U.S. patent application number 15/361593 was filed with the patent office on 2017-03-16 for polymers containing an acetoacetate moiety.
This patent application is currently assigned to ISP Investments LLC. The applicant listed for this patent is ISP Investments LLC. Invention is credited to David K. Hood, Surya Kamin, Karyn B. Visscher.
Application Number | 20170073447 15/361593 |
Document ID | / |
Family ID | 48745371 |
Filed Date | 2017-03-16 |
United States Patent
Application |
20170073447 |
Kind Code |
A1 |
Hood; David K. ; et
al. |
March 16, 2017 |
POLYMERS CONTAINING AN ACETOACETATE MOIETY
Abstract
The present invention provides polymers containing an
acetoacetate moiety. The polymers may be readily functionalized and
the functionalized polymers may be further derivatized to provide a
wide variety of useful polymers having desirable chemical and
physical properties. The polymers of the present invention may be
employed in a wide variety of compositions, wherein
R.sub.1-R.sub.6, w, y, and z are described herein. ##STR00001##
Inventors: |
Hood; David K.; (Basking
Ridge, NJ) ; Kamin; Surya; (Skillman, NJ) ;
Visscher; Karyn B.; (Morris Plains, NJ) |
|
Applicant: |
Name |
City |
State |
Country |
Type |
ISP Investments LLC |
Wilmington |
DE |
US |
|
|
Assignee: |
ISP Investments LLC
Wilmington
DE
|
Family ID: |
48745371 |
Appl. No.: |
15/361593 |
Filed: |
November 28, 2016 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
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14370702 |
Jul 3, 2014 |
9505862 |
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PCT/US12/70599 |
Dec 19, 2012 |
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15361593 |
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61583941 |
Jan 6, 2012 |
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Current U.S.
Class: |
1/1 |
Current CPC
Class: |
C08F 220/1811 20200201;
C08F 220/1811 20200201; C08F 220/283 20200201; C08F 220/283
20200201; C08F 220/1812 20200201; C08F 220/30 20130101; C08F
220/283 20200201; C08F 220/282 20200201; C08F 220/1811 20200201;
C08F 220/1812 20200201; C08F 220/1811 20200201; C08F 220/1811
20200201; C08F 220/18 20130101; C08F 220/301 20200201; C08F 220/301
20200201; C08F 220/283 20200201; C08F 220/301 20200201; C08F 220/28
20130101; C08F 220/1811 20200201; C08F 220/301 20200201; C08F
220/283 20200201; C08F 222/06 20130101; C08F 216/085 20200201; C08F
220/301 20200201; C08F 220/301 20200201; C08F 220/283 20200201;
C08F 220/283 20200201; C08F 222/06 20130101; C08F 222/06 20130101;
C08F 216/085 20200201; C08F 222/06 20130101; C08F 220/283 20200201;
C08F 220/1812 20200201; C08F 220/12 20130101; C08F 220/283
20200201; C08F 220/301 20200201; C08F 220/1812 20200201 |
International
Class: |
C08F 220/28 20060101
C08F220/28; C08F 220/18 20060101 C08F220/18; C08F 220/12 20060101
C08F220/12 |
Claims
1. A polymer containing an acetoacetate moiety having the following
structure: ##STR00024## wherein R.sub.1 and R.sub.2 are each
independently selected from the group consisting of hydrogen and
C.sub.1-C.sub.30 functionalized and unfunctionalized alkyl groups,
wherein any of the before mentioned groups may be with or without
heteroatoms, and mixtures thereof; each R.sub.3 is independently
selected from the group consisting of hydrogen and C.sub.1-C.sub.6
functionalized and unfunctionalized alkyl, amide, carbonyl, and
carboxyl groups, wherein any of the before mentioned groups may be
with or without heteroatoms, and mixtures thereof; each R.sub.4 is
independently selected from the group consisting of functionalized
and unfunctionalized alkenyl, alkoxy, alkyl, amide, aryl, carbonyl,
carboxyl, cycloalkyl groups, and moieties derived from
trialkoxyvinyl silanes, wherein any of the before mentioned groups
may be with or without heteroatoms, and mixtures thereof; each
R.sub.5 is independently selected from the group consisting of
C.sub.1-C.sub.12 functionalized and unfunctionalized alkyl and
alkenyl groups, wherein any of the before mentioned groups may be
with or without heteroatoms, and mixtures thereof; w, y, and z are
mole percent, the sum of which=100%, with the proviso that z may be
0% mole percent.
2. The polymer according to claim 1, wherein each R.sub.1 and
R.sub.2 are independently hydrogen or methyl.
3. The polymer according to claim 1, wherein --R.sub.3-- is
--C(O)OCH.sub.2CH.sub.2--.
4. The polymer according to claim 1, wherein each R.sub.4 is
independently selected from the group consisting of functionalized
and unfunctionalized alkoxy, amide, aryl, carbonyl, carboxyl,
cycloalkyl groups, and moieties derived from triethoxyvinyl silane,
wherein any of the before mentioned groups may be with or without
heteroatoms, and mixtures thereof.
5. The polymer according to claim 1, wherein each R.sub.5 is
independently selected from the group consisting of C.sub.1-C.sub.8
functionalized and unfunctionalized alkyl and alkenyl groups,
wherein any of the before mentioned groups may be with or without
heteroatoms, and mixtures thereof.
6. The polymer according to claim 1, wherein x ranges from 1-98%, y
ranges from 1-98%, and w ranges from 0-98%.
7. The polymer according to claim 1, wherein the polymer has a
structure selected from the group consisting of: ##STR00025##
8. A polymer containing an acetoacetate moiety having the following
structure: ##STR00026## wherein R.sub.1 and R.sub.2 are each
independently selected from the group consisting of hydrogen and
C.sub.1-C.sub.30 functionalized and unfunctionalized alkyl groups,
wherein any of the before mentioned groups may be with or without
heteroatoms, and mixtures thereof; each R.sub.3 is independently
selected from the group consisting of hydrogen and C.sub.1-C.sub.6
functionalized and unfunctionalized alkyl, amide, carbonyl, and
carboxyl groups, wherein any of the before mentioned groups may be
with or without heteroatoms, and mixtures thereof; each R.sub.4 is
independently selected from the group consisting of functionalized
and unfunctionalized alkenyl, alkoxy, alkyl, amide, aryl, carbonyl,
carboxyl, cycloalkyl groups, and moieties derived from
trialkoxyvinyl silanes, wherein any of the before mentioned groups
may be with or without heteroatoms, and mixtures thereof; each
R.sub.5 is independently selected from the group consisting of
C.sub.1-C.sub.12 functionalized and unfunctionalized alkyl and
alkenyl groups, wherein any of the before mentioned groups may be
with or without heteroatoms, and mixtures thereof; y and z are mole
percent, the sum of which=100%.
9. The polymer according to claim 8, wherein each R.sub.1 and
R.sub.2 are independently hydrogen or methyl.
10. The polymer according to claim 8, wherein --R.sub.3-- is
--C(O)OCH.sub.2CH.sub.2--.
11. The polymer according to claim 8, wherein each R.sub.4 is
independently selected from the group consisting of functionalized
and unfunctionalized alkoxy, amide, aryl, carbonyl, carboxyl,
cycloalkyl groups, and moieties derived from triethoxyvinyl silane,
wherein any of the before mentioned groups may be with or without
heteroatoms, and mixtures thereof.
12. The polymer according to claim 8, wherein each R.sub.5 is
independently selected from the group consisting of C.sub.1-C.sub.8
functionalized and unfunctionalized alkyl and alkenyl groups,
wherein any of the before mentioned groups may be with or without
heteroatoms, and mixtures thereof.
13. The polymer according to claim 8, wherein y ranges from 1-99%
and z ranges from 1-99%.
14. The polymer according to claim 8, wherein the polymer has a
structure selected from the group consisting of: ##STR00027##
##STR00028##
15. A composition comprising a polymer containing an acetoacetate
moiety having the following structure: ##STR00029## wherein R.sub.1
and R.sub.2 are each independently selected from the group
consisting of hydrogen and C.sub.1-C.sub.30 functionalized and
unfunctionalized alkyl groups, wherein any of the before mentioned
groups may be with or without heteroatoms, and mixtures thereof;
each R.sub.3 is independently selected from the group consisting of
hydrogen and C.sub.1-C.sub.6 functionalized and unfunctionalized
alkyl, amide, carbonyl, and carboxyl groups, wherein any of the
before mentioned groups may be with or without heteroatoms, and
mixtures thereof; each R.sub.4 is independently selected from the
group consisting of functionalized and unfunctionalized alkenyl,
alkoxy, alkyl, amide, aryl, carbonyl, carboxyl, cycloalkyl groups,
and moieties derived from trialkoxyvinyl silanes, wherein any of
the before mentioned groups may be with or without heteroatoms, and
mixtures thereof; each R.sub.5 is independently selected from the
group consisting of C.sub.1-C.sub.12 functionalized and
unfunctionalized alkyl and alkenyl groups, wherein any of the
before mentioned groups may be with or without heteroatoms, and
mixtures thereof; w, y, and z are mole percent, the sum of
which=100%, with the proviso that z may be 0% mole percent.
16. The composition according to claim 15, wherein each R.sub.1 and
R.sub.2 are independently hydrogen or methyl.
17. The composition according to claim 15, wherein --R.sub.3-- is
--C(O)OCH.sub.2CH.sub.2--.
18. The composition according to claim 15, wherein each R.sub.4 is
independently selected from the group consisting of functionalized
and unfunctionalized alkoxy, amide, aryl, carbonyl, carboxyl,
cycloalkyl groups, and moieties derived from triethoxyvinyl silane,
wherein any of the before mentioned groups may be with or without
heteroatoms, and mixtures thereof.
19. The composition according to claim 15, wherein each R.sub.5 is
independently selected from the group consisting of C.sub.1-C.sub.8
functionalized and unfunctionalized alkyl and alkenyl groups,
wherein any of the before mentioned groups may be with or without
heteroatoms, and mixtures thereof.
20. The composition according to claim 15, wherein x ranges from
1-98%, y ranges from 1-98%, and w ranges from 0-98%.
21. The composition according to claim 15, wherein the polymer has
a structure selected from the group consisting of: ##STR00030##
22. A composition containing an acetoacetate moiety having the
following structure: ##STR00031## wherein R.sub.1 and R.sub.2 are
each independently selected from the group consisting of hydrogen
and C.sub.1-C.sub.30 functionalized and unfunctionalized alkyl
groups, wherein any of the before mentioned groups may be with or
without heteroatoms, and mixtures thereof; each R.sub.3 is
independently selected from the group consisting of hydrogen and
C.sub.1-C.sub.6 functionalized and unfunctionalized alkyl, amide,
carbonyl, and carboxyl groups, wherein any of the before mentioned
groups may be with or without heteroatoms, and mixtures thereof;
each R.sub.4 is independently selected from the group consisting of
functionalized and unfunctionalized alkenyl, alkoxy, alkyl, amide,
aryl, carbonyl, carboxyl, cycloalkyl groups, and moieties derived
from trialkoxyvinyl silanes, wherein any of the before mentioned
groups may be with or without heteroatoms, and mixtures thereof;
each R.sub.5 is independently selected from the group consisting of
C.sub.1-C.sub.12 functionalized and unfunctionalized alkyl and
alkenyl groups, wherein any of the before mentioned groups may be
with or without heteroatoms, and mixtures thereof; y and z are mole
percent, the sum of which=100%.
23. The composition according to claim 22, wherein each R.sub.1 and
R.sub.2 are independently hydrogen or methyl.
24. The composition according to claim 22, wherein --R.sub.3-- is
--C(O)OCH.sub.2CH.sub.2--.
25. The composition according to claim 22, wherein each R.sub.4 is
independently selected from the group consisting of functionalized
and unfunctionalized alkoxy, amide, aryl, carbonyl, carboxyl,
cycloalkyl groups, and moieties derived from triethoxyvinyl silane,
wherein any of the before mentioned groups may be with or without
heteroatoms, and mixtures thereof.
26. The composition according to claim 22, wherein each R.sub.5 is
independently selected from the group consisting of C.sub.1-C.sub.8
functionalized and unfunctionalized alkyl and alkenyl groups,
wherein any of the before mentioned groups may be with or without
heteroatoms, and mixtures thereof.
27. The composition according to claim 22, wherein y ranges from
1-99% and z ranges from 1-99%.
28. The composition according to claim 22, wherein the polymer has
a structure selected from the group consisting of: ##STR00032##
##STR00033##
29. The composition according to claim 15, wherein the composition
comprises adhesives, aerosols, agricultural compositions, anti-soil
redeposition agents, batteries, beverages, biocides, block
copolymers, branch/comb copolymers, cementing compositions,
cleaning compositions, coating compositions, conductive materials,
cosmetic compositions, cross-linkers, dental compositions,
decorated pigments, detergents, dispersants, drugs, electronics,
encapsulations, foods, hair sprays,
household-industrial-institutional, inks and coatings,
interlaminate adhesives, lithographic solutions, membrane additive
compositions, metal working fluids, oilfield compositions, paints,
paper, personal care compositions, pharmaceuticals, pigment
additives, plasters, plastics, printing, reactive biocides,
refractive index modifiers, sequestrants, soil release
compositions, static control agents, and wood-care
compositions.
30. The composition according to claim 22, wherein the composition
comprises adhesives, aerosols, agricultural compositions, anti-soil
redeposition agents, batteries, beverages, biocides, block
copolymers, branch/comb copolymers, cementing compositions,
cleaning compositions, coating compositions, conductive materials,
cosmetic compositions, cross-linkers, decorated pigments, dental
compositions, detergents, dispersants, drugs, electronics,
encapsulations, foods, hair sprays,
household-industrial-institutional, inks and coatings,
interlaminate adhesives, lithographic solutions, membrane additive
compositions, metal working fluids, oilfield compositions, paints,
paper, personal care compositions, pharmaceuticals, pigment
additives, plasters, plastics, printing, reactive biocides,
refractive index modifiers, sequestrants, soil release
compositions, static control agents, and wood-care compositions.
Description
FIELD OF THE INVENTION
[0001] The present invention provides polymers containing an
acetoacetate moiety. The polymers may be readily functionalized and
the functionalized polymers may be further derivatized to provide a
wide variety of useful polymers having desirable chemical and
physical properties. The polymers of the present invention may be
employed in a wide variety of compositions.
BACKGROUND OF THE INVENTION
[0002] Inkjet printers form an image by firing a plurality of
discrete drops of ink from one or more nozzles on to the surface of
a recording sheet placed adjacent the nozzles. Modern inkjet
printers can print on almost any conventional paper or similar
medium. The quality of images produced by such printers is greatly
affected by the properties of the medium used. More particularly,
to produce high quality images reliably, it is necessary that the
recording medium, i.e., the inkjet recording sheet, dry rapidly,
exhibit good ink adhesion, resist image cracking, not promote
excessive spreading of the ink droplet, not promote "wicking", that
is spreading of ink by capillary action through fibrous medium such
as paper, and, importantly, be such that the contrast of the dried
image with moist surfaces does not result in bleeding of ink from
the image. Printing technologies are applied to many different
surfaces, for example, polyester film, polyolefin films including
polyethylene (PE), polypropylene (PP), polycarbonate, polyimide
films, metals (i.e., aluminum, steel, copper), glass, vinyl film,
Tyvek, canvas, polyvinylidene chloride films, textiles, canvas,
leather, rubber, paper, polyurethane, ceramics, wood and the
like.
