U.S. patent application number 17/094461 was filed with the patent office on 2022-05-12 for permeate gap membrane distillation.
The applicant listed for this patent is King Fahd University of Petroleum & Minerals, Saudi Arabian Oil Company. Invention is credited to Hasan Al Abdulgader, Mohammed Abdul AZEEM, Turki Nabieh BAROUD, Dahiru Umar LAWAL.
Application Number | 20220144671 17/094461 |
Document ID | / |
Family ID | |
Filed Date | 2022-05-12 |
United States Patent
Application |
20220144671 |
Kind Code |
A1 |
LAWAL; Dahiru Umar ; et
al. |
May 12, 2022 |
PERMEATE GAP MEMBRANE DISTILLATION
Abstract
A membrane distillation apparatus includes a housing and an
impeller. The housing includes a hot medium compartment, a cold
medium compartment, a permeate gap compartment, a membrane, and a
thermally conductive plate. The hot medium compartment includes a
hot medium inlet configured to receive a hot medium stream
including water. The cold medium compartment includes a cold medium
inlet configured to receive a cold medium stream. The membrane
defines pores that are sized to allow water vapor originating from
the hot medium stream to pass from the hot medium compartment
through the membrane to the permeate gap compartment. The thermally
conductive plate and the cold medium stream are cooperatively
configured to condense the water vapor from the hot medium stream.
The permeate gap compartment includes a permeate outlet configured
to discharge the condensed water vapor. The impeller is disposed
within the permeate gap compartment.
Inventors: |
LAWAL; Dahiru Umar;
(Dhahran, SA) ; AZEEM; Mohammed Abdul; (Dhahran,
SA) ; BAROUD; Turki Nabieh; (Dhahran, SA) ;
Abdulgader; Hasan Al; (Dammam, SA) |
|
Applicant: |
Name |
City |
State |
Country |
Type |
Saudi Arabian Oil Company
King Fahd University of Petroleum & Minerals |
Dhahran
Dhahran |
|
SA
SA |
|
|
Appl. No.: |
17/094461 |
Filed: |
November 10, 2020 |
International
Class: |
C02F 1/44 20060101
C02F001/44 |
Claims
1. A membrane distillation apparatus comprising: a housing
comprising: a hot medium compartment comprising a hot medium inlet
and a hot medium outlet, the hot medium inlet configured to receive
a hot medium stream comprising water; a cold medium compartment
comprising a cold medium inlet and a cold medium outlet, the cold
medium inlet configured to receive a cold medium stream; a permeate
gap compartment comprising a permeate outlet, the permeate gap
compartment intermediate of the hot medium compartment and the cold
medium compartment; a membrane disposed between the hot medium
compartment and the permeate gap compartment, the membrane defining
a plurality of pores sized to allow water vapor originating from
the hot medium stream to pass from the hot medium compartment
through the membrane to the permeate gap compartment; and a
thermally conductive plate disposed between the permeate gap
compartment and the cold medium compartment, the thermally
conductive plate and the cold medium stream within the cold medium
compartment cooperatively configured to condense the water vapor
from the hot medium compartment that passed through the membrane,
wherein the permeate outlet is configured to discharge the
condensed water vapor from the permeate gap compartment; and an
impeller disposed within the permeate gap compartment and connected
to a rotatable shaft configured to couple to and be rotated by a
motor, wherein the impeller is configured to mix fluid within the
permeate gap compartment in response to the rotatable shaft being
rotated by the motor.
2. The apparatus of claim 1, wherein: the housing comprises a first
end and a second end opposite the first end; each of the hot medium
compartment, the permeate gap compartment, the cold medium
compartment, the membrane, and the thermally conductive plate span
from the first end to the second end; the hot medium inlet and the
cold medium outlet are disposed at the first end of the housing;
and the hot medium outlet and the cold medium inlet are disposed at
the second end of the housing.
3. The apparatus of claim 2, wherein the permeate gap compartment
comprises a liquid comprising water.
4. The apparatus of claim 2, wherein the membrane is configured to
prevent liquid from passing through the membrane, and the membrane
comprises a composite membrane, a nano-composite membrane, a
hydrophobic membrane, an omniphobic membrane, a hydrophilic and
hydrophobic composite dual layer membrane, a modified ceramic
membrane, a porous ceramic membrane, a surface modified membrane, a
polymer electrolyte membrane, a porous graphene membrane, or a
polymeric membrane.
5. The apparatus of claim 4, wherein a contact angle of a droplet
of the hot medium stream on the membrane is greater than 90
degrees.
6. The apparatus of claim 2, wherein the impeller has a blade angle
in a range of from 1 degree (.degree.) to 55.degree..
7. The apparatus of claim 2, wherein the thermally conductive plate
comprises metal, composite material, carbon fibers, carbon
nanotubes, or sapphire.
8. The apparatus of claim 2, wherein the hot medium stream
comprises seawater, industrial wastewater, brackish water, produced
water, fruit juice, blood, milk, dye, non-condensable gas,
non-potable water, or a combination thereof.
9. The apparatus of claim 2, wherein the cold medium stream
comprises the hot medium stream after the hot medium stream has
been cooled, water, air, oil, or a combination thereof.
10. The apparatus of claim 2, comprising a first heat exchanger in
fluid communication with the hot medium compartment and the
membrane, the first heat exchanger configured to heat the hot
medium stream before the hot medium stream is received by the hot
medium inlet.
11. The apparatus of claim 10, comprising a second heat exchanger
in fluid communication with the cold medium compartment and the
thermally conductive plate, the second heat exchanger configured to
cool the cold medium stream before the cold medium stream is
received by the cold medium inlet.
