U.S. patent application number 15/407477 was filed with the patent office on 2017-05-04 for malodor reduction compositions.
The applicant listed for this patent is The Procter & Gamble Company. Invention is credited to Jonathan Robert CETTI, Gayle Marie FRANKENBACH, Judith Ann HOLLINGSHEAD, Steven Anthony HORENZIAK, Zaiyou LIU, Prakash J. MADHAV, Christine Marie READNOUR, David Thomas STANTON.
Application Number | 20170119917 15/407477 |
Document ID | / |
Family ID | 54256860 |
Filed Date | 2017-05-04 |
United States Patent
Application |
20170119917 |
Kind Code |
A1 |
FRANKENBACH; Gayle Marie ;
et al. |
May 4, 2017 |
MALODOR REDUCTION COMPOSITIONS
Abstract
The present invention relates to malodor reduction compositions
and methods of making and using same. The malodor reduction
compositions are suitable for use in a variety of applications,
including use in consumer products, for example, air freshening
compositions, laundry detergents, fabric enhancers, surface
cleaners, beauty care products, dish care products, diapers,
feminine protection articles, and plastic films for garbage bags.
Such malodor control technologies do not unduely interfere with the
scent of the perfumed or unperfumed situs that is treated with the
malodor control technology.
Inventors: |
FRANKENBACH; Gayle Marie;
(Cincinnati, OH) ; HOLLINGSHEAD; Judith Ann;
(Batavia, OH) ; HORENZIAK; Steven Anthony;
(Cincinnati, OH) ; MADHAV; Prakash J.;
(Maineville, OH) ; STANTON; David Thomas;
(Hamilton, OH) ; READNOUR; Christine Marie; (Fort
Mitchell, KY) ; LIU; Zaiyou; (West Chester, OH)
; CETTI; Jonathan Robert; (Mason, OH) |
|
Applicant: |
Name |
City |
State |
Country |
Type |
The Procter & Gamble Company |
Cincinnati |
OH |
US |
|
|
Family ID: |
54256860 |
Appl. No.: |
15/407477 |
Filed: |
January 17, 2017 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
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14864927 |
Sep 25, 2015 |
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15407477 |
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62055844 |
Sep 26, 2014 |
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62143862 |
Apr 7, 2015 |
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Current U.S.
Class: |
1/1 |
Current CPC
Class: |
A61K 8/11 20130101; C08K
5/0008 20130101; A61L 9/127 20130101; A61L 15/28 20130101; A61Q
19/10 20130101; C11D 17/042 20130101; A61K 8/37 20130101; A61Q
19/00 20130101; A61K 8/498 20130101; C11D 3/0068 20130101; A61K
8/731 20130101; A61K 2800/5922 20130101; A61K 8/58 20130101; A61Q
13/00 20130101; C11D 3/30 20130101; C11D 3/001 20130101; B01J 20/24
20130101; C11D 17/0043 20130101; G06F 17/11 20130101; A61L 2/18
20130101; A61K 8/494 20130101; C11B 9/0053 20130101; C11B 9/008
20130101; C11D 3/505 20130101; C11B 9/0015 20130101; C11B 9/003
20130101; A61L 9/012 20130101; C11B 9/0042 20130101; A61K 8/36
20130101; C11B 9/0019 20130101; C11D 3/184 20130101; G06F 30/23
20200101; C11D 3/43 20130101; C11D 3/50 20130101; G06F 17/10
20130101; D06B 1/02 20130101; A61L 9/01 20130101; G06Q 99/00
20130101; A61L 9/03 20130101; C11B 9/0076 20130101; G16C 10/00
20190201; C11B 9/0061 20130101; A61K 8/8152 20130101; A61L 2300/62
20130101; A61K 8/4966 20130101; C11D 3/2096 20130101; C11B 9/0049
20130101; A61K 8/35 20130101; A61K 8/34 20130101; A61K 8/4926
20130101; A61K 2800/592 20130101; C11D 3/2072 20130101; A61K 8/31
20130101; A61K 8/4973 20130101; A61K 2800/56 20130101; C11B 9/0034
20130101; C11D 3/222 20130101; C11D 3/2034 20130101; C11D 3/2093
20130101; A61L 15/20 20130101; C11D 17/06 20130101; A61K 8/361
20130101; A61K 8/342 20130101; A61L 15/46 20130101; A61Q 5/02
20130101; C11D 11/0017 20130101; A61L 2209/21 20130101; G16C 20/40
20190201; C11D 3/2068 20130101; C11B 9/0038 20130101; A61Q 15/00
20130101; C11D 3/2079 20130101; C11D 17/047 20130101; A61K 8/368
20130101; A61K 8/33 20130101; A61L 9/122 20130101; C11B 9/0092
20130101 |
International
Class: |
A61L 9/01 20060101
A61L009/01; A61L 15/46 20060101 A61L015/46; A61Q 19/10 20060101
A61Q019/10; A61Q 15/00 20060101 A61Q015/00; A61K 8/35 20060101
A61K008/35; A61K 8/49 20060101 A61K008/49; A61K 8/33 20060101
A61K008/33; A61K 8/36 20060101 A61K008/36; A61K 8/37 20060101
A61K008/37; A61K 8/34 20060101 A61K008/34; A61Q 13/00 20060101
A61Q013/00; C11B 9/00 20060101 C11B009/00; C11D 3/00 20060101
C11D003/00; C11D 11/00 20060101 C11D011/00; C11D 3/50 20060101
C11D003/50; C11D 17/04 20060101 C11D017/04; C11D 17/00 20060101
C11D017/00; C08K 5/00 20060101 C08K005/00; G06F 17/11 20060101
G06F017/11; A61L 9/012 20060101 A61L009/012 |
Claims
1. A malodor reduction composition comprising, based on total
malodor reduction composition weight: a) from about 2% to about 8%
(E)-1-(2,6,6-trimethyl-1-cyclohex-2-enyl)pent-1-en-3-one; b) from
about 0% to about 3% ethyl dodecanoate; c) from about 1% to about
30% 3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-1-yl propanoate; d)
from about 0% to about 2%
[1R-(1R*,4R*,6R*,10S*)]-4,12,12-trimethyl-9-methylene-5-oxatricyclo[8.2.0-
.04,6]dodecane; e) from about 0% to about 7%
(8E)-cyclohexadec-8-en-1-one; f) from about 15% to about 60%
3,5,5-trimethylhexyl acetate; g) from about 0% to about 5% ethyl
(2,3,6-trimethylcyclohexyl) carbonate; h) from about 10% to about
25% 2,4-dimethyl-4,4a,5,9b-tetrahydroindeno[1,2-d][1,3]dioxine; i)
from about 5% to about 9%
2,2,7,7-tetramethyltricyclo[6.2.1.01,6]undecan-5-one; j) from about
0% to about 0.7% (3,5-dimethylcyclohex-3-en-1-yl)methanol; and k)
from about 15% to about 30%
3-(7,7-dimethyl-4-bicyclo[3.1.1]hept-3-enyl)-2,2-dimethylpropanal
with the proviso that the sum of the elements a) through k) does
not exceed 100%.
2. A malodor reduction composition according to claim 1 comprising
from about 0.3% to about 2%
[1R-(1R*,4R*,6R*,10S*)]-4,12,12-trimethyl-9-methylene-5
oxatricyclo[8.2.0.04,6]dodecane.
3. A malodor reduction composition comprising, based on total
composition weight, from 0.0001% to 100% of a malodor reduction
composition according to claim 1 and an adjunct material, said
composition being a consumer product.
4. A malodor reduction composition according to claim 3 wherein
said adjunct material is selected from the group consisting of
surfactants, builders, chelating agents, dye transfer inhibiting
agents, dispersants, enzymes, and enzyme stabilizers, catalytic
materials, bleach activators, hydrogen peroxide, sources of
hydrogen peroxide, preformed peracids, polymeric dispersing agents,
clay soil removal/anti-redeposition agents, brighteners, suds
suppressors, dyes, hueing dyes, perfumes, perfume delivery systems,
structure elasticizing agents, carriers, structurants, hydrotropes,
processing aids, solvents, pigments, fabric softener actives and
mixtures thereof.
5. A malodor reduction composition comprising, based on total
composition weight, from 0.0001% to 100% of a malodor reduction
composition according to claim 2 and an adjunct material, said
composition being a consumer product.
6. A malodor reduction composition according to claim 5 wherein
said adjunct material is selected from the group consisting of
surfactants, builders, chelating agents, dye transfer inhibiting
agents, dispersants, enzymes, and enzyme stabilizers, catalytic
materials, bleach activators, hydrogen peroxide, sources of
hydrogen peroxide, preformed peracids, polymeric dispersing agents,
clay soil removal/anti-redeposition agents, brighteners, suds
suppressors, dyes, hueing dyes, perfumes, perfume delivery systems,
structure elasticizing agents, carriers, structurants, hydrotropes,
processing aids, solvents, pigments, fabric softener actives and
mixtures thereof.
7. A plastic film said plastic film comprising linear low-density
polyethylene, low-density polyethylene, high-density polyethylene,
and/or compostable film and a malodor reduction composition
according to claim 1.
8. A plastic film said plastic film comprising linear low-density
polyethylene, low-density polyethylene, high-density polyethylene,
and/or compostable film and a malodor reduction composition
according to claim 2.
9. A method of controlling malodors comprising contacting a
material comprising a malodor with a malodor reduction composition
according to claim 1.
10. A method of controlling malodors comprising contacting a
material comprising a malodor with a malodor reduction composition
according to claim 2.
11. A method of determining the material's ability to decrease or
even eliminate the perception of one or more malodors comprising
determining the MORV and/or Universal MORV of said material.
Description
FIELD OF THE INVENTION
[0001] The present invention relates to malodor reduction
compositions and methods of making and using same.
BACKGROUND OF THE INVENTION
[0002] Unscented or scented products are desired by consumers as
they may be considered more natural and discreet than scented
products. Manufacturers of unscented or scented products for
controlling malodors rely on malodor reduction ingredients or other
technologies (e.g. filters) to reduce malodors. However,
effectively controlling malodors, for example, amine-based malodors
(e.g. fish and urine), thiol and sulfide-based malodors (e.g.
garlic and onion), C.sub.2-C.sub.12 carboxylic acid based malodors
(e.g. body and pet odor), indole based malodors (e.g. fecal and bad
breath), short chain fatty aldehyde based malodors (e.g. grease)
and geosmin based malodors (e.g. mold/mildew) may be difficult, and
the time required for a product to noticeably reduce malodors may
create consumer doubt as to the product's efficacy on malodors.
Often times, manufacturers incorporate scented perfumes to help
mask these difficult malodors.
[0003] Unfortunately, malodor control technologies typically cover
up the malodor with a stronger scent and thus interfere with the
scent of the perfumed or unperfumed situs that is treated with the
malodor control technology. Thus, limited nature of the current
malodor control technologies is extremely constraining. Thus what
is needed is a broader palette of malodor control technologies so
the perfume community can deliver the desired level of character in
a greater number of situations/applications. Surprisingly,
Applicants recognized that in addition to blocking a malodor's
access to a sensory cell, in order to achieve the desired goal, a
malodor control technology must leave such sensor cell open to
other molecules, for example scent molecules. Thus, the malodor
control technologies disclosed herein do not unduely interfere with
the scent of the perfumed or unperfumed situs that is treated with
the malodor control technology.
SUMMARY OF THE INVENTION
[0004] The present invention relates to malodor reduction
compositions and methods of making and using same. The malodor
reduction compositions are suitable for use in a variety of
applications, including use in consumer products, for example, air
freshening compositions, laundry detergents, fabric enhancers,
surface cleaners, beauty care products, dish care products,
diapers, feminine protection articles, and plastic films for
garbage bags. Such malodor control technologies do not unduely
interfere with the scent of the perfumed or unperfumed situs that
is treated with the malodor control technology.
DETAILED DESCRIPTION OF THE INVENTION
[0005] As used herein "MORV" is the calculated malodor reduction
value for a subject material. A material's MORV indicates such
material's ability to decrease or even eliminate the perception of
one or more malodors. For purposes of the present application, a
material's MORV is calculated in accordance with method found in
the test methods section of the present application.
[0006] As used herein "consumer product" means baby care, beauty
care, fabric & home care, family care, feminine care, health
care, snack and/or beverage products or devices. Such products
include but are not limited to plastic films garbage bags, storage
bags, storage wraps, diapers, bibs, wipes, garments, textiles
including sheets and towels, composters; products for and/or
methods relating to treating hair (human, dog, and/or cat),
including, bleaching, coloring, dyeing, conditioning, wet or dry
shampooing, styling, scalp treatments; deodorants and
antiperspirants; personal cleansing; cosmetics; skin care including
application of creams, lotions, fine fragrances and other topically
applied products for consumer use; and shaving products, products
for and/or methods relating to treating fabrics, hard surfaces and
any other surfaces in the area of fabric and home care, including:
air care including air filtration, car care, dishwashing, fabric
conditioning (including softening), laundry detergency, laundry and
rinse additive and/or care, hard surface cleaning and/or treatment,
towel bowl cleaners and other cleaning and/or malodor treatments
for consumer, agricultural, industrial or institutional use;
products and/or methods relating to bath tissue, facial tissue,
paper handkerchiefs, and/or paper towels; tampons, feminine
napkins; products and/or methods relating to oral care including
toothpastes, tooth gels, tooth rinses, denture adhesives, tooth
whitening.
[0007] As used herein "energized system", refers to a system that
operates by using an electrical and/or mechanical energy source
such as a battery or electrical wall outlet to emit the malodor
reduction composition. Examples of such devices include but are
limited to liquid electric pluggable type air freshening
devices.
[0008] As used herein, "malodor" refers to compounds generally
offensive or unpleasant to most people, such as the complex odors
associated with bowel movements.
[0009] As used herein, "neutralize" or "neutralization" refers to
the ability of a compound or product to reduce or eliminate
malodorous compounds. Odor neutralization may be partial, affecting
only some of the malodorous compounds in a given context, or
affecting only part of a malodorous compound. A malodorous compound
may be neutralized by chemical reaction resulting in a new chemical
entity, by sequestration, by chelation, by association, or by any
other interaction rendering the malodorous compound less malodorous
or non-malodorous. Neutralization is distinguishable from odor
masking or odor blocking by a change in the malodorous compound, as
opposed to a change in the ability to perceive the malodor without
any corresponding change in the condition of the malodorous
compound. Malodor neutralization provides a sensory and
analytically measurable (e.g. gas chromatograph) malodor reduction.
Thus, if a malodor reduction composition delivers genuine malodor
neutralization, the composition will reduce malodors in the vapor
and/or liquid phase.
[0010] As used herein, "non-energized" refers to a system that
emits a targeted active passively or without the need for an
electrical energy source. Handheld aerosol sprayers and traditional
trigger/pump sprayers are considered non-energized systems.
[0011] As used herein, "odor blocking" refers to the ability of a
compound to dull the human sense of smell.
[0012] As used herein, "odor masking" refers to the ability of a
compound with a non-offensive or pleasant smell that is dosed such
that it limits the ability to sense a malodorous compound.
Odor-masking may involve the selection of compounds which
coordinate with an anticipated malodor to change the perception of
the overall scent provided by the combination of odorous
compounds.
[0013] As used herein, the terms "a" and "an" mean "at least
one".
[0014] As used herein, the terms "include", "includes" and
"including" are meant to be non-limiting.
[0015] Unless otherwise noted, all component or composition levels
are in reference to the active portion of that component or
composition, and are exclusive of impurities, for example, residual
solvents or by-products, which may be present in commercially
available sources of such components or compositions.
[0016] All percentages and ratios are calculated by weight unless
otherwise indicated. All percentages and ratios are calculated
based on the total composition unless otherwise indicated.
[0017] It should be understood that every maximum numerical
limitation given throughout this specification includes every lower
numerical limitation, as if such lower numerical limitations were
expressly written herein. Every minimum numerical limitation given
throughout this specification will include every higher numerical
limitation, as if such higher numerical limitations were expressly
written herein. Every numerical range given throughout this
specification will include every narrower numerical range that
falls within such broader numerical range, as if such narrower
numerical ranges were all expressly written herein.
Malodor Reduction Materials
TABLE-US-00001 [0018] Codes A = Vapor Pressure >0.1 torr B =
Vapor Pressure is between 0.01 torr and 0.1 torr C = ClogP <3 D
= ClogP >3 E = Probability of Ingredient Color Instability = 0%
F = Probability of Ingredient Color Instability <71% G = Odor
Detection Threshold less than p.ol = 8 H = Odor Detection Threshold
greater than p.ol = 8 I = Melamine formaldehyde PMC Headspace
Response Ratio greater than or equal to 10 J = Melamine
formaldehyde PMC leakage less than or equal to 5% K = Log of liquid
dish neat product liquid-air partition coefficient greater than or
equal to -7 L = Log of liquid dish neat product liquid-air
partition coefficient greater than or equal to -5
TABLE-US-00002 TABLE 1 List of materials with at least one MORV
from 1 to 5 Num- CAS Comment ber Material Name Number Code 1
2-ethylhexyl (Z)-3-(4- 5466-77-3 DEFHJ methoxyphenyl)acrylate 2
2,4-dimethyl-2-(5,5,8,8-tetramethyl- 131812-67-4 DFHJ
5,6,7,8-tetrahydronaphthalen-2-yl)- 1,3-dioxolane 3
1,1-dimethoxynon-2-yne 13257-44-8 ACEFHJK 4 para-Cymen-8-ol
1197-01-9 BCGIJK 7 3-methoxy-7,7-dimethyl-10- 216970-21-7 BDEFHJK
methylenebicyclo[4.3.1]decane 9 Methoxycyclododecane 2986-54-1
DEFHJK 10 1,1-dimethoxycyclododecane 950-33-4 DEFHJK 11
(Z)-tridec-2-enenitrile 22629-49-8 DEFHJK 13 Oxybenzone 131-57-7
DEFGJ 14 Oxyoctaline formate 65405-72-3 DFHJK 16
4-methyl-1-oxaspiro[5.5]undecan-4- 57094-40-3 CFGIJK ol 17
7-methyl-2H-benzo[b][1,4]dioxepin- 28940-11-6 CGIK 3(4H)-one 18
1,8-dioxacycloheptadecan-9-one 1725-01-5 DGJ 21
4-(tert-pentyl)cyclohexan-1-one 16587-71-6 ADFGIJKL 22 o-Phenyl
anisol 86-26-0 DEFHJK 23 3a,5,6,7,8,8b-hexahydro- 823178-41-2
DEFHJK 2,2,6,6,7,8,8-heptamethyl-4H- indeno(4,5-d)-1,3-dioxole 25
7-isopropyl-8,8-dimethyl-6,10- 62406-73-9 BDEFHIJK
dioxaspiro[4.5]decane 28 Octyl 2-furoate 39251-88-2 DEFHJK 29 Octyl
acetate 112-14-1 BDEFHJKL 30 octanal propylene glycol acetal
74094-61-4 BDEFHJKL 31 Octanal 124-13-0 ACHIKL 32 Octanal dimethyl
acetal 10022-28-3 ACEFGJKL 33 Myrcene 123-35-3 ADEFGIKL 34 Myrcenol
