U.S. patent application number 15/564546 was filed with the patent office on 2018-03-22 for flexible container with fitment.
The applicant listed for this patent is Dow Global Technologies LLC. Invention is credited to Jeffrey E. Bonekamp, Ryan S. Gaston, Rashi Tiwari, Mark W. Vansumeren, Kenneth R. Wilkes.
Application Number | 20180079573 15/564546 |
Document ID | / |
Family ID | 55806784 |
Filed Date | 2018-03-22 |
United States Patent
Application |
20180079573 |
Kind Code |
A1 |
Wilkes; Kenneth R. ; et
al. |
March 22, 2018 |
Flexible Container with Fitment
Abstract
The present disclosure provides a flexible container. In an
embodiment, the flexible container includes (A) four panels, each
panel comprising a flexible multilayer film. The flexible
multilayer film includes a polymeric material composed of a
polymeric material. The four panels form (i) a body, and (ii) a
neck. The flexible container includes (B) a fitment having a top
portion and a base. The fitment is composed of a polymeric
material. The base is sealed in the neck. The base has (C) a
cross-sectional shape with a diameter (d), and the base has a wall
thickness (WT). The base has a d/WT ratio wherein the d/WT ratio
(in mm) is from 35 to 800.
Inventors: |
Wilkes; Kenneth R.;
(Asheville, NC) ; Gaston; Ryan S.; (Freeport,
TX) ; Bonekamp; Jeffrey E.; (Midland, MI) ;
Tiwari; Rashi; (Freeport, TX) ; Vansumeren; Mark
W.; (Midland, MI) |
|
Applicant: |
Name |
City |
State |
Country |
Type |
Dow Global Technologies LLC |
Midland |
MI |
US |
|
|
Family ID: |
55806784 |
Appl. No.: |
15/564546 |
Filed: |
April 6, 2016 |
PCT Filed: |
April 6, 2016 |
PCT NO: |
PCT/US2016/026113 |
371 Date: |
October 5, 2017 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
|
|
62146021 |
Apr 10, 2015 |
|
|
|
Current U.S.
Class: |
1/1 |
Current CPC
Class: |
B65B 61/186 20130101;
B65B 61/005 20130101; B65B 3/045 20130101; B65D 2575/586 20130101;
B65D 75/5872 20130101; B65D 75/5866 20130101; B65D 75/5883
20130101; B65D 75/008 20130101; B65D 75/28 20130101; B65D 75/563
20130101 |
International
Class: |
B65D 75/00 20060101
B65D075/00; B65D 75/58 20060101 B65D075/58; B65B 61/18 20060101
B65B061/18 |
Claims
1. A flexible container comprising: (A) four panels, each panel
comprising a flexible multilayer film comprising a polymeric
material, the four panels forming (i) a body, and (ii) a neck; (B)
a fitment comprising a top portion and a base, the fitment composed
of a polymeric material, the base sealed in the neck; and (C) the
base has a cross-sectional shape with a uniform diameter (d), the
base has a wall thickness (WT), wherein the d/WT ratio (in mm) is
from 35 to 800.
2. The flexible container of claim 1 wherein the cross-sectional
shape of the base is selected from the group consisting of circle
and regular polygon.
3. The flexible container of claim 1 wherein the cross-sectional
shape of the base is a circle.
4. The flexible container of claim 1 wherein the cross-sectional
shape of the base is a square.
5. The flexible container of claim 1 wherein the diameter of the
base is greater than the diameter of the top portion.
6. The flexible container of claim 1 wherein the diameter (d) is
from 10 mm to 120 mm.
7. The flexible container of claim 1 wherein the wall thickness
(WT) is from 0.15 mm to 0.75 mm.
8. The flexible container of claim 1 wherein the polymeric material
for the fitment is selected from the group consisting of
propylene-based polymer, ethylene-based polymer, polyamide, cyclic
olefin copolymer, polyester, copolyester, cellulose ester, and
combinations thereof.
9. The flexible container of claim 1 wherein polymeric material for
the fitment is an ethylene-based polymer having a 2% secant
flexural modulus from 10 MPa a to less than 200 MPa.
10. The flexible container of claim 1 wherein the flexible
multilayer film has a clarity greater than 80% and haze less than
20% (at 0.5 mm thickness).
11. The flexible container of claim 1 wherein the polymeric
material for the fitment has clarity greater than 80% and haze less
than 20% (at 0.5 mm thickness).
12. The flexible container of claim 1 comprising a hermetic seal
between the neck and the base.
Description
BACKGROUND
[0001] The present disclosure is directed to a flexible container
with a dispensing fitment and a standup flexible container with a
dispensing fitment in particular.
[0002] Flexible packaging is known to offer significant value and
sustainability benefits to product manufacturers, retailers and
consumers as compared to solid, molded plastic packaging
containers. Flexible packaging provides many consumer conveniences
and benefits, including extended shelf life, easy storage,
microwavability and refillability. Flexible packaging has proven to
require less energy for creation and creates fewer emissions during
disposal.
[0003] Flexible packaging includes flexible containers with a
gusseted body section. These gusseted flexible containers are
currently produced using flexible films which are folded to form
gussets and heat sealed in a perimeter shape. The gusseted body
section opens to form a flexible container with a square cross
section or a rectangular cross section. The gussets are terminated
at the bottom of the container to form a substantially flat base,
providing stability when the container is partially or wholly
filled. The gussets are also terminated at the top of the container
to form an open neck for receiving a rigid fitment and closure.
[0004] Conventional procedures for fabricating gusseted flexible
containers with a rigid fitment have shortcomings. The fitment
requires a material and a thickness strong enough to withstand the
heat and compression force imparted by opposing seal bars during
the sealing process. This requirement constrains the diameter of
the fitment base. The fitment material must also be compatible with
the container film material in order to form a heat seal weld.
[0005] Fitments with a canoe-shaped base or a base with extended
radial fins oriented 180.degree. apart, are not practical for
flexible containers with more than two panels because the base
geometry of these fitments does not match the geometry of
containers with three, four, or more panels.
[0006] A need exists for a gusseted flexible container having an
enlarged fitment base diameter. A need further exists for a
gusseted flexible container having a thin-wall fitment, alone or in
combination with, an enlarged fitment base diameter.
SUMMARY
[0007] The present disclosure provides a flexible container. In an
embodiment, the flexible container includes (A) four panels, each
panel comprising a flexible multilayer film. The flexible
multilayer film includes a polymeric material. The four panels form
(i) a body and (ii) a neck. The flexible container includes (B) a
fitment having a top portion and a base. The fitment is composed of
a polymeric material. The base is sealed in the neck. The base has
(C) a cross-sectional shape with a diameter (d), and the base has a
wall thickness (WT). The base has a d/WT ratio, wherein the d/WT
ratio (in mm) is from 35 to 800.
[0008] An advantage of the present disclosure is a flexible
container with improved seal strength between the fitment and the
flexible container panels.
[0009] An advantage of the present disclosure is a flexible
container with a transparent fitment through which the material
being dispensed from the flexible container can be seen.
[0010] An advantage of the present disclosure is a flexible
container with a fitment made with a reduced amount of polymeric
material.
[0011] An advantage of the present disclosure is a flexible
container with a thin-wall fitment.
[0012] An advantage of the present disclosure is a flexible
container with a flexible fitment.
[0013] An advantage of the present disclosure is a flexible
container with a fitment made from a polymeric material having a
low modulus.
BRIEF DESCRIPTION OF THE DRAWINGS
[0014] FIG. 1 is a front elevation view of a flexible container in
a collapsed configuration in accordance with an embodiment of the
present disclosure.
[0015] FIG. 2 is an exploded side elevation view of a panel
sandwich.
[0016] FIG. 3 is a perspective view of the flexible container of
FIG. 1 in an expanded configuration and in accordance with an
embodiment of the present disclosure.
[0017] FIG. 4 is a bottom plan view of the expanded flexible
container of FIG. 3 in accordance with an embodiment of the present
disclosure.
[0018] FIG. 5 is a top plan view of the flexible container of FIG.
3.
[0019] FIG. 6 is an enlarged view of Area 6 of FIG. 1.
[0020] FIG. 7 is an elevation view of a fitment in accordance with
an embodiment of the present disclosure.
[0021] FIG. 8 is a bottom plan view of the fitment taken along line
8-8 of FIG. 7.
DETAILED DESCRIPTION
[0022] The present disclosure provides a flexible container. In an
embodiment, the flexible container includes (A) four panels. Each
panel includes a flexible multilayer film. The flexible multilayer
film includes a polymeric material. The four panels form (i) a body
and (ii) a neck. The flexible container includes (B) a fitment. The
fitment has a top portion and a base. The fitment is composed of a
polymeric material. The base is sealed in the neck. The base has
(C) a cross sectional shape with a diameter (d), and the base has a
wall thickness (WT).
[0023] 1. Flexible Container
[0024] The flexible container includes panels, each panel composed
of a flexible multilayer film. The flexible container can be made
from two, three, four, five, six, or more panels. In an embodiment,
the flexible container 10 has a collapsed configuration (as shown
in FIG. 1) and has an expanded configuration (shown in FIGS. 3, 4,
5). FIG. 1 shows the flexible container 10 having a bottom section
I, a body section II, a tapered transition section III, and a neck
section IV. In the expanded configuration, the bottom section I
forms a bottom segment 26, as shown in FIG. 4. The body section II
forms a body portion. The tapered transition section III forms a
tapered transition portion. The neck section IV forms a neck
portion.
[0025] In an embodiment, the flexible container 10 is made from
four panels, as shown in FIGS. 1-6. During the fabrication process,
the panels are formed when one or more webs of film material are
sealed together. While the webs may be separate pieces of film
material, it will be appreciated that any number of the seams
between the webs could be "pre-made," as by folding one or more of
the source webs to create the effect of a seam or seams. For
example, if it were desired to fabricate the present flexible
container from two webs instead of four, the bottom, left center,
and right center webs could be a single folded web, instead of
three separate webs. Similarly, one, two, or more webs may be used
to produce each respective panel (i.e., a bag-in-a-bag
configuration or a bladder configuration).
[0026] FIG. 2 shows the relative positions of the four webs as they
form four panels (in a "one up" configuration) as they pass through
the fabrication process. For clarity, the webs are shown as four
individual panels, the panels separated and the heat seals not
made. The constituent webs form first gusset panel 18, second
gusset panel 20, front panel 22 and rear panel 24. The panels 18-24
are a multilayer film, as discussed in detail below. The gusset
fold lines 60 and 62 are shown in FIGS. 1 and 2.
[0027] As shown in FIG. 2, the folded gusset panels 18, 20 are
placed between the rear panel 24 and the front panel 22 to form a
"panel sandwich." The gusset panel 18 opposes the gusset panel 20.
The edges of the panels 18-24 are configured, or otherwise
arranged, to form a common periphery 11 as shown in FIG. 1. The
flexible multilayer film of each panel web is configured so that
the heat seal layers face each other. The common periphery 11
includes the bottom seal area including the bottom end of each
panel.
[0028] When the flexible container 10 is in the collapsed
configuration, the flexible container is in a flattened state, or
in an otherwise evacuated state. The gusset panels 18, 20 fold
inwardly (dotted gusset fold lines 60, 62 of FIG. 1) and are
sandwiched by the front panel 22 and the rear panel 24.
