U.S. patent application number 17/381472 was filed with the patent office on 2021-11-11 for apparatus and methods for modifying keratinous surfaces.
The applicant listed for this patent is The Procter & Gamble Company. Invention is credited to Thomas Elliot Rabe, Faiz Feisal Sherman.
Application Number | 20210345757 17/381472 |
Document ID | / |
Family ID | 1000005728469 |
Filed Date | 2021-11-11 |
United States Patent
Application |
20210345757 |
Kind Code |
A1 |
Rabe; Thomas Elliot ; et
al. |
November 11, 2021 |
APPARATUS AND METHODS FOR MODIFYING KERATINOUS SURFACES
Abstract
A device for analyzing and treating tonal imperfections on human
skin. The device, or apparatus has an applicator comprising a head
and one or more nozzles, preferably the nozzles are arranged in an
array. The apparatus further has a reservoir comprising a skin
treatment composition, a sensor, and a CPU. The sensor takes an
image of at least 10 .mu.m.sup.2 of skin. The CPU analyzes the
image to calculate a localized L value of individual pixels or
group of pixels. The CPU then compares the local L value to a
background L value to identify one or more skin deviations, and
wherein the sensor is in wireless communication with the CPU, and
wherein the CPU is adjacent the sensor or is remotely located.
Further, the sensor may be enclosed within an apparatus handle and
the CPU is either within the handle or external to the handle. In
another embodiment of this invention, there are two or more CPUs
and the sensor can be in wireless communication with none, one or
more than one CPU.
Inventors: |
Rabe; Thomas Elliot;
(Baltimore, MD) ; Sherman; Faiz Feisal; (Mason,
OH) |
|
Applicant: |
Name |
City |
State |
Country |
Type |
The Procter & Gamble Company |
Cincinnati |
OH |
US |
|
|
Family ID: |
1000005728469 |
Appl. No.: |
17/381472 |
Filed: |
July 21, 2021 |
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Application
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14858357 |
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11116302 |
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17381472 |
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14736507 |
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9925362 |
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14736524 |
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14736534 |
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14736551 |
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Current U.S.
Class: |
1/1 |
Current CPC
Class: |
G06T 2207/10016
20130101; A45D 2034/005 20130101; A61K 8/8182 20130101; A61B 5/7485
20130101; A61K 8/345 20130101; G06T 7/90 20170101; A61K 8/731
20130101; A61Q 19/00 20130101; G06T 7/0012 20130101; A61B 2560/0431
20130101; A61B 5/0075 20130101; A45D 40/26 20130101; A61K 8/29
20130101; A61B 2560/0443 20130101; A61B 5/0077 20130101; G06T
2207/30088 20130101; A45D 44/005 20130101; A45D 2044/007 20130101;
A61K 8/342 20130101; G06T 2207/30201 20130101; A61K 2800/87
20130101; A45D 2200/057 20130101; A61M 35/003 20130101; A45D 34/04
20130101; A61K 8/19 20130101; A61B 5/441 20130101; A61K 8/73
20130101; A61K 8/26 20130101 |
International
Class: |
A45D 40/26 20060101
A45D040/26; A45D 44/00 20060101 A45D044/00; A61M 35/00 20060101
A61M035/00; G06T 7/00 20060101 G06T007/00; A61K 8/26 20060101
A61K008/26; A61K 8/34 20060101 A61K008/34; A61K 8/19 20060101
A61K008/19; A61K 8/29 20060101 A61K008/29; A61K 8/81 20060101
A61K008/81; A61K 8/73 20060101 A61K008/73; A61Q 19/00 20060101
A61Q019/00; A61B 5/00 20060101 A61B005/00; G06T 7/90 20060101
G06T007/90; A45D 34/04 20060101 A45D034/04 |
Claims
1. An apparatus for treating human skin comprising: a. an
applicator comprising a head and one or more nozzles; b. a
reservoir comprising a skin treatment composition that comprises
from about 0.01% to about 25% by weight of the composition of a
skin care active; c. a sensor; d. a CPU; wherein the sensor takes
the image of at least 10 .mu.m.sup.2 of skin; the CPU analyzes the
image to identify one or more skin deviations.
2. The apparatus of claim 1, wherein the skin care active is an
anti-acne active.
3. The apparatus of claim 1, wherein the skin care active is an oil
control agent.
4. The apparatus of claim 1, wherein the skin care active is
selected from the group consisting of salicylic acid, dehydroacetic
acid, benzoyl peroxide, vitamin B3 compounds, isomers, esters,
derivatives, or salts thereof, and mixtures thereof.
5. The apparatus of claim 4, wherein the skin care active is
selected from the group consisting of salicylic acid, benzoyl
peroxide, and mixtures thereof.
6. The apparatus of claim 1, wherein the skin care active is a
vitamin selected from the group consisting of vitamin A, vitamin
B3, vitamin B5, vitamin C, vitamin E, and mixtures thereof.
7. The apparatus of claim 6, wherein the vitamin is a vitamin B3
compound selected from the group consisting of niacinamide,
niacinnicotinic acid, tocopheryl nicotinate, and mixtures
thereof.
8. The apparatus of claim 7, wherein the vitamin B3 compound is
niacinamide.
9. The apparatus of claim 1, wherein the skin treatment composition
further comprises from about 50% to about 99.99% of a
dermatologically-acceptable carrier.
10. The apparatus of claim 9, wherein the
dermatologically-acceptable carrier is selected from the group
consisting of water, a polyhydric alcohol, and mixtures
thereof.
11. The apparatus of claim 10, wherein the
dermatologically-acceptable carrier is a mixture of water and
polyethylene glycol.
12. The apparatus of claim 1, wherein the skin treatment
composition further comprises an anti-fungal component, an
anti-bacterial component, or mixtures thereof.
13. The apparatus of claim 1, wherein the skin treatment
composition further comprises hexanediol, caprylyl glycol, or
mixtures thereof.
14. The apparatus of claim 1, wherein the apparatus further
comprises a handle that contains the sensor, the applicator, the
reservoir, and CPU.
15. The apparatus of claim 1, wherein the sensor is a camera
capable of taking continuous images at a rate of at least 4 frames
per second.
16. The apparatus of claim 1, wherein the applicator is a thermal
inkjet or piezoelectric printer and cartridge assembly, wherein the
cartridge assembly comprises a foam core, solid wax, bladder core,
a membrane and combinations of these.
17. The apparatus of claim 1, wherein the applicator further
comprises one or more of an illumination source, a memory unit, an
energy source, and an applicator tip.
18. The apparatus of claim 1, wherein the applicator comprises a
thermal inkjet printer cartridge.
19. The apparatus of claim 1, wherein the treatment composition is
applied to the skin deviation after the skin deviation is
identified.
20. The apparatus of claim 19, wherein the skin deviation is acne.
Description
FIELD OF THE INVENTION
[0001] This invention relates to an apparatus and methods for
applying compositions to skin, and other keratinous surfaces. The
compositions can modify color or structure of the keratinous
surface. The apparatus has wireless communication capabilities
within itself or with other apparatuses, such as a personal
computer, a cell phone a tablet computing device and the like.
BACKGROUND OF THE INVENTION
[0002] Tonal variations on human skin have multiple causes. Acne,
freckles, sun damage, and age spots are just a few of the common
causes of visible defects on skin. Textural variations such as fine
lines, wrinkles and scars are also well known. Both tonal and
textural deviations are noticeable and are highly noticeable to the
human eye, even when they are quite small. Covering large areas of
skin on and around deviations with makeup or other concealers is
known.
[0003] Moreover, attempts have been made at more precise, and
localized application of compositions that hide, or cover-up skin
deviations. Handheld devices that are moved across the skin have
been developed to apply skin treatment compositions to local
defects. But these devices have been plagued by the absence of two
necessary components, speed and accuracy. For these handheld
devices to work effectively, they must find the defects quickly,
and treat them immediately. Finding a spot on the skin is of little
use if the user has moved the applicator head to a different area
of the skin before the spot can be effectively treated.
