U.S. patent application number 14/785968 was filed with the patent office on 2016-09-08 for extruded lightweight thermal insulating cement-based materials.
The applicant listed for this patent is THE INTELLECTUAL GORILLA GMBH. Invention is credited to Per Just Andersen, Evan R. Daniels.
Application Number | 20160257613 14/785968 |
Document ID | / |
Family ID | 51792381 |
Filed Date | 2016-09-08 |
United States Patent
Application |
20160257613 |
Kind Code |
A2 |
Daniels; Evan R. ; et
al. |
September 8, 2016 |
Extruded Lightweight Thermal Insulating Cement-Based Materials
Abstract
An extrudable cement-based material is formed from a mixture
that includes cement in the range of about 40 to 90% by wet weight
percent, a lightweight expanded aggregate in the range of about 10
to 60% by wet weight percent, a secondary material in the range of
about 0.1 to 50% by wet weight percent, a reinforcement fiber in
the range of about 1 to 20% by wet weight percent, a rheology
modifying agent in the range of about 0.5 to 10% by wet weight
percent, a retarder in the range of about 0.1 to 8% by wet weight
percent, and water in the range of 10 to 60% of a total wet
material weight.
Inventors: |
Daniels; Evan R.; (Dallas,
TX) ; Andersen; Per Just; (Dorfen, DE) |
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Applicant: |
Name |
City |
State |
Country |
Type |
THE INTELLECTUAL GORILLA GMBH |
Entlebuch |
|
CH |
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Prior
Publication: |
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Document Identifier |
Publication Date |
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US 20160068435 A1 |
March 10, 2016 |
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Family ID: |
51792381 |
Appl. No.: |
14/785968 |
Filed: |
April 24, 2014 |
PCT Filed: |
April 24, 2014 |
PCT NO: |
PCT/US2014/035277 PCKC 00 |
371 Date: |
October 21, 2015 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
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61815308 |
Apr 24, 2013 |
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61815328 |
Apr 24, 2013 |
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61815332 |
Apr 24, 2013 |
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61820850 |
May 8, 2013 |
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Current U.S.
Class: |
1/1 |
Current CPC
Class: |
C04B 41/4543 20130101;
C04B 2111/28 20130101; Y02W 30/94 20150501; C04B 14/16 20130101;
C04B 2111/00129 20130101; C04B 2201/32 20130101; Y02W 30/91
20150501; C04B 28/02 20130101; Y02W 30/92 20150501; Y02W 30/97
20150501; C04B 18/027 20130101; C04B 2111/40 20130101; C04B 28/02
20130101; C04B 14/06 20130101; C04B 14/12 20130101; C04B 14/16
20130101; C04B 14/185 20130101; C04B 14/24 20130101; C04B 14/28
20130101; C04B 14/42 20130101; C04B 16/0633 20130101; C04B 16/0641
20130101; C04B 16/065 20130101; C04B 18/08 20130101; C04B 18/141
20130101; C04B 18/146 20130101; C04B 18/24 20130101; C04B 22/143
20130101; C04B 24/06 20130101; C04B 24/14 20130101; C04B 24/38
20130101; C04B 24/383 20130101; C04B 28/02 20130101; C04B 14/06
20130101; C04B 14/12 20130101; C04B 14/16 20130101; C04B 14/185
20130101; C04B 14/24 20130101; C04B 14/42 20130101; C04B 16/0633
20130101; C04B 16/0641 20130101; C04B 16/065 20130101; C04B 18/08
20130101; C04B 18/146 20130101; C04B 18/24 20130101; C04B 2103/0079
20130101; C04B 2103/20 20130101 |
International
Class: |
C04B 18/02 20060101
C04B018/02; C04B 14/16 20060101 C04B014/16; C04B 41/45 20060101
C04B041/45; C04B 28/02 20060101 C04B028/02 |
Claims
1. An extrudable lightweight thermal insulating cement-based
material formed from a mixture comprising: a cement in the range of
about 40 to 90% by wet weight percent; a lightweight expanded
aggregate in the range of about 5 to 40% by wet weight percent; a
secondary material in the range of about 0.1 to 50% by wet weight
percent; a reinforcement fiber in the range of about 1 to 20% by
wet weight percent; a rheology modifying agent in the range of
about 0.5 to 10% by wet weight percent; a retarder in the range of
about 0.1 to 8% by wet weight percent; a water in the range of 10
to 60% of a total wet material weight; and the mixture is
extrudable.
2. The extrudable lightweight thermal insulating cement-based
material as recited in claim 1, the lightweight expanded aggregate
comprising clay, Perlite, expanded glass, expanded pumice, or a
combination thereof.
3. The extrudable lightweight thermal insulating cement-based
material as recited in claim 2, the expanded glass or the expanded
pumice formed from a mixture comprising: a ground glass or pumice
in the range of about 40 to 60% by weight percent for a slurry; a
water in the range of about 40 to 60% by weight percent for the
slurry; a sodium silicate in the range of about 3 to 15% by weight
percent for the slurry; a NaNO.sub.3 in the range of about 0.1 to
5% for the slurry; the ground glass or pumice in the range of about
50 to 80% by weight percent for a granulator; and the slurry in the
range of about 15 to 50% by weight percent for the granulator.