543-39-5 BCEFGIJK 35 Myrcenyl acetate 1118-39-4 ADEFGJK 36
Myristaldehyde 124-25-4 DFHJK 37 Myristicine 607-91-0 CGJK 38
Myristyl nitrile 629-63-0 DEFHJK 39
2,2,6,8-tetramethyl-1,2,3,4,4a,5,8,8a- 103614-86-4 DEFHIJK
octahydronaphthalen-1-ol 42 Ocimenol 5986-38-9 BCHIJK 43 Ocimenol
28977-58-4 BCHIJK 47 Nopyl acetate 128-51-8 DEFHJK 48 Nootkatone
4674-50-4 DHJK 49 Nonyl alcohol 143-08-8 BDEFGIJKL 50 Nonaldehyde
124-19-6 ADHIKL 52 12-methyl-14-tetradec-9-enolide 223104-61-8
DFHJK 57 N-ethyl-p-menthane-3-carboxamide 39711-79-0 DEFGIJK 61
1-(3-methylbenzofuran-2-yl)ethan-1- 23911-56-0 CEFHIK one 62
2-methoxynaphthalene 93-04-9 BDEFHK 63 Nerolidol 7212-44-4 DEFHJK
64 Nerol 106-25-2 BCHIK 65 1-ethyl-3- 31996-78-8 ACEFHIJKL
methoxytricyclo[2.2.1.02,6]heptane 67 Methyl (E)-non-2-enoate
111-79-5 ADEFHJKL 68 10-isopropyl-2,7-dimethyl-1- 89079-92-5
BDEFHIJK oxaspiro[4.5]deca-3,6-diene 69
2-(2-(4-methylcyclohex-3-en-1- 95962-14-4 DHJK
yl)propyl)cyclopentan-1-one 70 Myrtenal 564-94-3 ACFHIJKL 71
(E)-4-(2,2,3,6- 54992-90-4 BDEFHIJK
tetramethylcyclohexyl)but-3-en-2- one 74 Myraldyl acetate
53889-39-7 DHJK 75 Musk tibetine 145-39-1 DHIJ 76
1,7-dioxacycloheptadecan-8-one 3391-83-1 DGJ 77 Musk ketone 81-14-1
DHJ 78 Musk ambrette 83-66-9 DHIJ 79 3-methylcyclopentadecan-1-one
541-91-3 DEFHJK 80 (E)-3-methylcyclopentadec-4-en-1- 82356-51-2
DHJK one 82 3-methyl-4-phenylbutan-2-ol 56836-93-2 BCEFHIK 83
1-(4-isopropylcyclohexyl)ethan-1-ol 63767-86-2 BDEFHIJK 85 Milk
Lactone 72881-27-7 DEFHJK 91 Methyl octine carbonate 111-80-8
BDEFHKL 92 Methyl octyl acetaldehyde 19009-56-4 ADFHJKL 93
6,6-dimethoxy-2,5,5-trimethylhex-2- 67674-46-8 ACHIJKL ene 98
Methyl phenylethyl carbinol 2344-70-9 BCEFHIK 100 Methyl stearate
112-61-8 DEFHJ 101 Methyl nonyl acetaldehyde dimethyl 68141-17-3
BDEFHJK acetal 102 Methyl nonyl ketone 112-12-9 BDFHJKL 103 Methyl
nonyl acetaldehyde 110-41-8 BDFHJK 104 Methyl myristate 124-10-7
DEFHJK 105 Methyl linoleate 112-63-0 DEFHJ 106 Methyl lavender
ketone 67633-95-8 CFHJK 108 Methyl isoeugenol 93-16-3 ACEFHK 109
Methyl hexadecanoate 112-39-0 DEFHJK 110 Methyl eugenol 93-15-2
ACEFHK 112 Methyl epijasmonate 1211-29-6 CHJK 113 Methyl
dihydrojasmonate 24851-98-7 DFHJK 114 Methyl diphenyl ether
3586-14-9 DEFHJK 117 Methyl cinnamate 103-26-4 BCEFHK 119 Methyl
chavicol 140-67-0 ADEFHK 120 Methyl beta-naphthyl ketone 93-08-3
CEFHK 122 Methyl 2-octynoate 111-12-6 ACEFHKL 123 Methyl
alpha-cyclogeranate 28043-10-9 ACHIJKL 126 Methoxycitronellal
3613-30-7 ACFGIJK 128 Menthone 1,2-glycerol ketal 67785-70-0 CEFHJ
(racemic) 130 Octahydro-1H-4,7-methanoindene-1- 30772-79-3 BCFHIJKL
carbaldehyde 134 3-(3-(tert-butyl)phenyl)-2- 62518-65-4 BDHJK
methylpropanal 135 (E)-4-(4,8-dimethylnona-3,7-dien-1- 38462-23-6
DEFHJK yl)pyridine 137 (E)-trideca-3,12-dienenitrile 134769-33-8
DEFHJK 140 2,2-dimethyl-3-(m-tolyl)propan-1-ol 103694-68-4 CEFHIJK
141 2,4-dimethyl-4,4a,5,9b- 27606-09-3 CEFHJK
tetrahydroindeno[1,2-d][1,3]dioxine 142 Maceal 67845-30-1 BDFHJK
143 4-(4-hydroxy-4- 31906-04-4 CHJ methylpentyl)cyclohex-3-ene-1-
carbaldehyde 145 l-Limonene 5989-54-8 ADEFGIJKL 146
(Z)-3-hexen-1-yl-2-cyclopenten-1- 53253-09-1 BDHK one 148 Linalyl
octanoate 10024-64-3 DEFHJ 149 Linalyl isobutyrate 78-35-3 BDHJK
152 Linalyl benzoate 126-64-7 DFHJ 153 Linalyl anthranilate
7149-26-0 DFHJ 155 Linalool oxide (furanoid) 60047-17-8 BCHIJK 156
linalool oxide 1365-19-1 CGIJK 158 (2Z,6E)-3,7-dimethylnona-2,6-
61792-11-8 BDEFHJK dienenitrile 159 3-(4-methylcyclohex-3-en-1-
6784-13-0 ACFHIJK yl)butanal 161 (2,5-dimethyl-1,3-dihydroinden-2-
285977-85-7 CEFHJK yl)methanol 162 3-(4-(tert-butyl)phenyl)-2-
80-54-6 BDHJK methylpropanal 167 (E)-1-(1-methoxypropoxy)hex-3-ene
97358-54-8 ACEFGJKL 168 Leaf acetal 88683-94-7 ACEFGJKL 170
l-Carveol 2102-58-1 BCHIJK 174 Lauryl alcohol 112-53-8 DEFGJK 175
Lauryl acetate 112-66-3 DEFHJK 176 Lauric acid 143-07-7 DEFHJ 177
Lactojasmone 7011-83-8 BDEFHIJKL 178 Lauraldehyde 112-54-9 BDFHJK
179 3,6-dimethylhexahydrobenzofuran- 92015-65-1 BCEFHIJKL 2(3H)-one
182 4-(1-ethoxyvinyl)-3,3,5,5- 36306-87-3 BDFHIJK
tetramethylcyclohexan-1-one 183 Khusimol 16223-63-5 CEFHJK 184
5-(sec-butyl)-2-(2,4- 117933-89-8 DEFHJ
dimethylcyclohex-3-en-1-yl)-5- methyl-1,3-dioxane 185
(1-methyl-2-((1,2,2- 198404-98-7 DEFHJK
trimethylbicyclo[3.1.0]hexan-3- yl)methyl)cyclopropyl)methanol 186
2-propylheptanenitrile 208041-98-9 ADEFHIJKL 187
(E)-6-(pent-3-en-1-yl)tetrahydro-2H- 32764-98-0 BCFHIKL pyran-2-one
189 2-hexylcyclopentan-1-one 13074-65-2 BDFHJKL 190
2-methyl-4-phenyl-1,3-dioxolane 33941-99-0 BCEFGIK 192
2,6,9,10-tetramethyl-1- 71078-31-4 BDEFHIJK
oxaspiro(4.5)deca-3,6-diene 193 Isopulegol 89-79-2 BCEFHIJKL 195
Isopropyl palmitate 142-91-6 DEFHJ 196 Isopropyl myristate 110-27-0
DEFHJK 197 Isopropyl dodecanoate 10233-13-3 DEFHJK 199
Isopimpinellin 482-27-9 CFGJ 206 Iso3-methylcyclopentadecan-1-one
3100-36-5 DEFGJK 208 Isomenthone 491-07-6 ADEFGIJKL 209 Isojasmone
95-41-0 BDFHJKL 210 Isomenthone 36977-92-1 ADEFGIJKL 211 Isohexenyl
cyclohexenyl 37677-14-8 DFHJK carboxaldehyde 212 Isoeugenyl benzyl
ether 120-11-6 DFHJ 215 1-((2S,3S)-2,3,8,8-tetramethyl- 54464-57-2
DHJK 1,2,3,4,5,6,7,8-octahydronaphthalen- 2-yl)ethan-1-one 218
Isocyclocitral 1335-66-6 ACFHIJKL 221 Isobutyl quinoline 65442-31-1
DEFHJK 227 Isobornylcyclohexanol 68877-29-2 DEFHJK 228 Isobornyl
propionate 2756-56-1 BDEFHIJK 229 Isobornyl isobutyrate 85586-67-0
BDEFHIJK 230 Isobornyl cyclohexanol 66072-32-0 DEFHJK 231 Isobornyl
acetate 125-12-2 ADEFHIJKL 233 Isobergamate 68683-20-5 DEFHJK 234
Isoamyl undecylenate 12262-03-2 DEFHJK 238 Isoamyl laurate
6309-51-9 DEFHJK 242 Isoambrettolide 28645-51-4 DGJ 243 Irisnitrile
29127-83-1 ADEFHKL 244 Indolene 68527-79-7 DEFHJ 246
Indol/Hydroxycitronellal Schiff base 67801-36-9 DEFHJ 247
4,4a,5,9b-tetrahydroindeno[1,2- 18096-62-3 BCEFGJK d][1,3]dioxine
249 Hydroxy-citronellol 107-74-4 CEFGIJK 252
2-cyclododecylpropan-1-ol 118562-73-5 DEFHJK 253 Hydrocitronitrile
54089-83-7 CEFHJK 254 Hydrocinnamyl alcohol 122-97-4 BCEFHIK 256
Hydratropaldehyde dimethyl acetal 90-87-9 ACEFHJK 259
5-ethyl-4-hydroxy-2-methylfuran- 27538-09-6 CFGIK 3(2H)-one 260
2,3-dihydro-3,3-dimethyl-1H-indene- 173445-44-8 DHJK 5-propanal 261
3-(3,3-dimethyl-2,3-dihydro-1H- 173445-65-3 DHJK
inden-5-yl)propanal 263 Hexyl octanoate 1117-55-1 DEFHJK 267 Hexyl
hexanoate 6378-65-0 DEFHJKL 269 Hexyl cinnamic aldehyde 101-86-0
DHJ 271 Hexyl benzoate 6789-88-4 DEFHJK 274 Hexenyl tiglate
84060-80-0 BDEFHJK 276 (E)-3,7-dimethylocta-2,6-dien-1-yl 3681-73-0
DEFHJ palmitate 277 Hexadecanolide 109-29-5 DEFGJK 278
2-butyl-4,4,6-trimethyl-1,3-dioxane 54546-26-8 ADEFHIJKL 280 Ethyl
(1R,2R,3R,4R)-3- 116126-82-0 BDEFHIJK
isopropylbicyclo[2.2.1]hept-5-ene-2- carboxylate 281
3a,4,5,6,7,7a-hexahydro-1H-4,7- 5413-60-5 CEFGJK methanoinden-6-yl
acetate 285 2-(1-(3,3- 141773-73-1 DEFHJ
dimethylcyclohexyl)ethoxy)-2- methylpropyl propionate 286
Heliotropine diethyl acetal 40527-42-2 CEFGJ 288 Helional 1205-17-0
CHJK 289 (E)-oxacyclohexadec-13-en-2-one 111879-80-2 DGJK 290
Gyrane 24237-00-1 ADEFHIJKL 292 Guaiol 489-86-1 DEFHJK 293
1-(2,6,6-trimethylcyclohex-2-en-1- 68611-23-4 DHJK yl)pentan-3-one
294 Ethyl 2-ethyl-6,6-dimethylcyclohex- 57934-97-1 BDEFHIJK
2-ene-1-carboxylate 295 Germacrene B 15423-57-1 DEFHJK 296
Germacrene D 23986-74-5 DEFHJK 300 Geranyl phenylacetate 102-22-7
DFHJ 301 Geranyl phenyl acetate 71648-43-6 DFHJ 303 Geranyl
linalool 1113-21-9 DFHJ 307 Geranyl cyclopentanone 68133-79-9 DHJK
316 gamma-Undecalactone (racemic) 104-67-6 DEFHJKL 317
gamma-Terpinyl acetate 10235-63-9 BDHJK 318 gamma-Terpineol
586-81-2 BCGIJK 321 gamma-Nonalactone 104-61-0 BCEFHIKL 322
gamma-Muurolene 30021-74-0 DEFHJKL 323 gamma-(E)-6-(pent-3-en-1-
63095-33-0 BCEFHKL yl)tetrahydro-2H-pyran-2-one 324 gamma-Ionone
79-76-5 BDEFHIJK 325 gamma-Himachalene 53111-25-4 BDEFHJKL 328
gamma-Gurjunene 22567-17-5 DEFHJKL 329 gamma-Eudesmol 1209-71-8
DFHJK 330 gamma-Dodecalactone 2305-05-7 DEFHJK
331 gamma-Damascone 35087-49-1 BDEFHIJK 332 gamma-Decalactone
706-14-9 BDEFHIJKL 333 gamma-Cadinene 39029-41-9 DEFHJKL 334
1-(3,3-dimethylcyclohexyl)pent-4- 56973-87-6 BDEFHJK en-1-one 335
4,6,6,7,8,8-hexamethyl-1,3,4,6,7,8- 1222-05-5 DEFHJK
hexahydrocyclopenta[g]isochromene 336 Furfuryl octanoate 39252-03-4
DEFHJK 338 Furfuryl hexanoate 39252-02-3 CEFHJK 339 Furfuryl
heptanoate 39481-28-2 CEFHJK 342 2-methyldecanenitrile 69300-15-8
BDEFHJKL 343 8,8-dimethyl-3a,4,5,6,7,7a- 76842-49-4 DEFHJK
hexahydro-1H-4,7-methanoinden-6- yl propionate 344 Ethyl
(3aR,4S,7R,7aR)-octahydro- 80657-64-3 DEFHIJK
3aH-4,7-methanoindene-3a- carboxylate 347 Diethyl cyclohexane-1,4-
72903-27-6 CEFHJK dicarboxylate 349 (6-isopropyl-9-methyl-1,4-
63187-91-7 CEFHJ dioxaspiro[4.5]decan-2-yl)methanol 350
2-isobutyl-4-methyltetrahydro-2H- 63500-71-0 BCEFHIJK pyran-4-ol
352 Undec-10-enenitrile 53179-04-7 BDEFHJK 353
(Z)-6-ethylideneoctahydro-2H-5,8- 69486-14-2 CEFGJK
methanochromen-2-one 356 3-(2-ethylphenyl)-2,2- 67634-15-5 BDHJK
dimethylpropanal 358 (E)-4,8-dimethyldeca-4,9-dienal 71077-31-1
BDFHJK 359 (E)-4-((3aR,4R,7R,7aR)- 501929-47-1 DEFHJK
1,3a,4,6,7,7a-hexahydro-5H-4,7- methanoinden-5-ylidene)-3-
methylbutan-2-ol 360 8,8-dimethyl-3a,4,5,6,7,7a- 171102-41-3 DEFHJK
hexahydro-1H-4,7-methanoinden-6- yl acetate 361
3-(4-ethylphenyl)-2,2- 134123-93-6 DEFHJK dimethylpropanenitrile
362 2-heptylcyclopentan-1-one 137-03-1 DFHJKL 363 1-ethoxyethoxy
Cyclododecane 389083-83-4 DEFHJK 364 3-cyclohexene-1-carboxylic
acid, 815580-59-7 ACHIJKL 2,6,6-trimethyl-, methyl ester 368
Farnesyl acetate 29548-30-9 DEFHJK 369 Farnesol 4602-84-0 DEFHJK
370 Oxacyclohexadecan-2-one 106-02-5 DEFGJK 371
1-cyclopentadec-4-en-1-one 14595-54-1 DEFGJK 372
1-cyclopentadec-4-en-1-one 35720-57-1 DEFGJK 373 2-methoxy-4-(4-
128489-04-3 CGJ methylenetetrahydro-2H-pyran-2- yl)phenol 374
Eugenyl acetate 93-28-7 CFHJK 375 Eugenol 97-53-0 CHIK 377
Ethylmethylphenylglycidate 77-83-8 CFHJK 378 Ethylene brassylate
105-95-3 DFGJ 381 Ethyl undecylenate 692-86-4 DEFHJK 385 Ethyl
palmitate 628-97-7 DEFHJ 386 Ethyl nonanoate 123-29-5 BDEFHJKL 388
Ethyl myristate 124-06-1 DEFHJK 390 Ethyl linalool 10339-55-6
BCEFHJK 391 Ethyl laurate 106-33-2 DEFHJK 394 Ethyl hexyl ketone
925-78-0 ADFHIKL 397 Ethyl decanoate 110-38-3 BDEFHJK 398 Ethyl
gamma-Safranate 35044-57-6 ADHIJK 407 Ethyl 3-phenylglycidate
121-39-1 CGJK 413 6-ethyl-2,10,10-trimethyl-1- 79893-63-3 BDEFHIJK
oxaspiro[4.5]deca-3,6-diene 414 Elemol 639-99-6 DEFHJK 415
(2-(1-ethoxyethoxy)ethyl)benzene 2556-10-7 BCEFHJK 416
(E)-3-methyl-5-(2,2,3- 67801-20-1 DHJK
trimethylcyclopent-3-en-1-yl)pent-4- en-2-ol 417 d-xylose 58-86-6
CGIJ 418 (E)-4-((3aS,7aS)-octahydro-5H-4,7- 30168-23-1 DFHJK
methanoinden-5-ylidene)butanal 421 Dodecanal dimethyl acetal
14620-52-1 DEFHJK 424 d-Limonene 5989-27-5 ADEFGIJKL 425
Dipropylene Glycol 25265-71-8 CEFGIK 426 Dispirone 83863-64-3
BDEFHJK 428 Diphenyloxide 101-84-8 BDEFHK 429 Diphenylmethane
101-81-5 DEFGK 432 Dimethyl benzyl carbinyl butyrate 10094-34-5
DEFHJK 436 2,6-dimethyloct-7-en-4-one 1879-00-1 ADEFHIJKL 441
Octahydro-1H-4,7-methanoinden-5- 64001-15-6 DEFHJKL yl acetate 444
Dihydrocarveol acetate 20777-49-5 BDEFHIJK 445 Dihydrocarveol
619-01-2 BCEFHIJKL 449 Dihydro Linalool 18479-51-1 BCEFGIJKL 450
Dihydro Isojasmonate 37172-53-5 DHJK 453 Dibutyl sulfide 544-40-1
ADEFHIKL 457 Dibenzyl 103-29-7 DEFGJK 459 delta-Undecalactone
710-04-3 DEFHJKL 461 delta-Elemene 20307-84-0 BDEFHJK 462
delta-Guaiene 3691-11-0 DEFHJKL 463 delta-Dodecalactone 713-95-1
DEFHJK 464 delta-Decalactone 705-86-2 BDEFHIJKL 465 delta-Cadinene
483-76-1 DEFHJKL 466 delta-damascone 57378-68-4 ADHIJK 467
delta-Amorphene 189165-79-5 DEFHJKL 468 delta-3-Carene 13466-78-9
ADEFGIJKL 470 Decylenic alcohol 13019-22-2 BDEFHJK 471 Decyl
propionate 5454-19-3 DEFHJK 473 Decanal diethyl acetal 34764-02-8
DEFHJK 474 Decahydro-beta-naphthol 825-51-4 BCEFGIK 475
1-cyclohexylethyl (E)-but-2-enoate 68039-69-0 BDFHJK 478
3-(4-isopropylphenyl)-2- 103-95-7 BDFHJK methylpropanal 479
Cyclotetradecane 295-17-0 DEFGJKL 480 Cyclopentadecanone 502-72-7
DEFGJK 482 Cyclohexyl salicylate 25485-88-5 DFGJ 484
3a,4,5,6,7,7a-hexahydro-1H-4,7- 113889-23-9 DEFHJK
methanoinden-6-yl butyrate 485 Cyclic ethylene dodecanedioate
54982-83-1 DFGJ 486 8,8-dimethyl-1,2,3,4,5,6,7,8- 68991-97-9 DHJK
octahydronaphthalene-2- carbaldehyde 487
3a,4,5,6,7,7a-hexahydro-1H-4,7- 67634-20-2 DEFHJK methanoinden-5-yl
isobutyrate 488 Curzerene 17910-09-7 DHJK 491 Cumic alcohol
536-60-7 CHIJK 493 Coumarone 1646-26-0 BCEFHIK 497
2-(3-phenylpropyl)pyridine 2110-18-1 CEFHJK 498 Dodecanenitrile
2437-25-4 DEFHJK 501 (E)-cycloheptadec-9-en-1-one 542-46-1 DEFGJ
502 Citryl acetate 6819-19-8 DFHJK 503 Citrus Propanol 15760-18-6
CEFHIJK 505 Citronitrile 93893-89-1 CEFHJK 519 Citral propylene
glycol acetal 10444-50-5 CEFHJK 520 Citral dimethyl acetal
7549-37-3 BCEFHJK 521 Citral diethyl acetal 7492-66-2 BDEFHJK 524
cis-Ocimene 3338-55-4 ADGIKL 527 cis-Limonene oxide 13837-75-7
ADEFGIJKL 529 Cis-iso-ambrettolide 36508-31-3 DGJ 530 cis-6-nonenol
35854-86-5 BCEFHIKL 531 cis-carveol 1197-06-4 BCHIJK 532
cis-4-Decen-1-al 21662-09-9 ADHKL 534 cis-3-hexenyl-cis-3-hexenoate
61444-38-0 BDEFHJK 537 cis-3-Hexenyl salicylate 65405-77-8 DEFGJ
541 Cis-3-hexenyl Benzoate 25152-85-6 DEFHJK 544 cis-3-Hexenyl
2-methylbutyrate 53398-85-9 ADEFHJKL 546 cis-3, cis-6-nonadienol
53046-97-2 ACEFHK 548 Cinnamyl propionate 103-56-0 DEFHJK 550
Cinnamyl isobutyrate 103-59-3 DEFHJK 551 Cinnamyl formate 104-65-4
BCEFHK 552 Cinnamyl cinnamate 122-69-0 DHJ 553 Cinnamyl acetate
103-54-8 BCEFHK 555 Cinnamic alcohol 104-54-1 BCEFHIK 558 Cetyl
alcohol 36653-82-4 DEFHJ 559 (E)-1-(2,6,6-trimethylcyclohex-2-en-
79-78-7 DHJK 1-yl)hepta-1,6-dien-3-one 560
2-methyl-4-(2,6,6-trimethylcyclohex- 65405-84-7 DFHJK
1-en-1-yl)butanal 561 (3aR,5aR,9aR,9bR)-3a,6,6,9a- 3738-00-9 DEFHJK
tetramethyldodecahydronaphtho[2,1- b]furan 562
1,6-dioxacycloheptadecan-7-one 6707-60-4 DGJ 563
1-(6-(tert-butyl)-1,1-dimethyl-2,3- 13171-00-1 DEFHJK
dihydro-1H-inden-4-yl)ethan-1-one 565 Cedryl methyl ether
19870-74-7 ADEFHJK 566 Cedryl formate 39900-38-4 BDEFHJK 567 Cedryl
acetate 77-54-3 DEFHJK 568 (4Z,8Z)-1,5,9-trimethyl-13- 71735-79-0
DFHJK oxabicyclo[10.1.0]trideca-4,8-diene 569 Cedrol 77-53-2 DEFHJK
570 5-methyl-1-(2,2,3- 139539-66-5 DEFHJK
trimethylcyclopent-3-en-1-yl)-6- oxabicyclo[3.2.1]octane 571
5-methyl-1-(2,2,3- 426218-78-2 DFHJ
trimethylcyclopent-3-en-1-yl)-6- oxabicyclo[3.2.1]octane 572
1,1,2,3,3-pentamethyl-1,2,3,5,6,7- 33704-61-9 BDEFHIJK
hexahydro-4H-inden-4-one 573 Caryophyllene alcohol acetate
32214-91-8 DEFHJK 574 Caryolan-1-ol 472-97-9 DEFHJK 577 Carvyl
acetate 97-42-7 BDHIJK 578 Caprylnitrile 124-12-9 ACEFGIKL 580
Caprylic alcohol 111-87-5 ACEFGIKL 581 Caprylic acid 124-07-2
BCEFHIK 582 Capric acid 334-48-5 DEFHJK 584 Capraldehyde 112-31-2
ADHKL 586 3-(4-methoxyphenyl)-2- 5462-06-6 BCHJK methylpropanal 587
Camphorquinone 10373-78-1 ACEFGIJK 589 Camphene 79-92-5 ADEFGIJKL
591 Ethyl 2-methyl-4-oxo-6- 59151-19-8 DHJ
pentylcyclohex-2-ene-1-carboxylate 592 Butylated hydroxytoluene
128-37-0 DEFGIJK 594 Butyl stearate 123-95-5 DEFHJ 595 Butyl
butyryl lactate 7492-70-8 CEFGJK 599 Butyl 10-undecenoate 109-42-2
DEFHJK 600 2-methyl-4-(2,2,3- 72089-08-8 DEFHJK
trimethylcyclopent-3-en-1-yl)butan- 1-ol 601
3-(4-(tert-butyl)phenyl)propanal 18127-01-0 BDHJK 603 Bornyl
isobutyrate 24717-86-0 BDEFHIJK 604 Bornyl acetate 76-49-3
ADEFHIJKL 606 2-ethoxy-2,6,6-trimethyl-9- 68845-00-1 BDEFHJK
methylenebicyclo[3.3.1]nonane 607 (ethoxymethoxy)cyclododecane
58567-11-6 DEFHJK 608 Bisabolene 495-62-5 DEFHJK 609 Bigarade oxide
72429-08-4 ADEFHJKL 610 beta-Vetivone 18444-79-6 DHJK 611
beta-Terpinyl acetate 10198-23-9 BDHJK 612 beta-Terpineol 138-87-4
BCGIJK 613 beta-Sinensal 60066-88-8 DHJK 614
beta-Sesquiphellandrene 20307-83-9 DEFHJK 615 beta-Selinene
17066-67-0 BDEFGJK 616 beta-Santalol 77-42-9 DEFHJK 618 beta-Pinene
127-91-3 ADEFGIJKL 620 beta-Naphthyl ethyl ether 93-18-5 BDEFHJK
621 beta-Patchoulline 514-51-2 BDEFGJKL 624 beta-Himachalene Oxide
57819-73-5 BDFHJK 625 beta-Himachalene 1461-03-6 DEFHJKL 626
beta-Guaiene 88-84-6 DEFHJKL 627 (2,2-dimethoxyethyl)benzene
101-48-4 DHJK 628 beta-Farnesene 18794-84-8 DEFHJK 631 beta-Copaene
18252-44-3 BDEFHJKL 632 beta-Cedrene 546-28-1 BDEFGJKL 633
beta-Caryophyllene 87-44-5 DEFHJKL 635 beta-Bisabolol 15352-77-9
DFHJK 636 Beta ionone epoxide 23267-57-4 BDEFHIJK 638 Bergaptene
484-20-8 CGJ 639 Benzyl-tert-butanol 103-05-9 CEFGJK 644 Benzyl
laurate 140-25-0 DEFHJ 649 Benzyl dimethyl carbinol 100-86-7
BCEFGIK 650 Benzyl cinnamate 103-41-3 DHJ 653 Benzyl benzoate
120-51-4 DHJ 655 Benzophenone 119-61-9 DEFHK 658 7-isopentyl-2H-
362467-67-2 DHJ benzo[b][1,4]dioxepin-3(4H)-one 659
2'-isopropyl-1,7,7- 188199-50-0 DEFHJK
trimethylspiro[bicyclo[2.2.1]heptane- 2,4'-[1,3]dioxane] 660
4-(4-methylpent-3-en-1-yl)cyclohex- 21690-43-7 DEFHJK
3-ene-1-carbonitrile 661 Aurantiol 89-43-0 DEFHJ 663 Anisyl
phenylacetate 102-17-0 DFHJ 668 Methyl (E)-octa-4,7-dienoate
189440-77-5 ACEFHKL 671 Amyl Cinnamate 3487-99-8 DEFHJK 673
(3aR,5aS,9aS,9bR)-3a,6,6,9a- 6790-58-5 DEFHJK
tetramethyldodecahydronaphtho[2,1- b]furan 674
(4aR,5R,7aS,9R)-2,2,5,8,8,9a- 211299-54-6 DEFHJK
hexamethyloctahydro-4H-4a,9- methanoazuleno[5,6-d][1,3]dioxole 675
2,5,5-trimethyl-1,2,3,4,5,6,7,8- 71832-76-3 DEFHJK
octahydronaphthalen-2-ol 676 2,5,5-trimethyl-1,2,3,4,5,6,7,8-
41199-19-3 DEFHJK octahydronaphthalen-2-ol 677 1-((2-(tert-
139504-68-0 DEFHJK butyl)cyclohexyl)oxy)butan-2-ol 678
(3S,5aR,7aS,11aS,11bR)-3,8,8,11a- 57345-19-4 DEFHJ
tetramethyldodecahydro-5H-3,5a- epoxynaphtho[2,1-c]oxepine 679
2,2,6,6,7,8,8-heptamethyldecahydro- 476332-65-7 ADEFHJK
2H-indeno[4,5-b]furan 680 2,2,6,6,7,8,8-heptamethyldecahydro-
647828-16-8 ADEFHJK 2H-indeno[4,5-b]furan 681 Amber acetate
37172-02-4 BDEFHJK 682 Alpinofix 811436-82-5 DEFHJ 683
alpha-Thujone 546-80-5 ADEFGIJKL 684 alpha-Vetivone 15764-04-2 DHJK
686 alpha-Terpinyl propionate 80-27-3 BDEFHJK 691 alpha-Sinensal
17909-77-2 DHJK 692 alpha-Selinene 473-13-2 BDEFHJK 693
alpha-Santalene 512-61-8 ADEFHJKL 694 alpha-Santalol 115-71-9
DEFHJK 696 alpha-Patchoulene 560-32-7 ADEFHJKL 697
alpha-neobutenone 56973-85-4 BDHJK 698 alpha-Muurolene 10208-80-7
DEFHJKL 700 alpha-methyl ionone 127-42-4 BDHJK 702 alpha-Limonene
138-86-3 ADEFGIJKL 704 alpha-Irone 79-69-6 BDHJK 706 alpha-Humulene
6753-98-6 DEFHJK 707 alpha-Himachalene 186538-22-7 BDEFHJK 708
alpha-Gurjunene 489-40-7 BDEFHJKL 709 alpha-Guaiene 3691-12-1
DEFHJKL 710 alpha-Farnesene 502-61-4 DEFHJK 711 alpha-Fenchene
471-84-1 ADEFGIJKL 712 alpha-Eudesmol 473-16-5 DEFHJK 713
alpha-Curcumene 4176-17-4 DEFHJK 714 alpha-Cubebene 17699-14-8
ADEFHJKL 715 alpha-Cedrene epoxide 13567-39-0 ADEFHJK 716
alpha-Cadinol 481-34-5 DEFHJK 717 alpha-Cadinene 24406-05-1 DEFHJKL
718 alpha-Bisabolol 515-69-5 DFHJK 719 alpha-bisabolene 17627-44-0
DEFHJK 720 alpha-Bergamotene 17699-05-7 BDEFHJKL 721
