U.S. patent number 3,552,441 [Application Number 04/670,600] was granted by the patent office on 1971-01-05 for piercable closure diaphragm for a chamber.
Invention is credited to Hartmut Luhleich.
United States Patent |
3,552,441 |
Luhleich |
January 5, 1971 |
PIERCABLE CLOSURE DIAPHRAGM FOR A CHAMBER
Abstract
A diaphragm having opposite surfaces of convex shape, in the
manner of a lens, and constituted of elastic material to enable its
being pierced by the sharp end of a hollow element and form a seal
with the hollow element during penetration and withdrawal thereof,
whereby the diaphragm can constitute a closure for an open vessel
and prevent contamination of its interior.
Inventors: |
Luhleich; Hartmut (Geesthacht,
DT) |
Family
ID: |
24691059 |
Appl.
No.: |
04/670,600 |
Filed: |
September 26, 1967 |
Current U.S.
Class: |
137/625.48;
137/318; 138/103; 138/155; 604/86; 73/864.86; 138/89; 138/120;
138/178; 604/411 |
Current CPC
Class: |
F16K
11/065 (20130101); Y10T 137/86879 (20150401); Y10T
137/6123 (20150401) |
Current International
Class: |
F16K
11/065 (20060101); F16k 011/07 () |
Field of
Search: |
;128/218.1,218.M,272
;251/Needle Valve/ ;137/525.1,318,625.68,625.4,625.48 ;141/329 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Nelson; M. Cary
Assistant Examiner: Sturm; Michael O.
Claims
I claim:
1. Apparatus for sealing a chamber, said apparatus comprising a
diaphragm constituted of a material which is pierceable by a
retractable hollow element for gaining access to the interior of
the chamber, said material being elastic and having opposite
surfaces, through both of which the hollow element passes, said
surfaces in normal, unstressed condition of the diaphragm being of
convex shape, and in consequence of the specific material of the
diaphragm, urging the diaphragm into sealing contact with the
hollow element both during penetration and retraction thereof
whereby the interior of the chamber is isolated from the outside
atmosphere.
2. Apparatus as claimed in claim 1 comprising a rigid ring, said
diaphragm being supported in said ring under pressure, said ring
having an inner diameter for receiving the diaphragm which is
smaller than the outer diameter of the diaphragm whereby the
diaphragm is compressed when mounted in the ring.
3. Apparatus as claimed in claim two wherein said ring includes a
depending portion adapted for being mounted on a vessel defining
said chamber, and an upstanding portion with a terminal annular
bulge defining an opening with said inner diameter for receiving
said diaphragm.
4. Apparatus as claimed in claim 3 wherein said ring is constituted
of elastic material which is less elastic than that of the
diaphragm.
5. Apparatus as claimed in claim 1 comprising a sleeve member
integral with said diaphragm and depending therefrom for being
mounted on a vessel defining said chamber.
6. Apparatus as claimed in claim 1 comprising a body portion
including sleeve members extending from said diaphragm for being
mounted on two vessels which are to be coupled together.
7. Apparatus as claimed in claim 6 wherein said diaphragm extends
transversely in said body portion, said sleeve members being two in
number and extending in opposite directions from said
diaphragm.
8. Apparatus as claimed in claim 6 wherein said sleeve members are
two in number and extend at right angles to one another to form a
connection element, said diaphragm being connected to said sleeve
members to form a portion of an outer wall of the connection
element.
9. Apparatus as claimed in claim 5 wherein said sleeve member has a
groove therein or receiving the end of the vessel.
10. Apparatus as claimed in claim 1 wherein said apparatus
comprises a single body which has a plurality of pierceable
bounding walls, and includes a diaphragm at each of a number of
walls.
11. Apparatus as claimed in claim 10 wherein said walls define a
polyhedron, each of the walls being provided with a diaphragm.
12. Apparatus as claimed in claim 11 wherein said polyhedron
defines an internal closed chamber.
