U.S. patent application number 16/880090 was filed with the patent office on 2021-05-06 for extreme ultraviolet exposure system.
This patent application is currently assigned to SAMSUNG ELECTRONICS CO., LTD.. The applicant listed for this patent is SAMSUNG ELECTRONICS CO., LTD.. Invention is credited to Keunhee Bai, Sungho JANG, Sungyeol Kim, Injae Lee, Hyuck Shin.
Application Number | 20210132515 16/880090 |
Document ID | / |
Family ID | 1000004867674 |
Filed Date | 2021-05-06 |
![](/patent/app/20210132515/US20210132515A1-20210506\US20210132515A1-2021050)
United States Patent
Application |
20210132515 |
Kind Code |
A1 |
JANG; Sungho ; et
al. |
May 6, 2021 |
EXTREME ULTRAVIOLET EXPOSURE SYSTEM
Abstract
An extreme ultraviolet exposure system includes an exposure
chamber having an internal space, upper and lower electrostatic
chucks, a power supply, a light source, and a mask. The upper
electrostatic chuck includes first and second electrodes that are
adjacent to one another and that generate an electric field of
different polarities, respectively, to provide an electrostatic
force. The mask is attachable to the lower surface of the upper
electrostatic chuck by the electrostatic force. The mask has a
metal thin film pattern including a first region in which a metal
thin film that shields the electric field, and a second region in
which the metal thin film is not disposed and through which the
electric field is transmitted. When the mask is attached, the
electric field transmitted through the second region applies an
attractive force or a repulsive force to charged particles in the
exposure chamber.
Inventors: |
JANG; Sungho; (Hwaseong-si,
KR) ; Kim; Sungyeol; (Yongin-si, KR) ; Shin;
Hyuck; (Bucheon-si, KR) ; Bai; Keunhee;
(Suwon-si, KR) ; Lee; Injae; (Suwon-si,
KR) |
|
Applicant: |
Name |
City |
State |
Country |
Type |
SAMSUNG ELECTRONICS CO., LTD. |
Suwon-si |
|
KR |
|
|
Assignee: |
SAMSUNG ELECTRONICS CO.,
LTD.
Suwon-si
KR
|
Family ID: |
1000004867674 |
Appl. No.: |
16/880090 |
Filed: |
May 21, 2020 |
Current U.S.
Class: |
1/1 |
Current CPC
Class: |
G03F 7/70916 20130101;
G03F 7/70741 20130101; G03F 7/70033 20130101; G03F 7/70808
20130101 |
International
Class: |
G03F 7/20 20060101
G03F007/20 |
Foreign Application Data
Date |
Code |
Application Number |
Oct 30, 2019 |
KR |
10-2019-0136669 |
Claims
1. An extreme ultraviolet exposure system comprising: an exposure
chamber having an internal space; an upper electrostatic chuck that
is disposed in the internal space, the upper electrostatic chuck
including a first electrode and a second electrode adjacent to one
another in a first direction that is parallel to a lower surface of
the upper electrostatic chuck, and the first and second electrodes
generating an electric field of different polarities, respectively,
to provide an electrostatic force; a power supply that supplies
power to the upper electrostatic chuck; a light source that is
disposed in the internal space and irradiates extreme ultraviolet
light in a direction of the upper electrostatic chuck; a lower
electrostatic chuck that is disposed in the internal space; and a
mask that is attachable to the lower surface of the upper
electrostatic chuck by the electrostatic force, the mask having a
metal thin film pattern including a first region in which a metal
thin film that shields the electric field is disposed, and a second
region in which the metal thin film is not disposed and through
which the electric field is transmitted, wherein, when the mask is
attached to the upper electrostatic chuck, the electric field
transmitted through the second region applies an attractive force
or a repulsive force to charged particles in the exposure
chamber.
2. The extreme ultraviolet exposure system of claim 1, wherein the
charged particles receive the attractive force by the electric
field transmitted through the second region and are attracted to
and attached to a surface of the mask.
3. The extreme ultraviolet exposure system of claim 1, wherein the
charged particles receive the repulsive force by the electric field
transmitted through the second region and move in a direction away
from the upper electrostatic chuck.
4. The extreme ultraviolet exposure system of claim 1, wherein a
voltage applied to the first and second electrodes has a different
polarity and a same magnitude.
5. The extreme ultraviolet exposure system of claim 1, wherein the
first region is disposed to correspond to the first electrode, and
the second region is disposed to correspond to the second
electrode.