4. The extrudable lightweight thermal insulating cement-based
material as recited in claim 3, the granulator having a ratio of
about 1 part slurry to about 2.5 parts ground glass or pumice.
5. The extrudable lightweight thermal insulating cement-based
material as recited in claim 2, the expanded glass or the expanded
pumice formed from a mixture consisting essentially of: a ground
glass or pumice in the range of about 40 to 60% by weight percent
for a slurry; a water in the range of about 40 to 60% by weight
percent for the slurry; a sodium silicate in the range of about 3
to 15% by weight percent for the slurry; a NaNO.sub.3 in the range
of about 0.1 to 5% for the slurry; the ground glass or pumice in
the range of about 50 to 80% by weight percent for a granulator;
and the slurry in the range of about 15 to 50% by weight percent
for the granulator.
6. The extrudable lightweight thermal insulating cement-based
material as recited in claim 2, the expanded glass or the expanded
pumice formed from a mixture comprising: a ground glass or pumice
in the range of about 40 to 60% by weight percent for a slurry; a
water in the range of about 45 to 50% by weight percent for the
slurry; a sodium silicate in the range of about 6 to 7% by weight
percent for the slurry; a NaNO.sub.3 in the range of about 0.9 to
1.1% for the slurry; and a granulator having a ratio of 1 part
slurry to about 2.5 parts ground glass or pumice.
7. The extrudable lightweight thermal insulating cement-based
material as recited in claim 2, the expanded glass or the expanded
pumice having a diameter of about 0-8 mm, a bulk density in the
range of about 0.10 to 0.5 g/cm.sup.3, a effective density in the
range of about 0.10 to 0.8 g/cm.sup.3, a compressive strength in
the range of about 0.5 MPa to 5 MPa, and a heat conductance in the
range of about 0.04 to 0.15 W/mK.
8. The extrudable lightweight thermal insulating cement-based
material as recited in claim 1, the lightweight expanded aggregate
having a particle size comprising about 0-1 mm, 1-2 mm, 2-4 mm, 4-8
mm or a combination thereof.
9. The extrudable lightweight thermal insulating cement-based
material as recited in claim 1, the secondary material comprising
sand, gypsum, silica fume, fumed silica, fly ash, slag, rock,
cellulose fiber, glass fiber, plastic fiber, polyvinyl alcohol
(PVA) fiber, or a combination thereof.
10. The extrudable lightweight thermal insulating cement-based
material as recited in claim 1, the reinforcement fiber comprising
cellulose fiber, glass fiber, polypropylene fiber, polyvinyl
alcohol (PVA) fiber, Dolanit fiber, or a combination thereof.
11. The extrudable lightweight thermal insulating cement-based
material as recited in claim 1, the rheology modifying agent
comprising a polysaccharide, a polysaccharide derivative, a
protein, a protein derivative, a synthetic organic material, a
synthetic organic material derivative, or a combination
thereof.
12. The extrudable lightweight thermal insulating cement-based
material as recited in claim 11, the polysaccharide comprising a
cellulose-based material, a cellulose-based material derivative, a
starch-based material, a starch-based material derivative, or a
combination thereof.
13. The extrudable lightweight thermal insulating cement-based
material as recited in claim 12, the cellulose-based material is
selected from the group consisting essentially of
methylhydroxyethylcellulose (MHEC), hydroxymethylethylcellulose
(HMEC), carboxymethylcellulose (CMC), methylcellulose (MC),
ethylcellulose (EC), hydroxyethylcellulose (HEC),
hydroxyethylpropylcellulose (HEPC) and hydroxypropoylmethylcelluose
(HPMC).
14. The extrudable lightweight thermal insulating cement-based
material as recited in claim 12, the starch-based material is
selected from the group consisting essentially of wheat starch,
pre-gelled wheat starch, potato starch, pre-gelled potato starch,
amylopectin, amylose, seagel, starch acetates, starch hydroxyethyl
ethers, ionic starches, long-chain alkylstarches, dextrins, amine
starches, phosphate starches, or dialdehyde starches.
15. The extrudable lightweight thermal insulating cement-based
material as recited in claim 1, the retarder comprising sodium
citrate, or a mixture of Plaster of Paris, sodium citrate and
crystalline silica.
16. The extrudable lightweight thermal insulating cement-based
material as recited in claim 1, the extrudable lightweight thermal
insulating cement-based material having a density in the range of
about 0.2 to 1.0 g/cm.sup.3, a compressive strength in the range of
about 0.5 MPa to 10 MPa, and a heat conductance in the range of
about 0.05 to 0.3 W/mK.
17. An extrudable lightweight thermal insulating cement-based
material formed from a mixture consisting essentially of: a cement
in the range of about 40 to 90% by wet weight percent; a
lightweight expanded aggregate in the range of about 5 to 40% by
wet weight percent; a secondary material in the range of about 0.1
to 50% by wet weight percent; a reinforcement fiber in the range of
about 1 to 20% by wet weight percent; a rheology modifying agent in
the range of about 0.5 to 10% by wet weight percent; a retarder in
the range of about 0.1 to 8% by wet weight percent; a water in the
range of 10 to 60% of a total wet material weight; and the mixture
is extrudable.
