U.S. patent number 3,872,604 [Application Number 05/460,528] was granted by the patent office on 1975-03-25 for process of treating laundry in laundry driers.
This patent grant is currently assigned to Joh. A. Benckiser GmbH. Invention is credited to Herbert Keller.
United States Patent |
3,872,604 |
Keller |
March 25, 1975 |
Process of treating laundry in laundry driers
Abstract
The novel and advantageous process of treating laundry comprises
predrying the washed and rinsed laundry to a predetermined degree
of dryness such as to a moisture content between 5 and 70 percent
and preferably to a moisture content of about 15 percent,
subjecting the predried laundry, preferably in a laundry drier, to
the action of laundry treating agents, such as brighteners,
antistatic, softening, aromatizing, and the like agents, preferably
by spraying said agents thereon, and completing drying of the
laundry. Thereby, any moldy smell of the laundry and/or its
becoming electrostatically charged are eliminated and/or the
properties of the finished laundry are considerably improved.
Drying is preferably effected in laundry dryers of the tumbler type
and the treating composition is preferably sprayed on the laundry
in aerosol form.
Inventors: |
Keller; Herbert
(Ludwigshafen/Rhein, DT) |
Assignee: |
Joh. A. Benckiser GmbH
(Ludwigshafen/Rhein, DT)
|
Family
ID: |
5877909 |
Appl.
No.: |
05/460,528 |
Filed: |
April 12, 1974 |
Foreign Application Priority Data
|
|
|
|
|
Apr 13, 1973 [DT] |
|
|
2318596 |
|
Current U.S.
Class: |
34/342;
427/242 |
Current CPC
Class: |
D06M
13/46 (20130101); D06F 58/30 (20200201); C11D
3/001 (20130101); C11D 11/0017 (20130101); C11D
17/0043 (20130101); D06F 58/203 (20130101) |
Current International
Class: |
C11D
3/00 (20060101); D06M 13/46 (20060101); D06M
13/00 (20060101); C11D 11/00 (20060101); D06F
58/20 (20060101); F26b 003/00 () |
Field of
Search: |
;34/9,17,133 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Camby; John J.
Attorney, Agent or Firm: Radde; Erich M. H.
Claims
I claim:
1. In a process of subjecting laundry to a finishing treatment, the
improvement which consists in the steps of
a. predrying the laundry to a moisture content between about 5
percent and about 70 percent subsequently to the rinsing step,
b. spraying upon the predried laundry a composition containing at
least one conventional agent for treating laundry to improve its
properties, and
c. completing drying.
2. The process of claim 1, in which solutions of such agents are
sprayed upon the predried laundry.
3. The process of claim 1, in which emulsions of such agents are
sprayed upon the predried laundry.
4. The process of claim 1, in which the laundry is predried in step
(a) to a moisture content of about 15 percent.
5. The process of claim 1, in which the treating composition is
sprayed automatically upon the laundry, said spraying being
initiated by an impulse controlled by and dependent on the drying
time.
6. The process of claim 1, in which the spraying step is
automatically initiated at a predetermined degree of dryness.
7. The process of claim 1, in which the composition consists of
10 parts to 50 parts of a non-combustible aerosol propellant,
0.5 parts to 80 parts of water,
0.0 parts to 50 parts of a cationic surface active treating
agent,
0.0 parts to 5 parts of a deodorant,
0.0 parts to 5 parts of an optical brightener, and 0.0 parts to 5
parts of a perfume,
at least one of said treating agents being present in said
composition.
8. The process of claim 1, in which the composition consists of
10 parts to 50 parts of a non-combustible aerosol propellant,
0.5 parts to 80 parts of water,
0.0 parts to 50 parts of a non-ionogenic treating agent,
0.0 parts to 5 parts of a deodorant,
0. 0 parts to 5 parts of an optical brightener, and
0.0 parts to 5 parts of a perfume,
at least one of said treating agents being present in said
composition.
9. The process of claim 7, in which at least part of the water is
replaced by an organic solvent.
