U.S. patent application number 15/077110 was filed with the patent office on 2016-08-04 for fungicidal compositions.
This patent application is currently assigned to Syngenta Participations AG. The applicant listed for this patent is Syngenta Participations AG. Invention is credited to Renaud BEAUDEGNIES, Ulrich Johannes HAAS, Dietrich HERMANN, Thomas James HOFFMAN, Olivier JACOB, Long LU, Qiang LU, Kurt NEBEL, Gabriel Didier SCALLIET, Jianzhong YANG, Werner ZAMBACH.
Application Number | 20160219879 15/077110 |
Document ID | / |
Family ID | 51228833 |
Filed Date | 2016-08-04 |
United States Patent
Application |
20160219879 |
Kind Code |
A1 |
HAAS; Ulrich Johannes ; et
al. |
August 4, 2016 |
FUNGICIDAL COMPOSITIONS
Abstract
The present invention provides a composition comprising a
combination of components A) and B), wherein component A) is a
compound of formula (I) ##STR00001## and the component (B) is a
further fungicide, insecticide or herbicide.
Inventors: |
HAAS; Ulrich Johannes;
(Stein, CH) ; HERMANN; Dietrich; (Stein, CH)
; SCALLIET; Gabriel Didier; (Stein, CH) ; NEBEL;
Kurt; (Stein, CH) ; LU; Long; (Shanghai,
CN) ; LU; Qiang; (Shanghai, CN) ; YANG;
Jianzhong; (Shanghai, CN) ; HOFFMAN; Thomas
James; (Stein, CH) ; BEAUDEGNIES; Renaud;
(Stein, CH) ; ZAMBACH; Werner; (Stein, CH)
; JACOB; Olivier; (Stein, CH) |
|
Applicant: |
Name |
City |
State |
Country |
Type |
Syngenta Participations AG |
Basel |
|
CH |
|
|
Assignee: |
Syngenta Participations AG
Basel
CH
|
Family ID: |
51228833 |
Appl. No.: |
15/077110 |
Filed: |
March 22, 2016 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
|
|
14362709 |
Jun 4, 2014 |
9326513 |
|
|
PCT/CN2012/073665 |
Apr 9, 2012 |
|
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15077110 |
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Current U.S.
Class: |
1/1 |
Current CPC
Class: |
C07D 407/12 20130101;
A01N 55/00 20130101; A01N 43/56 20130101; A01N 43/80 20130101; Y02P
60/21 20151101; A01N 47/42 20130101; A01N 53/00 20130101; A01N
37/10 20130101; A01N 43/54 20130101; A01N 37/38 20130101; C07D
405/12 20130101; C07D 409/04 20130101; A01N 41/10 20130101; A01N
43/82 20130101; A01N 57/20 20130101; C07D 409/12 20130101; A01N
47/40 20130101; A01N 43/52 20130101; A01N 35/06 20130101; A01N
43/84 20130101; A01N 43/88 20130101; A01N 43/38 20130101; A01N
43/40 20130101; C07D 213/74 20130101; A01N 37/18 20130101; C07D
413/12 20130101; A01N 43/653 20130101; A01N 43/22 20130101; A01N
37/34 20130101; C07D 417/12 20130101; C07F 7/0812 20130101; C07F
7/0814 20130101; C07C 59/08 20130101; A01N 59/16 20130101; A01N
59/20 20130101; A01N 43/36 20130101; A01N 43/42 20130101; A01N
43/40 20130101; A01N 37/36 20130101; A01N 37/42 20130101; A01N
39/04 20130101; A01N 41/10 20130101; A01N 43/36 20130101; A01N
43/40 20130101; A01N 43/54 20130101; A01N 43/56 20130101; A01N
43/653 20130101; A01N 43/84 20130101; A01N 43/90 20130101; A01N
45/02 20130101; A01N 47/18 20130101; A01N 47/24 20130101; A01N
47/38 20130101; A01N 47/40 20130101; A01N 51/00 20130101; A01N
57/20 20130101; A01N 59/16 20130101; A01N 59/20 20130101; A01N
2300/00 20130101; A01N 47/42 20130101; A01N 37/36 20130101; A01N
37/42 20130101; A01N 39/04 20130101; A01N 41/10 20130101; A01N
43/36 20130101; A01N 43/40 20130101; A01N 43/54 20130101; A01N
43/56 20130101; A01N 43/653 20130101; A01N 43/84 20130101; A01N
43/90 20130101; A01N 45/02 20130101; A01N 47/18 20130101; A01N
47/24 20130101; A01N 47/38 20130101; A01N 47/40 20130101; A01N
51/00 20130101; A01N 57/20 20130101; A01N 59/16 20130101; A01N
59/20 20130101; A01N 2300/00 20130101 |
International
Class: |
A01N 43/40 20060101
A01N043/40; C07F 7/08 20060101 C07F007/08; A01N 55/00 20060101
A01N055/00; C07D 405/12 20060101 C07D405/12; C07D 407/12 20060101
C07D407/12; C07D 413/12 20060101 C07D413/12; A01N 43/80 20060101
A01N043/80; A01N 43/52 20060101 A01N043/52; C07D 417/12 20060101
C07D417/12; C07D 409/12 20060101 C07D409/12; A01N 43/42 20060101
A01N043/42; C07C 59/08 20060101 C07C059/08; C07D 409/04 20060101
C07D409/04; A01N 43/653 20060101 A01N043/653; A01N 53/00 20060101
A01N053/00; A01N 35/06 20060101 A01N035/06; A01N 37/38 20060101
A01N037/38; A01N 43/54 20060101 A01N043/54; A01N 43/56 20060101
A01N043/56; A01N 37/34 20060101 A01N037/34; A01N 59/20 20060101
A01N059/20; C07D 213/74 20060101 C07D213/74 |
Foreign Application Data
Date |
Code |
Application Number |
Dec 14, 2011 |
CN |
PCT/CN2011/084016 |
Claims
1. A compound of formula (I) ##STR03048## wherein R.sub.1 and
R.sub.2 are each independently selected from hydrogen and
C.sub.1-C.sub.4 alkyl; or R.sub.1 and R.sub.2 together with the
nitrogen atom to which they are connected form pyrrolidine or
piperidine; R.sub.3 represents hydrogen, halogen, cyano,
C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 haloalkyl, C.sub.2-C.sub.4
alkenyl, C.sub.2-C.sub.4 alkynyl, C.sub.1-C.sub.4 alkoxy,
C.sub.3-C.sub.6 cycloalkyl, amino, C.sub.1-C.sub.2 alkylamino,
di(C.sub.1-C.sub.6alkyl)amino, pyrrolidino, imidazolino,
triazolino, formyl, phenyl, C.sub.2-C.sub.4 alkylcarbonyl,
C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6 alkylsulfinyl,
C.sub.1-C.sub.6 alkylsulfonyl or C.sub.1-C.sub.6 hydroxyalkyl;
R.sub.4 is selected from fluorine, chlorine, bromine,
C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 alkenyl, C.sub.1-C.sub.4
haloalkyl, C.sub.1-C.sub.4 alkoxy and C.sub.3-C.sub.6 cycloalkyl;
R.sub.5 is selected from G.sup.5, G.sup.6-G.sup.7 and
G.sup.10-G.sup.11; G.sup.5 is C.sub.3-C.sub.7 cycloalkyl, which is
substituted by one or more groups independently selected from
ethyl, n-propyl, iso-propyl, n-butyl, iso-butyl, sec-butyl,
tert-butyl, n-pentyl, --CH(CH.sub.3)--CH.sub.2--CH.sub.2--CH.sub.3,
--CH--CH(CH.sub.3)--CH.sub.2--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3)--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3).sub.2,
--CH(CH.sub.3)--CH(CH.sub.3).sub.2, C.sub.2-C.sub.6 haloalkyl,
C.sub.1-C.sub.6 alkoxy, C.sub.3-C.sub.4-alkenyloxy, phenoxy and
C.sub.1-C.sub.6 alkylthio; G.sup.6 is phenyl, which must be
substituted by at least one fluorine and is optionally further
substituted by one or more groups independently selected from
halogen, CN, C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6 haloalkyl,
C.sub.3-C.sub.6 cycloalkyl, C.sub.2-C.sub.6 alkenyl,
C.sub.2-C.sub.6 alkynyl, C.sub.1-C.sub.6 alkoxy, C.sub.3-C.sub.6
alkenyloxy, C.sub.3-C.sub.6 alkynyloxy and C.sub.1-C.sub.6
alkylthio; G.sup.7 is methylene; G.sup.10 is phenyl, which is
optionally substituted by one or more groups independently selected
from halogen, CN, OH, SH, CHO, C.sub.1-C.sub.6 alkyl,
C.sub.1-C.sub.6 haloalkyl, C.sub.3-C.sub.6 cycloalkyl,
C.sub.2-C.sub.6 alkenyl, C.sub.2-C.sub.6 haloalkenyl,
C.sub.2-C.sub.6 alkynyl, C.sub.1-C.sub.6 alkoxy, C.sub.1-C.sub.6
haloalkoxy, C.sub.3-C.sub.6 alkenyloxy, C.sub.3-C.sub.6 alkynyloxy,
C.sub.3-C.sub.6 cycloalkoxy, phenyl, C.sub.1-C.sub.6 alkylthio,
C.sub.1-C.sub.6 alkylsulfinyl and C.sub.1-C.sub.6 alkylsulfonyl.
G.sup.11 is methylene substituted by at least one group
independently selected from C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4
haloalkyl, CN, C.sub.1-C.sub.4 alkoxy and C.sub.1-C.sub.4
haloalkoxy; R.sub.6 is hydrogen; R.sub.7 is selected from hydrogen
and C.sub.1-C.sub.4 alkyl; or an agronomically acceptable salt,
metallic complex, metalloidic complex, isomer, structural isomer,
stereo-isomer, diastereoisomer, enantiomer, tautomer, or N-oxide
thereof.
2. A compound of formula (I) according to claim 1 wherein R.sub.1
and R.sub.2 are each C.sub.1-C.sub.4 alkyl; R.sub.3 represents
hydrogen, halogen, cyano, C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4
haloalkyl, C.sub.2-C.sub.4 alkenyl, C.sub.2-C.sub.4 alkynyl,
C.sub.1-C.sub.4 alkoxy, C.sub.3-C.sub.6 cycloalkyl, C.sub.1-C.sub.4
alkylthio, C.sub.1-C.sub.4 alkylsulfinyl or C.sub.1-C.sub.4
alkylsulfonyl; R.sub.4 is selected from methyl, ethyl, methoxy,
fluorine and chlorine; R.sub.6 is hydrogen; R.sub.7 is hydrogen or
C.sub.1-C.sub.4 alkyl.
3. A compound of formula (I) according to claim 1 wherein R.sub.1
and R.sub.2 are each independently selected from methyl, ethyl and
isopropyl; R.sub.3 represents hydrogen, halogen, C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 haloalkyl, cyclopropyl, ethynyl or
C.sub.1-C.sub.4 alkoxy; R.sub.4 is selected from methyl, methoxy,
fluorine and chlorine; R.sub.6 is hydrogen; R.sub.7 is
hydrogen.
4. A compound of formula (I) according to claim 1 wherein R.sub.1
is methyl; R.sub.2 is ethyl; R.sub.3 is selected from hydrogen,
bromine, iodine, methyl, CHF.sub.2, cyclopropyl, ethynyl and
methoxy; R.sub.4 is methyl; R.sub.6 is hydrogen; R.sub.7 is
hydrogen.
5. A compound of formula (I) according to claim 1 wherein R.sub.5
is G.sup.5; and G.sup.5 is C.sub.6 cycloalkyl, which is substituted
by one or more groups independently selected from ethyl, n-propyl,
iso-propyl, n-butyl, iso-butyl, sec-butyl, tert-butyl, n-pentyl,
--CH(CH.sub.3)--CH.sub.2--CH.sub.2--CH.sub.3,
--CH--CH(CH.sub.3)--CH.sub.2--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3)--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3).sub.2 and
--CH(CH.sub.3)--CH(CH.sub.3).sub.2.
6. A compound according to claim 1 wherein R.sub.5 is
G.sup.6-G.sup.7; G.sup.6 is phenyl, which must be substituted by at
least one fluorine and is optionally further substituted by one or
more halogen, CHF.sub.2, CF.sub.3 and C.sub.1-C.sub.4 alkyl; and
G.sup.7 is methylene.
7. A compound according to claim 1 wherein R.sub.5 is
G.sup.10-G.sup.11; G.sup.10 is phenyl, which is optionally
substituted by one or more groups independently selected from
halogen, CN, methyl, ethyl, n-propyl, iso-propyl, methoxy,
CHF.sub.2, CF.sub.3 and OCHF.sub.2 and G.sup.11 is methylene
substituted by at least one group independently selected from
methyl, CF.sub.3 and ethyl.
8. A compound according to claim 1 wherein R.sub.1 is methyl;
R.sub.2 is ethyl; R.sub.3 is selected from hydrogen, bromine,
iodine, methyl, CHF.sub.2, cyclopropyl, ethynyl and methoxy;
R.sub.4 is methyl; R.sub.5 is selected from G.sup.5,
G.sup.6-G.sup.7 and G.sup.10-G.sup.11; G.sup.5 is C.sub.6
cycloalkyl, which is substituted by one or more groups
independently selected from ethyl, n-propyl, iso-propyl, n-butyl,
iso-butyl, sec-butyl, tert-butyl, n-pentyl,
--CH(CH.sub.3)--CH.sub.2--CH.sub.2--CH.sub.3,
--CH--CH(CH.sub.3)--CH.sub.2--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3)--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3).sub.2 and
--CH(CH.sub.3)--CH(CH.sub.3).sub.2; G.sup.6 is phenyl, which must
be substituted by at least one fluorine and is optionally further
substituted by one or more halogen, CHF.sub.2, CF.sub.3 and
C.sub.1-C.sub.4 alkyl; G.sup.7 is methylene; G.sup.10 is phenyl,
which is optionally substituted by one or more groups independently
selected from halogen, CN, methyl, ethyl, n-propyl, iso-propyl,
methoxy, CHF.sub.2, CF.sub.3 and OCHF.sub.2; G.sup.11 is methylene
substituted by at least one group independently selected from
methyl, CF.sub.3 and ethyl; R.sub.6 is hydrogen; and R.sub.7 is
hydrogen; and agronomically acceptable salts/metallic
complexes/metalloidic complexes/isomers/structural
isomers/stereo-isomers/diastereoisomers/enantiomers/tautomers/N-oxides
of those compounds.
9. A fungicidal composition comprising a compound of formula (I)
according to any one of claims 1 to 8, an inert carrier and,
optionally, an adjuvant.
10. A fungicidal composition, comprising a combination of
components A) and B), wherein component A) is a compound of formula
(I) as defined in any of claims 1 to 8, and agronomically
acceptable salts/metallic complexes/metalloidic
complexes/isomers/structural
isomers/stereo-isomers/diastereoisomers/enantiomers/tautomers/N-oxides
of those compounds, and component B) is a strobilurin fungicide, a
sterol biosynthesis inhibitor, a triazole fungicide, a pro-triazole
fungicide, a DMI fungicide, a SDHI fungicide, or a compound
selected from the group consisting of Chlorothalonil, Fludioxonil,
Cyprodinil, Mandipropamid, Fluazinam, Procymedone, Carbendazim,
Abamectin, Clothianidin, Emamectin benzoate, Imidacloprid,
Tefluthrin, Mefenoxam, Orocymedone, Thiamethoxam,
Lambda-cyhalothrin, Gamma-cyhalothrin, Profenofos, Lufenuron,
Diflubenzuron, Cypermethrin, Novaluron, Bifenthrin, Methomyl,
Chlopyrifos, Methamidophos, Endosulfan, Betacyfluthrin,
Triflumuron, Teflubenzuron, SulcotrioneAcephat, Glyphosate,
Glufosinate, Mesotrione, Tembotrione, Sulcotrione, Auxins,
Trinexapac-ethyl, Prohexadione-Ca, Paclobutrazol,
Acibenzolar-S-methyl, Methyl-Jasmonate, Cis-Jasmone, Manganese,
Cyflufenamid, Tebufloquin and Copper.
11. A method of controlling phytopathogenic diseases on useful
plants or on propagation material thereof, which comprises applying
to the useful plants, the locus thereof or propagation material
thereof a compound of formula (I) according to any one of claims 1
to 8 or a fungicidal composition according to claim 9 or claim
10.
12. A method of protecting natural substances of plant origin,
which have been taken from their natural life cycle, and/or their
processed forms, which comprises applying to said natural
substances of plant origin or their processed forms a compound of
formula (I) according to any one of claims 1 to 8 or a fungicidal
composition according to claim 9 or claim 10.
Description
RELATED APPLICATION INFORMATION
[0001] This application is a divisional of U.S. patent application
Ser. No. 14/362,709 filed on 4 Jun. 2014, which is a 371 of
International Application No. PCT/CN2012/073665, filed 9 Apr. 2012,
which claims priority to International Application No.
PCT/CN2011/084016, filed 14 Dec. 2011, the contents of which are
incorporated herein by reference.
[0002] The present invention relates to novel fungicidal
compositions which comprise fungicidally active pyridylamidine
compounds for the treatment of phytopathogenic diseases of useful
plants, especially phytopathogenic fungi, and to a method of
controlling phytopathogenic diseases on useful plants.
[0003] Certain phenylamidine derivatives are described in
WO2008/101682 as microbicidally active ingredients in
pesticides.
[0004] The present invention provides a composition comprising a
combination of components A) and B), wherein component A) is a
compound of formula (I)
##STR00002## [0005] wherein [0006] R.sub.1 and R.sub.2 are each
independently selected from hydrogen, C.sub.1-C.sub.4 alkyl,
C.sub.3-C.sub.4 alkenyl, C.sub.3-C.sub.4 alkynyl,
(R.sub.10)carbonyl and (R.sub.10)oxycarbonyl; [0007] or R.sub.1 and
R.sub.2 together with the nitrogen atom to which they are attached
form a 5- or 6 membered cyclic group which may be saturated or
unsaturated and may contain a further heteroatom selected from S or
O;
[0008] R.sub.3 represents hydrogen, halogen, cyano, nitro,
mercapto, hydroxy, --C(.dbd.S)NH.sub.2, --SF.sub.5, C.sub.1-C.sub.6
alkyl, C.sub.1-C.sub.6 haloalkyl, C.sub.2-C.sub.6 alkenyl,
C.sub.2-C.sub.6 haloalkenyl, C.sub.2-C.sub.6 alkynyl,
C.sub.2-C.sub.6 haloalkynyl, C.sub.1-C.sub.6 alkoxy,
C.sub.1-C.sub.6 haloalkoxy, C.sub.3-C.sub.6 cycloalkyl, amino,
C.sub.1-C.sub.2 alkylamino, di(C.sub.1-C.sub.6 alkyl)amino, a
5-membered heterocycle containing 1-4 nitrogen atoms, piperidino,
morpholino, thiomorpholino, formyl, hydroxycarbonyl,
C.sub.2-C.sub.7 alkoxycarbonyl, C.sub.2-C.sub.7 haloalkoxycarbonyl,
C.sub.4-C.sub.7 alkenyloxycarbonyl, C.sub.4-C.sub.7
haloalkenyloxycarbonyl, C.sub.2-C.sub.7 alkylcarbonyl,
C.sub.2-C.sub.7 haloalkylcarbonyl, C.sub.1-C.sub.6 alkylthio,
C.sub.1-C.sub.6 alkylsulfinyl, C.sub.1-C.sub.6 alkylsulfonyl,
C.sub.1-C.sub.6 haloalkylthio, C.sub.1-C.sub.6 haloalkylsulfinyl,
C.sub.1-C.sub.6 haloalkylsulfonyl, C.sub.1-C.sub.6 hydroxyalkyl,
phenyl or benzyl wherein the phenyl and benzyl are optionally
substituted by one or more groups independently selected from the
group consisting of halogen, cyano, hydroxy, mercapto, amino,
C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6 haloalkyl, C.sub.1-C.sub.6
alkoxy, C.sub.1-C.sub.6 haloalkoxy, C.sub.1-C.sub.6 alkylthio,
C.sub.1-C.sub.6 alkylsulfinyl and C.sub.1-C.sub.6
alkylsulfonyl;
[0009] R.sub.4 represents hydrogen, halogen, cyano, amino,
C.sub.1-C.sub.4alkyl, C.sub.1-C.sub.4 haloalkyl, C.sub.3-C.sub.6
cycloalkyl, C.sub.2-C.sub.4 alkenyl, C.sub.2-C.sub.4 alkynyl,
C.sub.1-C.sub.4 alkoxy, C.sub.1-C.sub.4 haloalkoxy, C.sub.1-C.sub.4
alkylthio, C.sub.1-C.sub.4 alkylsulfinyl, C.sub.1-C.sub.4
alkylsulfonyl, methylamino and dimethylamino;
[0010] R.sub.5 is hydrogen, C.sub.1-C.sub.12alkyl,
C.sub.3-C.sub.12alkenyl, C.sub.3-C.sub.12alkynyl,
C.sub.1-C.sub.12alkylsulfonyl, C.sub.2-C.sub.12alkenylsulfonyl,
phenylsulfonyl or benzylsulfonyl, or is C.sub.1-C.sub.12alkyl,
C.sub.2-C.sub.12alkenyl, C.sub.2-C.sub.12alkynyl,
C.sub.1-C.sub.12alkylsulfonyl, C.sub.2-C.sub.12alkenylsulfonyl,
phenylsulfonyl or benzylsulfonyl mono- to polysubstituted by
substituents independently selected from the group consisting of
halogen, cyano, nitro, hydroxy, mercapto, azido, formyl,
C.sub.2-C.sub.7alkylcarbonyl, C.sub.2-C.sub.7haloalkylcarbonyl,
C.sub.1-C.sub.6alkyl, C.sub.1-C.sub.6haloalkyl,
C.sub.1-C.sub.6alkoxy, C.sub.1-C.sub.6haloalkoxy,
C.sub.1-C.sub.6alkylthio, C.sub.1-C.sub.6alkylsulfinyl and
C.sub.1-C.sub.6alkylsulfonyl; or
[0011] R.sub.5 is formyl, C.sub.2-C.sub.12 alkylcarbonyl,
C.sub.3-C.sub.12 alkenylcarbonyl, C.sub.3-C.sub.12 alkynylcarbonyl,
C.sub.4-C.sub.12 cycloalkylcarbonyl, benzylcarbonyl,
phenylcarbonyl, C.sub.2-C.sub.12 alkoxycarbonyl, C.sub.4-C.sub.12
alkenyloxycarbonyl, C.sub.4-C.sub.12 alkynyloxycarbonyl,
C.sub.4-C.sub.12 cycloalkoxycarbonyl, benzyloxycarbonyl or
phenoxycarbonyl, or is C.sub.2-C.sub.12 alkylcarbonyl,
C.sub.3-C.sub.12 alkenylcarbonyl, C.sub.3-C.sub.12 alkynylcarbonyl,
C.sub.4-C.sub.12 cycloalkylcarbonyl, benzylcarbonyl,
phenylcarbonyl, C.sub.2-C.sub.12 alkoxycarbonyl, C.sub.4-C.sub.12
alkenyloxycarbonyl, C.sub.4-C.sub.12 alkynyloxycarbonyl,
C.sub.4-C.sub.12 cycloalkoxycarbonyl, benzyloxycarbonyl or
phenoxycarbonyl mono- to polysubstituted by substituents
independently selected from the group consisting of halogen, cyano,
C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6 haloalkyl and
C.sub.1-C.sub.6 alkoxy; or
[0012] R.sub.5 is (R.sub.51)(R.sub.52)(R.sub.53)Si--,
(R.sub.51)(R.sub.52)(R.sub.53)Si--(C.sub.1-C.sub.12alkyl)-,
(R.sub.51)(R.sub.52)(R.sub.53)Si--(C.sub.3-C.sub.8cycloalkyl)-,