18. A method for manufacturing an extrudable lightweight thermal
insulating cement-based material comprising the steps of: mixing a
cement, a lightweight expanded aggregate, a secondary material, a
reinforcement fiber, a rheology modifying agent and a retarder with
water; extruding the mixture through a die using an extruder; and
allowing the extruded mixture to set.
19. The method as recited in claim 18, the mixture comprising: the
cement in the range of about 40 to 90% by wet weight percent; the
lightweight expanded aggregate in the range of about 5 to 40% by
wet weight percent; the secondary material in the range of about
0.1 to 50% by wet weight percent; the reinforcement fiber in the
range of about 1 to 20% by wet weight percent; the rheology
modifying agent in the range of about 0.5 to 10% by wet weight
percent; the retarder in the range of about 0.1 to 8% by wet weight
percent; and the water in the range of 10 to 60% of a total wet
material weight.
20. The method as recited in claim 18, the mixture consisting
essentially of: the cement in the range of about 40 to 90% by wet
weight percent; the lightweight expanded aggregate in the range of
about 5 to 40% by wet weight percent; the secondary material in the
range of about 0.1 to 50% by wet weight percent; the reinforcement
fiber in the range of about 1 to 20% by wet weight percent; the
rheology modifying agent in the range of about 0.5 to 10% by wet
weight percent; the retarder in the range of about 0.1 to 8% by wet
weight percent; and the water in the range of 10 to 60% of a total
wet material weight.
21. The method as recited in claim 18, the lightweight expanded
aggregate comprising clay, Perlite, expanded glass, expanded
pumice, or a combination thereof.
22. The method as recited in claim 21, the expanded glass or the
expanded pumice formed from a mixture comprising: a ground glass or
pumice in the range of about 40 to 60% by weight percent for a
slurry; a water in the range of about 40 to 60% by weight percent
for the slurry; a sodium silicate in the range of about 3 to 15% by
weight percent for the slurry; a NaNO.sub.3 in the range of about
0.1 to 5% for the slurry; the ground glass or pumice in the range
of about 50 to 80% by weight percent for a granulator; and the
slurry in the range of about 15 to 50% by weight percent for the
granulator.
23. The method as recited in claim 22, the granulator having a
ratio of about 1 part slurry to about 2.5 parts ground glass or
pumice.
24. The method as recited in claim 21, the expanded glass or the
expanded pumice formed from a mixture consisting essentially of: a
ground glass or pumice in the range of about 40 to 60% by weight
percent for a slurry; a water in the range of about 40 to 60% by
weight percent for the slurry; a sodium silicate in the range of
about 3 to 15% by weight percent for the slurry; a NaNO.sub.3 in
the range of about 0.1 to 5% for the slurry; the ground glass or
pumice in the range of about 50 to 80% by weight percent for a
granulator; and the slurry in the range of about 15 to 50% by
weight percent for the granulator.
25. The method as recited in claim 21, the expanded glass or the
expanded pumice formed from a mixture comprising: a ground glass or
pumice in the range of about 40 to 60% by weight percent for a
slurry; a water in the range of about 45 to 50% by weight percent
for the slurry; a sodium silicate in the range of about 6 to 7% by
weight percent for the slurry; a NaNO.sub.3 in the range of about
0.9 to 1.1% for the slurry; and a granulator having a ratio of 1
part slurry to about 2.5 parts ground glass or pumice.
26. The method as recited in claim 21, the expanded glass or the
expanded pumice having a diameter of about 0-8 mm, a bulk density
in the range of about 0.10 to 0.5 g/cm.sup.3, a effective density
in the range of about 0.10 to 0.8 g/cm.sup.3, a compressive
strength in the range of about 0.5 MPa to 5 MPa, and a heat
conductance in the range of about 0.04 to 0.15 W/mK.
27. The method as recited in claim 18, further comprising the step
of making the lightweight expanded aggregate comprising the steps
of: mixing a ground glass or pumice in the range of about 40 to 60%
by weight percent with water in the range of about 40 to 60% by
weight percent to produce a slurry; adding a sodium silicate in the
range of about 3 to 15% by weight percent to the slurry; adding a
NaNO.sub.3 in the range of about 0.1 to 5% to the slurry; forming
aggregates in a granulator by feeding the ground glass or pumice in
the range of about 50 to 80% by weight percent with the slurry in
the range of about 15 to 50% by weight percent; drying the formed
aggregates; heating the dried aggregates together with about 30%
finely ground kaolin to a temperature of about 800 to 1400 degrees
Celsius; and cooling the heated aggregates.
28. The method as recited in claim 18, the lightweight expanded
aggregate having a particle size comprising about 0-1 mm, 1-2 mm,
2-4 mm, 4-8 mm or a combination thereof.
29. The method as recited in claim 18, the secondary material
comprising sand, gypsum, silica fume, fumed silica, fly ash, slag,
rock, cellulose fiber, glass fiber, plastic fiber, polyvinyl
alcohol (PVA) fiber, or a combination thereof.