12. A method comprising: receiving a feed stream comprising water
in a hot medium compartment of a membrane distillation apparatus;
receiving a cold medium stream in a cold medium compartment of the
membrane distillation apparatus, wherein the membrane distillation
apparatus comprises a permeate gap compartment intermediate of the
hot medium compartment and the cold medium compartment; allowing,
by a membrane disposed within the membrane distillation apparatus
between the hot medium compartment and the permeate gap
compartment, water vapor originating from the feed stream to pass
from the hot medium compartment through the membrane to the
permeate gap compartment while preventing liquid from passing
through the membrane; rotating an impeller disposed within the
permeate gap compartment, thereby resulting in mixing fluid within
the permeate gap compartment, decreasing pressure on a side of the
membrane facing the permeate gap compartment, and promoting heat
and mass transfer within the permeate gap compartment; condensing,
by a thermally conductive plate disposed within the membrane
distillation apparatus between the cold medium compartment and the
permeate gap compartment, the water vapor from the hot medium
compartment that passed through the membrane to form a permeate
stream having a water purity level greater than the feed stream;
and discharging, by a permeate outlet of the permeate gap
compartment, the permeate stream from the membrane distillation
apparatus.
13. The method of claim 12, wherein condensing the water vapor from
the hot medium compartment that passed through the membrane
comprises contacting the water vapor on a first side of the
thermally conductive plate facing the permeate gap compartment and
contacting the cold medium stream on a second side of the thermally
conductive plate facing the cold medium compartment.
14. The method of claim 13, comprising heating, by a first heat
exchanger, the feed stream before the feed stream is received in
the hot medium compartment.
15. The method of claim 14, comprising heating, by the first heat
exchanger, the membrane.
16. The method of claim 13, comprising cooling, by a second heat
exchanger, the cold medium stream before the cold medium stream is
received in the cold medium compartment.
17. The method of claim 16, comprising cooling, by the second heat
exchanger, the thermally conductive plate.
18. A membrane distillation system comprising: an apparatus
comprising: a housing comprising: a first end; a second end
opposite the first end; a hot medium compartment spanning from the
first end to the second end, the hot medium compartment comprising
a hot medium inlet and a hot medium outlet, the hot medium inlet
disposed at the first end and configured to receive a hot medium
stream comprising water; a cold medium compartment spanning from
the first end to the second end, the cold medium compartment
comprising a cold medium inlet and a cold medium outlet, the cold
medium inlet disposed at the second end and configured to receive a
cold medium stream; a permeate gap compartment spanning from the
first end to the second end, the permeate gap compartment
intermediate of the hot medium compartment and the cold medium
compartment, the permeate gap compartment comprising a permeate
outlet; a membrane spanning from the first end to the second end
and disposed between the hot medium compartment and the permeate
gap compartment, the membrane defining a plurality of pores sized
to allow water vapor originating from the hot medium stream to pass
from the hot medium compartment through the membrane to the
permeate gap compartment; and a thermally conductive plate spanning
from the first end to the second end and disposed between the
permeate gap compartment and the cold medium compartment, the
thermally conductive plate and the cold medium stream within the
cold medium compartment cooperatively configured to condense the
water vapor from the hot medium compartment that passed through the
membrane, wherein the permeate outlet is configured to discharge
the condensed water vapor from the permeate gap compartment; and an
impeller disposed within the permeate gap compartment and connected
to a rotatable shaft, wherein the impeller is configured to mix
fluid within the permeate gap compartment in response to the
rotatable shaft being rotated; and a motor coupled to the rotatable
shaft, the motor configured to rotate the rotatable shaft in
response to receiving power.
19. The system of claim 18, wherein the impeller has a blade angle
in a range of from 1 degree (.degree.) to 55.degree..
20. The system of claim 19, comprising: a first heat exchanger in
fluid communication with the hot medium compartment and the
membrane, the first heat exchanger configured to heat the hot
medium stream before the hot medium stream is received by the hot
medium inlet; and a second heat exchanger in fluid communication
with the cold medium compartment and the thermally conductive
plate, the second heat exchanger configured to cool the cold medium
stream before the cold medium stream is received by the cold medium
inlet.
Description
TECHNICAL FIELD
[0001] This disclosure relates to membrane distillation, and in
particular, permeate gap membrane distillation.
BACKGROUND
[0002] Membrane distillation is a separation process that is driven
by phase change. A membrane provides a barrier for a liquid phase
while allowing a vapor phase to pass through the membrane. Membrane
distillation can be used, for example, in water treatment. Several
membrane distillation methods exist. Some examples include direct
contact membrane distillation, air gap membrane distillation,
vacuum membrane distillation, sweeping gas membrane distillation,
vacuum multi-effect membrane distillation, and permeate gap
membrane distillation.
SUMMARY
[0003] This disclosure describes technologies relating to membrane
distillation, and in particular, permeate gap membrane
distillation. Certain aspects of the subject matter described can
be implemented as a membrane distillation apparatus. The apparatus
includes a housing and an impeller. The housing includes a hot
medium compartment, a cold medium compartment, a permeate gap
compartment, a membrane, and a thermally conductive plate. The hot
medium compartment includes a hot medium inlet and a hot medium
outlet. The hot medium inlet is configured to receive a hot medium
stream including water. The cold medium compartment includes a cold
medium inlet and a cold medium outlet. The cold medium inlet is
configured to receive a cold medium stream. The permeate gap
compartment includes a permeate outlet. The permeate gap
compartment is intermediate of the hot medium compartment and the
cold medium compartment. The membrane is disposed between the hot
medium compartment and the permeate gap compartment. The membrane
defines pores that are sized to allow water vapor originating from
the hot medium stream to pass from the hot medium compartment
through the membrane to the permeate gap compartment. The thermally
conductive plate is disposed between the permeate gap compartment
and the cold medium compartment. The thermally conductive plate and
the cold medium stream within the cold medium compartment are
cooperatively configured to condense the water vapor from the hot
medium compartment that passed through the membrane. The permeate
outlet is configured to discharge the condensed water vapor from
the permeate gap compartment. The impeller is disposed within the
permeate gap compartment. The impeller is connected to a rotatable
shaft that is configured to couple to and be rotated by a motor.
