U.S. patent application number 16/081557 was filed with the patent office on 2019-03-14 for electroplating apparatus.
The applicant listed for this patent is Nippon Steel & Sumitomo Metal Corporation, Vallourec Oil and Gas France. Invention is credited to Kazuya Ishii, Masanari Kimoto, Masahiro Oshima.
Application Number | 20190078225 16/081557 |
Document ID | / |
Family ID | 59744087 |
Filed Date | 2019-03-14 |
United States Patent
Application |
20190078225 |
Kind Code |
A1 |
Kimoto; Masanari ; et
al. |
March 14, 2019 |
Electroplating Apparatus
Abstract
An electroplating apparatus is provided that minimizes unplated
regions when an alloy plating layer is provided on the surface of a
thread on a steel pipe. An electroplating apparatus (10) includes
an electrode (1), sealing members (2, 3), and a plating-solution
supply unit (4). The electrode (1) faces the thread (Tm). The
sealing member (2) is positioned within the steel pipe (P1). The
sealing member (3) is attached to the end portion of the steel pipe
(P1) and, together with the sealing member (2), forms a receiving
space (8). The plating-solution supply unit (4) includes a
plurality of nozzles (42). The nozzles (42) are positioned within
the receiving space (8) and adjacent one end of the thread (Tm) and
arranged around the pipe axis of the steel pipe (P1). The
plating-solution supply unit (4) injects a plating solution between
the thread (Tm) and electrode (1) through the nozzles (42). The
direction in which plating solution is injected from the nozzles
(42) is inclined at an angle larger than 20 degrees and smaller
than 90 degrees toward the thread (Tm) relative to a plane
perpendicular to the pipe axis.
Inventors: |
Kimoto; Masanari;
(Chiyoda-ku, Tokyo, JP) ; Ishii; Kazuya;
(Chiyoda-ku, Tokyo, JP) ; Oshima; Masahiro;
(Chiyoda-ku, Tokyo, JP) |
|
Applicant: |
Name |
City |
State |
Country |
Type |
Nippon Steel & Sumitomo Metal Corporation
Vallourec Oil and Gas France |
Tokyo
Aulnoye-Aymeries |
|
JP
FR |
|
|
Family ID: |
59744087 |
Appl. No.: |
16/081557 |
Filed: |
March 2, 2017 |
PCT Filed: |
March 2, 2017 |
PCT NO: |
PCT/JP2017/008279 |
371 Date: |
August 31, 2018 |
Current U.S.
Class: |
1/1 |
Current CPC
Class: |
C25D 7/04 20130101; C25D
17/02 20130101; C25D 5/08 20130101; C25D 5/026 20130101; C25D
17/004 20130101; C25D 5/028 20130101; C25D 21/10 20130101; C25D
17/12 20130101 |
International
Class: |
C25D 5/02 20060101
C25D005/02; C25D 7/04 20060101 C25D007/04; C25D 5/08 20060101
C25D005/08; C25D 17/12 20060101 C25D017/12; C25D 17/00 20060101
C25D017/00 |
Foreign Application Data
Date |
Code |
Application Number |
Mar 3, 2016 |
JP |
2016-041436 |
Claims
1. An electroplating apparatus used for a steel pipe having a
thread on an inner periphery or an outer periphery of an end
portion of the steel pipe, the electroplating apparatus comprising:
a first sealing member positioned within the steel pipe; a second
sealing member attached to the end portion of the steel pipe and,
together with the steel pipe and the first sealing member, form a
receiving space for receiving a plating solution; an electrode
located in the receiving space and facing the thread; and a
plurality of nozzles positioned within the receiving space and
arranged around a pipe axis of the steel pipe for injecting a
plating solution between the thread and the electrode, wherein the
plating solution is injected by each of the nozzles in a direction
inclined at an angle larger than 20 degrees and smaller than 90
degrees toward the thread relative to a plane perpendicular to the
pipe axis.
2. An electroplating apparatus used for a steel pipe having a male
thread on an outer periphery of an end portion of the steel pipe,
the electroplating apparatus comprising: a sealing member
positioned at an end of the steel pipe to seal the steel pipe; a
container having an opening to receive the end portion, the
container configured to contain the end portion and a plating
solution; an electrode located in the container and facing the male
thread; and a plurality of nozzles positioned within the container
and arranged around a pipe axis of the steel pipe for injecting a
plating solution between the male thread and the electrode, wherein
the plating solution is injected by each of the nozzles in a
direction inclined at an angle larger than 20 degrees and smaller
than 90 degrees toward the male thread relative to a plane
perpendicular to the pipe axis.
3. The electroplating apparatus according to claim 2, further
comprising: a support member located on a side opposite to the
opening of the container to support the plurality of nozzles,
wherein the support member includes a plating-solution channel for
supplying the plating solution to the nozzles, and the sealing
member is fixed to the support member.
4. The electroplating apparatus according to claim 3, wherein the
support member includes a first channel extending along the pipe
axis, and wherein the sealing member includes: a disc including a
second channel extending to an outer periphery thereof and
communicating with the first channel; and packing mounted on the
outer periphery of the disc and in contact with an inner periphery
of the steel pipe.
