U.S. patent application number 15/407684 was filed with the patent office on 2017-05-18 for environmentally friendly lubricant for drilling purposes.
This patent application is currently assigned to Earth Lubricants, LLC. The applicant listed for this patent is Earth Lubricants, LLC. Invention is credited to Brent Deroo, Blaine Herdman, Craig Taylor.
Application Number | 20170137691 15/407684 |
Document ID | / |
Family ID | 58690461 |
Filed Date | 2017-05-18 |
United States Patent
Application |
20170137691 |
Kind Code |
A1 |
Deroo; Brent ; et
al. |
May 18, 2017 |
Environmentally Friendly Lubricant for Drilling Purposes
Abstract
Yellow grease is an inexpensive, environmentally friendly
commodity that can be used as a lubricant on oil drilling sites as
well as for many other applications. The present invention outlines
use of yellow grease and a lubricant on drilling sites.
Inventors: |
Deroo; Brent; (Greeley,
CO) ; Herdman; Blaine; (Greeley, CO) ; Taylor;
Craig; (Greeley, CO) |
|
Applicant: |
Name |
City |
State |
Country |
Type |
Earth Lubricants, LLC |
Brighton |
CO |
US |
|
|
Assignee: |
Earth Lubricants, LLC
Brighton
CO
|
Family ID: |
58690461 |
Appl. No.: |
15/407684 |
Filed: |
January 17, 2017 |
Related U.S. Patent Documents
|
|
|
|
|
|
Application
Number |
Filing Date |
Patent Number |
|
|
15279986 |
Sep 29, 2016 |
|
|
|
15407684 |
|
|
|
|
62256923 |
Nov 18, 2015 |
|
|
|
Current U.S.
Class: |
1/1 |
Current CPC
Class: |
C09K 2208/34 20130101;
C09K 8/035 20130101; E21B 21/062 20130101 |
International
Class: |
C09K 8/035 20060101
C09K008/035; E21B 21/06 20060101 E21B021/06 |
Claims
1. A method for providing an environmentally friendly, non-toxic,
and non-hazardous drilling lubricant to a drilling fluid, the
method comprising the steps of: a. collecting yellow grease from a
yellow grease producer; b. filtering non-grease components from the
yellow grease; c. optionally dewatering the yellow grease; d.
transporting the yellow grease to a drill site; e. mixing the
yellow grease with a drill fluid to form a drill fluid-yellow
grease mixture; and f. pumping the drill fluid-yellow grease
mixture into the drill hole.
2. A method for reuse of yellow grease, the method comprising the
steps of: a. transporting the yellow grease to a drill site; b.
mixing the yellow grease with a drill fluid to form a drill
fluid-yellow grease mixture; and c. pumping the drill fluid-yellow
grease mixture into the drill hole.
3. The method of claim 2 further comprising the steps of: a.
reclaiming the drill fluid-yellow grease mixture from the drill
hole; and b. separating the solids of the drill fluid-yellow grease
mixture from the liquid components.
4. The method of claim 2 further comprising: a. adding water to the
dewatered yellow grease; and b. optionally adding a freezing
temperature modifier.
5. The method of claim 4, wherein the temperature modifier is an
acid added to a concentration of about at least 0.1% to about
10%
6. The method of claim 4, wherein the temperature modifier is
citric acid added to a concentration of about at least 0.1% to
about 10%.
7. The method of claim 4, wherein the temperature modifier is
citric acid added to a concentration of about at least 0.2% to
about 5%.
8. The method of claim 4, wherein the temperature modifier is
citric acid added to a concentration of about at least 0.5% to
about 2%.
9. The method of claim 2, wherein the drill fluid-yellow grease
mixture contains at least twenty percent yellow grease.
10. The method of claim 2, wherein the drill fluid-yellow grease
mixture contains at least thirty percent yellow grease.
11. The method of claim 2, wherein the drill fluid-yellow grease
mixture contains at least forty percent yellow grease.
12. The method of claim 2, wherein the drill fluid-yellow grease
mixture contains at least fifty percent yellow grease.
13. The method of claim 2, wherein the drill fluid-yellow grease
mixture contains at least sixty percent yellow grease.
14. The method of claim 2, wherein the drill fluid-yellow grease
mixture contains at least eighty percent yellow grease.
15. The method of claim 2, wherein the yellow grease comprises less
than about fifteen percent fatty acids.
16. A drilling lubricant comprising a restaurant waste product.
17. The drilling lubricant of claim 16, wherein the waste product
is yellow grease.
18. The drilling lubricant of claim 17 wherein the waste product
comprises about ninety-percent fatty acids.