[0004] Further, known beauty care devices lack certain technical
features that are available on common consumer devices like cell
phones, computers and tablet devices. Communication between a cell
phone and other computing devices, such as a tablet, are common and
can be done wirelessly. This wireless communication capability
allows for many advantages, such as data storage, data retrieval,
the transfer and use of applications or "apps", and the use of one
device for consumer input and feedback intended for the other
device. Thus, communication between multiple devices, without
cumbersome cords, is a highly desirable goal that provides many
advantages to the end consumer.
[0005] Therefore, there exists a need for methods and apparatuses
that can quickly and precisely detect tonal and textural defects on
skin. Then with equal speed and precision, apply treatment
compositions directly to the deviations. And it is desired to have
an apparatus that can communicate wirelessly with a multitude of
other electronic devices. These methods and apparatuses are defined
by the present invention.
SUMMARY OF THE INVENTION
[0006] The present invention relates to a device for analyzing and
treating tonal imperfections on human skin. The device or apparatus
has an applicator comprising a head and one or more nozzles,
preferably the nozzles are arranged in an array. The apparatus
further has a reservoir comprising a skin treatment composition, a
sensor, and a CPU. The sensor takes an image of at least 10
.mu.m.sup.2 of skin. The CPU analyzes the image to calculate a
localized L value of individual pixels or group of pixels. The CPU
then compares the local L value to a background L value to identify
one or more skin deviations, and wherein the sensor is in wireless
communication with the CPU, and wherein the CPU is adjacent the
sensor or is remotely located. Further, the sensor may be enclosed
within an apparatus handle and the CPU is either within the handle
or external to the handle.
[0007] In another embodiment of this invention, there are two or
more CPUs and the sensor can be in wireless communication with
none, one or more than one CPU. For example, the sensor can be hard
wired to a CPU the apparatus handle and the CPU in the handle
communicates wirelessly with one or more external CPUs.
Commercially available computers, tablets and cell phones have both
wired, and wireless communication capabilities today. They can use
them individually or simultaneously. It is envisioned that the
individual components of the present devices (and hence, the
devices themselves) will have wireless communication capabilities
alone or in conjunction with wired communication.
[0008] The present invention solves many problems with prior
devices and methods. Specifically, tonal variations on skin are
more accurately and quickly detected. The speed with which a skin
deviation is found and identified is critical because the
applicator is continuously moving across the skin. The quicker the
deviation is identified, the quicker the applicator nozzle, or
nozzles can be activated. The quicker the nozzles are activated the
more likely the skin treatment composition will hit the deviation
precisely. This allows for the optimal coverage of the deviation,
and minimal coverage on the areas of natural skin that do not need
treatment. Wireless communication between the individual components
of the device, and the present device with existing computing
devices, allows for a multitude of improvements, and consumer
benefits. Computing speed, consumer interfaces, consumer feedback,
are just a few of the advantages that an existing device might
provide to the current device via wireless communication. This is a
substantial improvement over more complicated, slower and less
precise apparatuses and methods of the past.
BRIEF DESCRIPTION OF THE DRAWINGS
[0009] While the specification concludes with claims particularly
pointing out and distinctly claiming the present invention, it is
believed the same will be better understood from the following
description taken in conjunction with the accompanying drawing in
which:
[0010] FIG. 1 is a schematic representation of an analytical window
according to the present invention wherein skin is analyzed
according to the methods of the present invention;
[0011] FIG. 2 is a hand held apparatus according to the present
invention;
[0012] FIG. 3 is an ink jet cartridge according to the present
invention;
[0013] FIG. 4 is the natural, uncovered skin of a female
consumer;
[0014] FIG. 5 is the same female consumer in FIG. 4 with applied
makeup; and,
[0015] FIG. 6 is the same female consumer as shown in FIG. 4, with
no makeup on, after being treated by the methods and apparatuses of
the present invention.
DETAILED DESCRIPTION OF THE INVENTION
[0016] The present invention may be understood more readily by
reference to the following detailed description of illustrative and
preferred embodiments. It is to be understood that the scope of the
claims is not limited to the specific compositions, methods,
conditions, devices, or parameters described herein, and that the
terminology used herein is not intended to be limiting of the
claimed invention. Also, as used in the specification, including
the appended claims, the singular forms "a," "an," and "the"
include the plural, and reference to a particular numerical value
includes at least that particular value, unless the context clearly
dictates otherwise. When a range of values is expressed, another
embodiment includes from the one particular value and/or to the
other particular value. Similarly, when values are expressed as
approximations, by use of the antecedent basis "about," it will be
understood that the particular values form another embodiment. All
ranges are inclusive and combinable.
[0017] Wireless communications between devices and between
components within devices are known to those skilled in the art.
The terms "wireless" and "wireless communications" shall mean the
communication between components or devices that are accomplished
by any of a variety of means including, Wireless Local Area
Networks (WLAN) and Wireless Personal Area Networks (WPAN). WLAN
networks use the IEEE 802.11 standards, typically known as WIFI,
which is intended to replace high speed cabling with wireless
communications. WPAN networks use the Bluetooth Special Interest
Group standards, which are intended for wireless communication
between portable equipment or fixed equipment (for example a home
thermostat) and its applications. Near Field Communication (NFC)
technology is another suitable wireless communication tool using
standards from, for example, the NFC Forum. The apparatuses and
methods of the present invention may also use wireless Radio
Frequency Identification communication technology (RFID), with
standards from a number of regulatory bodies, including
International Organization for Standards (ISO), International
Electrotechnical Commission (IEC), ASTM International, DASH7
Alliance and EPC Global. WPAN is also known as LAN (Local Area
Networks) or WLAN (Wireless Local Area Networks), which is a
wireless computer network that links two or more devices using a
wireless distribution method within a limited area such as a home,
school, office space, and the like. A piconet is a computer network
which links a wireless user group of devices using Bluetooth
technology protocols. For example, a piconet could include an
apparatus according to the present invention connected to a smart
phone or a cell phone connected to a computer, a laptop and a
Bluetooth-enabled sensor, for example, a digital camera.
[0018] The term "frexel" is defined as a small pixel-like region of
the keratinous surface. A frexel might correspond to a small
portion of a freckle or other skin feature, or it may correspond to
an area of the keratinous surface that does not have special
features. The term frexel is used to suggest that what is being
measured is on a 3-D surface rather than a flat surface. A region
of keratinous surface is comprised of a plurality of frexels. For
instance, if a resolution of 300 dots per inch (11.8 dots per mm or
"dpmm") is used, a frexel may have a width and height of about
1/300th of an inch (0.085 mm) so that there are approximately
90,000 frexels per square inch (about 140 frexels per square mm).
The surface of the human body may have millions of frexels.
[0019] All percentages and ratios used herein are by weight of the
total composition, and all measurements made are at 25.degree. C.,
unless otherwise designated.
[0020] The methods, apparatuses, and compositions of the present
invention are best understood with reference to the method of use.
Each of the process steps, the apparatuses and the compositions
used in that step are described in turn below. The terms "device"
and "apparatus" are used interchangeably throughout this
specification.
[0021] To better understand how the apparatuses of the present
invention work, and why they are so beneficial to the consumer, it
is best to understand first what the device does. The present
methods, in their simplest form, are directed to analyzing and
treating tonal imperfections on human skin that comprises the steps
of taking at least one background image of at least 10 .mu.m.sup.2
of skin and then calculating the average background L value of the
image on a grey scale. Further, from the same image, a localized L
value is calculated for individual pixels or a group of pixels. The
local L value is then compared to the background L value to
identify skin deviations. A skin deviation is an area of skin where
the absolute value of the difference between a local L value and
the background L, (this difference being defined as
".DELTA.L.sub.M" or the measured .DELTA.L, ".DELTA." is commonly
defined as the symbol for a difference between two values) is
greater than a predetermined .DELTA.L.sub.S. The background L can
be preset, or calculated by a variety of methods described below.
The skin deviations are then treated with a treatment composition
having a predetermined or variable contrast ratio.
[0022] The background L can be calculated anywhere within the
image. The image is taken where the nozzles will fire the treatment
composition. The background L can be the arithmetic average,
median, or mean of a plurality of local Ls, which means the
calculation can include all of the local Ls in the image, or a
subset thereof.
