U.S. patent number 3,565,127 [Application Number 04/769,542] was granted by the patent office on 1971-02-23 for inextensible filamentary structures, and fabrics woven therefrom.
This patent grant is currently assigned to Monsanto Company, St. Louis, MO. Invention is credited to Doyle C. Nicely, Samuel J. Davis.
United States Patent |
3,565,127 |
|
February 23, 1971 |
INEXTENSIBLE FILAMENTARY STRUCTURES, AND FABRICS WOVEN
THEREFROM
Abstract
Strands of brittle, highly inextensible filamentary materials
are collimated into a bundle and wrapped or braided covering
applied to form a composite yarn structure having sufficient
flexibility and mechanical stability to permit the yarn to be woven
as the warp of a fabric, the fill yarn being any conventional
fibrous material. The inextensible filamentary materials include,
among others, boron, boron carbide, silicon, silicon carbide,
carbon, quartz, and similar inorganic refractory fibers which are
characterized by high strength and modulus, brittleness, and
inextensibility.
Inventors: |
Doyle C. Nicely (Durham,
NC), Samuel J. Davis (Chapel Hill, NC) |
Assignee: |
Monsanto Company, St. Louis, MO
(N/A)
|
Family
ID: |
25085761 |
Appl.
No.: |
04/769,542 |
Filed: |
October 22, 1968 |
Current U.S.
Class: |
139/426R; 87/6;
57/210; 139/425R |
Current CPC
Class: |
D02G
3/16 (20130101); D02G 3/38 (20130101); D03D
15/513 (20210101) |
Current International
Class: |
D03D
15/12 (20060101); D03d 015/00 (); D02g 003/16 ();
D02g 003/26 () |
Field of
Search: |
;139/420,426,425,420(A)--420(D)
;57/139,140,140(B),140(Coated),144--146,160--162 ;87/6,7 |
References Cited
[Referenced By]
U.S. Patent Documents
Other References
Business Week - Production - Weaving Tough Fabric With New
Dimension Aug. .
31, 1968 Pgs. 84 & 86 139-11 Copy in Gr..
|
Primary Examiner: James Kee Chi
Attorney, Agent or Firm: Thomas Y. Awalt, Jr. Robert L.
Broad, Jr. R. P. Wymbs
Claims
We claim:
1. A composite filamentary structure comprising a central core of a
plurality of essentially straight and parallel inextensible
filaments comprising a tungsten wire core and a sheath selected
from the group consisting of boron, boron nitride and boron carbide
and an outer covering of a flexible fiber selected from the group
consisting of cotton, rayon, acetate, polyamide, polyester,
acrylics, polyolefins, glass and quartz.
2. A woven fabric the fill of which being a flexible textile
material selected from the group consisting of glass, cotton, wool
and organic manmade fibers, and each warp of which being comprised
of a plurality of essentially straight and parallel inextensible
filaments selected from the group consisting of boron, boron
nitride and boron carbide and having a covering fiber selected from
the group consisting of cotton, wool, rayon, acetate, polyamide,
polyesters, acrylics, polyolefins, glass and quartz forming an
integral bundle therewith.
Description
1. Field in the Invention
This invention relates to a method of weaving fabrics from brittle
and highly inextensible filamentary materials. More particularly,
this invention relates to a method for forming a composite yarn
structure from inorganic refractory fibers and utilizing this
composite as the warp yarn in waving a fabric.
2. Description of Prior Art
Recent developments in the field of high strength, temperature
resistant materials have included the use of inorganic refractory
fibers, such as boron, boron nitride, boron carbide, silicon,
silicon carbide, alumina, alumina-silica, carbon, glass, and quartz
to fabricate reinforced composite structures having outstanding
stiffness and strength-to-weight ratios. These inorganic refractory
fibers are characterized by high strength modulus, brittleness,
limited flexibility, and by essentially zero elongation as defined
by the term "inextensible."
Although many of these refractory fibers are presently available
only in short lengths or as whiskers, efforts are being made to
produce the materials in continuous filament form. Continuous
filament boron formed by the vapor deposition of boron on a fine
wire tungsten substrate is now commercially available.
