U.S. patent application number 16/450000 was filed with the patent office on 2020-01-02 for method and apparatus for forming pattern on imprint material.
The applicant listed for this patent is CANON KABUSHIKI KAISHA. Invention is credited to Hiroshi Morohoshi, Hiroshi Sato.
Application Number | 20200004139 16/450000 |
Document ID | / |
Family ID | 69007570 |
Filed Date | 2020-01-02 |
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United States Patent
Application |
20200004139 |
Kind Code |
A1 |
Sato; Hiroshi ; et
al. |
January 2, 2020 |
METHOD AND APPARATUS FOR FORMING PATTERN ON IMPRINT MATERIAL
Abstract
A method for forming a pattern of an imprint material on a shot
region of a substrate by using a mold, includes determining a
plurality of marks for alignment of the shot region and the mold,
performing measurement for the alignment using the plurality of
marks determined in the determining, setting an origin position of
a coordinate system for acquisition of an alignment error between
the shot region and the mold based on an arrangement of the
plurality of marks determined in the determining, and acquiring the
alignment error based on a measurement result in the measurement
and the origin position determined in the setting.
Inventors: |
Sato; Hiroshi;
(Utsunomiya-shi, JP) ; Morohoshi; Hiroshi;
(Utsunomiya-shi, JP) |
|
Applicant: |
Name |
City |
State |
Country |
Type |
CANON KABUSHIKI KAISHA |
Tokyo |
|
JP |
|
|
Family ID: |
69007570 |
Appl. No.: |
16/450000 |
Filed: |
June 24, 2019 |
Current U.S.
Class: |
1/1 |
Current CPC
Class: |
G03F 9/7042 20130101;
G03F 7/0002 20130101 |
International
Class: |
G03F 7/00 20060101
G03F007/00 |
Foreign Application Data
Date |
Code |
Application Number |
Jun 28, 2018 |
JP |
2018-123520 |
Claims
1. A method for forming a pattern of an imprint material on a shot
region of a substrate by using a mold, the method comprising:
determining a plurality of marks for alignment of the shot region
and the mold; performing measurement for the alignment using the
plurality of marks determined in the determining; setting an origin
position of a coordinate system for acquisition of an alignment
error between the shot region and the mold based on an arrangement
of the plurality of marks determined in the determining; and
acquiring the alignment error based on a measurement result in the
measurement and the origin position determined in the setting.
2. The method according to claim 1, further comprising transferring
a pattern of the mold onto an imprint material on the shot region
upon performing alignment of the shot region and the mold based on
the alignment error acquired in the acquiring.
3. The method according to claim 1, wherein in the setting, the
origin position is set such that the origin position is arranged
inside a figure defined by vertices thereof which are positions of
the plurality of marks.
4. The method according to claim 1, wherein the number of the
plurality of marks is at least three.
5. The method according to claim 1, wherein in the setting, the
origin position is determined such that distances between the
plurality of marks and the origin position are equalized within an
allowable range.
6. The method according to claim 1, wherein in the setting, the
origin position is determined such that the origin position
coincides with, within an allowable range, a center of gravity of a
figure defined by vertices thereof which are the positions of the
plurality of marks.
7. The method according to claim 1, wherein the alignment error
acquired in the acquiring includes at least one ofa shift
component, a magnification component, a rotation component, a
trapezoid component, and a skew component.
8. The method according to claim 1, further comprising determining
at least one component to be acquired as the alignment error among
a plurality of components.
9. The method according to claim 1, wherein the substrate includes
a first shot region having a rectangular shape and a second shot
region smaller than the first shot region and having a shape
defined by edges of the substrate, and in the determining, the
plurality of marks for the first shot region and the plurality of
marks for the second shot region are selected such that a relative
position between the plurality of marks selected for the first shot
region differs from a relative position between the plurality of
marks selected for the second shot region.
10. The method according to claim 9, wherein an area of a figure
defined by vertices thereof which are positions of the plurality of
marks selected for the second shot region is smaller than an area
of a figure defined by vertices thereof which are positions of the
plurality of marks selected as vertices for the first shot region
in the determining.
11. A method for forming a pattern of an imprint material on a
plurality of shot regions of a substrate by using a mold, the
method comprising: performing measurement for alignment of the mold
and a shot region selected from the plurality of shot regions;
setting an origin position of a coordinate system for acquisition
of an alignment error between the selected shot region and the mold
based on the selected shot region; and acquiring the alignment
error based on a measurement result obtained in the measurement and
an origin position determined in the setting.
12. An imprint apparatus for forming a pattern of an imprint
material on a shot region of a substrate by using a mold, the
apparatus comprising: a measurement device configured to perform
measurement for alignment of the shot region and the mold; and a
controller configured to cause the measurement device to perform
the measurement with respect to a plurality of marks for alignment
of the shot region and the mold, acquire an alignment error between
the shot region and the mold based on the measurement result, and
control the alignment based on the alignment error, wherein the
controller determines an origin position of a coordinate system for
acquisition of an alignment error between the shot region and the
mold based on an arrangement of the plurality of marks for
alignment of the shot region and the mold.
13. A method of adjusting an imprint apparatus defined in claim 12,
the method comprising: performing imprinting to form a second
pattern on a first pattern on a first substrate by using the
imprint apparatus and the mold; measuring an overlay error between
the first pattern and the second pattern by using an overlay
inspection apparatus; acquiring a first correction value based on
an overlay error obtained in the measuring by using a first origin
position as an origin position of a coordinate system for
acquisition of an alignment error; determining, based on an
arrangement of a plurality of marks for alignment of a shot region
of a second substrate and the mold which are processed in the
imprint apparatus, a second origin position as an origin position
of a coordinate system for acquisition of an alignment error
between the shot region of the second substrate and the mold;
converting the first correction value into a second correction
value based on the second origin position; and setting an offset
value corresponding to the second correction value in the imprint
apparatus.
14. An imprint apparatus for forming a pattern of an imprint
material on a plurality of shot regions of a substrate by using a
mold, the apparatus comprising: a measurement device configured to
perform measurement for alignment of a shot region selected from
the plurality of shot regions and the mold; and a controller
configured to cause the measurement device to perform the
measurement with respect to a plurality of marks for alignment of
the selected shot region and the mold, acquire an alignment error
between the selected shot region and the mold based on the
measurement result, and control the alignment based on the
alignment error, wherein the controller determines an origin
position of a coordinate system for acquisition of an alignment
error between the selected shot region and the mold based on the
selected shot region.
15. A method of adjusting an imprint apparatus defined in claim 14,
the method comprising: performing imprinting to form a second
pattern on a first pattern on a first substrate by using the
imprint apparatus and the mold; measuring an overlay error between
the first pattern and the second pattern by using an overlay
inspection apparatus; acquiring a first correction value based on
an overlay error obtained in the measuring by using a first origin
position as an origin position of a coordinate system for
acquisition of an alignment error; determining, based on a shot
region selected from a plurality of shot regions of a second
substrate which is processed in the imprint apparatus, a second
origin position as an origin position of a coordinate system for
acquisition of an alignment error between the mold and the selected
shot region of the second substrate; converting the first
correction value into a second correction value based on the second
origin position; and setting an offset value corresponding to the
second correction value in the imprint apparatus.
16. A method for manufacturing an article from a processed
substrate, the method comprising: forming a pattern on the
substrate by using an imprint apparatus defined in claim 12; and
processing the substrate on which the pattern is formed in the
forming.