[0003] In curable ink systems, the inks can be prepared by a
polymerization process initiated by thermal or photo irradiation
(.alpha., .gamma., and x-rays, UV, E-beam, and the like). Desirable
properties in polymeric inks include solution viscosity, lubricity,
gloss, cure speed, adhesion, impact resistance, toughness, coating
hardness, water resistance, tack, surface tension, wetting,
foaming, tensile strength, solvency, dispersive properties,
flexibility, chemical resistance, abrasion resistance, and
penetration.
[0004] The functional attributes of acetoacetoxyethyl methacrylate
are disclosed in Eastman Chemical's "Acetoacetoxyethyl methacrylate
(AAEM) Acetoacetyl Chemistry" Brochure (Publication Number N-319C,
December 1999), which disclosure is incorporated by reference
herein. The functional and chemical attributes of diketene
chemistry are disclosed in "Diketene" by R. Clemens (Chemical
Reviews, Volume 86, Number 2, April 1986), which disclosure is
incorporated by reference herein. The functional and chemical
attributes of ketene chemistry are disclosed in "Ketenes II" by T.
Tidwell (J. Wiley and Sons, New Jersey, USA, 2006), which
disclosure is incorporated by reference herein.
[0005] EP 1578824B1 describes a curable liquid composition
containing an acryloyl group containing resin produced by reacting
monofunctional vinyl compounds and multifunctional acrylic esters
with .beta.-dicarbonyl group containing compound in which the two
activated hydrogen atoms are in its methylene position.
Self-initiating photocurable resins that UV-cure with little or no
photoinitiator are described in Michael L. Gould et al., Novel
Self-Initiating UV-Curable Resins: Generation Three, 1 PROCEEDINGS
FROM RADTECH EUROPE 05, 245-51 (2005). These disclosures are
incorporated by reference herein.
[0006] U.S. 2010/0041846 discloses lactam/vinyl alcohol copolymers,
specifically, hydrophobic cross-linkable) acetylated lactam/vinyl
alcohol copolymers. U.S. Pat. No. 6,933,024 discloses the use and
preparation of poly(vinylpyrrolidone-(PVP) co-vinylalcohol) as an
inkjet recording material by hydrolyzing PVP/polyvinylacetate
copolymer. U.S. Pat. No. 4,350,788 describes a synthetic resin
emulsion containing an acetoacetylated polyvinyl alcohol. U.S. Pat.
No. 2,536,980 describes synthetic polyvinyl
alcohol-1-butene-1,3-diones. U.S. Pat. No. 5,227,423 describes
latex paint comprised of polymers having a non-self-polymerizable
monomer, such as maleic acid and itaconic acid, a co-polymerizable
monomer, such as a N-vinyl lactam, an acrylate, such as
2-hydroxyethyl acrylate, a wet adhesion promoting monomer, such as
acetoacetoxyethyl methacrylate.
[0007] Additional examples for lactamic monomers can be found in "A
novel route to substituted poly(vinyl pyrrolidone)s via simple
functionalization of 1-vinyl-2-pyrrolidone in the 3-position by
ring-opening reactions" by H. Reinecke et. al. (Eur. Poly. 1, 46
(2010) p 1557-1562. Additional examples for lactamic monomers can
be found in "Synthesis and polymerization of new
pyrrolidone-containing methacrylate monomers" by T. P. Davis et.
al. (Polymer, 39, 17, p 4165-4169, 1998).
[0008] Accordingly, new polymeric inks are desirable having
improved properties including solution viscosity, lubricity, gloss,
cure speed, adhesion, impact resistance, toughness, coating
hardness, water resistance, pigment surface decoration, tack,
surface tension, wetting, foaming, tensile strength, solvency,
dispersive properties, flexibility, chemical resistance, abrasion
resistance, and penetration.
SUMMARY OF THE INVENTION
[0009] The present invention provides polymers containing an
acetoacetate moiety having the following structure:
##STR00002##
[0010] wherein R.sub.1 and R.sub.2 are each independently selected
from the group consisting of hydrogen and C.sub.1-C.sub.30
functionalized and unfunctionalized alkyl groups, wherein any of
the before mentioned groups may be with or without heteroatoms, and
mixtures thereof; each R.sub.3 is independently selected from the
group consisting of hydrogen and C.sub.1-C.sub.6 functionalized and
unfunctionalized alkyl, amide, carbonyl, and carboxyl groups,
wherein any of the before mentioned groups may be with or without
heteroatoms, and mixtures thereof; each R.sub.4 is independently
selected from the group consisting of functionalized and
unfunctionalized alkenyl, alkoxy, alkyl, amide, aryl, carbonyl,
carboxyl, cycloalkyl groups, and moieties derived from
trialkoxyvinyl silanes, wherein any of the before mentioned groups
may be with or without heteroatoms, and mixtures thereof; each
R.sub.5 is independently selected from the group consisting of
C.sub.1-C.sub.12 functionalized and unfunctionalized alkyl and
alkenyl groups, wherein any of the before mentioned groups may be
with or without heteroatoms, and mixtures thereof; w, y, and z are
mole percent, the sum of which=100%, with the proviso that z may be
0% mole percent.
[0011] The present invention further provides polymers containing
an acetoacetate moiety having the following structure:
##STR00003##
[0012] wherein R.sub.1 and R.sub.2 are each independently selected
from the group consisting of hydrogen and C.sub.1-C.sub.30
functionalized and unfunctionalized alkyl groups, wherein any of
the before mentioned groups may be with or without heteroatoms, and
mixtures thereof; each R.sub.3 is independently selected from the
group consisting of hydrogen and C.sub.1-C.sub.6 functionalized and
unfunctionalized alkyl, amide, carbonyl, and carboxyl groups,
wherein any of the before mentioned groups may be with or without
heteroatoms, and mixtures thereof; each R.sub.4 is independently
selected from the group consisting of functionalized and
unfunctionalized alkenyl, alkoxy, alkyl, amide, aryl, carbonyl,
carboxyl, cycloalkyl groups, and moieties derived from
trialkoxyvinyl silanes, wherein any of the before mentioned groups
may be with or without heteroatoms, and mixtures thereof; each
R.sub.5 is independently selected from the group consisting of
C.sub.1-C.sub.12 functionalized and unfunctionalized alkyl and
alkenyl groups, wherein any of the before mentioned groups may be
with or without heteroatoms, and mixtures thereof; y and z are mole
percent, the sum of which=100%.
[0013] The polymers of the present invention may be employed in a
wide variety of compositions.
DETAILED DESCRIPTION OF THE INVENTION
[0014] The present invention provides polymers containing an
acetoacetate moiety. The polymers may be readily functionalized and
the functionalized polymers may be further derivatized to provide a
wide variety of useful polymers having desirable chemical and
physical properties.
[0015] In one embodiment, the polymers comprise a monomer derived
from maleic anhydride (cis-butenedioic anhydride), a monomer
containing an acetoacetate moiety, and optionally a monomer to
provide desirable characteristics in the polymer for use in a wide
variety of compositions. The monomer derived from maleic anhydride
provides a wide range of useful properties because of the ability
to fully or partially hydrolyze maleic anhydride to produce
carboxylic acids, esters, salts, half acids, half esters, half
salts, and mixtures thereof. Depending upon the type and amount of
monomers selected and the degree and type of hydrolyzed maleic
anhydride, a wide variety of water-soluble and water-insoluble
polymers may be prepared. The monomer containing an acetoacetate
moiety provides a monomer that can be functionalized with a wide
variety of groups to change the physical and chemical properties of
the polymer. The acetyl group (CH.sub.3CO--) present in the
acetoacetate moiety is thermally and photically labile. Upon
heating or exposure to light, this group can decompose, resulting
in the formation of a radical that can form "macro-initiator" or
"self-initiator" polymers. The monomer that can provide desirable
characteristics in the polymer may be selected from a wide variety
of groups to provide desirable chemical/physical characteristics in
the polymer. The monomer that can provide desirable characteristics
may comprise C.sub.1-C.sub.30 functionalized and unfunctionalized
alkyls, alkenyls, alkoxyls, amides, aryls, carbonyls, carboxyls,
cycloalkyl groups, moieties derived from trialkoxyvinyl silanes,
and mixtures thereof; any of the before mentioned groups may be
with or without heteroatoms.
[0016] In another embodiment, the polymers comprise a monomer
containing an acetoacetate moiety and a monomer to provide
desirable characteristics in the polymer for use in a wide variety
of compositions.
[0017] The monomers containing an acetoacetate moiety may require
no or very little photic or heat initiators, depending upon the
particular polymer. The "macro-initiator" or "self-initiator"
polymers may then be reacted via a polymerization reaction with a
variety of monomer moieties comprising a functional group capable
of "addition polymerization" as a result of exposure to a free
radical. Examples of suitable "addition polymerizable" monomers
include styrenics, vinylics, acrylates, maleics, maleimides,
dienes, etc. Further moieties suitable for derivatization include
those disclosed in Eastman brochure Publication N-319C, December
1999 entitled "Acetoacetoxyethyl Methacrylate (AAEM) Acetoacetyl
Chemistry, which disclosure is incorporated by reference herein.
Insight to addition polymerization processes and techniques can be
found in "Principles of Polymer Chemistry" by Paul J. Flory
(Cornell University Press, Ithaca, N.Y., 1953), which disclosure is
incorporated by reference herein. Further insight can also be found
in "Principles of Polymerization, 4.sup.th Ed." by George Odian (J.
Wiley and Sons, Hoboken, N.J., 2004), which disclosure is
incorporated by reference herein. Properties of many useful
monomers can be found in the "Polymer Handbook, 4.sup.th Ed.,"
edited by J. Brandrup et. al. (J. Wiley and Sons, New York, 1999),
which disclosure is incorporated by reference herein.
[0018] The monomers that can provide desirable characteristics in
the polymers may further include hydroxyethyl acrylate (HEA),
hydroxyethyl methacrylate (HEMA), hydroxybutyl acrylate (HBA),
ethyl hexyl methacrylate (EHMA), phenoxy ethyl acrylate (PEA),
vinylene carbonate, hydroxyethyl pyrrolidone methacrylate, vinyl
acetate (VA), ethyl acrylate, methyl acrylate, iso(butyl)
(meth)acrylates, methylmethacrylate, dimethylaminoethyl
methacrylate (DMAEMA), dimethylaminopropyl methacrylamide (DMAPMA),
2-(2-ethoxyethoxy)ethyl acrylate (EOEOEA), lauryl acrylate (LA),
Stearyl acrylate (SA), acrylic acid-2-ethylhexyl ester, isodecyl
acrylate, diacetone acrylamide, acryloyl morpholine (ACMO),
3-(methacryloylamino)propyl]trimethylammonium chloride (MAPTAC),
4-hydroxybutyl acrylate, (3-acrylamidopropyl)trimethylammonium
chloride (APTAC), isodecyl acrylate (ISODA), lauryl methacrylate
(LM), stearyl methacrylate (SM), 2,2,2-trifluoroethyl methacrylate,
2-acrylamido-2-methyl-1-propanesulfonic acid,
2-acrylamido-2-methyl-1-propanesulfonic acid sodium salt,
[2-(methacryloyloxy)ethyl]dimethyl-(3-sulfopropyl)ammonium
hydroxide,
[3-(methacryloylamino)propyl]dimethyl(3-sulfopropyl)ammonium
hydroxide inner salt, acrylamide, methacrylamide, acrylonitrile,
isobornyl acrylate, cyanoacrylates, C8-C10 acrylate (ODA),
ethylene, styrene, C.sub.8-C.sub.10 acrylate, highly branched vinyl
ester, maleic anhydride (MAN), acrylic acid (AA), sodium
vinylsulfonate, diacetone acrylamide, vinyl carbonate,
mono-acrylated glycols, vinyl ethylene carbonate, vinyl chloride,
4-vinyl aniline, vinylpyridine, trimethylvinylsilane, vinyl
propionate, crotonic acid, polyfunctional acrylates, polyfunctional
allyl ethers, vinyl imidazole, N-vinyl imidazole, glycidyl
methacrylate (GMA) and allyl acetate and allyl alcohol.
[0019] In another aspect, the present invention provides polymers
containing an acetoacetate moiety useful in a wide variety of
compositions including adhesives, aerosols, agricultural
compositions, anti-soil redeposition agents, batteries, beverages,
biocides, block copolymers, branched copolymers, cementing
compositions, cleaning compositions, coating compositions,
conductive materials, comb copolymers, cosmetic compositions,
cross-linkers, decorated pigment surfaces, dental compositions,
detergents, dispersants, drugs, electronics, encapsulations, foods,
graft copolymers, hair sprays, household-industrial-institutional
(HI&I), inks and coatings (suitable for use as a moisture
resistant inkjet recording medium), interlaminate adhesives,
lithographic solutions, membrane additive compositions, metal
working fluids, oilfield compositions, paints, paper, personal care
and hygiene compositions, pharmaceuticals, pigment additives,
plasters, plastics, printing, reactive biocides, refractive index
modifiers, sequestrants, soil release compositions, static control
agents, surfactants, and wood-care compositions.
[0020] Personal care compositions refers to such illustrative
non-limiting compositions as cosmetics, drug delivery systems,
hair, oil, pharmaceuticals, pigment dispersions, preservative
compositions, including those to alter the color and appearance of
the skin, skin, sun, and tissue regeneration scaffolds. Other
personal care compositions include, but are not limited to,
modified natural oils for increased flexibility in styling, durable
styling, increased humidity resistance for hair, skin, and color
cosmetics, sun care water-proof/resistance, wear-resistance, shower
gels, shampoos, and thermal protecting/enhancing compositions.
Dental personal care compositions include denture adhesives,
toothpastes, mouth washes, and the like. Pharmaceutical
compositions include tablet coatings, tablet binders, transdermal
patches, and the like. The wide variety of compositions are
described below in detail.
[0021] As used herein, the following terms have the meanings set
out below.
[0022] The term "acetoacetate moiety" refers to the group
##STR00004##
wherein R' is defined herein. The CH.sub.3--CO-- moiety in the
acetoacetate moiety is thermally and photically labile.
[0023] The term "acidic conditions" refers to conditions relating
to the pH value of an aqueous solution. Pure water is considered to
be neutral, with a pH close to 7.0 at 25.degree. C. Solutions with
a pH value less than 7 are considered to be acidic solutions.
[0024] The term "are each independently selected from the group
consisting of" means that when a group appears more than once in a
structure, that group may be independently selected each time it
appears. For example, in the structure below:
##STR00005##
[0025] R.sub.1-R.sub.5 each appear more than once. The term "are
each independently selected from the group consisting of" means
that each R.sub.1-R.sub.5 group may be the same or different.