6. The extreme ultraviolet exposure system of claim 1, wherein each
of the first and second regions are disposed to have portions
overlapping the first and second electrodes, respectively.
7. The extreme ultraviolet exposure system of claim 1, wherein the
first region is disposed to correspond to the first and second
electrodes, respectively, and the second region comprises a
plurality of regions, each of the plurality of regions being
disposed to correspond to a region in which the first and second
electrodes are in contact with each other, and each of the
plurality of regions has width less than a width of one of the
first and second electrodes in the first direction.
8. The extreme ultraviolet exposure system of claim 1, wherein the
first region comprises a plurality of divided regions, and the
plurality of divided regions have a same shape as each other.
9. The extreme ultraviolet exposure system of claim 1, wherein the
mask comprises: a light transmissive substrate having a first
surface that is attracted to and attached to the upper
electrostatic chuck and a second surface opposing the first
surface; and a particle collecting layer that is disposed on the
second surface and to which the charged particles are attracted and
attached.
10. The extreme ultraviolet exposure system of claim 9, wherein the
particle collecting layer is formed of a porous thin film including
a plurality of nanowires and a plurality of nanotubes arranged to
cross each other to form a network structure.
11. The extreme ultraviolet exposure system of claim 9, wherein the
particle collecting layer is formed of an adhesive material.
12. The extreme ultraviolet exposure system of claim 1, wherein the
internal space has a pressure of about 5 Pa or less.
13. An extreme ultraviolet exposure system comprising: an exposure
chamber; an upper electrostatic chuck that is disposed in the
exposure chamber, and includes a first electrode and a second
electrode alternately disposed on a lower surface thereof, the
first and second electrodes generating an electric field having
different polarities, respectively, to provide an electrostatic
force; and a mask that is attachable to the lower surface of the
upper electrostatic chuck by the electrostatic force, and that
comprises a metal thin film pattern selectively shielding the
electric field generated by the first and second electrodes.
14. The extreme ultraviolet exposure system of claim 13, wherein
the mask comprises a light transmissive substrate having a first
surface that is attached to the upper electrostatic chuck and a
second surface opposing the first surface, and the metal thin film
pattern is disposed on the second surface.
15. The extreme ultraviolet exposure system of claim 13, wherein
the mask comprises a light transmissive substrate, and the metal
thin film pattern is disposed in the interior of the light
transmissive substrate.
16. The extreme ultraviolet exposure system of claim 13, wherein
the metal thin film pattern has a first region in which a metal
thin film is disposed to block the electric field; and a second
region from which the metal thin film is not disposed and through
which the electric field is transmitted.
17. The extreme ultraviolet exposure system of claim 16, wherein
the mask comprises a light transmissive substrate having a first
surface and a second surface opposing the first surface, the first
and second regions being disposed on the first surface, and a
portion of the metal thin film pattern extends from the first
surface to the second surface by penetrating through the light
transmissive substrate, the portion of the metal thin film pattern
being in contact with the second region.
18-20. (canceled)
21. An extreme ultraviolet exposure system comprising: an exposure
chamber having an internal space that is maintained at a pressure
of about 5 Pa or less; an electrostatic chuck that is disposed in
the internal space, and that includes a first electrode and a
second electrode that generate an electric field having different
polarities, respectively, to provide an electrostatic force; and a
light source that is disposed in the internal space and irradiates
extreme ultraviolet light to expose a wafer in an exposure
configuration of the extreme ultraviolet exposure system, wherein,
in a cleaning configuration, a first mask is attached to a lower
surface of the electrostatic chuck by the electrostatic force, the
first mask comprising a metal thin film pattern that shields a
portion of the electric field generated by the first and second
electrodes such that charged particles in the exposure chamber are
attracted and attached to a surface of the first mask or repelled
away from the first mask by a portion of the electric field that is
transmitted through the first mask.
22. The extreme ultraviolet exposure system of claim 21, wherein
the charged particles are repelled away from the first mask and are
stacked on a surface of the exposure chamber opposite the
electrostatic chuck.
23. The extreme ultraviolet exposure system of claim 21, wherein,
in the exposure configuration, a second mask is attached to the
lower surface of the electrostatic chuck by the electrostatic
force, the second mask comprising a metal thin film pattern that
shields the electric field generated by the first and second
electrodes such that the wafer is exposed by the extreme
ultraviolet light.
