U.S. patent application number 15/189005 was filed with the patent office on 2016-12-29 for consumer goods product comprising lignin oligomer.
The applicant listed for this patent is The Procter & Gamble Company. Invention is credited to Bouchra BENJELLOUN-MLAYAH, Claudia CRESTINI, Heiko LANGE, Anju Deepali MASSEY-BROOKER, Stefano SCIALLA, Mauro VACCARO.
Application Number | 20160374935 15/189005 |
Document ID | / |
Family ID | 53489875 |
Filed Date | 2016-12-29 |
United States Patent
Application |
20160374935 |
Kind Code |
A1 |
MASSEY-BROOKER; Anju Deepali ;
et al. |
December 29, 2016 |
CONSUMER GOODS PRODUCT COMPRISING LIGNIN OLIGOMER
Abstract
The present invention relates to a consumer goods product
comprising a consumer goods product ingredient and a lignin
oligomer, wherein the lignin oligomer: (a) comprises less than 1 wt
% sulphur content; (b) has a number average molecular weight
(M.sub.n) of from 800 Da to 1,800 Da; and (c) has a molar ratio of
aromatic hydroxyl content to aliphatic hydroxyl content in the
range of from 1.2 to 1.9, wherein the consumer goods product
ingredient is an emulsifier, and wherein the lignin oligomer is in
the form of an emulsion, and wherein the consumer goods product is
selected from skin treatment composition, oral care treatment
composition, and detergent composition.
Inventors: |
MASSEY-BROOKER; Anju Deepali;
(Newcastle upon Tyne, GB) ; VACCARO; Mauro;
(Newcastle upon Tyne, GB) ; SCIALLA; Stefano;
(Strombeek-Bever, BE) ; BENJELLOUN-MLAYAH; Bouchra;
(Pompertuzat, FR) ; CRESTINI; Claudia; (Rome,
IT) ; LANGE; Heiko; (Rome, IT) |
|
Applicant: |
Name |
City |
State |
Country |
Type |
The Procter & Gamble Company |
Cincinnati |
OH |
US |
|
|
Family ID: |
53489875 |
Appl. No.: |
15/189005 |
Filed: |
June 22, 2016 |
Current U.S.
Class: |
424/58 |
Current CPC
Class: |
C08L 97/005 20130101;
C11D 3/382 20130101; A61K 8/736 20130101; C09G 1/00 20130101; A61Q
19/02 20130101; A61Q 5/12 20130101; A61K 8/72 20130101; A61Q 19/00
20130101; A61Q 11/00 20130101; A61K 8/06 20130101; C11D 3/0084
20130101; A61K 8/9794 20170801; A61Q 5/02 20130101; A61Q 19/007
20130101; C08H 6/00 20130101 |
International
Class: |
A61K 8/97 20060101
A61K008/97; A61Q 19/00 20060101 A61Q019/00; C11D 3/382 20060101
C11D003/382; A61K 8/06 20060101 A61K008/06; A61Q 19/02 20060101
A61Q019/02; C11D 3/00 20060101 C11D003/00; A61Q 11/00 20060101
A61Q011/00; A61K 8/73 20060101 A61K008/73 |
Foreign Application Data
Date |
Code |
Application Number |
Jun 24, 2015 |
EP |
15173584.2 |
Claims
1. A consumer goods product comprising a consumer goods product
ingredient and a lignin oligomer, wherein the lignin oligomer: (a)
comprises less than about 1 wt % sulphur content; (b) has a number
average molecular weight (M.sub.n) of from about 800 Da to about
1,800 Da; and (c) has a molar ratio of aromatic hydroxyl content to
aliphatic hydroxyl content in the range of from about 1.2 to about
1.9, wherein the consumer goods product ingredient is an
emulsifier, and wherein the lignin oligomer is in the form of an
emulsion, and wherein the consumer goods product is selected from
skin treatment composition, oral care treatment composition, and
detergent composition.
2. A consumer goods product according to claim 1, wherein the
lignin oligomer comprises from about 2.0 mmol/g to about 3.0 mmol/g
aromatic hydroxyl content.
