U.S. patent application number 15/264916 was filed with the patent office on 2017-01-19 for packaging.
This patent application is currently assigned to INFIANA GERMANY GMBH & CO. KG. The applicant listed for this patent is INFIANA GERMANY GMBH & CO. KG. Invention is credited to Felix GRIMM, Werner SCHMIDT, Ingrid SEBALD.
Application Number | 20170015478 15/264916 |
Document ID | / |
Family ID | 52737059 |
Filed Date | 2017-01-19 |
United States Patent
Application |
20170015478 |
Kind Code |
A1 |
SEBALD; Ingrid ; et
al. |
January 19, 2017 |
PACKAGING
Abstract
Wrapper-type packaging composed of a flexible plastics sheet
material in the form of a sack or bag having a front wall and a
rear wall, which are located opposite one another and are sealed by
a side sealing seam to form a flexible sack-like or bag-like tube,
of which the opening is covered by a closure flap which is formed
by a projection of the rear wall and is folded onto the front wall
at least as far as the opening and is closed by longitudinal
sealing and, possibly, transverse sealing or adhesive bonding, the
opening having an opening aid, wherein the flexible plastics sheet
material is oriented at least uniaxially and optionally is embossed
and has a tear-propagation resistance in the machine direction
which differs by at least 30% from the tear propagation resistance
in the direction transverse to the machine direction.
Inventors: |
SEBALD; Ingrid; (Lauf an der
Pegnitz, DE) ; SCHMIDT; Werner; (Forchheim, DE)
; GRIMM; Felix; (Erlangen, DE) |
|
Applicant: |
Name |
City |
State |
Country |
Type |
INFIANA GERMANY GMBH & CO. KG |
Forchheim |
|
DE |
|
|
Assignee: |
INFIANA GERMANY GMBH & CO.
KG
Forchheim
DE
|
Family ID: |
52737059 |
Appl. No.: |
15/264916 |
Filed: |
September 14, 2016 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
|
|
PCT/EP2015/000612 |
Mar 19, 2015 |
|
|
|
15264916 |
|
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Current U.S.
Class: |
1/1 |
Current CPC
Class: |
B32B 2307/514 20130101;
B32B 2307/7246 20130101; B65D 65/00 20130101; B29C 48/18 20190201;
B32B 27/08 20130101; B32B 2255/10 20130101; B32B 2555/00 20130101;
B32B 1/08 20130101; B32B 38/06 20130101; B32B 7/06 20130101; B32B
37/04 20130101; B29L 2031/7128 20130101; B32B 7/12 20130101; B32B
2255/26 20130101; B32B 2307/7248 20130101; B32B 2250/242 20130101;
B32B 2307/544 20130101; B32B 2307/748 20130101; B29C 48/0018
20190201; B29C 48/002 20190201; B32B 2307/7244 20130101; B29K
2101/12 20130101; B32B 2037/148 20130101; B65D 65/14 20130101; B32B
3/30 20130101; B32B 27/32 20130101; B32B 2307/516 20130101; B32B
37/12 20130101; B32B 2307/7242 20130101; B65D 33/007 20130101; B32B
2307/5825 20130101; B32B 2553/00 20130101; B32B 2439/46 20130101;
B32B 1/00 20130101; B32B 2250/24 20130101 |
International
Class: |
B65D 65/14 20060101
B65D065/14; B32B 27/08 20060101 B32B027/08; B65D 33/00 20060101
B65D033/00; B29C 47/06 20060101 B29C047/06; B29C 47/00 20060101
B29C047/00; B32B 1/08 20060101 B32B001/08; B32B 27/32 20060101
B32B027/32 |
Foreign Application Data
Date |
Code |
Application Number |
Mar 21, 2014 |
DE |
10 2014 004 042.9 |
Mar 21, 2014 |
DE |
10 2014 010 691.8 |
Jul 29, 2014 |
DE |
10 2014 010 987.9 |
Claims
1: A wrapper-type packaging composed of a flexible polymeric film
in the form of a sack or bag, having a front wall and a rear wall,
which are opposite to one another and are sealed in each case by a
side sealing seam to form a sack like or bag like tube, of which
the opening is covered by a closure flap which is formed by a
projection of the rear wall and is folded onto the front wall, and
also closed by respectively longitudinal side sealing and
optionally transverse sealing or adhesive bonding, and optionally
having an opening aid, wherein the flexible polymeric film is
comprised of to an extent of at least 50 wt % of polyolefins, has
through monoaxially orientation a tear propagation resistance in
machine direction which differs by at least 30% in relation to the
tear propagation resistance in the direction transverse to the
machine direction, measured according to DIN 53356-trouser leg, and
the opening aid marks the direction of relatively low tear
propagation resistance for opening the packaging without tearing
one of the sealed seams.
2: A wrapper-type packaging as claimed in claim 1, wherein the at
least longitudinally side sealed closure flap projects over the
opening of the sack or bag and does not fully cover the front wall
of the packaging and the packaging optionally has a marking in the
opening direction in the form of a notch or of a barcode.
3: A wrapper-type packaging as claimed in claim 1, wherein the
closure flap does not fully cover the front wall of the packaging,
and the lower edge region of the closure flap is transversely
sealed with the longitudinal, unsealed edge region of the opening
of the sack or bag in the form of a fin seam, and the fin seam has
a notching, extending optionally perpendicular thereto, for marking
the direction of opening.
4: A wrapper-type packaging as claimed in claim 1, wherein the
polymeric film has a draw ratio of at least 1:2 in machine
direction.
5: A wrapper-type packaging as claimed in claim 1, wherein the
polymeric film is comprised to an extent of at least 70 wt % of
polyolefins.
6: A wrapper-type packaging as claimed in claim 1, wherein the
polymeric film contains as polyolefins polyethylenes (PE),
optionally LDPE, MDPE, LLDPE, HDPE, polypropylenes (PP) or a
mixture of at least two of said polyethylenes.