[0029] FIGS. 3-5 show flexible container 10 in the expanded
configuration. The flexible container 10 has four panels, a front
panel 22, a rear panel 24, a first gusset panel 18 and a second
gusset panel 20. The four panels 18, 20, 22, and 24 form the body
section II and extend toward a top end 44 and extend toward a
bottom end 46 of the container 10. Sections III and IV (respective
tapered transition section, neck section) form a top segment 28.
Section I (bottom section) forms a bottom segment 26.
[0030] The four panels 18, 20, 22 and 24 can each be composed of a
separate web of film material. The composition and structure for
each web of film material can be the same or different.
Alternatively, one web of film material may also be used to make
all four panels and the top and bottom segments. In a further
embodiment, two or more webs can be used to make each panel.
[0031] In an embodiment, four webs of film material are provided,
one web of film for each respective panel 18, 20, 22, and 24. The
process includes sealing edges of each film to the adjacent web of
film to form peripheral seals 41 and peripheral tapered seals
40a-40d (40) (FIGS. 1, 3, 4, 5). The peripheral tapered seals
40a-40d are located on the bottom segment 26 of the container, as
shown in FIG. 4, and have an inner edge 29a-29f. The peripheral
seals 41 are located on the side edges of the container 10, as
shown in FIG. 3. Consequently, the process includes forming a
closed bottom section I, a closed body section II, and a closed
tapered transition section III.
[0032] To form the top segment 28 and the bottom segment 26, the
four webs of film converge together at the respective end and are
sealed together. For instance, the top segment 28 can be defined by
extensions of the panels sealed together at the tapered transition
section III, and the neck section IV. The top end 44 includes four
top panels 28a-28d (FIG. 5) of film that define the top segment 28.
The bottom segment 26 can be defined by extensions of the panels
sealed together at the bottom section I. The bottom segment 26 can
also have four bottom panels 26a-26d of film sealed together and
can also be defined by extensions of the panels at the opposite end
46, as shown in FIG. 4.
[0033] The neck portion can be located at a corner of the body 47,
or in one of the four panels. In an embodiment, the neck 30 is
positioned at a midpoint of the top segment 28. The neck 30 may (or
may not) be sized smaller than a width of the body section II, such
that the neck 30 can have an area that is less than a total area of
the top segment 28. The location of the neck 30 can be anywhere on
the top segment 28 of the container 10.
[0034] In an embodiment, the neck 30 is formed from two or more
panels. In a further embodiment, the neck 30 is formed from four
panels.
[0035] In an embodiment, the neck 30 is sized to accommodate a
wide-mouth fitment. A "wide-mouth fitment," is a fitment 70 having
a diameter greater than 50 mm.
[0036] Although FIGS. 1 and 3 show the flexible container 10 with a
top handle 12 and a bottom handle 14, it is understood the flexible
container 10 may be fabricated without handles or with only one
handle. When the flexible container 10 has a top handle 12, the
neck 30 is located centered on the top segment 28 between the
handle bases to facilitate easy pouring.
[0037] The four panels of film that form the flexible container 10
extend from the body section II (forming body 47), to the tapered
transition section III (forming tapered transition portion 48), to
form a neck 30 (in the neck section IV). The four panels of film
also extend from the body section II to the bottom section I
(forming bottom portion 49). When the flexible container 10 is in
the collapsed configuration (FIG. 1), the neck 30 has a width, F,
that is less than the width of the tapered transition section III.
The neck 30 includes a neck wall 50. FIGS. 1 and 3 show the neck
wall 50 forms an open end 51 for access into the flexible container
interior. The panels are sealed together to form a closed bottom
section I, a closed body section II, and a closed tapered
transition section III. Nonlimiting examples of suitable heating
procedures include heat sealing and/or ultrasonic sealing. When the
flexible container 10 is in the expanded configuration, the open
end 51 of the neck wall 50 is open or is otherwise unsealed. When
the flexible container 10 is in the collapsed configuration, the
open end 51 is unsealed and is openable. The open end 51 permits
access to the container interior through the neck wall 50 and the
neck 30 as shown in FIGS. 3 and 5.
[0038] As shown in FIGS. 1, 3-4, the flexible bottom handle 14 can
be positioned at a bottom end 46 of the container 10 such that the
bottom handle 14 is an extension of the bottom segment 26.
[0039] Each panel includes a respective bottom face. FIG. 4 shows
four triangle-shaped bottom faces 26a-26d, each bottom face being
an extension of a respective film panel. The bottom faces 26a-26d
make up the bottom segment 26. The four panels 26a-26d come
together at a midpoint of the bottom segment 26. The bottom faces
26a-26d are sealed together, such as by using a heat-sealing
technology, to form the bottom handle 14. For instance, a weld can
be made to form the bottom handle 14, and to seal the edges of the
bottom segment 26 together. Nonlimiting examples of suitable
heat-sealing technologies include hot bar sealing, hot die sealing,
impulse sealing, high frequency sealing, or ultrasonic sealing
methods.
[0040] FIG. 4 shows bottom segment 26. Each panel 18, 20, 22, 24
has a respective bottom face 26a-26d that is present in the bottom
segment 26. Each bottom face is bordered by two opposing peripheral
tapered seals 40a-40d. Each peripheral tapered seal 40a-40d extends
from a respective peripheral seal 41. The peripheral tapered seals
for the front panel 22 and the rear panel 24 have an inner edge
29a-29d (FIG. 4) and an outer edge 31 (FIG. 6). The peripheral
tapered seals 40a-40d converge at a bottom seal area 33 (FIGS. 1,
4, 6).
[0041] The front panel bottom face 26a includes a first line A
defined by the inner edge 29a of the first peripheral tapered seal
40a and a second line B defined by the inner edge 29b of the second
peripheral tapered seal 40b. The first line A intersects the second
line B at an apex point 35a in the bottom seal area 33. The front
panel bottom face 26a has a bottom distalmost inner seal point 37a
("BDISP 37a"). The BDISP 37a is located on the inner edge.
[0042] The apex point 35a is separated from the BDISP 37a by a
distance S from 0 millimeter (mm) to less than 8.0 mm.
[0043] In an embodiment, the rear panel bottom face 26c includes an
apex point 35c similar to the apex point 35c on the front panel
bottom face 26a. The rear panel bottom face 26c includes a first
line C defined by the inner edge of the 29c first peripheral
tapered seal 40c and a second line D defined by the inner edge 29d
of the second peripheral tapered seal 40d. The first line C
intersects the second line D at an apex point 35c in the bottom
seal area 33. The rear panel bottom face 26c has a bottom
distalmost inner seal point 37c ("BDISP 37c"). The BDISP 37c is
located on the inner edge. The apex point 35c is separated from the
BDISP 37c by a distance T from 0 millimeter (mm) to less than 8.0
mm.
[0044] It is understood the following description to the front
panel bottom face 26a applies equally to the rear panel bottom face
26c, with reference numerals to the rear panel bottom face 26c
shown in adjacent closed parentheses.
[0045] In an embodiment, the BDISP 37a (37c) is located where the
inner edges 29a (29c) and 29b (29d) intersect. The distance S
(distance T) between the BDISP 37a (37c) and the apex point 35a
(35c) is 0 mm.
[0046] In an embodiment, the inner seal edge diverges from the
inner edges 29a, 29b (29c, 29d), to form an inner seal arc 39a
(front panel) and inner seal arc 39c (rear panel) as shown in FIGS.
4 and 6. The BDISP 37a (37c) is located on the inner seal arc 39a
(39c). The apex point 35a (apex point 35c) is separated from the
BDISP 37a (BDISP 37c) by the distance S (distance T), which is from
greater than 0 mm, or 0.5 mm, or 1.0 mm, or 2.0 mm, or 2.6 mm, or
3.0 mm, or 3.5 mm, or 3.9 mm to 4.0 mm, or 4.5 mm, or 5.0 mm, or
5.2 mm, or 5.3 mm, or 5.5 mm, or 6.0 mm, or 6.5 mm, or 7.0 mm, or
7.5 mm, or 7.9 mm.
[0047] In an embodiment, apex point 35a (35c) is separated from the
BDISP 37a (37c) by the distance S (distance T), which is from
greater than 0 mm to less than 6.0 mm.
[0048] In an embodiment, the distance S (distance T) from the apex
point 35a (35c) to the BDISP 37a (37c) is from greater than 0 mm,
or 0.5 mm or 1.0 mm, or 2.0 mm to 4.0 mm, or 5.0 mm, or less than
5.5 mm.
[0049] In an embodiment, apex point 35a (apex point 35c) is
separated from the BDISP 37a (BDISP 37c) by the distance S
(distance T), which is from 3.0 mm, or 3.5 mm, or 3.9 mm to 4.0 mm,
or 4.5 mm, or 5.0 mm, or 5.2 mm, or 5.3 mm, or 5.5 mm.
[0050] In an embodiment, the distal inner seal arc 39a (39c) has a
radius of curvature from 0 mm, or greater than 0 mm, or 1.0 mm to
19.0 mm, or 20.0 mm.
[0051] In an embodiment, each peripheral tapered seal 40a-40d
(outside edge) and an extended line from respective peripheral seal
41 (outside edge) form an angle Z, as shown in FIG. 1. The angle Z
is from 40.degree., or 42.degree., or 44.degree., or 45.degree. to
46.degree., or 48.degree., or 50.degree.. In an embodiment, angle Z
is 45.degree..
[0052] The bottom segment 26 includes a pair of gussets 54 and 56
formed there at, which are essentially extensions of the bottom
faces 26a-26d. The gussets 54 and 56 can facilitate the ability of
the flexible container 10 to stand upright. These gussets 54 and 56
are formed from excess material from each bottom face 26a-26d that
are joined together to form the gussets 54 and 56. The triangular
portions of the gussets 54 and 56 comprise two adjacent bottom
segment panels sealed together and extending into its respective
gusset. For example, adjacent bottom faces 26a and 26d extend
beyond the plane of their bottom surface along an intersecting edge
and are sealed together to form one side of a first gusset 54.
Similarly, adjacent bottom faces 26c and 26d extend beyond the
plane of their bottom surface along an intersecting edge and are
sealed together to form the other side of the first gusset 54.
Likewise, a second gusset 56 is similarly formed from adjacent
bottom faces 26a-26b and 26b-26c. The gussets 54 and 56 can contact
a portion of the bottom segment 26, where the gussets 54 and 56 can
contact bottom faces 26b and 26d covering them, while bottom
segment panels 26a and 26c remain exposed at the bottom end 46.
[0053] As shown in FIG. 4, the gussets 54 and 56 of the flexible
container 10 can further extend into the bottom handle 14. In the
aspect where the gussets 54 and 56 are positioned adjacent bottom
segment panels 26b and 26d, the bottom handle 14 can also extend
across bottom faces 26b and 26d, extending between the pair of
panels 18 and 20. The bottom handle 14 can be positioned along a
center portion or midpoint of the bottom segment 26 between the
front panel 22 and the rear panel 24.
[0054] The top handle 12 and the bottom handle 14 can comprise up
to four plys of film sealed together for a four panel container 10.
When more than four panels are used to make the container, the
handles 12, 14 can include the same number of panels used to
produce the container. Any portion of the handles 12, 14 where all
four plys are not completely sealed together by the heat-sealing
method, can be adhered together in any appropriate manner, such as
by a tack seal to form a fully-sealed multilayer handle.
Alternatively, the top handle 12 can be made from as few as a
single ply of film from one panel only or can be made from only two
plies of film from two panels. The handles 12, 14 can have any
suitable shape and generally will take the shape of the film end.