3. A consumer goods product according to claim 1, wherein the
lignin oligomer comprises from about 1.0 mmol/g to about 2.0 mmol/g
aliphatic hydroxyl content.
4. A consumer goods product according to claim 1, wherein the
lignin oligomer has a weight average molecular weight (M.sub.w) in
the range of from about 800 Da to about 5,000 Da.
5. A consumer goods product according to claim 1, wherein the
lignin oligomer has a number average molecular weight (M.sub.n) in
the range of from about 800 Da to about 1,200 Da.
6. A consumer goods product according to claim 1, wherein the
lignin oligomer has a hydrolysable ester content in the range of
from about 0.3 mmol/g to about 0.7 mmol/g.
7. A consumer goods product according to claim 1, wherein the
lignin oligomer is non-cross linked.
8. A consumer goods product according to claim 1, wherein the
lignin oligomer is derived from corn, sugar cane, wheat and any
combination thereof.
9. A consumer goods product according to claim 1, wherein the
consumer goods product comprises an emollient and/or humectant.
10. A consumer goods product according to claim 1, wherein the
consumer goods product comprises chitin and/or chitin
derivatives.
11. A consumer goods product according to claim 1, wherein the
consumer goods product is a skin treatment composition.
12. A consumer goods product according to claim 1, wherein the
consumer goods product, wherein the consumer goods products is an
oral care composition.
13. A consumer goods product according to claim 1, wherein the
consumer goods product, wherein the consumer goods products is a
detergent composition.
Description
FIELD OF THE INVENTION
[0001] The present invention relates to consumer goods products
comprising lignin oligomers.
BACKGROUND OF THE INVENTION
[0002] Lignins provide anti-oxidant benefits and can act as a
surface deposition aid in consumer goods products, such as skin
treatment compositions, hair treatment compositions, oral care
compositions home care compositions and detergent compositions
(especially hand wash detergents). In addition, for home care
applications, lignins can also provide surface modification
benefits which lead to improved shine and water repellence
benefits.
[0003] However, lignins are difficult to incorporate in consumer
goods products due to their poor solubility in water. In addition,
many lignins, such as Kraft lignin, comprise sulphur, which leads
to poor chemical compatibility with other ingredients that may be
present in consumer goods products, such as transition metals.
Sulphur may also cause malodour problems.
[0004] The inventors have found that the above problems can be
overcome by controlling the level of sulphur content, controlling
the number average molecular weight, and controlling the molar
ratio of aromatic hydroxyl moiety to aliphatic hydroxyl
content.
[0005] The inventors have found that specific lignin oligomers can
be incorporated into consumer goods products, and give benefits
such as anti-oxidation, surface affinity and surface modification
benefits without problems such as poor solubility, chemical
compatibility and malodour.
SUMMARY OF THE INVENTION
[0006] The present invention relates to a consumer goods product
comprising a consumer goods product ingredient and a lignin
oligomer, wherein the lignin oligomer:
(a) comprises less than 1 wt % sulphur content; (b) has a number
average molecular weight (M.sub.n) of from 800 Da to 1,800 Da; and
(c) has a molar ratio of aromatic hydroxyl content to aliphatic
hydroxyl content in the range of from 1.2 to 1.9, wherein the
consumer goods product ingredient is an emulsifier, and wherein the
lignin oligomer is in the form of an emulsion, and wherein the
consumer goods product is selected from skin treatment composition,
oral care treatment composition, and detergent composition.
DETAILED DESCRIPTION OF THE INVENTION
[0007] Consumer Goods Product:
[0008] The consumer goods product comprises a consumer goods
product ingredient and a lignin oligomer. The consumer goods
product ingredient and lignin oligomer are described in more detail
below.
[0009] The consumer goods product may comprise an emollient and/or
humectant.
[0010] The consumer goods product comprise an emulsifier, this may
be preferred when the lignin oligomer is in the form of an
emulsion.
[0011] The consumer goods product may be a skin treatment
composition. The consumer goods product may be an oral care
composition.
[0012] The consumer goods product may be a detergent
composition.
