U.S. patent application number 17/386208 was filed with the patent office on 2021-11-18 for methods of making z-shielding.
The applicant listed for this patent is UNITED STATES OF AMERICA AS REPRESENTED BY THE ADMINISTRATOR OF NASA, UNITED STATES OF AMERICA AS REPRESENTED BY THE ADMINISTRATOR OF NASA. Invention is credited to JOEL A. ALEXA, ROBERTO J. CANO, STEPHEN J. HALES, BRIAN J. JENSEN, DONALD L. THOMSEN, III.
Application Number | 20210360841 17/386208 |
Document ID | / |
Family ID | 1000005750050 |
Filed Date | 2021-11-18 |
United States Patent
Application |
20210360841 |
Kind Code |
A1 |
THOMSEN, III; DONALD L. ; et
al. |
November 18, 2021 |
METHODS OF MAKING Z-SHIELDING
Abstract
Aspects relate to building Z-graded radiation shielding and
covers. In one aspect, the method includes: providing a substrate
surface having about medium Z-grade; plasma spraying a first metal
having higher Z-grade than the substrate surface; and infusing a
polymer layer to form a laminate. In another aspect, the method
includes electro/electroless plating a first metal having higher
Z-grade than the substrate surface. In other aspects, the invention
provides methods of improving an existing electronics enclosure to
build a Z-graded radiation shield by applying a temperature
controller to at least part of the enclosure and affixing at least
one layer of a first metal having higher Z-grade than the
enclosure.
Inventors: |
THOMSEN, III; DONALD L.;
(YORKTOWN, VA) ; CANO; ROBERTO J.; (YORKTOWN,
VA) ; JENSEN; BRIAN J.; (WILLIAMSBURG, VA) ;
HALES; STEPHEN J.; (POQUOSON, VA) ; ALEXA; JOEL
A.; (HAMPTON, VA) |
|
Applicant: |
Name |
City |
State |
Country |
Type |
UNITED STATES OF AMERICA AS REPRESENTED BY THE ADMINISTRATOR OF
NASA |
WASHINGTON |
DC |
US |
|
|
Family ID: |
1000005750050 |
Appl. No.: |
17/386208 |
Filed: |
July 27, 2021 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
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16047474 |
Jul 27, 2018 |
11076516 |
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17386208 |
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13963484 |
Aug 9, 2013 |
10039217 |
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16047474 |
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13191882 |
Jul 27, 2011 |
8661653 |
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13963484 |
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61368361 |
Jul 28, 2010 |
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Current U.S.
Class: |
1/1 |
Current CPC
Class: |
C23C 28/00 20130101;
C23C 4/08 20130101; Y10T 442/259 20150401; Y10T 29/4902 20150115;
Y10T 442/2049 20150401; B29C 70/88 20130101; C23C 4/02 20130101;
C23C 4/18 20130101; Y10T 29/49002 20150115; Y10T 29/49224 20150115;
H05K 13/00 20130101; Y10T 442/2041 20150401; C23C 28/021 20130101;
B29C 70/48 20130101; C23C 28/023 20130101 |
International
Class: |
H05K 13/00 20060101
H05K013/00; B29C 70/48 20060101 B29C070/48; B29C 70/88 20060101
B29C070/88; C23C 4/02 20060101 C23C004/02; C23C 4/08 20060101
C23C004/08; C23C 4/18 20060101 C23C004/18; C23C 28/00 20060101
C23C028/00; C23C 28/02 20060101 C23C028/02 |
Goverment Interests
STATEMENT REGARDING FEDERALLY SPONSORED RESEARCH AND
DEVELOPMENT
[0002] This invention was made in part with Government support
under Contract Numbers NNO7AA008 and NNL07AM071 awarded by the
National Aeronautics and Space Administration. The Government may
have certain rights in this invention.
Claims
1. A laminate, comprising: a layered material including a substrate
having a substrate surface with a Z-grade; and a first metal bonded
onto the substrate surface, wherein the first metal has a higher
Z-grade than the substrate surface; and a polymer layer infused
into the layered material.
2. The laminate of claim 1, wherein the first metal comprises a
compound selected from the group consisting of tantalum, copper,
tungsten, titanium, aluminum, rhenium, alloys of one or more of
tantalum, copper, tungsten, titanium, aluminum, rhenium, and
combinations thereof.
3. The laminate of claim 1, wherein the polymer comprises a
compound selected from the group consisting of epoxy, polyimide,
cyanate ester, and mixtures thereof.
4. The laminate of claim 1, wherein the substrate surface comprises
metal, glass or graphite fibers.