5. An electroplating apparatus used for a steel pipe having a
female thread on an inner periphery of an end portion of the steel
pipe, the electroplating apparatus comprising: a first sealing
member positioned within the steel pipe and inward of the end
portion to seal the steel pipe; a second sealing member positioned
at an end of the steel pipe and, together with the steel pipe and
the first sealing member, form a receiving space for receiving a
plating solution; an electrode located in the receiving space and
facing the female thread; and a plurality of nozzles positioned
within the receiving space and arranged around a pipe axis of the
steel pipe for injecting a plating solution between the female
thread and the electrode, wherein the plating solution is injected
by each of the nozzles in a direction inclined at an angle larger
than 20 degrees and smaller than 90 degrees toward the female
thread relative to a plane perpendicular to the pipe axis.
6. The electroplating apparatus according to claim 5, further
comprising: a support member provided on the second sealing member
to support the plurality of nozzles, wherein the support member
includes a plating-solution channel for supplying the plating
solution to the nozzles, and the first sealing member is fixed to
the support member.
7. The electroplating apparatus according to claim 6, wherein the
support member includes a first channel extending along the pipe
axis, and wherein the first sealing member includes: a disc
including a second channel extending to an outer periphery thereof
and communicating with the first channel; and packing mounted on
the outer periphery of the disc and in contact with an inner
periphery of the steel pipe.
8. The electroplating apparatus according to claim 1, wherein the
number of the nozzles is six or larger.
9. The electroplating apparatus according to claim 2, wherein the
number of the nozzles is six or larger.
10. The electroplating apparatus according to claim 3, wherein the
number of the nozzles is six or larger.
11. The electroplating apparatus according to claim 4, wherein the
number of the nozzles is six or larger.
12. The electroplating apparatus according to claim 5, wherein the
number of the nozzles is six or larger.
13. The electroplating apparatus according to claim 6, wherein the
number of the nozzles is six or larger.
14. The electroplating apparatus according to claim 7, wherein the
number of the nozzles is six or larger.
Description
TECHNICAL FIELD
[0001] The present disclosure relates to an electroplating
apparatus, and more particularly to an electroplating apparatus for
steel pipe having a thread on the inner or outer periphery of an
end thereof.
BACKGROUND OF THE INVENTION
[0002] In oil wells and natural-gas wells, oil-well pipes are used
to mine underground resources. An oil-well pipe is composed of a
series of steel pipes that are connected with each other. A
threaded connection is used to connect such steel pipes. Threaded
connections are generally categorized as coupling-type and
integral-type.
[0003] A coupling-type connection uses a tubular coupling to
connect steel pipes. A female thread is provided on the inner
periphery of each end of the coupling. A male thread is provided on
the outer periphery of each end of a steel pipe. The male thread on
a steel pipe is screwed into a female thread on the coupling to
connect steel pipes.
[0004] In an integral-type connection, a male thread is provided on
the outer periphery of one end of a steel pipe, while a female
thread is provided on the inner periphery of the other end. The
male thread on one steel pipe is screwed into the female thread on
another steel pipe to connect the steel pipes.
[0005] Traditionally, a lubricant is used when steel pipes are
connected. Lubricant is applied to at least one of the male thread
and female thread to prevent galling at the connection. Lubricants
specified by the American Petroleum Institute (API) standards
(hereinafter referred to as API dopes) contain heavy metals such as
lead (Pb).
[0006] The use of API dopes is restricted in areas with strict
environmental regulations. In such areas, lubricants containing no
heavy metals (hereinafter referred to as green dopes) are used.
Green dopes have lower lubricities than API dopes. Accordingly,
when a green dope is used, it is desirable to provide an
electroplating layer on the male thread and/or female thread to
compensate for the insufficient lubricity. JP Sho60(1985)-9893 A
discloses a local automatic plating apparatus for depositing an
electroplating layer on a male thread.
[0007] During electroplating, air bubbles of hydrogen and/or oxygen
are usually generated at the same time as an electroplating layer
is deposited. If such air bubbles remain on the surface of the
thread, the surface of the thread will have regions without an
electroplating layer (hereinafter referred to as "unplated
regions"), decreasing the galling resistance of the connection.
[0008] To address this problem, Japanese Patent No. 5699253
proposes an electroplating apparatus for depositing a uniform
electroplating layer that has no unplated regions. The
electroplating apparatus includes a plurality of nozzles that
inject copper plating solution. The nozzles extend in a radial
manner with the center at the pipe axis of the steel pipe, where
the tips of the nozzles are located between the female thread and
an insoluble electrode. Each nozzle has a direction of injection
that crosses its direction of extension and that is
circumferentially consistent with the directions of injection of
the other nozzles. This generates a spiral jet stream of plating
solution between the female thread and insoluble electrode, which
causes small air bubbles that have been generated during
electroplating to leave the thread roots. This minimizes unplated
regions.