[0013] The consumer goods product may comprise chitin and/or chitin
derivatives.
[0014] The consumer goods product may be selected from: hard
surface cleaning sheet and/or wipe; and teeth treatment strip.
[0015] The consumer goods product is typically selected from: skin
cream; skin lotion; shaving preparation gel or foam; handwash
laundry detergent; handwash dishwashing detergent; soap bar; liquid
handwash soap; body wash; and toothpaste.
[0016] Consumer Goods Product Ingredient: The Consumer Goods
Product Comprises an Emulsifier.
[0017] Suitable consumer goods product ingredients may include
emmolient, humectants, and any combination thereof.
[0018] Lignin Oligomer:
[0019] The lignin oligomer: (a) comprises less than 1 wt % sulphur
content; (b) has a number average molecular weight (M.sub.n) of
from 800 Da to 1,800 Da; and (c) has a molar ratio of aromatic
hydroxyl content to aliphatic hydroxyl content in the range of from
1.2 to 1.9.
[0020] Preferably, the lignin oligomer comprises from 2.0 mmol/g to
3.0 mmol/g aromatic hydroxyl content.
[0021] Preferably, the lignin oligomer comprises from 1.0 mmol/g to
2.0 mmol/g aliphatic hydroxyl content.
[0022] Preferably, the lignin oligomer has a weight average
molecular weight (M.sub.w) in the range of from 800 Da to 5,000
Da.
[0023] Preferably, the lignin oligomer has a number average
molecular weight (M.sub.n) in the range of from 800 Da to 1,200
Da.
[0024] Preferably, the lignin oligomer is essentially free of
sulphur.
[0025] Preferably, the lignin oligomer has a hydrolysable ester
content in the range of from 0.3 mmol/g to 0.7 mmol/g.
[0026] Preferably, the lignin oligomer is non-cross linked.
[0027] Preferably, the lignin oligomer is derived from corn, sugar
cane, wheat and any combination thereof.
[0028] Preferably, the lignin oligomer is obtained by an
organosolv-like isolation process for the lignins, using
preferentially wheat straw, corn stover and/or sugar cane bagasse
lignin starting materials.
[0029] Preferably, the ratio of aromatic hydroxyl groups to
aliphatic hydroxyl groups of the lignin oligomer is within the
range of 1.2 to 1.9.
[0030] Preferably, the lignin oligomer has a hydrolysable ester
content in the range of from 0.2 to 0.5 mmol/g. The hydrolysable
ester content preferably comprises acetate and formate functional
groups.
[0031] Method of Measuring Sulphur Content:
[0032] The chemical composition of a lignin sample in terms of its
carbon (C), hydrogen (H), nitrogen (N) and sulphur (S) content can
be determined by elemental analysis in form of a CHNS analysis of
at least three different representative samples of a given batch of
the respective lignin. Typical sample sizes are 2.0 mg of a lignin
sample that was oven-dried at 105.degree. C. until a steady weight
was obtained. The samples are placed in aluminum dishes and
analyzed using a Carlo-Erba NA 1500 analyzer, using helium as
carrier gas. Carbon (C), hydrogen (H), nitrogen (N) and sulphur (S)
were detected in form of carbon dioxide, water, nitrogen, and
sulphur dioxide, which are chromatographically separated to exit
the instrument in the order of nitrogen, carbon dioxide, water, and
sulphur dioxide. Quantification is achieved against calibrations
using typical standard substances used for the calibration of
elemental analysers, such as (bis(5-tert-butyl-2-benzo-oxazol-2-yl)
thiophene, based on the peak areas of the chromatograms obtained
for each lignin sample.