5. The laminate of claim 1, further comprising a second metal
having a higher Z-grade than the substrate surface bonded to the
first metal.
6. The laminate of claim 5, wherein the second metal is different
from the first metal, and comprises a compound selected from the
group consisting of tantalum, copper, tungsten, titanium, aluminum,
rhenium, and alloys of one or more of tantalum, copper, tungsten,
titanium, aluminum, rhenium, and combinations thereof.
7. The laminate of claim 1, wherein the first metal is patterned in
a shape of a thermal heat pipe.
8. The laminate of claim 3, wherein the compound of the polymer
layer comprises a conductive filler to provide increased
electro-magnetic-interference resistance.
9. The laminate of claim 1, wherein the laminate forms a radiation
shielding cover or structure.
10. The laminate of claim 9, wherein the laminate is shaped into a
structure selected from the group consisting of slab, thermal
barrier, vault, spot enclosure, PCI card chassis structures, and
combinations thereof.
11. The laminate of claim 1, wherein the laminate is shaped into a
structure selected from the group consisting of slab, thermal
barrier, vault, spot enclosure, PCI card chassis structures, and
combinations thereof.
Description
CROSS-REFERENCE TO RELATED APPLICATIONS
[0001] This patent application claims the benefit of priority to
and is a divisional of U.S. Non-Provisional patent application Ser.
No. 16/047,474 filed on Jul. 27, 2018, which is a divisional of
U.S. Non-Provisional patent application Ser. No. 13/963,484 filed
on Aug. 9, 2013 (issued as U.S. Pat. No. 10,039,217 on Jul. 31,
2018), which was a divisional application of U.S. Non-Provisional
patent application Ser. No. 13/191,882, filed on Jul. 27, 2011
(issued as U.S. Pat. No. 8,661,653 on Mar. 4, 2014), which claims
the benefit of and priority to U.S. Provisional Patent Application
No. 61/368,361, filed Jul. 28, 2010. The contents of each of the
foregoing applications are hereby incorporated by reference in
their entireties for any and all non-limiting purposes.
BACKGROUND OF THE INVENTION
[0003] Current methods of radiation shielding incorporate thick
single layer sheet metal using typically one metal or two metals
with different atomic numbers (Z) in separate sheets. Such
radiation shielding is needed for various purposes such as for
nuclear reactors or piping for radioactive fluids. Such shielding
is also needed for protective clothing for nuclear hazardous waste
handlers. Such shielding is also needed for various spacecraft,
extra-vehicular-activity (EVA) suits, and instrumentation tools or
electronics enclosures. Accordingly, a continuing need exists for
improved methods of making shielding tailored to reduced
thicknesses, weights, and/or specific applications.
BRIEF SUMMARY OF THE INVENTION
[0004] In view of the foregoing, it is an object of the invention
to provide a method for manufacturing Z-graded radiation shielding
with tailored weights for specific applications.
[0005] It is a related object of the invention to provide the
ability to manufacture Z-graded laminates for shielding covers or
structures, or to improve existing electronics enclosures with
additional Z-graded materials.
[0006] These objects are achieved by the present invention, which
provides methods of building Z-graded radiation shielding and
covers. In at least one embodiment, methods of building a Z-graded
laminate are provided that include the steps of providing a
substrate surface having about medium Z-grade; plasma spraying a
first metal having higher Z-grade than the substrate surface; and
infusing a polymer layer to form a laminate. In other embodiments,
the methods include providing a substrate surface having about
medium Z-grade; electro/electroless plating a first metal having
higher Z-grade than the substrate surface; and infusing a polymer
layer to form a laminate.
[0007] In yet other embodiments, the invention provides methods of
improving an existing electronics enclosure to build a Z-graded
radiation shield having the steps of providing an existing
electronics enclosure; applying a temperature controller to at
least part of the enclosure; and affixing at least one layer of a
first metal having higher Z-grade than the enclosure.
[0008] Additional objects, embodiments, and details of this
invention can be obtained from the following detailed description
of the invention.
DETAILED DESCRIPTION OF THE INVENTION
[0009] Typical radiation shielding has been made by increasing the
thickness of aluminum enclosures to meet radiation reduction
requirements. For example, methods and programs for engineering
design processes for shields controlling radiation doses to targets
of interest have been disclosed in, inter alia, U.S. Patent
Application Publication No. 2008/0249753 AI, which is entirely
herein incorporated by reference thereto. Z-grading is a method of
improving radiation shielding by using metal layers with varying
densities or layers of other materials. Radiation shielding has
been traditionally done by increasing aluminum sheet thickness for
enclosures to protect electronics. It has been shown that varying
metal densities with different sheets can increase shielding
effectiveness. However, such shielding is typically parasitic,
where it increases the weight of the enclosure with only marginal
structural contribution
[0010] The use of fabrics in Z-shielding increases the
incorporation of flexible materials and laminate materials into
radiation shielding applications. For instance, the use of fabrics
permits spot shields and cable shields in areas where shielding can
improve instrumentation performance and data transfer. The use of
fabrics also permits custom molding and is amenable to having
metal(s) affixed using known methods, including plasma spray
deposition and/or electro/electroless plating. In some advantageous
embodiments, metals may be layered onto other metals as well.