[0026] The term "basic conditions" refers to conditions relating to
the pH value. Pure water is considered to be neutral, with a pH
close to 7.0 at 25.degree. C. Solutions with a pH value greater
than 7 are considered to be basic or alkaline.
[0027] The term "branched and unbranched alkyl groups" refers to
alkyl groups, which may be straight chained or branched. For
example, the alkyl groups have from 1 to about 18 carbon atoms,
more particularly, from 1 to about 10 carbon atoms, and yet more
particularly from 1 to about 6 carbon atoms. Branched groups
include isopropyl, tert-butyl, and the like.
[0028] The term "condensation reaction" refers to a chemical
reaction in which two molecules or moieties (functional groups)
combine to form one single molecule, together with the loss of a
small molecule. When this small molecule is water, the reaction is
known as a dehydration reaction.
[0029] The term "copolymer" refers to chains comprising more than
one type of monomer unit.
[0030] The term "halogen" refers to chloro, bromo, iodo and fluoro,
and in one embodiment is bromo and/or chloro.
[0031] The term "heteroatom" refers to atoms such as oxygen,
nitrogen, sulfur, and phosphorous. When the heteroatom is a
nitrogen atom, the nitrogen atom may be present in the form of a
quaternary amine.
[0032] The term "hydrolyzing" refers to a hydrolysis reaction
(hydrolysis) in which a parent molecule is split into two parts by
the addition of a molecule of water. During the hydrolysis
reaction, molecules of water are split into hydrogen cations
(H.sup.+) and hydroxide anions (OH.sup.-). One fragment of the
parent molecule gains a hydrogen cation from the water molecule;
the other fragment gains the hydroxide anion.
[0033] The term "imide" refers to an organic compound comprising
two carbonyl groups (acyl groups) bound to nitrogen atom. The
nitrogen atom in the imide functional group may or may not be
substituted with an organic functional group.
[0034] The term "inert solvent" refers to a solvent that does not
interfere chemically with the reaction.
[0035] The term "intermediate compound" refers to a compound, which
is produced during the course of a chemical synthesis. An
intermediate compound is not itself, the final product, but is used
in further reactions, which produce the final product. This is in
contrast to the starting material and final product. An
intermediate compound is generally not isolated or purified but
rather is used "as is" in the synthesis. Many different
intermediate compounds may be produced during the course of a
synthesis, especially for economical reasons on the industrial
level.
[0036] The term "lactam" refers to a cyclic amide, which generally
can contain from 4-7 ring atoms in total.
[0037] The term "maleic anhydride" (cis-butenedioic anhydride,
toxilic anhydride, 2,5-dioxofuran) is an organic compound with the
formula C.sub.2H.sub.2(CO).sub.2O. Maleic anhydride is the acid
anhydride of maleic acid and in its pure state it is a colorless or
white solid with an acrid odor. Maleic anhydride has the
structure:
##STR00006##
[0038] The term "maleimide" is the chemical compound with the
formula H.sub.2C.sub.2(CO).sub.2NH. Maleimide is an unsaturated
imide, which is an important building block in organic synthesis.
The name is a contraction of maleic acid and imide, the
--C(O)NHC(O) functional group. Maleimide has the structure:
##STR00007##
[0039] The term "Michael addition" or "Michael reaction" generally
refers to the nucleophilic addition of a carbanion or another
nucleophile to an alpha, beta unsaturated carbonyl compound
(electrophile).
[0040] The term "mineral acid" refers to an acid derived from one
or more inorganic compounds. Mineral acids release hydrogen ions
when dissolved in water. Commonly used mineral acids are sulfuric
acid, hydrochloric acid, and nitric acid.
[0041] The term "monomer" refers to the repeat units comprising a
polymer. A monomer is a small molecule that chemically bonds to
other monomers to form a polymer.
[0042] The term "non-homopolymer" refers to a polymer formed from
two or more monomers and includes essentially all polymers that are
not homopolymers. Nonlimiting examples of non-homopolymers include
copolymers, terpolymers, tetramers, and the like, wherein the
non-homopolymer is a random, blocked, or alternating polymer.
[0043] The term "oligomer" refers to a polymer molecule consisting
of only a few monomeric units that are connected by covalent bond.
For example, dimers, trimers, tetramers, etc. The term "polymer"
refers to a large molecule (macromolecule) composed of repeating
structural units (monomers) connected by covalent chemical bonds.
The terms oligomer and polymer are used interchangeably herein.
[0044] The term "ODA" refers to octyl/decyl acrylate, which is a
mixture of n-octyl acrylate and n-decyl acrylate, the structures of
which are set out below, respectively. The % composition of each
component in the mixture is about 30%-70%, by weight.
##STR00008##
[0045] The term "pH" refers to a measure of the acidity or basicity
of an aqueous solution. Pure water is considered to be neutral,
with a pH close to 7.0 at 25.degree. C. Solutions with a pH less
than 7 are considered to be acidic and solutions with a pH greater
than 7 are considered to be basic or alkaline.
[0046] The term "pharmaceutically acceptable," such as
pharmaceutically acceptable carrier, excipient, etc., means
pharmacologically acceptable and substantially non-toxic to the
subject to which the particular compound is administered.
[0047] The term "pharmaceutically acceptable salt" refers to
conventional acid-addition salts or base-addition salts that retain
the biological effectiveness and properties of the compounds of the
present invention and are formed from suitable non-toxic organic or
inorganic acids or organic or inorganic bases. Sample acid-addition
salts include those derived from inorganic acids such as
hydrochloric acid, hydrobromic acid, hydroiodic acid, sulfuric
acid, sulfamic acid, phosphoric acid and nitric acid, and those
derived from organic acids such as p-toluenesulfonic acid,
salicylic acid, methanesulfonic acid, oxalic acid, succinic acid,
citric acid, malic acid, lactic acid, fumaric acid, and the like.
Sample base-addition salts include those derived from ammonium,
potassium, sodium, and quaternary ammonium hydroxides, such as for
example, tetramethylammonium hydroxide. Chemical modification of a
pharmaceutical compound (i.e., drug) into a salt is a technique
well known to pharmaceutical chemists to obtain improved physical
and chemical stability, hydroscopicity, and solubility of
compounds. See, e.g., H. Ansel et. al., Pharmaceutical Dosage Forms
and Drug Delivery Systems (6.sup.th Ed. 1995) at pp. 196 and
1456-1457.
[0048] The term "polymerization" refers to methods for chemically
reacting monomer compounds to form polymer chains. The polymer
chain may be alternating, blocked, or random. The type of
polymerization method may be selected from a wide variety of
methods. Such methods include, but are not limited to, free radical
polymerization methods, such as classical radical polymerization
and controlled radical polymerization, Nitroxide Mediation
Polymerization (NMP), Atom Transfer Radical Polymerization (ATRP),
and Reversible Addition Fragmentation Chain-Transfer (RAFT).
[0049] The term "respectively" is a term that denotes that the
items in a list correspond to each other in the order they are
given. With reference to two or more items, the term refers in a
parallel or sequential manner.
[0050] The present invention provides polymers containing an
acetoacetate moiety having the following structure:
##STR00009##
[0051] wherein R.sub.1 and R.sub.2 are each independently selected
from the group consisting of hydrogen and C.sub.1-C.sub.30
functionalized and unfunctionalized alkyl groups, wherein any of
the before mentioned groups may be with or without heteroatoms, and
mixtures thereof; each R.sub.3 is independently selected from the
group consisting of hydrogen and C.sub.1-C.sub.6 functionalized and
unfunctionalized alkyl, amide, carbonyl, and carboxyl groups,
wherein any of the before mentioned groups may be with or without
heteroatoms, and mixtures thereof; each R.sub.4 is independently
selected from the group consisting of functionalized and
unfunctionalized alkenyl, alkoxy, alkyl, amide, aryl, carbonyl,
carboxyl, cycloalkyl groups, and moieties derived from
trialkoxyvinyl silanes, wherein any of the before mentioned groups
may be with or without heteroatoms, and mixtures thereof; each
R.sub.5 is independently selected from the group consisting of
C.sub.1-C.sub.12 functionalized and unfunctionalized alkyl and
alkenyl groups, wherein any of the before mentioned groups may be
with or without heteroatoms, and mixtures thereof; w, y, and z are
mole percent, the sum of which=100%, with the proviso that z may be
0% mole percent.
[0052] Preferably, each R.sub.1 and R.sub.2 are independently
hydrogen or methyl; R.sub.3 is --C(O)OCH.sub.2CH.sub.2--; each
R.sub.4 is independently selected from the group consisting of
functionalized and unfunctionalized alkoxy, amide, aryl, carbonyl,
carboxyl, cycloalkyl groups, and moieties derived from
triethoxyvinyl silane, wherein any of the before mentioned groups
may be with or without heteroatoms, and mixtures thereof; each
R.sub.5 is independently selected from the group consisting of
C.sub.1-C.sub.8 functionalized and unfunctionalized alkyl and
alkenyl groups, wherein any of the before mentioned groups may be
with or without heteroatoms, and mixtures thereof; w ranges from
1-99%, y ranges from 1-99%, and z ranges from 0-98%; more
preferably w ranges from 1-60%, y ranges from 1-60%, and z ranges
from 0-80%; most preferably w ranges from 1-50%, y ranges from
1-50%, and z ranges from 0-80%.
[0053] Preferably, the polymer has a structure selected from the
group consisting of:
##STR00010##
[0054] The present invention further provides polymers containing
an acetoacetate moiety having the following structure:
##STR00011##
[0055] wherein R.sub.1 and R.sub.2 are each independently selected
from the group consisting of hydrogen and C.sub.1-C.sub.30
functionalized and unfunctionalized alkyl groups, wherein any of
the before mentioned groups may be with or without heteroatoms, and
mixtures thereof; each R.sub.3 is independently selected from the
group consisting of hydrogen and C.sub.1-C.sub.6 functionalized and
unfunctionalized alkyl, amide, carbonyl, and carboxyl groups,
wherein any of the before mentioned groups may be with or without
heteroatoms, and mixtures thereof; each R.sub.4 is independently
selected from the group consisting of functionalized and
unfunctionalized alkenyl, alkoxy, alkyl, amide, aryl, carbonyl,
carboxyl, cycloalkyl groups, and moieties derived from
trialkoxyvinyl silanes, wherein any of the before mentioned groups
may be with or without heteroatoms, and mixtures thereof; each
R.sub.5 is independently selected from the group consisting of
C.sub.1-C.sub.12 functionalized and unfunctionalized alkyl and
alkenyl groups, wherein any of the before mentioned groups may be
with or without heteroatoms, and mixtures thereof; y and z are mole
percent, the sum of which=100%.
[0056] Preferably, each R.sub.1 and R.sub.2 are independently
hydrogen or methyl; R.sub.3 is --C(O)OCH.sub.2CH.sub.2--; each
R.sub.4 is independently selected from the group consisting of
functionalized and unfunctionalized alkoxy, amide, aryl, carbonyl,
carboxyl, cycloalkyl groups, and moieties derived from
triethoxyvinyl silane, wherein any of the before mentioned groups
may be with or without heteroatoms, and mixtures thereof; each
R.sub.5 is independently selected from the group consisting of
C.sub.1-C.sub.8 functionalized and unfunctionalized alkyl and
alkenyl groups, wherein any of the before mentioned groups may be
with or without heteroatoms, and mixtures thereof; y ranges from
1-99% and z ranges from 1-99%; more preferably y ranges from 1-80%
and z ranges from 1-80%; most preferably y ranges from 1-60% and z
ranges from 1-60%.
[0057] Preferably, the polymer has a structure selected from the
group consisting of:
##STR00012## ##STR00013##
[0058] The present invention discloses reactive co-solvents. These
materials consist of (meth)acryl monomers or pre-polymers, a
(meth)acryl ester of an epoxy type monomer or pre-polymer, and a
urethane type monomers or pre-polymers.
[0059] Examples of reactive co-solvents include but are not limited
to 2-hydroxy methyl methacrylate (HEMA), 2-hydroxy ethyl acrylate
(HEA), 2-phenoxy ethyl acrylate (PEA), 2-ethylhexyl-diglycol
acrylate, 2-(2-ethoxyethoxy)ethyl acrylate (EOEOEA), lauryl
acrylate (LA), Stearyl acrylate (SA), isobornyl acrylate (IBOA),
acrylic acid-2-ethylhexyl ester, isodecyl acrylate, diacetone
acrylamide, acryloyl morpholine (ACMO), cyclic trimethylol-propane
formal acrylate (CTFA),
3-(Methacryloylamino)propyl]trimethylammonium chloride (MAPTAC),
4-hydroxybutyl acrylate, (3-Acrylamidopropyl)trimethylammonium
chloride (APTAC), C8-C10 acrylate (ODA), isodecyl acrylate (ISODA),
lauryl methacrylate (LM), stearyl methacrylate (SM),
2,2,2-Trifluoroethyl methacrylate,
2-Acrylamido-2-methyl-1-propanesulfonic acid,
2-Acrylamido-2-methyl-1-propanesulfonic acid sodium salt,
[2-(Methacryloyloxy)ethyl]dimethyl-(3-sulfopropyl)ammonium
hydroxide,
[3-(Methacryloylamino)propyl]dimethyl(3-sulfopropyl)ammonium
hydroxide inner salt, 1,6-hexanediol diacrylate (HDDA), dipropylene
glycol diacrylate (DPGDA), tripropylene glycol diacrylate (TPGDA),
water, alcohol, hydro-alcohol mixtures, 1,4-butanediol diacrylate
(BDDA), Tripropylene glycol diacrylate (TPGDA), dipropyleneglycol
diacrylate (DPGDA), Tripropylene glycol diacrylate (TRPGDA),
1,9-nonanediol diacrylate (NKDA), neopentyl glycol diacrylate
(NPGDA), propoxylated neopentyl glycol diacrylate (NPG2PODA),
polyethylene glycol (200) diacrylate (PEG(200)DA), polyethylene
glycol (400) diacrylate (PEG(400)DA), polyethylene glycol (600)
diacrylate (PEG(600)DA), ethoxylated bisphenol-A diacrylate
(BPA2EODA), triethylene glycol diacrylate (TEGDA), triethylene
glycol dimethacrylate (TEGDMA), glycerol propoxylated triacrylate
(GPTA), diethylene glycol dimethacrylate (DEGDMA), ethoxylated
bisphenol-A dimethacrylate (BPA10EODMA), trimethylolpropane
triacrylate (TMPTA), pentaerythritol triacrylate (PET3A),
ethoxylated tri-methylolpropane triacrylate (TMP3EOTA), propxylated
tri-methylolpropane triacrylate (TMP3POTA), propoxylated glyceryl
triacrylate (GPTA), trimethylolpropane trimethylacrylate (TMPTMA),
ethoxylated trimethylolpropane trimethacrylate (TMP3EOTMA),
2,2-dionol diacrylate, pentaerythritol tetraacrylate (PETA),
neopentylglycol diacrylate hydroxypivalate,
2-acryloyloxyethylphthalic acid,
2-acryloyloxyethyl-2-hydroxyethylphthalic acid,
dimethyloltricyclodecane diacrylate, 2-acryloyloxyethylsuccinic
acid, nonylphenol ethylene oxide adduct acrylate, phenol acrylates,
methoxy-polyethylene glycol acrylate, tetramethylolmethane
triacrylate, dipentaerythritol hexaacrylate (DPHA),
isocyanate-functional unsaturated acrylic ester resin, urethane
diacrylates oligomers, urethane acrylates, modified urethane
acrylates, polyester acrylates, modified bisphenol A diacrylate,
phenoxy-polyethylene glycol acrylate, bisphenol A propylene oxide
modified diacrylate, bisphenol A ethylene oxide adduct diacrylate,
pentaerythritol triacrylate hexamethylenediisocyanate, urethane
prepolymer, isoamyl acrylate, isomyristyl acrylate, isostearyl
acrylate, carbitol acrylate, cyclohexyl acrylate,
tetrahydrofurfuryl acrylate, glycidyl acrylates, acrylamides,
polyfunctional acrylamides, polyfunctional (polyethylene glycol)
acrylates, polyfunctional vinyl amides,
1,4-butane-diol-monoacrylate and/or diglycidyl ether of
1,4-butanediol, and the like. Mixtures of monomers are also
envisioned in the present invention.