(R.sub.54O)(R.sub.55O)(R.sub.56O)Si--,
(R.sub.54O)(R.sub.55O)(R.sub.56O)Si--(C.sub.1-C.sub.12alkyl)- or
(R.sub.54O)(R.sub.55O)(R.sub.56O)Si--(C.sub.3-C.sub.8cycloalkyl)-;
or
[0013] R.sub.5 is C.sub.1-C.sub.6alkyl-B--C.sub.1-C.sub.12alkyl-,
C.sub.2-C.sub.6alkenyl-B--C.sub.1-C.sub.12alkyl-,
C.sub.2-C.sub.6alkynyl-B--C.sub.1-C.sub.12alkyl-,
C.sub.3-C.sub.8cycloalkyl-B--C.sub.1-C.sub.12alkyl-,
benzyl-B--C.sub.1-C.sub.12alkyl-, phenyl-B--C.sub.1-C.sub.12alkyl-,
C.sub.1-C.sub.6alkyl-B--C.sub.2-C.sub.12alkenyl-,
C.sub.2-C.sub.6alkenyl-B--C.sub.2-C.sub.12alkenyl-,
C.sub.2-C.sub.6alkynyl-B--C.sub.2-C.sub.12alkenyl-,
C.sub.3-C.sub.8cycloalkyl-B--C.sub.2-C.sub.12alkenyl-,
benzyl-B--C.sub.2-C.sub.12alkenyl-,
phenyl-B--C.sub.2-C.sub.12alkenyl-,
C.sub.1-C.sub.6alkyl-B--C.sub.2-C.sub.12alkynyl-,
C.sub.2-C.sub.6alkenyl-B--C.sub.2-C.sub.12alkynyl-,
C.sub.2-C.sub.6alkynyl-B--C.sub.2-C.sub.12alkynyl-,
C.sub.3-C.sub.8cycloalkyl-B--C.sub.2-C.sub.12alkynyl-,
benzyl-B--C.sub.2-C.sub.12alkynyl-,
phenyl-B--C.sub.2-C.sub.12alkynyl-,
C.sub.1-C.sub.6alkyl-B--C.sub.3-C.sub.8cycloalkyl-,
C.sub.2-C.sub.6alkenyl-B--C.sub.3-C.sub.8cycloalkyl-,
C.sub.2-C.sub.6alkynyl-B--C.sub.3-C.sub.8cycloalkyl-,
C.sub.3-C.sub.8cycloalkyl-B--C.sub.3-C.sub.8cycloalkyl-,
benzyl-B--C.sub.3-C.sub.12cycloalkyl- or
phenyl-B--C.sub.3-C.sub.12cycloalkyl-, wherein the group B is
selected from --C(.dbd.O)--, --C(.dbd.S)--, --C(.dbd.NOR.sub.59)--,
--C(R.sub.60).dbd.NO--, --ON.dbd.C(R.sub.60)--, --O--C(.dbd.O)--,
--C(.dbd.O)--O--, --O--, --S--, --S(.dbd.O)--, --S(.dbd.O)2-,
--S(.dbd.O)(.dbd.NR.sub.13)--, --S(.dbd.O)(R.sub.14).dbd.N--,
--N.dbd.S(.dbd.O)(R.sub.14)--, --N(R.sub.62)--C.dbd.O)--,
--C.dbd.O)--N(R.sub.62)--, --N(R.sub.62)--SO.sub.2-- or
--SO.sub.2--N(R.sub.62)--; or
[0014] R.sub.5 is C.sub.1-C.sub.6alkyl-B--C.sub.1-C.sub.12alkyl-,
C.sub.2-C.sub.6alkenyl-B--C.sub.1-C.sub.12alkyl-,
C.sub.2-C.sub.6alkynyl-B--C.sub.1-C.sub.12alkyl-,
C.sub.3-C.sub.8cycloalkyl-B--C.sub.1-C.sub.12alkyl-,
benzyl-B--C.sub.1-C.sub.12alkyl-, phenyl-B--C.sub.1-C.sub.12alkyl-,
C.sub.1-C.sub.6alkyl-B--C.sub.2-C.sub.12alkenyl-,
C.sub.2-C.sub.6alkenyl-B--C.sub.2-C.sub.12alkenyl-,
C.sub.2-C.sub.6alkynyl-B--C.sub.2-C.sub.12alkenyl-,
C.sub.3-C.sub.8cycloalkyl-B--C.sub.2-C.sub.12alkenyl-,
benzyl-B--C.sub.2-C.sub.12alkenyl-,
phenyl-B--C.sub.2-C.sub.12alkenyl-,
C.sub.1-C.sub.6alkyl-B--C.sub.2-C.sub.12alkynyl-,
C.sub.2-C.sub.6alkenyl-B--C.sub.2-C.sub.12alkynyl-,
C.sub.2-C.sub.6alkynyl-B--C.sub.2-C.sub.12alkynyl-,
C.sub.3-C.sub.8cycloalkyl-B--C.sub.2-C.sub.12alkynyl-,
benzyl-B--C.sub.2-C.sub.12alkynyl-,
phenyl-B--C.sub.2-C.sub.12alkynyl-,
C.sub.1-C.sub.6alkyl-B--C.sub.3-C.sub.5cycloalkyl-,
C.sub.2-C.sub.6alkenyl-B--C.sub.3-C.sub.8cycloalkyl-,
C.sub.2-C.sub.6alkynyl-B--C.sub.3-C.sub.8cycloalkyl-,
C.sub.3-C.sub.8cycloalkyl-B--C.sub.3-C.sub.8cycloalkyl-,
benzyl-B--C.sub.3-C.sub.12cycloalkyl-,
phenyl-B--C.sub.3-C.sub.12cycloalkyl-, all of which, in turn, are
mono- to poly-substituted by substituents independently selected
from the group consisting of halogen, cyano, hydroxy, mercapto,
C.sub.1-C.sub.6 haloalkyl, C.sub.1-C.sub.6 alkoxy, formyl,
C.sub.2-C.sub.6 alkylcarbonyl, C.sub.1-C.sub.6 alkylthio,
C.sub.1-C.sub.6 alkylsulfinyl and C.sub.1-C.sub.6 alkylsulfonyl;
or
[0015] R.sub.5 is A-, A-(C.sub.1-C.sub.6alkyl)-,
A-O--(C.sub.1-C.sub.6alkyl)-, A-(C.sub.3-C.sub.6alkenyl)-,
A-O--(C.sub.4-C.sub.6alkenyl)-, A-(C.sub.3-C.sub.6-alkynyl)-,
A-O--(C.sub.4-C.sub.6alkynyl)-, A-(C.sub.3-C.sub.8cycloalkyl)- or
A-O--(C.sub.3-C.sub.8cycloalkyl)-;
[0016] wherein A is a three- to ten-membered monocyclic or fused
bicyclic ring system which can be aromatic, partially saturated or
fully saturated and can contain 1 to 4 hetero atoms selected from
the group consisting of nitrogen, oxygen and sulphur, it not being
possible for each ring system to contain --O--O--, --S--S-- and
--O--S-- fragments, and it being possible for the three- to
ten-membered ring system to be itself mono- or polysubstituted
[0017] A1) by substituents independently selected from the group
consisting of
[0018] halogen, cyano, nitro, hydroxy, mercapto, azido, formyl,
carboxy, .dbd.O, .dbd.S, C.sub.1-C.sub.6alkyl, C.sub.2-C.sub.6
alkenyl, C.sub.2-C.sub.6 alkynyl, C.sub.3-C.sub.8 cycloalkyl,
C.sub.1-C.sub.6 haloalkyl, C.sub.2-C.sub.6 haloalkenyl,
C.sub.2-C.sub.6 haloalkynyl, C.sub.3-C.sub.8 halocycloalkyl,
C.sub.1-C.sub.6 alkoxy, C.sub.1-C.sub.6 haloalkoxy, C.sub.3-C.sub.6
alkenyloxy, C.sub.3-C.sub.6 haloalkenyloxy, C.sub.3-C.sub.6
alkynyloxy, C.sub.3-C.sub.8 cycloalkyloxy, benzyl, benzyloxy,
phenyl and phenoxy, where the benzyl, benzyloxy, phenyl and
phenoxy, in turn, may be mono- to polysubstituted by substituents
independently selected from the group consisting of halogen, cyano,
nitro, hydroxy, mercapto, amino, C.sub.1-C.sub.6 alkyl,
C.sub.1-C.sub.6 haloalkyl, C.sub.1-C.sub.6 alkoxy, C.sub.1-C.sub.6
haloalkoxy, C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6
alkylsulfinyl and C.sub.1-C.sub.6 alkylsulfonyl; or
[0019] A2) by substituents independently selected form the group
consisting of
[0020] (R.sub.14)S(.dbd.O)(.dbd.NR.sub.13)--,
(R.sub.14)(R.sub.15)S(.dbd.O).dbd.N--;
--Si(R.sub.51)(R.sub.52)(R.sub.53), --NR.sub.57R.sub.58,
--C(.dbd.O)NR.sub.57R.sub.58, --C(.dbd.S)NR.sub.57R.sub.58,
HC(.dbd.NOR.sub.59)--, (C.sub.1-C.sub.6alkyl)C(.dbd.NOR.sub.59)--,
(C.sub.1-C.sub.6haloalkyl)C(.dbd.NOR.sub.59)--,
(C.sub.1-C.sub.6alkyl)C(.dbd.NOR.sub.59)C.sub.1-C.sub.6alkyl-,
(C.sub.1-C.sub.6haloalkyl)C(.dbd.NOR.sub.59)C.sub.1-C.sub.6alkyl-,
N(C.sub.1-C.sub.6alkyl)aminosulfonyl and
N,N-di(C.sub.1-C.sub.6alkyl)aminosulfonyl; or
[0021] A3) by substituents independently selected from the group
consisting of
[0022] formyl, C.sub.2-C.sub.7 alkylcarbonyl, C.sub.2-C.sub.7
haloalkylcarbonyl, C.sub.3-C.sub.7 alkenylcarbonyl, C.sub.3-C.sub.7
haloalkenylcarbonyl, C.sub.4-C.sub.9 cycloalkylcarbonyl,
C.sub.4-C.sub.9 halocycloalkylcarbonyl, C.sub.2-C.sub.7
alkoxycarbonyl, C.sub.2-C.sub.7 haloalkoxycarbonyl, C.sub.3-C.sub.7
alkenyloxycarbonyl, C.sub.3-C.sub.7 alkynyloxycarbonyl,
C.sub.4-C.sub.9 cycloalkoxycarbonyl, C.sub.2-C.sub.7
alkylthiocarbonyl and benzyloxycarbonyl, and benzyloxycarbonyl
mono- to polysubstituted by substituents independently selected
from the group consisting of halogen, cyano, hydroxy,
C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6 haloalkyl and
C.sub.1-C.sub.6 alkoxy; or
[0023] A4) by substituents independently selected from the group
consisting of hydroxyl, C.sub.1-C.sub.4 alkyl, C.sub.2-C.sub.4
alkenyl, C.sub.2-C.sub.4 alkynyl, C.sub.1-C.sub.4 alkoxy, halogen,
C.sub.1-C.sub.4 haloalkyl, C.sub.2-C.sub.4 haloalkenyl, cyano,
benzyl, phenyl, .dbd.C(R.sup.36').sub.2, .dbd.N--OH,
.dbd.N--O--C.sub.1-C.sub.4-alkyl, .dbd.N--O--C.sub.3-C.sub.4
alkenyl, .dbd.N--O--C.sub.3-C.sub.4 alkynyl,
.dbd.N--O--C.sub.1-C.sub.4 haloalkyl, .dbd.N--O--C.sub.3-C.sub.4
haloalkenyl, .dbd.N--O-benzyl and .dbd.N--O-phenyl, wherein the
.dbd.N--O-benzyl and .dbd.N--O-phenyl are optionally substituted by
one or more group selected from the group consisting of halogen,
methyl, halomethyl; or
[0024] R.sub.5 is --N.dbd.C(R.sub.8)(R.sub.9); or
[0025] R.sub.5 is a C.sub.8-C.sub.11 spirobicyclic system
containing 0, 1 or 2 O or N atoms, wherein there are no adjacent O
atoms, which is optionally substituted by one or more groups
independently selected from halogen, CN, NO.sub.2, OH, SH, CHO,
COOH, tri(C.sub.1-C.sub.6-alkyl)silyl, C.sub.1-C.sub.6 alkyl,
--CH(CH.sub.3)--CH.sub.2--CH.sub.2--CH.sub.3,
--CH--CH(CH.sub.3)--CH.sub.2--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3)--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3).sub.2,
--CH(CH.sub.3)--CH(CH.sub.3).sub.2, C.sub.1-C.sub.6 haloalkyl,
C.sub.3-C.sub.6 cycloalkyl, C.sub.3-C.sub.6 halocycloalkyl,
C.sub.2-C.sub.6 alkenyl, C.sub.2-C.sub.6 haloalkenyl,
C.sub.1-C.sub.6 alkoxy, C.sub.1-C.sub.6 haloalkoxy,
C.sub.2-C.sub.7-alkylcarbonyl, C.sub.2-C.sub.7-alkoxycarbonyl,
C.sub.4-C.sub.7-alkenyloxycarbonyl,
C.sub.4-C.sub.7-alkynyloxycarbonyl, C.sub.1-C.sub.6 alkylthio,
C.sub.1-C.sub.6 alkylsulfinyl, C.sub.1-C.sub.6 alkylsulfonyl,
.dbd.O, --C(.dbd.O)NH.sub.2, --C(.dbd.O)NH(CH.sub.3),
--C(.dbd.O)N(CH.sub.3).sub.2 and --C(.dbd.S)NH.sub.2;
[0026] R.sub.6 is selected from hydrogen and SH;
[0027] R.sub.7 is hydrogen, halogen or C.sub.1-C.sub.4 alkyl;
[0028] R.sub.8 and R.sub.9, independently from each other, are
hydrogen, halogen, cyano, C.sub.1-C.sub.12 alkyl, C.sub.2-C.sub.12
alkenyl, C.sub.2-C.sub.12 alkynyl, C.sub.1-C.sub.12 alkoxy, formyl,
C.sub.2-C.sub.12 alkylcarbonyl, C.sub.3-C.sub.12 alkenylcarbonyl,
carboxy, C.sub.2-C.sub.12 alkoxycarbonyl and C.sub.4-C.sub.12
alkenyloxycarbonyl, or C.sub.1-C.sub.12 alkyl, C.sub.2-C.sub.12
alkenyl, C.sub.2-C.sub.12 alkynyl, C.sub.1-C.sub.12 alkoxy,
C.sub.2-C.sub.12 alkylcarbonyl, C.sub.3-C.sub.12 alkenylcarbonyl,
C.sub.2-C.sub.12 alkoxycarbonyl and C.sub.4-C.sub.12
alkenyloxycarbonyl mono- to polysubstituted by substituents
independently selected from the group consisting of halogen, cyano,
nitro, hydroxy, mercapto, C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6
haloalkyl, C.sub.1-C.sub.6 alkoxy, C.sub.1-C.sub.6 haloalkoxy,
C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6 alkylsulfinyl and
C.sub.1-C.sub.6 alkylsulfonyl; or R.sub.8 and R.sub.9 together from
a C.sub.2-C.sub.8 alkylene bridge which may optionally be mono- to
polysubstituted by substituents independently selected from the
group consisting of halogen, cyano, C.sub.1-C.sub.6 alkyl and
C.sub.1-C.sub.6 haloalkyl; or R.sub.8 and R.sub.9, independently
from each other, are the groups A-, A-O-- or
A-(C.sub.1-C.sub.6alkyl)-;
[0029] R.sub.10 is H, C.sub.1-C.sub.4 alkyl, C.sub.2-C.sub.4
alkenyl or C.sub.1-C.sub.4 haloalkyl;
[0030] R.sub.13 is hydrogen, C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6
haloalkyl, C.sub.3-C.sub.6 alkenyl, C.sub.3-C.sub.6 haloalkenyl,
C.sub.3-C.sub.6 alkynyl, C.sub.3-C.sub.8 cycloalkyl,
C.sub.3-C.sub.8 halocycloalkyl, phenyl and benzyl, or is phenyl and
benzyl mono- to polysubstituted by halogen, cyano, hydroxy,
C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6 haloalkyl or C.sub.1-C.sub.6
alkoxy;
[0031] R.sub.14 and R.sub.15, independently of each other, are
C.sub.1-C.sub.6 alkyl, C.sub.3-C.sub.8 cycloalkyl, C.sub.1-C.sub.6
haloalkyl, C.sub.3-C.sub.8 halocycloalkyl, C.sub.2-C.sub.6 alkenyl,
C.sub.2-C.sub.6 haloalkenyl, C.sub.2-C.sub.6 alkynyl, benzyl or
phenyl, or benzyl or phenyl independently of each other,
substituted by substituents selected from the group consisting of
halogen, cyano, hydroxy, C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6
haloalkyl and C.sub.1-C.sub.6 alkoxy;
[0032] R.sub.51, R.sub.52, R.sub.53, independently of each other,
are halogen, cyano, C.sub.1-C.sub.6 alkyl, C.sub.2-C.sub.6alkenyl,
C.sub.3-C.sub.8 cycloalkyl, C.sub.5-C.sub.8 cycloalkenyl,
C.sub.2-C.sub.6 alkynyl, C.sub.1-C.sub.6 alkoxy, benzyl or
phenyl;
[0033] R.sub.54, R.sub.55, R.sub.56, independently of each other,
are C.sub.1-C.sub.6 alkyl, C.sub.3-C.sub.6 alkenyl, C.sub.3-C.sub.8
cycloalkyl, C.sub.3-C.sub.6 alkynyl, benzyl or phenyl;
[0034] R.sub.57 and R.sub.58, independently of each other, are
hydrogen, C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6 haloalkyl,
C.sub.3-C.sub.6 alkenyl, C.sub.3-C.sub.6 haloalkenyl,
C.sub.3-C.sub.6 alkynyl, C.sub.3-C.sub.8 cycloalkyl,
C.sub.3-C.sub.8 halocycloalkyl, phenyl or benzyl, where phenyl or
benzyl for their part may be mono- to polysubstituted on the phenyl
ring by substituents independently selected from the group
consisting of halogen, cyano, hydroxy, C.sub.1-C.sub.6 alkyl,
C.sub.1-C.sub.6 haloalkyl and C.sub.1-C.sub.6 alkoxy, or R.sub.57
and R.sub.58 together with their interconnecting nitrogen atom are
aziridino, azetidino, pyrazolino, pyrazolidino, pyrrolino,
pyrrolidino, imidazolino, imidazolidino, triazolino, tetrazolino,
piperazino, piperidino, morpholino, thiomorpholino, each of which,
in turn, may be mono- or polysubstituted by substituents selected
from the group consisting of methyl, halogen, cyano;
[0035] R.sub.59 is hydrogen, C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6
haloalkyl, C.sub.3-C.sub.6 alkenyl, C.sub.3-C.sub.6 haloalkenyl,
C.sub.3-C.sub.6 alkynyl, C.sub.3-C.sub.8 cycloalkyl,
C.sub.3-C.sub.8 halocycloalkyl, benzyl and phenyl, and benzyl and
phenyl mono- to polysubstituted by halogen, cyano, hydroxy,
C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6 haloalkyl or C.sub.1-C.sub.6
alkoxy;
[0036] R.sub.60 is hydrogen, C.sub.1-C.sub.6 alkyl, C.sub.3-C.sub.8
cycloalkyl, C.sub.1-C.sub.6 haloalkyl, C.sub.3-C.sub.8
halocycloalkyl, C.sub.2-C.sub.6 alkenyl, C.sub.2-C.sub.6
haloalkenyl, C.sub.2-C.sub.6 alkynyl, benzyl or phenyl, or benzyl
or phenyl mono- to polysubstituted by substituents independently
selected from the group consisting of halogen, cyano, hydroxy,
C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6 haloalkyl and
C.sub.1-C.sub.6 alkoxy; R.sub.62 is hydrogen, C.sub.1-C.sub.6
alkyl, C.sub.3-C.sub.8 cycloalkyl, C.sub.1-C.sub.6 haloalkyl,
C.sub.3-C.sub.8 halocycloalkyl, C.sub.3-C.sub.6 alkenyl,
C.sub.3-C.sub.6 alkynyl, benzyl or phenyl, or benzyl or phenyl
mono- to polysubstituted by substituents independently selected
from the group consisting of halogen, cyano, hydroxy,
C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6 haloalkyl and
C.sub.1-C.sub.6 alkoxy;
[0037] each R.sup.36' is independently selected from hydrogen,
halogen and C.sub.1-C.sub.4 alkyl;
[0038] and agronomically acceptable salts/metallic
complexes/metalloidic complexes/isomers/structural
isomers/stereo-isomers/diastereoisomers/enantiomers/tautomers/N-oxides
of those compounds; and
[0039] component B) is a strobilurin fungicide, a sterol
biosynthesis inhibitor fungicide, a triazole fungicide, or a
pro-triazole fungicide, or a DMI fungicide, or a SDHI fungicide, or
a compound selected from the group consisting of Chlorothalonil,
Fludioxonil, Cyprodinil, Mandipropamid, Fluazinam, Procymedone,
Carbendazim, Abamectin, Clothianidin, Emamectin benzoate,
Imidacloprid, Tefluthrin, Mefenoxam, Orocymedone, Thiamethoxam,
Lambda-cyhalothrin, Gamma-cyhalothrin, Profenofos, Lufenuron,
Diflubenzuron, Cypermethrin, Novaluron, Bifenthrin, Methomyl,
Chlopyrifos, Methamidophos, Endosulfan, Betacyfluthrin,
Triflumuron, Teflubenzuron, SulcotrioneAcephat, Glyphosate,
Glufosinate, Mesotrione, Bicyclopyrone, Tembotrione, Sulcotrione,
Sulcotrione, Auxins, Trinexapac-ethyl, Prohexadione-Ca,
Paclobutrazol, Acibenzolar-S-methyl, Methyl-Jasmonate, Cis-Jasmone,
Manganese, Cyflufenamid, Tebufloquin and Copper.
[0040] A further aspect of present invention provides a composition
comprising a combination of components A) and B) in a
synergistically effective ratio between the component A) and
component B).
[0041] A further aspect of the present invention provides a method
of controlling phytopathogenic diseases on useful plants or on
propagation material thereof, which comprises applying to the
useful plants, the locus thereof or propagation material thereof a
combination of components A) and B) in as synergistically effective
amount and ratio between the component A) and component B).
[0042] A further aspect of the present invention relates to novel
compounds according to formula (I).
[0043] A further aspect of the present invention relates to novel
intermediates to provide compounds according to formula (I).
[0044] Preferably, component B is a strobilurin fungicide, a sterol
biosynthesis inhibitor fungicide, a triazole fungicide, a
pro-triazole fungicide, a DMI fungicide, a SDHI fungicide, or is a
compound selected from Chlorothalonil, Fludioxonil, Cyprodinil,
Mandipropamid, Mefenoxam, Orocymedone, Fluazinam, Procymedone,
Carbendazim, Abamectin, Clothianidin, Emamectin benzoate,
Imidacloprid, Tefluthrin, Thiamethoxam, Lambda-cyhalothrin,
Gamma-cyhalothrin, Profenofos, Lufenuron, Diflubenzuron,
Cypermethrin, Novaluron, Bifenthrin, Methomyl, Chlopyrifos,
Methamidophos, Endosulfan, Betacyfluthrin, Triflumuron,
Teflubenzuron, SulcotrioneAcephat, Glyphosate, Glufosinate,
Mesotrione, Bicyclopyrone, Tembotrione, Sulcotrione, Auxins,
Trinexapac-ethyl, Prohexadione-Ca, Paclobutrazol,
Acibenzolar-S-methyl, Methyl-Jasmonate, Cis-Jasmone, Manganese and
Copper.
[0045] Preferably, component B is a strobilurin fungicide, a sterol
biosynthesis inhibitor fungicide, a triazole fungicide, a
pro-triazole fungicide, a DMI fungicide, a SDHI fungicide, or is a
compound selected from the group consisting of Chlorothalonil,
Fludioxonil, Cyprodinil, Mandipropamid, Mefenoxam, Orocymedone,
Fluazinam, Carbendazim, Thiamethoxam, Glyphosate, 2,4-D,
Trinexapac-ethyl, Prohexadione-Ca, Paclobutrazol and
cis-Jasmone.
[0046] In one group of mixtures, component B is a strobilurin
fungicide.
[0047] In another group of mixtures, component B is a Sterol
biosynthesis inhibitor
[0048] In another group of mixtures, component B is a triazole
fungicide or a protriazole compound.
[0049] In another group of mixtures, component B is a DMI
fungicide.
[0050] In another group of mixtures, component B is a SDHI
fungicide.
[0051] In another group of mixtures, component B is a compound of
formula (III)
##STR00003##
[0052] wherein R.sup.70' is phenyl, which is unsubstituted or
substituted with 1, 2 or 3 substituents selected from halogen,
haloalkyl, haloalkoxy and cyano, and;
[0053] R.sup.71' is phenyl, which is unsubstituted or substituted
with 1, 2 or 3 substituents selected from halogen, haloalkyl,
haloalkoxy and cyano.
[0054] Preferred compounds of formula (III) are
(S)-[3-(4-Chloro-2-fluoro-phenyl)-5-(2,4-difluoro-phenyl)-isoxazol-4-yl]--
pyridin-3-yl-methanol and
3-(4-Chloro-2-fluoro-phenyl)-5-(2,4-difluoro-phenyl)-isoxazol-4-yl]-pyrid-
in-3-yl-methanol.
[0055] In another group of mixtures, component B is selected from
the group consisting of Chlorothalonil, Fludioxonil, Cyprodinil,
Mandipropamid, Fluazinam, Procymedone, Carbendazim, Abamectin,
Clothianidin, Emamectin benzoate, Imidacloprid, Tefluthrin,
Mefenoxam, Orocymedone, Thiamethoxam, Lambda-cyhalothrin,
Gamma-cyhalothrin, Profenofos, Lufenuron, Diflubenzuron,
Cypermethrin, Novaluron, Bifenthrin, Methomyl, Chlopyrifos,
Methamidophos, Endosulfan, Betacyfluthrin, Triflumuron,
Teflubenzuron, SulcotrioneAcephat, Glyphosate, Glufosinate,
Mesotrione, Bicyclopyrone, Tembotrione, Sulcotrione, Auxins (e.g.