[0033] Method of Measuring M.sub.n and M.sub.w:
[0034] The number average molecular weight, M.sub.n, as well as the
weight average molecular weight, M.sub.w, can be determined using
gel permeation chromatography (GPC). Prior to analysis,
representative lignin samples are acetobrominated as reported in
archival literature (J. Asikkala, T. Tamminen, D. S. Argyropoulos,
J. Agric. Food Chem. 2012, 60, 8968-8973.) to ensure complete
solubilisation in tetrahydrofuran (THF). 5 mg lignin is suspended
in lmL glacial acetic acid/acetyl bromide (9:1 v/v) for 2 h. The
solvent is then removed under reduced pressure, and the residue is
dissolved in HPLC-grade THF and filtered over a 0.45 .mu.m syringe
filter prior to injection into a 20 .mu.L sample loop. Typical
analysis set-ups resemble the following specific example:
GPC-analyses are performed using a Shimadzu instrument consisting
of a controller unit (CBM-20A), a pumping unit (LC 20AT), a degas
ser unit (DGU-20A3), a column oven (CTO-20AC), a diode array
detector (SPD-M20A), and a refractive index detector (RID-10A); the
instrumental set-up is controlled using the Shimadzu LabSolution
software package (Version 5.42 SP3). Three analytical GPC columns
(each 7.5.times.30 mm) are connected in series for analyses:
Agilent PLgel 5 .mu.m 10000 .ANG., followed by Agilent PLgel 5
.mu.m 1000 .ANG. and Agilent PLgel 5 .mu.m 500 .ANG.. HPLC-grade
THF (Chromasolv.RTM., Sigma-Aldrich) is used as eluent (isocratic
at 0.75 mL min-1, at 40.degree. C.). Standard calibration is
performed with polystyrene standards (Sigma Aldrich, MW range
162-5.times.106 g mol-1), and lower calibration limits are
verified/adjusted by the use of synthesized dimeric and trimeric
lignin models. Final analyses of each sample is performed using the
intensities of the UV signal at .lamda.=280 nm employing a
tailor-made MS Excel-based table calculation, in which the number
average molecular weight (M.sub.n) and the weight average molecular
weight (M.sub.w) is calculated based on the measured absorption (in
a.u.) at a given time (min) after corrections for baseline drift
and THF-stemming artifacts.
M.sub.n is calculated according to the formula
M _ n = w i w i M i ##EQU00001##
in which M.sub.n is the number average molecular weight w.sub.i is
obtained via
w i = - V ( log M ) ##EQU00002##
with M being molecular weight hi being the signal intensity of a
given log M measurement point V being the volume of the curve over
a given log M interval d(log M). M.sub.i is a given molecular
weight. The analysis is run in triplicate, and final values are
obtained as the standard average. M.sub.w is calculated according
to the formula
M _ w = w i M i w i ##EQU00003##
in which M.sup.w is the number average molecular weight w.sub.i is
obtained via
w i = - V ( log M ) ##EQU00004##
with M being the molecular weight hi being the signal intensity of
a given log M measurement point V being the volume of the curve
over a given log M interval d(log M). M.sub.i is a given molecular
weight. The analysis is run in triplicate, and final values are
obtained as the standard average.
[0035] Eventually necessary adjustment of M.sub.n and M.sub.w with
respect to the desired applications is achieved by mechanical
breaking of polymeric lignin using a ball mill, by chemically or
enzymatically polymerising oligomeric lignin.
[0036] Method of Measuring Aromatic Hydroxyl and Aliphatic Hydroxyl
Content:
[0037] Typically, a procedure similar to the one originally
published can be used (A. Granata, D. S. Argyropoulos, J. Agric.
Food Chem. 1995, 43, 1538-1544). A solvent mixture of pyridine and
(CDCl3) (1.6:1 v/v) is prepared under anhydrous conditions. The NMR
solvent mixture is stored over molecular sieves (4 .ANG.) under an
argon atmosphere. Cholesterol is used as internal standard at a
concentration of 0.1 mol/L in the aforementioned NMR solvent
mixture. 50 mg of Cr(III) acetyl acetonate are added as relaxation
agent to this standard solution.