17. A method for manufacturing an article from a processed
substrate, the method comprising: forming a pattern on the
substrate by using an imprint apparatus defined in claim 14; and
processing the substrate on which the pattern is formed in the
forming.
Description
BACKGROUND OF THE INVENTION
Field of the Invention
[0001] The present invention relates to a method of forming a
pattern of an imprint material, an imprint apparatus, a method of
adjusting the imprint apparatus, and a method of manufacturing an
article.
Description of the Related Art
[0002] As a new technique for manufacturing articles such as
semiconductor devices, an imprint technique for forming a pattern
of an imprint material on a plurality of shot regions of a
substrate by using a mold has begun to be used. In the imprint
technique, in order to improve the alignment accuracy between a
shot region of a substrate and a pattern region of a mold, an
alignment error as a difference between the shape of the shot
region and the shape of the pattern region can be detected by using
marks provided for the shot region and the pattern region. When
there is a difference in shape between the shot region and the
pattern region, the difference can be reduced by changing at least
one of the shot region and the pattern region based on the
difference (Japanese Patent Laid-Open No. 2016-143838). An
alignment error can be decomposed into a plurality of components
such as a shift component, magnification component, rotation
component, trapezoid component, and skew component.
[0003] Shot regions on a substrate can have different geometric
characteristics in accordance with the positions of the shot
regions. For example, a plurality of shot regions arranged on a
substrate can include a shot region having a rectangular shape
(full shot region) and a shot region defined by an edge of the
substrate (partial shot region). A full shot region and a partial
shot region can differ in the positions and layouts of a plurality
of marks used to detect an alignment error. In addition, even a
full shot region is sometimes aligned by using marks at positions
different from planned positions or a smaller number of marks than
planned because of defective marks. As described above, the
positions and layout of marks used for detecting an alignment error
can differ for each shot region.
SUMMARY OF THE INVENTION
[0004] The present inventor has thought that an alignment error can
be properly corrected by acquiring alignment error components with
reference to the central position of a shot region as the origin
position regardless of the positions and layout of a plurality of
marks used to detect alignment errors. However, the present
inventor has found out, as a result of studies, that such a
acquisition method is not preferable.
[0005] The present invention provides a technique advantageous in
properly correcting an alignment error.
[0006] One of aspects of the present invention provides a method
for forming a pattern of an imprint material on a shot region of a
substrate by using a mold, the method comprising: determining a
plurality of marks for alignment of the shot region and the mold;
performing measurement for the alignment using the plurality of
marks determined in the determining; setting an origin position of
a coordinate system for acquisition of an alignment error between
the shot region and the mold based on an arrangement of the
plurality of marks determined in the determining; and acquiring the
alignment error based on a measurement result in the measurement
and the origin position determined in the setting.
[0007] Further features of the present invention will become
apparent from the following description of exemplary embodiments
with reference to the attached drawings.
BRIEF DESCRIPTION OF THE DRAWINGS
[0008] FIG. 1 is a view showing the arrangement of an imprint
apparatus according to the first embodiment of the present
invention;
[0009] FIGS. 2A to 2D are views for explaining the principle of
detecting the relative position between two marks by using a moire
pattern;
[0010] FIGS. 3A to 3C are views each exemplarily showing the
positional relationship between alignment scopes, a shot region of
a substrate, marks on the substrate, and marks on a mold at the
time of detection of an alignment error;
[0011] FIG. 4 is a view exemplarily showing the arrangement of a
deformation mechanism;
[0012] FIGS. 5A and 5B are views for explaining the origin position
of a coordinate system for computing an alignment error;
[0013] FIG. 6 is a flowchart showing an operation for pattern
formation for one shot region;
[0014] FIGS. 7A to 7D are views for exemplarily explaining rules
for specifying alignment error components;
[0015] FIG. 8 is a view for explaining a comparative example;
[0016] FIG. 9 is a view exemplarily showing the distribution of an
alignment error according to the second embodiment of the present
invention;
[0017] FIGS. 10A and 10B are block diagrams for explaining the
third embodiment of the present invention;
[0018] FIG. 11 is a flowchart showing procedures in an adjustment
method according to the third embodiment of the present
invention;
[0019] FIGS. 12A to 12F are sectional views exemplarily showing a
method of manufacturing an article; and
[0020] FIGS. 13A to 13D are sectional views exemplarily showing a
method of manufacturing an article.
DESCRIPTION OF THE EMBODIMENTS
[0021] The present invention will be described below through
exemplary embodiments with reference to the accompanying
drawings.
[0022] FIG. 1 shows the arrangement of an imprint apparatus 100
according to the first embodiment of the present invention. The
imprint apparatus 100 is configured to form a pattern formed from a
cured product of an imprint material IM on a plurality of shot
regions of a substrate S by an imprint process. An imprint process
is a process of forming a pattern formed from a cured product of
the imprint material IM on a plurality of shot regions of the
substrate S by using a mold M. An imprint process can include, for
example, a contact process, alignment process, curing process, and
separation process. A contact process is a process of bringing a
pattern region PR of the mold M into contact with an imprint
material IM on a shot region of the substrate S. An alignment
process is a process of aligning a shot region of the substrate S
with the pattern region PR of the mold M. An alignment process in
an imprint process can include a deformation process of deforming
at least one of the pattern region PR of the mold M and a shot
region of the substrate S so as to reduce the overlay error between
the shot region of the substrate S and the pattern region PR of the
mold M. A curing process is a process of curing the imprint
material IM. A separation process is a process of separating a
pattern formed from a cured product of the imprint material IM from
the pattern region PR of the mold M.
[0023] As an imprint material, a curable composition (to be also
referred to a resin in an uncured state) to be cured by receiving
the curing energy is used. Examples of the curing energy are an
electromagnetic wave, heat, and the like. The electromagnetic wave
is, for example, light selected from the wavelength range of 10 nm
(inclusive) to 1 mm (inclusive). Examples of the electromagnetic
wave can be infrared light, a visible light beam, and ultraviolet
light. The curable composition can be a composition cured with
light irradiation or heating. Among these compositions, the
photo-curable composition cured by light irradiation contains at
least a polymerizable composition and a photopolymerization
initiator, and may further contain a nonpolymerizable compound or a
solvent, as needed. The nonpolymerizable compound is at least one
material selected from the group consisting of a sensitizer, a
hydrogen donor, an internal mold release agent, a surfactant, an
antioxidant, and a polymer component. The imprint material can be
arranged on the substrate in the form of droplets or in the form of
an island or film obtained by connecting a plurality of droplets
supplied by the imprint material supplier. The viscosity (the
viscosity at 25.degree. C.) of the imprint material is, for
example, 1 mPa-s (inclusive) to 100 mPas (inclusive). Examples of
the substrate material can be glass, a ceramic, a metal, a
semiconductor, a resin, and the like. A member made of a material
different from the substrate may be formed on the surface of the
substrate, as needed. Examples of the substrate are a silicon
wafer, a compound semiconductor wafer, and silica glass.
[0024] In the specification and the accompanying drawings,
directions will be indicated by an XYZ coordinate system in which
directions parallel to the surface of the substrate S are set as
the X-Y plane. Assume that directions parallel to the X-axis, the
Y-axis, and the Z-axis of the XYZ coordinate system are the X
direction, the Y direction, and the Z direction, respectively.