10. The process of claim 8, in which at least part of the water is
replaced by an organic solvent.
11. In a process of subjecting laundry to a finishing treatment
with at least one of the finishing agents selected from the group
consisting of a cationic surface active treating agent, a
non-ionogenic surface active treating agent, an antistatic agent, a
perfume, a deodorant, an optical brightener, a dyestuff, a
germicidal agent, a starching agent, and a softening agent, the
improvement which consists in the steps of
a. predrying the washed and rinsed laundry to a moisture content
between about 5 percent and about 70 percent
b. spraying upon the predried laundry a composition containing at
least one of said finishing agents, and
b. completing drying of the thus treated laundry.
12. The process of claim 11, in which the rinsed laundry is
predried in step (a) to a moisture content of about 15 percent.
Description
BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to a process of treating laundry in
laundry driers and more particularly to a process of treating the
laundry in such driers in order to eliminate the undesired moldy,
typical laundry smell and/or electrostatic charging of the
laundry.
2. Description of the Prior Art
During the last few years laundry driers, socalled tumblers, which
are controlled, regulated, and operated electronically and/or in
dependence on the drying time, have been marketed. In such laundry
driers or tumblers the washed laundry can be dried so that, after
being centrifuged in the automatic washing machine, it is ready for
ironing or can be placed into the linen closets or storage
rooms.
However, when drying the laundry in such driers, it frequently
takes on an undesired moldy, typical laundry smell and/or it
becomes electrostatically charged. Especially laundry consisting of
or containing synthetic fiber material has the tendency to be
electrostatically charged.
In order to overcome these disadvantages the laundry was
additionally subjected, after having been washed and rinsed --
usually four to five times -- in the washing machine to a so-called
softening rinsing procedure. Thereby, preferably cation active
and/or non-ionogenic agents, emulsifiers, perfumes, optical
brighteners or clarifying agents, deodorants, and coloring agents
were added to the rinsing water. Part of said agents get on or
become attached to the laundry and are supposed to prevent the
above-described disadvantages on subsequently drying the laundry in
the laundry drier. However, no satisfactory results could be
achieved by proceeding in this manner because said agents -- most
of which are readily volatile -- were separated and removed from
the laundry during drying by the air current which passes through
the tumbler. Thus the losses in such agents were considerable.
Furthermore, rather large amounts of said agents added to the
rinsing liquor, did not adhere to the laundry but went along
together with the rinsing water. As a result thereof the rinsing
water containing such agents represents a rather considerable
burden upon sewage or waste water purification. This is highly
undersirable in view of the attempts to protect the
environment.
In addition thereto such softening rinsing procedure followed
automatically the rinsing procedures in the washing machine. As a
result thereof, the entire laundry present in the washing machine
is -- by necessity -- treated although this is not always required
and sometimes even not desired, for instance, with laundry which is
to be starched subsequently.
Also cartridges filled with concentrated perfume solutions have
been placed at a predetermined position into the air current
circulating through the tumbler in order to transfer by
vaporization the perfume upon the laundry. Proceeding in this
manner, however, is accompanied by two rather important
disadvantages. On the one hand, only readily volatile perfumes can
be applied in this manner to the laundry and, on the other hand,
such application of the perfume takes place during the entire
drying procedure. As a result thereof a large proportion of the
vaporized perfume is carried along by the air current and is
carried away and thus is not absorbed by the laundry.
SUMMARY OF THE INVENTION
It is one object of the present invention to provide a simple and
effective process of treating laundry in laundry driers so as to
eliminate, for instance, the moldy smell of dried laundry and that
it becomes electrically charged.
Another object of the present invention is to provide a simple and
effective device for carrying out said process.
Other objects of the present invention and advantageous features
thereof will become apparent as the description proceeds.
In principle the process according to the present invention
comprises the step of applying the treating solutions or emulsions
of agents for treating laundry -- as they are known per se -- in
the laundry drier or tumbler after the laundry has attained a
predetermined degree of dryness. When proceeding in this manner the
above-described disadvantages of the known processes are
avoided.
