U.S. patent application number 15/891403 was filed with the patent office on 2018-06-14 for corrugated and apertured web.
The applicant listed for this patent is The Procter & Gamble Company. Invention is credited to Richard George Coe, Sarah Beth Gross, John Lee Hammons, Leroy Joseph Kocher, Timothy Ian Mullane, Jill Marlene Orr.
Application Number | 20180162082 15/891403 |
Document ID | / |
Family ID | 47068114 |
Filed Date | 2018-06-14 |
United States Patent
Application |
20180162082 |
Kind Code |
A1 |
Orr; Jill Marlene ; et
al. |
June 14, 2018 |
Corrugated And Apertured Web
Abstract
A web having a micro-textured film and a nonwoven is disclosed
herein. The micro-textured film has a first surface and an opposing
second surface and a plurality of cones extending from the first
surface. A plurality of apertures extends through the web, wherein
the plurality of apertures have sidewalls formed from the
micro-textured film and the nonwoven. The sidewalls extend from the
first surface, and wherein the caliper of the micro-textured film
in the sidewall is less than the caliper of the microtextured film
of the first surface.
Inventors: |
Orr; Jill Marlene; (Liberty
Township, OH) ; Coe; Richard George; (Cincinnati,
OH) ; Hammons; John Lee; (Hamilton, OH) ;
Gross; Sarah Beth; (Harrison, OH) ; Kocher; Leroy
Joseph; (Sunman, IN) ; Mullane; Timothy Ian;
(Union, KY) |
|
Applicant: |
Name |
City |
State |
Country |
Type |
The Procter & Gamble Company |
Cincinnati |
OH |
US |
|
|
Family ID: |
47068114 |
Appl. No.: |
15/891403 |
Filed: |
February 8, 2018 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
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13455925 |
Apr 25, 2012 |
9925731 |
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15891403 |
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13094195 |
Apr 26, 2011 |
8657596 |
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13455925 |
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Current U.S.
Class: |
1/1 |
Current CPC
Class: |
B32B 3/266 20130101;
B29D 28/00 20130101; B32B 3/28 20130101; B29C 55/18 20130101; Y10T
428/24273 20150115; B26F 1/10 20130101; Y10T 428/24322 20150115;
B29C 53/24 20130101 |
International
Class: |
B29D 28/00 20060101
B29D028/00; B32B 3/28 20060101 B32B003/28; B32B 3/26 20060101
B32B003/26; B29C 55/18 20060101 B29C055/18; B29C 53/24 20060101
B29C053/24 |
Claims
1. A web comprising: a micro-textured film comprising a first
surface and an opposing second surface, wherein the micro-textured
film comprises a plurality of cones extending from the first
surface; a nonwoven comprising a plurality of fibers; wherein the
web comprises a plurality of apertures extending therethrough, the
plurality of apertures having sidewalls formed from the
micro-textured film and the nonwoven, wherein the sidewalls extend
from the first surface, and wherein the caliper of the
micro-textured film in the sidewall is less than the caliper of the
microtextured film of the first surface.
2. The web of claim 1, wherein the apertures have a
center-to-center spacing of between 2 mm to 10 mm.
3. The web of claim 1, wherein the apertures are distributed on the
web such that there are greater than 25 apertures per square
inch.
4. The web of claim 1, wherein the apertures are distributed on the
web such that there are greater than 100 apertures per square
inch.
5. The web of claim 1, wherein the apertures are distributed on the
web such that there are between 100 and 250 apertures per square
inch.
6. The web of claim 1, further comprising a total open area of from
5 percent to 25 percent.
7. The web of claim 1, further comprising a total open area of from
9 percent to 21 percent.
8. The web of claim 1, further comprising a total open area of from
14 percent to 20 percent.
9. The web of claim 1, wherein the each of the plurality of
apertures has an open area of between 0.5 square mm to 10 square
mm.
10. The web of claim 1, wherein each of the plurality of apertures
has an open area of between 0.5 square mm to 5 square mm.
11. The web of claim 1, wherein each of the plurality of apertures
has an open area of less than 0.5 square mm.
12. The web of claim 1, wherein each of the plurality of apertures
have an aspect ratio of from 1 to 4.
13. The web of claim 1, wherein each of the plurality of apertures
have an aspect ratio of from 1.25 to 3.
14. The web of claim 1, wherein each of plurality of cones extends
have a height of 120 microns.
15. The web of claim 1, wherein each of the plurality of cones have
a center-to-center spacing of about 462 microns.
16. The web of claim 1, wherein each of the plurality of cones has
a distal end, and wherein each of the plurality of cones has an
aperture at its respective distal end, and wherein each of the
apertures has a diameter of between 175 microns to 200 microns.
17. The web of claim 1, wherein the nonwoven comprises a bonded
carded web and wherein the web has a basis weight of 26 grams per
square meter.
18. The web of claim 1, wherein the nonwoven comprises a spunbonded
nonwoven and wherein the web has a basis weight of 25 grams per
square meter.
19. The web of claim 1, wherein the film are joined together via
extrusion laminating.
20. The web of claim 1, wherein the plurality of fibers comprise
bicomponent fibers.
Description
FIELD OF THE INVENTION
[0001] The present invention is directed to apertured web
materials. More specifically, the webs comprise alternating ridges
and grooves, wherein apertures are located in the grooves.
BACKGROUND OF THE INVENTION
[0002] Various methods and apparatuses for aperturing, deforming,
and/or stretching webs are disclosed in the patent literature. With
an aperturing method such as rotary knife aperturing, it is
difficult to produce a web having closely-spaced apertures wherein
the apertures have desirable widths in the cross-machine direction
("CD"). In order to space aperture rows close together, activation
teeth may be provided which have a very small included angle.
However, this approach poses a problem because apertures are
produced which do not have sufficient aperture width in the CD,
even at high engagement depths (the interference of an activation
tooth roll with a mating ring roll). The resultant apertures are
often elongated in the machine direction--leading to a slit-like
appearance, low open area, and potential stress concentrations
which cause in-use tearing. Creating slit-like, low-open-area
apertures is particularly problematic as tougher and more
tear-resistant webs are utilized. Rounded or tapered hot-pin
aperturing is common, but has the drawback of requiring greater
registration precision for the mating rolls, and it typically
results in greater aperture spacing. Rounded or tapered hot-pin
aperturing is typically run at lower linear speeds.
[0003] Post ring-rolling an apertured web to stretch it is
possible, but can result in alternating rows of aperture sizes
since apertures cannot be lined up with the subsequent ring roll
stretching process. It is difficult to align features in the cross
direction with later processes due to variable spreading of the
substrate. Post ring-rolling can also significantly weaken the web,
making it more prone to tearing.
[0004] It is desirable to produce a web having discrete,
closely-spaced apertures wherein the apertures have larger CD
widths than previously possible. A need exists for an apertured web
which is stronger in the cross-machine direction so it doesn't
easily tear in the cross-machine direction. A need exists for a
method of producing an apertured web having larger, wider, more
open apertures. A need also exists for apparatuses that will allow
a web to be apertured with the apertures having desired,
larger-widths in the cross-machine direction.
[0005] There are many known processes for creating a web with
ridges and grooves, for example ring rolling. There are also many
know processes for creating a web with apertures, for example, hot
pin aperturing. However, it is difficult to produce a corrugated
web having alternating ridges and grooves which are registered to a
specific aperture pattern. Processes exist for micro-aperturing
followed by ring-rolling; however, this results in flattened webs
with no corrugation. A web with ridges and grooves (flat strips)
may be formed via air-jetting or water jetting on a patterned belt.
However, air-jetting or water jetting are much slower processes and
requires more energy than the invention described herein. In
addition, the ridges are not hollow and can retain more fluid.
[0006] It is desirable to produce a web having alternating ridges
and grooves wherein apertures are located in specific positions in
the web, for instance, in the grooves or in the ridges. A need
exists for an apertured web which comprises a registered
corrugation pattern.
[0007] These are all goals of the present invention; embodiments
described herein may achieve various combinations of these goals. A
particular embodiment may, but need not, embody every goal.
BRIEF DESCRIPTION OF THE DRAWINGS
[0008] The accompanying drawings are included to provide a further
understanding of the present inventions. The drawings illustrate
the present inventions described herein, and together with the
description, serve to explain the claimed subject matter.