Assume that a rotation about the X-axis, a rotation about the
Y-axis, and a rotation about the Z-axis are .theta.X, .theta.Y, and
.theta.Z, respectively. Control operations or driving operations
related to the X-axis, the Y-axis, and the Z-axis represent control
operations or driving operations related to a direction parallel to
the X-axis, a direction parallel to the Y-axis, and a direction
parallel to the Z-axis, respectively. In addition, control
operations or driving operations related to the .theta.X-axis, the
.theta.Y-axis, and the .theta.Z-axis indicate control operations or
driving operations related to a rotation about an axis parallel to
the X-axis, a rotation about an axis parallel to the Y-axis, and a
rotation about an axis parallel to the Z-axis, respectively. In
addition, a position is information that can be specified based on
coordinates on the X-, Y-, and Z-axes, and an orientation is
information that can be specified by values on the .theta.X-,
.theta.Y-, and .theta.Z-axes. Positioning indicates control of the
position and/or orientation. Alignment (positioning) or an
alignment process can include control of the position and/or
orientation of at least one of the substrate and the mold.
[0025] The imprint apparatus 100 can include a substrate driving
mechanism SDM for holding and driving the substrate S, a base frame
BF for supporting the substrate driving mechanism SDM, a mold
driving mechanism MDM for holding and driving the mold M, and a
structure ST for holding the mold driving mechanism MDM. The
substrate driving mechanism SDM can include a substrate stage SS
including a substrate chuck SC for holding the substrate S and a
substrate positioning mechanism SA for positioning the substrate S
by positioning the substrate stage SS. The mold driving mechanism
MDM can include a mold chuck MC for holding the mold M and a mold
positioning mechanism MA for positioning the mold M by positioning
the mold chuck MC. The mold driving mechanism MDM may include a
load cell LC for detecting the force exerted on the mold M in a
contact process and/or a separation process. The mold driving
mechanism MDM can further include a pressure mechanism for applying
a pressure on a surface on the opposite side to the pattern region
PR of the mold M so as to deform the pattern region PR into a
convex shape toward the substrate S.
[0026] The substrate driving mechanism SDM and the mold driving
mechanism MDM constitute a driving mechanism DM for driving at
least one of the substrate S and the mold M so as to change the
relative position between the substrate S and the mold M. Changing
the relative position by using the driving mechanism DM includes
driving for bringing the pattern region PR of the mold M into
contact with the imprint material IM on the substrate S and
separating the mold M from the cured imprint material (the pattern
of the cured product). In other words, changing the relative
position by using the driving mechanism DM includes changing the
relative position between the substrate S and the mold M so as to
perform a contact process and a separation process. The substrate
driving mechanism SDM can be configured to drive the substrate S
with respect to a plurality of axes (for example, three axes
including the X-axis, Y-axis, and .theta.Z-axis, and preferably six
axes including the X-axis, Y-axis, Z-axis, .theta.X-axis,
.theta.Y-axis, and .theta.Z-axis). The mold driving mechanism MDM
can be configured to drive the mold M with respect to a plurality
of axes (for example, three axes including the Z-axis,
.theta.X-axis, and .theta.Y-axis, and preferably six axes including
the X-axis, Y-axis, Z-axis, .theta.X-axis, .theta.Y-axis, and
.theta.Z-axis).
[0027] The imprint apparatus 100 can further include a deformation
mechanism MAG that deforms the pattern region PR of the mold M. The
deformation mechanism MAG can deform the pattern region PR so as to
change the shape (including the size) of the pattern region PR
within a plane parallel to an X-Y plane. The deformation mechanism
MAG can deform the pattern region PR by applying forces to the four
side surfaces of the mold M. The imprint apparatus 100 can further
include a shot region deformation unit SRD that deforms a shot
region of the substrate S. The shot region deformation unit SRD can
deform a shot region so as to change the shape (including the size)
of the shot region within a plane parallel to an X-Y plane. The
shot region deformation unit SRD can deform a shot region of the
substrate S by forming a temperature distribution on the substrate
S. A temperature distribution can be formed by irradiating the
substrate S with light having a wavelength that does not cure an
imprint material and is selected from the wavelength range of
ultraviolet light or the wavelength range of visible light.
[0028] The imprint apparatus 100 can include a dispenser DSP. The
dispenser DSP may be configured as an external apparatus of the
imprint apparatus 100. The dispenser DSP arranges the imprint
material IM on a shot region of the substrate S. The imprint
material IM can be arranged on a shot region of the substrate S,
while the substrate S is driven by the substrate driving mechanism
SDM, by causing the dispenser DSP to discharge the imprint material
IM in synchronism with the driving. In this case, every time the
dispenser DSP arranges the imprint material IM on one shot region
on the substrate S, a contact process, alignment process, curing
process, and separation process can be executed. Alternatively,
after the dispenser DSP arranges the imprint material IM on a
plurality of shot regions on the substrate S, a contact process,
alignment process, curing process, and separation process may be
executed for each of the plurality of shot regions.
[0029] The imprint apparatus 100 can further include a curing unit
CU. The curing unit CU cures the imprint material IM by irradiating
the imprint material IM with curing energy while the pattern region
PR of the mold M is in contact with the imprint material IM on the
substrate S. This forms a pattern formed from a cured product of
the imprint material IM on the substrate S.
[0030] The imprint apparatus 100 can include an alignment detection
system (measurement device) AS that detects (measures) the
positions of marks SMK on a shot region of the substrate S, the
positions of marks MMK on the mold M, the relative positions
between the marks SMK on the shot region of the substrate S and the
marks MMK on the mold M, and the like. The alignment detection
system AS can detect the relative positions between the marks SMK
on a shot region of the substrate S and the marks MMK on the mold M
based on, for example, the moire pattern formed by the marks SMK on
a shot region of the substrate S and the marks MMK on the mold M.
The imprint apparatus 100 can include an off-axis scope OAS that
detects (measures) the position of the mark SMK on a shot region of
the substrate S.
[0031] The imprint apparatus 100 can further include a controller
CNT. The controller CNT can control the driving mechanism DM, the
deformation mechanism MAG, the shot region deformation unit SRD,
the dispenser DSP, the curing unit CU, the alignment detection
system AS, and the off-axis scope OAS. The controller CNT can be
formed from, for example, a PLD (the abbreviation of a Programmable
Logic Device) such as an FPGA (the abbreviation of a Field
Programmable Gate Array), an ASIC (the abbreviation of an
Application Specific Integrated Circuit), a general purpose
computer embedded with a program, or a combination of all or some
of these components.
[0032] The controller CNT can compute the overlay error between a
shot region of the substrate S and the pattern region PR of the
mold M based on the detection results obtained by the alignment
detection system AS, for example, the relative positions between
the marks SMK on the substrate S and the marks MMK on the mold M.
In other words, the controller CNT can compute the alignment error
between the shot region of the substrate S and the pattern region
PR of the mold M based on outputs from the alignment detection
system AS. An alignment error is a concept including an overlay
error. An alignment error or overlay error can include, for
example, a plurality of components (for example, a shift component,
magnification component, rotation component, trapezoid component,
and skew component).