DISCLOSURE OF THE INVENTION
[0009] The electroplating apparatus of U.S. Pat. No. 5,699,253 is
capable of depositing a copper plating layer, i.e. a single-metal
plating layer, on the surface of a thread without producing
unplated regions. However, when an alloy plating layer (e.g.
zinc-nickel alloy plating layer) is to be deposited on the surface
on a thread using this electroplating apparatus, plating defects
that are not produced when a copper plating layer is deposited may
occur, such as irregularities in appearance or small plating
peels.
[0010] An object of the present disclosure is to provide an
electroplating apparatus that minimizes such plating defects when
depositing an alloy plating layer on the surface of a thread on a
steel pipe.
[0011] An electroplating apparatus according to the present
disclosure is used for a steel pipe having a thread on an inner
periphery or an outer periphery of an end portion of the steel
pipe. The electroplating apparatus includes a first sealing member,
a second sealing member, an electrode, and a plurality of nozzles.
The first sealing member is positioned within the steel pipe. The
second sealing member is attached to the end portion of the steel
pipe and, together with the steel pipe and the first sealing
member, forms a receiving space for receiving a plating solution.
The electrode is located in the receiving space and faces the
thread. The plurality of nozzles are positioned within the
receiving space and arranged around a pipe axis of the steel pipe
for injecting a plating solution between the thread and the
electrode. The plating solution is injected by each of the nozzles
in a direction inclined at an angle larger than 20 degrees and
smaller than 90 degrees toward the thread relative to a plane
perpendicular to the pipe axis.
[0012] The present disclosure will minimize plating defects such as
irregularities in appearance and small plating peels when
depositing an alloy plating layer such as a zinc-nickel alloy
plating layer on the surface of a thread.
BRIEF DESCRIPTION OF THE DRAWINGS
[0013] FIG. 1 is a schematic illustration of a state during
electroplating.
[0014] FIG. 2 is a schematic vertical cross-sectional view of an
electroplating apparatus according to a first embodiment.
[0015] FIG. 3 is a schematic front view of the plating-solution
supply unit of the electroplating apparatus shown in FIG. 1.
[0016] FIG. 4 is a schematic view of a nozzle of the
plating-solution supply unit shown in FIG. 3 as viewed in the
direction in which the body portion extends.
[0017] FIG. 5 is a schematic vertical cross-sectional view of an
electroplating apparatus according to a second embodiment.
[0018] FIG. 6 is a schematic front view of the plating-solution
supply unit of the electroplating apparatus shown in FIG. 5.
[0019] FIG. 7 is a schematic view of a nozzle of the
plating-solution supply unit shown in FIG. 6 as viewed in the
direction in which the body portion extends.
[0020] FIG. 8 is a graph showing the relationship between the
composition (Ni content) and brightness of color (L value) of the
Zn--Ni alloy plating layer.
[0021] FIG. 9 shows pictures for comparison between a steel pipe of
an inventive example and a steel pipe of a comparative example.
EMBODIMENTS FOR CARRYING OUT THE INVENTION
[0022] Generally, if the surface of a thread on a steel pipe is
electroplated, it is said to be preferable not to let plating
solution directly impinge on the surface of the thread, to minimize
turbulence in the liquid flow. For example, the electroplating
apparatus of U.S. Pat. No. 5,699,253 is constructed to reduce the
inclination of the direction of injection of plating solution
toward the thread to prevent plating solution injected from the
nozzles from impinging on the thread.
[0023] However, when an alloy plating layer (e.g. zinc-nickel alloy
plating layer) is to be provided on the surface of the thread, an
excessively small inclination of the direction of injection of
plating solution can easily result in plating defects such as
irregularities in appearance or small plating peels. The present
inventors assumed that such plating defects result from the
following circumstances during the deposition of an alloy plating
layer.
[0024] FIG. 1 is a schematic illustration of a state during
electroplating. As shown in FIG. 1, during electroplating, a
diffusion layer D is generated in a plating solution L adjacent to
the material M. The diffusion layer D has a concentration gradient
relative to the plating solution body resulting from mass transfer
due to diffusion. The rate of transfer of materials within the
diffusion layer D is not affected by a stir of the plating solution
L. A stir of the plating solution L affects the thickness of the
diffusion layer D.
[0025] The thickness of the diffusion layer D decreases as the
plating solution L is stirred more strongly. If the plating
solution L is stirred gently, the thickness of the diffusion layer
increases, as indicated by character T1. If the plating solution L
is stirred strongly, the thickness of the diffusion layer
decreases, as indicated by character T2.
[0026] Microscopically, the thickness of the diffusion layer D
during electroplating is not uniform, but has fluctuations of about
10% of the average thickness measured in a state of rest. That is,
the greater the thickness of the diffusion layer D, the larger the
fluctuations. In the example shown in FIG. 1, the fluctuations in
the thickness of the diffusion layer D occurring when the layer has
an average thickness in a state of rest of T1 are larger than those
occurring when the layer has an average thickness in a state of
rest of T2.
[0027] Fluctuations in the thickness of the diffusion layer D
affect the rate of deposition of metal on the surface of the
material M. That is, metal ions I.sup.+ arrive at the surface of
the material M relatively early in portions of the diffusion layer
D where the distance between the interface with the plating
solution body and the surface of the material M is relatively
short, while metal ions I.sup.+ arrive at the surface of the
material M relatively late in portions of the diffusion layer where
the distance between the interface with the plating solution body
and the surface of the material M is relatively long. This causes
variations in the rate of deposition of the metal.