Description
CROSS-REFERENCE TO RELATED APPLICATION
[0001] This application claims priority from Korean Patent
Application No. 10-2019-0136669 filed on Oct. 30, 2019 in the
Korean Intellectual Property Office, the disclosure of which is
incorporated reference herein by in its entirety.
BACKGROUND
1. Field
[0002] The present disclosure relates to an extreme ultraviolet
exposure system.
2. Description Of Related Art
[0003] In a related art exposure system, a light transmissive
exposure system using deep ultraviolet (DUV) light as a light
source has been widely used, but recently, as integration density
of semiconductor devices are improved and line widths become finer,
next-generation lithography technologies have been studied to
improve a resolution of optical lithography. Among the lithography
technologies, development of an extreme ultraviolet exposure system
as a light source using extreme ultraviolet (EUV) light, having a
shorter wavelength than deep ultraviolet light, has been actively
conducted. In order to effectively operate the extreme ultraviolet
exposure system, a method of removing particles from the interior
of an extreme ultraviolet exposure system using airflow has been
used, but since the interior of the extreme ultraviolet system is
maintained in a low vacuum state to prevent absorption of extreme
ultraviolet light by gas, there has been a limitation in removing
particles through the airflow. In particular, particles charged
with a particular charge may be electrostatically adsorbed to
surfaces of structures and components interior the extreme
ultraviolet exposure system, making them difficult to remove with
airflow.
SUMMARY
[0004] It is an aspect to provide an exposure system capable of
effectively removing charged particles in an extreme ultraviolet
exposure chamber.
[0005] According to an aspect of an example embodiment, there is
provided an extreme ultraviolet exposure system that includes an
exposure chamber having an internal space; an upper electrostatic
chuck that is disposed in the internal space, the upper
electrostatic chuck including a first electrode and a second
electrode adjacent to one another in a first direction that is
parallel to a lower surface of the upper electrostatic chuck, and
the first and second electrodes generating an electric field of
different polarities, respectively, to provide an electrostatic
force; a power supply that supplies power to the upper
electrostatic chuck; a light source that is disposed in the
internal space and irradiates extreme ultraviolet light in a
direction of the upper electrostatic chuck; a lower electrostatic
chuck that is disposed in the internal space; and a mask that is
attachable to the lower surface of the upper electrostatic chuck by
the electrostatic force, the mask having a metal thin film pattern
including a first region in which a metal thin film that shields
the electric field is disposed, and a second region in which the
metal thin film is not disposed and through which the electric
field is transmitted, wherein, when the mask is attached to the
upper electrostatic chuck, the electric field transmitted through
the second region applies an attractive force or a repulsive force
to charged particles in the exposure chamber.
[0006] According to another aspect of an example embodiment, there
is provided an extreme ultraviolet exposure system including an
exposure chamber; an upper electrostatic chuck that is disposed in
the exposure chamber, and includes a first electrode and a second
electrode alternately disposed on a lower surface thereof, the
first and second electrodes generating an electric field having
different polarities, respectively, to provide an electrostatic
force; and a mask that is attachable to the lower surface of the
upper electrostatic chuck by the electrostatic force, and that
comprises a metal thin film pattern selectively shielding the
electric field generated by the first and second electrodes.
[0007] According to another aspect of an example embodiment, there
is provided an extreme ultraviolet exposure system including an
exposure chamber having an internal space; an upper electrostatic
chuck that is disposed in the internal space, and that includes a
first electrode and a second electrode alternately disposed on a
lower surface of the upper electrostatic chuck, the first and
second electrodes generating an electric field having different
polarities, respectively, to provide an electrostatic force; a
lower electrostatic chuck that is disposed in the internal space; a
first mask that is attachable to the lower surface of the upper
electrostatic chuck by the electrostatic force, and that comprises
a metal thin film pattern selectively shielding the electric field
generated by the first and second electrodes; and a second mask
that is attachable to the lower surface of the upper electrostatic
chuck by the electrostatic force, and having a metal thin film
pattern shielding the electric field generated by the first and
second electrodes, wherein, when the first mask is attached to the
upper electrostatic chuck, charged particles in the exposure
chamber are attracted and attached to a surface of the first mask
by the electric field having a first polarity of the different
polarities that is selectively transmitted through the first mask,
and when the second mask is attached to the upper electrostatic
chuck, the electric field is shielded to allow exposure of a wafer
in the exposure chamber.