[0033] The principle of detecting a relative position which can be
applied to the alignment detection system AS, more specifically,
the principle of detecting (measuring) the relative position
between two marks by using a moire pattern will be described with
reference to FIGS. 2A to 2D. FIGS. 2A and 2B show two types of
grating marks with different pitches. One of the two types of
grating marks is the mark SMK on the substrate S, and the other is
the mark MMK on the mold M. Overlaying these grating marks on each
other will generate a bright and dark stripe pattern like that
shown in FIG. 2C. This stipe pattern is a moire pattern. The
positions of the bright fringes and dark fringes of a moire pattern
change depending on the relative position between the two types of
grating marks. For example, when one of the two types of grating
marks is slightly moved to the right, the moire pattern shown in
FIG. 2C changes to a moire pattern like that shown in FIG. 2D. This
moire pattern is generated as large bright and dark fringes with an
increased shift amount between the two types of grating marks, and
hence allows even the alignment detection system AS with low
resolution to accurately detect the relative positional
relationship between the two types of grating marks. The alignment
detection system AS can detect the relative position between the
mark SMK on the substrate S and the mark MMK on the mold M (its
pattern region PR) based on such a principle.
[0034] The above has exemplified the case of detecting the relative
position between the mark SMK on a shot region of the substrate S
and the mark MMK on the mold M by using a moire pattern. However,
this is merely an example. The alignment detection system AS may
detect the relative position between the mark SMK on a shot region
of the substrate S and the mark MMK on the mold M in accordance
with another principle or method. For example, the alignment
detection system AS may detect the relative position between the
mark SMK on a shot region of the substrate S and the mark MMK on
the mold M based on the position of an image of the mark SMK in a
visual field and the position of an image of the mark MMK in the
visual field. Alternatively, the alignment detection system AS may
detect the relative position between the mark SMK on a shot region
of the substrate S and the mark MMK on the mold M based on the
relative position between an image of the mark SMK in a visual
field and an image of the mark MMK in a visual field.
[0035] FIGS. 3A to 3C exemplarily show the positional relationship
between the alignment system AS, a shot region SR of the substrate
S, the marks (substrate-side marks) SMK on the substrate S, and the
marks (mold-side marks) MMK on the mold M. FIG. 3A shows how an
alignment error concerning a full shot region is detected. FIG. 3C
shows how an alignment error concerning a partial shot region is
detected. FIG. 3B is a reference figure for explaining differences
between a full shot region and a partial shot region. A full shot
region (first shot region) is the shot region SR having a
rectangular shape. A full shot region has the same shape as that of
the pattern region PR on the mold M. A partial shot region (second
shot region) is the shot region SR whose shape is defined by edges
of the substrate S. A full shot region (first shot region) includes
the first count of chip regions, and a partial shot region (second
shot region) includes the second count of chip regions smaller than
the first count. FIGS. 3A to 3C show both a full shot region and a
partial shot region as shot regions SR.
[0036] In this case, a full shot region includes six chip regions
CR-1, CR-2, CR-3, CR-4, CR-5, and CR-6. In contrast to this, a
partial shot region includes only a chip region or chip regions of
the six chip regions CR-1, CR-2, CR-3, CR-4, CR-5, and CR-6 which
falls or fall inside the effective region of the substrate S. In
the case shown in FIGS. 3B and 3C, the partial shot region includes
only the chip region CR-5. Although FIGS. 3B and 3C each show all
the chip regions CR-1, CR-2, CR-3, CR-4, CR-5, and CR-6, this is
for convenience sake only. Referring to FIGS. 3B and 3C, partial
shot region of the substrate S actually includes only the chip
region CR-5. Note that the effective region of the substrate S is a
region of the entire principal surface of the substrate S which
allows the formation of a pattern. Referring to FIGS. 3A to 3C,
each mark SMK on the substrate S and each mark MMK on the mold M
are indicated by small rectangles. Of these rectangles, the solid
black rectangles are the marks SMK and MMK that enable the
detection of a relative position. In contrast to this, the hollow
rectangles are the marks MMK by which the detection of the relative
position with respect to the marks SMK is not possible because the
marks SMK on the substrate S side do not actually exist.
[0037] In the cases shown in FIGS. 3A to 3C, the alignment
detection system AS includes eight alignment scopes AS-1 to AS-8.
The eight alignment scopes AS-1 to AS-8 are configured to detect
the relative positions between the marks SMK on the substrate S and
the corresponding marks MMK on the mold M. In this case, the
alignment scopes AS-1, AS-2, AS-5, and AS-6 detect the relative
positions between the marks SMK and the marks MMK in the X
direction. The alignment scopes AS-3, AS-4, AS-7, and AS-8 detect
the relative positions between the marks SMK and the marks MMK in
the Y direction.
[0038] FIG. 4 shows an example of the arrangement of the
deformation mechanism MAG. The deformation mechanism MAG can
include, for example, a plurality of force applying units 40 that
apply a force to side surfaces of the mold M. Each force applying
unit 40 can include a suction unit 41 that sucks a side surface of
the mold M and an actuator 42 that presses the suction unit 41
against a side surface of the mold M and moves the suction unit 41
away from the side surface of the mold M. The controller CNT
acquires the relationship between command values given to the
actuator 42 and the deformation amounts of the mold M in advance,
and then sends, to the actuator 42, the command value determined
based on the relationship and the required deformation amount
determined based on the measurement result obtained by the
alignment detection system AS. The deformation mechanism MAG can
correct (reduce), for example, a magnification component, trapezoid
component, and skew component of a plurality of components
constituting the alignment error (overlay error) between the shot
region SR and the pattern region PR.
[0039] When an alignment error is to be detected with respect to a
full shot region, as exemplarily shown in FIG. 3A, eight mark pairs
are used, out of a plurality of mark pairs (marks SMK and MMK)
provided for the full shot region, which are arranged as outward as
possible. In this case, the alignment scopes AS-1 to AS-8 can be
respectively positioned at positions respectively corresponding to
the eight mark pairs.
[0040] However, the alignment scopes AS-1 to AS-8 arranged in this
manner cannot detect any alignment error with respect to a partial
shot region. For example, in the case shown in FIG. 3B, only the
alignment scopes AS-6 and AS-7 can detect the relative position
between the marks SMK and MMK. Accordingly, when an alignment error
is to be detected with respect to a partial shot region, as
exemplarily shown in FIG. 3C, a plurality of mark pairs (marks SMK
and MMK) provided for the effective chip region CR-5 or its
adjacent chip region, for example, eight mark pairs can be used. In
this case, the alignment scopes AS-1 to AS-8 can be positioned at
positions respectively corresponding to the eight mark pairs.
[0041] The controller CNT computes the alignment error between the
shot region SR and the pattern region PR based on the relative
positions between the respective mark pairs SMK and MMK detected by
using the alignment detection system AS (alignment scopes AS-1 to
AS-8). In this alignment error computation, the origin position of
the coordinate system needs to be determined.
[0042] In a comparative example, in both a full shot region and a
partial shot region, the center of a pattern region is set as the
origin position of a coordinate system for the computation
(acquisition) of an alignment error. In this case, there is no
problem in setting the center of the pattern region PR as the
origin position of the coordinate system for the computation of an
alignment error with respect to a full shot region. However, there
is a problem in setting the center of the pattern region PR as the
origin position of the coordinate system for the computation of an
alignment error with respect to a partial shot region. Although the
center of the full shot region coincides with the center of the
pattern region PR, the center of the partial shot region does not
coincide with the center of the pattern region PR because the
partial shot region is smaller than the full shot region (or the
pattern region PR).
[0043] The following will describe, with reference to FIG. 5A, a
problem in setting the center of the pattern region PR as the
origin position of the coordinate system for the computation of an
alignment error with respect to a partial shot region.