[0028] Such variations in the rate of deposition of metal are not
particularly problematic if a plating layer of a single metal is
being deposited. However, if an alloy plating layer is being
deposited, variations in the rate of deposition of the metals may,
for example, locally increase the amount of deposition of one metal
on the surface of the material M, and therefore make the
composition of the alloy plating layer deposited on the surface of
the material M non-uniform. This may decrease the adherence of the
alloy plating layer to the surface of the material M, causing
plating peels or irregularities in the tone of color in
appearance.
[0029] To make the composition of the alloy plating layer uniform,
it is preferable to reduce fluctuations in the thickness of the
diffusion layer D. To reduce fluctuations in the thickness of the
diffusion layer D, the thickness of the diffusion layer D itself
must be reduced.
[0030] Based on the above-discussed findings, the present inventors
arrived at the electroplating apparatuses according to the
embodiments.
[0031] An electroplating apparatus according to the present
disclosure is used for a steel pipe having a thread on an inner
periphery or an outer periphery of an end portion of the steel
pipe. The electroplating apparatus includes a first sealing member,
a second sealing member, an electrode, and a plurality of nozzles.
The first sealing member is positioned within the steel pipe. The
second sealing member is attached to the end portion of the steel
pipe and, together with the first sealing member, forms a receiving
space for receiving a plating solution. The electrode is located in
the receiving space and faces the thread. The plurality of nozzles
are positioned within the receiving space and arranged around a
pipe axis of the steel pipe for injecting a plating solution
between the thread and the electrode. The plating solution is
injected by each of the nozzles in a direction inclined at an angle
larger than 20 degrees and smaller than 90 degrees toward the
thread relative to a plane perpendicular to the pipe axis.
[0032] An electroplating apparatus according to an embodiment is
used for a steel pipe having a thread on an inner periphery or an
outer periphery of an end portion. The electroplating apparatus
includes a first sealing member, a second sealing member, an
electrode, and a plurality of nozzles. The first sealing member is
positioned within the steel pipe. The second sealing member is
attached to the end portion of the steel pipe and, together with
the steel pipe and the first sealing member, forms a receiving
space for receiving a plating solution. The electrode is located in
the receiving space and faces the thread. The plurality of nozzles
are positioned in the receiving space and arranged around a pipe
axis of the steel pipe for injecting a plating solution between the
thread and the electrode. The plating solution is injected by each
of the nozzles in a direction inclined at an angle larger than 20
degrees and smaller than 90 degrees toward the thread relative to a
plane perpendicular to the pipe axis.
[0033] In the above-described electroplating apparatus, the
direction of injection of the nozzles is inclined toward the thread
at an angle larger than 20 degrees and smaller than 90 degrees.
Thus, during electroplating, the plating solution is injected
toward the thread such that the plating solution is stirred
strongly near the thread. This will reduce the thickness of the
diffusion layer itself, which will also reduce fluctuations
therein. This will prevent variations in the rate of precipitation
of the metals, resulting in a uniform composition of the alloy
plating layer deposited on the surface of the thread. As a result,
plating defects such as irregularities in appearance and small
plating peels will be minimized.
[0034] In the above-described electroplating apparatus, the
plurality of nozzles may be six or more nozzles.
[0035] Embodiments will now be described in more details with
reference to the drawings. The same and corresponding elements in
the drawings are labeled with the same reference characters, and
their description will not be repeated. For ease of explanation,
some elements may be simplified or shown schematically in the
drawings, or some elements may not be shown.
First Embodiment
[0036] [Construction of Electroplating Apparatus]
[0037] FIG. 2 is a schematic vertical cross-sectional view of an
electroplating apparatus 10 according to a first embodiment. The
electroplating apparatus 10 is used to electroplate a steel pipe
P1. More specifically, the electroplating apparatus 10 deposits an
alloy plating layer on the surface of a male thread Tm provided on
the outer periphery of an end portion of the steel pipe P1.
Generally, such an end portion of a steel pipe P1 is referred to as
"pin".
[0038] As shown in FIG. 2, the electroplating apparatus 10 includes
an electrode 1, a sealing member 2, a vessel 3, and a
plating-solution supply unit 4.
[0039] The electrode 1 is a known insoluble anode that can be used
for electroplating. The electrode 1 may be, for example, a titanium
plate covered with iridium oxide or a stainless steel plate
deformed to have a desired shape. The electrode 1 is not limited to
a particular shape, but preferably shaped as a cylinder.
[0040] An electrically conductive rod 9 is connected to the
electrode 1. The electrically conductive rod 9 may be, for example,
a titanium rod or a stainless steel rod. Any number of electrically
conductive rods 9 may be used; for example, three electrically
conductive rods may be used.