30. The method as recited in claim 18, the reinforcement fiber
comprising cellulose fiber, glass fiber, polypropylene fiber,
polyvinyl alcohol (PVA) fiber, Dolanit fiber, or a combination
thereof.
31. The method as recited in claim 18, the rheology modifying agent
comprising a polysaccharide, a polysaccharide derivative, a
protein, a protein derivative, a synthetic organic material, a
synthetic organic material derivative, or a combination
thereof.
32. The method as recited in claim 31, the polysaccharide
comprising a cellulose-based material, a cellulose-based material
derivative, a starch-based material, a starch-based material
derivative, or a combination thereof.
33. The method as recited in claim 32, the cellulose-based material
is selected from the group consisting essentially of
methylhydroxyethylcellulose (MHEC), hydroxymethylethylcellulose
(HMEC), carboxymethylcellulose (CMC), methylcellulose (MC),
ethylcellulose (EC), hydroxyethylcellulose (HEC),
hydroxyethylpropylcellulose (HEPC) and hydroxypropoylmethylcelluose
(HPMC).
34. The method as recited in claim 32, the starch-based material is
selected from the group consisting essentially of wheat starch,
pre-gelled wheat starch, potato starch, pre-gelled potato starch,
amylopectin, amylose, seagel, starch acetates, starch hydroxyethyl
ethers, ionic starches, long-chain alkylstarches, dextrins, amine
starches, phosphate starches, or dialdehyde starches.
35. The method as recited in claim 18, the retarder comprising
sodium citrate, or a mixture of Plaster of Paris, sodium citrate
and crystalline silica.
36. The method as recited in claim 18, the extruded mixture having
a density in the range of about 0.2 to 1.0 g/cm.sup.3, a
compressive strength in the range of about 0.5 MPa to 10 MPa, and a
heat conductance in the range of about 0.05 to 0.3 W/mK after being
set, cured or dried.
37. The method as recited in claim 18, wherein the extruded mixture
is allowed to set for up to 2 to 3 hours.
38. The method as recited in claim 18, further comprising the step
of curing the extruded mixture.
39. The method as recited in claim 18, further comprising the step
of drying the extruded mixture.
40. The method as recited in claim 18, further comprising the step
of molding, cutting, trimming, sanding or routing the extruded
mixture into a specified shape.
41. The method as recited in claim 18, further comprising the step
of spraying the extruded mixture with a water repellent.
Description
CROSS-REFERENCE TO RELATED APPLICATIONS
[0001] This application claims priority to, and is the National
Stage of International Application No. PCT/US2014/035277 filed on
Apr. 24, 2014 and claims priority to U.S. Provisional Patent
Application Ser. No. 61/815,308, filed on Apr. 24, 2013, U.S.
Provisional Patent Application Ser. No. 61/815,328, filed on Apr.
24, 2013, U.S. Provisional Patent Application Ser. No. 61/815,332,
filed on Apr. 24, 2013, and U.S. Provisional Patent Application
Ser. No. 61/820,850, filed on May 8, 2013. The contents of both
applications are hereby incorporated by reference herein in their
entirety.
FIELD OF THE INVENTION
[0002] The present invention relates in general to cement-based
materials, and more particularly to extruded lightweight thermal
insulating cement-based materials.
BACKGROUND ART
[0003] Cement-based materials are generally produced using large
amount of water to form a slurry that is too wet to extrude.
Moreover, cement-based materials are generally not both lightweight
and thermally insulating.
SUMMARY OF THE INVENTION
[0004] The present invention provides an extrudable lightweight
thermal insulating cement-based material that is formed from a
mixture that includes cement in the range of about 40 to 90% by wet
weight percent, water in the range of about 10 to 60%, a
lightweight expanded aggregate in the range of about 5 to 40% by
wet weight percent, a secondary material (e.g., sand, rock, fly
ash, slag, silica fume, calcium carbonate, etc.) in the range of
about 0.1 to 50% by wet weight percent, a reinforcement fiber in
the range of about 1 to 20% by wet weight percent, a rheology
modifying agent in the range of about 0.5 to 10% by wet weight
percent, and a retarder in the range of about 0.1 to 8% by dry
weight percent.
[0005] In addition, the present invention provides a method for
manufacturing an extrudable cement-based material by mixing a
cement, a lightweight expanded aggregate, a secondary material, a
reinforcement fiber, a rheology modifying agent and a retarder with
water, extruding the mixture through a die using an extruder, and
allowing the extruded mixture to set.
[0006] Moreover, the present invention provides a method of making
the extrudable lightweight thermal insulating cement-based material
(composite) by the following steps: (1) mixing about 40 to 90% Wt.
wet cement with about 10 to 60% Wt. wet water; (2) blending the
cement-water mixture with about 5 to 40% Wt. wet lightweight
expanded aggregate, about 0.1 to 50% Wt. wet secondary material
(e.g., sand, rock, fly ash, slag, silica fume, calcium carbonate,
etc.), and about 1 to 20% Wt. wet reinforcement fiber; and (3)
adding about 0.5 to 10% Wt. wet rheology modifying agent and about
0.1 to 8% Wt. wet retarder to the mixture. The resulting extrudable
lightweight thermal insulating cement-based material can then be
extruded and cured (e.g., allowed to sit, heating, steam,
etc.).