alpha-Amylcinnamyl alcohol 101-85-9 DEFHJ 722 alpha-Amylcinnamyl
acetate 7493-78-9 DEFHJ 723 alpha-Amylcinnamaldehyde diethyl
60763-41-9 DEFHJ acetal 724 alpha-Amylcinnamaldehyde 122-40-7 DHJK
725 alpha-Amorphene 23515-88-0 DEFHJKL 726 alpha-Agarofuran
5956-12-7 BDEFHJK 727 1-methyl-4-(4-methyl-3-penten-1- 52475-86-2
DFHJK yl)-3-Cyclohexene-1-carboxaldehyde 730 1-Phenyl-2-pentanol
705-73-7 CEFHK 731 1-Phenyl-3-methyl-3-pentanol 10415-87-9 CEFHJK
733 2,3,4-trimethoxy-benzaldehyde 2103-57-3 BCGI 735
2,4,5-trimethoxy-benzaldehyde 4460-86-0 BCG 736
2,4,6-trimethoxybenzaldehyde 830-79-5 BCGI 738 2,4-Nonadienal
6750-03-4 ACHKL 741 2,6,10-Trimethylundecanal 105-88-4 BDFGJK 742
alpha,4-Dimethyl benzenepropanal 41496-43-9 ACHJK 746 Allyl
cyclohexyl propionate 2705-87-5 BDEFHJK 748 Allyl amyl glycolate
67634-00-8 BCEFGJK 750 Allo-aromadendrene 25246-27-9 BDEFHJKL 752
Aldehyde C-11 143-14-6 ADHJK 754 Methyl (E)-2-(((3,5- 94022-83-0
DEFHJ dimethylcyclohex-3-en-1- yl)methylene)amino)benzoate 757
2,6,10-trimethylundec-9-enal 141-13-9 BDFHJK 758
Acetoxymethyl-isolongifolene 59056-62-1 BDEFHJK (isomers) 763
Acetate C9 143-13-5 BDEFHJKL 764 Acetarolle 744266-61-3 DFHJK 766
Acetaldehyde phenylethyl propyl 7493-57-4 CEFHJK acetal 767
Acetaldehyde dipropyl acetal 105-82-8 ACEFGIKL 768 Acetaldehyde
benzyl 2-methoxyethyl 7492-39-9 BCEFHJK acetal 769
(Z)-2-(4-methylbenzylidene)heptanal 84697-09-6 DHJ 770 9-decenal
39770-05-3 ADHKL 771 8-Hexadecenolide 123-69-3 DGJ 772
7-Methoxycoumarin 531-59-9 CHK 774 7-epi-alpha-Selinene 123123-37-5
BDEFHJK 775 7-eip-alpha-Eudesmol 123123-38-6 DEFHJK 776
7-Acetyl-1,1,3,4,4,6- 1506-02-1 DEFHJ hexamethyltetralin 778
6-Isopropylquinoline 135-79-5 CEFHJK 781
6,6-dimethyl-2-norpinene-2- 33885-51-7 BCFHJK propionaldehyde 782
6,10,14-trimethyl-2-Pentadecanone 502-69-2 DEFHJK 786
5-Isopropenyl-2-methyl-2- 13679-86-2 ACGIJKL vinyltetrahydrofuran
788 5-Cyclohexadecenone 37609-25-9 DEFGJK 791 4-Terpinenol 562-74-3
BCHIJK 792 4-Pentenophenone 3240-29-7 BCEFHIK 800 4-Carvomenthenol
28219-82-1 BCHIJK 802 4,5,6,7-Tetrahydro-3,6- 494-90-6 BCEFHIJKL
dimethylbenzofuran 803 4-(p-Methoxyphenyl)-2-butanone 104-20-1
BCEFHJK 804 3-Thujopsanone 25966-79-4 BDEFHJK 805
3-Propylidenephthalide 17369-59-4 CEFHK 806 3-Nonylacrolein
20407-84-5 BDFHJK 807 3-Methyl-5-phenyl-1-pentanal 55066-49-4
BDFHJK 814 3-Hexenyl isovalerate 10032-11-8 ADEFHJKL 821
3,6-Dimethyl-3-octanyl acetate 60763-42-0 ADEFHIJKL 824
3,4,5-trimethoxybenzaldehyde 86-81-7 BCGIK 826 3-(p- 7775-00-0
BDFHJK Isopropylphenyl)propionaldehyde 827 2-Undecenenitrile
22629-48-7 BDEFHJK 828 2-Undecenal 2463-77-6 ADHJK 829
2-trans-6-trans-Nonadienal 17587-33-6 ACHKL 831 2-Phenylethyl
butyrate 103-52-6 DEFHJK 833 2-Phenyl-3-(2-furyl)prop-2-enal
57568-60-2 CHJ 834 2-Phenoxyethanol 122-99-6 BCEFGIK 837
2-Nonen-1-al 2463-53-8 ADHKL 839 2-Nonanol 628-99-9 BDEFGIKL 840
2-Nonanone 821-55-6 ADFHIKL 849 2-Isobutyl quinoline 93-19-6 CEFHJK
850 2-Hexylidene cyclopentanone 17373-89-6 DFHJKL 852 2-Heptyl
tetrahydrofuran 2435-16-7 BDEFHJKL 856 2-Decenal 3913-71-1 ADHKL
864 2,6-Nonadienal 26370-28-5 ACHKL 865 2,6-Nonadien-1-ol 7786-44-9
ACEFHK 866 2,6-dimethyl-octanal 7779-07-9 ADFGIJKL 868 1-Decanol
112-30-1 BDEFGJK 869 1-Hepten-1-ol, 1-acetate 35468-97-4 ACEFHKL
870 10-Undecen-1-ol 112-43-6 DEFHJK 871 10-Undecenal 112-45-8 ADHJK
872 10-epi-gamma-Eudesmol 15051-81-7 DFHJK 873 1,8-Thiocineol
68391-28-6 ADEFHIJKL 876 1,3,5-undecatriene 16356-11-9 ADEFHJKL 877
1,2-Dihydrolinalool 2270-57-7 BCEFGIJKL 878
1,3,3-trimethyl-2-norbornanyl 13851-11-1 ADEFHIJKL acetate 879
1,1,2,3,3-Pentamethylindan 1203-17-4 ADHIJKL 881
(Z)-6,10-dimethylundeca-5,9-dien-2- 3239-37-0 DEFHJK yl acetate 884
(Z)-3-Dodecenal 68141-15-1 BCFHJK 885 (S)-gamma-Undecalactone
74568-05-1 DEFHJKL 886 (R)-gamma-Undecalactone 74568-06-2 DEFHJKL
890 (E)-6,10-dimethylundeca-5,9-dien-2- 3239-35-8 DEFHJK yl acetate
892 (2Z)-3-methyl-5-phenyl-2- 53243-59-7 DEFHJK Pentenenitrile 893
(2S,5S,6S)-2,6,10,10-tetramethyl-1- 65620-50-0 DFHIJK
oxaspiro[4_5]decan-6-ol 894 (2E)-3-methyl-5-phenyl-2- 53243-60-0
CEFHJK pentenenitrile 897 (+)-Dihydrocarveol 22567-21-1 BCEFHIJKL
905 Menthone 89-80-5 ADEFGIJKL 908 (R,E)-2-methyl-4-(2,2,3-
185068-69-3 CHJK trimethylcyclopent-3-en-1-yl)but-2- en-1-ol 912
2-(8-isopropyl-6- 68901-32-6 DEFHJK
methylbicyclo[2.2.2]oct-5-en-2-yl)- 1,3-dioxolane 913 gamma-methyl
ionone 7388-22-9 BDHIJK 914 3-(3-isopropylphenyl)butanal
125109-85-5 BDHJK 916 3-(1-ethoxyethoxy)-3,7- 40910-49-4 BDEFHJK
dimethylocta-1,6-diene 919 3a,4,5,6,7,7a-hexahydro-1H-4,7-
17511-60-3 CEFHJK methanoinden-6-yl propionate 920 Bulnesol
22451-73-6 DEFHJK 922 Benzyl phenylacetate 102-16-9 DHJ 923 Benzoin
119-53-9 CEFHJ 924 (E)-1,2,4-trimethoxy-5-(prop-1-en-1- 2883-98-9
BCFGJK yl)benzene 925 alpha,alpha,6,6-tetramethyl 33885-52-8 BDFHJK
bicyclo[3.1.1]hept-2-ene-propanal 926 7-epi-sesquithujene
159407-35-9 DEFHJKL 927 5-Acetyl-1,1,2,3,3,6- 15323-35-0 DEFHJK
hexamethylindan 928 3-Methylphenethyl alcohol 1875-89-4 BCEFHIK 929
3,6-Nonadien-1-ol 76649-25-7 ACEFHK 930 2-Tridecenal 7774-82-5
BDFHJK 933 Patchouli alcohol 5986-55-0 DEFHIJK 937 p-Cresyl
isobutyrate 103-93-5 BDHJK 939 p-Cresyl n-hexanoate 68141-11-7
DEFHJK 941 5-hexyl-4-methyldihydrofuran- 67663-01-8 BDEFHIJKL
2(3H)-one 942 Ethyl (2Z,4E)-deca-2,4-dienoate 3025-30-7 BDEFHJK 943
Pelargene 68039-40-7 DEFHJK 945 2-cyclohexylidene-2- 10461-98-0
DFHJK phenylacetonitrile 946 Perillaldehyde 2111-75-3 ACHIJK 947
Perillyl acetate 15111-96-3 DFHJK 948 Perillyl alcohol 536-59-4
CHIJK 950 (2-isopropoxyethyl)benzene 68039-47-4 ACEFHJKL 951 Ethyl
(2Z,4E)-deca-2,4-dienoate 313973-37-4 BDEFHJK 953
(2-(cyclohexyloxy)ethyl)benzene 80858-47-5 DEFHJK 954 Phenethyl
2-methylbutyrate 24817-51-4 DEFHJK 955 Phenethyl alcohol 60-12-8
BCEFGIK 959 Phenethyl phenylacetate 102-20-5 DHJ 962 Phenoxanol
55066-48-3 DEFHJK 965 Phenyl benzoate 93-99-2 DFHJK 967 Phenyl
ethyl benzoate 94-47-3 DHJ 969 Phenylacetaldehyde ethyleneglycol
101-49-5 BCEFGIK acetal 973 2-(6,6-dimethylbicyclo[3.1.1]hept-2-
30897-75-7 ACFHIJKL en-2-yl)acetaldehyde 974 Pinocarveol 5947-36-4
BCEFGIJKL 976 Piperonyl acetone 55418-52-5 CEFGJ 978
3a,4,5,6,7,7a-hexahydro-1H-4,7- 68039-44-1 DEFHJK methanoinden-6-yl
pivalate 980 (4aR,8aS)-7-methyloctahydro-1,4- 41724-19-0 CEFGJKL
methanonaphthalen-6(2H)-one 982 p-Menth-3-en-1-ol 586-82-3 BCGIJK
985 (E)-3,3-dimethyl-5-(2,2,3- 107898-54-4 DHJK
trimethylcyclopent-3-en-1-yl)pent-4- en-2-ol 988
1-methyl-4-(4-methylpent-3-en-1- 52474-60-9 DFHJK
yl)cyclohex-3-ene-1-carbaldehyde 993 Propylene glycol 57-55-6
ACEFGIKL 998 p-Tolyl phenylacetate 101-94-0 DFHJ 1000 Ethyl
2,4,7-decatrienoate 78417-28-4 BDEFHJK 1003
2-benzyl-4,4,6-trimethyl-1,3-dioxane 67633-94-7 DEFHJK 1006
2,4-dimethyl-4- 82461-14-1 BDEFHJK phenyltetrahydrofuran 1007
(2R,4a'R,8a'R)-3,7'-dimethyl- 41816-03-9 DEFHJK
3',4',4a',5',8',8a'-hexahydro-1'H- spiro[oxirane-2,2'-
[1,4]methanonaphthalene] 1008 (Z)-6-ethylideneoctahydro-2H-5,8-
93939-86-7 BCEFHJKL methanochromene 1009 2-((S)-1-((S)-3,3-
236391-76-7 DFHJ dimethylcyclohexyl)ethoxy)-2- oxoethyl propionate
1010 Methyl 2,2-dimethyl-6- 81752-87-6 ADHIJKL
methylenecyclohexane-1-carboxylate 1012
2-methyl-5-phenylpentan-1-ol 25634-93-9 DEFHJK 1016
4-methyl-2-phenyl-3,6-dihydro-2H- 60335-71-9 BCEFGJK pyran 1020
Sabinol 471-16-9 BCEFHIJKL 1021 Safrole 94-59-7 BCEFHK 1022
2,2,7,9-tetramethylspiro(5.5)undec- 502847-01-0 DHIJK 8-en-1-one
1023 3-methyl-5-(2,2,3- 65113-99-7 DEFHJK
trimethylcyclopent-3-en-1-yl)pentan- 2-ol 1024
(Z)-2-ethyl-4-(2,2,3- 28219-61-6 DEFHJK
trimethylcyclopent-3-en-1-yl)but-2- en-1-ol 1025
(E)-2-methyl-4-(2,2,3- 28219-60-5 CHJK
trimethylcyclopent-3-en-1-yl)but-2- en-1-ol 1026
5-methoxyoctahydro-1H-4,7- 86803-90-9 CHJK
methanoindene-2-carbaldehyde 1027 5-methoxyoctahydro-1H-4,7-
193425-86-4 CHJK methanoindene-2-carbaldehyde 1028 Sclareol
515-03-7 DEFHJ 1029 Sclareol oxide 5153-92-4 DEFHJK 1031
Selina-3,7(11)-diene 6813-21-4 DEFHJKL 1032 2-(1-(3,3- 477218-42-1
DEFHJ dimethylcyclohexyl)ethoxy)-2- methylpropyl
cyclopropanecarboxylate 1033 3-(4-isobutylphenyl)-2- 6658-48-6 DHJK
methylpropanal 1035 Spathulenol 6750-60-3 DEFHJK
1036 Spirambrene 533925-08-5 BCEFHJK 1037 Spirodecane 6413-26-9
BCEFGIJKL 1038 1-(spiro[4.5]dec-7-en-7-yl)pent-4-en- 224031-70-3
DGJK 1-one 1042 2-(4-methylthiazol-5-yl)ethan-1-ol 137-00-8 CGIKL
1043 2-(heptan-3-yl)-1,3-dioxolane 4359-47-1 ACEFHIJKL 1045
(Z)-dodec-4-enal 21944-98-9 BDFHJK 1046 tau-Cadinol 5937-11-1
DEFHJK 1047 tau-Muurolol 19912-62-0 DEFHJK 1053 Tetrahydrojasmone
13074-63-0 BDFHIJKL 1057 2,6,10,10-tetramethyl-1- 36431-72-8
BDFHIJKL oxaspiro[4.5]dec-6-ene 1059 Thiomenthone 38462-22-5
BDEFHIJKL 1060 Thujopsene 470-40-6 BDEFGJKL 1062 Thymol methyl
ether 1076-56-8 ADHIJKL 1063 1-(2,2,6-trimethylcyclohexyl)hexan-
70788-30-6 DEFHJK 3-ol 1064 trans, trans-2,4-Nonadienal 5910-87-2
ACHKL 1065 trans, trans-Farnesol 106-28-5 DEFHJK 1066 trans-2,
cis-6-Nonadienal 557-48-2 ACHKL 1067 trans-2-Decenal 3913-81-3
ADHKL 1070 trans-2-Nonen-1-al 18829-56-6 ADHKL 1072 trans-3,
cis-6-nonadienol 56805-23-3 ACEFHK 1073 trans-4-Decen-1-al
65405-70-1 ADHKL 1075 trans-ambrettolide 51155-12-5 DGJ 1077
trans-beta-ocimene 13877-91-3 ADGIKL 1078 trans-beta-Ocimene
3779-61-1 ADGIKL 1082 trans-Geraniol 106-24-1 BCHIK 1083
trans-Hedione 2570-03-8 DFHJK 1085 7-(1,1-Dimethylethyl)-2H-1,5-
195251-91-3 CEFHJ benzodioxepin-3(4H)-one 1089 Tricyclone
68433-81-8 DEFHJK 1090 Tridecyl alcohol 112-70-9 DEFGJK 1091
Triethyl citrate 77-93-0 CEFGJ 1093 Methyl 2-((1-hydroxy-3-
144761-91-1 DFHJ phenylbutyl)amino)benzoate 1095
1-((2E,5Z,9Z)-2,6,10- 28371-99-5 DHJK
trimethylcyclododeca-2,5,9-trien-1- yl)ethan-1-one 1097
Decahydro-2,6,6,7,8,8-hexamethyl- 338735-71-0 BDEFHJK
2h-indeno(4,5-b)furan 1099 13-methyl oxacyclopentadec-10-en-
365411-50-3 DEFHJK 2-one 1102 Undecanal 112-44-7 BDHJK 1104
(E)-4-methyldec-3-en-5-ol 81782-77-6 BDEFHIJK 1105 Valencene
4630-07-3 BDEFHJK 1107 Valerianol 20489-45-6 DEFHJK 1111 Vanillin
isobutyrate 20665-85-4 CHJ 1113 Vaniwhite 5533-03-9 CGIK 1116
(Z)-2-methyl-4-(2,6,6- 68555-62-4 BDFHJK
trimethylcyclohex-2-en-1-yl)but-2- enal 1117 Methyl
2,4-dihydroxy-3,6- 4707-47-5 CGIJ dimethylbenzoate 1120
1-methoxy-3a,4,5,6,7,7a-hexahydro- 27135-90-6 ACEFHJKL
1H-4,7-methanoindene 1121 Methyl (Z)-2-((3-(4-(tert- 91-51-0 DFHJ
butyl)phenyl)-2- methylpropylidene)amino)benzoate 1125
(Z)-hex-3-en-1-yl isobutyrate 41519-23-7 ADEFHJKL 1126 Vertacetal
5182-36-5 BCFHJK 1129 1-((3R,3aR,7R,8aS)-3,6,8,8- 32388-55-9 DHJK
tetramethyl-2,3,4,7,8,8a-hexahydro-
1H-3a,7-methanoazulen-5-yl)ethan- 1-one 1131 Methyl (Z)-2-(((2,4-
68738-99-8 DEFHJ dimethylcyclohex-3-en-1-
yl)methylene)amino)benzoate 1135 Vetiverol 89-88-3 CEFHIJK 1136
Vetivert Acetate 117-98-6 DEFHJK 1137
Decahydro-3H-spiro[furan-2,5'- 68480-11-5 DEFGJKL
[4,7]methanoindene] 1138 (2Z,6E)-nona-2,6-dienenitrile 67019-89-0
ACEFHKL 1139 (Z)-cyclooct-4-en-1-yl methyl 87731-18-8 BCHJKL
carbonate 1140 (1aR,4S,4aS,7R,7aS,7bS)-1,1,4,7- 552-02-3 DEFHJK
tetramethyldecahydro-1H- cyclopropa[e]azulen-4-ol 1142
3,5,5,6,7,8,8-heptamethyl-5,6,7,8- 127459-79-4 DHJ
tetrahydronaphthalene-2-carbonitrile 1143 (1S,2S,3S,5R)-2,6,6-
133636-82-5 DEFHJK trimethylspiro[bicyclo[3.1.1]heptane-
3,1'-cyclohexan]-2'-en-4'-one 1144
1',1',5',5'-tetramethylhexahydro- 154171-76-3 DEFHJK
2'H,5'H-spiro[[1,3]dioxolane-2,8'- [2,4a]methanonaphthalene] 1145
1',1',5',5'-tetramethylhexahydro- 154171-77-4 DEFHJK
2'H,5'H-spiro[[1,3]dioxolane-2,8'- [2,4a]methanonaphthalene] K 1146
4-(4-hydroxy-3- 122-48-5 CEFGJ methoxyphenyl)butan-2-one 1147
(1R,8aR)-4-isopropyl-1,6-dimethyl- 41929-05-9 DEFHJKL
1,2,3,7,8,8a-hexahydronaphthalene
TABLE-US-00003 TABLE 2 List of materials with at least one MORV
greater than 5 to 10 Number Material Name CAS Number Comment Code 2
2,4-dimethyl-2-(5,5,8,8-tetramethyl- 131812-67-4 DFHJ
5,6,7,8-tetrahydronaphthalen-2-yl)- 1,3-dioxolane 23
3a,5,6,7,8,8b-hexahydro- 823178-41-2 DEFHJK
2,2,6,6,7,8,8-heptamethyl-4H- indeno(4,5-d)-1,3-dioxole 141
2,4-dimethyl-4,4a,5,9b- 27606-09-3 CEFHJK
tetrahydroindeno[1,2-d][1,3]dioxine 185 (1-methyl-2-((1,2,2-
198404-98-7 DEFHJK trimethylbicyclo[3.1.0]hexan-3-
yl)methyl)cyclopropyl)methanol 227 Isobornylcyclohexanol 68877-29-2
DEFHJK 230 Isobornyl cyclohexanol 66072-32-0 DEFHJK 246
Indol/Hydroxycitronellal Schiff base 67801-36-9 DEFHJ 248
Hydroxymethyl isolongifolene 59056-64-3 DEFHJK 343
8,8-dimethyl-3a,4,5,6,7,7a- 76842-49-4 DEFHJK
hexahydro-1H-4,7-methanoinden-6- yl propionate 359
(E)-4-((3aR,4R,7R,7aR)- 501929-47-1 DEFHJK
1,3a,4,6,7,7a-hexahydro-5H-4,7- methanoinden-5-ylidene)-3-
methylbutan-2-ol 565 Cedryl methyl ether 19870-74-7 BDEFHJK 631
beta-Copaene 18252-44-3 BDEFHJKL 659 2'-isopropyl-1,7,7-
869292-93-3 BDEFHJK trimethylspiro[bicyclo[2.2.1]heptane-
2,4'-[1,3]dioxane] 674 (4aR,5R,7aS,9R)-2,2,5,8,8,9a- 211299-54-6
DEFHJK hexamethyloctahydro-4H-4a,9-
methanoazuleno[5,6-d][1,3]dioxole 678
(3S,5aR,7aS,11aS,11bR)-3,8,8,11a- 57345-19-4 DEFHJ
tetramethyldodecahydro-5H-3,5a- epoxynaphtho[2,1-c]oxepine 679
2,2,6,6,7,8,8-heptamethyldecahydro- 476332-65-7 DEFHJK
2H-indeno[4,5-b]furan 715 alpha-Cedrene epoxide 13567-39-0 BDEFHJK
758 Acetoxymethyl-isolongifolene 59056-62-1 DEFHJK (isomers) 1028
Sclareol 515-03-7 DEFHJ 1097 Decahydro-2,6,6,7,8,8-hexamethyl-
338735-71-0 DEFHJK 2h-indeno(4,5-b)furan
TABLE-US-00004 TABLE 3 List of materials with at least one MORV
from 0.5 to less than 1 Number Material Name CAS Number Comment
Code 12 1-ethoxy-4-(tert- 181258-89-9 ADEFHJK pentyl)cyclohexane 19
(3Z)-1-(2-buten-1-yloxy)-3- 888744-18-1 ADEFHJKL hexene 20
4-(2-methoxypropan-2-yl)-1- 14576-08-0 ADHIJKL methylcyclohex-1-ene
24 O-Methyl linalool 60763-44-2 ADHIJKL 26 o-Methoxycinnamaldehyde
1504-74-1 ACHK 27 Octanal, 3,7-dimethyl- 25795-46-4 ADGIJKL 53
3,3-Dimethyl-5(2,2,3- 329925-33-9 CEFHJ Trimethyl-3-Cyclopenten-
1yl)-4-Penten-2-ol 54 n-Hexyl salicylate 6259-76-3 DEFHJ 55 n-Hexyl
2-butenoate 19089-92-0 ADEFHJKL 59 Neryl Formate 2142-94-1 BCEFHJK
72 Methyl-beta-ionone 127-43-5 DHJK 73 Myroxide 28977-57-3 ADGIJKL
81 (E)-3,7-dimethylocta-4,6- 18479-54-4 BCEFGIJK dien-3-ol 84
(Z)-hex-3-en-1-yl 188570-78-7 BCEFHIKL cyclopropanecarboxylate 96
Methyl phenyl carbinyl 120-45-6 BCHJK propionate 97 Methyl
phenylacetate 101-41-7 ACEFHIKL 107 2-methyl-6- 91069-37-3 BCEFGIKL
oxaspiro[4.5]decan-7-one 111 Methyl geraniate 2349-14-6 BCHJKL 115
2-ethoxy-4- 5595-79-9 CFGK (methoxymethyl)phenol 116 Methyl
40203-73-4 ACEFHIKL cyclopentylideneacetate 125 Methoxymelonal
62439-41-2 ACGIJK 133 ((1s,4s)-4- 13828-37-0 BDEFHIJK
isopropylcyclohexyl)methanol 147 Linalyl propionate 144-39-8 BDFHJK
150 Linalyl formate 115-99-1 ACFHJK 151 Linalyl butyrate 78-36-4
BDEFHJK 154 Linalyl acetate 115-95-7 BDHJK 157 Linalool 78-70-6
BCEFGIJK 163 (Z)-hex-3-en-1-yl methyl 67633-96-9 ACEFGKL carbonate
166 Lepidine 491-35-0 BCEFHIKL 169 L-Carvone 6485-40-1 ACGIJKL 181
Khusinil 75490-39-0 DHJK 191 Isoraldeine 1335-46-2 BDHIJK 194
Isopropylvinylcarbinol 4798-45-2 ACGIKL 198 Isopropyl
2-methylbutyrate 66576-71-4 ACEFGIJKL 201 Isopentyrate 80118-06-5
ADEFGIJKL 204 Isononyl acetate 40379-24-6 BDEFHJKL 205 Isononanol
27458-94-2 BDEFGIKL 213 Isoeugenyl acetate 93-29-8 CFHJK 214
Isoeugenol 97-54-1 CEFHIK 232 Isoborneol 124-76-5 ACEFHIJKL 237
Isoamyl octanoate 2035-99-6 DEFHJK 239 Isoamyl isobutyrate
2050-01-3 ACEFGIJKL 255 Hydrocinnamic acid 501-52-0 CEFHIK 258
Hydratopic alcohol 1123-85-9 BCEFHIK 264 Hexyl propanoate 2445-76-3
ADEFHIKL 270 Hexyl butyrate 2639-63-6 BDEFHJKL 273 Hexyl
2-methylbutanoate 10032-15-2 BDEFHJKL 275 Hexyl 2-furoate
39251-86-0 DEFHJK 282 Heptyl alcohol 111-70-6 ACEFGIKL 283 Heptyl
acetate 112-06-1 ADEFHKL 284 Heptaldehyde 111-71-7 ACHIKL 287
Heliotropin 120-57-0 BCGIK 302 Geranyl nitrile 5146-66-7 BCEFHKL
306 Geranyl formate 105-86-2 BCEFHJK 308 Geranyl caprylate
51532-26-4 DEFHJ 310 Geranyl benzoate 94-48-4 DFHJ 312 Geranial
141-27-5 ACHIKL 314 N,2-dimethyl-N- 84434-18-4 BCEFHJK
phenylbutanamide 319 gamma-Terpinene 99-85-4 ADEFGIJKL 346
2-(sec-butyl)cyclohexan-1- 14765-30-1 ADFHIKL one 354
3-(2-ethylphenyl)-2,2- 67634-14-4 BDHJK dimethylpropanal 355
2-(tert-butyl)cyclohexyl ethyl 67801-64-3 BDFHJK carbonate 365
2-(tert-butyl)cyclohexyl ethyl 81925-81-7 ACFHIKL carbonate 366
Fenchyl alcohol 1632-73-1 ACGIJKL 376 Eucalyptol 470-82-6 ADEFGIJKL
379 Ethyl vanillin acetate 72207-94-4 CHJ 387 Ethyl octanoate
106-32-1 BDEFHJKL 400 Ethyl cinnamate 103-36-6 BCEFHK 412 Ethyl 2-
2511-00-4 BDFHIJKL (cyclohexyl)propionate 419
d-p-8(9)-Menthen-2-one 5524-05-0 ACGIJKL 420
4-methyl-2-phenyltetrahydro- 94201-73-7 BDEFHJK 2H-pyran 437
Dihydromyrcenol 18479-58-8 ADEFGIJK 438 Dihydrojasmone 1128-08-1
BCFHIJKL 439 Dihydroisophorone 873-94-9 ACEFGIJKL 440
Dihydroeugenol 2785-87-7 CEFHIJK 442 Dihydrocoumarin 119-84-6
BCGIKL 443 Dihydrocarvone 7764-50-3 ACGIJKL 447
Dihydro-alpha-terpinyl 80-25-1 BDEFHIJKL acetate 448
Dihydro-alpha-ionone 31499-72-6 BDHIJK 454 Dibenzyl ether 103-50-4
DEFHJK 455 Dibutyl o-phthalate 84-74-2 DEFHJ 469
2-pentylcyclopentan-1-one 4819-67-4 BDFHIKL 472 Decyl anthranilate
18189-07-6 DEFHJ 477 Methyl (1s,4s)-1,4- 23059-38-3 ADEFHIJKL
dimethylcyclohexane-1- carboxylate 481 Cyclohexylethyl acetate
21722-83-8 BDEFHJKL 492 Creosol 93-51-6 BCHIK 495 Cosmene 460-01-5
ADEFGIKL 496 4-cyclohexyl-2-methylbutan- 83926-73-2 BDEFGIJK 2-ol
504 2-benzyl-2-methylbut-3- 97384-48-0 BDHJK enenitrile 509
Citronellyl nitrile 51566-62-2 BCEFGIKL 510 Citronellyl
phenylacetate 139-70-8 DFHJ 512 Citronellyl formate 105-85-1
BCEFGJKL 515 Citronellyl benzoate 10482-77-6 DFHJ 517 Citronellol
106-22-9 BCHIJKL 518 Citronellal 106-23-0 ACHIJKL 522 Citral
5392-40-5 ACHIKL 525 cis-Pinane 6876-13-7 ADEFGIJKL 526
(Z)-3-methyl-2-(pent-2-en-1- 488-10-8 BCHIJKL
yl)cyclopent-2-en-1-one 528 cis-iso-Eugenol 5912-86-7 CEFHIK 535
cis-3-Hexenyl valerate 35852-46-1 BDEFHJKL 536 cis-3-Hexenyl
tiglate 67883-79-8 BDEFHJK 538 cis-3-Hexenyl propionate 33467-74-2
ACEFHIKL 540 cis-3-Hexenyl butyrate 16491-36-4 ADEFHJKL 542
cis-3-Hexen-1-ol 928-96-1 ACEFHIKL 547 cis-2-Hexenol 928-94-9
ACEFHIKL 549 Cinnamyl nitrile 4360-47-8 ACEFGIK 554 Cinnamic
aldehyde 104-55-2 ACHIK 556 Cinnamyl nitrile 1885-38-7 ACEFGIK 557
Chloroxylenol 88-04-0 BCHIJK 575 Carvacrol 499-75-2 DHIJK 576
Carvone 99-49-0 ACGIJKL 579 Carbitol 111-90-0 BCEFGIK 583 Caproyl
alcohol 111-27-3 ACEFGIKL 585 2-(2,2,3-trimethylcyclopent-3-
15373-31-6 ACGIJKL en-1-yl)acetonitrile 588 Camphor 76-22-2
ACEFGIJKL 602 (E)-2-methyl-4-(2,6,6- 3155-71-3 DHJK
trimethylcyclohex-1-en-1- yl)but-2-enal 605 Borneol 507-70-0
ACEFHIJKL 617 beta-Pinene epoxide 6931-54-0 ACEFGIJKL 619
beta-Phellandrene 555-10-2 ADEFGIJKL 640 Benzylacetone 2550-26-7
ACEFGIK 641 Benzyl salicylate 118-58-1 DFGJ 645 Benzyl isovalerate
103-38-8 BDEFHJK 647 Benzyl isobutyrate 103-28-6 BCHJK 651 Benzyl
butyrate 103-37-7 BCEFHJK 652 Benzyl alcohol 100-51-6 ACEFGIKL 662
1-(3,3- 25225-08-5 ADEFHIJKL dimethylcyclohexyl)ethyl formate 664
