U.S. patent application number 15/618621 was filed with the patent office on 2017-09-28 for particles for malodor reduction.
The applicant listed for this patent is The Procter & Gamble Company. Invention is credited to Gayle Marie FRANKENBACH, Judith Ann HOLLINGSHEAD, Steven Anthony HORENZIAK.
Application Number | 20170275564 15/618621 |
Document ID | / |
Family ID | 57219034 |
Filed Date | 2017-09-28 |
United States Patent
Application |
20170275564 |
Kind Code |
A1 |
FRANKENBACH; Gayle Marie ;
et al. |
September 28, 2017 |
PARTICLES FOR MALODOR REDUCTION
Abstract
A composition including a plurality of particles, wherein the
particles include: about 30% to about 95% by weight of a carrier;
about 0.1% to about 30% by weight of a perfume; and about 0.00025%
to about 30% by weight of a malodor agent; wherein the malodor
agent comprises one or more malodor reduction materials having a
Blocker Index of less than 3 or a Blocker Index average of 3 to
about 0.001; and wherein each of the particles has a mass between
about 0.1 mg to about 5 g.
Inventors: |
FRANKENBACH; Gayle Marie;
(Cincinnati, OH) ; HOLLINGSHEAD; Judith Ann;
(Batavia, OH) ; HORENZIAK; Steven Anthony;
(Cincinnati, OH) |
|
Applicant: |
Name |
City |
State |
Country |
Type |
The Procter & Gamble Company |
Cincinnati |
OH |
US |
|
|
Family ID: |
57219034 |
Appl. No.: |
15/618621 |
Filed: |
June 9, 2017 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
|
|
14886855 |
Oct 19, 2015 |
9714401 |
|
|
15618621 |
|
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|
|
Current U.S.
Class: |
1/1 |
Current CPC
Class: |
A61L 9/01 20130101; C11D
3/505 20130101; C11D 3/50 20130101; C11D 3/0068 20130101; C11D
17/0034 20130101; A61L 2/23 20130101 |
International
Class: |
C11D 3/00 20060101
C11D003/00; C11D 3/50 20060101 C11D003/50; A61L 9/01 20060101
A61L009/01; A61L 2/23 20060101 A61L002/23 |
Claims
1. A composition comprising a plurality of particles (10), wherein
said particles comprise: about 30% to about 95% by weight of a
carrier; and about 0.00025% to about 30% by weight of a malodor
agent; wherein said malodor agent comprises one or more malodor
reduction materials having a Blocker Index of less than 3 or a
Blocker Index average of 3 to about 0.001; and wherein each of said
particles has a mass between about 0.1 mg to about 5 g.
2. The composition according to claim 1, wherein said carrier is
selected from the group consisting of water soluble organic alkali
metal salt, water soluble inorganic alkaline earth metal salt,
water soluble organic alkaline earth metal salt, water soluble
carbohydrate, water soluble silicate, water soluble urea, starch,
clay, water insoluble silicate, citric acid carboxymethyl
cellulose, fatty acid, fatty alcohol, glyceryl diester of
hydrogenated tallow, glycerol, polyethylene glycol, and
combinations thereof.
3. The composition according to claim 1, wherein said carrier is
selected from the group consisting of polyvinyl alcohol, modified
polyvinyl alcohol, polyvinyl pyrrolidone, polyvinyl
alcohol/polyvinyl pyrrolidone, polyvinyl alcohol/polyvinyl amine,
partially hydrolyzed polyvinyl acetate, polyalkylene oxide,
polyethylene glycol, acrylamide, acrylic acid, cellulose, alkyl
cellulosics, methyl cellulose, ethyl cellulose, propyl cellulose,
cellulose ethers, cellulose esters, cellulose amides, polyvinyl
acetates, polycarboxylic acids and salts, polyaminoacids or
peptides, polyamides, polyacrylamide, copolymers of maleic/acrylic
acids, polysaccharides, starch, modified starch, gelatin,
alginates, xyloglucans, hemicellulosic polysaccharides, xylan,
glucuronoxylan, arabinoxylan, mannan, glucomannan,
galactoglucomannan, natural gums, pectin, xanthan, carrageenan,
locus bean, arabic, tragacanth, polyacrylates, sulfonated
polyacrylates, water-soluble acrylate copolymers, alkylhydroxy
cellulosics, methylcellulose, carboxymethylcellulose sodium,
modified carboxy-methylcellulose, dextrin, ethylcellulose,
propylcellulose, hydroxyethyl cellulose, hydroxypropyl
methylcellulose, maltodextrin, polymethacrylates, polyvinyl alcohol
copolymers, hydroxypropyl methyl cellulose, and mixtures
thereof.
4. The composition according claim 1, wherein said carrier is water
soluble.
5. The composition according to claim 4, wherein said carrier is
polyethylene glycol having a weight average molecular weight from
about 2000 to about 13000.
6. The composition according to claim 1, wherein at least a portion
of said malodor agent is unencapsulated.
7. The composition according to claim 1, wherein at least a portion
of said malodor agent is encapsulated.
8. The composition according to claim 1, wherein said particles
comprise occlusions of gas.
9. The composition according to claim 8, wherein each of said
particles has a volume and said occlusions of gas within said
particles comprise between about 0.5% to about 50% by volume of
said particles.
10. The composition according to claim 9, wherein said occlusions
of gas have an effective diameter between about 1 micron to about
2000 microns.
11. The composition according to claim 10, wherein said occlusions
of gas are spherical occlusions of gas.
12. The composition according to claim 1, wherein said malodor
reduction materials have a Fragrance Fidelity Index of from about
Fragrance Fidelity Index of 3 to about 0.001.
13. The composition according to claim 1, wherein said malodor
agent comprises one or more malodor reduction materials having a
log P greater than 3 and said one or more malodor reduction
materials are selected from the group consisting of 2-ethylhexyl
(Z)-3-(4-methoxyphenyl)acrylate;
2,4-dimethyl-2-(5,5,8,8-tetramethyl-5,6,7,8-tetrahydronaphthalen-2-yl)-1,-
3-dioxolane; 1,1-dimethoxynon-2-yne;
3-methoxy-7,7-dimethyl-10-methylenebicyclo14.3.11decane;
methoxycyclododecane; 1,1-dimethoxycyclododecane;
(Z)-tridec-2-enenitrile;
(2-hydroxy-4-methoxyphenyl)(phenyl)methanone;
2,4a,5,8a-tetramethyl-1,2,3,4,4a,7, 8,8a-octahydronaphthalen-1-yl
formate; 1,8-dioxacycloheptadecan-9-one;
4-(tert-pentyl)cyclohexan-1-one; 2-methoxy-1,1'-biphenyl;
3a,5,6,7,8,8b-hexahydro-2,2,6,6,7,8,8-heptamethyl-4H-indeno(4,5-d)-1,3-di-
oxole; 7-isopropyl-8,8-dimethyl-6,10-dioxaspiro[4.5]decane; octyl
furan-2-carboxylate; octyl acetate;
2-heptyl-4-methyl-1,3-dioxolane; octanal; 1,1-dimethoxyoctane;
7-methyl-3-methyleneocta-1,6-diene;
2-methyl-6-methyleneoct-7-en-2-yl acetate; tetradecanal;
tetradecanenitrile;
2,2,6,8-tetramethyl-1,2,3,4,4a,5,8,8a-octahydronaphthalen-1-ol;
2-((1S,5R)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)ethyl acetate;
(4R,4aS,6R)-4,4a-dimethyl-6-(prop-1-en-2-yl)-4,4a,5,6,7,8-hexahydronaphth-
alen-2(3H)-one; nonan-1-ol; nonanal;
12-methyl-14-tetradec-9-enolide;
N-ethyl-2-isopropyl-5-methylcyclohexane-1-carboxamide;
2-methoxynaphthalene; (E)-3,7,11-trimethyldodeca-1,6,10-trien-3-ol;
(Z)-3,7-dimethylocta-2,6-dien-1-ol; methyl (E)-non-2-enoate;
10-isopropyl-2,7-dimethyl-1-oxaspiro[4.5]deca-3,6-diene;
2-(2-(4-methylcyclohex-3-en-1-yl)propyl)cyclopentan-1-one;
(E)-4-(2,2,3,6-tetramethylcyclohexyl)but-3-en-2-one;
(4-(4-methylpent-3-en-1-yl)cyclohex-3-en-1-yl)methyl acetate;
2-(tert-butyl)-4,5,6-trimethyl-1,3-phenylene dinitrite;
1,7-dioxacycloheptadecan-8-one;
1-(4-(tert-butyl)-2,6-dimethyl-3,5-dinitrophenyl)ethan-1-one;
1-(tert-butyl)-2-methoxy-4-methyl-3,5-dinitrobenzene;
3-methylcyclopentadecan-1-one;
(E)-3-methylcyclopentadec-4-en-1-one;
1-(4-isopropylcyclohexyl)ethan-1-ol; (E)-dec-5-enoic acid; methyl
non-2-ynoate; 2-methyldecanal;
6,6-dimethoxy-2,5,5-trimethylhex-2-ene; methyl stearate;
1,1-dimethoxy-2-methylundecane; undecan-2-one; 2-methylundecanal;
methyl tetradecanoate; methyl (9Z,12Z)-octadeca-9,12-dienoate;
methyl palmitate; 1-methyl-2-phenoxybenzene;
1-allyl-4-methoxybenzene; 1-(naphthalen-2-yl)ethan-1-one; methyl
oct-2-ynoate; methyl 2,6,6-trimethylcyclohex-2-ene-1-carboxylate;
7-isopropyl-10-methyl-1,5-dioxaspiro[5.5]undecan-3-ol;
3-(3-(tert-butyl)phenyl)-2-methylpropanal;
(E)-4-(4,8-dimethylnona-3,7-dien-1-yl)pyridine;
(E)-trideca-3,12-dienenitrile; 2,2-dimethyl-3-(m-tolyl)propan-1-ol;
8-isopropyl-6-methylbicyclo[2.2.2]oct-5-ene-2-carbaldehyde;
(S)-1-methyl-4-(prop-1-en-2-yl)cyclohex-1-ene;
3,7-dimethylocta-1,6-dien-3-yl octanoate;
3,7-dimethylocta-1,6-dien-3-yl isobutyrate;
3,7-dimethylocta-1,6-dien-3-yl benzoate;
3,7-dimethylocta-1,6-dien-3-yl 2-aminobenzoate;
(2Z,6E)-3,7-dimethylnona-2,6-dienenitrile;
3-(4-methylcyclohex-3-en-1-yl)butanal;
(2,5-dimethyl-1,3-dihydroinden-2-yl)methanol;
3-(4-(tert-butyl)phenyl)-2-methylpropanal; dodecan-1-ol; dodecyl
acetate; dodecanoic acid; 5-hexyl-5-methyldihydrofuran-2(3H)-one;
dodecanal; 4-(1-ethoxyvinyl)-3,3,5,5-tetramethylcyclohexan-1-one;
((3S,3aR,6R,8aS)-7,7-dimethyl-8-methyleneoctahydro-1H-3a,6-methanoazulen--
3-yl)methanol;
5-(sec-butyl)-2-(2,4-dimethylcyclohex-3-en-1-yl)-5-methyl-1,3-dioxane;
(1-methyl-2-((1,2,2-trimethylbicyclo[3.1.0]hexan-3-yl)methyl)cyclopropyl)-
methanol; 2-propylheptanenitrile; 2-hexylcyclopentan-1-one;
2,6,9,10-tetramethyl-1-oxaspiro(4.5)deca-3,6-diene; isopropyl
palmitate; isopropyl tetradecanoate; isopropyl dodecanoate;
(E)-cyclohexadec-8-en-1-one;
(2S,5S)-2-isopropyl-5-methylcyclohexan-1-one;
2-hexylcyclopent-2-en-1-one;
(2S,5S)-2-isopropyl-5-methylcyclohexan-1-one;
4-(4-methylpent-3-en-1-yl)cyclohex-3-ene-1-carbaldehyde;
(Z)-1-(benzyloxy)-2-methoxy-4-(prop-1-en-1-yl)benzene;
1-((2S,3S)-2,3,8,8-tetramethyl-1,2,3,4,5,6,7,8-octahydronaphthalen-2-yeet-
han-1-one; 6-(sec-butyl)quinoline;
2-(cyclohexyloxy)-1,7,7-trimethylbicyclo[2.2.1]heptane;
(1R,2R,4S)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl propionate;
(1S,2S,4S)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl isobutyrate;
4-((2R)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl)cyclohexan-1-ol;
(1R,4S)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl acetate;
2-(4-isopropylcyclohexa-1,4-dien-1-yl)ethyl formate; isopentyl
(E)-undec-6-enoate; isopentyl dodecanoate;
(E)-oxacycloheptadec-10-en-2-one; (E)-non-2-enenitrile;
(E)-8-(1H-indol-1-yl)-2,6-dimethyloct-7-en-2-ol;
8,8-di(1H-indol-1-yl)-2,6-dimethyloctan-2-ol;
2-cyclododecylpropan-1-ol; 3-methyl-5-phenylpentanenitrile;
2,3-dihydro-3,3-dimethyl-1H-indene-5-propanal;
3-(3,3-dimethyl-2,3-dihydro-1H-inden-5-yl)propanal; hexyl
octanoate; hexyl hexanoate; (Z)-2-benzylideneoctanal; hexyl
benzoate; (Z)-hex-1-en-1-yl (Z)-2-methylbut-2-enoate;
(E)-3,7-dimethylocta-2,6-dien-1-yl palmitate;
oxacycloheptadecan-2-one; ethyl
(1R,2R,3R,4R)-3-isopropylbicyclo[2.2.1]hept-5-ene-2-carboxylate;
2-(1-(3,3-dimethylcyclohexyl)ethoxy)-2-methylpropyl propionate;
(E)-oxacyclohexadec-13-en-2-one;
6-butyl-2,4-dimethyl-3,6-dihydro-2H-pyran;
2-((3S,5R,8S)-3,8-dimethyl-1,2,3,4,5,6,7,8-octahydroazulen-5-yl)propan-2--
ol; 1-(2,6,6-trimethylcyclohex-2-en-1-yl)pentan-3-one; ethyl
2-ethyl-6,6-dimethylcyclohex-2-ene-1-carboxylate;
(1Z,5Z)-1,5-dimethyl-8-(propan-2-ylidene)cyclodeca-1,5-diene;
(1E,6E)-8-isopropyl-1-methyl-5-methylenecyclodeca-1,6-diene;
(E)-3,7-dimethylocta-2,6-dien-1-yl 2-phenylacetate;
(E)-3,7-dimethylocta-2,6-dien-1-yl 2-phenylacetate;
(6E,10E)-3,7,11,15-tetramethylhexadeca-1,6,10,14-tetraen-3-ol;
(E)-2-(3,7-dimethylocta-2,6-dien-1-yl)cyclopentan-1-one;
5-heptyldihydrofuran-2(3H)-one;
1-methyl-4-(propan-2-ylidene)cyclohexyl acetate;
1-methyl-4-(propan-2-ylidene)cyclohexan-1-ol;
(1R,4aR,8aS)-1-isopropyl-7-methyl-4-methylene-1,2,3,4,4a,5,6,8a-octahydro-
naphthalene;
(Z)-4-(2,2-dimethyl-6-methylenecyclohexyl)but-3-en-2-one;
(4aS,9aR)-3,5,5,9-tetramethyl-2,4a,5,6,7,9a-hexahydro-1H-benzo[7]annulene-
;
(1R,3aR,4R,7R)-1,4-dimethyl-7-(prop-1-en-2-yl)-1,2,3,3a,4,5,6,7-octahydr-
oazulene;
2-((2R,4aR)-4a,8-dimethyl-1,2,3,4,4a,5,6,7-octahydronaphthalen-2-
-yl)propan-2-ol; 5-octyldihydrofuran-2(3H)-one;
(Z)-1-(2,2-dimethyl-6-methylenecyclohexyl)but-2-en-1-one;
(1R,4aS,8aS)-1-isopropyl-7-methyl-4-methylene-1,2,3,4,4a,5,6,8a-octahydro-
naphthalene; 1-(3,3-dimethylcyclohexyl)pent-4-en-1-one;
4,6,6,7,8,8-hexamethyl-1,3,4,6,7,8-hexahydrocyclopenta[g]isochromene;
furan-2-ylmethyl octanoate; furan-2-ylmethyl hexanoate;
furan-2-ylmethyl heptanoate; 2-methyldecanenitrile;
8,8-dimethyl-3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-yl
propionate; ethyl
(3aR,4S,7R,7aR)-octahydro-3aH-4,7-methanoindene-3a-carboxylate;
(6-isopropyl-9-methyl-1,4-dioxaspiro[4.5]decan-2-yemethanol;
undec-10-enenitrile; 3-(2-ethylphenyl)-2,2-dimethylpropanal;
(E)-4,8-dimethyldeca-4,9-dienal;
(E)-4-((3aR,4R,7R,7aR)-1,3a,4,6,7,7a-hexahydro-5H-4,7-methanoinden-5-ylid-
ene)-3-methylbutan-2-ol; 8,8-dimethyl-3 a,4,5
,6,7,7a-hexahydro-1H-4,7-methanoinden-6-yl acetate;
3-(4-ethylphenyl)-2,2-dimethylpropanenitrile;
2-heptylcyclopentan-1-one; 1-ethoxyethoxy Cyclododecane;
3-cyclohexene-1-carboxylic acid, 2,6,6-trimethyl-, methyl ester;
(2E,6E)-3,7,11-trimethyldodeca-2,6,10-trien-1-yl acetate;
(2E,6E)-3,7,11-trimethyldodeca-2,6,10-trien-1-ol;
oxacyclohexadecan-2-one; (E)-cyclopentadec-4-en-1-one;
1-cyclopentadec-4-en-1-one; 1,4-dioxacycloheptadecane-5,17-dione;
ethyl undec-10-enoate; ethyl palmitate; ethyl nonanoate; ethyl
tetradecanoate; (E)-3,7-dimethylnona-1,6-dien-3-ol; ethyl
dodecanoate; ethyl decanoate; ethyl
6,6-dimethyl-2-methylenecyclohex-3-ene-1-carboxylate;
6-ethyl-2,10,10-trimethyl-1-oxaspiro[4.5]deca-3,6-diene;
2-((1R,3S,4S)-4-methyl-3-(prop-1-en-2-yl)-4-vinylcyclohexyl)propan-2-ol;
(E)-3-methyl-5-(2,2,3-trimethylcyclopent-3-en-1-yl)pent-4-en-2-ol;
(E)-4-((3aS,7aS)-octahydro-5H-4,7-methanoinden-5-ylidene)butanal;
1,1-dimethoxydodecane;
(R)-1-methyl-4-(prop-1-en-2-yl)cyclohex-1-ene;
7,9-dimethylspiro[5.5]undecan-3-one; oxydibenzene; diphenylmethane;
2-methyl-1-phenylpropan-2-yl butyrate;
octahydro-1H-4,7-methanoinden-5-yl acetate;
2-methyl-5-(prop-1-en-2-yl)cyclohexyl acetate;
3,7-dimethyloct-6-en-3-ol; dibutylsulfane; 1,2-diphenylethane;
6-hexyltetrahydro-2H-pyran-2-one;
(3R,4R)-1-isopropyl-4-methyl-3-(prop-1-en-2-yl)-4-vinylcyclohex-1-ene;
(3S,3
aS,5R)-3,8-dimethyl-5-(prop-1-en-2-yl)-1,2,3,3a,4,5,6,7-octahydroaz-
ulene; 6-heptyltetrahydro-2H-pyran-2-one;
(1S,8aR)-4,7-dimethyl-1-(propan-2-yl)-1,2,3,5,6,8a-hexahydronaphthalene;
(Z)-1-((1R,2S)-2,6,6-trimethylcyclohex-3-en-1-yl)but-2-en-1-one;
(1S,8aS)-1-isopropyl-4,7-dimethyl-1,2,3,5,6,8a-hexahydronaphthalene;
3,7,7-trimethylbicyclo[4.1.0]hept-3-ene; dec-9-en-1-ol; decyl
propionate; 1,1-diethoxydecane; 1-cyclohexylethyl (E)-but-2-enoate;
3-(4-isopropylphenyl)-2-methylpropanal; cyclotetradecane;
cyclopentadecanone; cyclohexyl 2-hydroxybenzoate;
3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-yl butyrate;
8,8-dimethyl-1,2,3,4,5,6,7,8-octahydronaphthalene-2-carbaldehyde;
3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-5-yl isobutyrate;
(5R,6R)-3,6-dimethyl-5-(prop-1-en-2-yl)-6-vinyl-4,5,6,7-tetrahydrobenzofu-
ran; 2-(3-phenylpropyl)pyridine; dodecanenitrile;
(E)-cycloheptadec-9-en-1-one;
3-(4-methylcyclohex-3-en-1-yl)but-3-en-1-yl acetate;
3-(4-methylcyclohex-3-en-1-yl)butan-1-ol;
(E)-3-methyl-5-phenylpent-2-enenitrile;
(E)-2-(2,6-dimethylhepta-1,5-dien-1-yl)-4-methyl-1,3-dioxolane;
(E)-1,1-dimethoxy-3,7-dimethylocta-2,6-diene;
(E)-1,1-diethoxy-3,7-dimethylocta-2,6-diene;
(E)-3,7-dimethylocta-1,3,6-triene;
(E)-oxacycloheptadec-11-en-2-one; (Z)-dec-4-enal; (E)-hex-3-en-1-yl
(E)-hex-3-enoate; (Z)-hex-3-en-1-yl 2-hydroxybenzoate;
(Z)-hex-3-en-1-yl benzoate; (Z)-hex-3 -en-1-yl 2-methylbutanoate;
cinnamyl propionate; cinnamyl isobutyrate; cinnamyl cinnamate;
hexadecan-1-ol;
(E)-1-(2,6,6-trimethylcyclohex-2-en-1-yl)hepta-1,6-dien-3-one;
2-methyl-4-(2,6,6-trimethylcyclohex-1-en-1-yl)butanal;
(3aR,5aR,9aR,9bR)-3a,6,6,9a-tetramethyldodecahydronaphtho[2,1-b]furan;
1,6-dioxacycloheptadecan-7-one;
1-(6-(tert-butyl)-1,1-dimethyl-2,3-dihydro-1H-inden-4-yl)ethan-1-one;
(3R,3aR,6S,7S,8aS)-6-methoxy-3,6,8,8-tetramethyloctahydro-1H-3a,7-methano-
azulene;
(3R,3aS,6R,7R,8aS)-3,6,8,8-tetramethyloctahydro-1H-3a,7-methanoaz-
ulen-3-yl formate;
(3R,3aS,6R,7R,8aS)-3,6,8,8-tetramethyloctahydro-1H-3a,7-methanoazulen-6-y-
l acetate;
(4Z,8Z)-1,5,9-trimethyl-13-oxabicyclo[10.1.0]trideca-4,8-diene;
(3R,3aS,6R,7R,8aS)-3,6,8,8-tetramethyloctahydro-1H-3a,7-methanoazulen-6-o-
l;
5-methyl-1-(2,2,3-trimethylcyclopent-3-en-1-yl)-6-oxabicyclo[3.2.1]octa-
ne; 5
-methyl-1-(2,2,3-trimethylcyclopent-3-en-1-yl)-6-oxabicyclo[3.2.1]oc-
tane; 1,1,2,3,3-pentamethyl-1,2,3,5,6,7-hexahydro-4H-inden-4-one;
(Z)-4,11,11-trimethyl-8-methylenebicyclo[7.2.0]undec-3-en-5-yl
acetate;
(1S,2S,5R,8S)-4,4,8-trimethyltricyclo[6.3.1.02.5]dodecan-1-ol;
2-methyl-5-(prop-1-en-2-yl)cyclohex-2-en-1-yl acetate;
octanenitrile; decanoic acid; decanal;
2,2-dimethyl-3-methylenebicyclo[2.2.1]heptane; ethyl
2-methyl-4-oxo-6-pentylcyclohex-2-ene-1-carboxylate;
2,6-di-tert-butyl-4-methylphenol; butyl stearate; butyl
undec-10-enoate; 2-methyl-4-(2,2,3-trimethylcyclopent-3
-en-1-yl)butan-1-ol; 3-(4-(tert-butyl)phenyl)propanal;
(1S,2S)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl isobutyrate;
1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl acetate;
2-ethoxy-2,6,6-trimethyl-9-methylenebicyclo[3.3.1]nonane;
(ethoxymethoxy)cyclododecane;
(E)-1-methyl-4-(6-methylhept-5-en-2-ylidene)cyclohex-1-ene;
3,3,6,7-tetramethyloctahydro-2H-chromene;
(5R,10R)-6,10-dimethyl-2-(propan-2-ylidene)spiro[4.5]dec-6-en-8-one;
1-methyl-4-(prop-1-en-2-yl)cyclohexyl acetate;
(2Z,6E)-2,6-dimethyl-10-methylenedodeca-2,6,11-trienal;
(R)-3-methylene-6-((S)-6-methylhept-5-en-2-yl)cyclohex-1-ene;
(4aR,7R,8aS)-4a-methyl-1-methylene-7-(prop-1-en-2-yl)decahydronaphthalene-
;
(Z)-2-methyl-5-((1S,2R,4R)-2-methyl-3-methylenebicyclo[2.2.1]heptan-2-yl-
)pent-2-en-1-ol; 6,6-dimethyl-2-methylenebicyclo[3.1.1]heptane;
2-ethoxynaphthalene;
(1S,4R,7R)-1,4,9,9-tetramethyl-1,2,3,4,5,6,7,8-octahydro-4,7-methanoazule-
ne;
(1aS,5aR,9aR)-1a,5,5,7-tetramethyl-1a,2,3,4,5,5a,8,9-octahydrobenzol[1-
,7]cycloheptal[1,2-b]oxirene;
(R)-3,5,5,9-tetramethyl-2,4a,5,6,7,8-hexahydro-1H-benzol7lannulene;
(1S,4S)-1,4-dimethyl-7-(propan-2-ylidene)-1,2,3,4,5,6,7,8-octahydroazulen-
e; (E)-7,11-dimethyl-3-methylenedodeca-1,6,10-triene;
(1R,2S,6S,7S,8S)-8-isopropyl-1-methyl-3-methylenetricyclo[4.4.0.02,7]deca-
ne;
(3R,3aS,7S,8aS)-3,8,8-trimethyl-6-methyleneoctahydro-1H-3a,7-methanoaz-
ulene; (1R,9S
,Z)-4,11,11-trimethyl-8-methylenebicyclo[7.2.0]undec-4-ene;
(S)-4-methyl-1-((S)-6-methylhept-5-en-2-yl)cyclohex-3-en-1-ol;
benzyl dodecanoate; benzyl cinnamate; benzyl benzoate;
2'-isopropyl-1,7,7-trimethylspiro[bicyclo[2.2.1]heptane-2,4'-[1,3]dioxane-
]; 4-(4-methylpent-3-en-1-yl)cyclohex-3-ene-1-carbonitrile; methyl
(E)-2-((7-hydroxy-3,7-dimethyloctylidene)amino)benzoate;
4-methoxybenzyl 2-phenylacetate; pentyl (Z)-3-phenylacrylate;
(3aR,5aS,9aS,9bR)-3a,6,6,9a-tetramethyldodecahydronaphtho[2,1-b]furan;
(4aR,5R,7aS,9R)-2,2,5,8,8,9a-hexamethyloctahydro-4H-4a,9-methanoazuleno[5-
,6-d][1,3]dioxole;
2,5,5-trimethyl-1,2,3,4,5,6,7,8-octahydronaphthalen-2-ol;
2,5,5-trimethyl-1,2,3,4,4a,5,6,7-octahydronaphthalen-2-ol;
1-((2-(tert-butyl)cyclohexyl)oxy)butan-2-ol;
(3S,5aR,7aS,11aS,11bR)-3,8,8,11a-tetramethyldodecahydro-5H-3,5
a-epoxynaphtho[2,1-c]oxepine;
2,2,6,6,7,8,8-heptamethyldecahydro-2H-indeno[4,5-b]furan;
2,2,7,7,8,9,9-heptamethyldecahydroindeno[4,3a-b]furan;
2-(sec-butyl)-1-vinylcyclohexyl acetate;
(4R,4aS)-4,4a-dimethyl-6-(propan-2-ylidene)-4,4a,5,6,7,8-hexahydronaphtha-
len-2(3H)-one; 2-(4-methylcyclohex-3-en-1-yl)propan-2-yl
propionate; (2Z,6E,9E)-2,6,10-trimethyldodeca-2,6,9,11-tetraenal;
(2R,4aR,8aR)-4a,8-dimethyl-2-(prop-1-en-2-yl)-1,2,3,4,4a,5,6,8a-octahydro-
naphthalene;
1,7-dimethyl-7-(4-methylpent-3-en-1-yl)tricyclo[2.2.1.02,6]heptane;
(E)-5-(2,3-dimethyltricyclo[2.2.1.02,6]heptan-3-yl)-2-methylpent-2-en-1-o-
l;
(1R,3aS,7S,8aR)-1,4,9,9-tetramethyl-2,3,6,7,8,8a-hexahydro-1H-3a,7-meth-
anoazulene; 1-(5,5-dimethylcyclohex-1-en-1-yl)pent-4-en-1-one;
(1S,4aS,8aR)-1-isopropyl-4,7-dimethyl-1,2,4a,5,6,8a-hexahydronaphthalene;
(R,Z)-1-(2,6,6-trimethylcyclohex-2-en-1-yl)pent-1-en-3-one;
1-methyl-4-(prop-1-en-2-yl)cyclohex-1-ene;
(Z)-4-(2,5,6,6-tetramethylcyclohex-2-en-1-yl)but-3-en-2-one;
(1Z,4E,8Z)-2,6,6,9-tetramethylcycloundeca-1,4,8-triene;
(4aR,8S,9aS)-3,5,5,8-tetramethyl-9-methylene-2,4a,5,6,7,8,9,9a-octahydro--
1H-benzo[7]annulene;
(1aR,4R,4aR,7bS)-1,1,4,7-tetramethyl-1a,2,3,4,4a,5,6,7b-octahydro-1H-cycl-
opropa[e]azulene;
1,4-dimethyl-7-(prop-1-en-2-yl)-1,2,3,4,5,6,7,8-octahydroazulene;
(3E,6E)-3,7,11-trimethyldodeca-1,3,6,10-tetraene;
7,7-dimethyl-2-methylenebicyclo[2.2.1]heptane;
2-((2R,4aR,8aR)-4a,8-dimethyl-1,2,3,4,4a,5,6,8a-octahydronaphthalen-2-yl)-
propan-2-ol; (R)-1-methyl-4-(6-methylhept-5-en-2-yl)benzene;
(3aR,3bR,4S,7R,7aS)-4-isopropyl-7-methyl-3a,3b,4,5,6,7-hexahydro-1H-cyclo-
penta[1,3]cyclopropa[1,2]benzene;
(1aS,2aR,3R,5aS,7R,7aR)-3,6,6,7a-tetramethyloctahydro-2H-2a,7-methanoazul-
eno[5,6-b]oxirene;
(1R,4S,4aR,8aR)-4-isopropyl-1,6-dimethyl-1,2,3,4,4a,7,8,8a-octahydronapht-
halen-1-ol;
(1S,4aR,8aR)-1-isopropyl-4,7-dimethyl-1,2,4a,5,6,8a-hexahydronaphthalene;
(R)-2-((R)-4-methylcyclohex-3-en-1-yl)hex-5-en-2-ol;
(Z)-1-methyl-4-(6-methylhepta-2,5-dien-2-yl)cyclohex-1-ene;
2,6-dimethyl-6-(4-methylpent-3-en-1-yl)bicyclo[3.1.1]hept-2-ene;
(E)-2-benzylideneheptan-1-ol; (E)-2-benzylideneheptyl acetate;
(Z)-(2-(diethoxymethyl)hept-1-en-1-yl)benzene;
(E)-2-benzylideneheptanal;
(1S,4aR,8aS)-1-isopropyl-4,7-dimethyl-1,2,4a,5,6,8a-hexahydronaphthalene;
(3R,5aS,9aR)-2,2,5a,9-tetramethyl-3,4,5,5a,6,7-hexahydro-2H-3,9a-methanob-
enzo[b]oxepine;
1-methyl-4-(4-methylpent-3-en-1-yl)cyclohex-3-ene-1-carbaldehyde;
3-methyl-1-phenylpentan-3-ol; 2,6,10-trimethylundecanal; allyl
3-cyclohexylpropanoate;