BRIEF DESCRIPTION OF THE DRAWINGS
[0007] For a more complete understanding of the features and
advantages of the present invention, reference is now made to the
detailed description of the invention along with the accompanying
figures and in which:
[0008] Not applicable.
DESCRIPTION OF THE INVENTION
[0009] While the making and using of various embodiments of the
present invention are discussed in detail below, it should be
appreciated that the present invention provides many applicable
inventive concepts that can be embodied in a wide variety of
specific contexts. The specific embodiments discussed herein are
merely illustrative of specific ways to make and use the invention
and do not delimit the scope of the invention.
[0010] To facilitate the understanding of this invention, a number
of terms are defined below. Terms defined herein have meanings as
commonly understood by a person of ordinary skill in the areas
relevant to the present invention. Terms such as "a", "an," and
"the" are not intended to refer to only a singular entity, but
include the general class of which a specific example may be used
for illustration. The terminology herein is used to describe
specific embodiments of the invention, but their usage does not
delimit the invention, except as outlined in the claims.
[0011] Ordinary Portland cement or aluminate cement in its wet
state with water added before setting, can be rheologically
modified in to a clay-like material, which allows the use of the
conventional clay production method known as extrusion.
[0012] To make the cement-water mixture lightweight, it is blended
with about 5-40 wt. % of lightweight expanded aggregate of the
total wet volume. The preferred lightweight expanded aggregate is
either expanded clay, Perlite, expanded glass, expanded pumice, or
a combination thereof. The particle size of the lightweight
expanded aggregate is either about 0-1 mm, 1-2 mm, 2-4 mm, 4-8 mm
or a combination thereof. A process for making the lightweight
expanded glass or pumice aggregate will be described after the
discussion regarding the lightweight thermal insulating
cement-based material.
[0013] For extrusion, the cement-based lightweight thermal
insulating composite with approx. 10-60 wt. % water of the total
wet material and a suitable rheology modifying admixture is made to
feel and behave similar to plastic clay. The material feels
plastic/deformable to the touch and can be extruded similar to clay
with the use of a clay extruder where the material is conveyed
forward by an auger through a barrel and is formed continuously
through a die into a final shape with form stability.
[0014] Depending on the water content and the amount of rheology
modifying admixture, the extruded material can have more or less
form stability.
[0015] To allow enough time of the cement-based material to be
extruded before setting (hardening), the setting time can be
retarded up to several hours with the use of small additions of
suitable set retarders such as Sodate.TM. (USG Product) or sodium
citrate. Sodate.TM. is a mixture of Plaster of Paris, sodium
citrate and crystalline silica. Following extrusion, the material
will within a few hours develop the final strength of the finished
product.
[0016] To develop the final 28 days strength, the product is either
allowed to sit around for 28 days in a humid environment, or the
strength development can be accelerated within 24-48 hours by
heating either by its own internal heat development or by steam
curing such as is conventional in the state-of-the-art.
[0017] As will be described below, the present invention provides
an extrudable cement-based material that is formed from a mixture
that includes cement in the range of about 40 to 90% by dry weight
percent, a secondary material in the range of about 0.1 to 50% by
dry weight percent, a reinforcement fiber in the range of about 1
to 20% by dry weight percent, a rheology modifying agent in the
range of about 0.5 to 10% by dry weight percent, a retarder in the
range of about 0.1 to 8% by dry weight percent, a water in the
range of 10 to 50% of a total wet material weight.
[0018] The cement can be used as a binder with water in a composite
composition in combination with a multitude of materials such as
sand, gypsum, silica fume, fumed silica, fly ash, slag, rock,
cellulose fiber, glass fiber, plastic fiber, polyvinyl alcohol
(PVA) fiber, etc., or a combination thereof, which when
rheologically modified can be extruded as described above.
[0019] The rheology-modifying agents fall into the following
categories: (1) polysaccharides and derivatives thereof, (2)
proteins and derivatives thereof, and (3) synthetic organic
materials. Polysaccharide rheology-modifying agents can be further
subdivided into (a) cellulose-based materials and derivatives
thereof, (b) starch-based materials and derivatives thereof, and
(c) other polysaccharides.
[0020] Suitable cellulose-based rheology-modifying agents include,
for example, methylhydroxyethylcellulose (MHEC),
hydroxymethylethylcellulose (HMEC), carboxymethylcellulose (CMC),
methylcellulose (MC), ethylcellulose (EC), hydroxyethylcellulose
(HEC), hydroxyethylpropylcellulose (HEPC), or
hydroxypropoylmethylcelluose (HPMC), etc.
[0021] Suitable starch-based materials include, for example, wheat
starch, pre-gelled wheat starch, potato starch, pre-gelled potato
starch, amylopectin, amylose, seagel, starch acetates, starch
hydroxyethyl ethers, ionic starches, long-chain alkylstarches,
dextrins, amine starches, phosphate starches, and dialdehyde
starches.