[0008] According to another aspect of an example embodiment, there
is provided an extreme ultraviolet exposure system including an
exposure chamber having an internal space that is maintained at a
pressure of about 5 Pa or less; an electrostatic chuck that is
disposed in the internal space, and that includes a first electrode
and a second electrode that generate an electric field having
different polarities, respectively, to provide an electrostatic
force; and a light source that is disposed in the internal space
and irradiates extreme ultraviolet light to expose a wafer in an
exposure configuration of the extreme ultraviolet exposure system,
wherein, in a cleaning configuration, a first mask is attached to a
lower surface of the electrostatic chuck by the electrostatic
force, the first mask comprising a metal thin film pattern that
shields a portion of the electric field generated by the first and
second electrodes such that charged particles in the exposure
chamber are attracted and attached to a surface of the first mask
or repelled away from the first mask by a portion of the electric
field that is transmitted through the first mask.
BRIEF DESCRIPTION OF DRAWINGS
[0009] The above and other aspects will be more clearly understood
from the following detailed description, taken in conjunction with
the accompanying drawings, in which:
[0010] FIG. 1 is a schematic view illustrating an extreme
ultraviolet exposure system according to an example embodiment;
[0011] FIG. 2 is a view illustrating an upper electrostatic chuck
and a first mask of the extreme ultraviolet exposure system of FIG.
1;
[0012] FIG. 3 is an exploded perspective view illustrating the
upper electrostatic chuck and the first mask of FIG. 2;
[0013] FIGS. 4 and 5 are views illustrating a process of removing
charged particles using an extreme ultraviolet exposure system
according to an example embodiment;
[0014] FIGS. 6 to 9B illustrate various modified examples of the
first mask of FIGS. 2 and 3; and
[0015] FIG. 10 is a flowchart illustrating a method of
manufacturing a semiconductor device using an extreme ultraviolet
exposure system according to an example embodiment.
DETAILED DESCRIPTION
[0016] Hereinafter, example embodiments will be described with
reference to the accompanying drawings.
[0017] Referring to FIGS. 1 to 3, an extreme ultraviolet exposure
system according to an example embodiment will be described. FIG. 1
is a schematic view illustrating an extreme ultraviolet exposure
system according to an example embodiment, and FIG. 2 is a view
illustrating an upper electrostatic chuck and a first mask of the
extreme ultraviolet exposure system of FIG. 1. FIG. 3 is an
exploded perspective view illustrating the upper electrostatic
chuck and the first mask of FIG. 2.
[0018] Referring to FIG. 1, an extreme ultraviolet (EUV) exposure
system 10 may include a load lock chamber 100, a wafer exchange
chamber 200, and an exposure chamber 300. The extreme ultraviolet
exposure system 10 may be a device that performs extreme
ultraviolet exposure on a wafer W coated with a photoresist.
[0019] The load lock chamber 100 may be a chamber that functions as
a path for supplying and discharging the wafer W to the exposure
chamber 300 from a spinner performing a photoresist coating process
and a development process. The load lock chamber 100 may be
disposed at an inlet-side and/or an outlet-side of the exposure
chamber 300. The load lock chamber 100 may selectively maintain an
atmospheric pressure state and a vacuum state. The wafer may refer
to a semiconductor substrate on which an extreme ultraviolet
photolithography process, for example, ultraviolet exposure, is
performed, to form a pattern. Here, the wafer may include any kind
of substrates on which extreme ultraviolet exposure may be
performed without being limited to the semiconductor substrate.
[0020] The wafer exchange chamber 200 may be coupled to the load
lock chamber 100 through a first door 500, and may be coupled to
the exposure chamber 300 through a second door 600. A transfer
robot 210 for moving the wafer W may be disposed in the wafer
exchange chamber 200. The transfer robot 210 may have a multi-stage
arm 211, and an arm spoon 212 on which the wafer W is placed may be
disposed in an end portion of the multi-stage arm 211. When the
first door 500 is opened, the transfer robot 210 may select the
wafer W to be processed from the load lock chamber 100 to be loaded
on the arm spoon 212. In addition, when the second door 600 is
opened, the transfer robot 210 may load the loaded wafer W into the
exposure chamber 300. In addition, when an exposure process of the
wafer W is completed, the transfer robot 210 may unload the wafer W
from the exposure chamber 300 and then transfer the wafer W to the
load lock chamber 100 again. In addition, the transfer robot 210
may be used to load/unload a first mask 320 and a second mask 360
to be described below to an upper electrostatic chuck (ESC)
310.
[0021] However, a structure of the transfer robot 210 is not
limited thereto, and other transporting devices may be used in the
wafer exchange chamber 200 instead of the transfer robot 210.