(1aR,4aS,7R,7aR,7bS)-1,1,7-trimethyl-4-methylenedecahydro-1H-cyclopropa[e-
]azulene; (E)-undec-9-enal; methyl
(E)-2-(((3,5-dimethylcyclohex-3-en-1-yl)methylene)amino)benzoate;
2,6,10-trimethylundec-9-enal;
(7,7,8,8-tetramethyloctahydro-2,3b-methanocyclopenta[1,3]cyclopropa[1,2]b-
enzen-4-yl)methyl acetate; nonyl acetate;
(2-(1-propoxyethoxy)ethyl)benzene;
(Z)-2-(4-methylbenzylidene)heptanal; dec-9-enal;
(Z)-oxacycloheptadec-8-en-2-one;
(2S,4aR,8aR)-4a,8-dimethyl-2-(prop-1-en-2-yl)-1,2,3,4,4a,5,6,8a-octahydro-
naphthalene;
2-((2S,4aR,8aR)-4a,8-dimethyl-1,2,3,4,4a,5,6,8a-octahydronaphthalen-2-yl)-
propan-2-ol;
1-(3,5,5,6,8,8-hexamethyl-5,6,7,8-tetrahydronaphthalen-2-yl)ethan-1-one;
6-isopropylquinoline;
3-(6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)propanal;
6,10,14-trimethylpentadecan-2-one; (E)-cyclohexadec-5-en-1-one;
1-isopropyl-4-methylcyclohex-3-en-1-ol;
1-isopropyl-4-methylcyclohex-3-en-1-ol;
3,6-dimethyl-4,5,6,7-tetrahydrobenzofuran;
(1aR,2S,4aS)-2,4a,8,8-tetramethyloctahydrocyclopropa[d]naphthalen-3(1H)-o-
ne; (Z)-dodec-2-enal; (E)-hex-3-en-1-yl 3-methylbutanoate;
3,6-dimethyloctan-3-yl acetate; 3-(4-isopropylphenyl)propanal;
(Z)-undec-2-enenitrile; (E)-undec-2-enal; phenethyl butyrate;
(Z)-non-2-enal; nonan-2-ol; nonan-2-one; 2-isobutylquinoline;
(E)-2-hexylidenecyclopentan-1-one; 2-heptyltetrahydrofuran;
(E)-dec-2-enal; 2,6-dimethyloctanal; decan-1-ol; (E)-hept-1-en-1-yl
acetate; undec-10-en-1-ol; undec-10-enal;
2-((2R,4aS)-4a,8-dimethyl-1,2,3,4,4a,5,6,7-octahydronaphthalen-2-yl)propa-
n-2-ol; 1-isopropyl-4-methyl-7-thiabicyclo[2.2.1]heptane;
(3E,5Z)-undeca-1,3,5-triene; 3,7-dimethyloct-6-en-3-ol;
1,3,3-trimethylbicyclo[2.2.1]heptan-2-yl acetate;
1,1,2,3,3-pentamethyl-2,3-dihydro-1H-indene;
(Z)-6,10-dimethylundeca-5,9-dien-2-yl acetate; (Z)-dodec-3-enal;
(S)-5-heptyldihydrofuran-2(3H)-one;
(R)-5-heptyldihydrofuran-2(3H)-one;
(E)-6,10-dimethylundeca-5,9-dien-2-yl acetate;
(Z)-3-methyl-5-phenylpent-2-enenitrile; (2S,5
S,6S)-2,6,10,10-tetramethyl-1-oxaspiro[4.5]decan-6-ol;
(2E)-3-methyl-5-phenyl-2-pentenenitrile;
(2S,5R)-2-isopropyl-5-methylcyclohexan-1-one;
(R,E)-2-methyl-4-(2,2,3-trimethylcyclopent-3-en-1-yl)but-2-en-1-ol;
2-(8-isopropyl-6-methylbicyclo[2.2.2]oct-5-en-2-yl)-1,3-dioxolane;
(E)-4-(2,2-dimethyl-6-methylenecyclohexyl)-3-methylbut-3-en-2-one;
3-(3-isopropylphenyl)butanal;
3-(1-ethoxyethoxy)-3,7-dimethylocta-1,6-diene;
3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-yl propionate;
2-((3S,3aS,5R)-3,8-dimethyl-1,2,3,3a,4,5,6,7-octahydroazulen-5-yl)propan--
2-ol; benzyl 2-phenylacetate;
3-(6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2,2-dimethylpropanal;
2-methyl-5-(6-methylhept-5-en-2-yl)bicyclo[3 .1.0]hex-2-ene;
1-(1,1,2,3,3,6-hexamethyl-2,3-dihydro-1H-inden-5-yl)ethan-1-one;
(E)-tridec-2-enal;
(1R,4S,4aS,6R,8aS)-4,8a,9,9-tetramethyloctahydro-1,6-methanonaphthalen-1(-
2H)-ol; p-tolyl hexanoate; 5-hexyl-4-methyldihydrofuran-2(3H)-one;
ethyl (2Z,4E)-deca-2,4-dienoate;
2,4-dimethyl-6-phenyl-3,6-dihydro-2H-pyran;
2-cyclohexylidene-2-phenylacetonitrile;
(4-(prop-1-en-2-yl)cyclohex-1-en-1-yl)methyl acetate;
(4-(prop-1-en-2-yl)cyclohex-1-en-1-yl)methanol;
(2-isopropoxyethyl)benzene; 2-cyclohexylhepta-1,6-dien-3-one;
(2-(cyclohexyloxy)ethyl)benzene; phenethyl 2-methylbutanoate;
phenethyl 2-phenylacetate; phenyl benzoate; phenethyl benzoate;
2-(6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)acetaldehyde;
3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-yl pivalate;
(E)-3,3-dimethyl-5-(2,2,3-trimethylcyclopent-3-en-1-yl)pent-4-en-2-ol;
1-methyl-4-(4-methylpent-3-en-1-yl)cyclohex-3-ene-1-carbaldehyde;
p-tolyl 2-phenylacetate; Ethyl 2,4,7-decatrienoate;
2-benzyl-4,4,6-trimethyl-1,3-dioxane;
2,4-dimethyl-4-phenyltetrahydrofuran;
(2R,4a'R,8a'R)-3,7'-dimethyl-3',4',4a',5',8',8a'-hexahydro-1'H-spiro[oxir-
ane-2,2'-[1,4]methanonaphthalene];
(Z)-6-ethylideneoctahydro-2H-5,8-methanochromene;
2-((S)-1-((S)-3,3-dimethylcyclohexyl)ethoxy)-2-oxoethyl propionate;
methyl 2,2-dimethyl-6-methylenecyclohexane-1-carboxylate;
4-methyl-2-phenyl-3,6-dihydro-2H-pyran;
2,2,7,9-tetramethylspiro(5.5)undec-8-en-1-one; 3-methyl-5-(2,2,3
-trimethylcyclopent-3-en-1-yl)pentan-2-ol;
(Z)-2-ethyl-4-(2,2,3-trimethylcyclopent-3-en-1-yl)but-2-en-1-ol;
(E)-2-methyl-4-(2,2,3-trimethylcyclopent-3-en-1-yl)but-2-en-1-ol;
1-(3
-hydroxy-3-methylpent-4-en-1-yl)-2,5,5,8a-tetramethyldecahydronaphthalen--
2-ol; (4
aR,6aS,10aS,10bR)-3,4a,7,7,10a-pentamethyl-4a,5,6,6a,7,8,9,10,10a-
,10b-decahydro-1H-benzo[1]chromene ;
(4aR,8aR)-4a,8-dimethyl-2-(propan-2-ylidene)-1,2,3,4,4a,5,6,8a-octahydron-
aphthalene; 2-(1-(3,3-dimethylcyclohexyl)ethoxy)-2-methylpropyl
cyclopropanecarboxylate; 3-(4-isobutylphenyl)-2-methylpropanal;
(1aR,4aR,7S,7aR,7bR)-1,1,7-trimethyl-4-methylenedecahydro-1H-cyclopropa[e-
]azulen-7-ol; 1-(spiro[4.5]dec-7-en-7-yl)pent-4-en-1-one;
(Z)-dodec-4-enal;
(1S,4S,4aR,8aR)-4-isopropyl-1,6-dimethyl-1,2,3,4,4a,7,8,8a-octahydronapht-
halen-1-ol;
(1S,4S,4aR,8aS)-4-isopropyl-1,6-dimethyl-1,2,3,4,4a,7,8,8a-octahydronapht-
halen-1-ol; 3-methyl-2-pentylcyclopentan-1-one;
2,6,10,10-tetramethyl-1-oxaspiro[4.5]dec-6-ene;
(1aR,4aS)-2,4a,8,8-tetramethyl-1,1a,4,4a,5,6,7,8-octahydrocyclopropa[d]na-
phthalene; 1-isopropyl-2-methoxy-4-methylbenzene;
1-(2,2,6-trimethylcyclohexyl)hexan-3-ol;
(2E,6E)-3,7,11-trimethyldodeca-2,6,10-trien-1-ol; (Z)-dec-2-enal;
(E)-non-2-enal; (E)-dec-4-enal; (Z)-oxacycloheptadec-8-en-2-one;
(Z)-3,7-dimethylocta-1,3,6-triene;
(Z)-3,7-dimethylocta-1,3,6-triene;
(E)-3,7-dimethylocta-2,6-dien-1-ol;
(1R-(1alpha,3alpha,4aalpha))-2,3,4,4a,5,6-hexahydro-2,2-dimethyl-1,3-meth-
anonaphthalen-7(1H)-one; tridecan-1-ol; methyl
2-((1-hydroxy-3-phenylbutyl)amino)benzoate;
1-((2E,5Z,9Z)-2,6,10-trimethylcyclododeca-2,5,9-trien-1-yl)ethan-1-one;
decahydro-2,6,6,7,8,8-hexamethyl-2h-indeno(4,5-b)furan; pentamethyl
octahydroindenodioxane; undecanal; (E)-4-methyldec-3-en-5-ol;
(3R,4aS,5R)-4a,5-dimethyl-3-(prop-1-en-2-yl)-1,2,3,4,4a,5,6,7-octahydrona-
phthalene;
2-((2R,8R,8aS)-8,8a-dimethyl-1,2,3,4,6,7,8,8a-octahydronaphthal-
en-2-yl)propan-2-ol;
(Z)-2-methyl-4-(2,6,6-trimethylcyclohex-2-en-1-yl)but-2-enal;
1-methoxy-3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoindene; methyl
(Z)-2-((3-(4-(tert-butyl)phenyl)-2-methylpropylidene)amino)benzoate;
2,4,6-trimethyl-4-phenyl-1,3-dioxane;
1-((3R,3aR,7R,8aS)-3,6,8,8-tetramethyl-2,3,4,7,8,8a-hexahydro-1H-3a,7-met-
hanoazulen-5-yl)ethan-1-one; methyl
(Z)-2-(((2,4-dimethylcyclohex-3-en-1-yl)methylene)amino)benzoate;
4,8-dimethyl-2-(propan-2-ylidene)-1,2,3,3a,4,5,6,8a-octahydroazulen-6-ol;
4,8-dimethyl-2-(prop
an-2-ylidene)-1,2,3,3a,4,5,6,8a-octahydroazulen-6-yl acetate;
decahydro-3H-spiro[furan-2,5'-[4,7]methanoindene];
(2Z,6E)-nona-2,6-dienenitrile;
(1aR,4S,4aS,7R,7aS,7bS)-1,1,4,7-tetramethyldecahydro-1H-cyclopropa[e]azul-
en-4-ol;
3,5,5,6,7,8,8-heptamethyl-5,6,7,8-tetrahydronaphthalene-2-carboni-
trile; (1S,2S,3S,5R)-2,6,6-trimethylspiro[bicyclo[3.1.1]
heptane-3,1'-cyclohexan]-2'-en-4'-one;
1',1',5',5'-tetramethylhexahydro-2'H,5'H-spiro[[1,3]dioxolane-2,8'-[2,4a]-
methanonaphthalene];
(2'S,4a'S,8a'S)-1',1',5',5'-tetramethylhexahydro-2'H,5'H-spiro[[1,3]dioxo-
lane-2,8'-[2,4a]methanonaphthalene];
(1R,8aR)-4-isopropyl-1,6-dimethyl-1,2,3,7,8,8a-hexahydronaphthalene;
(7,7,8,8-tetramethyloctahydro-2,3b-methanocyclopenta[1,3]cyclopropa[1,2]b-
enzen-4-yl)methanol; 1-ethoxy-4-(tert-pentyl)cyclohexane;
(3Z)-1-(2-buten-1-yloxy)-3-hexene;
4-(2-methoxypropan-2-yl)-1-methylcyclohex-1-ene;
3-methoxy-3,7-dimethylocta-1,6-diene; 3,7-dimethyloctanal; hexyl
2-hydroxybenzoate; hexyl (Z)-but-2-enoate;
(Z)-3,7-dimethylocta-2,6-dien-1-yl formate;
(Z)-1-(2,6,6-trimethylcyclohex-1-en-1-yl)pent-1-en-3-one;
(E)-3,7-dimethylocta-4,6-dien-3-ol; methyl
(Z)-3,7-dimethylocta-2,6-dienoate;
((1s,4s)-4-isopropylcyclohexyl)methanol;
3,7-dimethylocta-1,6-dien-3-yl propionate;
3,7-dimethylocta-1,6-dien-3-yl formate;
3,7-dimethylocta-1,6-dien-3-yl butyrate;
3,7-dimethylocta-1,6-dien-3-yl acetate;
3,7-dimethylocta-1,6-dien-3-ol; 2,2-dimethyl-5-phenylhexanenitrile;
(Z)-4-(6,6-dimethylcyclohex-2-en-1-yl)-3-methylbut-3-en-2-one;
7-methyloctyl acetate; isopentyl octanoate; hexyl propionate; hexyl
butyrate; hexyl 2-methylbutanoate; hexyl furan-2-carboxylate;
heptyl acetate; (Z)-3,7-dimethylocta-2,6-dienenitrile;
(E)-3,7-dimethylocta-2,6-dien-1-yl formate;
(E)-3,7-dimethylocta-2,6-dien-1-yl octanoate;
(E)-3,7-dimethylocta-2,6-dien-1-yl benzoate;
(E)-3,7-dimethylocta-2,6-dienal;
1-isopropyl-4-methylcyclohexa-1,4-diene;
2-(sec-butyl)cyclohexan-1-one;
3-(2-ethylphenyl)-2,2-dimethylpropanal; 2-(tert-butyl)cyclohexyl
ethyl carbonate; ethyl octanoate; ethyl 2-cyclohexylpropanoate;
4-methyl-2-phenyltetrahydro-2H-pyran; 2,6-dimethyloct-7-en-2-ol;
3-methyl-2-pentylcyclopent-2-en-1-one;
2-(4-methylcyclohexyl)propan-2-yl acetate;
4-(2,6,6-trimethylcyclohex-2-en-1-yl)butan-2-one;
(oxybis(methylene))dibenzene; dibutyl phthalate; decyl
2-aminobenzoate; methyl
(1s,4s)-1,4-dimethylcyclohexane-1-carboxylate; 2-cyclohexylethyl
acetate; (3Z,5Z)-2,6-dimethylocta-1,3,5,7-tetraene;
4-cyclohexyl-2-methylbutan-2-ol; 2-benzyl-2-methylbut-3-enenitrile;
3,7-dimethyloct-6-enenitrile; 3,7-dimethyloct-6-en-1-yl
2-phenylacetate; 3,7-dimethyloct-6-en-1-yl formate;
3,7-dimethyloct-6-en-1-yl benzoate; 3,7-dimethyloct-6-en-1-ol;
3,7-dimethyloct-6-enal; (E)-3,7-dimethylocta-2,6-dienal;
(1R,2S,5R)-2,6,6-trimethylbicyclo[3.1.1]heptane; (Z)-hex-3 -en-1-yl
pentanoate; (E)-hex-3-en-1-yl (E)-2-methylbut-2-enoate;
(Z)-hex-3-en-1-yl butyrate; 4-chloro-3,5-dimethylphenol;
5-isopropyl-2-methylphenol;
(E)-2-methyl-4-(2,6,6-trimethylcyclohex-1-en-1-yl)but-2-enal;
3-isopropyl-6-methylenecyclohex-1-ene; benzyl 2-hydroxybenzoate;
benzyl 3-methylbutanoate; 1-(3,3-dimethylcyclohexyl)ethyl formate;
(Z)-1-methoxy-4-(prop-1-en-1-yl)benzene; pentyl benzoate;
2-(4-methylcyclohex-3-en-1-yl)propan-2-yl acetate;
(Z)-3-methyl-4-(2,6,6-trimethylcyclohex-2-en-1-yl)but-3-en-2-one;
(2-(allyloxy)ethyl)benzene; allyl heptanoate;
6,8-dimethylnonan-2-ol; 5-methyl-5-phenylhexan-3-one;
3,7-dimethyl-2-methyleneoct-6-enal; 3,7-dimethyloctan-1-ol;
2-pentylcyclopentan-1-ol;
(2S,4S)-2-heptyl-2,4-dimethyl-1,3-dioxolane;
(E)-2-isopropyl-5-methylhex-2-enal;
1-isopropyl-4-methyl-7-oxabicyclo[2.2.1]heptane;
(Z)-1-(2,6,6-trimethylcyclohex-2-en-1-yl)but-2-en-1-one;
(R)-3,7-dimethylocta-1,6-dien-3-ol; 3,7-dimethyloct-6-enal;
(R)-3,7-dimethyloct-6-enal; 3,7-dimethyloct-6-en-1-ol;
3,7-dimethyloct-6-en-1-ol; (1R,5R)-2,6,6-trimethylbicyclo[3.1.1]
hept-2-ene; (1S,5 S)-2,6,6-trimethylbicyclo[3.1.1] hept-2-ene;
hexyl (Z)-2-methylbut-2-enoate; p-cymene; phenethyl isobutyrate;
phenethyl (Z)-2-methylbut-2-enoate; phenethyl methacrylate;
(2Z,5Z)-5,6,7-trimethylocta-2,5-dien-4-one;
1-methoxy-4-propylbenzene; 2-(4-(tert-butyl)phenyl)acetaldehyde;
4-(tert-pentyl)cyclohexan-1-ol; 2,6,6-trimethylbicyclo[3.1.1]
hept-2-ene; ethyl (2,3,6-trimethylcyclohexyl)carbonate;
1-(3,3-dimethylcyclohexyl)ethyl acetate;
(S)-3,7-dimethylocta-1,6-dien-3-ol;
1-isopropyl-4-methylenebicyclo[3.1.0]hexane; 3,7-dimethyloctanal;
4-(2,2,6-trimethylcyclohexyl)butan-2-ol; 3,7-dimethyloctan-3-ol;
3,7-dimethyloctan-3-yl acetate; ethyl
(1R,6S)-2,2,6-trimethylcyclohexane-1-carboxylate;
2-isopropyl-5-methylphenol;
(Z)-1-(2,6,6-trimethylcyclohex-2-en-1-yl)but-2-en-1-one;
(Z)-1-methoxy-4-(prop-1-en-1-yl)benzene;
2,2,2-trichloro-1-phenylethyl acetate;
2,2,5-trimethyl-5-pentylcyclopentan-1-one;
(4-tert-butylcyclohexyl)acetate; 4-(tert-butyl)cyclohexyl acetate;
4-methyl-4-phenylpentan-2-yl acetate;
(Z)-1-((2-methylallyl)oxy)hex-3-ene;
4,5-epoxy-4,11,11-trimethyl-8-methylenebicyclo(7.2.0)undecane;
1,3,4,6,7,8alpha-hexahydro-1,1,5,5-tetramethyl-2H-2,4alpha-methanophtalen-
-8(5H)-one, and mixtures thereof.
14. The composition according to claim 1, wherein said malodor
reduction materials are not selected from the group consisting of
geranyl nitrile; helional; nonanal; linalool; (S)-(+)-linalool;
(R)-(-)-linalool; nerol; tetrahydrolinalool; 2-phenylethyl acetate;
eugenol; ethyl linalool; allyl heptoate; agrumen nitrile;
citronitrile; 2,2-dimethyl-3-(m-tolyl)propan-1-ol;
2-methyl-5-phenylpentan-1-ol; dodecanenitrile;
2-heptylcyclopentan-1-one; methyl nonyl acetaldehyde;
3-(2-ethylphenyl)-2,2-dimethylpropanal;
(Z)-1-(2,6,6-trimethylcyclohex-2-en-1 -yl)but-2-en-1-one;
(R,E)-2-methyl-4-(2,2,3-trimethylcyclopent-3-en-1-yl)but-2-en-1-ol;
4-(tert-butyl)cyclohexyl acetate; 1-cyclohexylethyl
(E)-but-2-enoate; allyl 2-(cyclohexyloxy)acetate; alpha terpinyl
acetate; beta terpinyl acetate; gamma terpinyl acetate; methyl
dodecyl ether;
2,4-dimethyl-4,4a,5,9b-tetrahydroindeno[1,2-d][1,3]dioxine;
cinnamyl isobutyrate;
(E)-2-methyl-4-(2,6,6-trimethylcyclohex-1-en-1-yl)but-2-enal; gamma
methyl ionone; ethyl 2,3,6-trimethyl cyclohexyl carbonate ethyl
2,3,6-trimethyl cyclohexyl carbonate; Citral diethyl acetal;
Dimethoxycyclododecane;
1-((2S,3S)-2,3,8,8-tetramethyl-1,2,3,4,5,6,7,8-octahydronaphthalen-2-yl)e-
than-1-one; oxacyclohexadecan-2-one;
4,6,6,7,8,8-hexamethyl-1,3,4,6,7,8-hexahydrocyclopenta[g]isochromene;
Ethylene brassylate; Methyl
(Z)-2-43-(4-(tert-butyl)phenyl)-2-methylpropylidene)amino)benzoate;
4,7-Methano-1H-inden-5-ol, 3a,4,5,6,7,7a-hexahydro-, 5-acetate;
cedryl methyl ether; vetivert acetate;
1-((3R,3aR,7R,8aS)-3,6,8,8-tetramethyl-2,3,4,7,8,8a-hexahydro-1H-3a,7-met-
hanoazulen-5-yl)ethan-1-one; Benzophenone; Farnesol; trans,
trans-farnesol; 3-(3-isopropylphenyl)butanal;
2,6,10-trimethylundec-9-enal; 3-(4-(tert-butyl)phenyl)propanal;
3-(4-isopropylphenyl)-2-methylpropanal; Citronellal (1);
Citronellal (d); (E)-4,8-dimethyldeca-4,9-dienal; Pino
Acetaldehyde; 3-(4-(tert-butyl)phenyl)-2-methylpropanal; Cinnamic
aldehyde; Citral; Geranial; MethoxyMelonal;
o-methoxycinnamaldehyde;
(E)-4-((3aS,7aS)-octahydro-5H-4,7-methanoinden-5-ylidene)butanal;
Methyl Octyl Acetaldehyde; 3-(4-methoxyphenyl)-2-methylpropanal;
5-methoxyoctahydro-1H-4,7-methanoindene-2-carbaldehyde; Iso
Cyclocitral; Octanal; 2-Undecenal; 10-Undecenal;
Trans-trans-2,6-Nonadienal; Trans-2,cis-6-nondienal; Heliotropin;
Hexyl Cinnamic aldehyde; p-methyl-alpha-pentylcinnamaldehyde;
Alpha-methyl cinnamaldehyde; 3,4-dimethoxybenzaldehyde; Myrtenal;
Perillaldehyde; Maceal; Methyl palmitate; Methyl iso eugenol; and
mixtures thereof.
15. The composition according to claim 1, wherein said composition
comprises from about 0.005% to about 10% of said malodor agent,
wherein said malodor agent comprises from about 1 to about 30
malodor reduction materials having a Blocker Index of 3 to about
0.001, wherein at least a portion of said malodor reduction
materials are encapsulated.
16. A process for treating a laundry article using the composition
according to claim 1 comprising the steps of: providing about 1 mg
to about 100 g of said particles in a washing machine or laundry
wash basin; and washing said laundry article in a wash liquor in
said washing machine or laundry wash basin into which said
particles are dissolved.
17. A process for reducing malodor from a laundry article using the
composition according to claim 1 comprising the steps of: providing
about 1 mg to about 100 g of said particles in a fluid pervious
package; and placing said package proximal to said laundry article
or contacting said laundry article with said fluid pervious
package.
Description
FIELD OF THE INVENTION
[0001] Particles including malodor reduction compositions and
methods of using such particles for managing malodor in laundry
articles.
BACKGROUND OF THE INVENTION
[0002] Laundry articles having significant malodors is a problem
that continues to face consumers.
[0003] People enjoy wearing garments that smell fresh and clean.
Maintaining a full wardrobe that is populated with a sufficient
number of garments that are fresh and clean can be a burden on many
people because they are too busy to regularly spend their time
taking care of their laundry and do not wish to pay for a service
that will take care of their laundry. Further, many people have
garments that comprise fabrics or appurtenances that may not be
durable enough to withstand multiple wearing, washing, and drying
cycles without a the appearance or function of the garment being
degraded.
[0004] To compensate for these problems, many people wear garments
multiple times before they launder the garment. In many
circumstances, wearing a garment multiple times between washings or
dry cleaning is fine. A shirt, pants, or skirt may be worn multiple
times between washings if the garment has not picked up any visible
stains, the person has not perspired appreciably, the person has
not been in an environment having odiferous air such as a smoky
environment, restaurant selling strong smelling foods, or the
person has not contacted strongly smelling objects such as a pet.
However, the typical experience for most people is that they do
perspire, are in environments where strong odors are present, or
come into contact with smelly pets and the like. So even if a
person avoids acquiring a stain or smudge on their garment during
wear, it is probable that the garment has picked up some odors
during wear.
[0005] Sometimes laundered garments are stored in a closet for
weeks or months prior to being worn. By the time the garment is
worn, the scent of the garment acquired during laundering has worn
off. Depending on the environment in which the garment is stored,
the garment may have a neutral or no odor or may have a musty,
moldy, stale malodor. The malodors associated with long term
storage of garments can negatively impact the experience of the
person, and those around her, who chooses to wear a garment that
has been stored for an appreciable period of time.
[0006] A similar situation arises when a person wants to continue
to wear an article of clothing that has been worn earlier in the
day. For example, after getting off work, a person may want to go
out with friends to a restaurant, pub, or movie. After wearing the
clothing during the work day, the clothing may have a neutral or
non-noticeable odor, or even worse may have an unattractive odor
that was acquired during the course of the day. The neutral or even
negative malodor can have a negative impact on the psyche of the
wearer and form a negative impression upon the people around the
wearer of such a garment.
[0007] Similar problems can be associated with storing laundry
articles that have been worn. With wear, clothing can become sweaty
and smelly. Prior to laundering, the soiled laundry article might
be stored in a gym bag, trunk of the car, laundry hamper, or pile
of clothing. Over time, the level of malodor can increase to a
degree such that it becomes repulsive for the consumer and those
around her. Further, the malodor may be experienced by the consumer
when she handles the soiled laundry prior to washing.
[0008] Common malodors and sources thereof can include amine-based
malodors (e.g. fish and urine), thiol and sulfide-based malodors
(e.g. garlic and onion), C.sub.2-C.sub.12 carboxylic acid based
malodors (e.g. body and pet odor), indole based malodors (e.g.
fecal and bad breath), short chain fatty aldehyde based malodors
(e.g. grease) and geosmin based malodors (e.g. mold/mildew). The
typical technical approach for managing malodors is to apply a
malodor reduction ingredient or to mask the malodor with perfume.
Unfortunately, malodor control technologies typically cover up the
malodor with a stronger scent and thus interfere with the scent of
the perfumed or unperfumed laundry article that is treated with the
malodor control technology. Thus, limited nature of the current
malodor control technologies is constraining.
[0009] With these limitations in mind, there is a continuing
unaddressed need for technologies for managing malodors in
laundered and soiled laundry articles.
SUMMARY OF THE INVENTION
[0010] A composition comprising a plurality of particles, wherein
said particles comprise: about 30% to about 95% by weight of a
carrier; about 0.1% to about 30% by weight of a perfume; and about
0.00025% to about 30% by weight of a malodor agent; wherein said
malodor agent comprises from about 1 to about 30 malodor reduction
materials having a Blocker Index of less than 3 or a Blocker Index
average of 3 to about 0.001; and wherein each of said particles has
a mass between about 0.1 mg to about 5 g.
BRIEF DESCRIPTION OF THE DRAWINGS
[0011] FIG. 1 is a particle.
[0012] FIG. 2 is a package containing particles.
[0013] FIG. 3 is a package containing particles.
DETAILED DESCRIPTION OF THE INVENTION
[0014] As used herein "MORV" is the calculated malodor reduction
value for a subject material. A material's MORV indicates such
material's ability to decrease or even eliminate the perception of
one or more malodors. For purposes of the present application, a
material's MORV is calculated in accordance with method found in
the test methods section of the present application.
[0015] As used herein, the term "perfume" does not include malodor
reduction materials. Thus, the perfume portion of a composition
does not include, when determining the perfume's composition, any
malodor reduction materials found in the composition as such
malodor reduction materials are described herein. In short, if a
material has a malodor reduction value "MORV" that is within the
range of the MORV recited in the subject claim, such material is a
malodor reduction material for purposes of such claim.
[0016] As used herein, "malodor" refers to compounds generally
offensive or unpleasant to most people, such as the complex odors
associated with bowel movements.