The impeller is configured to mix fluid within the permeate gap
compartment in response to the rotatable shaft being rotated by the
motor.
[0004] This, and other aspects, can include one or more of the
following features.
[0005] In some implementations, the housing includes a first end
and a second end opposite the first end. In some implementations,
each of the hot medium compartment, the permeate gap compartment,
the cold medium compartment, the membrane, and the thermally
conductive plate span from the first end to the first end. In some
implementations, the hot medium inlet and the cold medium outlet
are disposed at the first end of the housing. In some
implementations, the hot medium outlet and the cold medium inlet
are disposed at the second end of the housing.
[0006] In some implementations, the permeate gap compartment
includes a liquid including water.
[0007] In some implementations, the membrane is configured to
prevent liquid from passing through the membrane. In some
implementations, the membrane includes a composite membrane, a
nano-composite membrane, a hydrophobic membrane, an omniphobic
membrane, a hydrophilic and hydrophobic composite dual layer
membrane, a modified ceramic membrane, a porous ceramic membrane, a
surface modified membrane, a polymer electrolyte membrane, a porous
graphene membrane, or a polymeric membrane.
[0008] In some implementations, a contact angle of a droplet of the
hot medium stream on the membrane is greater than 90
degrees)(.degree..
[0009] In some implementations, the impeller has a blade angle in a
range of from 1.degree. to 55.degree..
[0010] In some implementations, the thermally conductive plate
includes metal, composite material, carbon fibers, carbon
nanotubes, or sapphire.
[0011] In some implementations, the hot medium stream includes
seawater, industrial wastewater, brackish water, produced water,
fruit juice, blood, milk, dye, non-condensable gas, non-potable
water, or a combination of these.
[0012] In some implementations, the cold medium stream includes the
hot medium stream after the hot medium stream has been cooled,
water, air, oil, or a combination of these.
[0013] In some implementations, the apparatus includes a first heat
exchanger in fluid communication with the hot medium compartment
and the membrane. In some implementations, the first heat exchanger
is configured to heat the hot medium stream before the hot medium
stream is received by the hot medium inlet.
[0014] In some implementations, the apparatus includes a second
heat exchanger in fluid communication with the cold medium
compartment and the thermally conductive plate. In some
implementations, the second heat exchanger is configured to cool
the cold medium stream before the cold medium stream is received by
the cold medium inlet.
[0015] Certain aspects of the subject matter described can be
implemented as a method. A feed stream including water is received
in a hot medium compartment of a membrane distillation apparatus. A
cold medium stream is received in a cold medium compartment of the
membrane distillation apparatus. The membrane distillation
apparatus includes a permeate gap compartment that is intermediate
of the hot medium compartment and the cold medium compartment.
Water vapor originating from the feed stream is allowed by a
membrane to pass from the hot medium compartment through the
membrane to the permeate gap compartment while preventing liquid
from passing through the membrane. The membrane is disposed within
the membrane distillation apparatus between the hot medium
compartment and the permeate gap compartment. An impeller disposed
within the permeate gap compartment is rotated, thereby resulting
in mixing fluid within the permeate gap compartment, decreasing
pressure on a side of the membrane facing the permeate gap
compartment, and promoting heat and mass transfer within the
permeate gap compartment. The water vapor from the hot medium
compartment that passed through the membrane is condensed by a
thermally conductive plate to form a permeate stream having a water
purity level that is greater than that of the feed stream. The
thermally conductive plate is disposed within the membrane
distillation apparatus between the cold medium compartment and the
permeate gap compartment. The permeate stream is discharged from
the membrane distillation apparatus by a permeate outlet of the
permeate gap compartment.
[0016] This, and other aspects, can include one or more of the
following features.
[0017] In some implementations, condensing the water vapor from the
hot medium compartment that passed through the membrane includes
contacting the water vapor on a first side of the thermally
conductive plate facing the permeate gap compartment and contacting
the cold medium stream on a second side of the thermally conductive
plate facing the cold medium compartment.
[0018] In some implementations, the method includes heating the
feed stream by a first heat exchanger before the feed stream is
received in the hot medium compartment.
[0019] In some implementations, the method includes heating the
membrane by the first heat exchanger.
[0020] In some implementations, the method includes cooling the
cold medium stream by a second heat exchanger before the cold
medium stream is received in the cold medium compartment.
[0021] In some implementations, the method includes cooling the
thermally conductive plate by the second heat exchanger.
[0022] Certain aspects of the subject matter described can be
implemented as a membrane distillation system. The system includes
an apparatus and a motor. The apparatus includes a housing and an
impeller. The housing includes a first end and a second end
opposite the first end. The housing includes a hot medium
compartment, a cold medium compartment, a permeate gap compartment,
a membrane, and a thermally conductive plate. The hot medium
compartment spans from the first end to the second end. The hot
medium compartment includes a hot medium inlet and a hot medium
outlet. The hot medium inlet is disposed at the first end. The hot
medium inlet is configured to receive a hot medium stream including
water. The cold medium compartment spans from the first end to the
second end. The cold medium compartment includes a cold medium
inlet and a cold medium outlet. The cold medium inlet is disposed
at the second end. The cold medium inlet is configured to receive a
cold medium stream. The permeate gap compartment spans from the
first end to the second end. The permeate gap compartment is
intermediate of the hot medium compartment and the cold medium
compartment. The permeate gap compartment includes a permeate
outlet. The membrane spans from the first end to the second end.