[0023] Likewise, there are provided apparatuses for treating human
skin. The apparatus has an applicator head that includes multiple
applicator nozzles and a reservoir for containing a treatment
composition, which can be a skin treatment composition. There is
further provided a sensor and a CPU. The sensor takes an image of
at least 10 .mu.m.sup.2 of skin and the CPU analyzes the image to
calculate the average background L value. The sensor output is also
used to calculate the localized L value of individual pixels or
groups of pixels of skin. The CPU then compares the local L value
to the background L value to identify skin deviations where the
difference between the two L values is greater than a predetermined
value.
[0024] Exemplary treatment compositions for use with the present
system include cosmetics, polymerics, aqueous, non-aqueous,
particle loaded, optical modifier, fillers, optical matchers, skin
actives, nail actives, hair actives, oral care actives,
anti-inflammatory, antibacterial, surfactant or surfactant
containing active, quantum dots and combinations thereof. Exemplary
surfaces and substrates for the application of the treatment
composition by the present deposition system include keratinous
surfaces, woven surfaces, non-woven surfaces, porous surfaces,
non-porous surfaces, wood, teeth, tongue, metallic, tile, fabric,
and combinations thereof.
[0025] The central processing unit ("CPU") of the device can be any
of a variety of commercially available devices. In its simplest
form, the CPU is a single programmable chip like those found in
consumer electronic devices such as a lap top computer, a cell
phone, an electric razor and the like. Those skilled in the art
will know of a variety of commercially available chips and other
processors suitable for use with this invention. CPU may include
Application Specific Integrated Circuit (ASIC), controller, Field
Programmable Gate Array (FPGA), integrated circuit,
microcontroller, microprocessor, processor, and the like. The CPU
may also include memory functionality, either internal to the CPU
as cache memory, for example Random Access Memory (RAM), Static
Random Access Memory (SRAM) and the like or external to the CPU for
example as Dynamic Random-Access Memory (DRAM), Read Only Memory
(ROM), Static RAM, Flash Memory (e.g., Compact Flash or SmartMedia
cards), disk drives, Solid State Disk Drives (SSD) or even Internet
Cloud storage. While it is anticipated that a remote CPU, either
tethered to the device, or which communicates wirelessly, can be
used to accomplish the methods of the present invention, a local
CPU within the device is exemplified herein. Size and speed of the
CPU is an important consideration of the design parameters, but
cost and other considerations will be considered by the device
designers.
[0026] The predetermined .DELTA.L.sub.S is the absolute value of
the difference between the local L and the background L. This
value, .DELTA.L.sub.S, can be defined in absolute numbers or as a
percentage. The sensor is for example a camera that takes black and
white or color images, a spectrophotometer or similar devices that
are sensitive to electromagnetic wavelengths. The images are taken,
or converted to a standard grey scale that is known to the art. It
is understood that any numerical scale that measures lightness to
darkness can be considered a "grey scale". Moreover, as used
herein, "grey scale" is intended to be a linear scale, or one band,
or one visual attribute. For example, one "grey scale" visual
attribute could be single wavelength or a narrow wavelength to
define a specific visual color. Another example of one "grey scale"
visual attribute could be a mix of wavelength numerical values
averaged for each pixel making up the image, such as a true black,
grey or white image from an RGB mixture.
[0027] It will also be understood to those skilled in the art that
the background L value should not be too close to the ends of this
scale. For example, if the grey scale is 0-100, with 0 being pure
black and 100 being pure white, a background in the 0-10 range, or
in the 90-100 range may be too light or too dark to show meaningful
differences. Accordingly, one can adjust the background lighting,
or the gain on the camera taking the image, to move the background
L closer to the middle of the scale. In this example, a background
L of 50 would be ideal, with a background L in the range of 10-90
preferred, 20-80 even more preferred.
[0028] The most common grey scale is 0-255 (no units) other
examples include 0-1024 and 0-4096. In this example it would be
desirable to use camera and lighting settings that provide a
background L value between 60 and 210. Using the 0-255 gray scale
the .DELTA.L.sub.S is preferably at least 0.5, more preferably at
least 1 and even more preferably at least 1.5, to initiate
treatment of the skin. Likewise, .DELTA.L.sub.S can be measured as
a percentage, for example, a numerical .DELTA.L.sub.S of 2.6 is
approximately equal to 1.0% of a 255 grey scale. Thus
.DELTA.L.sub.S may be plus or minus 0.25%, preferably plus or minus
0.5% even more preferably plus or minus 0.75%, of the
grayscale.
[0029] The skin treatment compositions used to hide, or more
appropriately, to camouflage a skin deviation are described and
exemplified in greater detail below. One important characteristic
of the skin treatment compositions of the present invention is the
contrast ratio. The contrast ratio of the treatment composition
when treating the skin is at least 0.1. The skin lightness and
treatment composition lightness can be measured by a calibrated
spectrophotometer using known methods. In the case of using a
calibrated spectrophotometer, the average L value of human skin
usually spans the range of about 25 to 75. In this case the
corresponding treatment composition has a lightness value of at
least 2 units greater, preferably at least 3 units greater, and
even more preferably at least 5 units greater than the average skin
lightness value of the consumer.
[0030] Images are taken in sequence or preferably continuously. A
camera that takes a minimum of 4 frames per second is preferred.
Higher speed cameras (greater than 4 frames per second) are desired
as well, for example greater than 200 frames per second. All images
are either taken in a grey scale or converted to a grey scale, the
grey scale can have any range, for example, 0-255, no units. This
corresponds approximately to a refresh rate of 0.2 seconds or
faster.
[0031] There is no technical difference between an image used for
background L values and those used for local L values, the
difference is in the analysis of the image. Hence, the images are
continually sent to the CPU, that is, the processing unit, to
calculate the L values, and .DELTA.L.sub.M values. By "sent" it is
understood, that preferably at least 4 bits of data per pixel are
transferred for each image, and preferably, this 4 bit (or more)
packet of data is used in the calculation of each local L value. It
is understood, that the background L can be calculated once in a
treatment period and that value reused throughout the treatment
period. Or it can be continually recalculated as long as the
treatment process goes on. Moreover, there can be pre-programmed
triggers to initiate a recalculation of the background L. Also, the
background L may be retrieved from the CPU memory to be used for
the current background L. For example, if an extended period of
time elapses and no skin deviations are found, or if skin
deviations are being found too frequently, a new background L might
automatically be calculated. Likewise, .DELTA.L.sub.S can be a set
value that remains constant throughout the treatment cycle or it
too can vary. .DELTA.L.sub.S can be reset during the treatment
cycle for any of a variety of reasons. If too many nozzles are
firing too frequently, the .DELTA.L.sub.S can be adjusted to lower
the intensity of the nozzle firing. Similarly, if the nozzles are
firing too infrequently, .DELTA.L.sub.S can be adjusted in the
opposite direction to increase the sensitivity of skin deviation
detection. Those skilled in the art will appreciate that modifying
.DELTA.L.sub.S during treatment is a matter of programming the CPU
to a desired algorithm.
[0032] When the .DELTA.L.sub.M exceeds the predetermined value, the
skin deviation is treated with the treatment composition. Treatment
requires firing one or more of the nozzles which dispense the
treatment composition onto the skin in the area of the skin
deviation. Preferably the treatment composition is applied to the
skin deviations in a discontinuous deposition pattern of discrete
droplets between about 100 .mu.m to about 100 .mu.m in size. It is
also preferred that no more than 85% of the skin deviation is
covered by the treatment composition. More specifically, the
treatment composition is applied via a array of nozzles and the
local L is calculated along the length of, and in the firing range
of, the array of nozzles. The "array" can be a linear
configuration, multiple rows, off-set, sine wave, curved, circular,
or saw tooth arrangements of nozzles. Those skilled in the printing
arts will appreciate the various configurations of nozzle arrays
that are possible for use in the methods and apparatuses disclosed
herein. The "firing range" of a nozzle will vary based on its size,
type, the speed the device is moving, distance from the target, and
other parameters. Examples of various types of nozzles suitable for
use in the present devices are given below. But in general, "near
the nozzle" as used herein is meant to mean the image taken to
calculate a local L value is close to the area of skin where the
treatment composition is deposited by the nozzle (the firing range,
or landing zone of the nozzle). Without intending to limit the
invention, near the nozzle means the image should be taken within a
radius of about 2 cm, preferably about 1 cm and even more
preferably, about 0.7 cm from the center of the nozzle.