[0017] As used herein, "odor blocking" refers to the ability of a
compound to dull the human sense of smell.
[0018] Unless otherwise noted, all component or composition levels
are in reference to the active portion of that component or
composition, and are exclusive of impurities, for example, residual
solvents or by-products, which may be present in commercially
available sources of such components or compositions.
[0019] All percentages and ratios are calculated by weight unless
otherwise indicated. All percentages and ratios are calculated
based on the total composition unless otherwise indicated.
[0020] It should be understood that every maximum numerical
limitation given throughout this specification includes every lower
numerical limitation, as if such lower numerical limitations were
expressly written herein. Every minimum numerical limitation given
throughout this specification will include every higher numerical
limitation, as if such higher numerical limitations were expressly
written herein. Every numerical range given throughout this
specification will include every narrower numerical range that
falls within such broader numerical range, as if such narrower
numerical ranges were all expressly written herein.
[0021] Malodor Reduction Materials
[0022] A non-limiting set of suitable malodor reduction materials
are provided in the tables below. For ease of use, each material in
Tables 1-3 is assigned a numerical identifier which is found in the
column for each table that is designated Number. Table 4 is a
subset of Table 1, Table 5 is a subset of Table 2 and Table 6 is a
subset of Table 3 and there for Tables 4, 5 and 6 each use the same
numerical identifier as found, respectively, in Tables 1-3.
Codes
[0023] A=Vapor Pressure >0.1 torr B=Vapor Pressure is between
0.01 torr and 0.1 torr C=logP<3 D=logP>3
E=Probability of Ingredient Color Instability=0%
F=Probability of Ingredient Color Instability<71%
[0024] G=Odor Detection Threshold less than p.ol=8 H=Odor Detection
Threshold greater than p.ol=8 I=Melamine formaldehyde PMC Headspace
Response Ratio greater than or equal to 10 J=Melamine formaldehyde
PMC leakage less than or equal to 5% K=Log of liquid dish neat
product liquid-air partition coefficient greater than or equal to
-7 L=Log of liquid dish neat product liquid-air partition
coefficient greater than or equal to -5
TABLE-US-00001 TABLE 1 List of materials with at least one MORV
from 1 to 5 Num- CAS Comment ber Material Name Number Code 1
2-ethylhexyl (Z)-3-(4- 5466-77-3 DEFHJ methoxyphenyl)acrylate 2
2,4-dimethyl-2-(5,5,8,8-tetramethyl- 131812-67-4 DFHJ
5,6,7,8-tetrahydronaphthalen-2-yl)- 1,3-dioxolane 3
1,1-dimethoxynon-2-yne 13257-44-8 ACEFHJK 4 para-Cymen-8-ol
1197-01-9 BCGIJK 7 3-methoxy-7,7-dimethyl-10- 216970-21-7 BDEFHJK
methylenebicyclo[4.3.1]decane 9 Methoxycyclododecane 2986-54-1
DEFHJK 10 1,1-dimethoxycyclododecane 950-33-4 DEFHJK 11
(Z)-tridec-2-enenitrile 22629-49-8 DEFHJK 13 Oxybenzone 131-57-7
DEFGJ 14 Oxyoctaline formate 65405-72-3 DFHJK 16
4-methyl-1-oxaspiro[5.5]undecan-4- 57094-40-3 CFGIJK ol 17
7-methyl-2H-benzo[b][1,4]dioxepin- 28940-11-6 CGIK 3(4H)-one 18
1,8-dioxacycloheptadecan-9-one 1725-01-5 DGJ 21
4-(tert-pentyl)cyclohexan-1-one 16587-71-6 ADFGIJKL 22 o-Phenyl
anisol 86-26-0 DEFHJK 23 3a,5,6,7,8,8b-hexahydro- 823178-41-2
DEFHJK 2,2,6,6,7,8,8-heptamethyl-4H- indeno(4,5-d)-1,3-dioxole 25
7-isopropyl-8,8-dimethyl-6,10- 62406-73-9 BDEFHIJK
dioxaspiro[4.5]decane 28 Octyl 2-furoate 39251-88-2 DEFHJK 29 Octyl
acetate 112-14-1 BDEFHJKL 30 octanal propylene glycol acetal
74094-61-4 BDEFHJKL 31 Octanal 124-13-0 ACHIKL 32 Octanal dimethyl
acetal 10022-28-3 ACEFGJKL 33 Myrcene 123-35-3 ADEFGIKL 34 Myrcenol
543-39-5 BCEFGIJK 35 Myrcenyl acetate 1118-39-4 ADEFGJK 36
Myristaldehyde 124-25-4 DFHJK 37 Myristicine 607-91-0 CGJK 38
Myristyl nitrile 629-63-0 DEFHJK 39
2,2,6,8-tetramethyl-1,2,3,4,4a,5,8,8a- 103614-86-4 DEFHIJK
octahydronaphthalen-1-ol 42 Ocimenol 5986-38-9 BCHIJK 43 Ocimenol
28977-58-4 BCHIJK 47 Nopyl acetate 128-51-8 DEFHJK 48 Nootkatone
4674-50-4 DHJK 49 Nonyl alcohol 143-08-8 BDEFGIJKL 50 Nonaldehyde
124-19-6 ADHIKL 52 12-methyl-14-tetradec-9-enolide 223104-61-8
DFHJK 57 N-ethyl-p-menthane-3-carboxamide 39711-79-0 DEFGIJK 61
1-(3-methylbenzofuran-2-yl)ethan-1- 23911-56-0 CEFHIK one 62
2-methoxynaphthalene 93-04-9 BDEFHK 63 Nerolidol 7212-44-4 DEFHJK
64 Nerol 106-25-2 BCHIK 65 1-ethyl-3- 31996-78-8 ACEFHIJKL
methoxytricyclo[2.2.1.02,6]heptane 67 Methyl (E)-non-2-enoate
111-79-5 ADEFHJKL 68 10-isopropyl-2,7-dimethyl-1- 89079-92-5
BDEFHIJK oxaspiro[4.5]deca-3,6-diene 69
2-(2-(4-methylcyclohex-3-en-1- 95962-14-4 DHJK
yl)propyl)cyclopentan-1-one 70 Myrtenal 564-94-3 ACFHIJKL 71
(E)-4-(2,2,3,6- 54992-90-4 BDEFHIJK
tetramethylcyclohexyl)but-3-en-2- one 74 Myraldyl acetate
53889-39-7 DHJK 75 Musk tibetine 145-39-1 DHIJ 76
1,7-dioxacycloheptadecan-8-one 3391-83-1 DGJ 77 Musk ketone 81-14-1
DHJ 78 Musk ambrette 83-66-9 DHIJ 79 3-methylcyclopentadecan-1-one
541-91-3 DEFHJK 80 (E)-3-methylcyclopentadec-4-en-1- 82356-51-2
DHJK one 82 3-methyl-4-phenylbutan-2-ol 56836-93-2 BCEFHIK 83
1-(4-isopropylcyclohexyl)ethan-1-ol 63767-86-2 BDEFHIJK 85 Milk
Lactone 72881-27-7 DEFHJK 91 Methyl octine carbonate 111-80-8
BDEFHKL 92 Methyl octyl acetaldehyde 19009-56-4 ADFHJKL 93
6,6-dimethoxy-2,5,5-trimethylhex-2- 67674-46-8 ACHIJKL ene 98
Methyl phenylethyl carbinol 2344-70-9 BCEFHIK 100 Methyl stearate
112-61-8 DEFHJ 101 Methyl nonyl acetaldehyde dimethyl 68141-17-3
BDEFHJK acetal 102 Methyl nonyl ketone 112-12-9 BDFHJKL 103 Methyl
nonyl acetaldehyde 110-41-8 BDFHJK 104 Methyl myristate 124-10-7
DEFHJK 105 Methyl linoleate 112-63-0 DEFHJ 106 Methyl lavender
ketone 67633-95-8 CFHJK 108 Methyl isoeugenol 93-16-3 ACEFHK 109
Methyl hexadecanoate 112-39-0 DEFHJK 110 Methyl eugenol 93-15-2
ACEFHK 112 Methyl epijasmonate 1211-29-6 CHJK 113 Methyl
dihydrojasmonate 24851-98-7 DFHJK 114 Methyl diphenyl ether
3586-14-9 DEFHJK 117 Methyl cinnamate 103-26-4 BCEFHK 119 Methyl
chavicol 140-67-0 ADEFHK 120 Methyl beta-naphthyl ketone 93-08-3
CEFHK 122 Methyl 2-octynoate 111-12-6 ACEFHKL 123 Methyl
alpha-cyclogeranate 28043-10-9 ACHIJKL 126 Methoxycitronellal
3613-30-7 ACFGIJK 128 Menthone 1,2-glycerol ketal 67785-70-0 CEFHJ
(racemic) 130 Octahydro-1H-4,7-methanoindene-1- 30772-79-3 BCFHIJKL
carbaldehyde 134 3-(3-(tert-butyl)phenyl)-2- 62518-65-4 BDHJK
methylpropanal 135 (E)-4-(4,8-dimethylnona-3,7-dien-1- 38462-23-6
DEFHJK yl)pyridine 137 (E)-trideca-3,12-dienenitrile 134769-33-8
DEFHJK 140 2,2-dimethyl-3-(m-tolyl)propan-1-ol 103694-68-4 CEFHIJK
141 2,4-dimethyl-4,4a,5,9b- 27606-09-3 CEFHJK
tetrahydroindeno[1,2-d][1,3]dioxine 142 Maceal 67845-30-1 BDFHJK
143 4-(4-hydroxy-4- 31906-04-4 CHJ methylpentyl)cyclohex-3-ene-1-
carbaldehyde 145 l-Limonene 5989-54-8 ADEFGIJKL 146
(Z)-3-hexen-1-yl-2-cyclopenten-1- 53253-09-1 BDHK one 148 Linalyl
octanoate 10024-64-3 DEFHJ 149 Linalyl isobutyrate 78-35-3 BDHJK
152 Linalyl benzoate 126-64-7 DFHJ 153 Linalyl anthranilate
7149-26-0 DFHJ 155 Linalool oxide (furanoid) 60047-17-8 BCHIJK 156
linalool oxide 1365-19-1 CGIJK 158 (2Z,6E)-3,7-dimethylnona-2,6-
61792-11-8 BDEFHJK dienenitrile 159 3-(4-methylcyclohex-3-en-1-
6784-13-0 ACFHIJK yl)butanal 161 (2,5-dimethyl-1,3-dihydroinden-2-
285977-85-7 CEFHJK yl)methanol 162 3-(4-(tert-butyl)phenyl)-2-
80-54-6 BDHJK methylpropanal 167 (E)-1-(1-methoxypropoxy)hex-3-ene
97358-54-8 ACEFGJKL 168 Leaf acetal 88683-94-7 ACEFGJKL 170
l-Carveol 2102-58-1 BCHIJK 174 Lauryl alcohol 112-53-8 DEFGJK 175
Lauryl acetate 112-66-3 DEFHJK 176 Lauric acid 143-07-7 DEFHJ 177
Lactojasmone 7011-83-8 BDEFHIJKL 178 Lauraldehyde 112-54-9 BDFHJK
179 3,6-dimethylhexahydrobenzofuran- 92015-65-1 BCEFHIJKL 2(3H)-one
182 4-(1-ethoxyvinyl)-3,3,5,5- 36306-87-3 BDFHIJK
tetramethylcyclohexan-1-one 183 Khusimol 16223-63-5 CEFHJK 184
5-(sec-butyl)-2-(2,4- 117933-89-8 DEFHJ
dimethylcyclohex-3-en-1-yl)-5- methyl-1,3-dioxane 185
(1-methyl-2-((1,2,2- 198404-98-7 DEFHJK
trimethylbicyclo[3.1.0]hexan-3- yl)methyl)cyclopropyl)methanol 186
2-propylheptanenitrile 208041-98-9 ADEFHIJKL 187
(E)-6-(pent-3-en-1-yl)tetrahydro-2H- 32764-98-0 BCFHIKL pyran-2-one
189 2-hexylcyclopentan-1-one 13074-65-2 BDFHJKL 190
2-methyl-4-phenyl-1,3-dioxolane 33941-99-0 BCEFGIK 192
2,6,9,10-tetramethyl-1- 71078-31-4 BDEFHIJK
oxaspiro(4.5)deca-3,6-diene 193 Isopulegol 89-79-2 BCEFHIJKL 195
Isopropyl palmitate 142-91-6 DEFHJ 196 Isopropyl myristate 110-27-0
DEFHJK 197 Isopropyl dodecanoate 10233-13-3 DEFHJK 199
Isopimpinellin 482-27-9 CFGJ 206 Iso3-methylcyclopentadecan-1-one
3100-36-5 DEFGJK 208 Isomenthone 491-07-6 ADEFGIJKL 209 Isojasmone
95-41-0 BDFHJKL 210 Isomenthone 36977-92-1 ADEFGIJKL 211 Isohexenyl
cyclohexenyl 37677-14-8 DFHJK carboxaldehyde 212 Isoeugenyl benzyl
ether 120-11-6 DFHJ 215 1-((2S,3S)-2,3,8,8-tetramethyl- 54464-57-2
DHJK 1,2,3,4,5,6,7,8-octahydronaphthalen- 2-yl)ethan-1-one 218
Isocyclocitral 1335-66-6 ACFHIJKL 221 Isobutyl quinoline 65442-31-1
DEFHJK 227 Isobornylcyclohexanol 68877-29-2 DEFHJK 228 Isobornyl
propionate 2756-56-1 BDEFHIJK 229 Isobornyl isobutyrate 85586-67-0
BDEFHIJK 230 Isobornyl cyclohexanol 66072-32-0 DEFHJK 231 Isobornyl
acetate 125-12-2 ADEFHIJKL 233 Isobergamate 68683-20-5 DEFHJK 234
Isoamyl undecylenate 12262-03-2 DEFHJK 238 Isoamyl laurate
6309-51-9 DEFHJK 242 Isoambrettolide 28645-51-4 DGJ 243 Irisnitrile
29127-83-1 ADEFHKL 244 Indolene 68527-79-7 DEFHJ 246
Indol/Hydroxycitronellal Schiff base 67801-36-9 DEFHJ 247
4,4a,5,9b-tetrahydroindeno[1,2- 18096-62-3 BCEFGJK d][1,3]dioxine
249 Hydroxy-citronellol 107-74-4 CEFGIJK 252
2-cyclododecylpropan-1-ol 118562-73-5 DEFHJK 253 Hydrocitronitrile
54089-83-7 CEFHJK 254 Hydrocinnamyl alcohol 122-97-4 BCEFHIK 256
Hydratropaldehyde dimethyl acetal 90-87-9 ACEFHJK 259
5-ethyl-4-hydroxy-2-methylfuran- 27538-09-6 CFGIK 3(2H)-one 260
2,3-dihydro-3,3-dimethyl-1H-indene- 173445-44-8 DHJK 5-propanal 261
3-(3,3-dimethyl-2,3-dihydro-1H- 173445-65-3 DHJK
inden-5-yl)propanal 263 Hexyl octanoate 1117-55-1 DEFHJK 267 Hexyl
hexanoate 6378-65-0 DEFHJKL 269 Hexyl cinnamic aldehyde 101-86-0
DHJ 271 Hexyl benzoate 6789-88-4 DEFHJK 274 Hexenyl tiglate
84060-80-0 BDEFHJK 276 (E)-3,7-dimethylocta-2,6-dien-1-yl 3681-73-0
DEFHJ palmitate 277 Hexadecanolide 109-29-5 DEFGJK 278
2-butyl-4,4,6-trimethyl-1,3-dioxane 54546-26-8 ADEFHIJKL 280 Ethyl
(1R,2R,3R,4R)-3- 116126-82-0 BDEFHIJK
isopropylbicyclo[2.2.1]hept-5-ene-2- carboxylate 281
3a,4,5,6,7,7a-hexahydro-1H-4,7- 5413-60-5 CEFGJK methanoinden-6-yl
acetate 285 2-(1-(3,3- 141773-73-1 DEFHJ
dimethylcyclohexyl)ethoxy)-2- methylpropyl propionate 286
Heliotropine diethyl acetal 40527-42-2 CEFGJ 288 Helional 1205-17-0
CHJK 289 (E)-oxacyclohexadec-13-en-2-one 111879-80-2 DGJK 290
Gyrane 24237-00-1 ADEFHIJKL 292 Guaiol 489-86-1 DEFHJK 293
1-(2,6,6-trimethylcyclohex-2-en-1- 68611-23-4 DHJK yl)pentan-3-one
294 Ethyl 2-ethyl-6,6-dimethylcyclohex- 57934-97-1 BDEFHIJK
2-ene-1-carboxylate 295 Germacrene B 15423-57-1 DEFHJK 296
Germacrene D 23986-74-5 DEFHJK 300 Geranyl phenylacetate 102-22-7
DFHJ 301 Geranyl phenyl acetate 71648-43-6 DFHJ 303 Geranyl
linalool 1113-21-9 DFHJ 307 Geranyl cyclopentanone 68133-79-9 DHJK
316 gamma-Undecalactone (racemic) 104-67-6 DEFHJKL 317
gamma-Terpinyl acetate 10235-63-9 BDHJK 318 gamma-Terpineol
586-81-2 BCGIJK 321 gamma-Nonalactone 104-61-0 BCEFHIKL 322
gamma-Muurolene 30021-74-0 DEFHJKL 323 gamma-(E)-6-(pent-3-en-1-
63095-33-0 BCEFHKL yl)tetrahydro-2H-pyran-2-one 324 gamma-Ionone
79-76-5 BDEFHIJK 325 gamma-Himachalene 53111-25-4 BDEFHJKL 328
gamma-Gurjunene 22567-17-5 DEFHJKL 329 gamma-Eudesmol 1209-71-8
DFHJK 330 gamma-Dodecalactone 2305-05-7 DEFHJK
331 gamma-Damascone 35087-49-1 BDEFHIJK 332 gamma-Decalactone
706-14-9 BDEFHIJKL 333 gamma-Cadinene 39029-41-9 DEFHJKL 334
1-(3,3-dimethylcyclohexyl)pent-4- 56973-87-6 BDEFHJK en-1-one 335
4,6,6,7,8,8-hexamethyl-1,3,4,6,7,8- 1222-05-5 DEFHJK
hexahydrocyclopenta[g]isochromene 336 Furfuryl octanoate 39252-03-4
DEFHJK 338 Furfuryl hexanoate 39252-02-3 CEFHJK 339 Furfuryl
heptanoate 39481-28-2 CEFHJK 342 2-methyldecanenitrile 69300-15-8
BDEFHJKL 343 8,8-dimethyl-3a,4,5,6,7,7a- 76842-49-4 DEFHJK
hexahydro-1H-4,7-methanoinden-6- yl propionate 344 Ethyl
(3aR,4S,7R,7aR)-octahydro- 80657-64-3 DEFHIJK
3aH-4,7-methanoindene-3a- carboxylate 347 Diethyl cyclohexane-1,4-
72903-27-6 CEFHJK dicarboxylate 349 (6-isopropyl-9-methyl-1,4-
63187-91-7 CEFHJ dioxaspiro[4.5]decan-2-yl)methanol 350
2-isobutyl-4-methyltetrahydro-2H- 63500-71-0 BCEFHIJK pyran-4-ol
352 Undec-10-enenitrile 53179-04-7 BDEFHJK 353
(Z)-6-ethylideneoctahydro-2H-5,8- 69486-14-2 CEFGJK
methanochromen-2-one 356 3-(2-ethylphenyl)-2,2- 67634-15-5 BDHJK
dimethylpropanal 358 (E)-4,8-dimethyldeca-4,9-dienal 71077-31-1
BDFHJK 359 (E)-4-((3aR,4R,7R,7aR)- 501929-47-1 DEFHJK
1,3a,4,6,7,7a-hexahydro-5H-4,7- methanoinden-5-ylidene)-3-
methylbutan-2-ol 360 8,8-dimethyl-3a,4,5,6,7,7a- 171102-41-3 DEFHJK
hexahydro-1H-4,7-methanoinden-6- yl acetate 361
3-(4-ethylphenyl)-2,2- 134123-93-6 DEFHJK dimethylpropanenitrile
362 2-heptylcyclopentan-1-one 137-03-1 DFHJKL 363 1-ethoxyethoxy
Cyclododecane 389083-83-4 DEFHJK 364 3-cyclohexene-1-carboxylic
acid, 815580-59-7 ACHIJKL 2,6,6-trimethyl-, methyl ester 368
Farnesyl acetate 29548-30-9 DEFHJK 369 Farnesol 4602-84-0 DEFHJK
370 Oxacyclohexadecan-2-one 106-02-5 DEFGJK 371
1-cyclopentadec-4-en-1-one 14595-54-1 DEFGJK 372
1-cyclopentadec-4-en-1-one 35720-57-1 DEFGJK 373 2-methoxy-4-(4-
128489-04-3 CGJ methylenetetrahydro-2H-pyran-2- yl)phenol 374
Eugenyl acetate 93-28-7 CFHJK 375 Eugenol 97-53-0 CHIK 377
Ethylmethylphenylglycidate 77-83-8 CFHJK 378 Ethylene brassylate
105-95-3 DFGJ 381 Ethyl undecylenate 692-86-4 DEFHJK 385 Ethyl
palmitate 628-97-7 DEFHJ 386 Ethyl nonanoate 123-29-5 BDEFHJKL 388
Ethyl myristate 124-06-1 DEFHJK 390 Ethyl linalool 10339-55-6
BCEFHJK 391 Ethyl laurate 106-33-2 DEFHJK 394 Ethyl hexyl ketone
925-78-0 ADFHIKL 397 Ethyl decanoate 110-38-3 BDEFHJK 398 Ethyl
gamma-Safranate 35044-57-6 ADHIJK 407 Ethyl 3-phenylglycidate
121-39-1 CGJK 413 6-ethyl-2,10,10-trimethyl-1- 79893-63-3 BDEFHIJK
oxaspiro[4.5]deca-3,6-diene 414 Elemol 639-99-6 DEFHJK 415
(2-(1-ethoxyethoxy)ethyl)benzene 2556-10-7 BCEFHJK 416
(E)-3-methyl-5-(2,2,3- 67801-20-1 DHJK
trimethylcyclopent-3-en-1-yl)pent-4- en-2-ol 417 d-xylose 58-86-6
CGIJ 418 (E)-4-((3aS,7aS)-octahydro-5H-4,7- 30168-23-1 DFHJK
methanoinden-5-ylidene)butanal 421 Dodecanal dimethyl acetal
14620-52-1 DEFHJK 424 d-Limonene 5989-27-5 ADEFGIJKL 425
Dipropylene Glycol 25265-71-8 CEFGIK 426 Dispirone 83863-64-3
BDEFHJK 428 Diphenyloxide 101-84-8 BDEFHK 429 Diphenylmethane
101-81-5 DEFGK 432 Dimethyl benzyl carbinyl butyrate 10094-34-5
DEFHJK 436 2,6-dimethyloct-7-en-4-one 1879-00-1 ADEFHIJKL 441
Octahydro-1H-4,7-methanoinden-5- 64001-15-6 DEFHJKL yl acetate 444
Dihydrocarveol acetate 20777-49-5 BDEFHIJK 445 Dihydrocarveol
619-01-2 BCEFHIJKL 449 Dihydro Linalool 18479-51-1 BCEFGIJKL 450
Dihydro Isojasmonate 37172-53-5 DHJK 453 Dibutyl sulfide 544-40-1
ADEFHIKL 457 Dibenzyl 103-29-7 DEFGJK 459 delta-Undecalactone
710-04-3 DEFHJKL 461 delta-Elemene 20307-84-0 BDEFHJK 462
delta-Guaiene 3691-11-0 DEFHJKL 463 delta-Dodecalactone 713-95-1
DEFHJK 464 delta-Decalactone 705-86-2 BDEFHIJKL 465 delta-Cadinene
483-76-1 DEFHJKL 466 delta-damascone 57378-68-4 ADHIJK 467
delta-Amorphene 189165-79-5 DEFHJKL 468 delta-3-Carene 13466-78-9
ADEFGIJKL 470 Decylenic alcohol 13019-22-2 BDEFHJK 471 Decyl
propionate 5454-19-3 DEFHJK 473 Decanal diethyl acetal 34764-02-8
DEFHJK 474 Decahydro-beta-naphthol 825-51-4 BCEFGIK 475
1-cyclohexylethyl (E)-but-2-enoate 68039-69-0 BDFHJK 478
3-(4-isopropylphenyl)-2- 103-95-7 BDFHJK methylpropanal 479
Cyclotetradecane 295-17-0 DEFGJKL 480 Cyclopentadecanone 502-72-7
DEFGJK 482 Cyclohexyl salicylate 25485-88-5 DFGJ 484
3a,4,5,6,7,7a-hexahydro-1H-4,7- 113889-23-9 DEFHJK
methanoinden-6-yl butyrate 485 Cyclic ethylene dodecanedioate
54982-83-1 DFGJ 486 8,8-dimethyl-1,2,3,4,5,6,7,8- 68991-97-9 DHJK
octahydronaphthalene-2- carbaldehyde 487
3a,4,5,6,7,7a-hexahydro-1H-4,7- 67634-20-2 DEFHJK methanoinden-5-yl
isobutyrate 488 Curzerene 17910-09-7 DHJK 491 Cumic alcohol
536-60-7 CHIJK 493 Coumarone 1646-26-0 BCEFHIK 497
2-(3-phenylpropyl)pyridine 2110-18-1 CEFHJK 498 Dodecanenitrile
2437-25-4 DEFHJK 501 (E)-cycloheptadec-9-en-1-one 542-46-1 DEFGJ
502 Citryl acetate 6819-19-8 DFHJK 503 Citrus Propanol 15760-18-6
CEFHIJK 505 Citronitrile 93893-89-1 CEFHJK 519 Citral propylene
glycol acetal 10444-50-5 CEFHJK 520 Citral dimethyl acetal
7549-37-3 BCEFHJK 521 Citral diethyl acetal 7492-66-2 BDEFHJK 524
cis-Ocimene 3338-55-4 ADGIKL 527 cis-Limonene oxide 13837-75-7
ADEFGIJKL 529 Cis-iso-ambrettolide 36508-31-3 DGJ 530 cis-6-nonenol
35854-86-5 BCEFHIKL 531 cis-carveol 1197-06-4 BCHIJK 532
cis-4-Decen-1-al 21662-09-9 ADHKL 534 cis-3-hexenyl-cis-3-hexenoate
61444-38-0 BDEFHJK 537 cis-3-Hexenyl salicylate 65405-77-8 DEFGJ
541 Cis-3-hexenyl Benzoate 25152-85-6 DEFHJK 544 cis-3-Hexenyl
2-methylbutyrate 53398-85-9 ADEFHJKL 546 cis-3, cis-6-nonadienol
53046-97-2 ACEFHK 548 Cinnamyl propionate 103-56-0 DEFHJK 550
Cinnamyl isobutyrate 103-59-3 DEFHJK 551 Cinnamyl formate 104-65-4
BCEFHK 552 Cinnamyl cinnamate 122-69-0 DHJ 553 Cinnamyl acetate
103-54-8 BCEFHK 555 Cinnamic alcohol 104-54-1 BCEFHIK 558 Cetyl
alcohol 36653-82-4 DEFHJ 559 (E)-1-(2,6,6-trimethylcyclohex-2-en-
79-78-7 DHJK 1-yl)hepta-1,6-dien-3-one 560
2-methyl-4-(2,6,6-trimethylcyclohex- 65405-84-7 DFHJK