7: A wrapper-type packaging as claimed in claim 1, wherein the
polymeric film has at least one layer, optionally at least two
layers based on a mixture of polyolefins, at least one barrier
layer, optionally at least a barrier layer against gasses, against
fats and oils, against migration of low molecular mass organic
compounds and/or against moisture.
8: A wrapper-type packaging as claimed in claim 7, wherein at least
one layer of the polymeric film is based on heat-sealable
polyolefins.
9: A wrapper-type packaging as claimed in claim 7, wherein the
barrier layer of the polymeric film is based on ethylene/vinyl
alcohol copolymers, polyvinyl alcohols, polyamides, copolyamides,
polyesters and/or a polyether/polyamide block copolymer.
10: A wrapper-type packaging as claimed in claim 9, wherein the
barrier layer is based on an aliphatic polyamide or (partially)
aromatic copolyamide, and optionally based on a copolyamide of
.epsilon.-caprolactam, isophoronediamine and isophthalic acid
units.
11: A wrapper-type packaging as claimed in claim 1, wherein the
polymeric film has at least a five-layer sequence of (a) a layer
(a) based on a mixture of polyethylenes, and optionally further
fillers and auxiliaries, (b) an adhesion promoter layer (b), (c) a
barrier layer (c) based on a polyamide, or copolyamide, (d) a
further adhesion promoter layer (d), and (e) a layer (e) based on a
mixture of polyethylenes.
12: A wrapper-type packaging as claimed in claim 1, wherein the
polymeric film has a polymeric film with release effect.
13: A wrapper-type packaging as claimed in claim 12, wherein the
release effect of the polymeric film is based on an at least
partial embossment on at least the inside surface of the polymeric
film facing the packaged product.
14: A wrapper-type packaging as claimed in claim 13, wherein the
embossment of the polymeric film has an embossment elevation of 5
.mu.m, measured according to DIN 53 370 2006.
15: A wrapper-type packaging as claimed in claim 13, wherein the
embossed polymeric film has a shrinkage of at least 50% lower than
the shrinkage of a corresponding unembossed, polymeric film.
16: A wrapper-type packaging as claimed in claim 12, wherein the
release effect of the polymeric film is based on a release coating
on the inside surface of the polymeric film facing a packaged
product.
17: A wrapper-type packaging as claimed in claim 13, wherein the
polymeric film has neither an embossment nor a release coating in
the regions of the longitudinal side sealing and of the transverse
sealing respectively.
18: A wrapper-type packaging as claimed in claim 1, wherein the
polymeric film has a total thickness of .ltoreq.30 .mu.m.
19: A wrapper-type packaging as claimed in claim 1 as individual
packaging for an article packaged therein.
20: A wrapper-type packaging as claimed in claim 1 as individual
packaging for a self-adhesive article of any kind packaged
therein.
21: A wrapper-type packaging as claimed in claim 1 as individual
packaging for a self-adhesive hygiene article.
Description
[0001] This application is a Continuation of International Patent
Application No. PCT/EP2015/000612, filed Mar. 19, 2015, which
claims foreign priority benefit under 35 U.S.C. .sctn.119 of German
Patent Applications 10 2014 004 042.9 filed Mar. 21, 2014, 10 2014
010 691.8 filed Mar. 21, 2014, and 10 2014 010 987.9 filed Jul. 29,
2014 the contents of all of which are incorporated herein by
reference.
[0002] A wrapper-type packaging made of a flexible polymeric film
in the form of a sack or bag and consisting of a front wall and a
rear wall, which are located opposite one another and are sealed in
each case by a side sealing seam to form a sack-like or bag-like
tube, of which the opening is covered by a closure flap which is
formed by a projection of the rear wall and is folded onto the
front wall at least as far as, and preferably beyond, the opening
and is closed by in each case longitudinal side sealing and,
optionally, transverse sealing or adhesive bonding, and preferably
having an opening aid, wherein the flexible polymeric film is
oriented at least monoaxially and is optionally embossed and has a
tear propagation resistance in machine direction which differs by
at least 30% in relation to the tear propagation resistance in the
direction transverse to the machine direction and the wrapper-type
packaging is suitable in particular for optionally self-adhesive
articles, preferably optionally self-adhesive hygiene articles,
which are preferably provided for single use.
BACKGROUND OF THE INVENTION
[0003] It is known that wrapper-type packagings made from flexible
polymeric films are suitable for packaging a very wide variety of
articles, especially articles for single use. In particular in the
hygiene sector an increasing tendency to package hygiene articles
for single use individually, in order to achieve the maximum
protection and the maximum hygiene for the sensitive use of such
products. A disadvantage of the known wrapper-type packaging for
folded hygiene products, such as sanitary towels or panty liners,
for example, has been that sealing during production or during
closing of a wrapper-type packaging made of an optionally sealable,
flexible polymeric film, if possible, has been avoided. The reason
for this is that such packaging even only partly closed in this way
can only be opened with difficulty and the simple removal of the
packaged product can risk a contamination. In order to facilitate
the opening and the removal of the packaged product, particularly
of an individually packaged hygiene product, in the production the
front wall and the rear wall for the formation of a sack-like or
bag-like tube of a wrapper-type packaging are preferably not sealed
longitudinally, but instead are joined longitudinally by a
particular type, namely by crimping, in each case together with the
closure flap folded over the front wall, whereby said closure flap
is closed transversely. Therefore, there is no need to tear any
seal seam for opening, which would be more difficult for the end
user and, furthermore, would cause not only a fairly unpleasant
noise, but also the risk of an unintended tearing of the
packaging.
[0004] Therefore, it was an object of the present invention to
provide a wrapper-type packaging which ensures secure packaging by
avoiding any access to the packaged product prior to the intended
use, but however is easy to open.