For example, typically the web of film has a rectangular shape when
unwound, such that its ends have a straight edge. Therefore, the
handles 12, 14 would also have a rectangular shape.
[0055] Additionally, the bottom handle 14 can contain a handle
opening 16 or cutout section therein sized to fit a user's hand, as
can be seen in FIG. 1. The handle opening 16 can be any shape that
is convenient to fit the hand and, in one aspect, the handle
opening 16 can have a generally oval shape. In another embodiment,
the handle opening 16 can have a generally rectangular shape.
Additionally, the handle opening 16 of the bottom handle 14 can
also have a flap 38 that comprises the cut material that forms the
handle opening 16. To define the handle opening 16, the bottom
handle 14 can have a section that is cut out of the multilayer
bottom handle 14 along three sides or portions while remaining
attached at a fourth side or lower portion. This provides a flap of
material 38 that can be pushed through the handle opening 16 by the
user and folded over an edge of the handle opening 16 to provide a
relatively smooth gripping surface at an edge that contacts the
user's hand. If the flap of material 38 were completely cut out,
this would leave an exposed fourth side or lower edge that could be
relatively sharp and could possibly cut or scratch the hand when
placed there.
[0056] Furthermore, a portion of the bottom handle 14 attached to
the bottom segment 26 can contain a dead machine fold 42 or a score
line that provides for the bottom handle 14 to consistently fold in
the same direction, as illustrated in FIG. 3. The machine fold 42
can comprise a fold line that permits folding in a first direction
X toward the front panel 22 and restricts folding in a second
direction Y toward the rear panel 24. The term "restricts," as used
throughout this application, can mean that it is easier to move in
one direction, or the first direction X, than in an opposite
direction, such as the second direction Y. The machine fold 42 can
cause the bottom handle 14 to consistently fold in the first
direction X because it can be thought of as providing a generally
permanent fold line in the bottom handle 14 that is predisposed to
fold in the first direction X, rather than in the second direction
Y. This machine fold 42 of the bottom handle 14 can serve multiple
purposes, one being that when a user is transferring the product
from the container 10 they can grasp the bottom handle 14 and it
will easily bend in the first direction X to assist in pouring.
Secondly, when the flexible container 10 is stored in an upright
position, the machine fold 42 in the bottom handle 14 encourages
the bottom handle 14 to fold in the first direction X along the
machine fold 42, such that the bottom handle 14 can fold underneath
the container 10 adjacent one of the bottom segment panels 26a, as
shown in FIG. 4. The weight of the product can also apply a force
to the bottom handle 14, such that the weight of the product can
further press on the bottom handle 14 and maintain the bottom
handle 14 in the folded position in the first direction X. As will
be discussed herein, the top handle 12 can also contain a similar
machine fold 34a, 34b that also allows it to fold consistently in
the same first direction X as the bottom handle 14.
[0057] Additionally, as the flexible container 10 is evacuated and
less product remains, the bottom handle 14 can continue to provide
support to help the flexible container 10 to remain standing
upright unsupported and without tipping over. Because the bottom
handle 14 is sealed generally along its entire length extending
between the pair of gusset panels 18 and 20, it can help to keep
the gussets 54 and 56 (FIGS. 3, 4) together and continue to provide
support to stand the container 10 upright, even as the container 10
is emptied.
[0058] As seen in FIGS. 1, 3, and 5, the top handle 12 can extend
from the top segment 28 and, in particular, can extend from the
four panels 28a-28d that make up the top segment 28. The four
panels 28a-28d of film that extend into the top handle 12 are all
sealed together to form a multilayer top handle 12. The top handle
12 can have a U-shape and, in particular, an upside down U-shape
with a horizontal upper handle portion 12a having two pairs of
spaced legs 13 and 15 extending therefrom. The pair of legs 13 and
15 extend from the top segment 28, adjacent the neck 30.
[0059] A portion of the top handle 12 can extend above the neck 30
and above the top segment 28 when the top handle 12 is extended in
a position perpendicular to the top segment 28 and, in particular,
the entire upper handle portion 12a can be above the neck wall 50
and the top segment 28. The two pairs of legs 13 and 15 along with
the upper handle portion 12a together make up the top handle 12
surrounding a handle opening that allows a user to place their hand
therethrough and grasp the upper handle portion 12a of the handle
12.
[0060] As with the bottom handle 14, the top handle 12 also can
have a dead machine fold 34a, 34b that permits folding in a first
direction toward the front side panel 22 and restricts folding in a
second direction toward the rear side panel 24, as shown in FIG. 5.
The machine fold 34a, 34b can be located in each of the pair of
legs 13, 15 at a location where the seal begins. The top handle 12
can be adhered together, such as with a tack adhesive, for example.
The machine fold 34a, 34b in the top handle 12 can allow for the
top handle 12 to be inclined to fold or bend consistently in the
same first direction X as the bottom handle 14, rather than in the
second direction Y. As shown in FIGS. 1, 3, and 5, the top handle
12 can likewise contain a flap portion 36 that folds upwards toward
the upper handle portion 12a of the top handle 12 to create a
smooth gripping surface of the top handle 12, as with the bottom
handle 14, such that the handle material is not sharp and can
protect the user's hand from getting cut on any sharp edges of the
top handle 12.
[0061] When the container 10 is in a rest position, such as when it
is standing upright on its bottom segment 26, as shown in FIG. 3,
the bottom handle 14 can be folded underneath the container 10
along the bottom machine fold 42 in the first direction X, so that
it is parallel to the bottom segment 26 and adjacent bottom panel
26a, and the top handle 12 will automatically fold along its
machine fold 34a, 34b in the same first direction X, with a front
surface of the top handle 12 parallel to a panel 28a of the top
segment 28. The top handle 12 folds in the first direction X,
rather than extending straight up, perpendicular to the top segment
28, because of the machine fold 34a, 34b. Both handles 12 and 14
are inclined to fold in the same direction X, such that upon
dispensing, the handles can fold the same direction, relatively
parallel to its respective end panel or end segment, to make
dispensing easier and more controlled. Therefore, in a rest
position, the handles 12 and 14 are both folded generally parallel
to one another. Additionally, the container 10 can stand upright
even with the bottom handle 14 positioned underneath the upright
container 10.
[0062] The material of construction of the flexible container 10
can comprise food-grade plastic. For instance, nylon,
polypropylene, polyethylene such as high density polyethylene
(HDPE) and/or low density polyethylene (LDPE) may be used, as
discussed later. The film of the plastic container 10 can have a
thickness and barrier properties that are adequate to maintain
product and package integrity during manufacturing, distribution,
product shelf life and customer usage. In an embodiment, the
flexible multilayer film has a thickness from 100 micrometers
(.mu.m), or 200 .mu.m, or 250 .mu.m to 300 .mu.m, or 350 .mu.m, or
400 .mu.m. In an embodiment, the film material can also be such
that it provides the appropriate atmosphere within the flexible
container 10 to maintain the product shelf life of at least about
180 days. Such films can comprise an oxygen barrier film, such as a
film having a low oxygen transmission rate (OTR) from greater than
0 to 0.4 cc/m.sup.2/atm/24 hrs at 23.degree. C. and 80% relative
humidity (RH). Additionally, the flexible multilayer film can also
comprise a water vapor barrier film, such as a film having a low
water vapor transmission rate (WVTR) from greater than 0 to 15
g/m.sup.2/24 hrs at 38.degree. C. and 90% RH. Moreover, it may be
desirable to use materials of construction having oil and/or
chemical resistance particularly in the seal layer, but not limited
to just the seal layer. The flexible multilayer film can be either
printable or compatible to receive a pressure sensitive label or
other type of label for displaying of indicia on the flexible
container 10. In an embodiment, the film can also be made of
non-food grade resins for producing containers for materials other
than food.
[0063] In an embodiment, each panel is made from a flexible
multilayer film having at least one, or at least two, or at least
three layers. The flexible multilayer film is resilient, flexible,
deformable, and pliable. The structure and composition of the
flexible multilayer film for each panel 18, 20, 22, 24 may be the
same or different. For example, each of the four panels 18, 20, 22,
24 can be made from a separate web, each web having a unique
structure and/or unique composition, finish, or print.
Alternatively, each of the four panels 18, 20, 22, 24 can be the
same structure and the same composition.
[0064] In an embodiment, each panel 18, 20, 22, 24 is a flexible
multilayer film having the same structure and the same
composition.
[0065] The flexible multilayer film may be (i) a coextruded
multilayer structure or (ii) a laminate, or (iii) a combination of
(i) and (ii). In an embodiment, the flexible multilayer film has at
least three layers: a seal layer, an outer layer, and a tie layer
between. The tie layer adjoins the seal layer to the outer layer.
The flexible multilayer film may include one or more optional inner
layers disposed between the seal layer and the outer layer.
[0066] In an embodiment, the flexible multilayer film is a
coextruded film having at least two, or three, or four, or five, or
six, or seven to eight, or nine, or ten, or eleven, or more layers.
Some methods, for example, used to construct films are by cast
co-extrusion or blown co-extrusion methods, adhesive lamination,
extrusion lamination, thermal lamination, and coatings such as
vapor deposition. Combinations of these methods are also possible.
Film layers can comprise, in addition to the polymeric materials,
additives such as stabilizers, slip additives, antiblocking
additives, process aids, clarifiers, nucleators, pigments or
colorants, fillers and reinforcing agents, and the like as commonly
used in the packaging industry. It is particularly useful to choose
additives and polymeric materials that have suitable organoleptic
and/or optical properties.
[0067] In another embodiment, the flexible multilayer film can
comprise a bladder, wherein two or more films that are adhered in
such a manner as to allow some delamination of one or more plies to
occur during a significant impact such that the inside film
maintains integrity and continues to hold contents of the
container.
[0068] The flexible multilayer film is composed of a polymeric
material. Nonlimiting examples of suitable polymeric materials for
the seal layer include olefin-based polymer (including any
ethylene/C.sub.3-C.sub.10 .alpha.-olefin copolymers linear or
branched), propylene-based polymer (including plastomer and
elastomer, random propylene copolymer, propylene homopolymer, and
propylene impact copolymer), ethylene-based polymer (including
plastomer and elastomer, high density polyethylene ("HDPE"), low
density polyethylene ("LDPE"), linear low density polyethylene
("LLDPE"), medium density polyethylene ("MDPE")), ethylene-acrylic
acid or ethylene-methacrylic acid and their ionomers with zinc,
sodium, lithium, potassium, magnesium salts, ethylene vinyl acetate
copolymers, and blends thereof.
[0069] Nonlimiting examples of suitable polymeric material for the
outer layer include those used to make biaxially or monoaxially
oriented films for lamination as well as coextruded films. Some
nonlimiting polymeric material examples are biaxially oriented
polyethylene terephthalate (OPET), monoaxially oriented nylon
(MON), biaxially oriented nylon (BON), and biaxially oriented
polypropylene (BOPP). Other polymeric materials useful in
constructing film layers for structural benefit are polypropylenes
(such as propylene homopolymer, random propylene copolymer,
propylene impact copolymer, thermoplastic polypropylene (TPO) and
the like), propylene-based plastomers (e.g., VERSIFY.TM. or
VISTAMAX.TM.)), polyamides (such as Nylon 6; Nylon 6,6; Nylon 6,66;
Nylon 6,12; Nylon 12; etc.), polyethylene norbornene, cyclic olefin
copolymers, polyacrylonitrile, polyesters, copolyesters (such as
polyethylene terephthlate glycol-modified (PETG)), cellulose
esters, polyethylene and copolymers of ethylene (e.g., LLDPE based
on ethylene octene copolymer such as DOWLEX.TM.), blends thereof;
and multilayer combinations thereof.
