U.S. patent number 3,561,337 [Application Number 04/572,419] was granted by the patent office on 1971-02-09 for sheet material for manufacture of transparencies.
This patent grant is currently assigned to Kalvar Corporation. Invention is credited to Jesse W. Mulkey.
United States Patent |
3,561,337 |
Mulkey |
February 9, 1971 |
SHEET MATERIAL FOR MANUFACTURE OF TRANSPARENCIES
Abstract
A sheet material having a transparent backing coated with a
layer containing a polymeric binder and particles of solid material
which is insoluble in the binder. The refractive index of the solid
material varies from that of the binder by at most .+-. 0.6. The
surface of the layer is ink receptive and, by printing on that
surface, a transparency is obtained.
Inventors: |
Mulkey; Jesse W. (New Orleans,
LA) |
Assignee: |
Kalvar Corporation (New
Orleans, LA)
|
Family
ID: |
24287733 |
Appl.
No.: |
04/572,419 |
Filed: |
August 15, 1966 |
Current U.S.
Class: |
428/328; 428/334;
428/918; 396/661; 430/302; 101/467 |
Current CPC
Class: |
B41M
5/52 (20130101); G03F 1/92 (20130101); B41M
5/508 (20130101); Y10S 428/918 (20130101); B41M
5/5218 (20130101); Y10T 428/256 (20150115); Y10T
428/263 (20150115) |
Current International
Class: |
B41M
5/52 (20060101); B41M 5/50 (20060101); G03F
1/06 (20060101); B41M 5/00 (20060101); G03b
041/00 () |
Field of
Search: |
;95/1,85
;355/16,133 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Horan; John M.
Claims
I claim:
1. A sheet material for manufacture of a transparency said sheet
material comprising a layer coated on a transparent backing said
layer having an ink-receptive exposed surface for receiving
printing which layer comprises a homogeneous mixture of:
1. a polymeric binder which has a light transmittance of at least
about 30 percent for a sample 0.00092 mm. thick in at least a
portion of the spectrum, and;
2. particles of a solid material which is insoluble in said binder
and has a light transmittance of at least about 30 percent for a
sample 0.00092 mm. thick at a wavelength at which said binder has
said transmittance, the refractive index of said solid material
varying from the refractive index of said binder by at most
.+-.0.6.
2. A sheet material as set forth in claim 1 in which said binder
and said particles each has an index of refraction in the range 1.4
to 2.0.
3. A sheet material as set forth in claim 1 in which the amounts of
said binder and said particles are each 20 to 80 percent by volume
of said sheet material.
4. A sheet material as set forth in claim 1 in which said particles
have a diameter of about 0.1 to 3 microns.
5. A sheet material as set forth in claim 1 in which said
homogeneous mixture is a coating on a transparent backing.
6. A sheet material as set forth in claim 5 in which the thickness
of said coating is 0.02 to 5 mils.
7. A sheet material as set forth in claim 1 in which said particles
and said binder have a light transmittance of at least 30 percent
in at least a portion of the spectrum between 3,400 and 6,000
angstrom units.
8. A sheet material receptive to printing for manufacture of a
transparency comprising a coating 0.02 to 5 mils thick on a
transparent backing of a homogeneous mixture of:
1. about 20 to 80 percent by volume of said mixture of a polymeric
binder which has a light transmittance of at least about 30 percent
for a sample 0.00092 mm. thick in at least a portion of the
spectrum between 3,400 and 6,000 angstrom units, and an index of
refraction in the range 1.4 to 2.0 and
2. about 80 to 20 percent by volume of said mixture of particles
having a diameter of about 0.1 to 3 microns of a solid material
which is insoluble in said binder, has an index of refraction in
the range 1.4 to 2.0 and has a light transmittance of at least
about 30 percent for a sample 0.00092 mm. thick at a wavelength
between 3,400 and 6,000 angstrom units at which said binder has
said light transmittance.
9. A sheet material as set forth in claim 8 in which said particles
are zinc oxide.
Description
The present invention relates to printing, and more particularly to
a sheet material to be used in a process of making offset printing
plates from type and halftone engravings. Briefly stated, type and
halftones are inked and printed on the sheet material which then
functions as a transparency in a photographic process, leading to
exposure and development of a photosensitive offset plate. Several
methods for producing a transparency useful in this way are known,
and the present invention provides improvements.