The membrane is disposed between the hot medium compartment and the
permeate gap compartment. The membrane defines pores that are sized
to allow water vapor originating from the hot medium stream to pass
from the hot medium compartment through the membrane to the
permeate gap compartment. The thermally conductive plate spans from
the first end to the second end. The thermally conductive plate is
disposed between the permeate gap compartment and the cold medium
compartment. The thermally conductive plate and the cold medium
stream within the cold medium compartment are cooperatively
configured to condense the water vapor from the hot medium
compartment that passed through the membrane. The permeate outlet
is configured to discharge the condensed water vapor from the
permeate gap compartment. The impeller is disposed within the
permeate gap compartment. The impeller is connected to a rotatable
shaft. The impeller is configured to mix fluid within the permeate
gap compartment in response to the rotatable shaft being rotated.
The motor is coupled to the rotatable shaft. The motor is
configured to rotate the rotatable shaft in response to receiving
power.
[0023] This, and other aspects, can include one or more of the
following features.
[0024] In some implementations, the impeller has a blade angle in a
range of from 1.degree. to 55.degree..
[0025] In some implementations, the system includes a first heat
exchanger in fluid communication with the hot medium compartment
and the membrane. In some implementations, the first heat exchanger
is configured to heat the hot medium stream before the hot medium
stream is received by the hot medium inlet. In some
implementations, the system includes a second heat exchanger in
fluid communication with the cold medium compartment and the
thermally conductive plate. In some implementations, the second
heat exchanger is configured to cool the cold medium stream before
the cold medium stream is received by the cold medium inlet.
[0026] The details of one or more implementations of the subject
matter of this disclosure are set forth in the accompanying
drawings and the description. Other features, aspects, and
advantages of the subject matter will become apparent from the
description, the drawings, and the claims.
DESCRIPTION OF DRAWINGS
[0027] FIG. 1A is a schematic diagram of an example membrane
distillation apparatus.
[0028] FIG. 1B is a schematic diagram of an example membrane
distillation system.
[0029] FIG. 1C is a schematic diagram of an example membrane
distillation system.
[0030] FIG. 2 is a flow chart of an example method for membrane
distillation.
[0031] FIG. 3 is a comparative chart of permeate flux at various
operating temperatures.
DETAILED DESCRIPTION
[0032] Membrane distillation (MD) is a combined thermal and
membrane-based separation process which allows vapor permeation
across a membrane and prevents liquid penetration. The MD
separation process is commonly applied in water desalination by
separating water vapor from a brine stream using a micro-porous
membrane. The feed stream received by the feed side of the MD is
usually warm to encourage evaporation, while the temperature of the
coolant stream received by the coolant side of the MD is usually
kept lower than that of the feed stream temperature to encourage
condensation. The driving force for water vapor permeation across
the membrane is the vapor pressure difference. The vapor pressure
difference is induced by the temperature gradient across the
membrane. Membrane distillation can be performed at a low feed
temperature (usually less than 100.degree. C.) and can be operated
by renewable energy and low grade energy sources, such as solar
energy, wind energy, geothermal energy, and waste heat.
[0033] The MD module generally exist in four main configurations
that include sweeping gas membrane distillation (SGMD), vacuum
membrane distillation (VIVID), direct contact membrane distillation
(DCMD) and air gap membrane distillation (AGMD). These MD
configurations is operated by the same principle (vapor generation,
vapor permeation across membrane and vapor condensation). The
differences among these configurations lie in the design of their
condensation chambers, while the feed side of the modules typically
remain the same for all configurations. While the direct contact
membrane distillation system yields high permeate flux, it is
characterized by high conductive heat loss and high temperature
polarization effect. Permeate contamination is possible in DCMD.
AGMD is characterized by low conductive heat loss and low
temperature polarization effect. However, AGMD yields low permeate
flux due to resistance to mass transfer by air in the distillate
chamber. Permeate gap membrane distillation (PGMD) is a type of MD
configuration with an enhanced permeate flux in comparison to AGMD.
PGMD is sometimes referred to as liquid gap membrane distillation
(LGMD) or water gap membrane distillation (WGMD). In PGMD, the
stagnant air in the distillate chamber of an AGMD is replaced with
a liquid, such as distilled water or deionized water. In PGMD,
vapor from the feed stream permeates across the membrane pores and
condenses at the interface between the permeate side of the
membrane and the water in the distillate zone.
[0034] Despite the introduction of innovative designs to MD and
advancements in the membrane development, membrane distillation
technology is still not commonly used at commercial scales. An
objective of the current disclosure is to propose a PGMD module
with an impeller installed within the distillate zone of the
module. The subject matter described in this disclosure can be
implemented, for example, in desalination, waste treatment, food,
and medical applications. The subject matter described in this
disclosure can be implemented in particular implementations, so as
to realize one or more of the following advantages. The rotating
impeller can produce suction (decreased pressure) on the permeate
side of the membrane, thereby promoting vapor permeation through
the membrane and enhancing permeate flux and energy efficiency.
Further, the rotating impeller can induce turbulent dissipation in
the distillation zone, thereby promoting mass and heat transfer
within the distillate zone.
[0035] FIG. 1A is a schematic diagram of a membrane distillation
apparatus 100. The apparatus 100 can be an MD module having a
configuration selected from a reinforced hollow tube configuration,
a non-reinforced hollow tube configuration, a spiral wound
configuration, a flat sheet configuration or non-flat
configuration. The apparatus 100 includes a housing 101 and an
impeller 190. The housing 101 includes a hot medium compartment
110, a permeate gap compartment 130, and a cold medium compartment
150. The housing 101 includes a membrane 120 disposed between the
hot medium compartment 110 and the permeate gap compartment 130.
The housing 101 includes a thermally conductive plate 140 disposed
between the permeate gap compartment 130 and the cold medium
compartment 150. The impeller 190 is disposed within the permeate
gap compartment 130. In some implementations, the housing 101
comprises a first end 101a and a second end 101b that is opposite
the first end 101a. In some implementations, each of the hot medium
compartment 110, the membrane 120, the permeate gap compartment
130, the thermally conductive plate 140, and the cold medium
compartment 150 spans from the first end 101a to the second end
101b.