Preferably the solutions or emulsions of the laundry treating
agents are sprayed upon the laundry whereby the spraying operation
is automatically initiated by a timing impulse or as soon as a
predetermined degree of dryness of the laundry is attained.
For this purpose there is installed in the tumbler, for instance,
an aerosol can or container at any place readily accessible to the
operator. Said aerosol can is connected by means of a suitable
pipeline with a nozzle which is in direct connection with the inner
space of the drying drum. A valve is actuated at a predetermined
moment by means of an electrical or mechanical impulse so that the
treating agents are sprayed into the rotating or tumbling
laundry.
Thereby, it is of advantage if spraying with the treating agents
takes place shortly before the laundry is completely dried.
Preferably the moisture content of the laundry should amount to
between about 5 percent and about 70 percent and most
advantageously to about 15 percent.
The process according to the present invention has the great
advantage -- in contrast to the heretofore known processes -- that
the agents used for treating the laundry are directly applied in
the desired concentration to the laundry without any loss of active
agent. As a result thereof, the effectiveness of the treating
agents is fully preserved and the disadvantages of the known
processes are not encountered.
All agents can be used in the process of the present invention that
are able and required to improve the quality of the laundry, such
as cation-active and/or non-ionogenic agents, antistatic agents,
perfumes, deodorants, optical brighteners, dyestuffs, and
others.
In addition to their brightening effect, the cation-active and/or
non-ionogenic agents used in the treatment of textiles according to
the present invention cause formation of layers and preferably of
monomolecular layers of said agents on the textile fibers and thus
produce a sliding effect of the fibers with respect to each other.
Said layers improve also sliding of the textile fibers on the skin
of the person wearing the laundered lingerie or garment. As a
result thereof, a positive feel and a pleasing fall of the textile
material will be achieved and subsequent ironing will be
facilitated. Furthermore, usually the layers have a pronounced
effect of dissipating static electricity and the textiles can be
more readily laundered. Numerous cation-active and/or non-ionogenic
agents can be used for this purpose. Especially suitable agents of
this type are:
a. Fatty acid polyglycol esters of the formula
R--COO--(CH.sub.2 --CH.sub.2 --O).sub.n H,
wherein R is preferably a higher saturated fatty acid such as
stearic acid or palmitic acid.
b. Fatty alcohol polyglycol ethers of the formula
R--O--(C.sub.2 H.sub.4 O) H
in which R-O preferably stands for a higher saturated fatty alcohol
group such as a stearyl or palmityl alcohol group.
c. Fatty acid alkanol amides of the formula
R--CO--NH--CH.sub.2 --CH.sub.2 --OH
wherein R--CO-- indicated preferably a higher saturated fatty acid
group.
d. Fatty acid amide polyglycol ethers of the formula ##SPC1##
wherein R--CO is preferably a higher saturated fatty acid
group.
e. Fatty amine polyglycol ethers of the formula
R--CH.sub.2 --N=[(CH.sub.2 --CH.sub.2 --O).sub.n H].sub.2
wherein R is preferably higher alkyl derived from a saturated fatty
amine.
f. Fatty acid sarkosides (this agent is an anionic agent but can
also be used in the claimed process) of the formula
R--CO--N(CH.sub.3)--CH.sub.2 --COONa
wherein R preferably is higher alkyl derived from a saturated fatty
acid.
g. Organic phosphoric acid esters and their salts of the formula
##SPC2##
h. Salts of primary, secondary, and tertiary fatty amines of the
formulas ##SPC3##
wherein R is higher alkyl.
i. Quaternary ammonium salts of the formula ##SPC4##
wherein R is higher alkyl derived from tallow which may be
hydrogenated.
j. Amphoteric ammonium compounds of the formula
R -- N = (CH.sub.2 --CH.sub.2 COONa).sub.2 .
k. Cation-active imidazoline compounds of the formula ##SPC5##
Such agents serve also as fabric softeners and antistatic
agents.