[0009] FIG. 1 is a perspective view of a prior art pair of ring
rolls for deforming a web.
[0010] FIG. 2A is a perspective view of a prior art pair of
rolls--a rotary knife aperturing (or "RKA") roll and a ring
roll--for aperturing a web.
[0011] FIG. 2B is a side view of the pair of prior art rolls shown
in FIG. 2A.
[0012] FIG. 2C is an enlarged side view of the nip between the
rolls shown in FIG. 2A.
[0013] FIG. 2D is a top view of an exemplary prior art web that can
be formed by using the rolls shown in FIG. 2A.
[0014] FIG. 3A is a perspective view of a pair of rolls for use in
the apparatuses and processes described herein, in which one roll
is a staggered "raised ridge" RKA roll and the other roll is a ring
roll.
[0015] FIG. 3B is an enlarged side view of the nip between the
rolls shown in FIG. 3A.
[0016] FIG. 4A is a perspective view of a portion of the surface of
an exemplary raised ridge RKA roll.
[0017] FIG. 4B is a perspective view of a portion of the surface of
an exemplary ring roll.
[0018] FIG. 4C is a perspective view of a portion of the surface of
an exemplary raised ridge SELF roll.
[0019] FIG. 5A is a perspective view of a portion of the surface of
another exemplary raised ridge RKA roll.
[0020] FIG. 5B is a side view of the tooth arrangement shown in
FIG. 5A.
[0021] FIG. 5C is an end view of the tooth arrangement shown in
FIG. 5A.
[0022] FIG. 5D is a top view of the tooth arrangement shown in FIG.
5A.
[0023] FIG. 5E is a section view along the line D-D of the tooth
arrangement shown in FIG. 5B.
[0024] FIG. 5F is a section view along the line E-E of the tooth
arrangement shown in FIG. 5B.
[0025] FIG. 6A is a front view of a first exemplary set of teeth,
wherein the teeth are tapered and truncated.
[0026] FIG. 6B is a front view of a second exemplary set of teeth,
wherein the teeth are tapered and semi-truncated.
[0027] FIG. 6C is a front view of a second exemplary set of teeth,
wherein the teeth are tapered and non-truncated.
[0028] FIG. 7 is a schematic of a tooth pattern wherein the end
facet angle .gamma. and the ridge finishing can be accomplished in
a single helical machining step.
[0029] FIG. 8 is an enlarged side view of a portion of the surface
of an alternative raised ridge RKA roll.
[0030] FIG. 9A is a top view of one example of a web that can be
formed by using a variation of the rolls in FIG. 3A.
[0031] FIG. 9B is an enlarged view of one of the apertures shown in
FIG. 9A.
[0032] FIG. 10 is a side view of another embodiment of an apparatus
for aperturing a web wherein the three rolls are in a planetary
arrangement.
[0033] FIG. 11 is a top view of a 25 gsm PE film web (film is
stretched/flattened out to show high and low basis weight
regions).
[0034] FIG. 12 is a top view of a 60 gsm PP nonwoven web (nonwoven
is stretched/flattened out to show high and low basis weight
regions).
[0035] FIG. 13 is a cross-section view of the web shown in FIG.
12.
[0036] FIG. 14 is side perspective view of another nonwoven
web.
[0037] FIG. 15 is a top perspective view of a nonwoven web.
[0038] FIG. 16 is a cross-sectional view of a film web.
[0039] FIGS. 17, 18A, and 18B are top views of apertured film webs
described in Example 1.
[0040] FIG. 19A is a top perspective view of an apertured nonwoven
web as described in Example 2.
[0041] FIG. 19B is a bottom perspective view of the web of FIG.
19A.
DETAILED DESCRIPTION
[0042] The following text sets forth a broad description of
numerous different embodiments of the present invention. The
description is to be construed as exemplary only and does not
describe every possible embodiment since describing every possible
embodiment would be impractical, if not impossible. And it will be
understood that any feature, characteristic, component,
composition, ingredient, product, step or methodology described
herein can be deleted, combined with or substituted for, in whole
or part, any other feature, characteristic, component, composition,
ingredient, product, step or methodology described herein. Numerous
alternative embodiments could be implemented, using either current
technology or technology developed after the filing date of this
patent, which would still fall within the scope of the claims. All
publications and patents cited herein are incorporated herein by
reference.
[0043] It should also be understood that, unless a term is
expressly defined in this specification using the sentence "As used
herein, the term `______` is hereby defined to mean . . . " or a
similar sentence, there is no intent to limit the meaning of that
term, either expressly or by implication, beyond its plain or
ordinary meaning, and such term should not be interpreted to be
limited in scope based on any statement made in any section of this
patent (other than the language of the claims). No term is intended
to be essential to the present invention unless so stated. To the
extent that any term recited in the claims at the end of this
patent is referred to in this patent in a manner consistent with a
single meaning, that is done for sake of clarity only so as to not
confuse the reader, and it is not intended that such a claim term
be limited, by implication or otherwise, to that single meaning.
Finally, unless a claim element is defined by reciting the word
"means" and a function without the recital of any structure, it is
not intended that the scope of any claim element be interpreted
based on the application of 35 U.S.C. .sctn. 112, sixth
paragraph.
[0044] The present invention enables an apertured web which is
stronger in the cross-machine direction so it doesn't easily tear
in the cross-machine direction. A process for producing an
apertured web having discrete, closely-spaced apertures with a
desired, larger width in the cross-machine direction is described.
The process can also produce a structure with alternating ridges
and grooves, with apertures contained in the grooves. An apparatus
that will allow a web to be apertured with desired, discrete,
closely-spaced, larger-width apertures in the cross-machine
direction is also described.
[0045] As used herein, the term "absorbent article" includes
disposable articles such as sanitary napkins, panty liners,
tampons, interlabial devices, wound dressings, diapers, adult
incontinence articles, wipes, and the like. Still further, the
absorbent members produced by the processes and apparatuses
disclosed herein can find utility in other webs such as scouring
pads, dry-mop pads (such as SWIFFER.RTM. pads), and the like. At
least some of such absorbent articles are intended for the
absorption of body liquids, such as menses or blood, vaginal
discharges, urine, and feces. Wipes may be used to absorb body
liquids, or may be used for other purposes, such as for cleaning
surfaces. Various absorbent articles described above will typically
comprise a liquid pervious topsheet, a liquid impervious backsheet
joined to the topsheet, and an absorbent core between the topsheet
and backsheet.
[0046] As used herein, the term "absorbent member" refers to the
components of the absorbent article that typically provide one or
more liquid handling functionality, e.g., liquid acquisition,
liquid distribution, liquid transportation, liquid storage, etc. If
the absorbent member comprises an absorbent core component, the
absorbent member can comprise the entire absorbent core or only a
portion of the absorbent core.
[0047] As used herein, the term "aperture" refers to a hole. The
apertures can either be punched cleanly through the web so that the
material surrounding the aperture lies in the same plane as the web
prior to the formation of the aperture (a "two dimensional"
aperture), or holes formed in which at least some of the material
surrounding the opening is pushed out of the plane of the web. In
the latter case, the apertures may resemble a "three dimensional"
aperture. Three dimensional apertures generally maintain more open
area under an applied load. As used herein, the term "apertured"
refers to a web comprising a plurality of apertures.
[0048] As used herein, the term "component" of an absorbent article
refers to an individual constituent of an absorbent article, such
as a topsheet, acquisition layer, liquid handling layer, absorbent
core or layers of absorbent cores, backsheets, and barriers such as
barrier layers and barrier cuffs.
[0049] As used herein, the terms "corrugated" or "corrugation" mean
a three-dimensional web topography comprising a plurality of
generally parallel alternating ridges and grooves, wherein the
ridges and grooves undulate about an axis X (drawn horizontally
through a cross-section of the web). The ridges and grooves may
undulate equally on either side of the axis, or may be
lopsided.
[0050] As used herein, the term "cross-machine direction", "cross
direction", or "CD" means the path that is perpendicular to the
machine direction in the plane of the web.
[0051] As used herein, the term "deformable material" is a material
which is capable of changing its shape or density in response to
applied stresses or strains.