SUMMARY OF THE INVENTION
[0005] This object is solved by the provision of a wrapper-type
packaging made of a flexible polymeric film in the form of a sack
or bag and consisting of a front wall and a rear wall, which are
located opposite one another and are sealed in each case by a side
sealing seam to form a sack-like or bag-like tube, of which the
opening is covered by a closure flap which is formed by a
projection of the rear wall and is folded onto the front wall and
is closed by in each case longitudinal side sealing and,
optionally, transverse sealing or adhesive bonding, and preferably
having an opening aid, characterized in that the flexible polymeric
film is oriented at least monoaxially and is optionally embossed
and has a tear propagation resistance in machine direction which
differs by at least 30% in relation to the tear propagation
resistance in the direction transverse to the machine
direction.
DETAILED DESCRIPTION
[0006] Preferably the closure flap can be closed completely by
longitudinal sealings at both sides and a transverse sealing or by
the transverse adhesive bonding of the closure flap, against the
front wall of the packaging, since by means of an opening aid, i.e.
a marking in the form, for example, of a notch, the tearing
direction for the opening of the packaging can be provided without
any tearing of one of the seal seams. This marked tearing direction
marks the direction of relatively low tearing propagation
resistance of the polymeric film used. In case the inventive
packaging is closed completely by means of the sealed closure flap
the end user has a guaranty for retained hygiene requirements and
that no unallowed access to the packaged product took place before
its end use.
[0007] The sealable, flexible polymeric film used for producing the
inventive wrapper-type packaging may be a single-layer or
multilayer film. Preferably it is a multilayer polymeric film, more
preferably an at least 3-layer film, very preferably an at least
5-layer film.
[0008] The polymeric film used according to the invention has at
least a monoaxial orientation in the machine direction. This
orientation is usually achieved by a difference in speed between
its extrusion speed and takeoff speed during the film production.
The ratio of the speed (i.e., the draw ratio) is preferably at
least 1:30, preferably at least 1:50.
[0009] Optionally the polymeric film used according to the
invention can additionally also have at least a monoaxial
orientation in machine direction of at least 1:2, preferably of at
least 1:3, more preferably from 1:3 to 1:5. It can also be
biaxially oriented, i.e., can also have orientation transverse to
the machine direction of 1:2 to 1:3.5. In the case of a biaxial
direction and transversely to the machine direction, the draw ratio
in the two directions should be different, whereby preferably the
orientation in machine direction is higher than transversely to the
machine direction.
[0010] The multilayer polymeric film used according to the
invention preferably comprises at least a three-layer sequence of
[0011] (a) an optionally sealable layer (a) as surface layer,
[0012] (b) optionally an adhesion promoter layer (b), [0013] (c) a
layer (c), optionally with barrier effect, [0014] (d) optionally an
adhesion promoter layer (d), and [0015] (e) an optionally sealable
layer (e) as surface layer, with at least one of the surface layers
preferably being sealable.
[0016] The layers of the polymeric film used according to the
invention have preferably been prepared from thermoplastic polymers
selected from the group comprising polyolefins, polyamides,
polyesters, biodegradable polymers, copolymers of at least two
monomers of the mentioned polymers and mixtures of at least two of
the mentioned polymers.
[0017] The polymeric film used according to the invention
preferably consists of at least 50 wt %, more preferably of at
least 70 wt % of polyolefins, preferably of C.sub.2-C.sub.8 olefin
polymers, more preferably of C.sub.2-C.sub.3 olefin polymers, their
mixtures or copolymers, olefin copolymers or their mixtures.
[0018] The layers (a) and (e) and also, optionally, the layer (c)
of the multilayer film used according the invention are based
preferably in each case, identically or differently, on polyolefins
and olefin copolymers of .alpha.,.beta.-unsaturated olefins having
2-8, preferably 2-3, carbon atoms, which are preferably selected
from the group comprising polyethylenes (PE)--especially
polyethylenes of low density between 0.86 and 0.93 g/cm.sup.3
(LDPE), linear polyethylenes of low density between 0.86 and 0.94
g/cm.sup.3 (LLDPE) containing as comonomer one or more
.alpha.-olefins having more than 2 carbon atoms, polyethylenes of
medium density between 0.926 and 0.94 g/cm.sup.3 (MDPE),
polyethylenes of high density between 0.94 and 0.97 g/cm.sup.3
(HDPE), copolymers of ethylene with an .alpha.-olefin having 4 or
more carbon atoms (mPE); polypropylenes (PP), polyisobutylenes
(PI), polybutylenes (PB) and ethylene-propylene copolymers with
preferably 1-10 mol % of ethylene (EPC). With particular preference
a mixture of LDPE and MDPE or a mixture of LDPE, MDPE and PP can be
used in which case the fraction of MDPE and optionally PP in the
mixture can amount to 25 wt % to 85 wt %, based on the total weight
of the respective layer.
[0019] The layers (a) and (e) can also consist of
olefin/vinylcarboxylic acid copolymers or olefin/vinyl ester
copolymers such as ethylene-acrylic acid copolymers (EAA), their
esters such as (EMA), ethylene-methacrylic acid copolymers (EMAA),
their esters such as (EMMA), ethylene-vinyl acetate copolymers with
preferably 60-99 mol % of ethylene (EVA), or of mixtures of in each
case at least two of the before mentioned types of polymers.
[0020] In a further embodiment, at least the layer (e) as surface
layer may be based on at least one polyester or at least one
copolyester which is preferably selected from the group comprising
polyethylene terephthalates (PET, c-PET, a-PET) and copolymers such
as coPET, PBT and CoPBT). "PET" refers to polyethylene
terephthalates prepared by polycondensation of ethylene glycol and
terephthalic acid. Furthermore, amorphous PET (a-PET) and
crystalline PET (c-PET) can be used. "CoPET" refers to copolyesters
which in addition to ethylene glycol and terephthalic acid can
additionally contain further monomers, such as branched or aromatic
diols, for example. "CoPBT" refers to polybutylene terephthalates.