[0070] Nonlimiting examples of suitable polymeric materials for the
tie layer include functionalized ethylene-based polymers such as
ethylene-vinyl acetate (EVA) copolymer, polymers with maleic
anhydride-grafted to polyolefins such as any polyethylene,
ethylene-copolymers, or polypropylene, and ethylene acrylate
copolymers such an ethylene methyl acrylate (EMA) copolymer,
glycidyl containing ethylene copolymers, propylene and ethylene
based olefin block copolymers (OBC) such as INTUNE.TM. (PP-OBC) and
INFUSE.TM. (PE-OBC), both available from The Dow Chemical Company,
and blends thereof.
[0071] The flexible multilayer film may include additional layers
which may contribute to the structural integrity or provide
specific properties. The additional layers may be added by direct
means or by using appropriate tie layers to the adjacent polymer
layers. Polymers which may provide additional mechanical
performance such as stiffness or opacity, as well polymers which
may offer gas barrier properties or chemical resistance can be
added to the structure.
[0072] Nonlimiting examples of suitable material for the optional
barrier layer include copolymers of vinylidene chloride and methyl
acrylate, methyl methacrylate or vinyl chloride (e.g., SARAN resins
available from The Dow Chemical Company); vinylethylene vinyl
alcohol (EVOH) copolymer; and metal foil (such as aluminum foil).
Alternatively, modified polymeric films such as vapor deposited
aluminum or silicon oxide on such films as BON, OPET, or oriented
polypropylene (OPP), can be used to obtain barrier properties when
used in laminate multilayer film.
[0073] In an embodiment, the flexible multilayer film includes a
seal layer selected from LLDPE (sold under the trade name
DOWLEX.TM. (The Dow Chemical Company)); single-site LLDPE;
substantially linear, or linear ethylene alpha-olefin copolymers,
including polymers sold under the trade name AFFINITY''' or
ELITE''' (The Dow Chemical Company) for example; propylene-based
plastomers or elastomers such as VERSIFY.TM. (The Dow Chemical
Company); and blends thereof. An optional tie layer is selected
from either ethylene-based olefin block copolymer PE-OBC (sold as
INFUSE.TM.) or propylene-based olefin block copolymer PP-OBC (sold
as INTUNE.TM.). The outer layer includes greater than 50 wt % of
resin(s) having a melting point, Tm, that is from 25.degree. C., to
30.degree. C., or 40.degree. C. higher than the melting point of
the polymer in the seal layer, wherein the outer layer polymer is
selected from resins such as VERSIFY.TM. or VISTAMAX.TM.,
ELITE.TM., HDPE or a propylene-based polymer such as propylene
homopolymer, propylene impact copolymer or TPO.
[0074] In an embodiment, the flexible multilayer film is
co-extruded.
[0075] In an embodiment, flexible multilayer film includes a seal
layer selected from LLDPE (sold under the trade name DOWLEX.TM.
(The Dow Chemical Company)); single-site LLDPE; substantially
linear, or linear, olefin polymers, including polymers sold under
the trade name AFFINITY.TM. or ELITE.TM. (The Dow Chemical Company)
for example; propylene-based plastomers or elastomers such as
VERSIFY.TM. (The Dow Chemical Company); and blends thereof. The
flexible multilayer film also includes an outer layer that is a
polyamide.
[0076] In an embodiment, the flexible multilayer film is a
coextruded film and includes:
[0077] (i) a seal layer composed of an olefin-based polymer having
a first melt temperature less than 105.degree. C., (Tm1); and
[0078] (ii) an outer layer composed of a polymeric material having
a second melt temperature, (Tm2),
[0079] wherein Tm2-Tm1>40.degree. C.
[0080] The term "Tm2-Tm1" is the difference between the melt
temperature of the polymer in the outer layer and the melt
temperature of the polymer in the seal layer, and is also referred
to as ".DELTA.Tm." In an embodiment, the .DELTA.Tm is from
41.degree. C., or 50.degree. C., or 75.degree. C., or 100.degree.
C. to 125.degree. C., or 150.degree. C., or 175.degree. C., or
200.degree. C.
[0081] In an embodiment, the flexible multilayer film is a
coextruded film, the seal layer is composed of an ethylene-based
polymer, such as a linear or a substantially linear polymer, or a
single-site catalyzed linear or substantially linear polymer of
ethylene and an alpha-olefin monomer such as 1-butene, 1-hexene or
1-octene, having a Tm from 55.degree. C. to 115.degree. C. and a
density from 0.865 to 0.925 g/cm.sup.3, or from 0.875 to 0.910
g/cm.sup.3, or from 0.888 to 0.900 g/cm.sup.3 and the outer layer
is composed of a polyamide having a Tm from 170.degree. C. to
270.degree. C.
[0082] In an embodiment, the flexible multilayer film is a
coextruded and/or laminated film having at least five layers, the
coextruded film having a seal layer composed of an ethylene-based
polymer, such as a linear or substantially linear polymer, or a
single-site catalyzed linear or substantially linear polymer of
ethylene and an alpha-olefin comonomer such as 1-butene, 1-hexene
or 1-octene, the ethylene-based polymer having a Tm from 55.degree.
C. to 115.degree. C. and a density from 0.865 to 0.925 g/cm.sup.3,
or from 0.875 to 0.910 g/cm.sup.3, or from 0.888 to 0.900
g/cm.sup.3 and an outermost layer composed of a material selected
from LLDPE, OPET, OPP (oriented polypropylene), BOPP, polyamide,
and combinations thereof.
[0083] In an embodiment, the flexible multilayer film is a
coextruded and/or laminated film having at least seven layers. The
seal layer is composed of an ethylene-based polymer, such as a
linear or substantially linear polymer, or a single-site catalyzed
linear or substantially linear polymer of ethylene and an
alpha-olefin comonomer such as 1-butene, 1-hexene or 1-octene, the
ethylene-based polymer having a Tm from 55.degree. C. to
115.degree. C. and density from 0.865 to 0.925 g/cm.sup.3, or from
0.875 to 0.910 g/cm.sup.3, or from 0.888 to 0.900 g/cm.sup.3. The
outer layer is composed of a material selected from LLDPE, OPET,
OPP (oriented polypropylene), BOPP, polyamide, and combinations
thereof.
[0084] In an embodiment, the flexible multilayer film is a
coextruded (or laminated) five layer film, or a coextruded (or
laminated) seven layer film having at least two layers containing
an ethylene-based polymer. The ethylene-based polymer may be the
same or different in each layer.
[0085] In an embodiment, the flexible multilayer film includes a
seal layer composed of an ethylene-based polymer, or a linear or
substantially linear polymer, or a single-site catalyzed linear or
substantially linear polymer of ethylene and an alpha-olefin
monomer such as 1-butene, 1-hexene or 1-octene, having a heat seal
initiation temperature (HSIT) from 65.degree. C. to less than
125.degree. C. Applicant discovered that the seal layer with an
ethylene-based polymer with a HSIT from 65.degree. C. to less than
125.degree. C. advantageously enables the formation of secure seals
and secure sealed edges around the complex perimeter of the
flexible container. The ethylene-based polymer with HSIT from
65.degree. C. to less than 125.degree. C. is a robust sealant which
also allows for better sealing to the rigid fitment which is prone
to failure. The ethylene-based polymer with HSIT from 65.degree. C.
to 125.degree. C. enables lower heat sealing pressure/temperature
during container fabrication. Lower heat seal pressure/temperature
results in lower stress at the fold points of the gusset, and lower
stress at the union of the films in the top segment and in the
bottom segment. This improves film integrity by reducing wrinkling
during the container fabrication. Reducing stresses at the folds
and seams improves the finished container mechanical performance.
The low HSIT ethylene-based polymer seals at a temperature below
what would cause the outer layer to be compromised.
[0086] In an embodiment, the flexible multilayer film is a
coextruded and/or laminated five layer, or a coextruded (or
laminated) seven layer film having at least one layer containing a
material selected from LLDPE, OPET, OPP (oriented polypropylene),
BOPP, and polyamide.
[0087] In an embodiment, the flexible multilayer film is a
coextruded and/or laminated five layer, or a coextruded (or
laminated) seven layer film having at least one layer containing
OPET or OPP.
[0088] In an embodiment, the flexible multilayer film is a
coextruded (or laminated) five layer, or a coextruded (or
laminated) seven layer film having at least one layer containing
polyamide.
[0089] In an embodiment, the flexible multilayer film is a
seven-layer coextruded (or laminated) film with a seal layer
composed of an ethylene-based polymer, or a linear or substantially
linear polymer, or a single-site catalyzed linear or substantially
linear polymer of ethylene and an alpha-olefin monomer such as
1-butene, 1-hexene or 1-octene, having a Tm from 90.degree. C. to
106.degree. C. The outer layer is a polyamide having a Tm from
170.degree. C. to 270.degree. C. The film has a .DELTA.Tm from
40.degree. C. to 200.degree. C. The film has an inner layer (first
inner layer) composed of a second ethylene-based polymer, different
than the ethylene-based polymer in the seal layer. The film has an
inner layer (second inner layer) composed of a polyamide the same
or different to the polyamide in the outer layer. The seven layer
film has a thickness from 100 micrometers to 250 micrometers.
[0090] FIG. 6 shows an enlarged view of the bottom seal area 33
(Area 6) of FIG. 1 and the front panel 26a. The fold lines 60 and
62 of respective gusset panels 18, 20 are separated by a distance U
that is from 0 mm, or greater than 0 mm, or 0.5 mm, or 1.0 mm, or
2.0 mm, or 3.0 mm, or 4.0 mm, or 5.0 mm to 12.0 mm, or greater than
60.0 mm (for larger containers, for example). In an embodiment,
distance U is from greater than 0 mm to less than 6.0 mm. FIG. 6
shows line A (defined by inner edge 29a) intersecting line B
(defined by inner edge 29b) at apex point 35a. BDISP 37a is on the
distal inner seal arc 39a. Apex point 35a is separated from BDISP
37a by a distance S having a length from greater than 0 mm, or 1.0
mm, or 2.0 mm, or 2.6 mm, or 3.0 mm, or 3.5 mm, or 3.9 mm to 4.0
mm, or 4.5 mm, or 5.0 mm, or 5.2 mm, or 5.5 mm, or 6.0 mm, or 6.5
mm, or 7.0 mm, or 7.5 mm, or 7.9 mm.
[0091] In FIG. 6, an overseal 64 is formed where the four
peripheral tapered seals 40a-40d converge in the bottom seal area
33. The overseal 64 includes 4-ply portions 66, where a portion of
each panel is heat sealed to a portion of every other panel. Each
panel represents 1-ply in the 4-ply heat seal. The overseal 64 also
includes a 2-ply portion 68 where two panels (front panel 22 and
rear panel 24) are sealed together. Consequently, the "overseal,"
as used herein, is the area where the peripheral tapered seals
40a-40d converge that is subjected to a subsequent heat seal
operation (and subjected to at least two heat seal operations
altogether). The overseal is located in the peripheral tapered
seals 40a-40d and does not extend into the chamber of the flexible
container 10.
[0092] In an embodiment, the apex point 35a is located above the
overseal 64. The apex point 35a is separated from, and does not
contact the overseal 64. The BDISP 37a is located above the
overseal 64. The BDISP 37a is separated from and does not contact
the overseal 64.