1-en-1-yl)butanal 561 (3aR,5aR,9aR,9bR)-3a,6,6,9a- 3738-00-9 DEFHJK
tetramethyldodecahydronaphtho[2,1- b]furan 562
1,6-dioxacycloheptadecan-7-one 6707-60-4 DGJ 563
1-(6-(tert-butyl)-1,1-dimethyl-2,3- 13171-00-1 DEFHJK
dihydro-1H-inden-4-yl)ethan-1-one 565 Cedryl methyl ether
19870-74-7 ADEFHJK 566 Cedryl formate 39900-38-4 BDEFHJK 567 Cedryl
acetate 77-54-3 DEFHJK 568 (4Z,8Z)-1,5,9-trimethyl-13- 71735-79-0
DFHJK oxabicyclo[10.1.0]trideca-4,8-diene 569 Cedrol 77-53-2 DEFHJK
570 5-methyl-1-(2,2,3- 139539-66-5 DEFHJK
trimethylcyclopent-3-en-1-yl)-6- oxabicyclo[3.2.1]octane 571
5-methyl-1-(2,2,3- 426218-78-2 DFHJ
trimethylcyclopent-3-en-1-yl)-6- oxabicyclo[3.2.1]octane 572
1,1,2,3,3-pentamethyl-1,2,3,5,6,7- 33704-61-9 BDEFHIJK
hexahydro-4H-inden-4-one 573 Caryophyllene alcohol acetate
32214-91-8 DEFHJK 574 Caryolan-1-ol 472-97-9 DEFHJK 577 Carvyl
acetate 97-42-7 BDHIJK 578 Caprylnitrile 124-12-9 ACEFGIKL 580
Caprylic alcohol 111-87-5 ACEFGIKL 581 Caprylic acid 124-07-2
BCEFHIK 582 Capric acid 334-48-5 DEFHJK 584 Capraldehyde 112-31-2
ADHKL 586 3-(4-methoxyphenyl)-2- 5462-06-6 BCHJK methylpropanal 587
Camphorquinone 10373-78-1 ACEFGIJK 589 Camphene 79-92-5 ADEFGIJKL
591 Ethyl 2-methyl-4-oxo-6- 59151-19-8 DHJ
pentylcyclohex-2-ene-1-carboxylate 592 Butylated hydroxytoluene
128-37-0 DEFGIJK 594 Butyl stearate 123-95-5 DEFHJ 595 Butyl
butyryl lactate 7492-70-8 CEFGJK 599 Butyl 10-undecenoate 109-42-2
DEFHJK 600 2-methyl-4-(2,2,3- 72089-08-8 DEFHJK
trimethylcyclopent-3-en-1-yl)butan- 1-ol 601
3-(4-(tert-butyl)phenyl)propanal 18127-01-0 BDHJK 603 Bornyl
isobutyrate 24717-86-0 BDEFHIJK 604 Bornyl acetate 76-49-3
ADEFHIJKL 606 2-ethoxy-2,6,6-trimethyl-9- 68845-00-1 BDEFHJK
methylenebicyclo[3.3.1]nonane 607 (ethoxymethoxy)cyclododecane
58567-11-6 DEFHJK 608 Bisabolene 495-62-5 DEFHJK 609 Bigarade oxide
72429-08-4 ADEFHJKL 610 beta-Vetivone 18444-79-6 DHJK 611
beta-Terpinyl acetate 10198-23-9 BDHJK 612 beta-Terpineol 138-87-4
BCGIJK 613 beta-Sinensal 60066-88-8 DHJK 614
beta-Sesquiphellandrene 20307-83-9 DEFHJK 615 beta-Selinene
17066-67-0 BDEFGJK 616 beta-Santalol 77-42-9 DEFHJK 618 beta-Pinene
127-91-3 ADEFGIJKL 620 beta-Naphthyl ethyl ether 93-18-5 BDEFHJK
621 beta-Patchoulline 514-51-2 BDEFGJKL 624 beta-Himachalene Oxide
57819-73-5 BDFHJK 625 beta-Himachalene 1461-03-6 DEFHJKL 626
beta-Guaiene 88-84-6 DEFHJKL 627 (2,2-dimethoxyethyl)benzene
101-48-4 DHJK 628 beta-Farnesene 18794-84-8 DEFHJK 631 beta-Copaene
18252-44-3 BDEFHJKL 632 beta-Cedrene 546-28-1 BDEFGJKL 633
beta-Caryophyllene 87-44-5 DEFHJKL 635 beta-Bisabolol 15352-77-9
DFHJK 636 Beta ionone epoxide 23267-57-4 BDEFHIJK 638 Bergaptene
484-20-8 CGJ 639 Benzyl-tert-butanol 103-05-9 CEFGJK 644 Benzyl
laurate 140-25-0 DEFHJ 649 Benzyl dimethyl carbinol 100-86-7
BCEFGIK 650 Benzyl cinnamate 103-41-3 DHJ 653 Benzyl benzoate
120-51-4 DHJ 655 Benzophenone 119-61-9 DEFHK 658 7-isopentyl-2H-
362467-67-2 DHJ benzo[b][1,4]dioxepin-3(4H)-one 659
2'-isopropyl-1,7,7- 188199-50-0 DEFHJK
trimethylspiro[bicyclo[2.2.1]heptane- 2,4'-[1,3]dioxane] 660
4-(4-methylpent-3-en-1-yl)cyclohex- 21690-43-7 DEFHJK
3-ene-1-carbonitrile 661 Aurantiol 89-43-0 DEFHJ 663 Anisyl
phenylacetate 102-17-0 DFHJ 668 Methyl (E)-octa-4,7-dienoate
189440-77-5 ACEFHKL 671 Amyl Cinnamate 3487-99-8 DEFHJK 673
(3aR,5aS,9aS,9bR)-3a,6,6,9a- 6790-58-5 DEFHJK
tetramethyldodecahydronaphtho[2,1- b]furan 674
(4aR,5R,7aS,9R)-2,2,5,8,8,9a- 211299-54-6 DEFHJK
hexamethyloctahydro-4H-4a,9- methanoazuleno[5,6-d][1,3]dioxole 675
2,5,5-trimethyl-1,2,3,4,5,6,7,8- 71832-76-3 DEFHJK
octahydronaphthalen-2-ol 676 2,5,5-trimethyl-1,2,3,4,5,6,7,8-
41199-19-3 DEFHJK octahydronaphthalen-2-ol 677 1-((2-(tert-
139504-68-0 DEFHJK butyl)cyclohexyl)oxy)butan-2-ol 678
(3S,5aR,7aS,11aS,11bR)-3,8,8,11a- 57345-19-4 DEFHJ
tetramethyldodecahydro-5H-3,5a- epoxynaphtho[2,1-c]oxepine 679
2,2,6,6,7,8,8-heptamethyldecahydro- 476332-65-7 ADEFHJK
2H-indeno[4,5-b]furan 680 2,2,6,6,7,8,8-heptamethyldecahydro-
647828-16-8 ADEFHJK 2H-indeno[4,5-b]furan 681 Amber acetate
37172-02-4 BDEFHJK 682 Alpinofix .RTM. 811436-82-5 DEFHJ 683
alpha-Thujone 546-80-5 ADEFGIJKL 684 alpha-Vetivone 15764-04-2 DHJK
686 alpha-Terpinyl propionate 80-27-3 BDEFHJK 691 alpha-Sinensal
17909-77-2 DHJK 692 alpha-Selinene 473-13-2 BDEFHJK 693
alpha-Santalene 512-61-8 ADEFHJKL 694 alpha-Santalol 115-71-9
DEFHJK 696 alpha-Patchoulene 560-32-7 ADEFHJKL 697
alpha-neobutenone 56973-85-4 BDHJK 698 alpha-Muurolene 10208-80-7
DEFHJKL 700 alpha-methyl ionone 127-42-4 BDHJK 702 alpha-Limonene
138-86-3 ADEFGIJKL 704 alpha-Irone 79-69-6 BDHJK 706 alpha-Humulene
6753-98-6 DEFHJK 707 alpha-Himachalene 186538-22-7 BDEFHJK 708
alpha-Gurjunene 489-40-7 BDEFHJKL 709 alpha-Guaiene 3691-12-1
DEFHJKL 710 alpha-Farnesene 502-61-4 DEFHJK 711 alpha-Fenchene
471-84-1 ADEFGIJKL 712 alpha-Eudesmol 473-16-5 DEFHJK 713
alpha-Curcumene 4176-17-4 DEFHJK 714 alpha-Cubebene 17699-14-8
ADEFHJKL 715 alpha-Cedrene epoxide 13567-39-0 ADEFHJK 716
alpha-Cadinol 481-34-5 DEFHJK 717 alpha-Cadinene 24406-05-1 DEFHJKL
718 alpha-Bisabolol 515-69-5 DFHJK 719 alpha-bisabolene 17627-44-0
DEFHJK 720 alpha-Bergamotene 17699-05-7 BDEFHJKL 721
alpha-Amylcinnamyl alcohol 101-85-9 DEFHJ 722 alpha-Amylcinnamyl
acetate 7493-78-9 DEFHJ 723 alpha-Amylcinnamaldehyde diethyl
60763-41-9 DEFHJ acetal 724 alpha-Amylcinnamaldehyde 122-40-7 DHJK
725 alpha-Amorphene 23515-88-0 DEFHJKL 726 alpha-Agarofuran
5956-12-7 BDEFHJK 727 1-methyl-4-(4-methyl-3-penten-1- 52475-86-2
DFHJK yl)-3-Cyclohexene-1-carboxaldehyde 730 1-Phenyl-2-pentanol
705-73-7 CEFHK 731 1-Phenyl-3-methyl-3-pentanol 10415-87-9 CEFHJK
733 2,3,4-trimethoxy-benzaldehyde 2103-57-3 BCGI 735
2,4,5-trimethoxy-benzaldehyde 4460-86-0 BCG 736
2,4,6-trimethoxybenzaldehyde 830-79-5 BCGI 738 2,4-Nonadienal
6750-03-4 ACHKL 741 2,6,10-Trimethylundecanal 105-88-4 BDFGJK 742
alpha,4-Dimethyl benzenepropanal 41496-43-9 ACHJK 746 Allyl
cyclohexyl propionate 2705-87-5 BDEFHJK 748 Allyl amyl glycolate
67634-00-8 BCEFGJK 750 Allo-aromadendrene 25246-27-9 BDEFHJKL 752
Aldehyde C-11 143-14-6 ADHJK 754 Methyl (E)-2-(((3,5- 94022-83-0
DEFHJ dimethylcyclohex-3-en-1- yl)methylene)amino)benzoate 757
2,6,10-trimethylundec-9-enal 141-13-9 BDFHJK 758
Acetoxymethyl-isolongifolene 59056-62-1 BDEFHJK (isomers) 763
Acetate C9 143-13-5 BDEFHJKL 764 Acetarolle .RTM. 744266-61-3 DFHJK
766 Acetaldehyde phenylethyl propyl 7493-57-4 CEFHJK acetal 767
Acetaldehyde dipropyl acetal 105-82-8 ACEFGIKL 768 Acetaldehyde
benzyl 2-methoxyethyl 7492-39-9 BCEFHJK acetal 769
(Z)-2-(4-methylbenzylidene)heptanal 84697-09-6 DHJ 770 9-decenal
39770-05-3 ADHKL 771 8-Hexadecenolide 123-69-3 DGJ 772
7-Methoxycoumarin 531-59-9 CHK 774 7-epi-alpha-Selinene 123123-37-5
BDEFHJK 775 7-eip-alpha-Eudesmol 123123-38-6 DEFHJK 776
7-Acetyl-1,1,3,4,4,6- 1506-02-1 DEFHJ hexamethyltetralin 778
6-Isopropylquinoline 135-79-5 CEFHJK 781
6,6-dimethyl-2-norpinene-2- 33885-51-7 BCFHJK propionaldehyde 782
6,10,14-trimethyl-2-Pentadecanone 502-69-2 DEFHJK 786
5-Isopropenyl-2-methyl-2- 13679-86-2 ACGIJKL vinyltetrahydrofuran
788 5-Cyclohexadecenone 37609-25-9 DEFGJK 791 4-Terpinenol 562-74-3
BCHIJK 792 4-Pentenophenone 3240-29-7 BCEFHIK 800 4-Carvomenthenol
28219-82-1 BCHIJK 802 4,5,6,7-Tetrahydro-3,6- 494-90-6 BCEFHIJKL
dimethylbenzofuran 803 4-(p-Methoxyphenyl)-2-butanone 104-20-1
BCEFHJK 804 3-Thujopsanone 25966-79-4 BDEFHJK 805
3-Propylidenephthalide 17369-59-4 CEFHK 806 3-Nonylacrolein
20407-84-5 BDFHJK 807 3-Methyl-5-phenyl-1-pentanal 55066-49-4
BDFHJK 814 3-Hexenyl isovalerate 10032-11-8 ADEFHJKL 821
3,6-Dimethyl-3-octanyl acetate 60763-42-0 ADEFHIJKL 824
3,4,5-trimethoxybenzaldehyde 86-81-7 BCGIK 826 3-(p- 7775-00-0
BDFHJK Isopropylphenyl)propionaldehyde 827 2-Undecenenitrile
22629-48-7 BDEFHJK 828 2-Undecenal 2463-77-6 ADHJK 829
2-trans-6-trans-Nonadienal 17587-33-6 ACHKL 831 2-Phenylethyl
butyrate 103-52-6 DEFHJK 833 2-Phenyl-3-(2-furyl)prop-2-enal
57568-60-2 CHJ 834 2-Phenoxyethanol 122-99-6 BCEFGIK 837
2-Nonen-1-al 2463-53-8 ADHKL 839 2-Nonanol 628-99-9 BDEFGIKL 840
2-Nonanone 821-55-6 ADFHIKL 849 2-Isobutyl quinoline 93-19-6 CEFHJK
850 2-Hexylidene cyclopentanone 17373-89-6 DFHJKL 852 2-Heptyl
tetrahydrofuran 2435-16-7 BDEFHJKL 856 2-Decenal 3913-71-1 ADHKL
864 2,6-Nonadienal 26370-28-5 ACHKL 865 2,6-Nonadien-1-ol 7786-44-9
ACEFHK 866 2,6-dimethyl-octanal 7779-07-9 ADFGIJKL 868 1-Decanol
112-30-1 BDEFGJK 869 1-Hepten-1-ol, 1-acetate 35468-97-4 ACEFHKL
870 10-Undecen-1-ol 112-43-6 DEFHJK 871 10-Undecenal 112-45-8 ADHJK
872 10-epi-gamma-Eudesmol 15051-81-7 DFHJK 873 1,8-Thiocineol
68391-28-6 ADEFHIJKL 876 1,3,5-undecatriene 16356-11-9 ADEFHJKL 877
1,2-Dihydrolinalool 2270-57-7 BCEFGIJKL 878
1,3,3-trimethyl-2-norbornanyl 13851-11-1 ADEFHIJKL acetate 879
1,1,2,3,3-Pentamethylindan 1203-17-4 ADHIJKL 881
(Z)-6,10-dimethylundeca-5,9-dien-2- 3239-37-0 DEFHJK yl acetate 884
(Z)-3-Dodecenal 68141-15-1 BCFHJK 885 (S)-gamma-Undecalactone
74568-05-1 DEFHJKL 886 (R)-gamma-Undecalactone 74568-06-2 DEFHJKL
890 (E)-6,10-dimethylundeca-5,9-dien-2- 3239-35-8 DEFHJK yl acetate
892 (2Z)-3-methyl-5-phenyl-2- 53243-59-7 DEFHJK Pentenenitrile 893
(2S,5S,6S)-2,6,10,10-tetramethyl-1- 65620-50-0 DFHIJK
oxaspiro[4_5]decan-6-ol 894 (2E)-3-methyl-5-phenyl-2- 53243-60-0
CEFHJK pentenenitrile 897 (+)-Dihydrocarveol 22567-21-1 BCEFHIJKL
905 Menthone 89-80-5 ADEFGIJKL 908 (R,E)-2-methyl-4-(2,2,3-
185068-69-3 CHJK trimethylcyclopent-3-en-1-yl)but-2- en-1-ol 912
2-(8-isopropyl-6- 68901-32-6 DEFHJK
methylbicyclo[2.2.2]oct-5-en-2-yl)- 1,3-dioxolane 913 gamma-methyl
ionone 7388-22-9 BDHIJK 914 3-(3-isopropylphenyl)butanal
125109-85-5 BDHJK 916 3-(1-ethoxyethoxy)-3,7- 40910-49-4 BDEFHJK
dimethylocta-1,6-diene 919 3a,4,5,6,7,7a-hexahydro-1H-4,7-
17511-60-3 CEFHJK methanoinden-6-yl propionate 920 Bulnesol
22451-73-6 DEFHJK 922 Benzyl phenylacetate 102-16-9 DHJ 923 Benzoin
119-53-9 CEFHJ 924 (E)-1,2,4-trimethoxy-5-(prop-1-en-1- 2883-98-9
BCFGJK yl)benzene 925 alpha,alpha,6,6-tetramethyl 33885-52-8 BDFHJK
bicyclo[3.1.1]hept-2-ene-propanal 926 7-epi-sesquithujene
159407-35-9 DEFHJKL 927 5-Acetyl-1,1,2,3,3,6- 15323-35-0 DEFHJK
hexamethylindan 928 3-Methylphenethyl alcohol 1875-89-4 BCEFHIK 929
3,6-Nonadien-1-ol 76649-25-7 ACEFHK 930 2-Tridecenal 7774-82-5
BDFHJK 933 Patchouli alcohol 5986-55-0 DEFHIJK 937 p-Cresyl
isobutyrate 103-93-5 BDHJK 939 p-Cresyl n-hexanoate 68141-11-7
DEFHJK 941 5-hexyl-4-methyldihydrofuran- 67663-01-8 BDEFHIJKL
2(3H)-one 942 Ethyl (2Z,4E)-deca-2,4-dienoate 3025-30-7 BDEFHJK 943
Pelargene 68039-40-7 DEFHJK 945 2-cyclohexylidene-2- 10461-98-0
DFHJK phenylacetonitrile 946 Perillaldehyde 2111-75-3 ACHIJK 947
Perillyl acetate 15111-96-3 DFHJK 948 Perillyl alcohol 536-59-4
CHIJK 950 (2-isopropoxyethyl)benzene 68039-47-4 ACEFHJKL 951 Ethyl
(2Z,4E)-deca-2,4-dienoate 313973-37-4 BDEFHJK 953
(2-(cyclohexyloxy)ethyl)benzene 80858-47-5 DEFHJK 954 Phenethyl
2-methylbutyrate 24817-51-4 DEFHJK 955 Phenethyl alcohol 60-12-8
BCEFGIK 959 Phenethyl phenylacetate 102-20-5 DHJ 962 Phenoxanol
55066-48-3 DEFHJK 965 Phenyl benzoate 93-99-2 DFHJK 967 Phenyl
ethyl benzoate 94-47-3 DHJ 969 Phenylacetaldehyde ethyleneglycol
101-49-5 BCEFGIK acetal 973 2-(6,6-dimethylbicyclo[3.1.1]hept-2-
30897-75-7 ACFHIJKL en-2-yl)acetaldehyde 974 Pinocarveol 5947-36-4
BCEFGIJKL 976 Piperonyl acetone 55418-52-5 CEFGJ 978
3a,4,5,6,7,7a-hexahydro-1H-4,7- 68039-44-1 DEFHJK methanoinden-6-yl
pivalate 980 (4aR,8aS)-7-methyloctahydro-1,4- 41724-19-0 CEFGJKL
methanonaphthalen-6(2H)-one 982 p-Menth-3-en-1-ol 586-82-3 BCGIJK
985 (E)-3,3-dimethyl-5-(2,2,3- 107898-54-4 DHJK
trimethylcyclopent-3-en-1-yl)pent-4- en-2-ol 988
1-methyl-4-(4-methylpent-3-en-1- 52474-60-9 DFHJK
yl)cyclohex-3-ene-1-carbaldehyde 993 Propylene glycol 57-55-6
ACEFGIKL 998 p-Tolyl phenylacetate 101-94-0 DFHJ 1000 Ethyl
2,4,7-decatrienoate 78417-28-4 BDEFHJK 1003
2-benzyl-4,4,6-trimethyl-1,3-dioxane 67633-94-7 DEFHJK 1006
2,4-dimethyl-4- 82461-14-1 BDEFHJK phenyltetrahydrofuran 1007
(2R,4a'R,8a'R)-3,7'-dimethyl- 41816-03-9 DEFHJK
3',4',4a',5',8',8a'-hexahydro-1'H- spiro[oxirane-2,2'-
[1,4]methanonaphthalene] 1008 (Z)-6-ethylideneoctahydro-2H-5,8-
93939-86-7 BCEFHJKL methanochromene 1009 2-((S)-1-((S)-3,3-
236391-76-7 DFHJ dimethylcyclohexyl)ethoxy)-2- oxoethyl propionate
1010 Methyl 2,2-dimethyl-6- 81752-87-6 ADHIJKL
methylenecyclohexane-1-carboxylate 1012
2-methyl-5-phenylpentan-1-ol 25634-93-9 DEFHJK 1016
4-methyl-2-phenyl-3,6-dihydro-2H- 60335-71-9 BCEFGJK pyran 1020
Sabinol 471-16-9 BCEFHIJKL 1021 Safrole 94-59-7 BCEFHK 1022
2,2,7,9-tetramethylspiro(5.5)undec- 502847-01-0 DHIJK 8-en-1-one
1023 3-methyl-5-(2,2,3- 65113-99-7 DEFHJK
trimethylcyclopent-3-en-1-yl)pentan- 2-ol 1024
(Z)-2-ethyl-4-(2,2,3- 28219-61-6 DEFHJK
trimethylcyclopent-3-en-1-yl)but-2- en-1-ol 1025
(E)-2-methyl-4-(2,2,3- 28219-60-5 CHJK
trimethylcyclopent-3-en-1-yl)but-2- en-1-ol 1026
5-methoxyoctahydro-1H-4,7- 86803-90-9 CHJK
methanoindene-2-carbaldehyde 1027 5-methoxyoctahydro-1H-4,7-
193425-86-4 CHJK methanoindene-2-carbaldehyde 1028 Sclareol
515-03-7 DEFHJ 1029 Sclareol oxide 5153-92-4 DEFHJK 1031
Selina-3,7(11)-diene 6813-21-4 DEFHJKL 1032 2-(1-(3,3- 477218-42-1
DEFHJ dimethylcyclohexyl)ethoxy)-2- methylpropyl
cyclopropanecarboxylate 1033 3-(4-isobutylphenyl)-2- 6658-48-6 DHJK
methylpropanal 1035 Spathulenol 6750-60-3 DEFHJK
1036 Spirambrene 533925-08-5 BCEFHJK 1037 Spirodecane 6413-26-9
BCEFGIJKL 1038 1-(spiro[4.5]dec-7-en-7-yl)pent-4-en- 224031-70-3
DGJK 1-one 1042 2-(4-methylthiazol-5-yl)ethan-1-ol 137-00-8 CGIKL
1043 2-(heptan-3-yl)-1,3-dioxolane 4359-47-1 ACEFHIJKL 1045
(Z)-dodec-4-enal 21944-98-9 BDFHJK 1046 tau-Cadinol 5937-11-1
DEFHJK 1047 tau-Muurolol 19912-62-0 DEFHJK 1053 Tetrahydrojasmone
13074-63-0 BDFHIJKL 1057 2,6,10,10-tetramethyl-1- 36431-72-8
BDFHIJKL oxaspiro[4.5]dec-6-ene 1059 Thiomenthone 38462-22-5
BDEFHIJKL 1060 Thujopsene 470-40-6 BDEFGJKL 1062 Thymol methyl
ether 1076-56-8 ADHIJKL 1063 1-(2,2,6-trimethylcyclohexyl)hexan-
70788-30-6 DEFHJK 3-ol 1064 trans,trans-2,4-Nonadienal 5910-87-2
ACHKL 1065 trans,trans-Farnesol 106-28-5 DEFHJK 1066
trans-2,cis-6-Nonadienal 557-48-2 ACHKL 1067 trans-2-Decenal
3913-81-3 ADHKL 1070 trans-2-Nonen-1-al 18829-56-6 ADHKL 1072
trans-3, cis-6-nonadienol 56805-23-3 ACEFHK 1073 trans-4-Decen-1-al
65405-70-1 ADHKL 1075 trans-ambrettolide 51155-12-5 DGJ 1077
trans-beta-ocimene 13877-91-3 ADGIKL 1078 trans-beta-Ocimene
3779-61-1 ADGIKL 1082 trans-Geraniol 106-24-1 BCHIK 1083
trans-Hedione 2570-03-8 DFHJK 1085 7-(1,1-Dimethylethyl)-2H-1,5-
195251-91-3 CEFHJ benzodioxepin-3(4H)-one 1089 Tricyclone
68433-81-8 DEFHJK 1090 Tridecyl alcohol 112-70-9 DEFGJK 1091
Triethyl citrate 77-93-0 CEFGJ 1093 Methyl 2-((1-hydroxy-3-
144761-91-1 DFHJ phenylbutyl)amino)benzoate 1095
1-((2E,5Z,9Z)-2,6,10- 28371-99-5 DHJK
trimethylcyclododeca-2,5,9-trien-1- yl)ethan-1-one 1097
Decahydro-2,6,6,7,8,8-hexamethyl- 338735-71-0 BDEFHJK
2h-indeno(4,5-b)furan 1099 13-methyl oxacyclopentadec-10-en-
365411-50-3 DEFHJK 2-one 1102 Undecanal 112-44-7 BDHJK 1104
(E)-4-methyldec-3-en-5-ol 81782-77-6 BDEFHIJK 1105 Valencene
4630-07-3 BDEFHJK 1107 Valerianol 20489-45-6 DEFHJK 1111 Vanillin
isobutyrate 20665-85-4 CHJ 1113 Vaniwhite .RTM. 5533-03-9 CGIK 1116
(Z)-2-methyl-4-(2,6,6- 68555-62-4 BDFHJK
trimethylcyclohex-2-en-1-yl)but-2- enal 1117 Methyl
2,4-dihydroxy-3,6- 4707-47-5 CGIJ dimethylbenzoate 1120
1-methoxy-3a,4,5,6,7,7a-hexahydro- 27135-90-6 ACEFHJKL
1H-4,7-methanoindene 1121 Methyl (Z)-2-((3-(4-(tert- 91-51-0 DFHJ
butyl)phenyl)-2- methylpropylidene)amino)benzoate 1125
(Z)-hex-3-en-1-yl isobutyrate 41519-23-7 ADEFHJKL 1126 Vertacetal
5182-36-5 BCFHJK 1129 1-((3R,3aR,7R,8aS)-3,6,8,8- 32388-55-9 DHJK
tetramethyl-2,3,4,7,8,8a-hexahydro-
1H-3a,7-methanoazulen-5-yl)ethan- 1-one 1131 Methyl (Z)-2-(((2,4-
68738-99-8 DEFHJ dimethylcyclohex-3-en-1-
yl)methylene)amino)benzoate 1135 Vetiverol 89-88-3 CEFHIJK 1136
Vetivert Acetate 117-98-6 DEFHJK 1137
Decahydro-3H-spiro[furan-2,5'- 68480-11-5 DEFGJKL
[4,7]methanoindene] 1138 (2Z,6E)-nona-2,6-dienenitrile 67019-89-0
ACEFHKL 1139 (Z)-cyclooct-4-en-1-yl methyl 87731-18-8 BCHJKL
carbonate 1140 (1aR,4S,4aS,7R,7aS,7bS)-1,1,4,7- 552-02-3 DEFHJK
tetramethyldecahydro-1H- cyclopropa[e]azulen-4-ol 1142
3,5,5,6,7,8,8-heptamethyl-5,6,7,8- 127459-79-4 DHJ
tetrahydronaphthalene-2-carbonitrile 1143 (1S,2S,3S,5R)-2,6,6-
133636-82-5 DEFHJK trimethylspiro[bicyclo[3.1.1]heptane-
3,1'-cyclohexan]-2'-en-4'-one 1144
1',1',5',5'-tetramethylhexahydro- 154171-76-3 DEFHJK
2'H,5'H-spiro[[1,3]dioxolane-2,8'- [2,4a]methanonaphthalene] 1145
1',1',5',5'-tetramethylhexahydro- 154171-77-4 DEFHJK
2'H,5'H-spiro[[1,3]dioxolane-2,8'- [2,4a]methanonaphthalene] K 1146
4-(4-hydroxy-3- 122-48-5 CEFGJ methoxyphenyl)butan-2-one 1147
(1R,8aR)-4-isopropyl-1,6-dimethyl- 41929-05-9 DEFHJKL
1,2,3,7,8,8a-hexahydronaphthalene 1148
4,5-epoxy-4,11,11-trimethyl-8- 1139-30-6 DEFHJK
methylenebicyclo(7.2.0)undecane 1149
1,3,4,6,7,8alpha-hexahydro-1,1,5,5- 23787-90-8 DEFHIJK
tetramethyl-2H-2,4alpha- methanophtalen-8(5H)-one
TABLE-US-00002 TABLE 2 List of materials with at least one MORV
greater than 5 to 10 Num- CAS Comment ber Material Name Number Code
2 2,4-dimethyl-2-(5,5,8,8-tetramethyl- 131812-67-4 DFHJ
5,6,7,8-tetrahydronaphthalen-2-yl)- 1,3-dioxolane 23
3a,5,6,7,8,8b-hexahydro- 823178-41-2 DEFHJK
2,2,6,6,7,8,8-heptamethyl-4H- indeno(4,5-d)-1,3-dioxole 141
2,4-dimethyl-4,4a,5,9b- 27606-09-3 CEFHJK
tetrahydroindeno[1,2-d][1,3]dioxine 185 (1-methyl-2-((1,2,2-
