U.S. patent application number 17/731341 was filed with the patent office on 2022-08-11 for microwave drying apparatus for the minimization of drinking water plant residuals.
This patent application is currently assigned to U.S. Environmental Protection Agency. The applicant listed for this patent is U.S. Environmental Protection Agency. Invention is credited to Darren A LYTLE, Mallikarjuna N. Nadagouda.
Application Number | 20220250943 17/731341 |
Document ID | / |
Family ID | |
Filed Date | 2022-08-11 |
United States Patent
Application |
20220250943 |
Kind Code |
A1 |
LYTLE; Darren A ; et
al. |
August 11, 2022 |
MICROWAVE DRYING APPARATUS FOR THE MINIMIZATION OF DRINKING WATER
PLANT RESIDUALS
Abstract
A method and apparatus for treating residuals or waste streams
from a plant, such as a drinking water treatment plant. The method
includes the steps of obtaining plant residuals or waste streams
from a water treatment plant and irradiating the plant residuals or
waste streams using microwave radiation from a microwave source.
The method also includes the step of drying the plant residuals or
waste streams to a predetermined moisture, volume, or weight
content reduction and disposing of the same.
Inventors: |
LYTLE; Darren A; (Liberty,
OH) ; Nadagouda; Mallikarjuna N.; (Mason,
OH) |
|
Applicant: |
Name |
City |
State |
Country |
Type |
U.S. Environmental Protection Agency |
Washington |
DC |
US |
|
|
Assignee: |
U.S. Environmental Protection
Agency
Washington
DC
|
Appl. No.: |
17/731341 |
Filed: |
April 28, 2022 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
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15906157 |
Feb 27, 2018 |
11345617 |
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17731341 |
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62600737 |
Mar 1, 2017 |
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International
Class: |
C02F 1/30 20060101
C02F001/30; H05B 6/80 20060101 H05B006/80 |
Claims
1. An apparatus for treating residuals from a water treatment plant
comprising: a processing vessel configured to store plant residuals
from a water treatment plant; and a microwave radiation source
configured to dry the plant residuals in the processing vessel by
heating using microwave radiation.
2. The apparatus according to claim 1, wherein the processing
vessel comprises ceramic, refractive, or china materials.
3. The apparatus according to claim 1, where the processing vessel
is open to the atmosphere.
4. The apparatus according to claim 1, wherein the processing
vessel is configured to operate in a batch mode operation.
5. The apparatus according to claim 1, wherein the microwave
radiation source is a magnetron.
6. The apparatus according to claim 5, wherein the magnetron is
configured to produce microwave radiation having a wavelength
between 5 centimeters and 40 centimeters.
7. An apparatus for treating residuals from a water treatment plant
comprising: a processing vessel configured to store plant residuals
from a water treatment plant; and a microwave radiation source
configured to dry and treat the plant residuals in the processing
vessel by irradiating the plant residuals using microwave radiation
from the microwave source, at a power output between 0.1 and 100 kW
at 500 MHz to 2500 MHz frequencies to control a temperature in the
processing vessel to be between 90.degree. C. and 125.degree. C.,
wherein the processing vessel comprises ceramic, refractive, or
china materials that reflect radiation.
8. The apparatus of claim 7, wherein the processing vessel is open
to atmosphere.
9. The apparatus of claim 7, wherein the microwave source is a
magnetron, and the magnetron powered is powered between 0.1 and 50
kW.
10. The apparatus of claim 9, wherein the microwave radiation has a
wavelength between 5 centimeters and 40 centimeters.
11. The apparatus of claim 7, wherein the microwave radiation
source is configured to irradiate the plant residuals in five
minute intervals until the plant residuals are dried to at least an
80% moisture reduction percentage.
12. The apparatus of claim 7, wherein the microwave radiation
source is configured to irradiate the plant residuals until the
plant residuals are dried to at least 80% volume reduction.
13. The apparatus of claim 7, wherein the microwave radiation
source is configured to irradiate the plant residuals until the
plant residuals are dried to at least 80% weight reduction.