2,4-D and MCPA), Trinexapac-ethyl, Prohexadione-Ca, Paclobutrazol,
Acibenzolar-S-methyl, Methyl-Jasmonate, Cis-Jasmone, Manganese and
Copper, preferably from the group consisting of Chlorothalonil,
Fludioxonil, Cyprodinil, Fenpropidin, Mandipropamid, Mefenoxam,
Orocymedone, Fluazinam, Procymedone, Carbendazim, Abamectin,
Clothianidin, Emamectin benzoate, Imidacloprid, Tefluthrin,
Thiamethoxam, Lambda-cyhalothrin, Gamma-cyhalothrin, Profenofos,
Lufenuron, Diflubenzuron, Cypermethrin, Novaluron, Bifenthrin,
Methomyl, Chlopyrifos, Methamidophos, Endosulfan, Betacyfluthrin,
Triflumuron, Teflubenzuron, SulcotrioneAcephat, Glyphosate,
Glufosinate, Mesotrione, Bicyclopyrone, Tembotrione, Sulcotrione,
Auxins, Trinexapac-ethyl, Prohexadione-Ca, Paclobutrazol,
Acibenzolar-S-methyl, Methyl-Jasmonate, Cis-Jasmone, Manganese and
Copper, more preferably from the group consisting of
Chlorothalonil, Fludioxonil, Cyprodinil, Fenpropidin,
Mandipropamid, Mefenoxam, Orocymedone, Fluazinam, Carbendazim,
Thiamethoxam, Glyphosate, 2,4-D, Trinexapac-ethyl, Prohexadione-Ca,
Paclobutrazol and cis-Jasmone.
[0056] In a preferred embodiment the component B) is a compound
selected from Chlorothalonil, Fludioxonil, Cyprodinil, Fenpropidin,
Mandipropamid, Fenpropimorph, Fluazinam, Procymedone, Carbendazim,
Abamectin, Clothianidin, Emamectin benzoate, Imidacloprid,
Tefluthrin, Mefenoxam, Orocymedone, Thiamethoxam,
Lambda-cyhalothrin, Gamma-cyhalothrin, Profenofos, Lufenuron,
Diflubenzuron, Cypermethrin, Novaluron, Bifenthrin, Methomyl,
Chlopyrifos, Methamidophos, Endosulfan, Betacyfluthrin,
Triflumuron, Teflubenzuron, Acephat, Glyphosate, Glufosinate,
Mesotrione, Bicyclopyrone, Tembotrione, Sulcotrione, 2,4-D, MCPA,
Trinexapac-ethyl, Prohexadione-Ca, Paclobutrazol,
Acibenzolar-S-methyl, Methyl-Jasmonate, Cis-Jasmone, Manganese,
Copper, Coumoxystrobin, Dicloaminostrobin, Flufenoxystrobin,
Pyrametostrobin, Pyraoxystrobin, Trifloxystrobin, Azoxystrobin,
Pyraclostrobin, Picoxystrobin, Jiaxiangjunzhi, Enoxastrobin,
Triclopyricarb, the compound of formula II, Cyproconazole,
Difenoconazole, Metconazole, Propiconazole, Epoxiconazole,
Tebuconazole, Flutriafol, Ipconazole, prothioconazole,
(S)-[3-(4-Chloro-2-fluoro-phenyl)-5-(2,4-difluoro-phenyl)-isoxazol-4-yl]--
pyridin-3-yl-methanol,
3-(4-Chloro-2-fluoro-phenyl)-5-(2,4-difluoro-phenyl)-isoxazol-4-yl]-pyrid-
in-3-yl-methanol, Pyrisoxazole,
3-(Difluoromethyl)-N-methoxy-1-methyl-N-[1-methyl-2-(2,4,6-trichloropheny-
l)ethyl]-1H-pyrazole-4-carboxamide,
N-[9-(dichloromethylene)-1,2,3,4-tetrahydro-1,4-methanonaphthalen-5-yl]-3-
-(difluoromethyl)-1-methyl-1H-pyrazole-4-carboxamide, Isopyrazam,
Sedaxane, Boscalid, Fluxapyroxad, Penthiopyrad, Penflufen, Bixafen
and Fluopyram.
[0057] The term strobilurin fungicide is well known to the person
skilled in the art, and includes, for example, Coumoxystrobin,
Dicloaminostrobin, Flufenoxystrobin, Pyrametostrobin,
Pyraoxystrobin, Trifloxystrobin, Azoxystrobin, Pyraclostrobin,
Picoxystrobin, Jiaxiangjunzhi, Enoxastrobin, Triclopyricarb,
Fluoxastrobin, Dimoxystrobin, Fenaminostrobin and the compound of
formula (II). Preferred strobilurin fungicides are Azoxystrobin,
Pyraclostrobin and Picoxystrobin. Even more preferred strobilurin
fungicides are Azoxystrobin and Pyraclostrobin.
##STR00004##
[0058] The term sterol biosynthesis inhibitor fungicide is well
known to the person skilled in the art, and includes, for example,
Spiroxamine, Fenpropimorph, Tridemorph, Fenpropidin, Fenhexamid,
Terbinafine, Naftifine
[0059] The term triazole fungicide is well known to the person
skilled in the art, and includes, for example, Cyproconazole,
Difenoconazole, Metconazole, Propiconazole, Epoxiconazole,
Tebuconazole, Flutriafol, Ipconazole and
1-(2-chlorophenyl)-2-(1-chlorocycloprop-1-yl)-3-(1,2,4-triazol-1-yl)propa-
n-2-ol [CAS number 120983-64-4]. Preferred triazole fungicide
compounds are Cyproconazole, Difenoconazole, Metconazole and
Tebuconazole. Even more preferred is Cyproconazole.
[0060] The term pro-triazole fungicide is well known to the person
skilled in the art and includes, for example, prothioconazole.
[0061] The term DMI fungicides is well known to the person skilled
in the art and includes, for example,
(S)-[3-(4-Chloro-2-fluoro-phenyl)-5-(2,4-difluoro-phenyl)-isoxazol-4-yl]--
pyridin-3-yl-methanol,
3-(4-Chloro-2-fluoro-phenyl)-5-(2,4-difluoro-phenyl)-isoxazol-4-yl]-pyrid-
in-3-yl-methanol and Pyrisoxazole. Preferred DMI fungicides are
(S)-[3-(4-Chloro-2-fluoro-phenyl)-5-(2,4-difluoro-phenyl)-isoxazol-4-yl]--
pyridin-3-yl-methanol and
3-(4-Chloro-2-fluoro-phenyl)-5-(2,4-difluoro-phenyl)-isoxazol-4-yl]-pyrid-
in-3-yl-methanol.
[0062] The term SDHI fungicide is well known to the person skilled
in the art and includes, for example,
N-[9-(dichloromethylene)-1,2,3,4-tetrahydro-1,4-methanonaphthalen-5-yl]-3-
-(difluoromethyl)-1-methyl-1H-pyrazole-4-carboxamide, Isopyrazam,
Sedaxane, Boscalid Fluxapyroxad, Penthiopyrad, Penflufen, Bixafen,
Fluopyram,
3-(Difluoromethyl)-N-methoxy-1-methyl-N-[1-methyl-2-(2,4,6-trichloropheny-
l)ethyl]-1H-pyrazole-4-carboxamide, Preferred SDHI fungicides are
N-[9-(dichloromethylene)-1,2,3,4-tetrahydro-1,4-methanonaphthalen-5-yl]-3-
-(difluoromethyl)-1-methyl-1H-pyrazole-4-carboxamide, Isopyrazam,
3-(Difluoromethyl)-N-methoxy-1-methyl-N-[1-methyl-2-(2,4,6-trichloropheny-
l)ethyl]-1H-pyrazole-4-carboxamide and Fluxapyroxad.
[0063] The term Auxins is well known to the person skilled in the
art and includes, for example, 2,4-D, MCPA and Dicamba
[0064] In a further preferred embodiment the component B is
Chlorothalonil. In a further preferred embodiment the component B
is Fludioxonil. In a further preferred embodiment the component B
is Cyprodinil. In a further preferred embodiment the component B is
Fenpropidin. In a further preferred embodiment the component B is
Mandipropamid. In a further preferred embodiment the component B is
Fluazinam. In a further preferred embodiment the component B is
Procymedone. In a further preferred embodiment the component B is
Carbendazim. In a further preferred embodiment the component B is
Abamectin. In a further preferred embodiment the component B is
Clothianidin. In a further preferred embodiment the component B is
Emamectin benzoate. In a further preferred embodiment the component
B is Imidacloprid. In a further preferred embodiment the component
B is Tefluthrin. In a further preferred embodiment the component B
is Mefenoxam. In a further preferred embodiment the component B is
Orocymedone. In a further preferred embodiment the component B is
Thiamethoxam. In a further preferred embodiment the component B is
Lambda-cyhalothrin. In a further preferred embodiment the component
B is Gamma-cyhalothrin. In a further preferred embodiment the
component B is Profenofos. In a further preferred embodiment the
component B is Lufenuron. In a further preferred embodiment the
component B is Diflubenzuron. In a further preferred embodiment the
component B is Cypermethrin. In a further preferred embodiment the
component B is Novaluron. In a further preferred embodiment the
component B is Bifenthrin. In a further preferred embodiment the
component B is Methomyl. In a further preferred embodiment the
component B is Chlopyrifos. In a further preferred embodiment the
component B is Methamidophos. In a further preferred embodiment the
component B is Endosulfan. In a further preferred embodiment the
component B is Betacyfluthrin. In a further preferred embodiment
the component B is Triflumuron. In a further preferred embodiment
the component B is Teflubenzuron. In a further preferred embodiment
the component B is Acephat. In a further preferred embodiment the
component B is Glyphosate. In a further preferred embodiment the
component B is Glufosinate. In a further preferred embodiment the
component B is Mesotrione. In a further preferred embodiment the
component B is Bicyclopyrone. In a further preferred embodiment the
component B is Tembotrione. In a further preferred embodiment the
component B is Sulcotrione. In a further preferred embodiment the
component B is 2,4-D. In a further preferred embodiment the
component B is MCPA. In a further preferred embodiment the
component B is Trinexapac-ethyl. In a further preferred embodiment
the component B is Prohexadione-Ca. In a further preferred
embodiment the component B is Paclobutrazol. In a further preferred
embodiment the component B is Acibenzolar-S-methyl. In a further
preferred embodiment the component B is Methyl-Jasmonate. In a
further preferred embodiment the component B is Cis-Jasmone. In a
further preferred embodiment the component B is Manganese. In a
further preferred embodiment the component B is Copper. In a
further preferred embodiment the component B is Cyflufenamid. In a
further preferred embodiment the component B is Tebufloquin. In a
further preferred embodiment the component B is Coumoxystrobin. In
a further preferred embodiment the component B is
Dicloaminostrobin. In a further preferred embodiment the component
B is Flufenoxystrobin. In a further preferred embodiment the
component B is Pyrametostrobin. In a further preferred embodiment
the component B is Pyraoxystrobin. In a further preferred
embodiment the component B is Trifloxystrobin. In a further
preferred embodiment the component B is Azoxystrobin. In a further
preferred embodiment the component B is Pyraclostrobin. In a
further preferred embodiment the component B is Picoxystrobin. In a
further preferred embodiment the component B is Jiaxiangjunzhi. In
a further preferred embodiment the component B is Enoxastrobin. In
a further preferred embodiment the component B is Triclopyricarb.
In a further preferred embodiment the component B is Fluoxastrobin.
In a further preferred embodiment the component B is Dimoxystrobin.
In a further preferred embodiment the component B is
Fenaminostrobin In a further preferred embodiment the component B
is the compound of formula II. In a further preferred embodiment
the component B is Cyproconazole. In a further preferred embodiment
the component B is Difenoconazole. In a further preferred
embodiment the component B is Metconazole. In a further preferred
embodiment the component B is Propiconazole. In a further preferred
embodiment the component B is Epoxiconazole. In a further preferred
embodiment the component B is Tebuconazole. In a further preferred
embodiment the component B is Flutriafol. In a further preferred
embodiment the component B is Ipconazole. In a further preferred
embodiment the component B is
1-(2-chlorophenyl)-2-(1-chlorocycloprop-1-yl)-3-(1,2,4-triazol-1-yl)propa-
n-2-ol [CAS number 120983-64-4]. In a further preferred embodiment
the component B is prothioconazole. In a further preferred
embodiment the component B is
(S)-[3-(4-Chloro-2-fluoro-phenyl)-5-(2,4-difluoro-phenyl)-isoxazol-4-yl]--
pyridin-3-yl-methanol. In a further preferred embodiment the
component B is
3-(4-Chloro-2-fluoro-phenyl)-5-(2,4-difluoro-phenyl)-isoxazol-4-yl]-py-
ridin-3-yl-methanol. In a further preferred embodiment the
component B is Pyrisoxazole. In a further preferred embodiment the
component B is
3-(difluoromethyl)-N-methoxy-1-methyl-N-[1-methyl-2-(2,4,6-trichloropheny-
l)ethyl]-1H-Pyrazole-4-carboxamide. In a further preferred
embodiment the component B is
N-[9-(dichloromethylene)-1,2,3,4-tetrahydro-1,4-methanonaphthalen-5-yl]-3-
-(difluoromethyl)-1-methyl-1H-pyrazole-4-carboxamide. In a further
preferred embodiment the component B is Isopyrazam. In a further
preferred embodiment the component B is Sedaxane. In a further
preferred embodiment the component B is Boscalid, In a further
preferred embodiment the component B is Fluxapyroxad. In a further
preferred embodiment the component B is Penthiopyrad. In a further
preferred embodiment the component B is Penflufen. In a further
preferred embodiment the component B is Bixafen. In a further
preferred embodiment the component B is Fluopyram. In a further
preferred embodiment the component B is
1-(2-chlorophenyl)-2-(1-chlorocycloprop-1-yl)-3-(1,2,4-triazol-1-yl)propa-
n-2-ol.
[0065] The active ingredient mixture according to the invention may
bring about the additive enhancement of the spectrum of action with
respect to the phytopathogen to be controlled that may in principle
be expected but achieves a synergistic effect which extends the
range of action of the component (A) and of the component (B) in
two ways. Firstly, the rates of application of the component (A)
and of the component (B) may be lowered whilst the action remains
equally good. Secondly, the active ingredient mixture may still
achieve a high degree of phytopathogen control even where the two
individual components have become totally ineffective in such a low
application rate range. This allows, on the one hand, a substantial
broadening of the spectrum of phytopathogens that can be controlled
and, on the other hand, increased safety in use.
[0066] However, besides the actual synergistic action with respect
to fungicidal activity, the pesticidal compositions according to
the invention may also have further surprising advantageous
properties which can also be described, in a wider sense, as
synergistic activity. Examples of such advantageous properties that
may be mentioned are: a broadening of the spectrum of fungicidal
activity to other phytopathogens, for example to resistant strains;
a reduction in the rate of application of the active ingredients;
synergistic activity against animal pests, such as insects or
representatives of the order Acarina; a broadening of the spectrum
of pesticidal activity to other animal pests, for example to
resistant animal pests; adequate pest control with the aid of the
compositions according to the invention, even at a rate of
application at which the individual compounds are totally
ineffective; advantageous behaviour during formulation and/or upon
application, for example upon grinding, sieving, emulsifying,
dissolving or dispensing; increased storage stability; improved
stability to light; more advantageous degradability; improved
toxicological and/or ecotoxicological behaviour; improved
characteristics of the useful plants including: emergence, crop
yields, more developed root system, tillering increase, increase in
plant height, bigger leaf blade, less dead basal leaves, stronger
tillers, greener leaf colour, less fertilizers needed, less seeds
needed, more productive tillers, earlier flowering, early grain
maturity, less plant verse (lodging), increased shoot growth,
improved plant vigor, and early germination; or any other
advantages familiar to a person skilled in the art.
[0067] Substituents at a nitrogen atom are always different from
halogen. A hydroxy, mercapto or amino substituent is not to be
placed on an .alpha.-carbon relative to a heteroatom of a core
fragment.
[0068] The alkyl groups occurring in the definitions of the
substituents can be straight-chain or branched and are, for
example, methyl, ethyl, n-propyl, isopropyl, n-butyl, sec-butyl,
iso-butyl, tert-butyl, pentyl, hexyl, heptyl and octyl and their
branched isomers. Alkoxy, alkenyl and alkynyl radicals are derived
from the alkyl radicals mentioned. The alkenyl and alkynyl groups
can be mono- or polyunsaturated.
[0069] The cycloalkyl groups occurring in the definitions of the
substituents are, for example, cyclopropyl, cyclobutyl, cyclopentyl
or cyclohexyl.
[0070] Halogen is generally fluorine, chlorine, bromine or iodine,
preferably fluorine, bromine or chlorine. This also applies,
correspondingly, to halogen in combination with other meanings,
such as haloalkyl or haloalkoxy.
[0071] Haloalkyl groups preferably have a chain length of from 1 to
6 carbon atoms. Haloalkyl is, for example, fluoromethyl,
difluoromethyl, trifluoromethyl, chloromethyl, dichloromethyl,
trichloromethyl, 2,2,2-trifluoroethyl, 2-fluoroethyl,
2-chloroethyl, pentafluoroethyl, 1,1-difluoro-2,2,2-trichloroethyl,
2,2,3,3-tetrafluoroethyl, 2,2,2-trichloroethyl,
5,5,5-trifluoropentan-1-yl, 5,5-difluoro-pentan-1-yl,
6,6,6-trifluorohexan-1-yl, 6,6-difluoro-hexan-1-yl,
heptafluoro-prop-2-yl and 2-fluoro-prop-2-yl; preferably
trichloromethyl, difluorochloromethyl, difluoromethyl,
trifluoromethyl and dichlorofluoromethyl.
[0072] Suitable haloalkenyl groups are alkenyl groups which are
mono- di- or trisubstituted by halogen, halogen being fluorine,
chlorine, bromine and iodine and in particular fluorine and
chlorine, for example 2,2-difluoro-1-methylvinyl, 3-fluoropropenyl,
3-chloropropenyl, 3-bromopropenyl, 2,3,3-trifluoropropenyl,
2,3,3-trichloropropenyl and 4,4,4-trifluorobut-2-en-1-yl.
[0073] Suitable haloalkynyl groups are, for example, alkynyl groups
which are mono- or polysubstituted by halogen, halogen being
bromine, iodine and in particular fluorine and chlorine, for
example 3-fluoropropynyl, 3-chloropropynyl, 3-bromopropynyl,
3,3,3-trifluoro-propynyl and 4,4,4-trifluorobut-2-yn-1-yl.
[0074] Alkoxy is, for example, methoxy, ethoxy, propoxy, i-propoxy,
n-butoxy, isobutoxy, sec-butoxy and tert-butoxy; preferably methoxy
and ethoxy. Halogenalkoxy is, for example, fluoromethoxy,
difluoromethoxy, trifluoromethoxy, 2,2,2-trifluoroethoxy,
1,1,2,2-tetrafluoroethoxy, 2-fluoroethoxy, 2-chloroethoxy,
2,2-difluoroethoxy and 2,2,2-trichloroethoxy; preferably
difluoromethoxy, 2-chloroethoxy and trifluoromethoxy.
[0075] Alkoxycarbonyl is, for example, methoxycarbonyl,
ethoxycarbonyl, propoxycarbonyl, isopropoxycarbonyl,
n-butoxycarbonyl, isobutoxycarbonyl, sec-butoxycarbonyl or
tert-butoxycarbonyl; preferably methoxycarbonyl or ethoxycarbonyl.
Haloalkoxy groups preferably have a chain length of from 1 to 6
carbon atoms. Haloalkoxy is, for example, fluoromethoxy,
difluoromethoxy, trifluoromethoxy, 2,2,2-trifluoroethoxy,
1,1,2,2-tetrafluoroethoxy, 2-fluoroethoxy, 2-chloroethoxy,
2,2-difluoroethoxy and 2,2,2-trichloroethoxy; preferably
difluoromethoxy, 2-chloroethoxy and trifluoromethoxy. Alkylthio
groups preferably have a chain length of from 1 to 6 carbon
atoms.
[0076] Alkoxyalkyl is, for example, methoxymethyl, methoxyethyl,
ethoxymethyl, ethoxyethyl, n-propoxymethyl, n-propoxyethyl,
isopropoxymethyl or isopropoxyethyl.
[0077] Alkylthio is, for example, methylthio, ethylthio,
propylthio, isopropylthio, n-butylthio, isobutylthio, sec-butylthio
or tert-butylthio, preferably methylthio and ethylthio.
Alkylsulfinyl is, for example, methylsulfinyl, ethylsulfinyl,
propylsulfinyl, isopropylsulfinyl, n-butylsulfinyl,
isobutylsulfinyl, sec-butylsulfinyl, tert-butylsulfinyl; preferably
methylsulfinyl and ethylsulfinyl. Alkylsulfonyl is, for example,
methylsulfonyl, ethylsulfonyl, propylsulfonyl, isopropylsulfonyl,
n-butylsulfonyl, isobutylsulfonyl, sec-butylsulfonyl or
tert-butylsulfonyl; preferably methylsulfonyl or ethylsulfonyl.
[0078] C.sub.2-C.sub.6 alkylcarbonyl is, for example,
methylcarbonyl, ethylcarbonyl, propylcarbonyl, isopropylcarbonyl,
n-butylcarbonyl, isobutylcarbonyl, sec-butylcarbonyl,
tert-butylcarbonyl or n-pentylcarbonyl and their branched isomers,
preferably methylcarbonyl and ethylcarbonyl. Haloalkylcarbonyl
radicals are derived from the alkyl radicals mentioned.
[0079] In the context of the present invention "mono- to
polysubstituted" in the definition of the substituents, means
typically, depending on the chemical structure of the substituents,
monosubstituted to seven-times substituted, preferably
monosubstituted to five-times substituted, more preferably mono-,
double- or triple-substituted.
[0080] According to the present invention, a three- to ten-membered
monocyclic or fused bicyclic ring system which may be aromatic,
partially saturated or fully saturated is, depending of the number
of ring members, for example, selected from the group consisting
of
##STR00005##
[0081] cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, where said
cycloalkylgroups for their part may be preferably unsubstituted or
substituted by C.sub.1-C.sub.6alkyl or halogen, or is phenyl,
benzyl, naphthyl or the following heterocyclic groups: pyrrolyl;
pyridyl; pyrazolyl; pyrimidyl; pyrazinyl; imidazolyl; thiadiazolyl;
quinazolinyl; furyl; oxadiazolyl; indolizinyl; pyranyl;
isobenzofuranyl; thienyl; naphthyridinyl;
(1-methyl-1H-pyrazol-3-yl)-; (1-ethyl-1H-pyrazol-3-yl)-;
(1-propyl-1H-pyrazol-3-yl)-; (1H-pyrazol-3-yl)-;
(1,5-dimethyl-1H-pyrazol-3-yl)-;
(4-chloro-1-methyl-1H-pyrazol-3-yl)-; (1H-pyrazol-1-yl)-;
(3-methyl-1H-pyrazol-1-yl)-; (3,5-dimethyl-1H-pyrazol-1-yl)-;
(3-isoxazolyl)-; (5-methyl-3-isoxazolyl)-;
(3-methyl-5-isoxazolyl)-; (5-isoxazolyl)-; (1H-pyrrol-2-yl)-;
(1-methyl-1H-pyrrol-2-yl)-; (1H-pyrrol-1-yl)-;
(1-methyl-1H-pyrrol-3-yl)-; (2-furanyl)-; (5-methyl-2-furanyl)-;
(3-furanyl)-; (5-methyl-2-thienyl)-; (2-thienyl)-; (3-thienyl)-;
(1-methyl-1H-imidazol-2-yl)-; (1H-imidazol-2-yl)-;
(1-methyl-1H-imidazol-4-yl)-; (1-methyl-1H-imidazol-5-yl)-;
(4-methyl-2-oxazolyl)-; (5-methyl-2-oxazolyl)-; (2-oxazolyl)-;
(2-methyl-5-oxazolyl)-; (2-methyl-4-oxazolyl)-;
(4-methyl-2-thiazolyl)-; (5-methyl-2-thiazolyl)-; (2-thiazolyl)-;
(2-methyl-5-thiazolyl)-; (2-methyl-4-thiazolyl)-;
(3-methyl-4-isothiazolyl)-; (3-methyl-5-isothiazolyl)-;
(5-methyl-3-isothiazolyl)-; (1-methyl-1H-1,2,3-triazol-4-yl)-;
(2-methyl-2H-1,2,3-triazol-4-yl)-;
(4-methyl-2H-1,2,3-triazol-2-yl)-;
(1-methyl-1H-1,2,4-triazol-3-yl)-;
(1,5-dimethyl-1H-1,2,4-triazol-3-yl)-;
(3-methyl-1H-1,2,4-triazol-1-yl)-;
(5-methyl-1H-1,2,4-triazol-1-yl)-;
(4,5-dimethyl-4H-1,2,4-triazol-3-yl)-;
(4-methyl-4H-1,2,4-triazol-3-yl)-; (4H-1,2,4-triazol-4-yl)-;
(5-methyl-1,2,3-oxadiazol-4-yl)-; (1,2,3-oxadiazol-4-yl)-;
(3-methyl-1,2,4-oxadiazol-5-yl)-; (5-methyl-1,2,4-oxadiazol-3-yl)-;
(4-methyl-3-furazanyl)-; (3-furazanyl)-;
(5-methyl-1,2,4-oxadiazol-2-yl)-;
(5-methyl-1,2,3-thiadiazol-4-yl)-; (1,2,3-thiadiazol-4-yl)-;
(3-methyl-1,2,4-thiadiazol-5-yl)-;
(5-methyl-1,2,4-thiadiazol-3-yl)-;
(4-methyl-1,2,5-thiadiazol-3-yl)-;
(5-methyl-1,3,4-thiadiazol-2-yl)-; (1-methyl-1H-tetrazol-5-yl)-;
(1H-tetrazol-5-yl)-; (5-methyl-1H-tetrazol-1-yl)-;
(2-methyl-2H-tetrazol-5-yl)-; (2-ethyl-2H-tetrazol-5-yl)-;
(5-methyl-2H-tetrazol-2-yl)-; (2H-tetrazol-2-yl)-; (2-pyridyl)-;
(6-methyl-2-pyridyl)-; (4-pyridyl)-; (3-pyridyl)-;
(6-methyl-3-pyridazinyl)-; (5-methyl-3-pyridazinyl)-;
(3-pyridazinyl)-; (4,6-dimethyl-2-pyrimidinyl)-;
(4-methyl-2-pyrimidinyl)-; (2-pyrimidinyl)-;
(2-methyl-4-pyrimidinyl)-; (2-chloro-4-pyrimidinyl)-;
(2,6-dimethyl-4-pyrimidinyl)-; (4-pyrimidinyl)-;
(2-methyl-5-pyrimidinyl)-; (6-methyl-2-pyrazinyl)-; (2-pyrazinyl)-;
(4,6-dimethyl-1,3,5-triazin-2-yl)-;
(4,6-dichloro-1,3,5-triazin-2-yl)-; (1,3,5-triazin-2-yl)-;
(4-methyl-1,3,5-triazin-2-yl)-; (3-methyl-1,2,4-triazin-5-yl)-;
(3-methyl-1,2,4-triazin-6-yl)-;
##STR00006## ##STR00007##
[0082] wherein each R.sub.26 is methyl, each R.sub.27 and each
R.sub.28 are independently hydrogen, C.sub.1-C.sub.3alkyl,
C.sub.1-C.sub.3alkoxy, C.sub.1-C.sub.3alkylthio or trifluoromethyl,
X.sub.4 is oxygen or sulfur and r=1, 2, 3 or 4.
