U.S. patent number 3,910,831 [Application Number 05/452,207] was granted by the patent office on 1975-10-07 for hydrogen generating system.
Invention is credited to Alfred G. Helart.
United States Patent |
3,910,831 |
Helart |
October 7, 1975 |
Hydrogen generating system
Abstract
A hydrogen generator comprises a U-tube electrolysis unit, the
hydrogen being produced in one side and oxygen in the other. The
hydrogen is passed from the unit through filter chambers for
preventing the final discharge of acid or of water and the hydrogen
is stored in a tank containing lanthanum-nickel alloy for
increasing the storage capacity.
Inventors: |
Helart; Alfred G. (Lakewood,
CO) |
Family
ID: |
23795525 |
Appl.
No.: |
05/452,207 |
Filed: |
March 18, 1974 |
Current U.S.
Class: |
204/278; 204/258;
204/266; 96/119; 96/132 |
Current CPC
Class: |
C01B
3/0005 (20130101); C01B 3/0068 (20130101); C25B
1/04 (20130101); C01B 3/56 (20130101); C01B
2203/042 (20130101); C01B 2203/0465 (20130101); Y02E
60/32 (20130101); Y02E 60/36 (20130101) |
Current International
Class: |
C25B
1/00 (20060101); C25B 1/04 (20060101); C01B
3/56 (20060101); C01B 3/00 (20060101); C25B
001/04 (); C25D 015/08 (); B01J 001/22 () |
Field of
Search: |
;204/129,275-278,258,266
;55/16,74 ;252/462,463 |
References Cited
[Referenced By]
U.S. Patent Documents
Foreign Patent Documents
Primary Examiner: Mack; John H.
Assistant Examiner: Weisstuch; Aaron
Attorney, Agent or Firm: Edwards; Wm. Griffith
Claims
I claim:
1. A hydrogen gas generating and storage system comprising:
means utilizing the electrolysis of water for producing oxygen and
hydrogen and including means providing zones for collecting and for
discharging the two gases separately;
means for supplying water to said producing means and for
maintaining a predetermined range of pressures in said system;
a reservoir for storing the hydrogen gas at the pressure maintained
by said supplying means and connected to the hydrogen zone of said
producing means;
a body of lanthanum-nickel in said reservoir for raising the
storage capacity thereof; and,
means for withdrawing hydrogen from said reservoir for use.
2. A hydrogen gas generating and storage system as set forth in
claim 1 including means connected between said producing means and
said storage means for removing water from the hydrogen flowing to
said storage reservoir.
3. A hydrogen gas generating and storage system as set forth in
claim 1 including means for removing acid from the hydrogen flowing
toward said reservoir.
4. A hydrogen gas generating and storage system as set forth in
claim 1 including filtering and cleaning means for removing foreign
matter from the hydrogen and disposed in a hydrogen conduit between
said producing means and said reservoir means for supplying
substantially pure hydrogen to said reservoir.
5. A hydrogen gas generating and storage system as set forth in
claim 1 wherein said producing means is an electrolysis generator
of the U-tube type wherein oxygen is generated in the water inlet
leg of the U-tube and hydrogen in the other leg thereof and
including a first float controlled valve for shutting the water
supply on a predetermined rise of water in said inlet leg and a
second float controlled valve for closing the hydrogen outlet of
said producing means upon a predetermined rise of water in said
other leg.
6. A hydrogen gas generating and storage system as set forth in
claim 4 including two closed chambers connected in series in the
hydrogen conduit between said producing means and said reservoir,
one of said chambers having means for retaining a mass of acid
removing material therein and having means for directing the flow
of hydrogen from the lower portion upwardly through said mass, and
the second of said chambers having a mass of dehydrating material
therein and means for directing the hydrogen flowing therethrough
upwardly through said mass.
7. A hydrogen gas generating and storage system as set forth in
claim 1 including filter means connected in the discharge conduit
of said reservoir for removing particulate matter from the hydrogen
removed from said reservoir.