[0022] The currently preferred rheology-modifying agent is
methylhydroxypropylcellulose, examples of which are Methocel.TM.
240 and Methocel.TM. 240S, both of which are available from DOW
Chemicals, USA.
[0023] The finished lightweight thermal insulating cement-based
composite will have densities in the range of about 0.2-1.0 g/cm3,
compressive strengths in the range of about 0.5 MPa-10 MPa and heat
conductance in the range of about 0.05-0.3 W/mK.
[0024] In one embodiment of the present invention, the
compositional ranges of cement-based material can be:
TABLE-US-00001 Component Wt. % Range of Wet Cement 40-90 Water
10-60 Lightweight expanded aggregate 5-40 Secondary material (e.g.,
sand, rock, 0.1-50 fly ash, slag, silica fume, calcium carbonate,
etc.) Reinforcement fiber 1-20 Rheology modifying agent 0.5-10
Retarder 0.1-8
[0025] The cement can be about 40%, 41%, 42%, 43%, 44%, 45%, 46%,
47%, 48%, 49%, 50%, 51%, 52%, 53%, 54%, 55%, 56%, 57%, 58%, 59%,
60%, 61%, 62%, 63%, 64%, 65%, 66%, 67%, 68%, 69%, 70%, 71%, 72%,
73%, 74%, 75%, 76%, 77%, 78%, 79%, 80%, 81%, 82%, 83%, 84%, 85%,
86%, 87%, 88%, 89% or 90% by weight or other incremental percentage
between.
[0026] The water can be about 10%, 11%, 12%, 13%, 14%, 15%, 16%,
17%, 18%, 19%, 20%, 21%, 22%, 23%, 24%, 25%, 26%, 27%, 28%, 29%,
30%, 31%, 32%, 33%, 34%, 35%, 36%, 37%, 38%, 39%, 40%, 41%, 42%,
43%, 44%, 45%, 46%, 47%, 48%, 49%, 50% 51%, 52%, 53%, 54%, 55%,
56%, 57%, 58%, 59% or 60% by weight or other incremental percentage
between.
[0027] The lightweight expanded aggregate can be about 5%, 6%, 7%,
8%, 9%, 10%, 11%, 12%, 13%, 14%, 15%, 16%, 17%, 18%, 19%, 20%, 21%,
22%, 23%, 24%, 25%, 26%, 27%, 28%, 29%, 30%, 31%, 32%, 33%, 34%,
35%, 36%, 37%, 38%, 39% or 40% by weight or other incremental
percentage between.
[0028] The secondary material can be about 0.1%, 0.2%, 0.3%, 0.4%,
0.5%, 0.6%, 0.7%, 0.8%, 0.9%, 1%, 2%, 3%, 4%, 5%, 6%, 7%, 8%, 9%,
10%, 11%, 12%, 13%, 14%, 15%, 16%, 17%, 18%, 19%, 20%, 21%, 22%,
23%, 24%, 25%, 26%, 27%, 28%, 29%, 30%, 31%, 32%, 33%, 34%, 35%,
36%, 37%, 38%, 39%, 40%, 41%, 42%, 43%, 44%, 45%, 46%, 47%, 48%,
49% or 50% by weight or other incremental percentage between.
[0029] The reinforcement fiber can be about 1%, 2%, 3%, 4%, 5%, 6%,
7%, 8%, 9%, 10%, 11%, 12%, 13%, 14%, 15%, 16%, 17%, 18%, 19% or 20%
by weight or other incremental percentage between.
[0030] The rheology modifying agent can be about 0.5%, 0.6%, 0.7%,
0.8%, 0.9%, 1.0%, 1.1%, 1.2%, 1.3%, 1.4%, 1.5%, 1.6%, 1.7%, 1.8%,
1.9%, 2.0%, 2.1%, 2.2%, 2.3%, 2.4%, 2.5%, 2.6%, 2.7%, 2.8%, 2.9%,
3.0%, 3.1%, 3.2%, 3.3%, 3.4%, 3.5%, 3.6%, 3.7%, 3.8%, 3.9%, 4.0%,
4.1%, 4.2%, 4.3%, 4.4%, 4.5%, 4.6%, 4.7%, 4.8%, 4.9%, 5.0%, 5.1%,
5.2%, 5.3%, 5.4%, 5.5%, 5.6%, 5.7%, 5.8%, 5.9%, 6.0%, 6.1%, 6.2%,
6.3%, 6.4%, 6.5%, 6.6%, 6.7%, 6.8%, 6.9%, 7.0%, 7.1%, 7.2%, 7.3%,
7.4%, 7.5%, 7.6%, 7.7%, 7.8%, 7.9%, 8.0%, 8.1%, 8.2%, 8.3%, 8.4%,
8.5%, 8.6%, 8.7%, 8.8%, 8.9%, 9.0%, 9.1%, 9.2%, 9.3%, 9.4%, 9.5%,
9.6%, 9.7%, 9.8%, 9.9%, 10.0% by weight or other incremental
percentage between.