[0036] The hot medium compartment 110 includes a hot medium inlet
111 and a hot medium outlet 113. The hot medium inlet 111 is
configured to receive a hot medium stream 112 that includes water.
The hot medium stream 112 can be considered a feed stream. The hot
medium stream 112 can be, for example, seawater, industrial
wastewater, brackish water, produced water, fruit juice, blood,
milk, dye, harmful waste flow, brine solution, non-condensable gas,
non-potable water, or any liquid including dissolved salt, for
example, a mixture of salts, a salt and organic contaminant
mixture, a salt and inorganic contaminant mixture, or a combination
of these. The hot medium outlet 113 is configured to discharge the
hot medium stream 112 from the housing 101. In some
implementations, the hot medium inlet 111 is disposed at the first
end 101a of the housing 101. In some implementations, the hot
medium outlet 113 is disposed at the second end 101b of the housing
101.
[0037] The membrane 120 defines multiple pores 121 that are sized
to allow water vapor originating from the hot medium stream 112 to
pass from the hot medium compartment 110 through the membrane 120
to the permeate gap compartment 130. The membrane 120 is configured
to prevent liquid from passing through the membrane 120. The
membrane 120 can be, for example, a composite membrane, a
nano-composite membrane, a hydrophobic membrane, an omniphobic
membrane, a hydrophilic and hydrophobic composite dual layer
membrane, a modified ceramic membrane, a porous ceramic membrane, a
surface modified membrane, a polymer electrolyte membrane, a porous
graphene membrane, or a polymeric membrane. In some
implementations, the membrane 120 includes a support layer and an
active layer. The membrane 120 can be made, for example, from a
porous material. In some implementations, a contact angle of a
droplet of the hot medium stream 112 on the membrane 120 is greater
than 90 degrees)(.degree..
[0038] The permeate gap compartment 130 includes a permeate outlet
131. In some implementations, the permeate gap compartment 130
includes a liquid including water. For example, the permeate gap
compartment 130 includes pure water, distilled water, or deionized
water. In some implementations, the permeate gap compartment 130
includes a pure liquid other than water. In some implementations,
the width of the permeate gap compartment 130 is in a range of from
about 0.05 millimeters (mm) to 200 mm. In some implementations, the
permeate gap compartment 130 is a fixed gap compartment. For
example, the width of the permeate gap compartment 130 between the
membrane 120 and the thermally conductive plate 140 is uniform from
the first end 101a to the second end 101b. In some implementations,
the permeate gap compartment 130 is a variable gap compartment. For
example, the width of the permeate gap compartment 130 between the
membrane 120 and the thermally conductive plate 140 is non-uniform
from the first end 101a to the second end 101b. For example, the
thermally conductive plate 140 can be disposed at an angle
deviating from the vertical, such that the width of the permeate
gap compartment 130 between the membrane 120 and the thermally
conductive plate 140 gradually increases from the first end 101a to
the second end 101b.
[0039] The impeller 190 is connected to a rotatable shaft 191 that
is configured to couple to and be rotated by a motor (shown in FIG.
1B and described in more detail later). In some implementations,
rotation of the rotatable shaft 191 (and in turn, the impeller 190)
is provided by a motor-less magnetic induction means, Geneva drive,
Maltese cross mechanism, or anchor escapement. The impeller 190 is
configured to mix fluid within the permeate gap compartment 130 in
response to the rotatable shaft 191 being rotated by the motor. In
some implementations, the impeller 190 includes a single blade. In
some implementations, the impeller 190 includes multiple blades. In
some implementations, the impeller 190 has a blade angle in a range
of from 1.degree. to 55.degree.. The blade(s) of the impeller 190
can be of a regular shape (such as circular or triangular) or an
irregular shape. In some implementations, the impeller 190 is
maintained at a distance of at least 1 mm or at least 2 mm away
from the membrane 120. In some implementations, the impeller 190 is
maintained at a distance of at least 1 mm or at least 2 mm away
from the thermally conductive plate 140. The impeller 190 can be
made of a material that is non-corrosive (that is, resistant to
corrosion) and chemically inert in relation to the hot medium
stream 112, the cold medium stream 152, and the permeate stream
132. The impeller 190 can be made, for example, from metallic
material, polymeric material, composite material, carbon fibers,
carbon nanotubes, or sapphire.
[0040] In some implementations, the rotatable shaft 191 penetrates
the housing 101 through a rubber seal bearing. The rubber seal
bearing prevents and/or mitigates fluid leakage from the housing,
for example, while the rotatable shaft 191 rotates. In some
implementations, the rubber seal bearing maintains a position of
the rotatable shaft 191 relative to other components of the
apparatus 100, for example, while the rotatable shaft 191 rotates.
For example, the rubber seal bearing can maintain the rotatable
shaft 191 to be perpendicular to the membrane 120 and the thermally
conductive place 140. For example, the rubber seal bearing can
maintain an axial position of the rotatable shaft 191 such that the
impeller 190 is maintained at a distance of at least 1 mm or at
least 2 mm away from the membrane 120 and also at least 1 mm or at
least 2 mm away from the thermally conductive plate 140. In some
implementations, the rubber seal bearing includes an inner rubber
ring and an outer rubber ring separated by multiple roller balls.
In some implementations, the roller balls are carried within a cage
that is covered by a sealing disk. In some implementations, the
rubber seal bearing is fit into the thermally conductive plate 140,
which can prevent leakage of fluid through the thermally conductive
plate 140.