[0041] The electrode 1 is disposed in the container 3 and adjacent
the outer periphery of the steel pipe P1. In implementations where
the electrode 1 is cylindrical in shape, the electrode 1 is
positioned to be concentric with the steel pipe P1. The electrode 1
faces the male thread Tm on the steel pipe P1. A plating solution
is supplied between the electrode 1 and male thread Tm, and a
potential difference is applied between the electrode 1 and steel
pipe P1 such that a plating layer is deposited on the surface of
the male thread Tm.
[0042] The sealing member 2 is positioned at an end of the steel
pipe P1 to seal the steel pipe P1. According to the present
embodiment, the sealing member 2 is attached to an end portion
inside the steel pipe P1. The sealing member 2 tightly seals the
entire inner periphery of the steel pipe P1 to close the interior
of the steel pipe P1. Although not limiting, the sealing member 2
may be a "hexaplug" for plumbing, for example.
[0043] The container 3 has an opening 33 for receiving the end
portion of the steel pipe P1 and is used to contain plating
solution, and functions as a sealing member. More specifically, the
container 3 is attached to the end portion of the steel pipe P1.
The container 3 is mounted on the end portion of the steel pipe P1
so as to envelop the outer periphery of the end portion of the
steel pipe P1.
[0044] The container 3 is generally shaped as a cylinder having one
closed end as determined along the axial direction. The end side of
the container 3 supports the electrode 1 by means of the
electrically conductive rod 9. The electrically conductive rod 9 is
fixed to the end side of the container 3. Thus, the peripheral wall
of the container 3 is disposed adjacent the outer periphery of the
electrode 1.
[0045] The other end of the container 3 as determined along the
axial direction tightly seals the outer peripheral surface of the
steel pipe P1. The other end of the sealing member 3 as determined
along the axial direction is in contact with a portion of the outer
peripheral surface of the steel pipe P1 that is closer to the
middle of the pipe than the male thread Tm is. Thus, the container
3, together with the steel pipe P1 and sealing member 2, forms a
receiving space 8. The electrode 1 and male thread Tm are housed in
the receiving space 8. The receiving space 8 is filled with a
plating solution during electroplating.
[0046] The container 3 further includes orifices 31 and 32. The
opening 31 is mainly used to discharge plating solution during and
after plating. The opening 31 is preferably located lower than the
steel pipe P1 when the container 3 is attached to the steel pipe
P1.
[0047] The opening 32 is used to facilitate discharge of plating
solution after plating. Discharging used plating solution quickly
from the receiving space 8 prevents the alloy plating layer
deposited on the male thread Tm from corroding and thus
discoloring. Also, the opening 32 is used as an outlet for gas
(i.e. air) when the receiving space 8 is being filled with plating
solution. The opening 32 is preferably located higher than the
steel pipe P1 when the sealing member 3 is attached to the steel
pipe P1.
[0048] The opening 32 may be configured to be openable and closable
by means of an electromagnetic valve, for example. In such
implementations, the opening 32 may be opened as necessary to
facilitate discharge of plating solution out of the receiving space
8. Alternatively, compressed air may be supplied to the receiving
space 8 through the opening 32 to facilitate discharge of plating
solution.
[0049] In some implementations, the opening 32 may have a hose
connected thereto and extending upward. In such implementations,
the pressure and weight of plating solution supplied to the
receiving space 8 may be balanced to prevent plating solution from
squirting out of the container 3.
[0050] The plating-solution supply unit 4 supplies plating solution
to the receiving space 8. The plating-solution supply unit 4
includes a support member 41 and a plurality of nozzles 42.
[0051] The support member 41 is located on the side of the
container 3 that is opposite to that with the opening 33 for
supporting the nozzles 42. The support member 41 extends from
outside the receiving space 8 through the end side of the container
3 into the receiving space 8. The support member 41 is connected to
the sealing member 2 by means of fastening members. That is, the
sealing member 2 is fixed to the support member 41. The support
member 41 includes a channel 43 extending along the pipe axis X1
and a plating-solution channel 44 for supplying plating solution to
the nozzles 42. The plating-solution channel 44 also extends along
the pipe axis X1 and surrounds the channel 43. The sealing member 2
includes a disc 21 and packing 22. The disc 21 has a channel 23
extending to its outer periphery and communicating with the channel
43. The packing 22 is mounted on the outer periphery of the disc 21
and is in contact with the inner periphery of the steel pipe P1.
When high-pressure air is supplied to the channel 23 through the
channel 43, the packing 22 is strongly pressed against the inner
periphery of the steel pipe P1.
[0052] The support member 41 includes a supply orifice 41a. The
supply orifice 41a is located outside the receiving space 8. The
supply orifice 41a is connected to a reservoir (not shown) that
stores plating solution through tubing (not shown). Plating
solution forwarded from the reservoir flows into the
plating-solution channel 44 in the support member 41 through the
supply orifice 41a. The plating solution is supplied to the nozzles
42 through the plating-solution channel 44.
[0053] The plating solution used for depositing the alloy plating
layer may be, for example, a zinc-nickel (Zn--Ni) plating solution,
a zinc-iron (Zn--Fe) plating solution, a zinc-cobalt (Zn--Co)
plating solution, a nickel-tungsten (Ni--W) plating solution, or a
copper-tin (Cu--Sn) plating solution. Alternatively, the plating
solution may be a copper-tin-zinc (Cu--Sn--Zn) plating solution or
a copper-tin-bismuth (Cu--Sn--Bi) plating solution, for
example.