14. An apparatus for treating residuals from a water treatment
plant comprising: a processing vessel configured to store plant
residuals from a water treatment plant; and a microwave radiation
source configured to dry and treat the plant residuals in the
processing vessel by irradiating the plant residuals using
microwave radiation from the microwave source, at a power output
between 0.1 and 100 kW at 500 MHz to 2500 MHz frequencies to
control a temperature in the processing vessel to be between
90.degree. C. and 125.degree. C., wherein the processing vessel is
formed of ceramic materials.
Description
CROSS-REFERENCE TO RELATED APPLICATIONS
[0001] This application claims the benefit of U.S. provisional
application No. 62/600,737, filed Mar. 1, 2017, and is incorporated
by reference herein in its entirety. This application is a
divisional of U.S. application Ser. No. 15/906,157 filed Feb. 27,
2018.
FIELD OF THE INVENTION
[0002] The present disclosure relates to processing residuals or
waste streams from a plant, and, more specifically, to treating
residuals from a drinking water plant using microwave
radiation.
BACKGROUND OF THE INVENTION
[0003] Drinking water treatment (DWT) plants are used to provide
potable water to its customers or consumers. Typically, DWT plants
receive water directly from a water source, e.g., river, lake,
reservoir or wells, or from a secondary supplier. The DWT plants
then processes or treats the received water prior to providing
potable water to its customers or consumers. Water treatment
operations can include filtration, precipitative softening,
membrane separation, ion exchange, activated carbon filtering,
disinfection, chlorination, sedimentation, and/or coagulation.
During the processing or treatment of the water, the DWT plants
treat the water and remove contaminants that are unhealthy or
undesirable for consumption, which become waste streams or plant
residuals. For example, such contaminants include aluminum, copper,
lead, nitrates, barium, radium, selenate, ammonia, arsenic,
cadmium, zinc, phosphorus, iron, manganese, potassium, and salts
thereof, oil and grease, biochemical oxygen demand (BOD), materials
at a pH that is significantly different from 7, settleable solids,
total residual chlorine, chlorides, and suspended or dissolved
solids, radionuclides, and/or other water plant impurities and
wastes. Of these contaminants, solids are the most common pollutant
in the plant residuals, where the suspended solids include
inorganic, e.g., silt, sand, clay, and insoluble hydrated metal
oxides, and organic matter, e.g., flocculated colloids and
compounds that contribute to color, where the dissolved solids
primarily consist of dissolved inorganic compounds.
[0004] The plant residuals are then disposed of, where common
methods for plant residual disposal include discharging directly
into an on-site sanitary sewer, discharging or shipping to a
wastewater treatment plant, where the plant residuals are processed
in sedimentation tanks and/or ponds and thickened or dried,
discharging into a water body or stream, or using zero discharge
methods such as, drying followed by landfilling, evaporation,
recycling, land application, deep well injection, evaporation, and
spray irrigation.
[0005] Given the regulatory constraints, disposal restrictions and
the potentially hazardous nature of drinking water treatment plant
residuals, developing effective, safe, affordable, and sustainable
residual management practices is a critical consideration to any
drinking water treatment design and environmental protection.
SUMMARY OF THE INVENTION
[0006] Accordingly, it is one of the aspects of the present
invention to provide a method and apparatus that affordably and
quickly reduces the amount of and/or treats residuals from a
processing plant. A method is provided for treating residuals or
waste streams from a drinking water treatment (DWT) plant that
comprises the steps of obtaining plant residuals or waste streams
from the DWT plant and irradiating the plant residuals or waste
streams with microwave radiation. The method may further comprise
the step of drying the plant residuals from the DWT plant to a
desired moisture, weight, or volume reduction content
percentage.
[0007] In one embodiment of the invention, the method is performed
using batch mode operation, where the plant residuals or waste
streams are irradiated with microwave radiation from a microwave
source, such as a magnetron, in predetermined time intervals.
[0008] In another embodiment of the invention, the method is
performed in continuous mode operation, where the plant residuals
or waste streams are continuously dried on a conveyor or trough
system using at least one microwave source.
[0009] The invention includes an apparatus for performing the
microwave drying method.
[0010] The numerous advantages, features and functions of the
various embodiments of the invention described herein will become
readily apparent and better understood in view of the following
description and accompanying drawings. The following description is
not intended to limit the scope of the invention but instead merely
provides exemplary embodiments for ease of understanding and
practicing the invention.