Cation-active and non-ionogenic agents for treating laundry are
also described, for instance, by K. LINDNER
"Tenside-Textilhilfsmittel-Waschrohstoffe" vol. II (1964) on pages
1610 to 1625, where numerous agents useful for carrying out the
present invention are listed.
Suitable optical brightening agents are, for instance, derivatives
of 4,4'-diamino stilbene-2,2'-disulfonic acid, in which the amino
groups are substituted by triazinyl or other basic groups or by
acyl groups, such as acetyl, phenoxy acetyl or alkoxybenzoyl
groups. Ureido substituted diamino stilbene disulfonic acids are
also useful for this purpose.
Derivatives of di-benzo thiophene-5,5-dioxide of the formula
##SPC6##
can also be used.
Azoles, such as monoazoles in the form of their sulfonic acids or
bisazoles, such as bis-naphthotriazolyl compounds are also useful
optical brighteners, likewise coumarin derivatives. Such optical
brighteners are described, for instance, in Kirk-Othmer
"Encyclopedia of Chemical Technology" Second Edition, volume 3,
pages 737 to 749.
Especially useful quaternary ammonium compounds are, for instance,
dimethyl benzyl cetyl ammonium chloride, dimethyl distearyl
ammonium chloride, and the like compounds which in aqueous solution
have not only a germicidal effect but also act as deodorants
because they inhibit the production of malodors due to the action
of micro-organisms and, therefore, are useful odor controlling
agents.
Perfumes act as malodor counteracting and masking agents without
involving any chemical changes. They also have a deodorizing and/or
odor modifying effect. Any suitable perfume may be used, whereby,
of course, the preferred perfumes are those which do not stain and
do not cause discoloration of the laundry. Especially useful are
the perfumes of the floral group, imparting flower odors to the
laundry, as well as those of the herbal group imparting thereto the
odor of hay and grass, clover, and the like. Lavender fragrances or
the fragrances of citrus fruits may, of course, also be applied to
the laundry.
Suitable deodorants are, for instance, phenolic polyoxymethylene
derivatives, quaternary ammonium compounds, formaldehyde
derivatives, 2,4,4'-trichloro-2'-hydroxy diphenyl ether,
3,4,4'-trichloro carbanilide, alkylolamides of undecylenic acid,
and others.
Antistatic agents are added especially when washing synthetic fiber
materials. There are a number of antistatic agents know, such as
polyhydric alcohols, for instance, glycerol; amines, for instance,
triethanolamine; amides, for instance, N,N-bis-(2-hydroxy ethyl)
stearyl amide; polyoxy ethylene derivatives, for instance,
hexadecyl ethers of polyethylene glycols; amine soaps, for
instance, the soaps of stearic acid and octadecyl amine; amine
salts of alkyl sulfates, for instance, the salts of guanidine and
octadecyl sulfate; quaternary ammonium compounds, for instance,
octadecyl trimethyl ammonium chloride; alkyl phosphates, for
instance, bisdodecyl hydrogen phosphates; amine salts of alkyl
phosphonic acids, for instance, the salts of triethanolamine and
octadecyl phosphonic acid, and others.
An aerosol composition which has proved to be useful for carrying
out the present invention may have the following composition:
10 parts to 50 parts of a liquified or compressed, non-combustible
aerosol propellant agent,
0.0 parts and, if present, at least 0.5 parts to 50 parts of a
cationic and/or non-ionogenic rinsing additive,
0.0 parts and, if present, at least 0.1 parts to 5 parts of a
deodorant,
0.0 parts and, if present, at least 0.1 parts to 5 parts of an
optical brightening agent,
0.0 parts and, if present, at least 0.1 parts to 5 parts of a
perfume, and/or
0.5 parts to 80 parts of water or a suitable solvent, especially a
lower alcohol or a halogenated alkane.
It may be mentioned that the preparations used for treating the
partly dried laundry need not contain all the above mentioned
groups of active agents. Their composition can be varied
considerably; for instance, if a special softening effect is to be
achieved, the predominant component of the preparation is the
softening agent while the other agents may be omitted or added only
in relatively small amounts. Likewise, the preparations may
specifically contain a perfume or an aromatizing agent if a
pronounced aromatizing effect is desired, or such agents may be
omitted completely, for instance, when laundering hospital
linen.