The polyester or copolyester used preferably has an intrinsic
viscosity of preferably 0.1 to 2.0 dl/g, more preferably of 0.3 to
1.5 dl/g, more particularly of 0.6 to 1.0 dl/g, the methods for
determining the intrinsic viscosity being known to the skilled
person. A comprehensive description of suitable PET and PBT is
disclosed in Kunststoffhandbuch volume 3/1--technische
Thermoplaste: Polycarbonate, Polyacetale, Polyester, Cellulosester;
Carl Hanser Verlag, 1992, the content of which is hereby referenced
in full.
[0021] In a further embodiment, at least the layer (e) may be based
on at least one biodegradable polymer. As suitable biodegradable,
thermoplastic polymers it is possible to use at least one
biodegradable polymer selected from the group comprising lactic
acid homopolymers and copolymers, preferably polylactides, more
preferably of DL-lactide, of L-lactide and of D-lactide,
polyhydroxyalkanoates, cellulose, cellulose derivatives,
thermoplastic starch, polyesters, preferably polycaprolactones,
polyethers, at least partly hydrolyzed polyvinyl acetates,
ethylene-vinyl alcohol copolymers and copolymers of at least two
monomers of the mentioned polymers.
[0022] In the selection of the polymer components of the layer (a)
and (e), respectively, it should preferably be ensured that the
layer (a) can be bonded to the layer (e) by heat sealing, at least
with respect to the two longitudinal side seal seams of the
wrapper-type packaging.
[0023] According to a preferred embodiment, the multilayer
polymeric film used according to the invention has at least one
layer (c) having a barrier effect. The skilled person is aware of
suitable polymers with which it is possible to achieve a barrier
effect, more particularly against loss of gas or loss of aroma,
against migration of low molecular mass components and/or against
impairment of flavor and/or odor, or against moisture and/or
against oils and fats.
[0024] Accordingly the layer (c) with a barrier effect against
gases, preferably against O.sub.2, (H.sub.2O--) vapor and/or
gaseous flavors, against migration of low molecular mass organic
compounds and/or against impairment of taste and/or odor, is based
on at least one thermoplastic polymer selected from the group
comprising ethylene-vinyl alcohol copolymers, polyvinyl alcohols,
polyvinylidene chlorides, vinylidene chloride copolymers,
polyether-polyamide block copolymers and mixtures of the polymers
with ethylene-vinyl acetate copolymers. Preferred vinylidene
chloride copolymers have a vinylidene chloride fraction of 80% or
more. Ethylene-vinyl alcohol copolymers are particularly
preferred.
[0025] According to another preferred embodiment, the layer (c) has
a barrier effect against moisture and/or oils and fats which is
based preferably on a thermoplastic, aliphatic or (partially)
aromatic polyamide or copolyamide or mixtures thereof.
[0026] As polyamides (PA) or copolyamides (coPA) it is possible,
for producing at least one layer (c), to use preferably aliphatic
or (partially) aromatic polyamides, preferably having a melting
point in the range from 160 to 240.degree. C., more preferably from
170 to 220.degree. C. Preference is given to aliphatic polyamides,
for which at least one polyamide or copolyamide is selected from
the group comprising PA 6, PA 12, PA 6,6, PA 6,12, PA 6/6,6, PA
6,6/6; or partially aromatic polyamides, such as PA6T and PA6I,
which may preferably also comprise isophorone diamine units. A
comprehensive description of polyamides and copolyamides is found
in Kunstoff-Handbuch volume VI, Polyamide, Carl Hanser Verlag
Munich, 1966; and Melvin I. Kohan, Nylon Plastics Handbook, Carl
Hanser Verlag Munich, 1995, the content of which is hereby included
by reference in full.
[0027] As already mentioned, particularly for producing the layer
(c), it is possible to use homopolyamides and/or copolyamides
selected from the group comprising thermoplastic, aliphatic,
partially aromatic and aromatic homopolyamides or copolyamides with
isophorone diamine units. These homopolyamides or copolyamides with
isophorone diamine units can be composed of further aliphatic
and/or cycloaliphatic diamines having 2-10 carbon atoms such as
hexamethylene diamine and/or aromatic diamines having 6-10 carbon
atoms such as p-phenylene diamine, and of aliphatic or aromatic
dicarboxylic acids having 6-14 carbon atoms such as adipic acid,
terephthalic acid or isophthalic acid. Furthermore, copolyamides
with isophorone diamine units can also comprise lactam units having
4-10 carbon atoms such as s-caprolactam, for example. To produce
homopolyamides and/or copolyamides, isophorone diamine can
preferably be used as at least one diamine component that the
homopolyamides and/or copolyamides which are preferably suitable
for producing the layer (c) having units consisting of isophthalic
acid or terephthalic acid and isophorone diamine. Homopolyamides
and/or copolyamides which are particularly preferably used
according to the invention comprise units consisting of
s-caprolactam, isophorone diamine and of an aromatic dicarboxylic
acid, preferably isophthalic acid.
[0028] In one preferred embodiment the fraction of the units of
isophorone diamine and isophthalic acid of the polyamide component
of the layer (c) is at least 1 to 10 wt %, most preferably 2 to 6
wt %, based on the total weight of the polyamide component.
[0029] The thermoplastic polyesters mentioned before useful for the
production of the layer (e) can also be used for producing the
layer (c).
[0030] With the composition of the layer (c) as barrier layer and
with appropriate selection of suitable polymers it is possible to
provide a multilayer polymeric film having also a DIN 53380-3
oxygen permeability which is significantly reduced which amounts up
to 10.00 cm.sup.3/(m.sup.2dbar) at 23.degree. C. and 50% rh.