8. A hydrogen gas generating and storage system as set forth in
claim 4 including detachable couplings in the hydrogen conduit
between said producing means and said filtering and cleaning means
and between said last mentioned means and said reservoir, and
shut-off valves on each side of each of said couplings for
preventing the loss of hydrogen to the atmosphere.
9. A hydrogen gas generating and storage system comprising:
means utilizing the electrolysis of water for producing oxygen and
hydrogen including means providing respective separate zones for
collecting the gases and means for discharging the separate
gases;
means for supplying water under pressure to said producing means
and utilizing the pressure of the water for maintaining a
predetermined range of pressures in said system;
a closed reservoir connected to the hydrogen zone of said producing
means for receiving the discharged gas for storage at the pressure
maintained by said supplying means;
a body of metal alloy capable of absorbing large amounts of
hydrogen gas at pressures of the order of twenty-five pounds
arranged in said reservoir for raising the storage capacity
thereof; and,
means for discharging hydrogen from said reservoir for use.
10. A hydrogen gas generating and storage system as set forth in
claim 9 wherein said producing means is an electrolysis generator
of the U-tube type wherein oxygen is generated in the water inlet
leg of the U-tube and hydrogen in the other leg thereof and
including a first float controlled valve for shutting the water
supply on a predetermined rise of water in said inlet leg and a
second float controlled valve for closing the hydrogen outlet of
said producing means upon a predetermined rise of water in said
other leg and wherein said separate zones lie in the upper portions
of respective ones of said legs.
Description
My invention relates to hydrogen gas generators and particularly to
an improved hydrogen generator for storing the gas at relatively
low pressures.
The production of hydrogen gas by the electrolysis of water is well
known and many designs of apparatus have been provided for this
purpose. The use of hydrogen for the production of heat by
combustion is attractive from the standpoint of minimizing
atmospheric pollution, the product of combustion being pure water
vapor. The storage of hydrogen involves the problems of high
pressure gas storage and it is desirable to store the gas at as low
a pressure as can be used while storing sufficient gas in an
economical manner and in quantities sufficient for relatively long
periods of time. Accordingly, it is an object of my invention to
provide an improved system for the economical generation and
storage of hydrogen gas.
It is another object of my invention to provide a hydrogen gas
generating system including a new and improved arrangement for
storing the generated gas in preparation for use.
Briefly, in carrying out the objects of my invention in one
embodiment thereof, an electrolysis unit of the U-tube type is
connected to discharge hydrogen to cleaning equipment for removing
acid and water and thence to a storage chamber. The water input to
the electrolysis unit is controlled by a float valve on the oxygen
side of the unit and the discharge of hydrogen is shut off by a
float valve or a predetermined rise of water in the hydrogen side.
Acid is prevented from reaching the storage tank by a mass of zinc
particles in a first cleaning stage and water is trapped by a mass
of granular calcium chloride in a second cleaning stage. The
hydrogen is stored in a reservoir at pressure dependent upon the
supply pressure of the water at the electrolysis unit. The storage
reservoir is charged with a quantity of lanthanum-nickel which
absorbs hydrogen without chemical change and greatly increases the
storage capacity of the reservoir.
The features of novelty which characterize my invention are pointed
out with particularity in the claims annexed to and forming a part
of this specification. My invention itself, however, both as to its
organization and its method of operation together with other
objects and advantages thereof, will best be understood upon
reference to the following description taken in connection with the
accompanying drawing in which the single FIGURE represents
diagrammatically a hydrogen gas generator embodying my
invention.
The drawing illustrates a sealed hydrogen generating and storage
system. This system includes a hydrogen generator comprising a
U-tube electrolysis unit 10 arranged to receive water through an
inlet 11 under control of an automatic pressure regulating valve 12
and to deliver it to the U-tube under control of a float valve 13.