[0033] An individual nozzle may be fired to deposit the treatment
composition, or multiple nozzles fired at the same time. The number
of nozzles fired along the linear array of nozzles can be adjusted
based on the size of the .DELTA.L.sub.M and the size of the skin
deviation. Furthermore the frequency of nozzle firing can be
adjusted based on the .DELTA.L.sub.M, with more droplets being
fired in succession in response to larger .DELTA.L.sub.M
values.
[0034] Firing intensity curves can be programmed into the CPU to
adjust the firing rate of nozzles. For example, if .DELTA.L.sub.M
is equal to or slightly greater than .DELTA.L.sub.S, then the
adjacent nozzle is fired 1 time. If .DELTA.L.sub.M increases to
2*.DELTA.L.sub.S, then the adjacent nozzle is fired 25 times. If
the .DELTA.L.sub.M is 3*.DELTA.L.sub.S, then the adjacent nozzle is
fired 100 times. This non-limiting example is intended to show how
the size of the .DELTA.L.sub.M with respect to the .DELTA.L.sub.S
can determine the amount, and hence, the intensity of the firing of
the nozzles adjacent the skin deviation. Those skilled in the art
will appreciate that plotting a firing intensity curve using 2, 3
or more data points, and then programming that firing intensity
curve into the CPU are known techniques.
[0035] The methods and apparatuses used by the present invention
can be briefly summarized as follows. Referring now to FIG. 1,
where analytical window 10 is an area that comprises a sample of
skin 12 and nozzle array 20. Nozzle array 20 contains individual
nozzles that are off or not firing 24, and individual nozzles that
are firing 22. Skin deviations 30 and 31 are shown underneath
nozzle array sections 32 and 33. Background L is calculated on and
around skin area 12, skin area 14 is where local L.sub.1 is
measured and skin area 16 is where local L.sub.2 is measured. Skin
area 14 is under nozzle array 20 but not within a skin deviation.
Thus, the absolute value of local L.sub.1--background L
(.DELTA.L.sub.1M) is less than the preset threshold to initiate
nozzle firing. The .DELTA.L.sub.S threshold required to initiate
nozzle firing is a variable and is dependent on the scale used. For
example, in a case where the 0-255 gray scale is utilized then the
.DELTA.L.sub.S threshold required to initiate nozzle firing would
commonly be a value of 2 or greater. Thus in the example shown in
FIG. 1 the value of .DELTA.L.sub.1M is less than 2. Likewise, skin
area 16 is within skin deviation 30, and the absolute value of
local L.sub.2--background L (.DELTA.L.sub.2M) is greater than about
2. Thus the nozzles around skin areas 24 and 14 are generally off,
and the nozzles around skin area 16 are generally firing. To insure
the nozzles do not clog with particles or dried treatment
composition, any nozzle can be fired at any time simply to keep it
clean and "healthy". And as discussed above, the number of nozzles
directly over a skin deviation that are fired in response to the
skin deviation can be adjusted based on the size of .DELTA.L.sub.S,
the size (e.g., surface area) of the skin deviation or other
parameters devised by those skilled in the art.
[0036] Treatment times will vary based on the size of the treatment
area and the precision and amount of the treatment. For example, a
woman may wish to simply touch up a few small areas on her face
before going to grocery store. This treatment might take a few
minutes. Alternatively, a young bride might wear her wedding dress
to a salon where a salon professional meticulously treats all
exposed areas of skin prior to the wedding and the taking of her
wedding pictures. This full body treatment might take hours.
Accordingly, the consumer will have tremendous control over the
amount of time they choose to use the present device.
[0037] Referring now to FIG. 2, which shows a handheld apparatus 40
according to the present invention. The term "line" as used herein
means a line, or method of communication between two elements. This
line of communication, for example, image capture line 48, can be a
physical connection such as a hard wire or it can be a wireless
communication as described herein.
[0038] Apparatus 40 is directly above skin 18, separated by
physical spacer 42. Physical spacer 42 has a set, predetermined
height a such that when it contacts skin 18, the mechanical and
electrical elements above the skin are all at a known distance from
the skin. The mechanical and electrical elements are associated
with apparatus 40 and include, but may not be limited to, light 44,
image capture device 46, nozzle array 20 which is embedded on
cartridge die 54 which is attached to printer cartridge 52. All of
these elements are enclosed within optional apparatus housing 41.
Light 44 illuminates the area skin 18 within spacer 42 such that
the image capture device 46 has relatively constant illumination.
Background lighting will affect the image capture as portions of
spacer 42 lift off of skin 18 and allow background light in and the
illumination from light 44 to escape, but small deviations in
illumination can be corrected for provided light 44 provides a
relatively constant background illumination. Light 44 can be a
light emitting diode (LED), incandescent light, neon based or any
other commercially available source of illumination. Light 44 can
have constant illumination or adjustable illumination. For example,
an adjustable light source might be useful if the background
illumination is excessively bright or dark.
[0039] Image capture device 46 can be any of a variety of
commercially available devices such as a simple camera or a digital
cmos camera chip. Image capture device 46 takes a picture of skin
18 and sends it to processor 50 via image capture line 48 for
analysis. Processor 50 is generally referred to as a central
processing unit, or CPU, which may comprise a simple circuit board,
a more complex computer, or the like and may include memory
functionality. Those skilled in the art will appreciate that a CPU
can be any of wide variety of commercially available programmable
devices. As described above, the image may be analyzed for local L
values, background L values or both. Grey scale conversion occurs
within the analytical processing capabilities of processor 50. The
comparison of background L to local L to determine the
.DELTA.L.sub.M occurs within processor 50, which can be a
commercially available programmable chip, or other commercially
available processing units.
[0040] Further provided is optional external CPU 43. External CPU
43 may be in communication with any or all of the electronic
components of the apparatus described herein. By way of example,
external CPU 43 can communicate with CPU processor 50 via external
CPU communication line 45 and communicate with sensor 20 via sensor
external communication line 47. Lines 47 and 45 can be physical
communication lines or, more preferably, they are wireless
communication lines.
[0041] The results of the image analysis, when compared to criteria
pre-programmed into the processor, may result in a desired
treatment of the skin. In such a case, for example when the
calculate .DELTA.L.sub.M exceeds the pre-determined .DELTA.L.sub.S,
a signal is sent from processor 50 to cartridge 52, via cartridge
line 51, to fire one or more of the nozzles in nozzle array 20.
Power for cartridge 52, light 44, image capture device 46,
processor 50, and other mechanical and electrical elements that
might be present is supplied by power element 54 via multiple power
lines 55. Power element 54 can be turned off and on, which in turn
turns apparatus 40 off and on, via power switch 56 which can be
located anywhere on apparatus 40, but is shown here on apparatus
cover 58. Power element 54 may include energy storage functionality
via a rechargeable battery, a double-layer capacitor, a
supercapacitor or a hybrid battery-capacitor system.
[0042] No Foam
[0043] Turning now to FIG. 3 which is an exploded view of the
cartridge 52 comprising cartridge cap 62 and cartridge body 64.
Body 64 includes standpipe 66 which is typically enclosed within
body 66 and defines nozzle outlet 68. Optional filter 70 helps keep
excessively large particles, and other debris out of the nozzle
array 76. Filter 70 and nozzle array 76 are on opposite sides of
nozzle outlet 68. Treatment composition 74 partially fills
cartridge body 64. Foam core 72 fills cartridge 64 and helps to
regulate back pressure of the treatment composition 74. While a
foam core cartridge is used to describe and exemplify Back pressure
can be regulated via bladders (not shown) and other methods known
to the art, the foam core shown here is just one example of how to
help regulate flow of the treatment composition 74 to standpipe 66
through filter 70 and into nozzle array 76. Connector 78 provides
the electrical power and signal to nozzle array 76. Connector 76
may be in wireless communication with the CPU processor 50,
external CPU 43, sensor 20 or any other electronic component of
apparatus 40 and external apparatus associated therewith.