13. Apparatus as claimed in claim 12 comprising an integral
depending sleeve member on the polyhedron for being mounted on a
vessel defining said chamber.
14. Apparatus as claimed in claim 1 in combination with said hollow
element for constituting a valve for controlling communication
between a plurality of vessels, said apparatus including a body
with means for engaging a plurality of vessels, said body being
provided with cavities in communication with respective vessels,
said cavities being arranged in alignment, said body including a
plurality of said diaphragms arranged in alignment to bound said
cavities, said hollow element having closed ends and extending
axially through said diaphragms and having a plurality of axially
spaced openings which provide communication between selected
cavities depending upon the axial position of the hollow element in
the body.
15. The combination as claimed in claim 14 wherein said hollow
element includes solid end portions beyond the endmost of said
openings. 3The combination as claimed in claim 15 wherein one of
said end portions of said hollow element extends externally of the
body, said one end portion including exposed marking means for
visually indicating the various positions for said hollow element
which provide communication between
selected cavities. 17. The combination as claimed in claim 14
wherein said body, said diaphragms, and said means for engaging the
vessels, are
integral and are formed from a one piece element. 18. Apparatus as
claimed in claim 3 comprising an internal annular projection on
said ring spaced from said diaphragm for limiting the depth of
engagement of the ring on the vessel and for covering the upper
edge of the vessel.
Description
BRIEF SUMMARY OF THE INVENTION
The invention relates to pierceable diaphragms for closures of
vessels such as ampuls flasks, cuvettes, or other chemical or
physical apparatus, as well as to parts of chemical or physical
apparatus provided with pierceable diaphragms such as prefabricated
valves provided with such diaphragms. Pierceable caps, preferably
of rubber, with a plane or convex diaphragm for closing ampuls,
flasks or nipples of chemical apparatus for operations in closed
systems are known (see Journal Kerntechnik, Isotopentechnik, and
Chemie, Vol. 7, 1965, No. 7, p.p. 326-- 329). They are applied with
a sleeve over the neck of the vessel opening and permit filling or
withdrawing substances by means of hypodermic needles. Such
diaphragms provide a reliable seal during the piercing of the
needle. By carrying along material of the diaphragm due to friction
therewith, the curvature of the diaphragm is flattened and the
diaphragm surface thus reduced, so that the material of the
diaphragm close to the surface is compressed around the needle.
When the needle is extracted, this effect is reversed, however,
since the diaphragm is curved to the outside beyond its rest
position, due to the friction on the needle, so that the edges of
the piercing point gape, resulting in leaks. The latter are
particularly evident when the vessel is under pressure. Such
diaphragms thus do not provide a reliable seal.
Pierceable diaphragms of elastic material have also been suggested
(German utility model No. 1,928,384) which are curved in the case
of substantially parallel diaphragm surfaces toward the vessel
interior. In this arrangement a leak by gaping of the edges is
avoided when the needle is extracted, but the leakage effect is
present during the piercing of the diaphragm by the needle.
In known diaphragms which are already pierced, leaks appear due to
pressure differences between the chambers separated by them, since
the piercing openings are stretched apart due to deformation of the
diaphragm. In curved diaphragms this is avoided when the pressure
acts on the convex side, but the leaks are more aggravated if the
direction of the pressure is reversed, where the piercing holes act
like valves.
An object of the invention is to provide diaphragms which avoid the
known disadvantages and which seal reliably even after several
punctures both during the piercing and the extraction of the needle
and in the case of pressure differences between the separated
chambers.
This objective is achieved according to the invention by the
provision of a convex curvature on the opposite surfaces of the
diaphragm, in the manner of a lens. The diaphragm according to the
invention consists of a sufficiently elastic material which
restores deformation immediately. Due to its convex form on both
sides, the piercing point is sealed automatically both during the
piercing and during the extraction of the needle, due to the
material of the diaphragm carried along by friction, the movement
of the needle causing flattening and inward deformation of the
convexity of the diaphragm opposing the direction of motion of the
needle whereby a reliable seal is achieved by the resulting
compression of the surface material around the needle.