[0083] There no free valency is indicated in those definitions, for
example as in
##STR00008##
the linkage site is located at the carbon atom labelled "CH" or in
a case such as, for example,
##STR00009##
at the bonding site indicated at the bottom left.
[0084] The following substituents definitions, including preferred
definitions, may be combined in any combination:
[0085] R.sub.1 and R.sub.2 are each independently selected from
hydrogen, C.sub.1-C.sub.4 alkyl, C.sub.3-C.sub.4 alkenyl,
C.sub.3-C.sub.4 alkynyl, (R.sub.10)carbonyl and
(R.sub.10)oxycarbonyl; [0086] or R.sub.1 and R.sub.2 together with
the nitrogen atom to which they are attached form a 5- or 6
membered cyclic group which may be saturated or unsaturated and may
contain a further heteroatom selected from S or O.
[0087] Preferably, R.sub.1 and R.sub.2 are each independently
selected from hydrogen, C.sub.1-C.sub.4 alkyl, C.sub.3-C.sub.4
alkenyl and C.sub.3-C.sub.4 alkynyl;
[0088] or R.sub.1 and R.sub.2 together with the nitrogen atom to
which they are attached form a pyrrolidine or piperidine.
[0089] More preferably, R.sub.1 and R.sub.2 are each independently
selected from hydrogen or C.sub.1-C.sub.4 alkyl;
[0090] or R.sub.1 and R.sub.2 together with the nitrogen atom to
which they are attached form a pyrrolidine or piperidine.
[0091] Even more preferably, R.sub.1 and R.sub.2 are each
independently selected from hydrogen or C.sub.1-C.sub.4 alkyl.
[0092] More preferably again, R.sub.1 and R.sub.2 are each
C.sub.1-C.sub.4 alkyl.
[0093] More favourably again, R.sub.1 and R.sub.2 are each
independently selected from methyl, ethyl and isopropyl.
[0094] Yet more favourably, R.sub.1 is methyl and R.sub.2 is
selected from methyl, ethyl and isopropyl.
[0095] Yet more favourably still, R.sub.1 is methyl and R.sub.2 is
selected from ethyl and isopropyl.
[0096] Most preferably, R.sub.1 is methyl and R.sub.2 is ethyl.
[0097] R.sub.3 represents hydrogen, halogen, cyano, nitro,
mercapto, hydroxy, --C(.dbd.S)NH.sub.2, --SF.sub.5, C.sub.1-C.sub.6
alkyl, C.sub.1-C.sub.6 haloalkyl, C.sub.2-C.sub.6 alkenyl,
C.sub.2-C.sub.6 haloalkenyl, C.sub.2-C.sub.6 alkynyl,
C.sub.2-C.sub.6 haloalkynyl, C.sub.1-C.sub.6 alkoxy,
C.sub.1-C.sub.6 haloalkoxy, C.sub.3-C.sub.6cycloalkyl, amino,
C.sub.1-C.sub.2alkylamino, di(C.sub.1-C.sub.6alkyl)amino, a
5-membered heterocycle containing 1-4 nitrogen atoms, piperidino,
morpholino, thiomorpholino, formyl, hydroxycarbonyl,
C.sub.2-C.sub.7 alkoxycarbonyl, C.sub.2-C.sub.7 haloalkoxycarbonyl,
C.sub.4-C.sub.7 alkenyloxycarbonyl, C.sub.4-C.sub.7
haloalkenyloxycarbonyl, C.sub.2-C.sub.7 alkylcarbonyl,
C.sub.2-C.sub.7 haloalkylcarbonyl, C.sub.1-C.sub.6 alkylthio,
C.sub.1-C.sub.6 alkylsulfinyl, C.sub.1-C.sub.6 alkylsulfonyl,
C.sub.1-C.sub.6 haloalkylthio, C.sub.1-C.sub.6 haloalkylsulfinyl,
C.sub.1-C.sub.6 haloalkylsulfonyl, C.sub.1-C.sub.6 hydroxyalkyl,
phenyl or benzyl wherein the phenyl and benzyl are optionally
substituted by one or more groups independently selected from the
group consisting of halogen, cyano, hydroxy, mercapto, amino,
C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6 haloalkyl, C.sub.1-C.sub.6
alkoxy, C.sub.1-C.sub.6 haloalkoxy, C.sub.1-C.sub.6 alkylthio,
C.sub.1-C.sub.6 alkylsulfinyl and C.sub.1-C.sub.6
alkylsulfonyl.
[0098] Preferably, R.sub.3 represents hydrogen, halogen, cyano,
mercapto, hydroxy, C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4
haloalkyl, C.sub.2-C.sub.4 alkenyl, C.sub.2-C.sub.4 haloalkenyl,
C.sub.2-C.sub.4 alkynyl, C.sub.1-C.sub.4 alkoxy, C.sub.1-C.sub.4
haloalkoxy, C.sub.3-C.sub.6 cycloalkyl, amino, C.sub.1-C.sub.2
alkylamino, di(C.sub.1-C.sub.6alkyl)amino, pyrrolidino,
imidazolino, triazolino, tetrazolino, formyl, C.sub.2-C.sub.5
alkylcarbonyl, C.sub.2-C.sub.5 haloalkylcarbonyl, C.sub.1-C.sub.6
alkylthio, C.sub.1-C.sub.6 alkylsulfinyl, C.sub.1-C.sub.6
alkylsulfonyl, C.sub.1-C.sub.6 haloalkylthio, C.sub.1-C.sub.6
haloalkylsulfinyl, C.sub.1-C.sub.6 haloalkylsulfonyl or
C.sub.1-C.sub.6 hydroxyalkyl.
[0099] More preferably, R.sub.3 represents hydrogen, halogen,
cyano, C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 haloalkyl,
C.sub.2-C.sub.4 alkenyl, C.sub.2-C.sub.4 alkynyl, C.sub.1-C.sub.4
alkoxy, C.sub.3-C.sub.6 cycloalkyl, amino, C.sub.1-C.sub.2
alkylamino, di(C.sub.1-C.sub.6alkyl)amino, pyrrolidino,
imidazolino, triazolino, formyl, phenyl, C.sub.2-C.sub.4
alkylcarbonyl, C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6
alkylsulfinyl, C.sub.1-C.sub.6 alkylsulfonyl or C.sub.1-C.sub.6
hydroxyalkyl.
[0100] Even more preferably, R.sub.3 represents hydrogen, halogen,
cyano, C.sub.1-C.sub.4 alkyl, C.sub.2-C.sub.4 alkenyl,
C.sub.2-C.sub.4 alkynyl, C.sub.1-C.sub.4 alkoxy,
C.sub.3-C.sub.6cycloalkyl, amino, C.sub.1-C.sub.2 alkylamino,
di(C.sub.1-C.sub.6alkyl)amino, pyrrolidino, imidazolino,
triazolino, formyl, C.sub.2-C.sub.4alkylcarbonyl,
C.sub.1-C.sub.4alkylthio, C.sub.1-C.sub.4 alkylsulfinyl,
C.sub.1-C.sub.4 alkylsulfonyl, C.sub.1-C.sub.4 haloalkylthio,
C.sub.1-C.sub.4 haloalkylsulfinyl or C.sub.1-C.sub.4
haloalkylsulfonyl or C.sub.1-C.sub.6 hydroxyalkyl.
[0101] More preferably again, R.sub.3 represents hydrogen, halogen,
cyano, C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 haloalkyl,
C.sub.2-C.sub.4 alkenyl, C.sub.2-C.sub.4 alkynyl, C.sub.1-C.sub.4
alkoxy, C.sub.3-C.sub.6 cycloalkyl, C.sub.1-C.sub.4 alkylthio,
C.sub.1-C.sub.4 alkylsulfinyl or C.sub.1-C.sub.4 alkylsulfonyl.
[0102] Favourably, R.sub.3 represents hydrogen, halogen, cyano,
C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 haloalkyl, C.sub.2-C.sub.4
alkenyl, C.sub.2-C.sub.4 alkynyl, C.sub.1-C.sub.4 alkoxy,
C.sub.3-C.sub.6 cycloalkyl, C.sub.1-C.sub.4 alkylthio,
C.sub.1-C.sub.4 alkylsulfinyl or C.sub.1-C.sub.4 alkylsulfonyl.
[0103] Even more favourably, R.sub.3 represents hydrogen, halogen,
cyano, C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 haloalkyl,
C.sub.2-C.sub.4 alkynyl, C.sub.1-C.sub.4 alkoxy or C.sub.3-C.sub.6
cycloalkyl.
[0104] More favourably again, R.sub.3 represents hydrogen, halogen,
C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 haloalkyl, cyclopropyl,
ethynyl or C.sub.1-C.sub.4 alkoxy.
[0105] Yet more favourably, R.sub.3 is selected from hydrogen,
bromine, iodine, methyl, CHF.sub.2, cyclopropyl, ethynyl and
methoxy.
[0106] Yet more favourably still, R.sub.3 represents hydrogen,
bromine, iodine, methyl, difluoromethyl or methoxy.
[0107] Most preferably, R.sub.3 represents bromine or methyl.
[0108] R.sub.4 represents hydrogen, halogen, cyano, amino,
C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 haloalkyl, C.sub.3-C.sub.6
cycloalkyl, C.sub.2-C.sub.4 alkenyl, C.sub.2-C.sub.4 alkynyl,
C.sub.1-C.sub.4 alkoxy, C.sub.1-C.sub.4 haloalkoxy, C.sub.1-C.sub.4
alkylthio, C.sub.1-C.sub.4 alkylsulfinyl, C.sub.1-C.sub.4
alkylsulfonyl, methylamino or dimethylamino.
[0109] Preferably, R.sub.4 is selected from hydrogen, fluorine,
chlorine, bromine, C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 alkenyl,
C.sub.1-C.sub.4 haloalkyl, C.sub.1-C.sub.4 alkoxy and
C.sub.3-C.sub.6 cycloalkyl.
[0110] More preferably, R.sub.4 is selected from fluorine,
chlorine, bromine, C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 alkenyl,
C.sub.1-C.sub.4 haloalkyl, C.sub.1-C.sub.4 alkoxy and
C.sub.3-C.sub.6 cycloalkyl.
[0111] Even more preferably, R.sub.4 is selected from fluorine,
chlorine, methyl, ethyl, ethenyl, propyl, propenyl, isopropyl,
isopropenyl, cyclopropanyl, methoxy, ethoxy, monofluoromethyl,
polyfluoromethyl, monofluoroethyl and polyfluoromethyl.
[0112] More preferably again, R.sub.4 is selected from methyl,
ethyl, methoxy, fluorine and chlorine.
[0113] More favourably again, R.sub.4 is selected from methyl,
methoxy, fluorine and chlorine.
[0114] Most preferably, R.sub.4 is methyl.
[0115] In another group of compounds, R.sub.4 is selected from
methoxy, fluorine and chlorine.
[0116] R.sub.5 is hydrogen, C.sub.1-C.sub.12alkyl,
C.sub.3-C.sub.12alkenyl, C.sub.3-C.sub.12alkynyl,
C.sub.1-C.sub.12alkylsulfonyl, C.sub.2-C.sub.12alkenylsulfonyl,
phenylsulfonyl or benzylsulfonyl, or is C.sub.1-C.sub.12alkyl,
C.sub.2-C.sub.12alkenyl, C.sub.2-C.sub.12alkynyl,
C.sub.1-C.sub.12alkylsulfonyl, C.sub.2-C.sub.12alkenylsulfonyl,
phenylsulfonyl or benzylsulfonyl mono- to polysubstituted by
substituents independently selected from the group consisting of
halogen, cyano, nitro, hydroxy, mercapto, azido, formyl,
C.sub.2-C.sub.7alkylcarbonyl, C.sub.2-C.sub.7haloalkylcarbonyl,
C.sub.1-C.sub.6alkyl, C.sub.1-C.sub.6haloalkyl,
C.sub.1-C.sub.6alkoxy, C.sub.1-C.sub.6haloalkoxy,
C.sub.1-C.sub.6alkylthio, C.sub.1-C.sub.6alkylsulfinyl and
C.sub.1-C.sub.6alkylsulfonyl; or
[0117] R.sub.5 is formyl, C.sub.2-C.sub.12 alkylcarbonyl,
C.sub.3-C.sub.12 alkenylcarbonyl, C.sub.3-C.sub.12 alkynylcarbonyl,
C.sub.4-C.sub.12 cycloalkylcarbonyl, benzylcarbonyl,
phenylcarbonyl, C.sub.2-C.sub.12 alkoxycarbonyl,
C.sub.4-C.sub.12alkenyloxycarbonyl, C.sub.4-C.sub.12
alkynyloxycarbonyl, C.sub.4-C.sub.12 cycloalkoxycarbonyl,
benzyloxycarbonyl or phenoxycarbonyl, or is C.sub.2-C.sub.12
alkylcarbonyl, C.sub.3-C.sub.12 alkenylcarbonyl, C.sub.3-C.sub.12
alkynylcarbonyl, C.sub.4-C.sub.12 cycloalkylcarbonyl,
benzylcarbonyl, phenylcarbonyl, C.sub.2-C.sub.12 alkoxycarbonyl,
C.sub.4-C.sub.12 alkenyloxycarbonyl, C.sub.4-C.sub.12
alkynyloxycarbonyl, C.sub.4-C.sub.12 cycloalkoxycarbonyl,
benzyloxycarbonyl or phenoxycarbonyl mono- to polysubstituted by
substituents independently selected from the group consisting of
halogen, cyano, C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6 haloalkyl
and C.sub.1-C.sub.6 alkoxy; or
[0118] R.sub.5 is (R.sub.51)(R.sub.52)(R.sub.53)Si--,
(R.sub.51)(R.sub.52)(R.sub.53)Si--(C.sub.1-C.sub.12alkyl)-,
(R.sub.51)(R.sub.52)(R.sub.53)Si--(C.sub.3-C.sub.8cycloalkyl)-,
(R.sub.54O)(R.sub.55O)(R.sub.56O)Si--,
(R.sub.54O)(R.sub.55O)(R.sub.56O)Si--(C.sub.1-C.sub.12alkyl)- or
(R.sub.54O)(R.sub.55O)(R.sub.56O)Si--(C.sub.3-C.sub.8cycloalkyl)-;
or R.sub.5 is C.sub.1-C.sub.6alkyl-B--C.sub.1-C.sub.12alkyl-,
C.sub.2-C.sub.6alkenyl-B--C.sub.1-C.sub.12alkyl-,
C.sub.2-C.sub.6alkynyl-B--C.sub.1-C.sub.12alkyl-,
C.sub.3-C.sub.8cycloalkyl-B--C.sub.1-C.sub.12alkyl-,
benzyl-B--C.sub.1-C.sub.12alkyl-, phenyl-B--C.sub.1-C.sub.12alkyl-,
C.sub.1-C.sub.6alkyl-B--C.sub.2-C.sub.12alkenyl-,
C.sub.2-C.sub.6alkenyl-B--C.sub.2-C.sub.12alkenyl-,
C.sub.2-C.sub.6alkynyl-B--C.sub.2-C.sub.12alkenyl-,
C.sub.3-C.sub.8cycloalkyl-B--C.sub.2-C.sub.12alkenyl-,
benzyl-B--C.sub.2-C.sub.12alkenyl-,
phenyl-B--C.sub.2-C.sub.12alkenyl-,
C.sub.1-C.sub.6alkyl-B--C.sub.2-C.sub.12alkynyl-,
C.sub.2-C.sub.6alkenyl-B--C.sub.2-C.sub.12alkynyl-,
C.sub.2-C.sub.6alkynyl-B--C.sub.2-C.sub.12alkynyl-,
C.sub.3-C.sub.8cycloalkyl-B--C.sub.2-C.sub.12alkynyl-,
benzyl-B--C.sub.2-C.sub.12alkynyl-,
phenyl-B--C.sub.2-C.sub.12alkynyl-,
C.sub.1-C.sub.6alkyl-B--C.sub.3-C.sub.8cycloalkyl-,
C.sub.2-C.sub.6alkenyl-B--C.sub.3-C.sub.8cycloalkyl-,
C.sub.2-C.sub.6alkynyl-B--C.sub.3-C.sub.8cycloalkyl-,
C.sub.3-C.sub.8cycloalkyl-B--C.sub.3-C.sub.8cycloalkyl-,
benzyl-B--C.sub.3-C.sub.12cycloalkyl- or
phenyl-B--C.sub.3-C.sub.12cycloalkyl-, wherein the group B is
selected from --C(.dbd.O)--, --C(.dbd.S)--, --C(.dbd.NOR.sub.59)--,
--C(R.sub.60).dbd.NO--, --ON.dbd.C(R.sub.60)--, --O--C(.dbd.O)--,
--C(.dbd.O)--O--, --O--, --S--, --S(.dbd.O)--, --S(.dbd.O).sub.2--,
--S(.dbd.O)(.dbd.NR.sub.13)--, --S(.dbd.O)(R.sub.14).dbd.N--,
--N.dbd.S(.dbd.O)(R.sub.14)--, --N(R.sub.62)--C.dbd.O)--,
--C.dbd.O)--N(R.sub.62)--, --N(R.sub.62)--SO.sub.2-- or
--SO.sub.2--N(R.sub.62)--; or
[0119] R.sub.5 is C.sub.1-C.sub.6alkyl-B--C.sub.1-C.sub.12alkyl-,
C.sub.2-C.sub.6alkenyl-B--C.sub.1-C.sub.12alkyl-,
C.sub.2-C.sub.6alkynyl-B--C.sub.1-C.sub.12alkyl-,
C.sub.3-C.sub.8cycloalkyl-B--C.sub.1-C.sub.12alkyl-,
benzyl-B--C.sub.1-C.sub.12alkyl-, phenyl-B--C.sub.1-C.sub.12alkyl-,
C.sub.1-C.sub.6alkyl-B--C.sub.2-C.sub.12alkenyl-,
C.sub.2-C.sub.6alkenyl-B--C.sub.2-C.sub.12alkenyl-,
C.sub.2-C.sub.6alkynyl-B--C.sub.2-C.sub.12alkenyl-,
C.sub.3-C.sub.8cycloalkyl-B--C.sub.2-C.sub.12alkenyl-,
benzyl-B--C.sub.2-C.sub.12alkenyl-,
phenyl-B--C.sub.2-C.sub.12alkenyl-,
C.sub.1-C.sub.6alkyl-B--C.sub.2-C.sub.12alkynyl-,
C.sub.2-C.sub.6alkenyl-B--C.sub.2-C.sub.12alkynyl-,
C.sub.2-C.sub.6alkynyl-B--C.sub.2-C.sub.12alkynyl-,
C.sub.3-C.sub.8cycloalkyl-B--C.sub.2-C.sub.12alkynyl-,
benzyl-B--C.sub.2-C.sub.12alkynyl-,
phenyl-B--C.sub.2-C.sub.12alkynyl-,
C.sub.1-C.sub.6alkyl-B--C.sub.3-C.sub.8cycloalkyl-,
C.sub.2-C.sub.6alkenyl-B--C.sub.3-C.sub.8cycloalkyl-,
C.sub.2-C.sub.6alkynyl-B--C.sub.3-C.sub.8cycloalkyl-,
C.sub.3-C.sub.8cycloalkyl-B--C.sub.3-C.sub.8cycloalkyl-,
benzyl-B--C.sub.3-C.sub.12cycloalkyl-,
phenyl-B--C.sub.3-C.sub.12cycloalkyl-, all of which, in turn, are
mono- to poly-substituted by substituents independently selected
from the group consisting of halogen, cyano, hydroxy, mercapto,
C.sub.1-C.sub.6 haloalkyl, C.sub.1-C.sub.6 alkoxy, formyl,
C.sub.2-C.sub.6 alkylcarbonyl, C.sub.1-C.sub.6 alkylthio,
C.sub.1-C.sub.6 alkylsulfinyl and C.sub.1-C.sub.6 alkylsulfonyl;
or
[0120] R.sub.5 is A-, A-(C.sub.1-C.sub.6alkyl)-,
A-O--(C.sub.1-C.sub.6alkyl)-, A-(C.sub.3-C.sub.6alkenyl)-,
A-O--(C.sub.4-C.sub.6alkenyl)-, A-(C.sub.3-C.sub.6-alkynyl)-,
A-O--(C.sub.4-C.sub.6alkynyl)-, A-(C.sub.3-C.sub.8cycloalkyl)- or
A-O--(C.sub.3-C.sub.8cycloalkyl)-; or
[0121] wherein A is a three- to ten-membered monocyclic or fused
bicyclic ring system which can be aromatic, partially saturated or
fully saturated and can contain 1 to 4 hetero atoms selected from
the group consisting of nitrogen, oxygen and sulphur, it not being
possible for each ring system to contain --O--O--, --S--S-- and
--O--S-- fragments, and it being possible for the three- to
ten-membered ring system to be itself mono- or polysubstituted
[0122] A1) by substituents independently selected from the group
consisting of
[0123] halogen, cyano, nitro, hydroxy, mercapto, nitro, azido,
formyl, carboxy, .dbd.O, .dbd.S, C.sub.1-C.sub.6 alkyl,
C.sub.2-C.sub.6 alkenyl, C.sub.2-C.sub.6 alkynyl, C.sub.3-C.sub.8
cycloalkyl, C.sub.1-C.sub.6 haloalkyl, C.sub.2-C.sub.6 haloalkenyl,
C.sub.2-C.sub.6 haloalkynyl, C.sub.3-C.sub.8 halocycloalkyl,
C.sub.1-C.sub.6 alkoxy, C.sub.1-C.sub.6 haloalkoxy, C.sub.3-C.sub.6
alkenyloxy, C.sub.3-C.sub.6 haloalkenyloxy, C.sub.3-C.sub.6
alkynyloxy, C.sub.3-C.sub.8 cycloalkyloxy, benzyl, benzyloxy,
phenyl and phenoxy, where the benzyl, benzyloxy, phenyl and
phenoxy, in turn, may be mono- to polysubstituted by substituents
independently selected from the group consisting of halogen, cyano,
nitro, hydroxy, mercapto, amino, C.sub.1-C.sub.6 alkyl,
C.sub.1-C.sub.6 haloalkyl, C.sub.1-C.sub.6 alkoxy, C.sub.1-C.sub.6
haloalkoxy, C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6
alkylsulfinyl and C.sub.1-C.sub.6 alkylsulfonyl; or
[0124] A2) by substituents independently selected form the group
consisting of (R.sub.14)S(.dbd.O)(.dbd.NR.sub.13)--,
(R.sub.14)(R.sub.15)S(.dbd.O).dbd.N--;
--Si(R.sub.51)(R.sub.52)(R.sub.53), --NR.sub.57R.sub.58,
--C(.dbd.O)NR.sub.57R.sub.58, --C(.dbd.S)NR.sub.57R.sub.58,
HC(.dbd.NOR.sub.59)--, (C.sub.1-C.sub.6alkyl)C(.dbd.NOR.sub.59)--,
(C.sub.1-C.sub.6haloalkyl)C(.dbd.NOR.sub.59)--,
(C.sub.1-C.sub.6alkyl)C(.dbd.NOR.sub.59)C.sub.1-C.sub.6alkyl-,
(C.sub.1-C.sub.6haloalkyl)C(.dbd.NOR.sub.59)C.sub.1-C.sub.6alkyl-,
N(C.sub.1-C.sub.6alkyl)aminosulfonyl and
N,N-di(C.sub.1-C.sub.6alkyl)aminosulfonyl; or
[0125] A3) by substituents independently selected from the group
consisting of
[0126] formyl, C.sub.2-C.sub.7 alkylcarbonyl, C.sub.2-C.sub.7
haloalkylcarbonyl, C.sub.3-C.sub.7 alkenylcarbonyl, C.sub.3-C.sub.7
haloalkenylcarbonyl, C.sub.4-C.sub.9 cycloalkylcarbonyl,
C.sub.4-C.sub.9 halocycloalkylcarbonyl, C.sub.2-C.sub.7
alkoxycarbonyl, C.sub.2-C.sub.7 haloalkoxycarbonyl, C.sub.3-C.sub.7
alkenyloxycarbonyl, C.sub.3-C.sub.7 alkynyloxycarbonyl,
C.sub.4-C.sub.9 cycloalkoxycarbonyl, C.sub.2-C.sub.7
alkylthiocarbonyl and benzyloxycarbonyl, and benzyloxycarbonyl
mono- to polysubstituted by substituents independently selected
from the group consisting of halogen, cyano, hydroxy,
C.sub.1-C.sub.6alkyl, C.sub.1-C.sub.6 haloalkyl and C.sub.1-C.sub.6
alkoxy; or A4) by substituents independently selected from the
group consisting of hydroxyl, C.sub.1-C.sub.4 alkyl,
C.sub.2-C.sub.4 alkenyl, C.sub.2-C.sub.4 alkynyl, C.sub.1-C.sub.4
alkoxy, halogen, C.sub.1-C.sub.4 haloalkyl, C.sub.2-C.sub.4
haloalkenyl, cyano, benzyl, phenyl, .dbd.C(R.sup.36').sub.2,
.dbd.N--OH, .dbd.N--O--C.sub.1-C.sub.4-alkyl,
.dbd.N--O--C.sub.3-C.sub.4 alkenyl, .dbd.N--O--C.sub.3-C.sub.4
alkynyl, .dbd.N--O--C.sub.1-C.sub.4 haloalkyl,
.dbd.N--O--C.sub.3-C.sub.4 haloalkenyl, .dbd.N--O-benzyl and
.dbd.N--O-phenyl, wherein the .dbd.N--O-benzyl and .dbd.N--O-phenyl
are optionally substituted by one or more group selected from the
group consisting of halogen, methyl, halomethyl; or
[0127] R.sub.5 is --N.dbd.C(R.sub.8)(R.sub.9); or
[0128] R.sub.5 is a C.sub.8-C.sub.11 spirobicyclic system
containing 0, 1 or 2 O, S or N atoms, wherein there are no adjacent
O atoms, which is optionally substituted by one or more groups
independently selected from halogen, CN, NO.sub.2, OH, SH, CHO,
COOH, tri(C.sub.1-C.sub.6-alkyl)silyl, C.sub.1-C.sub.6 alkyl,
--CH(CH.sub.3)--CH.sub.2--CH.sub.2--CH.sub.3,
--CH--CH(CH.sub.3)--CH.sub.2--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3)--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3).sub.2,
--CH(CH.sub.3)--CH(CH.sub.3).sub.2, C.sub.1-C.sub.6 haloalkyl,
C.sub.3-C.sub.6 cycloalkyl, C.sub.3-C.sub.6 halocycloalkyl,
C.sub.2-C.sub.6 alkenyl, C.sub.2-C.sub.6 haloalkenyl,
C.sub.1-C.sub.6 alkoxy, C.sub.1-C.sub.6 haloalkoxy,
C.sub.2-C.sub.7-alkylcarbonyl, C.sub.2-C.sub.7-alkoxycarbonyl,
C.sub.4-C.sub.7-alkenyloxycarbonyl,
C.sub.4-C.sub.7-alkynyloxycarbonyl, C.sub.1-C.sub.6 alkylthio,
C.sub.1-C.sub.6 alkylsulfinyl, C.sub.1-C.sub.6 alkylsulfonyl,
.dbd.O, --C(.dbd.O)NH.sub.2, --C(.dbd.O)NH(CH.sub.3),
--C(.dbd.O)N(CH.sub.3).sub.2 and --C(.dbd.S)NH.sub.2.