[0093] In an embodiment, the apex point 35a is located between the
BDISP 37a and the overseal 64, wherein the overseal 64 does not
contact the apex point 35a and the overseal 64 does not contact the
BDISP 37a.
[0094] The distance between the apex point 35a to the top edge of
the overseal 64 is defined as distance W, shown in FIG. 6. In an
embodiment, the distance W has a length from 0 mm, or greater than
0 mm, or 2.0 mm, or 4.0 mm to 6.0 mm, or 8.0 mm, or 10.0 mm or 15.0
mm.
[0095] When more than four webs are used to produce the container,
the portion 68 of the overseal 64 may be a 4-ply, or a 6-ply, or an
8-ply portion.
[0096] In an embodiment, the flexible container 10 has a vertical
drop test pass rate from 90%, or 95% to 100%. The vertical drop
test is conducted as follows. The container is filled with tap
water to its nominal capacity, conditioned at 25.degree. C. for at
least 3 hours, held in upright position from its top handle 12 at
1.5 m height (from the base or side of the container to the
ground), and released to a free fall drop onto a concrete slab
floor. If any leak is detected immediately after the drop, the test
is recorded as a failure. A minimum of twenty flexible containers
are tested. A percentage for pass/fail containers is then
calculated.
[0097] In an embodiment, the flexible container 10 has a side drop
pass rate from 90%, or 95% to 100%. This side drop test is
conducted as follows. The container is filled with tap water to its
nominal capacity, conditioned at 25.degree. C. for at least 3
hours, held in upright position from its top handle 12. The
flexible container is released on its side from a 1.5 m height to a
free fall drop onto a concrete slab floor. If any leak is detected
immediately after the drop, the test is recorded as failure. A
minimum of twenty flexible containers are tested. A percentage for
pass/fail containers is then calculated.
[0098] In an embodiment, the flexible container 10 passes the
stand-up test where the package is filled with water at ambient
temperature and placed on a flat surface for seven days and it
should remain in the same position, with unaltered shape or
position.
[0099] In an embodiment, the flexible container 10 has a volume
from 0.050 liters (L), or 0.1 L, or 0.15 L, or 0.2 L, or 0.25 L, or
0.5 L, or 0.75 L, or 1.0 L, or 1.5 L, or 2.5 L, or 3 L, or 3.5 L,
or 4.0 L, or 4.5 L, or 5.0 L to 6.0 L, or 7.0 L, or 8.0 L, or 9.0
L, or 10.0 L, or 20 L, or 30 L.
[0100] The flexible container 10 can be used to store any number of
flowable substances therein. In particular, a flowable food product
can be stored within the flexible container 10. In one aspect,
flowable food products such as salad dressings; sauces; dairy
products; mayonnaise; mustard; ketchup; other condiments; syrup;
beverages such as water, juice, milk, carbonated beverages, beer,
or wine; animal feed; pet feed; and the like can be stored inside
of the flexible container 10.
[0101] The flexible container 10 is suitable for storage of other
flowable substances including, but not limited to, oil, paint,
grease, chemicals, suspensions of solids in liquid, and solid
particulate matter (powders, grains, granular solids).
[0102] The flexible container 10 is suitable for storage of
flowable substances with higher viscosity and requiring application
of a squeezing force to the container in order to discharge.
Nonlimiting examples of such squeezable and flowable substances
include grease, butter, margarine, soap, shampoo, animal feed,
sauces, and baby food.
[0103] 2. Fitment
[0104] The present flexible container includes a fitment 70
inserted into the neck 30 of the flexible container 10. The fitment
70 includes a base 72 and a top portion 74, as shown in FIG. 7. The
fitment 70 is composed of one or more polymeric materials. The base
72 and the top portion 74 may be made from the same polymeric
material or from different polymeric materials. In an embodiment,
the base 72 and the top portion 74 are made from the same polymeric
material.
[0105] The top portion 74 may include threads 75 or other suitable
structure for attachment to a closure. Nonlimiting examples of
suitable fitments and closures, include, screw cap, flip-top cap,
snap cap, liquid or beverage dispensing fitments (stop-cock or
thumb plunger), Colder fitment connector, tamper evident pour
spout, vertical twist cap, horizontal twist cap, aseptic cap, vitop
press, press tap, push on tap, lever cap, conro fitment connector,
and other types of removable (and optionally reclosable) closures.
The closure and/or fitment 70 may or may not include a gasket. In
an embodiment, the closure is watertight. In a further embodiment,
the closure provides a hermetic seal to the container 10.
[0106] The base 72 has a cross sectional shape. The cross sectional
shape of the base 72 is selected from ellipse, circle, and regular
polygon.
[0107] In an embodiment, the cross-sectional shape of the base 72
is an ellipse. An "ellipse," as used herein, is a plane curve such
that the sums of the distances of each point in its periphery from
two fixed points, the foci, are equal. The ellipse has a center
which is the midpoint of the line segment linking the two foci. The
ellipse has a major axis (the longest diameter through the center).
The minor axis is the shortest line through the center. The ellipse
center is the intersection of the major axis and the minor axis. As
used herein, the diameter (d) for the ellipse is the major
axis.
[0108] In an embodiment, the cross-sectional shape is slightly
elliptical where the ratio of major axis to minor axis is between
1.01 to 1.25.
[0109] In an embodiment, the cross-sectional shape for the base 72
is a circle (or is substantially a circle). A "circle," as used
herein, is a closed plane curve consisting of all points at a given
distance from a point within it called the center. The radius (r)
for the circle is the distance from the center of the circle to any
point on the circle. The diameter (d) for the circle is 2r.
[0110] In an embodiment, the cross sectional shape for the base is
a regular polygon. A "polygon," as used herein, is a closed plane
figure, having three or more straight sides. The point where two
sides meet is a "vertex." A "regular polygon," as used herein, is a
polygon that is equiangular (all angles are equal in measure) and
equilateral (all sides have the same length.
[0111] The radius (r) for a regular polygon is defined by Formula
(1) below.
radius = s 2 sin ( .pi. n ) Formula ( 1 ) ##EQU00001## [0112]
wherein [0113] s is the length of any side; [0114] n is the number
of sides; and [0115] sin is the sine function.
[0116] The diameter (d) for a regular polygon is 2(r) wherein the
radius, r, for the regular polygon is determined by way of Formula
(1). Nonlimiting examples of suitable regular polygon shapes for
the cross-section of the base 72 include equilateral triangular,
regular square, regular pentagon, regular hexagon, regular
heptagon, regular octagon, regular nonagon, regular decagon,
regular hendecagon, or regular dodecagon shape.
[0117] The cross-sectional shape of the top portion 74 may be the
same or different than the cross-sectional shape of the base
72.
[0118] The cross-sectional shape of the base 72 may be circular,
slightly elliptical, or regular polygonal. In an embodiment, the
cross-sectional shape of the base 72 is circular, or substantially
circular, as shown in FIGS. 7 and 8.
[0119] The base 72 with a circular or regular polygon
cross-sectional shape is distinct from fitments with a canoe-shaped
fitment base or fitments with a base having opposing radial fins.
In an embodiment, the fitment 70 excludes fitments that include a
canoe-shaped base, fitments with a base that has radial fins,
fitments with a wing-shaped base, and fitments with an eye-shaped
base.
[0120] The outer surface of the base 72 may or may not include
surface texture. In an embodiment, the outer surface of the base 72
has surface texture. Nonlimiting examples of surface texture
include embossment, and a plurality of radial ridges to promote
sealing to the inner surface of the neck wall 50.
[0121] In an embodiment, the outer surface of base 72 is smooth and
does not include surface texture, as shown in FIG. 7.
[0122] In an embodiment, the diameter of the base 72 is greater
than the diameter of the top portion 74. FIG. 8 shows a base 72
with circle cross-sectional shape and the diameter of base 72 is G
having a length that is greater than the length of the diameter Q,
the diameter of the top portion 74. The fitment 70 with a base
diameter G that is greater than top portion diameter Q
advantageously promotes unimpeded pouring of content from the
flexible container 10.
[0123] The base 72 is welded, or is otherwise heat sealed to the
multilayer film that forms the neck 30. In other words, the base 72
is welded to the neck 30. Heat sealing can be made by means of hot
bar, impulse seal, ultrasonic or in some cases by high frequency
(HF) sealing.
[0124] In an embodiment, the base 72 is welded to the neck 30 by
way of a mandrel with an expandable collar as disclosed in
co-pending case, U.S. Ser. No. 62/146,002, filed on 10 Apr. 2015,
the entire content of which is incorporated by reference
herein.
[0125] The fitment 70 is made from a polymeric material.
Nonlimiting examples of suitable polymeric materials include
propylene-based polymer, ethylene-based polymer, polyamides (such
as Nylon 6; Nylon 6,6; Nylon 6,66; Nylon 6,12; Nylon 12; and the
like), cyclic olefin copolymers (COC)(such as TOPAS.TM. or
APEL.TM.), polyesters (crystalline and amorphous), copolyester
resin (such as PETG), cellulose esters (such as polylactic acid
(PLA)), and combinations thereof.
[0126] In an embodiment, the fitment 70 is composed of, or is
otherwise formed from, a propylene-based polymer. Nonlimiting
examples of suitable propylene-based polymer include propylene
homopolymer (hPP), impact copolymer polypropylene (ICP), random
copolymer polypropylene (rPPO), propylene-based interpolymer both
plastomers or elastomers such as VERSIFY.TM. (The Dow Chemical
Company), syndiotactic polypropylene (sPP), metallocene
polypropylene (mPP), thermoplastic polyolefin (TPO), and
combinations thereof.
[0127] In an embodiment, the fitment 70 is composed of, or is
otherwise formed from, a blend of one or more propylene-based
polymers, and a modifier containing a block composite. A "block
composite," as used herein, is a block copolymer having from 70-99
wt % of ethylene/propylene (EP) soft blocks (with 65 wt % of
ethylene, based on the total weight of the EP block) and from 30-1
wt % of isotactic polypropylene (iPP) hard blocks that is
twin-screw compounded with the olefin modifier resin composition
prior to blending with the propylene-based polymer. Suitable
processes useful in producing the block composites may be found in,
U.S. Pat. Nos. 8,053,529, 8,686,087, and 8,716,400. The blend can
contain greater than 0 wt % to 40 wt % block composite. In a
further embodiment, the blend includes 80 wt % of Pro-fax RP448S
rPP (available from LyondellBasell) and 20 wt % of the modifier.
The compounded modifier includes 30 wt % block composite (The Dow
Chemical Company), 50 wt % AFFINITY.TM. GA 1950 (available from The
Dow Chemical Company) and 20 wt % ENGAGE.TM. 8402 (available from
The Dow Chemical Company). The blend has a transparency of 99%, a
haze of 11% at (0.75 mm) and an Izod Impact Strength @-20.degree.
C. of 9 kJ/m.sup.2, measured according to ASTM D256 on 0.75
mm.times.76 mm.times.76 mm injection molded plaques.
[0128] In an embodiment, the fitment 70 is composed of, or is
otherwise formed from, an ethylene-based polymer. Nonlimiting
examples of suitable ethylene-based polymer include high density
polyethylene ("HDPE"), medium density polyethylene ("MDPE"), low
density polyethylene ("LDPE"), linear low density polyethylene
("LLDPE"), ultra low density polyethylene ("ULDPE"), very low
density polyethylene ("VLDPE"), single-site LLDPE, substantially
linear, or linear ethylene alpha-olefin copolymers, including
polymers sold under the trade name ENGAGE.TM. elastomers,
AFFINITY.TM. plastomers or ELITE''' Enhanced Polyethylene resins
("EPE") (all available from The Dow Chemical Company) for example,
ethylene-alpha-olefin multi-block copolymer sold as INFUSE.TM.