[0011] In at least one embodiment, a high density metal, such as
tungsten or tantalum, or other a high density alloy (like
copper-tungsten), is plasma spray coated to fabric, such as carbon
fiber or glass fiber. Then a lower density metal, such as copper,
is plasma spray coated to fiber. Then a lower density metal, such
as titanium or aluminum, can be added to fiber. Then composite
fiber without metal can be added for the lowest Z-grade layer.
These varying density fiber layers can be shaped and then molded
into appropriate geometry with polymeric resin, such as epoxy,
cyanoester (such as, for example, EX1510 and/or EX1545 by TenCate),
or polyimide, in order to make a laminate. These fabrics may
optionally only be partially infused with polymer or else they may
be fully laminated into a stiff laminate. They can alternatively be
stacked and bent or flexed into a shape and attached to a place
needing shielding with varying amounts of polymer as needed.
[0012] Direct deposition of tantalum, a refractory metal, onto
carbon fiber fabric using radio frequency (RF) plasma spraying has
enabled the development of hybrid metal laminates for reducing high
energy electron radiation. Tantalum bulk values and thin film
values have been reported in the literature as 16.6 and 15.6 g/cm3
respectively. See, e.g. Maissel and Glang, Handbook of Thin Film
Technology, McGraw Hill Publishing, 1970. Tantalum RF plasma spray
foil showed a density of 16.02+/-0.02 g/cm3, volume resistivity
49+/-6 .mu.ohms-cm, and body-centered cubic (bcc) crystal
structure. These values are representative of a dense tantalum
coating, important for radiation shielding of energetic electrons.
The coating process also enables the capability to build
functionally graded layers with varying atomic number (Z). The
incorporation of tantalum coatings (Z=73) with carbon fiber (Z=6)
produces a Z gradient from high to low. Other metals which have
also been successfully RF plasma spray coated on to the carbon
fiber fabric include titanium (Z=22) and copper (Z=29). The
incorporation of high Z and low Z materials increases radiation
shielding performance as a result of the inherently different
stopping powers of each Z material at the atomic level and
collisional/radiative losses at the nuclear level. The ability to
coat carbon fiber fabric with Z-layers permits processing of
radiation shielding with new techniques such as vacuum assisted
resin transfer molding (VARTM) in comparison to traditional sheet
metal methods. These fabrics and resulting consolidated structural
composite laminates demonstrate utility in non-traditional
shielding arrangements, designs, and/or multifunctional structures.
In addition, direct tantalum coating of existing aluminum materials
augments radiation shielding to existing space technologies.
Relevant radiation environments include geostationary earth orbit
(GEO) and outer planetary trajectories where high energy electrons
dominate. Analytical modeling of the GEO electron radiation
environment show gains in radiation shielding when more than one Z
material is layered together. Metal fiber laminates can increase
the radiation shielding effectiveness as a function of weight with
a broad range of applications based on composite manufacturing
processes.
[0013] The incorporation of high Z metal with low Z carbon fiber
composites into a simple Z-grade builds a tailored radiation shield
for high energy electron radiation. Lower Z metals such as Al, Ti,
and Cu have also been sprayed. In some embodiments, preferred
features of the new materials made by the invention are that layers
of RF Plasma sprayed metals can be manufactured on top of each
other. Typical Z-layering approaches require the use of metal rod
or sheet that must be cut and machined. If more than one metal is
used on top of each other, the materials must be attached by screws
or adhesive with individual layers grounded. Varying thicknesses
between sheet layers is difficult because the metal form does not
allow conformability to the surface. The plasma spray approach,
preferably using RF techniques, allows the ability via the spraying
process to vary thickness selectively of each layer based on the
positioning in the plasma spray. This coating approach, by
increasing shielding in one area and reducing it in other areas,
changes the way shields can be designed and manufactured. The
hybrid nature of high Z metal with carbon fiber laminates offer a
game changing opportunity to increase radiation shielding
performance, instrument capability, and mission assurance for Space
Science and Exploration missions. Radiation is the highest risk to
mission assurance for long duration interplanetary and some of
planetary missions for spacecraft and instruments. The use of
structurally efficient radiation shielding reduces this risk.