Anisyl acetate 104-21-2 BCEFGK 665 Anisyl formate 122-91-8 BCEFGK
667 Anethole 104-46-1 ACEFHK 672 Amyl benzoate 2049-96-9 DEFHJK 687
alpha-Terpinyl acetate 80-26-2 BDHJK 699 alpha-methyl- 10528-67-3
BDEFHIK cyclohexanepropanol 701 alpha-methyl cinnamaldehyde
101-39-3 ACHIK 703 alpha-Isomethylionone 127-51-5 BDHIJK 740
2,5-Dimethyl-4-methoxy- 4077-47-8 ACEFGIJKL 3(2H)-furanone 743
Allyl phenoxyacetate 7493-74-5 BCGK 744 Allyl Phenethyl ether
14289-65-7 ACEFHK 745 Allyl heptanoate 142-19-8 ADEFHJKL 755
N-ethyl-N-(m- 179911-08-1 CEFHJK tolyl)propionamide 760
3-hydroxybutan-2-one 513-86-0 ACEFGIKL 761 Acetoanisole 100-06-1
BCEFHIK 777 6-Methylquinoline 91-62-3 BCEFHIKL 779
6,8-Diethyl-2-nonanol 70214-77-6 BDEFGIJKL 784 5-Methyl-3-heptanone
541-85-5 ACFGIKL 789 4-Vinylphenol 2628-17-3 BCHIK 796
4-hydroxy-3-methoxy- 458-36-6 CH cinnamaldehyde 797 4-Ethylguaiacol
2785-89-9 CEFHIK 799 4-Damascol 4927-36-0 BDFHJK 808
3-methyl-4-phenylpyrazole 13788-84-6 CEFHK 810 3-Methyl-1,2-
765-70-8 ACEFGIKL cyclopentanedione 811 3-Methoxy-5-methylphenol
3209-13-0 BCHIK 812 3-Methoxy-3-Methyl Butanol 56539-66-3 ACGIKL
817 3-Hexenol 544-12-7 ACEFHIKL 819 3,7-dimethyl-2-methylene-6-
22418-66-2 ADFHIJK octenal 820 3,7-dimethyl-1-octanol 106-21-8
BDEFGIJKL 832 2-Phenylethyl acetate 103-45-7 BCEFHK 835 2-Phenethyl
propionate 122-70-3 BCEFHJK 836 2-Pentylcyclopentan-1-ol 84560-00-9
DEFHIKL 838 2-nonanone propylene glycol 165191-91-3 BDEFHJK acetal
845 2-Methoxy-3-(1- 24168-70-5 BCEFGIK methylpropyl)pyrazine 846
2-isopropyl-N,2,3- 51115-67-4 ACEFGIJK trimethylbutyramide 847
2-Isopropyl-5-methyl-2- 35158-25-9 ADFGIJKL hexenal 848
2-Isopropyl-4-methylthiazole 15679-13-7 ACHIJKL 851 2-Hexen-1-ol
2305-21-7 ACEFHIKL 858 2-Butoxyethanol 111-76-2 ACEFGIKL 875
1,4-Cineole 470-67-7 ADGIJKL 880 1-(2,6,6-Trimethyl-2- 43052-87-5
BDHIJK cyclohexen-1-yl)-2-buten-1- one 882 (Z)-3-hepten-1-yl
acetate 1576-78-9 ACEFHKL 883 (S)-(1R,5R)-4,6,6- 1196-01-6
ACEFGIJKL trimethylbicyclo[3.1.1]hept-3- en-2-one 888
(R)-(-)-Linalool 126-91-0 BCEFGIJK 889 (l)-Citronellal 5949-05-3
ACHIJKL 891 (d)-Citronellal 2385-77-5 ACHIJKL 899 (+)-Citronellol
1117-61-9 BCHIJKL 900 (-)-Citronellol 7540-51-4 BCHIJKL 901
(+)-alpha-Pinene 7785-70-8 ADEFGIJKL 902 (+)-Carvone 2244-16-8
ACGIJKL 903 (-)-alpha-Pinene 7785-26-4 ADEFGIJKL 904 Methyl
2-methylbutyrate 868-57-5 ACEFGIKL 909 Hexyl tiglate 16930-96-4
BDEFHJKL 918 Allyl 2- 68901-15-5 CHJK (cyclohexyloxy)acetate 921
1,5- 75147-23-8 CFHIJK dimethylbicyclo[3.2.1]octan- 8-one oxime 931
alpha-acetoxystyrene 2206-94-2 ACEFHIK 940 p-Cymene 99-87-6 ADGIJKL
956 Phenethyl formate 104-62-1 ACEFHK 958 Phenethyl isobutyrate
103-48-0 DHJK 960 Phenethyl tiglate 55719-85-2 DHJK 971 Phenylethyl
methacrylate 3683-12-3 DHJK 977 p- 4395-92-0 BDFHK
Isopropylphenylacetaldehyde 981 1,2-dimethyl-3-(prop-1-en-2-
72402-00-7 BCEFGIJKL yl)cyclopentan-1-ol 983 p-Methoxyphenylacetone
122-84-9 BCEFHK 986 (2Z,5Z)-5,6,7-trimethylocta- 358331-95-0
ADHIJKL 2,5-dien-4-one 987 p-Propyl anisole 104-45-0 ADEFHKL 994
p-t-butyl phenyl acetaldehyde 109347-45-7 BDHJK 995 p-tert-Amyl
cyclohexanol 5349-51-9 BDEFHIJK
1001 Racemic alpha-Pinene 80-56-8 ADEFGIJKL 1002
4-(4-hydroxyphenyl)butan-2- 5471-51-2 CEFGIK one 1004 Rhodinol
141-25-3 BCHIJKL 1005 Ethyl (2,3,6- 93981-50-1 BDEFHJKL
trimethylcyclohexyl)carbonate 1011 1-(3,3- 25225-10-9 ADHIJKL
dimethylcyclohexyl)ethyl acetate 1017 S)-(+)-Linalool 126-90-9
BCEFGIJK 1018 Sabinene 3387-41-5 ADEFGIJKL 1019 Sabinene hydrate
546-79-2 ADEFGIJKL 1030 Propyl (S)-2-(tert- 319002-92-1 BDEFHJK
pentyloxy)propanoate 1039 Spirolide 699-61-6 BCGIKL 1040
(Z)-5-methylheptan-3-one 22457-23-4 BCEFGIJKL oxime 1041
1-phenylethyl acetate 93-92-5 ACEFHIK 1051 Tetrahydrogeranial
5988-91-0 ADGIJKL 1052 Tetrahydroionol 4361-23-3 BDEFHIJK 1054
Tetrahydrolinalool 78-69-3 BDEFGIJKL 1055 Tetrahydrolinalyl acetate
20780-48-7 ADEFHJKL 1058 Ethyl (1R,6S)-2,2,6- 22471-55-2 ADEFHIJKL
trimethylcyclohexane-1- carboxylate 1061 Thymol 89-83-8 BDHIJK 1069
trans-2-Hexenol 928-95-0 ACEFHIKL 1071 trans-2-tert- 5448-22-6
ACGIJKL Butylcyclohexanol 1074 trans-alpha-Damascone 24720-09-0
BDHIJK 1076 trans-Anethole 4180-23-8 ACEFHK 1079 trans-Cinnamic
acid 140-10-3 CEFHK 1081 trans-Dihydrocarvone 5948-04-9 ACGIJKL
1084 trans-Isoeugenol 5932-68-3 CEFHIK 1088 Trichloromethyl phenyl
90-17-5 BDEFGJ carbinyl acetate 1098 2-mercapto-2-methylpentan-
258823-39-1 ACEFHIJKL 1-ol 1110 Vanillin acetate 881-68-5 CH 1112
Vanitrope 94-86-0 CEFHK 1115 2,2,5-trimethyl-5- 65443-14-3 BDFGIJKL
pentylcyclopentan-1-one 1118 Veratraldehyde 120-14-9 BCGIK 1119
(1R,5R)-4,6,6- 18309-32-5 ACEFGIJKL trimethylbicyclo[3.1.1]hept-3-
en-2-one 1122 Verdol 13491-79-7 ACGIJKL 1127
4-(tert-butyl)cyclohexyl 10411-92-4 BDEFHJK acetate 1128
4-(tert-butyl)cyclohexyl 32210-23-4 BDEFHJK acetate 1133 Vethymine
7193-87-5 CEFGK 1134 4-methyl-4-phenylpentan-2-yl 68083-58-9 BDFHJK
acetate 1141 (Z)-1-((2- 292605-05-1 ADEFHKL
methylallyl)oxy)hex-3-ene
TABLE-US-00005 TABLE 4 List of materials with ALL MORVs from 1 to 5
Num- CAS Comment ber Material Name Number Code 7
3-methoxy-7,7-dimethyl-10- 216970-21-7 BDEFHJK
methylenebicyclo[4.3.1]decane 14 Oxyoctaline formate 65405-72-3
DFHJK 39 2,2,6,8-tetramethyl-1,2,3,4,4a,5,8,8a- 103614-86-4 DEFHIJK
octahydronaphthalen-1-ol 48 Nootkatone 4674-50-4 DHJK 183 Khusimol
16223-63-5 CEFHJK 199 Isopimpinellin 482-27-9 CFGJ 206
Iso3-methylcyclopentadecan-1-one 3100-36-5 DEFGJK 212 Isoeugenyl
benzyl ether 120-11-6 DFHJ 215 1-((2S,3S)-2,3,8,8-tetramethyl-
54464-57-2 DHJK 1,2,3,4,5,6,7,8-octahydronaphthalen-
2-yl)ethan-1-one 229 Isobornyl isobutyrate 85586-67-0 BDEFHIJK 260
2,3-dihydro-3,3-dimethyl-1H-indene- 173445-44-8 DHJK 5-propanal 261
3-(3,3-dimethyl-2,3-dihydro-1H- 173445-65-3 DHJK
inden-5-yl)propanal 281 3a,4,5,6,7,7a-hexahydro-1H-4,7- 5413-60-5
CEFGJK methanoinden-6-yl acetate 329 gamma-Eudesmol 1209-71-8 DFHJK
335 4,6,6,7,8,8-hexamethyl-1,3,4,6,7,8- 1222-05-5 DEFHJK
hexahydrocyclopenta[g]isochromene 353
(Z)-6-ethylideneoctahydro-2H-5,8- 69486-14-2 CEFGJK
methanochromen-2-one 360 8,8-dimethyl-3a,4,5,6,7,7a- 171102-41-3
DEFHJK hexahydro-1H-4,7-methanoinden-6- yl acetate 441
Octahydro-1H-4,7-methanoinden-5- 64001-15-6 DEFHJKL yl acetate 484
3a,4,5,6,7,7a-hexahydro-1H-4,7- 113889-23-9 DEFHJK
methanoinden-6-yl butyrate 487 3a,4,5,6,7,7a-hexahydro-1H-4,7-
67634-20-2 DEFHJK methanoinden-5-yl isobutyrate 488 Curzerene
17910-09-7 DHJK 501 (E)-cycloheptadec-9-en-1-one 542-46-1 DEFGJ 566
Cedryl formate 39900-38-4 BDEFHJK 567 Cedryl acetate 77-54-3 DEFHJK
569 Cedrol 77-53-2 DEFHJK 570 5-methyl-1-(2,2,3- 139539-66-5 DEFHJK
trimethylcyclopent-3-en-1-yl)-6- oxabicyclo[3.2.1]octane 573
Caryophyllene alcohol acetate 32214-91-8 DEFHJK 574 Caryolan-1-ol
472-97-9 DEFHJK 603 Bornyl isobutyrate 24717-86-0 BDEFHIJK 616
beta-Santalol 77-42-9 DEFHJK 621 beta-Patchoulline 514-51-2
BDEFGJKL 624 beta-Himachalene Oxide 57819-73-5 BDFHJK 627
(2,2-dimethoxyethyl)benzene 101-48-4 DHJK 632 beta-Cedrene 546-28-1
BDEFGJKL 663 Anisyl phenylacetate 102-17-0 DFHJ 680
2,2,6,6,7,8,8-heptamethyldecahydro- 647828-16-8 ADEFHJK
2H-indeno[4,5-b]furan 684 alpha-Vetivone 15764-04-2 DHJK 694
alpha-Santalol 115-71-9 DEFHJK 696 alpha-Patchoulene 560-32-7
ADEFHJKL 708 alpha-Gurjunene 489-40-7 BDEFHJKL 712 alpha-Eudesmol
473-16-5 DEFHJK 714 alpha-Cubebene 17699-14-8 ADEFHJKL 726
alpha-Agarofuran 5956-12-7 BDEFHJK 750 Allo-aromadendrene
25246-27-9 BDEFHJKL 764 Acetarolle 744266-61-3 DFHJK 775
7-eip-alpha-Eudesmol 123123-38-6 DEFHJK 776 7-Acetyl-1,1,3,4,4,6-
1506-02-1 DEFHJ hexamethyltetralin 788 5-Cyclohexadecenone
37609-25-9 DEFGJK 804 3-Thujopsanone 25966-79-4 BDEFHJK 872
10-epi-gamma-Eudesmol 15051-81-7 DFHJK 919
3a,4,5,6,7,7a-hexahydro-1H-4,7- 17511-60-3 CEFHJK methanoinden-6-yl
propionate 927 5-Acetyl-1,1,2,3,3,6- 15323-35-0 DEFHJK
hexamethylindan 933 Patchouli alcohol 5986-55-0 DEFHIJK 978
3a,4,5,6,7,7a-hexahydro-1H-4,7- 68039-44-1 DEFHJK methanoinden-6-yl
pivalate 1007 (2R,4a'R,8a'R)-3,7'-dimethyl- 41816-03-9 DEFHJK
3',4',4a',5',8',8a'-hexahydro-1'H- spiro[oxirane-2,2'-
[1,4]methanonaphthalene] 1022 2,2,7,9-tetramethylspiro(5.5)undec-
502847-01-0 DHIJK 8-en-1-one 1024 (Z)-2-ethyl-4-(2,2,3- 28219-61-6
DEFHJK trimethylcyclopent-3-en-1-yl)but-2- en-1-ol 1027
5-methoxyoctahydro-1H-4,7- 193425-86-4 CHJK
methanoindene-2-carbaldehyde 1029 Sclareol oxide 5153-92-4 DEFHJK
1035 Spathulenol 6750-60-3 DEFHJK 1038
1-(spiro[4.5]dec-7-en-7-yl)pent-4-en- 224031-70-3 DGJK 1-one 1060
Thujopsene 470-40-6 BDEFGJKL 1089 Tricyclone 68433-81-8 DEFHJK 1107
Valerianol 20489-45-6 DEFHJK 1129 1-((3R,3aR,7R,8aS)-3,6,8,8-
32388-55-9 DHJK tetramethyl-2,3,4,7,8,8a-hexahydro-
1H-3a,7-methanoazulen-5-yl)ethan- 1-one 1131 Methyl (Z)-2-(((2,4-
68738-99-8 DEFHJ dimethylcyclohex-3-en-1-
yl)methylene)amino)benzoate 1136 Vetivert Acetate 117-98-6 DEFHJK
1137 Decahydro-3H-spiro[furan-2,5'- 68480-11-5 DEFGJKL
[4,7]methanoindene] 1140 (1aR,4S,4aS,7R,7aS,7bS)-1,1,4,7- 552-02-3
DEFHJK tetramethyldecahydro-1H- cyclopropa[e]azulen-4-ol 1142
3,5,5,6,7,8,8-heptamethyl-5,6,7,8- 127459-79-4 DHJ
tetrahydronaphthalene-2-carbonitrile 1143 (1S,2S,3S,5R)-2,6,6-
133636-82-5 DEFHJK trimethylspiro[bicyclo[3.1.1]heptane-
3,1'-cyclohexan]-2'-en-4'-one 1144
1',1',5',5'-tetramethylhexahydro- 154171-76-3 DEFHJK
2'H,5'H-spiro[[1,3]dioxolane-2,8'- [2,4a]methanonaphthalene] 1145
1',1',5',5'-tetramethylhexahydro- 154171-77-4 DEFHJK
2'H,5'H-spiro[[1,3]dioxolane-2,8'- [2,4a]methanonaphthalene] K
TABLE-US-00006 TABLE 5 List of materials with ALL MORVs greater
than 5 to 10 Number Material Name CAS Number Comment Code 248
Hydroxymethyl 59056-64-3 BDEFHJK isolongifolene
TABLE-US-00007 TABLE 6 List of materials with ALL MORVs from 0.5 to
less than 1 Number Material Name CAS Number Comment Code 472 Decyl
anthranilate 18189-07-6 DEFHJ 526 (Z)-3-methyl-2-(pent- 488-10-8
BCHIJKL 2-en-1-yl)cyclopent- 2-en-1-one
Compositions and Methods
[0019] A composition comprising a malodor reduction material having
an MORV of at least 0.5, from about 0.5 to about 10, from 0.5 to
about 10, from about 1 to about 10, or from about 1 to about 5 is
disclosed.
[0020] In one aspect, said composition comprises a malodor
reduction material is selected from the group consisting of Table 1
materials Table 2 materials, Table 3 materials and mixtures
thereof; in one aspect said material is selected from the group
consisting of Table 1 materials 3; 4; 7; 9; 21; 25; 29; 30; 31; 32;
33; 34; 35; 42; 49; 50; 62; 64; 65; 67; 70; 91; 92; 93; 98; 101;
102; 103; 108; 110; 114; 117; 119; 122; 123; 126; 130; 142; 145;
146; 149; 155; 159; 167; 168; 170; 178; 186; 189; 190; 192; 193;
208; 209; 210; 218; 228; 229; 231; 243; 254; 256; 259; 267; 274;
278; 280; 281; 290; 294; 317; 318; 322; 325; 333; 338; 342; 344;
358; 362; 364; 375; 386; 394; 397; 398; 415; 421; 424; 428; 429;
436; 441; 444; 445; 449; 453; 461; 466; 468; 471; 473; 474; 475;
491; 519; 520; 524; 527; 530; 531; 532; 534; 544; 546; 551; 555;
565; 578; 580; 581; 584; 586; 587; 589; 603; 604; 606; 609; 611;
612; 614; 615; 618; 621; 627; 628; 631; 632; 633; 639; 649; 659;
668; 683; 686; 692; 693; 696; 698; 702; 708; 711; 714; 715; 717;
720; 725; 730; 738; 742; 748; 750; 752; 763; 766; 767; 768; 770;
774; 778; 781; 786; 791; 792; 800; 802; 806; 814; 821; 826; 827;
828; 829; 834; 837; 839; 840; 850; 852; 856; 864; 865; 866; 868;
869; 871; 873; 876; 877; 878; 879; 884; 897; 905; 914; 926; 928;
929; 937; 946; 947; 950; 955; 969; 973; 974; 982; 993; 1006; 1008;
1010; 1016; 1020; 1021; 1031; 1037; 1043; 1045; 1053; 1057; 1060;
1062; 1064; 1066; 1067; 1070; 1072; 1073; 1077; 1078; 1082; 1102;
1104; 1105; 1120; 1125; 1137; 1138; 1144; 1145, Table 2 materials
565; 631; 659; 715, Table 3 materials 9; 12; 19; 20; 21; 24; 25;
27; 32; 34; 53; 55; 59; 64; 65; 70; 73; 81; 84; 96; 97; 98; 108;
110; 111; 114; 116; 119; 125; 126; 133; 142; 146; 147; 150; 154;
157; 159; 163; 166; 167; 169; 178; 189; 192; 194; 198; 201; 204;
205; 228; 231; 232; 237; 239; 254; 256; 258; 264; 270; 273; 282;
283; 284; 287; 290; 302; 306; 312; 319; 322; 325; 333; 338; 344;
346; 354; 358; 362; 365; 366; 375; 376; 387; 412; 419; 420; 428;
429; 437; 438; 439; 443; 444; 447; 448; 461; 469; 474; 477; 481;
491; 492; 495; 496; 509; 512; 517; 518; 522; 525; 530; 535; 536;
538; 540; 542; 544; 547; 549; 554; 555; 556; 557; 575; 576; 579;
583; 585; 588; 589; 604; 605; 609; 617; 619; 633; 640; 645; 647;
651; 652; 662; 664; 665; 667; 683; 686; 687; 693; 698; 699; 701;
717; 725; 730; 740; 742; 744; 745; 760; 761; 777; 779; 784; 789;
792; 797; 806; 810; 812; 817; 819; 820; 827; 828; 832; 835; 836;
838; 839; 845; 846; 847; 848; 850; 851; 858; 865; 875; 878; 879;
882; 883; 888; 889; 891; 899; 900; 901; 902; 903; 904; 909; 914;
931; 937; 940; 946; 947; 956; 977; 981; 986; 987; 994; 995; 1001;
1004; 1008; 1010; 1011; 1017; 1018; 1019; 1020; 1030; 1031; 1039;
1040; 1041; 1051; 1053; 1054; 1055; 1057; 1058; 1061; 1062; 1069;
1071; 1076; 1081; 1082; 1098; 1102; 1104; 1105; 1115; 1119; 1120;
1122; 1127; 1128; 1141 and mixtures thereof, in one aspect, said
composition comprises a malodor reduction material selected from
the group consisting of Table 1 materials 3; 4; 7; 9; 21; 25; 29;
30; 31; 32; 34; 35; 42; 49; 50; 62; 64; 65; 67; 70; 91; 92; 93; 98;
101; 102; 103; 108; 114; 117; 122; 123; 126; 130; 142; 145; 146;
149; 155; 159; 167; 168; 170; 178; 186; 189; 190; 192; 193; 208;
209; 210; 218; 228; 229; 231; 243; 254; 256; 259; 267; 274; 278;
280; 281; 290; 294; 317; 318; 322; 325; 333; 338; 342; 344; 358;
362; 364; 375; 386; 394; 397; 398; 415; 421; 424; 428; 429; 436;
441; 444; 445; 449; 453; 461; 466; 468; 471; 473; 474; 475; 491;
519; 520; 524; 527; 530; 531; 532; 534; 544; 546; 551; 555; 565;
578; 580; 581; 584; 586; 587; 589; 603; 604; 606; 609; 611; 612;
614; 615; 618; 621; 627; 628; 631; 632; 633; 639; 649; 659; 668;
683; 686; 692; 693; 696; 698; 702; 708; 711; 714; 715; 717; 720;
725; 730; 742; 748; 750; 752; 763; 766; 767; 768; 770; 774; 778;
781; 786; 791; 792; 800; 802; 806; 814; 821; 826; 827; 828; 829;
834; 837; 839; 840; 850; 852; 856; 864; 865; 866; 868; 869; 871;
873; 876; 877; 878; 879; 884; 897; 905; 914; 926; 928; 929; 937;
946; 947; 950; 955; 969; 973; 974; 982; 993; 1006; 1008; 1010;
1016; 1020; 1021; 1031; 1037; 1043; 1045; 1053; 1057; 1060; 1062;
1066; 1067; 1070; 1072; 1073; 1077; 1078; 1082; 1102; 1104; 1105;
1120; 1125; 1137; 1138; 1144; 1145, Table 2 materials 565; 631;
659; 715, Table 3 materials 9; 12; 19; 20; 21; 24; 25; 27; 32; 34;
53; 55; 59; 64; 65; 70; 73; 81; 84; 96; 97; 98; 108; 110; 111; 114;
116; 119; 125; 126; 133; 142; 146; 147; 150; 154; 157; 159; 163;
166; 167; 169; 178; 189; 192; 194; 198; 201; 204; 205; 228; 231;
232; 237; 239; 254; 256; 258; 264; 270; 273; 282; 283; 284; 287;
290; 306; 312; 319; 322; 325; 333; 338; 344; 346; 354; 358; 362;
365; 366; 375; 376; 387; 412; 419; 420; 428; 429; 437; 438; 439;
443; 444; 447; 448; 461; 469; 474; 477; 481; 491; 492; 495; 496;
509; 512; 517; 518; 522; 525; 530; 535; 536; 538; 540; 542; 544;
547; 549; 554; 555; 556; 557; 575; 576; 579; 583; 585; 588; 589;
604; 605; 609; 617; 619; 633; 640; 645; 647; 651; 652; 662; 664;
665; 667; 683; 686; 687; 693; 698; 699; 701; 717; 725; 730; 740;
742; 744; 745; 760; 761; 777; 779; 784; 789; 792; 797; 806; 810;
812; 817; 819; 820; 827; 828; 832; 835; 836; 838; 839; 845; 846;
847; 848; 850; 851; 858; 865; 875; 878; 879; 882; 883; 888; 889;
891; 899; 900; 901; 902; 903; 904; 909; 914; 931; 937; 940; 946;
947; 956; 977; 981; 986; 987; 994; 995; 1001; 1004; 1008; 1010;
1011; 1017; 1018; 1019; 1020; 1030; 1031; 1039; 1040; 1041; 1051;
1053; 1054; 1055; 1057; 1058; 1061; 1062; 1069; 1071; 1076; 1081;
1082; 1098; 1102; 1104; 1105; 1115; 1119; 1120; 1122; 1127; 1128;
1141 and mixtures thereof, in one aspect, said composition
comprises a malodor reduction material selected from the group
consisting of Table 1 materials 4; 29; 30; 31; 32; 50; 65; 67; 70;
92; 93; 103; 122; 123; 145; 167; 168; 208; 210; 218; 243; 256; 278;
290; 364; 386; 394; 424; 436; 453; 468; 524; 527; 532; 578; 580;
584; 589; 609; 618; 627; 668; 683; 702; 711; 763; 767; 770; 786;
802; 821; 829; 837; 839; 840; 852; 864; 866; 869; 873; 876; 878;
905; 950; 973; 993; 1010; 1037; 1043; 1066; 1070; 1073; 1077; 1078;
1102; 1120; 1125, Table 3 materials 12; 19; 20; 24; 27; 32; 53; 55;
65; 70; 73; 97; 116; 119; 125; 154; 163; 167; 194; 198; 201; 204;
239; 256; 264; 270; 273; 282; 283; 284; 290; 319; 346; 365; 376;
387; 412; 419; 437; 439; 443; 447; 469; 477; 481; 495; 518; 525;
538; 540; 542; 547; 583; 588; 589; 609; 617; 619; 652; 683; 740;
744; 745; 760; 784; 789; 810; 812; 817; 838; 839; 847; 848; 851;
858; 875; 878; 882; 889; 891; 901; 903; 904; 940; 987; 1001; 1010;
1011; 1018; 1041; 1051; 1054; 1055; 1069; 1081; 1098; 1102; 1120;
1127; 1128; 1141.
[0021] In another aspect, said composition comprises a malodor
reduction material selected from the group consisting of Table 1
materials 3; 7; 9; 25; 29; 30; 32; 33; 34; 35; 42; 49; 62; 65; 67;
70; 91; 92; 98; 101; 102; 103; 108; 110; 114; 117; 119; 122; 126;
130; 142; 145; 159; 167; 168; 178; 186; 189; 190; 192; 193; 208;
209; 210; 218; 228; 229; 231; 243; 254; 256; 259; 267; 274; 278;
280; 281; 290; 294; 322; 325; 333; 338; 342; 344; 358; 362; 386;
394; 397; 415; 421; 424; 428; 429; 436; 441; 444; 445; 449; 453;
461; 468; 471; 473; 474; 475; 519; 520; 527; 530; 534; 544; 546;
551; 555; 565; 578; 580; 581; 587; 589; 603; 604; 606; 609; 614;
615; 618; 621; 628; 631; 632; 633; 639; 649; 659; 668; 683; 686;
692; 693; 696; 698; 702; 708; 711; 714; 715; 717; 720; 725; 730;
748; 750; 763; 766; 767; 768; 774; 778; 781; 792; 802; 806; 814;
821; 826; 827; 834; 839; 840; 850; 852; 865; 866; 868; 869; 873;
876; 877; 878; 884; 897; 905; 926; 928; 929; 950; 955; 969; 973;
974; 993; 1006; 1008; 1016; 1020; 1021; 1031; 1037; 1043; 1045;
1053; 1057; 1060; 1072; 1104; 1105; 1120; 1125; 1137; 1138; 1144;
1145 and table 3 materials 9; 12; 19; 21; 25; 32; 34; 53; 55; 59;
65; 70; 81; 84; 97; 98; 108; 110; 114; 116; 119; 126; 133; 142;
147; 150; 157; 159; 163; 166; 167; 178; 189; 192; 198; 201; 204;
205; 228; 231; 232; 237; 239; 254; 256; 258; 264; 270; 273; 282;
283; 290; 302; 306; 319; 322; 325; 333; 338; 344; 346; 358; 362;
365; 376; 387; 412; 420; 428; 429; 437; 438; 439; 444; 447; 461;
469; 474; 477; 481; 495; 496; 509; 512; 525; 530; 535; 536; 538;
540; 542; 544; 547; 549; 579; 583; 588; 589; 604; 605; 609; 617;
619; 633; 640; 645; 651; 652; 662; 664; 665; 667; 683; 686; 693;
698; 699; 744; 745; 760; 761; 777; 779; 784; 792; 797; 806; 810;
817; 819; 820; 827; 832; 835; 836; 838; 839; 845; 846; 847; 850;
851; 858; 865; 878; 882; 883; 888; 901; 903; 904; 909; 931; 987;
995; 1001; 1008; 1017; 1018; 1019; 1020; 1030; 1031; 1040; 1041;
1053; 1054; 1055; 1057; 1058; 1069; 1076; 1098; 1127; 1128; 1141
and mixtures thereof.