When applying the treating preparations to the laundry,
satisfactory results are achieved only by a compromise between the
following facts:
a. On the one hand, the treatment with the treating solution should
be effected as early as possible, i.e., with laundry of a
relatively high moisture content because then optimum distribution
of the active agents over and throughout the laundry will be
achieved due to the extended drying and thus treatment time.
b. On the other hand, the treating solution should be applied as
late as possible, i.e., when the moisture content of the laundry is
very low and thus its degree of dryness is high. Thereby optimum
utilization of the treating agents will be achieved and, at the
same time, the optimum amount of perfume will adhere to the
laundry.
As has been found, satisfactory results are achieved if the
treating solution is applied to the laundry at a moisture content
between about 5 percent and about 70 percent and preferably at a
moisture content of about 15 percent in order to meet both above
mentioned requirements. Such a moisture content corresponds to a
degree of dryness between 95 percent and 30 percent and preferably
of 85 percent.
Instead of subjecting the laundry to a softening, brightening and
the like treatment as described hereinabove, it is also possible to
subject it to a starching treatment. In this case, those pieces of
the laundry which are to be starched must be separated from those
pieces which are not to be starched, and must be treated
separately, too. Heretofore this was not possible, because the
softening rinsing step took place as the last step in the washing
machine so that the entire laundry had to be subjected to the
treatment with the solftening or other agents, although laundry
which subsequently had to be starched needed not be treated
therewith.
It is, of course, also possible to use the compositions according
to the present invention without a propellant and to spray them
into the dryer by the action of compressed air. Preferably a
solvent is then added to the composition such as, for instance,
"FREON TF" i.e., 1,1,2-trichloro-1,2,2-trifluoro ethane and the
like.
BRIEF DESCRIPTION OF THE DRAWING
The attached drawing illustrates a device for introducing the
treating agent into the laundry drier. In said drawing
FIG. 1 illustrates a dosing device introducing an aerosol
composition into the laundry drier by means of a nozzle and valve
controlled by a timer.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
In said FIG. 1 the aerosol can 1 is placed into the holding device
2 with an opening at its bottom through which the outlet 4 of the
aerosol can 1 can be connected by means of adapter 3 to pipe 5. The
adapter 3 is designed so that it opens the valve of the aerosol can
1. The electrically controlled valve 6 is provided in said pipe 5.
Pipe 5 thus is under permanent pressure. Pipe 10 leads from valve 6
to nozzle 7. Valve 6 is also connected with timing device 8 which
is either controlled by the moisture content of the air leaving the
drier or by the moisture content of the laundry tumbling in said
drier. At a predetermined moment valve 7 is actuated for a certain
period of time by an impulse issued from said timing device 8 so
that a predetermined amount of active treating agent is sprayed
into the dryer and onto the tumbling laundry through nozzle 7. If
the aerosol can 1 becomes exhausted, it can easily be replaced by a
new aerosol can. The entire dosing device is attached to door 9 of
the drier.
The aerosol composition in the aerosol can 1 may be composed as
described hereinafter in the Examples although it is not limited
thereto.
EXAMPLE 1
6 percent of dimethyl distearyl ammonium chloride,
0.5 percent of nonyl phenol polyglycol ether (with 9 moles of
ethylene oxide),
1 percent of the quaternary ammonium compound designated as "BTC
776" i.e., an alkyl dimethyl benzyl ammonium chloride, of Organon
of Duesseldorf, West-Germany,
1 percent of the optical brightening agent designated as "UVITEX
SEB," i.e., thiophene-2,5-bisbenzoxazole of Ciba-Geigy of Basel,
Switzerland,
1 percent of a perfume designated as "HERPYL 49S/72" of the firm
UOP of Paris-Colombes, France, and 90.5 percent of water.