[0052] As used herein, the term "depth of engagement" ("DOE") means
a degree of meshing between two rolls. The distance is measured
from the outermost tip of the tooth or ridges on a first roll to
the outermost tip of the tooth or ridges on a second roll. The
terms "meshing" or "intermeshing," as used herein, refer to
arrangements when the teeth/ridges on one of the rolls extends
toward the surface of the other roll and at least some of the
teeth/ridges have portions that extend between and below an
imaginary plane drawn though the tips of the teeth/ridges on the
surface of the other roll.
[0053] As used herein, the term "discrete" means distinct or
unconnected. When the term "discrete" is used relative to teeth on
a raised ridge roll, it is meant that the distal (or radially
outwardmost) ends of the teeth are distinct or unconnected in all
directions, including in the machine and cross-machine directions
(even though bases of the teeth may be formed into the same surface
of a roll, for example). For example, the ridges on a ring roll are
not considered to be discrete.
[0054] As used herein, the term "disposable" describes absorbent
articles and other products which are not intended to be laundered
or otherwise restored or reused as an absorbent article or product
(i.e., they are intended to be discarded after use and, preferably,
to be recycled, composted or otherwise disposed of in an
environmentally compatible manner).
[0055] As used herein, the term "hollow" describes ridges and
grooves present in a web made by the apparatuses and processes
described herein; the ridges and grooves comprise open spaces
having no web material present. For instance, a web comprises
ridges, grooves, and an X axis drawn horizontally through a
cross-section of the web; the area above the X axis but under the
top of the ridge is hollow, or comprises a hollow area. Likewise,
the area below the X axis but above the bottom of the groove is
hollow, or comprises a hollow area.
[0056] As used herein, the term "machine direction" or "MD" means
the path that material, such as a web, follows through a
manufacturing process.
[0057] As used herein, the term "macroscopic" refers to structural
features or elements that are readily visible and distinctly
discernible to a human having 20/20 vision when the perpendicular
distance between the viewer's eye and the web is about 12 inches
(30 cm). Conversely, as used herein, the term "microscopic" refers
to such features that are not readily visible and distinctly
discernible under such conditions.
[0058] As used herein, the terms "ring roll" or "ring rolling"
refer to a process using deformation members comprising counter
rotating rolls, intermeshing belts, or intermeshing plates
containing at least portions of continuous ridges and grooves where
intermeshing ridges (or projections) and grooves (or recesses) of
deformation members engage and stretch a web interposed
therebetween. Unless otherwise stated, ring rolls alone do not
aperture webs. For ring rolling, the deformation members can be
arranged to stretch the web in the cross machine direction, the
machine direction, or in a helical direction/at an angle to the CD
or MD depending on the orientation of the ridges and grooves.
Examples described herein which pertain to one direction are to be
understood as enabling the non-described directions.
[0059] As used herein, the term "rotary knife aperturing" (RKA)
refers to a process and apparatus using intermeshing deformation
members, or rolls, wherein one or more roll comprises a plurality
of teeth. The teeth can be sharpened to cut through as well as
deform a web to produce an apertured web, or in some cases, a
three-dimensionally apertured web, as disclosed in US
2005/0064136A1 and US 2006/0087053A1.
[0060] The terms "SELF" or "SELF'ing", refer to Procter &
Gamble technology in which SELF stands for Structural Elastic Like
Film. Processes, apparatus, and patterns produced via SELF are
illustrated and described in U.S. Pat. Nos. 5,518,801; 5,691,035;
5,723,087; 5,891,544; 5,916,663; 6,027,483; and 7,527,615 B2. While
the process was originally developed using tooth geometries that
would deform a polymer film without producing apertures, other
tooth geometries have been developed that are more conducive to
forming tufts (in the case of a nonwoven) or tents (in the case of
a film) with apertures on the leading and trailing ends. A process
using SELF'ing to form tufts with apertures in a nonwoven web is
disclosed in U.S. Pat. No. 7,682,686 B2.
[0061] As used herein, the term "teeth" refers to any elements on
the surface of a roll that are capable of aperturing a web.
I. Apertured Web Materials
[0062] While the term "apertured web materials" is utilized herein,
the object is to create components, such as absorbent members (or
non-absorbent members), for absorbent articles from such apertured
web materials. In such cases, the apertured web materials will be
cut into individual components for absorbent articles (such as
topsheets, backsheets, acquisition layers, absorbent cores). In the
case of webs used in absorbent articles, such new structures may
include those that provide improved properties (such as improved
softness, fluid handling, or other properties) in a predetermined
portion of the web. These apertured webs can be cut to form various
other components of products for packaging (e.g., flow wrap, shrink
wrap, and polybags), wipes, facial tissue, toilet tissue, paper
towels, and the like.
[0063] Discrete, closely-spaced apertures having a larger width in
the CD direction can be provided in webs and the components formed
therefrom which are not possible to produce with current methods
and tooling. The new apertures comprise greater open areas and
lower aspect ratios (aperture length:aperture width) which (in the
case of a film) result in increased web strength, as compared to
equivalent open area apertures achievable via the prior art (see
FIG. 2D).
[0064] In addition, webs created with this new technology have a
unique, more textured appearance. The textured webs may comprise
alternating ridges and grooves, wherein apertures are intentionally
contained within the grooves. In the case of the apertured webs
being used for absorbent articles, the web may offer better fluid
acquisition, breathability, or separation from the body, thus
promoting a drier, cleaner feeling. For example, in a sanitary
napkin, apertures located in grooves help channel and transfer
fluid from a topsheet to lower absorbent members. Not only do the
apertures provide these benefits, but any corrugation present in
the final web may additionally support these benefits. For
instance, the corrugation offers at least partial non-contact with
the body, which improves breathability, produces a drier feel, and
promotes less contact with a wet/soiled surface which may irritate
skin or feel uncomfortable. In the case of a sanitary napkin,
corrugations may channel fluid in a longitudinal direction along
the sanitary napkin and keep fluid away from the side edges of the
sanitary napkin.
[0065] The web (or "precursor web") that will be apertured can
comprise any suitable deformable material, such as a woven,
nonwoven, film, flat film, micro-textured film, combination, or
laminate of any of the foregoing materials. As used herein, the
term "nonwoven web" refers to a web having a structure of
individual fibers or threads which are interlaid, but not in a
repeating pattern as in a woven or knitted fabric, which do not
typically have randomly oriented fibers. Nonwoven webs may or may
not comprise thermal bond points. This may include paper
substrates, such as tissue, drylap, liner board, filter paper, and
combinations thereof. Nonwoven webs or fabrics have been formed
from many processes, such as, for example, meltblowing,
spunbonding, hydroentangling, airlaid, wetlaid, through-air-dried
paper making processes, and bonded carded web processes, including
carded thermal bonding. Depending on the forming process, the
nonwoven web may or may not comprise thermal bond points. Film
materials can be single layer, multi-layer, embossed, or
micro-textured. The woven, nonwoven, film, combination, or laminate
can be made of any suitable materials including, but not limited to
natural materials, synthetic materials, and combinations thereof.
Suitable natural materials include, but are not limited to
cellulose, cotton linters, bagasse, wool fibers, silk fibers, etc.
In some embodiments, the web materials may be substantially free of
cellulose, and/or exclude paper materials. In other embodiments,
the processes described herein may be performed on
cellulose-containing precursor materials. Suitable synthetic
materials include, but are not limited to rayon and polymeric
materials. Suitable polymeric materials include, but are not
limited to: polyethylene (PE) (e.g., linear low density
polyethylene (LLDPE), low density polyethylene (LDPE), high density
polyethylene (HDPE), or the like), polyester, polyethylene
terephthalate (PET), and polypropylene (PP). Any of the materials
described above may comprise post-consumer recycled material. The
apparatuses described herein work with a wide range of materials
and lower cost materials. For instance, one can use commodity
spunbond nonwovens, multiple layers with different chemical &
mechanical properties and control the degree of inter-mixing of the
two or more layers, nonwovens with various fiber formulations &
formations; or films. In addition, this apparatus can run directly
on-line (and not lose loft due to roll compression/storage).