[0129] Preferably, R.sub.5 represents hydrogen, C.sub.1-C.sub.12
alkylsulfonyl, C.sub.1-C.sub.12 alkyl, C.sub.3-C.sub.12 alkenyl,
C.sub.3-C.sub.12 alkynyl, or is C.sub.1-C.sub.12 alkyl,
C.sub.2-C.sub.12 alkenyl, C.sub.2-C.sub.12 alkynyl mono- to
polysubstituted by substituents independently selected from the
group consisting of halogen, cyano, nitro, hydroxy, mercapto,
azido, formyl, C.sub.2-C.sub.7 alkylcarbonyl, C.sub.2-C.sub.7
haloalkylcarbonyl, C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6
haloalkyl, C.sub.1-C.sub.6 alkoxy, C.sub.1-C.sub.6 haloalkoxy,
C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6 alkylsulfinyl and
C.sub.1-C.sub.6 alkylsulfonyl; or
[0130] R.sub.5 is (R.sub.51)(R.sub.52)(R.sub.53)Si--,
(R.sub.51)(R.sub.52)(R.sub.53)Si--(C.sub.1-C.sub.12alkyl)-,
(R.sub.51)(R.sub.52)(R.sub.53)Si--(C.sub.3-C.sub.8cycloalkyl)-,
(R.sub.54O)(R.sub.55O)(R.sub.56O)Si--,
(R.sub.54O)(R.sub.55O)(R.sub.56O)Si--(C.sub.1-C.sub.12alkyl)- or
(R.sub.54O)(R.sub.55O)(R.sub.56O)Si--(C.sub.3-C.sub.8cycloalkyl)-;
or
[0131] R.sub.5 is C.sub.1-C.sub.6alkyl-B--C.sub.1-C.sub.12alkyl-,
C.sub.2-C.sub.6alkenyl-B--C.sub.1-C.sub.12alkyl-,
C.sub.2-C.sub.6alkynyl-B--C.sub.1-C.sub.12alkyl-,
C.sub.3-C.sub.8cycloalkyl-B--C.sub.1-C.sub.12alkyl-,
benzyl-B--C.sub.1-C.sub.12alkyl-, phenyl-B--C.sub.1-C.sub.12alkyl-,
C.sub.1-C.sub.6alkyl-B--C.sub.2-C.sub.12alkenyl-,
C.sub.2-C.sub.6alkenyl-B--C.sub.2-C.sub.12alkenyl-,
C.sub.2-C.sub.6alkynyl-B--C.sub.2-C.sub.12alkenyl-,
C.sub.3-C.sub.8cycloalkyl-B--C.sub.2-C.sub.12alkenyl-,
benzyl-B--C.sub.2-C.sub.12alkenyl-,
phenyl-B--C.sub.2-C.sub.12alkenyl-,
C.sub.1-C.sub.6alkyl-B--C.sub.2-C.sub.12alkynyl-,
C.sub.2-C.sub.6alkenyl-B--C.sub.2-C.sub.12alkynyl-,
C.sub.2-C.sub.6alkynyl-B--C.sub.2-C.sub.12alkynyl-,
C.sub.3-C.sub.8cycloalkyl-B--C.sub.2-C.sub.12alkynyl-,
benzyl-B--C.sub.2-C.sub.12alkynyl-,
phenyl-B--C.sub.2-C.sub.12alkynyl-,
C.sub.1-C.sub.6alkyl-B--C.sub.3-C.sub.8cycloalkyl-,
C.sub.2-C.sub.6alkenyl-B--C.sub.3-C.sub.8cycloalkyl-,
C.sub.2-C.sub.6alkynyl-B--C.sub.3-C.sub.8cycloalkyl-,
C.sub.3-C.sub.8cycloalkyl-B--C.sub.3-C.sub.8cycloalkyl-,
benzyl-B--C.sub.3-C.sub.12cycloalkyl- or
phenyl-B--C.sub.3-C.sub.12cycloalkyl-, wherein the group B is
selected from --C(.dbd.O)--, --C(.dbd.S)--, --C(.dbd.NOR.sub.59)--,
--C(R.sub.60).dbd.NO--, --ON.dbd.C(R.sub.60)--, --O--C(.dbd.O)--,
--C(.dbd.O)--O--, --O--, --S--, --S(.dbd.O)--, --S(.dbd.O).sub.2--,
--S(.dbd.O)(.dbd.NR.sub.13)--, --S(.dbd.O)(R.sub.14).dbd.N--,
--N.dbd.S(.dbd.O)(R.sub.14)--, --N(R.sub.62)--C.dbd.O)--,
--C.dbd.O)--N(R.sub.62)--, --N(R.sub.62)--SO.sub.2-- or
--SO.sub.2--N(R.sub.62)--; or
[0132] R.sub.5 is C.sub.1-C.sub.6alkyl-B--C.sub.1-C.sub.12alkyl-,
C.sub.2-C.sub.6alkenyl-B--C.sub.1-C.sub.12alkyl-,
C.sub.2-C.sub.6alkynyl-B--C.sub.1-C.sub.12alkyl-,
C.sub.3-C.sub.8cycloalkyl-B--C.sub.1-C.sub.12alkyl-,
benzyl-B--C.sub.1-C.sub.12alkyl-, phenyl-B--C.sub.1-C.sub.12alkyl-,
C.sub.1-C.sub.6alkyl-B--C.sub.2-C.sub.12alkenyl-,
C.sub.2-C.sub.6alkenyl-B--C.sub.2-C.sub.12alkenyl-,
C.sub.2-C.sub.6alkynyl-B--C.sub.2-C.sub.12alkenyl-,
C.sub.3-C.sub.8cycloalkyl-B--C.sub.2-C.sub.12alkenyl-,
benzyl-B--C.sub.2-C.sub.12alkenyl-,
phenyl-B--C.sub.2-C.sub.12alkenyl-,
C.sub.1-C.sub.6alkyl-B--C.sub.2-C.sub.12alkynyl-,
C.sub.2-C.sub.6alkenyl-B--C.sub.2-C.sub.12alkynyl-,
C.sub.2-C.sub.6alkynyl-B--C.sub.2-C.sub.12alkynyl-,
C.sub.3-C.sub.8cycloalkyl-B--C.sub.2-C.sub.12alkynyl-,
benzyl-B--C.sub.2-C.sub.12alkynyl-,
phenyl-B--C.sub.2-C.sub.12alkynyl-,
C.sub.1-C.sub.6alkyl-B--C.sub.3-C.sub.8cycloalkyl-,
C.sub.2-C.sub.6alkenyl-B--C.sub.3-C.sub.8cycloalkyl-,
C.sub.2-C.sub.6alkynyl-B--C.sub.3-C.sub.8cycloalkyl-,
C.sub.3-C.sub.8cycloalkyl-B--C.sub.3-C.sub.8cycloalkyl-,
benzyl-B--C.sub.3-C.sub.12cycloalkyl-,
phenyl-B--C.sub.3-C.sub.12cycloalkyl-, all of which, in turn, are
mono- to polysubstituted by substituents independently selected
from the group consisting of halogen, cyano, hydroxy, mercapto,
C.sub.1-C.sub.6 haloalkyl, C.sub.1-C.sub.6 alkoxy, formyl,
C.sub.2-C.sub.6 alkylcarbonyl, C.sub.1-C.sub.6 alkylthio,
C.sub.1-C.sub.6 alkylsulfinyl and C.sub.1-C.sub.6 alkylsulfonyl;
or
[0133] R.sub.5 is selected from A-, A-(C.sub.1-C.sub.6alkyl)-,
A-O--(C.sub.1-C.sub.6alkyl)-, A-(C.sub.3-C.sub.6alkenyl)-,
A-O--(C.sub.4-C.sub.6alkenyl)-, A-(C.sub.3-C.sub.6-alkynyl)-,
A-O--(C.sub.4-C.sub.6alkynyl)-, A-(C.sub.3-C.sub.8cycloalkyl)- and
A-O--(C.sub.3-C.sub.8cycloalkyl)-;
[0134] wherein A is a three- to ten-membered monocyclic or fused
bicyclic ring system which can be aromatic, partially saturated or
fully saturated and can contain 1 to 4 hetero atoms selected from
the group consisting of nitrogen, oxygen and sulphur, it not being
possible for each ring system to contain --O--O--, --S--S-- and
--O--S-- fragments, and it being possible for the three- to
ten-membered ring system to be itself mono- or polysubstituted
[0135] A1) by substituents independently selected from the group
consisting of
[0136] halogen, cyano, nitro, hydroxy, mercapto, nitro, azido,
formyl, carboxy, .dbd.O, .dbd.S, C.sub.1-C.sub.6 alkyl,
C.sub.2-C.sub.6 alkenyl, C.sub.2-C.sub.6 alkynyl, C.sub.3-C.sub.8
cycloalkyl, C.sub.1-C.sub.6 haloalkyl, C.sub.2-C.sub.6 haloalkenyl,
C.sub.2-C.sub.6 haloalkynyl, C.sub.3-C.sub.8 halocycloalkyl,
C.sub.1-C.sub.6 alkoxy, C.sub.1-C.sub.6 haloalkoxy, C.sub.3-C.sub.6
alkenyloxy, C.sub.3-C.sub.6 haloalkenyloxy, C.sub.3-C.sub.6
alkynyloxy, C.sub.3-C.sub.8 cycloalkyloxy, C.sub.3-C.sub.8
halocycloalkyloxy, C.sub.3-C.sub.8 cycloalkenyloxy, C.sub.3-C.sub.8
halocycloalkenyloxy, benzyl, benzyloxy, phenyl and phenoxy, where
the benzyl, benzyloxy, phenyl and phenoxy, in turn, may be mono- to
polysubstituted by substituents independently selected from the
group consisting of halogen, cyano, nitro, hydroxy, mercapto,
amino, C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6 haloalkyl,
C.sub.1-C.sub.6 alkoxy, C.sub.1-C.sub.6 haloalkoxy, C.sub.1-C.sub.6
alkylthio, C.sub.1-C.sub.6 alkylsulfinyl and C.sub.1-C.sub.6
alkylsulfonyl; or
[0137] A3) by substituents independently selected from the group
consisting of
[0138] formyl, C.sub.2-C.sub.7 alkylcarbonyl, C.sub.2-C.sub.7
haloalkylcarbonyl, C.sub.3-C.sub.7 alkenylcarbonyl, C.sub.3-C.sub.7
haloalkenylcarbonyl, C.sub.4-C.sub.9 cycloalkylcarbonyl,
C.sub.2-C.sub.7 alkoxycarbonyl, C.sub.4-C.sub.7 alkenyloxycarbonyl,
C.sub.4-C.sub.7 alkynyloxycarbonyl, C.sub.4-C.sub.9
cycloalkoxycarbonyl and benzyloxycarbonyl, and benzyloxycarbonyl
mono- to polysubstituted by substituents independently selected
from the group consisting of halogen, cyano, hydroxy,
C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6 haloalkyl and
C.sub.1-C.sub.6 alkoxy; or
[0139] A4) by substituents independently selected from the group
consisting of hydroxyl, C.sub.1-C.sub.4 alkyl, C.sub.2-C.sub.4
alkenyl, C.sub.2-C.sub.4 alkynyl, C.sub.1-C.sub.4 alkoxy, halogen,
C.sub.1-C.sub.4 haloalkyl, C.sub.2-C.sub.4 haloalkenyl, cyano,
benzyl, phenyl, .dbd.C(R.sup.36').sub.2, .dbd.N--OH,
.dbd.N--O--C.sub.1-C.sub.4-alkyl, .dbd.N--O--C.sub.3-C.sub.4
alkenyl, .dbd.N--O--C.sub.3-C.sub.4 alkynyl,
.dbd.N--O--C.sub.1-C.sub.4 haloalkyl, .dbd.N--O--C.sub.3-C.sub.4
haloalkenyl, .dbd.N--O-benzyl and .dbd.N--O-phenyl, wherein the
.dbd.N--O-benzyl and .dbd.N--O-phenyl are optionally substituted by
one or more group selected from the group consisting of halogen,
methyl, halomethyl; or
[0140] R.sub.5 is a C.sub.8-C.sub.11 spirobicyclic system
containing 0, 1 or 2 O, S or N atoms, wherein there are no adjacent
O atoms, which is optionally substituted by one or more groups
independently selected from halogen, CN, NO.sub.2, OH, SH, CHO,
COOH, tri(C.sub.1-C.sub.6-alkyl)silyl, C.sub.1-C.sub.6 alkyl,
--CH(CH.sub.3)--CH.sub.2--CH.sub.2--CH.sub.3,
--CH--CH(CH.sub.3)--CH.sub.2--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3)--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3).sub.2,
--CH(CH.sub.3)--CH(CH.sub.3).sub.2, C.sub.1-C.sub.6 haloalkyl,
C.sub.3-C.sub.6 cycloalkyl, C.sub.3-C.sub.6 halocycloalkyl,
C.sub.2-C.sub.6 alkenyl, C.sub.2-C.sub.6 haloalkenyl,
C.sub.1-C.sub.6 alkoxy, C.sub.1-C.sub.6 haloalkoxy,
C.sub.2-C.sub.7-alkylcarbonyl, C.sub.2-C.sub.7-alkoxycarbonyl,
C.sub.4-C.sub.7-alkenyloxycarbonyl,
C.sub.4-C.sub.7-alkynyloxycarbonyl, C.sub.1-C.sub.6 alkylthio,
C.sub.1-C.sub.6 alkylsulfinyl, C.sub.1-C.sub.6 alkylsulfonyl,
.dbd.O, --C(.dbd.O)NH.sub.2, --C(.dbd.O)NH(CH.sub.3),
--C(.dbd.O)N(CH.sub.3).sub.2 and --C(.dbd.S)NH.sub.2.
[0141] More preferably, R.sub.5 is selected from G.sup.1, G.sup.2,
G.sup.3-G.sup.4, G.sup.5, G.sup.6-G.sup.7, G.sup.8, G.sup.9,
G.sup.10-G.sup.11, G.sup.12, G.sup.13, G.sup.14, G.sup.15 and
G.sup.16.
[0142] More preferably again, R.sub.5 is selected from G.sup.1,
G.sup.2, G.sup.5, G.sup.6-G.sup.7, G.sup.8, G.sup.9,
G.sup.10-G.sup.11, G.sup.12, G.sup.14, G.sup.15 and G.sup.16.
[0143] More favourably again, R.sub.5 is selected from G.sup.2,
G.sup.5, G.sup.6-G.sup.7, G.sup.8, G.sup.9, G.sup.10-G.sup.11,
G.sup.14 and G.sup.16.
[0144] Most preferably, R.sub.5 is selected from G.sup.2, G.sup.5,
G.sup.8 and G.sup.10-G.sup.11.
[0145] R.sub.6 is selected from hydrogen and SH.
[0146] Most preferably, R.sub.6 is hydrogen.
[0147] In one group of compounds, R.sub.6 is SH.
[0148] R.sub.7 is hydrogen, halogen or C.sub.1-C.sub.4 alkyl.
[0149] Preferably, R.sub.7 is hydrogen or C.sub.1-C.sub.4
alkyl.
[0150] Most preferably, R.sub.7 is hydrogen.
[0151] R.sub.8 and R.sub.9, independently from each other, are
hydrogen, halogen, cyano, C.sub.1-C.sub.12 alkyl, C.sub.2-C.sub.12
alkenyl, C.sub.2-C.sub.12 alkynyl, C.sub.1-C.sub.12 alkoxy, formyl,
C.sub.2-C.sub.12 alkylcarbonyl, C.sub.3-C.sub.12 alkenylcarbonyl,
carboxy, C.sub.2-C.sub.12 alkoxycarbonyl and C.sub.4-C.sub.12
alkenyloxycarbonyl, or C.sub.1-C.sub.12 alkyl, C.sub.2-C.sub.12
alkenyl, C.sub.2-C.sub.12 alkynyl, C.sub.1-C.sub.12 alkoxy,
C.sub.2-C.sub.12 alkylcarbonyl, C.sub.3-C.sub.12 alkenylcarbonyl,
C.sub.2-C.sub.12 alkoxycarbonyl and C.sub.4-C.sub.12
alkenyloxycarbonyl mono- to polysubstituted by substituents
independently selected from the group consisting of halogen, cyano,
nitro, hydroxy, mercapto, C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6
haloalkyl, C.sub.1-C.sub.6 alkoxy, C.sub.1-C.sub.6 haloalkoxy,
C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6 alkylsulfinyl and
C.sub.1-C.sub.6 alkylsulfonyl; or R.sub.8 and R.sub.9 together from
a C.sub.2-C.sub.8 alkylene bridge which may optionally be mono- to
polysubstituted by substituents independently selected from the
group consisting of halogen, cyano, C.sub.1-C.sub.6 alkyl and
C.sub.1-C.sub.6 haloalkyl; or R.sub.8 and R.sub.9, independently
from each other, are the groups A-, A-O-- or
A-(C.sub.1-C.sub.6alkyl)-.
[0152] R.sub.10 is H, C.sub.1-C.sub.4 alkyl, C.sub.2-C.sub.4
alkenyl or C.sub.1-C.sub.4 haloalkyl.
[0153] R.sub.13 is hydrogen, C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6
haloalkyl, C.sub.3-C.sub.6 alkenyl, C.sub.3-C.sub.6 haloalkenyl,
C.sub.3-C.sub.6 alkynyl, C.sub.3-C.sub.8 cycloalkyl,
C.sub.3-C.sub.8 halocycloalkyl, phenyl and benzyl, or is phenyl and
benzyl mono- to polysubstituted by halogen, cyano, hydroxy,
C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6 haloalkyl or C.sub.1-C.sub.6
alkoxy.
[0154] R.sub.14 and R.sub.15, independently of each other, are
C.sub.1-C.sub.6 alkyl, C.sub.3-C.sub.8 cycloalkyl, C.sub.1-C.sub.6
haloalkyl, C.sub.3-C.sub.8 halocycloalkyl, C.sub.2-C.sub.6 alkenyl,
C.sub.2-C.sub.6 haloalkenyl, C.sub.2-C.sub.6 alkynyl, benzyl or
phenyl, or benzyl or phenyl independently of each other,
substituted by substituents selected from the group consisting of
halogen, cyano, hydroxy, C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6
haloalkyl and C.sub.1-C.sub.6 alkoxy.
[0155] R.sub.51, R.sub.52, R.sub.53, independently of each other,
are halogen, cyano, C.sub.1-C.sub.6 alkyl, C.sub.2-C.sub.6alkenyl,
C.sub.3-C.sub.8 cycloalkyl, C.sub.5-C.sub.8 cycloalkenyl,
C.sub.2-C.sub.6 alkynyl, C.sub.1-C.sub.6 alkoxy, benzyl or
phenyl.
[0156] R.sub.54, R.sub.55, R.sub.56, independently of each other,
are C.sub.1-C.sub.6 alkyl, C.sub.3-C.sub.6 alkenyl, C.sub.3-C.sub.8
cycloalkyl, C.sub.3-C.sub.6 alkynyl, benzyl or phenyl.
[0157] R.sub.57 and R.sub.58, independently of each other, are
hydrogen, C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6 haloalkyl,
C.sub.3-C.sub.6 alkenyl, C.sub.3-C.sub.6 haloalkenyl,
C.sub.3-C.sub.6 alkynyl, C.sub.3-C.sub.8 cycloalkyl,
C.sub.3-C.sub.8 halocycloalkyl, phenyl or benzyl, where phenyl or
benzyl for their part may be mono- to polysubstituted on the phenyl
ring by substituents independently selected from the group
consisting of halogen, cyano, hydroxy, C.sub.1-C.sub.6 alkyl,
C.sub.1-C.sub.6 haloalkyl and C.sub.1-C.sub.6 alkoxy, or R.sub.57
and R.sub.58 together with their interconnecting nitrogen atom are
aziridino, azetidino, pyrazolino, pyrazolidino, pyrrolino,
pyrrolidino, imidazolino, imidazolidino, triazolino, tetrazolino,
piperazino, piperidino, morpholino, thiomorpholino, each of which,
in turn, may be mono- or polysubstituted by substituents selected
from the group consisting of methyl, halogen, cyano.
[0158] R.sub.59 is hydrogen, C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6
haloalkyl, C.sub.3-C.sub.6 alkenyl, C.sub.3-C.sub.6 haloalkenyl,
C.sub.3-C.sub.6 alkynyl, C.sub.3-C.sub.8 cycloalkyl,
C.sub.3-C.sub.8 halocycloalkyl, benzyl and phenyl, and benzyl and
phenyl mono- to polysubstituted by halogen, cyano, hydroxy,
C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6 haloalkyl or C.sub.1-C.sub.6
alkoxy.
[0159] R.sub.60 is hydrogen, C.sub.1-C.sub.6 alkyl, C.sub.3-C.sub.8
cycloalkyl, C.sub.1-C.sub.6 haloalkyl, C.sub.3-C.sub.8
halocycloalkyl, C.sub.2-C.sub.6 alkenyl, C.sub.2-C.sub.6
haloalkenyl, C.sub.2-C.sub.6 alkynyl, benzyl or phenyl, or benzyl
or phenyl mono- to polysubstituted by substituents independently
selected from the group consisting of halogen, cyano, hydroxy,
C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6 haloalkyl and
C.sub.1-C.sub.6 alkoxy;
[0160] R.sub.62 is hydrogen, C.sub.1-C.sub.6 alkyl, C.sub.3-C.sub.8
cycloalkyl, C.sub.1-C.sub.6 haloalkyl, C.sub.3-C.sub.8
halocycloalkyl, C.sub.3-C.sub.6 alkenyl, C.sub.3-C.sub.6 alkynyl,
benzyl or phenyl, or benzyl or phenyl mono- to polysubstituted by
substituents independently selected from the group consisting of
halogen, cyano, hydroxy, C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6
haloalkyl and C.sub.1-C.sub.6 alkoxy.