[0022] The exposure chamber 300 may have an internal space 301, and
may include a light source 330, the upper electrostatic chuck (ESC)
310, a projection unit 340, and a lower electrostatic chuck 350 in
the internal space 301 thereof. The first and second masks 320 and
360 may be loaded/unloaded on the upper electrostatic chuck 310,
and the wafer W may be loaded/unloaded on the lower electrostatic
chuck 350. The first mask 320 may be a mask for removing particles
in the interior of the exposure chamber 300, which will be
described later. The second mask 360 may be a mask for irradiating
a pattern on the photoresist of the wafer W. The internal space of
the exposure chamber 300 may be in a low-pressure state or a vacuum
state of about 5 Pa or less to prevent absorption of extreme
ultraviolet light into a gas.
[0023] The light source 330 may include an extreme ultraviolet
light source 331, and may generate extreme ultraviolet light (EUV)
having a wavelength of less than about 100 nm. The extreme
ultraviolet light source 331 may be, for example, a plasma source
or a synchrotron light source. In addition, the plasma light source
may be a laser-produced plasma (LPP) light source targeting tin
(Sn) using a CO.sub.2 laser as an excitation light source. The
light source 330 may include a plurality of mirrors to irradiate
extreme ultraviolet light (EUV) emitted from the extreme
ultraviolet light source 331 in a direction of the upper
electrostatic chuck 310. It is noted that, in FIG. 1, only the
first mirror 332 for collecting extreme ultraviolet light from the
extreme ultraviolet light source 331 and supplying the extreme
ultraviolet light to other lighting mirrors is shown, and the
remaining mirrors are omitted for simplicity and convenience of
explanation.
[0024] Referring to FIG. 1, the upper electrostatic chuck 310 may
be disposed above the internal space 301. The upper electrostatic
chuck 310 may include a plurality of first electrodes and a
plurality of second electrodes. For example, referring to FIGS. 2
and 4, the upper electrostatic chuck 310 may include first
electrodes A1 and A3 and second electrodes A2 and A4, for
generating an electric field, and the first electrodes A1 and A3
and the second electrodes A2 and A4 may be alternately disposed on
a lower surface P1 of the upper electrostatic chuck 310. In an
example embodiment, the first electrodes A1 and A3 and the second
electrodes A2 and A4 may be disposed to be adjacent to each other
in a horizontal direction, parallel to the lower surface P1 of the
upper electrostatic chuck 310. The first electrodes A1 and A3 and
the second electrodes A2 and A4 may use power applied from a power
supply 400 to form electric fields having different polarities,
thereby providing electrostatic force in a downward direction.
[0025] In an example embodiment, the first electrodes A1 and A3 and
the second electrodes A2 and A4 may have a rectangular shape that
is long in one direction, respectively, and two thereof are
alternately disposed, respectively. In addition, the first
electrodes A1 and A3 and the second electrodes A2 and A4 may have
the same shapes. In addition, an electric field of (+) polarity may
be formed in the first electrodes A1 and A3, and an electric field
(-) polarity may be formed in the second electrodes A2 and A4.
However, shape, number, arrangement and polarity of the first and
second electrodes A1 to A4 are not limited thereto, and may be
variously modified. Since the first and second electrodes A1 to A4
form electric fields having opposite polarities, respectively, a
first surface P2 of the first mask 320 may be attracted by
electrostatic force to the lower surface P1 of the upper
electrostatic chuck 310 and attached thereto.
[0026] A mask attracted and attached to the upper electrostatic
chuck 310 may include the first mask 320 for removing particles
interior the exposure chamber 300 and the second mask 360 for
transferring a pattern to the wafer W. In some cases, the mask may
be referred to as a reticle. An example embodiment will be
described based on a case in which the first mask 320 for removing
particles interior the exposure chamber 300 is employed.
[0027] Referring to FIGS. 2 and 3, the first mask 320 may include a
light transmissive substrate 321 and a metal thin film pattern 322.
The light transmissive substrate 321 may have the first surface P2,
which is a surface that may be attached to the lower surface P1 of
the upper electrostatic chuck 310 and a second surface P3 that is
opposite to the first surface P2. The light transmissive substrate
321 may include a low thermal expansion material (LTEM) having a
low coefficient of thermal expansion. The light transmissive
substrate 321 may include, for example, quartz glass, alumina
silicate glass, soda lime glass, and/or SiO.sub.2-TiO.sub.2 based
glass.