[0066] Various polymers can be used to produce the webs of
interest. Potential materials include biopolymers made from
non-petroleum sources such as bio-derived polyethylene (bio-PE),
bio-derived polypropylene (bio-PP), bio-derived polyethylene
terephthalate (bio-PET), and bio-derived
poly(ethylene-2,5-furandicarboxylate) (bio-PEF). These materials
can be partially or completely derived from at least one renewable
resource where a renewable resource refers to a natural resource
that can be replenished within a 100 year time frame. Renewable
resources include plants, animals, fish, bacteria, fungi, and
forestry products and may be naturally occurring, hybrids, or
genetically engineered organisms. Natural resources such as crude
oil, coal, and peat which take longer than 100 years to form are
not considered to be renewable resources. Other polymers derived
from non-petroleum sources include starch-based polymers and
cellulosics. Additionally, recycled resins such as post-consumer
regrind r-HDPE, r-LLDPE, r-LDPE, r-PET, r-PEF, or r-PP can be used
at 100% or blended with various resins. Polymers derived from
renewable resources and recycled resins could be used on their own,
or blended into petroleum-based polymers at varying levels in order
to control the cost. Sources and methods of making polymers from
non-petroleum sources can be found in U.S. Pat. No. 8,063,064 B1
and US 2011/0319849 A1.
[0067] The present inventions are directed to apertured web
materials and apparatuses and processes for aperturing and
stretching a web to create such materials that overcome one or more
of the shortcomings of the prior art. Stretching, or growing, a web
is beneficial because it enables lower costs via overall basis
weight reduction of the web. By aperturing and then stretching in
the same process step, a wider, more preferred aperture is created
in the web material. Here, aperturing and stretching occurs in a
single unit op in a registered manner so that the stretching occurs
while the tooth is still penetrating the material and, therefore,
doesn't allow the aperture to collapse when stretched. The
additional stretching step not only allows an aperture to be wider,
but also has the potential to create a web with a corrugated
appearance. Such an aperturing-then-stretching combination must be
exactly registered. If aperturing and stretching were in separate
steps, like the prior art, the apertures wouldn't be registered
with the stretching ring roll and the apertures may close up. Also,
webs created with this new process are softer and more drapable
from stretching (loosened and/or thinned fibers and/or films).
Thinner webs are generally desirable because less fluid can be
retained by the web. This is important when a web is used as a
topsheet for an absorbent article, as there is less saturation in
the topsheet.
[0068] In one non-limiting embodiment, the apertured web material
comprises a web having discrete apertures formed therein. The web
has a first surface and a second surface opposite the first
surface. The web comprises substantially non-apertured regions, or
lands, which surround a plurality of discrete apertures.
[0069] The apertures are densely packed within a relatively small
area. For example, the center-to-center spacing in any direction
between apertures may be less than or equal to about 20 mm, 10 mm,
5 mm, 3 mm, 2 mm, 1 mm, or 0.5 mm. The total number of apertures in
an area that measures 1 square inch (645 mm.sup.2) may be greater
than or equal to 4, 25, 100, 250, 500, 1000, or 3000. The number of
apertures in a one inch square area can be determined by marking a
square area on the material that measures 1 inch (25.4 mm) by 1
inch with a fine tip pen or marker and counting the number of
first, second, third, etc. apertures that lie fully or partially
within and on the boundary of the 1 inch square. A low power
microscope or other magnifying aid can be used to aid visibility of
the apertures in the material if needed. The apertures may be of
any suitable configuration.
[0070] The apertures may be of any suitable size. Typically, the
apertures will be macroscopic. The plan view area of the apertures
may be greater than or equal to about 0.5 mm.sup.2, 1 mm.sup.2, 5
mm.sup.2, 10 mm.sup.2, or 15 mm.sup.2. The processes described
herein can also be used to create apertures that are microscopic
which have plan view areas less than 0.5 mm.sup.2.
[0071] In addition to apertures, the web may comprise alternating
ridges and grooves, wherein the apertures are located in the
grooves. The ridges may extend continuously or form discontinuous
ridges in the deformed region of the web. The grooves may extend
continuously with apertures spaced at regular intervals within the
grooves. Note that if the web is turned upside-down, the grooves
will become the ridges and the ridges will become grooves, and the
apertures will now be in located in the ridges. The apertures may
be two-dimensional or three-dimensional, depending on the process
and material parameters. In the case of three-dimensional
apertures, the base of the apertures will extend in the opposite
direction of the ridges. The sides of the ridges and sides of the
grooves are more oriented in the z-direction than the tops of the
ridges and bottoms of the grooves.
[0072] In the case of a film, the sides of the ridges and the sides
of the grooves may be thinner and have a lower basis weight than
the tops of the ridges and the bottoms of the grooves as a result
of the stretching process. This results in a web with alternating
regions of higher caliper and basis weight, and regions of lower
caliper and lower basis weight, with the higher caliper and basis
weight regions being located in the tops of the ridges and bottoms
of the grooves, and the regions with lower caliper and basis weight
located in the sidewalls in-between. Alternating basis weight
provides thinned/flexible areas for comfort and maintained
thickness for strength.
[0073] In the case of a nonwoven, the basis weight is also
decreased in the stretched areas, again resulting in a web with
alternating regions of higher and lower basis weight, with the
higher basis weight regions located in the tops of the ridges and
bottoms of the grooves, and the lower basis weight regions located
in the sidewalls in-between. In the case of a nonwoven, the web
thickness may not decrease in the stretched areas because the
fibers may detangle and move away from each other. However, the
thickness of some of the individual fibers may decrease as a result
of the stretching, resulting in fiber diameters that range from 40%
to 80% of the original fiber diameter. The average fiber diameter
at the tops of the ridges and the average fiber diameter at the
bottoms of the grooves may be greater than the average fiber
diameter at the sidewalls. While in tooth lock at the ridges and
grooves, the base web thickness does not vary significantly.
Although the web is textured, the thickness of the web locally at
the ridges and grooves does not vary significantly as the ridges
and grooves are not filled, rather they form hollow areas, because
they have been deformed out of plane. Hollow ridges are not able to
retain as much fluid as filled ridges, which can provide dryness
benefits when used as a topsheet in an absorbent article. As a
result of the stretching, the web permanently elongates in the
direction of the stretching. Suitably, the web thickness in the
stretched areas is from 20% to 80% of the original web
thickness.
II. Prior Art Apparatuses for Deforming Web Materials
[0074] Prior art approaches are not suitable for creating apertures
having wider dimensions in the cross-machine
direction--particularly with tough or tear-resistant films.
Therefore, it is desirable to design a process that enables
aperturing and then stretching in the same process step (i.e.,
within the same nip and while the aperturing teeth are still
penetrating the web) to obtain apertures in the web material which
have larger dimensions in the cross-machine direction than are
obtainable with the prior art approaches. Prior art approaches are
also not suitable for creating webs having alternating ridges and
grooves, with apertures located in the grooves, using high speed
aperturing and stretching means such as that described here.
[0075] FIG. 1 shows a first prior art apparatus 10 in which the
rolls 12 and 14 are referred to herein as ring rolls. The rolls 12,
14, as in the case of the rolls in the other apparatuses shown and
described herein, are carried on respective rotatable shafts having
their axes A of rotation disposed in a parallel relationship. In
all of the embodiments described herein, the rolls are
non-contacting, and axially-driven. In this embodiment, the
surfaces of the rolls have a plurality of alternating grooves 16
and ridges 18 extending around the circumference of the rolls. In
other embodiments, the ridges and grooves may extend parallel to
the axes A of the rolls. One or more such rolls can be used in the
various embodiments of the apparatuses described herein.
[0076] In the embodiment shown in FIG. 1, and the various other
embodiments described herein, the rolls mesh or at least partially
intermesh. As shown in FIG. 1, the rolls typically rotate in
opposite directions (that is, the rolls are counter-rotating). This
is also the case for the other embodiments described herein.
[0077] FIGS. 2A-2C show a second prior art apparatus 20 in which
the top roll 22 is a Rotary Knife Aperturing (or "RKA") roll and
the bottom roll 24 is referred to herein as a ring roll. The
apparatus comprises a pair of counter-rotating, intermeshing rolls,
wherein the top roll 22 comprises pyramidal teeth 30 having four or
more sides, the sides being substantially triangular and being
tapered from a base towards a tip, and the bottom roll 24 comprises
circumferentially-extending grooves 26 and ridges 28. The teeth 30
are arranged in spaced apart circumferential rows with grooves
therebetween. The teeth 30 extend from the top roll 22 at the base,
and the base of the tooth has a cross-sectional length dimension
greater than a cross-sectional width dimension. Typically,
apertures are formed in a web material as the teeth 30 on the RKA
roll 22 intermesh with grooves 26 on the ring roll 24. With respect
to tooth height, tooth spacing, pitch, depth of engagement, and
other processing parameters, RKA and the RKA apparatus can be the
same as described in U.S. Patent Application Publication No. US
2006/0087053 A1.