[0044] Treatment composition 74 within cartridge body 64 may
comprise particles and the treatment compositions preferably have a
particle settling rate of less than 0.06 mm per day at 25.degree.
C. and 1 atm pressure. The treatment composition may further have
an elastic modulus between about 0.1 Pa to about 1000 Pa at 25 C
and 1000 Hz. Preferably, the particles in the treatment composition
have a refractive index of between about 1.1 and about 5.0.
[0045] While inkjet cartridges are shown and exemplified herein,
treatment compositions may be applied with other "flow control"
devices or non-drop control devices. Flow control devices typically
are characterized as "drop control techniques" where individual
droplets of the substance are controlled. Ink jet printers, which
are known to the art, are examples of drop on demand applicators
and this technology is applicable for use in the present invention.
Piezo electric drop control devices and other micro
electromechanical systems are appropriate for use with the current
devices. Spray devices and electrostatic spray devices are non-drop
control techniques where droplets are produced and controlled only
in aggregate. Often in a spray device, a lack of individual droplet
control, or "randomness" is desired in order to produce a smooth
application over a relatively large area. By contrast, it is often
desirable to provide very specific control of the amount and
placement of the treatment compositions.
[0046] Examples of drop control include "fine flow control" where
the flow of the substance is precisely controlled to deliver
droplets as desired; and "inkjet technologies." An older inkjet
technology includes supplying a continuous flow of charged droplets
past electrostatic deflector plates which are alternately charged
so that the plates either permit a droplet to pass or deflect to a
gutter. This technique was the original design basis for inkjet
printers. Other inkjet technologies include "drop on demand" such
as thermal devices provided by Hewlett Packard, and piezoelectric
devices such as provided by Epson and other printer manufacturers.
In one embodiment of the current invention, the drop on demand
technology is combined with charging the droplets.
[0047] Equipment that might be useful in constructing an apparatus
of the present invention are described in the following published
patent applications: WO 2008/098234 A2, Handheld Apparatus and
Method for the Automated Application of Cosmetics and Other
Surfaces, first filed 11 Feb. 2007; WO 2008/100878 A1, System and
Method for Applying a Treatment composition to Change a Person's
Appearance Based on a Digital Image, first filed 12 Feb. 2007; WO
2008/098235 A2, System and Method for Providing Simulated Images
Through Cosmetic Monitoring, first filed 11 Feb. 2007; WO
2008/100880 A1, System and Method for Applying Agent
Electrostatically to Human Skin, first filed 12 Feb. 2007; US
2007/0049832 A1, System and Method for Medical Monitoring and
Treatment Through Cosmetic Monitoring and Treatment, first filed 12
Aug. 2005; and US 2007/0035815 A1, System and Method for Applying a
Treatment composition to Improve the Visual Attractiveness of Human
Skin, first filed 12 Aug. 2005; All six applications filed by Edgar
et al. The entire disclosure of each of the six Edgar et al.
applications is incorporated herein by reference.
[0048] The apparatuses of the present invention are preferably
handheld but can be tethered to a structure that moves the
apparatus across the keratinous surface to be modified. If
handheld, the consumer would simply move the apparatus across the
keratinous surface to be treated. Optionally, multiple apparatuses
can be configured in a stationary structure wherein the consumer
places the keratinous surface to be modified and multiple readings
and applications occur simultaneously or in sequence.
[0049] The treatment composition can be applied to the keratinous
surface by scanning and applying at the same time while making
multiple passes over the surface. Several advantages result from
using multiple pass application. The process for multiple pass
applications is to make a partial application of the treatment
composition, then to scan again the area of skin that has received
the partial application. A further application of treatment
compositions can be made, and still further multiple pass scanning
and applications can be made to approach an aesthetic goal. Thus,
the consumer can select the end point of the treatment, i.e. the
"aesthetic goal", thus tailoring the treatment time to individual
needs and preferences. Attempting to make all corrections in one
treatment pass has been shown to overcorrect in certain areas.
[0050] It may be desirable for the apparatus to treat from about
1.0% to about 10% of the keratinous surface that is read by the
sensor with a treatment composition. And the applicator may apply
the first treatment composition in droplets having an average
diameter of from about from about 0 .mu.m to about 50 .mu.m.
Treatment Compositions
[0051] The present invention may utilize a variety of treatment
compositions, for example, inks, dyes, pigments, adhesives, curable
compositions, optically activated compounds (for example quantum
dots), metal oxides (for example, TiO2), bleaching agents, texture
reducing polymers, skin care compositions, hair colorants, hair
removal compositions (often referred to as depilatories), hair
growth stimulants and mixtures thereof.
[0052] The treatment compositions of this invention can be
delivered alone or in the presence of a dermatologically-acceptable
carrier. The phrase "dermatologically-acceptable carrier", as used
herein, means that the carrier is suitable for topical application
to the keratinous tissue, has good aesthetic properties, is
compatible with any additional components of the skin care
composition, and will not cause any untoward safety or toxicity
concerns. The carrier can be in a wide variety of forms.
Non-limiting examples include simple solutions (water or oil
based), emulsions, and solid forms (gels, sticks, flowable solids,
amorphous materials). In certain embodiments, the dermatologically
acceptable carrier is in the form of an emulsion. Emulsion may be
generally classified as having a continuous aqueous phase (e.g.,
oil-in-water and water-in-oil-in-water) or a continuous oil phase
(e.g., water-in-oil and oil-in-water-in-oil). The oil phase of the
present invention may comprise silicone oils, non-silicone oils
such as hydrocarbon oils, esters, ethers, and the like, and
mixtures thereof. For example, emulsion carriers can include, but
are not limited to, continuous water phase emulsions such as
silicone-in-water, oil-in-water, and water-in-oil-in-water
emulsion; and continuous oil phase emulsions such as water-in-oil
and water-in-silicone emulsions, and oil-in-water-in-silicone
emulsions. The treatment composition can be delivered in a variety
of product forms including, but not limited to, a cream, a lotion,
a gel, a foam, a paste, or a serum. Additionally, the treatment
composition can include for purposes of proper formulation and
stabilization anti-fungal and anti-bacterial components.
[0053] The treatment compositions of the present invention may
comprises humectants as a carrier or chassis for the other
components in the treatment composition. An exemplary class of
humectants is polyhydric alcohols. Suitable polyhydric alcohols
include polyalkylene glycols and alkylene polyols and their
derivatives, including propylene glycol, dipropylene glycol,
polypropylene glycol, polyethylene glycol and derivatives thereof;
sorbitol; hydroxypropyl sorbitol; erythritol; threitol;
pentaerythritol; xylitol; glucitol; mannitol; butylene glycol
(e.g., 1,3-butylene glycol); pentylene glycol; hexane triol (e.g.,
1,2,6-hexanetriol); glycerin; ethoxylated glycerine; and
propoxylated glycerine.
[0054] Other suitable humectants include sodium
2-pyrrolidone-5-carboxylate, guanidine; glycolic acid and glycolate
salts (e.g., ammonium and quaternary alkyl ammonium); lactic acid
and lactate salts (e.g., ammonium and quaternary alkyl ammonium);
aloe vera in any of its variety of forms (e.g., aloe vera gel);
hyaluronic acid and derivatives thereof (e.g., salt derivatives
such as sodium hyaluronate); lactamide monoethanolamine; acetamide
monoethanolamine; urea; sodium pyroglutamate, water-soluble
glyceryl poly(meth)acrylate lubricants (such as Hispagel.RTM.) and
mixtures thereof.