In the diaphragm according to the invention no leaks are formed in
the case of pressure differences between the adjoining chambers,
since the outside curvature of the diaphragm positively prevents
gaping of the piercing holes. The pressure acts in the diaphragm
according to the invention on a curvature opposing the direction of
the pressure, so that the piercing openings are compressed and
reliably sealed.
It is of advantage to arrange the diaphragm according to the
invention so that it is under inward radial pressure at its
periphery in order to obtain an initial stress which improves the
elastic restoration of the piercing holes. Diffusion of gases
through the diaphragm is thus prevented even after several
punctures and even if there is a major pressure difference between
the chambers separated by the diaphragm. This pressure effect on
the diaphragm can be achieved by mounting the diaphragm in a ring
which is constituted of a firm or elastic material and whose inside
diameter is less than the outside diameter of the diaphragm body.
The diaphragm body is therefore inserted under pressure into the
ring. The joint between the ring and the diaphragm body can be
formed by cementing, welding or a toothing, as for example, by
corrugations.
In this arrangement it is possible to use softer rubber as a
material for the diaphragm, which by themselves would cause leaks
in their connection with the wall of the chambers to be closed by
the diaphragm, but which are better suitable to close the piercing
damages both during the stress by piercing and in the long run.
This arrangement is also particularly suitable for sealing ducts of
needles or wires extending through the diaphragm and which are to
remain therein for a longer period of time.
The diaphragm according to the invention is secured in known manner
by elastic sleeves or collars rigidly connected with the diaphragm
and pulled over the open neck of the vessels or by screwing or
pressing.
The diaphragms according to the invention can also be attached on
or in pipe lines, for example, for chemical apparatus or on or in
sleeves connecting tubes inserted therein.
The compressed diaphragms in the above-mentioned ring can be
secured together with the ring in the same manner as described
above. However, the diaphragm bodies can also be inserted under
stress in the collars, sleeves or tubes themselves, which then
assume the function of the above-described ring.
In order to avoid leaks after several punctures, several diaphragms
according to the invention can be arranged on the same opening side
by side. The diaphragm can be formed in walls defining a
polyhedron, such as a cube, and a connecting collar extends from
the polyhedron.
The diaphragms according to the invention can also be used in the
known protective tubes (see Dr. H. Luhleich: "On Isomers in the
Silane-series on the Basis of Preparative and Physical-Chemical
Investigations," Cologne, Diss, 1958, p. 55, journal: Zeitschrift
f. inoganische and allegemeine Chemie, Vol. 303, 1960, p.p.
294--302 and journal: Zeitschrift f. Naturforschung, Vol. 14 b, No.
7, 1955, p.p. 466 and 467). The protective tube can be designed
preferably as a closed hollow body where opposing walls include
diaphragms according to the invention, particularly in the form of
a cube, in each of the six faces of which is provided a
diaphragm.
In a corresponding manner the diaphragms according to the invention
can also be used in the known sealing lock technique (see German
utility model No. 1,920,471) which serves to improve the sealing of
pierceable cap closures. Instead of two superposed piercing caps, a
hollow body can be arranged ahead of the diaphragm directly sealing
the opening to be sealed, in the wall of which are provided several
diaphragms according to the invention side by side.
In another embodiment of the invention valves can be formed by
using the diaphragms according to the invention. In the walls of
the valve chambers, namely between the latter and the outside
atmosphere, there are arranged diaphragms according to the
invention in series in parallel planes in such a way that they can
be pierced jointly by a needle. In a wall of the needle penetrating
them in this manner, are provided lateral openings by which the
chambers of the valves are connected with each other selectively,
depending on the depth of puncture of the needle. Such valve
arrangements can be composed of a one piece body with integral
diaphragms according to the invention, or they can consist of a
uniform body provided with pipe connection sleeves.