19. The drilling lubricant of claim 17 wherein the waste product
comprises less than about fifteen percent free fatty acids.
Description
REFERENCE TO RELATED APPLICATIONS
[0001] The present application claims priority to U.S. Prov. App.
No. 62/256,923 filed Nov. 18, 2015 and is a continuing application
claiming priority to U.S. patent application Ser. No. 15/279.986
filed Sep. 29, 2016.
FIELD OF INVENTION
[0002] The present invention relates to the field of oil and
natural gas drilling lubricants.
BACKGROUND OF THE INVENTION
[0003] The most common drill rigs used on drilling sites are the
rotary rig type as illustrated in FIG. 1. Multiple engines (power
supply) 101 supply power to hoisting equipment 102 that raises and
lowers the drill string or pipe 103 and rotating equipment 104 that
turns the drill string and the drill bit. The power supply also
drives the circulating equipment 104 or pumps drilling liquids 105
called mud down the hole into the annular space 106 to lubricate
the drill string and drill bit which are rotating in the hole. This
mud removes cuttings, loose bits of rock, and controls downhole
pressure to prevent blowouts, and also serves to cool and lubricate
the drill bit.
[0004] The conventional drill bit has three movable cones
containing teeth made of tungsten carbide steel and sometimes
industrial diamonds. The rotating cones are the cutting heads. The
downward force on the drill bit is the result of the weight of the
overhead drill stem, called collars, and drilling equipment on the
derrick which can amount to thousands of pounds. The entire pipe
and bit assembly rotate together in the hole.
[0005] While the bit buts the rock at the bottom of the hole,
surface pumps force drilling fluids 105 such as mud down the hole
through the inside of the drill pipe and out the bit. The fluid
lubricates and removes cuttings. The fluid, with the cuttings, then
flows out the center of the drill bit, and is forced back up the
outside of the drill pipe to the surface of the ground where it is
cleaned of debris and pumped back down the hole.
[0006] Drilling produces waste material including drilling mud,
rock cuttings, and salt water brine (highly concentrated salt
water). A reserve pond is often dug to temporarily hold the brine
and drilling mud. All waste materials must be moved off site and
sent to a properly licensed landfill for disposal.
SUMMARY OF THE PRIOR ART
[0007] The following documents and their synopsis are presented for
your review:
[0008] 1. U.S. Pat. No. 7,648,539 (2010) to Wetzel describes a
hybrid diesel fuel and method of manufacture. The fuel composes a
petroleum diesel fuel mixed into biosynthetic waste or virgin oil,
and a stabilizer. They hybrid fuel is 10-50% Diesel Number 1, or 2,
or Farm Diesel petroleum fuels and up to 90% filtered and polished
biosynthetic oil, measured by volume. The biosynthetic oil can
contain all levels of common commercial vegetable and animal fats
in any ratio.
[0009] 2. U.S. Pat. No. 8,846,583 (2014) describes a biodegradable
lubricant composition consisting in majority of fatty acid(s). The
lubricant is based on a hydrocarbon mineral oil of non-aromatic
oils (95-99%) and on fatty acids (C16-C22 monocarboxylic fatty
acids, optionally in mixture with resin acids) with not more than
1% by mass aromatic oil. Mineral oils can vary from light to heavy
with light oil containing shorter chain alkanes and heavier oils
containing longer chain alkanes.
[0010] 3. U.S. Pat. No. 3,791,975 (1974) describes a biodegradable
lubricant containing either straight chain alkyl compounds of
C1-C18, and straight chain ester of a fatty organic acid having C1
to C20.
[0011] 4. U.S. Pat. No. 5,691,285 (1997) describes a nontoxic
biodegradable lubricant composition including a nontoxic oil base
such as vegetable oil, preferably coin or olive oil, and a nontoxic
solvent such as ethanol, either ethyl alcohol, and/or a citrus
solvent (this could be citric acid), such as terpene, or
limonene.
[0012] 5. DE 101012255 A1 German Patent Application:
Semi-continuous production of biodegradable fatty acid ester
mixtures of use e.g. as a synthetic lubricant, etc. Waste materials
from drilling sites must be moved off site and sent to a properly
licensed landfill for disposal. The drilling fluid or mud is a big
portion of these waste materials. Drilling fluid generally serves
to cool and lubricate the drill bit, remove rock fragments or drill
cuttings and transport them to the surface, counter balance
pressure formation, and prevent uncased wellbores from caving in.