[0031] The oxygen permeability of the multilayer polymeric film
used according to the invention can be further reduced to at most 8
cm.sup.3/(m.sup.2dbar), preferably at most 7 or 6
cm.sup.3/(m.sup.2dbar), more preferably at most 5, 4 or 3
cm.sup.3/(m.sup.2dbar), even more preferably at most 2, 1 or 0.5
cm.sup.3/(m.sup.2dbar), most preferably at most 0.4, 0.3 or 0.2
cm.sup.3/(m.sup.2dbar), and more particularly at most 0.1, 0.09 or
0.08 cm.sup.3/(m.sup.2dbar) (in each case at 23.degree. C. and 50%
rh).
[0032] With the composition of the layer (c) as barrier layer and
with appropriate selection of suitable polymers it is likewise
possible to reduce the water vapor permeability of the multilayer
polymeric film used according to the invention down to the values
mentioned above for the oxygen permeability, the water vapor
permeability being determined in accordance with DIN ISO 53
122.
[0033] If layer (c) functions as barrier layer (c), it is
preferably connected to the adjacent layers via adhesion promoter
layers (b) and (d).
[0034] Suitable thermoplastic polymers which can be used as
adhesion promoting materials are known to the skilled person. The
adhesion promoter layers (b) and (d), identically or differently,
are preferably based on a preferably modified polyolefin and/or
olefin copolymers, preferably selected from the group comprising
carboxyl group-modified or cyclic anhydride group-modified
polyethylenes, polypropylenes, more particularly maleic anhydride
group-modified polyethylenes, polypropylenes, and ethylene-vinyl
acetate copolymers. Preferred are maleic anhydride-modified PE, PE
modified with COOH groups, carboxyl group-modified copolymers of
ethylene-vinyl acetate, or of ethylene(meth)acrylate or
anhydride-modified ethylene-vinyl acetate copolymers, and a polymer
blend containing at least two of the mentioned polymers. Copolymers
modified with maleic anhydride are particularly preferred.
[0035] In one preferred embodiment the polymeric film employed in
accordance with the invention has at least a five-layer sequence of
[0036] (a) a layer (a) based on a mixture of polyethylenes,
preferably composed of a mixture of MDPE and LDPE or of LLDPE and
LDPE and optionally further fillers and auxiliaries, [0037] (b) an
adhesion promoter layer (b), [0038] (c) a barrier layer (c) based
on a polyamide, preferably aliphatic polyamide, or copolyamide,
preferably a (partially) aromatic copolyamide, [0039] (d) a further
adhesion promoter layer (d), and [0040] (e) a layer (e) based on a
mixture of polyethylenes, preferably composed of a mixture of MDPE
and LDPE or of LLDPE and LDPE.
[0041] In a further particularly preferred embodiment the
multilayer polymeric film used according to the invention comprises
more than one layer (c) and comprises the following layer sequence:
[0042] (a) an optionally heat-sealable, optionally multi-ply layer
(a) preferably of at least one thermoplastic olefin homopolymer or
copolymer or mixtures thereof, which is optionally coated with a
release layer as surface layer, [0043] (b) an adhesion promoter
layer (b), [0044] (c) a layer (c) preferably based on at least one
homopolyamide and/or copolyamide, [0045] (b) optionally a further
adhesion promoter layer (b), [0046] (c) a further layer (c),
preferably based on at least one homopolyamide and/or copolyamide,
or ethylene-vinyl alcohol copolymers, [0047] (d) a further adhesion
promoter layer (d), and [0048] (e) an optionally heat-sealable
surface layer (e) based on at least one thermoplastic olefin
homopolymer or copolymer or mixtures thereof, with at least one
surface layer preferably being heat-sealable.
[0049] The layers (c) are preferably based on homopolymers,
copolymers or mixtures of polymers as described before, more
preferably on copolyamides or ethylene-vinyl alcohol copolymers.
The other layers as well correspond preferably in their composition
to the details given before in relation to these layers and have
the mentioned property profile.
[0050] The layers of the multilayer polymeric film used according
to the invention can in each case contain the same or different
additives selected from the group encompassing antioxidants,
antiblocking agents, antifog agents, antistats, active
antimicrobial ingredients, light stabilizers, UV absorbers, UV
filters, dyes, color pigments, stabilizers, preferably heat
stabilizers, process stabilizers, and UV and/or light stabilizers,
preferably based on at least one sterically hindered amine (HALS),
process assistants, flame retardants, nucleating agents,
crystallizing agents, preferably crystal seed formers, lubricants,
optical brighteners, plasticizers, silanes, spacers, fillers, such
as CaCO3, silicates, peel additives, seal additives, waxes, wetting
agents, surface-active compounds, preferably surfactants, and
dispersants.
[0051] The layers of the polymeric film can contain at least
0.01-30 wt %, preferably at least 0.1-20 wt %, in each case based
on the total weight of an individual layer, of at least one of the
before mentioned additives.
[0052] Advantageously, by the monoaxial orientation of the
polymeric film used according to the invention a tear propagation
resistance in machine direction is obtained which differs by at
least 30%, preferably up to 50%, from the tear propagation
resistance transverse to the machine direction (measured according
to DIN 53356-trouser leg). Thus, an inventive packaging produced
from such a preferably multilayer and monoaxially oriented
polymeric films is easy to open outside any seal seam region and
the optionally present adhesive seam regions, i.e., without the
need of the end user for opening a seal seam or adhesive seam for
this purpose.
[0053] Furthermore, the difference in the tear propagation
resistance can also be increased by a corresponding monoaxial
stretching and thereby the difference in the tear propagation
resistance modified in the desired amount.
[0054] In this context it has been found that, surprisingly,
additionally monoaxially stretching a polymeric film in machine
direction, which is already monoaxially oriented and having an at
least five-layer sequence, comprising a barrier layer, which is
composed preferably of a partially aromatic copolyamide, a film
with a tear propagation resistance in machine direction up to 50%
higher than the tear propagation resistance transverse to the
machine direction is obtained. As a result it is possible not only
to produce the wrapper-type packaging of the invention with far
less reject material, but also to facilitate the tearing of an
inventive packaging by a corresponding marking, as for example by
notching, to identify the tearing direction for the end user.