Finally, chemical or physical apparatus can be assembled easily and
without difficulty so that they can be exchanged and used again
from single elements carrying diaphragms according to the invention
together with pipe connection, angle and reducing sleeves with
standardized connection cross sections of rubber or other elastic
material together with other standardized elements, pipe lines and
devices according to the assembly system.
If diaphragms according to the invention are exposed to corrosive
substances or to higher temperatures, surface coatings, for example
of inert metals or any other laminated structure may be of
advantage.
BRIEF DESCRIPTION OF THE DRAWING
FIG. 1 is a sectional view of a pierceable cap with a diaphragm
according to the invention;
FIG. 2 is a sectional view of a known cap with curved
diaphragm;
FIG. 3 is a sectional view of the known cap according to FIG. 2
during the extraction of a needle;
FIG. 4 is a sectional view of the pierceable cap with the diaphragm
according to the invention during the extraction of the needle;
FIG. 5 is a sectional view of another embodiment of the diaphragm
according to the invention;
FIG. 6 is a sectional view of a pierceable cap with the diaphragm
according to the invention inserted therein;
FIGS. 7 and 8 are sectional views of diaphragms secured on the open
neck of a vessel;
FIG. 9 is a sectional view of a diaphragm according to the
invention which is secured under pressure with a flanged sheet
metal ring on the open neck of a vessel;
FIGS. 10 and 11 are sectional views of diaphragms according to the
invention, which are connected with integral fastening collars
mounted on the open neck of a vessel;
FIG. 12 is a sectional view of a diaphragm according to the
invention arranged in the wall of an elbow pipe connection
member;
FIG. 13 is a sectional view of a pipe connection member with a
diaphragm according to the invention arranged transversely
therein;
FIG. 14 is a side view of a pierceable cap with five walls with
diaphragms according to the invention;
FIG. 15 is a sectional view of the pierceable cap of FIG. 14;
FIG. 16 is a side view of a pipe connection member with four walls
having diaphragms according to the invention arranged therein;
FIG. 17 is a sectional view of the pipe connection member of FIG.
16;
FIG. 18 is a sectional view of a protective tube with two
diaphragms according to the invention in the form of a closed
hollow body;
FIG. 19 is a side view of a protective tube in the form of a cubic
closed hollow body with six diaphragms according to the
invention;
FIG. 20 is a sectional view of the protective tube of FIG. 19;
FIG. 21 is a side view of a sealing lock with five outside
diaphragms according to the invention and one inside diaphragm
according to the invention;
FIG. 22 is a sectional view of the sealing lock of FIG. 21;
FIG. 23 is a sectional view through a two-way valve composed of a
connection member according to FIG. 12 and one according to FIG.
13;
FIG. 24 is a sectional view of a two-way valve according to the
invention; and
FIG. 25 is a sectional view of a three-way valve according to the
invention.
DETAILED DESCRIPTION OF THE INVENTION
In FIG. 1 there is shown a cap C with a lens-shaped diaphragm 1
provided with a convex outer surface 2 and with a convex inner
surface 3. A connection sleeve 4 extends from the diaphragm and can
be attached to a vessel or tube 5 with a contact pressure
sufficient for sealing the vessel or tube 5 (FIG. 4). The diaphragm
1 and sleeve 4 are integral and composed of elastic material, as
for example, rubber.
FIG. 2 shows for comparison purposes a known pierceable cap with a
diaphragm having a planar inner surface 3a. The caps are adapted
for being placed on vessels such as flasks, ampuls, tubes etc. for
closing the open mouths thereof. In order to remove or introduce a
substance in the vessel, a hollow tubular element such as a
hypodermic needle is inserted into the vessel through the
diaphragm. Such hollow tubular elements will hereafter be referred
to simply as a tubule.