The valve element, which is indicated diagrammatically, is
preferably of the needle type for fine control and shut-off. The
details of the valve are not shown as they are not essential to an
understanding of the invention. The valve is actuated by a pair of
floats, one on either side of an electrode 14 and connected by a
yoke 15, only the near side float appearing in the drawing as
indicated at 16. The electrode 14 extends through a sealed top cap
17 from which it is insulated by a bushing 18 of a suitable
insulating material. The water pressure at the valve inlet is
indicated by a gauge 19 connected to the inlet 11. The other side
of the U includes an electrode 20 mounted in a sealing cap 21 in an
insulated bushing 22 and extending downwardly into the right hand
leg of the U. The liquid in the U-tube is a suitable electrolyte
and in the present system may be a dilute solution of sulphuric
acid. Oxygen is generated in the left hand leg and hydrogen in the
right hand leg when a current is passed between the electrodes 14
and 20, the electrode 14 being the anode and the electrode 20 the
cathode. The anode 14 is preferably nickel plated and the cathode
20 is made of iron without plating. As the gases are produced by
electrolysis in the generator 10, oxygen is removed for use or
dissipated to the atmosphere from the left hand leg of the U-tube
through the control valve of a gas pressure regulator 23. Hydrogen
flows from the right hand leg through a conduit 24 and into an acid
removing chamber 25. The chamber 25 is cylindrical and provided
with a sealed top 26 secured by bolts 27 to a flange 28 at the top
of the cylinder. The conduit 24 is provided with a flanged coupling
30 and manual shut-off valves 31 and 32 which are closed when the
flange 30 is opened for servicing. A check valve 33 is provided in
the conduit 24 between the flange 30 and the valve 31 for
preventing back flow from the chamber 25 to the U-tube. In the
event that the electrolyte rises sufficiently, a float controlled
valve 34 is closed. This valve is controlled by a pair of floats
similar to those of the valve 15, one on either side of the
electrode 20, the near one of which appears at 35. The two floats
are connected by a yoke 36 attached to the valve 34.
The conduit 24, the water inlet conduit 11 and a conduit 43 through
which the oxygen is discharged, are all insulated from the outer
metal wall of the U-tube in a manner similar to the insulation
between the electrodes and the top caps 17 and 21. The insulation
between the wall of the U-tube and the conduits is indicated at 44,
45 and 46 for the conduits 11, 24 and 43, respectively. The U-tube
10 comprises an outer metal wall 47 and a glass liner 47a.
Hydrogen gas flowing through the conduit 24 flows downwardly toward
the bottom of the chamber 25, a screen or foraminous plate 37 being
provided at the bottom and extending across the entire cross
section of the chamber except for an opening accommodating the tube
24. The screen 37 slopes in all directions away from the outlet of
the conduit 24a and supports a mass of zinc particles generally
indicated at 38. The screen 37 prevents the particles from falling
to the bottom of the chamber 25 and holds them in position so that
all the gas which flows through the conduit 24 must flow up through
the mass of zinc particles before it can be discharged from the
chamber through the discharge outlet indicated at 40. In the event
that excess water or electrolyte should be accumulated in the
chamber 25 under unusual conditions of operation, a float 41 is
arranged to close a valve 42 to prevent passage of the electrolyte
into the conduit 40.