[0055] The polymeric film used according to the invention can also
be embossed. As a result at least a certain area of the surface
layer (a) has an embossed structure, more preferably the entire
surface of the layer (a), preferably with the exception of the seal
seam regions.
[0056] This embossed structure of such release film used according
to the invention is based preferably on a repeating, regularly or
irregularly arranged pattern. The embossed structure can be a
continuous embossed structure such as a continuous groove
structure, for example, or two or more, preferably repeating,
individual embossed structures, or a regularly repeating but
inherently random embossed structure, in each case corresponding to
the embossing roll employed.
[0057] According to one embodiment, each embossed structure can be
based on a multiplicity of preferably repeating individual embossed
structures. These respective individual embossed structures can be
based preferably on a structure with embossment indentations
(grooves), which have more or less pronounced embossment elevations
such as ridges, for example, by which the embossed height of the
embossed structure is defined. In accordance with the respective
geometry of the elevations of a preferably repeating individual
embossed structure, a plan view may show a multiplicity of
respectively different, preferably repeating, individual embossed
structures such as, for example, preferably serpentine, sawtooth,
hexagonal, diamond-shape, rhomboidal, parallelogrammatical,
honeycomb, circular, dot-shaped, star-shaped, rope-shaped,
reticular, polygonal, preferably triangular, tetragonal, more
preferably rectangular and square, pentagonal, hexagonal,
heptagonal, and octagonal, wire-shaped, ellipsoidal, oval, and
lattice-shape-designed patterns, it also being possible for at
least two patterns to be superimposed on one another. The
embossment elevations may each preferably have a length in
longitudinal direction of up to one centimeter, particular
preference being given to a length of 0.001 mm to 10 mm. The
fraction of the elevations as a proportion of the total length of
the structure with indentations can be preferably 75%, more
preferably from 5% to 60%, and very preferably from 10% to 50%. The
elevations are arranged preferably at uniform or alternating
repeating distances. The elevations of the individual embossed
structures may also preferably have a curvature, i.e., a convex or
concave structure.
[0058] In a further preferred embodiment, the embossed structure
has repeating units of randomly arranged embossment indentations
and embossment elevations. The embossment elevations of the
embossed structure are to amount preferably to .ltoreq.75%, more
preferably 50%, based on the overall embossed area of the polymeric
film of the invention.
[0059] The embossment elevation of the optionally uniform
embossment elevations of the polymeric film used according to the
invention amounts preferably to .gtoreq.5 .mu.m as measured
according to DIN 53370 2006.
[0060] The embossment elevation of the embossed structure of the
polymeric film used according to the invention is determined in
accordance with DIN 53370 2006 by mechanical scanning of the
surface. In this procedure, the embossment elevations are measured
at not less than 10 locations, distributed uniformly in a line over
the web width of the sample, it being necessary to ensure that the
scanning device does not compress the embossed structure of the
polymeric film, and the average of the measurements is formed, from
which the thickness of the corresponding unembossed polymeric is
subtracted.
[0061] In a further preferred embodiment, the polymeric film used
according to the invention has an asymmetric embossed structure,
i.e., an embossed structure which is present consistently
throughout the film and provides both the top face and the bottom
face of the film with an embossment, meaning that these faces are
no longer planar, but the extent of the embossment is different on
the two faces of the film. Below, the top face of the film is
identified as that film side on which the embossing tool acts or
has acted. The bottom face of the film, accordingly, may have a
weaker embossment (negative form).
[0062] The effect achieved by the embossment of the polymeric film
used according to the invention is not only to obtain a release
effect on the part of the polymeric film used according to the
invention but also, surprisingly, to reduce the shrinkage of the
oriented and optionally stretched polymeric film drastically, by
more than 50% in comparison to a corresponding oriented and
optionally stretched, unembossed polymeric film.
[0063] The oriented, optionally stretched and embossed polymeric
film employed in accordance with the invention, moreover, has
excellent tensile strength, good to very good tear characteristics,
and an excellent puncture resistance, which markedly improves the
handling and the opening characteristics of the packaging according
to the invention.
[0064] The multilayer polymeric film used according to the
invention may also have a release coating on a surface layer, to
improve its release effect, said surface layer being that which
comes into contact with the packaged product in the context of the
inventive wrapper-type packaging that is produced from the
film.
[0065] The release coating is based preferably on a cured
polysiloxane coating, with which the polymeric film employed in
accordance with the invention may be furnished even prior to any
occurring orientation or after this additional orientation. The
release coating that generates release effect is present over
substantially the whole area, preferably except for at least one
stripe which extends in machine direction, or over a partial area,
preferably in the form of in-register transverse stripes with all
of the seal seam regions of the packaging of the invention
preferably not being furnished with a release coating.
[0066] The term "polysiloxane" in the sense of the present
invention refers to compounds whose polymer chains are constructed
alternately of silicon atoms and oxygen atoms. A polysiloxane is
based on n repeating siloxane units --[Si(R.sub.2)--O]--, which
each independently of one another are disubstituted by two organic
radicals R, with R preferably being in each case R.sup.1 or
OR.sup.1, and with R.sup.1 in each case being an alkyl radical or
an aryl radical. The cured polysiloxane coating is preferably based
on a repeating dialkylsiloxane unit or on a repeating
alkylarylsiloxane unit. Depending on the number of Si--O bonds
possessed by an individual siloxane unit, based in each case on a
tetravalent silicon atom, these units may be differentiated as
terminal monofunctional siloxanes (M) having one Si--O bond,
difunctional siloxanes (D) having two Si--O bonds, trifunctional
siloxanes (T) having three Si--O bonds, and tetrafunctional
siloxanes (Q) having four Si--O bonds. The polysiloxane coating of
the invention preferably has a crosslinked cyclic or catenated
structure, more preferably a crosslinked catenated structure, which
is linked by (D), (T) and/or (Q) units to form a two- or
three-dimensional network. The number n of the repeating siloxane
units --[Si(R.sub.2)--O]-- in the polysiloxane chain is termed the
degree of polymerization of the polysiloxane.