[0044] FIG. 5A exemplarily shows a partial shot region wherein only
the chip region CR-2 of the chip regions CR-1 to CR-6 falls inside
the effective region of the substrate S. The black circles indicate
the positions of the marks MMK on the pattern region PR which
correspond to the marks SMK located at the four corners of the chip
region CR-2. The black triangles indicate the actual positions of
the marks SMK located at the four corners of the chip region CR-2.
Assume that in this case, the alignment detection system AS detects
the relative positions between the positions of the black circles
and the black triangles. For the sake of simplicity, assume that
the marks MMK on the mold M have no error, and the positions of the
marks MMK coincide with the design positions.
[0045] Let (x.sub.1, y.sub.1) be the position of the mark MMK on
the pattern region PR which corresponds to the mark SMK located at
the upper right of the chip region CR-2, (x.sub.2, y.sub.2) be the
position of the mark MMK on the pattern region PR which corresponds
to the mark SMK located at the lower right of the chip region CR-2,
(x.sub.3, y.sub.3) be the position of the mark MMK on the pattern
region PR which corresponds to the mark SMK located at the lower
left of the chip region CR-2, and (x.sub.4, y.sub.4) be the
position of the mark MMK on the pattern region PR which corresponds
to the mark SMK located at the upper left of the chip region
CR-2.
[0046] Let (.DELTA.x.sub.1, .DELTA.y.sub.1) be the shift amount
(alignment error) of the position of the mark SMK at the upper
right with respect to (x.sub.1, y.sub.1). If (.DELTA.x.sub.1,
.DELTA.y.sub.1) is defined as the sum of shift components,
magnification components, rotation components, and trapezoid
components, (.DELTA.x.sub.1, .DELTA.y.sub.1) is expressed as
equations (1) given below:
.DELTA.x.sub.1=Sx+Mxx.sub.1+rot.theta.xy.sub.1+Txx.sub.1y.sub.1
.DELTA.y.sub.1=Sy+Myy.sub.1+rot.theta.yx.sub.1+Tyx.sub.1y.sub.1
where Sx and Sy are shift components, Mx and My are magnification
components, rot.theta.x and rot.theta.y are rotation components,
and Tx and Ty are trapezoid components. Although the alignment
error can include skew components and higher-order components,
consider, for the sake of simplicity, shift components,
magnification components, rotation components, and trapezoid
components which have larger influences.
[0047] Likewise, the following equations (2) are defined with
respect to the marks arranged at other positions.
.DELTA.x.sub.2=Sx+Mxx.sub.2+rot.theta.xy.sub.2+Txx.sub.2y.sub.2
.DELTA.y.sub.2=Sy+Myy.sub.2+rot.theta.yx.sub.2+Tyx.sub.2y.sub.2
.DELTA.x.sub.3=Sx+Mxx.sub.3+rot.theta.xy.sub.3+Txx.sub.3y.sub.3
.DELTA.y.sub.3=Sy+Myy.sub.3+rot.theta.yx.sub.3+Tyx.sub.3y.sub.3
.DELTA.x.sub.4=Sx+Mxx.sub.4+rot.theta.xy.sub.4+Txx.sub.4y.sub.4
.DELTA.y.sub.4=Sy+Myy.sub.4+rot.theta.yx.sub.4+Tyx.sub.4y.sub.4
(2)
[0048] In order to provide a specific example, the size of a full
shot region is defined as 4a.times.6a. In this case, the positions
of the marks MMK on the pattern region are expressed as equations
(3) given below:
(x.sub.1,y.sub.1)=(2a,3a)
(x.sub.2,y.sub.2)=(2a,a)
(x.sub.3,y.sub.3)=(0,a)
(x.sub.4,y.sub.4)=(0,3a) (3)
[0049] For the sake of simplicity, consider only an alignment error
in the X direction, that is, equations (4) given below:
.DELTA.x.sub.1=Sx+2aMx+3arot.theta.x+6a.sup.2Tx
.DELTA.x.sub.2=Sx+2aMx+arot.theta.x+2a.sup.2Tx
.DELTA.x.sub.3=Sx+arot.theta.x
.DELTA.x.sub.4=Sx+3arot.theta.x (4)
[0050] When this alignment error is solved with respect to each
component, equations (5) given below are established:
Sx=1/2(3.DELTA.x.sub.3-.DELTA.x.sub.4)
Mx=1/4a(-.DELTA.x.sub.1+3.DELTA.x.sub.2-3.DELTA.x.sub.3+.DELTA.x.sub.4)
Rot.theta.x=1/2a(-.DELTA.x.sub.3+.DELTA.x.sub.4)
Tx=1/4a.sup.2(.DELTA.x.sub.1-.DELTA.x.sub.2+.DELTA.x.sub.3-.DELTA.x.sub.-
4) (5)
[0051] Consider, for example, Sx and Rot.theta.x. In this case,
although the relative positions between four mark pairs are
detected, only the relative positions between two mark pairs of the
four mark pairs are reflected in Sx and Rot.theta.x. In addition,
consider Mx. In this case, coefficients are applied to detection
results on the relative positions between four mark pairs. It is,
therefore, obvious that the detection results on the relative
positions between the four mark pairs with respect to Mx differ in
influence. Accordingly, when detection results on the relative
positions between a plurality of mark pairs include an error, a
sufficient averaging effect cannot be obtained in spite of the fact
that the relative positions between a plurality of mark pairs are
detected. In addition, a computation result will place a
disproportionate emphasis on detection results on some mark
pairs.
[0052] Accordingly, in this embodiment, the controller CNT uses a
plurality of marks on the chip region CR-2 of the partial shot
region which falls inside the effective region of the substrate S
for the detection of an alignment error. The controller CNT
determines the origin position of the coordinate system for the
computation of an alignment error based on the arrangement of the
plurality of marks. On the other hand, with respect to a full shot
region, the controller CNT uses the marks on the four corners (that
is, the four mark pairs) to detect an alignment error, and
determines the origin position of the coordinate system for the
computation of an alignment error based on the arrangement of the
four mark pairs.
[0053] In other words, the controller CNT uses different marks
(mark pairs) for the detection of an alignment error between a
partial shot region and a full shot region. However, the controller
CNT determines the origin position of the coordinate system for the
computation of an alignment error in accordance with a plurality of
marks (mark pairs) used for the detection of an alignment error
with respect to both a partial shot region and a full shot
region.
[0054] In an example, the controller CNT determines the center of a
plurality of marks (mark pairs) used for the detection of an
alignment error as the origin position of the coordinate system for
the computation of an alignment error in both a partial shot region
and a full shot region. The center of a plurality of marks (mark
pairs) can be, for example, the center of a figure defined by
vertices thereof which are positions of the plurality of marks
(mark pairs). In this case, the area of a figure defined by
vertices thereof which are positions of a plurality of marks
selected for a partial shot region is smaller than the area of a
figure defined by vertices thereof which are positions of a
plurality of marks selected for a full shot region.
[0055] Alternatively, the controller CNT can determine the origin
position of the coordinate system for the computation of an
alignment error such that the origin position is located inside the
above figure with respect to both a partial shot region and a full
shot region depending on allowable accuracy for the correction of
an alignment error. The number of the plurality of marks (mark
pairs) can be at least three.