The hydrogen gas which has passed through the chamber 25 and out
through the conduit 40 and its downwardly extending portion
indicated at 40a within a second chamber 48, and flows upwardly in
the chamber 48 from the bottom portion after passing through a
screen or foraminous plate 50, and passes through a mass of
granular calcium chloride 51 for the purpose of removing any water
which may have reached the chamber 48. The two sections of the
conduit 40 between the chambers 25 and 48 are joined by a
detachable flanged coupling 52 and are provided with respective
shut-off valves 53 and 54 for preventing the passage of gas in or
out of the two chambers when the coupling is opened. The dry
hydrogen gas passes out of the chamber 48 through a conduit 55
having therein a filter 56 and a shut-off valve 57. This gas flows
through a detachable flanged coupling 58 and a shut-off valve 60
and thence downwardly through a conduit 61 to a storage tank 62. A
safety or emergency float valve comprising a valve 63 and a float
64 is provided in the tank 48 to close the outlet in the event of
flooding of the chamber 48. In the event of such emergency this
prevents the admission of water to the storage tank 62. The storage
tank 62 is provided with an outlet conduit 65 from the top thereof
and the conduit is provided with a shut-off valve 66 and a filter
67. A supply conduit 68 for an appliance or other utilization
device employing hydrogen is connected to the conduit 65 by a
flanged coupling 70 and is provided with a manual shut-off valve
71. The pressure within the system as illustrated in the drawing is
controlled by the pressure of the water entering the electrolysis
unit 10 through the inlet 11. The system throughout is
substantially at this pressure except for differences in pressure
due to the flow of the hydrogen gas, and for differences in
pressure due to the water levels in the U-tube. The combined action
of the regulators 12 and 23 serves to control the pressure in the
system and maintain it within selected limits. For example, with a
water supply pressure at say fifty pounds per square inch, the
regulators may be set to maintain a system pressure of the order of
twenty-five pounds per square inch for the generation and storage
of hydrogen. The pressure maintained in the system may be somewhat
variable over a selected relatively narrow range in the
neighborhood of twenty-five pounds per square inch during the
operation of the system.
It is desirable to store large quantities of gas without requiring
storage at high pressure and for this purpose I provide in the
storage tank 62 a body of lanthanum-nickel alloy indicated at 72
and which is initially in the form of rods or bars as supplied by
the manufacturer. At the present time this lanthanum-nickel alloy
may be purchased from Molybdenum Company of America, White Plains,
New York. Over the period of the operation of the system,
lanthanum-nickel (La.sub.2 Ni.sub.5) disintegrates from its bar
form and forms a mass of powdered material in the lower portion of
the tank 62. This material will last as a storage means over a long
period of time provided water and oxygen or other substances
capable of reacting with the alloy are prevented from reaching it.
The lanthanum-nickel alloy has the property of absorbing large
amounts of hydrogen and the presence of the metal within the tank
makes it possible to charge a substantially greater volume of gas
within the tank than can be charged in the tank at the same
pressure without the metal present. As a result, substantial
amounts of hydrogen gas may be stored within the tank 62 for use as
required by the utilization devices connected to the supply conduit
68. The electrolysis generator 10 may thus be run substantially
continuously over long periods of time subject to shut-down in the
event of long periods of non-use of a stored gas. The electrolysis
operation is discontinued when the gas in the tank 62 reaches a
predetermined pressure which forces the electrolyte in the U-tube
down below the electrode 20 and which disconnects the electric
circuit until the electrolyte again rises to contact the electrode,
whereupon the generation of hydrogen is resumed.
The hydrogen generating system as disclosed has the advantage of
providing a gas which is clean in that it burns without particulate
residue, the product of combustion being pure water vapor.
The electricity for operation of the electrolysis generator may be
supplied in any suitable manner and for many installations it is
preferable to employ electrical generating means which do not
require the combustion of ordinary fuels. Thus, water wheel
generators, windmills and solar generators are suited for use in
connection with this system. In all cases the electrolysis
generation may be continued during the operation of the water
wheel, windmill or solar generator to store substantial amounts of
hydrogen during the active period of the power means, the hydrogen
being available over extended periods due to the increased storage
capability of the tank 62 when the generator is not in
operation.
While I have illustrated a specific preferred arrangement of my
hydrogen gas generating system, other applications and
modifications will occur to those skilled in the art. Therefore, I
do not desire my invention to be limited to the details of the
system illustrated and I intend by the appended claims to cover all
modifications which fall within the spirit and scope of my
invention.
* * * * *