Drilling fluids may be water-based, oil-based, or synthetic. About
eighty percent of drilling fluids are water based using a base
fluid of fresh or salt water. These systems may incorporate natural
clays. Water based fluids may be either non-dispersed or dispersed
systems. The non-dispersed system are generally simple
gel-and-water systems used for tophole drilling. Natural clays are
incorporated into the mud as are high- and low-weight long-chain
polymers which provide viscosity and fluid-loss control. Dispersed
systems use chemical dispersants to deflocculate clay particles and
allow improved rheology control in higher-density muds and require
addition of caustic soda to maintain a high pH.
[0013] Additives to drilling fluids include weighting materials,
corrosion inhibitors, dispersants, flocculants, surfactants like
fatty acids and soaps to de-foam and emulsify mud, biocides to kill
bacteria and help reduce the souring of drilling mud, and fluid
loss reducers such starch and organic polymers that limit loss of
drilling mud to under-pressured or high-permeability
formations.
SUMMARY OF THE INVENTION
[0014] It is required that all drilling fluids be non-toxic to the
environment to reduce potential negative effects on the surrounding
area. To this end, it is one aspect of the invention to provide a
non-toxic environmentally friendly drilling lubricant to be used in
drilling mud. A second aspect of the invention is to provide a
low-cost drilling lubricant. Further, a method for producing a
low-cost environmentally friendly drilling fluid is presented
herein. Yet another aspect of the present invention is to provide a
drilling lubricant that is a re-used product.
[0015] A second aspect of the invention is to provide a low-cost
drilling lubricant. Further, a method for producing low-cost
environmentally friendly drilling fluid is presented herein.
[0016] Yet another aspect of the present invention is to provide a
drilling lubricant that is a re-used product.
[0017] Other aspects of this invention will appear from the
following description and appended claims, reference being made to
the accompanying drawings forming a part of this specification
wherein like reference characters designate corresponding parts in
the several views.
BRIEF DESCRIPTION OF THE DRAWINGS
[0018] FIG. 1. is an illustration of a drilling rig.
[0019] FIG. 2 is an illustration of a process for re-use of yellow
grease as a drilling lubricant, a process of the present
invention.
[0020] Before explaining the disclosed embodiment of the present
invention in detail, it is to be understood that the invention is
not limited in its application to the details of the particular
arrangement shown, since the invention is capable of other
embodiments. Also, the terminology used herein is for the purpose
of description and not of limitation.
DETAILED DESCRIPTION OF THE DRAWINGS
[0021] Yellow grease is a product produced from the recycling of
used cooking oil. Used cooking oil and yellow grease are collected
from restaurants and other food industry sites and is readily
available as a commodity product. It comes from the vegetable oil
restaurants and industries use in their deep fryers and food
processing. Yellow grease is also produced as a by-product of the
animal rendering process. Currently yellow grease is utilized as a
high energy additive in various livestock rations to increase the
calories animals ingest, in the manufacture of oleo chemicals
industry to manufacture soap, make-up, paint, rubber, and
detergents. Further, yellow grease may be used to produce biofuel.
There are two types of waste oil from food preparation. The
cleanest is the cooking oil or waste vegetable oil from frying
processes and is known as yellow grease. The second is "trap
grease" or brown grease. The trap grease is used to produce biofuel
and the waste oil or yellow grease and is sold at about nineteen to
thirty dollars/cwt (100 pounds), depending on the market and
location. A challenge for biofuel production is high free fatty
acids (FFA) in the grease products. The FFAs form soaps instead of
biodiesel. Generally yellow grease is less than fifteen percent
FFA, while brown grease will contain greater than fifteen
percent.
[0022] Yellow grease is non-toxic, non-hazardous, non-flammable,
and stable. No special equipment is needed to handle the product.
It is ninety percent fatty acids including mainly palmitic acid,
palmitoleic acid, steric acid, oleic acid, linoleic acid, linolenic
acid, and small percentages, less than one percent, lauric acid,
myrsitic acid, myristoleic acid, pentadecanoic acid, archidic acid,
and behenic acid. The Extracable Petroleum Hydrocarbons of yellow
grease were analyzed via EPA Method 8015. Results showed 32,000
mg/kg C10-C28 and 2500 mg/kg C28-C36.