[0038] Ca. 30 mg of the lignin are accurately weighed in a
volumetric flask and suspended in 400 .mu.L of the above prepared
solvent solution. One hundred microliters of the internal standard
solution are added, followed by 100 .mu.L of
2-chloro-4,4,5,5-tetramethyl-1,3,2-dioxaphospholane (Cl-TMDP). The
flask is tightly closed, and the mixture is stirred for 120 min at
ambient temperature. 31P NMR spectra are recorded using suitable
equipment, similar or identical to the following example: On a
Bruker 300 MHz NMR spectrometer, the probe temperature is set to
20.degree. C. To eliminate NOE effects, the inverse gated
decoupling technique is used. Typical spectral parameters for
quantitative studies are as follows: 90.degree. pulse width and
sweep width of 6600 Hz. The spectra are accumulated with a delay of
15 s between successive pulses. Line broadening of 4 Hz is applied,
and a drift correction is performed prior to Fourier transform.
Chemical shifts are expressed in parts per million from 85% H3PO4
as an external reference. All chemical shifts reported are relative
to the reaction product of water with Cl-TMDP, which has been
observed to give a sharp signal in pyridine/CDCl3 at 132.2 ppm. To
obtain a good resolution of the spectra, a total of 256 scans are
acquired. The maximum standard deviation of the reported data is
0.02 mmol/g, while the maximum standard error is 0.01 mmol/g. (A.
Granata, D. S. Argyropoulos, J. Agric. Food Chem. 1995, 43,
1538-1544). Quantification on the basis of the signal areas at the
characteristic shift regions (in ppm, as reported in A. Granata, D.
S. Argyropoulos, J. Agric. Food Chem. 1995, 43, 1538-1544) is done
using a tailor-made table calculation in which the abundances,
given in mmol/g, of the different delineable phosphitylated
hydroxyl groups are determined on the basis of the integral
obtained for the signal of the internal standard, that is present
in the analysis sample at a concentration of 0.1 m, creating a
signal at the interval ranging from 144.5 ppm to 145.3 ppm. The
area underneath the peak related to the internal standard is set to
a value of 1.0 during peak integration within the standard
processing of the crude NMR data, allowing for determining
abundances using simple rule-of-proportion mathematics under
consideration of the accurate weight of the sample used for this
analysis. The analysis is run in triplicate, and final values are
obtained as the standard average.
[0039] Method of Measuring Hydrolysable Ester Content:
[0040] The total ester content of the lignin can be determined by
subjecting the lignin to alkaline hydrolysis conditions: Ca. 500 mg
of lignin are dissolved in an excess of 1 M sodium hydroxide
solution and heated to temperatures of above 70-80.degree. C. for
12 h. The lignin is subsequently precipitated by acidifying the
reaction mixture, isolated and freeze-dried.
[0041] Ca. 30 mg of the lignin are accurately weighed in a
volumetric flask and suspended in 400 .mu.L of the above prepared
solvent solution. One hundred microliters of the internal standard
solution are added, followed by 100 .mu.L of
2-chloro-4,4,5,5-tetramethyl-1,3,2-dioxaphospholane (Cl-TMDP). The
flask is tightly closed, and the mixture is stirred for 120 min at
ambient temperature. .sup.31P NMR spectra are recorded using
suitable equipment under the conditions reported above for the
determination of aliphatic and aromatic hydroxyl contents.
Quantification of the acid content is done on the basis of the
signal intensities at the characteristic shift regions (in ppm)
using a tailor-made table calculation referring to the signal of
the internal standard. Abundances are typically given in mmol/g.
The ester content is obtained as the difference in the abundances
of acid groups, aliphatic hydroxyl groups, and aromatic hydroxyl
groups found in untreated vs. the lignin treated with sodium
hydroxide as outlined above. The analysis is run in triplicate, and
final values are obtained as the standard average.
[0042] Emollient:
[0043] Suitable emollients are silicon based emollients.
Silicone-based emollients are organo-silicone based polymers with
repeating siloxane (Si 0) units. Silicone-based emollients of the
present invention are hydrophobic and exist in a wide range of
molecular weights. They include linear, cyclic and crosslinked
varieties. Silicone oils are generally chemically inert and usually
have a high flash point. Due to their low surface tension, silicone
oils are easily spreadable and have high surface activity. Examples
of silicon oil include: Cyclomethicones, Dimethicones,
Phenyl-modified silicones, Alkyl-modified silicones, Silicones
resins, Silica. Other emollients useful in the present invention
can be unsaturated esters or fatty esters. Examples of unsaturated
esters or fatty esters of the present invention include: Caprylic
Capric Triglycerides in combination with Bis-PEG/PPG-1 6/16
PEG/PPG-16/16 Dimethicone and C12-C15 Alkylbenzoate.
