in a suitable vessel
equipped with an agitator, are added 10 parts of 2,2.sup.1
-azodiisobutyronitrile in small increments over a period of 6 to 10
hours. After the last addition of the polymerization initiator, the
reaction mass is held at 75.degree. C. for 2 hours, and the
temperature is then raised to 100.degree. C. and held at that
temperature for about one-half hour. The charge is then diluted
with 2,000 parts by weight of molten paraffin wax, to give a
wax-copolymer ratio of 3:1. All parts herein are by weight.
Into 100 parts by weight of the above wax-copolymer composition,
melted by heating to between 65.degree. and 70.degree. C., 4 parts
by weight of glacial acetic acid are stirred. The wax-copolymer
mass is then slowly added to 294 parts by weight of water kept
under vigorous agitation with a high shear mixer, and maintained at
65.degree. to 70.degree. C. Agitation is then continued for a
sufficient time to complete the emulsification. The resulting
product is then cooled to room temperature. The product has a
molecular weight of between about 20,000 and 80,000 and a viscosity
of about 16 centipoises at 80.degree. F. (Brookfield).
EXAMPLE 2
Twelve percent by volume of the emulsion of example 1 was mixed
with 37.5 percent by volume of p,p'-methylenedianiline, 0.5 percent
by volume "Teflon P-TFE" having a molecular weight of about
1,500,000, and 50 percent by volume lanolin. Three drops of perfume
were then added. The mixture was thoroughly agitated at room
temperature and pressure until a homogeneous, greaselike cream was
produced.
EXAMPLE 3
Twenty five percent by volume of the emulsion of example 1 was
mixed with about 25 percent by volume of "Rhoplex HA-12," 1 percent
by volume "Kynar," having a molecular weight of about 600,000, and
49 percent by volume lanolin. About five drops of perfume were then
added. The mixture was thoroughly agitated at room temperature and
pressure until a homogeneous, greaselike cream was produced.
EXAMPLE 4
About 0.2 ounces of the product formed in example 2 was applied to
a human head of hair by rubbing it into the hair until the hair was
completely coated. A heated iron straightening comb was then passed
through the hair in a manner to hold the hair strands under tension
while heat from the comb was applied thereto. When this treatment
was completed, it was noted that each strand of hair possessed a
thin, highly flexible film that repelled water, moisture from the
air and perspiration. The treated hair was then styled in a
desirable manner.
EXAMPLE 5
About 0.2 ounces of the product formed in example 3 was applied to
a human head of hair by rubbing it into the hair until the hair was
completely coated. A heated iron straightening comb heated to about
250.degree. F., was then passed through the hair in a manner to
hold the hair strands under tension while heat from the comb was
applied thereto. When this treatment was completed, it was noted
that each strand of hair possessed a thin, highly flexible film
that repelled water, moisture from the air and perspiration. The
treated hair was then styled in a desirable manner.
It is to be understood that the amount of the composition used may
vary widely depending on the type and condition of the hair.
It is also possible to obtain a utilizable product for treating
hair in accordance with the present invention which consists
essentially only of a water-repellent agent, as described above,
and the hardening and adhesive agent. In such a composition, the
relative percentages by volume are about 20-- 50 percent of the
water-repellent agent and about 80-- 50 percent by volume of the
hardening agent. Such a product, although it may feasibly be used,
is less preferable than the products described above because it is
more difficult to apply and to retain on the hair. A composition of
this type is illustrated in example 6 as follows:
EXAMPLE 6
Twenty five percent by volume of the emulsion of example 1 was
mixed, at room temperature and pressure, with 75 percent by volume
of the acrylic-modified vinylidene chloride polymer, disclosed and
claimed in U.S. Pat. No. 2,570,478, until a homogeneous mixture was
obtained. This composition was then applied as a coating to a human
head of hair, by placing a dab of cream on the fingers and rubbing
it into the hair until a thin film was formed, and a heated iron
straightening comb was then passed through the hair. The strands of
hair were generally all provided with a thin, highly flexible film
similar to that of example 4.
EXAMPLE 7
One-half pound of nylon fiber, dyed to a particular shade, and
containing about 10,000 individual fibers, was coated with the
composition of example 2 and passed between a series of rollers to
smooth out the coating. The coated fibers were then baked in an
oven at a temperature of between about 300.degree.-- 400.degree. F.
The resulting fibers have the appearance of human hair.
Although specific commercially available products have been
utilized as components for the exemplified compositions, it is to
be understood that equivalent materials may be substituted within
the concept of this invention.
Obviously, many modifications of the present invention are possible
in the light of the above teachings. It is, therefore, to be
understood that within the scope of the appended claims, the
invention may be practiced otherwise than as specifically
described.
* * * * *