[0055] Inks, dyes, metal oxides and pigments (collectively referred
to as "colorants" below) are used to modify the color or
reflectance of the keratinous surface. These compositions are
commonly used to modify color and reflectance in cosmetic,
"make-up" compositions. Foundation, lipstick, eyeliner are just a
few examples of these compositions, but they are all applied evenly
across large portions of the keratinous surface, that is they are
macro-applications. In sharp contrast, the present treatment
compositions are selectively applied on a very small scale to
select areas, that is, a micro application. Suitable colorants may
include inorganic or organic pigments and powders. Organic pigments
can include natural colorants and synthetic monomeric and polymeric
colorants. Organic pigments include various aromatic types such as
azo, indigoid, triphenylmethane, anthraquinone, and xanthine dyes
which are designated as D&C and FD&C blues, browns, greens,
oranges, reds, yellows, etc. Organic pigments may consist of
insoluble metallic salts of certified color additives, referred to
as the Lakes. Inorganic pigments include iron oxides, ferric
ammonium ferrocyanide, manganese violet, ultramarines, chromium,
chromium hydroxide colors, and mixtures thereof. The pigments may
be coated with one or more ingredients that cause the pigments to
be hydrophobic. Suitable coating materials that will render the
pigments more lipophilic in nature include silicones, lecithin,
amino acids, phospholipids, inorganic and organic oils,
polyethylene, and other polymeric materials. Suitable silicone
treated pigments as disclosed in U.S. Pat. No. 5,143,722. Inorganic
white or uncolored pigments include TiO2, ZnO, ZrO2, or
semiconductor quantum dots, which are commercially available from a
number of sources. Other suitable colorants are identified in U.S.
Pat. No. 7,166,279. Colorants are generally included at a weight
percent such that the skin care composition yields a perceptible
color. In one embodiment, the skin care composition exhibits a
color that is perceptibly different from the color of the
applicator. By perceptibly different, refers to a difference in
color that is perceptible to a person having normal sensory
abilities under standard lighting conditions (e.g., natural
illumination as experienced outdoors during daylight hours, the
illumination of a standard 100 watt incandescent white light bulb
at a distance of 2 meters, or as defined by CIE D65 standard
illuminate lighting at 800 lux to a 1964 CIE standard observer).
Adhesives that are compatible with keratinous surfaces are known
and any such adhesive can be applied with the apparatuses of the
present invention. Commercially available adhesives compatible with
keratinous surfaces are available from the 3M Corporation of
Minneapolis Minn. See, for example: U.S. Pat. No. 6,461,467, issued
to Blatchford, et al., filed on Apr. 23, 2001; U.S. Pat. No.
5,614,310, issued to Delgado, et al., filed on Nov. 4, 1994; and
U.S. Pat. No. 5,160,315, issued to Heinecke et al., filed on Apr.
5, 1991. The entire disclosures of these patent applications are
incorporated by reference. After the adhesive is selectively
applied to the keratinous surface, a second treatment composition
can be dusted on the keratinous surface where it will stick to the
adhesive. The second modification that is not adhered to the
keratinous surface can then be removed leaving behind a selective,
micro application of the second treatment composition. Likewise
compositions that cure upon exposure to certain wavelengths of
energy, infrared light for example, are known to the art and can be
applied by the apparatuses of the present invention. By this
method, the curable composition is selectively applied to the
keratinous surface and then it is cured by exposing the keratinous
surface to the curing energy source. The entire keratinous surface
can be exposed, or the exposure can be done at the same time as the
application.
[0056] Wrinkle or texture reducing polymers and skin tightening are
known. See, for example: U.S. Pat. No. 6,139,829, issued to Estrin
on Oct. 31, 2000; and US Patent Applications US20060210513A1, filed
by Luizzi, et al. on Mar. 21, 2005; US20070224158A1, filed by
Cassin et al. on Mar. 18, 2005; and US20070148120A1, filed by Omura
et al. on Jan. 14, 2005. The entire disclosures of this patent and
these published patent applications are incorporated by reference.
More specifically, a cosmetic process for softening the wrinkles of
wrinkled skin may comprise applying, to the wrinkled skin, a
cosmetic composition, in particular an anti-wrinkle composition,
comprising, in a physiologically acceptable medium suitable for
topical application to the skin of the face: from 0.1 to 20% by
weight of at least one tensioning agent, with respect to the total
weight of the composition.
[0057] Optically-activated particles can be used as or added to the
treatment compositions of this invention. Sometimes referred to a
"interference pigments", these particles include a plurality of
substrate particles selected from the group consisting of nylons,
acrylics, polyesters, other plastic polymers, natural materials,
regenerated cellulose, metals, semiconductor quantum dots and
minerals; an optical brightener chemically bonded to each of the
plurality of substrate particles to form integral units in the form
of optically-activated particles for diffusing light. These
particles help to reduce the visual perception of skin
imperfections, including cellulite, shadows, skin discolorations,
and wrinkles. Each of the optically-activated particles are
encapsulated with a UV transparent coating to increase the
diffusion of light to further reduce the visual perception of the
skin imperfections. The encapsulated optically-activated particles
are able to absorb ultraviolet radiation and emit visible light;
and the encapsulated optically-activated particles are able to both
scatter and absorb light in a diffuse manner in order to reduce the
visual perception of skin imperfections, including cellulite,
wrinkles, shadows, and skin discolorations, when the
optically-activated particles are applied to the skin surface.
[0058] Hair colorants and hair removal compositions are also
suitable for use with the apparatuses of the present invention.
These compositions, and their component parts, are best described
by the examples given below. Each of the individual chemical
compositions described below for hair colorants can be used in
combination with any of the others ingredients, and likewise, those
skilled in the art will appreciate that the individual compositions
given for depilatories can be used with other ingredients listed in
other examples.
[0059] Skin care compositions can be applied with the apparatuses
of this invention. The skin care composition may be used as, for
example, a moisturizer, a conditioner, an anti-aging treatment, a
skin lightening treatment, a sunscreen, a sunless tanner, and
combinations thereof.
[0060] The skin care composition may comprise a safe and effective
amount of one or more skin care active ("active") useful for
regulating and/or improving skin condition. "Safe and effective
amount" means an amount of a compound or composition sufficient to
induce a positive benefit but low enough to avoid serious side
effects (i.e., provides a reasonable benefit to risk ratio within
the judgment of a skilled artisan). A safe and effective amount of
a skin care active can be from about 1.times.10.sup.-6 to about 25%
by weight of the total composition, in another embodiment from
about 0.0001 to about 25% by weight of the total composition, in
another embodiment from about 0.01 to about 10% by weight of the
total composition, in another embodiment from about 0.1 to about 5%
by weight of the total composition, in another embodiment from
about 0.2 to about 2% by weight of the total composition. Suitable
actives include, but are not limited to, vitamins (e.g., B3
compounds such as niacinamide, niacinnicotinic acid, tocopheryl
nicotinate; B5 compounds, such as panthenol; vitamin A compounds
and natural and/or synthetic analogs of Vitamin A, including
retinoids, retinol, retinyl acetate, retinyl palmitate, retinoic
acid, retinaldehyde, retinyl propionate, carotenoids (pro-vitamin
A); vitamin E compounds, or tocopherol, including tocopherol
sorbate, tocopherol acetate; vitamin C compounds, including
ascorbate, ascorbyl esters of fatty acids, and ascorbic acid
derivatives such as magnesium ascorbyl phosphate and sodium
ascorbyl phosphate, ascorbyl glucoside, and ascorbyl sorbate),
peptides (e.g., peptides containing ten or fewer amino acids, their
derivatives, isomers, and complexes with other species such as
metal ions), sugar amines (e.g., N-acetyl-glucosamine), sunscreens,
oil control agents, tanning actives, anti-acne actives,
desquamation actives, anti-cellulite actives, chelating agents,
skin lightening agents, flavonoids, protease inhibitors (e.g.,
hexamidine and derivatives), non-vitamin antioxidants and radical
scavengers, peptides, salicylic acid, hair growth regulators,
anti-wrinkle actives, anti-atrophy actives, minerals, phytosterols
and/or plant hormones, tyrosinase inhibitors, N-acyl amino acid
compounds, moisturizers, plant extracts, and derivatives of any of
the aforementioned actives. The term "derivative" as used herein
refers to structures which are not shown but which one skilled in
the art would understand are variations of the basic compound. For
example, removing a hydrogen atom from benzene and replacing it
with a methyl group. Suitable actives are further described in U.S.
application publication No. US2006/0275237A1 and
US2004/0175347A1.