[0060] Additional examples include methyl vinylether, ethyl
vinylether, propyl vinylether, n-butyl vinylether, t-butyl
vinylether, 2-ethylhexyl vinylether, n-nonyl vinylether, lauryl
vinylether, cyclohexyl vinylether, cyclohexylmethyl vinylether,
4-methylcyclohexylmethyl vinylether, benzyl vinylether,
dicyclopentenyl vinylether, 2-dicyclopentenoxyethyl vinyl ether,
methoxyethyl vinylether, ethoxyethyl vinylether, butoxyethyl vinyl
ether, methoxyethoxy vinylether, ethoxyethoxyethyl vinylether,
methoxypolyethylene glycol vinylether, tetrahydrofurfuryl
vinylether, dodecyl vinylether, diethylene glycol monovinylether,
2-hydroxyethyl vinylether, 2-hydroxypropyl vinylether,
4-hydroxybutyl vinylether, 4-hydroxymethylcyclohexylmethyl
vinylether, polyethylene glycol vinylether, chloroethyl vinylether,
chlorobutyl vinylether, phenylethyl vinylether, phenoxypolyethylene
glycol vinylether, ethylene glycol divinylether, butylenes glycol
divinylether, hexandiol divinylether, bisphenol A alkyleneoxide
divinylethers, bisphenol F alkyleneoxide divinylethers,
propyleneoxide adducts of trimethylolpropane trivinylether,
triethylene glycol divinylether, cyclohexane dimethanol
divinylether, N-vinyl-2-pyrrolidone (VP), N-vinyl caprolactam
(VCap), N-vinyl imidazole (VI), n-vinyl amides, 4-vinyl pyridine,
2-vinyl pyridine, styrene, 5-vinyl-2-norbornene and the like.
[0061] The non-limiting examples of monofunctional epoxy compounds
include phenyl glycidylether, p-tert-butylphenyl glycidylether,
butyl glycidylether, 2-ethylhexyl glycidylether, allyl
glycidylether, 1,2-butyleneoxide, 1,3-butadienemonooxide,
1,2-epoxydodecane, epichlorohydrin, 1,2-epoxydecane, styreneoxide,
cyclohexeneoxide, 3-methacryloyloxymethylcylcohexeneoxide,
3-acryloyloxymethylcylcohexeneoxide, 3-vinylcylcohexeneoxide, and
the like.
[0062] The non-limiting examples of multifunctional epoxy compounds
include 3,4-Epoxycyclohexylmethyl-3,4-epoxycyclohexane carboxylate,
3-ethyl-3-((ethyloxetane-3-yl)methoxy) methyl)oxetane, bisphenol A
diglycidylether, bisphenol F diglycidylether, bisphenol S
diglycidylether, brominated bisphenol A diglycidylether, brominated
bisphenol F diglycidylethers, brominated bisphenol S
diglycidylether, epoxy novolak resins, hydrogenated bisphenol A
diglycidylethers, hydrogenated bisphenol F diglycidylethers,
hydrogenated bisphenol S diglycidylethers,
3,4-epoxycyclohexylmethyl-3',4'-epoxycyclohexanecarboxylate,
2-(3,4-epoxycyclohexyl-5,5-spiro-3,4-epoxy)
cyclohexane-meta-dioxane, bis(3,4-epoxycyclohexylmethyl) adipate,
vinylcylcohexeneoxide, 4-vinylepoxycyclohexane,
bis(3,4-epoxy-6-methylcyclohexylmethyl) adipate,
3,4-epoxy-6-methylcyclohexyl-3',4'-epoxy-6'-methylcyclohexane
carboxylate, methylene-bis(3,4-epoxycyclohexane), dicyclopentadiene
diepoxide, ethylene glycol di(3,4-epoxycyclohexylmethyl)ether,
ethylene bis(3,4-epoxycyclohexanecarboxylate),
epoxyhexahydrodioctyl phthalate, epoxyhexahydrodi-2-ethylhexyl
phthalate, 1,4-butanediol diglycidylether, 1,6-hexanediol
diglycidylether, glycerol triglycidylether, trimethylolpropane
triglycidylether, polyethylene glycol diglycidylether,
polypropylene glycol diglycidylether, 1,1,3-tetradecadienedioxide,
limonenedioxide, 1,2,7,8-diepoxyoctane, 1,2,5,6-diepoxycyclooctane,
and the like.
[0063] The present invention relates to curing or cross-linking or
polymerizing a polymerizable material is carried out by any
appropriate method known or explored in the prior-arts by a person
skilled in the art. Insight to curing and cross-linking technology
is further disclosed in "Thermosetting Polymers," J. P. Pascault
et. al. (Marcel Dekker, New York, 2002) and is referred and
disclosed herein in its entirety. Particularly, the polymerization
of reactive solution comprising polymerizable polymer is carried
out by employing any one of the method disclosed in "Principles of
Polymerization 4.sup.th edition," by George Odian (J. Wiley and
Sons, Hoboken, N.J., 2004) and is referred and disclosed herein in
its entirety. The preferable techniques or methods employed by the
present invention to polymerize the polymers would include
UV-radiation, UV-LED, laser beam, electron beam, gamma irradiation,
free-radical, cationic, anionic, thermal, exposure to e-beam and/or
by employing a high-energy source in presence of suitable photo
initiator for the initiation of polymerization. Suitable source of
radiation including but not limited to mercury, xenon, halogen,
carbon arc lamps, sunlight, and radioactive sources.
[0064] The present invention relates to material suitable for
decorating (functionalizing or surface modification) the surface of
a pigment. A pigment is defined as an insoluble substance, in
solvent or water that is a particule. Often it is desirable to
decorate the pigment surface in order to impart new and useful
properties. For example, K. Holmberg et. al. describes technology
related to surface modifications of aluminium (inorganic) pigments
in Adv. Colloidal and Interface Sci. 128-130 (2006) 121-134, and is
referred and disclosed herein in its entirety. Additionally,
organic pigments, such as polyvinyl polypyrrolidone (PVPP), are not
easily functionalized. Incorporation of acetoacetate functionality
provides for many decoration approaches to functionalizing the
surface of such particles, with either new organic and/or inorganic
features.
[0065] In order to induce polymerization via irradiation, often an
appropriate photoinitiator(s), which has high storage stability
after being added, are incorporated to initiate the polymerization
reaction system. Preferable photoinitiators are selected from the
following non-limiting group or class of compounds such as
2-hydroxy-2-methyl-1-phenylpropane-1-one, 1-hydroxycyclohexyl
phenyl ketone, and
2-methyl-1-[4-(methylthio)phenyl]-2-morphorinopropane-1-on;
benzoins e.g. benzyl dimethyl ketal; benzophenones such as
benzophenone, 4-phenylbenzophenone, and hydroxybenzophenone;
thioxanthones such as isopropylthioxanthone and
2,4-diethylthioxanthone; acylphosphine oxides; and other special
initiators such as methyl phenyl glyoxylate;
bis[4-(di(4-(2-hydroxyethyl)phenyl)sulfonio)phenyl sulfide], a
mixture of bis[4-diphenylsulfonio]phenyl)sulfide
bis(hexafluoroantimonate and diphenyl-4-thiophenoxyphenylsulfonium
hexafluoroantimonate,
bis[4-(di(4-(2-hydroxyethyl)phenyl)sulfonio)phenyl sulfide],
5-2,4-cyclopentadiene-1-yl-[(1,2,3,4,5,6-.eta.)-(1-methylethyl-)benzene]--
iron (1+)-hexafluorophosphate(1-)), 4-(2-hydroxytetradecanyloxy)
diphenyliodonium hexafluoroantimonate, (4-hydroxynaphtyl)
dimethylsulfonium hexafluoroantimonate), photo latent bases such as
photo latent diazabicyclo nonene, triphenylsulfonium
hexafluorophosphate, triphenylsulfonium hexafluoroantimonate,
4-methoxyphenyldiphenylsulfonium hexafluoroantimonate,
4-methoxyphenyliodonium hexafluoroantimonate,
bis(4-tert-butylphenypiodonium tetrafluoroborate,
(bis(4-tert-butylphenyl)iodonium hexafluorophosphate),
(bis(4-tert-phenyl)iodonium hexafluoroantimonate),
(bis[4-(diphenylsulfonio)phenyl]sulfide bis(hexafluorophosphate)),
Aryldiazonium salts, diaryliodonium salts, triaylsulfonium salts,
triarylselenonium salts, dialkylphenacylsulfonium salts,
triarylsulfoxonium salts, triethanol amine, aryloxydiarylsulfonium
salts, and the like for example, triphenylsulfonium
hexaflurophosphate, methyidiphenylsulfonium hexafluorophosphate,
dimethylphenylsulfonium hexaflurophosphate,
diphenyinapththylsulfonium hexaflurophosphate,
di(methoxynapththyl)methylsulfonium hexaflurophosphate,
(4-octyloxyphenyl) phenyl iodonium hexafluoro antimonate,
(4-octyloxyphenyl) diphenyl sulfonium hexafluoro antimonate,
(4-decyloxyphenyl) phenyl iodonium hexafluoro antimonite,
(4-dodecyloxyphenyl)diphenyl sulfonium hexafluoroantimonate.
Particularly, employed photoinitiators include
10-biphenyl-4-yl-2-isopropyl-9H-thixanthen-10-ium
hexaflurophosphate, 4,4'-dimethyl iodonium hexaflurophosphate,
mixed triarylsulfonium hexaflurophosphate salts and reaction
products of polyol and
10-(2-carboxymethoxy)-biphenyl-4yl-2-isopropyl-9-oxo-9H-thioxanthen-10-iu-
m hexaflurophosphate. Further, these photoinitiators are used alone
or in combination thereof. Alternatively, if essential, the
photoinitiator may be used by mixing it with one or more
photopolymerization accelerator, such as a benzoic acid (e.g.,
4-dimethylaminobenzoic acid) or a tertiary amine (e.g.,
diazabicyclo nonene (DBN)), in any appropriate ratio. The
photoinitiator is preferably added to the photopolymerizable
composition in the range of about 0.1% to about 20% by weight.
[0066] In order to induce the Michael Addition, often an
appropriate base is required. Preferable bases include diazabicyclo
nonene (DBN), diazabicyclo undecene (DBU), tetramethylguanidine
(TMG), sodium hydroxide (NaOH), potassium hydroxide (KOH) and the
like. Additional insight to suitable bases can be found in "Super
Bases for Organic Synthesis" edited by T. Ishikawa (J. Wiley and
Sons, West Sussex, U K, 2009.
[0067] According to one embodiment of the present invention, the
polymerizable material reacted through free-radical polymerization
in presence of a free-radical initiator. It refers to any chemical
moiety, which, upon exposure to an appropriate energy source (e.g.
light or heat) decomposes in to two independent uncharged fragments
left with highly reactive one unpaired electron. The contemplated
free radical initiator for polymerization would include but are not
limited to various derivatives of peroxides, peresters and/or azo
compounds. More particularly, selected from the group consisting of
dicumyl peroxide, dibenzoyl peroxide, 2-butanone peroxide,
tert-butyl perbenzoate, di-tert-butyl peroxide,
2,5-bis(tert-butylperoxy)-2,5-dimethylhexane, bis(tert-butyl
peroxyisopropyl)benzene, and tert-butyl hydroperoxide), diacyl
peroxides, cumene hydroperoxide, dialkyl peroxides, hydroperoxides,
ketone peroxides, monoperoxycarbonates, peroxydicarbonates,
peroxyesters, and peroxyketals, including tertiary butyl
perbenzoate, tertiary butyl peroctoate in diallyl phthalate,
diacetyl peroxide in dimethyl phthalate, dibenzoyl peroxide,
1-hydroxy cyclohexyl-1-phenyl ketone, bis (2,4,6-trimethyl
benzoyl)phenyl phosphine, benzoin ethyl ether,
2,2-dimethoxy-2-phenyl acetophenone, di(p-chlorobenzoyl) peroxide
in dibutyl phthalate, di(2,4-dichlorobenzoyl) peroxide with dibutyl
phthalate, dilauroyl peroxide, methyl ethyl ketone peroxide,
cyclohexanone peroxide in dibutyl phthalate,
3,5-dihydroxy-3,4-dimethyl-1,2-dioxacyclopentane,
t-butylperoxy(2-ethyl hexanoate), caprylyl peroxide,
2,5-dimethyl-2,5-di(benzoyl peroxy) hexane, 1-hydroxy cyclohexyl
hydroperoxide-1, t-butyl peroxy (2-ethyl butyrate),
2,5-dimethyl-2,5-bis(t-butyl peroxy) hexane, cumyl hydroperoxide,
diacetyl peroxide, t-butyl hydroperoxide, ditertiary butyl
peroxide, 3,5-dihydroxy-3,5-dimethyl-1,2-oxacyclopentane, and
1,1-bis(t-butyl peroxy)-3,3,5-trimethyl cyclohexane and
di-(4-t-butyl cyclohexyl) peroxydicarbonate, azo compounds such as
azobisisobutyronitrile and azobiscyclohexanenitrile (e.g.,
2,2'-azobis(2-methyl-propanenitrile),
2,2'-azobis(2-methylbutanenitrile), and
1,1'-azobis(cyclohexanecarbonitrile)) and the like mixtures and
combinations thereof. Alternatively, all of the above revealed free
radical initiator can be used for thermal based polymerization
alone or appropriate mixture thereof and wherein, the
polymerization reaction is initiated through heat energy.