BRIEF DESCRIPTION OF THE DRAWINGS
[0011] Examples of a method and apparatus according to different
embodiments of the invention will now be explained in more detail
with reference to the drawings, wherein:
[0012] FIG. 1 is a schematic view of a drinking water treatment
process;
[0013] FIG. 2 is a schematic view of a second embodiment of a
drinking water treatment process;
[0014] FIG. 3 is a schematic view of a third embodiment of a
drinking water treatment process;
[0015] FIG. 4 illustrates the different residuals from samples
after different drying methods were used;
[0016] FIG. 5 illustrates the different residuals of the dried
samples after being removed from the crucibles;
[0017] FIG. 6 illustrates the air drying process of a sample;
and
[0018] FIG. 7 illustrates the different residuals of the dried
samples after being removed from the crucibles.
[0019] In the various figures, similar elements are provided with
similar reference numbers. It should be noted that the drawing
figures are not necessarily drawn to any scale, or proportion, but
instead are drawn to provide an understanding of the method and
apparatus according to the invention. Thus, the illustrations are
not intended to be limiting as to the scope of the invention
described herein, but rather to provide exemplary illustrations
thereof.
DETAILED DESCRIPTION OF THE INVENTION
A. Discussion of Various Embodiments
[0020] As generally discussed above, there is a need to develop an
effective, safe, affordable, quick and sustainable plant residual
management practice to reduce the total amount or volume of plant
residuals or waste streams from a drinking water treatment plant
for landfill or other disposal. Often, however, the development of
such treatment is confronted by the choice of treatment being
dictated by the waste streams, where the constraints in plant
residuals limits the type of treatment alternatives. However, if
the plant residuals did not have to be further treated, e.g., by
further drying, more effective and efficient treatment choices
could be made.
[0021] A method and apparatus for treating residuals from a
processing plant, and more particularly, to drinking water
treatment plant residuals, is provided, where the plant residuals
are irradiated using microwave radiation.
[0022] Not only do alternative or renewable energy sources show
significant promise in helping to reduce the green gas emissions
and help to preserve many of the natural resources that we
currently use as sources of energy, they can protect against
harmful emissions and further dry samples in a more efficient
manner. For example, microwave radiation is an efficient,
environmentally friendly and economically viable heating method for
many applications. Microwave technology is emerging as an
alternative energy source powerful enough to accomplish chemical
transformations in minutes, instead of hours or even days and,
consequently, microwave radiation is presently seeing an
exponential increase in acceptance as a technique for enhancing
chemical synthesis.
[0023] For example, patents have been granted for equipment to
remove volatile organic compound (VOCs) and semi-volatile organic
compounds (SVOCs) from contaminated materials using microwave
radiation, along with other hazardous constituents absorbed onto
activated carbon. Additionally, a number of patents exist for the
application of microwave radiation to mineral ores and heavy metal
wastes including electroplating wastes, arsenic-containing wastes,
and radionuclides. For radionuclides, these methods included
desiccation, densification, pyrolysis, or vitrification.
Furthermore, patents have been granted for the regeneration of
adsorbent/desiccant materials (such as silica gel, activated
alumina, zeolite) via microwave drying. For example, various
patents exist where microwave heating is combined with a
stabilizing agent such as thermoplastic resin or encapsulating
material to minimize leaching. There are also patents for treating
organic solids through an admixture of hydrogen peroxide and
exposure to microwaves.
[0024] However, the prior art directed to the treatment of plant
residuals from a processing plant, and specifically, a drinking
water treatment plant, does not use microwave radiation, as in the
present invention.
[0025] The present invention includes a method in which microwave
radiation is used to irradiate plant residuals in the context of
the drying and treatment of plant residuals, where it was found to
be more effective than alternative sources of heating/drying, e.g.,
air or oven. That is, microwave irradiation was found to be a more
efficient approach to greatly reducing waste volume and weight, and
thereby allowing the use of more effective water treatment
approaches at later stages, e.g., disposal. Specifically, the
treatment of drinking water treatment plant residuals using
microwave radiation compared to heating using conventional energy
resources such as coal and oil, is more environmentally-friendly
and, therefore, benefits both the economy and the environment. The
present invention of microwave drying and treatment of the drinking
water treatment plant residuals provides a quicker drying method to
reduce the volume, weight, and moisture content of the drinking
water treatment plant residuals.