[0078] The RKA roll 22 shown in FIG. 2A comprises a staggered (vs.
standard) tooth pattern. As used herein, the term "staggered" means
that adjacent teeth do not align in rows in the CD. As used herein,
the term "standard" means that adjacent teeth align in rows in the
CD and thus are non-staggered. As shown in FIG. 2C, the rolls 22
and 24 are aligned in the cross-machine direction such that the
teeth 30 on the RKA roll 22 align with the grooves 26 on the ring
roll 24. As the teeth 30 penetrate the web, the ridges on the
mating ring roll 28 support the web such that the teeth 30 can
penetrate the web and simultaneously form apertures in the opposite
direction. FIG. 2D shows a top view of an exemplary prior art web
34 that can be made by an apparatus like that shown in FIGS. 2A-2C.
The resultant web 34 comprises lands 36 surrounding apertures 38.
Apertures 38 formed by prior art apparatuses like that of FIGS.
2A-2C comprise a length in the machine direction L and a width in
the cross-machine direction W. These apertures are typically
slit-like, having widths W much smaller than lengths L,
particularly with tougher and more recoverable webs.
III. Apparatuses and Processes Employing a Roll with Teeth
Extending from a Raised Ridge to Aperture Web Materials
[0079] In general, the apparatus comprises two intermeshing forming
structures that form a nip therebetween. Forming structures may
comprise rollers, plates, belts, sleeves, other structures capable
of imparting a texture to a web, or combinations thereof. The first
forming structure comprises a plurality of first ridges and first
grooves on the surface of the forming structure, wherein said first
ridges have a top surface and said first grooves have a bottom
surface. The first forming structure further comprises a plurality
of spaced-apart teeth extending outwardly from the top surface of
said first ridges, each tooth being capable of forming an aperture,
wherein the top surface of said first ridge is located between the
tips of said teeth and the bottom surface of said first grooves. A
second forming structure comprises a plurality of continuous second
ridges and second grooves.
[0080] More specifically, the apparatus comprises a single pair of
counter-rotating, intermeshing rolls that form a single nip N
therebetween. Although the apparatuses will be described herein for
convenience primarily in terms of rolls, it should be understood
that the description will be applicable to any suitable apparatus
that may comprise any suitable type(s) of forming members,
including, but not limited to: a pair of rolls; pairs of plates;
conveyors with pucks (or small plates); belts; or combinations
thereof. The first roll and second roll each comprise a surface
106, 108 which comprises a plurality of circumferentially-extending
ridges and grooves. Alternatively, the ridges and grooves could
extend in a direction parallel to the axis of the roll, as long as
it is mated to a roll that has ridges and grooves extending in the
same direction. The first roll additionally comprises a plurality
of spaced-apart teeth, wherein the teeth extend outwardly from the
top surfaces of the ridges. This creates a "raised ridge." The
ridges of the second roll extend toward the axis of the first roll
to a depth beyond the top of at least some of the ridges on the
first roll. In this manner, the initial engagement of the tooth
creates an aperture, which is then stretched in the cross-machine
direction when the engagement proceeds to a depth below the raised
ridge. By first aperturing, and then stretching in one process
step, while the tooth is still penetrating the web, the resulting
apertures have a larger width in the cross-machine direction than
would apertures produced by a standard toothed roll as described
above and shown in FIGS. 2A-2D.
[0081] The apertures of the present invention comprise lower aspect
ratios (aperture length:aperture width) and much higher open areas
than the apertures of the prior art, particularly when utilized
with tougher films, e.g., those containing high levels of LLDPE.
The new tooth geometry facilitates a high open area at lower
tooling temperatures, enabling the formation of apertures in webs
which could not be apertured with traditional tooth geometry. The
new tooling geometry provides the ability to aperture webs at lower
heats (e.g., between 35 and 70 degrees Celsius) or even at ambient
temperatures rather than requiring the heating of the apparatus.
Further, there are minimal to lower costs involved to create this
tooling vs. prior tooling since, inter alia, less metal is removed.
Accordingly, room temperature precursor webs may be used. In one
embodiment, the precursor web and intermeshing rolls are not
heated. Or, overall preheated webs may be used. Or, zoned
preheating of webs may enable apertures in some zones and bubbles
in others. Preheating may be accomplished by wrapping the RKA roll
prior to engagement (with varying wrap times prior to engagement
possible) or, by wrapping the ring roll prior to engagement.
Likewise, heated or non-heated tooling may be used. Suitably, the
web is heated by wrapping the RKA roll heated to 50-200 deg C., or
50-100 deg C. The RKA roll and ring roll may be driven at identical
speeds of the outermost surface or there may be a speed
differential between the two rolls.
[0082] The following figures show non-limiting examples of specific
roll arrangements and the apertured web materials that can be
formed thereby. These apparatuses are able to utilize a single nip,
and run at higher processing speeds, with no heat in some cases,
and at less expense than prior art methods for aperturing and
stretching (e.g., since it is a simple mechanical process--just two
intermeshing rolls).
[0083] FIGS. 3A and 3B show an exemplary apparatus 100 of the
present invention which comprises a single pair of
counter-rotating, intermeshing rolls 102, 104 that form a single
nip N therebetween. The first (top) roll 102 is a variation of the
RKA roll shown in FIG. 2A. This particular variation will be
referred to herein as a "raised-ridge RKA roll." The second
(bottom) roll 104 in the apparatus 100 shown in FIGS. 3A and 3B is
a ring roll.
[0084] As shown in FIG. 4A, the first roll 102 comprises a
plurality of grooves 110 and ridges 120 and a plurality of
staggered, spaced-apart teeth 130 extending outwardly from the top
surface 122 of the ridges 120. The configuration of the roll 104 is
such that the top surface 122 of the ridges 120 is disposed between
the tips 134 of the teeth 130 and the bottom surface 112 of the
grooves 110, directionally relative to the axis A of the roll. As
shown in FIG. 4B, the second roll 104 comprises a plurality of
grooves 140 and ridges 150. The grooves 140 have a bottom surface
142 and the ridges 150 have a top surface 152. Here, the distance
between the top surfaces 152 of the ridges 150 and the bottom
surfaces 142 of the grooves 140 is substantially the same around
the circumference of the roll. FIG. 4C is an alternative second
roll 104B in the form of a raised ridge staggered CD SELF roll. The
configuration of the roll 104B is such that the top surface 122 of
the ridges 120 is disposed between the tips 134 of the teeth 130
and the bottom surface 112 of the grooves 110, directionally
relative to the axis A of the roll. Turning back to FIGS. 3A and
3B, the teeth 130 and ridges 120 of the first roll 102 extend
toward the axis A of the second roll 104, intermeshing to a depth
beyond the top 152 of at least some of the ridges 150 on the second
roll 104.
[0085] Teeth suitable for this process must be conducive to
aperturing webs. The teeth on the rolls may have any suitable
configuration. A given tooth can have the same plan view length and
width dimensions (such as a tooth with a circular or square shaped
plan view). Alternatively, the tooth may have a length that is
greater than its width (such as a tooth with a rectangular plan
view), in which case, the tooth may have any suitable aspect ratio
of its length to its width. Suitable configurations for the teeth
include, but are not limited to: teeth having a triangular-shaped
side view; square or rectangular-shaped side view; columnar shaped;
pyramid-shaped; teeth having plan view configurations including
circular, oval, hour-glass shaped, star shaped, polygonal, and the
like; and combinations thereof. Polygonal shapes include, but are
not limited to rectangular, triangular, pentagonal, hexagonal, or
trapezoidal. The side-walls of the teeth may taper at a constant
angle from the base to the tip, or they may change angles. The
teeth may taper towards a single point at the tooth tip, like that
shown in FIG. 4A. The teeth can have tips that are rounded, flat or
form a sharp point. Alternatively, the teeth may taper towards a
multi-point, elongated tooth tip, like the SELF teeth shown in FIG.