High-strength reinforced structures are generally fabricated
generally by filament winding or by sheet layup. In filament
winding, strands of reinforcement are oriented directly onto
surfaces which control their form. In sheet layup, the strands are
first formed into sheets, and the sheets are laid up and laminated
to provide the desired form and orientation. While these methods
are useful, composites made by these processes do not possess the
cross-reinforcement provided by a woven structure. For this reason,
it is desirable to prepare woven fabrics of the inextensible
materials as reinforcement for composite structures.
Although the art of weaving is ancient, the inextensible and
brittle nature of the inorganic refractory fibers make it extremely
difficult to weave these materials in a conventional manner.
Conventional textile yarns have a reasonable amount of elongation
due to the intrinsic properties of the fibers used and due to the
generally twisted yarn structure. Consequently, such yarns are
capable of absorbing energy to fairly high strain levels, without
breaking. They may also be bent to very short radii of curvature
without damage.
Filaments of the inorganic refractory fibers presently available
conform to none of these conditions. The high filament modulus, in
combination with a relatively large filament diameter, results in a
gross stiffness and consequent fabrication difficulties. Since the
bending moment of a circular rod is proportional to the fourth
power of the radius of the rod, it is apparent that the intrinsic
stiffness of the material is augmented by its geometry. Attempts at
weaving individual monofilaments into the warp of a fabric have
resulted in frequent breakage of the brittle filaments. A method
for handling and weaving these materials was clearly needed if the
advantages of the woven fabric in reinforced composited structures
were to be obtained.
It has been discovered that a multiplicity of high-modulus,
high-strength, brittle, and highly inextensible filaments may be
collimated into a bundle and covered to hold the bundle as a unit
for further processing. The preferred covering is a braid since
braid structures are torque-free and braid-covering density may be
varied with ease. However, other conventional methods for covering
yarns may be successfully used.
The inextensible filaments which may be used in the practice of
this invention are the inorganic refractory fibers which have a
tensile strength of at least 50,000 p.s.i. and an elastic modulus
of at least 4 million p.s.i. Included among others are boron, boron
nitride, boron carbide, silicon, silicon carbide, alumina,
alumina-silica, carbon, and quartz. The filament may also be a
composite structure consisting for example of a tungsten wire core
with a sheath of boron, boron carbide, or titanium diboride.
The covered bundles can be handled with relative ease and can be
woven into tapes, ribbons, or fabrics using the bundles as warp
ends. The advantage of the bundle structure arises from the freedom
of the component filaments to move with respect to the others,
particularly in bending, and to assume a position of minimum
strain. Furthermore, should one or more individual filaments be
broken, the integrity of the bundle is maintained by the cover. Yet
further, the cover is exposed to and absorbs much of the abrasion
of the weaving process, sparing the brittle filaments this
attrition.
The density of the braid covering can be varied to suit filament
length. Thus, for covering long continuous strands of filamentary
material, the braid may be of a relatively open nature, while for
covering shorter lengths of from 2 to about 8 inches, a fairly
close braid would be desired.
The covering yarn may be spun cotton, spun wool, spun rayon, spun
acetate, spun polyamide, spun polyester, spun acrylic, spun
polyolefin, continuous filament rayon, continuous filament acetate,
continuous filament polyamide, continuous filament polyester,
continuous filament acrylic, continuous polyolefin, continuous
filament glass, continuous filament quartz or other suitable supple
textile material. In some instances where the presence of the
foreign fiber may be undesirable in the ultimate composite, the
covered bundle may be woven and the covering yarn may subsequently
be removed by dissolving it from the fabric prior to making the
ultimate composite structure.
Filling yarns for weaving the collimated bundle warp fabric may be
selected from a wide variety of available materials, including
glass, cotton, wool, and organic manmade fibers. If the transverse
properties of the fabric reinforcement in the ultimate composite
are not critical, it is convenient to use synthetic organic fiber
yarns, such as nylon, polyester polyacrylonitrile, or polyolefin.
If, however, the transverse properties are of consequence,
high-performance synthetic organic fibers, glass, quartz and other
available materials may be used.