[0061] Contrast Ratio
[0062] Herein, "contrast ratio" refers to the opacity of the
composition, or the ability of the composition to reduce or prevent
light transmission, determined after the composition is drawn onto
an opacity chart (Form N2A, Leneta Company of Manwah, N.J. or the
equivalent thereof), and by using a spectrophotometer with settings
selected to exclude specular reflection. The composition is applied
to the top of the opacity chart and then is drawn into a film
having a thickness of approximately 0.01 inches using a film
applicator (e.g., as commercially available from BYK Gardner of
Columbia, Md., or the equivalent thereof). The film is allowed to
dry for 2 hours under conditions of 22.degree. C.+/-1.degree. C., 1
atm. Using a spectrophotometer, the Y tristimulus value (i.e., the
XYZ color space of the film) of the product film is measured and
recorded. The Y tristimulus value is measured in three different
areas of the product film over the black section of the opacity
chart, and also in three different areas of the product film over
the white section of the opacity chart.
[0063] The contrast ratio for the individual layers of the present
invention, that is the contrast ratio for the first layer or the
powder layer is less than about 20, preferably less than about 10,
and even more preferably less than about 6.
[0064] The contrast ratio is calculated as the mathematical average
of the three Y tristimulus values over the black areas, divided by
the mathematical average of the three Y tristimulus values over the
white areas, times 100:
Contrast .times. .times. Ratio = average .times. .times. ( Yblack )
average .times. .times. ( Ywhite ) .times. 100 ##EQU00001##
EXAMPLES
[0065] The following examples further describe and demonstrate
embodiments within the scope of the present invention. The examples
are given solely for the purpose of illustration and are not to be
construed as limitations of the present invention, as many
variations thereof are possible without departing from the spirit
and scope of the invention.
[0066] The following 9 Examples are all treatment compositions of
the present inventions. They can be applied by any of the methods
and apparatuses described herein, preferably, they are applied via
a thermal ink jet printer head and cartridge combination.
Example 1
TABLE-US-00001 [0067] Treatment Composition Phase ingredient
description wt % A Water water 64.80 A Veegum HS Magnesium Aluminum
2.00 Silicate B Propylene Glycol Propylene Glycol 15.00 B PEG-2M
PEG2M 0.10 C GLW45GYAP 45% Iron Oxide slurry 0.60 (yellow iron
oxide) in glycerin/water C GLW75PFAP-MP 75% TiO2 slurry in 15.00
glycerin/water C PVP/VA W 735 50% VP/VA 1.50 Copolymer in water D
Symdiol Hexanediol/ 1.00 Caprylyl glycol
[0068] Combine ingredients of phase A using a homogenizer for
mixing and sifting the Veegum into the water. Begin heating water
to 75 C. Continue to mix for 20 min at 75 C. Then shut off heat.
Combine phase B in a separate container and add to phase A with
mixing while phase A cools. Add components of phase C one at a time
to phase A/B while it continues to cool. When temperature reaches
approximately 50 C, Add phase D while continuing to mix. Mix for
2-3 minutes to ensure homogeneity then pour into container.
Example 2
TABLE-US-00002 [0069] Treatment Composition Phase ingredient
description wt % A Water water 66.40 A Veegum HS Magnesium Aluminum
0.50 Silicate B Propylene Glycol Propylene Glycol 15.00 B GLW45GYAP
45% Iron Oxide slurry 0.60 (yellow iron oxide) in glycerin/water B
GLW75PFAP-MP 75% TiO2 slurry in 15.00 glycerin/water B PVP/VA W 735
50% VP/VA 1.50 Copolymer in water C Symdiol Hexanediol/ 1.00
Caprylyl glycol
[0070] Combine ingredients of phase A using a homogenizer for
mixing and sifting the Veegum into the water. Begin heating water
to 75 C. Continue to mix for 20 min at 75 C. Then shut off heat.
Add components of phase B one at a time to phase A while it
continues to cool. When temperature reaches approximately 50 C, Add
phase C while continuing to mix. Mix for 2-3 minutes to ensure
homogeneity then pour into container.
Example 3
TABLE-US-00003 [0071] Treatment Composition phase ingredient
description wt % A Water water 68.25 A Veegum Ultra Magnesium
Aluminum 0.50 Silicate B Propylene Glycol Propylene Glycol 13.50 B
Sicovit Yellow 100% Yellow Iron Oxide 0.25 Iron Oxide B
GLW75PFAP-MP 75% TiO2 slurry in 15.00 glycerin/water B PVP/VA W 735
50% VP/VA 1.50 Copolymer in water C Symdiol Hexanediol/ 1.00
Caprylyl glycol
[0072] Combine ingredients of phase A using a homogenizer for
mixing and sifting the Veegum into the water. Begin heating water
to 75 C. Continue to mix for 20 min at 75 C. Then shut off heat.
Add components of phase B one at a time to phase A while it
continues to cool. When temperature reaches approximately 50 C, Add
phase C while continuing to mix. Mix for 2-3 minutes to ensure
homogeneity then pour into container.
Example 4
TABLE-US-00004 [0073] Treatment Composition phase ingredient
description wt % A Propylene Glycol Propylene Glycol 15.00 A
Versaflex V-150 Steareth-100, Steareth-2, 0.50 Mannan, Xanthan Gum
B Water Water 66.75 B Symdiol Hexanediol/ 1.00 Caprylyl glycol C
Sicovit Yellow 100% Yellow Iron 0.25 Iron Oxide Oxide C
GLW75PFAP-MP 75% TiO2 slurry in 15.00 glycerin/water C PVP/VA W 735
50% VP/VA 1.50 Copolymer in water
[0074] Combine ingredients of phase A until uniform. Slowly add
components of phase B one at a time with mixing. Add components of
phase C one at a time using homogenizer to phase A/B to ensure
uniformity and even dispersion. Mix for 2-3 minutes then pour into
container.
Example 5
TABLE-US-00005 [0075] Treatment Composition phase ingredient
description wt % A Water water 70.23 A Veegum Ultra Magnesium
Aluminum 0.40 Silicate B Propylene Glycol Propylene Glycol 12.50 B
Sodium Cellulose Gum 0.40 Carboxymethyl Cellulose 7L2P C Sicovit
Yellow 100% Yellow Iron 0.22 Iron Oxide Oxide C Sachtleben RC402
Titanium Dioxide 13.75 C PVP/VA W 735 50% VP/VA 1.50 Copolymer in
water D Symdiol Hexanediol/ 1.00 Caprylyl glycol
[0076] Combine ingredients of phase A using a homogenizer for
mixing and sifting the Veegum into the water. Begin heating water
to 75 C. Continue to mix for 20 min at 75 C. Then shut off heat.
Combine phase B in a separate container and add to phase A with
mixing while phase A cools. Add components of phase C one at a time
to phase A/B while it continues to cool. When temperature reaches
approximately 50 C, add phase D while continuing to mix. Mix for
2-3 minutes to ensure homogeneity then pour into container.
Example 6
TABLE-US-00006 [0077] Treatment Composition phase ingredient
description wt % A Water water 65.80 A Veegum HS Magnesium Aluminum
2.00 Silicate B Propylene Glycol Propylene Glycol 15.00 B Natrosol
250 LR Hydroxyethylcellulose 0.50 B PEG-2M PEG2M 0.10 C GLW45GYAP
45% Iron Oxide slurry 0.60 (yellow iron oxide) in glycerin/water C
GLW75PFAP-MP 75% TiO2 slurry in 15.00 glycerin/water D Symdiol
Hexanediol/ 1.00 Caprylyl glycol
[0078] Combine ingredients of phase A using a homogenizer for
mixing and sifting the Veegum into the water. Begin heating water
to 75 C. Continue to mix for 20 min at 75 C. Then shut off heat.
Combine phase B in a separate container and add to phase A with
mixing while phase A cools. Add components of phase C one at a time
to phase A/B while it continues to cool. When temperature reaches
approximately 50 C, Add phase D while continuing to mix. Mix for
2-3 minutes to ensure homogeneity then pour into container.