Particular thermal initiator employed for the polymerization of
polymer would comprise 2,2'-azobis (2,4-dimethylpentanenitrile),
2,2'-azobis (2-methylpropanenitrile), 2,2'-azobis
(2-methylbutanenitrile), peroxides such as benzoyl peroxide, and
the like. Preferably, the thermal initiator is
2,2'-azobis(isobutyronitrile).
[0068] The structure of polymerizable polymer present in the
reactive solution is confirmed from appropriate spectral techniques
that are known in the art and preferably employed spectral
techniques would include .sup.1H-NMR, .sup.13C-NMR, and FT-IR
spectra.
[0069] According to one embodiment of the present invention, a
colorant may be added. The colorant can be in the form of a
pigments or dye. Combinations of pigments and dyes are also
envisioned. Suitable pigment materials are described in Hunger's
"Industrial Organic Pigments," Itoh's "Dictionary of Pigments," and
Leach and Pierce's "Printing Ink Manual."
[0070] According to one embodiment of the present invention, a
solvent may be added. Suitable solvents are described in the
"Industrial Solvents Handbook, 4.sup.th Edition" edited by E. W.
Flick (Noyes Data Corporation, Park Ridge, N.J., 1991), which
disclosure is incorporated by reference herein. For additional
consideration of solvents, useful information is described in
"Polymer Handbook, 4.sup.th Edition," edited by J. Brandrup et. al.
(J. Wiley and Sons, New York, 1999), which disclosure is
incorporated by reference herein.
[0071] In one process for preparing a reactive solution comprising
acetoacetate polymer is (a) producing polymerizable polymer in a
low boiling solvent, (b) eliminating the low boiling solvent at
atmospheric or reduced pressure; and (c) replenishing with at least
one higher boiling reactive solvent. Wherein, the solvent is
selected from polar and non-polar category. The typical
non-limiting example of the solvents employed in the process would
include toluene, xylene, cyclohexanone, chlorobenzene, methyl ethyl
ketone, dichloroethane, chloroform, chloromethane, dichloromethane,
carbon tetrachloride, ethylene chloride, trichloroethane, ethyl
acetate, n-propyl acetate, iso-propyl acetate, 2-nitropropane, any
form of water (distilled, deionized or tap) and water miscible
solvents such as tetrahydrofuran, acetone, dioxane, dimethyl
formamide, dimethyl sulfoxide, ethanol, methanol, propanol,
isopropanol, butanol, isobutanol, ethylene glycol, ethylene glycol
monomethyl ether, and propylene glycol. The solvent is eliminated
from the reaction mixture employing suitable techniques that are
known in the art to concentrate the reaction mixture, however, the
preferable method of elimination is boiling, distilling,
evaporating with or without vacuum.
[0072] In another aspect, application of a wide variety of
compositions comprising the novel modified polymers are provided,
including adhesives, aerosols, agricultural compositions, anti-soil
redeposition agents, batteries, beverages, biocides, block
copolymers, branch copolymers, cementing compositions, cleaning
compositions, comb copolymers, coating compositions, conductive
materials, cosmetic compositions, cross-linkers, decorated pigment
surfaces, dental compositions, detergents, dispersants, drugs,
electronics, encapsulations, foods, graft copolymers, hair sprays,
household-industrial-institutional (HI&I), inks and coatings
(suitable for use as a moisture resistant inkjet recording medium),
interlaminate adhesives, lithographic solutions, membrane additive
compositions, metal working fluids, oilfield compositions, paints,
paper, personal care compositions, pharmaceuticals, pigment
additives, plasters, plastics, printing, reactive biocides,
refractive index modifiers, sequestrants, soil release
compositions, static control agents, and wood-care
compositions.
[0073] Compositions belonging to the personal care/cosmetic and
pharmaceutical arts find utility in altering, delivering an active,
enhancing, improving, modifying the appearance, condition, color,
health, style of the skin (including face, scalp, and lips), hair,
nails, and oral cavity. Many examples and product forms of these
compositions are known. These compositions can impart benefits that
include, but are not limited to, hair style flexibility, hair style
durability, humidity resistance for hair, color and/or color
protection, moisturization, wrinkle reduction, protection from
ultraviolet radiation, water proofness, water resistance, wear
resistance, thermal protection, adhesion, active ingredient
delivery, anti-cavity, and/or anti-gingivitis protection. As such,
these compositions are sometimes categorized in the following
areas: skin care, hair care (both styling and non-styling), sun
care, cosmetics (including color cosmetics), antiperspirants,
deodorants, oral hygiene, and men's and women's personal
hygiene/grooming. In some cases these benefits and care areas
overlap with another.
[0074] Skin care compositions include those materials used on the
body, face, hands, lips, and/or scalp, and are beneficial for many
reasons, such as firming, anti-cellulite, moisturizing, nourishing,
cleaning, reducing or eliminating the appearance of wrinkles or
lentigo, toning, and/or purifying. They also can be used to
sanitize.
[0075] Consumers can identify many of the compositions that serve
the sun care area, for example after-fun, children's, beach,
self-tan, sports (i.e., being sweatproof, waterproof, resistant to
running, or having added UV absorbers and/or antioxidants),
sensitive skin products (i.e., having low irritation to the eyes
and/or skin, and/or being free of fragrances and/or dyes), daily
wear, leave-on hair creams, lotions, styling products, and hair
sprays. Typically, sun care products also comprise one or more UV
actives, which are those organic and inorganic materials that
scatter, absorb, and/or reflect radiation having a wavelength from
about 100 nm to about 400 nm. In one aspect, the sun care product
protects against UV-A and/or UV-B radiation. UV-A radiation, from
about 320 nm to about 400 nm, has the longest wavelength within the
UV spectrum, and consequently is the least energetic. While UV-A
rays can induce skin tanning, they are liable to induce adverse
changes as well, especially in the case of sensitive skin or of
skin, which is continually exposed to solar radiation. In
particular UV-A rays cause a loss of skin elasticity and the
appearance of wrinkles, leading to premature skin aging. UV-B rays
have shorter wavelengths, from about 290 nm to about 320 nm, and
their higher energy can cause erythema and skin burns, which may be
harmful. Alternatively, sun care products may omit UV actives, and
may be regarded as a tanning oil or a tan promoter. Some sun care
compositions may promote soothe skin after sun exposure, and/or be
formulated for application to the lips, hair, or the area around
the eyes. Self-tan compositions, which are products that color skin
without requiring full sun exposure, also fit under the sun care
umbrella. The many different sun care product formats include may
assume a consistency ranging from liquid to semiliquid forms (e.g.,
milks, creams), to thicker forms like gels, creams, pastes, and
even solid- and wax-like forms. Sun care products also may take the
form of an aerosol, spray, mist, roll-on, or wipe.
[0076] Hair care compositions include shampoos, leave-on and
rinse-out conditioners used for conditioning, moisturizing,
repairing, hair colors, hair relaxers, and deep conditioners and
treatments such as hot oils and waxes, 2-in-1 shampoo/conditioner
combination products, 3-in-1 shampoo/conditioner/styling agent. The
many types of hair care products can be delivered in an array of
formats, including aerosol sprays, pump sprays, gel sprays,
mousses, gels, waxes, creams, pomades, spritzes, putties, lacquers,
de-frizzing serums, perms, relaxants and colorants.
[0077] Color cosmetic compositions include facial make-up, eye
makeup, mascaras, lip and nail products. Facial make-up
compositions include foundation (liquid, solid, and
semi-solid)--skin tinted creams, liquid, sticks, mousses used as a
base under make-up, rouge, face powder, blusher, highlighters, face
bronzers, concealers, and 2-way cake products.
[0078] Personal care/cosmetics also include eye make-up, mascaras,
eyeliners, eye shadows, eyebrow pencils and eye pencils. Lip
products include lipsticks, lip pencils, lip gloss, transparent
bases and tinted lip moisturizers as well as multi-function color
sticks that can also be used for cheeks and eyes. Nail products
include nail varnishes/enamels, nail varnish removers, treatments,
home-manicure products such as cuticle softeners and nail
strengtheners.
[0079] In addition to the skin, hair, and sun care compositions
summarized above, the polymers related herein also find application
in oral care compositions. Non-limiting examples or oral care
compositions include toothpastes (including toothpaste gels),
denture adhesives, whiteners, anesthetics, and dental floss and
related products. These compositions may take any product format,
such as pastes, gels, creams, solutions, dispersions, rinses,
flosses, aerosols, powders, and lozenges.
[0080] Grooming products for men and women include shaving products
and toiletries, which may find use in preparing the skin and/or
hair for dry or wet shaving. In addition, these compositions may
help to moisturize, cool, and/or soothe skin. A variety of product
forms are known, a few of which are foams, gels, creams, sticks,
oils, solutions, tonics, balms, aerosols, mists, sprays, and
wipes.
[0081] The polymer can also be used in other personal care/cosmetic
applications, such as an absorbent material in appropriate
applications such as diapers, incontinence products, feminine
products, and other related products.
[0082] The polymers described herein also find application in bath
and shower compositions, such as foams, gels, salts, oils, balls,
liquids, powders and pearls. Also included are bar soaps, body
washes, shower gels, cleansers, gels, oils, foams, scrubs and
creams. As a natural extension of this category, these compositions
also include liquid soaps and hand sanitizers used for cleaning
hands.
[0083] The polymer of the invention can be used in combination with
one or more additional personal care/cosmetically acceptable
additives chosen from, for example, conditioning agents, protecting
agents, such as, for example, hydrosoluble, liposoluble and
water-insoluble UV filters, antiradical agents, antioxidants,
vitamins and pro-vitamins, fixing agents, oxidizing agents,
reducing agents, dyes, cleansing agents, anionic, cationic,
nonionic and amphoteric surfactants, thickeners, perfumes,
pearlizing agents, stabilizers, pH adjusters, filters,
preservatives, hydroxy acids, various cationic, anionic and
nonionic polymers, cationic and nonionic polyether associative
polyurethanes, vegetable oils, mineral oils, synthetic oils,
polyols such as glycols and glycerol, silicones, aliphatic
alcohols, colorants, bleaching agents, highlighting agents and
sequestrants.
[0084] For some embodiments, it may be preferred to add one or more
preservatives and/or antimicrobial agents, such as, but not limited
to, benzoic acid, sorbic acid, dehydroacetic acid, piroctone
olamine, DMDM hydantoin, IPBC, triclosan, bronopol, formaldehyde,
isothiazolinones, nitrates/nitrites, parabens, phenoxyethanol,
potassium sorbate, sodium benzoate, sulphites, and sulphur dioxide.
Combinations of preservatives may be used.
[0085] In other embodiments it may be desirable to incorporate
preservative boosters/solvents, select examples of which include
caprylyl glycol, hexylene glycol, pentylene glycol,
ethylhexylglycerin, caprylhydroxamic acid, and glyceryl caprylate.
Humectants, which include glycerin, butylene glycol, propylene
glycol, sorbitol, mannitol, and xylitol may be added.
Polysaccharides, such as gum Arabic, may be included as well. It
may be desirable to include one or more other ingredients, such as
those described in U.S. patent publication 2010/0183532 and WO
2010/105050, which disclosures are incorporated herein by
reference.
[0086] These additives may be present in the composition according
to the invention in proportions that may range from about 0% to
about 20% by weight in relation to the total weight of the
composition. The precise amount of each additive may be easily
determined by an expert in the field according to its nature and
its function.
[0087] Examples of these co-ingredients and many others can be
found in the following references, each of which is herein
incorporated in its entirety by reference: "Inventory and common
nomenclature of ingredients employed in cosmetic products,"
Official Journal of the European Union, 5.4.2006, pages L 97/1
through L 97/528; and International Cosmetic Ingredient Dictionary
and Handbook, 13.sup.th edition, ISBN: 1882621476, published by The
Personal Care Products Council in January 2010.
[0088] Any known conditioning agent is useful in the personal
care/cosmetic compositions of this invention. Conditioning agents
function to improve the cosmetic properties of the hair,
particularly softness, thickening, untangling, feel, and static
electricity and may be in liquid, semi-solid, or solid form such as
oils, waxes, or gums. Similarly, any known skin-altering agent is
useful in the compositions of this invention. A few examples of
conditioning agents include cationic polymers, cationic surfactants
and cationic silicones. Conditioning agents may be chosen from
synthesis oils, mineral oils, vegetable oils, fluorinated or
perfluorinated oils, natural or synthetic waxes, silicones,
cationic polymers, proteins and hydrolyzed proteins, ceramide type
compounds, cationic surfactants, fatty amines, fatty acids and
their derivatives, as well as mixtures of these different
compounds.
[0089] The synthesis oils include polyolefins, e.g.,
poly-.alpha.-olefins such as polybutenes, polyisobutenes and
polydecenes. The polyolefins can be hydrogenated. The mineral oils
suitable for use in the compositions of the invention include
hexadecane and oil of paraffin. Suitable animal and vegetable oils
include sunflower, corn, soy, avocado, jojoba, squash, raisin seed,
sesame seed, walnut oils, fish oils, glycerol tricaprocaprylate,
Purcellin oil or liquid jojoba. Suitable natural or synthetic oils
include eucalyptus, lavender, vetiver, litsea cubeba, lemon,
sandalwood, rosemary, chamomile, savory, nutmeg, cinnamon, hyssop,
caraway, orange, geranium, cade, and bergamot. Suitable natural and
synthetic waxes include carnauba wax, candelila wax, alfa wax,
paraffin wax, ozokerite wax, vegetable waxes such as olive wax,
rice wax, hydrogenated jojoba wax, absolute flower waxes such as
black currant flower wax, animal waxes such as bees wax, modified
bees wax (cerabellina), marine waxes and polyolefin waxes such as
polyethylene wax.
[0090] The cationic polymers that may be used as a conditioning
agent according to the invention are those known to improve the
cosmetic properties of hair treated by detergent compositions. The
expression "cationic polymer" as used herein, indicates any polymer
containing cationic groups and/or ionizable groups in cationic
groups. The cationic polymers used generally have a molecular
weight the average number of which falls between about 500 and
5,000,000, for example between 1000 and 3,000,000. Cationic
polymers may be chosen from among those containing units including
primary, secondary, tertiary, and/or quaternary amine groups that
may either form part of the main polymer chain or a side chain.
Useful cationic polymers include known polyamine, polyaminoamide,
and quaternary polyammonium types of polymers, such as:
[0091] homopolymers and copolymers derived from acrylic or
methacrylic esters or amides. The copolymers can contain one or
more units derived from acrylamides, methacrylamides, diacetone
acrylamides, acrylamides and methacrylamides, acrylic or
methacrylic acids or their esters, vinyllactams such as vinyl
pyrrolidone or vinyl caprolactam, and vinyl esters. Specific
examples include: copolymers of acrylamide and dimethyl amino ethyl
methacrylate quaternized with dimethyl sulfate or with an alkyl
halide; copolymers of acrylamide and methacryloyl oxyethyl
trimethyl ammonium chloride; the copolymer of acrylamide and
methacryloyl oxyethyl trimethyl ammonium methosulfate; copolymers
of vinyl pyrrolidone/dialkylaminoalkyl acrylate or methacrylate,
optionally quaternized, such as the products sold under the name
Gafquat.RTM. by International Specialty Products; the dimethyl
amino ethyl methacrylate/vinyl caprolactam/vinyl pyrrolidone
terpolymers, such as the product sold under the name Gaffix.RTM. VC
713 by International Specialty Products; the vinyl
pyrrolidone/methacrylamidopropyl dimethylamine copolymer, marketed
under the name Styleze.RTM. CC-10 by International Specialty
Products; the vinyl pyrrolidone/quaternized dimethyl amino propyl
methacrylamide copolymers such as the product sold under the name
Gafquat.RTM. HS-100 by International Specialty Products; and the
vinyl pyrrolidone/dimethylaminopropyl
methacrylamide/C.sub.9-C.sub.24 alkyldimethylaminopropyl
methacrylic acid quaternized terpolymers described in U.S. Pat. No.