[0026] In one embodiment of the invention, as illustrated in FIG.
1, a batch operation for the DWT treatment plant residual is shown.
Specifically, water from a source 101 is provided to a drinking
water treatment (DWT) plant 110, where the water source 101 can be
pumped from a river, lake, reservoir, natural spring, or other
fresh water source, or delivered from a secondary supplier. The DWT
plant 110 processes or treats the water from the water source 101
to provide potable water to its customers or consumers. For
example, the processing or treatment at the DWT plant can include,
but not limited to, filtration, precipitative softening, membrane
separation, ion exchange, activated carbon filtration,
disinfection, chlorination, sedimentation, and coagulation. During
this processing, the contaminants that are unhealthy or undesirable
for consumption are separated, which become waste streams or plant
residual streams 120, where the contaminants can include aluminum,
copper, lead, nitrates, barium, radium, selenate, ammonia, arsenic,
cadmium, zinc, phosphorus, iron, manganese, potassium, and salts
thereof, oil and grease, biochemical oxygen demand (BOD), materials
at a pH that is significantly different from 7, settleable solids,
total residual chlorine, chlorides, and suspended or dissolved
solids, radionuclides, or other water plant impurities and
wastes.
[0027] As seen in FIG. 1, the waste streams or plant residuals 120
are then provided into at least one processing vessel 130 in a
batch filling operation. The processing vessel 130 is a vessel that
is open to the atmosphere, which avoids the dangers associated with
over-pressurization when heated. Additionally, the processing
vessel 130 can be a ceramic container, such as alumina, china
crucible, or refractive material, or a stainless steel vessel lined
with such ceramic material. Other materials that are capable of
reflecting radiation, e.g., heat and microwave, can also be used
and are not limited by this disclosure. Furthermore, the processing
vessel can be contained in a separate vessel to avoid overexposure
of the microwave radiation to the environment, e.g., metal mesh
screens, cages, or other structure that prevents microwave
radiation from escaping. Additionally, multiple processing vessels
can be used, where the plant residuals or waste streams are dried
and/or treated in iterative steps.
[0028] A microwave source 140 such as a magnetic microwave source
or magnetron is provided to irradiate the plant residuals or waste
streams in or near the processing vessel 130 with microwave
radiation. The microwave source 140 can be coupled to the
processing vessel 130 or provided above the processing vessel to
irradiate the plant residuals or waste streams.
[0029] While not wishing to be bound by theory, it is understood
that the process of irradiating plant residuals or waste streams
with microwave radiation at least includes providing radiation from
a source, e.g., electromagnetic, that is used to expose the plant
residuals or waste streams to electromagnetic radiation in the
microwave frequency to produce thermal energy, e.g., dielectric
heating. For example, the electromagnetic radiation source can be a
magnetron having a given operating frequency and wavelength that is
used to excite the plant residuals or waste streams or the water
contained in the plant residuals or waste streams to a given
temperature, e.g., between 90.degree. C. and 125.degree. C.
measured by temperature sensors, in different intervals of time,
for example, five minute periods until the moisture content reaches
a predetermined level, e.g., 80%, 90%, or 95% or more moisture
content reduction using, e.g., a moisture meter 150.
[0030] The microwave source 140 may have a power output between 0.1
and 100 kW to produce microwave radiation having a wavelength
between 5 centimeters and 40 centimeters, where the plant residuals
in the processing vessel are irradiated in predetermined time
intervals until dried. For example, while a standard commercially
available magnetron such as one that is used in a microwave cooking
apparatus, e.g., Rival model RGC7702, can be used for batch
processing small amounts of plant residuals, the microwave
radiation can also be introduced using commercially available
magnetron sources that produce wavelengths greater than 15
centimeters for large scale batch processing, e.g., 100 kW and 900
MHz.