4C. However, the tip of the tooth must form a sharp vertex with at
least one of the vertical walls of the tooth (for example, the
vertical walls on the leading and trailing ends of the teeth as
shown in FIG. 4C), so the teeth aperture or puncture the web. In
the case of the teeth shown in FIG. 4C, each tooth may form 2
apertures, one at the leading edge and one at the trailing edge of
each tooth.
[0086] In one exemplary embodiment shown in FIGS. 5A-F, the first
roll 102 comprises a plurality of pyramid-shaped teeth 130
extending outwardly from the top surface 122 of the ridges 120.
FIG. 5A is a perspective view of a portion of the surface of
another exemplary raised ridge RKA roll. FIG. 5B is a side view,
FIG. 5C is an end view, and FIG. 5D is a top view of the tooth
arrangement shown in FIG. 5A. FIG. 5E is a section view along the
line D-D of the tooth arrangement shown in FIG. 5B. FIG. 5F is a
section view along the line E-E of the tooth arrangement shown in
FIG. 5B. The tooth cross-sectional area A.sub.t shown in FIG. 5E is
less than the tooth cross-sectional area A.sub.tb shown in FIG. 5F.
The sides (e.g., 130a-130f shown in FIG. 5E) are substantially
triangular and tapered at a constant angle from a tip 134 to a base
132. The number of sides may be four (e.g., FIG. 4A), six (e.g.,
FIGS. 5A-6C), or another number less than or equal to twelve. The
teeth 130 are arranged in spaced-apart circumferential rows with
grooves 110 therebetween. The MD tip-to-tip tooth spacing S.sub.MD
is from 0.4 mm to 15 mm (or from 3 mm to 8 mm). The CD pitch P is
from 0.4 mm to 10 mm (or from 1 mm to 3 mm). The teeth have an
included angle .alpha. of from 30 to 90 degrees (or from 45 to 65
degrees), a side wall angle .beta. on the long side of the teeth
(e.g., 130c, 130f) of from 3 to 15 degrees, and an end-facet
included angle .gamma. of the leading and trailing edges of the
teeth (e.g., the angle between sides 130a and 130b or the angle
between sides 130d and 130e) of from 45 to 120 degrees (or from 60
to 90 degrees). In some cases, the MD and CD tooth spacing,
staggering, and included end-facet angle .gamma. are chosen when
the teeth are created by helical grinding.
[0087] There are different ways to finish the portion 136 where the
teeth 130 and ridge surface 122 meet, for instance, truncated (FIG.
6A), wherein the taper on each side is cut off by a plane;
semi-truncated (FIG. 6B), wherein the taper on at least one side is
cut off by an arc; or non-truncated (FIG. 6C), wherein the taper on
each side is not cut off in any manner. The teeth 130 shown in FIG.
6A taper from the tip 134 towards the base 132 and have a truncated
lower portion 136. The taper and/or truncation may occur at
different degrees. A truncated taper on a tooth makes the tooth
easier to manufacture. In this case, referring to FIG. 7, the end
facet angle .gamma. and the ridge finishing can be accomplished in
a single helical machining step as is well known in fabrication
practices, by rotating the tooling in the circumferential direction
Dc while simultaneously advancing the machining in the axial
direction of the tooling. The end facet of the tooth 130 will be
created following the machining path M.sub.P. For a tooth stagger
Ts, the included end facet angle .gamma. is thus created as
2*Arctan (CD Tooth Pitch "P"/Tooth Stagger "T.sub.S").
[0088] The top surfaces 122 of the ridge between the teeth 130 may
be finished in different manners. For instance, the surface 122 may
be radiused or non-radiused. A radiused surface would protect the
web from tears during forming, particularly in the case of a film,
while a non-radiused surface (such as the surface 122 shown in
FIGS. 6A-6C) may be more cost effective.
[0089] The configuration of the raised ridge RKA roll 102 is such
that the top surface 122 of the ridges 120 are disposed between the
tips 134 of the teeth 130 and the bottom surface 112 of the grooves
110, directionally relative to the axis A of the roll 102. The
tooth height h.sub.t is defined as the distance between the tip 134
of the tooth 130 and the bottom surface 112 of the grooves 110. The
tooth height h.sub.t is from 1 mm to 12 mm, or from 2 mm to 8 mm,
or from 3 mm to 6 mm. The ridge height h.sub.r is at least 20%,
typically from 20% to 95%, of the tooth height. The cross-cut depth
d.sub.cc is defined as the distance between the tip 134 of the
tooth 130 and the top surface 122 of the ridge 120. In this
embodiment, the distance between the tip 134 of the tooth 130 and
the top surface 122 of the ridge 120 is substantially the same
around the circumference of the roll. The cross-cut depth d.sub.cc
depends on the amount of deformation that is required to form the
apertures. For example, the cross-cut depth d.sub.cc may be within
the range of 0.2 mm to 9 mm, or from 1.0 mm to 4.0 mm or from 2.0
mm to 3.5 mm A smaller cross-cut depth d.sub.cc (at the same DOE)
creates a more open aperture. The depth of engagement of the pair
of rolls 102, 104 must be greater than the cross-cut depth
d.sub.cc. Suitably, the depth of engagement is at least 0.1 mm
greater or 0.3 mm greater than the cross-cut depth. The DOE at the
nip N is from 0.5 mm to 10 mm, or from 3 mm to 7 mm, or from 3 mm
to 4 mm.
[0090] The ridge height h.sub.r is defined as the distance between
the top surface 122 of the ridge 120 and the bottom surface 112 of
the grooves 110. In some embodiments, such as shown in FIGS. 3B and
4A, the first roll 102 comprises a cross-direction width, and the
distance between the top surfaces 122 of the ridges 120 and the
bottom surfaces 112 of the grooves 110 is substantially the same
around the circumference and across the CD width of the roll 102.
Or, the distance between the top surfaces of the first ridges and
the bottom surfaces of the second grooves can vary around the
circumference or across the CD width of the first roll. Various
alternative embodiments of the raised ridge rolls are possible. For
example, as shown on roll 162 in FIG. 8, the height of the ridges
h.sub.r may vary between at least some of the teeth 168. The ridge
height h.sub.r depends on the amount of deformation that is
required to form the desired apertures. The top surface 166 of at
least one ridge 164 between a pair of teeth 168 will have a height
h.sub.r1 that is at least 10%, 20%, or 30% greater than the height
h.sub.r2 of another ridge 164 between another pair of pair of teeth
168. This roll 162 could be used in a process such as that shown in
FIG. 3A in place of the raised-ridge RKA roll 102. The second roll
may be a ring roll with ridges of different heights in either the
circumferential or axial directions.
[0091] FIG. 9A shows an example of a web 170 which can be made by
the apparatus shown in FIG. 3A: an RKA raised-ridge roll with a
staggered tooth pattern for the upper roll 102 and a ring roll for
the lower roll 104. The rolls 102 and 104 are aligned in the
cross-machine direction such that the teeth 130 on the first roll
102 align with the grooves 140 on the second roll 104. As the teeth
130 on the first roll 102 penetrate the web 170, the ridges 120
between the teeth 130 on the RKA raised ridge roll 102 support the
web 170 such that the ridges 150 on the second roll 104 can stretch
the web 170 in the cross-machine direction.
[0092] The web in its initial state can be thought of as being
relatively flat, and comprised entirely of non-apertured regions.
The web 170 has a first surface 170A and a second surface 170B.
When the web is fed in the machine direction into the nip N between
the rolls (e.g., those shown in FIG. 3A), the web is: (i) apertured
by the teeth 130 of the first roll 102 to form a plurality of
spaced apart apertures 172; and (ii) stretched by the ridges 120 of
the first roll 102 to stretch the apertures 172 in the
cross-machine direction. As shown in the FIG. 9A web top view, the
result is an apertured web 170 comprising apertures 172 and lands
174 surrounding the apertures 172. The apertures 172 may be pushed
out of the plane of the web 160 in one direction (downward as
viewed in FIG. 9A) thus the aperture 172 may have a height H.sub.a.