[0044] The basic reference of the evaluation of surface tension,
polarity, viscosity and spreadability of emollient can be found
under Dietz, T., Basic properties of cosmetic oils and their
relevance to emulsion preparations. SOFW-Journal, July 1999, pages
1-7.
[0045] Humectant:
[0046] A humectant is a hygroscopic substance used to keep things
moist. Typically, it is often a molecule with several hydrophilic
groups, most often hydroxyl groups; however, amines and carboxyl
groups, sometimes esterified, can be encountered as well (its
affinity to form hydrogen bonds with molecules of water is the
crucial trait). A humectant typically attracts and retains the
moisture in the air nearby via absorption, drawing the water vapour
into and/or beneath the organism/object's surface.
[0047] Suitable humectants include: Propylene glycol, hexylene
glycol, and butylene glycol, Glyceryl triacetate, Neoagarobiose,
Sugar alcohols (sugar polyols) such as glycerol, sorbitol, xylitol,
maltitol, Polymeric polyols such as polydextrose, Quillaia, Urea,
Aloe vera gel, MP diol, Alpha hydroxy acids such as lactic acid,
Honey, Lithium chloride
[0048] Emulsifier:
[0049] An emulsifier generally helps disperse and suspend a
discontinuous phase within a continuous phase in an oil-in-water
emulsion. A wide variety of conventional emulsifiers are suitable
for use herein. Suitable emulsifiers include:
hydrophobically-modified cross-linked polyacrylate polymers and
copolymers, polyacrylamide polymers and copolymers, and
polyacryloyldimethyl taurates. More preferred examples of the
emulsifiers include: acrylates/C10-30 alkyl acrylate cross-polymer
having tradenames Pemulen.TM. TR-1, Pemulen.TM. TR-2 (all available
from Lubrizol); acrylates/steareth-20 methacrylate copolymer with
tradename ACRYSOL.TM. 22 (from Rohm and Hass); polyacrylamide with
tradename SEPIGEL 305 (from Seppic).
EXAMPLES
Example 1
[0050] The following samples were evaluated by the method described
below. Sample A is organosolv lignin extracted from Bagasse, Sample
B is organosolv lignin extracted from Corn Stover, Sample C is
organosolv lignin extracted from wheat straw, Sample D is lignin
extracted via steam explosion process (comparative example).
Samples A, B and C are the invention examples and Sample D is the
comparison example.
TABLE-US-00001 TABLE 2 Characteristic data for the example lignins:
Sulfur Mn .sup.b OH.sub.ali. .sup.c OH.sub.arom. .sup.c
OH.sub.arom/ content .sup.a Lignin (Da) (mmol/g) (mmol/g)
OH.sub.ali. (%) WS-OSL .sup.e 1000 1.4 2.2 1.6 <1 CS-OSL .sup.f
1100 1.4 2.3 1.6 <1 bagasse- 1100 1.6 2.4 1.5 <1 OSL .sup.g
ind. SEL .sup.h 8000 3.2 1.3 0.4 <1 .sup.a Determined via
elemental analysis (CHNS analysis). .sup.b Determined via gel
permeation chromatography of acetobrominated samples. .sup.c
Determined via .sup.31P NMR spectroscopy of phosphitylated sample..
.sup.e Industrially produced wheat straw organosolv lignin .sup.f
Industrially produced corn stover organosolv lignin. .sup.g
Industrially produced bagasse organosolv lignin. .sup.h
Industrially produced steam explosion lignin.
[0051] Preparation of Turbidity Samples:
[0052] Weigh out 0.1 g of lignin and disperse in non-ionic based
hard surface cleaning product (Flash diluted in de-ionized water at
the recommended dosage of 4.8 ml/l) and stir it for 15 minutes at
200 rpm at room temperature to form a lignin emulsion hard surface
cleaning composition. Then, measure the turbidity of the hard
surface cleaning composition using the above method with Turbiscan
Ageing Station.