[0041] The cold medium compartment 150 includes a cold medium inlet
151 and a cold medium outlet 153. The cold medium inlet 151 is
configured to receive a cold medium stream 152. The cold medium
stream 152 can be considered a coolant. The cold medium stream 152
can be, for example, the hot medium stream 112 after the hot medium
stream 112 exits the hot medium outlet 113 and has been cooled for
use as a coolant. In some implementations, the cold medium stream
152 includes water, air, oil, or a combination of these. In some
implementations, the cold medium stream 152 includes a fluid other
than water, air, or oil. The cold medium outlet 153 is configured
to discharge the cold medium stream 152 from the housing 101. In
some implementations, the cold medium inlet 151 is disposed at the
second end 101b of the housing 101. In some implementations, the
cold medium outlet 153 is disposed at the first end 101a of the
housing 101. Having the hot medium inlet 111 and the cold medium
inlet 151 at opposing ends of the housing 101 and the hot medium
outlet 113 and the cold medium outlet 153 at opposing ends of the
housing 101 allows for the hot medium stream 112 and the cold
medium stream 152 to flow in a counter-current manner through the
housing 101, which can improve heat transfer within the housing
101. In some implementations, the hot medium stream 112 and the
cold medium stream 152 flow in a concurrent flow manner through the
housing 101. In some implementations, the hot medium stream 112 and
the cold medium stream 152 flow in a cross-flow manner through the
housing 101.
[0042] The thermally conductive plate 140 and the cold medium
stream 152 within the cold medium compartment 150 are cooperatively
configured to condense the water vapor (from the hot medium
compartment 110 that passed through the membrane 120) in the
permeate gap compartment 130 to form a permeate stream 132. In some
implementations, the thermally conductive plate 140 is in the form
of a thin, metallic plate or a thin, polymeric plate. In some
implementations, the thermally conductive plate 140 is in the form
of thin, metallic tubes or thin, polymeric tubes. The thermally
conductive plate 140 can be made, for example, from metallic
material, composite material, carbon fibers, carbon nanotubes, or
sapphire. The permeate stream 132 formed in the permeate gap
compartment 130 is discharged from the apparatus 100 via the
permeate outlet 131. The permeate stream 132 has a water purity
level that is greater than a water purity level of the hot medium
stream 112.
[0043] In some implementations, the apparatus 100 includes a first
heat exchanger 160a in fluid communication with the hot medium
compartment 110 and the membrane 120. In such implementations, the
first heat exchanger 160a can be configured to heat the hot medium
stream 112 before the hot medium stream 112 is received by the hot
medium inlet 111. The first heat exchanger 160a can utilize, for
example, renewable energy, low-enthalpy geothermal energy,
industrial waste heat, low or high-grade energy sources, an
electric source, low-grade steam from nuclear power plants, heat
from any thermal plants such as diesel engines, power plants,
desalination plants, or a combination of these to heat the hot
medium stream 112. In some implementations, the hot medium stream
112 is pressurized before being received by the hot medium inlet
111. In some cases, pressurizing the hot medium stream 112 can also
result in increasing the temperature of the hot medium stream
112.
[0044] In some implementations, the apparatus 100 includes a second
heat exchanger 160b in fluid communication with the cold medium
compartment 150 and the thermally conductive plate 140. In such
implementations, the second heat exchanger 160b can be configured
to cool the cold medium stream 152 before the cold medium stream
152 is received by the cold medium inlet 151.
[0045] The hot medium compartment 110, the permeate gap compartment
130, and the cold medium compartment 150 of the apparatus 100 may
be of any shape, such as rectangular, triangular, square, circular,
cylindrical, hexagonal, or spherical. The housing 101 can be made,
for example, from metallic material, polymeric material, composite
material, carbon fiber, carbon nanotube, or sapphire. In some
implementations, the housing 101 is made of steel, brass, copper,
high density polyethylene (HDPE), acrylic, or polyvinyl chloride
(PVC).
[0046] In some implementations, the housing 101 includes a frame,
support, gasket, or a combination of these, which can provide
structural support for any of the compartments (110, 130, 150), the
membrane 120, and/or the thermally conductive plate 140. The
supporting structure can be made of a material that is
non-corrosive and chemically inert in relation to the hot medium
stream 112 and the cold medium stream 152. The supporting structure
can be made, for example, from metallic material, polymeric
material, composite material, carbon fibers, carbon nanotubes, or
sapphire.
[0047] FIG. 1B is a schematic diagram of a system 1000a including
multiple implementations of the apparatus 100 in series. Each
individual implementation of the apparatus 100 is labeled with a
letter (100a, 100b, 100c) in this example. Although shown in FIG.
1B as including three implementations of the apparatus 100 in
series, the system 1000a can include fewer implementations (for
example, two implementations) or additional implementations (for
example, four or five implementations) of the apparatus 100 in
series. The system 1000a includes a motor 195 that is coupled to
the rotatable shafts 191 of the apparatuses 100. The motor 195 is
configured to rotate the rotatable shafts 191 (and in turn, the
impellers 190) in response to receiving power. The motor 195 can
receive power, for example, from electricity, a photovoltaic cell,
a battery, mechanical means, or chemical means. Although shown in
FIG. 1B as including a single motor 195 connected to all of the
rotatable shafts 191, the system 1000a can include additional
implementations of the motor 195. For example, the system 1000a can
include a separate motor 195 for each of the rotatable shafts 191.
For example, if the system 1000a includes three rotatable shafts
191, then the system 1000a can include three motors 195.
[0048] In the series configuration, the hot medium outlet 113 of
apparatus 100a discharges the hot medium stream 112 to the hot
medium inlet 111 of apparatus 100b, and the hot medium outlet 113
of apparatus 100b discharges the hot medium stream 112 to the hot
medium inlet 111 of apparatus 100c. In some implementations (as
shown in FIG. 1B), the cold medium stream 152 is split and
distributed to each of the cold medium inlets 151 of the various
apparatuses 100a, 100b, and 100c in a parallel configuration. In
some implementations similar to the series flow configuration of
the hot medium stream 112, the cold medium outlet 153 of apparatus
100c discharges the cold medium stream 152 to the cold medium inlet
151 of apparatus 100b, and the cold medium outlet 153 of apparatus
100b discharges the cold medium stream 152 to the cold medium inlet
151 of apparatus 100a. Regardless of the configuration, the
difference between the operating temperature of the hot medium
stream 112 and the operating temperature of the cold medium stream
152 entering each apparatus (100a, 100b, 100c) is at least 10
degrees Celsius (.degree. C.). In some implementations, the
difference between the operating temperature of the hot medium
stream 112 and the operating temperature of the cold medium stream
152 entering each apparatus (100a, 100b, 100c) is in a range of
from 10.degree. C. and 20.degree. C.