[0054] The nozzles 42 are connected to that end of the support
member 41 which is located inside the receiving space 8. The
nozzles 42, when in the receiving space 8, are arranged around the
pipe axis X1 of the steel pipe P1. The nozzles 42 are disposed in a
radial manner and separated by an equal distance as viewed in a
pipe-axis direction.
[0055] The nozzles 42, when in the receiving space 8, are located
adjacent one end of the male thread Tm. According to the present
embodiment, the nozzles 42 are located between the end portion of
the steel pipe P1 and the end side of the sealing member 3. The
nozzles 42 inject, between the male thread Tm and electrode 1,
plating solution that has been supplied from the support member
41.
[0056] FIG. 3 is a schematic view of the plating-solution supply
unit 4 as viewed in an axial direction of the support member 41. As
shown in FIG. 3, according to the present embodiment, the
plating-solution supply unit 4 includes eight nozzles 42. The
number of nozzles 42 is not limited to eight, but preferably six or
more nozzles are provided.
[0057] Each nozzle 42 includes a body portion 42a and a tip portion
42b. The body portion 42a extends substantially parallel to a plane
that is perpendicular to the pipe axis X1 of the steel pipe P1. The
body portion 42a extends radially outward from adjacent the pipe
axis X1 of the steel pipe P1.
[0058] The tip portion 42b is contiguous to the body portion 42a.
Plating solution passes through the body portion 42a and is
injected through a jet orifice on the tip portion 42b. As viewed
looking at the electroplating apparatus 10 in a pipe-axis direction
of the steel pipe P1, the jet orifice on the tip portion 42b is
positioned between the electrode 1 and male thread Tm (FIG. 2).
[0059] The nozzles 42 inject plating solution through the jet
orifices on the tip portions 42b in one circumferential direction
about the pipe axis X1. That is, the direction of injection S1 of
the nozzles 42 is clockwise or counterclockwise about the pipe axis
X1. Thus, the plating solution injected from the nozzles 42 forms a
spiral flow with its center at the pipe axis X1. Preferably, the
direction of the spiral flow formed by the nozzles 42 is the same
as the thread direction of the male thread Tm (FIG. 2).
[0060] FIG. 4 is a schematic view of a nozzle 42 as viewed in a
direction, R1, in which the body portion 42a extends. The tip
portion 42b is inclined toward the male thread Tm relative to a
plane that is perpendicular to the pipe axis X1 of the steel pipe
P1. A direction along a plane perpendicular to the pipe axis X1, or
more specifically, the direction that is perpendicular to the
direction of extension R1 and the pipe axis X1, will be referred to
as reference direction V1.
[0061] As shown in FIG. 4, as viewed looking at the nozzle 42 in a
direction of extension R1 of its body portion 42a, the tip portion
42b is inclined at an angle of inclination .alpha.1 toward the male
thread Tm relative to the reference direction V1. That is, a
direction, S1, in which the nozzle 42 injects plating solution is
inclined at the angle of inclination .alpha.1 toward the male
thread Tm relative to the reference direction V1.
[0062] The angle of inclination .alpha.1 is larger than 20 degrees
and smaller than 90 degrees. More preferably, the angle of
inclination .alpha.1 is larger than 30 degrees and not larger than
60 degrees.
[0063] [Effects]
[0064] In the electroplating apparatus 10 according to the first
embodiment, the direction S1 in which each nozzle 42 injects
plating solution is inclined at an angle larger than 20 degrees and
smaller than 90 degrees toward the male thread Tm relative to the
reference direction V1. Thus, during electroplating, plating
solution is injected toward the male thread Tm, thereby strongly
stirring plating solution near the male thread Tm. This causes the
diffusion layer produced adjacent the male thread Tm to become
thinner, thereby reducing the fluctuations in the thickness of the
diffusion layer. This mitigates the variations in the rate of
deposition of metal, preventing the composition of the alloy
plating layer deposited on the surface of the male thread Tm from
being non-uniform. This minimizes plating defects such as
irregularities in appearance and small plating peels.
Second Embodiment
[0065] [Construction of Electroplating Apparatus]
[0066] FIG. 5 is a schematic vertical cross-sectional view of an
electroplating apparatus 20 according to a second embodiment. The
electroplating apparatus 20 deposits an alloy plating layer on the
surface of a female thread Tf provided on the inner periphery of an
end of the steel pipe P2. Generally, such an end portion of a steel
pipe P2 is referred to as "box".
[0067] As shown in FIG. 5, similar to the electroplating apparatus
10 according to the first embodiment (FIG. 2), the electroplating
apparatus 20 includes an electrode 1, sealing members 2 and 3, and
a plating-solution supply unit 4. However, the electroplating
apparatus 20 is different from the electroplating apparatus 10
according to the first embodiment 1 in the arrangement of these
elements.