198404-98-7 DEFHJK trimethylbicyclo[3.1.0]hexan-3-
yl)methyl)cyclopropyl)methanol 227 Isobornylcyclohexanol 68877-29-2
DEFHJK 230 Isobornyl cyclohexanol 66072-32-0 DEFHJK 246
Indol/Hydroxycitronellal Schiff base 67801-36-9 DEFHJ 248
Hydroxymethyl isolongifolene 59056-64-3 DEFHJK 343
8,8-dimethyl-3a,4,5,6,7,7a- 76842-49-4 DEFHJK
hexahydro-1H-4,7-methanoinden-6- yl propionate 359
(E)-4-((3aR,4R,7R,7aR)- 501929-47-1 DEFHJK
1,3a,4,6,7,7a-hexahydro-5H-4,7- methanoinden-5-ylidene)-3-
methylbutan-2-ol 565 Cedryl methyl ether 19870-74-7 BDEFHJK 631
beta-Copaene 18252-44-3 BDEFHJKL 659 2'-isopropyl-1,7,7-
869292-93-3 BDEFHJK trimethylspiro[bicyclo[2.2.1]heptane-
2,4'-[1,3]dioxane] 674 (4aR,5R,7aS,9R)-2,2,5,8,8,9a- 211299-54-6
DEFHJK hexamethyloctahydro-4H-4a,9-
methanoazuleno[5,6-d][1,3]dioxole 678
(3S,5aR,7aS,11aS,11bR)-3,8,8,11a- 57345-19-4 DEFHJ
tetramethyldodecahydro-5H-3,5a- epoxynaphtho[2,1-c]oxepine 679
2,2,6,6,7,8,8-heptamethyldecahydro- 476332-65-7 DEFHJK
2H-indeno[4,5-b]furan 715 alpha-Cedrene epoxide 13567-39-0 BDEFHJK
758 Acetoxymethyl-isolongifolene 59056-62-1 DEFHJK (isomers) 1028
Sclareol 515-03-7 DEFHJ 1097 Decahydro-2,6,6,7,8,8-hexamethyl-
338735-71-0 DEFHJK 2h-indeno(4,5-b)furan
TABLE-US-00003 TABLE 3 List of materials with at least one MORV
from 0.5 to less than 1 Number Material Name CAS Number Comment
Code 12 1-ethoxy-4-(tert- 181258-89-9 ADEFHJK pentyl)cyclohexane 19
(3Z)-1-(2-buten-1-yloxy)-3- 888744-18-1 ADEFHJKL hexene 20
4-(2-methoxypropan-2-yl)-1- 14576-08-0 ADHIJKL methylcyclohex-1-ene
24 O-Methyl linalool 60763-44-2 ADHIJKL 26 o-Methoxycinnamaldehyde
1504-74-1 ACHK 27 Octanal, 3,7-dimethyl- 25795-46-4 ADGIJKL 53
3,3-Dimethyl-5(2,2,3- 329925-33-9 CEFHJ Trimethyl-3-Cyclopenten-
1yl)-4-Penten-2-ol 54 n-Hexyl salicylate 6259-76-3 DEFHJ 55 n-Hexyl
2-butenoate 19089-92-0 ADEFHJKL 59 Neryl Formate 2142-94-1 BCEFHJK
72 Methyl-beta-ionone 127-43-5 DHJK 73 Myroxide 28977-57-3 ADGIJKL
81 (E)-3,7-dimethylocta-4,6- 18479-54-4 BCEFGIJK dien-3-ol 84
(Z)-hex-3-en-1-yl 188570-78-7 BCEFHIKL cyclopropanecarboxylate 96
Methyl phenyl carbinyl 120-45-6 BCHJK propionate 97 Methyl
phenylacetate 101-41-7 ACEFHIKL 107 2-methyl-6- 91069-37-3 BCEFGIKL
oxaspiro[4.5]decan-7-one 111 Methyl geraniate 2349-14-6 BCHJKL 115
2-ethoxy-4- 5595-79-9 CFGK (methoxymethyl)phenol 116 Methyl
40203-73-4 ACEFHIKL cyclopentylideneacetate 125 Methoxymelonal
62439-41-2 ACGIJK 133 ((1s,4s)-4- 13828-37-0 BDEFHIJK
isopropylcyclohexyl)methanol 147 Linalyl propionate 144-39-8 BDFHJK
150 Linalyl formate 115-99-1 ACFHJK 151 Linalyl butyrate 78-36-4
BDEFHJK 154 Linalyl acetate 115-95-7 BDHJK 157 Linalool 78-70-6
BCEFGIJK 163 (Z)-hex-3-en-1-yl methyl 67633-96-9 ACEFGKL carbonate
166 Lepidine 491-35-0 BCEFHIKL 169 L-Carvone 6485-40-1 ACGIJKL 181
Khusinil 75490-39-0 DHJK 191 Isoraldeine 1335-46-2 BDHIJK 194
Isopropylvinylcarbinol 4798-45-2 ACGIKL 198 Isopropyl
2-methylbutyrate 66576-71-4 ACEFGIJKL 201 Isopentyrate 80118-06-5
ADEFGIJKL 204 Isononyl acetate 40379-24-6 BDEFHJKL 205 Isononanol
27458-94-2 BDEFGIKL 213 Isoeugenyl acetate 93-29-8 CFHJK 214
Isoeugenol 97-54-1 CEFHIK 232 Isoborneol 124-76-5 ACEFHIJKL 237
Isoamyl octanoate 2035-99-6 DEFHJK 239 Isoamyl isobutyrate
2050-01-3 ACEFGIJKL 255 Hydrocinnamic acid 501-52-0 CEFHIK 258
Hydratopic alcohol 1123-85-9 BCEFHIK 264 Hexyl propanoate 2445-76-3
ADEFHIKL 270 Hexyl butyrate 2639-63-6 BDEFHJKL 273 Hexyl
2-methylbutanoate 10032-15-2 BDEFHJKL 275 Hexyl 2-furoate
39251-86-0 DEFHJK 282 Heptyl alcohol 111-70-6 ACEFGIKL 283 Heptyl
acetate 112-06-1 ADEFHKL 284 Heptaldehyde 111-71-7 ACHIKL 287
Heliotropin 120-57-0 BCGIK 302 Geranyl nitrile 5146-66-7 BCEFHKL
306 Geranyl formate 105-86-2 BCEFHJK 308 Geranyl caprylate
51532-26-4 DEFHJ 310 Geranyl benzoate 94-48-4 DFHJ 312 Geranial
141-27-5 ACHIKL 314 N,2-dimethyl-N- 84434-18-4 BCEFHJK
phenylbutanamide 319 gamma-Terpinene 99-85-4 ADEFGIJKL 346
2-(sec-butyl)cyclohexan-1- 14765-30-1 ADFHIKL one 354
3-(2-ethylphenyl)-2,2- 67634-14-4 BDHJK dimethylpropanal 355
2-(tert-butyl)cyclohexyl ethyl 67801-64-3 BDFHJK carbonate 365
2-(tert-butyl)cyclohexyl ethyl 81925-81-7 ACFHIKL carbonate 366
Fenchyl alcohol 1632-73-1 ACGIJKL 376 Eucalyptol 470-82-6 ADEFGIJKL
379 Ethyl vanillin acetate 72207-94-4 CHJ 387 Ethyl octanoate
106-32-1 BDEFHJKL 400 Ethyl cinnamate 103-36-6 BCEFHK 412 Ethyl 2-
2511-00-4 BDFHIJKL (cyclohexyl)propionate 419
d-p-8(9)-Menthen-2-one 5524-05-0 ACGIJKL 420
4-methyl-2-phenyltetrahydro- 94201-73-7 BDEFHJK 2H-pyran 437
Dihydromyrcenol 18479-58-8 ADEFGIJK 438 Dihydrojasmone 1128-08-1
BCFHIJKL 439 Dihydroisophorone 873-94-9 ACEFGIJKL 440
Dihydroeugenol 2785-87-7 CEFHIJK 442 Dihydrocoumarin 119-84-6
BCGIKL 443 Dihydrocarvone 7764-50-3 ACGIJKL 447
Dihydro-alpha-terpinyl 80-25-1 BDEFHIJKL acetate 448
Dihydro-alpha-ionone 31499-72-6 BDHIJK 454 Dibenzyl ether 103-50-4
DEFHJK 455 Dibutyl o-phthalate 84-74-2 DEFHJ 469
2-pentylcyclopentan-1-one 4819-67-4 BDFHIKL 472 Decyl anthranilate
18189-07-6 DEFHJ 477 Methyl (1s,4s)-1,4- 23059-38-3 ADEFHIJKL
dimethylcyclohexane-1- carboxylate 481 Cyclohexylethyl acetate
21722-83-8 BDEFHJKL 492 Creosol 93-51-6 BCHIK 495 Cosmene 460-01-5
ADEFGIKL 496 4-cyclohexyl-2-methylbutan- 83926-73-2 BDEFGIJK 2-ol
504 2-benzyl-2-methylbut-3- 97384-48-0 BDHJK enenitrile 509
Citronellyl nitrile 51566-62-2 BCEFGIKL 510 Citronellyl
phenylacetate 139-70-8 DFHJ 512 Citronellyl formate 105-85-1
BCEFGJKL 515 Citronellyl benzoate 10482-77-6 DFHJ 517 Citronellol
106-22-9 BCHIJKL 518 Citronellal 106-23-0 ACHIJKL 522 Citral
5392-40-5 ACHIKL 525 cis-Pinane 6876-13-7 ADEFGIJKL 526
(Z)-3-methyl-2-(pent-2-en-1- 488-10-8 BCHIJKL
yl)cyclopent-2-en-1-one 528 cis-iso-Eugenol 5912-86-7 CEFHIK 535
cis-3-Hexenyl valerate 35852-46-1 BDEFHJKL 536 cis-3-Hexenyl
tiglate 67883-79-8 BDEFHJK 538 cis-3-Hexenyl propionate 33467-74-2
ACEFHIKL 540 cis-3-Hexenyl butyrate 16491-36-4 ADEFHJKL 542
cis-3-Hexen-1-ol 928-96-1 ACEFHIKL 547 cis-2-Hexenol 928-94-9
ACEFHIKL 549 Cinnamyl nitrile 4360-47-8 ACEFGIK 554 Cinnamic
aldehyde 104-55-2 ACHIK 556 Cinnamyl nitrile 1885-38-7 ACEFGIK 557
Chloroxylenol 88-04-0 BCHIJK 575 Carvacrol 499-75-2 DHIJK 576
Carvone 99-49-0 ACGIJKL 579 Carbitol 111-90-0 BCEFGIK 583 Caproyl
alcohol 111-27-3 ACEFGIKL 585 2-(2,2,3-trimethylcyclopent-3-
15373-31-6 ACGIJKL en-1-yl)acetonitrile 588 Camphor 76-22-2
ACEFGIJKL 602 (E)-2-methyl-4-(2,6,6- 3155-71-3 DHJK
trimethylcyclohex-1-en-1- yl)but-2-enal 605 Borneol 507-70-0
ACEFHIJKL 617 beta-Pinene epoxide 6931-54-0 ACEFGIJKL 619
beta-Phellandrene 555-10-2 ADEFGIJKL 640 Benzylacetone 2550-26-7
ACEFGIK 641 Benzyl salicylate 118-58-1 DFGJ 645 Benzyl isovalerate
103-38-8 BDEFHJK 647 Benzyl isobutyrate 103-28-6 BCHJK 651 Benzyl
butyrate 103-37-7 BCEFHJK 652 Benzyl alcohol 100-51-6 ACEFGIKL 662
1-(3,3- 25225-08-5 ADEFHIJKL dimethylcyclohexyl)ethyl formate 664
Anisyl acetate 104-21-2 BCEFGK 665 Anisyl formate 122-91-8 BCEFGK
667 Anethole 104-46-1 ACEFHK 672 Amyl benzoate 2049-96-9 DEFHJK 687
alpha-Terpinyl acetate 80-26-2 BDHJK 699 alpha-methyl- 10528-67-3
BDEFHIK cyclohexanepropanol 701 alpha-methyl cinnamaldehyde
101-39-3 ACHIK 703 alpha-Isomethylionone 127-51-5 BDHIJK 740
2,5-Dimethyl-4-methoxy- 4077-47-8 ACEFGIJKL 3(2H)-furanone 743
Allyl phenoxyacetate 7493-74-5 BCGK 744 Allyl Phenethyl ether
14289-65-7 ACEFHK 745 Allyl heptanoate 142-19-8 ADEFHJKL 755
N-ethyl-N-(m- 179911-08-1 CEFHJK tolyl)propionamide 760
3-hydroxybutan-2-one 513-86-0 ACEFGIKL 761 Acetoanisole 100-06-1
BCEFHIK 777 6-Methylquinoline 91-62-3 BCEFHIKL 779
6,8-Diethyl-2-nonanol 70214-77-6 BDEFGIJKL 784 5-Methyl-3-heptanone
541-85-5 ACFGIKL 789 4-Vinylphenol 2628-17-3 BCHIK 796
4-hydroxy-3-methoxy- 458-36-6 CH cinnamaldehyde 797 4-Ethylguaiacol
2785-89-9 CEFHIK 799 4-Damascol 4927-36-0 BDFHJK 808
3-methyl-4-phenylpyrazole 13788-84-6 CEFHK 810 3-Methyl-1,2-
765-70-8 ACEFGIKL cyclopentanedione 811 3-Methoxy-5-methylphenol
3209-13-0 BCHIK 812 3-Methoxy-3-Methyl Butanol 56539-66-3 ACGIKL
817 3-Hexenol 544-12-7 ACEFHIKL 819 3,7-dimethyl-2-methylene-6-
22418-66-2 ADFHIJK octenal 820 3,7-dimethyl-1-octanol 106-21-8
BDEFGIJKL 832 2-Phenylethyl acetate 103-45-7 BCEFHK 835 2-Phenethyl
propionate 122-70-3 BCEFHJK 836 2-Pentylcyclopentan-1-ol 84560-00-9
DEFHIKL 838 2-nonanone propylene glycol 165191-91-3 BDEFHJK acetal
845 2-Methoxy-3-(1- 24168-70-5 BCEFGIK methylpropyl)pyrazine 846
2-isopropyl-N,2,3- 51115-67-4 ACEFGIJK trimethylbutyramide 847
2-Isopropyl-5-methyl-2- 35158-25-9 ADFGIJKL hexenal 848
2-Isopropyl-4-methylthiazole 15679-13-7 ACHIJKL 851 2-Hexen-1-ol
2305-21-7 ACEFHIKL 858 2-Butoxyethanol 111-76-2 ACEFGIKL 875
1,4-Cineole 470-67-7 ADGIJKL 880 1-(2,6,6-Trimethyl-2- 43052-87-5
BDHIJK cyclohexen-1-yl)-2-buten-1- one 882 (Z)-3-hepten-1-yl
acetate 1576-78-9 ACEFHKL 883 (S)-(1R,5R)-4,6,6- 1196-01-6
ACEFGIJKL trimethylbicyclo[3.1.1]hept-3- en-2-one 888
(R)-(-)-Linalool 126-91-0 BCEFGIJK 889 (l)-Citronellal 5949-05-3
ACHIJKL 891 (d)-Citronellal 2385-77-5 ACHIJKL 899 (+)-Citronellol
1117-61-9 BCHIJKL 900 (-)-Citronellol 7540-51-4 BCHIJKL 901
(+)-alpha-Pinene 7785-70-8 ADEFGIJKL 902 (+)-Carvone 2244-16-8
ACGIJKL 903 (-)-alpha-Pinene 7785-26-4 ADEFGIJKL 904 Methyl
2-methylbutyrate 868-57-5 ACEFGIKL 909 Hexyl tiglate 16930-96-4
BDEFHJKL 918 Allyl 2- 68901-15-5 CHJK (cyclohexyloxy)acetate 921
1,5- 75147-23-8 CFHIJK dimethylbicyclo[3.2.1]octan- 8-one oxime 931
alpha-acetoxystyrene 2206-94-2 ACEFHIK 940 p-Cymene 99-87-6 ADGIJKL
956 Phenethyl formate 104-62-1 ACEFHK 958 Phenethyl isobutyrate
103-48-0 DHJK 960 Phenethyl tiglate 55719-85-2 DHJK 971 Phenylethyl
methacrylate 3683-12-3 DHJK 977 p- 4395-92-0 BDFHK
Isopropylphenylacetaldehyde 981 1,2-dimethyl-3-(prop-1-en-2-
72402-00-7 BCEFGIJKL yl)cyclopentan-1-ol 983 p-Methoxyphenylacetone
122-84-9 BCEFHK 986 (2Z,5Z)-5,6,7-trimethylocta- 358331-95-0
ADHIJKL 2,5-dien-4-one 987 p-Propyl anisole 104-45-0 ADEFHKL 994
p-t-butyl phenyl acetaldehyde 109347-45-7 BDHJK 995 p-tert-Amyl
cyclohexanol 5349-51-9 BDEFHIJK
1001 Racemic alpha-Pinene 80-56-8 ADEFGIJKL 1002
4-(4-hydroxyphenyl)butan-2- 5471-51-2 CEFGIK one 1004 Rhodinol
141-25-3 BCHIJKL 1005 Ethyl (2,3,6- 93981-50-1 BDEFHJKL
trimethylcyclohexyl) carbonate 1011 1-(3,3- 25225-10-9 ADHIJKL
dimethylcyclohexyl)ethyl acetate 1017 S)-(+)-Linalool 126-90-9
BCEFGIJK 1018 Sabinene 3387-41-5 ADEFGIJKL 1019 Sabinene hydrate
546-79-2 ADEFGIJKL 1030 Propyl (S)-2-(tert- 319002-92-1 BDEFHJK
pentyloxy)propanoate 1039 Spirolide 699-61-6 BCGIKL 1040
(Z)-5-methylheptan-3-one 22457-23-4 BCEFGIJKL oxime 1041
1-phenylethyl acetate 93-92-5 ACEFHIK 1051 Tetrahydrogeranial
5988-91-0 ADGIJKL 1052 Tetrahydroionol 4361-23-3 BDEFHIJK 1054
Tetrahydrolinalool 78-69-3 BDEFGIJKL 1055 Tetrahydrolinalyl acetate
20780-48-7 ADEFHJKL 1058 Ethyl (1R,6S)-2,2,6- 22471-55-2 ADEFHIJKL
trimethylcyclohexane-1- carboxylate 1061 Thymol 89-83-8 BDHIJK 1069
trans-2-Hexenol 928-95-0 ACEFHIKL 1071 trans-2-tert- 5448-22-6
ACGIJKL Butylcyclohexanol 1074 trans-alpha-Damascone 24720-09-0
BDHIJK 1076 trans-Anethole 4180-23-8 ACEFHK 1079 trans-Cinnamic
acid 140-10-3 CEFHK 1081 trans-Dihydrocarvone 5948-04-9 ACGIJKL
1084 trans-Isoeugenol 5932-68-3 CEFHIK 1088 Trichloromethyl phenyl
90-17-5 BDEFGJ carbinyl acetate 1098 2-mercapto-2-methylpentan-
258823-39-1 ACEFHIJKL 1-ol 1110 Vanillin acetate 881-68-5 CH 1112
Vanitrope 94-86-0 CEFHK 1115 2,2,5-trimethyl-5- 65443-14-3 BDFGIJKL
pentylcyclopentan-1-one 1118 Veratraldehyde 120-14-9 BCGIK 1119
(1R,5R)-4,6,6- 18309-32-5 ACEFGIJKL trimethylbicyclo[3.1.1]hept-3-
en-2-one 1122 Verdol 13491-79-7 ACGIJKL 1127
4-(tert-butyl)cyclohexyl 10411-92-4 BDEFHJK acetate 1128
4-(tert-butyl)cyclohexyl 32210-23-4 BDEFHJK acetate 1133 Vethymine
7193-87-5 CEFGK 1134 4-methyl-4-phenylpentan-2-yl 68083-58-9 BDFHJK
acetate 1141 (Z)-1-((2- 292605-05-1 ADEFHKL
methylallyl)oxy)hex-3-ene
TABLE-US-00004 TABLE 4 List of malodor reduction materials with ALL
MORVs from 1 to 5 Num- CAS Comment ber Material Name Number Code 7
3-methoxy-7,7-dimethyl-10- 216970-21-7 BDEFHJK
methylenebicyclo[4.3.1]decane 14 Oxyoctaline formate 65405-72-3
DFHJK 39 2,2,6,8-tetramethyl-1,2,3,4,4a,5,8,8a- 103614-86-4 DEFHIJK
octahydronaphthalen-1-ol 48 Nootkatone 4674-50-4 DHJK 183 Khusimol
16223-63-5 CEFHJK 199 Isopimpinellin 482-27-9 CFGJ 206
Iso3-methylcyclopentadecan-1-one 3100-36-5 DEFGJK 212 Isoeugenyl
benzyl ether 120-11-6 DFHJ 215 1-((2S,3S)-2,3,8,8-tetramethyl-
54464-57-2 DHJK 1,2,3,4,5,6,7,8-octahydronaphthalen-
2-yl)ethan-1-one 229 Isobornyl isobutyrate 85586-67-0 BDEFHIJK 260
2,3-dihydro-3,3-dimethyl-1H-indene- 173445-44-8 DHJK 5-propanal 261
3-(3,3-dimethyl-2,3-dihydro-1H- 173445-65-3 DHJK
inden-5-yl)propanal 281 3a,4,5,6,7,7a-hexahydro-1H-4,7- 5413-60-5
CEFGJK methanoinden-6-yl acetate 329 gamma-Eudesmol 1209-71-8 DFHJK
335 4,6,6,7,8,8-hexamethyl-1,3,4,6,7,8- 1222-05-5 DEFHJK
hexahydrocyclopenta[g]isochromene 353
(Z)-6-ethylideneoctahydro-2H-5,8- 69486-14-2 CEFGJK
methanochromen-2-one 360 8,8-dimethyl-3a,4,5,6,7,7a- 171102-41-3
DEFHJK hexahydro-1H-4,7-methanoinden-6- yl acetate 441
Octahydro-1H-4,7-methanoinden-5- 64001-15-6 DEFHJKL yl acetate 484
3a,4,5,6,7,7a-hexahydro-1H-4,7- 113889-23-9 DEFHJK
methanoinden-6-yl butyrate 487 3a,4,5,6,7,7a-hexahydro-1H-4,7-
67634-20-2 DEFHJK methanoinden-5-yl isobutyrate 488 Curzerene
17910-09-7 DHJK 501 (E)-cycloheptadec-9-en-1-one 542-46-1 DEFGJ 566
Cedryl formate 39900-38-4 BDEFHJK 567 Cedryl acetate 77-54-3 DEFHJK
569 Cedrol 77-53-2 DEFHJK 570 5-methyl-1-(2,2,3- 139539-66-5 DEFHJK
trimethylcyclopent-3-en-1-yl)-6- oxabicyclo[3.2.1]octane 573
Caryophyllene alcohol acetate 32214-91-8 DEFHJK 574 Caryolan-1-ol
472-97-9 DEFHJK 603 Bornyl isobutyrate 24717-86-0 BDEFHIJK 616
beta-Santalol 77-42-9 DEFHJK 621 beta-Patchoulline 514-51-2
BDEFGJKL 624 beta-Himachalene Oxide 57819-73-5 BDFHJK 627
(2,2-dimethoxyethyl)benzene 101-48-4 DHJK 632 beta-Cedrene 546-28-1
BDEFGJKL 663 Anisyl phenylacetate 102-17-0 DFHJ 680
2,2,6,6,7,8,8-heptamethyldecahydro- 647828-16-8 ADEFHJK
2H-indeno[4,5-b]furan 684 alpha-Vetivone 15764-04-2 DHJK 694
alpha-Santalol 115-71-9 DEFHJK 696 alpha-Patchoulene 560-32-7
ADEFHJKL 708 alpha-Gurjunene 489-40-7 BDEFHJKL 712 alpha-Eudesmol
473-16-5 DEFHJK 714 alpha-Cubebene 17699-14-8 ADEFHJKL 726
alpha-Agarofuran 5956-12-7 BDEFHJK 750 Allo-aromadendrene
25246-27-9 BDEFHJKL 764 Acetarolle 744266-61-3 DFHJK 775
7-eip-alpha-Eudesmol 123123-38-6 DEFHJK 776 7-Acetyl-1,1,3,4,4,6-
1506-02-1 DEFHJ hexamethyltetralin 788 5-Cyclohexadecenone
37609-25-9 DEFGJK 804 3-Thujopsanone 25966-79-4 BDEFHJK 872
10-epi-gamma-Eudesmol 15051-81-7 DFHJK 919
3a,4,5,6,7,7a-hexahydro-1H-4,7- 17511-60-3 CEFHJK methanoinden-6-yl
propionate 927 5-Acetyl-1,1,2,3,3,6- 15323-35-0 DEFHJK
hexamethylindan 933 Patchouli alcohol 5986-55-0 DEFHIJK 978
3a,4,5,6,7,7a-hexahydro-1H-4,7- 68039-44-1 DEFHJK methanoinden-6-yl
pivalate 1007 (2R,4a'R,8a'R)-3,7'-dimethyl- 41816-03-9 DEFHJK
3',4',4a',5',8',8a'-hexahydro-1'H- spiro[oxirane-2,2'-
[1,4]methanonaphthalene] 1022 2,2,7,9-tetramethylspiro(5.5)undec-
502847-01-0 DHIJK 8-en-1-one 1024 (Z)-2-ethyl-4-(2,2,3- 28219-61-6
DEFHJK trimethylcyclopent-3-en-1-yl)but-2- en-1-ol 1027
5-methoxyoctahydro-1H-4,7- 193425-86-4 CHJK
methanoindene-2-carbaldehyde 1029 Sclareol oxide 5153-92-4 DEFHJK
1035 Spathulenol 6750-60-3 DEFHJK 1038
1-(spiro[4.5]dec-7-en-7-yl)pent-4-en- 224031-70-3 DGJK 1-one 1060
Thujopsene 470-40-6 BDEFGJKL 1089 Tricyclone 68433-81-8 DEFHJK 1107
Valerianol 20489-45-6 DEFHJK 1129 1-((3R,3aR,7R,8aS)-3,6,8,8-
32388-55-9 DHJK tetramethyl-2,3,4,7,8,8a-hexahydro-
1H-3a,7-methanoazulen-5-yl)ethan- 1-one 1131 Methyl (Z)-2-(((2,4-
68738-99-8 DEFHJ dimethylcyclohex-3-en-1-
yl)methylene)amino)benzoate 1136 Vetivert Acetate 117-98-6 DEFHJK
1137 Decahydro-3H-spiro[furan-2,5'- 68480-11-5 DEFGJKL
[4,7]methanoindene] 1140 (1aR,4S,4aS,7R,7aS,7bS)-1,1,4,7- 552-02-3
DEFHJK tetramethyldecahydro-1H- cyclopropa[e]azulen-4-ol 1142
3,5,5,6,7,8,8-heptamethyl-5,6,7,8- 127459-79-4 DHJ
tetrahydronaphthalene-2-carbonitrile 1143 (1S,2S,3S,5R)-2,6,6-
133636-82-5 DEFHJK trimethylspiro[bicyclo[3.1.1]heptane-
3,1'-cyclohexan]-2'-en-4'-one 1144
1',1',5',5'-tetramethylhexahydro- 154171-76-3 DEFHJK
2'H,5'H-spiro[[1,3]dioxolane-2,8'- [2,4a]methanonaphthalene] 1145
1',1',5',5'-tetramethylhexahydro- 154171-77-4 DEFHJK
2'H,5'H-spiro[[1,3]dioxolane-2,8'- [2,4a]methanonaphthalene] K 1148
4,5-epoxy-4,11,11-trimethyl-8- 1139-30-6 DEFHJK
methylenebicyclo(7.2.0)undecane 1149
1,3,4,6,7,8alpha-hexahydro-1,1,5,5- 23787-90-8 DEFHIJK
tetramethyl-2H-2,4alpha- methanophtalen-8(5H)-one
TABLE-US-00005 TABLE 5 List of malodor reduction materials with ALL
MORVs greater than 5 to 10 Number Material Name CAS Number Comment
Code 248 Hydroxymethyl 59056-64-3 BDEFHJK isolongifolene
TABLE-US-00006 TABLE 6 List of malodor reduction materials with ALL
MORVs from 0.5 to less than 1 Number Material Name CAS Number
Comment Code 472 Decyl anthranilate 18189-07-6 DEFHJ 526
(Z)-3-methyl-2-(pent- 488-10-8 BCHIJKL 2-en-1-yl)cyclopent-
2-en-1-one
[0025] The materials in Tables 1-6 can be supplied by one or more
of the following: Firmenich Inc. of Plainsboro N.J. USA;
International Flavor and Fragrance Inc. New York, N.Y. USA;
Takasago Corp. Teterboro, N.J. USA; Symrise Inc. Teterboro, N.J.
USA; Sigma-Aldrich/SAFC Inc. Carlsbad, Calif. USA; and Bedoukian
Research Inc. Danbury, Conn. USA.
[0026] Actual MORV values for each material listed in Tables 1-6
above are as follows:
TABLE-US-00007 Material MORV value for MORV Value MORV Value MORV
value for No. Equation a.) for Equation b.) for Equation c.)