[0056] In another aspect, the controller CNT can determine an
origin position such that the distances between the origin position
and a plurality of marks (mark pairs) used to detect an alignment
error are equal to each other within an allowable accuracy
(allowable range) with respect to both a partial shot region and a
full shot region. Alternatively, the controller CNT can determine
an origin position such that the origin position coincides with the
center of gravity of a figure defined by vertices thereof which are
positions of a plurality of marks (mark pairs) used for the
detection of an alignment error with respect to both a partial shot
region and a full shot region.
[0057] In still another aspect, the controller CNT may be
configured to determine an origin position in accordance with shot
regions (a partial shot region and a full shot region). For
example, this determination can be performed based on a table
including information designating shot regions and corresponding
origin positions.
[0058] FIG. 5B shows a case in which an origin position is
determined such that the distances between the origin position and
a plurality of marks (mark pairs) used to detect an alignment error
are equal to each other with respect to a partial shot region.
[0059] When such an origin position is determined, positions
(x.sub.1, y.sub.1), (x.sub.2, y.sub.2), (x.sub.3, y.sub.3), and
(x.sub.4, y.sub.4) of the marks MMK on the pattern region PR which
correspond to the mark SMK at the upper left of the chip region
CR-2 are respectively expressed as equations (6) given below:
(x.sub.1,y.sub.1)=(a,a)
(x.sub.2,y.sub.2)=(a,-a)
(x.sub.3,y.sub.3)=(-a,-a)
(x.sub.4,y.sub.4)=(-a,a) (6)
[0060] Therefore, .DELTA.x.sub.1, .DELTA.x.sub.2, .DELTA.x.sub.3,
and .DELTA.x.sub.4 are expressed as equations (7) given below:
.DELTA.x.sub.1=Sx+aMx+arot.theta.x+a.sup.2Tx
.DELTA.x.sub.2=Sx+aMx-a-rot.theta.x-a.sup.2Tx
.DELTA.x.sub.3=Sx-aMx-a-rot.theta.x+a.sup.2Tx
.DELTA.x.sub.4=Sx-aMx+a-rot.theta.x-a.sup.2Tx (7)
[0061] Solving this alignment error with respect to the respective
components will provide equations (8) given below:
Sx=1/4(.DELTA.x.sub.1+.DELTA.x.sub.2+.DELTA.x.sub.3+.DELTA.x.sub.4)
Mx=1/4a(.DELTA.x.sub.1+.DELTA.x.sub.2-.DELTA.x.sub.3-.DELTA.x.sub.4)
Rot.theta.x=1/4a(.DELTA.x.sub.1-.DELTA.x.sub.2-.DELTA.x.sub.3+.DELTA.x.s-
ub.4)
Tx=1/4a.sup.2(.DELTA.x.sub.1-.DELTA.x.sub.2+.DELTA.x.sub.3-.DELTA.x.sub.-
4) (8)
[0062] The components Sx, Mx, Rot.theta.x, and Tx each are included
in the alignment error with similar degrees of sensitivity at the
relative positions between the four mark pairs. Accordingly,
averaging detection results on the relative positions between a
plurality of mark pairs will provide an effect of reducing an error
included in a computation result on an alignment error.
[0063] This embodiment is useful when the area (size) of a region
on which a pattern is formed by one imprint process differs among a
plurality of shot regions. However, the embodiment can also be
applied to a case in which the area (size) of a region on which a
pattern is formed by one imprint process remains the same among a
plurality of shot regions. For example, when the arrangement (the
positions and/or the number) of a plurality of marks used for the
detection of an alignment error differs in accordance with shot
regions, the origin position of the coordinate system can be
changed in accordance with the arrangement of the plurality of
marks. When, for example, an abnormal mark is formed on a substrate
in a previous step, the mark can sometimes be excluded from marks
as detection targets. In such a case, the origin position of the
coordinate system can be changed in accordance with the arrangement
of a plurality of marks as final detection targets.
[0064] When the controller CNT determines an origin position
regardless of user's intention, the controller CNT can arrange the
origin position at an unintended position. Accordingly, this
apparatus may be provided with a setting function of validating or
invalidating a function of causing the controller CNT to determine
an origin position. In addition, when the controller CNT determines
an origin position, the apparatus may be provided with a limiting
function of limiting a region in which an origin position can be
arranged. Such setting function and limiting function can be
provided by a user interface UI that communicates with the
controller CNT, as exemplarily shown in FIG. 1.
[0065] FIG. 6 exemplarily shows an operation for forming a pattern
on one shot region SR of the substrate S in the imprint apparatus
100 according to the first embodiment of the present invention. The
controller CNT controls this operation. Assume that before this
operation, the imprint material IM is arranged with respect to the
shot region SR as a pattern formation target by the dispenser DSP
or an apparatus outside the imprint apparatus 100. The imprint
material IM can be arranged with respect to one shot region SR or
can be continuously arranged with respect to a plurality of shot
regions SR.
[0066] In step S601, the controller CNT specifies the shot region
SR as a pattern formation target. In step S602 (determination
step), the controller CNT determines a plurality of marks SMK for
the alignment of the shot region SR determined in step S601 with
the mold M (its pattern region PR). In this case, determining a
plurality of marks SMK on the shot region SR will determine a
plurality of corresponding marks MMK on the mold M which
respectively correspond to the plurality of the marks SMK on the
shot region SR. That is, in step S602, the controller CNT
determines a plurality of mark pairs (each mark pair is constituted
by the mark SMK and the mark MMK) for the alignment of the shot
region SR specified in step S601 with the mold M (its pattern
region PR). In this case, the relative positions between the
plurality of marks (mark pairs) determined for a full shot region
can typically differ from the relative positions between the
plurality of marks (mark pairs) determined for a partial shot
region.
[0067] In step S603 (measurement step), the controller CNT controls
the alignment detection system AS to detect the relative positions
(the relative positions between the marks SMK and the marks MMK)
between the plurality of mark pairs determined in step S602. This
causes the controller CNT to measure the relative positions between
the plurality of mark pairs selected in step S602. In step S604
(setting step), the controller CNT sets the origin position of the
coordinate system for the computation of the alignment error
between the shot region SR specified in step S601 and the mold M
(its pattern region PR) based on the arrangement of the plurality
of mark pairs selected in step S602. Step S604 includes a step of
determining an origin position. A method of determining an origin
position can comply with the above description. Step S604 can be
executed before step S603 as long as executed after step S602. In
step S604, the controller CNT may set the origin position of the
coordinate system for the computation of the alignment error
between the shot region SR and the mold M (its pattern region PR)
based on the shot region SR specified in step S601. A method of
determining an origin position can comply with the above
description. In this case, step S604 can be executed before step
S603 or step S602 as long as it is executed after step S601.
[0068] In step S605, the controller CNT computes an alignment error
based on the measurement result obtained in step S603 (measurement
step) and the origin position set in step S604 (setting step). A
method of computing an alignment error can comply with the above
description. In step S606, the controller CNT controls the driving
mechanism DM, the deformation mechanism MAG, the shot region
deformation unit SRD, and the curing unit CU to execute an imprint
process.
[0069] The second embodiment of the present invention will be
described below. Note that matters that are not mentioned in the
second embodiment can comply with the first embodiment. FIGS. 7A to
7D each exemplarily show a rule for specifying a component of an
alignment error. In the following description, each mark pair is
constituted by one mark MMK (black circle) and one mark SMK (black
triangle). Note that because either mark can be used as a reference
concerning deformation, the relationship between MMK and SMK of
each mark pair may be reversed.