6,207,778 and marketed under the name Styleze.RTM. W-20 by
International Specialty Products.
[0092] derivatives of cellulose ethers containing quaternary
ammonium groups, such as hydroxy ethyl cellulose quaternary
ammonium that has reacted with an epoxide substituted by a
trimethyl ammonium group.
[0093] derivatives of cationic cellulose such as cellulose
copolymers or derivatives of cellulose grafted with a hydrosoluble
quaternary ammonium monomer, as described in U.S. Pat. No.
4,131,576, such as the hydroxy alkyl cellulose, and the
hydroxymethyl-, hydroxyethyl- or hydroxypropyl-cellulose grafted
with a salt of methacryloyl ethyl trimethyl ammonium,
methacrylamidopropyl trimethyl ammonium, or dimethyl diallyl
ammonium.
[0094] cationic polysaccharides such as described in U.S. Pat. Nos.
3,589,578 and 4,031,307, guar gums containing cationic trialkyl
ammonium groups and guar gums modified by a salt, e.g., chloride of
2,3-epoxy propyl trimethyl ammonium.
[0095] polymers composed of piperazinyl units and alkylene or
hydroxy alkylene divalent radicals with straight or branched
chains, possibly interrupted by atoms of oxygen, sulfur, nitrogen,
or by aromatic or heterocyclic cycles, as well as the products of
the oxidation and/or quaternization of such polymers.
[0096] water-soluble polyamino amides prepared by polycondensation
of an acid compound with a polyamine. These polyamino amides may be
reticulated.
[0097] derivatives of polyamino amides resulting from the
condensation of polyalkylene polyamines with polycarboxylic acids
followed by alkylation by bi-functional agents.
[0098] polymers obtained by reaction of a polyalkylene polyamine
containing two primary amine groups and at least one secondary
amine group with a dioxycarboxylic acid chosen from among
diglycolic acid and saturated dicarboxylic aliphatic acids having 3
to 8 atoms of carbon. Such polymers are described in U.S. Pat. Nos.
3,227,615 and 2,961,347.
[0099] the cyclopolymers of alkyl dialyl amine or dialkyl diallyl
ammonium such as the homopolymer of dimethyl diallyl ammonium
chloride and copolymers of diallyl dimethyl ammonium chloride and
acrylamide.
[0100] quaternary diammonium polymers such as hexadimethrine
chloride. Polymers of this type are described particularly in U.S.
Pat. Nos. 2,273,780, 2,375,853, 2,388,614, 2,454,547, 3,206,462,
2,261,002, 2,271,378, 3,874,870, 4,001,432, 3,929,990, 3,966,904,
4,005,193, 4,025,617, 4,025,627, 4,025,653, 4,026,945, and
4,027,020.
[0101] quaternary polyammonium polymers, including, for example,
Mirapol.RTM. A 15, Mirapol.RTM. AD1, Mirapol.RTM. AZ1, and
Mirapol.RTM. 175 products sold by Miranol.
[0102] the quaternary polymers of vinyl pyrrolidone and vinyl
imidazole such as the products sold under the names Luviquat.RTM.
FC 905, FC 550, and FC 370 by BASF.
[0103] quaternary polyamines.
[0104] reticulated polymers known in the art.
[0105] Other cationic polymers that may be used within the context
of the invention are cationic proteins or hydrolyzed cationic
proteins, polyalkyleneimines such as polyethyleneimines, polymers
containing vinyl pyridine or vinyl pyridinium units, condensates of
polyamines and epichlorhydrins, quaternary polyurethanes, and
derivatives of chitin. In one aspect, the cationic polymers may be
derivatives of quaternary cellulose ethers, the homopolymers and
copolymers of dimethyl diallyl ammonium chloride, quaternary
polymers of vinyl pyrrolidone and vinyl imidazole, and mixtures
thereof.
[0106] The conditioning agent can be any silicone known by those
skilled in the art to be useful as a conditioning agent. The
silicones suitable for use according to the invention include
polyorganosiloxanes that are insoluble in the composition. The
silicones may be present in the form of oils, waxes, polymers, or
gums. They may be volatile or non-volatile. The silicones can be
selected from polyalkyl siloxanes, polyaryl siloxanes, polyalkyl
aryl siloxanes, silicone gums and polymers, and polyorgano
siloxanes modified by organofunctional groups, and mixtures
thereof. Suitable polyalkyl siloxanes include polydimethyl
siloxanes with terminal trimethyl silyl groups or terminal dimethyl
silanol groups (dimethiconol) and polyalkyl (C.sub.1-C.sub.20)
siloxanes. Suitable polyalkyl aryl siloxanes include polydimethyl
methyl phenyl siloxanes and polydimethyl diphenyl siloxanes, linear
or branched. The silicone gums suitable for use herein include
polydiorganosiloxanes including those having a number-average
molecular weight between 200,000 and 1,000,000, used alone or mixed
with a solvent. Examples include polymethyl siloxane, polydimethyl
siloxane/methyl vinyl siloxane gums, polydimethyl siloxane/diphenyl
siloxane, polydimethyl siloxane/phenyl methyl siloxane and
polydimethyl siloxane/diphenyl siloxane/methyl vinyl siloxane.
Suitable silicone polymers include silicones with a
dimethyl/trimethyl siloxane structure and polymers of the trimethyl
siloxysilicate type. The organo-modified silicones suitable for use
in the invention include silicones such as those previously defined
and containing one or more organofunctional groups attached by
means of a hydrocarbon radical and grafted siliconated polymers. In
one embodiment the silicones are amino functional silicones. The
silicones may be used in the form of emulsions, nano-emulsions, or
micro-emulsions.
[0107] The conditioning agent can be a protein or hydrolyzed
cationic or non-cationic protein. Examples of these compounds
include hydrolyzed collagens having triethyl ammonium groups,
hydrolyzed collagens having trimethyl ammonium and trimethyl
stearyl ammonium chloride groups, hydrolyzed animal proteins having
trimethyl benzyl ammonium groups (benzyltrimonium hydrolyzed animal
protein), hydrolyzed proteins having groups of quaternary ammonium
on the polypeptide chain, including at least one C.sub.1-C.sub.18
alkyl. Hydrolyzed proteins include Croquat.TM. L, in which the
quaternary ammonium groups include a C.sub.12 alkyl group,
Croquat.TM. M, in which the quaternary ammonium groups include
C.sub.10-C.sub.18 alkyl groups, Croquat.TM. S in which the
quaternary ammonium groups include a C.sub.18 alkyl group and
Crotein Q in which the quaternary ammonium groups include at least
one C.sub.1-C.sub.18 alkyl group. These products are sold by Croda.
The conditioning agent can comprise quaternized vegetable proteins
such as wheat, corn, or soy proteins such as cocodimonium
hydrolyzed wheat protein, laurdimonium hydrolyzed wheat protein and
steardimonium hydrolyzed wheat protein.
[0108] The conditioning agent can be a ceramide type of compound
such as a ceramide, a glycoceramide, a pseudoceramide, or a
neoceramide. These compounds can be natural or synthetic. Compounds
of the ceramide type are, for example, described in patents pending
DE4424530, DE4424533, DE4402929, DE4420736, WO95/23807, WO94/07844,
EP-A-0646572, WO95/16665, FR-2 673 179, EP-A-0227994, WO 94/07844,
WO 94/24097, and WO 94/10131. Ceramide type compounds useful herein
include 2-N-linoleoyl amino-octadecane-1,3-diol, 2-N-oleoyl
amino-octadecane-1,3-diol, 2-N-palmitoyl amino-octadecane-1,3-diol,
2-N-stearoyl amino-octadecane-1,3-diol, 2-N-behenoyl
amino-octadecane-1,3-diol,
2-N-[2-hydroxy-palmitoyl]-amino-octadecane-1,3-diol, 2-N-stearoyl
amino-octadecane-1,3,4-triol, N-stearoyl phytosphingosine,
2-N-palmitoyl amino-hexadecane-1,3-diol, bis-(N-hydroxy ethyl
N-cetyl) malonamide, N(2-hydroxy ethyl)-N-(3-cetoxyl-2-hydroxy
propyl) amide of cetylic acid, N-docosanoyl N-methyl-D-glucamine
and mixtures of such compounds.
[0109] The conditioning agent can be a cationic surfactant such as
a salt of a primary, secondary, or tertiary fatty amine, optionally
polyoxyalkylenated, a quaternary ammonium salt, a derivative of
imidazoline, or an amine oxide. Suitable examples include mono-,
di-, or tri-alkyl quaternary ammonium compounds with a counter-ion
such as a chloride, methosulfate, tosylate, etc. including, but not
limited to, cetrimonium chloride, dicetyldimonium chloride,
behentrimonium methosulfate, and the like. The presence of a
quaternary ammonium compound in conjunction with the polymer
described above reduces static and enhances combing of hair in the
dry state. The polymer also enhances the deposition of the
quaternary ammonium compound onto the hair substrate thus enhancing
the conditioning effect of hair.
[0110] The conditioning agent can be any fatty amine known to be
useful as a conditioning agent; e.g. dodecyl, cetyl or stearyl
amines, such as stearamidopropyl dimethylamine. The conditioning
agent can be a fatty acid or derivatives thereof known to be useful
as conditioning agents. Suitable fatty acids include myristic acid,
palmitic acid, stearic acid, behenic acid, oleic acid, linoleic
acid, and isostearic acid. The derivatives of fatty acids include
carboxylic ester acids including mono-, di-, tri- and
tetra-carboxylic acids.
[0111] The conditioning agent can be a fluorinated or
perfluorinated oil. Fluorinated oils include perfluoropolyethers
described in EP-A-486135 and the fluorohydrocarbon compounds
described in WO 93/11103. The fluoridated oils may also be
fluorocarbons such as fluoramines, e.g., perfluorotributylamine,
fluoridated hydrocarbons, such as perfluorodecahydronaphthalene,
fluoroesters, and fluoroethers. Of course, mixtures of two or more
conditioning agents can be used.
[0112] The conditioning agent or agents can be present in an amount
from about 0.001% to about 20%, particularly from about 0.01% to
about 10%, and even more particularly from about 0.1% to about 3%
by weight based on the total weight of the final composition. The
personal care/cosmetic compositions of the invention can contain
one or more protecting agents in combination with the
above-described polymer to prevent or limit the degrading effects
of natural physical and/or chemical assaults on the keratinous
materials.
[0113] The protecting agent can be chosen from hydrosoluble,
liposoluble and water-insoluble UV filters, antiradical agents,
antioxidants, vitamins and pro-vitamins. The above-described
cationic polymer enhances the deposition of these materials onto
the hair or skin substrate enhancing protection of hair to UV
damage. Organic UV filters (systems that filter out UV rays) can be
chosen from among hydrosoluble or liposoluble filters, whether
siliconated or nonsiliconated, and mineral oxide particles, the
surface of which may be treated. Hydrosoluble organic UV filters
may be chosen from para-amino benzoic acid and its salts,
anthranilic acid and its salts, salicylic acid and its salts,
hydroxy cinnamic acid and its salts, sulfonic derivatives of
benzothiazoles, benzimidizoles, benzoxazoles and their salts,
sulfonic derivatives of benzophenone and their salts, sulfonic
derivatives of benzylidene camphor and their salts, derivatives of
benzylidene camphor substituted by a quaternary amine and their
salts, derivatives of phthalydene-camphosulfonic acids and their
salts, sulfonic derivatives of benzotriazole, and mixtures thereof.
Hydrophilic polymers, which have light-protective qualities against
UV rays, can be used. These include polymers containing benzylidene
camphor and/or benzotriazole groups.
[0114] Suitable liposoluble organic UV filters include derivatives
of para-aminobenzoic acid, such as the esters or amides of
para-aminobenzoic acid; derivatives of salicylic acid; derivatives
of benzophenone; derivatives of dibenzoyl methane; derivatives of
diphenyl acrylates; derivatives of benzofurans; UV filter polymers
containing one or more silico-organic residues; esters of cinnamic
acid; derivatives of camphor; derivatives of trianilino-s-triazine;
the ethylic ester urocanic acid; benzotriazoles; derivatives of
hydroxy phenyl triazine; bis-resorcinol-dialkyl amino triazine; and
mixtures thereof. The liposoluble (or lipophilic) organic UV filter
can be chosen from octyl salicylate; 4-tert-butyl-4'-methoxy
dibenzoyl methane; octocrylene; 4-methoxy cinnamate; 2-ethylhexyl
[2-ethylhexyl 4-methoxycinnamate]; and
2-(2H-benzotriazol-2-yl)-4-methyl-6-[2-methyl-3-[1,3,3,3-tetramethyl-1-[(-
trimethyl silyl)oxy] disiloxanyl]propynyl] phenol. Other UV filters
that may be useful are derivatives of benzophenones such as
2-hydroxy-4-methoxy benzophenone-5-sulfonic acid,
2-hydroxy-4-methoxy benzophenone, derivatives of benzalmalonates
such as poly dimethyl/methyl (3(4-(2,2-bis-ethoxy carbonyl
vinyl)-phenoxy)-propenyl) siloxane, derivatives of benzylidene
camphor such as b-b'camphosulfonic [1-4 divinylbenzene] acid and
derivatives of benzimidazole such as
2-phenyl-benzimidazol-5-sulfonic acid. Water-insoluble UV filters
include various mineral oxides. The mineral oxides may be selected
from among titanium oxides, zinc oxides, and cerium oxides. The
mineral oxides can be used in the form of ultrafine nanoparticles.
For example, the UV filters can include Escalol.RTM. HP-610
(dimethylpabamido propyl laurdimonium tosylate and propylene glycol
stearate) or Crodasorb HP (polyquaternium 59).
[0115] The antioxidants or antiradical agents can be selected from
phenols such as BHA (tert-butyl-4-hydroxy anisole), BHT
(2,6-di-tert-butyl-p-cresol), TBHQ (tert-butyl hydroquinone),
polyphenols such as proanthocyanodic oligomers, flavonoids,
hindered amines such as tetra amino piperidine, erythorbic acid,
polyamines such as spermine, cysteine, glutathione, superoxide
dismutase, and lactoferrin.