[0028] The metal thin film pattern 322 may be disposed on the first
surface P2. The metal thin film pattern 322 may provide an
attractive force for the first mask 320 to be attracted to and
attached to the upper electrostatic chuck 310. In addition, the
metal thin film pattern 322 may include first regions B1 and B3 on
which a metal thin film is disposed and second regions B2 and B4
from on which the metal thin film is not disposed. In some example
embodiments, the metal thin film pattern 322 include the second
regions B2 and B4 from which the metal thin film is removed. In the
first regions B1 and B3, the metal thin film may be disposed to
shield electric fields E1 and E3 emitted from the upper
electrostatic chuck 310. In the second regions B2 and B4, the metal
thin film may be not disposed or may be removed to transmit the
electric fields E2 and E4 emitted from the upper electrostatic
chuck 310. Therefore, the metal thin film pattern 322 may allow the
electric fields E2 and E4 to be transmitted to the lower portion of
the first mask 320, while providing an attractive force for
attaching the first mask 320 to the upper electrostatic chuck 310.
While FIGS. 2-3 show the metal thin film pattern 322 disposed on
the first surface P2, this is only an example, and in some example
embodiments, the metal thin film pattern 322 may be formed in the
light transmissive substrate 321.
[0029] According to some example embodiments, a particle collecting
layer 313 may be disposed on the second surface P3 of the light
transmissive substrate 321. The particle collecting layer 313 may
be provided to keep particles firmly in place when the particles
are attached to the second surface P3 of the first mask 320.
[0030] The particle collecting layer 313 may be formed of a porous
thin film including a plurality of nanowires or a plurality of
nanotubes arranged to cross each other to form a network structure.
In addition, the particle collecting layer 313 may be made of an
adhesive material providing chemical adhesion. Therefore, the
particles attached to the particle collecting layer 313 may remain
attached to the surface of the particle collecting layer 313.
[0031] In the case of the second mask 360 for transferring the
pattern to the wafer W, a metal thin film may be coated to entirely
cover one surface of the light transmissive substrate 321, such
that the electric fields E1 to E4 of the upper electrostatic chuck
310 may not be transmitted to the lower portion of the second mask
360. The metal thin film of the second mask 360 may prevent bending
of the mask due to the electrostatic force of the upper
electrostatic chuck 310, and may block the electric field of the
upper electrostatic chuck 310, thereby preventing the extreme
ultraviolet light of the light source 330 and the projection unit
340 from being affected by the electric fields E1 to E4 of the
upper electrostatic chuck 310.
[0032] On the other hand, in the case of the first mask 320 for
removing the particles interior the exposure chamber 300, a metal
thin film pattern 322 from which a portion of the thin film is
removed may be disposed, and a portion of electric fields, e.g.,
electric fields E2 and E4, of the electric fields E1 to E4 of the
upper electrostatic chuck 310 may be applied to the lower portion
of the first mask 320. The metal thin film pattern 322 may be
coated on the first surface P2 of the light transmissive pattern
321. The metal thin film pattern 322 may be formed of a conductive
metal layer. In detail, the metal thin film pattern 322 may be
formed by coating a material including at least one of chromium
nitride (CrN), titanium nitride (TiN), molybdenum silicide
(MoSi.sub.2), silicon carbide (SiC), or silicon nitride
(Si.sub.3N.sub.4).
[0033] As illustrated in FIG. 3, the metal thin film pattern 322
may be disposed on the first surface P2 of the light transmissive
substrate 321. The metal thin film pattern 322 may include first
regions B1 and B3 on which metal thin films 322-1 and 322-2 are
disposed, respectively, and second regions B2 and B4 on which the
metal thin film is not disposed or on which the metal thin film is
removed. In this case, the first regions B1 and B3 may be disposed
in a region corresponding to the first electrodes A1 and A3 of the
upper electrostatic chuck 310, and the second regions B2 and B4 may
be disposed in a region corresponding to the second electrodes A2
and A4 of the upper electrostatic chuck 310. Therefore, the
electric fields E1 and E3 emitted from the region in which the
first electrodes A1 and A3 of the upper electrostatic chuck 310 are
disposed are shielded, and the electric fields E2 and E4 emitted
from a region in which the second electrodes A2 and A4 are disposed
may be emitted through the first mask 320. Therefore, by using the
electric fields E2 and E4 emitted in the region in which the second
electrodes A2 and A4 are disposed, attractive or repulsive force
may be applied to the charged particles in the exposure chamber
300. There may be many particles interior the exposure chamber 300,
and a portion of the particles may be charged to a specific charge
by a photoelectric effect by photons of extreme ultraviolet light,
or by plasma. The charged particles as described above may be fixed
to a surface of a structure and a component interior the exposure
chamber 300 by the electrostatic force. In the related art,
attempts were made to remove the fixed particles by generating
airflow interior the exposure chamber 300. However, since the
interior of the exposure chamber 300 is in a low-pressure state or
a vacuum state, there was a limitation in removing the particles
fixed by airflow. By contrast, according to an example embodiment,
the charged particles may be removed by applying a charged or a
repulsive force to the charged particles via an electromagnetic
force. In this regard to this, a process for removing the charged
particles will be described with reference to FIGS. 4 and 5.