Olefin Block Copolymers (available from The Dow Chemical Company),
copolymers of polyethylene such as ethylene-vinyl acetate ("EVA")
polymer, ethylene ethyl acrylate ("EEA") polymer or ethylene methyl
acrylate ("EMA") polymer and combinations thereof.
[0129] In an embodiment, the fitment 70 is formed from an
ethylene-based polymer having a 2% secant flexural modulus (ASTM
D790) of less than 200 megapascal (MPa), or a 2% secant flexural
modulus from 10 MPa, or 25 MPa, or 50 MPa, or 75 MPa, or 100 MPa to
125 MPa, or 150 MPa, or 175 MPa, or 200 MPa. A nonlimiting example
of an ethylene-based polymer with a 2% secant flexural modulus from
10 MPa to 200 MPa is ethylene/alpha-olefin multi-block copolymer
sold under the tradename INFUSE.TM. (available from the Dow
Chemical Company) such as INFUSE.TM. 9817.
[0130] In an embodiment, the fitment 70 is composed of, or is
otherwise formed from, a blend of one or more propylene-based
polymers, alone, or in combination with one or more ethylene-based
polymers. Nonlimiting examples of such blends include
propylene-based polymer such as hPP or rPP or propylene based
interpolymer (VERSIFY.TM.) that is blended with from 5 wt % to 30
wt % of ethylene based plastomers or elastomers such as
AFFINITY.TM. 1280, AFFINITY.TM. GA1950, ENGAGE.TM. 8100, ENGAGE.TM.
8200, ENGAGE.TM. 8401, ENGAGE.TM. 8402 ENGAGE.TM. 8411, ENGAGE.TM.
XLT 8677, INFUSE.TM. 9817 olefin block copolymer resin, VERSIFY.TM.
2400, VERSIFY.TM. 3401 or VERSIFY.TM. 4301, and combinations
thereof.
[0131] In an embodiment, the fitment 70 is formed from a compounded
blend containing 80 wt % of R751-12N rPP (available from Braskem)
and 20 wt % ENGAGE.TM. 8411 (available from The Dow Chemical
Company) with a transparency of 99.2+/-0.2%, a haze of 6.9+/-0.4%
at 0.5 mm and a Gardner Impact @-29.degree. C. of 3.0+/-0.7 J,
measured in accordance with ASTM D5420GC at -29.degree. C. using
standard ring in method with a 1.8 kg hammer on plaques with the
following dimensions: 0.5 mm.times.60 mm.times.60 mm.
[0132] In an embodiment, the fitment 70 is composed of, or is
otherwise formed from, a polyamide. Nonlimiting examples of
suitable polyamide include Nylon 6; Nylon 6,6; Nylon 6,66; Nylon
6,12; Nylon 12 and the like.
[0133] In an embodiment, the fitment 70 is composed of, or is
otherwise formed from, a copolyester. As used herein, the term
"copolyester" is a polymer that contains repeating units of two or
more different polyester monomers. Nonlimiting examples of suitable
copolyesters include copolyesters formed from aromatic dicarboxylic
acids, esters of dicarboxylic acids, anhydrides of dicarboxylic
esters, glycols, and mixtures thereof. Suitable partially aromatic
copolyesters are formed from repeat units comprising terephthalic
acid, dimethyl terephthalate, isophthalic acid, dimethyl
isophthalate, dimethyl-2,6 naphthalenedicarboxylate,
2,6-naphthalenedicarboxylic acid, 1,2-, 1,3- and 1,4 phenylene
dioxydoacetic acid, ethylene glycol, diethylene glycol,
1,4-cyclohexane-dimethanol, 1,4-butanediol, and neopentyl glycol
mixtures thereof.
[0134] In an embodiment, the fitment 70 is composed of, or is
otherwise formed from, a cycle olefin copolymer. Nonlimiting
examples of suitable COC's include "COC", such as TOPAS.TM. or
APEL.TM.
[0135] In an embodiment, the copolyester includes polymerization
units derived from terephthalic acid (TPA) and, optionally
polymerization units derived from cyclohexanedimethanol (CHDM), and
ethylene glycol (EG), and the copolyester includes greater than 50
mol % glycol polymerization units (such as PETG) or wherein the
copolymer includes greater than 50 percent by mole of CHDM, such as
glycol-modified polycyclohexylenemethylene terephthalate, PCTG.
[0136] In an embodiment, the copolyester includes terephthalic
acid, Spiro glycol, and ethylene glycol known as SPG-PET available
from Mitsubishi. Alternatively, copolyesters can include
polymerization units derived from terephthalic acid,
cyclohexanedimethanol (CHDM) and isophthalic acid (IPA) such as
used to produce PCTA resins.
[0137] In an embodiment, the copolyester is polyethylene
terephthlate glycol-modified (PETG) such as Eastman's Eastar.TM.
copolyester 6763 with a haze of 0.8% or a branched PETG such as
Provista.TM. copolymer MP002 with 1.3% haze and notched izod at
-40.degree. C. of 0.63 J/cm, as determined by ASTM D256.
[0138] In an embodiment, the copolyester is a PCTG such as
Eastman's Eastar.TM. copolyester DN010, with 1.4% haze and notched
izod at -40.degree. C. of 0.77 J/cm, as determined by ASTM
D4812
[0139] In an embodiment, the copolyester is a PCTA including
DuraStar.TM. polymer DS2010 (available from Eastman) having haze of
0.3% and notched izod at -40.degree. C. of 0.6 J/cm, as determined
by ASTM D256.
[0140] In an embodiment, the copolyester is impact modified with
from 5 wt % to 30 wt % of one or more of the following nonlimiting
modifiers: styrene-ethylene/butylene-styrene block copolymers
(SEBS) which have been functionalized with maleic anhydride (such
as KRATON.RTM. FG 1901X supplied by the Shell Chemical Co.),
ethylene methacrylic acid copolymers (such as SURLYN.RTM. ionomer
resins supplied by DuPont Polymer Products like SURLYN.RTM. 1601-2
ionomer resin), and butadiene/acrylic monomer shell core polymers
(such as Paraloid.RTM. compositions based on butyl acrylate or
methyl acrylate supplied by The Dow Chemical Company like
Paraloid.RTM. EXL-3361).
[0141] In an embodiment, copolyester has an intrinsic viscosity
(IV) from 0.5 deca-liters per gram (dl/g), or 0.6 dl/g, or 0.7 dl/g
to 0.80 dl/g, or 0.85 dl/g, or 0.90 dl/g, or 1.1 dl/g. The
copolyester IV is determined on a 0.5 gram sample in 100 ml of a by
weight solution of 60/40 phenol/tetrachloroethane at 25.degree. C.,
as taught in U.S. Patent Publication 2003/0141625.
[0142] The polymeric material used to make the fitment 70 can
include additives such as stabilizers (such as hindered phenol or
phosphites or blends therein), slip additives (such as erucamide or
polymethyl siloxane), antiblocking additives (such as synthetic
silica), process aids, clarifiers, nucleators, crack stopping
agents, pigments or colorants, fillers and reinforcing agents, and
the like as commonly used in the packaging industry. It is
particularly useful to choose additives and polymeric materials
that have suitable organoleptic properties and can impart benefit
optical properties to the fitment.
[0143] In an embodiment, the fitment 70 is formed from any of the
foregoing polymeric materials, the polymeric material having one,
some, or all of the following properties:
[0144] a 2% secant flexural modulus (ASTM D790) from 10 MPa, or 25
MPa, or 50 MPa, or 75 MPa, or 100 MPa to 125 MPa, or 150 MPa, or
175 MPa, or 200 MPa;
[0145] a clarity from 80%, or 83%, or 85%, or 87%, or 89% to 90%,
or 92%, or 94%, or 96%, or 98%, or 99%, or 99.5%; and
[0146] a haze from 0.3%, or 0.5%, or 1.0%, or 3.0%, or 5.0%, or
7.0%, or 9.0%, or 10%, or 11% to 13%, or 15%, or 17%, or 19%, or
20%.
[0147] In an embodiment, the fitment 70 is composed of a resin sold
under the tradename ELITE.TM. Enhanced Polyethylene resin, such as
ELITE.TM. 5230G (available from The Dow Chemical Company).
[0148] In an embodiment, the fitment 70 includes a polymeric
composition having an Izod impact resistance from greater than 50
Joules (J)/meter (m), or 100 J/m, or 150 J/m, or 200 J/m, or 250
J/m to 300 J/m, or 350 J/m, or 400 J/m, or 450 J/m, or 500 J/m.
Izod impact resistance is measured in accordance with ASTM D 256.
In a further embodiment, the fitment includes a polyolefin having
an Izod impact resistance from greater than 50 J/m, or 100 J/m, or
150 J/m, or 200 J/m, or 250 J/m to 300 J/m, or 350 J/m, or 400 J/m,
or 450 J/m, or 500 J/m.
[0149] In an embodiment, the fitment 70 includes a polymeric
composition containing a polyolefin with a melt temperature (Tm)
greater than or equal to the melt temperature of the polyolefin
present in the seal layer of the multilayer film used to make the
panels 18, 20, 22, 24. When clamp heat sealing is utilized to form
the seal between the base 72 and the neck 30, a nonlimiting example
includes a fitment 70 composed of a HDPE having a Tm of 125.degree.
C. and the seal layer for the container 10 contains an LDPE with a
Tm of 105.degree. C. Another nonlimiting example is a fitment 70
composed of LLDPE with Tm of 120.degree. C., and the container 10
has a seal layer containing an ethylene/.alpha.-olefin copolymer
(AFFINITY.TM. PL 1140G) with a Tm 96.degree. C.
[0150] In an embodiment, the flexible container 10 includes a
hermetic seal between the neck 30 and the base 72.
[0151] In an embodiment, the polymeric material for the fitment 70
has a haze as determined by ASTM D1003 (method B) at 0.5 mm
thickness from 0.3%, or 0.5%, or 1.0%, or 3.0%, or 5.0%, or 7.0%,
or 9.0%, or 10%, or 11% to 13%, or 15%, or 17%, or 19%, or 20% and
also has high clarity where the clarity is determined by ASTM D1746
and clarity is from 80%, or 83%, or 85%, or 87%, or 89% to 90%, or
92%, or 94%, or 96%, or 98%, or 99%, or 99.5%.
[0152] In a further embodiment, the fitment 70 is made from a
copolyester resin having a haze from 0.3% to 4% and a clarity from
80% to 90%.
[0153] In an embodiment, the base 72 has a diameter (d) and a wall
thickness (WT) as shown in FIG. 8. In FIG. 8, the base 72 diameter
(d) is shown as distance G and the wall thickness (WT) is shown as
the distance H. The base 72 diameter (d) can be uniform or can vary
along the length of the base 72. Similarly, the wall thickness (WT)
can be uniform or can vary along the length of the base 72.
[0154] In an embodiment, the diameter of the base 72 is uniform
along the base length and the wall thickness (WT) is uniform along
the base length.