Eighty parts of said mixture are mixed with 20 parts of the
propellant designated as "FRIGEN 12A" i.e., dichlorodifluoro
methane of Farbwerke Hoechst, West-Germany.
This composition for the treatment of laundry is compounded by
heating the dimethyl stearyl ammonium chloride and the nonyl phenol
polyglycol ether to about 60.degree. C. The quaternary ammonium
compound is then added thereto and the mixture is thoroughly
emulsified in water of 60.degree. C. After cooling the mixture to
40.degree. C., the optical brightening agent and the perfume are
admixed thereto. Thereafter, 80 parts of said mixture are then
filled with 20 parts of the propellant into suitable aerosol
cans.
An aerosol can with about 350 g. of said mixture is sufficient for
treating an average amount of laundry (3-5 kg. of dry laundry) in a
laundry drier about 20 times. The aerosol has a softening,
bactericidal, and antistatic effect.
EXAMPLE 2
Composition which has an aromatizing and softening effect and, at
the same time, acts as an optical brightener:
13.0 percent of dimethyl distearyl ammonium chloride,
1.5 percent of nonyl phenyl polyglycol ether,
14.9 percent of isopropanol,
0.5 percent of perfume,
0.1 percent of the optical brightener "Blankophor FBO" of Farbwerke
Bayer, i.e., a derivative of 3-phenyl-7-amino carbostyril.
As propellant there is admixed thereto
70.0 percent of the propellant mixture "FRIGEN 11/12," i.e., a
mixture of 37 parts of trichloro fluoro methane and 63 parts of
dichloro difluoro methane of Farbwerke Hoechst, West-Germany.
EXAMPLE 3
Composition with a softening and bactericidal effect, low in
perfume and not containing any brightening agent:
12.0 percent of dimethyl distearyl ammonium chloride,
1.75 percent of alkyl (C.sub.12 - C.sub.18) dimethyl benzyl
ammonium chloride
1.00 percent of nonyl phenol polyglycol ether,
15.00 percent of isopropanol,
0.25 percent of perfume.
This mixture is used together with
70.0 percent of the propellant "FRIGEN 11/12."
EXAMPLE 4
Composition with a good softening and antistatic effect for natural
and synthetic fibers:
9.5 percent of dimethyl distearyl ammonium chloride,
2.0 percent of a fatty amine polyglycol ether, i.e., a tallow amine
(C.sub.16 - C.sub.18) polyglycol ether
2.0 percent of cetyl trimethyl ammonium chloride,
1.0 percent of dialkyl (C.sub.12 - C.sub.18) dimethyl ammonium
chloride,
15.0 percent of isopropanol,
0.5 percent of perfume.
This mixture is used with 70.0 percent of the propellant "FRIGEN
11/12."
EXAMPLE 5
Composition with a satisfactory softening effect for natural and
artificial fibers and an excellent bactericidal effect.
12.75 percent of a fatty acid (C.sub.16 - C.sub.18)
ethanolamide,
1.50 percent of nonyl phenyl polyglycol ether,
0.25 percent of a perfume,
15.25 percent of isopropanol,
0.25 percent of "IRGASAN DP 300" (2,4,4-trichloro-2'-hydroxy
diphenyl ether of the firm Ciba-Geigy, Basel, Switzerland, as
bactericidal agent.
This mixture is used with 70.0 percent of the propellant "FRIGEN
11/12."
While the process according to the present invention has proved to
be especially useful when applied to laundry dried in laundry
tumbler driers, it can also be employed for the treatment of
laundry in drying chambers or other drying apparatus.
It has been found that at least small amounts of water or solvent
must be present in the treating solution or aerosol because
otherwise no homogeneous solution would be formed.
Of course, many changes and variations in the composition of the
treating agents to be applied to the laundry, in the apparatus used
for applying them thereto, in the manner of applying them thereto,
in the degree of dryness of the laundry on application of the
treating agent, and the like may be made by those skilled in the
art in accordance with the principles set forth herein and in the
claims annexed hereto.
* * * * *