Example 7
TABLE-US-00007 [0079] Treatment Composition phase ingredient
description wt % A Water water 70.08 A Veegum Ultra Magnesium
Aluminum 0.40 Silicate B Propylene Glycol Propylene Glycol 12.50 B
Keltrol CG-T Xanthan Gum 0.05 C Sicovit Yellow 100% Yellow Iron
0.22 Iron Oxide Oxide C Sachtleben RC402 Titanium Dioxide 13.75 C
PVP K15 30% PVP in water 2.00 D Symdiol Hexanediol/ 1.00 Caprylyl
glycol
[0080] Combine ingredients of phase A using a homogenizer for
mixing and sifting the Veegum into the water. Begin heating water
to 75 C. Continue to mix for 20 min at 75 C. Then shut off heat.
Combine phase B in a separate container and add to phase A with
mixing while phase A cools. Add components of phase C one at a time
to phase A/B while it continues to cool. When temperature reaches
approximately 50 C, Add phase D while continuing to mix. Mix for
2-3 minutes to ensure homogeneity then pour into container.
Example 8
TABLE-US-00008 [0081] Treatment Composition phase ingredient
description wt % A Propylene Glycol Propylene Glycol 15.00 A
Versaflex V-150 Steareth-100, 0.50 Steareth-2, Mannan Xanthan Gum B
Water Water 64.90 B Symdiol Hexanediol/ 1.00 Caprylyl glycol C
Sicovit Yellow 100% Yellow Iron 2.00 Iron Oxide Oxide C Sicovit Red
100% Red Iron 0.10 Iron Oxide Oxide C GLW75PFAP-MP 75% TiO2 slurry
in 15.00 glycerin/water C PVP/VA W 735 50% PVP/VA 1.50 Copolymer in
water
[0082] Combine ingredients of phase A until uniform. Slowly add
components of phase B one at a time with mixing. Add components of
phase C one at a time using homogenizer to phase A/B to ensure
uniformity and even dispersion. Mix for 2-3 minutes then pour into
container.
Example 9
TABLE-US-00009 [0083] Treatment Composition Phase ingredient
description wt % A Water water 61.25 A Veegum HS Magnesium Aluminum
2.00 Silicate B Propylene Glycol Propylene Glycol 15.00 B PEG-2M
Polyethylene Glycol 0.10 C GLW45GYAP 45% Iron Oxide slurry 4.00
(yellow iron oxide) in glycerin/water C GLW55GRAP 55% Iron Oxide
slurry 0.15 (red iron oxide) in glycerin/water C GLW75PFAP-MP 75%
TiO2 slurry in 15.00 glycerin/water C PVP/VA W 735 50% PVP/VA 1.50
Copolymer in water D Symdiol 50/50 Hexanediol/ 1.00 Caprylyl
glycol
[0084] Combine ingredients of phase A using a homogenizer for
mixing and sifting the Veegum into the water. Begin heating water
to 75 C. Continue to mix for 20 min at 75 C. Then shut off heat.
Combine phase B in a separate container and add to phase A with
mixing while phase A cools. Add components of phase C one at a time
to phase A/B while it continues to cool. When temperature reaches
approximately 50 C, add phase D while continuing to mix. Mix for
2-3 minutes to ensure homogeneity then pour into container.
Example 10
TABLE-US-00010 [0085] Treatment Composition Phase ingredient
description wt % A GLW75PFAP-MP 75% TiO2 slurry in 22.50
glycerin/water A GLW45GYAP 45% Iron Oxide slurry in 3.33 (yellow
iron oxide) glycerin/water A GLW55GRAP 55% Iron Oxide slurry in
0.17 (red iron oxide) glycerin/water B Water water 5.00 B Sodium
Hydroxide NaOH pellets 0.02 Solid C Water water 43.15 C Propylene
Glycol Propylene Glycol 15.00 C PVP/VA W 735 50% PVP/VA 1.50
Copolymer in water C Symdiol 50/50 Hexanediol/ 1.00 Caprylyl glycol
D Water water 8.33
[0086] Combine the ingredients in phase A and mix until color is
homogenous. Combine the ingredients in phase B and mix until the
solid NaOH is thoroughly dissolved. Combine the ingredients in
phase C using an overhead mixer to disperse the ingredients. Use a
homogenizer to begin milling phase C and slowly adding phase A to
phase C. Use phase D as a wash for the phase A container and add
the wash to phase C. Mill for 10 minutes or until all ingredients
are homogenous. Add phase B to the combined phases as the final
addition. Mill and mix the combined phases until homogenous.
Example 11
[0087] The following Example includes relatively large particles,
and significantly reduced visible red tint.
TABLE-US-00011 Treatment Composition Phase ingredient description
wt % A GLW55GRAP 55% Iron Oxide slurry 0.17 (red iron oxide) in
glycerin/water A GLW45GYAP 45% Iron Oxide slurry 3.33 (yellow iron
oxide) in glycerin/water A GLW75PFAP-MP 75% TiO2 slurry in 22.50
glycerin/water A Water water 24.00 B Water water 32.48 B Propylene
Glycol Propylene Glycol 15.00 B PVP/VA W 735 50% PVP/VA 1.50
Copolymer in water B Symdiol 50/50 Hexanediol/ 1.00 Caprylyl glycol
B Sodium NaOH pellets 0.02 Hydroxide Solid
[0088] Combine the components of phase A together using an overhead
mixer until all ingredients are homogenous. Combine the ingredients
of phase B together in a separate container with an overhead mixer
until the solid NaOH is dissolved and all ingredients are
homogenous. Add phase A to one injection chamber of a liquid
whistle sonolator system and the other to the second injection
chamber. These will serve as two streams of material to form the
final product Simultaneously pump both phases into the liquid
whistle at 2500 PSI with the internal blade set at a half turn.
Collect final product that has reached the required pressure.
[0089] Referring now to FIGS. 4, 5 and 6, which are photographs of
the same female consumer. FIG. 4 represents her washed, natural,
and uncoated skin. FIG. 5 was taken after the subject applied
makeup to her face in a manner she would normally do. FIG. 6 was
taken after the consumer's makeup was removed and her face treated
with the apparatus and methods of this invention. FIGS. 4, 5 and 6
are all taken on the same day, with no appreciable sun exposure
between photographs (i.e. the consumer was indoors for the entire
treatment period).
[0090] Skin deviations 101, 102, 103 and 104 are clear in FIG. 4.
After makeup is applied, skin deviations 101, 102, 103 and 104 are
all still visible. There are tonal differences on the consumer's
skin as well as the skin deviations of FIG. 5 vs. FIG. 4. It is
clear from FIGS. 4 and 5 that makeup changes the overall tone of
human skin, but does not cover up imperfections.
[0091] The consumer washes her face to remove the applied makeup
after the photograph of FIG. 5 is taken, and then her skin is
treated with the apparatuses and methods of this invention, then
the photograph of FIG. 6 is taken. Skin deviations 101, 102 and 104
from FIGS. 4 and 5 are largely invisible in FIG. 6. Skin deviation
103 is barely visible after treatment with the present apparatuses
and methods. Accordingly, the present apparatuses and methods
provide a substantial and visible change to the appearance of human
skin versus the natural condition of the skin and the skin with
applied makeup.
[0092] The dimensions and values disclosed herein are not to be
understood as being strictly limited to the exact numerical values
recited. Instead, unless otherwise specified, each such dimension
is intended to mean both the recited value and a functionally
equivalent range surrounding that value. For example, a dimension
disclosed as "40 mm" is intended to mean "about 40 mm."
[0093] Every document cited herein, including any cross referenced
or related patent or application, is hereby incorporated herein by
reference in its entirety unless expressly excluded or otherwise
limited. The citation of any document is not an admission that it
is prior art with respect to any invention disclosed or claimed
herein or that it alone, or in any combination with any other
reference or references, teaches, suggests or discloses any such
invention. Further, to the extent that any meaning or definition of
a term in this document conflicts with any meaning or definition of
the same term in a document incorporated by reference, the meaning
or definition assigned to that term in this document shall
govern.
[0094] While particular embodiments of the present invention have
been illustrated and described, it would be obvious to those
skilled in the art that various other changes and modifications can
be made without departing from the spirit and scope of the
invention. It is therefore intended to cover in the appended claims
all such changes and modifications that are within the scope of
this invention.
* * * * *