[0116] The vitamins can be selected from ascorbic acid (vitamin C),
vitamin E, vitamin E acetate, vitamin E phosphate, B vitamins such
as B3 and B5, vitamin PP, vitamin A, and derivatives thereof. The
provitamins can be selected from panthenol and retinol.
[0117] The protecting agent can be present in an amount from about
0.001% to about 20% by weight, particularly from about 0.01% to
about 10% by weight, and more particularly from 0.1% to about 5% by
weight of the total weight of the final composition.
[0118] The composition of the invention can contain a fixing agent
in combination with the above-described polymer. The fixing agent
can be an anionic polymer chosen from polymers containing
carboxylic units derived from unsaturated carboxylic mono- or
polyacids of the formula:
##STR00014##
[0119] in which n is a whole number from 0 to 10, A.sub.1 denotes a
methylene group, optionally bonded to the carbon atom of the
unsaturated group or to a neighboring methylene group when n is
greater than 1 by means of a heteroatom like oxygen or sulfur,
R.sub.7 denotes a hydrogen atom, a phenyl or benzyl group, R.sub.8
denotes a hydrogen atom, a lower alkyl or carboxyl group, R.sub.9
denotes a hydrogen atom, a lower alkyl group, a --CH.sub.2--COOH,
phenyl or benzyl group and polymers containing units derived from
sulfonic acid like vinylsulfonic, styrenesulfonic,
acrylamidoalkylsulfonic units.
[0120] The fixing agent can be an amphoteric polymer chosen from
the polymer containing recurring units derived from:
[0121] at least one monomer chosen from acrylamides or
methacrylamides substituted on the nitrogen with an alkyl
radical,
[0122] at least one acid copolymer containing one or more reactive
carboxyl groups, and
[0123] at least one basic comonomer, such as esters with primary,
secondary, tertiary, and quaternary amino substituents of acrylic
and methacrylic acids and the product of quaternization of
dimethylaminoethyl methacrylate with dimethyl or diethyl
sulfate.
[0124] The fixing agent can be a nonionic polymer chosen from
polyalkyloxazolines; vinyl acetate homopolymers; vinyl acetate and
acrylic ester copolymers; vinyl acetate and ethylene copolymers;
vinyl acetate and maleic ester copolymers; polyethylene and maleic
anhydride copolymers; homopolymers of alkyl acrylates; homopolymers
of alkyl methacrylates; copolymers of acrylic esters; copolymers of
alkyl acrylates and alkyl methacrylates; copolymers of
acrylonitrile and a nonionic monomer chosen from among butadiene
and alkyl (meth)acrylates; copolymers of alkyl acrylate and
urethane; and polyamides. The fixing agent can be a functionalized
or unfunctionalized, silicone or non-silicone polyurethane. The
fixing polymer can be a polymer of the grafted silicone type
containing a polysiloxane portion and a portion consisting of a
nonsilicone organic chain, with one of the two portions forming the
main chain of the polymer, and with the other being grafted onto
the main chain.
[0125] The fixing agent can be present in the composition in a
relative weight concentration between about 0.1% to about 10%, for
example, from about 0.5% to about 5%.
[0126] The personal care/cosmetic composition of the invention can
contain an oxidizing agent in combination with the above-described
polymer. The oxidizing agent can be chosen from the group of
hydrogen peroxide, urea peroxide, alkali metal bromates,
ferricyanides, persalts, and redox enzymes, optionally with their
respective donor or cofactor. For example, the oxidizing agent can
be hydrogen peroxide. The oxidizing agent can be a solution of
oxygenated water whose titer varies from 1 to 40 volumes.
[0127] The personal care/cosmetic composition of the invention can
contain at least one reducing agent in combination with the
above-described polymer in amounts from about 0.01% to about 30%,
particularly from about 0.05% to about 20% of the total weight of
the composition. The reducing agents can be selected from thiols,
like cysteine, thioglycolic acid, thiolactic acid, their salts and
esters, cysteamine, and its salts or sulfites. In the case of
compositions intended for bleaching, ascorbic acid, its salts and
its esters, erythorbic acid, its salts and its esters, and
sulfinates, like sodium hydroxymethanesulfinate can be used.
[0128] The personal care/cosmetic composition of the invention can
contain a dye in combination with the above-described polymer. The
dye can be selected from the group consisting of neutral acid or
cationic nitrobenzene dyes, neutral acid or cationic azo dyes,
quinone dyes, neutral, acid or cationic anthraquinone dyes, azine
dyes, triarylmethane dyes, indoamine dyes and natural dyes. The dye
or dyes can be present in a concentration from about 0.001% to
about 20%, and particularly from about 0.005% to about 10% based on
the total weight of the composition.
[0129] The personal care/cosmetic composition of the invention can
contain at least one amphoteric polymer or a cationic polymer in
combination with the above-described polymer. Suitable cationic
polymers include a poly(quaternary ammonium) consisting of
recurrent units corresponding to the following formulae (W) and
(U):
##STR00015##
[0130] Suitable amphoteric polymers include a copolymer containing
at least one acrylic acid and a dimethyldiallyammonium salt as a
monomer. The cationic or amphoteric polymer or polymers can be
present in an amount from about 0.01% to about 10%, particularly
from about 0.05% to about 5%, and more particularly from about 0.1%
to about 3% by weight of the total weight of the composition.
[0131] In addition, the personal care/cosmetic compositions can
include at least one surfactant in combination with the
above-described polymer. The surfactant can be present in an amount
from about 0.1% to about 60%, particularly from about 1% to about
40%, and more particularly from about 5% to about 30% by weight
based on the total weight of the composition. The surfactant may be
chosen from among anionic, amphoteric, or non-ionic surfactants, or
mixtures of them known to be useful in personal care/cosmetic
compositions.
[0132] One or more suitable thickeners or viscosity increasing
agents may be included in combination with the above-described
polymer in the personal care/cosmetic compositions of the
invention. Suitable thickeners and/or viscosity increasing agents
include: Acetamide MEA; Acrylamide/Ethalkonium Chloride Acrylate
Copolymer; Acrylamide/Ethyltrimonium Chloride Acrylate/Ethalkonium
Chloride Acrylate Copolymer; Acrylamides Copolymer;
Acrylamide/Sodium Acrylate Copolymer; Acrylamide/Sodium
Acryloyldimethyltaurate Copolymer; Acrylates/Acetoacetoxyethyl
Methacrylate Copolymer; Acrylates/Beheneth-25 Methacrylate
Copolymer; Acrylates/C10-30 Alkyl Acrylate Crosspolymer;
Acrylates/Ceteth-20 Itaconate Copolymer; Acrylates/Ceteth-20
Methacrylate Copolymer; Acrylates/Laureth-25 Methacrylate
Copolymer; Acrylates/Palmeth-25 Acrylate Copolymer;
Acrylates/Palmeth-25 Itaconate Copolymer; Acrylates/Steareth-50
Acrylate Copolymer; Acrylates/Steareth-20 Itaconate Copolymer;
Acrylates/Steareth-20 Methacrylate Copolymer; Acrylates/Stearyl
Methacrylate Copolymer; AcrylatesNinyl Isodecanoate Crosspolymer;
Acrylic Acid/Acrylonitrogens Copolymer; Adipic Acid/Methyl DEA
Crosspolymer; Agar; Agarose; Alcaligenes Polysaccharides; Algin;
Alginic Acid; Almondamide DEA; Almondamidopropyl Betaine;
Aluminum/Magnesium Hydroxide Stearate; Ammonium
Acrylates/Acrylonitrogens Copolymer; Ammonium Acrylates Copolymer;
Ammonium Acryloyldimethyltaurate/Vinyl Formamide Copolymer;
Ammonium AcryloyldimethyltaurateNP Copolymer; Ammonium Alginate,
Ammonium Chloride; Ammonium Polyacryloyldimethyl Taurate; Ammonium
Sulfate; Amylopectin; Apricotamide DEA; Apricotamidopropyl Betaine;
Arachidyl Alcohol; Arachidyl Glycol; Arachis Hypogaea (Peanut)
Flour; Ascorbyl Methylsilanol Pectinate; Astragalus Gummifer Gum;
Attapulgite; Avena Sativa (Oat) Kernel Flour; Avocadamide DEA;
Avocadamidopropyl Betaine, Azelamide MEA; Babassuamide DEA;
Babassuamide MEA; Babassuamidopropyl Betaine; Behenamide DEA;
Behenamide MEA, Behenamidopropyl Betaine; Behenyl Betaine;
Bentonite; Butoxy Chitosan, Caesalpinia Spinosa Gum; Calcium
Alginate; Calcium Carboxymethyl Cellulose; Calcium Carrageenan;
Calcium Chloride; Calcium Potassium Carbomer; Calcium Starch
Octenylsuccinate; C20-40 Alkyl Stearate; Canolamidopropyl Betaine;
Capramide DEA; Capryl/Capramidopropyl Betaine; Carbomer;
Carboxybutyl Chitosan; Carboxymethyl Cellulose Acetate Butyrate;
Carboxymethyl Chitin; Carboxymethyl Chitosan; Carboxymethyl
Dextran; Carboxymethyl Hydroxyethylcellulose; Carboxymethyl
Hydroxypropyl Guar; Carnitine; Cellulose Acetate Propionate
Carboxylate; Cellulose Gum; Ceratonia Siliqua Gum; Cetearyl
Alcohol; Cetyl Alcohol; Cetyl Babassuate; Cetyl Betaine; Cetyl
Glycol; Cetyl Hydroxyethylcellulose; Chimyl Alcohol;
Cholesterol/HDI/Pullulan Copolymer; Cholesteryl Hexyl Dicarbamate
Pullulan; Citrus Aurantium Dulcis (Orange) Peel Extract; Cocamide
DEA; Cocamide MEA; Cocamide MIPA; Cocamidoethyl Betaine;
Cocamidopropyl Betaine; Cocamidopropyl Hydroxysultaine;
Coco-Betaine; Coco-Hydroxysultaine; Coconut Alcohol;
Coco/Oleamidopropyl Betaine; Coco-Sultaine; Cocoyl Sarcosinamide
DEA; Cornamide/Cocamide DEA; Cornamide DEA; Croscarmellose;
Crosslinked Bacillus/Glucose/Sodium Glutamate Ferment; Cyamopsis
Tetragonoloba (Guar) Gum; Decyl Alcohol; Decyl Betaine;
Dehydroxanthan Gum; Dextrin; Dibenzylidene Sorbitol;
Diethanolaminooleamide DEA; Diglycol/CHDM/Isophthalates/SIP
Copolymer; Dihydroabietyl Behenate; Dihydrogenated Tallow
Benzylmonium Hectorite; Dihydroxyaluminum Aminoacetate;
Dimethicone/PEG-10 Crosspolymer; Dimethicone/PEG-15 Crosspolymer;
Dimethicone Propyl PG-Betaine; Dimethylacrylamide/Acrylic
Acid/Polystyrene Ethyl Methacrylate Copolymer;
Dimethylacrylamide/Sodium Acryloyldimethyltaurate Crosspolymer;
Disteareth-100 IPDI; DMAPA Acrylates/Acrylic Acid/Acrylonitrogens
Copolymer; Erucamidopropyl Hydroxysultaine; Ethylene/Sodium
Acrylate Copolymer; Gelatin; Gellan Gum; Glyceryl Alginate; Glycine
Soja (Soybean) Flour; Guar Hydroxypropyltrimonium Chloride;
Hectorite; Hyaluronic Acid; Hydrated Silica; Hydrogenated Potato
Starch; Hydrogenated Tallow; Hydrogenated Tallowamide DEA;
Hydrogenated Tallow Betaine; Hydroxybutyl Methylcellulose;
Hydroxyethyl Acrylate/Sodium Acryloyldimethyl Taurate Copolymer;
Hydroxyethylcellulose; Hydroxyethyl Chitosan; Hydroxyethyl
Ethylcellulose; Hydroxyethyl Stearamide-MIPA;
Hydroxylauryl/Hydroxymyristyl Betaine; Hydroxypropylcellulose;
Hydroxypropyl Chitosan; Hydroxypropyl Ethylenediamine Carbomer;
Hydroxypropyl Guar; Hydroxypropyl Methylcellulose; Hydroxypropyl
Methylcellulose Stearoxy Ether; Hydroxypropyl Starch; Hydroxypropyl
Starch Phosphate; Hydroxypropyl Xanthan Gum; Hydroxystearamide MEA;
Isobutylene/Sodium Maleate Copolymer; Isostearamide DEA;
Isostearamide MEA; Isostearamide MIPA; Isostearamidopropyl Betaine;
Lactamide MEA; Lanolinamide DEA; Lauramide DEA; Lauramide MEA;
Lauramide MIPA; Lauramide/Myristamide DEA; Lauramidopropyl Betaine;
Lauramidopropyl Hydroxysultaine; Laurimino Bispropanediol; Lauryl
Alcohol; Lauryl Betaine; Lauryl Hydroxysultaine; Lauryl/Myristyl
Glycol Hydroxypropyl Ether; Lauryl Sultaine; Lecithinamide DEA;
Linoleamide DEA; Linoleamide MEA; Linoleamide MIPA; Lithium
Magnesium Silicate; Lithium Magnesium Sodium Silicate; Macrocystis
Pyrifera (Kelp); Magnesium Alginate;
Magnesium/Aluminum/Hydroxide/Carbonate; Magnesium Aluminum
Silicate; Magnesium Silicate; Magnesium Trisilicate; Methoxy
PEG-22/Dodecyl Glycol Copolymer; Methylcellulose; Methyl
Ethylcellulose; Methyl Hydroxyethylcellulose; Microcrystalline
Cellulose; Milkamidopropyl Betaine; Minkamide DEA; Minkamidopropyl
Betaine; MIPA-Myristate; Montmorillonite; Moroccan Lava Clay;
Myristamide DEA; Myristamide MEA; Myristamide MIPA;
Myristamidopropyl Betaine; Myristamidopropyl Hydroxysultaine;
Myristyl Alcohol; Myristyl Betaine; Natto Gum; Nonoxynyl
Hydroxyethylcellulose; Oatamide MEA; Oatamidopropyl Betaine;
Octacosanyl Glycol Isostearate; Octadecene/MA Copolymer; Oleamide
DEA; Oleamide MEA; Oleamide MIPA; Oleamidopropyl Betaine;
Oleamidopropyl Hydroxysultaine; Oleyl Betaine; Olivamide DEA;
Olivamidopropyl Betaine; Oliveamide MEA; Palmamide DEA; Palmamide
MEA; Palmamide MIPA; Palmamidopropyl Betaine; Palmitamide DEA;
Palmitamide MEA; Palmitamidopropyl Betaine; Palm Kernel Alcohol;
Palm Kernelamide DEA; Palm Kernelamide MEA; Palm Kernelamide MIPA;
Palm Kernelamidopropyl Betaine; Peanutamide MEA; Peanutamide MIPA;
Pectin; PEG-800; PEG-Crosspolymer; PEG-150/Decyl Alcohol/SMDI
Copolymer; PEG-175 Diisostearate; PEG-190 Distearate; PEG-15
Glyceryl Tristearate; PEG-140 Glyceryl Tristearate; PEG-240/HDI
Copolymer Bis-Decyltetradeceth-20 Ether; PEG-100/IPDI Copolymer;
PEG-180/Laureth-50/TMMG Copolymer; PEG-10/Lauryl Dimethicone
Crosspolymer; PEG-15/Lauryl Dimethicone Crosspolymer; PEG-2M;