[0155] In an embodiment, the base 72 has a diameter (d) from 5 mm,
or 10 mm or 20 mm, or 25 mm, or 30 mm, or 35 mm, or 38 mm, or 40
mm, or 45 mm, or 47 mm, or 50 mm, or 60 mm, or 70 mm, or 80 mm, or
90 mm to 100 mm, or 110 mm, or 125 mm, or 150 mm, or 175 mm, or 200
mm.
[0156] In an embodiment, the base 72 has a wall thickness (WT) from
0.15 mm, or 0.2 mm, or 0.3 mm, or 0.4 mm, or 0.5 mm, or 0.6 mm, or
0.7 mm, or 0.75 mm, or 0.8 mm, or 0.9 mm, or 1.0 mm to 1.3 mm, or
1.5 mm, or 1.7 mm, or 1.9 mm, or 2.0 mm.
[0157] In an embodiment, the base 72 has a wall thickness (WT) from
0.15 mm, or 0.2 mm, or 0.3 mm, or 0.4 mm to 0.5 mm, or 0.6 mm, or
0.7 mm, or 0.75 mm. As used herein, a base wall thickness (WT) with
the foregoing wall thickness from 0.15 mm to 0.75 mm is a
"thin-wall."
[0158] The base 72 has a diameter to wall thickness ratio. The
"diameter to wall thickness ratio" (denoted as "d/WT") is the
diameter (d) of the base 72 (in millimeters, mm) divided by the
wall thickness (WT), in mm, of the base 72. In an embodiment, the
base 72 has a d/WT from 5, or 8, or 10, or 20, or 30, or 40, or 50,
or 60, or 70, or 80, or 90, or 100, or 125, or 150, or 175, or 200
to 500, or 525, or 550, or 575, or 600, or 625, or 650, or 675, or
700, or 725, or 750, or 775, or 800, or 825, or 850, or 875, or
900, or 925, or 950, or 975, or 1000, or 1100, or 1200, or 1300, or
1400, or 1500, or 1600, or 1700, or 1800, or 1900, or 2000.
[0159] In an embodiment, the base 72 has a d/WT from 35, or 40, or
50, or 60, or 70, or 80, or 90, or 100, or 125, or 150, or 175 to
200, or 225, or 250, or 275, or 300, or 325, or 350, or 375, or
400, or 425, or 450, or 475, or 500, or 525, or 550 or 600, or 650,
or 700, or 750, or 800.
[0160] In an embodiment, the base 72 has a d/WT ratio from 35 to
800, the diameter (d) is from 10 mm, or 20 mm, or 30 mm, or 35 mm,
or 38 mm, or 40 mm, or 45 mm, or 47 mm, or 50 mm to 60 mm, or 70
mm, or 80 mm, or 90 mm, or 100 mm, or 110 mm, or 120 mm; and the
wall thickness (WT) is from 0.15 mm, or 0.2 mm, or 0.3 mm, or 0.4
mm to 0.5 mm, or 0.6 mm, or 0.7 mm, or 0.75 mm. Thus, the base 72
has a thin-wall structure.
[0161] In an embodiment, the base 72 has a d/WT ratio from 35 to
800 as disclosed above. The diameter (d) for the base 72 is from 47
mm to 120 mm. The wall thickness (WT) for the base 72 is from 0.15
mm to 0.75 mm. Thus, the base 72 has a thin-wall structure.
[0162] In an embodiment, the base 72 has a d/WT ratio from 50 to
550 as disclosed above. The diameter (d) for the base 72 is from 10
mm to 110 mm. The wall thickness (WT) for the base 72 is from 0.2
mm to 0.5 mm. Thus, the base 72 has a thin-wall structure.
[0163] The fitment with a d/WT from 35 to 800 can include a base
with a thin-wall structure. Thin-wall fitments advantageously
reduce production costs, reduce material cost, and reduce the
weight of the final flexible container 10.
[0164] The present flexible container may comprise two or more
embodiments disclosed herein.
Definitions
[0165] The numerical ranges disclosed herein include all values
from, and including, the lower value and the upper value. For
ranges containing explicit values (e.g., 1, or 2, or 3 to 5, or 6,
or 7) any subrange between any two explicit values is included
(e.g., 1 to 2; 2 to 6; 5 to 7; 3 to 7; 5 to 6; etc.).
[0166] Unless stated to the contrary, implicit from the context, or
customary in the art, all parts and percents are based on weight,
and all test methods are current as of the filing date of this
disclosure.
[0167] Clarity is measured in accordance with ASTM-D1746.
[0168] The term "composition," as used herein, refers to a mixture
of materials which comprise the composition, as well as reaction
products and decomposition products formed from the materials of
the composition.
[0169] The terms "comprising," "including," "having," and their
derivatives, are not intended to exclude the presence of any
additional component, step or procedure, whether or not the same is
specifically disclosed. In order to avoid any doubt, all
compositions claimed through use of the term "comprising" may
include any additional additive, adjuvant, or compound, whether
polymeric or otherwise, unless stated to the contrary. In contrast,
the term, "consisting essentially of" excludes from the scope of
any succeeding recitation any other component, step or procedure,
excepting those that are not essential to operability. The term
"consisting of" excludes any component, step or procedure not
specifically delineated or listed.
[0170] Density is measured in accordance with ASTM D 792.
[0171] An "ethylene-based polymer," as used herein is a polymer
that contains more than 50 mole percent polymerized ethylene
monomer (based on the total amount of polymerizable monomers) and,
optionally, may contain at least one comonomer.
[0172] Haze is measured in accordance with ASTM D1003 (method B)
and noting the thickness of the part.
[0173] The term "heat seal initiation temperature," is minimum
sealing temperature required to form a seal of significant
strength, in this case, 2 lb/in (8.8N/25.4 mm). The seal is
performed in a Topwave HT tester with 0.5 seconds dwell time at 2.7
bar (40 psi) seal bar pressure. The sealed specimen is tested in an
Instron Tensiomer at 10 in/min (4.2 mm/sec or 250 mm/min).
[0174] Melt flow rate (MFR) is measured I accordance with ASTM D
1238, Condition 280.degree. C./2.16 kg (g/10 minutes).
[0175] Melt index (MI) is measured in accordance with ASTM D 1238,
Condition 190.degree. C./2.16 kg (g/10 minutes).
[0176] Tm or "melting point" as used herein (also referred to as a
melting peak in reference to the shape of the plotted DSC curve) is
typically measured by the DSC (Differential Scanning calorimetry)
technique for measuring the melting points or peaks of polyolefins
as described in U.S. Pat. No. 5,783,638. It should be noted that
many blends comprising two or more polyolefins will have more than
one melting point or peak, many individual polyolefins will
comprise only one melting point or peak.
[0177] An "olefin-based polymer," as used herein is a polymer that
contains more than 50 mole percent polymerized olefin monomer
(based on total amount of polymerizable monomers), and optionally,
may contain at least one comonomer. Nonlimiting examples of
olefin-based polymer include ethylene-based polymer and
propylene-based polymer.
[0178] A "polymer" is a compound prepared by polymerizing monomers,
whether of the same or a different type, that in polymerized form
provide the multiple and/or repeating "units" or "mer units" that
make up a polymer. The generic term polymer thus embraces the term
homopolymer, usually employed to refer to polymers prepared from
only one type of monomer, and the term copolymer, usually employed
to refer to polymers prepared from at least two types of monomers.
It also embraces all forms of copolymer, e.g., random, block, etc.
The terms "ethylene/.alpha.-olefin polymer" and
"propylene/.alpha.-olefin polymer" are indicative of copolymer as
described above prepared from polymerizing ethylene or propylene
respectively and one or more additional, polymerizable
.alpha.-olefin monomer. It is noted that although a polymer is
often referred to as being "made of" one or more specified
monomers, "based on" a specified monomer or monomer type,
"containing" a specified monomer content, or the like, in this
context the term "monomer" is understood to be referring to the
polymerized remnant of the specified monomer and not to the
unpolymerized species. In general, polymers herein are referred to
has being based on "units" that are the polymerized form of a
corresponding monomer.
[0179] A "propylene-based polymer" is a polymer that contains more
than 50 mole percent polymerized propylene monomer (based on the
total amount of polymerizable monomers) and, optionally, may
contain at least one comonomer.
[0180] Some embodiments of the present disclosure will now be
described in detail in the following Examples.
Examples
[0181] 1. Production of Flexible Container (No Fitment)
[0182] Four panel flexible containers having a neck and a body as
shown in FIGS. 1-6 are formed using the seven-layer film provided
in Table 1. Each of the four panels is made with the seven-layer
film shown in Table 1. The four-panel flexible containers are
produced with a volume of either 3.875 L or 20 L and are produced
by ISO Poly Films (Gray Court, S.C.). The 3.875 L flexible
containers use a 150 micrometer (.mu.m) film and the 20 L
containers use both 150 .mu.m and 250 .mu.m film.
TABLE-US-00001 TABLE 1 Composition of flexible multilayer film for
flexible container panels (7 layer co-extruded flexible multilayer
film) Overall Description % Thickness Weight % Layer Density
ULTRAMID C33L01 Nylon 6/66 viscosity number 195 cm.sup.3/g (ISO
13.0% 15.3% 1 1.12 307 @ 0.5% in 96% H.sub.2SO.sub.4), melting
point 196.degree. C. (ISO 3146) AMPLIFY TY1352 Maleic anhydride
grafted polyethylene 0.922 12.0% 11.6% 2 0.922 g/cm.sup.3; 1.0 MI @
2.16 Kg 190.degree. C., melting point 125.degree. C. ELITE 5400G
Polyethylene density 0.916 g/cm.sup.3; 20.0% 19.2% 3 0.916 1.0 MI @
2.16 Kg 190.degree. C., melting point 123.degree. C. AMPLIFY TY1352
Maleic anhydride grafted polyethylene 0.922 12.0% 11.6% 4 0.922
g/cm.sup.3; 1.0 MI @ 2.16 Kg 190.degree. C., melting point
125.degree. C. ULTRAMID C33L01 Nylon 6/66 viscosity number 195
cm.sup.3/g (ISO 6.0% 7.0% 5 1.12 307 @0.5% in 96% H.sub.2SO.sub.4),
melting point 196.degree. C. (ISO 3146) AMPLIFY TY1352 Maleic
anhydride grafted polyethylene 0.922 12.0% 11.6% 6 0.922
g/cm.sup.3; 1.0 MI @ 2.16 Kg 190.degree. C., melting point
125.degree. C. AFFINITY PF1146G Ethylene alpha-olefin copolymer
0.899 g/cm.sup.3; 23.6% 22.3% 7* 0.899 1.0 MI @ 2.16 Kg 190.degree.
C., melting point 95.degree. C. AMPACET 10090 Slip masterbatch
available from Ampacet 1.0% 1.0% 7* 0.92 (S) Corp. containing LDPE
AMPACET 10063 Antiblock masterbatch available from 0.4% 0.4% 7*
1.05 (AB) Ampacet Corp. containing polyethylene Total 100.0% 100.0%
*layer 7 is a 3-component blend, layer 7 is the heat seal layer (or
seal layer)
[0183] Four panels made from the flexible multilayer film in Table
1 are heat sealed together under the heat seal conditions provided
in Table 2 (below) to produce flexible containers. The flexible
containers are fabricated by KRW Machinery Inc (Weaverville, N.C.).
All heat seals in the flexible containers are made with one
strike.
Tables 2A-2B. Heat Seal Conditions for Multilayer Films
TABLE-US-00002 [0184] TABLE 2A Web Sandwich of 0.6 mm, 4 ply, 150
.mu.m panels Seal Bar Platen Overseal Temper- Pres- Dwell
protrusion ature, sure, Time, height, Seal Bar Seals .degree. C.