[0031] The retarder can be about 0.1%, 0.2%, 0.3%, 0.4%, 0.5%,
0.6%, 0.7%, 0.8%, 0.9%, 1.0%, 1.1%, 1.2%, 1.3%, 1.4%, 1.5%, 1.6%,
1.7%, 1.8%, 1.9%, 2.0%, 2.1%, 2.2%, 2.3%, 2.4%, 2.5%, 2.6%, 2.7%,
2.8%, 2.9%, 3.0%, 3.1%, 3.2%, 3.3%, 3.4%, 3.5%, 3.6%, 3.7%, 3.8%,
3.9%, 4.0%, 4.1%, 4.2%, 4.3%, 4.4%, 4.5%, 4.6%, 4.7%, 4.8%, 4.9%,
5.0%, 5.1%, 5.2%, 5.3%, 5.4%, 5.5%, 5.6%, 5.7%, 5.8%, 5.9%, 6.0%,
6.1%, 6.2%, 6.3%, 6.4%, 6.5%, 6.6%, 6.7%, 6.8%, 6.9%, 7.0%, 7.1%,
7.2%, 7.3%, 7.4%, 7.5%, 7.6%, 7.7%, 7.8%, 7.9% or 8.0% by weight or
other incremental percentage between.
[0032] In addition, the present invention provides a method for
manufacturing an extrudable lightweight thermal insulating
cement-based material by mixing a cement, a lightweight expanded
aggregate, a secondary material, a reinforcement fiber, a rheology
modifying agent and a retarder with water, extruding the mixture
through a die using an extruder, and allowing the extruded mixture
to set (e.g., up to 2 to 3 hours, etc).
[0033] Additional steps may include: (1) drying the extruded
mixture; (2) curing the extruded mixture; (3) molding, cutting,
trimming, sanding or routing the extruded mixture into a specified
shape; and/or (4) spraying the extruded mixture with a water
repellent.
[0034] Following setting and drying of the finished product, the
surface of the finished product can be made water resistant with
the use of silanes or surface coatings.
[0035] Making the lightweight expanded aggregate from glass or
pumice will now be described. The lightweight expanded glass or
pumice aggregate can be made as follows:
[0036] 1) Grind glass or pumice in a ball mill to produce ground
material predominantly less than about 100 microns.
[0037] 2) Mix the ground material with about 45-50% water to
produce a slurry.
[0038] 3) Add about 6-7% sodium silicate (substitution ratio of
2.5) to the slurry.
[0039] 4) Add about 1% sodium nitrate (NaNO.sub.3) to the slurry.
This later acts as a blowing agent.
[0040] 5) Aggregates are produced in conventional granulator by
feeding about 1 part mixed slurry to 2.5 parts of ground pumice. By
varying the amount of water in the slurry and the ratio of ground
pumice to the slurry, the aggregate size can be tailored to set a
maximum final aggregate size.
[0041] 6) Following, the formed aggregates are dried in a
conventional rotary drier.
[0042] 7) Following, the dried aggregates together with about 30%
finely ground kaolin are fed into a rotary kiln where it is heated
between about 800-1400 degrees Celsius, during which process the
granules expand to its final size of about 0-8 mm diameter and
forms the light weight expanded aggregate.
[0043] 8) Upon exiting the rotary kiln as last steps the aggregates
are cooled and then sieved to divide the aggregate into different
end use size ranges such as 0-2 mm, 2-4 mm and 4-8 mm
[0044] 9) Alternatively finer aggregates can be formed by following
the granulator, feeding the finer aggregates directly in to a flash
drier that heat the material above about 800 degrees Celsius and
creates expanded aggregates in the size of about 0-1 mm.
[0045] The finished lightweight expanded glass or pumice aggregate
has a diameter of about 0-8 mm, a bulk density of about 0.10-0.50
g/cm3 and an effective density of about 0.10-0.8 g/cm3. The
aggregates further have a compressive strength of about 0.5-5 MPa
and are very good heat insulators with heat conductance of about
0.04-0.15 W/mK.
[0046] In one embodiment of the present invention, the
compositional ranges of the expanded lightweight glass or pumice
aggregate can be:
TABLE-US-00002 Component Wt. % Range Slurry: Ground glass or pumice
40-60 Water 40-60 Sodium silicate 3-15 NaNO.sub.3 0.1-5 For
granulator: Ground glass or pumice 50-85 Slurry 15-50
[0047] For the slurry, the ground glass or pumice can be about 40%,
41%, 42%, 43%, 44%, 45%, 46%, 47%, 48%, 49%, 50%, 51%, 52%, 53%,
54%, 55%, 56%, 57%, 58%, 59% or 60% by weight or other incremental
percentage between.
[0048] For the slurry, the water can be about 40%, 41%, 42%, 43%,
44%, 45%, 46%, 47%, 48%, 49%, 50%, 51%, 52%, 53%, 54%, 55%, 56%,
57%, 58%, 59% or 60% by weight or other incremental percentage
between.
[0049] For the slurry, the sodium silicate can be about 3%, 4%, 5%,
6%, 7%, 8%, 9%, 10%, 11%, 12%, 13%, 14% or 15% by weight or other
incremental percentage between.