[0022] In another aspect, said composition comprises a malodor
reduction material selected from the group consisting of Table 1
materials 1; 2; 3; 7; 9; 10; 11; 13; 14; 18; 21; 22; 23; 25; 28;
29; 30; 31; 32; 33; 35; 36; 38; 39; 47; 48; 49; 50; 52; 57; 62; 63;
64; 67; 68; 69; 71; 74; 75; 76; 77; 78; 79; 80; 83; 85; 91; 92; 93;
100; 101; 102; 103; 104; 105; 109; 114; 119; 120; 122; 123; 128;
134; 135; 137; 140; 142; 145; 148; 149; 152; 153; 158; 159; 161;
162; 174; 175; 176; 177; 178; 182; 183; 184; 185; 186; 189; 192;
195; 196; 197; 206; 208; 209; 210; 211; 212; 215; 221; 227; 228;
229; 230; 231; 233; 234; 238; 242; 243; 244; 246; 252; 253; 260;
261; 263; 267; 269; 271; 274; 276; 277; 280; 285; 289; 290; 292;
293; 294; 295; 296; 300; 301; 303; 307; 316; 317; 318; 322; 324;
325; 328; 329; 330; 331; 333; 334; 335; 336; 338; 339; 342; 343;
344; 349; 352; 356; 358; 359; 360; 361; 362; 363; 364; 368; 369;
370; 371; 372; 378; 381; 385; 386; 388; 390; 391; 397; 398; 413;
414; 416; 418; 421; 424; 426; 428; 429; 432; 441; 444; 449; 453;
457; 459; 461; 462; 463; 465; 466; 467; 468; 470; 471; 473; 475;
478; 479; 480; 482; 484; 486; 487; 488; 497; 498; 501; 502; 503;
505; 519; 520; 521; 524; 529; 532; 534; 537; 541; 544; 548; 550;
552; 558; 559; 560; 561; 562; 563; 565; 566; 567; 568; 569; 570;
571; 572; 573; 574; 577; 578; 582; 584; 589; 591; 592; 594; 599;
600; 601; 603; 604; 606; 607; 608; 609; 610; 611; 613; 614; 615;
616; 618; 620; 621; 624; 625; 626; 628; 631; 632; 633; 635; 644;
650; 653; 659; 660; 661; 663; 671; 673; 674; 675; 676; 677; 678;
679; 680; 681; 684; 686; 691; 692; 693; 694; 696; 697; 698; 700;
702; 704; 706; 707; 708; 709; 710; 711; 712; 713; 714; 715; 716;
717; 718; 719; 720; 721; 722; 723; 724; 725; 726; 727; 731; 741;
746; 750; 752; 754; 757; 758; 763; 766; 769; 770; 771; 774; 775;
776; 778; 781; 782; 788; 791; 800; 802; 804; 806; 814; 821; 826;
827; 828; 831; 837; 839; 840; 849; 850; 852; 856; 866; 868; 869;
870; 871; 872; 873; 876; 877; 878; 879; 881; 884; 885; 886; 890;
892; 893; 894; 905; 908; 912; 913; 914; 916; 919; 920; 922; 925;
926; 927; 930; 933; 939; 941; 942; 943; 945; 947; 948; 950; 951;
953; 954; 959; 965; 967; 973; 978; 985; 988; 998; 1000; 1003; 1006;
1007; 1008; 1009; 1010; 1016; 1022; 1023; 1024; 1025; 1028; 1029;
1031; 1032; 1033; 1035; 1038; 1045; 1046; 1047; 1053; 1057; 1060;
1062; 1063; 1065; 1067; 1070; 1073; 1075; 1077; 1078; 1082; 1089;
1090; 1093; 1095; 1097; 1099; 1102; 1104; 1105; 1107; 1116; 1120;
1121; 1126; 1129; 1131; 1135; 1136; 1137; 1138; 1140; 1142; 1143;
1144; 1145; 1147, Table 2 materials 2; 23; 185; 227; 230; 246; 248;
343; 359; 565; 631; 659; 674; 678; 679; 715; 758; 1028; 1097; and
Table 3 materials 1; 9; 12; 13; 19; 20; 21; 24; 25; 27; 32; 38; 54;
55; 59; 64; 68; 71; 72; 79; 81; 83; 85; 100; 105; 109; 111; 114;
119; 133; 134; 135; 137; 140; 142; 147; 148; 150; 151; 152; 153;
154; 157; 159; 162; 178; 181; 189; 191; 192; 195; 197; 204; 211;
228; 231; 233; 234; 237; 238; 242; 246; 252; 264; 270; 273; 275;
277; 283; 285; 289; 290; 292; 293; 295; 300; 301; 302; 306; 308;
310; 312; 319; 322; 325; 331; 333; 334; 336; 338; 339; 344; 346;
354; 355; 356; 358; 361; 362; 363; 370; 371; 372; 378; 381; 385;
387; 388; 390; 412; 413; 418; 420; 428; 429; 432; 437; 438; 444;
447; 448; 454; 455; 457; 461; 465; 467; 472; 477; 478; 479; 480;
481; 482; 495; 496; 497; 502; 503; 504; 509; 510; 512; 515; 517;
518; 522; 525; 529; 535; 536; 537; 540; 541; 544; 550; 557; 558;
559; 560; 561; 568; 571; 572; 575; 589; 592; 594; 599; 600; 602;
604; 609; 619; 620; 625; 626; 633; 641; 644; 645; 650; 653; 662;
667; 672; 673; 675; 676; 681; 686; 687; 693; 697; 698; 700; 703;
704; 706; 707; 716; 717; 718; 722; 725; 744; 745; 746; 757; 769;
771; 779; 782; 799; 806; 819; 820; 827; 828; 836; 838; 839; 847;
850; 875; 878; 879; 880; 881; 888; 889; 890; 891; 893; 899; 900;
901; 903; 909; 912; 914; 920; 922; 930; 939; 940; 941; 945; 947;
948; 953; 954; 958; 959; 960; 965; 967; 971; 986; 987; 994; 995;
998; 1000; 1001; 1003; 1005; 1008; 1009; 1010; 1011; 1017; 1018;
1023; 1031; 1032; 1046; 1047; 1051; 1052; 1053; 1054; 1055; 1057;
1058; 1061; 1062; 1063; 1074; 1075; 1076; 1082; 1088; 1093; 1095;
1099; 1102; 1104; 1105; 1115; 1116; 1120; 1127; 1128; 1134; 1135;
1141; 1147 and mixtures thereof, in one aspect, said composition
comprises a material selected from the group consisting of Table 1
materials 1; 2; 3; 7; 9; 10; 11; 13; 14; 18; 21; 22; 23; 25; 28;
29; 30; 31; 32; 35; 36; 38; 39; 47; 48; 49; 50; 52; 57; 62; 63; 64;
67; 68; 69; 71; 74; 75; 76; 77; 78; 79; 80; 83; 85; 91; 92; 93;
100; 101; 102; 103; 104; 105; 109; 114; 120; 122; 123; 128; 134;
135; 137; 140; 142; 145; 148; 149; 152; 153; 158; 159; 161; 162;
174; 175; 176; 177; 178; 182; 183; 184; 185; 186; 189; 192; 195;
196; 197; 206; 208; 209; 210; 211; 212; 215; 221; 227; 228; 229;
230; 231; 233; 234; 238; 242; 243; 244; 246; 252; 253; 260; 261;
263; 267; 269; 271; 274; 276; 277; 280; 285; 289; 290; 292; 293;
294; 295; 296; 300; 301; 303; 307; 316; 317; 318; 322; 324; 325;
328; 329; 330; 331; 333; 334; 335; 336; 338; 339; 342; 343; 344;
349; 352; 356; 358; 359; 360; 361; 362; 363; 364; 368; 369; 370;
371; 372; 378; 381; 385; 386; 388; 390; 391; 397; 398; 413; 414;
416; 418; 421; 424; 426; 428; 429; 432; 441; 444; 449; 453; 457;
459; 461; 462; 463; 465; 466; 467; 468; 470; 471; 473; 475; 478;
479; 480; 482; 484; 486; 487; 488; 497; 498; 501; 502; 503; 505;
519; 520; 521; 524; 529; 532; 534; 537; 541; 544; 548; 550; 552;
558; 559; 560; 561; 562; 563; 565; 566; 567; 568; 569; 570; 571;
572; 573; 574; 577; 578; 582; 584; 589; 591; 592; 594; 599; 600;
603; 604; 606; 607; 608; 609; 610; 611; 613; 614; 615; 616; 618;
620; 621; 624; 625; 626; 628; 631; 632; 633; 635; 644; 650; 653;
659; 660; 661; 663; 671; 673; 674; 675; 676; 677; 678; 679; 680;
681; 684; 686; 691; 692; 693; 694; 696; 697; 698; 700; 702; 704;
706; 707; 708; 709; 710; 711; 712; 713; 714; 715; 716; 717; 718;
719; 720; 721; 722; 723; 724; 725; 726; 727; 731; 741; 746; 750;
752; 754; 757; 758; 763; 766; 769; 770; 771; 774; 775; 776; 778;
781; 782; 788; 791; 800; 802; 804; 806; 814; 821; 826; 827; 828;
831; 837; 839; 840; 849; 850; 852; 856; 866; 868; 869; 870; 871;
872; 873; 876; 877; 878; 879; 881; 884; 885; 886; 890; 892; 893;
894; 905; 908; 912; 913; 914; 916; 919; 920; 922; 925; 926; 927;
930; 933; 939; 941; 942; 943; 945; 947; 948; 950; 951; 953; 954;
959; 965; 967; 973; 978; 985; 988; 998; 1000; 1003; 1006; 1007;
1008; 1009; 1010; 1016; 1022; 1023; 1024; 1025; 1028; 1029; 1031;
1032; 1033; 1035; 1038; 1045; 1046; 1047; 1053; 1057; 1060; 1062;
1063; 1065; 1067; 1070; 1073; 1075; 1077; 1078; 1082; 1089; 1090;
1093; 1095; 1097; 1099; 1102; 1104; 1105; 1107; 1116; 1120; 1121;
1126; 1129; 1131; 1135; 1136; 1137; 1138; 1140; 1142; 1143; 1144;
1145; 1147, Table 2 materials 2; 23; 185; 227; 230; 246; 248; 343;
359; 565; 631; 659; 674; 678; 679; 715; 758; 1028; 1097; and Table
3 materials 1; 9; 12; 13; 19; 20; 21; 24; 25; 27; 32; 38; 54; 55;
59; 64; 68; 71; 72; 79; 81; 83; 85; 100; 105; 109; 111; 114; 119;
133; 134; 135; 137; 140; 142; 147; 148; 150; 151; 152; 153; 154;
157; 159; 162; 178; 181; 189; 191; 192; 195; 197; 204; 211; 228;
231; 233; 234; 237; 238; 242; 246; 252; 264; 270; 273; 275; 277;
283; 285; 289; 290; 292; 293; 295; 300; 301; 306; 308; 310; 312;
319; 322; 325; 331; 333; 334; 336; 338; 339; 344; 346; 354; 355;
356; 358; 361; 362; 363; 370; 371; 372; 378; 381; 385; 387; 388;
390; 412; 413; 418; 420; 428; 429; 432; 437; 438; 444; 447; 448;
454; 455; 457; 461; 465; 467; 472; 477; 478; 479; 480; 481; 482;
495; 496; 497; 502; 503; 504; 509; 510; 512; 515; 517; 518; 522;
525; 529; 535; 536; 537; 540; 541; 544; 550; 557; 558; 559; 560;
561; 568; 571; 572; 575; 589; 592; 594; 599; 600; 602; 604; 609;
619; 620; 625; 626; 633; 641; 644; 645; 650; 653; 662; 667; 672;
673; 675; 676; 681; 686; 687; 693; 697; 698; 700; 703; 704; 706;
707; 716; 717; 718; 722; 725; 744; 745; 746; 757; 769; 771; 779;
782; 799; 806; 819; 820; 827; 828; 836; 838; 839; 847; 850; 875;
878; 879; 880; 881; 888; 889; 890; 891; 893; 899; 900; 901; 903;
909; 912; 914; 920; 922; 930; 939; 940; 941; 945; 947; 948; 953;
954; 958; 959; 960; 965; 967; 971; 986; 987; 994; 995; 998; 1000;
1001; 1003; 1005; 1008; 1009; 1010; 1011; 1017; 1018; 1023; 1031;
1032; 1046; 1047; 1051; 1052; 1053; 1054; 1055; 1057; 1058; 1061;
1062; 1063; 1074; 1075; 1076; 1082; 1088; 1093; 1095; 1099; 1102;
1104; 1105; 1115; 1116; 1120; 1127; 1128; 1134; 1135; 1141; 1147
and mixtures thereof.
[0023] In another aspect, said composition comprises a malodor
reduction material selected from the group consisting of Table 1
materials 4; 13; 16; 17; 18; 21; 32; 33; 34; 35; 37; 42; 49; 57;
76; 126; 145; 156; 167; 168; 174; 190; 199; 206; 208; 210; 242;
247; 249; 259; 277; 281; 286; 289; 318; 353; 370; 371; 372; 373;
378; 407; 417; 424; 425; 429; 449; 457; 468; 474; 479; 480; 482;
485; 501; 524; 527; 529; 537; 562; 578; 580; 587; 589; 592; 595;
612; 615; 618; 621; 632; 638; 639; 649; 683; 702; 711; 733; 735;
736; 741; 748; 767; 771; 786; 788; 824; 834; 839; 866; 868; 877;
905; 924; 955; 969; 974; 976; 980; 982; 993; 1016; 1037; 1038;
1042; 1060; 1075; 1077; 1078; 1090; 1091; 1117; 1137; 1146, Table 3
materials 13; 21; 27; 32; 34; 37; 73; 81; 107; 115; 125; 126; 157;
163; 167; 169; 194; 198; 201; 205; 239; 242; 277; 282; 286; 287;
289; 319; 366; 370; 371; 372; 376; 378; 407; 417; 419; 429; 437;
439; 442; 443; 457; 474; 479; 480; 482; 485; 495; 496; 509; 512;
525; 529; 537; 549; 556; 576; 579; 583; 585; 588; 589; 592; 617;
619; 638; 640; 641; 652; 664; 665; 683; 740; 743; 760; 771; 779;
784; 810; 812; 820; 839; 845; 846; 847; 858; 875; 883; 888; 901;
902; 903; 904; 940; 981; 1001; 1002; 1017; 1018; 1019; 1039; 1040;
1051; 1054; 1071; 1075; 1081; 1088; 1091; 1115; 1118; 1119; 1122;
1133; 114, and mixtures thereof, in one aspect, said composition
comprises a material selected from Table 1 materials 4; 21; 32; 33;
34; 35; 42; 49; 145; 167; 168; 190; 208; 210; 259; 281; 424; 429;
449; 468; 474; 524; 527; 578; 580; 587; 589; 612; 615; 618; 621;
632; 639; 649; 683; 702; 711; 748; 767; 786; 834; 839; 866; 868;
877; 905; 955; 969; 974; 982; 993; 1016; 1037; 1060; 1077; 1078;
1137, Table 3 materials 21; 27; 32; 34; 73; 81; 125; 126; 157; 163;
167; 169; 194; 198; 201; 205; 239; 282; 287; 319; 366; 376; 419;
429; 437; 439; 443; 474; 495; 496; 509; 512; 525; 549; 556; 576;
579; 583; 585; 588; 589; 617; 619; 640; 652; 664; 665; 683; 740;
760; 779; 784; 810; 812; 820; 839; 845; 846; 847; 858; 875; 883;
888; 901; 902; 903; 904; 940; 981; 1001; 1017; 1018; 1019; 1039;
1040; 1051; 1054; 1071; 1081; 1115; 1122 and mixtures thereof.
[0024] In one aspect, said composition comprising a malodor
reduction material, in one aspect, comprises a malodor reduction
material having a Universal MORV.
[0025] Preferably, said composition comprising a malodor reduction
material having a Universal MORV comprises a malodor reduction
material selected from the group consisting of Table 4 materials 7;
229; 281; 441; 603; 621; 627; 632; 696; 708; 714; 750; 1060; 1137;
1144; 1145, and Table 6 material 627 and mixtures thereof. In one
aspect, such materials are selected from Table 4 material 627 and
mixtures thereof are disclosed.
[0026] In one aspect, said composition comprising a malodor
reduction material having a Universal MORV. In one aspect, said
composition comprises, a malodor reduction material selected from
the group consisting of Table 4 materials 7; 229; 281; 441; 603;
621; 632; 696; 708; 714; 750; 1060; 1137; 1144; 1145, and mixtures
thereof are disclosed.
[0027] In one aspect, said composition comprising a malodor
reduction material having a Universal MORV comprises, a malodor
reduction material selected from the group consisting of Table 4
materials 7; 14; 39; 48; 183; 206; 212; 215; 229; 260; 261; 329;
335; 360; 441; 484; 487; 488; 501; 566; 567; 569; 570; 573; 574;
603; 616; 621; 624; 632; 663; 680; 684; 694; 696; 708; 712; 714;
726; 750; 775; 776; 788; 804; 872; 919; 927; 933; 978; 1007; 1022;
1024; 1029; 1035; 1038; 1060; 1089; 1107; 1129; 1131; 1136; 1137;
1140; 1142; 1143; 1144; 1145, Table 5 materials 248, and Table 6
material 472 and mixtures thereof.
[0028] In one aspect, said composition comprising a malodor
reduction material having a Universal MORV comprises, a malodor
reduction material selected from the group consisting of Table 4
materials 199; 206; 281; 353; 501; 621; 632; 788; 1038; 1060; 1137
and mixtures thereof. In one aspect, such materials are selected
from Table 4 281; 621; 632; 1060; 1137 and mixtures thereof.
[0029] A composition according to any preceding embodiment wherein
said malodor reduction material is not a material selected from the
group consisting of 302; 288; 50; 157; 1017; 888; 64; 1054; 832;
375; 390; 745; 504; 505; 140; 1012; 498; 362; 103; 356; 1074; 908;
1127; 475; 918; 687; 611; 317; 9; 141; 550; 602; 913; 1005; 521;
10; 215; 370; 335; 378; 1121; 360; 565; 1136; 1129; 655; 369; 1065;
914; 757; 601; 478; 889; 891; 358; 973; 162; 554; 522; 312; 125;
26; 418; 92; 586; 1026; 218; 31; 828; 871; 829; 1066; 287; 269;
769; 701; 1118; 70; 946; 142; 109; 108 and mixtures thereof.
[0030] A composition according to any preceding embodiment, said
malodor reduction composition being a consumer product, said
consumer comprising a total of, based on total consumer product
weight, from about 0.0001% to about 100% of one or more of said
malodor reduction materials and an adjunct material is
disclosed.
[0031] In one aspect, said malodor reduction composition that is a
consumer product is a laundry detergent that comprises a total of,
based on total consumer product weight, from about 0.0001% to about
10%, in one aspect, from about 0.001% to about 5%, in one aspect,
from about 0.1% to about 3%, in one aspect, from about 0.3% to
about 2% of one or more of said malodor reduction materials and, a
material selected from the group consisting of surfactants,
builders, chelating agents, dye transfer inhibiting agents,
dispersants, enzymes, and enzyme stabilizers, catalytic materials,
bleach activators, a fabric softener active, hydrogen peroxide,
sources of hydrogen peroxide, preformed peracids, polymeric
dispersing agents, clay soil removal/anti-redeposition agents,
brighteners, suds suppressors, dyes, hueing dyes, perfumes, perfume
delivery systems, structure elasticizing agents, carriers,
structurants, hydrotropes, processing aids, solvents, pigments and
mixtures thereof, in none aspect, said laundry detergent comprises
an adjunct material selected from the group consisting of an
organic acid, in one aspect, citric acid and/or lactic acid,
hydrogenated castor oil, ethoxylated polyethleneimines, in one
aspect, PEI 600 EO 20 and/or PEI 600, an enzyme, in one aspect, a
cold water amylase, cold water protease and/or xylogluconase.
[0032] In one aspect, said malodor reduction composition that is a
consumer product is air care composition that comprises a total of,
based on total consumer product weight, from about 0.001% to about
100%, in none apect, from 0.01 to 10%, of one or more of said
malodor reduction materials and, optionally, one or more materials
selected from the group consisting of surfactants, antimicrobial
agents, wetting agents, buffering agents, cyclodextrins,
propellants, and solvents.
[0033] In one aspect, said malodor reduction composition that is a
consumer product is a liquid fabric enhancer that comprises a total
of, based on total composition weight, from about 0.05% to about
10% of one or more of said malodor reduction materials and, a
fabric softener active selected from the group consisting of a
quaternary ammonium compound, a silicone polymer, a polysaccharide,
a clay, an amine, a fatty ester, a dispersible polyolefin, a
polymer latex and mixtures thereof, in one aspect, said quaternary
ammonium compound is selected from the group consisting of
bis-(2-hydroxypropyl)-dimethylammonium methylsulphate fatty acid
ester, 1,2-di(acyloxy)-3-trimethylammoniopropane chloride,
N,N-bis(stearoyl-oxy-ethyl) N,N-dimethyl ammonium chloride,
N,N-bis(tallowoyl-oxy-ethyl) N,N-dimethyl ammonium chloride,
N,N-bis(stearoyl-oxy-ethyl) N-(2 hydroxyethyl) N-methyl ammonium
methylsulfate, 1,2 di (stearoyl-oxy) 3 trimethyl ammoniumpropane
chloride, dicanoladimethylammonium chloride,
di(hard)tallowdimethylammonium chloride dicanoladimethylammonium
methylsulfate,
1-methyl-1-stearoylamidoethyl-2-stearoylimidazolinium
methylsulfate, 1-tallowylamidoethyl-2-tallowylimidazoline,
Dipalmethyl Hydroxyethylammoinum Methosulfate and mixtures thereof,
in one aspect, said fabric softening active has an Iodine Value of
between 0-140, in one aspect, 5-100, in one aspect,10-80, in one
aspect, 15-70, in one aspect 18-25.
[0034] In one aspect, said malodor reduction composition that is a
consumer product is a fabric enhancer solid particle or bead
composition comprising from 0.05% to about 10% of one or more of
said malodor reduction materials and at least about 25% PEG
8000.
[0035] In one aspect, said malodor reduction composition that is a
consumer product is a soluble unit-dose composition contained
within a PVA film.
[0036] In one aspect, said malodor reduction composition that is a
consumer product is a fabric softener dryer added sheet
composition, said fabric softener dryer added sheet composition
comprising from 0.05% to about 10% of one or more of said malodor
reduction materials and impregnated onto a non-woven sheet.
[0037] In one aspect, said malodor reduction composition that is a
consumer product is a spray-dried laundry detergent powder, said
composition comprising from about 0.05% to about 20% of one or more
of said malodor reduction materials and at least 10% solids chosen
from the following list or combinations thereof: sodium carbonate,
sodium sulfate, carboxy methyl cellulose powder, a polymer
comprising an acrylate monomer.
[0038] In one aspect, said malodor reduction composition that is a
consumer product is a plastic film said plastic film comprising
LLDPE, LDPE, HDPE, and/or compostable film, in one aspect, said
plastic film comprises about 0.5 mg to about 100 mg of said malodor
reduction composition per 20 grams of said plastic film, in one
aspect, said malodor reduction composition is present in the amount
of about 5 mg to about 30 mg per 20 grams of said plastic film, in
one aspect, said malodor reduction composition is present in the
amount of about 5 mg to about 15 mg per 20 grams of said plastic
film.
[0039] In one aspect, said malodor reduction composition that is a
consumer product is an absorbent article said absorbent article
comprising a total of, based on total consumer product weight, from
about 0.1% to about 75%, in one aspect, from about 1% to about 50%,
in one aspect, from about 5% to about 40%, in one aspect, from
about 12% to about 30% of one or more of said malodor reduction
materials and, wherein the article comprises a topsheet, a
backsheet, an absorbent core disposed between the topsheet and the
backsheet, and an acquisition layer disposed between the topsheet
and the absorbent core, wherein the malodor reduction composition
is disposed on one of the backsheet, absorbent core, or acquisition
layer, in one aspect, said absorbant article comprises a hot melt
adhesive and the hot melt adhesive comprises the malodor reduction
composition, in one aspect, the hot melt adhesive adheres the
backsheet to the topsheet, in one aspect, the backsheet comprises a
nonwoven layer and a film layer, and the hot melt adhesive adheres
the backsheet nonwoven layer to the backsheet film layer.
[0040] In one aspect, said malodor reduction composition that is a
consumer product is a personal care deodorant composition, said
deodorant composition comprising a total of, based on total
consumer product weight, from about 0.1% to about 7% of one or more
of said malodor reduction materials and, optionally, from about
0.01% to about 75% of an antimicrobial, in one aspect, said
antimicrobialsare selected from the group consisting of metals,
zeolites, metal zeolites, quaternary ammonium (quat) compounds
(e.g., cetyl pyridinium chloride, and benzylalkonium chloride),
quat bound clays, metal bound clays, polyaspirin. salicylic acid,
polyvinyl amines, coal tar, sulfur, whitfield's ointment,
castellani's paint, aluminum chloride, gentian violet, octopirox
(piroctone olamine), ciclopirox olamine, undecylenic acid and it's
metal salts, potassium permanganate, selenium sulfide, sodium
thiosulfate, glycols, diols, oil of bitter orange, urea
preparations, griseofulvin, 8-Hydroxyquinoline ciloquinol,
thiobendazole, thiocarbamates, haloprogin, polyenes,
hydroxypyridone, morpholine, benzylamine, allylamines (such as
terbinafine), tea tree oil, clove leaf oil, coriander, palmarosa,
berberine, thyme red, cinnamon oil, citronellic acid, hinokitol,
ichthyol pale, Sensiva SC-50, Elestab HP-100, azelaic acid,
lyticase, iodopropynyl butylcarbamate (IPBC), triclosan,
triclocarban, isothiazalinones and azoles, and combinations
thereof, more preferably, hexanediol, triclosan, octyl
isothiazalinone metals selected from the group consisting of Zn,
Cu, Al, Ti, Sn, Bi, and Ag, metal salts selected from the group
consisting of zinc carbonate, copper sulfate, and zinc gluconate,
metal pyrithione salts selected from the group consisting of ZPT
and CuPT, glycols selected from the group consisting of propylene
glycol, dipropylene glycol and hexylene glycol and mixtures
thereof, in one aspect, said personal care deodorant composition
comprises, based on total deodorant weight, from about 10% to about
75% glycol.
[0041] In one aspect, said malodor reduction composition that is a
consumer product is a personal care body wash/shampoo composition,
said body wash/shampoo comprising a total of, based on total
consumer product weight, from about 0.1% to about 7% of one or more
of said malodor reduction materials from about 3% to 30% of a
surfactant, and, optionally, a miscellar phase and/or lamellar
phase.
[0042] In one aspect, said malodor reduction composition that is a
consumer product is a personal care antiperspirant composition,
said antiperspirant composition comprising a total of, based on
total consumer product weight, from about 0.1% to about 7% of one
or more of said malodor reduction materials and, optionally, from
about 1% to about 25% of an aluminum salt antiperspirant
active.
[0043] In one aspect, said malodor reduction composition that is a
consumer product is an anhydrous antiperspirant composition, said
anhydrous antiperspirant composition comprising a total of, based
on total consumer product weight, from about 0.1% to about 7% of
one or more of said malodor reduction materials and from about 1%
to about 25% oof an antiperspirant actives slected from the group
consisiting of astringent metallic salts, in one aspect, inorganic
and organic salts of aluminum, zirconium and zinc, as well as
mixtures thereof, in one aspect, aluminum halides, aluminum
chlorohydrate, aluminum hydroxyhalides, zirconyl oxyhalides,
zirconyl hydroxyhalides, and mixtures thereof.
[0044] In one aspect, said malodor reduction composition that is a
consumer product is a dish cleaning composition, said dish cleaning
composition comprising a total of, based on total consumer product
weight, from about 0.1% to about 7% of one or more of said malodor
reduction materials.
[0045] In one aspect, a method of controlling malodors comprising:
contacting the material comprising a malodor with a composition
selected from the group consisting of any of the compositions
comprising a malodor reduction material disclosed herein and
mixtures thereof, in one aspect, said contacting step comprises
contacting said material containing a malodor with about 1 mg to
about 50 mg, from about 3 mg to 30 mg, or from about 5 mg to about
20 mg of said composition per 20 grams of said material containing
a malodor is disclosed.
[0046] In one aspect, a method of determining the material's
ability to decrease or even eliminate the perception of one or more
malodors comprising determining the MORV and/or Universal MORV of
said material, in one aspect, determining said MORV and/or
Universal MORV by the MORV and Universal MORV method provided in
Test Method 1, is disclosed.
Process of Making Encapsulates
[0047] Methods of making suitable encapsulated malodor reduction
compositions, for example condensation processes, as well as
suitable shell materials for such encapsulated malodor reduction
compositions are described in U.S. Pat. No. 6,869,923 B1 and US
Published Patent Applications Nos. 2005/0276831 A1 and 2007/020263
A1. Such shell materials include acrylates, acrylics, aminoplast
materials such as melamine formaldehyde material and combinations
thereof. Suitable equipment for use in the processes disclosed
herein may include continuous stirred tank reactors, homogenizers,
turbine agitators, recirculating pumps, paddle mixers, ploughshear
mixers, ribbon blenders, vertical axis granulators and drum mixers,
both in batch and, where available, in continuous process
configurations, spray dryers, and extruders. Such equipment can be
obtained from Lodige GmbH (Paderborn, Germany), Littleford Day,
Inc. (Florence, Ky., U.S.A.), Forberg AS (Larvik, Norway), Glatt
Ingenieurtechnik GmbH (Weimar, Germany), Niro (Soeborg, Denmark),
Hosokawa Bepex Corp. (Minneapolis, Minn., U.S.A.), Arde Barinco
(N.J., U.S.A.).