[0031] In another embodiment of the invention, as illustrated in
FIG. 2, where like reference numerals refer to like elements, the
plant residuals 130 from the DWT plant 110 are provided in a closed
processing vessel 230. In this case, the microwave source 240 is
provided so that the electromagnetic element or antenna protrudes
into the processing vessel 230 to irradiate the plant residuals or
waste streams inside the closed processing vessel 230. For example,
the magnetron source is provided off-center or at the center
through an opening in a top of the processing vessel and provides
the microwave radiation downwards towards the plant residuals or
waste streams.
[0032] In a similar manner as discussed above, the microwave
radiation is used to heat the plant residuals to dry the plant
residuals at a temperature between 90 and 125.degree. C. Since the
processing vessel 230 is closed, however, a pressure equalization
or relief system can be provided to protect against
over-pressurization and to maintain the temperature in the
processing vessel 230. In addition to or alternatively, the
processing vessel 230 can include a vacuum system or vent system to
control the pressure in the processing vessel 230 to a
predetermined pressure. After the plant residuals are dried to the
desired moisture reduction content, the dried plant residuals may
be disposed of.
[0033] Alternatively, in another embodiment of the invention, the
plant residuals or waste streams 120 from the DWT plant 110 are not
contained in a vessel, but continuously processed. For example, as
seen in FIG. 3, the plant residuals or waste streams 120 are
continuously transferred to a conveyor belt or trough system 330.
At least one or multiple microwave sources 340 in series are then
used to dry the plant residuals using constant or varied microwave
radiation bombardment intervals that can be at the same or
different power and frequency levels, e.g., increased power as the
plant residuals is dried. Additionally, the plant residuals or
waste streams 120 can be processed before transfer to the conveyor
belt or trough system to decrease the water content.
B. Discussion of Various Methods of Operation
[0034] The operation of the drying and treatment of the plant
residuals will now be described in detail.
[0035] Referring back to FIG. 1, in one embodiment of the
invention, the method of drying and treating plant residuals or
waste streams 120 from a DWT plant comprises the step of obtaining
the plant residuals from a water treatment plant which is received
in a processing vessel 130. The processing vessel receives the
plant residuals or waste streams in a batch filling operation by
transferring the plant residuals or waste streams using a pump,
conveyor, or other transferring device.
[0036] The plant residuals are then irradiated in the processing
vessel 130 using microwave radiation from a microwave source 140
until the plant residuals are dried to a predetermined moisture
content reduction percentage, e.g., 80, 90, 95, or more moisture
reduction percentage. The plant residuals may alternatively or in
addition to be controlled to a predetermined weight or volume
reduction, e.g., volume or weight reduction of 80, 90, 95, 99% or
more, where the processing vessel 130 can be provided with level
and weight meters. The microwave radiation may be supplied at a
power output between 0.1 and 100 kW at 500 MHz to 2500 MHz
frequencies to control the temperature to be between 90 and
125.degree. C. in the open processing vessel. The microwave
radiation may be applied in predetermined time intervals, e.g.,
every 1 minute, 5 minutes, 10 minutes, 30 minutes, until the plant
residuals are dried to the predetermined moisture content
percentage. Additionally, a mixer such as impellers, agitators, and
stators, may be used to mix the plant residuals or waste stream in
the processing vessel 130.
[0037] The processing vessel 130 may be formed of ceramic
materials. It was surprisingly found that the use of ceramic
materials accelerated the drying process. Not wishing to be bound
by theory, but it is understood that the ceramic material reflected
the microwave radiation and radiant heat from the microwave source
and heated plant residuals for the continued heating of the plant
residuals.
[0038] After the irradiating and the drying was complete, the
method further comprises the step of disposing of the dried plant
residuals by landfilling, land application, or deep well injection.
For example, the dried plant residuals can be pumped, scraped, or
otherwise removed from the processing vessel 130 and transported to
a vessel or transport for disposal.
[0039] In the second embodiment of the invention, as seen in FIG.
2, the method is similar to the first embodiment, but uses a closed
processing vessel 230. In this embodiment, the method further
comprises controlling the pressure in the processing vessel 230 to
be between 0.2 atmospheres to 5 atmospheres to control the
temperature of the processing vessel between 30 and 125.degree. C.
After the drying is complete, the dried plant residuals are
disposed of.