[0068] The electrode 1 is located adjacent the inner periphery of
the steel pipe P2. The electrode 1 faces the female thread Tf on
the steel pipe P2. A plating solution is supplied between the
electrode 1 and female thread Tf, and a potential difference is
applied between the electrode 1 and steel pipe P2 such that a
plating layer is deposited on the surface of the female thread
Tf.
[0069] The sealing member 2 is located inside the steel pipe P2 and
inward of the end portion to seal the steel pipe P2. Similar to
that of the first embodiment, the sealing member 2 tightly seals
the entire inner periphery of the steel pipe P2 to close the
interior of the steel pipe P1. The sealing member 2 of the present
embodiment, when in the steel pipe 2, is located closer to the
middle of the pipe than the female thread Tf is.
[0070] The sealing member 3 is attached to the end portion of the
steel pipe P2, similar to that of the first embodiment. However,
according to the present embodiment, the location on the outer
periphery of the steel pipe P2 with which the sealing member 3 is
in contact is not limited to a particular location, since the
female thread Tf to be electroplated is provided on the inner
periphery of the steel pipe P2. The sealing member 3 may be in
contact with a location on the outer periphery of the steel pipe P2
that is relatively close to the end of the steel pipe P2. In this
implementation, the sealing member 3 is located at the end of the
steel pipe P2 and, together with the steel pipe P2 and sealing
member 2, forms a receiving space 8 for receiving plating solution.
The electrode 1 is located within the receiving space 8.
[0071] The plating-solution supply unit 4 includes a plurality of
nozzles 42A. The nozzles 42A are located in the receiving space 8
adjacent one end of the female thread Tf. The nozzles 42A are
located between the female thread Tf and sealing member 2. That is,
the nozzles 42A, when in the steel pipe P2, are located closer to
the middle of the pipe than the female thread Tf is.
[0072] FIG. 6 is a schematic view of the plating-solution supply
unit 4 as viewed in an axial direction of the support member 41. As
shown in FIG. 6, according to the present embodiment, too, eight
nozzles 42A are arranged in a radial manner and separated by an
equal distance. Each nozzle 42A includes a body portion 42Aa and a
tip portion 42Ab.
[0073] The body portion 42Aa extends substantially parallel to a
plane that is perpendicular to the pipe axis X2 of the steel pipe
P2. As viewed looking at the electroplating apparatus 20 in a
pipe-axis direction of the steel pipe P2, the jet orifice on the
tip portion 42Ab is positioned between the electrode 1 and female
thread Tf (FIG. 5).
[0074] Similar to the nozzles 42 of the first embodiment, the
nozzles 42A inject plating solution through the jet orifices on the
tip portions 42Ab in one circumferential direction about the pipe
axis X2. The plating solution injected from the nozzles 42A forms a
spiral flow with its center at the pipe axis X2. Preferably, the
direction of the spiral flow is the same as the thread direction of
the female thread Tf (FIG. 5).
[0075] FIG. 7 is a schematic view of a nozzle 42A as viewed in a
direction, R2, in which the body portion 42Aa extends. The tip
portion 42Ab is inclined toward the female thread Tf relative to a
plane that is perpendicular to the pipe axis X2 of the steel pipe
P2. A direction along a plane perpendicular to the pipe axis X2, or
more specifically, the direction that is perpendicular to the
direction of extension R2 and the pipe axis X2, will be referred to
as reference direction V2.
[0076] As shown in FIG. 7, as viewed looking at the nozzle 42A in a
direction of extension R2 of its body portion 42Aa, the tip portion
42Ab is inclined at an angle of inclination .alpha.2 toward the
female thread Tf relative to the reference direction V2. That is, a
direction, S2, in which the nozzle 42A injects plating solution, is
inclined at the angle of inclination .alpha.2 toward the female
thread Tf relative to the reference direction V2. The angle of
inclination .alpha.2 is larger than 20 degrees and smaller than 90
degrees, and more preferably, larger than 30 degrees and not larger
than 60 degrees.
[0077] The direction S2 in which the nozzles 42A inject plating
solution is inclined toward the opposite side to the direction S1
in which the nozzles 42 of the first embodiment inject plating
solution. This is because the nozzles 42A of the second embodiment
are positioned in an opposite manner to the nozzles 42 of the first
embodiment across a pipe section extending in the pipe-axis
direction.
[0078] Toward which side the direction of injection of plating
solution is to be inclined may be determined depending on the
relative positional relationship between the thread and nozzles. In
short, the direction of injection of the nozzles is only required
to be inclined toward the thread relative to a plane that is
perpendicular to the axial direction of the steel pipe such that
plating solution is injected toward the thread.
[0079] [Effects]
[0080] In the electroplating apparatus 20 according to the second
embodiment, the direction S2 in which each nozzle 42A injects
solution is inclined at an angle larger than 20 degrees and smaller
than 90 degrees toward the female thread Tf relative to the
reference direction V2. Thus, during electroplating, plating
solution near the female thread Tf is strongly stirred. This causes
the diffusion layer to become thinner, thereby reducing the
fluctuations in the thickness of the diffusion layer. This prevents
the composition of the alloy plating layer deposited on the surface
of the female thread Tf from being non-uniform. This minimizes
plating defects such as irregularities in appearance and small
plating peels.