J/cm.sup.2 sec mm Dimensions Periph- 143 258 0.75 0 10 mm .times.
eral perimeter for 3.875 L 15 mm .times. perimeter for 20 L
Overseal 182 258 0.75 0.30 3.2 mm .times. 25.4 mm (overseal bar,
centered about the apex point, W = 3.5 mm)
TABLE-US-00003 TABLE 2B Web Sandwich of 1.0 mm, 4 ply, 250 .mu.m
panels Seal Bar Platen Overseal Temper- Pres- Dwell protrusion
ature, sure, Time, height, Seal Bar Seals .degree. C. bar sec mm
Dimensions Periph- 174 7.4 3.6 0 10 mm .times. eral perimeter for
3.875 L 15 mm .times. perimeter for 20 L Overseal 185 7.4 3.6 0.5
3.2 mm .times. 25.4 mm (overseal bar, centered about the apex
point, W = 3.5 mm)
[0185] 2. Fitment Sealed to Neck Using Expandable Mandrel
[0186] Fitments with different base diameters and different base
wall thicknesses are inserted into the neck for respective flexible
containers. The fitments are made from the same high density
polyethylene (HDPE). The dimensions and surface texture of the base
for each fitment are provided in Table 3 below.
TABLE-US-00004 TABLE 3 Fitment properties Base Base Wall Fitment
Diameter, Thickness, outer surface Fitment (d) mm (WT) mm d/WT
texture HDPE 1 41 1.6 25.6 Ribbed HDPE 2 41 0.75 54.7 Ribbed HDPE 3
110 1.27 86.7 Smooth HDPE 4 110 0.5 220 Smooth HDPE 5 110 0.2 550
Smooth INFUSE .TM. 9817 41 1.6 25.6 Ribbed
[0187] The fitments are washed thoroughly in denatured alcohol and
allowed to dry to prepare surfaces prior to heat sealing to the
neck of the flexible container.
[0188] Two mandrels are used to heat seal fitments to the flexible
containers. A 38 mm diameter mandrel is used for the 3.875 L
flexible containers. A 110 mm diameter mandrel is used for the 20 L
flexible containers. Each mandrel includes an expandable collar.
Each expandable collar is made of Shore A 30+/-5 durometer FDA
approved silicone rubber. Applicant discovered that silicone rubber
is advantageous because of its heat stability, softness and
durability.
[0189] Properties for the expandable collars are provided in Table
4 below.
TABLE-US-00005 TABLE 4 Expandable Collar Properties 38 mm mandrel
for 110 mm mandrel for Expandable 3.875 L flexible 20 L flexible
Collar properties container container Center hole diameter (mm)
6.35 44.5 Relaxed diameter (mm) 29.4 97.1 Radially expanded 44.6
(at 150% 118.3 (at 122% diameter (mm) expansion, 110 psi)
expansion, 75 psi)
[0190] For the 3.875 L flexible containers, opposing seal bars each
with a length of 41 mm are used. The seal width for each opposing
seal bar is 10.2 mm. The seal bar area for each 41 mm seal bar is
0.0004907 m.sup.2.
[0191] For the 20 L flexible containers, opposing seals bars each
with a length of 110 mm are used. The seal width for each opposing
seal bar is 15.2 mm. The seal bar area for each of the 110 mm seal
bars is 0.00179 m.sup.2.
[0192] The base of the fitment is heat sealed to the neck of the
flexible container using a mandrel with an expandable collar as set
forth in copending case, U.S. Ser. No. 62/146,002, filed on 10 Apr.
2015, the entire contents of which are incorporated by reference
herein. The heat seal conditions for the fitment seal are provided
in Table 5 below. Table 5 also provides fitment seal integrity
data--(i) burst test data and (ii) hang test data for the fitment
seal. In Table 5, "E" denotes inventive example, "CE" denotes
comparative sample, and "NS" denotes not sampled.
[0193] 3. Tests
[0194] Burst Test Procedure
[0195] Process: [0196] 1.) All flexible containers are
numbered/tagged with testing number, identifying film #, and
production set points (if necessary). [0197] 2.) All flexible
containers are pre-inflated via manual inflation or compressed air.
[0198] 3.) Caps are applied tightly. [0199] 4.) Flexible containers
are placed inside the vacuum pressure chamber and lid is closed.
[0200] 5.) Vacuum pressure is applied via vacuum pump. Pressure
should be applied slowly as flexible container continues to
inflate. [0201] 6.) Units of vacuum are recorded in (inHg).
Exceptional results are 18 (inHG) held for 60 seconds. Passing is
12 (inHg). [0202] 7.) Any weak areas of seal will be exposed as
leaks during the testing time period. Bubbles should be looked for
and can indicate a weak area of the flexible container. [0203] 8.)
The flexible container is filled completely with air and the
closure on the fitment is tightened. Then, the flexible container
is completely submerged in a water bath. The chamber over the water
is then evacuated to create a vacuum. A "pass" score for the burst
test is when there are no bubbles visually observed in the water
bath after 30 seconds at 40 kilopascals of vacuum.
[0204] Gravity Hang Test Procedure
[0205] Process: [0206] 1.) All flexible containers are
numbered/tagged with testing number, identifying film #, and
production set points (if necessary). [0207] 2.) All flexible
containers are filled with room temp water to recommended fill
height. [0208] 3.) 3 drops of Methylene Blue die and 3 drops of
surfactant (soap) are added to each flexible container and
agitated. [0209] 4.) Closures are applied tightly to the fitment.
[0210] 5.) Flexible containers are then hung both neck side down
and neck side up to test the strength of both the neck seal and the
caulk seal areas. [0211] 6.) Flexible containers are left hanging
for 48 hours. [0212] 7.) Any weak areas of seal will be exposed as
leaks during the testing time period. [0213] 8.) A "pass" score for
the hang test is hanging the flexible container for 48 hours
without a leak detected. Leaks are detected by visual
identification of white paper below the flexible container to show
any drops that have fallen. The water solution added to the
flexible container contains a blue vegetable dye for aiding visual
detection of the leak. The water solution also contains a drop or
two of soap (Dawn dish soap) where the soap surfactant helps allow
water to penetrate any gaps in seal that might be present.
TABLE-US-00006 [0213] TABLE 5 Permanent Seal deformation Base Wall
Fitment Film Temper- Seal Seal Expandable of fitment Exam-
Diameter, Thickness, outer thickness, ature, pressure, time,
Collar, during Burst Hang ple Fitment (d) mm (WT) mm d/WT surface
.mu.m .degree. C. bar sec Expansion sealing Test Test CE1 HDPE1 41
1.65 24.8 Ribbed 150 177 2 5.5 0% No Fail -- 177 2 6 0% No Pass
Pass 177 2.2 NS 0% Yes -- -- 177 4.9 NS 0% Yes -- -- HDPE1 41 1.65
24.8 Ribbed HDPE1 177 4.9 2 150% No Fail -- E1 HDPE1 41 1.65 24.8
Ribbed HDPE1 177 4.9 2.5 150% No Pass Pass CE2 HDPE2 41 0.75 54.7
Ribbed 150 177 2 5 0% No Fail 177 2 6 0% Yes -- -- 177 2.2 NS 0%
Yes -- -- 177 4.9 NS 0% Yes -- -- HDPE2 41 0.75 54.7 Ribbed 150 177
4.9 2 150% No Fail -- E2 HDPE2 41 0.75 54.7 Ribbed 150 177 4.9 2.5
150% No Pass Pass CE3 HDPE3 110 1.27 86.7 Smooth 250 177 1.3 10 0%
No Pass Fail 177 1.3 20 0% No Pass Pass E3 HDPE3 110 1.27 86.7
Smooth 250 177 1.3 7 116% No Pass Pass CE4 HDPE4 110 0.5 220 Smooth
250 149 1.3 NS 0% No Fail -- E4 HDPE4 110 0.5 220 Smooth 250 149
1.3 10 116% No Pass Pass CE5 HDPE4 110 0.5 220 Smooth 150 149 1.3
NS 0% No Fail -- E5 HDPE4 110 0.5 220 Smooth 150 149 1.3 6 116% No
Pass Pass CE6 HDPE5 110 0.2 550 Smooth 250 149 1.3 NS 0% No Fail --
E6 HDPE5 110 0.2 550 Smooth 250 149 1.3 9 116% No Pass Pass E7
HDPE5 110 0.2 550 Smooth 150 149 1.3 5 122% No Pass Pass CE7 INFUSE
.TM. 41 1.6 25.6 Ribbed 150 177 4.9 NS 0% No Fail -- 9817 INFUSE
.TM. 41 1.6 25.6 Ribbed 150 177 4.9 3 150% No Fail -- 9817 E8
INFUSE .TM. 41 1.6 25.6 Ribbed 150 177 4.9 4 150% No Pass Pass
9817
[0214] Applicant discovered that utilization of the mandrel with
expandable collar during the fitment heat seal procedure
advantageously enables the use of fitment base having thin-wall
structure. Thin-wall or thin-walling is the reduction of the wall
thickness for the fitment base. Examples E2, E4, E5, E6, and E7,
show that fitments with d/WT ratio from 35, or 54.7 (thin-wall), or
86.7 to 220 (thin-wall), or 550 (thin-wall) (i) can be successfully
heat sealed to the neck of the flexible container, (ii) avoid
deformation, (iii) pass the burst test, (iv) pass the hang test,
and (v) simultaneously fulfill each of (i) through (iv).
[0215] Utilization of the mandrel with expandable collar during the
fitment heat seal procedure also enables the use of polymeric
materials not previously suitable for fitment applications. The
mandrel with expandable collar supports the fitment during the
sealing, and prevents deformation. Thus, the mandrel with
expandable collar enables polymeric materials previously either too
soft or too rigid (cracking) to now be used as fitments alone or
thin-walled. Example E8 (with expandable collar) shows that INFUSE
9817, an elastomer, can be used as a suitable fitment material.
Whereas comparative sample CE7 (INFUSE 9817) sealed without the
expandable collar fails the burst test. Example E8 (i) is
successfully heat sealed to the neck of the flexible container,
(ii) avoids deformation, (iii) passes the burst test, (iv) pass the
hang test, and (v) simultaneously fulfill each of (i) through
(iv).
[0216] Utilization of the mandrel with expandable collar during the
fitment heat seal procedure also enables shorter seal times without
degrading seal strength. Example E3 (with expandable collar) yields
an acceptable fitment seal (passing burst test and hang test) with
7 seconds seal time while comparative sample CE3 (no expandable
collar) requires 20 seconds to produce an acceptable fitment
seal.
[0217] The mandrel with expandable collar enables greater seal
pressure to be applied to the fitment. Example E2 (with expandable
collar) yields an acceptable fitment seal (passing burst test and
hang test) at 4.9 seal bar pressure, whereas comparative sample CE2
at 4.9 seal bar pressure is permanently deformed.
[0218] Applicant unexpectedly found that the mandrel with
expandable collar enables the production of a four-panel flexible
container with a hermetically sealed fitment wherein the base wall
thickness is from 0.2 mm, or 0.5 mm to 0.75 mm (thin-wall
base).
[0219] It is specifically intended that the present disclosure not
be limited to the embodiments and illustrations contained herein,
but include modified forms of those embodiments including portions
of the embodiments and combinations of elements of different
embodiments as come with the scope of the following claims.
* * * * *