[0040] The third embodiment is a continuous process, as opposed to
being a batch operation. In this case, the method of drying and
treating plant residuals or waste streams 120 from a DWT plant
comprises the step of obtaining the plant residuals from a water
treatment plant which are received on a conveyor or trough system
330. The plant residuals are then irradiated with microwave
radiation from at least one microwave source 340 or a plurality of
microwave sources in series.
[0041] When multiple microwave sources are used, the microwave
sources may be varied having different operating power and
frequencies to aid in the drying and treatment process. For
example, the first microwave source 340 may be at a higher power
and lower frequency to dry or treat the plant residuals more
quickly, and the second microwave source may be at a lower power
and higher frequency to further dry or treat the plant residuals or
waste steam. The multiple microwave sources may also be arranged so
that the plant residuals are only irradiated in predetermined time
intervals, e.g., every one minute, five minutes, or ten minutes,
before the next irradiation treatment.
[0042] After the drying or treatment reaches a predetermined
criteria, e.g., moisture, weight, or volume reduction percentage,
the dried plant residuals are disposed of
[0043] Examples are provided below to illustrate the effects and
advantages of the various embodiments of the present invention.
[0044] As a result of the need to treat these plant residuals,
studies were conducted to identify the most effective drying
technique of the plant residuals or waste streams, which were
received from different processes in drinking water treatment
plants for content and solids analysis. Specifically, filter
backwash water from iron/arsenic removal treatment (GCBW); backwash
sludge from iron/arsenic removal treatment (CLS); backwash sludge
from iron coagulation/arsenic removal (GLS); and wastewater
recovered from the regeneration of iron-based adsorptive media
(TPW) were studied. With the exception of TPW, the wastes were
primarily suspensions of arsenic-containing iron solids. TPW was
produced as a result of regenerating an exhausted iron media
adsorption bed with caustic followed by neutralization with acid
and binding with iron which resulted in a waste with similar
properties as the filter backwash waters.
[0045] These samples were dried using air drying, oven drying, and
microwave drying, where different types of analyses were conducted
to compare several factors affecting disposal, such as, reduction
of weight, volume, and moisture content.
[0046] Air drying was conducted by placing a processing vessel,
such as a ceramic crucible, and sample inside a Thermo Scientific
Hamilton Concept Fume Hood Superstructure with a constant 61 fpm
face velocity. The sample was then checked periodically to record
observations and drying time. Samples were typically dry within 4
to 5 days based simply on visual examination or by measuring
moisture content, where the development of cracks, small fissures,
and clumps of solids at the bottom of the crucible were signs of
dryness. Once dried, the ceramic crucible and dry sample were
placed on an electronic scale and the weight was recorded. The
sample was removed from the evaporation crucible and the dried
sample was then carefully poured into a clear 20 ML vial and capped
tightly for further analysis.
[0047] In the conventional oven drying procedure, the ceramic
evaporation crucible and sample were placed inside an oven (e.g.,
model 20AF, Quincy Lab Inc.) that was set at 110.+-.5.degree. C.
The sample was checked periodically to record the amount of time it
took to dry. Samples were usually dry within 5 to 8 hours, where
the residual was considered dry when small fissures at the bottom
center or solids clumped together or when they met the same
criteria as applied to air drying. Once dried, the ceramic crucible
and dry sample was placed immediately into a desiccator and the
sample was allowed to cool completely (between 15 to 30 minutes) in
the desiccator. Once dried, the ceramic crucible and dry sample was
placed on an electronic scale and the weight was recorded. The
sample was removed from the evaporation crucible and the dried
sample was then carefully poured into a clear 20 mL vial and capped
tightly for further analysis.
[0048] Using the inventive microwave drying method, the ceramic
evaporation crucible and sample were placed inside a microwave
(e.g., model RGC7702, Rival, 900 W, 2450 MHz). The microwave was
placed into a Thermo Scientific Hamilton Concept Fume Hood
Superstructure with a constant 61 fpm face velocity. The sample was
dried in the microwave oven in five minute intervals until the
sample appeared nearly dry and then was microwaved in one minute
intervals until completely dried as defined earlier. Samples were
typically dry within 10 to 20 minutes. Once dried, the ceramic
crucible and dry sample were placed immediately into a desiccator,
where the sample was allowed to cool to room temperature
(approximately 30 minutes) in the desiccator. The sample was
scraped from the evaporation crucible and the dried sample was
poured into a clear, 20 mL vial and capped tightly for further
analysis.