[0161] G.sup.1 is a C.sub.8-C.sub.10 fused bicyclic ring system
which may be saturated or comprise one carbon-carbon double bond
and is optionally substituted by one or more groups independently
selected from hydroxyl, C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4
alkoxy, halogen, C.sub.1-C.sub.4 haloalkyl and cyano.
[0162] More preferably, G.sup.1 is a C.sub.9-C.sub.10 fused
bicyclic ring system which may be saturated or comprise one
carbon-carbon double bond and is optionally substituted by one or
more groups independently selected from hydroxyl, C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 alkoxy, halogen, C.sub.1-C.sub.4 haloalkyl
and cyano.
[0163] More preferably again, G.sup.1 is a C.sub.9-C.sub.10 fused
bicyclic ring system which may be saturated or comprise one
carbon-carbon double bond and is optionally substituted by one or
more groups independently selected from C.sub.1-C.sub.4 alkyl,
fluorine, methoxy and C.sub.1-C.sub.4 fluoroalkyl.
[0164] More favourably, G.sup.1 is a saturated C.sub.9-C.sub.10
fused bicyclic ring system which is optionally substituted by one
or more groups independently selected from C.sub.1-C.sub.4 alkyl,
fluoro, methoxy and C.sub.1-C.sub.4 fluoroalkyl.
[0165] More favourably again, G.sup.1 is a saturated C.sub.10 fused
bicyclic ring system which is optionally substituted by one or more
groups independently selected from C.sub.1-C.sub.4 alkyl, fluorine,
methoxy and C.sub.1-C.sub.4 fluoroalkyl.
[0166] Most preferably, G.sup.1 is a saturated C.sub.10 fused
bicyclic ring system.
[0167] G.sup.2 is C.sub.3-C.sub.6 cycloalkenyl, which is optionally
substituted by one or more groups independently selected from
halogen, CN, NO.sub.2, OH, SH, CHO, COOH,
tri(C.sub.1-C.sub.6-alkyl)silyl, ethyl, n-propyl, iso-propyl,
n-butyl, iso-butyl, sec-butyl, tert-butyl, n-pentyl,
--CH(CH.sub.3)--CH.sub.2--CH.sub.2--CH.sub.3,
--CH--CH(CH.sub.3)--CH.sub.2--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3)--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3).sub.2,
--CH(CH.sub.3)--CH(CH.sub.3).sub.2, C.sub.2-C.sub.6 haloalkyl,
C.sub.3-C.sub.6 cycloalkyl, C.sub.3-C.sub.6 halocycloalkyl,
C.sub.2-C.sub.6 alkenyl, C.sub.2-C.sub.6 haloalkenyl,
C.sub.1-C.sub.6 alkoxy, C.sub.1-C.sub.6 haloalkoxy, C.sub.2-C.sub.7
alkylcarbonyl, C.sub.2-C.sub.7 alkoxycarbonyl, C.sub.4-C.sub.7
alkenyloxycarbonyl, C.sub.4-C.sub.7 alkynyloxycarbonyl,
C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6 alkylsulfinyl,
C.sub.1-C.sub.6 alkylsulfonyl, --C(.dbd.O)NH.sub.2,
--C(.dbd.O)NH(CH.sub.3), --C(.dbd.O)N(CH.sub.3).sub.2 and
--C(.dbd.S)NH.sub.2;
[0168] More preferably again, G.sup.2 is C.sub.3-C.sub.6
cycloalkenyl, which is optionally substituted by one or more groups
independently selected from halogen, ethyl, n-propyl, iso-propyl,
n-butyl, iso-butyl, sec-butyl, tert-butyl, n-pentyl,
--CH(CH.sub.3)--CH.sub.2--CH.sub.2--CH.sub.3,
--CH--CH(CH.sub.3)--CH.sub.2--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3)--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3).sub.2,
--CH(CH.sub.3)--CH(CH.sub.3).sub.2, C.sub.2-C.sub.6 haloalkyl,
C.sub.1-C.sub.6 alkoxy and C.sub.1-C.sub.6 alkylthio.
[0169] Favourably, G.sup.2 is C.sub.5-C.sub.6 cycloalkenyl, which
is optionally substituted by one or more groups independently
selected from halogen, ethyl, n-propyl, iso-propyl, n-butyl,
iso-butyl, sec-butyl, tert-butyl, n-pentyl,
--CH(CH.sub.3)--CH.sub.2--CH.sub.2--CH.sub.3,
--CH--CH(CH.sub.3)--CH.sub.2--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3)--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3).sub.2,
--CH(CH.sub.3)--CH(CH.sub.3).sub.2, C.sub.2-C.sub.6 haloalkyl and
C.sub.1-C.sub.6 alkoxy.
[0170] More favourably, G.sup.2 is a C.sub.5-C.sub.6 cycloalkenyl
group optionally substituted by one or more groups independently
selected from fluorine, ethyl, n-propyl, iso-propyl, n-butyl,
iso-butyl, sec-butyl, tert-butyl.
[0171] More favourably again, G.sup.2 is a C.sub.5-C.sub.6
cycloalkenyl group optionally substituted by one or more fluorine
atoms.
[0172] Most preferably, G.sup.2 is a C.sub.5-C.sub.6 cycloalkenyl
group.
[0173] In one group of compounds, G.sup.2 is a C.sub.5-C.sub.6
cycloalkenyl group optionally substituted one or more groups
selected from ethyl, n-propyl, iso-propyl, n-butyl, iso-butyl,
sec-butyl, tert-butyl, n-pentyl,
--CH(CH.sub.3)--CH.sub.2--CH.sub.2--CH.sub.3,
--CH--CH(CH.sub.3)--CH.sub.2--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3)--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3).sub.2,
--CH(CH.sub.3)--CH(CH.sub.3).sub.2, C.sub.2-C.sub.6 haloalkyl and
C.sub.1-C.sub.6 alkoxy.
[0174] Preferably in this group of compounds, G.sup.2 is a
C.sub.5-C.sub.6 cycloalkenyl group optionally substituted one or
more groups selected from ethyl, n-propyl, iso-propyl, n-butyl,
iso-butyl, sec-butyl, tert-butyl.
[0175] G.sup.3 is phenyl, which is optionally substituted by one or
more groups independently selected from hydroxyl, C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 haloalkyl, C.sub.2-C.sub.4 alkenyl,
C.sub.2-C.sub.4 alkynyl, C.sub.1-C.sub.4 alkoxy, halogen and cyano,
wherein the alkyl groups are optionally substituted by one or more
halogen.
[0176] More preferably again, G.sup.3 is phenyl, which is
optionally substituted by one or more groups independently selected
from hydroxyl, C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 fluoroalkyl,
C.sub.1-C.sub.4 alkoxy and halogen.
[0177] More favourably again, G.sup.3 is phenyl, which is
optionally substituted by one or more groups independently selected
from hydroxyl, C.sub.1-C.sub.4 alkyl, CHF.sub.2, CF.sub.3,
C.sub.1-C.sub.4 alkoxy and halogen.
[0178] Yet more favourably, G.sup.3 is phenyl, which is optionally
substituted by one or more groups independently selected from
C.sub.1-C.sub.4 alkyl, CHF.sub.2, CF.sub.3, C.sub.1-C.sub.4 alkoxy
and halogen.
[0179] Most preferably, G.sup.3 is phenyl.
[0180] G.sup.4 is C.sub.3-C.sub.12 cycloalkyl which is optionally
substituted by one or more groups independently selected from
hydroxyl, C.sub.1-C.sub.4 alkyl, C.sub.2-C.sub.4 alkenyl,
C.sub.2-C.sub.4 alkynyl, C.sub.1-C.sub.4 alkoxy, halogen and cyano,
wherein the alkyl groups are optionally substituted by one or more
halogen.
[0181] More preferably again, G.sup.4 is C.sub.5-C.sub.6 cycloalkyl
which is optionally substituted by one or more groups independently
selected from hydroxyl, C.sub.1-C.sub.4 alkyl, C.sub.2-C.sub.4
alkenyl, C.sub.2-C.sub.4 alkynyl, C.sub.1-C.sub.4 alkoxy, halogen
and cyano, wherein the alkyl groups are optionally substituted by
one or more halogen.
[0182] More favourably again, G.sup.4 is C.sub.5-C.sub.6 cycloalkyl
which is optionally substituted by one or more groups independently
selected from hydroxyl, C.sub.1-C.sub.4 alkyl, C.sub.2-C.sub.4
alkenyl, C.sub.2-C.sub.4 alkynyl, C.sub.1-C.sub.4 alkoxy and
halogen.
[0183] Yet more favourably, G.sup.4 is C.sub.5-C.sub.6 cycloalkyl
which is optionally substituted by one or more groups independently
selected from C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 alkoxy and
halogen.
[0184] Yet more favourably still, G.sup.4 is cyclohexyl or
cyclopentyl.
[0185] Most preferably, G.sup.4 is cyclohexyl.
[0186] G.sup.5 is C.sub.3-C.sub.7 cycloalkyl, which is optionally
substituted by one or more groups independently selected from
halogen, ON, NO.sub.2, OH, SH, CHO, COOH,
tri(C.sub.1-C.sub.6-alkyl)silyl, ethyl, n-propyl, iso-propyl,
n-butyl, iso-butyl, sec-butyl, tert-butyl, n-pentyl,
--CH(CH.sub.3)--CH.sub.2--CH.sub.2--CH.sub.3,
--CH--CH(CH.sub.3)--CH.sub.2--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3)--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3).sub.2,
--CH(CH.sub.3)--CH(CH.sub.3).sub.2, C.sub.2-C.sub.6 haloalkyl,
C.sub.3-C.sub.6 cycloalkyl, C.sub.3-C.sub.6 halocycloalkyl,
C.sub.2-C.sub.6 alkenyl, C.sub.2-C.sub.6 haloalkenyl,
C.sub.1-C.sub.6 alkoxy, C.sub.1-C.sub.6 haloalkoxy,
C.sub.3-C.sub.6-alkenyloxy, C.sub.2-C.sub.7 alkylcarbonyl,
C.sub.2-C.sub.7 alkoxycarbonyl, C.sub.4-C.sub.7 alkenyloxycarbonyl,
C.sub.4-C.sub.7 alkynyloxycarbonyl, C.sub.1-C.sub.6 alkylthio,
C.sub.1-C.sub.6 alkylsulfinyl, C.sub.1-C.sub.6 alkylsulfonyl,
phenoxy, --C(.dbd.O)NH.sub.2, --C(.dbd.O)NH(CH.sub.3),
--C(.dbd.O)N(CH.sub.3).sub.2 and --C(.dbd.S)NH.sub.2.
[0187] More preferably, G.sup.5 is C.sub.3-C.sub.7 cycloalkyl,
which is optionally substituted by one or more groups independently
selected from halogen, ethyl, n-propyl, iso-propyl, n-butyl,
iso-butyl, sec-butyl, tert-butyl, n-pentyl,
--CH(CH.sub.3)--CH.sub.2--CH.sub.2--CH.sub.3,
--CH--CH(CH.sub.3)--CH.sub.2--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3)--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3).sub.2,
--CH(CH.sub.3)--CH(CH.sub.3).sub.2, C.sub.2-C.sub.6 haloalkyl,
C.sub.1-C.sub.6 alkoxy, C.sub.3-C.sub.4-alkenyloxy, phenoxy and
C.sub.1-C.sub.6 alkylthio.
[0188] More preferably again, G.sup.5 is C.sub.3-C.sub.7
cycloalkyl, which is substituted by one or more groups
independently selected from ethyl, n-propyl, iso-propyl, n-butyl,
iso-butyl, sec-butyl, tert-butyl, n-pentyl,
--CH(CH.sub.3)--CH.sub.2--CH.sub.2--CH.sub.3,
--CH--CH(CH.sub.3)--CH.sub.2--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3)--OH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3).sub.2,
--CH(CH.sub.3)--CH(CH.sub.3).sub.2, C.sub.2-C.sub.6 haloalkyl,
C.sub.1-C.sub.6 alkoxy, C.sub.3-C.sub.4-alkenyloxy, phenoxy and
C.sub.1-C.sub.6 alkylthio.
[0189] More preferably still, G.sup.5 is C.sub.5-C.sub.7
cycloalkyl, which is substituted by one or more groups
independently selected from ethyl, n-propyl, iso-propyl, n-butyl,
iso-butyl, sec-butyl, tert-butyl, n-pentyl,
--CH(CH.sub.3)--CH.sub.2--CH.sub.2--CH.sub.3,
--CH--CH(CH.sub.3)--CH.sub.2--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3)--OH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3).sub.2,
--CH(CH.sub.3)--CH(CH.sub.3).sub.2, C.sub.1-C.sub.4 alkoxy,
C.sub.3-C.sub.4-alkenyloxy, phenoxy and C.sub.2-C.sub.6
haloalkyl.
[0190] More favourably again, G.sup.5 is C.sub.5-C.sub.6
cycloalkyl, which is substituted by one or more groups
independently selected from ethyl, n-propyl, iso-propyl, n-butyl,
iso-butyl, sec-butyl, tert-butyl, n-pentyl,
--CH(CH.sub.3)--CH.sub.2--CH.sub.2--CH.sub.3,
--CH--CH(CH.sub.3)--CH.sub.2--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3)--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3).sub.2,
--CH(CH.sub.3)--CH(CH.sub.3).sub.2 and C.sub.2-C.sub.6
haloalkyl.
[0191] Yet more favourably, G.sup.5 is C.sub.5-C.sub.6 cycloalkyl,
which is substituted by one or more groups independently selected
from ethyl, n-propyl, iso-propyl, n-butyl, iso-butyl, sec-butyl,
tert-butyl, n-pentyl, --CH(CH.sub.3)--CH.sub.2--CH.sub.2--CH.sub.3,
--CH--CH(CH.sub.3)--CH.sub.2--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3)--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3).sub.2--CH(CH.sub.3)--CH(CH.sub.3).sub.-
2, CHF.sub.2 and CF.sub.3.
[0192] Most preferably, G.sup.5 is C.sub.6 cycloalkyl, which is
substituted by one or more groups independently selected from
ethyl, n-propyl, iso-propyl, n-butyl, iso-butyl, sec-butyl,
tert-butyl, n-pentyl, --CH(CH.sub.3)--CH.sub.2--CH.sub.2--CH.sub.3,
--CH--CH(CH.sub.3)--CH.sub.2--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3)--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3).sub.2 and
--CH(CH.sub.3)--CH(CH.sub.3).sub.2.
[0193] In another group of compounds, G.sup.5 is a C.sub.5-C.sub.6
cycloalkyl, which is optionally substituted by one or more
halogen.
[0194] More preferably in this group, G.sup.5 is a C.sub.5-C.sub.6
cycloalkyl, which is optionally substituted by one or more
fluorine.
[0195] Even more preferably in this group, G.sup.5 is an
unsubstituted C.sub.5-C.sub.6 cycloalkyl.
[0196] In another group of compounds, G.sup.5 is a C.sub.5-C.sub.6
cycloalkyl, which is optionally substituted by one or more groups
selected from the group consisting of C.sub.1-C.sub.4 alkoxy,
C.sub.3-C.sub.4-alkenyloxy or phenoxy.
[0197] Preferably in this group of compounds, G.sup.5 is a
C.sub.5-C.sub.6 cycloalkyl, which is optionally substituted by one
or more groups selected from the group consisting of methoxy,
ethoxy, C.sub.3-C.sub.4 alkenyloxy and phenoxy.
[0198] G.sup.6 is phenyl, which must be substituted by at least one
fluorine and is optionally further substituted by one or more
groups independently selected from halogen, ON, NO.sub.2, OH, SH,
CHO, C(.dbd.O)NH.sub.2, C(.dbd.O)NH(CH.sub.3),
C(.dbd.O)N(CH.sub.3).sub.2, C(.dbd.S)NH.sub.2,
C(.dbd.S)NH(CH.sub.3), C(.dbd.S)N(CH.sub.3).sub.2,
SO.sub.2NH.sub.2, SO.sub.2NH(CH.sub.3), SO.sub.2N(CH.sub.3).sub.2,
C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6 haloalkyl, C.sub.3-C.sub.6
cycloalkyl, C.sub.2-C.sub.6 alkenyl, C.sub.2-C.sub.6 haloalkenyl,
C.sub.2-C.sub.6 alkynyl, C.sub.2-C.sub.6 haloalkynyl,
C.sub.1-C.sub.6 alkoxy, C.sub.1-C.sub.6 haloalkoxy, C.sub.3-C.sub.6
alkenyloxy, C.sub.3-C.sub.6 haloalkenyloxy, C.sub.3-C.sub.6
alkynyloxy, C.sub.3-C.sub.6 cycloalkoxy, C.sub.3-C.sub.6
halocycloalkoxy, C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6
haloalkylthio, C.sub.1-C.sub.6 alkylsulfinyl, C.sub.1-C.sub.6
haloalkylsulfinyl, C.sub.1-C.sub.6 alkylsulfonyl and
C.sub.1-C.sub.6 haloalkylsulfonyl.
[0199] More preferably again, G.sup.6 is phenyl, which must be
substituted by at least one fluorine and is optionally further
substituted by one or more groups independently selected from
halogen, ON, NO.sub.2, OH, SH, CHO, C(.dbd.O)NH.sub.2,
C(.dbd.O)NH(CH.sub.3), C(.dbd.O)N(CH.sub.3).sub.2,
C(.dbd.S)NH.sub.2, C(.dbd.S)NH(CH.sub.3),
C(.dbd.S)N(CH.sub.3).sub.2, SO.sub.2NH.sub.2, SO.sub.2NH(CH.sub.3),
SO.sub.2N(CH.sub.3).sub.2, C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6
haloalkyl, C.sub.3-C.sub.6 cycloalkyl, C.sub.2-C.sub.6 alkenyl,
C.sub.2-C.sub.6 haloalkenyl, C.sub.2-C.sub.6 alkynyl,
C.sub.1-C.sub.6 alkoxy, C.sub.1-C.sub.6 haloalkoxy, C.sub.3-C.sub.6
alkenyloxy, C.sub.3-C.sub.6 alkynyloxy, C.sub.1-C.sub.6 alkylthio,
C.sub.1-C.sub.6 alkylsulfinyl and C.sub.1-C.sub.6
alkylsulfonyl.
[0200] Yet more preferably, G.sup.6 is phenyl, which must be
substituted by at least one fluorine and is optionally further
substituted by one or more groups independently selected from
halogen, CN, C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6 haloalkyl,
C.sub.3-C.sub.6 cycloalkyl, C.sub.2-C.sub.6 alkenyl,
C.sub.2-C.sub.6 alkynyl, C.sub.1-C.sub.6 alkoxy, C.sub.3-C.sub.6
alkenyloxy, C.sub.3-C.sub.6 alkynyloxy and C.sub.1-C.sub.6
alkylthio.
[0201] Favourably, G.sup.6 is phenyl, which must be substituted by
at least one fluorine and is optionally further substituted by one
or more groups independently selected from halogen, ON,
C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6 haloalkyl and
C.sub.1-C.sub.6 alkoxy.
[0202] More favourably again, G.sup.6 is phenyl, which must be
substituted by at least one fluorine and is optionally further
substituted by one or more groups independently selected from
halogen, CN, C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 haloalkyl and
C.sub.1-C.sub.4 alkoxy.
[0203] Yet more favourably, G.sup.6 is phenyl, which must be
substituted by at least one fluorine and is optionally further
substituted by one or more halogen, CHF.sub.2, CF.sub.3 and
C.sub.1-C.sub.4 alkyl.
[0204] Most preferably, G.sup.6 is phenyl, which must be
substituted by at least one fluorine and is optionally further
substituted by one or more methyl, bromine, iodine or chlorine.
[0205] In one group of compounds, G.sup.6 is phenyl substituted at
the para-position by fluorine and further substituted as in the
above paragraphs.
[0206] In one group of compounds, G.sup.6 is phenyl substituted at
the ortho-position by fluorine and further substituted as in the
above paragraphs.
[0207] In one group of compounds, G.sup.6 is phenyl substituted at
the meta-position by fluorine and further substituted as in the
above paragraphs.
[0208] G.sup.7 is methylene.
[0209] G.sup.8 is
##STR00010##
[0210] G.sup.9 is
##STR00011##
[0211] G.sup.10 is phenyl, which is optionally substituted by one
or more groups independently selected from halogen, CN, NO.sub.2,
OH, SH, CHO, C(.dbd.O)NH.sub.2, C(.dbd.O)NH(CH.sub.3),
C(.dbd.O)N(CH.sub.3).sub.2, C(.dbd.S)NH.sub.2,
C(.dbd.S)NH(CH.sub.3), C(.dbd.S)N(CH.sub.3).sub.2,
SO.sub.2NH.sub.2, SO.sub.2NH(CH.sub.3), SO.sub.2N(CH.sub.3).sub.2,
C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6 haloalkyl, C.sub.3-C.sub.6
cycloalkyl, C.sub.2-C.sub.6 alkenyl, C.sub.2-C.sub.6 haloalkenyl,
C.sub.2-C.sub.6 alkynyl, C.sub.2-C.sub.6 haloalkynyl,
C.sub.1-C.sub.6 alkoxy, C.sub.1-C.sub.6 haloalkoxy, C.sub.3-C.sub.6
alkenyloxy, C.sub.3-C.sub.6 haloalkenyloxy, C.sub.3-C.sub.6
alkynyloxy, C.sub.3-C.sub.6 cycloalkoxy, C.sub.3-C.sub.6
halocycloalkoxy, phenyl, C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6
haloalkylthio, C.sub.1-C.sub.6 alkylsulfinyl, C.sub.1-C.sub.6
haloalkylsulfinyl, C.sub.1-C.sub.6 alkylsulfonyl, C.sub.1-C.sub.6
haloalkylsulfonyl, phenyl, 2-phenyl-ethynyl and 2-phenyl-ethyl.
[0212] Preferably, G.sup.10 is phenyl, which is optionally
substituted by one or more groups independently selected from
halogen, CN, NO.sub.2, OH, SH, CHO, C(.dbd.O)NH.sub.2,
C(.dbd.O)NH(CH.sub.3), C(.dbd.O)N(CH.sub.3).sub.2,
C(.dbd.S)NH.sub.2, C(.dbd.S)NH(CH.sub.3),
C(.dbd.S)N(CH.sub.3).sub.2, SO.sub.2NH.sub.2, SO.sub.2NH(CH.sub.3),
SO.sub.2N(CH.sub.3).sub.2, C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6
haloalkyl, C.sub.3-C.sub.6 cycloalkyl, C.sub.2-C.sub.6 alkenyl,
C.sub.2-C.sub.6 haloalkenyl, C.sub.2-C.sub.6 alkynyl,
C.sub.1-C.sub.6 alkoxy, C.sub.1-C.sub.6 haloalkoxy, C.sub.3-C.sub.6
alkenyloxy, C.sub.3-C.sub.6 alkynyloxy, C.sub.3-C.sub.6
cycloalkoxy, C.sub.3-C.sub.6 halocycloalkoxy, phenyl,
C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6 haloalkylthio,
C.sub.1-C.sub.6 alkylsulfinyl, C.sub.1-C.sub.6 haloalkylsulfinyl,
C.sub.1-C.sub.6 alkylsulfonyl and C.sub.1-C.sub.6
haloalkylsulfonyl.
[0213] More preferably, G.sup.10 is phenyl, which is optionally
substituted by one or more groups independently selected from
halogen, CN, OH, SH, CHO, C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6
haloalkyl, C.sub.3-C.sub.6 cycloalkyl, C.sub.2-C.sub.6 alkenyl,
C.sub.2-C.sub.6 haloalkenyl, C.sub.2-C.sub.6 alkynyl,
C.sub.1-C.sub.6 alkoxy, C.sub.1-C.sub.6 haloalkoxy, C.sub.3-C.sub.6
alkenyloxy, C.sub.3-C.sub.6 alkynyloxy, C.sub.3-C.sub.6
cycloalkoxy, phenyl, C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6
alkylsulfinyl and C.sub.1-C.sub.6 alkylsulfonyl.
[0214] More preferably again, G.sup.10 is phenyl, which is
optionally substituted by one or more groups independently selected
from halogen, CN, OH, SH, CHO, methyl, ethyl, n-propyl, iso-propyl,
phenyl, CH.sub.2F, CHF.sub.2, CF.sub.3, CHF--CH.sub.3,
CF.sub.2--CH.sub.3, CF.sub.2--CF.sub.3, cyclopropyl,
CH.dbd.CH.sub.2, C(CH.sub.3).dbd.CH.sub.2, CH.dbd.CH(CH.sub.3),
C(CH.sub.3).dbd.CH(CH.sub.3), CH.dbd.C(CH.sub.3).sub.2,
C(CH.sub.3).dbd.C(CH.sub.3).sub.2, CH.dbd.CF.sub.2,
CH.dbd.CCl.sub.2, C.ident.CH, methoxy, ethoxy, iso-propyloxy,
OCHF.sub.2, OCH.sub.2--C.ident.CH, OCH(CH.sub.3)--C.ident.CH,
SCH.sub.3, SCH.sub.2CH.sub.3, S(.dbd.O)CH.sub.3,
S(.dbd.O)CH.sub.2CH.sub.3, S(.dbd.O).sub.2CH.sub.3 and
S(.dbd.O).sub.2CH.sub.2CH.sub.3.