[0014] Whether metal is affixed to a substrate using plasma
spraying or by electro/electroless plating, the subsequent metal
surface may be optionally polished, finished, sanded, or otherwise
treated to obtain desired thickness, uniformity, and smoothness.
One desirable feature of plasma spraying involves the porous, or
semi-permeable nature, of the resulting material which
synergistically allows infusion of polymer through laminating
processes as known to those of skill in the art.
[0015] Plasma spraying and/or electro/electroless plating of metal
layers also provides the advantage of allowing the ability to
pattern or vary the thickness of different Z-graded layers, as
opposed to Z-grade sheets of metal which typically only come in
fixed thicknesses and uniform size. Such pattern printing may be
done through physical masking during the spray process, or by post
processing treatments, such as, e.g. etching, scoring, or cracking
the material. In some instances, it may be beneficial to embed
functional patterns such as for thermal heat pipes,
radiative/conductive/and/or convective cooling piping, channels or
other integrated functionality, such as would permit piping or
channels to be embedded in the shielding to allow circulation of
heating or cooling fluids or other thermal conductors as are known
to those of skill in the art. Also, with thermal protection in
mind, the shielding made by methods of the invention can also be
used as thermal shielding to avoid high temperature or low
temperature excursions with or without embedded radiator-like
cooling sub-piping or channels. For example, and without
limitation, it is believed that tantalum and/or rhenium would make
excellent thermal shielding material that would provide excellent
benefits when made by the Z-graded methods of the instant
invention.
[0016] Accordingly, in at least some embodiments, the instant
inventive methods include where the shielding cover and structure
is selected from the group consisting of slabs, vaults, spot
enclosures, thermal barriers, and PCI card chassis structures. In
some preferred embodiments, the plasma spraying step comprises
depositing metal by low-pressure radio frequency plasma spray
technique, such as disclosed and described in U.S. Pat. No.
7,851,062 and references cited therein. The substrate surface can
comprise metal, glass, or graphite fibers or their equivalents as
known to those skilled in the art. As mentioned above, the metals
can comprise a compound selected from the group consisting of
tantalum, copper, tungsten, titanium, aluminum, and alloys or
combinations thereof. The polymer or resin preferable comprises a
compound selected from the group consisting of epoxy, polyimide,
cyanoacrylate, and mixtures thereof. In some electronic shielding
applications, the polymer preferably comprises a conductive filler
to provide increased electro-magnetic-interference resistance. And
as also mentioned above, when a second metal is applied to the
shield, it may be applied over the first metal whereby one or the
other metal is used as a thermal heat pipe that can be integrated
into the shield without expensive post finishing, the use of extra
conductive epoxies to bond the insert, and/or other difficult and
expensive post-treatment steps necessary to prepare a thermal heat
pipe inside a Z-graded shield material.
[0017] Moreover, and without wishing to be bound by any one theory,
use, or application; it is believed that beneficial uses for
shielding made by methods of the invention include shields for
nuclear reactors or piping for radioactive fluids, protective
clothing for nuclear hazardous waste handlers or astronauts, and
spacecraft instrumentation or electronic enclosures. Shielding may
be applicable to electron or gamma ray applications. Spacecraft
applications range from primary shielding of electronics and
instrument sensors to secondary shielding applications for
instruments with specific additional radiation shielding
requirements. The radiation shielding of transients in CCD arrays
is a systemic challenge, where improved shielding methods have
significant payoff in camera resolution and contrast. The
combination of high and low Z materials can be used in layers to
take advantage of the different stopping powers of the materials to
increase shielding efficiency as a function of weight. Accordingly,
in some aspects of the invention at least, the technology is
flexible, moldable, and can be made for custom, hard-to-shield
locations; it has less weight than traditional radiation shielding
material; the shield can be integrated with resins to provide easy
adhesion and a conformal shape; and such flexible shielding
material can be of particular utility in end cap components.
[0018] The following examples further illustrate the invention but,
of course, should not be construed as in any way limiting its
scope.
Examples
[0019] Various samples were prepared in accord with the methods of
the invention.
[0020] The Ta Rf Plasma Spray foil was determined to be 16.02
g/cm3. The laminate thicknesses were approximated to be 10 mils
formed during the lamination process. The Ta/Cyanate composite film
thickness were Ta 14 mils/30 mils cyanate composite, Ta 15 mils/20
mils cyanate composite, 16 mils Ta/10 mils cyanate composite, also
10 mils Ta/70 mils cyanate composite. These ratios were compared
with aluminum, tantalum, Ta/Al, and cyanate composite. A cyanate
ester liquid resin, such as EX1510 by TenCate can be used to infuse
the layered materials per the VARTM process and cured as known to
the art, including such methods as described in U.S. Pat. Nos.