[0081] <Variations>
[0082] Although some particular embodiments have been described,
the present disclosure is not limited to the above-illustrated
embodiments, and various modifications are possible without
departing from the spirit of the disclosure.
[0083] In the above-illustrated embodiments, the body portions of
the nozzles extend parallel to a plane that is perpendicular to the
pipe axis of the steel pipe, and the tip portions of the nozzles
are inclined relative to this plane; however, the present
disclosure is not limited to such a configuration. For example, the
entire nozzles may be inclined relative to a plane that is
perpendicular to the pipe axis of the steel pipe to inject plating
solution at a predetermined angle.
[0084] In the above-illustrated embodiments, the sealing member
inside the steel pipe is fixed to the support member of the
plating-solution supply unit by means of fastening members.
Alternatively, the sealing member may not be fixed to the
plating-solution supply unit.
Examples
[0085] The effects of the present disclosure will be illustrated
below with reference to examples. However, the present disclosure
is not limited to the examples illustrated below.
[0086] A degreasing liquid (50 g/L of sodium hydroxide), Ni strike
bath (250 g/L of nickel chloride, 80 g/L of hydrochloric acid),
Zn--Ni plating bath ("Dain Zinalloy" from Daiwa Fine Chemicals Co.,
Ltd.) were prepared, and the electroplating apparatus (10) shown in
FIG. 1 was used to perform Zn--Ni alloy plating (Ni content
(target): 12 to 16%) on the surface of a male thread (Tm) on a
steel pipe (P1). The steps of the electroplating process and their
conditions are shown in Table 1.
TABLE-US-00001 TABLE 1 Cathode electrolytic degreasing Ni strike
Zn--Ni plating Bath Current Process Bath Current Process Bath
Current Process temperature density time temperature density time
temperature density time Step (.degree. C.) (A/dm.sup.2) (sec.)
(.degree. C.) (A/dm.sup.2) (sec.) (.degree. C.) (A/dm.sup.2) (sec.)
Process conditions 50 6 60 35 6 120 25 2 1080
[0087] Plating was performed with different angles of inclination
(al) of the direction of injection (S1) by the nozzles (42) and
with different numbers of nozzles (42), and it was investigated
whether there were plating peels. The presence of plating peels was
visually evaluated using a three-grade scale: "Good" means that
there were no unplated regions; "Normal" means that there were
small unplated regions; and "Bad" means that there were large
unplated regions. The results of investigation are shown in Table
2.
TABLE-US-00002 TABLE 2 Nozzle angle Number Tone of color Category
.alpha. 1 (.degree.) of nozzles Plating peels L value Uniformity
Comp. ex. 20 8 Bad 76 Irregular Inv. ex. 1 45 3 Normal 80.3 Uniform
Inv. ex. 2 35 8 Good 81.1 Uniform Inv. ex. 3 45 6 Good 80.7 Uniform
Inv. ex. 4 60 8 Good 79.5 Uniform
[0088] As shown in Table 2, the comparative example with an angle
of inclination (al) of 20 degrees had a large numbers of plating
peels. On the other hand, inventive examples 1 to 4, which had
angles of inclination (al) larger than 20 degrees, had only limited
numbers of plating peels compared with those of the comparative
example. Particularly, inventive examples 2 to 4, which had six or
more nozzles (42), had no plating peels at all.
[0089] FIG. 9 shows pictures for comparison between the steel (P1)
of inventive example 2 and the steel (P1) of the comparative
example. FIG. 9 shows that the steel pipe (P1) of inventive example
2 had no plating peels, while the steel pipe (P1) of the
comparative example had a large number of plating peels.
[0090] Further, regarding the brightness of color of the plating,
as shown in Table 2, inventive examples 1 to 4 had L values of 79.5
to 81.1, which means substantially uniform silver white, while the
comparative example had an L value of 76, which means a relatively
dark tone, and, as a whole, had irregularities with relatively dark
portions mixed into the silver-white portion.
[0091] FIG. 8 shows the relationship between the composition (Ni
content) and brightness of color (L value) of the Zn--Ni alloy
plating layer. When the Ni content is in the range of 12 to 16 wt.
%, the L value is in the range of 78 to 83, meaning that the tone
of color is silver white. When the Ni content is still higher, the
L value becomes lower, which means a relatively dark tone of color.
That is, it can be concluded that, in each of inventive examples 1
to 4, the composition of the alloy plating layer was in the range
of target composition of the present examples and was substantially
uniform. On the other hand, it can be concluded that, in the
comparative example, portions with higher Ni contents were locally
present and the composition of the alloy plating layer was not
uniform.
[0092] The inventive and comparative examples demonstrate that
inclining the direction in which the nozzles inject plating
solution at an angle larger than 20 degrees and smaller than 90
degrees toward the thread relative to a plane that is perpendicular
to the pipe axis of the steel pipe will minimize plating defects
left after the deposition of an alloy plating layer. The inventive
and comparative examples also demonstrate that having six or more
nozzles will further improve the effect of minimizing plating
defects.
* * * * *