[0023] The need for lubricant in drilling fluid or mud arrives from
several issues. First heat is generated from mechanical and
hydraulic forces at the bit and when the drill string rotates and
rubs against casing and wellbore. The lubricant cools and transfers
heat away from source and lower to temperature than bottom hole. If
this did not occur, the bit, drill string, and mud motors would
fail more rapidly. Lubrication is based on the coefficient of
friction. Oil- and synthetic-based muds generally lubricate better
than water-based mud (but the latter can be improved by the
addition of lubricants). Amount of lubrication provided by drilling
fluid depends on type & quantity of drill solids and weight
materials and chemical composition of system. Poor lubrication
causes high torque and drag, heat checking of the drill string, but
these problems are also caused by key seating, poor hole cleaning
and incorrect bottom hole assemblies design. Drilling fluids also
support portion of drill-string or casing through buoyancy. Suspend
in drilling fluid, buoyed by force equal to weight (or density) of
mud, so reducing hook load on the derrick. Weight that the derrick
can support is limited by mechanical capacity, in increasing the
depth the weight of drill-string and casing increase. When running
long, heavy string or casing, buoyancy possible to run casing
strings whose weight exceed a rig's hook load capacity.
[0024] The present invention is a lubricant, yellow grease, and
process for the re-use of yellow grease as a lubricant in drilling
processes. As shown in FIG. 2, the contained yellow grease 202 is
transported as by truck 201 from restaurants and industrial sites,
or having been bought as a commodity product, to a drilling site
203 where it can be mixed into the drilling fluid or mud 204 in a
truck 205 or in another vessel and pumped into the drill hole as
shown in FIG. 1. The reclaimed material can be stored on-site in a
pond 206, or a tank 207, and then loaded into a truck 201 or
transferred to an offsite facility for disposal 208.
[0025] As a non-limiting example the yellow grease is filtered to
remove food matter or other impurities. In addition, the yellow
grease may be dewatered. As an example the yellow grease may
comprise between twenty and eighty percent of the drilling mud by
weight, or even thirty to seventy percent by weight, or even
further forty to sixty percent by weight. As a further example,
about four to eight totes of yellow grease weighing 2,060 pounds
each may be added to six to ten totes of drilling fluid also
weighing 2,060pounds each. In a further example, six totes of
yellow grease may be added to eight totes of drilling mud. This
ratio may vary for different reasons including type of rock at the
drilling site. For instance, a hard granite rock may require more
lubricant.
[0026] Other ingredients may be added to the yellow grease to
increase useability. These may include acids, such as citric acid,
or other non-toxic acids or other components that may lower
freezing temperature of the solution or impart other useful
properties. Citric acid may be used for example added from 0.1% to
10% by weight of the yellow grease. Or the citric acid may be added
at 0.2% to 5%, or at 0.5-2% weight. In a further example the citric
acid may be added at 1% by weight. Further some water may be left
in the yellow grease or water may be added back to the filtered and
dewatered yellow grease at 0.1 to 10% by weight, or 0.2 to 5%, or
at 1% by weight.
[0027] In addition to the foregoing the inventors have established
that yellow grease is applicable to other lubrication needs. For
instance Cutting fluid is a type of coolant and lubricant designed
specifically for metalworking processes, such as machining and
stamping. There are various kinds of cutting fluids, which include
oils, oil-water emulsions, pastes, gels, aerosols (mists), and air
or other gases. They may be made from petroleum distillates, animal
fats, plant oils, water and air, or other raw ingredients.
Depending on context and on which type of cutting fluid is being
considered, it may be referred to as cutting fluid, cutting oil,
cutting compound, coolant, or lubricant.
[0028] Most metalworking and machining processes can benefit from
the use of cutting fluid, depending on workpiece material. Common
exceptions to this are cast iron and brass, which are machined dry.
The properties that are sought after in a good cutting fluid are
the ability to: keep the workpiece at a stable temperature
(critical when working to close tolerances). Very warm is OK, but
extremely hot or alternating hot-and-cold are avoided; maximize the
life of the cutting tip by lubricating the working edge and
reducing tip welding; ensure safety for the people handling it
(toxicity, bacteria, fungi) and for the environment upon disposal;
and prevent rust on machine parts and cutters.
[0029] Functions of yellow grease in this application may include
cooling and metal cutting. Metal cutting generates heat due to
friction and energy lost deforming the material. The surrounding
air has low thermal conductivity (conducts heat poorly) meaning it
is a poor coolant. Ambient air cooling is sometimes adequate for
light cuts and low duty cycles typical of maintenance, repair and
operations (MRO) or hobbyist work. Production work requires heavy
cutting over long time periods and typically produces more heat
than air cooling can remove. Rather than pausing production while
the tool cools, using liquid coolant removes significantly more
heat more rapidly, and can also speed cutting and reduce friction
and tool wear. However, it is not just the tool which heats up but
also the work surface. Excessive temperature in the tool or work
surface can ruin the temper of both, soften either to the point of
uselessness or failure, burn adjacent material, create unwanted
thermal expansion or lead to unwanted chemical reactions such as
oxidation.