[0034] FIGS. 4 and 5 are views illustrating a process of removing
charged particles using an extreme exposure system according to an
example embodiment.
[0035] FIG. 4 shows that the electric fields E2 and E4 emitted from
the region in which the second electrodes A2 and A4 are disposed,
through the second regions B2 and B4 of the first mask 320, are
emitted through the first mask 320. The emitted electric fields E2
and E4 may apply an attractive or a repulsive force to the
particles depending on polarities of the charged particles. For
example, a first particle PC1 charged to a negative polarity (-)
may be subjected to a repulsive force F1 by an electric field of a
negative polarity (-). In addition, a second particle PC2 charged
to a positive polarity (+) may be subjected to an attractive force
F2 by an electric field of a negative polarity (-). As a result, as
shown in FIG. 5, the first particle PC1 may move in a direction
away and spaced apart from the upper electrostatic chuck 310, and
may be stacked on a bottom surface BF of the exposure chamber 300.
On the other hand, the second particle PC2 may move in a direction
toward the upper electrostatic chuck 310, and may be attached to
the first mask 320 disposed below the upper electrostatic chuck
310. An example embodiment shows that the second particle PC2 is
attached to the particle collecting layer 313 of the first mask
320.
[0036] Through the process as described above, the charged
particles present in the exposure chamber 300 may be stacked on the
bottom surface BF of the exposure chamber 300, or may be attached
to the first mask 320. Therefore, the particles may be effectively
removed by removing particles stacked on the bottom surface BF of
the exposure chamber 300, or by unloading and discarding the first
mask 320 from the upper electrostatic chuck 310. In some example
embodiments, the first mask 320 may be cleaned using a cleaning
process and reused. In an example embodiment, charged particles may
be stacked on the bottom surface BF of the exposure chamber 300 by
allowing an electric field of the same polarity as that of the
charged particles to transmit through the first mask 320. In
addition, the charged particles may be attached to the first mask
320 by allowing an electric field having a polarity different from
that of the charged particles to transmit through the first mask
320. Therefore, the charged particles may be selectively processed
according to a configuration of a metal thin film pattern 322
formed on the first mask 320.
[0037] The metal thin film pattern 322 of the first mask 320 may be
variously modified. FIGS. 6 to 9B illustrate various modified
examples of the first mask. Like reference numbers are provided for
like elements, and the description below will focus mainly on
differences from the example embodiments described with reference
to FIGS. 1 and 2.
[0038] Referring to FIG. 6, first regions 1322-1 to 1322-4 of a
metal thin film pattern 1322 disposed on a light transmissive
substrate 1321 may be disposed in a region corresponding to first
and second electrodes A1 to A4 of the upper electrostatic chuck
310, and second regions C1, C2, and C3 may be disposed in a region
in which the first electrodes A1 and A3 and the second electrodes
A2 and A4 are in contact with each other. The second regions C1,
C2, and C3 may have a width, and the width may be predetermined. In
some example embodiments, the width may be less than a width of
each of the first and second electrodes. In this case, as compared
to the example embodiment as described with reference to FIGS. 1-5,
since an area of the metal thin film patterns 1322 is increased, a
first mask 1320 may be firmly attached to the upper electrostatic
chuck 310, but it may be more difficult to selectively apply the
attractive or the repulsive force to charged particles depending on
the polarities. While FIG. 6 shows the metal thin film pattern 1322
disposed on the first surface P2, this is only an example, and in
some example embodiments, the metal thin film pattern 1322 may be
formed in the light transmissive substrate 1321.