Adjunct Materials
[0048] While not essential for the purposes of the present
invention, the non-limiting list of adjuncts illustrated
hereinafter are suitable for use in the instant compositions and
may be desirably incorporated in certain aspects of the invention,
for example to assist or enhance cleaning performance, for
treatment of the substrate to be cleaned, or to modify the
aesthetics of the composition as is the case with perfumes,
colorants, dyes or the like. The precise nature of these additional
components, and levels of incorporation thereof, will depend on the
physical form of the composition and the nature of the fabric
treatment operation for which it is to be used. Suitable adjunct
materials include, but are not limited to, surfactants, builders,
chelating agents, dye transfer inhibiting agents, dispersants,
enzymes, and enzyme stabilizers, catalytic materials, bleach
activators, hydrogen peroxide, sources of hydrogen peroxide,
preformed peracids, polymeric dispersing agents, clay soil
removal/anti-redeposition agents, brighteners, suds suppressors,
dyes, hueing dyes, perfumes, perfume delivery systems, structure
elasticizing agents, carriers, structurants, hydrotropes,
processing aids, solvents, pigments and/or fabric softener
actives.
[0049] As stated, the adjunct ingredients are not essential to
Applicants' compositions. Thus, certain aspects of Applicants'
compositions do not contain one or more of the following adjuncts
materials: surfactants, builders, chelating agents, dye transfer
inhibiting agents, dispersants, enzymes, and enzyme stabilizers,
catalytic materials, bleach activators, hydrogen peroxide, sources
of hydrogen peroxide, preformed peracids, polymeric dispersing
agents, clay soil removal/anti-redeposition agents, brighteners,
suds suppressors, dyes, hueing dyes, perfumes, perfume delivery
systems structure elasticizing agents, carriers, hydrotropes,
processing aids, solvents, pigments and/or fabric softener actives.
However, when one or more adjuncts are present, such one or more
adjuncts may be present as detailed below.
[0050] Hueing Dye--The liquid laundry detergent composition may
comprise a hueing dye. The hueing dyes employed in the present
laundry care compositions may comprise polymeric or non-polymeric
dyes, organic or inorganic pigments, or mixtures thereof. In one
aspect, the hueing dye comprises a polymeric dye, comprising a
chromophore constituent and a polymeric constituent. The
chromophore constituent is characterized in that it absorbs light
in the wavelength range of blue, red, violet, purple, or
combinations thereof upon exposure to light. In one aspect, the
chromophore constituent exhibits an absorbance spectrum maximum
from about 520 nanometers to about 640 nanometers in water and/or
methanol, and in another aspect, from about 560 nanometers to about
610 nanometers in water and/or methanol.
[0051] Although any suitable chromophore may be used, the dye
chromophore is, in one aspect, selected from benzodifuranes,
methine, triphenylmethanes, napthalimides, pyrazole, napthoquinone,
anthraquinone, azo, oxazine, azine, xanthene, triphenodioxazine and
phthalocyanine dye chromophores. Mono and di-azo dye chromophores
are may be preferred.
[0052] The hueing dye may comprise a dye polymer comprising a
chromophore covalently bound to one or more of at least three
consecutive repeat units. It should be understood that the repeat
units themselves do not need to comprise a chromophore. The dye
polymer may comprise at least 5, or at least 10, or even at least
20 consecutive repeat units.
[0053] The repeat unit can be derived from an organic ester such as
phenyl dicarboxylate in combination with an oxyalkyleneoxy and a
polyoxyalkyleneoxy. Repeat units can be derived from alkenes,
epoxides, aziridine, carbohydrate including the units that comprise
modified celluloses such as hydroxyalkylcellulose; hydroxypropyl
cellulose; hydroxypropyl methylcellulose; hydroxybutyl cellulose;
and, hydroxybutyl methylcellulose or mixtures thereof. The repeat
units may be derived from alkenes, or epoxides or mixtures thereof.
The repeat units may be C.sub.2-C.sub.4 alkyleneoxy groups,
sometimes called alkoxy groups, in one aspect, derived from
C.sub.2-C.sub.4 alkylene oxide. The repeat units may be
C.sub.2-C.sub.4 alkoxy groups, in one aspect, ethoxy groups.
[0054] For the purposes of the present invention, the at least
three consecutive repeat units form a polymeric constituent. The
polymeric constituent may be covalently bound to the chromophore
group, directly or indirectly via a linking group. Examples of
suitable polymeric constituents include polyoxyalkylene chains
having multiple repeating units. In one aspect, the polymeric
constituents include polyoxyalkylene chains having from 2 to about
30 repeating units, from 2 to about 20 repeating units, from 2 to
about 10 repeating units or even from about 3 or 4 to about 6
repeating units. Non-limiting examples of polyoxyalkylene chains
include ethylene oxide, propylene oxide, glycidol oxide, butylene
oxide and mixtures thereof.
[0055] Surfactants--The compositions according to the present
invention may comprise a surfactant or surfactant system wherein
the surfactant can be selected from nonionic surfactants, anionic
surfactants, cationic surfactants, ampholytic surfactants,
zwitterionic surfactants, semi-polar nonionic surfactants and
mixtures thereof.
[0056] The surfactant is typically present at a level of from about
0.1% to about 60%, from about 1% to about 50% or even from about 5%
to about 40% by weight of the subject composition.
[0057] Chelating Agents--The compositions herein may contain a
chelating agent. Suitable chelating agents include copper, iron
and/or manganese chelating agents and mixtures thereof. When a
chelating agent is used, the composition may comprise from about
0.1% to about 15% or even from about 3.0% to about 10% chelating
agent by weight of the subject composition.
[0058] Dye Transfer Inhibiting Agents--The compositions of the
present invention may also include one or more dye transfer
inhibiting agents. Suitable polymeric dye transfer inhibiting
agents include, but are not limited to, polyvinylpyrrolidone
polymers, polyamine N-oxide polymers, copolymers of
N-vinylpyrrolidone and N-vinylimidazole, polyvinyloxazolidones and
polyvinylimidazoles or mixtures thereof.
[0059] When present in a subject composition, the dye transfer
inhibiting agents may be present at levels from about 0.0001% to
about 10%, from about 0.01% to about 5% or even from about 0.1% to
about 3% by weight of the composition.
[0060] Dispersants--The compositions of the present invention can
also contain dispersants. Suitable water-soluble organic materials
include the homo- or co-polymeric acids or their salts, in which
the polycarboxylic acid comprises at least two carboxyl radicals
separated from each other by not more than two carbon atoms.
[0061] Perfumes--The dispersed phase may comprise a perfume that
may include materials selected from the group consisting of
perfumes such as 3-(4-t-butylphenyl)-2-methyl propanal,
3-(4-t-butylphenyl)-propanal,
3-(4-isopropylphenyl)-2-methylpropanal,
3-(3,4-methylenedioxyphenyl)-2-methylpropanal, and
2,6-dimethyl-5-heptenal, .alpha.-damascone, .beta.-damascone,
.delta.-damascone, .beta.-damascenone,
6,7-dihydro-1,1,2,3,3-pentamethyl-4(5H)-indanone,
methyl-7,3-dihydro-2H-1,5-benzodioxepine-3-one,
2-[2-(4-methyl-3-cyclohexenyl-1-yl)propyl]cyclopentan-2-one,
2-sec-butylcyclohexanone, and .beta.-dihydro ionone, linalool,
ethyllinalool, tetrahydrolinalool, and dihydromyrcenol.
[0062] Perfume Delivery Technologies--The compositions of the
present invention may comprise one or more perfume delivery
technologies that stabilize and enhance the deposition and release
of perfume ingredients from treated substrate. Such perfume
delivery technologies can also be used to increase the longevity of
perfume release from the treated substrate. Perfume delivery
technologies, methods of making certain perfume delivery
technologies and the uses of such perfume delivery technologies are
disclosed in US 2007/0275866 A1.
[0063] In one aspect, the compositions of the present invention may
comprise from about 0.001% to about 20%, or from about 0.01% to
about 10%, or from about 0.05% to about 5%, or even from about 0.1%
to about 0.5% by weight of the perfume delivery technology. In one
aspect, said perfume delivery technologies may be selected from the
group consisting of: perfume microcapsules, pro-perfumes, polymer
particles, functionalized silicones, polymer assisted delivery,
molecule assisted delivery, fiber assisted delivery, amine assisted
delivery, cyclodextrins, starch encapsulated accord, zeolite and
inorganic carrier, and mixtures thereof:
[0064] In one aspect, said perfume delivery technology may comprise
microcapsules formed by at least partially surrounding a benefit
agent with a wall material. Said benefit agent may include
materials selected from the group consisting of perfumes such as
3-(4-t-butylphenyl)-2-methyl propanal,
3-(4-t-butylphenyl)-propanal,
3-(4-isopropylphenyl)-2-methylpropanal,
3-(3,4-methylenedioxyphenyl)-2-methylpropanal, and
2,6-dimethyl-5-heptenal, .alpha.-damascone, .beta.-damascone,
.delta.-damascone, .beta.-damascenone,
6,7-dihydro-1,1,2,3,3-pentamethyl-4(5H)-indanone,
methyl-7,3-dihydro-2H-1,5-benzodioxepine-3-one,
2-[2-(4-methyl-3-cyclohexenyl-1-yl)propyl]cyclopentan-2-one,
2-sec-butylcyclohexanone, and .beta.-dihydro ionone, linalool,
ethyllinalool, tetrahydrolinalool, and dihydromyrcenol. Suitable
perfume materials can be obtained from Givaudan Corp. of Mount
Olive, N.J., USA, International Flavors & Fragrances Corp. of
South Brunswick, N.J., USA, or Quest Corp. of Naarden, Netherlands.
In one aspect, the microcapsule wall material may comprise:
melamine, polyacrylamide, silicones, silica, polystyrene, polyurea,
polyurethanes, polyacrylate based materials, gelatin, styrene malic
anhydride, polyamides, and mixtures thereof. In one aspect, said
melamine wall material may comprise melamine crosslinked with
formaldehyde, melamine-dimethoxyethanol crosslinked with
formaldehyde, and mixtures thereof. In one aspect, said polystyrene
wall material may comprise polyestyrene cross-linked with
divinylbenzene. In one aspect, said polyurea wall material may
comprise urea crosslinked with formaldehyde, urea crosslinked with
gluteraldehyde, and mixtures thereof. In one aspect, said
polyacrylate based materials may comprise polyacrylate formed from
methylmethacrylate/dimethylaminomethyl methacrylate, polyacrylate
formed from amine acrylate and/or methacrylate and strong acid,
polyacrylate formed from carboxylic acid acrylate and/or
methacrylate monomer and strong base, polyacrylate formed from an
amine acrylate and/or methacrylate monomer and a carboxylic acid
acrylate and/or carboxylic acid methacrylate monomer, and mixtures
thereof. In one aspect, the perfume microcapsule may be coated with
a deposition aid, a cationic polymer, a non-ionic polymer, an
anionic polymer, or mixtures thereof. Suitable polymers may be
selected from the group consisting of: polyvinylformaldehyde,
partially hydroxylated polyvinylformaldehyde, polyvinylamine,
polyethyleneimine, ethoxylated polyethyleneimine, polyvinylalcohol,
polyacrylates, and combinations thereof. In one aspect, the
microcapsule may be a perfume microcapsule. In one aspect, one or
more types of microcapsules, for example two microcapsules types
having different benefit agents may be used.
[0065] In one aspect, said perfume delivery technology may comprise
an amine reaction product (ARP) or a thio reaction product. One may
also use "reactive" polymeric amines and or polymeric thiols in
which the amine and/or thiol functionality is pre-reacted with one
or more PRMs to form a reaction product. Typically the reactive
amines are primary and/or secondary amines, and may be part of a
polymer or a monomer (non-polymer). Such ARPs may also be mixed
with additional PRMs to provide benefits of polymer-assisted
delivery and/or amine-assisted delivery. Nonlimiting examples of
polymeric amines include polymers based on polyalkylimines, such as
polyethyleneimine (PEI), or polyvinylamine (PVAm). Nonlimiting
examples of monomeric (non-polymeric) amines include hydroxyl
amines, such as 2-aminoethanol and its alkyl substituted
derivatives, and aromatic amines such as anthranilates. The ARPs
may be premixed with perfume or added separately in leave-on or
rinse-off applications. In another aspect, a material that contains
a heteroatom other than nitrogen and/or sulfur, for example oxygen,
phosphorus or selenium, may be used as an alternative to amine
compounds. In yet another aspect, the aforementioned alternative
compounds can be used in combination with amine compounds. In yet
another aspect, a single molecule may comprise an amine moiety and
one or more of the alternative heteroatom moieties, for example,
thiols, phosphines and selenols. The benefit may include improved
delivery of perfume as well as controlled perfume release. Suitable
ARPs as well as methods of making same can be found in USPA
2005/0003980 A1 and U.S. Pat. No. 6,413,920 B1.
Fabric Softening Actives
[0066] The compositions of the present invention may comprise a
fabric softening active ("FSA"). Suitable fabric softening actives,
include, but are not limited to, materials selected from the group
consisting of quaternary ammonium compounds (quat), amines, fatty
esters, sucrose esters, silicones, dispersible polyolefins, clays,
polysaccharides, fatty acids, softening oils, polymer latexes and
mixtures thereof.
[0067] Non-limiting examples of water insoluble fabric care benefit
agents include dispersible polyethylene and polymer latexes.
[0068] Quat--Suitable quats include but are not limited to,
materials selected from the group consisting of ester quats, amide
quats, imidazoline quats, alkyl quats, amdioester quats and
mixtures thereof. Suitable ester quats include but are not limited
to, materials selected from the group consisting of monoester
quats, diester quats, triester quats and mixtures thereof. In one
aspect, a suitable ester quat is
bis-(2-hydroxypropyl)-dimethylammonium methylsulphate fatty acid
ester having a molar ratio of fatty acid moieties to amine moieties
of from 1.85 to 1.99, an average chain length of the fatty acid
moieties of from 16 to 18 carbon atoms and an iodine value of the
fatty acid moieties, calculated for the free fatty acid, of from
0.5 to 60 or 15 to 50. In one aspect, the cis-trans-ratio of double
bonds of unsaturated fatty acid moieties of the bis (2
hydroxypropyl)-dimethylammonium methylsulphate fatty acid ester is
from 55:45 to 75:25, respectively. Suitable amide quats include but
are not limited to, materials selected from the group consisting of
monoamide quats, diamide quats and mixtures thereof. Suitable alkyl
quats include but are not limited to, materials selected from the
group consisting of mono alkyl quats, dialkyl quats quats, trialkyl
quats, tetraalkyl quats and mixtures thereof.
[0069] In one embodiment, the fabric softening active is a
quaternary ammonium compound suitable for softening fabric in a
rinse step. In one embodiment, the fabric softening active is
formed from a reaction product of a fatty acid and an aminoalcohol
obtaining mixtures of mono-, di-, and, in one embodiment, tri-ester
compounds. In another embodiment, the fabric softening active
comprises one or more softener quaternary ammonium compounds such,
but not limited to, as a monoalkyquaternary ammonium compound,
dialkylquaternary ammonium compound, a diamido quaternary compound,
a diester quaternary ammonium compound, or a combination
thereof.
[0070] In one aspect, the fabric softening active comprises a
diester quaternary ammonium or protonated diester ammonium
(hereinafter "DQA") compound composition. In certain embodiments of
the present invention, the DQA compound compositions also encompass
diamido fabric softening actives s and fabric softening actives
with mixed amido and ester linkages as well as the aforementioned
diester linkages, all herein referred to as DQA.
[0071] In one embodiment, the fabric softening agent is chosen from
at least one of the following: ditallowoyloxyethyl dimethyl
ammonium chloride, dihydrogenated-tallowoyloxyethyl dimethyl
ammonium chloride, ditallow dimethyl ammonium chloride,
dihydrogenatedtallow dimethyl ammonium chloride,
ditallowoyloxyethyl methylhydroxyethylammonium methyl sulfate,
dihydrogenated-tallowoyloxyethyl methyl hydroxyethylammonium
chloride, or combinations thereof.
[0072] It will be understood that combinations of softener actives
disclosed above are suitable for use in this invention.
Anion A
[0073] In the cationic nitrogenous salts herein, the anion A.sup.-,
which comprises any softener compatible anion, provides electrical
neutrality. Most often, the anion used to provide electrical
neutrality in these salts is from a strong acid, especially a
halide, such as chloride, bromide, or iodide. However, other anions
can be used, such as methylsulfate, ethylsulfate, acetate, formate,
sulfate, carbonate, fatty acid anions and the like. In one aspect,
the anion A may comprise chloride or methylsulfate. The anion, in
some aspects, may carry a double charge. In this aspect, A.sup.-
represents half a group.
[0074] Silicone
[0075] In one embodiment, the compositions of the present invention
may comprise a silicone. Suitable levels of silicone may comprise
from about 0.1% to about 70%, alternatively from about 0.3% to
about 40%, alternatively from about 0.5% to about 30%,
alternatively from about 1% to about 20% by weight of the
composition. Useful silicones can be any silicone comprising
compound. In one embodiment, the silicone polymer is selected from
the group consisting of cyclic silicones, polydimethylsiloxanes,
aminosilicones, cationic silicones, silicone polyethers, silicone
resins, silicone urethanes, and mixtures thereof. In one
embodiment, the silicone is a polydialkylsilicone, alternatively a
polydimethyl silicone (polydimethyl siloxane or "PDMS"), or a
derivative thereof. In another embodiment, the silicone is chosen
from an aminofunctional silicone, amino-polyether silicone,
alkyloxylated silicone, cationic silicone, ethoxylated silicone,
propoxylated silicone, ethoxylated/propoxylated silicone,
quaternary silicone, or combinations thereof.
[0076] In another embodiment, the silicone may be chosen from a
random or blocky organosilicone polymer having the following
formula:
[R.sub.1R.sub.2R.sub.3SiO.sub.1/2].sub.(j+2)[(R.sub.4Si(X--Z)O.sub.2/2].-
sub.k[R.sub.4R.sub.4SiO.sub.2/2].sub.m[R.sub.4SiO.sub.3/2].sub.j
[0077] wherein: [0078] j is an integer from 0 to about 98; in one
aspect j is an integer from 0 to about 48; in one aspect, j is 0;
[0079] k is an integer from 0 to about 200, in one aspect k is an
integer from 0 to about 50; when k=0, at least one of R.sub.1,
R.sub.2 or R.sub.3 is --X--Z; [0080] m is an integer from 4 to
about 5,000; in one aspect m is an integer from about 10 to about
4,000; in another aspect m is an integer from about 50 to about
2,000; [0081] R.sub.1, R.sub.2 and R.sub.3 are each independently
selected from the group consisting of H, OH, C.sub.1-C.sub.32
alkyl, C.sub.1-C.sub.32 substituted alkyl, C.sub.5-C.sub.32 or
C.sub.6-C.sub.32 aryl, C.sub.5-C.sub.32 or C.sub.6-C.sub.32
substituted aryl, C.sub.6-C.sub.32 alkylaryl, C.sub.6-C.sub.32
substituted alkylaryl, C.sub.1-C.sub.32 alkoxy, C.sub.1-C.sub.32
substituted alkoxy and X--Z; [0082] each R.sub.4 is independently
selected from the group consisting of H, OH, C.sub.1-C.sub.32
alkyl, C.sub.1-C.sub.32 substituted alkyl, C.sub.5-C.sub.32 or
C.sub.6-C.sub.32 aryl, C.sub.5-C.sub.32 or C.sub.6-C.sub.32
substituted aryl, C.sub.6-C.sub.32 alkylaryl, C.sub.6-C.sub.32
substituted alkylaryl, C.sub.1-C.sub.32 alkoxy and C.sub.1-C.sub.32
substituted alkoxy; [0083] each X in said alkyl siloxane polymer
comprises a substituted or unsubstituted divalent alkylene radical
comprising 2-12 carbon atoms, in one aspect each divalent alkylene
radical is independently selected from the group consisting of
--(CH.sub.2).sub.s-- wherein s is an integer from about 2 to about
8, from about 2 to about 4; in one aspect, each X in said alkyl
siloxane polymer comprises a substituted divalent alkylene radical
selected from the group consisting of:
--CH.sub.2--CH(OH)--CH.sub.2--; --CH.sub.2--CH.sub.2--CH(OH)--;
and
[0083] ##STR00001## [0084] each Z is selected independently from
the group consisting of
##STR00002##
[0084] with the proviso that when Z is a quat, Q cannot be an
amide, imine, or urea moiety and if Q is an amide, imine, or urea
moiety, then any additional Q bonded to the same nitrogen as said
amide, imine, or urea moiety must be H or a C.sub.1-C.sub.6 alkyl,
in one aspect, said additional Q is H; for Z A.sup.n- is a suitable
charge balancing anion. In one aspect A.sup.n- is selected from the
group consisting of Cl.sup.-, Br.sup.-, I.sup.-, methylsulfate,
toluene sulfonate, carboxylate and phosphate; and at least one Q in
said organosilicone is independently selected from
--CH.sub.2--CH(OH)--CH.sub.2--R.sub.5;
##STR00003## [0085] each additional Q in said organosilicone is
independently selected from the group comprising of H,
C.sub.1-C.sub.32 alkyl, C.sub.1-C.sub.32 substituted alkyl,
C.sub.5-C.sub.32 or C.sub.6-C.sub.32 aryl, C.sub.5-C.sub.32 or
C.sub.6-C.sub.32 substituted aryl, C.sub.6-C.sub.32 alkylaryl,
C.sub.6-C.sub.32 substituted alkylaryl,
--CH.sub.2--CH(OH)--CH.sub.2--R.sub.5;
[0085] ##STR00004## [0086] wherein each R.sub.5 is independently
selected from the group consisting of H, C.sub.1-C.sub.32 alkyl,
C.sub.1-C.sub.32 substituted alkyl, C.sub.5-C.sub.32 or
C.sub.6-C.sub.32 aryl, C.sub.5-C.sub.32 or C.sub.6-C.sub.32
substituted aryl, C.sub.6-C.sub.32 alkylaryl, C.sub.6-C.sub.32
substituted alkylaryl, --(CHR.sub.6--CHR.sub.6--O--).sub.w-L and a
siloxyl residue; [0087] each R.sub.6 is independently selected from
H, C.sub.1-C.sub.18 alkyl [0088] each L is independently selected
from --C(O)--R.sub.7 or R.sub.7; [0089] w is an integer from 0 to
about 500, in one aspect w is an integer from about 1 to about 200;
in one aspect w is an integer from about 1 to about 50; [0090] each
R.sub.7 is selected independently from the group consisting of H;
C.sub.1-C.sub.32 alkyl; C.sub.1-C.sub.32 substituted alkyl,
C.sub.5-C.sub.32 or C.sub.6-C.sub.32 aryl, C.sub.5-C.sub.32 or
C.sub.6-C.sub.32 substituted aryl, C.sub.6-C.sub.32 alkylaryl;
C.sub.6-C.sub.32 substituted alkylaryl and a siloxyl residue;
[0091] each T is independently selected from H, and
##STR00005##
[0091] and wherein each v in said organosilicone is an integer from
1 to about 10, in one aspect, v is an integer from 1 to about 5 and
the sum of all v indices in each Q in the said organosilicone is an
integer from 1 to about 30 or from 1 to about 20 or even from 1 to
about 10.
[0092] In another embodiment, the silicone may be chosen from a
random or blocky organosilicone polymer having the following
formula:
[R.sub.1R.sub.2R.sub.3SiO.sub.1/2].sub.(j+2)[(R.sub.4Si(X--Z)O.sub.2/2].-
sub.k[R.sub.4R.sub.4SiO.sub.2/2].sub.m[R.sub.4SiO.sub.3/2].sub.j
[0093] wherein [0094] j is an integer from 0 to about 98; in one
aspect j is an integer from 0 to about 48; in one aspect, j is 0;
[0095] k is an integer from 0 to about 200; when k=0, at least one
of R.sub.1, R.sub.2 or R.sub.3.dbd.--X--Z, in one aspect, k is an
integer from 0 to about 50 [0096] m is an integer from 4 to about
5,000; in one aspect m is an integer from about 10 to about 4,000;
in another aspect m is an integer from about 50 to about 2,000;
[0097] R.sub.1, R.sub.2 and R.sub.3 are each independently selected
from the group consisting of H, OH, C.sub.1-C.sub.32 alkyl,
C.sub.1-C.sub.32 substituted alkyl, C.sub.5-C.sub.32 or
C.sub.6-C.sub.32 aryl, C.sub.5-C.sub.32 or C.sub.6-C.sub.32
substituted aryl, C.sub.6-C.sub.32 alkylaryl, C.sub.6-C.sub.32
substituted alkylaryl, C.sub.1-C.sub.32 alkoxy, C.sub.1-C.sub.32
substituted alkoxy and X--Z; [0098] each R.sub.4 is independently
selected from the group consisting of H, OH, C.sub.1-C.sub.32
alkyl, C.sub.1-C.sub.32 substituted alkyl, C.sub.5-C.sub.32 or
C.sub.6-C.sub.32 aryl, C.sub.5-C.sub.32 or C.sub.6-C.sub.32
substituted aryl, C.sub.6-C.sub.32 alkylaryl, C.sub.6-C.sub.32
substituted alkylaryl, C.sub.1-C.sub.32 alkoxy and C.sub.1-C.sub.32
substituted alkoxy; [0099] each X comprises of a substituted or
unsubstituted divalent alkylene radical comprising 2-12 carbon
atoms; in one aspect each X is independently selected from the
group consisting of --(CH.sub.2).sub.s--O--;
--CH.sub.2--CH(OH)--CH.sub.2--O--;
[0099] ##STR00006## [0100] wherein each s independently is an
integer from about 2 to about 8, in one aspect s is an integer from
about 2 to about 4; [0101] At least one Z in the said
organosiloxane is selected from the group consisting of
R.sub.5;
##STR00007##
[0101] provided that when X is
##STR00008##
then Z.dbd.--OR.sub.5 or
##STR00009## [0102] wherein A.sup.- is a suitable charge balancing
anion. In one aspect A.sup.- is selected from the group consisting
of Cl.sup.-, Br.sup.-, [0103] I.sup.-, methylsulfate, toluene
sulfonate, carboxylate and phosphate and [0104] each additional Z
in said organosilicone is independently selected from the group
comprising of H, C.sub.1-C.sub.32 alkyl, C.sub.1-C.sub.32
substituted alkyl, C.sub.5-C.sub.32 or C.sub.6-C.sub.32 aryl,
C.sub.5-C.sub.32 or C.sub.6-C.sub.32 substituted aryl,
C.sub.6-C.sub.32 alkylaryl, C.sub.6-C.sub.32 substituted alkylaryl,
R.sub.5,
##STR00010##
[0104] provided that when X is
##STR00011##
then Z.dbd.--OR.sub.5 or
##STR00012## [0105] each R.sub.5 is independently selected from the
group consisting of H; C.sub.1-C.sub.32 alkyl; C.sub.1-C.sub.32
substituted alkyl, C.sub.5-C.sub.32 or C.sub.6-C.sub.32 aryl,
C.sub.5-C.sub.32 or C.sub.6-C.sub.32 substituted aryl or
C.sub.6-C.sub.32 alkylaryl, or C.sub.6-C.sub.32 substituted
alkylaryl, [0106]
--(CHR.sub.6--CHR.sub.6--O--).sub.w--CHR.sub.6--CHR.sub.6-L and
siloxyl residue wherein each L is independently selected from
--O--C(O)--R.sub.7 or --O--R.sub.7;
[0106] ##STR00013## [0107] w is an integer from 0 to about 500, in
one aspect w is an integer from 0 to about 200, one aspect w is an
integer from 0 to about 50; [0108] each R.sub.6 is independently
selected from H or C.sub.1-C.sub.18 alkyl; [0109] each R.sub.7 is
independently selected from the group consisting of H;
C.sub.1-C.sub.32 alkyl; C.sub.1-C.sub.32 substituted alkyl,
C.sub.5-C.sub.32 or C.sub.6-C.sub.32 aryl, C.sub.5-C.sub.32 or
C.sub.6-C.sub.32 substituted aryl, C.sub.6-C.sub.32 alkylaryl, and
C.sub.6-C.sub.32 substituted aryl, and a siloxyl residue; [0110]
each T is independently selected from H;
[0110] ##STR00014## [0111] wherein each v in said organosilicone is
an integer from 1 to about 10, in one aspect, v is an integer from
1 to about 5 and the sum of all v indices in each Z in the said
organosilicone is an integer from 1 to about 30 or from 1 to about
20 or even from 1 to about 10.