[0030] Besides cooling, cutting fluids also aid the cutting process
by lubricating the interface between the tool's cutting edge and
the chip. By preventing friction at this interface, some of the
heat generation is prevented. This lubrication also helps prevent
the chip from being welded onto the tool, which interferes with
subsequent cutting. Extreme pressure additives are often added to
cutting fluids to further reduce tool wear.
[0031] Delivery methods for yellow grease in this application may
include but would not be limited to the following: any conceivable
method of applying cutting fluid (e.g., flooding, spraying,
dripping, misting, brushing) can be used, with the best choice
depending on the application and the equipment available. For many
metal cutting applications the ideal has long been high-pressure,
high-volume pumping to force a stream of liquid (usually an
oil-water emulsion) directly into the tool-chip interface, with
walls around the machine to contain the splatter and a sump to
catch, filter, and recirculate the fluid. This type of system is
commonly employed, especially in manufacturing. It is often not a
practical option for MRO or hobbyist metal cutting, where smaller,
simpler machine tools are used. Fortunately, it is also not
necessary in those applications, where heavy cuts, aggressive
speeds and feeds, and constant, all-day cutting are not vital. As
technology continually advances, the flooding paradigm is no longer
always the clear winner. It has been complemented since the 2000s
by new permutations of liquid, aerosol, and gas delivery, such as
minimum quantity lubrication and through-the-tool-tip cryogenic
cooling (detailed below).
[0032] Through-tool coolant systems, also known as through-spindle
coolant systems, are systems plumbed to deliver coolant through
passages inside the spindle and through the tool, directly to the
cutting interface. Many of these are also high-pressure coolant
systems, in which the operating pressure can be hundreds to several
thousand psi (1 to 30 MPa)--pressures comparable to those used in
hydraulic circuits. High-pressure through-spindle coolant systems
require rotary unions that can withstand these pressures. Drill
bits and endmills tailored for this use have small holes at the
lips where the coolant shoots out. Various types of gun drills also
use similar arrangements.
[0033] Yet another application for yellow grease is as a concrete
release agent in the concrete construction industry. Form release
agents prevent the adhesion of freshly placed concrete to the
forming surface, usually plywood, overlaid plywood, steel or
aluminum. In this application, there are two types of release
agents available: barrier and reactive. Barrier release agents
prevent adhesion by the development of a physical film or barrier
between the forming surface and the concrete.
[0034] Reactive release agents are chemically active and work by
the process of a chemical reaction between the release agent and
the free limes available in fresh concrete. A soapy film is created
which prevents adhesion. Because it is a chemically reactive
process, there is generally little to no residue or unreacted
product left on the forming surface or concrete which provides for
a cleaner process. Therefore, yellow grease serves as a release
agent. It is applied to the forming surface by spraying.
[0035] Even further, the yellow grease described herein is used as
a dust control agent. Most governmental EPAs, including the United
States Environmental Protection Agency (EPA) mandate that
facilities that generate dust, minimize or mitigate the production
of dust in their operation. The most frequent dust control
violations occur at new residential housing developments in urban
areas. United States Federal law requires that construction sites
obtain permits to conduct earth moving, clearing of areas, to
include plans to control dust emissions when the work is being
carried out. Control measures include such simple practices as
spraying construction and demolition sites with water, and
preventing the tracking of dust onto adjacent roads.
[0036] Some of the issues include: reducing dust related health
risks that include allergic reactions, pneumonia and asthmatic
attacks; improving visibility and road safety; providing cleaner
air, cleaner vehicles and cleaner homes and promoting better
health; improving crop productivity in agriculture; reducing
vehicle maintenance costs by lowering the levels of dust that clog
filters, bearings and machinery; reducing driver fatigue,
maintenance on suspension systems and improving fuel economy; and
increasing cumulative effect--each new application builds on
previous residuals reducing re-application rate while improving
performance.
[0037] US federal laws require dust control on sources such as
vacant lots, unpaved parking lots, and unpaved roads. Dust in such
places may be suppressed by mechanical methods, including paving or
laying down gravel, or stabilizing the surface with water,
vegetable oils or other dust suppressants, or by using water
misters to suppress dust that is already airborne. Therefore,
yellow grease serves as a perfect dust control agent.
[0038] Although the present invention has been described with
reference to the disclosed embodiments, numerous modifications and
variations can be made and still the result will come within the
scope of the invention. No limitation with respect to the specific
embodiments disclosed herein is intended or should be inferred.
Each apparatus embodiment described herein has numerous
equivalents.
* * * * *