[0039] Referring to FIG. 7, metal thin film patterns 2322-1 and
2322-2 on a light transmissive substrate 2321 may be disposed such
that first regions D1 and D3 and second regions D2 and D4 are
orthogonal to the first and second regions A1 to A4 of the upper
electrostatic chuck 310. Therefore, the metal thin film patterns
2322-1 and 2322-2 may contact both the first regions A1 and A3 and
the second regions A2 and A4 of the upper electrostatic chuck 310.
In this case, the first mask 2320 may be firmly attached to the
upper electrostatic chuck 310, but it may be more difficult to
selectively apply an attractive or a repulsive force to the charged
particles according to the polarity. While FIG. 7 shows the metal
thin film pattern 2322 disposed on the first surface P2, this is
only an example, and in some example embodiments, the metal thin
film pattern 2322 may be formed in the light transmissive substrate
2321.
[0040] Referring to FIG. 8A, metal thin film patterns 3322-1 to
3322-3 may be disposed to have a pattern as shown in FIG. 8A. Since
an electric field is blocked in a region corresponding to the metal
thin film patterns 3322-1 to 3322-3, a distribution of the electric
field applied to a lower region thereof may be changed according to
disposition of the metal thin film patterns 3322-1 to 3322-3. In
addition, referring to FIG. 8B, in some example embodiments, the
metal thin film patterns 3322-1 to 3322-3 may be disposed in the
light transmissive substrate 3321. It is noted that FIG. 8B shows
an example in which the metal thin film patterns 3322-1 to 3322-3
of FIG. 8A may be formed in the light transmissive substrate 3321.
However, this configuration is not limited to the example
embodiment of FIGS. 8A-8B, and as noted above, this configuration
may be applied to the example embodiments described above with
respect to FIGS. 1-7.
[0041] Referring to FIGS. 9A and 9B, a metal thin film pattern 4322
may have a first region G1 in which a metal thin film is disposed
and a second region G2 from which a metal thin film is omitted or
removed. In addition, the metal thin film pattern 4322 may have a
through portion 4323 penetrating through a light transmissive
substrate 4321 in a region in which the first region G1 and the
second region G2 are in contact with each other. The through
portion 4323 may provide an electric shielding wall to prevent the
electric field emitted through the second region G2 from being
directed below the first region Gl.
[0042] Referring to FIG. 10, a method of manufacturing a
semiconductor device using an extreme exposure system according to
an example embodiment will be described. FIG. 10 is a flowchart
illustrating a method of manufacturing a semiconductor device using
an extreme exposure system according to an example embodiment.
Reference numerals will be described with reference to FIG. 1.
[0043] First, a first mask 320 may be loaded on an upper
electrostatic chuck 310 (S10), power may be applied to the upper
electrostatic chuck 310 through the power supply 400, and thus
charged particles in an exposure chamber 300 may be attracted and
attached to the surface of the first mask 320 (S20).
[0044] Next, the first mask 320 to which the charged particles are
attached may be unloaded from the upper electrostatic chuck 310
(S30). The unloaded first mask 320 may be discarded or reused
through a cleaning process.
[0045] Next, a second mask 360 may be loaded on the upper
electrostatic chuck 310 (S40). The second mask 360 may be used as a
mask for irradiating a pattern on a photoresist applied to a wafer
W in a subsequent process.
[0046] Next, the wafer W may be loaded on a lower electrostatic
chuck 350 (S50), an extreme ultraviolet pattern may be irradiated
onto the photoresist applied to the wafer W, and an exposure
process may be performed (S60). In brief, an exposure process
performed in an exposure chamber 300 will be described. The extreme
ultraviolet light irradiated from a light source 330 may be
incident and reflected by the second mask 360, and may be
irradiated to the wafer W of the lower electrostatic chuck 350
through a projection unit 340. Through this process, the extreme
ultraviolet light may be transferred to the photoresist on which a
pattern of the second mask 360 is applied to the wafer W.
[0047] Next, the wafer W on which exposure is completed may be
unloaded (S70). Subsequently, a process of manufacturing a
semiconductor device using the wafer W on which exposure is
completed may be performed.
[0048] As set forth above, according to an aspect of various
example embodiments, the extreme ultraviolet exposure system may
effectively remove charged particles in the interior of the
exposure chamber.
[0049] The various and advantageous advantages and effects of the
example embodiments are not limited to the above description, and
can be more easily understood in the course of describing a
specific embodiment.
[0050] While example embodiments have been shown and described
above, it will be apparent to those skilled in the art that
modifications and variations may be made without departing from the
scope of the present disclosure as defined by the appended
claims.
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