Collimated bundle fabrics made from high-modulus, high-strength,
brittle, and highly inextensible filaments may be incorporated in
resin matrices to produce high-performance composite. The
reinforcing filaments are present in high density, and their
intrinsic filament properties are unimpared by the geometry of the
fabric. Therefore, the composite has a high strenght-to-weight
ratio, high modulus, and high stiffness.
DESCRIPTION OF DRAWING
FIGS. 1, 2, and 3 show three typical cross-sectional views of the
braid-covered composite yarn structure. The inextensible filaments
are designated by numeral 10, and the braid material by number
12.
FIG. 4 shows a representative side view of a braid-covered
composite yarn structure produced in accordance with the instant
invention.
DESCRIPTION OF PREFERRED EMBODIMENTS
In the practice of the present invention, a plurality of the
inextensible inorganic refractory fibers are collimated into a
bundle and bound together in a parallel and substantially untwisted
relationship by wrapping or braiding a thread around the bundle to
maintain its integrity. Generally, the bundle will be comprised
from three to seven essentially continuous inextensible
monofilaments of 100 yards or greater length. The bundle may also
be comprised of an arrangement of an inextensible filament having
shorter lengths of from 2 to about 8 inches, or longer. Generally,
2 inches is the practical minimum length which can be used in
accordance with this invention.
For ease of handling, and for superior product characteristics, the
continuous monofilaments are preferred. Excellent results are
obtained using the commercially available filaments produced by
vapor deposition of boron on a very fine tungsten wire substrate.
These filaments have a tensile strength of about 400,000 p.s.i., an
elastic modulus of about 60.times.10.sup.6 p.s.i., and an upper
temperature limit of about 2,000.degree. C. in an inert atmosphere.
Three to seven of these composite monofilaments, bound by a widely
spaced nylon braid covering, are easily handled and can be used as
warp ends to weave a fabric having in the warp direction the same
high strength and modulus as the boron-tungsten filaments.
Although a number of commercial machines may be used to place the
braided cover about the inextensible filament bundle, good results
have been obtained using a No. 1 Braider having eight carriers
manufactured by New England Butt Company, Providence, Rhode
Island.
The covered composite yarns can be handled with relative ease and
with little danger of breaking any of the inextensible filaments if
reasonable precautions are taken to avoid folding or bending the
yarn about a very small radius. Although the composite yarns are
generally used as warp ends in constructing the fabric, they may
also be used as fill if it is preferred. In this case, the
inextensible filaments are most conveniently cut to a length
corresponding to the width of the fabric, and individually placed
through the warp shed during the weaving process. When using the
inextensible filaments as fill, it is generally advisable to use a
flexible textile yarn as the warp.
The following examples will serve to further illustrate the
invention:
EXAMPLE I
Seven ends of continuous boron-tungsten sheath-core composite
monofilament 8 mills in diameter were collimated and passed through
the center of an eight-carrier braider where a covering braid of 50
denier nylon was applied at 8 braids/inch to form a composite yarn
structure. A woven fabric was prepared by using 80 braid bundles
per inch of width as warp ends and a single 189 denier fiberglass
yarn as the fill. The resulting fabric was completely flexible in
the fill direction and sufficiently flexible in the warp direction
to bend around a 2-inch radius mandrel with no fracture of boron
filaments.
EXAMPLE II
Three boron-tungsten monofilaments were covered with a braiding of
20 denier acetate yarn according to the procedure of example I. The
composite was very flexible and easily woven into a fabric having
120 braid covered bundles per inch as warp ends with a single 189
denier fiberglass yarn as fill. The lightweight fabric had
excellent flexibility. The acetate braid covering could be removed
by washing the fabric with acetone, thereby producing a fabric
comprised solely of boron and glass fibers.
It will be apparent from the foregoing description and examples
that this invention provides a novel method for preparing yarns and
fabrics from highly inextensible filamentary materials. As many
widely different embodiments of this invention may be made without
departing from the spirit and scope thereof, it is to be understood
that this invention is not to be limited to the specific
embodiments thereof, except as defined in the appended claims.
* * * * *