One form of material suitable for producing transparencies is a
pressure-sensitive foil. This is an opaque sheet material which can
be made clear by application of pressure. An example of such a
material previously made available is offered by duPont under the
name Cronapress. In this system, the type is first coated with an
antistatic agent, a carefully dusted film is laid over the type, a
vacuum is applied and then a pellet pressure device is placed over
the film. The device contains over 500 tiny metal balls each
weighing about 0.01 oz. and these are vibrated. They strike the
type, applying a momentary pressure of about 3 tons per square
inch. The method is extremely sensitive to dust between the type
and the film, which causes the formation of dark spots surrounded
by light halos. A further step is required to correct these. In
addition, certain kinds of type cannot be used because of the risk
of damage from the impact of the steel balls.
Another form of pressure-sensitive foil is disclosed in copending
U.S. Pat. application of Fleming et al. No. 434,694, filed Feb. 23,
1965. It involves a coating of plastic, containing an opacifying
agent, on a flexible base, which is rendered opaque and pressure
sensitive by contact with an aqueous fluid, e.g., by immersion in
boiling water, prior to use. This process, while an improvement
over prior art, still has limitations, especially in halftone
work.
Another material useful for this purpose is a form of heat
sensitive foil described in U.S. Pat. No. 2,993,805, which utilizes
essentially a sheet of vesicular photographic material which has
been exposed overall to light. The exposed sheet is contacted with
metal type at a sufficiently elevated temperature to effect
development of the film in the areas of contact. While a
transparency is obtained, the method has the practical disadvantage
that the developed areas tend to spread beyond the area contacted
by the hot type because of diffusion of heat. This gives a fuzzy
appearance to the characters, and makes halftone work very
difficult.
In another process, repro-proof printing paper, a paper coated with
a pigment in a binder, is passed over the type and/or halftone
which has been inked, and it picks up the ink on contact with the
characters. The repro-proof is then reflection-photographed with a
special camera, ordinarily with silver-sensitized film, to obtain a
silver negative which can be contact printed onto a
negative-working offset printing plate. The inherent difficulty in
this process is that the finite resolution of the camera results in
the loss of many small details of the original metal type or
halftone in making the silver negative.
A variant on the above process is repro-proof printing film, in
which the coating which contains pigment is applied to a
transparent base and is of low enough density to allow contact
printing it to silver-sensitized film to obtain the silver negative
print. Since no camera is used, resolution is no longer a serious
problem, and there is less trouble in retaining fine details of the
original metal form. The known material comprises a binder and
titanium dioxide as a pigment. However, such a material is
incapable of printing directly to an offset plate and requires
lengthy exposure in printing to the silver-sensitized film.
In essence, the present invention relates to an improved product of
the character of repro-proofing film. The product has sufficient
transmittance to light on the near ultraviolet, the range of
maximum sensitivity of diazo-sensitized offset printing plates, to
allow exposure through the product directly onto such plates,
eliminating the need for intermediate formation of a negative on
silver film and the associated steps and extra equipment to process
silver-sensitized film.
The material of the present invention comprises coating on a clear
substrate, of a homogeneous mixture of binder and small particles
of a solid material which is insoluble in the binder. The particles
of solid material and the binder have closely similar indices of
refraction.
The small particles of solid material may be of almost any material
which is relatively transparent and insoluble in the binder, in the
sense that it forms a separate solid phase having a distinct
boundary between itself and the binder. Most of the materials found
useful have been inorganic, but suitable organic substances may
also be used. By relatively transparent, it is intended to signify
that the transmittance is at least 30 percent for a sample 0.00092
millimeters thick. It is not necessary that the material be
transparent to all wavelengths of light, but only the portion of
the spectrum required to expose a photographic product, e.g. an
offset printing plate. For practical purposes with diazo and
silver-sensitized photographic products, the solid material should
have a transmittance of at least 30 percent for at least a portion
of the spectrum in the range 3,400--6,000 angstrom units.
The size of the particles of solid material should be relatively
small. Best results have been observed where the particle diameter
is in the range 0.1 to 3 microns. Of course the particles should be
relatively inert chemically to the binder. The following is a list
of some of the many materials which meet the above requirements.
##SPC1##
It also has been found possible to use small glass spheres.
The binder is a continuous coating of natural or synthetic normally
solid organic polymer. It too must be relatively transparent, that
is it must have a transmittance of at least 30 percent to light, as
defined above, to at least a portion of the spectrum, preferably in
the range 3,400--6,000 angstrom units. Preferably, the binder wets
the dispersed small particles of solid material but this is not
essential for the broader purposes of the invention. Reasonable
resistance to printing inks is desirable.