Equation d.) 1 0.548223914 0.876283261 1.22018588 -0.41901144 2
1.520311929 3.493450446 2.70657265 5.11342862 3 2.267801995
-0.81712657 0.43218875 1.595983683 4 -0.591063369 -0.48283571
0.16199804 1.210497701 7 1.437444636 2.131822996 3.81633465
1.318339345 9 2.151445882 -0.46189495 0.56090469 1.206360803 10
2.5733592 -0.58780849 1.39751471 1.258361951 11 3.052627325
1.008519135 -0.30475953 0.076323462 12 0.683776599 -0.01157903
0.82853231 0.326169402 13 1.549643217 1.809183231 0.70864531
2.22799611 14 2.82111224 2.339505033 1.240818 2.502429355 16
-0.31551128 -0.06816599 -0.04371934 2.76742389 17 -1.334904153
-0.5773313 1.75644798 1.898455724 18 -1.34154226 -2.63596666
0.06885109 1.001431671 19 0.15532384 0.09866097 0.64214585
-0.33330779 20 0.640261783 0.693213268 0.54637273 -0.97556029 21
0.936895364 -0.01521118 1.1697513 -0.63510809 22 1.158981042
1.115900089 -0.25859776 1.318200884 23 3.702361074 1.399942641
5.23954766 7.089933671 24 0.773874141 0.146848137 -1.05705847
-0.36193173 25 -1.016103969 -1.18967936 0.78064625 2.944710012 25
-1.016103969 -1.18967936 0.78064625 2.944710012 26 0.615085491
-0.00096877 -0.35697252 -0.18121401 27 0.70261974 -0.22197386
0.19710806 -2.37196477 28 1.366472597 -0.42546942 -0.59394241
-0.01417395 29 1.096043453 -1.02972898 -1.42167356 -0.63817943 30
1.143415203 -0.85945441 -0.41416913 2.499807942 31 1.138642907
-0.19595476 -0.54547769 -0.98828898 32 1.914414495 -0.64487788
0.63212987 1.166699371 33 0.314847366 1.848003955 -1.3905032
-0.62848261 34 -0.113542761 0.981530917 0.32824239 1.126524277 35
0.472382903 1.494882467 -0.07201236 -0.64589543 36 3.158513795
1.084094934 -0.00328981 -0.17786385 37 -1.055631982 2.240172964
0.92596118 2.105391988 38 3.158513795 0.592820874 -0.49326241
0.212867212 39 1.083800659 2.069727985 2.48170879 3.205630609 42
-0.103134861 0.267726008 -0.65350189 1.125952363 43 0.323961628
1.469295081 -0.52991193 0.797908251 47 1.703678841 1.348737095
2.00634162 -0.16505407 48 2.370955056 2.783472865 2.68240273
1.221864405 49 1.670680003 -0.41866107 -0.9173849 1.181929544 50
1.670680003 0.076369374 -0.49915943 -0.85392575 52 0.464485039
0.057512869 1.31230219 -0.11170276 53 0.626671823 -0.46954947
-0.33383736 0.277079201 54 0.666149043 0.009549925 -0.36226343
0.197224432 55 0.723473579 -1.50916383 -0.3848989 -0.71458778 57
0.381273227 1.192994109 1.65593321 -1.65739236 59 0.561360663
-0.17793966 -1.63250554 -0.7564969 61 0.146473611 -0.01535544
-0.16339658 1.738656146 62 1.20162032 -0.3576095 -0.10695443
1.322155191 63 1.084291915 2.258720158 -1.01245416 1.688283974 64
0.744770665 0.155243763 -1.8029919 1.023503542 65 0.972835178
2.797151284 1.53453579 0.857051645 67 2.069410561 0.021831924
0.37855159 -0.67235457 68 0.527636614 0.590831983 1.02843762
2.208655795 69 2.133965691 2.088998449 2.05751412 -0.9433713 70
0.327378959 0.996844599 1.23648533 -1.25138371 71 1.40093669
0.778222691 0.70401172 -0.24075444 72 0.617697349 -0.29503359
0.52404847 0.816184656 73 0.617792473 0.888976061 -0.45289639
0.615659244 74 1.437359024 1.548292147 0.10314807 -0.48982286 75
-1.970885622 3.398008325 4.08025266 -0.89948156 76 -1.32746934
-2.65365233 0.10272816 1.001614125 77 -2.541686116 3.295534192
3.75284227 0.404837808 78 -2.110794 2.109874746 3.13350902
-0.3880285 79 1.641162056 -0.28533994 1.53676145 0.652696023 80
1.594400214 0.283682865 2.23140233 1.111682021 81 0.176566806
-2.0786518 -2.13986952 0.981126964 82 0.980373758 -0.28813159
0.19404501 1.252564677 83 0.941833098 0.317310013 1.17606727
0.72992237 84 0.774237336 -0.27140727 0.72461427 -1.56415746 85
2.092976965 0.810644229 0.82999192 -0.62861806 91 2.061595915
-0.79930338 -0.18285395 -0.66898499 92 2.068748434 -0.24299896
0.07214682 -1.11758276 93 -0.08984279 -1.06025959 -0.05068694
1.560050105 96 0.927758203 -0.44129515 0.89190422 0.744284978 97
0.658667572 -0.68771072 0.46051026 -0.53120883 98 0.853222693
-0.2037738 -0.21414441 1.119784962 100 1.654535066 0.995056228
2.35139085 0.543654824 101 2.173663649 -0.11491477 1.48285148
1.698527571 102 2.066679492 -0.16785146 -0.84780149 0.12159477 103
2.335152618 -0.02866585 0.16993375 -0.98254522 104 2.760588276
0.459513599 1.35310241 0.000336976 105 1.654535066 3.654489674
3.13033965 0.544225478 106 1.750588169 -0.55853348 0.50257773
1.630011313 107 0.896789863 0.73615897 0.53011623 -0.54697747 108
0.532375207 0.826537134 1.21040312 0.690230716 109 2.407655187
0.742651426 1.80322099 0.271832856 110 0.54830833 2.916795026
1.40126098 0.690230716 111 0.939597126 -0.3750368 -1.23479972
-0.89366351 112 1.398518854 1.265740274 4.19618377 -0.12762692 113
1.415726941 0.086297006 3.43559555 -0.12964168 115 -1.557729423
-0.44113526 0.86330536 0.590708892 116 0.193562268 -1.58091165
0.83247813 -0.70978039 117 1.353510875 -0.59062398 -0.31776345
-0.3050158 119 0.830052725 2.28725579 0.38409695 0.219336109 120
1.261997955 -0.22622961 -1.04772194 2.028504137 122 1.505653628
-1.14748206 -0.19760084 -0.81373045 123 -0.658721962 -0.21299878
1.01439841 -0.76731016 125 0.749676998 -1.0761601 0.99563924
-1.15409002 126 0.931054384 -0.35067079 1.06050832 -1.62171794 128
-1.344832644 -0.09451199 1.19145467 1.621274257 130 1.153249538
1.605070708 2.38047907 -0.93842293 133 0.840066046 0.2323025
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1.451782586 -0.565439 -0.32447381 -0.43378383 943 1.188491672
0.120632811 0.20106994 3.078484746 945 1.214814941 0.806987609
0.47605587 1.372949466 946 0.561732094 1.21448402 0.35542793
-1.03704442 947 0.956565856 1.505997176 0.88115653 -0.60583691 948
0.592575441 1.383482681 0.93567635 1.058669028 950 0.343657562
-0.85471906 -0.21125904 1.184648122 951 1.236659334 3.828926809
1.57729777 -0.31942874 953 1.836389049 0.755753735 -0.36014522
1.262853393 953 1.836389049 0.755753735 -0.36014522 1.262853393 954
1.001653875 -0.85635082 0.89224781 -0.39245818 955 -0.122918652
-0.846489 -0.63367729 1.182912962 956 0.589766639 -0.9783487
-0.67638264 -0.38772225 958 0.715082397 -0.90020686 0.86817768
0.030652004 959 1.609198886 0.500797943 0.795571 0.908389449 960
0.952787327 -0.90555475 -0.17381408 0.06786323 962 1.836429446
0.208275147 -0.14300625 1.067462181 965 1.9158432 0.35211823
-1.02174589 0.625657932 967 1.383869627 0.274520494 -0.11659267
0.840327437 969 -0.445579934 -1.68867059 -0.5241276 2.233793943 971
0.736419048 0.409875189 -0.63140848 0.034514594 973 1.073465817
2.18418874 2.01361447 -0.93754437 974 0.130904221 1.882440008
1.85101055 0.112524893 976 -0.236681385 -0.09745533 0.1779313
2.08923366 977 0.904402612 0.936956925 0.87731788 0.102346515 978
2.201759817 2.123549573 3.7881607 2.358768953 980 1.784266982
1.845281076 3.42873622 -0.31098233 981 -0.225023329 0.087962898
-0.29053012 0.514272787 982 -0.231175318 -0.0159671 1.27391892
1.090487158 983 0.889215441 0.24321159 0.06877629 0.816247177 985
1.864634345 0.133647536 1.29803755 1.951226654 986 0.511450274
-2.33512445 -0.56246315 -0.42184152 987 0.847260813 0.368638185
0.4114346 0.219336109 988 1.596170102 1.592158381 0.30052357
0.283467897 993 -3.549941097 -2.6847861 -0.17502622 1.41034664 994
0.445802042 0.899738574 0.61059602 0.323194673
995 0.949498724 0.357111159 0.28371155 -0.14156488 998 2.197271885
1.578871826 0.90563334 1.056619658 998 2.197271885 1.578871826
0.90563334 1.056619658 1000 1.456120673 0.626173572 0.07683183
-0.43324035 1001 -0.440378333 0.918089245 0.03050609 -1.62235977
1002 0.819929066 0.459101825 -0.09227583 0.324342063 1003
1.64412453 -0.09343399 0.70197344 3.710273595 1004 0.796928207
0.459954079 -0.88538616 0.152000937 1005 0.044923203 -0.19994963
0.60082875 0.258347835 1006 -0.320452673 -0.33232662 -0.52315783
1.406273663 1007 4.040291133 3.474551355 3.57146797 3.565985043
1008 0.764519082 0.917635102 2.88258762 2.319622474 1009
-0.071112206 0.539362906 2.98048732 0.580423329 1010 -0.689737481
0.547928768 1.98805626 -0.76653376 1011 0.343668917 0.931501008
-0.05483722 0.395369857 1012 1.926713131 0.124849138 -0.09654906
1.126499382 1016 0.124247716 0.193102712 0.39003599 1.737670628
1017 0.131224136 0.21510779 -1.70996346 0.964902175 1018
0.499624069 0.962843507 0.77617619 -1.15296947 1019 0.813491983
0.322635656 0.02800396 0.599500927 1020 0.715468114 1.015469049
1.45994989 0.352548581 1021 -1.176339404 1.539767848 -0.14427147
1.389902738 1022 1.364966718 1.690570939 2.05914194 2.364375484
1023 2.154641091 0.800066339 0.85365652 0.965810338 1024
2.302280068 1.252164308 1.73414439 1.549538352 1025 1.878331515
1.287303121 0.11530502 1.132065786 1026 2.97722987 2.096441965
3.87172868 0.550274831 1027 2.474381478 1.950326182 3.81861867
1.366897355 1028 1.778414353 3.114931059 4.47690731 6.054314034
1029 3.672910795 2.760483725 3.26915034 3.042677588 1030
-0.604959715 -2.13584086 0.8687855 0.024144016 1031 2.012732245
2.293857161 0.54405555 1.261882121 1032 -1.086688867 0.953083194
2.92177054 0.876865185 1033 1.617520676 1.008017006 2.21183536
-0.1288484 1035 2.506372295 3.419954592 4.58206882 4.134341651 1036
-0.675805062 -0.15357004 0.94597719 3.966016669 1037 -0.275092569
-0.67687665 -0.52763797 1.489972106 1038 2.753559643 3.81185814
2.71344734 2.243351472 1039 0.65087433 0.026885305 -0.0153558
0.011870127 1040 0.141526548 -1.65455278 0.50170705 -1.90794 1041
0.458680435 -0.69730218 -0.48806249 0.586073092 1042 -0.513264812
-0.22001961 0.36339519 1.03208599 1043 -1.497887014 -1.76116109
-0.76634926 1.137002742 1045 2.863652137 1.96790869 0.43661485
-0.44756897 1046 0.981194248 1.73892162 2.21166953 2.738129365 1047
0.981194248 1.73892162 2.21166953 2.738129365 1051 0.70261974
-0.22197386 0.19710806 -2.37196477 1052 0.662126832 0.741436531
0.61672724 0.289359903 1053 0.87463644 -0.19717783 1.2664131
-0.4187507 1054 0.284558077 -1.46754925 -0.03124571 0.587227244
1055 0.885837831 -0.91907796 -0.45817355 -1.1936897 1057
0.790964847 1.387925398 -0.18370692 1.302393792 1058 -1.052897931
-0.85226912 0.90324527 -1.09684959 1059 -0.871565421 -0.17856476
1.51267137 -1.52734367 1060 3.311161199 3.074783921 2.10199297
1.822541682 1061 -0.655128061 0.497032417 0.92381279 -0.56348341
1062 -0.443129049 0.96200606 1.51641349 -0.22974864 1063
1.385675542 0.738759296 1.1677069 0.501211562 1064 1.670680003
-0.20756775 -0.73755051 -0.84924056 1065 1.43532227 1.656262941
-1.09448841 1.674272267 1066 1.670680003 1.284791101 0.14864516
-0.84985664 1067 2.237616041 0.345329863 -0.60597063 -0.71581056
1069 -0.24632881 -0.23975349 -0.01449288 0.574861147 1070
1.670680003 0.070165381 -0.64700996 -0.85055617 1071 -1.02687397
-0.36244273 0.13010074 0.535909448 1072 1.670680003 1.94609957
0.19633838 1.14825764 1073 2.237616041 1.438074134 0.31117554
-0.71786492 1074 -0.192632911 0.142411101 0.79310676 0.125548041
1075 0.909356011 0.368597887 1.03689838 1.001198751 1076
0.812238101 0.195908668 0.21564664 0.219336109 1077 0.325255266
1.131242708 -2.79377204 -0.62848261 1078 0.325255266 1.131242708
-2.79377204 -0.62848261 1079 0.85330799 -0.6855194 -0.90046979
-0.46415796 1081 -0.131519393 0.731836014 0.81604919 -1.29993979
1082 0.744770665 0.155243763 -1.8029919 1.023503542 1083
1.415726941 0.086297223 3.43559555 -0.12964168 1084 0.161304111
0.66712144 0.58401752 0.373809692 1085 -0.72863532 -0.2873027
2.21251376 3.003873022 1088 -1.1773616 -0.23258175 0.40529195
0.994988969 1089 2.769817302 1.661618789 3.97585272 1.059236597
1090 3.052627325 0.420821685 -0.57080756 1.751222205 1091
-3.379896722 -3.71174986 2.53586709 0.644702886 1093 0.72304265
1.667011476 2.53982093 2.7903213 1095 0.744219765 1.372184572
0.15852396 1.126053442 1097 4.407270402 2.670641491 5.02636153
5.361271976 1098 -1.85804837 -2.59071226 -0.46522239 0.655734646
1099 0.745797788 -0.20547378 4.27836342 4.646390386 1102
2.068748434 -0.24299896 0.07214682 -1.11758276 1104 1.018876287
0.025163067 -0.1106021 0.838914654 1105 2.387326861 3.865456674
2.2251199 0.728667998 1107 2.352582059 2.595496601 3.20492728
2.844590737 1110 0.302703712 0.599942142 -0.25637571 -0.03195517
1111 0.750930333 0.656784751 1.68326413 0.329846578 1112
-0.205527848 0.287622624 -0.00340777 0.59203719 1115 0.999825037
0.662221152 0.43571192 0.342558518 1116 0.873381263 1.544324176
0.13703728 -0.38172701 1117 -0.682983903 1.798204302 2.42110319
-0.39173951 1118 0.069769623 0.496895599 0.67857133 -0.14954441
1119 -0.671908804 -0.65984824 0.5238174 -0.85314111 1120
0.953790113 1.106552668 3.00006904 1.585038764 1121 -1.184630973
2.476138312 4.80971952 2.450646806 1122 -1.02687397 -0.36244273
0.13010074 0.535909448 1125 0.387315524 -0.36101406 1.14153708
-0.75303953 1126 1.021783831 -0.0070257 -0.14327539 3.954381426
1127 0.990592079 0.305612583 0.14155512 -0.29526854 1128
0.990592079 0.305612583 0.14155512 -0.29526854 1129 3.18966648
3.284362987 4.49398568 3.950809104 1131 1.650621055 1.545704806
2.37535081 1.259373143 1133 -1.519747805 -0.60804324 0.02746106
0.590708892 1134 0.815942067 -0.16126019 -0.54117238 0.613093526
1135 0.626973385 1.998305877 2.61706075 1.570404253 1136
2.812199484 1.353198146 2.05618426 1.869204406 1137 2.208307057
1.387136198 3.21521374 2.069795393 1138 1.670680003 1.316442078
0.14822999 -0.46985154 1139 1.408517438 0.890457374 1.24524408
0.685687797 1140 2.765860952 2.525539595 4.12464228 3.833744077
1141 -0.484394663 0.677713073 -0.22783646 -0.37267608 1142
2.54335679 4.298105601 3.36234238 2.684404542 1143 4.204367611
3.062126931 3.4234313 2.072899554 1144 2.479165229 3.226545885
4.65897152 4.952127235 1145 2.479158921 3.226545885 4.65897152
4.952127235 1146 0.774334025 1.075800774 1.06893156 1.011113116
1147 0.844648531 1.21935371 2.59138595 0.805938034 1148 2.906236436
1.550674121 3.56959167 2.832126896 1149 2.837627443 3.707154326
4.53384262 2.625871865
Particles
[0027] The malodor reduction materials can be practical for
inclusion in particles. The particles can comprise about 30% to
about 95% by weight of a carrier. The particles can comprise about
0.1% to about 30% by weight of a perfume. The particles can
comprise about 0.00025% to about 30% by weight of a malodor agent.
The particles can comprise about 0.001% to about 30% by weight of a
malodor agent. The malodor agent can comprise one or more reduction
materials having a Blocker Index of less than 3 or a Blocker Index
average of 3 to about 0.001. The particles can have a mass between
about 0.1 mg to about 5 g.
[0028] The malodor reduction materials can have a Fragrance
Fidelity Index of from about Fragrance Fidelity Index of less than
3, more preferable less than about 2.5 even more preferably less
than about 2 and still more preferably less than about 1 and most
preferably 0 or a Fragrance Fidelity Index average of 3 to about
0.001.
[0029] The particles can comprise a weight ratio of parts of
malodor agent to perfume of from about 1:20,000 to about 3000:1,
optionally from about 1:10,000 to about 1,000:1, optionally 5,000:1
to about 500:1, optionally from about 1:15 to about 1:1.
[0030] The particles can comprise one or more malodor reduction
materials having a log P greater than 3, preferably greater than 3
but less than 8, preferably said one or more malodor reduction
materials are selected from the group consisting of Table 1
materials 1; 2; 3; 7; 9; 10; 11; 13; 14; 18; 21; 22; 23; 25; 28;
29; 30; 31; 32; 33; 35; 36; 38; 39; 47; 48; 49; 50; 52; 57; 62; 63;
64; 67; 68; 69; 71; 74; 75; 76; 77; 78; 79; 80; 83; 85; 91; 92; 93;
100; 101; 102; 103; 104; 105; 109; 114; 119; 120; 122; 123; 128;
134; 135; 137; 140; 142; 145; 148; 149; 152; 153; 158; 159; 161;
162; 174; 175; 176; 177; 178; 182; 183; 184; 185; 186; 189; 192;
195; 196; 197; 206; 208; 209; 210; 211; 212; 215; 221; 227; 228;
229; 230; 231; 233; 234; 238; 242; 243; 244; 246; 252; 253; 260;
261; 263; 267; 269; 271; 274; 276; 277; 280; 285; 289; 290; 292;
293; 294; 295; 296; 300; 301; 303; 307; 316; 317; 318; 322; 324;
325; 328; 329; 330; 331; 333; 334; 335; 336; 338; 339; 342; 343;
344; 349; 352; 356; 358; 359; 360; 361; 362; 363; 364; 368; 369;
370; 371; 372; 378; 381; 385; 386; 388; 390; 391; 397; 398; 413;
414; 416; 418; 421; 424; 426; 428; 429; 432; 441; 444; 449; 453;
457; 459; 461; 462; 463; 465; 466; 467; 468; 470; 471; 473; 475;
478; 479; 480; 482; 484; 486; 487; 488; 497; 498; 501; 502; 503;
505; 519; 520; 521; 524; 529; 532; 534; 537; 541; 544; 548; 550;
552; 558; 559; 560; 561; 562; 563; 565; 566; 567; 568; 569; 570;
571; 572; 573; 574; 577; 578; 582; 584; 589; 591; 592; 594; 599;
600; 601; 603; 604; 606; 607; 608; 609; 610; 611; 613; 614; 615;
616; 618; 620; 621; 624; 625; 626; 628; 631; 632; 633; 635; 644;
650; 653; 659; 660; 661; 663; 671; 673; 674; 675; 676; 677; 678;
679; 680; 681; 684; 686; 691; 692; 693; 694; 696; 697; 698; 700;
702; 704; 706; 707; 708; 709; 710; 711; 712; 713; 714; 715; 716;
717; 718; 719; 720; 721; 722; 723; 724; 725; 726; 727; 731; 741;
746; 750; 752; 754; 757; 758; 763; 766; 769; 770; 771; 774; 775;
776; 778; 781; 782; 788; 791; 800; 802; 804; 806; 814; 821; 826;
827; 828; 831; 837; 839; 840; 849; 850; 852; 856; 866; 868; 869;
870; 871; 872; 873; 876; 877; 878; 879; 881; 884; 885; 886; 890;
892; 893; 894; 905; 908; 912; 913; 914; 916; 919; 920; 922; 925;
926; 927; 930; 933; 939; 941; 942; 943; 945; 947; 948; 950; 951;
953; 954; 959; 965; 967; 973; 978; 985; 988; 998; 1000; 1003; 1006;
1007; 1008; 1009; 1010; 1016; 1022; 1023; 1024; 1025; 1028; 1029;
1031; 1032; 1033; 1035; 1038; 1045; 1046; 1047; 1053; 1057; 1060;
1062; 1063; 1065; 1067; 1070; 1073; 1075; 1077; 1078; 1082; 1089;
1090; 1093; 1095; 1097; 1099; 1102; 1104; 1105; 1107; 1116; 1120;
1121; 1126; 1129; 1131; 1135; 1136; 1137; 1138; 1140; 1142; 1143;
1144; 1145; 1147; 1148; 1149; Table 2 materials 2; 23; 185; 227;
230; 246; 248; 343; 359; 565; 631; 659; 674; 678; 679; 715; 758;
1028; 1097; Table 3 materials 1; 9; 12; 13; 19; 20; 21; 24; 25; 27;
32; 38; 54; 55; 59; 64; 68; 71; 72; 79; 81; 83; 85; 100; 105; 109;
111; 114; 119; 133; 134; 135; 137; 140; 142; 147; 148; 150; 151;
152; 153; 154; 157; 159; 162; 178; 181; 189; 191; 192; 195; 197;
204; 211; 228; 231; 233; 234; 237; 238; 242; 246; 252; 264; 270;
273; 275; 277; 283; 285; 289; 290; 292; 293; 295; 300; 301; 302;
306; 308; 310; 312; 319; 322; 325; 331; 333; 334; 336; 338; 339;
344; 346; 354; 355; 356; 358; 361; 362; 363; 370; 371; 372; 378;
381; 385; 387; 388; 390; 412; 413; 418; 420; 428; 429; 432; 437;
438; 444; 447; 448; 454; 455; 457; 461; 465; 467; 472; 477; 478;
479; 480; 481; 482; 495; 496; 497; 502; 503; 504; 509; 510; 512;
515; 517; 518; 522; 525; 529; 535; 536; 537; 540; 541; 544; 550;
557; 558; 559; 560; 561; 568; 571; 572; 575; 589; 592; 594; 599;
600; 602; 604; 609; 619; 620; 625; 626; 633; 641; 644; 645; 650;
653; 662; 667; 672; 673; 675; 676; 681; 686; 687; 693; 697; 698;
700; 703; 704; 706; 707; 716; 717; 718; 722; 725; 744; 745; 746;
757; 769; 771; 779; 782; 799; 806; 819; 820; 827; 828; 836; 838;
839; 847; 850; 875; 878; 879; 880; 881; 888; 889; 890; 891; 893;
899; 900; 901; 903; 909; 912; 914; 920; 922; 930; 939; 940; 941;
945; 947; 948; 953; 954; 958; 959; 960; 965; 967; 971; 986; 987;
994; 995; 998; 1000; 1001; 1003; 1005; 1008; 1009; 1010; 1011;
1017; 1018; 1023; 1031; 1032; 1046; 1047; 1051; 1052; 1053; 1054;
1055; 1057; 1058; 1061; 1062; 1063; 1074; 1075; 1076; 1082; 1088;
1093; 1095; 1099; 1102; 1104; 1105; 1115; 1116; 1120; 1127; 1128;
1134; 1135; 1141; 1147;1148, 1149, and mixtures thereof; optionally
the malodor reduction materials are selected from the group
consisting of Table 1 materials 1; 2; 3; 7; 9; 10; 11; 13; 14; 18;
21; 22; 23; 25; 28; 29; 30; 31; 32; 33; 35; 36; 38; 39; 47; 48; 49;
50; 52; 57; 62; 63; 64; 67; 68; 69; 71; 74; 75; 76; 77; 78; 79; 80;
83; 85; 91; 92; 93; 100; 101; 102; 103; 104; 105; 109; 114; 119;
120; 122; 123; 128; 134; 135; 137; 140; 142; 145; 148; 149; 152;
153; 158; 159; 161; 162; 174; 175; 176; 177; 178; 182; 183; 184;
185; 186; 189; 192; 195; 196; 197; 206; 208; 209; 210; 211; 212;
215; 221; 227; 228; 229; 230; 231; 233; 234; 238; 242; 243; 244;
246; 252; 253; 260; 261; 263; 267; 269; 271; 274; 276; 277; 280;
285; 289; 290; 292; 293; 294; 295; 296; 300; 301; 303; 307; 316;
317; 318; 322; 324; 325; 328; 329; 330; 331; 333; 334; 335; 336;
338; 339; 342; 343; 344; 349; 352; 356; 358; 359; 360; 361; 362;
363; 364; 368; 369; 370; 371; 372; 378; 381; 385; 386; 388; 390;
391; 397; 398; 413; 414; 416; 418; 421; 424; 426; 428; 429; 432;
441; 444; 449; 453; 457; 459; 461; 462; 463; 465; 466; 467; 468;
470; 471; 473; 475; 478; 479; 480; 482; 484; 486; 487; 488; 497;
498; 501; 502; 503; 505; 519; 520; 521; 524; 529; 532; 534; 537;
541; 544; 548; 550; 552; 558; 559; 560; 561; 562; 563; 565; 566;
567; 568; 569; 570; 571; 572; 573; 574; 577; 578; 582; 584; 589;
591; 592; 594; 599; 600; 601; 603; 604; 606; 607; 608; 609; 610;
611; 613; 614; 615; 616; 618; 620; 621; 624; 625; 626; 628; 631;
632; 633; 635; 644; 650; 653; 659; 660; 661; 663; 671; 673; 674;
675; 676; 677; 678; 679; 680; 681; 684; 686; 691; 692; 693; 694;
696; 697; 698; 700; 702; 704; 706; 707; 708; 709; 710; 711; 712;
713; 714; 715; 716; 717; 718; 719; 720; 721; 722; 723; 724; 725;
726; 727; 731; 741; 746; 750; 752; 754; 757; 758; 763; 766; 769;
770; 771; 774; 775; 776; 778; 781; 782; 788; 791; 800; 802; 804;
806; 814; 821; 826; 827; 828; 831; 837; 839; 840; 849; 850; 852;
856; 866; 868; 869; 870; 871; 872; 873; 876; 877; 878; 879; 881;
884; 885; 886; 890; 892; 893; 894; 905; 908; 912; 913; 914; 916;
919; 920; 922; 925; 926; 927; 930; 933; 939; 941; 942; 943; 945;
947; 948; 950; 951; 953; 954; 959; 965; 967; 973; 978; 985; 988;
998; 1000; 1003; 1006; 1007; 1008; 1009; 1010; 1016; 1022; 1023;
1024; 1025; 1028; 1029; 1031; 1032; 1033; 1035; 1038; 1045; 1046;
1047; 1053; 1057; 1060; 1062; 1063; 1065; 1067; 1070; 1073; 1075;
1077; 1078; 1082; 1089; 1090; 1093; 1095; 1097; 1099; 1102; 1104;
1105; 1107; 1116; 1120; 1121; 1126; 1129; 1131; 1135; 1136; 1137;
1138; 1140; 1142; 1143; 1144; 1145; 1147; 1148; 1149; Table 2
materials 2; 23; 185; 227; 230; 246; 248; 343; 359; 565; 631; 659;
674; 678; 679; 715; 758; 1028; 1097 and mixtures thereof;
optionally the malodor reduction materials are selected from the
group consisting of Table 4 materials 7; 14; 39; 48; 183; 206; 212;
215; 229; 260; 261; 329; 335; 360; 441; 484; 487; 488; 501; 566;
567; 569; 570; 573; 574; 603; 616; 621; 624; 632; 663; 680; 684;
694; 696; 708; 712; 714; 726; 750; 775; 776; 788; 804; 872; 919;
927; 933; 978; 1007; 1022; 1024; 1029; 1035; 1038; 1060; 1089;
1107; 1129; 1131; 1136; 1137; 1140; 1142; 1143; 1144; 1145; 1148,
1149 Table 5 material 248 and mixtures thereof, optionally the
malodor reduction materials are selected from the group consisting
of Table 4 materials 261; 680; 788;1129, 1148, 1149 and mixtures
thereof. All of the aforementioned odor reduction materials have a
log P that is equal to or greater than 3, thus they deposit through
the wash especially well. The more selective lists of malodor
materials above can be practical for counteracting all of the key
malodors.
[0031] In one aspect of said product, said malodor reduction
materials are not selected from the group consisting of Table 1-3
malodor reduction materials 302; 288; 50; 157; 1017; 888; 64; 1054;
832; 375; 390; 745; 504; 505; 140; 1012; 498; 362; 103; 356; 1074;
908; 1127; 475; 918; 687; 611; 317; 9; 141; 550; 602; 913; 1005;
521; 10; 215; 370; 335; 378; 1121; 360; 565; 1136; 1129; 655; 369;
1065; 914; 757; 601; 478; 889; 891; 358; 973; 162; 554; 522; 312;
125; 26; 418; 92; 586; 1026; 218; 31; 828; 871; 829; 1066; 287;
269; 769; 701; 1118; 70; 946; 142; 109; 108 or mixtures
thereof.
[0032] The malodor reduction materials can be unencapsulated. The
malodor reduction materials can be encapsulated. The malodor agent
can comprise one or more encapsulated malodor reduction materials
and one or more unencapsulated malodor reduction materials. One or
more of the malodor reduction materials can be provided in a
delivery system. The delivery system can include a delivery system
selected from the group consisting of polymer-assisted delivery,
molecular assisted deliver, cyclodextrin deliver, starch
encapsulated delivery, zeolite delivery, inorganic delivery, and
combinations thereof.
[0033] The carrier can be or comprise a material selected from the
group consisting of water soluble inorganic alkali metal salt,
water-soluble alkaline earth metal salt, water-soluble organic
alkali metal salt, water-soluble organic alkaline earth metal salt,
water soluble carbohydrate, water-soluble silicate, water soluble
urea, and any combination thereof. Alkali metal salts can be, for
example, selected from the group consisting of salts of lithium,
salts of sodium, and salts of potassium, and any combination
thereof. Useful alkali metal salts can be, for example, selected
from the group consisting of alkali metal fluorides, alkali metal
chlorides, alkali metal bromides, alkali metal iodides, alkali
metal sulfates, alkali metal bisulfates, alkali metal phosphates,
alkali metal monohydrogen phosphates, alkali metal dihydrogen
phosphates, alkali metal carbonates, alkali metal monohydrogen
carbonates, alkali metal acetates, alkali metal citrates, alkali
metal lactates, alkali metal pyruvates, alkali metal silicates,
alkali metal ascorbates, and combinations thereof.
[0034] Alkali metal salts can be selected from the group consisting
of, sodium fluoride, sodium chloride, sodium bromide, sodium
iodide, sodium sulfate, sodium bisulfate, sodium phosphate, sodium
monohydrogen phosphate, sodium dihydrogen phosphate, sodium
carbonate, sodium hydrogen carbonate, sodium acetate, sodium
citrate, sodium lactate, sodium tartrate, sodium silicate, sodium
ascorbate, potassium fluoride, potassium chloride, potassium
bromide, potassium iodide, potassium sulfate, potassium bisulfate,
potassium phosphate, potassium monohydrogen phosphate, potassium
dihydrogen phosphate, potassium carbonate, potassium monohydrogen
carbonate, potassium acetate, potassium citrate, potassium lactate,
potassium tartrate, potassium silicate, potassium, ascorbate, and
combinations thereof. Alkaline earth metal salts can be selected
from the group consisting of salts of magnesium, salts of calcium,
and the like, and combinations thereof. Alkaline earth metal salts
can be selected from the group consisting of alkaline metal
fluorides, alkaline metal chlorides, alkaline metal bromides,
alkaline metal iodides, alkaline metal sulfates, alkaline metal
bisulfates, alkaline metal phosphates, alkaline metal monohydrogen
phosphates, alkaline metal dihydrogen phosphates, alkaline metal
carbonates, alkaline metal monohydrogen carbonates, alkaline metal
acetates, alkaline metal citrates, alkaline metal lactates,
alkaline metal pyruvates, alkaline metal silicates, alkaline metal
ascorbates, and combinations thereof. Alkaline earth metal salts
can be selected from the group consisting of magnesium fluoride,
magnesium chloride, magnesium bromide, magnesium iodide, magnesium
sulfate, magnesium phosphate, magnesium monohydrogen phosphate,
magnesium dihydrogen phosphate, magnesium carbonate, magnesium
monohydrogen carbonate, magnesium acetate, magnesium citrate,
magnesium lactate, magnesium tartrate, magnesium silicate,
magnesium ascorbate, calcium fluoride, calcium chloride, calcium
bromide, calcium iodide, calcium sulfate, calcium phosphate,
calcium monohydrogen phosphate, calcium dihydrogen phosphate,
calcium carbonate, calcium monohydrogen carbonate, calcium acetate,
calcium citrate, calcium lactate, calcium tartrate, calcium
silicate, calcium ascorbate, and combinations thereof. Inorganic
salts, such as inorganic alkali metal salts and inorganic alkaline
earth metal salts, do not contain carbon. Organic salts, such as
organic alkali metal salts and organic alkaline earth metal salts,
contain carbon. The organic salt can be an alkali metal salt or an
alkaline earth metal salt of sorbic acid (i.e., asorbate). Sorbates
can be selected from the group consisting of sodium sorbate,
potassium sorbate, magnesium sorbate, calcium sorbate, and
combinations thereof.
[0035] The carrier can be or comprise a material selected from the
group consisting of a water-soluble inorganic alkali metal salt, a
water-soluble organic alkali metal salt, a water-soluble inorganic
alkaline earth metal salt, a water-soluble organic alkaline earth
metal salt, a water-soluble carbohydrate, a water-soluble silicate,
a water-soluble urea, and combinations thereof. The carrier or
water soluble-soluble carrier can be selected from the group
consisting of sodium chloride, potassium chloride, calcium
chloride, magnesium chloride, sodium sulfate, potassium sulfate,
magnesium sulfate, sodium carbonate, potassium carbonate, sodium
hydrogen carbonate, potassium hydrogen carbonate, sodium acetate,
potassium acetate, sodium citrate, potassium citrate, sodium
tartrate, potassium tartrate, potassium sodium tartrate, calcium
lactate, water glass, sodium silicate, potassium silicate,
dextrose, fructose, galactose, isoglucose, glucose, sucrose,
raffinose, isomalt, xylitol, candy sugar, coarse sugar, and
combinations thereof. In one embodiment, the carrier or
water-soluble carrier can be sodium chloride. In one embodiment,
the carrier or water-soluble carrier can be table salt.
[0036] The carrier can be or comprise a material selected from the
group consisting of sodium bicarbonate, sodium sulfate, sodium
carbonate, sodium formate, calcium formate, sodium chloride,
sucrose, maltodextrin, corn syrup solids, corn starch, wheat
starch, rice starch, potato starch, tapioca starch, clay, silicate,
citric acid carboxymethyl cellulose, fatty acid, fatty alcohol,
glyceryl diester of hydrogenated tallow, glycerol, and combinations
thereof.
[0037] The carrier can be selected from the group consisting of
water soluble organic alkali metal salt, water soluble inorganic
alkaline earth metal salt, water soluble organic alkaline earth
metal salt, water soluble carbohydrate, water soluble silicate,
water soluble urea, starch, clay, water insoluble silicate, citric
acid carboxymethyl cellulose, fatty acid, fatty alcohol, glyceryl
diester of hydrogenated tallow, glycerol, polyethylene glycol, and
combinations thereof.