[0049] In the series configuration, because some mass from the hot
medium stream 112 is transferred as permeate in each of the
apparatuses 100a, 100b, and 100c, the hot medium stream 112 exiting
each apparatus has a decreased mass flow in comparison to the hot
medium stream 112 that entered that respective apparatus. Further,
the hot medium stream 112 exiting each apparatus has a decreased
water purity in comparison to the hot medium stream 112 that
entered that respective apparatus. For example, the hot medium
stream 112 exiting apparatus 100a has a decreased mass flow and a
decreased water purity in comparison to the hot medium stream 112
entering apparatus 100a. For example, the hot medium stream 112
exiting apparatus 100b has a decreased mass flow and a decreased
water purity in comparison to the hot medium stream 112 entering
apparatus 100b. For example, the hot medium stream 112 exiting
apparatus 100c has a decreased mass flow and a decreased water
purity in comparison to the hot medium stream 112 entering
apparatus 100c.
[0050] The permeate streams 132 exiting each of the apparatuses
100a, 100b, and 100c can be combined. The resulting combined stream
can be considered the purified water stream. In some
implementations, the purified water stream can undergo additional
processing to further purify the water stream.
[0051] FIG. 1C is a schematic diagram of a system 1000b that is
substantially similar to the system 1000a, but includes multiple
implementations of the apparatus 100 in parallel (as opposed to in
series). Although shown in FIG. 1C as including three
implementations of the apparatus 100 in parallel, the system 1000b
can include fewer implementations (for example, two
implementations) or additional implementations (for example, four
or five implementations) of the apparatus 100 in parallel. The
system 1000b includes a motor 195 that is coupled to the rotatable
shafts 191 of the apparatuses 100. The motor 195 is configured to
rotate the rotatable shafts 191 (and in turn, the impellers 190) in
response to receiving power. The motor 195 can receive power, for
example, from electricity, a photovoltaic cell, a battery,
mechanical means, or chemical means. Although shown in FIG. 1C as
including a single motor 195 connected to all of the rotatable
shafts 191, the system 1000b can include additional implementations
of the motor 195. For example, the system 1000b can include a
separate motor 195 for each of the rotatable shafts 191. For
example, if the system 1000b includes three rotatable shafts 191,
then the system 1000b can include three motors 195.
[0052] In the parallel configuration, the hot medium stream 112 is
split and distributed to each of the hot medium inlets 111 of the
various apparatuses 100a, 100b, and 100c. In some implementations
(as shown in FIG. 1C), the cold medium stream 152 is split and
distributed to each of the cold medium inlets 151 of the various
apparatuses 100a, 100b, and 100c in a parallel configuration.
[0053] The permeate streams 132 exiting each of the apparatuses
100a, 100b, and 100c can be combined. The resulting combined stream
can be considered the purified water stream. In some
implementations, the purified water stream can undergo additional
processing to further purify the water stream.
[0054] FIG. 2 is a flow chart of a method 200 for membrane
distillation. The apparatus 100 can be used to implement the method
200. At step 202, a feed stream including water (such as the hot
medium stream 112) is received in a hot medium compartment (such as
the hot medium compartment 110) of a membrane distillation
apparatus (such as the apparatus 100). In some implementations, the
hot medium stream 112 is heated (for example, by a first heat
exchanger 160a) before the hot medium stream 112 is received in the
hot medium compartment 110 at step 202.
[0055] At step 204, a cold medium stream (such as the cold medium
stream 152) is received in a cold medium compartment (such as the
cold medium compartment 150) of the apparatus 100. As described
previously, the apparatus 100 includes a permeate gap compartment
130 that is intermediate of the hot medium compartment 110 and the
cold medium compartment 150. In some implementations, the cold
medium stream 152 is cooled (for example, by a second heat
exchanger 160b) before the cold medium stream 152 is received in
the cold medium compartment 150 at step 204.
[0056] At step 206, water vapor originating from the hot medium
stream 112 is allowed by a membrane (such as the membrane 120) to
pass from the hot medium compartment 110 through the membrane 120
to the permeate gap compartment 130 while liquid is prevented from
passing through the membrane 120. As described previously, the
membrane 120 is disposed within the apparatus 100 between the hot
medium compartment 110 and the permeate gap compartment 130. In
some implementations, the first heat exchanger 160a heats the
membrane 120.
[0057] At step 208, an impeller (such as the impeller 190) disposed
within the permeate gap compartment 130 is rotated, thereby
resulting in mixing fluid within the permeate gap compartment 130.
Rotating the impeller 190 at step 208 can also result in decreasing
pressure on a side of the membrane 120 facing the permeate gap
compartment 130. Rotating the impeller 190 at step 208 can also
result in promoting heat and mass transfer within the permeate gap
compartment 130.
[0058] At step 210, the water vapor from the hot medium compartment
110 that passed through the membrane 120 is condensed by a
thermally conductive plate (such as the thermally conductive plate
140) to form a permeate stream (such as the permeate stream 132)
having a water purity level that is greater than that of the hot
medium stream 112. As described previously, the thermally
conductive plate 140 is disposed within the apparatus 100 between
the cold medium compartment 150 and the permeate gap compartment
130. In some implementations, condensing the water vapor at step
210 includes contacting the water vapor on a first side of the
thermally conductive plate 140 facing the permeate gap compartment
130 and contacting the cold medium stream 152 on a second side of
the thermally conductive plate 140 facing the cold medium
compartment 150. In some implementations, the second heat exchanger
160b cools the thermally conductive plate 140.