Polymers which are suitable are the vesicular photographic vehicles
disclosed in James, U.S. Pat. No. 3,032,414; Parker et al., U.S.
Pat. Nos. 3,161,511 and 3,251,690; Daech, U.S. Pat. No. 3,189,455
and Notley et al., application Ser. No. 403,633 filed Oct. 13,
1964, Ser. No. 405,597 filed Oct. 21, 1964 and Ser. No. 533,745
filed Feb. 1, 1966.
In addition to the individual requirements of the binder and
particles of solid material set forth above, an important
requirement is that the refractive index of each material be
essentially the same as that of the other material. That is, the
refractive indices of the small particles of solid material and the
binder should differ by at most .+-.0.6. the
The relative amounts of binder and particles of solid material can
be varied. In general, the amount of particles of solid material
affects the adhesion of ink to the surface of the product.
Therefore, for any given pair of materials, it is desirable to
measure ink adhesion as a function of proportions. Ink adhesion can
be measured, after drying, by rubbing. A more critical test,
probably more severe than required, is the Scotch Tape test in
which one tries to lift the ink with pressure-sensitive tape. This
is a simple experimental procedure which enables determination of
optimum proportions. However, in general, one will use about 20--80
percent by volume each of binder and particles of solid material,
preferably about 50 percent by volume of each.
The binder and particles of solid material are blended by any
suitable means to form a uniform mixture and coated on a backing to
form a layer in which the particles are uniformly dispersed in the
polymer. For example the particles of solid material may be blended
with a solution or dispersion of binder and the mixture coated on a
backing. The solvent or dispersing liquid may be evaporated.
Ordinarily the coating has a dry thickness of about 0.02 to 5 mils,
or corresponding to about 5 to 36 pounds per ream, a ream being
3,000 square feet.
As a backing material, any material which is essentially
transparent to light of the wavelength used with the product is
suitable. For example, clear polyethylene, polypropylene,
polycarbonates (e.g. G.E.'s Lexan), cellulose acetate or Mylar
(oriented polyethylene terephthalate) are satisfactory. Glass
plates also may be used.
The process is illustrated schematically in the drawing and by the
following examples, wherein all parts and percentages are by weight
unless otherwise indicated.
EXAMPLE 1 ##SPC2##
In order to obtain optimum dispersion, the zinc oxide was added to
the resin concentrate and mixed at a very high speed to impart work
on the system before adding the additional solvent (toluene). After
adding the solvent, the mixture is coated on a clear Mylar
polyester base, using traditional thin film coating equipment, at a
thickness which corresponds to approximately 18 pounds/ream of
coating after drying. The coating is dried at 140.degree. F. for 5
minutes.
A sample so prepared was mounted on a standard letterpress and
passed over an inked type form. The ink was well received by the
sheet, it showed no tendency to spread, and the letters were sharp
and clear.
EXAMPLE 2
A sample prepared as in Example 1 was printed as in Example 1. It
was contact printed to a piece of vesicular photographic image film
by exposure in a vacuum frame to a 400-watt mercury arc lamp for 2
minutes and developed with a 240.degree. F. hot roll providing a
dwell time of 2 seconds. The vesicular film was then contacted to a
negative offset plate in the usual manner familiar to those skilled
in the art. A plate of good uniform density was produced.
EXAMPLE 3
The following were assembled: ##SPC3##
These were mixed, coated and dried as in Example 1. A sample thus
produced was printed as in Example 1 and then contact printed to an
autopositive silver film using a 15 second exposure with a standard
carbon arc source. The autopositive print was then contact printed
to a positive working offset plate, resulting in a good quality
image.
EXAMPLE 4
The following were assembled: ##SPC4##
These were mixed, coated and dried as in Example 1. A sample thus
produced was mounted on a standard proofing press and passed over
an inked halftone plate. Again, there was no spreading of the dots
on the proof. It was then contact printed to a silver halide film
with a 12 second exposure from a Colight pinpoint source. The
silver print was contact printed to a negative-working plate, and
the resulting image showed sharp definition with good dot quality
and no spreading.
EXAMPLE 5
The following were assembled: ##SPC5##
These were mixed, coated and dried as in Example 1. A sample thus
produced was mounted on a standard letterpress and passed over
halftone metal form which previously had been inked. The sample was
used as in Example 2. The halftone dots maintained proper size and
clarity and a good plate was produced.
EXAMPLE 6
A sample was produced and printed as in Example 1. It was then
contact printed directly to a positive working offset plate, using
a carbon arc source for 3 minutes. The resulting plate was clear of
all background and had clear definition of the image.
* * * * *