PEG-5M; PEG-7M; PEG-9M; PEG-14M; PEG-20M; PEG-23M; PEG-25M;
PEG-45M; PEG-65M; PEG-90M; PEG-115M; PEG-160M; PEG-180M; PEG-120
Methyl Glucose Trioleate; PEG-180/Octoxynol-40/TMMG Copolymer;
PEG-150 Pentaerythrityl Tetrastearate; PEG-4 Rapeseedamide;
PEG-150/Stearyl Alcohol/SMDI Copolymer; Phaseolus Angularis Seed
Powder; Polianthes Tuberosa Extract; Polyacrylate-3; Polyacrylic
Acid; Polycyclopentadiene; Polyether-1; Polyethylene/Isopropyl
Maleate/MA Copolyol; Polyglyceryl-3 Disiloxane Dimethicone;
Polyglyceryl-3 Polydimethylsiloxyethyl Dimethicone; Polymethacrylic
Acid; Polyquaternium-52; Polyvinyl Alcohol; Potassium Alginate;
Potassium Aluminum Polyacrylate; Potassium Carbomer; Potassium
Carrageenan; Potassium Chloride; Potassium Palmate; Potassium
Polyacrylate; Potassium Sulfate; Potato Starch Modified; PPG-2
Cocamide; PPG-1 Hydroxyethyl Caprylamide; PPG-2 Hydroxyethyl
Cocamide; PPG-2 Hydroxyethyl Coco/Isostearamide; PPG-3 Hydroxyethyl
Soyamide; PPG-14 Laureth-60 Hexyl Dicarbamate; PPG-14 Laureth-60
Isophoryl Dicarbamate; PPG-14 Palmeth-60 Hexyl Dicarbamate;
Propylene Glycol Alginate; PVP/Decene Copolymer; PVP
Montmorillonite; Pyrus Cydonia Seed; Pyrus Malus (Apple) Fiber;
Rhizobian Gum; Ricebranamide DEA; Ricinoleamide DEA; Ricinoleamide
MEA; Ricinoleamide MIPA; Ricinoleamidopropyl Betaine; Ricinoleic
Acid/Adipic Acid/AEEA Copolymer; Rosa Multiflora Flower Wax;
Sclerotium Gum; Sesamide DEA; Sesamidopropyl Betaine; Sodium
Acrylate/Acryloyldimethyl Taurate Copolymer; Sodium
Acrylates/Acrolein Copolymer; Sodium Acrylates/Acrylonitrogens
Copolymer; Sodium Acrylates Copolymer; Sodium Acrylates
Crosspolymer; Sodium Acrylate/Sodium Acrylamidomethylpropane
Sulfonate Copolymer; Sodium AcrylatesNinyl Isodecanoate
Crosspolymer; Sodium Acrylate/Vinyl Alcohol Copolymer; Sodium
Carbomer; Sodium Carboxymethyl Chitin; Sodium Carboxymethyl
Dextran; Sodium Carboxymethyl Beta-Glucan; Sodium Carboxymethyl
Starch; Sodium Carrageenan; Sodium Cellulose Sulfate; Sodium
Chloride; Sodium Cyclodextrin Sulfate; Sodium Hydroxypropyl Starch
Phosphate; Sodium Isooctylene/MA Copolymer; Sodium Magnesium
Fluorosilicate; Sodium Oleate; Sodium Palmitate; Sodium Palm
Kernelate; Sodium Polyacrylate; Sodium Polyacrylate Starch; Sodium
Polyacryloyldimethyl Taurate; Sodium Polygamma-Glutamate; Sodium
Polymethacrylate; Sodium Polystyrene Sulfonate; Sodium
Silicoaluminate; Sodium Starch Octenylsuccinate; Sodium Stearate;
Sodium Stearoxy PG-Hydroxyethylcellulose Sulfonate; Sodium
Styrene/Acrylates Copolymer; Sodium Sulfate; Sodium Tallowate;
Sodium Tauride Acrylates/Acrylic Acid/Acrylonitrogens Copolymer;
Sodium Tocopheryl Phosphate; Solanum Tuberosum (Potato) Starch;
Soyamide DEA; Soyamidopropyl Betaine; Starch/Acrylates/Acrylamide
Copolymer; Starch Hydroxypropyltrimonium Chloride; Stearamide AMP;
Stearamide DEA; Stearamide DEA-Distearate; Stearamide
DIBA-Stearate; Stearamide MEA; Stearamide MEA-Stearate; Stearamide
MIPA; Stearamidopropyl Betaine; Steareth-60 Cetyl Ether;
Steareth-100/PEG-136/HDI Copolymer; Stearyl Alcohol; Stearyl
Betaine; Sterculia Urens Gum; Synthetic Fluorphlogopite; Tallamide
DEA; Tallow Alcohol; Tallowamide DEA; Tallowamide MEA;
Tallowamidopropyl Betaine; Tallowamidopropyl Hydroxysultaine;
Tallowamine Oxide; Tallow Betaine; Tallow Dihydroxyethyl Betaine;
Tamarindus Indica Seed Gum; Tapioca Starch; TEA-Alginate;
TEA-Carbomer; TEA-Hydrochloride; Trideceth-2 Carboxamide MEA;
Tridecyl Alcohol; Triethylene Glycol Dibenzoate; Trimethyl Pentanol
Hydroxyethyl Ether; Triticum Vulgare (Wheat) Germ Powder; Triticum
Vulgare (Wheat) Kernel Flour; Triticum Vulgare (Wheat) Starch;
Tromethamine Acrylates/Acrylonitrogens Copolymer; Tromethamine
Magnesium Aluminum Silicate; Undecyl Alcohol; Undecylenamide DEA;
Undecylenamide MEA; Undecylenamidopropyl Betaine; Welan Gum; Wheat
Germamide DEA; Wheat Germamidopropyl Betaine; Xanthan Gum; Yeast
Beta-Glucan; Yeast Polysaccharides and Zea Mays (Corn) Starch.
[0133] In one such embodiment, the thickeners or viscosity
increasing agents include carbomers, Aculyn.TM. and Stabileze.RTM.,
e.g., crosslinked acrylic acid, crosslinked poly(methylvinyl
ether/maleic anhydride) copolymer, acrylamides, carboxymethyl
cellulose, and the like.
[0134] The personal care/cosmetic compositions may be used to wash
and treat keratinous material such as hair, skin, eyelashes,
eyebrows, fingernails, lips, and hairy skin.
[0135] The personal care/cosmetic compositions can be detergent
compositions such as shampoos, bath gels, and bubble baths. In this
mode, the compositions will comprise a generally aqueous washing
base. The surfactant or surfactants that form the washing base may
be chosen alone or in blends, from known anionic, amphoteric, or
non-ionic surfactants. The quantity and quality of the washing base
must be sufficient to impart a satisfactory foaming and/or
detergent value to the final composition. The washing base can be
from about 4% to about 50% by weight, particularly from about 6% to
about 35% by weight, and even more particularly from about 8% to
about 25% by weight of the total weight of the final
composition.
[0136] The pH of the composition applied to the keratinous material
is generally between 2 and 12. In one embodiment, the pH is from
about 3 to about 8, and may be adjusted to the desired value by
means of acidifying or alkalinizing agents that are well known in
the state of the art. Thus, the composition of the invention can
contain at least one alkalizing or acidifying agent in amounts from
about 0.01% to about 30% based on the total weight of the
composition.
[0137] The alkalizing agent can be chosen from ammonia, alkali
carbonates, alkanolamines, like mono-, di- and triethanolamines, as
well as their derivatives, hydroxyalkylamines and ethoxylated
and/or propoxylated ethylenediamines, sodium or potassium
hydroxides and compounds of the following formula:
##STR00016##
[0138] in which R is a propylene residue optionally substituted
with an hydroxyl group or a C.sub.1-C.sub.4 alkyl radical;
R.sub.38, R.sub.39, R.sub.40 and R.sub.41, identical or different,
represent a hydrogen atom, a C.sub.1-C.sub.4 alkyl radical or
C.sub.1-C.sub.4 hydroxyalkyl radical.
[0139] The acidifying agent can be chosen from mineral or organic
acids, like hydrochloric acid, orthophosphoric acid, carboxylic
acids like tartaric acid, citric acid, or lactic acid, or sulfonic
acids, and the like.
[0140] The personal care/cosmetic compositions of the invention may
include a physiological and cosmetically acceptable medium. Such
medium may consist exclusively of water, a cosmetically acceptable
solvent, or a blend of water and a cosmetically acceptable solvent,
such as a lower alcohol composed of C.sub.1 to C.sub.4, such as
ethanol, isopropanol, t-butanol, n-butanol, alkylene glycols such
as propylene glycol, and glycol ethers. Alternatively, the personal
care/cosmetic compositions can be anhydrous.
[0141] Generally, personal care/cosmetic compositions can be
prepared by simple mixing procedures well known in the art. The
invention provides a method for treating keratinous material
including the skin or hair, by applying to skin or keratinous
materials a personal care/cosmetic composition as described above,
and then eventually rinsing it with water. Accordingly, the method
makes it possible to maintain the hairstyle, treatment, care,
washing, or make-up removal of the skin, the hair, and any other
keratinous material. The personal care/cosmetic compositions may
also take the form of after-shampoo compositions, to be rinsed off
or not, for permanents, straightening, waving, dyeing, or
bleaching, or the form of rinse compositions to be applied before
or after dyeing, bleaching, permanents, straightening, relaxing,
waving or even between the two stages of a permanent or
straightening process. The personal care/cosmetic compositions may
also take the form of skin-washing compositions, and particularly
in the form of solutions or gels for the bath or shower, or of
make-up removal products. The personal care/cosmetic compositions
may also be in the form of aqueous or hydro-alcoholic solutions for
skin and/or hair care. The personal care/cosmetic compositions
described herein are useful in personal care/cosmetic products,
including, but not limited to, gels, lotions, glazes, glues,
mousses, sprays, fixatives, shampoos, conditioners, 2-in-1
shampoos, temporary hair dyes, semi-permanent hair dyes, permanent
hair dyes, straighteners, permanent waves, relaxers, creams,
putties, waxes, pomades, moisturizers, mascaras, lip balms and foam
enhancers.
[0142] The modified polymers can be prepared according to the
examples set out below. The examples are presented for purposes of
demonstrating, but not limiting, the preparation of the compounds
and compositions of this invention.
EXAMPLES
[0143] The following non-limiting examples are provided to
illustrate a few of the methods for preparing novel containing an
acetoacetate moiety and functionalized polymers. The examples are
presented for purposes of demonstrating, but not limiting, the
preparation of the compounds and compositions of this
invention.
Example 1
##STR00017##
[0145] Feed 1 was prepared with 37.62 g of phenoxyethyl acrylate
(PEA), 37.62 g of methyl ethyl ketone (MEK), 19.18 g of maleic
anhydride (MAN), and 41.91 g of acetoacetoxyethyl methacrylate
(AAEM, AcAc). 180.58 g of MEK were placed into a reaction flask and
the reaction flask was purged with nitrogen. The reaction flask
containing MEK was heated to reflux, .about.78.degree. C. In a
separate reaction flask, a mixture of Triganox 25C 75 (15.0 g) and
MEK (15 g) was prepared. This reaction flask was labeled "Triganox
Solution". When the MEK reaction flask reached reflux temperature,
Feed 1 was added drop-wise over a period of about 180 minutes.
After 15 minutes of monomer feed, 3 g of the Triganox Solution was
added into the reaction flask and the drop-wise addition of Feed 1
was continued over a period of about 165 minutes. After 30 minutes
into the monomers being feed into the reaction flask, 3.0 g of the
Triganox solution was added. After 45, 60, 75, 90, 105, 120, and
150 minutes, 3.0 g Triganox solution was added into the reaction
flask. At the completion of the monomer feeds, the remainder of the
Triganox solution was added to the reaction flask. The reaction
flask was heated at reflux for an additional 180 minutes. During
the additions, additional MEK was added to replace any that
volatilized. The reaction flask was cooled; this was the end of
"day one". On "day two", the contents in the reaction flask were
heated to reflux and charged with 2.0 g Triganox 25C 75 and
maintained at reflux for 2 hours. An additional 2.0 g of Triganox
25C 75 was added at reflux for 5 hours and then the reaction
mixture was cooled.
TABLE-US-00001 Monomer Mass (grams) Moles PEA 37.62 0.196 MAN 19.18
0.196 AAEM 41.91 0.196
Example 2
##STR00018##
[0147] Using the procedure set out in Example 1, the compound
illustrated above was prepared, using Ebecryl IBOA (IBOA,
(1S,4S)-1,7,7-trimethyl-6-bicyclo[2.2.1]heptanyl]prop-2-enoate) and
allyl acetoacetate (prop-2-enyl 3-oxobutanoate).
TABLE-US-00002 Monomer Mass (grams) Moles IBOA 42.06 0.202 MAN 19.8
0.202 Allyl acetoacetate 28.71 0.202
Example 3
##STR00019##
[0149] Using the procedure set out in Example 1, the compound
illustrated above was prepared.
TABLE-US-00003 Monomer Mass (grams) Moles PEA 8.66 0.045 AAEM 86.92
0.406
Example 4
##STR00020##
[0151] Using the procedure set out in Example 1, the compound
illustrated above was prepared, using lauryl methacrylate (LM,
2-propenoic acid, 2-methyl-, dodecyl ester).
TABLE-US-00004 Monomer Mass (grams) Moles LM 61.6 0.24 PEA 46.5
0.24 AAEM 11.5 0.05
Example 5
##STR00021##
[0153] Using the procedure set out in Example 1, the compound
illustrated above was prepared.
TABLE-US-00005 Monomer Mass (grams) Moles IBOA 75 0.36 AAEM 8.6
0.04
Example 6
##STR00022##
[0155] Using the procedure set out in Example 1, the compound
illustrated above was prepared, using ODA (octyl/decyl
acrylate).
TABLE-US-00006 Monomer Mass (grams) Moles IBOA 29.16 0.14 ODA 28.42
0.14 AAEM 25.71 0.12
Example 7
##STR00023##
[0157] Using the procedure set out in Example 1, the compound
illustrated above was prepared, using ODA (octyl/decyl
acrylate).
TABLE-US-00007 Monomer Mass (grams) Moles PEA 48.2 0.251 ODA 51.0
0.251 AAEM 11.9 0.06
[0158] While a number of embodiments of this invention have been
represented, it was apparent that the basic construction can be
altered to provide other embodiments that utilize the invention
without departing from the spirit and scope of the invention. All
such modifications and variations are intended to be included
within the scope of the invention as defined in the appended claims
rather than the specific embodiments that have been presented by
way of example.
* * * * *