Turbidity Data:
TABLE-US-00002 [0053] Sample name % Transmission (A) Bagasse 26.00
(B) Corn Stover 30.00 (C) Wheat Straw 54.00 (D) Steam Explosion
8.50 Sample A, B and C in accordance with the present invention
showed higher transmission values corresponding to superior
solubility properties than the comparison example (Sample D).
Example 2
Illustrative Examples
Hand Dishwashing
TABLE-US-00003 [0054] Wt % Wt % Examples Product I Product II Alkyl
ethoxy sulfate AExS 16 16 Amine oxide 5.0 5.0 C9-11 EO8 5 5 GLDA
0.7 0.7 Solvent 1.3 1.3 Polypropylene glycol (Mn = 2000) 0.5 0.5
Sodium chloride 0.8 0.8 Lignin 0.01 1.0 Water Balance Balance
Granular Laundry Detergent Compositions Designed for Front-Loading
Automatic Washing Machines:
TABLE-US-00004 [0055] Wt % Wt % Product I Product II Linear
alkylbenzenesulfonate 8 8 C12-14 Alkylsulfate 1 1 AE7 2.2 2.2
C.sub.10-12 Dimethyl 0.75 0.75 hydroxyethylammonium chloride
Crystalline layered silicate (.delta.- 4.1 4.1
Na.sub.2Si.sub.2O.sub.5) Zeolite A 5 5 Citric Acid 3 3 Sodium
Carbonate 15 15 Silicate 2R (SiO.sub.2:Na.sub.2O at ratio 0.08 0.08
2:1) Soil release agent 0.75 0.75 Acrylic Acid/Maleic Acid
Copolymer 1.1 1.1 Carboxymethylcellulose 0.15 0.15 Protease -
Purafect .RTM. 0.2 0.2 (84 mg active/g) Amylase - Stainzyme Plus
.RTM. 0.2 0.2 (20 mg active/g) Lipase - Lipex .RTM. 0.05 0.05
(18.00 mg active/g) Amylase - Natalase .RTM. 0.1 0.1 (8.65 mg
active/g) TAED 3.6 3.6 Percarbonate 13 13 Na salt of
Ethylenediamine- 0.2 0.2 N,N'-disuccinic acid, (S,S) isomer (EDDS)
Hydroxyethane di phosphonate 0.2 0.2 (HEDP) MgSO.sub.4 0.42 0.42
Perfume 0.5 0.5 Suds suppressor agglomerate 0.05 0.05 Soap 0.45
0.45 Sulphonated zinc phthalocyanine 0.0007 0.0007 (active) S-ACMC
0.01 0.01 Lignin 0.01 1.0 Sulfate/Water & Miscellaneous Balance
Balance
Beauty Lotion/Cream:
TABLE-US-00005 [0056] Wt % Wt % Product I Product II Water Balance
Balance Glycerin 7 7 Disodium EDTA 0.05 0.05 Methylparaben 0.1 0.1
Sodium Dehydroacetate 0.5 0.5 Benzyl alcohol 0.25 0.25 GLW75CAP-MP
(75% aq. 0.5 0.5 TiO2 dispersion).sup.1 Palmitoyl-dipeptide.sup.2
0.0001 0.0001 N-acetyl glucosamine 2 2 Salicylic Acid 1.5 1.5
Isohexadecane 3 3 PPG15 Stearyl Ether 4 4 Isopropyl Isostearate 1.3
1.3 Sucrose polyester 0.7 0.7 Phytosterol 0.5 0.5 Cetyl alcohol 0.4
0.4 Stearyl alcohol 0.5 0.5 Behenyl alcohol 0.4 0.4 PEG-100
stearate 0.1 0.1 Cetearyl glucoside 0.1 0.1 Polyacrylamide/C13-14 2
2 isoparaffin/laureth-7 Dimethicone/dimethiconol 2 2
Polymethylsilsequioxane 0.25 0.25 Lignin 0.01 1.00
Personal Care Product Containing Skin Lightening:
TABLE-US-00006 [0057] Wt % Wt % Component Product I Product II
Disodium EDTA 0.100 0.100 Phlorogine BG 2.000 0 deoxyArbutin 0
2.000 Niacinamide 5.000 5.000 Isohexadecane 3.000 3.000 Isopropyl
isostearate 1.330 1.330 Sucrose polycottonseedate 0.670 0.670
Polymethylsilsesquioxane 0.250 0.250 Cetearyl glucoside + cetearyl
alcohol 0.200 0.200 Behenyl alcohol 0.400 0.400 Ethylparaben 0.200
0.200 Propylparaben 0.100 0.100 Cetyl alcohol 0.320 0.320 Stearyl