[0067] The cured polysiloxane coating of the polymeric film
employed in accordance with the invention is based preferably on at
least one cured, i.e., crosslinked, polysiloxane selected from the
group comprising addition-crosslinked, preferably
addition-crosslinked with metal catalysis,
condensation-crosslinked, radically crosslinked and/or cationically
crosslinked polysiloxanes.
[0068] More preferably the polysiloxane coating is based on at
least one cured polysiloxane which has been cured by thermocuring
and/or under the action of UV radiation. The polysiloxane coating
is based preferably on at least one cured polysiloxane selected
from the group comprising polydialkyl siloxanes, preferably
polydimethyl siloxanes and polyalkylaryl siloxanes, preferably
polymethylphenyl siloxanes, which in each case are cured. Thermally
cured polysiloxanes may be obtained by thermal hydrosililation of
polysiloxanes containing silane functions, using a compound having
at least one carbon double bond. If orientation of the film used
according to the invention is carried out, thermocuring, as well as
UV curing, takes place preferably after orientation of the
polymeric film employed in accordance with the invention.
[0069] The polymeric film used according to the invention can be
produced in principle by any known production methods, such as by
extrusion or by coextrusion, for example.
[0070] Here, both individual layers and all the layers of the
polymeric film used according to the invention may be formed by
extrusion, more particularly by blown film extrusion and/or flat
film extrusion (cast extrusion), or preferably coextrusion, more
particularly blown film coextrusion and/or flat film coextrusion
(cast coextrusion), the latter being preferred. Here it should be
ensured that in the case of doping of the layer (a) or of other
layers with additives, these additives are employed by blending,
where appropriate as a masterbatch, with the polymer component or
components of the respective layer for processing. This blending
may take place dry in pellet/powder form or pellet/pellet form. An
alternative possibility is for the additive to be added to the
melted polymer component or components of the respective layer,
preferably by metering in an extruder used for the extrusion of the
layer in question.
[0071] After the coextrusion process, which is known per se, the
melts corresponding to the individual layers of the polymeric film
used according to the invention are coextruded simultaneously and
jointly through a round die or a flat die, the resulting polymeric
film is taken off for orienting and solidification on one or more
rolls, at a rate conforming to the before mentioned removal ratio
of at least 1:30, in such a way that the ratio of removal is
greater than the rate of extrusion and the film oriented in this
way is heat-set.
[0072] Subsequent monoaxial or biaxial stretching may be carried
out sequentially or simultaneously. Sequential stretching is
generally carried out successively, with preference being given to
the successive biaxial stretching, where stretching is performed
first longitudinally (in machine direction) and transversely
(perpendicularly to the machine direction).
[0073] In the case of film production after flat film extrusion
with any subsequent monoaxial or biaxial stretching, the polymer or
the polymer mixture of the individual layers is compressed in an
extruder and fluidized, it being possible for any additives added
to be already present in the polymer or polymer mixture. The melts
are then pressed simultaneously through a flat die (slot die) and
the multilayer film extruded is taken off on one or more take-off
rolls at a temperature of 10 to 100.degree. C., preferably 10 to
50.degree. C., with the rate of removal being necessarily greater
than the rate of extrusion in order to achieve the before mentioned
removal ratio, and it cools and solidifies.
[0074] The multilayer polymeric film used according to the
invention can then optionally oriented either only longitudinally,
or longitudinally and transversely to the extrusion direction,
leading to further orientation of the molecule chains. Longitudinal
orientation is carried out preferably at a temperature of 70 to
130.degree. C., preferably 80 to 110.degree. C., usefully with the
aid of two rolls which run at different speeds in line with the
target draw ratio, and the additional transverse orientation, when
practiced, is carried out preferably at a temperature of 120 to
180.degree. C. by means of a corresponding tenter frame. The
desired transverse orientation ratios can be set at this point.
Orientation is preferably orientation in machine direction in
accordance with the invention.
[0075] Any orientation taking place of the polymeric film used
according to with the invention is followed preferably by its
heat-setting (heat treatment) where the film is held for about 0.1
to 10 s at a temperature of 100 to 160.degree. C. Subsequently,
where appropriate after interim storage, the polymeric film of the
invention may be furnished with any release coating present. It is
also possible for the extruded multilayer stretched polymeric film
used according to the invention to be provided with any release
coating even prior to orientation.
[0076] The flexible multilayer polymeric films used according to
the invention can be transparent, transparently colored, opaque or
non transparent. The film can have a printing on the outer side
facing away from the packaged product.
BRIEF DESCRIPTION OF THE DRAWINGS
[0077] FIG. 1 shows an inventive wrapper-type packing in plan
view.
[0078] FIG. 2 shows a plan view of the wrapper-type packaging of
FIG. 1 in the opened condition.
[0079] FIG. 3 shows a further embodiment of the inventive
wrapper-type packaging in plan view.
[0080] FIG. 4 shows a plan view of the wrapper-type packaging of
FIG. 3 in the opened condition.
[0081] FIG. 5 shows a further embodiment of the inventive
wrapper-type packaging in plan view.
[0082] FIG. 6 shows a plan view of the wrapper-type packaging of
FIG. 5 in the opened condition.
[0083] FIG. 7 shows a further embodiment of the inventive
wrapper-type packaging in accordance with FIG. 1, without
transverse sealing of the closure tab, in plan view.
[0084] FIG. 8 shows a plan view of the wrapper-type packaging of
FIG. 7 in the opened condition.
[0085] FIG. 9 shows a further embodiment of the inventive
wrapper-type packaging in accordance with FIG. 3, without
transverse sealing of the closure tab, in plan view.