[0215] More favourably again, G.sup.10 is phenyl, which is
optionally substituted by one or more groups independently selected
from halogen, CN, OH, methyl, ethyl, n-propyl, iso-propyl,
CH.sub.2F, CHF.sub.2, CF.sub.3, CHF--CH.sub.3, CF.sub.2--CH.sub.3,
CF.sub.2--CF.sub.3, CH.dbd.CH.sub.2, C(CH.sub.3).dbd.CH.sub.2,
CH.dbd.CH(CH.sub.3), C(CH.sub.3).dbd.CH(CH.sub.3),
CH.dbd.C(CH.sub.3).sub.2, C(CH.sub.3).dbd.C(CH.sub.3).sub.2,
CH.dbd.CF.sub.2, CH.dbd.CCl.sub.2, C.ident.CH, methoxy, phenyl,
ethoxy, iso-propyloxy and OCHF.sub.2.
[0216] Yet more favourably, G.sup.10 is phenyl, which is optionally
substituted by one or more groups independently selected from
halogen, CN, methyl, ethyl, n-propyl, iso-propyl, ethenyl, methoxy,
ethoxy, iso-propyloxy, phenyl, CHF.sub.2, CF.sub.3, CHF--CH.sub.3
and OCHF.sub.2.
[0217] Most preferably, G.sup.10 is phenyl, which is optionally
substituted by one or more groups independently selected from
halogen, CN, methyl, ethyl, n-propyl, iso-propyl, ethenyl, methoxy,
phenyl, CHF.sub.2, CF.sub.3 and CHF--CH.sub.3.
[0218] G.sup.11 is methylene substituted by at least one group
independently selected from C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4
haloalkyl, CN, C.sub.1-C.sub.4 alkoxy and C.sub.1-C.sub.4
haloalkoxy.
[0219] More preferably again, G.sup.11 is methylene substituted by
at least one group independently selected from C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 haloalkyl, C.sub.1-C.sub.4 alkoxy and
C.sub.1-C.sub.4 haloalkoxy.
[0220] More favourably again, G.sup.11 is methylene substituted by
at least one group independently selected from C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 haloalkyl and C.sub.1-C.sub.4 alkoxy.
[0221] Yet more favourably, G.sup.11 is methylene substituted by at
least one group independently selected from methyl, ethyl,
CHF.sub.2 and CF.sub.3.
[0222] More favourably still, G.sup.11 is methylene substituted by
at least one group independently selected from methyl, CF.sub.3 and
ethyl.
[0223] Most preferably, G.sup.11 is methylene substituted by at
least one group independently selected from methyl and ethyl.
[0224] G.sup.12 is
##STR00012##
[0225] G.sup.13 is a C.sub.8-C.sub.11 spirobicyclic system
containing 0, 1 or 2 O or N atoms, wherein there are no adjacent O
atoms, which is optionally substituted by one or more groups
independently selected from halogen, CN, NO.sub.2, OH, SH, CHO,
COOH, tri(C.sub.1-C.sub.6-alkyl)silyl, C.sub.1-C.sub.6 alkyl,
C.sub.1-C.sub.6 haloalkyl, C.sub.3-C.sub.6 cycloalkyl,
C.sub.3-C.sub.6 halocycloalkyl, C.sub.2-C.sub.6 alkenyl,
C.sub.2-C.sub.6 haloalkenyl, C.sub.1-C.sub.6 alkoxy,
C.sub.1-C.sub.6 haloalkoxy, C.sub.2-C.sub.7 alkylcarbonyl,
C.sub.2-C.sub.7 alkoxycarbonyl, C.sub.4-C.sub.7 alkenyloxycarbonyl,
C.sub.4-C.sub.7 alkynyloxycarbonyl, C.sub.1-C.sub.6 alkylthio,
C.sub.1-C.sub.6 alkylsulfinyl, C.sub.1-C.sub.6 alkylsulfonyl,
.dbd.O, --C(.dbd.O)NH.sub.2, --C(.dbd.O)NH(CH.sub.3),
--C(.dbd.O)N(CH.sub.3).sub.2 and --C(.dbd.S)NH.sub.2.
[0226] More preferably again, G.sup.13 is a C.sub.8-C.sub.11
spirobicyclic system containing 0, 1 or 2 O or N atoms, wherein
there are no adjacent O atoms, which is optionally substituted by
one or more groups independently selected from halogen,
C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6 haloalkyl, C.sub.1-C.sub.6
alkoxy, C.sub.1-C.sub.6 alkylthio and .dbd.O.
[0227] Most preferably, G.sup.13 is a C.sub.8-C.sub.11
spirobicyclic system containing 0, 1 or 2 O or N atoms, wherein
there are no adjacent O atoms, which is optionally substituted by
one or more groups independently selected from halogen,
C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 alkoxy and .dbd.O.
[0228] G.sup.14 is
##STR00013##
[0229] G.sup.15 is
##STR00014##
[0230] G.sup.16 is
##STR00015##
[0231] G.sup.17 is a five- to six-membered monocyclic
heteroaromatic ring system which can contain 1 to 4 members
selected from the group consisting of N, N(R.sup.69'), O and S (for
example, pyridine, pyrimidine, furan, pyrrole, thiazole, oxazole,
pyrazole, imidazole, oxadiazole, thiadiazole or tetrazole), it not
being possible for each ring system to contain --O--O--, --S--S--
and --O--S-- fragments, and it being possible for the five- to
six-membered ring system to be itself mono- or polysubstituted by
groups selected from the group consisting of halogen, CN, NO.sub.2,
OH, SH, CHO, C(.dbd.O)NH.sub.2, C(.dbd.O)NH(CH.sub.3),
C(.dbd.O)N(CH.sub.3).sub.2, C(.dbd.S)NH.sub.2,
C(.dbd.S)NH(CH.sub.3), C(.dbd.S)N(CH.sub.3).sub.2,
SO.sub.2NH.sub.2, SO.sub.2NH(CH.sub.3), SO.sub.2N(CH.sub.3).sub.2,
C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6 haloalkyl, C.sub.3-C.sub.6
cycloalkyl, C.sub.2-C.sub.6 alkenyl, C.sub.2-C.sub.6 haloalkenyl,
C.sub.2-C.sub.6 alkynyl, C.sub.2-C.sub.6 haloalkynyl,
C.sub.1-C.sub.6 alkoxy, C.sub.1-C.sub.6 haloalkoxy, C.sub.3-C.sub.6
alkenyloxy, C.sub.3-C.sub.6 haloalkenyloxy, C.sub.3-C.sub.6
alkynyloxy, C.sub.3-C.sub.6 cycloalkoxy, C.sub.3-C.sub.6
halocycloalkoxy, C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6
haloalkylthio, C.sub.1-C.sub.6 alkylsulfinyl, C.sub.1-C.sub.6
haloalkylsulfinyl, C.sub.1-C.sub.6 alkylsulfonyl and
C.sub.1-C.sub.6 haloalkylsulfonyl.
[0232] More favourably again, G.sup.17 is a five- to six-membered
monocyclic heteroaromatic ring system which can contain 1 to 4
members selected from the group consisting of N, N(R.sup.69'), O
and S, it not being possible for each ring system to contain
--O--O--, --S--S-- and --O--S-- fragments, and it being possible
for the five- to six-membered ring system to be itself mono- or
polysubstituted by groups selected from the group consisting of
halogen, CN, C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 haloalkyl,
C.sub.1-C.sub.4 alkoxy, C.sub.1-C.sub.4 haloalkoxy, phenyl or
benzyl, wherein the phenyl or benzyl are optionally substituted by
halogen, CN, C.sub.1-C.sub.4 alkyl or C.sub.1-C.sub.4
haloalkyl.
[0233] Yet more favourably, G.sup.17 is a five- to six-membered
monocyclic heteroaromatic ring system which can contain 1 or 2
members selected from the group consisting of N, N(R.sup.69'), O
and S, it not being possible for each ring system to contain
--O--O--, --S--S-- and --O--S-- fragments, and it being possible
for the five- to six-membered ring system to be itself mono- or
polysubstituted by groups selected from the group consisting of
halogen, CN, C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 haloalkyl,
C.sub.1-C.sub.4 alkoxy, C.sub.1-C.sub.4 haloalkoxy, phenyl or
benzyl, wherein the phenyl or benzyl are optionally substituted by
halogen, CN, C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 haloalkyl.
[0234] Most preferably, G.sup.17 is a five- to six-membered
monocyclic heteroaromatic ring system which can contain 1 or 2
members selected from the group consisting of N, O and S, it not
being possible for each ring system to contain --O--O--, --S--S--
and --O--S-- fragments, and it being possible for the five- to
six-membered ring system to be itself mono- or polysubstituted by
groups selected from the group consisting of halogen, CN,
C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 haloalkyl, C.sub.1-C.sub.4
alkoxy, C.sub.1-C.sub.4 haloalkoxy, phenyl or fluorophenyl.
[0235] In one group of compounds, G.sup.17 is selected from
pyridine, pyrimidine, furan, pyrrole, thiazole, oxazole, pyrazole,
imidazole, oxadiazole, thiadiazole or tetrazole each of which may
be substituted by one or more groups selected from the group
consisting of halogen, CN, NO.sub.2, OH, SH, CHO,
C(.dbd.O)NH.sub.2, C(.dbd.O)NH(CH.sub.3),
C(.dbd.O)N(CH.sub.3).sub.2, C(.dbd.S)NH.sub.2,
C(.dbd.S)NH(CH.sub.3), C(.dbd.S)N(CH.sub.3).sub.2,
SO.sub.2NH.sub.2, SO.sub.2NH(CH.sub.3), SO.sub.2N(CH.sub.3).sub.2,
C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6 haloalkyl, C.sub.3-C.sub.6
cycloalkyl, C.sub.2-C.sub.6 alkenyl, C.sub.2-C.sub.6 haloalkenyl,
C.sub.2-C.sub.6 alkynyl, C.sub.2-C.sub.6 haloalkynyl,
C.sub.1-C.sub.6 alkoxy, C.sub.1-C.sub.6 haloalkoxy, C.sub.3-C.sub.6
alkenyloxy, C.sub.3-C.sub.6 haloalkenyloxy, C.sub.3-C.sub.6
alkynyloxy, C.sub.3-C.sub.6 cycloalkoxy, C.sub.3-C.sub.6
halocycloalkoxy, C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6
haloalkylthio, C.sub.1-C.sub.6 alkylsulfinyl, C.sub.1-C.sub.6
haloalkylsulfinyl, C.sub.1-C.sub.6 alkylsulfonyl and
C.sub.1-C.sub.6 haloalkylsulfonyl.
[0236] More favourably again in this group, G.sup.17 is selected
from pyridine, pyrimidine, furan, pyrrole, thiazole, oxazole,
pyrazole, imidazole, oxadiazole, thiadiazole or tetrazole each of
which may be substituted by one or more groups selected from the
group consisting of halogen, CN, C.sub.1-C.sub.4 alkyl,
C.sub.1-C.sub.4 haloalkyl, C.sub.1-C.sub.4 alkoxy, C.sub.1-C.sub.4
haloalkoxy, phenyl or benzyl, wherein the phenyl or benzyl are
optionally substituted by halogen, CN, C.sub.1-C.sub.4 alkyl,
C.sub.1-C.sub.4 haloalkyl.
[0237] Yet more favourably in this group, G.sup.17 is selected from
pyridine, pyrimidine, furan, pyrrole, thiazole, oxazole, pyrazole,
or imidazole each of which may be substituted by one or more groups
selected from the group consisting of halogen, CN, C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 haloalkyl, C.sub.1-C.sub.4 alkoxy,
C.sub.1-C.sub.4 haloalkoxy, phenyl or benzyl, wherein the phenyl or
benzyl are optionally substituted by halogen, CN, C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 haloalkyl.
[0238] Most preferably in this group, G.sup.17 is selected from
pyridine, furan, pyrrole, thiazole or oxazole or imidazole each of
which may be substituted by one or more groups selected from the
group consisting of halogen, CN, C.sub.1-C.sub.4 alkyl,
C.sub.1-C.sub.4 haloalkyl, C.sub.1-C.sub.4 alkoxy, C.sub.1-C.sub.4
haloalkoxy, phenyl or fluorophenyl.
[0239] In another group of compounds, G.sup.17 is a five- to
six-membered monocyclic heteroaromatic ring system which can
contain 1 member selected from the group consisting of N and O (for
example, pyridine, furan or pyrrole), it being possible for the
five- to six-membered ring system to be itself mono- or
polysubstituted by groups selected from the group consisting of
halogen, CN, C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 haloalkyl,
C.sub.1-C.sub.4 alkoxy or C.sub.1-C.sub.4 haloalkoxy.
[0240] Preferably in this group, G.sup.17 is pyridine, furan or
pyrrole each of which may be mono- or polysubstituted by groups
selected from the group consisting of halogen, CN, C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 haloalkyl, C.sub.1-C.sub.4 alkoxy or
C.sub.1-C.sub.4 haloalkoxy.
[0241] In another group of compounds, G.sup.17 is a five- to
six-membered monocyclic heteroaromatic ring system which can
contain 2 members selected from the group consisting of N, O and S,
(for example oxazole or thiazole) it not being possible for each
ring system to contain --O--O--, --S--S-- and --O--S-- fragments,
and it being possible for the five- to six-membered ring system to
be itself mono- or polysubstituted by groups selected from the
group consisting of halogen, CN, C.sub.1-C.sub.4 alkyl,
C.sub.1-C.sub.4 haloalkyl, C.sub.1-C.sub.4 alkoxy, C.sub.1-C.sub.4
haloalkoxy, phenyl or fluorophenyl.
[0242] Preferably in this group, G.sup.17 is oxazole or thiazole
each of which may be mono- or polysubstituted by groups selected
from the group consisting of halogen, CN, C.sub.1-C.sub.4 alkyl,
C.sub.1-C.sub.4 haloalkyl, C.sub.1-C.sub.4 alkoxy, C.sub.1-C.sub.4
haloalkoxy, phenyl or fluorophenyl.
[0243] R.sup.1' is selected from the group consisting of hydrogen,
fluorine, C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 haloalkyl;
[0244] R.sup.2', R.sup.3', R.sup.4' and R.sup.5' are selected,
independently of each other, from the group consisting of hydrogen,
fluorine, C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 haloalkyl,
C.sub.1-C.sub.4 alkoxy and C.sub.1-C.sub.4 alkylthio.
[0245] More preferably again, R.sup.1' is selected from the group
consisting of hydrogen, fluorine, C.sub.1-C.sub.4 alkyl and
C.sub.1-C.sub.4 fluoroalkyl;
[0246] R.sup.2', R.sup.3', R.sup.4' and R.sup.5' are selected,
independently of each other, from the group consisting of hydrogen,
fluorine, C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 haloalkyl,
C.sub.1-C.sub.4 alkoxy and C.sub.1-C.sub.4 alkylthio.
[0247] Yet more preferably, R.sup.1', R.sup.2', R.sup.3', R.sup.4'
and R.sup.5' are selected, independently of each other, from the
group consisting of hydrogen, fluorine, methyl, ethyl, CH.sub.2F,
CHF.sub.2, CF.sub.3, CHF--CH.sub.3, CF.sub.2--CH.sub.3, methoxy,
ethoxy and S--CH.sub.3 S--CH.sub.2CH.sub.3.
[0248] More favourably again, R.sup.1' is selected from the group
consisting of hydrogen, fluorine, methyl, CH.sub.2F and
CF.sub.3;
[0249] R.sup.2', R.sup.3', R.sup.4' and R.sup.5' are selected,
independently of each other, from the group consisting of hydrogen,
fluorine, methyl, CH.sub.2F, CF.sub.3 and methoxy.
[0250] Most preferably, R.sup.1, R.sup.2', R.sup.3', R.sup.4' and
R.sup.5' are each hydrogen.
[0251] R.sup.11', R.sup.12', R.sup.13' and R.sup.14' are selected,
independently of each other, from the group consisting of hydrogen,
halogen, CN, NO.sub.2, OH, SH, CHO, C(.dbd.O)NH.sub.2,
C(.dbd.O)NH(CH.sub.3), C(.dbd.O)N(CH.sub.3).sub.2,
C(.dbd.S)NH.sub.2, C(.dbd.S)NH(CH.sub.3),
C(.dbd.S)N(CH.sub.3).sub.2, SO.sub.2NH.sub.2, SO.sub.2NH(CH.sub.3),
SO.sub.2N(CH.sub.3).sub.2, C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6
haloalkyl, C.sub.3-C.sub.6 cycloalkyl, C.sub.2-C.sub.6 alkenyl,
C.sub.2-C.sub.6 haloalkenyl, C.sub.2-C.sub.6 alkynyl,
C.sub.2-C.sub.6 haloalkynyl, C.sub.1-C.sub.6 alkoxy,
C.sub.1-C.sub.6 haloalkoxy, phenyl, C.sub.3-C.sub.6 alkenyloxy,
C.sub.3-C.sub.6 haloalkenyloxy, C.sub.3-C.sub.6 alkynyloxy,
C.sub.3-C.sub.6 cycloalkoxy, C.sub.3-C.sub.6 halocycloalkoxy,
benzyloxy, C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6
haloalkylthio, C.sub.1-C.sub.6 alkylsulfinyl, C.sub.1-C.sub.6
haloalkylsulfinyl, C.sub.1-C.sub.6 alkylsulfonyl and
C.sub.1-C.sub.6 haloalkylsulfonyl.
[0252] More preferably again, R.sup.11', R.sup.12', R.sup.13' and
R.sup.14' are selected, independently of each other, from the group
consisting of hydrogen, cyano, halogen, C.sub.1-C.sub.6 alkyl,
C.sub.1-C.sub.6 haloalkyl, C.sub.1-C.sub.6 alkoxy and
C.sub.1-C.sub.6 alkylthio.
[0253] More favourably again, R.sup.11', R.sup.12', R.sup.13' and
R.sup.14' are selected, independently of each other, from the group
consisting of hydrogen, halogen, cyano, C.sub.1-C.sub.4 alkyl,
CHF.sub.2, CF.sub.3 and C.sub.1-C.sub.4 alkoxy.
[0254] Most preferably, R.sup.11', R.sup.12', R.sup.13' and
R.sup.14' are selected, independently of each other, from the group
consisting of hydrogen, halogen, cyano, C.sub.1-C.sub.4 alkyl and
C.sub.1-C.sub.4 alkoxy.
[0255] R.sup.15' and R.sup.16' are independently selected from the
group consisting of hydrogen, halogen, cyano, C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 haloalkyl and C.sub.3-C.sub.6
cycloalkyl;
[0256] each R.sup.17', R.sup.18', R.sup.19', R.sup.20', R.sup.21'
and R.sup.22 are selected independently of each other, from the
group consisting of hydrogen, halogen, cyano, C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 haloalkyl, C.sub.1-C.sub.4 alkoxy,
C.sub.1-C.sub.4 haloalkoxy and C.sub.3-C.sub.6 cycloalkyl;
[0257] R.sup.23', R.sup.24' and R.sup.25' are independently
selected from the group consisting of hydrogen, halogen, cyano,
C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 haloalkyl, C.sub.1-C.sub.4
alkoxy, C.sub.3-C.sub.6 cycloalkyl, C.sub.3-C.sub.6 halocycloalkyl
and C.sub.1-C.sub.4 alkylthio.
[0258] More preferably again, R.sup.15', R.sup.16', R.sup.17',
R.sup.18', R.sup.19', R.sup.20', R.sup.21' and R.sup.22 are
independently selected from the group consisting of hydrogen,
halogen, methyl, ethyl, isopropyl, CH.sub.2F, CHF.sub.2, CF.sub.3,
CHF--CH.sub.3, CF.sub.2--CH.sub.3 and CF.sub.2CF.sub.3;
[0259] R.sup.23', R.sup.24' and R.sup.25' are independently
selected from the group consisting of hydrogen, halogen, cyano,
C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 haloalkyl, C.sub.1-C.sub.4
alkoxy, C.sub.3-C.sub.6 cycloalkyl, C.sub.3-C.sub.6 halocycloalkyl
and C.sub.1-C.sub.4 alkylthio.
[0260] Favourably, R.sup.15', R.sup.16', R.sup.17, R.sup.18',
R.sup.19', R.sup.20', R.sup.21' and R.sup.22' are independently
selected from the group consisting of hydrogen, fluorine, methyl,
ethyl, isopropyl, CH.sub.2F, CHF.sub.2, CF.sub.3, CHF--CH.sub.3,
CF.sub.2--CH.sub.3, CH.sub.2--CH.sub.2F CH.sub.2--CHF.sub.2 and
CH.sub.2--CF.sub.3;
[0261] R.sup.23', R.sup.24' and R.sup.25' are independently
selected from the group consisting of hydrogen, halogen, cyano,
C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 haloalkyl, C.sub.1-C.sub.4
alkoxy, C.sub.3-C.sub.6 cycloalkyl, C.sub.3-C.sub.6 halocycloalkyl
and C.sub.1-C.sub.4 alkylthio.
[0262] More favourably, R.sup.15', R.sup.16', R.sup.17', R.sup.18',
R.sup.19', R.sup.20', R.sup.21' and R.sup.22 are each independently
selected from hydrogen, fluorine, methyl, ethyl, CH.sub.2F,
CHF.sub.2 and CF.sub.3 and isopropyl;
[0263] R.sup.23', R.sup.24' and R.sup.25' are independently
selected from the group consisting of hydrogen, halogen, cyano,
C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 haloalkyl, C.sub.1-C.sub.4
alkoxy, C.sub.3-C.sub.6 cycloalkyl, C.sub.3-C.sub.6 halocycloalkyl
and C.sub.1-C.sub.4 alkylthio.
[0264] More favourably again, R.sup.15', R.sup.16', R.sup.17,
R.sup.18', R.sup.19', R.sup.20', R.sup.21 and R.sup.22 are each
independently selected from hydrogen, fluorine, methyl, ethyl,
CH.sub.2F, CHF.sub.2, CF.sub.3 and isopropyl;
[0265] R.sup.23', R.sup.24' and R.sup.25' are independently
selected from the group consisting of hydrogen, methyl, fluorine,
chlorine, bromine, ethyl, CH.sub.2F, CHF.sub.2 and CF.sub.3 and
isopropyl.
[0266] Yet more favourably, R.sup.15', R.sup.16', R.sup.17,
R.sup.18', R.sup.19', R.sup.20', R.sup.21' and R.sup.22' are each
independently selected from hydrogen, fluorine, methyl, ethyl,
CH.sub.2F, CHF.sub.2, CF.sub.3 and isopropyl;
[0267] R.sup.23', R.sup.24' and R.sup.25' are each independently
selected from hydrogen, fluorine, chlorine, bromine, methyl, ethyl
and isopropyl.
[0268] Most preferably, R.sup.15', R.sup.16', R.sup.17, R.sup.18',
R.sup.19', R.sup.20', R.sup.21', R.sup.22', R.sup.23', R.sup.24'
and R.sup.25' are each independently selected from hydrogen,
methyl, ethyl and isopropyl.
[0269] In one group of compounds, R.sup.15' and R.sup.16' are each
independently selected from the group consisting of hydrogen,
methyl, F and CF.sub.3.
[0270] In this group, R.sup.15', R.sup.16, R.sup.17, R.sup.18',
R.sup.19', R.sup.20, R.sup.21 and R.sup.22 are most preferably each
hydrogen.
[0271] In another preferred group of compounds, R.sup.15' is as
described above and R.sup.16, R.sup.17', R.sup.18', R.sup.19',
R.sup.20', R.sup.21' and R.sup.22 are each hydrogen.
[0272] In another group of compounds, R.sup.23', R.sup.24' and
R.sup.25' are independently selected from the group consisting of
hydrogen, fluorine, chlorine, bromine, methyl, ethyl, isopropyl,
CH.sub.2F, CHF.sub.2, CF.sub.3, CHF--CH.sub.3, CF.sub.2--CH.sub.3,
CH.sub.2--CH.sub.2F CH.sub.2--CHF.sub.2 and CH.sub.2--CF.sub.3.
[0273] R.sup.26' is C(R.sup.36').sub.2, N--OH,
N--O--C.sub.1-C.sub.4-alkyl, N--O--C.sub.2-C.sub.4-alkenyl,
N--O--C.sub.2-C.sub.4 alkynyl, N--O--C.sub.1-C.sub.4 haloalkyl,
N--O--C.sub.2-C.sub.4 haloalkenyl, N--O-benzyl, N--O-phenyl,
N--O-halophenyl, O wherein the N--O-benzyl and N--O-phenyl may be
substituted by one or more groups independently selected from the
group consisting of halogen, methyl and halomethyl.
[0274] Most preferably, R.sup.26' is N--OH, N--O--C.sub.1-C.sub.4
alkyl, N--O--C.sub.2-C.sub.4 alkenyl, N--O--C.sub.2-C.sub.4
alkynyl, N--O--C.sub.1-C.sub.4 haloalkyl, N--O--C.sub.2-C.sub.4
haloalkenyl, N--O-benzyl, N--O-phenyl, N--O-halophenyl, O or
C(R.sup.36).