[0038] The carrier can be selected from the group consisting of
polyvinyl alcohol, modified polyvinyl alcohol, polyvinyl
pyrrolidone, polyvinyl alcohol/polyvinyl pyrrolidone, polyvinyl
alcohol/polyvinyl amine, partially hydrolyzed polyvinyl acetate,
polyalkylene oxide, polyethylene glycol, acrylamide, acrylic acid,
cellulose, alkyl cellulosics, methyl cellulose, ethyl cellulose,
propyl cellulose, cellulose ethers, cellulose esters, cellulose
amides, polyvinyl acetates, polycarboxylic acids and salts,
polyaminoacids or peptides, polyamides, polyacrylamide, copolymers
of maleic/acrylic acids, polysaccharides, starch, modified starch,
gelatin, alginates, xyloglucans, hemicellulosic polysaccharides,
xylan, glucuronoxylan, arabinoxylan, mannan, glucomannan,
galactoglucomannan, natural gums, pectin, xanthan, carrageenan,
locus bean, arabic, tragacanth, polyacrylates, sulfonated
polyacrylates, water-soluble acrylate copolymers, alkylhydroxy
cellulosics, methylcellulose, carboxymethylcellulose sodium,
modified carboxy-methylcellulose, dextrin, ethylcellulose,
propylcellulose, hydroxyethyl cellulose, hydroxypropyl
methylcellulose, maltodextrin, polymethacrylates, polyvinyl alcohol
copolymers, hydroxypropyl methyl cellulose, and mixtures thereof. A
water soluble carrier can be practical. The particles can comprise
from about 40% by weight to about 99% by weight of the particles of
the carrier. The carrier can be polyethylene glycol.
[0039] The precursor material can comprise more than about 40% by
weight polyethylene glycol having a weight average molecular weight
from about 2000 to about 13000. Polyethylene glycol (PEG) has a
relatively low cost, may be formed into many different shapes and
sizes, minimizes unencapsulated perfume diffusion, and dissolves
well in water. PEG comes in various weight average molecular
weights. A suitable weight average molecular weight range of PEG
includes from about 2,000 to about 13,000, from about 4,000 to
about 12,000, alternatively from about 5,000 to about 11,000,
alternatively from about 6,000 to about 10,000, alternatively from
about 7,000 to about 9,000, alternatively combinations thereof. PEG
is available from BASF, for example PLURIOL E 8000.
[0040] The particles can comprise more than about 40% by weight of
the particles of PEG. The particles can comprise more than about
50% by weight of the particles of PEG. The particles can comprise
more than about 60% by weight of the particles of PEG. The
particles may comprise from about 65% to about 99% by weight of the
composition of PEG. The particles may comprise from about 40% to
about 99% by weight of the composition of PEG.
[0041] Alternatively, the particles can comprise from about 40% to
less than about 90%, alternatively from about 45% to about 75%,
alternatively from about 50% to about 70%, alternatively
combinations thereof and any whole percentages or ranges of whole
percentages within any of the aforementioned ranges, of PEG by
weight of the particles.
[0042] Depending on the application, the particles can comprise
from about 0.5% to about 5% by weight of the particles of a
balancing agent selected from the group consisting of glycerin,
polypropylene glycol, isopropyl myristate, dipropylene glycol,
1,2-propanediol, and PEG having a weight average molecular weight
less than 2,000, and mixtures thereof.
[0043] The particles can comprise an antioxidant. The antioxidant
can help to promote stability of the color and or odor of the
particles over time between production and use. The particles can
comprise between about 0.01% to about 1% by weight antioxidant. The
particles can comprise between about 0.001% to about 2% by weight
antioxidant. The particles can comprise between about 0.01% to
about 0.1% by weight antioxidant. The antioxidant can be butylated
hydroxytoluene.
[0044] In addition to the PEG in the particles, the particles can
comprise perfume. The perfume can be unencapsulated perfume,
encapsulated perfume, or a combination of encapsulated perfume and
unencapsulated perfume.
[0045] The particles can comprise 0.1% to about 30% by weight
perfume, or optionally 0.1% to about 20% by weight perfume. The
perfume can be unencapsulated perfume, encapsulated perfume,
perfume provided by a perfume delivery technology, or a perfume
provided in some other manner Perfumes are generally described in
U.S. Pat. No. 7,186,680 at column 10, line 56, to column 25, line
22. The particles can comprise unencapsulated perfume and are
essentially free of perfume carriers, such as perfume
microcapsules. The particles can comprise perfume carrier materials
(and perfume contained therein). Examples of perfume carrier
materials are described in U.S. Pat. No. 7,186,680, column 25, line
23, to column 31, line 7. Specific examples of perfume carrier
materials may include cyclodextrin and zeolites.
[0046] The particles can comprise about 0.1% to about 20%,
alternatively about 1% to about 15%, alternatively 2% to about 10%,
alternatively combinations thereof and any whole percentages within
any of the aforementioned ranges, of perfume by weight of the
particles. The particles can comprise from about 0.1% by weight to
about 6% by weight of the particles of perfume. The perfume can be
unencapsulated perfume and or encapsulated perfume.
[0047] The perfume can comprise a perfume raw material having a
saturation vapor pressure greater than about 0.01 torr. Such a
vapor pressure can be practical for having the perfume be
sufficiently volatile to reach the consumers nose when the
particles are in use. The composition can comprise a perfume raw
material having a logP greater than about 3. Such a logP for the
perfume can be practical for having acceptable deposition onto a
laundry article, article of clothing. The perfume can comprise a
perfume raw material having a saturation vapor pressure greater
than about 0.01 torr and a logP greater than about 3. Such a
perfume can be practical for providing sufficient volatility for
the perfume to reach the consumers nose and sufficient deposition
on to a laundry article, article of clothing, textile, or the
like.
[0048] The particles can be free or substantially free of a perfume
carrier. The particles may comprise about 0.1% to about 20%,
alternatively about 1% to about 15%, alternatively 2% to about 10%,
alternatively combinations thereof and any whole percentages within
any of the aforementioned ranges, of unencapsulated perfume by
weight of the particles.
[0049] The particles can comprise unencapsulated perfume and
perfume microcapsules. The particles may comprise about 0.1% to
about 20%, alternatively about 1% to about 15%, alternatively from
about 2% to about 10%, alternatively combinations thereof and any
whole percentages or ranges of whole percentages within any of the
aforementioned ranges, of the unencapsulated perfume by weight of
the particles. Such levels of unencapsulated perfume can be
appropriate for any of the particles disclosed herein that have
unencapsulated perfume.
[0050] The particles can comprise unencapsulated perfume and a
perfume microcapsule but be free or essentially free of other
perfume carriers. The particles can comprise unencapsulated perfume
and perfume microcapsules and be free of other perfume
carriers.
[0051] The particles can comprise encapsulated perfume.
Encapsulated perfume can be provided as a plurality of perfume
microcapsules. A perfume microcapsule is perfume oil enclosed
within a shell. The shell can have an average shell thickness less
than the maximum dimension of the perfume core. The perfume
microcapsules can be friable perfume microcapsules. The perfume
microcapsules can be moisture activated perfume microcapsules.
[0052] The perfume microcapsules can comprise a
melamine/formaldehyde shell. Perfume microcapsules may be obtained
from Appleton, Quest International, or International Flavor &
Fragrances, or other suitable source. The perfume microcapsule
shell can be coated with polymer to enhance the ability of the
perfume microcapsule to adhere to fabric. This can be desirable if
the particles are designed to be a fabric treatment composition.
The perfume microcapsules can be those described in U.S. Patent
Pub. 2008/0305982.
[0053] The particles can comprise about 0.1% to about 20%,
alternatively about 1% to about 15%, alternatively 2% to about 10%,
alternatively combinations thereof and any whole percentages within
any of the aforementioned ranges, of encapsulated perfume by weight
of the particles.
[0054] The particles can comprise perfume microcapsules but be free
of or essentially free of unencapsulated perfume. The particles may
comprise about 0.1% to about 20%, alternatively about 1% to about
15%, alternatively about 2% to about 10%, alternatively
combinations thereof and any whole percentages within any of the
aforementioned ranges, of encapsulated perfume by weight of the
particles.
[0055] The particles may comprise dye. The particles may comprise
less than about 0.1%, alternatively about 0.001% to about 0.1%,
alternatively about 0.01% to about 0.02%, alternatively
combinations thereof and any hundredths of percent or ranges of
hundredths of percent within any of the aforementioned ranges, of
dye by weight of the particles. Examples of suitable dyes include,
but are not limited to, LIQUITINT PINK AM, AQUA AS CYAN 15, and
VIOLET FL, available from Milliken Chemical.
[0056] The particles may have a variety of shapes. The particles
may be formed into different shapes include tablets, pills,
spheres, and the like. A particle can have a shape selected from
the group consisting of spherical, hemispherical, compressed
hemispherical, lentil shaped, and oblong. Lentil shaped refers to
the shape of a lentil bean. Compressed hemispherical refers to a
shape corresponding to a hemisphere that is at least partially
flattened such that the curvature of the curved surface is less, on
average, than the curvature of a hemisphere having the same radius.
A compressed hemispherical particle 10 can have a ratio of height
(H) to maximum base dimension B of from about 0.01 to about 0.45,
as shown in FIG. 1, alternatively from about 0.1 to about 0.45,
alternatively from about 0.1 to about 0.4, alternatively from about
0.2 to about 0.3, the base being the substantially flat surface of
the compressed hemispherical particle. Oblong shaped refers to a
shape having a maximum dimension and a maximum secondary dimension
orthogonal to the maximum dimension, wherein the ratio of maximum
dimension to the maximum secondary dimension is greater than about
1.2. An oblong shape can have a ratio of maximum base dimension to
maximum minor base dimension greater than about 1.5. An oblong
shape can have a ratio of maximum base dimension to maximum minor
base dimension greater than about 2. Oblong shaped particles 10 can
have a maximum base dimension from about 2 mm to about 6 mm, a
maximum minor base dimension of from about 2 mm to about 6 mm
[0057] Individual particles 10 can have a mass from about 0.1 mg to
about 5 g, alternatively from about 10 mg to about 1 g,
alternatively from about 10 mg to about 500 mg, alternatively from
about 10 mg to about 250 mg, alternatively from about 0.95 mg to
about 125 mg, alternatively combinations thereof and any whole
numbers or ranges of whole numbers of mg within any of the
aforementioned ranges. In a plurality of particles 10, individual
particles 10 can have a shape selected from the group consisting of
spherical, hemispherical, compressed hemispherical, lentil shaped,
and oblong.
[0058] An individual particle may have a volume from about 0.003
cm.sup.3 to about 0.15 cm.sup.3. A number of particles 10 may
collectively comprise a dose for dosing to a laundry washing
machine or laundry wash basin. A single dose of the particles 10
may comprise from about 1 g to about 27 g. A single dose of the
particles 10 may comprise from about 5 g to about 27 g,
alternatively from about 13 g to about 27 g, alternatively from
about 14 g to about 20 g, alternatively from about 15 g to about 19
g, alternatively from about 18 g to about 19 g, alternatively
combinations thereof and any whole numbers of grams or ranges of
whole numbers of grams within any of the aforementioned ranges. The
individual particles 10 forming the dose of particles 10 that can
make up the dose can have a mass from about 0.95 mg to about 2 g.
The plurality of particles 10 can be made up of particles 10 having
different size, shape, and/or mass. The particles 10 in a dose can
have a maximum dimension less than about 1 centimeter.
[0059] Particles 10 that have occlusions of gas can be practical
for possibly multiple reasons. Such particles 10 can float in a
liquid. Particles 10 that have gas entrained therein are comprised
of gas inclusions and solid and or liquid materials. Since the
particles 10 have gas entrained therein, the particles 10 have a
density that is less than the density of the constitutive solid and
or liquid materials forming the particle. For instance if the
particle is formed of a constitutive material having a density of 1
g/cm.sup.3, and the particle is 10% by volume air, the density of
the particle is 0.90 g/cm.sup.3.
[0060] For particles 10 that are used as a laundry scent additive,
it can be practical that the particles 10 float in the wash
solution of a laundry washing machine. Providing particles 10 that
float in a the wash solution of a washing machine can provide the
benefit of enhanced perfume bloom during the washing cycle as
compared to particles 10 that sink and remain submerged during the
washing cycle. As the particles 10 dissolve in the wash,
encapsulated perfume and or unencapsulated perfume can be released
from the particles 10. Perfume bloom during the washing cycle can
be important to the consumer in that it can promote a more pleasant
experience to the person doing the laundry and can provide a
pleasant scent in the portion of the household in which laundering
is conducted.
[0061] Further, providing particles 10 that float and comprise
malodor reduction materials can help release the malodor reduction
materials. The malodor reduction materials can reduce the perceived
malodor existing in the laundry room from soiled laundry articles
that may have been positioned in the laundry room for a long period
of time and have developed malodors.
[0062] The particles 10 can be packaged together as a packaged
composition comprising a plurality of particles 10. The particles
10 can comprise a carrier, perfume, malodor agent, and occlusions
of gas. Without being bound by theory, occlusions of gas are
thought to provide for improved strength of the particles 10 as
compared to particles 10 having occlusions of gas having other
shapes. Spherical occlusions of gas might provide for improved
strength over non-spherical occlusions of gas.
[0063] Each of the particles 10 can have a density less than 1
g/cm.sup.3. Each of the particles 10 can have a density less than
about 0.95 g/cm.sup.3. Since the density of a typical washing
solution is about 1 g/cm.sup.3, it can be desirable to provide
particles 10 that have a density less than 1 g/cm.sup.3 or even
less than about 0.95 g/cm.sup.3. By having the density less than 1
g/cm.sup.3 or even less than about 0.95 g/cm.sup.3, it is thought
that with the typical manufacturing variability for particle making
processes, that nearly all of the particles 10 produced will have a
density less than about 1 g/cm.sup.3. Having nearly all of the
particles 10 have a density less than about 1 g/cm.sup.3 can be
desirable for providing for particles 10 that float in a wash
liquor. The perfume bloom and release of malodor reduction
materials that can occur from a wash liquor may be greater for
particles 10 that float as compared to particles 10 that sink.
[0064] Each of the particles 10 can have a mass between about 0.1
mg to about 5 g. The particles 10 can have a maximum dimension of
less than about 20 mm The particles 10 can have a maximum dimension
of less than about 10 mm The particles 10 having such a mass and
maximum dimension are thought to be readily dissolvable in
solutions such a wash solutions used in laundering clothing.
[0065] Each of the particles 10 can have a volume and the
occlusions of gas within the particles 10 can comprise between
about 0.5% to about 50% by volume of the particle, or even between
about 1% to about 20% by volume of the particle, or even between
about 2% to about 15% by volume of the particle, or event between
about 4% to about 12% by volume of the particle. Without being
bound by theory, it is thought that if the volume of the occlusions
of gas is too great, the particles 10 may not be sufficiently
strong to be packaged, shipped, stored, and used without breaking
apart in an undesirable manner.
[0066] The occlusions of gas can have an effective diameter between
about 1 micron to about 2000 microns, or even between about 5
microns to about 1000 microns, or even between about 5 microns to
about 200 microns, or even between about 25 to about 50 microns. In
general, it is thought that smaller occlusions of gas are more
desirable than larger occlusions of gas. If the effective diameter
of the occlusions of gas are too large, it is thought that the
particles 10 might not be sufficiently strong to be to be packaged,
shipped, stored, and used without breaking apart in an undesirable
manner The effective diameter is diameter of a sphere having the
same volume as the occlusion of gas. The occlusions of gas can be
spherical occlusions of gas.
[0067] The particles 10 can be formed into water soluble particles
10 that carry the perfume and the malodor reduction materials. The
particles 10 can be formed by a rotoforming process. The particles
10 can be formed on a SANDVIK ROTOFORM 3000 having a 750 mm wide 10
m long belt. The rotoforming cylinder can have 2 mm diameter
apertures set at 10 mm pitch in the cross machine direction and
9.35 mm pitch in the machine direction. The rotoforming cylinder be
set at about 3 mm above the belt. The belt speed and rotational
speed of the rotoforming cylinder can be set at 10 m/min A melt of
the precursor material for the particles 10 can be pumped to the
rotoforming cylinder at a rate of about 3.1 kg/min from a mixer. A
plate and frame heat exchanger can be set to control the
temperature to be about 50 degrees Celsius. Upstream of the stator
of the rotoformer, a gas feed line and mill can be provided to
provide for particles 10 having occlusions of gas if desired. The
mill can be a rotor-stator type mill. The mill can be a Quadro Z1
in-line mixer with a single stage of medium rotor stators, operated
at about 400 RPM. The mill and gas feed line can be combined in a
single unit. An Oakes Foamer (E.T. Oakes Corporation, 686 Old
Willets Path, Hauppauge, N.Y. 11788) 2MT1A continuous foamer) can
be used to provide the gas feed line, flow regulator, and mill in a
single unit.
[0068] A precursor material comprising the composition of the
particles 10 can be prepared by providing molten carrier into a
mixer, which can optionally be a batch mixer. The mixer can be
heated so as to help prepare the precursor material at the desired
temperature. Perfume can added to the molten carrier, optionally in
the mixer. Dye, if present, can be added to the mixer. Other
adjunct materials can be added to the precursor material if
desired. The precursor material can optionally be prepared by
in-line mixing or other known approaches for mixing materials.
Method of Use
[0069] Any of the particles 10 disclosed herein may be used in any
conventional manner For example, the particles 10 can be used to
treat a laundry article. For instance, about 1 g to about 100 g of
the particles 10 can be provided in a washing machine or laundry
wash basin. The laundry article can be washed in a wash liquor into
which the particles 10 are dissolved. The perfume and or malodor
reduction materials can form part of the wash liquor. For instance
all or a portion of the perfume or perfumes and or malodor
reduction material or materials can be dispersed within the wash
liquor, dissolved in the wash liquor, exist as a separate phase, or
otherwise exist in or be part of the wash liquor. During the wash
cycle, all or a portion of the perfume or perfumes and or malodor
reduction material or materials can be deposited on the laundry
article being washed. All or a portion of the perfume or perfumes
and or malodor reduction material may be transported from the wash
liquor into the head space above the wash liquor and can be further
dispersed into the surroundings of the washing machine or wash
basin. The bloom of the malodor reduction materials can help to
reduce the impact of malodor present in the room in which the
laundry article is washed. The particles 10 can be provided in a
fluid pervious package 20, as shown in FIG. 2. The particles 10 can
be provided in a water soluble package. The water soluble package
20 can comprise a water soluble film 30, as shown in FIG. 3. The
water soluble film can be a polyvinyl alcohol film. The fluid
pervious package 20 or water soluble package 20 can contain from
about 1 mg to about 100 g of the particles 10.
[0070] The laundry article can be treated with a quantity of
particles 10 that deliver at least 0.001 mg of malodor agent/kg of
laundry article, preferably from about 0.001 mg of malodor agent/kg
of laundry article to about 30 mg of malodor agent/kg of laundry
article, more preferably from about 0.1 mg of malodor agent/kg of
laundry article to about 20 mg of malodor agent/kg of laundry
article, most preferably from about 0.2 of malodor agent/kg of
laundry article to about 10 mg of malodor agent /kg of laundry
article.
[0071] The particles 10 can also be used to reduce malodor from a
laundry article by providing about 1 g to about 100 g of any of the
particles 10 disclosed herein in a fluid pervious package. The
fluid pervious package can be a pouch, as shown in FIG. 2. The
package can be placed proximal to the laundry article or the
package can be contacted with the laundry article. By placing the
package proximal to the laundry article or contacting the laundry
article with the package one or more of the perfume and the malodor
agent can be transferred from the particles 10, through the
package, and to the laundry article or the air-space around the
laundry article. The mass transfer can occur via diffusion,
dispersion, transport of portions of the particles 10 through the
package to the laundry article by contact.
Perfumes
[0072] The dispersed phase may comprise a perfume that may include
materials selected from the group consisting of perfumes such as
3-(4-t-butylphenyl)-2-methyl propanal,
3-(4-t-butylphenyl)-propanal,
3-(4-isopropylphenyl)-2-methylpropanal,
3-(3,4-methylenedioxyphenyl)-2-methylpropanal, and
2,6-dimethyl-5-heptenal, alpha-damascone, beta-damascone,
delta-damascone, beta-damascenone,
6,7-dihydro-1,1,2,3,3-pentamethyl-4(5H)-indanone,
methyl-7,3-dihydro-2H-1,5-benzodioxepine-3-one,
2-[2-(4-methyl-3-cyclohexenyl-1-yl)propyl]cyclopentan-2-one,
2-sec-butylcyclohexanone, and beta-dihydro ionone, linalool,
ethyllinalool, tetrahydrolinalool, and dihydromyrcenol.
Perfume Delivery Technologies
[0073] The compositions of the present invention may comprise one
or more perfume delivery technologies that stabilize and enhance
the deposition and release of perfume ingredients from treated
substrate. Such perfume delivery technologies can also be used to
increase the longevity of perfume release from the treated
substrate. Perfume delivery technologies, methods of making certain
perfume delivery technologies and the uses of such perfume delivery
technologies are disclosed in US 2007/0275866 A1.
[0074] In one aspect, the compositions of the present invention may
comprise from about 0.001% to about 20%, or from about 0.01% to
about 10%, or from about 0.05% to about 5%, or even from about 0.1%
to about 0.5% by weight of the perfume delivery technology. In one
aspect, said perfume delivery technologies may be selected from the
group consisting of: perfume microcapsules, pro-perfumes, polymer
particles, functionalized silicones, polymer assisted delivery,
molecule assisted delivery, fiber assisted delivery, amine assisted
delivery, cyclodextrins, starch encapsulated accord, zeolite and
inorganic carrier, and mixtures thereof:
[0075] In one aspect, said perfume delivery technology may comprise
perfume microcapsules formed by at least partially surrounding a
benefit agent with a wall material. Said benefit agent may include
materials selected from the group consisting of perfumes such as
3-(4-t-butylphenyl)-2-methyl propanal,
3-(4-t-butylphenyl)-propanal,
3-(4-isopropylphenyl)-2-methylpropanal,
3-(3,4-methylenedioxyphenyl)-2-methylpropanal, and
2,6-dimethyl-5-heptenal, alpha-damascone, beta-damascone,
delta-damascone, beta-damascenone,
6,7-dihydro-1,1,2,3,3-pentamethyl-4 (5H)-indanone,
methyl-7,3-dihydro-2H-1,5-benzodioxepine-3-one,
2-[2-(4-methyl-3-cyclohexenyl-1-yl)propyl]cyclopentan-2-one, 2-
sec-butylcyclohexanone, and beta-dihydroionone, linalool,
ethyllinalool, tetrahydrolinalool, and dihydromyrcenol. Suitable
perfume materials can be obtained from Givaudan Corp. of Mount
Olive, N.J., USA, International Flavors & Fragrances Corp. of
South Brunswick, N.J., USA, or Quest Corp. of Naarden, Netherlands.
In one aspect, the microcapsule wall material may comprise:
melamine, polyacrylamide, silicones, silica, polystyrene, polyurea,
polyurethanes, polyacrylate based materials, gelatin, styrene malic
anhydride, polyamides, and mixtures thereof. In one aspect, said
melamine wall material may comprise melamine crosslinked with
formaldehyde, melamine-dimethoxyethanol crosslinked with
formaldehyde, and mixtures thereof. In one aspect, said polystyrene
wall material may comprise polyestyrene cross-linked with
divinylbenzene. In one aspect, said polyurea wall material may
comprise urea crosslinked with formaldehyde, urea crosslinked with
gluteraldehyde, and mixtures thereof. In one aspect, said
polyacrylate based materials may comprise polyacrylate formed from
methylmethacrylate/dimethylaminomethyl methacrylate, polyacrylate
formed from amine acrylate and/or methacrylate and strong acid,
polyacrylate formed from carboxylic acid acrylate and/or
methacrylate monomer and strong base, polyacrylate formed from an
amine acrylate and/or methacrylate monomer and a carboxylic acid
acrylate and/or carboxylic acid methacrylate monomer, and mixtures
thereof. In one aspect, the perfume microcapsule may be coated with
a deposition aid, a cationic polymer, a non-ionic polymer, an
anionic polymer, or mixtures thereof. Suitable polymers may be
selected from the group consisting of: polyvinylformaldehyde,
partially hydroxylated polyvinylformaldehyde, polyvinylamine,
polyethyleneimine, ethoxylated polyethyleneimine, polyvinylalcohol,
polyacrylates, and combinations thereof. In one aspect, the
microcapsule may be a perfume microcapsule. In one aspect, one or
more types of microcapsules, for example two microcapsules types
having different benefit agents may be used.
[0076] In one aspect, said perfume delivery technology may comprise
an amine reaction product (ARP) or a thio reaction product. One may
also use "reactive" polymeric amines and or polymeric thiols in
which the amine and/or thiol functionality is pre-reacted with one
or more PRMs to form a reaction product. Typically the reactive
amines are primary and/or secondary amines, and may be part of a
polymer or a monomer (non-polymer). Such ARPs may also be mixed
with additional PRMs to provide benefits of polymer-assisted
delivery and/or amine-assisted delivery. Nonlimiting examples of
polymeric amines include polymers based on polyalkylimines, such as
polyethyleneimine (PEI), or polyvinylamine (PVAm). Nonlimiting
examples of monomeric (non-polymeric) amines include hydroxyl
amines, such as 2-aminoethanol and its alkyl substituted
derivatives, and aromatic amines such as anthranilates. The ARPs
may be premixed with perfume or added separately in leave-on or
rinse-off applications. In another aspect, a material that contains
a heteroatom other than nitrogen and/or sulfur, for example oxygen,
phosphorus or selenium, may be used as an alternative to amine
compounds. In yet another aspect, the aforementioned alternative
compounds can be used in combination with amine compounds. In yet
another aspect, a single molecule may comprise an amine moiety and
one or more of the alternative heteroatom moieties, for example,
thiols, phosphines and selenols. The benefit may include improved
delivery of perfume as well as controlled perfume release. Suitable
ARPs as well as methods of making same can be found in USPA
2005/0003980 A1 and U.S. Pat. No. 6,413,920 B1.
Test Methods
[0077] Malodor reduction materials may be separated from mixtures
and indentified by analytical methods that include GC-MS and/or
NMR.
Test Method for Determining Saturation Vapor Pressure (VP)
[0078] The saturation Vapor Pressure (VP) values are computed for
each PRM in the perfume mixture being tested. The VP of an
individual PRM is calculated using the VP Computational Model,
version 14.02 (Linux) available from Advanced Chemistry Development
Inc. (ACD/Labs) (Toronto, Canada) to provide the VP value at
25.degree. C. expressed in units of torr. The ACD/Labs' Vapor
Pressure model is part of the ACD/Labs model suite.
Test Method for Determining the Logarithm of the Octanol/Water
Partition Coefficient (logP)
[0079] The value of the log of the Octanol/Water Partition
Coefficient (logP) is computed for each PRM in the perfume mixture
being tested. The logP of an individual PRM is calculated using the
Consensus logP Computational Model, version 14.02 (Linux) available
from Advanced Chemistry Development Inc. (ACD/Labs) (Toronto,
Canada) to provide the unitless logP value. The ACD/Labs' Consensus
logP Computational Model is part of the ACD/Labs model suite.
Test Method for the Generation of Molecular Descriptors
[0080] In order to conduct the calculations involved in the
computed-value test methods described herein, the starting
information required includes the identity, weight percent, and
molar percent of each PRM in the perfume being tested, as a
proportion of that perfume, wherein all PRMs in the perfume
composition are included in the calculations. Additionally for each
of those PRMs, the molecular structure, and the values of various
computationally-derived molecular descriptors are also required, as
determined in accordance with the Test Method for the Generation of
Molecular Descriptors described herein.
[0081] For each PRM in a perfume mixture or composition, its
molecular structure is used to compute various molecular
descriptors. The molecular structure is determined by the graphic
molecular structure representations provided by the Chemical
Abstract Service ("CAS"), a division of the American Chemical
Society, Columbus, Ohio, U.S.A. These molecular structures may be
obtained from the CAS Chemical Registry System database by looking
up the index name or CAS number of each PRM. For PRMs, which at the
time of their testing are not yet listed in the CAS Chemical
Registry System database, other databases or information sources
may be used to determine their structures. For a PRM which has
potentially more than one isomer present, the molecular descriptor
computations are conducted using the molecular structure of only
one of the isomers, which is selected to represent that PRM. The
selection of isomer is determined by the relative amount of
extension in the molecular structures of the isomers. Of all the
isomers of a given PRM, it is the isomer whose molecular structure
that is the most prevalent which is the one that is selected to
represent that PRM. The structures for other potential isomers of
that PRM are excluded from the computations. The molecular
structure of the isomer that is the most prevalent is paired with
the concentration of that PRM, where the concentration reflects the
presence of all the isomers of that PRM that are present.
[0082] A molecule editor or molecular sketching software program,
such as ChemDraw (CambridgeSoft/PerkinElmer Inc., Waltham, Mass.,
U.S.A.), is used to duplicate the 2-dimensional molecular structure
representing each PRM. Molecular structures should be represented
as neutral species (quaternary nitrogen atoms are allowed) with no
disconnected fragments (e.g., single structures with no counter
ions). The winMolconn program described below can convert any
deprotonated functional groups to the neutral form by adding the
appropriate number of hydrogen atoms and will discard the counter
ion.
[0083] For each PRM, the molecular sketching software is used to
generate a file which describes the molecular structure of the PRM.
The file(s) describing the molecular structures of the PRMs is
subsequently submitted to the computer software program winMolconn,
version 1.0.1.3 (Hall Associates Consulting, Quincy, Mass., U.S.A.,
www.molconn.com), in order to derive various molecular descriptors
for each PRM. As such, it is the winMolconn software program which
dictates the structure notations and file formats that are
acceptable options. These options include either a MACCS SDF
formatted file (i.e., a Structure-Data File); or a Simplified
Molecular Input Line Entry Specification (i.e., a SMILES string
structure line notation) which is commonly used within a simple
text file, often with a ".smi" or ".txt" file name extension. The
SDF file represents each molecular structure in the format of a
multi-line record, while the syntax for a SMILES structure is a
single line of text with no white space. A structure name or
identifier can be added to the SMILES string by including it on the
same line following the SMILES string and separated by a space,
e.g.: C1=CC=CC=C1 benzene.
[0084] The winMolconn software program is used to generate numerous
molecular descriptors for each PRM, which are then output in a
table format. Specific molecular descriptors derived by winMolconn
are subsequently used as inputs (i.e., as variable terms in
mathematical equations) for a variety of computer model test
methods in order to calculate values such as: saturation Vapor
Pressure (VP); Boiling Point (BP); logarithm of the Octanol/Water
Partition Coefficient (logP); Odor Detection Threshold (ODT);
Malodor Reduction Value (MORV); and/or Universal Malodor Reduction
Value (Universal MORV) for each PRM. The molecular descriptor
labels used in the models' test method computations are the same
labels reported by the winMolconn program, and their descriptions
and definitions can be found listed in the winMolconn
documentation. The following is a generic description of how to
execute the winMolconn software program and generate the required
molecular structure descriptors for each PRM in a composition.