[0112] In one embodiment, the silicone is one comprising a
relatively high molecular weight. A suitable way to describe the
molecular weight of a silicone includes describing its viscosity. A
high molecular weight silicone is one having a viscosity of from
about 10 cSt to about 3,000,000 cSt, or from about 100 cSt to about
1,000,000 cSt, or from about 1,000 cSt to about 600,000 cSt, or
even from about 6,000 cSt to about 300,000 cSt, [0113] In one
embodiment, the silicone comprises a blocky cationic
organopolysiloxane having the formula:
[0113] M.sub.wD.sub.xT.sub.yQ.sub.z [0114] wherein: [0115]
M=[SiR.sub.1R.sub.2R.sub.3O.sub.1/2],
[SiR.sub.1R.sub.2G.sub.1O.sub.1/2],
[SiR.sub.1G.sub.1G.sub.2O.sub.1/2],
[SiG.sub.1G.sub.2G.sub.3O.sub.1/2], or combinations thereof; [0116]
D=[SiR.sub.1R.sub.2O.sub.2/2], [SiR.sub.1G.sub.1O.sub.2/2],
[SiG.sub.1G.sub.2O.sub.2/2] or combinations thereof; [0117]
T=[SiR.sub.1O.sub.3/2], [SiG.sub.1O.sub.3/2] or combinations
thereof; [0118] Q=[SiO.sub.4/2]; [0119] w=is an integer from 1 to
(2+y+2z); [0120] x=is an integer from 5 to 15,000; [0121] y=is an
integer from 0 to 98; [0122] z=is an integer from 0 to 98; [0123]
R.sub.1, R.sub.2 and R.sub.3 are each independently selected from
the group consisting of H, OH, C.sub.1-C.sub.32 alkyl,
C.sub.1-C.sub.32 substituted alkyl, C.sub.5-C.sub.32 or
C.sub.6-C.sub.32 aryl, C.sub.5-C.sub.32 or C.sub.6-C.sub.32
substituted aryl, C.sub.6-C.sub.32 alkylaryl, C.sub.6-C.sub.32
substituted alkylaryl, C.sub.1-C.sub.32 alkoxy, C.sub.1-C.sub.32
substituted alkoxy, C.sub.1-C.sub.32 alkylamino, and
C.sub.1-C.sub.32 substituted alkylamino; [0124] at least one of M,
D, or T incorporates at least one moiety G.sub.1, G.sub.2 or
G.sub.3; and G.sub.1, G.sub.2, and G.sub.3 are each independently
selected from the formula:
[0124] ##STR00015## [0125] wherein: [0126] X comprises a divalent
radical selected from the group consisting of C.sub.1-C.sub.32
alkylene, C.sub.1-C.sub.32 substituted alkylene, C.sub.5-C.sub.32
or C.sub.6-C.sub.32 arylene, C.sub.5-C.sub.32 or C.sub.6-C.sub.32
substituted arylene, C.sub.6-C.sub.32 arylalkylene,
C.sub.6-C.sub.32 substituted arylalkylene, C.sub.1-C.sub.32 alkoxy,
C.sub.1-C.sub.32 substituted alkoxy, C.sub.1-C.sub.32
alkyleneamino, C.sub.1-C.sub.32 substituted alkyleneamino,
ring-opened epoxide, and ring-opened glycidyl, with the proviso
that if X does not comprise a repeating alkylene oxide moiety then
X can further comprise a heteroatom selected from the group
consisting of P, N and O; [0127] each R.sub.4 comprises identical
or different monovalent radicals selected from the group consisting
of H, C.sub.1-C.sub.32 alkyl, C.sub.1-C.sub.32 substituted alkyl,
C.sub.5-C.sub.32 or C.sub.6-C.sub.32 aryl, C.sub.5-C.sub.32 or
C.sub.6-C.sub.32 substituted aryl, C.sub.6-C.sub.32 alkylaryl, and
C.sub.6-C.sub.32 substituted alkylaryl; [0128] E comprises a
divalent radical selected from the group consisting of
C.sub.1-C.sub.32 alkylene, C.sub.1-C.sub.32 substituted alkylene,
C.sub.5-C.sub.32 or C.sub.6-C.sub.32 arylene, C.sub.5-C.sub.32 or
C.sub.6-C.sub.32 substituted arylene, C.sub.6-C.sub.32
arylalkylene, C.sub.6-C.sub.32 substituted arylalkylene,
C.sub.1-C.sub.32 alkoxy, C.sub.1-C.sub.32 substituted alkoxy,
C.sub.1-C.sub.32 alkyleneamino, C.sub.1-C.sub.32 substituted
alkyleneamino, ring-opened epoxide and ring-opened glycidyl, with
the proviso that if E does not comprise a repeating alkylene oxide
moiety then E can further comprise a heteroatom selected from the
group consisting of P, N, and O; [0129] E' comprises a divalent
radical selected from the group consisting of C.sub.1-C.sub.32
alkylene, C.sub.1-C.sub.32 substituted alkylene, C.sub.5-C.sub.32
or C.sub.6-C.sub.32 arylene, C.sub.5-C.sub.32 or C.sub.6-C.sub.32
substituted arylene, C.sub.6-C.sub.32 arylalkylene,
C.sub.6-C.sub.32 substituted arylalkylene, C.sub.1-C.sub.32 alkoxy,
C.sub.1-C.sub.32 substituted alkoxy, C.sub.1-C.sub.32
alkyleneamino, C.sub.1-C.sub.32 substituted alkyleneamino,
ring-opened epoxide and ring-opened glycidyl, with the proviso that
if E' does not comprise a repeating alkylene oxide moiety then E'
can further comprise a heteroatom selected from the group
consisting of P, N, and O; [0130] p is an integer independently
selected from 1 to 50; [0131] n is an integer independently
selected from 1 or 2; [0132] when at least one of G.sub.1, G.sub.2,
or G.sub.3 is positively charged, A.sup.-t is a suitable charge
balancing anion or anions such that the total charge, k, of the
charge-balancing anion or anions is equal to and opposite from the
net charge on the moiety G.sub.1, G.sub.2 or G.sub.3; wherein t is
an integer independently selected from 1, 2, or 3; and
k.ltoreq.(p*2/t)+1; such that the total number of cationic charges
balances the total number of anionic charges in the
organopolysiloxane molecule; and wherein at least one E does not
comprise an ethylene moiety.
Test Methods
[0132] [0133] Malodor reduction materials may be separated from
mixtures, including but not limited to finished products such as
consumer products and indentified, by analytical methods that
include GC-MS and/or NMR.
MORV and Universal MORV Calculation
[0133] [0134] 1.) Search Chemical Abstracts using the name and/or
the CAS Registry number for the material of interest and use the
structure provided. If there are multiple isomers for a given
material, use the structure provided by Chemical Abstracts or use
the isomer that is most prevalent in the material. Input structure
of material into winMolconn (Hall Associates, version 1.1.2.1).
[0135] 2.) Input values from 1.) above into the following four
equations:
[0135] a)
MORV=-8.5096+2.8597.times.(dxp9)+1.1253.times.(knotpv)-0.34484.times.(e1C-
2O2)-0.00046231.times.(idw)+3.3509.times.(idcbar)+0.11158.times.(n2pag22)
b)
MORV=-5.2917+2.1741.times.(dxvp5)-2.6595.times.(dxvp8)+0.45297.times.-
(e1C2C2d)-0.6202.times.(c1C2O2)+1.3542.times.(CdCH2)+0.68105.times.(CaasC)-
+1.7129.times.(idcbar)
c)
MORV=-0.0035+0.8028.times.(SHCsatu)+2.1673.times.(xvp7)-1.3507.times.-
(c1C1C3d)+0.61496.times.(c1C1O2)+0.00403.times.(idc)-0.23286.times.(nd2).
d)
MORV=-0.9926-0.03882.times.(SdO)+0.1869.times.(Ssp3OH)+2.1847.times.(-
xp7)+0.34344.times.(e1C3O2)-0.45767.times.(c1C2C3)+0.7684.times.(CKetone)
[0136] Equation a) is for the malodor trans-3-methyl-2-hexenoic
acid (carboxylic acid based malodors) [0137] Equation b) is for the
malodor trimethylamine (amine based malodors) [0138] Equation c) is
for the malodor 3-mercapto-3-methylhexan-1-ol (thiol based
malodors) [0139] Equation d) is for the malodor skatole (indole
based malodors) [0140] 3.) For purpose of the present application,
a material's MORV is the highest MORV value from equations 2.)a)
through 2.)d). [0141] 4.) If all MORV values from equations 2.)a)
through 2.)d) above are greater than 0.5, the subject material has
a Universal MORV.
EXAMPLE 1
Malodor Reduction Composition
TABLE-US-00008 [0142] MRC A MRC B MRC C Ingredient CAS # Percent
Percent Percent 5-Cyclohexadecen-1-One 37609-25-9 15.0 2.00 2.00
decahydro-2,2,7,7,8,9,9- 476332-65-7 0.005 0.01 0.01
heptamethylindeno(4,3a-b)furan 2,3-Dihydro-5,6-dimethoxy-2-(4-
33704-61-9 0.3 0.5 0.5 piperidinylmethylene)-1H-inden-1-one Cedryl
Methyl Ether 19870-74-7 6.0 10.0 4.0 Trans-4-Decenal 65405-70-1
0.005 0.002 0.002 Decyl Aldehyde 112-31-2 3.74 2.0 2.0 3-methyl
cyclopentadecenone 63314-79-4 0.4 1.0 1.0 Diphenyl Oxide 101-84-8
0.5 1.0 1.0 3a,4,5,6,7,7a-hexahydro-4,7-methano- 54830-99-8 5.0 8.0
8.0 1H-indenyl acetate 3a,4,5,6,7,7a-hexahydro-1H-4,7- 68912-13-0
6.0 8.0 8.0 methanoinden-1-yl propanoate
2-(5-methyl-2-propan-2-yl-8- 68901-32-6 10.0 15.0 15.0
bicyclo[2.2.2]oct-5-enyl)-1,3-dioxolane (E)-3,7-dimethyl-2,6-
3681-73-0 10.0 10.0 16.0 octadienylhexadecanoate Iso Nonyl Acetate
58430-94-7 6.65 8.0 3.0 2,2,7,7- 23787-90-8 10.0 8.0 8.0
tetramethyltricyclo[6.2.1.01,6]undecan- 5-one (1-Methyl-2-(1,2,2-
198404-98-7 0.1 0.3 0.3 trimethylbicyclo[3.1.0]-hex-3-
ylmethyl)cyclopropyl)methanol Lauric Aldehyde 112-54-9 0.625 1.0
0.7 Methyl Iso Eugenol 93-16-3 18.000 10.0 13.0 Methyl
hexadecanoate 112-39-0 3.000 10.0 12.0
2,3-dihydro-1,1-1H-dimethyl-indene- 300371-33-9 0.400 0.0 0.3
ar-propanal 4-tert-butylcyclohexanol 98-52-2 0.400 0.1 0.1
2-isobutyl-4-hydroxy-4- 63500-71-0 1.600 2.0 2.0
methyltetrahydropyran Undecyl Aldehyde 112-44-7 1.725 2.888 1.888
Undecylenic Aldehyde 112-45-8 0.550 0.2 1.2 Total 100 100.0
100.0
[0143] The term "air refresher" or "air freshener", as used herein,
refer to any suitable composition that reduces odors in air, and/or
reduces the impression of odors in the air by masking, layering or
including malodor counteractant perfume raw materials into the
composition.
EXAMPLE 2.1-2.3
Energized Air Refresher
[0144] An energized air refresher composition is prepared with
malodor reduction composition, according to the compositions shown
in Example 1.
TABLE-US-00009 Example Example Example 2.1 2.2 2.3 Perfume
composition 40-60 50-60 30-50 Malodor reducing composition 10-20
15-30 10-25 Functional Perfume Component 30-50 10-30 25-60
[0145] Use of Functional Perfume Components at the recited levels
may help modulate the evaporation profile of an entire perfume
composition to provide perfume character consistency over the
intended usage period. [0146] Suitable FPCs may be highly volatile,
low boiling, perfume ingredients. Non-limiting, suitable FPCs
include iso-nonyl acetate, dihydro myrcenol
(3-methylene-7-methyloctan-7-ol), linalool
(3-hydroxy-3,7-dimethyl-1,6 octadiene), geraniol (3,7
dimethyl-2,6-octadien-1-ol), d-limonene,
1-methyl-4-isopropenyl-1-cyclohexene, benzyl acetate, isopropyl
mystristate, and combinations thereof.
Functional Perfume Component Examples 2.1-2.3
TABLE-US-00010 [0147] Example A1 Example A2 Example A3 Benzyl
alcohol 10-50 0-50 0-20 Iso nonyl acetate 1-20 1-10 1-10
Dipropylene glycol methyl 40-70 5-65 2-50 ether
[0148] An energized air freshening device is filled with the
composition above. The resulting air freshener is effective at
reducing malodor.
EXAMPLES 3.1-3.3
Non-Energized Air Freshener
[0149] A non-energized air refresher composition is prepared with
malodor reduction composition, according to the compositions shown
in Example 1.
TABLE-US-00011 Example Example Example 3.1 3.2 3.3 Perfume
composition 20-30 20-50 10-30 Malodor reducing composition 10-20
10-20 20-50 Functional Perfume components 0-70 40-70 20-70 Example
Example Example Functional Perfume components 1 2 3
3a,4,5,6,7,7a-hexahydro-1H-4,7- 15-25 20-25 0-20 methanoinden-1-yl
propanoate Iso nonyl acetate 30-75 15-75 1-10
2-isobutyl-4-hydroxy-4- 20-30 5-65 2-50 methyltetrahydropyran
[0150] A non-energized air freshener is filled with the example
composition above. The resulting air freshener is effective at
reducing malodor.
EXAMPLES 4.1-4.2
Fabric and Air Refresher Composition
[0151] A fabric refresher composition is prepared with malodor
reduction composition, according to the compositions shown in
Example 1.
TABLE-US-00012 Example Example Example 4.3 Ingredient 4.1 4.2
(ranges) Deionized Water Balance Balance Balance Ethanol 3.0 3.0
1-5.0% Lupasol HF+ 0.0650 0.0650 0-0.1% Diethylene Glycol 0.175
0.175 0-0.2% Silwet L-7600 0.1 0.100 0-0.2.sup. Maleic Acid and/or
Citric 0.05 0.05 0-0.2.sup. Acid Koralone B-119 0.015 0.015
0-0.1.sup. Hydroxypropyl .beta.-cyclodextrin 0.630 0.630 0-2.0%
Sodium Hydroxide 0.003 0.003 0.001-0.01 .sup. Fragrance 0 0.4%
0-1.0% Malodor Reduction Composi- 0.03% 0.04% 0-0.1% tion (MRC A,
B, or C) Total 100.000 100.000 100.000 Lupasol HF Polyethyleneimine
(available from BASF) Silwet L-7600 Organosilicone (available from
BASF) Koralone B-119 19% active aqueous solution of 1,2
Benzisothiazolin-3-one (BIT) in dipropylene glycol and water
(available from Dow Chemical)
[0152] The resulting Fabric fresher composition is effective at
reducing or preventing malodor when sprayed on fabrics, such as
articles of clothing or upholstery.
EXAMPLE 5.1-5.2
Aerosol Air Freshener Composition
[0153] An aerosol air freshener composition is prepared with
malodor reduction composition, according to the compositions shown
in Example 1.
TABLE-US-00013 Ingredient Example 5.1 Example 5.2 Water Purified
USP Balance 92.370 Ethyl Alcohol 5.000 5.000 Acid Polyacrylic 0.185
-- Sodium Citrate, Dihydrate -- 0.100 Acid Citric Solution 50% --
0.100 Sodium Dicoctyl 0-0.200 -- Sulfosuccinate Silwet L-7600 0-0.2
0.200 Hydrogenated Castor Oil 1.400 1.400 PEG 60 Fragrance .sup.
0-1.5% 0-1.5% Malodor Reduction 1.0 0-1.50% Composition (MRC A, B,
or C) Hydroxypropyl 0.380 0.380 BetaCyclodextrine Koralone B-119
0.050 0.050 Sodium Hydroxide 20% 0-0.3 -- Total 100 100 Silwet
L-7600 Organosilicone (available from BASF) Koralone B-119 19%
active aqueous solution of 1,2 Benzisothiazolin-3-one (BIT) in
dipropylene glycol and water (available from Dow Chemical)
[0154] A resulting aerosol air freshener is effective at reducing
malodor in the air when sprayed. In addition the aerosol can be
sprayed on fabrics to reduce or prevent malodor.
EXAMPLES 6.1-6.4
Heavy Duty Liquid Composition
[0154] [0155] A HDL-Heavy Duty Liquid composition is prepared with
malodor reduction composition, according to the compositions shown
in Example 1.
TABLE-US-00014 [0155] Example Example Example Example 6.1 6.2 6.3
6.4 WT % WT % WT % WT % Ingredient Active Active Active Active
AE.sub.1.8S 16.3 16.3 12 8 C.sub.11.8 linear alkyl benzene 2.8 2.8
8 -- sulfonic acid HSAS 13.6 13.6 0 22 C24 alcohol, EO9 2.2 2.2 1
1.8 Citric Acid 0.9 0.9 2 1.7 Lactic Acid -- 5.8 -- --
C.sub.12-C.sub.18 Fatty Acid 2.3 1.3 0.8 3.0 Protease (55.3 mg/g)
1.7 1.7 1.7 1.7 Amylase (25.4 mg/g) 0.7 0.7 0.7 0.7 Borax 3.6 3.6
3.6 3.6 Calcium Formate 0.2 0.2 0.2 0.2 Polyethyleneimine 600, 1.6
1.6 -- 1.6 EO20 Polyethyleneimine 600, 1.6 -- 2.0 1.6 EO24, PO16
DTPA 0.3 0.3 0.3 0.3 Tiron .RTM. 0.8 0.8 0.8 0.8 Optical Brightener
[7] 0.3 0.3 0.3 0.3 NaOH 4.0 9.3 4.0 9.3 Na Cumene Sulfonate 1.1
1.1 1.1 1.1 Na Formate 0.2 0.2 0.2 0.2 Aesthetics Dye 0.03-1.0
0.03-1.0 0.03-1.0 0.03-1.0 Perfume 0.5-3.0 0.5-3.0 0.5-3.0 0.5-3.0
Malodor Reducing 0.15-1.0 0.15-1.0 0.15-1.0 0.15-1.0 Composition
Water and Solvent Balance Balance Balance Balance pH 5.0 8.0 5.0
8.0 HSAS secondary alkyl sulfate, acid form DTPA diethylene
triamine pentaacetic acid (DTPA) Tiron
4,5-Dihydroxy-1,3-benzenedisulfonic acid disodium salt
monohydrate
[0156] The resulting heavy duty liquid product when used to wash
articles of clothing is effective at reducing malodor on the washed
clothing.
EXAMPLES 7.1-7.3
Heavy Duty Liquid Composition
[0157] Other examples of HDL--Heavy Duty Liquid composition
prepared with malodor reduction composition, according to the
compositions shown in Example 1.
TABLE-US-00015 Example Example Example 7.1 7.2 7.33 WT % WT % WT %
Ingredient Active Active Active AE.sub.1.8S 14% 8% 11% Amine Oxide
2% -- -- C.sub.11.8 linear alkyl benzene sulfonic 10% -- -- acid
HSAS -- 20% 15 HF LAS -- -- -- C24 alcohol, EO9 1% 2% 1.2% Citric
Acid 3% 1.5% 0.9% C.sub.12-C.sub.18 Fatty Acid 2% 1% 1.5% Protease
(55.3 mg/g) 0.013 0.8 0.013 Amylase (25.4 mg/g) 0.02 0.7 0.02 Borax
.sup. 2-8.0 .sup. 2-8.0 .sup. 2-8.0 Calcium Formate 0.2 0.2 0.2
Carezyme 5.0L 0.01-0.5 -- 0.01-0.5 Polyethyleneimine 600, EO20
0.5-3.0 0.5-3.0 0.5-3.0 Polyethyleneimine 600, EO24, 0.5-3.0 --
0.5-3.0 PO16 DTPA 0.1-1.0 0.1-1.0 0.1-1.0 Tiron .RTM. 0.1-1.5
0.1-1.5 0.1-1.5 Optical Brightener 0.1-1.0 0.1-1.0 0.1-1.0 MEA-
Hydrogenated Castor Oil 0.5-3.0 -- NaOH 0.1-1.0 0.1-1.0 Na Cumene
Sulfonate 1.1 -- Na Formate 0.2 0.2 Dye 0.1 0.1 Malodor Reducing
Composition 0.15-1.0 0.15-1.0 0.15-1.0 Perfume 0.9 0.5-3.sup. Water
and Solvent Balance Balance Balance HSAS secondary alkyl sulfate,
acid form DTPA diethylene triamine pentaacetic acid (DTPA) Tiron
4,5-Dihydroxy-1,3-benzenedisulfonic acid disodium salt
monohydrate
[0158] The resulting heavy duty liquid product when used to wash
articles of clothing is effective at reducing malodor on the washed
clothing.
EXAMPLES 8.1-8.6
Soluble Uni-Dose Heavy Duty Liquid Composition
[0158] [0159] An example for a Soluble Uni-dose heavy duty liquid
composition prepared with malodor reduction composition, according
to the compositions shown in Example 1.
TABLE-US-00016 [0159] 3 compartments pouched product 8.1 8.2 8.3
8.4 8.5 8.6 Form liquid liquid liquid liquid gel liq liq liq
Compartment # 1 1 1 1 1 1 2 3 Dosage (g) 36.0 38.0 32.0 36.0 40.0
34.0 25 35 Alkylbenzene 14.5 13.8 16.0 14.5 13.5 14.5 20.0 sulfonic
acid C.sub.12-14 alkyl 8.5 16.4 10.0 8.5 15.0 8.5 ethoxy 3 sulfate
C.sub.12-13 alkyl 3- 13.0 ethoxylate C.sub.12-14 alkyl 7- 12.5 9.0
14.0 4.0 12.5 17.0 ethoxylate C12-18 Fatty 14.5 8.5 16.0 15.0 7.2
14.5 13.0 acid Citric acid 2.0 4.1 Enzymes 0-3 0-3 0-3 0-3 0-3 0-3
PAP granule.sup.1 50.0 Ethoxysulfated 3.0 2.2 Hexamethylene Diamine
Dimethyl Quat Ethoxylated 4.0 1.0 4.0 3.0 2.0 Polyethylenimine
Hydroxyethane 1.0 1.0 1.6 0.6 0.6 diphosphonic acid Ethylene 1.0
diamine tetra(methylene phosphonic) acid Brightener 0.2 0.2 0.3 0.3
0.2 0.2 0.2 Polydimethyl 3.0 Siloxane Hueing dye.sup.2 0.05 Perfume
1.5-2.0 1.5-2.0 1.5-2.0 1.5-2.0 1.5-2.0 1.5-2.0 Malodor 0.3-0.7
0.3-0.7 0.3-0.7 0.3-0.7 0.3-0.7 0.3-0.7 reducing composition Water
and To 100% minors Buffers (sodium To pH 8.0 carbonate,
monoethanolamine) Solvents (1,2 To 100% propanediol, ethanol),
Sulfate .sup.1PAP granule .sup.2Hueing dye
[0160] The resulting Unidose pouch product when used to wash
articles of clothing is effective at reducing malodor on the washed
clothing.
EXAMPLES 9.1-9.5
Fabric Enhancer Solid Particle or Bead Composition
[0160] [0161] An example of a Fabric Enhancer bead composition
prepared with malodor reduction composition, according to the
compositions shown in Example 1.
TABLE-US-00017 [0161] Example Example Example Example Example 9.1
9.2 9.3 9.4 9.5 Active Active Active Active Active Ingredients Wt %
Wt % Wt % Wt % Wt % PEG 8000 86.21 83.255 83.255 86.21 82.49 Free
(Neat) 4.41 5.88 4.41 4.25 5.88 Perfume Malodor 0.75-1.5 0.75-1.5
0.75-1.5 0.75-1.5 0.75-1.5 reducing composition Perfume 5.88 8.22
8.88 5.88 8.70 Micro Cap- sule (PMC) Encapsulated 1.88 1.88 1.88
1.88 1.88 Perfume Malodor 1.47 -- 1.47 1.63 -- Reducing Composition
Encapsulated -- 0.75 0.75 -- 0.9 Malodor Reducing Composition
Aesthetics 0.015 0.015 0.015 0.015 0.015 Dye 1. PMC is a friable
PMC with a urea-formaldehyde shell from Appvion-Encapsys. About 50%
water by weight of the PMC (including encapsulated perfume) is
assumed. 2. Encapsulated perfume (within PMC) assumes about 32%
active
[0162] The resulting Fabric enhancing bead product when added to an
automatic washing machine is effective at reducing malodor on the
clothing.
EXAMPLES 10.1-10.4
Dryer Added Fabric Softener Sheet Composition
[0162] [0163] An example of a dryer added fabric softener sheet
composition prepared with malodor reduction composition, according
to the compositions shown in Example 1.
TABLE-US-00018 [0163] Example Example Example Example 10.1 10.2
10.3 10.4 Wt % Wt % Wt % Wt % Ingredient Active Active Active
Active DEQA.sup.1 -- 50 -- -- DEQA.sup.2 30 -- -- 30 DTDMAMS.sup.3
-- -- 50 -- 7018FA.sup.4 -- -- 50 -- TS-20.sup.5 15 -- -- 15
SMS.sup.6 15 -- -- 15 SDASA.sup.7 19 25 -- 19 TPED.sup.8 -- 3 -- --
Complex.sup.9 16.5 16.5 -- 8.0 Clay.sup.10 3 4 -- 3 Free (Neat)
Perfume 1.5 1.5 -- 1.5 Free (Neat) malodor 0.5 0.5 0.5 -- reducing
compostion Encapsulated Perfume/ -- -- -- 1.56 malodor reducing
composition .sup.11 Encapsulated Perfume.sup.12 -- 0.4 -- -- Encap
malodor reducing -- -- -- 0.5 composition Active Weight (g/sheet)
2.4 2.4 1.9 2.4 .sup.1DEQA.sup.1: Di(soft
tallowoyloxyethyl)dimethylammonium methyl sulfate with 25%> 7018
FA, as described below, as solvent .sup.2DEQA.sup.2: Di(soft
tallowoyloxyethyl)hydroxyethylmethylammoniun methyl sulfate with
18% partially hydrogenated tallow fatty acid solvent .sup.3DTDMAMS:
Di(hydrogenated tallowalkyl)dimethylammonium methyl sulfate
.sup.47018FA: 70:30 Stearic Acid:Palmitic Acid (IV = 0) Industrene
7018 sold by Witco .sup.5TS-20: Polyoxyethylene-20 Sorbitan
Tristearate (Glycosperse TS-20, sold by Lonza .sup.6SMS: Sorbitan
Mono Stearate .sup.7SDASA: 1:2 ratio of stearyl dimethyl
amine:triple pressed stearic acid .sup.8TPED:
N,N,N',N'-Tetrakis(2-hydroxypropyl)ethylenediamine (Quadrol, sold
by BASF) .sup.9Complex: Beta-Cyclodextrin/Perfume Complex
.sup.10Clay: Calcium Bentonite Clay (Bentonite L sold by Southern
Clay Products Free (Neat) Perfume .sup.11 PMC is a friable PMC with
a urea-formaldehyde shell from Appleton. About 50% water by weight
of the PMC (including encapsulated perfume and/or blocker) is
assumed. .sup.12Encapsulated perfume and encapsulated malodor
reducing composition (within PMC) assumes about 32% active
[0164] The compositions of Example 10 are mixed homogeneously and
impregnated onto a non-woven polyester sheet having dimensions of
about 6% in.times.12'' (about 17.1 cm.times.30.5 cm) and weighing
about 1 gram. [0165] The resulting dryer added fabric softener
sheet product when added to an automatic dryer is effective at
reducing malodor on the clothing.
EXAMPLES 11.1-11.4
Liquid Fabric Enhancer Composition
[0165] [0166] An example of a Liquid Fabric Enhancer composition
prepared with malodor reduction composition, according to the
compositions shown in Example 1.