FIG. 3 shows the extraction of a tubule 6 from the known cap with
the diaphragm with the plane surface 3a. Since the material of the
diaphragm is pulled upwardly with the tubule due to the frictional
engagement with the tubule, the region where the tubule pierces the
cap is caused to widen externally thereby exposing an opening for
the penetration into the vessel of impurities from the outside
atmosphere.
FIG. 4 shows how the material at the surface 3 of the diaphragm
according to the invention is compressed around the tubule by the
removal of the tubule so that the danger of leakage is positively
prevented. During the piercing of the cap with the tubule, the
process is correspondingly reversed. Thus, the diaphragm according
to the invention is capable of sealing the vessel both during
insertion and removal of the tubule from the diaphragm.
In FIG. 5 the diaphragm body 7 is inserted into a tension ring 8
whose inside diameter is smaller than the outside diameter of the
normal diaphragm body 7. Consequently, the diaphragm is compressed
by its insertion into the tension ring 8. Thereby, the diaphragm is
subjected to an initial radial stress which tends to close any
openings formed in the diaphragms thus maintaining the interior of
the vessel isolated from the outside atmosphere.
The ring 8 can consist of rigid or elastic material. In the latter
case, the inside diameter of the ring must be somewhat smaller to
compensate for its expansion. The diaphragm body 7 consists of a
relatively soft rubber, which closes the piercing openings
automatically since it is under initial stress by the pressure of
the ring.
In the cap represented in FIG. 6, an annular bulge 9 at the upper
edge of the collar 4 performs the function of the tension ring 8.
Its inside diameter, before insertion of the diaphragm body 7, is
likewise smaller than the outside diameter of the diaphragm body.
When the diaphragm body 7 is inserted into the ring 9, the upper
part of the collar 4 is widened. In order to avoid loosening of its
seat on the neck 5 of the vessel, an annular internal projection 10
constituting a stop is provided on the inside of the collar 4 which
limits penetration of the neck 5 and at the same time protects the
penetrating point of the tubule against damage by contact with the
edge of the vessel neck 5. The material of the diaphragm body 7 is
softer than the rubber of which the collar 4 is made.
FIGS. 7--11 show different known means of fastening the diaphragm
according to the invention on the neck of the vessel 5. In FIGS. 7
and 8 the diaphragm is secured by screwing, in FIG. 9 by flanging
and in FIGS. 10 and 11 by insertion of the neck in an annular
groove provided in the collar 4.
FIGS. 12 and 13 show diaphragms 1 formed in vessel connection
elements having collars 4 for receiving the ends of the vessels 5
to be connected. In FIG. 12 the diaphragm 1 is formed in a wall of
the connection element whereas in FIG. 13 the diaphragm 1 extends
transversely between sleeves 4 which engage the vessels 5.
FIGS. 14 and 15 show a cap of rubber or corresponding elastic
material, wherein diaphragms 1 are provided on five sides in cubic
arrangement. It thus becomes possible to puncture the cap in the
walls of all five sides, thereby enhancing considerably the use and
longevity of the cap.
FIGS. 16 and 17 show a vessel connection element with diaphragms 1
according to the invention in corresponding multiple arrangement,
and wherein collars 4 are mounted on tube ends 5. Here again, all
of the walls with the diaphragms may be pierced thereby prolonging
the use of the connection element.
In the embodiment represented in FIG. 18, two opposing diaphragms
according to the invention are combined to form a uniform hollow
body. In the embodiment according to FIGS. 19 and 20, this hollow
body is in the shape of a cube in each wall of which, is provided a
diaphragm 1. FIGS. 21 and 22, show a sealing cap which corresponds
in its arrangement to the protective tube according to FIG. 19,
there being provided a depending collar 4 rigidly connected with
the cube for attachment on a vessel 5.
In FIG. 23 the embodiments according to FIGS. 12 and 13 are
connected by a tubular piece 5a to form in combination with a
tubule 11 a valve arrangement, as will be described hereafter. By
inserting the tubule 11 through the diaphragms 1b and 1c a
passageway is formed between the ends of vessels 5b and 5c via a
lateral opening 12 in the tubule wall. This passageway is closed,
when the point of the tubule is retracted in or withdrawn from
diaphragm 1c.