alcohol 0.480 0.480 Tocopheryl acetate 0.500 0.500 PEG-100 stearate
0.100 0.100 Glycerin 7.000 7.000 Titanium dioxide 0.604 0.604
Polyacrylamide + C13-14 2.000 2.000 isoparaffin + laureth-7
Panthenol 1.000 1.000 Benzyl alcohol 0.400 0.400 Dimethicone +
dimethiconol 2.000 2.000 Lignin 0.010 1.000 Water (to 100 g)
Balance Balance
Automatic Dishwashing Cleaning Composition:
TABLE-US-00007 [0058] Powder (wt % Powder (wt % based on 19 g based
on 19 g portion) portion) STPP 34-38 34-38 Alcosperse.sup.1 7-12
7-12 SLF-18 Polytergent.sup.2 1-2 1-2 Esterified substituted
benzene 0.1-6.0 0.1-6.0 sulfonate.sup.3 Polymer.sup.4 0.2-6.0
0.2-6.0 Sodium perborate monohydrate 2-6 2-6 Carbonate 20-30 20-30
2.0r silicate 5-9 5-9 Sodium disilicate 0-3 0-3 Enzyme system.sup.5
0.1-5.0 0.1-5.0 Pentaamine cobalt(III)chloride 10-15 10-15
dichloride salt TAED 0-3 0-3 Perfume, dyes, water and other Balance
to 100% Balance to 100% components Liquid (wt % Liquid (wt % based
on 1.9 g based on 1.9 g portion) portion) Dipropylene Glycol 35-45
35-45 SLF-19 Polytergent.sup.2 40-50 40-50 Neodol .RTM. C11EO9 1-3
1-3 Lignin 0.01 1.0 Dyes, water and other Balance Balance
components .sup.1such as Alcosperse .RTM. 246 or 247, a sulfonated
copolymer of acrylic acid from Alco Chemical Co. .sup.2linear
alcohol ethoxylate from Olin Corporation .sup.3such as those
described above .sup.4a sulfonated polymer such as those described
above .sup.5one or more enzymes such as protease, mannaway,
natalase, lipase and mixture thereof.
[0059] The dimensions and values disclosed herein are not to be
understood as being strictly limited to the exact numerical values
recited. Instead, unless otherwise specified, each such dimension
is intended to mean both the recited value and a functionally
equivalent range surrounding that value. For example, a dimension
disclosed as "40 mm" is intended to mean "about 40 mm."
[0060] Every document cited herein, including any cross referenced
or related patent or application, is hereby incorporated herein by
reference in its entirety unless expressly excluded or otherwise
limited. The citation of any document is not an admission that it
is prior art with respect to any invention disclosed or claimed
herein or that it alone, or in any combination with any other
reference or references, teaches, suggests or discloses any such
invention. Further, to the extent that any meaning or definition of
a term in this document conflicts with any meaning or definition of
the same term in a document incorporated by reference, the meaning
or definition assigned to that term in this document shall
govern.
[0061] While particular embodiments of the present invention have
been illustrated and described, it would be obvious to those
skilled in the art that various other changes and modifications can
be made without departing from the spirit and scope of the
invention. It is therefore intended to cover in the appended claims
all such changes and modifications that are within the scope of
this invention.
* * * * *