[0059] At step 212, the permeate stream 132 is discharged from the
apparatus 100 by a permeate outlet (such as the permeate outlet
131) of the permeate gap compartment 130.
[0060] Although shown in FIG. 2 as a progression of steps, the
steps of method 200 are not necessarily performed in sequence and
can instead be performed in parallel. That is, all of the steps of
method 200 can occur simultaneously. In some cases, portions of
each of the steps of method 200 can overlap temporally.
Example
[0061] A permeate gap membrane distillation module included a flat
sheet polytetrafluoroethylene membrane with an effective area of
0.00309 square meters and a mean pore size of 0.45 micrometers. The
permeate gap compartment width was created with acrylic plastic
having an effective gap width of 11 millimeters between the
thermally conductive plate and the membrane. A direct current motor
was used to drive rotation of the impeller installed within the
permeate gap compartment. The motor power consumption for each test
was 1.33 watts. The feed stream (hot medium stream) salinity was
maintained at about 1,000 milligrams per liter throughout the
experiment. The flow rate of the feed stream was maintained at 1.4
liters per minute. The flow rate of the cold medium stream was
maintained at 1.95 liters per minute. The operating temperature of
the cold medium stream entering the module was 15.degree. C. The
operating temperature of the feed stream entering the module was
varied for the various tests (60.degree. C., 70.degree. C., and
80.degree. C.). The total dissolved solids (TDS) level of the
permeate flux was less than 2.3 milligrams per liter throughout the
experiment.
[0062] FIG. 3 shows the permeate flux production for a PGMD system
without the rotating impeller and an R-PGMD system that included
the rotating impeller. The R-PGMD system including the rotating
impeller yielded more permeate flux for each test in comparison to
the PGMD system without the rotating impeller. The results
presented in FIG. 3 show that the R-PGMD system including the
rotating impeller attained, on average, a greater than 72% increase
in permeate flux in comparison to the PGMD system without the
rotating impeller under the same operating conditions. A maximum
permeate flux of greater than 125 kilograms per square meter-hour
was attained by the R-PGMD system including the rotating impeller
for the test with the feed stream at an operating temperature of
80.degree. C.
[0063] While this specification contains many specific
implementation details, these should not be construed as
limitations on the scope of what may be claimed, but rather as
descriptions of features that may be specific to particular
implementations. Certain features that are described in this
specification in the context of separate implementations can also
be implemented, in combination, in a single implementation.
Conversely, various features that are described in the context of a
single implementation can also be implemented in multiple
implementations, separately, or in any sub-combination. Moreover,
although previously described features may be described as acting
in certain combinations and even initially claimed as such, one or
more features from a claimed combination can, in some cases, be
excised from the combination, and the claimed combination may be
directed to a sub-combination or variation of a
sub-combination.
[0064] As used in this disclosure, the terms "a," "an," or "the"
are used to include one or more than one unless the context clearly
dictates otherwise. The term "or" is used to refer to a
nonexclusive "or" unless otherwise indicated. The statement "at
least one of A and B" has the same meaning as "A, B, or A and B."
In addition, it is to be understood that the phraseology or
terminology employed in this disclosure, and not otherwise defined,
is for the purpose of description only and not of limitation. Any
use of section headings is intended to aid reading of the document
and is not to be interpreted as limiting; information that is
relevant to a section heading may occur within or outside of that
particular section.
[0065] As used in this disclosure, the term "about" or
"approximately" can allow for a degree of variability in a value or
range, for example, within 10%, within 5%, or within 1% of a stated
value or of a stated limit of a range.
[0066] As used in this disclosure, the term "substantially" refers
to a majority of, or mostly, as in at least about 50%, 60%, 70%,
80%, 90%, 95%, 96%, 97%, 98%, 99%, 99.5%, 99.9%, 99.99%, or at
least about 99.999% or more.
[0067] Values expressed in a range format should be interpreted in
a flexible manner to include not only the numerical values
explicitly recited as the limits of the range, but also to include
all the individual numerical values or sub-ranges encompassed
within that range as if each numerical value and sub-range is
explicitly recited. For example, a range of "0.1% to about 5%" or
"0.1% to 5%" should be interpreted to include about 0.1% to about
5%, as well as the individual values (for example, 1%, 2%, 3%, and
4%) and the sub-ranges (for example, 0.1% to 0.5%, 1.1% to 2.2%,
3.3% to 4.4%) within the indicated range. The statement "X to Y"
has the same meaning as "about X to about Y," unless indicated
otherwise. Likewise, the statement "X, Y, or Z" has the same
meaning as "about X, about Y, or about Z," unless indicated
otherwise.
[0068] Particular implementations of the subject matter have been
described. Other implementations, alterations, and permutations of
the described implementations are within the scope of the following
claims as will be apparent to those skilled in the art. While
operations are depicted in the drawings or claims in a particular
order, this should not be understood as requiring that such
operations be performed in the particular order shown or in
sequential order, or that all illustrated operations be performed
(some operations may be considered optional), to achieve desirable
results. In certain circumstances, multitasking or parallel
processing (or a combination of multitasking and parallel
processing) may be advantageous and performed as deemed
appropriate.
[0069] Moreover, the separation or integration of various system
modules and components in the previously described implementations
should not be understood as requiring such separation or
integration in all implementations, and it should be understood
that the described components and systems can generally be
integrated together or packaged into multiple products.
[0070] Accordingly, the previously described example
implementations do not define or constrain the present disclosure.
Other changes, substitutions, and alterations are also possible
without departing from the spirit and scope of the present
disclosure.
* * * * *