In FIG. 24 there is shown a two-way valve in open position. The
valve is constituted by a body 13 made entirely of elastic material
and a tubule 17. The body 13 which preferably has a round cross
section, is provided with two radial connection collars 4 for the
ends of vessels 5c and 5b. Tube 5b opens into a cavity 14 in the
body 13 and tube 5c opens into cavity 15 in the body. Cavity 14 is
bounded on opposite sides by the two diaphragms 1b and 1c. Cavity
15 is bounded on one side by diaphragm 1c and on the opposite side
by body 13. On the upper surface of the body 13 is a guide 16 for
the tubule 17. The latter penetrates axially through the diaphragms
1b and 1c and its pointed end pierces the body below the cavity 15.
The tubule has two lateral openings 18a and 18b as well as setting
marks 19a and 19b on its shaft. The tubule is solid beyond the
openings. The valve is opened by setting the tubule 17 at mark 19b
by establishing communication between the tubes 5c and 5b via
cavities 14, 15, and lateral openings 18a and 18b of the tubule 17.
When the tubule 17 is set at mark 19a, the lateral openings 18a and
18b are respectively inside the diaphragm 1c and body 13 so that
communication between the ends of vessels 5b and 5c is
interrupted.
The three-way valve represented in FIG. 25 corresponds in its
material and principal arrangement to the valve represented in FIG.
24. In contrast to the latter, however, there are provided three
collars for the vessels 5a, 5b, and 5c and corresponding cavities
20, 21 and 22 which are separated from each other by diaphragms 1c
and 1d according to the invention. Lateral openings 18c, 18d, 18e,
18g, 18h, 18i, are provided in the walls of the tubule 17a and
respective setting marks 19c, 19d, 19e, 19f, 19g, 19h, are formed
on the tubule shaft. The tubule is solid beyond the endmost
openings 18c, 18i.
When setting the tubule to mark 19c, a passageway is established
between tubes 5b and 5c via the lateral openings 18d and 18g. When
the tubule is set at mark 19d, all lateral openings 18c to 18i, are
embedded in the material of the body 13 and the diaphragms 1b, 1c
and 1d, so that the valve is closed. When the tubule is set at mark
19e, a passageway is established between the tubes 5a, 5b and 5c
via lateral openings 18c, 18f and 18h. When the tubule is set at
mark 19f, a passageway is formed between tubes 5a and 5b via the
lateral openings 18d and 18g. Finally, when the tubule is set at
mark 19g a passageway is formed between tubes 5a and 5c via lateral
openings 18i and 18e.
The bodies according to the invention, carrying the diaphragms,
represented in FIGS. 12 to 25 can be made as a one piece body of
elastic material. However, diaphragms 7 of softer elastic material
as shown in FIG. 5, can be inserted into these bodies when mounted
in a tension ring 8. On the other hand, the mountings or walls of
these bodies can assume the function of the tension rings 8, as was
described for the annular bulge 9 in FIG. 6.
The embodiments described here can be used with standardized tube
cross sections and by means of connection sleeves, angles, reducing
or branching pieces together with vessels, ampuls or devices, there
can be formed according to the invention an assembly system which
can serve as exchangeable and reusable parts for apparatus, such
as, for chemical purposes.
The advantages achieved with the invention lie in the reliable
sealing, which excludes even traces of impurities, during and after
the introduction and withdrawal into or from chambers closed by
diaphragms according to the invention, as it is necessary when
working in closed systems. Such seals could be obtained heretofore
only partially and only by means of complicated measures. Another
advantage is the easy exchangeability and the resulting possible
combination of the elements equipped with diaphragms according to
the invention, but particularly the simplicity of the sealing parts
according to the invention, which applies particularly to valves
produced with diaphragms according to the invention.
* * * * *