[0070] As shown in FIG. 7A, when the relative position between the
mark MMK (black circle) on a pattern region PR and the mark SMK
(black triangle) on a shot region SR remains the same between each
of the four mark pairs within an allowable error, a controller CNT
determines that the alignment error is a shift component. In this
case, each relative position is specified by the direction of the
mark SMK relative to the mark MMK and the distance between the mark
MMK and the mark SMK. As shown in FIG. 7B, when the four marks MMK
overlay on the four marks SMK within an allowable error upon
rotating the figure defined by vertices thereof which are positions
of the four marks MMK about the center of the pattern region PR,
the controller CNT determines that the alignment error is a
rotation component.
[0071] As shown in FIG. 7C, when the four marks MMK overlay on the
four marks SMK within an allowable error upon performing
enlargement/reduction of the figure defined by vertices thereof
which are positions of the four marks MMK at the center of the
pattern region PR as the center of enlargement/reduction, the
controller CNT determines that the alignment error is a
magnification component. As shown in FIG. 7D, when the four marks
MMK overlay on the four marks SMK upon bringing the two ends of the
first side of the rectangle defined by vertices thereof which are
positons of the four marks MMK close to each other and separating
the two ends of the second side of the rectangle from each other,
the controller CNT determines that the alignment error is a
trapezoid component. In this case, the first and second sides are
two sides as opposite sides.
[0072] An example of determining a component of an alignment error
of a partial shot region according to the rules shown in FIGS. 7A
to 7D will be described as a comparative example with reference to
FIG. 8. Referring to FIG. 8, a partial shot region has only one
chip region CR in the effective region of a substrate S. Referring
to FIG. 8, the black circles indicate the four marks MMK
corresponding to the four marks SMK respectively arranged at the
four corners of the chip region CR of the partial shot region.
Referring to FIG. 8, when the figure defined by vertices thereof
which are positions of the four marks MMK is enlarged/reduced at
the center of the pattern region PR as the center of
enlargement/reduction, the four marks MMK overlay on the four marks
SMK within an allowable error. Therefore, the alignment error is
determined to be a magnification component according to the rules
shown in FIGS. 7A to 7D.
[0073] Distortion is likely to occur in a peripheral portion (a
portion near an edge) of the substrate S during a manufacturing
process. The chip region CR of a partial shot region can have
larger distortion than the chip region CR of a central portion of
the substrate S or a full shot region. When the alignment error
measured by using the marks on the chip region CR of the partial
shot region is converted into a correction value for the entire
pattern region PR, the correctable ranges of a deformation
mechanism MAG and a shot region deformation unit SRD may be
exceeded.
[0074] In the example shown in FIG. 8, the marks MMK arranged at
the four corners of the chip region CR of the partial shot region
can be overlaid on the corresponding marks SMK by shifting the
marks MMK. That is, in the example shown in FIG. 8, the alignment
error can be determined to be a shift error. If it be so, the
alignment error can be reduced by shift component correction using
a driving mechanism DM instead of magnification component
correction using the deformation mechanism MAG.
[0075] Accordingly, in the second embodiment, the controller CNT
sets the origin position of a coordinate system for the computation
of an alignment error of a partial shot region according to the
first embodiment, and computes each component of the alignment
error. In this case, as exemplarily shown in FIG. 9, the alignment
error in FIG. 8 is decomposed into a shift component, magnification
component, rotation component, and trapezoid component, and the
main component is the shift component. In this case, when the
alignment error is decomposed into a plurality of components, an
order of priority may be provided. For example, a higher priority
is preferably given to shift components and rotation components
that can be corrected by the driving mechanism DM than to
magnification components and trapezoid components that should be
corrected by the deformation mechanism MAG and the shot region
deformation unit SRD. In this case, components with higher
priorities are determined first, and the remaining alignment error
is decomposed into components with lower priorities.
[0076] The user may set an order of priority via a user interface
UI. The user may also set a rule for decomposing an alignment error
into a plurality of components via the user interface UI.
[0077] A case in which a correction value is determined by an
overlay inspection apparatus 110 and applied to an imprint
apparatus 100 will be described as the third embodiment of the
present invention with reference to FIGS. 10A and 10B.
[0078] A comparative example will be described first with reference
to FIG. 10A. A substrate on which a pattern formed from a cured
product of an imprint material IM is formed by the imprint
apparatus 100, that is, a substrate onto which a pattern on a mold
M is transferred, can be evaluated by using the overlay inspection
apparatus 110. First of all, a second pattern is formed on a
substrate (to be referred to as the first substrate) having a first
pattern by an imprint process using the imprint apparatus 100 and
the mold M. The first substrate is then sent to an overlay
inspection apparatus 110. The overlay inspection apparatus 110
measures the overlay error between the first pattern on the first
substrate and the second pattern formed on the first pattern. A
computing device 120 computes a correction value (offset value)
based on the overlay error measured by the overlay inspection
apparatus 110. This value is set in the imprint apparatus 100.
[0079] In general, the overlay inspection apparatus 110 as an
external apparatus of the imprint apparatus 100 is specifically
designed for measurement, and hence can measure many measurement
points (evaluation portions) without decreasing productivity.
Accordingly, using the overlay inspection apparatus 110 makes it
possible to accurately determine a correction value (offset value).
The imprint apparatus 100 can perform alignment based on the
alignment error component determined based on the measurement
result obtained by using the alignment detection system AS and a
preset offset value.
[0080] However, in using the scheme of determining the origin
position of a coordinate system for the computation of an alignment
error by using the imprint apparatus 100 as in the first and second
embodiments, the computation result obtained by the computing
device 120 configured to perform computation as in the above
comparative example does not match the imprint apparatus 100. In
this case, although the computing device 120 preferably
incorporates a computation algorithm complying with the first and
second embodiments, it may be difficult for the computing device
120 as a general-purpose device for a manufacturing process to
incorporate such an algorithm.
[0081] The system shown in FIG. 10B is configured to solve the
above problem. In the third embodiment, a computing device 122
re-computes a correction value matching the imprint apparatus 100
according to the first or second embodiment based on the correction
value output from the computing device 120.
[0082] First of all, based on the position of a measurement point
in the measurement performed by the overlay inspection apparatus
110 and the correction value computed by the computing device 120,
the computing device 122 inversely computes a measurement value at
the measurement point. Subsequently, the computing device 122
computes a correction value for each correction component
(alignment error component) upon setting the origin position
determined for each shot region in the imprint apparatus 100, and
sets an offset value corresponding to the correction value in the
imprint apparatus 100. An alignment error can include, as its
component, at least one ofa shift component, magnification
component, rotation component, trapezoid component, and skew
component. An offset value may be applied in the form of correcting
the relative position detected by each alignment scope.
[0083] FIG. 11 shows a procedure in an adjustment method according
to the third embodiment of the present invention. This adjustment
method is an adjustment method of adjusting the imprint apparatus
100 in the system shown in FIG. 10B. In step S1101 (imprint step),
an imprint process is formed to form a second pattern on a first
pattern on a first substrate by using the imprint apparatus 100 and
the mold M. The first substrate may be a substrate for a test or a
substrate for the manufacture of a device. Alignment in an imprint
process is performed in accordance with the first or second
embodiment.
[0084] In step S1102 (measurement step), the first substrate on
which the first pattern is formed in step S1101 is sent to the
overlay inspection apparatus 110, and the overlay inspection
apparatus 110 measures the overlay error between the first pattern
and the second pattern. In step S1103 (first computation step), the
computing device 120 computes a first correction value based on the
overlay error obtained in step S1102 by using a first origin
position as the origin position of the coordinate system set in
advance in the computing device 120 to calculate an alignment
error.