7,595,112 and 7,851,062, which are incorporated herein by reference
thereto.
[0021] The trend for the electron shielding effectiveness for the
samples were: Ta/Al, Ta, Ta/cyanate composite, Al, and cyanate
composite.
[0022] Aluminum performed best for proton shielding effectiveness:
aluminum, Ta/Al, cyanate composite, Ta, Ta/cyanate composites.
[0023] It was apparent the use of Ta with the cyanate composite
contributes to a large increase in mechanical properties as shown
in Table 1.
TABLE-US-00001 TABLE 1 Modulus and Strength Comparison. Material
Z-Number Density g/cm.sup.3 Modulus Strength Reference Tantalum 73
16.6 186 GPA 650 Mpa www.eaglealloys.com Aluminum 13 2.79 68.9 GPA
310 Mpa asm.matweb.com Cyanate M55J 6 160 324 GPA 650 Mpa Hexply
954-3
[0024] Table 2 shows that a 15 mil Ta/20 mil cyanate composite had
the highest stiffness of the shielding materials. The greater
amount of cyanate composite will increase stiffness, but reduce
electron radiation shielding. It was apparent there was a large
gain in thickness reduction and stiffness increase with a
Ta/cyanate composite.
TABLE-US-00002 TABLE 2 Stiffness Comparison of 0.686 g/cm.sup.2
materials Materials Thickness cm (mil) Stiffness Ta 0.630 (16) 117
MN/m Al 0.254 (100) 175 MN/m Cyanate Composite 0.429 (169) 1.39
GN/m Ta/Cyanate Composite (15/20) 110 + 164 = 274 MN/m
[0025] In another example, a Space 104 conduction cooled aluminum
stackable enclosure for space avionics based on the PCI-I 04 form
factor was used for a Z-shielding demonstration. Z-shielding was
affixed on to 100 mil Space 104 electronic aluminum endcaps by
using high density tantalum on the endcap top surface, and casting
low density engineering polymer coating underneath the endcap. This
high-Z, low-Z grading using the endcaps was modeled for radiation
performance and shows a reduction of radiation exposure to
approximately 5500 rad/day silicon (ref. 105 day Europa mission
fluence spectra).
[0026] It should be noted, that as far as Z-grading metal on other
metal materials, precautions may be required in some instances to
avoid melting too much or damaging the underlying metal or fabric
when adding a high melting metal on top of a lower melting metal
layer. Such precautions include monitoring or controlling
temperature, which may be done in preferred embodiments by using
cold-finger temperature controllers to remove excess heat as known
to those of skill in the art.
[0027] All references, including publications, patent applications,
and patents, cited herein are hereby incorporated by reference to
the same extent as if each reference were individually and
specifically indicated to be incorporated by reference and were set
forth in its entirety herein.
[0028] The use of the terms "a" and "an" and "the" and similar
referents in the context of describing the invention (especially in
the context of the following claims) are to be construed to cover
both the singular and the plural, unless otherwise indicated herein
or clearly contradicted by context. The terms "comprising,"
"having," "including," and "containing" are to be construed as
open-ended terms (i.e., meaning "including, but not limited to,")
unless otherwise noted. Recitation of ranges of values herein are
merely intended to serve as a shorthand method of referring
individually to each separate value falling within the range,
unless otherwise indicated herein, and each separate value is
incorporated into the specification as if it were individually
recited herein. All methods described herein can be performed in
any suitable order unless otherwise indicated herein or otherwise
clearly contradicted by context. The use of any and all examples,
or exemplary language (e.g., "such as") provided herein, is
intended merely to better illuminate the invention and does not
pose a limitation on the scope of the invention unless otherwise
claimed. No language in the specification should be construed as
indicating any non-claimed element as essential to the practice of
the invention.
[0029] Preferred embodiments of this invention are described
herein, including the best mode known to the inventors for carrying
out the invention. Variations of those preferred embodiments may
become apparent to those of ordinary skill in the art upon reading
the foregoing description. The inventors expect skilled artisans to
employ such variations as appropriate, and the inventors intend for
the invention to be practiced otherwise than as specifically
described herein. Accordingly, this invention includes all
modifications and equivalents of the subject matter recited in the
claims appended hereto as permitted by applicable law. Moreover,
any combination of the above-described elements in all possible
variations thereof is encompassed by the invention unless otherwise
indicated herein or otherwise clearly contradicted by context.
* * * * *
References