The apertures 172 are aligned in rows in the MD and the CD. FIG. 9B
shows an enlarged top view of a single aperture 172. The apertures
172 comprise a length in the machine direction L.sub.a and a width
in the cross-machine direction W.sub.a. The apertures will
preferably have a length-divided-by-width aspect ratio AR of from 1
to 4, or from 1.25 to 3, or from 1.5 to 2.5, or from 1.6 to 2.3.
The apertures 172 further comprise an individual open area A.sub.a
and a perimeter surrounding the open area P.sub.a. The apertured
web comprises a total open area of from 5% to 25%, or from 9% to
21%, or from 10% to 16%, or from 14% to 20% of the total web area.
The apertured film comprises a tear, or tensile, strength (per 25.4
mm) in the cross-machine direction in the range of 1.5 N to 5 N, 2
N to 4 N, 2.5 N to 4 N, 2.5 N to 3.5 N, or 2.7 N to 3.9 N. The
apertured nonwoven comprises a tensile strength (per 25.4 mm) in
the cross-machine direction in the range of 2 N to 20 N, or higher.
In one example, a web comprises a machine direction orientation and
a cross-machine direction orientation, wherein the apertures
comprise a length in the machine direction and a width in the
cross-machine direction, and wherein a plurality of apertures
comprise a length-divided-by-width aspect ratio of 1 to 4.
[0093] In some embodiments, the stretching step described above not
only increases the CD width of the aperture, but also creates
alternating ridges and grooves, where the apertures are located in
the grooves. The portion of the web that is in contact with the
ridges on the two rolls friction locks on the tops of the ridges
and is not stretched, while the web in-between the ridges is
stretched out of plane. The portion of the web that is stretched
out of plane becomes more oriented in the z-direction. As a result,
a web with ridges and grooves may be formed, with the apertures
located in the grooves. Note that if the web is turned upside-down,
the grooves will become the ridges and the ridges will become
grooves, and the apertures will now be in located in the ridges.
The fibers at the tops of the ridges and the fibers at the bottoms
of the grooves may be more oriented in an X-Y plane than are the
fibers at the sidewalls.
[0094] In the case of a film, the web is thinned and the basis
weight is decreased in the stretched regions, while the web
thickness and basis weight are maintained in the regions of the web
that are friction locked on the ridges of the rolls. This results
in a web with alternating regions of higher and lower caliper, and
alternating regions of higher and lower basis weight, with the
higher caliper and higher basis weight regions being located in the
tops of the ridges and bottoms of the grooves, and the regions with
lower caliper and lower basis weight located in the sidewalls
in-between. FIG. 11 is a top view of a 25 gsm PE film web 210 (film
is stretched/flattened out to show high basis weight regions 212
and low basis weight regions 214). Web 210 further shows ridges R,
grooves G, and sidewalls S. Apertures 216 are present in the
grooves G. As apparent, the high basis weight regions 212 are
located in the ridges R and grooves G, whereas the low basis weight
regions 214 are located in the sidewalls S.
[0095] In the case of a nonwoven, the basis weight is also
decreased in the stretched areas, again resulting in a web with
alternating regions of higher and lower basis weight, with the
higher basis weight regions located in the tops of the ridges and
bottoms of the grooves, and the lower basis weight regions located
in the sidewalls in-between. FIG. 12 is a top view of a 60 gsm
polypropylene nonwoven web 220 (nonwoven is stretched/flattened out
to show high basis weight regions 222, and low basis weight regions
224). Web 220 further shows ridges R, grooves G, and sidewalls S.
Apertures 226 are present in the grooves G. Thermal or fusion bond
points 228 may be present in various locations on the web 220. As
apparent, the high basis weight regions 222 are located in the
ridges R and grooves G, whereas the low basis weight regions 224
are located in the sidewalls S. In the case of a nonwoven, the web
thickness may not decrease in the stretched regions because the
fibers may detangle and move away from each other. However, the
thickness of some of the individual fibers may decrease as a result
of the stretching. Note that the "regions" of the web used to
characterize basis weight exclude the apertures themselves.
[0096] As a result of the stretching, the web permanently elongates
in the direction of the stretching. If the web remains in its
corrugated state, the majority of the increased web width is taken
up by the ridges and grooves that are formed in the web.
Alternatively, tension could be applied to expand the web, which
would result in a decrease in the height and frequency of the
ridges and grooves, and decrease the web's overall basis weight. If
desired, the web could be expanded such that ridges and grooves no
longer exist, and the web is back to its flattened state. This
deformation process may stretch or grow a web by 10%, by 15%, by
20%, by 25%, or more in the CD. The amount of permanent stretch and
degree of formation of the ridges and grooves depends on the
tooling geometry, process conditions and the properties of the
materials. Typically this process will permanently stretch or grow
a non-woven web material further than a film material. For example,
a web may grow from 165 mm to 190 mm in the CD. Suitably, the web
has an initial web basis weight and the lower basis weight regions
have a basis weight which is lower than the initial web basis
weight.
[0097] FIG. 13 is a cross-section view of the web 220 shown in FIG.
12 showing ridges R, grooves G, and axis X drawn horizontally
through a cross-section of the web; the area above the X axis but
under the top of the ridge is hollow, or comprises a hollow area
HA. Likewise, the area below the X axis but above the bottom of the
groove is hollow, or comprises a hollow area HA. Suitably, the web
thickness at the tops of the ridges and the web thickness at the
bottoms of the grooves are similar. The web thickness at the tops
of the ridges and the web thickness at the bottoms of the grooves
may be similar to the web thickness at the sidewalls. By similar,
it is meant that the thicknesses are within about 60% of one
another. Or, the web thickness at the tops of the ridges and the
web thickness at the bottoms of the grooves is greater than the web
thickness at the sidewalls. FIG. 14 is side perspective view of
another nonwoven web 230 having ridges 232, grooves 234, and
sidewalls 236. FIG. 15 is a top perspective view of 28 gsm
polyethylene/polypropylene bico nonwoven web 240 comprising ridges
242 and grooves 244 and apertures 246 wherein the aperture width
W.sub.a is greater than the ridge width W.sub.r. FIG. 16 is a
cross-sectional view of a film web 250 showing greater thinning at
the sidewall 256 than at the top of the ridge 252 or bottom of the
groove 254.
[0098] The processes of interest herein may also utilize multiple
deformation steps in order to more gently deform the material or to
impart a greater amount of permanent deformation. Such multiple
deformation steps can be carried out by any suitable apparatuses
described in U.S. patent application Ser. No. 13/094,195 to Lake,
et al. Suitably, at least the first roll or the second roll also
forms a nip with one or more additional rolls to thereby further
stretch or deform the web. In one arrangement 200, as shown in FIG.
10, a ring roll 202 is mated to a raised-ridge roll 204 which is in
turn mated to another ring roll 206 such that the rolls are in a
planetary or satellite configuration. Processes utilizing multiple
deformation steps may also be carried out on nested apparatuses
having a relatively small number of rolls in a nested arrangement,
or such apparatuses as the hybrid, closed loop, and shared bank
with any suitable number of rolls in order to carry out the desired
deformation.
[0099] Numerous alternative embodiments of the apertured web
materials and processes of making the same are possible. For
example, web materials can be provided which have different zones
(including deformed zones and/or undeformed zones) across their
surface with different features therein. The zones may by at least
one feature selected from the group consisting of: ridge height,
ridge spacing, aperture size, fiber diameter, film thickness, or
combinations thereof. In one embodiment, an apertured web material
can be provided which has zones of apertures, and in some cases,
ridges and grooves. Webs disclosed herein may contain zones with
different sizes of apertures and/or different sizes and frequencies
of ridges and grooves. The web can comprise one or more layers. In
another embodiment, the film is a micro-textured film comprising
stretched areas and unstretched areas, wherein the stretched areas
have micro-texture properties differing from the unstretched areas,
and wherein the micro-textured properties are selected from the
group consisting of open area, size, orientation, and combinations
thereof. Webs made by the processes and apparatuses described
herein may comprise ridges that run discontinuously across a
deformed zone, or, ridges that run continuously across a deformed
zone. To create such apertured web materials, the ring roll used
may comprise zones of ridges and grooves. Or, the ring roll can
have zones where the ridges are different heights, thereby creating
differing depth of engagement (DOE), differing depth below the
raised ridge, and thus apertures with differing widths and open
areas. Alternatively or in addition, the raised ridge roll may
comprise different zones, wherein ridge heights are different in
different zones.