[0085] In step S1104 (determination step), the computing device 122
determines a second origin position as the origin position of the
coordinate system based on the arrangement of a plurality of marks
for alignment between the mold M and a shot region of a second
substrate processed by the imprint apparatus 100. The second origin
position is the origin position of a coordinate system for causing
the imprint apparatus 100 to compute the alignment error between a
shot region of the second substrate and the mold M. The computing
device 122 acquires, from the imprint apparatus 100, information
concerning the layout of shot regions in an imprint process
executed by using the mold M, and can determine a second origin
position based on the acquired information. In step S1104, the
second origin position may be determined based on the arrangement
of a plurality of marks for alignment between the mold M and a shot
region of the second substrate processed by the imprint apparatus
100.
[0086] In step S1105 (second computation step), the computing
device 122 converts the first correction value into a second
correction value based on the second origin position. In step S1106
(setting step), the computing device 122 sets an offset value
corresponding to the second correction value in the imprint
apparatus 100.
[0087] The pattern of a cured product formed using an imprint
apparatus is used permanently for at least some of various kinds of
articles or temporarily when manufacturing various kinds of
articles. The articles are an electric circuit element, an optical
element, a MEMS, a recording element, a sensor, a mold, and the
like. Examples of the electric circuit element are volatile and
nonvolatile semiconductor memories such as a DRAM, a SRAM, a flash
memory, and a MRAM and semiconductor elements such as an LSI, a
CCD, an image sensor, and an FPGA. The optical element includes a
microlens, a light-guiding member, a waveguide, an antireflection
film, diffraction grating, a light polarization element, a color
filter, a light emitting element, a display, a solar battery, or
the like. The MEMS includes a DMD, a microchannel, an
electromechanical transducer, or the like. The recording element
includes an optical disk such as a CD or DVD, a magnetic disk, a
magnetooptical disk, a magnetic head, or the like. The sensor
includes a magnetic sensor, an optical sensor, a gyro sensor, or
the like. The mold includes an imprint mold or the like.
[0088] The pattern of the cured product is directly used as at
least some of the constituent members of the above-described
articles or used temporarily as a resist mask. After etching or ion
implantation is performed in the substrate processing step, the
resist mask is removed.
[0089] A method of manufacturing an article in which an imprint
apparatus forms a pattern on a substrate, processes the substrate
on which the pattern is formed, and manufactures an article from
the processed substrate will be described next. As shown FIG. 12A,
a substrate 1z such as a silicon wafer with a processed material 2z
such as an insulator formed on the surface is prepared. Next, an
imprint material 3z is applied to the surface of the processed
material 2z by an inkjet method or the like. A state in which the
imprint material 3z is applied as a plurality of droplets onto the
substrate is shown here.
[0090] As shown in FIG. 12B, a side of a mold 4z for imprint with a
concave-convex pattern is directed toward and made to face the
imprint material 3z on the substrate. As shown FIG. 12C, the
substrate 1z to which the imprint material 3z is applied is brought
into contact with the mold 4z, and a pressure is applied. The gap
between the mold 4z and the processed material 2z is filled with
the imprint material 3z. In this state, when the imprint material
3z is irradiated with energy for curing via the mold 4z, the
imprint material 3z is cured.
[0091] As shown in FIG. 12D, after the imprint material 3z is
cured, the mold 4z is separated from the substrate 1z, and the
pattern of the cured product of the imprint material 3z is formed
on the substrate 1z. In the pattern of the cured product, the
concave portion of the mold corresponds to the convex portion of
the cured product, and the convex portion of the mold corresponds
to the concave portion of the cured product. That is, the
concave-convex pattern of the mold 4z is transferred to the imprint
material 3z.
[0092] As shown in FIG. 12E, when etching is performed using the
pattern of the cured product as an etching resistant mold, a
portion of the surface of the processed material 2z where the cured
product does not exist or remains thin is removed to form a groove
5z. As shown in FIG. 12F, when the pattern of the cured product is
removed, an article with the grooves 5z formed in the surface of
the processed material 2z can be obtained. Here, the pattern of the
cured product is removed. However, instead of removing the pattern
of the cured product after the process, it may be used as, for
example, an interlayer dielectric film included in a semiconductor
element or the like, that is, a constituent member of an
article.
[0093] Another article manufacturing method will be described next.
As shown in FIG. 13A, a substrate 1y such as silica glass is
prepared, and then an imprint material 3y is applied on the surface
of the substrate 1y by the inkjet method or the like. A layer of
another material such as a metal or a metallic compound may be
provided on the surface of the substrate 1y, as needed.
[0094] As shown in FIG. 13B, a side of an imprint mold 4y on which
its three-dimensional pattern is formed faces the imprint material
3y on the substrate. As shown in FIG. 13C, a mold 4y and the
substrate 1y to which the imprint material 3y is applied are
brought into contact with each other, and a pressure is applied.
The imprint material 3y fills the gap between the mold 4y and the
substrate 1y. The imprint material 3y is cured by irradiating it
with light through the mold 4y in this state.
[0095] As shown in of FIG. 13D, the pattern of the cured product of
the imprint material 3y is formed on the substrate 1y by releasing
the mold 4y and the substrate 1y from each other after curing the
imprint material 3y. An article including the pattern of the cured
product as a constituent member is thus obtained. Note that if the
substrate 1y is etched by using the pattern of the cured product as
a mask in the state of FIG. 13D, it is also possible to obtain an
article with a concave portion and a convex portion being inverted
with respect to the mold 4y, for example, an imprint mold.
Other Embodiments
[0096] Embodiment(s) of the present invention can also be realized
by a computer of a system or apparatus that reads out and executes
computer executable instructions (e.g., one or more programs)
recorded on a storage medium (which may also be referred to more
fully as a `non-transitory computer-readable storage medium`) to
perform the functions of one or more of the above-described
embodiment(s) and/or that includes one or more circuits (e.g.,
application specific integrated circuit (ASIC)) for performing the
functions of one or more of the above-described embodiment(s), and
by a method performed by the computer of the system or apparatus
by, for example, reading out and executing the computer executable
instructions from the storage medium to perform the functions of
one or more of the above-described embodiment(s) and/or controlling
the one or more circuits to perform the functions of one or more of
the above-described embodiment(s). The computer may comprise one or
more processors (e.g., central processing unit (CPU), micro
processing unit (MPU)) and may include a network of separate
computers or separate processors to read out and execute the
computer executable instructions. The computer executable
instructions may be provided to the computer, for example, from a
network or the storage medium. The storage medium may include, for
example, one or more of a hard disk, a random-access memory (RAM),
a read only memory (ROM), a storage of distributed computing
systems, an optical disk (such as a compact disc (CD), digital
versatile disc (DVD), or Blu-ray Disc (BD).TM.), a flash memory
device, a memory card, and the like.
[0097] While the present invention has been described with
reference to exemplary embodiments, it is to be understood that the
invention is not limited to the disclosed exemplary embodiments.
The scope of the following claims is to be accorded the broadest
interpretation so as to encompass all such modifications and
equivalent structures and functions.
[0098] This application claims the benefit of Japanese Patent
Application No. 2018-123520, filed Jun. 28, 2018, which is hereby
incorporated by reference herein in its entirety.
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