[0086] FIG. 10 shows a plan view of the FIG. 9 in the opened
condition.
[0087] FIG. 1 shows an embodiment of the inventive wrapper-type
packaging (1), produced from a single film web of the before
described multilayer film used according to the invention. The
wrapper-type packaging comprises a bag with an opening (7) from
which the packaged product can be removed after opening. The bag is
formed from a front wall (2) and a rear wall (3) by folding the
film along the folding line (6). By means of a closure flap (8)
which is formed by a projection of the rear wall (3) and which is
folded at a distance from the opening (7) of the bag onto the front
wall (2) along the folding line (12), the wrapper-type packaging is
closed completely by means of the closure flap (8) by longitudinal
sealing (9, 10) and transverse sealing (11) of the inner layer of
the closure flap (8) against the outer layer of the front wall (2).
For production-related reasons the transverse seal seam (11) is
placed at a distance from the edge of the packaging flap.
[0088] Instead of the transverse seal seam (11), the closure flap
(8) can also be bonded to the front wall (2) by means of a strip of
an adhesive, which runs transversely on the inside of the closure
flap, in which case the bond strength of the adhesive, should
correspond to the seal strength of a seal seam that is ponding the
parts, which is preferably greater than the tear propagation
resistance of the inventive wrapper-type packaging in the direction
of the marking for the opening of the packaging. Suitable
commercial adhesives suitable are known to the person skilled in
the art. An opening aid (13), shown as a notch, marks the direction
of opening of the inventive packaging, in which the tear
propagation resistance is lower than in the direction extending
transversely thereto.
[0089] FIG. 2 shows a plan view of the inventive wrapper-type
packaging in accordance with FIG. 1, in which a part (14) of the
packaging, which is already torn away from the packaging to a
predominant extent, starting from the notch (13), via the opening
(7) with the packaged product (not shown). Furthermore, on the
front wall (2) of the inventive packaging, the side seal seams (11)
which extend longitudinally, and the seal seams placed transversely
for the closing of the closure flap (8), can be seen to be intact,
and so the packaged product can be removed without effort and
destruction of the rest of the packaging.
[0090] FIG. 3 shows a further embodiment of the inventive
wrapper-type packaging, which differs from the packaging shown in
FIG. 1 in that the marking (13) of the direction of opening is
located on the folding line (12) of the closure flap. This notch
could also be replaced by a barcode (not shown) or could be located
in the edge region of the closure flap (8) beneath the transverse
seal seam (11) and at right angles to the seal seam (11).
[0091] FIG. 4 shows a plan view of the wrapper-type packaging
according to FIG. 3 in the predominantly open condition, and
without the packaged product, which has already been removed.
Again, on the front wall of the wrapper-type packaging, the
transverse seal seam (11) of the closure flap and also the seal
seams extending at the sides longitudinally can be seen to be
intact.
[0092] Shown in FIG. 5 is a further preferred embodiment of the
inventive wrapper-type packaging. According to this packaging, the
closure tab (8) is joined to the front wall (2) directly at the
level of the opening (7) of the bag, with the edge region of the
closure flap being connected to the opening edge region of the
front wall by means of a transverse seal seam, formed as so called
fin seam. This fin seam has a notch (13) for marking the direction
of opening.
[0093] FIG. 6 shows a plan view of the inventive wrapper-type
packaging as per FIG. 5, in the partly opened condition and after
removal of the packaged product; again, the seal seams extending at
the sides longitudinally, and the fin seam extending transversely
can be seen to be intact, apart from the tearing along the
notch.
[0094] FIG. 7 and FIG. 8 correspond to FIG. 1 and FIG. 2, with the
exception that the wrapper-type packaging has no transverse seal
seam for the closing of the closure flap. Since, however, the seams
(9) and (10) extending at the sides longitudinally are seal seams,
and the packaging has a notch as opening aid, the consumer is able
to remove the packaged product without effort and without any need
for side seal seams to be torn open, in order to get to the
packaged product. In spite of the effortless opening of the
wrapper-type packaging according to FIG. 7, this wrapper-type
packaging ensures a better security during transport and storage
than corresponding packaging with less secure side seams for
closure.
[0095] Since FIG. 9 and FIG. 10 correspond to FIG. 3 and FIG. 4,
with the exception of a transverse seal seam for closing the
closure flap, for these embodiments of the invention the same
explanations as mentioned in relation to FIG. 7 and FIG. 8 are of
relevance.
[0096] Based on the difference in tear propagation resistance
between the tear propagation resistance in machine direction and
transverse to the machine direction, the inventive packagings, as
shown in FIGS. 1 to 6 among others, can be opened easily, without
the possibility of an unallowed access to the packaged product
before the intended opening for removing the packaged product and
the therefore partial destruction of the wrapper-type packaging
takes place. In spite of this excellent security against
manipulation of the packaged product, the inventive wrapper-type
packaging is easy to open.
[0097] The inventive wrapper-type packaging can be produced
according to known, conventional techniques; whereby during
production the difference in tear propagation resistance of the
film and the related opening behavior of the packaging produced
therefrom, has to be taken into account.
[0098] The inventive wrapper-type packaging is especially suitable
for the packaging of articles which are intended for single use,
preferably hygiene articles intended for single use, more
particularly sanitary towels, tampons, panty liners or incontinence
articles that are intended for single use.
[0099] Furthermore, the inventive wrapper-type packaging is
suitable as individual packaging for adhesive articles of any kind,
more particularly as individual packaging for self-adhesive
articles intended for single use, more preferably for self-adhesive
hygiene articles intended for single use. Very preferably the
inventive wrapper-type packaging is suitable for the packaging of
self-adhesive panty liners, self-adhesive sanitary towels or
self-adhesive incontinence articles which are intended for single
use and are packaged preferably in the folded shape.
* * * * *