EXAMPLES
Example 1
[0100] In one non-limiting example for making apertures in a
polymer film, like the web 300 shown in FIG. 17 (comprising
micro-apertures 312 and macro-apertures 314), an apparatus can be
used that comprises a 1.5 mm pitch raised ridge RKA roll
intermeshed with a 1.5 mm pitch ring roll at 3.8 mm depth of
engagement. The raised ridge RKA roll has teeth that are oriented
so the long direction runs in the MD. The teeth are arranged in a
staggered pattern as shown in FIG. 5A. The teeth have a pyramidal
shape with 6 sides that taper from the base to a sharp point at the
tip, and have a height h.sub.t of 4.7 mm. The teeth have an
included angle (.alpha. from FIG. 5B) of 62 degrees, a side wall
angle on the long side of the tooth of about 6 degrees (.beta. from
FIG. 5C), and an end facet included angle of 90 degrees (.gamma.
from FIG. 5E). The ridges that span between the teeth on the RKA
roll are non-radiused and form a flat surface. The teeth are
finished at the ridge in a semi-truncated format as shown in FIG.
6B. The ridges and grooves extend circumferentially around the ring
roll.
[0101] There are two different sections of teeth on the roll, which
are exhibited to demonstrate the benefits of the raised ridge and
referred to individually as "Section A" and "Section B". Section A
has a MD tooth spacing S.sub.MD tip to tip of 4.9 mm, a cross cut
depth (d.sub.cc in FIG. 6A) of 3.6 mm and resultant ridge height
(h.sub.R in FIG. 6A) of 1.1 mm. Section B has a MD tooth spacing
S.sub.MD tip to tip of 3.7 mm, a cross-cut depth d.sub.cc of 2.7
mm, and resultant ridge height h.sub.r of 2.0 mm.
[0102] The mating ring roll is 1.5 mm pitch with a height of 4.8
mm, a tip radius of 0.12 mm, and a side wall angle of about 4
degrees. Both rolls have a diameter of about 205 mm, and are heated
to 80 deg C. The RKA roll and ring roll are aligned in the CD such
that the clearances on either side of the teeth are about
equal.
[0103] The precursor web is a micro-apertured polymer film at a
basis weight of 26 g/m.sup.2, with a blend of LLDPE and LDPE,
obtained from RKW-Group, Germany. LLDPE comprises about 60% of the
film composition, LDPE about 30%, and inerts and fillers such as
TiO.sub.2 and the carrier resins thereof the remaining 10%. The
micro-apertures are 55 mesh (apertures per inch in orthogonal
directions), arranged in an equilateral triangle pattern with
center-to-center spacings of about 462 microns. Aperture diameters
are 175-200 microns and tapered cone heights of approximately 120
microns.
[0104] The precursor web is pre-wrapped on the ring roll prior to
passing between the intermeshing rolls at a linear web speed of 480
meters/min. The micro-apertured cones side of the film is placed
facing the RKA roll. A depth of engagement of 3.8 mm is used. The
resultant films are shown in low magnification in FIGS. 18A and
18B. The open areas (% of film area with an open aperture),
aperture lengths, and aperture widths of said films are measured
with a vision system, such as can be purchased from Cognex
Corporation of Natik, Mass., under the IN-SIGHT tradename. The open
area, length and width comparison of apertures from Section A (FIG.
18A) vs. Section B (FIG. 18B) are shown in the table below. FIGS.
18A and 18B depict film webs 320, 340 having micro-apertures 322,
342 and apertures 324, 344.
TABLE-US-00001 Cross-Cut Raised Ridge Aperture Aperture Depth
Height Open Length Width d.sub.CC (mm) h.sub.R (mm) Area % (mm)
(mm) Section A 3.6 1.1 5.76 1.20 0.52 Section B 2.7 2.0 14.63 1.40
0.63
Example 2
[0105] In one non-limiting example for making a corrugated web
having apertures in the grooves, an apparatus can be used that
comprises a 2.0 mm pitch raised ridge RKA roll intermeshed with a
2.0 mm pitch ring roll at 6.3 mm depth of engagement. The raised
ridge RKA roll has teeth that are oriented so the long direction
runs in the MD, and the ridges and grooves extend circumferentially
around the ring roll. The teeth are arranged in a staggered pattern
as shown in FIG. 5A. The teeth have a pyramidal shape with 4 sides
that taper from the base to a sharp point at the tip, and have a
height h.sub.t of 6.9 mm. The teeth have an included angle (.alpha.
from FIG. 5B) of 57 degrees and a side wall angle on the long side
of the tooth of about 5 degrees (.beta. from FIG. 5C). The ridges
that span between the teeth on the RKA roll are not rounded and
form a flat surface. The teeth are finished at the ridge in the
non-truncated format as shown in FIG. 6C. The teeth have an MD
tooth spacing S.sub.MD tip to tip of 8.0 mm, a cross cut depth
(d.sub.cc in FIG. 6A) of 3.7 mm and resultant ridge height (h.sub.R
in FIG. 6A) of 3.2 mm.
[0106] The mating ring roll is 2.0 mm pitch with a height of 6.9
mm, a tip radius of 0.12 mm, and a side wall angle of about 4
degrees. Both rolls have a diameter of about 142 mm. The RKA roll
and ring roll are aligned in the CD such that the clearances on
either side of the teeth are about equal.
[0107] The first precursor web is a polymer film at a basis weight
of 25 g/m2, with a blend of LLDPE and LDPE, obtained from Clopay
Plastics Co. in Ohio. The precursor web is pre-wrapped on the ring
roll prior to passing between the intermeshing rolls at a linear
web speed of 20 meters/min. The resultant corrugated, apertured
film is shown in FIG. 11 (film is stretched/flattened out to show
high and low basis weight regions). Images were taken at low
magnification using an optical microscope, such as can be purchased
from Allasso Industries, using red LED back lighting.
[0108] The second precursor web is a thermally bonded polypropylene
nonwoven at a basis weight of 60 g/m2, obtained from Fiberweb in
France. The precursor web is pre-wrapped on the ring roll prior to
passing between the intermeshing rolls at a linear web speed of 20
meters/min. The resultant corrugated, apertured nonwoven is shown
in FIG. 12 (top view; web is stretched/flattened out to show high
and low basis weight regions), FIG. 13 (cross-section view), FIG.
19A (raised-ridge RKA side), and FIG. 19B (ring roll side) Images
were taken at low magnification using an optical microscope, such
as can be purchased from Allasso Industries. The web 400 in FIGS.
19A and 19B comprises alternating ridges 402 and grooves 404;
apertures 406 are present in the grooves 404.
[0109] The dimensions and values disclosed herein are not to be
understood as being strictly limited to the exact numerical values
recited. Instead, unless otherwise specified, each such dimension
is intended to mean both the recited value and a functionally
equivalent range surrounding that value. For example, a dimension
disclosed as "40 mm" is intended to mean "about 40 mm" Furthermore,
the numerical ranges recited herein include each discrete numerical
value as well as any other narrower range which lies within the
range. It should be understood that every maximum numerical
limitation given throughout this specification includes every lower
numerical limitation, as if such lower numerical limitations were
expressly written herein. Every minimum numerical limitation given
throughout this specification will include every higher numerical
limitation, as if such higher numerical limitations were expressly
written herein. Every numerical range given throughout this
specification will include every narrower numerical range that
falls within such broader numerical range, as if such narrower
numerical ranges were all expressly written herein.
[0110] All documents cited in the Detailed Description of the
Invention are, in relevant part, incorporated herein by reference;
the citation of any document is not to be construed as an admission
that it is prior art with respect to the present invention. To the
extent that any meaning or definition of a term in this written
document conflicts with any meaning or definition of the term in a
document incorporated by reference, the meaning or definition
assigned to the term in this written document shall govern.
[0111] While particular embodiments of the present invention have
been illustrated and described, it would be obvious to those
skilled in the art that various other changes and modifications can
be made without departing from the spirit and scope of the
invention. It is therefore intended to cover in the appended claims
all such changes and modifications that are within the scope of
this invention.
* * * * *