TABLE-US-00019 [0166] Example Example Example Example 11.1 11.2
11.3 11.4 Wt % Wt % Wt % Wt % Ingredient Active Active Active
Active FSA.sup.1 12 21 18 14 Low MW alcohol 1.95 3.0 3.0 2.28
Structurant.sup.2,3 1.25.sup.e -- 0.2.sup.f -- Free (Neat) Perfume
1.50 1.8 2.0 1.50 Free (Neat) malodor 0.3 0.7 -- -- reducing
composition Encapsulated Perfume.sup.4 -- 0.6 -- 0.6 Encap malodor
reducing -- -- 0.6 0.6 composition.sup.4 Perfume/malodor -- 1.85
1.85 3.7 reducing composition encapsulated.sup.5 Calcium Chloride
0.10 0.12 0.1 0.45 DTPA.sup.6 0.005 0.005 0.005 0.005 Preservative
(ppm).sup.7 5 5 5 5 Antifoam.sup.8 0.015 0.15 0.11 0.011
Polyethylene imines.sup.9 0.15 0.05 -- 0.1 Delivery enhancing 0.1
0.1 0.2 0.05 PDMS emulsion.sup.10 -- 0.5 1 2.0 Dispersant.sup.11 --
-- 0.5 0.2 Organosiloxane 5 -- -- -- Front-end Stability
0.06.sup.11 0.63.sup.12 0.36.sup.11 0.14.sup.12 Aid.sup.12,13 Dye
(parts per million 40 11 30 40 ppm) Ammonium Chloride 0.10
Hydrochloric Acid 0.010 0.01 0.10 0.010 Deionized Water Balance
Balance Balance Balance
.sup.1N,N-di(tallowoyloxyethyl)-N,N-dimethylammonium chloride.
.sup.2Cationic high amylose maize starch-available from National
Starch under the trade name HYLON VII .RTM.. .sup.3Cationic polymer
available from BASF .RTM. under the name Rheovis .RTM. CDE.
.sup.4Encapsulated perfume and encapsulated malodor reducing
composition (within PMC) assumes about 32% active .sup.5PMC is a
friable PMC with a urea-formaldehyde shell from Appleton. About 50%
water by weight of the PMC (including encapsulated perfume and/or
malodor reducing composition) is assumed. .sup.6Diethylene triamine
pentaacetic acid .sup.719% active aqueous solution of 1,2
Benzisothiazolin-3-one (BIT) in dipropylene glycol and water
available from Dow Chemical under the trade name Koralone B-119
.sup.8Silicone antifoam agent available from Dow Corning .RTM.
under the trade name DC2310. .sup.9Polyethylene imines available
from BASF under the trade name Lupasol .RTM..
.sup.10Polydimethylsiloxane emulsion from Dow Corning .RTM. under
the trade name DC346. .sup.11Non-ionic such as TWEEN 20 .TM. or
cationic surfactant as Berol 648 and Ethoquad .RTM. C 25 from Akzo
Nobel. .sup.12Organosiloxane polymer condensate made by reacting
hexamethylenediisocyanate (HDI), and a, w silicone diol and
1,3-propanediamine, N'-(3-(dimethylamino)propyl)-N,N-dimethyl-
Jeffcat Z130) or N-(3-dimethylaminopropyl)-N,Ndiisopropanolamine
(Jeffcat ZR50) commercially available from Wacker Silicones,
Munich, Germany. .sup.13Fineoxocol .RTM. 180 from Nissan Chemical
Co. .sup.14Isofol .RTM. 16 from Sasol. **For example PGE
[0167] Examples 11.1 to 11.4 are made by combining the molten
fabric softener active with the front-end stability agent to form a
first mixture. This first mixture is combined with water and
hydrochloric acid using a high shear mixing device to form a second
mixture. The adjunct ingredients are combined with the second
mixture using low shear mixing to form the fabric enhancing
formula.
[0168] Examples 11.1 through 11.4 are used by dosing 10 to 60 g of
the formula into the rinse liquor for example via dispensing into a
clothes washing machine. Clothes are dried on a line or in an
automated clothes dryer. The fabrics treated with these formulas
have improved feel and scent and are effective at reducing malodor
on the clothing.
EXAMPLE 12.1-12.2
Spray-Dried Laundry Detergent Powder Composition and Process of
Making It
[0169] An example of a Spray-Dried Laundry Detergent Powder
composition prepared with malodor reduction composition, according
to the compositions shown in Example 1.
TABLE-US-00020 [0169] Dried Dried Slurry Powder Slurry Powder 12.1
12.1 12.2 12.2 Compositions w/w % w/w % w/w % w/w % Linear alkyl
benzene sulfonate 10.6 15.8 21.3 35.7 Acrylate/maleate copolymer
4.6 6.8 9.4 14.2 Ethylenediame disuccinic acid 1.4 2.1 1.7 2.9
and/or Hydroxyethane dimethylene phosphonic acid Sodium carbonate
19.4 26.5 18.8 29.9 Sodium sulfate 28.6 42.4 -- -- Carboxy methyl
cellulose polymer -- -- 4.3 7.1 Miscellaneous, such as magnesium
1.4 2.2 2.5 4.2 sulfate, brightener and one or more stabilizers
Free (Neat) Perfume (spray-on) -- 1.7 -- 2.4 Free (Neat) malodor
reduction -- 0.5 -- 0.6 composition (spray-on) Water 34.0 2.0 42.0
3.0
Preparation of Spray-Dried Laundry Detergent Powders.
[0170] Aqueous slurry 12.1 having the composition as described
above is prepared having a moisture content of 34.0%. Any
ingredient added above in liquid form is heated to 70.degree. C.,
such that the aqueous slurry is never at a temperature below
70.degree. C. At the end of preparation, the aqueous slurry is
heated to 80.degree. C. and pumped under pressure (5.times.10.sup.6
Nm.sup.-2), into a counter current spray-drying tower with an air
inlet temperature of from 290.degree. C. The aqueous slurry is
atomized and the atomized slurry is dried to produce a solid
mixture, which is then cooled and sieved to remove oversize
material (>1.8 mm) to form a spray-dried powder, which is
free-flowing. Fine material (<0.15 mm) is elutriated with the
exhaust the exhaust air in the spray-drying tower and collected in
a post tower containment system. The spray-dried powder 12.1 has a
moisture content of 2.0 wt %, a bulk density of 310 g/l and a
particle size distribution such that greater than 90 wt % of the
spray-dried powder has a particle size of from 150 to 710
micrometers. The composition of the spray-dried powder 12.1 is
listed in the table above. Perfume and malodor reduction
composition are sprayed onto the composition following the spray
dry procedure. [0171] Aqueous slurry 12.2 having the composition as
described above is prepared having a moisture content of 42.0%. Any
ingredient added above in liquid form is heated to 70.degree. C.,
such that the aqueous slurry is never at a temperature below
70.degree. C. At the end of preparation, the aqueous slurry is
heated to 85.degree. C. and pumped under pressure (from
6.5.times.10.sup.6 Nm.sup.-2), into a counter current spray-drying
tower with an air inlet temperature of from 275.degree. C. The
aqueous slurry is atomized and the atomized slurry is dried to
produce a solid mixture, which is then cooled and sieved to remove
oversize material (>1.8 mm) to form a spray-dried powder 12.2,
which is free-flowing. Fine material (<0.15 mm) is elutriated
with the exhaust the exhaust air in the spray-drying tower and
collected in a post tower containment system. The spray-dried
powder has a moisture content of 3.0 wt %, a bulk density of 250
g/l and a particle size distribution such that greater than 90 wt %
of the spray-dried powder has a particle size of from 150 to 710
micrometers. The composition of the spray-dried powder is given in
the table above. Perfume and malodor reduction composition are
sprayed onto the composition after the spray dry process.
EXAMPLE 13
Plastic Film Example with Malodor Reducing Composition
[0171] [0172] A plastic film is treated with an Malodor Reduction
Composition disclosed in the present specification. Said treatment
is accomplished by spraying said Malodor Reduction Composition on
the film. Said Malodor Reduction Composition is applied to at a
level of 0.1% to 5% based on weight of the film. The Malodor
Reduction Composition is found on the surface and may also be
absorbed into the plastic film.
EXAMPLE 14
Diaper Example with Malodor Reducing Composition
[0172] [0173] A diaper article, is treated with a Malodor Reduction
Composition disclosed in the present specification. The Malodor
Reduction Composition is disposed on one or more areas such as:
[0174] the garment-facing side; [0175] the body-facing side of the
topsheet; [0176] the absorbent core; [0177] the body-facing side of
the backsheet. [0178] The Malodor Reduction Composition may also be
disposed on the garment-facing side of the absorbent core and/or on
other components such as the garment facing side of a nonwoven
dusting layer or body-facing side of a secondary topsheet or
acquisition layer. In some embodiments, a topsheet or an
acquisition layer may comprise a tissue layer and/or a nonwoven
layer, and the malodor reduction composition may be disposed on
either the tissue layer or the nonwoven layer. As discussed below,
the Malodor Reduction Composition may be in the absorbent article
via incorporation into an adhesive. In some embodiments, the
Malodor Reduction Composition may be incorporated into the
absorbent article via a lotion that is applied to a substrate
component of the article. In some embodiments, the malodor
reduction composition may be incorporated into the absorbent
article via an elastomeric film. In some embodiments, the malodor
reduction composition may be in an article by having been
incorporated into the making of an article component, including,
but not limited to, a film, a nonwoven, AGM, elastics, and/or
ink.
EXAMPLE 16.1-16.5
Deodorant Example with Malodor Reducing Composition
[0178] [0179] An example of Deodorant compositions prepared with
malodor reduction composition, according to the compositions shown
in Example 1.
TABLE-US-00021 [0179] Ingredient 16.1 16.2 16.3 16.4 16.5 Product
Form Solid Solid Solid Solid Aerosol Deodor- Deodor- Deodor-
Deodor- Deodor- ant ant ant ant ant or Control Body Spray
dipropylene glycol 48 48 20 30 20 propylene glycol 19.3 19.3 22 --
-- tripopylene glycol -- -- 25 -- -- Glycerine -- -- -- 10 -- PEG
-8 -- -- -- 20 -- Propylene Glycol 3 1.4 1.4 -- -- -- Myristyl
Ether ethanol -- -- -- -- QS Water QS QS QS QS -- sodium stearate
5.4 5.4 5.5 5.5 -- tetra sodium EDTA 0.5 0.5 0.05 0.05 -- sodium
hydroxide -- -- 0.04 0.04 -- triclosan -- -- 0.3 0.3 -- Neat
Perfume 2.8 2.8 2 1.5 1.5 Malodor reducing -- 0.7 1.0 0.5 0.35
composition Blue 1 0.0009 0.0009 -- -- -- Propellant (1,1 -- -- --
-- 40 difluoroethane) QS - Indicates that this material is used to
bring the total to 100%.
EXAMPLES 17.1-17.3
Body Wash with Malodor Reducing Composition
[0180] An example of Body Wash compositions prepared with malodor
reduction composition, according to the compositions shown in
Example 1.
TABLE-US-00022 [0180] 17.1 Body 17.2Body 17.3Body Wash Wash Wash
Sodium Laureth-3 Sulfate (as 28% 27.85% 27.85% 27.85% active) Water
Q.S. Q.S. Q.S. Sodium Lauryl Sulfate (as 29% 10.34 10.34 10.34
active) Cocamidopropyl Betaine B (30% 4.01 4.01 4.01 active) Citric
Acid 0.18 0.18 0.18 Sodium Benzoate 0.3 0.3 0.3 Disodium EDTA 0.12
0.12 0.12 Methylchloroisothiazolinone/ 0.04 0.04 0.04
Methylisothiazolinone Sodium Chloride 2.35 1.7 1.6 Neat Perfume
1.25 1 2 Malodor reducing composition 0.25 0.175 0.25 QS -
indicates that this material is used to bring the total to
100%.
EXAMPLES 18.1-18.6
Antiperspirant Examples with Malodor Reducing Composition
[0181] An example of Antiperspirant compositions prepared with
malodor reduction composition, according to the compositions shown
in Example 1.
TABLE-US-00023 [0181] 18.1 18.2 18.3 18.4 18.5 18.6 Invisible
Invisible Invisible Soft Soft Soft Solid Solid Solid Solid Solid
Solid Aluminum 24 24 24 26.5 26.5 26.5 Zirconium Trichlorohydrex
Glycine Powder Cyclopentasiloxane Q.S Q.S. Q.S. Q.S. Q.S. Q.S.
Dimethicone -- -- -- 5 5 5 CO-1897 Stearyl 14 14 14 -- -- --
Alcohol NF Hydrogenated 3.85 3.85 3.85 -- -- -- Castor Oil MP80
Deodorized Behenyl Alcohol 0.2 0.2 0.2 -- -- -- Tribehenin -- -- --
4.5 4.5 4.5 C 18-36 acid -- -- -- 1.125 1.125 1.125 triglyceride
C12-15 Alkyl 9.5 9.5 5 -- -- -- Benzoate PPG-14 Butyl 6.5 6.5 --
0.5 0.5 0.5 Ether Phenyl 3 -- 3 -- -- -- Trimethicone White
Petrolatum 3 -- -- 3 3 3 Mineral Oil 1.0 1.0 1.0 -- -- -- Free
(Neat) 1.0 0.75 2.0 0.75 1.0 1.25 Perfume Malodor reducing 0.25 --
0.35 0.175 0.25 0.1 composition Beta-Cyclodextrin -- 3.0 -- -- --
3.0 complexed with Malodor reducing composition Talc Imperial 250
3.0 3.0 3.0 -- -- -- USP Polyacrylate -- -- 1.9 -- -- --
Microcapsule loaded with Malodor reducing composition QS -
indicates that this material is used to bring the total to
100%.
EXAMPLE 19.1-19.4
Dish Cleansing Composition Examples with Malodor Reducing
Composition
[0182] An example of Dish cleaning compositions prepared with
malodor reduction composition, according to the compositions shown
in Example 1.
TABLE-US-00024 [0182] 19.1 19.2 19.3 19.4 Alkyl C.sub.10-14 Ethoxy
26.9 -- -- 25.7 Sulphate (AE0.6S) Alkyl C.sub.10-14 Ethoxy -- 18.7
26.9 -- Sulphate (AE2S) Sodium alkyl benzene -- 8.0 -- -- sulfonate
C12-14 dimethyl amine 6.1 -- -- 4.1 oxide Cocamido propyl betaine
-- 4.5 6.8 3.2 Branched Nonionic: 1.0 0.8 -- -- 3-propyl heptanol
EO8 PEI600-EO10-PO7 -- -- 0.8 -- block polymer Perfume 0.15-0.3
0.15-0.3 0.15-0.3 0.15-0.3 Malodor Reducing 0.06-0.15 0.06-0.15
0.06-0.15 0.06-0.15 Composition Ethanol 4.0 5.0 3.0 3.0
Polypropylene glycol 1.1 0.8 1.1 1.1 MW2000 Sodium Chloride 1.3 0.8
1.3 0.5 Minors* and water to balance up to 100%
EXAMPLES 20.1-20.4
Heavy Duty Liquid Composition
[0183] A HDL-Heavy Duty Liquid composition is prepared with malodor
reduction composition, according to the compositions shown in
Example 1.
TABLE-US-00025 [0183] Example Example Example Example 20.1 20.2
20.3 20.4 WT % WT % WT % WT % Ingredient Active Active Active
Active AE.sub.1.8S 16 16 12 8 C.sub.11.8 linear alkyl benzene 3 3 8
-- sulfonic acid HSAS.sup.1 14 14 0 22 C24 alcohol, EO9 2 2 1 2
Citric Acid 1 1 2 2 Lactic Acid -- 6 -- -- C.sub.12-C.sub.18 Fatty
Acid 2 1 1 3 Protease (55.3 mg/g) 2 2 2 2 Amylase (25.4 mg/g) 0.7
0.7 0.7 0.7 Borax 3.6 3.6 3.6 3.6 Calcium Formate 0.2 0.2 0.2 0.2
Polyethyleneimine 600, 1.6 1.6 -- 1.6 EO20 Polyethyleneimine 600,
1.6 -- 2.0 1.6 EO24, PO16 DTPA.sup.2 0.3 0.3 0.3 0.3 Tiron
.RTM..sup.3 0.8 0.8 0.8 0.8 Optical Brightener 0.3 0.3 0.3 0.3 NaOH
4 9 4 9 Na Cumene Sulfonate 1 1 1 1 Na Formate 0.2 0.2 0.2 0.2
Aesthetics Dye 0.03-1 0.03-1 0.03-1 0.03-1 Perfume 0.5-3 0.5-3
0.5-3 0.5-3 Malodor Reducing 0.1-1 0.1-1 0.1-1 0.1-1 Composition
Water and Solvent Balance Balance Balance Balance pH 5 8 5 8
[0184] The resulting heavy duty liquid product when used to wash
articles of clothing is effective at reducing malodor on the washed
clothing.
EXAMPLES 21.1-21.3
Heavy Duty Liquid Composition
[0185] Other examples of HDL-Heavy Duty Liquid composition prepared
with malodor reduction composition, according to the compositions
shown in Example 1.
TABLE-US-00026 Example Example Example 21.1 21.2 21.3 WT % WT % WT
% Ingredient Active Active Active AE.sub.1.8S 14 8 11 Amine Oxide 2
-- -- C.sub.11.8 linear alkyl benzene sulfonic 10% -- -- acid
HSAS.sup.1 -- 20 15 C24 alcohol, EO9 .sup. 1-2 .sup. 1-2 .sup. 1-2
Citric Acid 0.5-3 0.5-3 0.5-3 C.sub.12-C.sub.18 Fatty Acid .sup.
1-2 .sup. 1-2 .sup. 1-2 Protease (55.3 mg/g) 0.013-0.8 0.013-0.8
0.013-0.8 Amylase (25.4 mg/g) 0.02-0.7 0.02-0.7 0.02-0.7 Borax
.sup. 2-8 .sup. 2-8 .sup. 2-8 Calcium Formate 0.2 0.2 0.2 Carezyme
5.0L 0.01-0.5 -- 0.01-0.5 Polyethyleneimine 600, EO20 0.5-3 0.5-3
0.5-3 Polyethyleneimine 600, EO24, 0.5-3 -- 0.5-3 PO16 DTPA.sup.2
0.1-1 0.1-1 0.1-1 Tiron .RTM. .sup.3 0.1-2 0.1-2 0.1-2 Optical
Brightener 0.1-1 0.1-1 0.1-1 MEA - Hydrogenated Castor Oil 0.5-3
0.5-3 NaOH 0.1-1 0.1-1 0.1-1 Na Cumene Sulfonate 1.1 -- -- Na
Formate 0.2 0.2 0.2 Dye 0.1 0.1 0.1 Malodor Reducing Composition
0.15-1.0 -- 0.15-1.0 Encapsulated Malodor Reducing.sup.4 -- 0.3-3
-- Perfume 0.5-2 0.5-2 -- Encapsulated Perfume.sup.4 -- -- 1.5-3
Water and Solvent Balance Balance Balance .sup.1HSAS is secondary
alkyl sulfate, acid form .sup.2DTPA is diethylene triamine
pentaacetic acid (DTPA) .sup.3 Tiron is
4,5-Dihydroxy-1,3-benzenedisulfonic acid disodium salt monohydrate
.sup.4Encapsulated perfume and encapsulated malodor reducing
composition is a slurry. One non-limiting example of an encapsulate
is a friable microcapsule with a urea-formaldehyde shell from
Appvion-Encapsys. About 50% water by weight of the PMC (including
encapsulated perfume) is assumed.
[0186] The resulting heavy duty liquid product when used to wash
articles of clothing is effective at reducing malodor on the washed
clothing.
EXAMPLES 22.1-22.3
Fabric Enhancer Solid Particle or Bead Composition
[0186] [0187] An example of a Fabric Enhancer bead composition
prepared with malodor reduction composition, according to the
compositions shown in Example 1.
TABLE-US-00027 [0187] Example Example Example 22.1 22.2 22.3 Active
Active Active Ingredients Wt % Wt % Wt % PEG 8000 80-90 80-90 80-90
Free (Neat) Perfume 3.5-6.sup. 4-6 3-5 Malodor reducing composition
0.5-2.sup. 0.5-2.sup. 0.5-2.sup. Encapsulated Perfume .sup.1 0-2
0-2 2-3 Encapsulated Malodor Reducing -- 0.5-2.sup. -- Composition
.sup.1 Dipropylene Glycol 0-6 0-5 .sup. 0-4.5 Aesthetics Dye 0.015
0.015 0.015
[0188] 3. Encapsulated perfume and encapsulated malodor reducing
composition is a slurry. One non-limiting example of an encapsulate
is a friable microcapsule with a urea-formaldehyde shell from
Appvion-Encapsys. About 50% water by weight of the PMC (including
encapsulated perfume) is assumed. [0189] The resulting Fabric
enhancing bead product when added to an automatic washing machine
is effective at reducing malodor on the clothing.
EXAMPLE: 23.1-23.6
Malodor Reduction Composition
[0189] [0190] The following malodor reduction malodor reduction
compositions are made by combining the listed ingredients. All
ingredients are in weight percent of the total malodor reduction
composition.
TABLE-US-00028 [0190] Ingredient CAS# 23.1 23.2 23.3 23.4 23.5 23.6
(3aR,5aS,9aS,9bR)- 6790-58-5 0.1 0.5 0 0 0.5 0.2
3a,6,6,9a-tetramethyl- 2,4,5,5a,7,8,9,9b- octahydro-1H-
benzo[e][1]benzofuran 7-(3-methylbutyl)-1,5- 362467-67-2 1 0.5 0.07
0.6 0.01 0 benzodioxepin-3-one triethyl 2- 77-93-0 0.05 0.2 1 0.5
0.09 0.03 hydroxypropane-1,2,3- tricarboxylate
1,1,2,3,3-pentamethyl- 33704-61-9 1 1 0.5 0.5 0.2 0.2
2,5,6,7-tetrahydroinden-4- one (3R,3aS,6S,7R,8aS)- 19870-74-7 2 1 0
2 1 3 octahydro-6-methoxy- 3,6,8,8-tetramethyl-1H-
3a,7-methanoazulene (5E)-3- 63314-79-4 0.3 0.2 0.43 0 0.15 0.17
methylcyclopentadec-5- en-1-one 4-(octahydro-4,7- 30168-23-1 0.5 1
0.7 1 0.2 0.4 methano-5H-inden-5- ylidene)butanal
3a,4,5,6,7,7a-hexahydro- 5413-60-5 3 1 0.5 0.5 1 0.8
4,7-methanoinden-6-yl acetate 3a,4,5,6,7,7a-hexahydro- 68912-13-0 4
0.8 2 2 0.5 1 1H-4,7-methanoinden-1-yl propanoate
5-(diethoxymethyl)-1,3- 40527-42-2 0.7 0.5 0 0 1 0 benzodioxole
1,3,4,6,7,8-hexahydro- 1222-05-5 5 8 3 8 10 5 4,6,6,7,8,8-
hexamethylcyclopenta(g)- 2-benzopyran 1-(2,3,8,8-tetramethyl-
54464-57-2 18 25 54 28 20 50 1,3,4,5,6,7- hexahydronaphthalen-2-
yl)ethanone 2,2,7,7- 23787-90-8 0.6 0.5 0.5 3 1 0
tetramethyltricyclo[6.2.1.0 1,6]undecan-5-one [(1R,2S)-1-methyl-2-
198404-98-7 0.05 0.5 0 0.18 0.05 0.1 [[(1R,3S,5S)-1,2,2-
trimethyl-3- bicyclo[3.1.0]hexanyl]methyl]cyclopropyl]methanol
2,4-dimethyl-4,4a,5,9b- 27606-09-3 40 38 26 26 20 10
tetrahydroindeno[1,2- d][1,3]dioxine methyl 3-oxo-2- 24851-98-7 15
7 5 15 22 22 pentylcyclopentaneacetate 2-[2-(4-methyl-1- 95962-14-4
5 7 5 10 16 5 cyclohex-3- enyl)propyl]cyclopentan- 1-one 2,2-
101-48-4 0.4 1 0.5 1 1 0 dimethoxyethylbenzene
(E)-3,3-dimethyl-5-(2,2,3- 107898-54-4 0.2 1 0 0.7 0.2 1
trimethyl-3-cyclopenten- 1-yl)-4-penten-2-ol
octahydro-5-methoxy-4,7- 86803-90-9 0.1 0.3 0.3 0.02 0.1 0.1
methano-1H-indene-2- carboxaldehyde 1-oxacycloheptadecan-2-
109-29-5 & 3 5 0.5 1 5 1 one & 502-72-7 cyclopentadecanone
TOTAL 100 100 100 100 100 100
[0191] Each of the malodor reduction compositions of Examples 23.1
through 23.6 is used in a consumer product by combining the malodor
reduction composition at a level of about 0.05% to about 0.35%,
based on total consumer product weight, with the consumer product.
Then the consumer product is applied to a site on the human body
that is in need of malodor reduction. In one aspect, the consumer
product is selected from a shampoo, body wash, conditioner and an
antiperspirant/deodorant.
EXAMPLES 24.1-24.6
Malodor Reduction Composition
[0191] [0192] The following malodor reduction malodor reduction
compositions are made by combining the listed ingredients. All
ingredients are in weight percent of the total malodor reduction
composition.
TABLE-US-00029 [0192] Ingredient CAS # 24.1 24.2 24.3 24.4 24.5
24.6 (E)-1-(2,6,6-trimethyl-1- 127-42-4 4 8 2 8 3 2
cyclohex-2-enyl)pent-1- en-3-one ethyl dodecanoate 106- 0 1 0 3 0 0
33-2 3a,4,5,6,7,7a-hexahydro- 68912- 8 30 1 4 1 3.5
1H-4,7-methanoinden-1- 13-0 yl propanoate [1R- 1139- 0 0.3 2 .5 0
0.5 (1R*,4R*,6R*,10S*)]- 30-6 4,12,12-trimethyl-9- methylene-5-
oxatricyclo[8.2.0.04,6]dodecane (8E)-cyclohexadec-8-en- 3100- 0 5 0
7 0 0 1-one 36-5 3,5,5-trimethylhexyl 58430- 25 15 50 35 60 56
acetate 94-7 ethyl (2,3,6- 93981- 0 1 0 5 0 0 trimethylcyclohexyl)
50-1 carbonate 2,4-dimethyl-4,4a,5,9b- 27606- 25 10 15 15 16 15
tetrahydroindeno[1,2- 09-3 d][1,3]dioxine 2,2,7,7- 23787- 8 9 5 7 5
5 tetramethyltricyclo[6.2.1.01, 90-8 6]undecan-5-one
(3,5-dimethylcyclohex-3- 67634- 0 0.7 0 .5 0 0 en-1-yl)methanol
16-6 3-(7,7-dimethyl-4- 33885- 30 20 25 15 15 18
bicyclo[3.1.1]hept-3- 52-8 enyl)-2,2- dimethylpropanal Total 100
100 100 100 100 100
[0193] Each of the malodor reduction compositions of Examples 24.1
through 24.6 is used as a perfume component in an air care device
at a level of form about 5% to about 100% or in other consumer
products by combining the malodor reduction composition at a level
of about 0.0003% to about 5% based on total consumer product
weight, with the consumer product. Then the consumer product is
applied to a site on the human body that is in need of malodor
reduction, used in an air care device and/or as a treatment
composition to treat a fabric and/or hard surface. In one aspect,
the consumer product is selected from a shampoo, body wash,
conditioner, an antiperspirant/deodorant and/or a fabric or hard
surface cleaner or treatment composition such as a detergent or
fabric enhancer.
[0194] The dimensions and values disclosed herein are not to be
understood as being strictly limited to the exact numerical values
recited. Instead, unless otherwise specified, each such dimension
is intended to mean both the recited value and a functionally
equivalent range surrounding that value. For example, a dimension
disclosed as "40 mm" is intended to mean "about 40 mm."
[0195] Every document cited herein, including any cross referenced
or related patent or application, is hereby incorporated herein by
reference in its entirety unless expressly excluded or otherwise
limited. The citation of any document is not an admission that it
is prior art with respect to any invention disclosed or claimed
herein or that it alone, or in any combination with any other
reference or references, teaches, suggests, or discloses any such
invention. Further, to the extent that any meaning or definition of
a term in this document conflicts with any meaning or definition of
the same term in a document incorporated by reference, the meaning
or definition assigned to that term in this document shall
govern.
[0196] While particular embodiments of the present invention have
been illustrated and described, it would be obvious to those
skilled in the art that various other changes and modifications can
be made without departing from the spirit and scope of the
invention. It is, therefore, intended to cover in the appended
claims all such changes and modifications that are within the scope
of this invention.
* * * * *