[0050] For the slurry, the NaNO3 can be about 0.1%, 0.2%, 0.3%,
0.4%, 0.5%, 0.6%, 0.7%, 0.8%, 0.9%, 1%, 2%, 3%, 4% or 5% by weight
or other incremental percentage between.
[0051] For the granulator, the ground glass or pumice can be about
50%, 51%, 52%, 53%, 54%, 55%, 56%, 57%, 58%, 59%, 60%, 61%, 62%,
63%, 64%, 65%, 66%, 67%, 68%, 69%, 70%, 71%, 72%, 73%, 74%, 75%,
76%, 77%, 78%, 79%, 80%, 81%, 82%, 83%, 84% or 85% by weight or
other incremental percentage between.
[0052] For the granulator, the slurry can be about 15%, 16%, 17%,
18%, 19%, 20%, 21%, 22%, 23%, 24%, 25%, 26%, 27%, 28%, 29%, 30%,
31%, 32%, 33%, 34%, 35%, 36%, 37%, 38%, 39%, 40%, 41%, 42%, 43%,
44%, 45%, 46%, 47%, 48%, 49% or 50% by weight or other incremental
percentage between.
[0053] In another embodiment of the present invention the
compositional ranges of the expanded lightweight glass or pumice
aggregate can be:
TABLE-US-00003 Component Wt. % Range Slurry: Ground glass or pumice
40-60 Water 45-50 Sodium silicate 6-7 NaNO.sub.3 0.9-1.1 For
granulator: 1 part slurry to 2.5 parts ground glass or pumice
[0054] For the slurry, the ground glass or pumice can be about 40%,
41%, 42%, 43%, 44%, 45%, 46%, 47%, 48%, 49%, 50%, 51%, 52%, 53%,
54%, 55%, 56%, 57%, 58%, 59% or 60% by weight or other incremental
percentage between.
[0055] For the slurry, the water can be about 45%, 46%, 47%, 48%,
49% or 50% by weight or other incremental percentage between.
[0056] For the slurry, the sodium silicate can be about 6.0%, 6.1%,
6.2%, 6.3%, 6.4%, 6.5%, 6.6%, 6.7%, 6.8%, 6.9% or 7.0% by weight or
other incremental percentage between.
[0057] For the slurry, the NaNO3 can be about 0.9%, 1.0% or 1.1% by
weight or other incremental percentage between.
[0058] It may be understood that particular embodiments described
herein are shown by way of illustration and not as limitations of
the invention. The principal features of this invention can be
employed in various embodiments without departing from the scope of
the invention. Those skilled in the art will recognize, or be able
to ascertain using no more than routine experimentation, numerous
equivalents to the specific procedures described herein. Such
equivalents are considered to be within the scope of this invention
and are covered by the claims.
[0059] All publications, patents and patent applications mentioned
in the specification are indicative of the level of skill of those
skilled in the art to which this invention pertains. All
publications, patents and patent applications are herein
incorporated by reference to the same extent as if each individual
publication, patent or patent application was specifically and
individually indicated to be incorporated by reference.
[0060] The use of the word "a" or "an" when used in conjunction
with the term "comprising" in the claims and/or the specification
may mean "one," but it is also consistent with the meaning of "one
or more," "at least one," and "one or more than one." The use of
the term "or" in the claims is used to mean "and/or" unless
explicitly indicated to refer to alternatives only or the
alternatives are mutually exclusive, although the disclosure
supports a definition that refers to only alternatives and
"and/or." Throughout this application, the term "about" is used to
indicate that a value includes the inherent variation of error for
the device, the method being employed to determine the value, or
the variation that exists among the study subjects.
[0061] As used in this specification and claim(s), the words
"comprising" (and any form of comprising, such as "comprise" and
"comprises"), "having" (and any form of having, such as "have" and
"has"), "including" (and any form of including, such as "includes"
and "include") or "containing" (and any form of containing, such as
"contains" and "contain") are inclusive or open-ended and do not
exclude additional, unrecited elements or method steps.
[0062] The term "or combinations thereof" as used herein refers to
all permutations and combinations of the listed items preceding the
term. For example, "A, B, C, or combinations thereof" is intended
to include at least one of: A, B, C, AB, AC, BC, or ABC, and if
order is important in a particular context, also BA, CA, CB, CBA,
BCA, ACB, BAC, or CAB.
[0063] Continuing with this example, expressly included are
combinations that contain repeats of one or more item or term, such
as BB, AAA, AB, BBC, AAABCCCC, CBBAAA, CABABB, and so forth. The
skilled artisan will understand that typically there is no limit on
the number of items or terms in any combination, unless otherwise
apparent from the context.
[0064] All of the compositions and/or methods disclosed and claimed
herein can be made and executed without undue experimentation in
light of the present disclosure. While the compositions and methods
of this invention have been described in terms of preferred
embodiments, it may be apparent to those of skill in the art that
variations may be applied to the compositions and/or methods and in
the steps or in the sequence of steps of the method described
herein without departing from the concept, spirit and scope of the
invention. All such similar substitutes and modifications apparent
to those skilled in the art are deemed to be within the spirit,
scope and concept of the invention as defined by the appended
claims.
* * * * *