[0085] Computing Molecular Structure Descriptors using winMolconn:
[0086] 1) Assemble the molecular structure for one or more perfume
ingredients in the form of a MACCS Structure-Data File, also called
an SDF file, or as a SMILES file. [0087] 2) Using version 1.0.1.3
of the winMolconn program, running on an appropriate computer,
compute the full complement of molecular descriptors that are
available from the program, using the SDF or SMILES file described
above as input. [0088] a. The output of winMolconn is in the form
of an ASCII text file, typically space delimited, containing the
structure identifiers in the first column and respective molecular
descriptors in the remaining columns for each structure in the
input file. [0089] 3) Parse the text file into columns using a
spreadsheet software program or some other appropriate technique.
The molecular descriptor labels are found on the first row of the
resulting table. [0090] 4) Find and extract the descriptor columns,
identified by the molecular descriptor label, corresponding to the
inputs required for each model. [0091] a. Note that the winMolconn
molecular descriptor labels are case-sensitive.
MORV and Universal MORV Calculation
[0091] [0092] 1.) Input Molecular Descriptor values as determined
via the method above into the following four equations:
[0092] a)
MORV=-8.5096+2.8597.times.(dxp9)+1.1253.times.(knotpv)-0.34484.times.(e1C-
2O2)-0.00046231.times.(idw)+3.3509.times.(idcbar)+0.11158.times.(n2pag22)
b)
MORV=-5.2917+2.1741.times.(dxvp5)-2.6595.times.(dxvp8)+0.45297.times.-
(e1C2C2d)-0.6202.times.(c1C2O2)+1.3542.times.(CdCH2)+0.68105.times.(CaasC)-
+1.7129.times.(idcbar)
c)
MORV=-0.0035+0.8028.times.(SHCsatu)+2.1673.times.(xvp7)-1.3507.times.-
(c1C1C3d)+0.61496.times.(c1C1O2)+0.00403.times.(idc)-0.23286.times.(nd2).
d)
MORV=-0.9926-0.03882.times.(Sd0)+0.1869.times.(Ssp3OH)+2.1847.times.(-
xp7)+0.34344.times.(e1C3O2)-0.45767.times.(c1C2C3)+0.7684.times.(CKetone)
[0093] Equation a) relates a material's effectiveness in reducing
the malodor trans-3-methyl-2-hexenoic acid (carboxylic acid based
malodors) [0094] Equation b) relates a material's effectiveness in
reducing the malodor trimethylamine (amine based malodors) [0095]
Equation c) relates a material's effectiveness in reducing the
malodor 3-mercapto-3-methylhexan-1-ol (thiol based malodors) [0096]
Equation d) relates a material's effectiveness in reducing the
malodor skatole (indole based malodors) [0097] 2.) For purpose of
the present application, a material's MORV is the highest MORV
value from equations 1.)a) through 1.)d). [0098] 3.) If all
MORVvalues from equations 1.)a) through 1.)d) above are greater
than 0.5, the subject material has a Universal MORV.
Method for Assigning Fragrance Fidelity Index (FFI) and the Blocker
Index (BI) for a Malodor Reduction Material
[0099] Blocker materials suitable for use in particles 10 of the
present invention are chosen for their ability to decrease malodor,
while not interfering with perception of a fragrance. Material
selection is done by assigning two indices to a test sample
material from two reference scales in order to rank odor strengths.
The two reference scales are the Fragrance Fidelity Index (FFI)
scale and the Blocker Index (BI) scale. The FFI ranks the ability
of the test sample material to impart a perceivable odor which
could cause interference when combined with another fragrance and
the BI ranks the ability of the test sample material to reduce
malodor perception. The two methods for assigning the indices to a
test sample on the FFI and the BI reference scales are given
below.
Method for Assigning the FFI to Test Samples
[0100] The first step in the method for assigning an FFI to the
test samples on the FFI reference scale is to create the FFI
reference swatches. The swatches for the scale are created by
treating clean fabrics swatches with a known amount of a known
concentration of an ethyl vanillin solution. Fabric swatches for
this test are white knit polycotton (4 inch.times.4 inch) swatches
from EMC ordered as PC 50/50. The supplier is instructed to strip
the swatches first, stripping involves washing twice with a
fragrance-free detergent and rinsing three times.
Making the FFI Reference Swatches
[0101] Make three solutions of ethyl vanillin using a 50%/50%
EtOH/water as the diluent at the following concentrations: 25 ppm,
120 ppm and 1000 ppm. Pipette 13 .mu.L of each of the three
solutions into the middle of a clean swatch resulting in about a 1
cm diameter of the solution in the middle of the swatch. This will
create a sensory scale of three swatches with three different odor
levels based on the concentration of the solution pipetted onto the
swatch. After drying for 30 minutes in a vented hood, the swatches
are wrapped in aluminum foil to prevent odor contamination to the
treated swatch. A clean untreated swatch is also included as the
lowest anchor point of reference for odor strength on the FFI
scale. The FFI reference scale swatches should be used within 0.5
to 12 hours and discarded after 12 hours. The swatches are used as
scale anchor points when graders evaluate a test sample(s) and are
assigned a Fragrance Fidelity Index (FFI) as show in Table 7.
[0102] At least four perfumers/expert graders are used to rank the
ethyl vanillin swatches in the FFI scale. The perfumer/expert
grader needs to demonstrate adequate discrimination on the scale.
The perfumer/expert panel is asked to rank order swatches according
to a scale between 0 and 3. The panel must demonstrate statistical
differences between the swatches as seen in Table 7.
TABLE-US-00008 TABLE 7 Results FFI of reference swatches from six
perfumers/expert graders. Expert Grader FFI Swatch 1 2 3 4 5 6 Ave
Std Dev. 0 Control: stripped swatch NIL 0 0 0.5 0 0 0 0.08 0.2
ethyl vanillin 1 Stripped swatch with 13 .mu.L 25 ppm 0.5 0.5 0.5
1.5 0.5 1.0 0.75 0.4 ethyl vanillin 2 Stripped swatch with 13 .mu.L
2.0 1.5 1.5 2.0 2.0 2.0 1.8 0.2 120 ppm ethyl vanillin 3 Stripped
swatch with 13 .mu.L 3.0 2.0 3.0 3.0 3.0 3.0 2.8 0.4 1000 ppm ethyl
vanillin
[0103] The expert graders must demonstrate a full range of 2.5 over
the 4 swatches to be acceptably discriminating. Grader 2 in table 1
has a range of only 2 and is eliminated from the panel. The panel
of expert graders must also demonstrated the ability to
statistically discriminate between swatches in the scale.
TABLE-US-00009 TABLE 8 This table demonstrates acceptable expert
graders with an acceptable range and the panel meets the
requirement for discriminating statistics. Expert Grader Std FFI
Swatch 1 3 4 5 6 Ave Dev. 0 Control: stripped swatch 0 0.5 0 0 0
0.08 0.2 NIL ethyl vanillin 1 Stripped swatch with 13 .mu.L 0.5 0.5
1.5 0.5 1.0 0.80 0.4 25 ppm ethyl vanillin 2 Stripped swatch with
13 .mu.L 2.0 1.5 2.0 2.0 2.0 1.9 0.2 120 ppm ethyl vanillin 3
Stripped swatch with 13 .mu.L 3.0 3.0 3.0 3.0 3.0 3.0 0.0 1000 ppm
ethyl vanillin
[0104] The reference swatches represent the 0, 1, 2, and 3 FFIs on
the FFI reference scale, Table 9. The expert grader should
familiarize them self with the strength of the odor on the FFI
reference swatches by sniffing each one starting at 0 (the lowest
odor strength) and ending at 3 (the highest odor strength). This
should be done prior to evaluating the test sample material treated
swatch.
TABLE-US-00010 TABLE 9 Swatch treatments comprising the Fragrance
Fidelity Index (FFI) reference scale Swatch treatment Conc. of
ethyl vanillin FFI Clean fabric swatch w/13 .mu.L ethyl 1000 ppm
ethyl vanillin 3 vanillin Clean fabric swatch w/13 .mu.L ethyl 120
ppm ethyl vanillin 2 vanillin Clean fabric swatch w/13 .mu.L ethyl
25 ppm ethyl vanillin 1 vanillin Clean fabric swatch NIL ethyl
vanillin NIL ethyl vanillin 0
Making Swatches Treated with the Test Material
[0105] A clean swatch is treated with 13 .mu.L of a known
concentration of a test sample material resulting in an about 1 cm
of the solution on the clean swatch. Just like the reference
swatches, the test sample material swatch is dried in a vented hood
for 30 minutes and then wrapped in aluminum foil to prevent
contamination. The test material swatches and the FFI reference
swatches should be made within 2 hours of each other. The test
material swatch must be used within 0.5 to 12 hours and discarded
after 12 hours.
Assigning the FFI to the Test Material
[0106] At least two perfumers/expert graders are used to assign an
FFI grade to a test sample. The perfumer/expert grader smells the
test sample swatch by holding that swatch 1 inch from their nose
with their nose centered over the area where the test sample was
pipetted on to the fabric and then assigns the test sample an FFI
grade using the FFI reference scale anchor swatches as references.
The test sample swatch is assigned an FFI grade at or between
numbers on the FFI scale shown in Table 9. In cases where the test
sample material is graded greater than 3, the test material is not
a blocker material or the concentration of the material needs to be
lowered and reevaluated to determine if a lower level has a malodor
blocker functionality.
Method for Assigning the BI to Test Sample
[0107] The first step in the method for assigning a BI to a test
sample material on the BI reference scale is to create the BI
reference swatches. The swatches for the scale are created by
treating clean fabrics swatches with a known amount of a known
volume of isovaleric acid solution at a known concentration. Fabric
swatches for this test are white knit polycotton (4 inch.times.4
inch) swatches from EMC ordered as PC 50/50. The supplier is
instructed to strip the swatches first, stripping involves washing
twice with a fragrance-free detergent and rinsing three times.
Making the BI Reference Swatches
[0108] Make one solution of 0.08% isovaleric acid using 50%/50%
EtOH/water as the diluent. The BI scale contains one clean swatch
with no malodor applied. Three other swatches each have a different
volume of the 0.08% isovaleric acid applied. Pipette 2 .mu.L of the
0.08% isovaleric acid solution to one clean swatch, 5 .mu.L of the
0.08% isovaleric acid solution to the next swatch and 20 .mu.L of
isovaleric acid to the final clean swatch. These solutions are
pipetted to the middle of the swatches. This will create a sensory
scale of three swatches with three different odor levels based on
the volume of the 0.08% isovaleric acid solution pipetted onto the
swatch. After drying for 30 minutes in a vented hood, the swatches
are wrapped in aluminum foil to prevent odor contamination to the
treated swatch. A clean untreated swatch is also included as the
lowest anchor point of reference for malodor strength on the BI
scale. The BI reference scale swatches should be used within 0.5 to
12 hours and discarded after 12 hours. The swatches are used as
scale anchor points when graders evaluate a test sample(s) and are
assigned a Blocker Index (BI) as show in Table 12.
[0109] At least four perfumers/expert graders are used to rank the
isovaleric acid swatches in the BI scale. The perfumer/expert
grader needs to demonstrate adequate discrimination on the scale.
The perfumer/expert grader is asked to rank order swatches
according to a scale between 0 and 3. The panel of graders must
demonstrate statistical differences between the swatches as seen in
Table 10.
TABLE-US-00011 TABLE 10 Results from six perfumers/expert graders
to create the BI scale. Expert Grader Std BI Swatch 1 2 3 4 5 Ave
Dev. 0 Control: stripped swatch NIL 0 0 0 0 0 0 0 isovaleric acid 1
Stripped swatch with 2 .mu.L 0.5 2.0 1.0 1.0 0.5 1.0 0.5 0.08%
isovaleric acid 2 Stripped swatch with 5 .mu.L 2.0 2.5 2.0 2.0 2.0
2.1 0.2 0.08% isovaleric acid 3 Stripped swatch with 20 .mu.L 3.0
3.0 3.0 3.0 2.5 2.8 0.2 0.08% isovaleric acid
[0110] The expert graders must demonstrate a full range of 2.5 over
the 4 swatches to be acceptably discriminating. The panel of expert
graders must also demonstrated the ability to statistically
discriminate between swatches in the scale. Expert grader #2 did
not demonstrate the ability to discriminate between the swatches
and is eliminated from the panel, see Table 11.
TABLE-US-00012 TABLE 11 This table demonstrates acceptable expert
graders with an acceptable range and the panel meets the
requirement for discriminating statistics. Expert Grader Std BI
Swatch 1 3 4 5 Ave Dev. 0 Control: stripped swatch NIL 0 0 0 0 0 0
isovaleric acid 1 Stripped swatch with 2 .mu.L 0.08% 0.5 1.0 1.0
0.5 0.8 0.3 isovaleric acid 2 Stripped swatch with 5 .mu.L 0.08%
2.0 2.0 2.0 2.0 2.0 0 isovaleric acid 3 Stripped swatch with 20
.mu.L 0.08% 3.0 3.0 3.0 2.5 2.9 0.2 isovaleric acid
[0111] The reference swatches represent the 0, 1, 2, and 3 BIs on
the BI reference scale, Table 12. The expert grader should
familiarizes him/herself with the strength of the odor on the BI
reference swatches by sniffing each one starting at 0 (the lowest
odor strength) and ending at 3 (the highest odor strength). This
should be done prior to evaluating the swatch treated with the test
material.
TABLE-US-00013 TABLE 12 Swatch treatments comprising the Blocker
Index (BI) reference scale. Swatch/treatment Wt. of isovaleric acid
BI Clean fabric swatch w/20 .mu.L 0.08% 16 mg isovaleric acid 3
isovaleric acid Clean fabric swatch w/5 .mu.L 0.08% 4 mg isovaleric
acid 2 isovaleric acid Clean fabric swatch w/2 .mu.L 0.08% 1.6 mg
isovaleric acid 1 isovaleric acid Clean fabric swatch NIL
isovaleric acid NIL isovaleric acid 0
Making the Malodorous Swatch and Treating it with a Test
Material
[0112] To evaluate the BI, the test material is applied to a
malodorous swatch to determine how well the test material blocks
the malodor. The malodorous swatch is made by treating a clean
swatch with 20 .mu.L of a 0.08% solution of isovaleric acid. Dry
the malodorous swatch treated with isovaleric acid in a vented hood
for 30 minutes. After drying the malodorous swatch a known
concentration of test material solution, between 1 ppm and 100 ppm
is pipetted onto the malodorous swatch. Apply the test material
solution right on top of the spot where the isovaleric acid
solution was applied making an about 1 cm diameter spot. Just like
the BI reference swatches, the isovaleric acid+test material swatch
is dried in a vented hood for 30 minutes and then wrapped in
aluminum foil to prevent contamination. The isovaleric acid+test
material swatches and the BI reference swatches should be made
within 2 hrs of each other. The isovaleric acid+test material
swatch must be used between 1-12 hours just like the reference
swatches. It is sometimes necessary to evaluate several levels of
the test material between about 1 and about 100 ppm to determine
the BI.
Assigning the BI to the Test Material
[0113] At least two perfumers/ expert graders are used to assign
the BI to the test sample. The expert grader smells the isovaleric
acid+test material swatch by holding that swatch one inch from
their nose with their nose centered over the area where the test
sample was pipetted on to the fabric and then assigns the
isovaleric acid+test material swatch a BI based on ranking its odor
strength against the odor strength of the swatches in the BI
reference scale. The test sample swatch is assigned a BI at or
between numbers on the BI in table. In cases where the isovaleric
acid+test material swatch odor is greater than 3 on the BI
reference scale, this indicates the material is not a blocker or
the concentration of the test material needs to be lowered to
achieve its blocker functionality.
Malodor Reduction Materials with FFI and BI Grades Based on the
Aforementioned
TABLE-US-00014 TABLE Ref # CAS# log P Name Conc FFI BI 281
54830-99-8 3.11 3a,4,5,6,7,7a-hexahydro-4,7- 10 ppm 0 2.0
methano-1H-indenyl acetate 50 ppm 0.5 2.0 677 139504-68-0 3.75
1-((2-(tert- 10 ppm 0 2.3 butyl)cyclohexyl)oxy)butan-2-ol 50 ppm
1.8 2.0 962 55066-48-3 3.17 3-methyl-5-phenylpentan-1-ol 10 ppm 0
2.3 50 ppm 0.5 1.7 261 173445-65-3 3.29
3-(3,3-dimethyl-2,3-dihydro-1H- 10 ppm 0 1.8 inden-5-yl)propanal 50
ppm 1.3 1.3 1139 87731-18-8 2.11 (Z)-cyclooct-4-en-1-yl methyl 10
ppm 0 2.0 carbonate 50 ppm 1.0 2.7 4430-31-3 1.43
3,4,4a,5,6,7,8,8a-octahydrochromen- 10 ppm 0 2.0 2-one 50 ppm 0 2.0
204 40379-24-6 3.89 7-methyloctyl acetate 10 ppm 0 2.0 50 ppm 0 2.7
1005 93981-50-1 5.59 ethyl (2,3,6-trimethylcyclohexyl) 50 ppm 0.5
2.6 carbonate 391 106-33-2 5.73 Ethyl laurate 50 ppm 0.3 2.2 1148
1139-30-6 4.06 Caryophyllene Oxide 50 ppm 0.5 2.3 524 13877-91-3
4.31 3,7-Dimethyl-1,3,6-Octatriene(cis-.beta. 50 ppm 0 2.8
3338-55-4 ocimene 70%) 1149 23787-90-8 4
1,3,4,6,7,8alpha-hexahydro- 10 ppm 0 1.5
1,1,5,5-tetramethyl-2H-2,4alpha- 50 ppm 0.8 2.3
methanophtalen-8(5H)-one 112-42-5 4.62 Undecanol 50 ppm 0.8 2.3 174
112-53-8 5.17 1-dodecanol 50 ppm 0.5 2.3 98-52-2 2.78 4-tert-butyl
cyclohexane 10 ppm 0 2.0 50 ppm 0.3 2.0 109 112-39-0 6.41 Methyl
palmitate 10 ppm 2.0
Malodor Control Materials with Improved Performance at Lower
Levels.
[0114] Below are some non-limiting examples of preferred behavior
by which the malodor control material gives improved malodor
control at lower concentration. These nonlimiting data provide
additional compelling data that malodor is being blocked, not
masked.
TABLE-US-00015 Table Ref # CAS# Name Conc FFI BI N/A 68912-13-0
8,8-dimethyl- 10 ppm 0 1.5 3a,4,5,6,7,7a- 50 ppm 0 2.2
hexahydro-1H-4,7- methanoinden-6- yl propionate N/A TBD
4,8-dimethyl- 10 ppm 2.0 1-(methylethyl)- 50 ppm 0.3 2.2
7-oxybiciclo [4.3.0]nonane
Retesting Malodor Reduction Compounds at Lower Levels.
[0115] The example below demonstrates that while a malodor
reduction material could fail to demonstrate odor blocking
(BI>2.5) at a higher concentration it should be retested at a
lower concentration to determine if it passes.
TABLE-US-00016 Table Ref # CAS # Name Conc FFI BI N/A 173445-65-3
1H-Indene-5-propanal, 10 ppm 0 1.5 2,3-dihydro-3,3-dimethyl- 50 ppm
0.5 2.7
EXAMPLE 1
Compositions Comprising Malodor Reduction Materials
[0116] In the present invention blends enable more potent malodor
reduction because blends are useful at a higher % of the product
composition before becoming olfactively noticeable. Below are
non-limiting examples of malodor reduction agents.
TABLE-US-00017 % wt Active Component CAS# A B C D E
2,2,8,8-tetramethyl-octahydro-1H- 29461-14-1 35-45 15-25 5-20 10-30
15-25 2,4a-methanonapthalene-10-one 1H-Indene-ar-propanal,2,3-
300371-33-9 10-20 1-30 NIL 5-10 1-5 dihydro-1,1-dimethyl-
Hexadecanoic acid, (2E)-3,7- 3681-73-0 35-45 10-25 NIL 30-40 35-50
dimethyl-2,6-octadien-1-yl ester 1-Pentanol-3-methyl-5-phenyl
55066-48-3 10-20 10-25 2-10 5-17 10 4,7-Methano-1H-inden-5-ol,
171102-41-3 0-5 10-25 NIL 1-6 1-5 3a,4,5,6,7,7a-hexahydro-,
5-acetate 4,8-dimethyl-1-(methylethyl)-7- N/A 0-5 NIL NIL NIL 1-5
oxybiciclo [4.3.0]nonane (3Z)-3,7-dimethylocta-1,3,6-triene
3338-55-4 NIL NIL 10-20 2-5 NIL 1H-Indene-5-propanal, 2,3-
173445-65-3 NIL NIL NIL 7.5-16 1-15 dihydro-3,3-dimethyl-
3,4,4a,5,6,7,8,8a- 4430-31-3 NIL NIL NIL 3-7 1-15
octahydrochromen-2-one 1-(2-tert- 139504-68-0 NIL NIL NIL 0.25-1.5
NIL butylcyclohexyl)oxybutan-2-ol ethyl (2,3,6-trimethylcyclohexyl)
93981-50-1 NIL NIL 15-30 NIL 2 carbonate benzyl 2-hydroxypropanoate
2051-96-9 NIL NIL 2-5 NIL NIL (3,5-dimethylcyclohex-3-en-1-
67634-16-6 NIL NIL 5-30 NIL NIL yl)methanol 2-Dodecanol 10203-28-8
NIL 0.25-1 NIL 0.5-3 NIL
EXAMPLE 2
Compositions Comprising Malodor Reduction Agents
TABLE-US-00018 [0117] % wt Active Ingredient CAS # A B C B D E
(E)-1-(2,6,6-trimethyl-1- 127-42-4 4 8 2 8 3 2
cyclohex-2-enyl)pent-1-en-3- one ethyl dodecanoate 106-33-2 NIL 1
NIL 3 NIL NIL 3a,4,5,6,7,7a-hexahydro-1H- 68912-13-0 8 30 1 4 1 3.5
4,7-methanoinden-1-yl propanoate [1R-(1R*,4R*,6R*,10S*)]- 1139-30-6
NIL 0.3 2 0.5 NIL 0.5 4,12,12-trimethyl-9- methylene-5-
oxatricyclo[8.2.0.04,6]dodecane (8E)-cyclohexadec-8-en-1-one
3100-36-5 NIL 5 NIL 7 NIL NIL 3,5,5-trimethylhexyl acetate
58430-94-7 25 15 50 35 60 56 ethyl (2,3,6- 93981-50-1 NIL 1 NIL 5
NIL NIL trimethylcyclohexyl) carbonate 2,4-dimethyl-4,4a,5,9b-
27606-09-3 25 10 15 15 16 15 tetrahydroindeno[1,2- d][1,3]dioxine
2,2,7,7- 23787-90-8 8 9 5 7 5 5 tetramethyltricyclo[6.2.1.01,6]
undecan-5-one (3,5-dimethylcyclohex-3-en- 67634-16-6 NIL 0.7 NIL
0.5 NIL NIL 1-yl)methanol 3-(7,7-dimethyl-4- 33885-52-8 30 20 25 15
15 18 bicyclo[3.1.1]hept-3-enyl)- 2,2-dimethylpropanal Total 100
100 100 100 100 100
EXAMPLE 3
Malodor Reduction Agent
TABLE-US-00019 [0118] % wt. Active Ingredient CAS # A B C
5-Cyclohexadecen-1-One 37609-25-9 15.0 2.00 2.00
decahydro-2,2,7,7,8,9,9- 476332-65-7 0.005 0.01 0.01
heptamethylindeno(4,3a-b)furan 2,3-Dihydro-5,6-dimethoxy-2-(4-
33704-61-9 0.3 0.5 0.5 piperidinylmethylene)-1H-inden-1-one Cedryl
Methyl Ether 19870-74-7 6.0 10.0 4.0 Trans-4-Decenal 65405-70-1
0.005 0.002 0.002 Decyl Aldehyde 112-31-2 3.74 2.0 2.0 3-methyl
cyclopentadecenone 63314-79-4 0.4 1.0 1.0 Diphenyl Oxide 101-84-8
0.5 1.0 1.0 3a,4,5,6,7,7a-hexahydro-4,7-methano- 54830-99-8 5.0 8.0
8.0 1H-indenyl acetate 3a,4,5,6,7,7a-hexahydro-1H-4,7-
methanoinden-1-yl propanoate 68912-13-0 6.0 8.0 8.0
2-(5-methyl-2-propan-2-yl-8- 68901-32-6 10.0 15.0 15.0
bicyclo[2.2.2]oct-5-enyl)-1,3-dioxolane (E)-3,7-dimethyl-2,6-
3681-73-0 10.0 10.0 16.0 octadienylhexadecanoate Iso Nonyl Acetate
58430-94-7 6.65 8.0 3.0 2,2,7,7- 23787-90-8 10.0 8.0 8.0
tetramethyltricyclo[6.2.1.01,6]undecan-5- one (1-Methyl-2-(1,2,2-
198404-98-7 0.1 0.3 0.3 trimethylbicyclo[3.1.0]-hex-3-
ylmethyl)cyclopropyl)methanol Lauric Aldehyde 112-54-9 0.625 1.0
0.7 Methyl Iso Eugenol 93-16-3 18.000 10.0 13.0 Methyl
hexadecanoate 112-39-0 3.000 10.0 12.0 2,3-dihydro-1,1-1H-dimethyl-
300371-33-9 0.400 0.0 0.3 indene-ar-propanal
4-tert-butylcyclohexanol 98-52-2 0.400 0.1 0.1
2-isobutyl-4-hydroxy-4- 63500-71-0 1.600 2.0 2.0
methyltetrahydropyran Undecyl Aldehyde 112-44-7 1.725 2.888 1.888
Undecylenic Aldehyde 112-45-8 0.550 0.2 1.2 Total 100 100.0
100.0
EXAMPLE 4
Malodor Reducing Agent
TABLE-US-00020 [0119] % wt Ingredients CAS# Active
5-Cyclohexadecen-1-One 37609-25-9 2.6
2,2,7,7,8,9,9-heptamethyldecahydroindeno[4,3a- 647828-16-8 0.005
b]furan 1,1,2,3,3-pentamethyl-1,2,3,5,6,7-hexahydro- 33704-61-9 0.3
4H-inden-4-one (3R,3aR,6S,7S,8aS)-6-methoxy-3,6,8,8- 19870-74-7 6
tetramethyloctahydro-1H-3a,7-methanoazulene dodecanenitrile
2437-25-4 0.06 Trans 4-Decenal 65405-70-1 0.001 decanal 112-31-2 3
(E)-3-methylcyclopentadec-4-en-1-one 82356-51-2 0.4 oxydibenzene
101-84-8 0.5 Dipropylene Glycol 25265-71-8 0.054
3a,4,5,6,7,7a-hexahydro-4,7-methano-1H-inden- 54830-99-8 4 (5 and
6)-yl acetate 3-(2-ethylphenyl)-2,2-dimethylpropanal 67634-15-5 3
3-(3-isopropylphenyl)butanal 125109-85-5 0.6
8,8-dimethyl-3a,4,5,6,7,7a-hexahydro-1H-4,7- 68912-13-0 6
methanoinden-6-yl propionate
2-(8-isopropyl-6-methylbicyclo[2.2.2]oct-5-en- 68901-32-6 10
2-yl)-1,3-dioxolane d E)-3,7-dimethylocta-2,6-dien-1-yl palmitate
3681-73-0 10 7-methyloctyl acetate 40379-24-6 3
2,2,7,7-tetramethyltricyclo(6.2.1.0(1,6))- 23787-90-8 10
undecan-5-one (1-methyl-2-((1,2,2-trimethylbicyclo[3.1.0]hexan-
198404-98-7 0.1 3-yl)methyl)cyclopropyl)methanol dodecanal 112-54-9
0.6 Linalyl Benzoate 126-64-7 1.74 4-(tert-butyl)cyclohexyl acetate
32210-23-4 4 octahydro-1H-4,7-methanoindene-1-carbaldehyde
30772-79-3 0.26 methyl 2-(3-oxo-2-pentylcyclopentyl)acetate
24851-98-7 4.15 (Z)-1,2-dimethoxy-4-(prop-1-en-1-yl)benzene 93-16-3
18.23 Methyl Palmitate 112-39-0 3
3-(3,3-dimethyl-2,3-dihydro-1H-inden-5- 300371-33-9 0.4 yl)propanal
4-tert-butyl cyclohexanol 98-52-2 0.05 3-methyl-5-phenylpentan-1-ol
55066-48-3 3.5 2-isobutyl-4-methyltetrahydro-2H-pyran-4-ol
63500-71-0 1.6 (E)-4-methyldec-3-en-5-ol 81782-77-6 0.8 undecanal
112-44-7 1.7 undec-10-enal 112-45-8 0.35
EXAMPLE 5
Particles Comprising a Malodor Agent
[0120] Examples of particles 10 that comprise a malodor reduction
agent.
TABLE-US-00021 Blue Purple Green Formula Formula Formula Component
Function GCAS/CAS Wt % Wt % Wt % PEG 8000 Carrier 95229421 80.79%
80.85% 80.89% 1-((2-(tert- Malodor 139504-68-0 9.60% 9.60% 9.60%
butyl)cyclo- reduction hexyl)oxy)butan-2-ol Malodor reduction
Malodor 2.40% 2.40% 2.40% agent of Example 5 reduction Blue AH Dye
95559345 0.0021% Liquitint Violet FL Dye 92038834 0.015% Liquitint
Green 101 Dye 10053851 0.0011% Water Carrier 0.2079% 0.1350%
0.1089% Unencapsulated Perfume 7.00% 7.00% 7.00% Perfume
[0121] The dimensions and values disclosed herein are not to be
understood as being strictly limited to the exact numerical values
recited. Instead, unless otherwise specified, each such dimension
is intended to mean both the recited value and a functionally
equivalent range surrounding that value. For example, a dimension
disclosed as "40 mm" is intended to mean "about 40 mm."
[0122] Every document cited herein, including any cross referenced
or related patent or application is hereby incorporated herein by
reference in its entirety unless expressly excluded or otherwise
limited. The citation of any document is not an admission that it
is prior art with respect to any invention disclosed or claimed
herein or that it alone, or in any combination with any other
reference or references, teaches, suggests, or discloses any such
invention. Further, to the extent that any meaning or definition of
a term in this document conflicts with any meaning or definition of
the same term in a document incorporated by reference, the meaning
or definition assigned to that term in this document shall
govern.
[0123] While particular embodiments of the present invention have
been illustrated and described, it would be obvious to those
skilled in the art that various other changes and modifications can
be made without departing from the spirit and scope of the
invention. It is, therefore, intended to cover in the appended
claims all such changes and modifications that are within the scope
of this invention.
* * * * *
References