[0049] The different drying processes were operated in batch mode
operation with the processing vessel having an open configuration
evaporation process which prevents the buildup of pressure.
Specifically, the drying tests were performed in ceramic crucibles,
which were shallow 150 mL crucibles that featured a lip, flat
bottom, and glazing, except for the rim and a section of the
outside bottom surface were used. The crucibles were highly
resistant to chemical interactions and suitable in high temperature
applications (up to 1150.degree. C.). It was surprisingly found
that the ceramic containers used in the present disclosure heated
faster than earlier reported versions and was found to be more
sustainable than existing market processes, e.g., the different
ceramic, refractive or china crucibles were used for heat
acceleration.
[0050] The results of the different drying methods are shown below
in Table 1. In testing the TPW sample, a 100 mL sample was
initially used, but the air drying method showed extremely slow
progress after one week, so the sample was switched to 20 mL and
was tracked on a weekly basis thereafter.
TABLE-US-00001 TABLE 1 Time to Moisture Sample Dry Volume Weight
Content Size Sample Reduction Reduction Reduction Residual Method
(mL) (hours) (%) (%) (%) GCBW Air 100 96 98.8 99.86 80.35 Oven 100
5.5 99.66 99.97 79.99 Micro 100 0.2 99.8 99.92 84.84 CLS Air 100
102 99.73 99.72 75.74 Oven 100 5.63 99.55 99.87 99.08 Micro 100
0.25 96.5 99.66 59 GS Air 100 144 97.6 97.43 78.15 Oven 100 6.23
97.43 98.01 89.06 Micro 100 0.22 97 98.09 93.49 TPW Air 20 -- -- --
-- Oven 100 6 91 94.69 89.99 Micro 100 0.25 83 95.72 92.64 TPW* 1
week 20 -- -- 90.54 66.63 2 weeks 20 -- -- 92.21 72.62 3 weeks 20
504 82 94.31 81.86
[0051] As seen in Table 1, the microwave drying method dried the
samples in shorter periods of time, e.g., between 0.2 and 0.25 hrs,
than the air drying and oven drying methods, while maintaining high
product quality. For example, as seen in FIGS. 4, 5, and 7, the
microwave drying method produced dried residuals having similar
characteristics as the air-dried and oven-dried plant residuals
with respect to size and clumping. FIG. 6 shows that the air-drying
method, while it results in a dried product, had the longest drying
time. It is appreciated that while the moisture content reduction
using the microwave method did not always produce the lowest
reduction percentage, it was determined to be an advantage over the
conventional drying methods due to its volume, weight, and moisture
content reduction and time for drying. That is, not only is the
microwave drying and treatment method quicker than the conventional
drying methods, such method reduces environmental impact and is
more sustainable than the conventional drying methods for the
treatment of drinking water treatment plant residuals.
[0052] It was also surprisingly found that the use of the ceramic
container such as, alumina, refractive materials, or china,
accelerated the drying process by accelerating the heating during
microwave irradiation.
[0053] That is, the present method and apparatus for treating
residuals from a water treatment plant has the following
advantages:
[0054] 1) Significantly reduced drying time demonstrated at
bench-scale with effective water removal/volume reduction.
[0055] 2) Improved overall efficiency and capacity for plant
residual or waste treatment over conventional drying methods.
[0056] 3) Higher processing speeds, with faster start-up and
shutdown.
[0057] 4) Better quality and quality control versus time.
[0058] 5) Reduced fire, explosion, toxic hazards, to have safer
operations.
[0059] 6) Reduced volatilization of hazardous constituents through
improved temperature control.
[0060] 7) Reduced environmental impact, for better
sustainability.
[0061] 8) Reduced the volume, which translates to lower costs for
transport and waste disposal.
[0062] It is appreciated that variations of the invention are
interchangeable without altering the inventive method and
apparatus. Additionally, while the methods of operation have been
discussed above in detail, the sequence of the steps is not limited
to the above described method. The sequence of the steps may be
performed in other orders as needed for the drying and treatment of
plant residuals. The invention is not to be limited by the
description of exemplary embodiments of the invention, but only by
the scope of the appended claims.
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