[0275] R.sup.27', R.sup.28', R.sup.29', R.sup.30', R.sup.31',
R.sup.32', R.sup.33', R.sup.34' and R.sup.35' are each
independently selected from the group consisting of hydrogen,
hydroxyl, C.sub.1-C.sub.4 alkyl, C.sub.2-C.sub.4 alkenyl,
C.sub.2-C.sub.4 alkynyl, C.sub.1-C.sub.4 alkoxy, halogen,
C.sub.1-C.sub.4 haloalkyl, C.sub.2-C.sub.4 haloalkenyl, cyano,
benzyl and phenyl;
[0276] or R.sup.28' and R.sup.29' together with the two carbon
atoms to which they are attached form a double bond.
[0277] More preferably again, R.sup.27', R.sup.28', R.sup.29',
R.sup.30', R.sup.31', R.sup.32', R.sup.33', R.sup.34' and R.sup.35'
are each independently selected from the group consisting of
hydrogen, hydroxyl, C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 alkoxy
and halogen;
[0278] or R.sup.28' and R.sup.29' together with the two carbon
atoms to which they are attached form a double bond.
[0279] More favourably again, R.sup.27', R.sup.28', R.sup.29',
R.sup.30', R.sup.31', R.sup.32', R.sup.33', R.sup.34' and R.sup.35'
are each independently selected from the group consisting of
hydrogen, C.sub.1-C.sub.4 alkyl and halogen;
[0280] or R.sup.28' and R.sup.29' together with the two carbon
atoms to which they are attached form a double bond.
[0281] Yet more favourably R.sup.27', R.sup.28', R.sup.29',
R.sup.30', R.sup.31', R.sup.32', R.sup.33', R.sup.34' and R.sup.35'
are each hydrogen or methyl;
[0282] or R.sup.28' and R.sup.29' together with the two carbon
atoms to which they are attached form a double bond.
[0283] Most preferably R.sup.27 is hydrogen or methyl;
[0284] R.sup.28', R.sup.29', R.sup.30', R.sup.31', R.sup.32',
R.sup.33', R.sup.34' and R.sup.35' are each hydrogen; or R.sup.28'
and R.sup.29' together with the two carbon atoms to which they are
attached form a double bond.
[0285] Each R.sup.36' is independently selected from hydrogen,
halogen and C.sub.1-C.sub.4 alkyl.
[0286] R.sup.37' and R.sup.38' are selected independently of each
other from the group consisting of hydrogen, halogen, cyano,
C.sub.1-C.sub.4 alkyl and C.sub.1-C.sub.4 haloalkyl;
[0287] R.sup.39', R.sup.40', R.sup.41', R.sup.42', R.sup.43' and
R.sup.44' are selected independently of each other from the group
consisting of hydrogen, halogen, hydroxy, cyano, C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 haloalkyl, C.sub.1-C.sub.4 alkoxy,
C.sub.1-C.sub.4 haloalkoxy and C.sub.1-C.sub.4 alkylthio.
[0288] More preferably again, R.sup.37', R.sup.38', R.sup.39',
R.sup.40', R.sup.41', R.sup.42', R.sup.43' and R.sup.44' are
selected independently of each other from a group consisting of
hydrogen, halogen, methyl, ethyl, isopropyl, monofluoromethyl,
polyfluoromethyl, monofluoroethyl, and polyfluoroethyl.
[0289] Favourably, R.sup.37', R.sup.38', R.sup.39', R.sup.40',
R.sup.41', R.sup.42', R.sup.43' and R.sup.44' are selected
independently of each other from a group consisting of hydrogen,
fluorine, methyl, ethyl, isopropyl, CH.sub.2F, CHF.sub.2, CF.sub.3,
CHF--CH.sub.3, CF.sub.2--CH.sub.3, CH.sub.2--CH.sub.2F
CH.sub.2--CHF.sub.2, and CH.sub.2--CF.sub.3.
[0290] More favourably again, R.sup.37', R.sup.38', R.sup.39',
R.sup.40', R.sup.41', R.sup.42', R.sup.43' and R.sup.44' are
independently selected from the group consisting of hydrogen,
fluorine, methyl and trifluoromethyl.
[0291] Yet more favourably, R.sup.37', R.sup.38', R.sup.39',
R.sup.40', R.sup.41', R.sup.42', R.sup.43' and R.sup.44' are
hydrogen or methyl.
[0292] Most preferably, R.sup.37', R.sup.38', R.sup.39', R.sup.40',
R.sup.41', R.sup.42', R.sup.43' and R.sup.44' are hydrogen.
[0293] In one group of compounds, R.sup.38', R.sup.39', R.sup.40',
R.sup.41', R.sup.42', R.sup.43' and R.sup.44' are each hydrogen,
and R.sup.37' is as defined above.
[0294] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, halogen, CN, NO.sub.2, OH, SH, CHO, C(.dbd.O)NH.sub.2,
C(.dbd.O)NH(CH.sub.3), C(.dbd.O)N(CH.sub.3).sub.2,
C(.dbd.S)NH.sub.2, C(.dbd.S)NH(CH.sub.3),
C(.dbd.S)N(CH.sub.3).sub.2, SO.sub.2NH.sub.2, SO.sub.2NH(CH.sub.3),
SO.sub.2N(CH.sub.3).sub.2, C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6
haloalkyl, C.sub.3-C.sub.6 cycloalkyl, C.sub.2-C.sub.6 alkenyl,
C.sub.2-C.sub.6 haloalkenyl, C.sub.2-C.sub.6 alkynyl,
C.sub.2-C.sub.6 haloalkynyl, C.sub.1-C.sub.6 alkoxy,
C.sub.1-C.sub.6 haloalkoxy, C.sub.3-C.sub.6 alkenyloxy,
C.sub.3-C.sub.6 haloalkenyloxy, C.sub.3-C.sub.6 alkynyloxy,
C.sub.3-C.sub.6 cycloalkoxy, C.sub.3-C.sub.6 halocycloalkoxy,
C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6 haloalkylthio,
C.sub.1-C.sub.6 alkylsulfinyl, C.sub.1-C.sub.6 haloalkylsulfinyl,
C.sub.1-C.sub.6 alkylsulfonyl and C.sub.1-C.sub.6
haloalkylsulfonyl.
[0295] More preferably again, R.sup.45', R.sup.46', R.sup.47',
R.sup.48' and R.sup.49' are independently selected from the group
consisting of hydrogen, fluorine, chlorine, bromine, iodine,
methyl, ethyl, isopropyl, cyclopropyl, C.ident.CH, CH.dbd.CH.sub.2,
C(CH.sub.3).dbd.CH.sub.2, CF.sub.3, CHF.sub.2, CH.sub.2F,
--CHF--CH.sub.3, --CF.sub.2--CH.sub.3, methoxy, ethoxy,
difluoromethoxy, trifluoromethoxy, methlythio, methylsulfinyl and
methylsulfonyl.
[0296] Most preferably, R.sup.45', R.sup.46', R.sup.47', R.sup.48'
and R.sup.49' are independently selected from the group consisting
of hydrogen, fluorine, chlorine, methyl, CF.sub.3, CHF.sub.2,
CH.sub.2F, methoxy, difluoromethoxy and trifluoromethoxy.
[0297] R.sup.50' is selected from the group consisting of hydrogen,
fluorine, C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 haloalkyl;
[0298] R.sup.51', R.sup.52', R.sup.53', R.sup.54', R.sup.55' and
R.sup.56' are selected, independently of each other, from the group
consisting of hydrogen, fluorine, C.sub.1-C.sub.4 alkyl,
C.sub.1-C.sub.4 haloalkyl, C.sub.2-C.sub.4 alkoxy and
C.sub.1-C.sub.4 alkylthio.
[0299] More preferably again, R.sup.50', is selected from the group
consisting of hydrogen, fluorine, C.sub.1-C.sub.4 alkyl,
C.sub.1-C.sub.4 haloalkyl;
[0300] R.sup.51', R.sup.52', R.sup.53', R.sup.54', R.sup.55' and
R.sup.56' are selected, independently of each other, from the group
consisting of hydrogen, fluorine, C.sub.1-C.sub.4 alkyl,
C.sub.1-C.sub.4 haloalkyl, C.sub.2-C.sub.4 alkoxy and
C.sub.1-C.sub.4 haloalkoxy.
[0301] Favourably, R.sup.50', R.sup.51', R.sup.52', R.sup.53',
R.sup.54', R.sup.55' and R.sup.56' are selected, independently of
each other, from the group consisting of hydrogen, fluorine,
methyl, ethyl, CH.sub.2F, CHF.sub.2, CF.sub.3, CHF--CH.sub.3 and
CF.sub.2--CH.sub.3.
[0302] More favourably again, R.sup.50, R.sup.51', R.sup.52',
R.sup.53', R.sup.54', R.sup.55' and R.sup.56' are selected,
independently of each other, from the group consisting of hydrogen,
fluorine, methyl, CH.sub.2F and CF.sub.3.
[0303] Most preferably, R.sup.50, R.sup.51', R.sup.52', R.sup.53',
R.sup.54', R.sup.55' and R.sup.56' are each hydrogen.
[0304] R.sup.57', R.sup.58', R.sup.59' and R.sup.60' are selected,
independently of each other, from the group consisting of hydrogen,
halogen, CN, NO.sub.2, OH, SH, CHO, C(.dbd.O)NH.sub.2,
C(.dbd.O)NH(CH.sub.3), C(.dbd.O)N(CH.sub.3).sub.2,
C(.dbd.S)NH.sub.2, C(.dbd.S)NH(CH.sub.3),
C(.dbd.S)N(CH.sub.3).sub.2, SO.sub.2NH.sub.2, SO.sub.2NH(CH.sub.3),
SO.sub.2N(CH.sub.3).sub.2, C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6
haloalkyl, C.sub.3-C.sub.6 cycloalkyl, C.sub.2-C.sub.6 alkenyl,
C.sub.2-C.sub.6 haloalkenyl, C.sub.2-C.sub.6 alkynyl,
C.sub.2-C.sub.6 haloalkynyl, C.sub.2-C.sub.6 alkoxy,
C.sub.2-C.sub.6 haloalkoxy, phenyl, C.sub.3-C.sub.6 alkenyloxy,
C.sub.3-C.sub.6 haloalkenyloxy, C.sub.3-C.sub.6 alkynyloxy,
C.sub.3-C.sub.6 cycloalkoxy, C.sub.3-C.sub.6 halocycloalkoxy,
benzyloxy, C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6
haloalkylthio, C.sub.1-C.sub.6 alkylsulfinyl, C.sub.1-C.sub.6
haloalkylsulfinyl, C.sub.1-C.sub.6 alkylsulfonyl and
C.sub.1-C.sub.6 haloalkylsulfonyl;
[0305] provided that at least one of R.sup.57', R.sup.58',
R.sup.59' and R.sup.60' is not hydrogen.
[0306] More preferably again, R.sup.57', R.sup.58', R.sup.59' and
R.sup.60' are selected, independently of each other, from the group
consisting of hydrogen, cyano, halogen, C.sub.1-C.sub.6 alkyl and
C.sub.1-C.sub.6 haloalkyl;
[0307] provided that at least one of R.sup.57', R.sup.58',
R.sup.59' and R.sup.60' is not hydrogen.
[0308] More favourably again, R.sup.57', R.sup.58', R.sup.59' and
R.sup.60' are selected, independently of each other, from the group
consisting of hydrogen, halogen, cyano, C.sub.1-C.sub.4 alkyl,
CHF.sub.2 and CF.sub.3; provided that at least one of R.sup.57',
R.sup.58', R.sup.59' and R.sup.60' is not hydrogen.
[0309] Most preferably, R.sup.57', R.sup.58', R.sup.59' and
R.sup.60' are selected, independently of each other, from the group
consisting of hydrogen and halogen;
[0310] provided that at least one of R.sup.57', R.sup.58',
R.sup.59' and R.sup.60' is not hydrogen.
[0311] In another group of compounds, R.sup.57', R.sup.58',
R.sup.59' and R.sup.60' are selected, independently of each other,
from the group consisting of hydrogen, phenyl and halophenyl;
[0312] provided that at least one of R.sup.57', R.sup.58',
R.sup.59' and R.sup.60' is not hydrogen.
[0313] In another group of compounds, R.sup.57', R.sup.58',
R.sup.59' and R.sup.60' are selected, independently of each other,
from the group consisting of hydrogen, methy, ethyl and
hydroxy-C.sub.2-C.sub.4-alkyl;
[0314] provided that at least one of R.sup.57', R.sup.58',
R.sup.59' and R.sup.60' is not hydrogen.
[0315] Preferably in this group, R.sup.57', R.sup.58', R.sup.59'
and R.sup.60' are selected, independently of each other, from the
group consisting of hydrogen and hydroxyethyl;
[0316] provided that at least one of R.sup.57', R.sup.58',
R.sup.59' and R.sup.60' is not hydrogen.
[0317] R.sup.61' and R.sup.62' are selected independently of each
other from the group consisting of hydrogen, fluorine, cyano,
C.sub.1-C.sub.4 alkyl and C.sub.1-C.sub.4 haloalkyl;
[0318] R.sup.63', R.sup.64', R.sup.65', R.sup.66', R.sup.67' and
R.sup.68' are selected independently of each other from the group
consisting of hydrogen, halogen, hydroxy, cyano, C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 haloalkyl, C.sub.1-C.sub.4 alkoxy,
C.sub.1-C.sub.4 haloalkoxy and C.sub.1-C.sub.4 alkylthio.
[0319] More preferably again, R.sup.61' and R.sup.62' are selected
independently of each other from the group consisting of hydrogen,
fluorine, cyano, C.sub.1-C.sub.4 alkyl and C.sub.1-C.sub.4
haloalkyl;
[0320] R.sup.63', R.sup.64', R.sup.65', R.sup.66, R.sup.67 and
R.sup.68' are selected independently of each other from the group
consisting of hydrogen, fluorine, cyano, C.sub.1-C.sub.4 alkyl,
C.sub.1-C.sub.4 haloalkyl, C.sub.1-C.sub.4 alkoxy and
C.sub.1-C.sub.4 haloalkoxy.
[0321] More favourably again, R.sup.61' and R.sup.62' are selected
independently of each other from the group consisting of hydrogen,
fluorine, methyl, ethyl, CHF.sub.2 and CF.sub.3;
[0322] R.sup.62', R.sup.63', R.sup.64', R.sup.65', R.sup.66',
R.sup.67' and R.sup.68' are selected independently of each other
from the group consisting of hydrogen, fluorine, methyl, ethyl,
methoxy, difluoromethoxy, trifluoromethoxy, CHF.sub.2 and
CF.sub.3.
[0323] Yet more favourably, R.sup.61', R.sup.62', R.sup.63',
R.sup.64', R.sup.65', R.sup.66', R.sup.67' and R.sup.68' are
hydrogen, CHF.sub.2, CF.sub.3 or methyl.
[0324] Yet more favourably still, R.sup.61', R.sup.62', R.sup.63,
R.sup.64, R.sup.65, R.sup.66, R.sup.67 and R.sup.68 are hydrogen or
methyl.
[0325] Most preferably, R.sup.61', R.sup.62, R.sup.63, R.sup.64,
R.sup.65, R.sup.66, R.sup.67 and R.sup.68 are hydrogen.
[0326] R.sup.69' is selected from hydrogen, C.sub.1-C.sub.4 alkyl,
C.sub.3-C.sub.4 alkenyl and C.sub.1-C.sub.4 alkylcarboxy.
[0327] More preferably again, R.sup.69' is selected from hydrogen,
C.sub.1-C.sub.4 alkyl and C.sub.1-C.sub.4 alkylcarboxy.
[0328] More favourably again, R.sup.69' is selected from hydrogen
and C.sub.1-C.sub.4 alkyl.
[0329] Most preferably, R.sup.69' is hydrogen.
[0330] n is 0 or 1.
[0331] In one preferred group of compounds, n is 0.
[0332] In another preferred group of compounds, n is 1.
[0333] p and q are independently selected from 0 and 1.
[0334] In one group of compounds, p and q are 0.
[0335] In another group of compounds, p and q are 1.
[0336] In another group of compounds, p is 1 and q is 0.
[0337] r, s and t are independently selected from 0 and 1.
[0338] More preferably again, r and s are 0 and t is 1 or 0.
[0339] Most preferably, r, s and t are each 0.
[0340] In a group of compounds of formula I, R.sub.1 and R.sub.2
are each independently selected from hydrogen, C.sub.1-C.sub.4
alkyl, C.sub.3-C.sub.4 alkenyl and C.sub.3-C.sub.4 alkynyl;
[0341] or R.sub.1 and R.sub.2 together with the nitrogen atom to
which they are attached form a pyrrolidine or piperidine;
[0342] R.sub.3 represents hydrogen, halogen, cyano, mercapto,
hydroxy, C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 haloalkyl,
C.sub.2-C.sub.4 alkenyl, C.sub.2-C.sub.4 haloalkenyl,
C.sub.2-C.sub.4 alkynyl, C.sub.1-C.sub.4 alkoxy, C.sub.1-C.sub.4
haloalkoxy, C.sub.3-C.sub.6 cycloalkyl, amino, C.sub.1-C.sub.2
alkyl amino, di(C.sub.1-C.sub.6alkyl)amino, pyrrolidino,
imidazolino, triazolino, tetrazolino, formyl, C.sub.2-C.sub.5
alkylcarbonyl, C.sub.2-C.sub.5 haloalkylcarbonyl, C.sub.1-C.sub.6
alkylthio, C.sub.1-C.sub.6 alkylsulfinyl, C.sub.1-C.sub.6
alkylsulfonyl, C.sub.1-C.sub.6 haloalkylthio, C.sub.1-C.sub.6
haloalkylsulfinyl, C.sub.1-C.sub.6 haloalkylsulfonyl or
C.sub.1-C.sub.6 hydroxyalkyl;
[0343] R.sub.4 represents hydrogen, halogen, cyano, amino,
C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 haloalkyl, C.sub.3-C.sub.6
cycloalkyl, C.sub.2-C.sub.4 alkenyl, C.sub.2-C.sub.4 alkynyl,
C.sub.1-C.sub.4 alkoxy, C.sub.1-C.sub.4 haloalkoxy, C.sub.1-C.sub.4
alkylthio, C.sub.1-C.sub.4 alkylsulfinyl, C.sub.1-C.sub.4
alkylsulfonyl, methylamino and dimethylamino;
[0344] R.sub.5 represents hydrogen, C.sub.1-C.sub.12-alkylsulfonyl,
C.sub.1-C.sub.12 alkyl, C.sub.3-C.sub.12 alkenyl, C.sub.3-C.sub.12
alkynyl, or is C.sub.1-C.sub.12 alkyl, C.sub.2-C.sub.12 alkenyl,
C.sub.2-C.sub.12 alkynyl mono- to polysubstituted by substituents
independently selected from the group consisting of halogen, cyano,
nitro, hydroxy, mercapto, azido, formyl,
C.sub.2-C.sub.7alkylcarbonyl, C.sub.2-C.sub.7 haloalkylcarbonyl,
C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6 haloalkyl, C.sub.1-C.sub.6
alkoxy, C.sub.1-C.sub.6 haloalkoxy, C.sub.1-C.sub.6 alkylthio,
C.sub.1-C.sub.6 alkylsulfinyl and C.sub.1-C.sub.6 alkylsulfonyl;
or
[0345] R.sub.5 is (R.sub.51)(R.sub.52)(R.sub.53)Si--,
(R.sub.51)(R.sub.52)(R.sub.53)Si--(C.sub.1-C.sub.12alkyl)-,
(R.sub.51)(R.sub.52)(R.sub.53)Si--(C.sub.3-C.sub.8cycloalkyl)-,
(R.sub.54O)(R.sub.55O)(R.sub.56O)Si--,
(R.sub.54O)(R.sub.55O)(R.sub.56O)Si--(C.sub.1-C.sub.12alkyl)- or
(R.sub.54O)(R.sub.55O)(R.sub.56O)Si--(C.sub.3-C.sub.8cycloalkyl)-;
or
[0346] R.sub.5 is C.sub.1-C.sub.6alkyl-B--C.sub.1-C.sub.12alkyl-,
C.sub.2-C.sub.6alkenyl-B--C.sub.1-C.sub.12alkyl-,
C.sub.2-C.sub.6alkynyl-B--C.sub.1-C.sub.12alkyl-,
C.sub.3-C.sub.8cycloalkyl-B--C.sub.1-C.sub.12alkyl-,
benzyl-B--C.sub.1-C.sub.12alkyl-, phenyl-B--C.sub.1-C.sub.12alkyl-,
C.sub.1-C.sub.6alkyl-B--C.sub.2-C.sub.12alkenyl-,
C.sub.2-C.sub.6alkenyl-B--C.sub.2-C.sub.12alkenyl-,
C.sub.2-C.sub.6alkynyl-B--C.sub.2-C.sub.12alkenyl-,
C.sub.3-C.sub.8cycloalkyl-B--C.sub.2-C.sub.12alkenyl-,
benzyl-B--C.sub.2-C.sub.12alkenyl-,
phenyl-B--C.sub.2-C.sub.12alkenyl-,
C.sub.1-C.sub.6alkyl-B--C.sub.2-C.sub.12alkynyl-,
C.sub.2-C.sub.6alkenyl-B--C.sub.2-C.sub.12alkynyl-,
C.sub.2-C.sub.6alkynyl-B--C.sub.2-C.sub.12alkynyl-,
C.sub.3-C.sub.8cycloalkyl-B--C.sub.2-C.sub.12alkynyl-,
benzyl-B--C.sub.2-C.sub.12alkynyl-,
phenyl-B--C.sub.2-C.sub.12alkynyl-,
C.sub.1-C.sub.6alkyl-B--C.sub.3-C.sub.8cycloalkyl-,
C.sub.2-C.sub.6alkenyl-B--C.sub.3-C.sub.8cycloalkyl-,
C.sub.2-C.sub.6alkynyl-B--C.sub.3-C.sub.8cycloalkyl-,
C.sub.3-C.sub.8cycloalkyl-B--C.sub.3-C.sub.8cycloalkyl-,
benzyl-B--C.sub.3-C.sub.12cycloalkyl- or
phenyl-B--C.sub.3-C.sub.12cycloalkyl-, wherein the group B is
selected from --C(.dbd.O)--, --C(.dbd.S)--, --C(.dbd.NOR.sub.59)--,
--C(R.sub.60).dbd.NO--, --ON.dbd.C(R.sub.60)--, --O--C(.dbd.O)--,
--C(.dbd.O)--O--, --O--, --S--, --S(.dbd.O)--, --S(.dbd.O)2-,
--S(.dbd.O)(.dbd.NR.sub.13)--, --S(.dbd.O)(R.sub.14).dbd.N--,
--N.dbd.S(.dbd.O)(R.sub.14)--, --N(R.sub.62)--C.dbd.O)--,
--C.dbd.O)--N(R.sub.62)--, --N(R.sub.62)--SO.sub.2-- or
--SO.sub.2--N(R.sub.62)--; or
[0347] R.sub.5 is C.sub.1-C.sub.6alkyl-B--C.sub.1-C.sub.12alkyl-,
C.sub.2-C.sub.6alkenyl-B--C.sub.1-C.sub.12alkyl-,
C.sub.2-C.sub.6alkynyl-B--C.sub.1-C.sub.12alkyl-,
C.sub.3-C.sub.8cycloalkyl-B--C.sub.1-C.sub.12alkyl-,
benzyl-B--C.sub.1-C.sub.12alkyl-, phenyl-B--C.sub.1-C.sub.12alkyl-,
C.sub.1-C.sub.6alkyl-B--C.sub.2-C.sub.12alkenyl-,
C.sub.2-C.sub.6alkenyl-B--C.sub.2-C.sub.12alkenyl-,
C.sub.2-C.sub.6alkynyl-B--C.sub.2-C.sub.12alkenyl-,
C.sub.3-C.sub.8cycloalkyl-B--C.sub.2-C.sub.12alkenyl-,
benzyl-B--C.sub.2-C.sub.12alkenyl-,
phenyl-B--C.sub.2-C.sub.12alkenyl-,
C.sub.1-C.sub.6alkyl-B--C.sub.2-C.sub.12alkynyl-,
C.sub.2-C.sub.6alkenyl-B--C.sub.2-C.sub.12alkynyl-,
C.sub.2-C.sub.6alkynyl-B--C.sub.2-C.sub.12alkynyl-,
C.sub.3-C.sub.8cycloalkyl-B--C.sub.2-C.sub.12alkynyl-,
benzyl-B--C.sub.2-C.sub.12alkynyl-,
phenyl-B--C.sub.2-C.sub.12alkynyl-,
C.sub.1-C.sub.6alkyl-B--C.sub.3-C.sub.5cycloalkyl-,
C.sub.2-C.sub.6alkenyl-B--C.sub.3-C.sub.8cycloalkyl-,
C.sub.2-C.sub.6alkynyl-B--C.sub.3-C.sub.8cycloalkyl-,
C.sub.3-C.sub.8cycloalkyl-B--C.sub.3-C.sub.8cycloalkyl-,
benzyl-B--C.sub.3-C.sub.12cycloalkyl-,
phenyl-B--C.sub.3-C.sub.12cycloalkyl-, all of which, in turn, are
mono- to polysubstituted by substituents independently selected
from the group consisting of halogen, cyano, hydroxy, mercapto,
C.sub.1-C.sub.6 haloalkyl, C.sub.1-C.sub.6 alkoxy, formyl,
C.sub.2-C.sub.6 alkylcarbonyl, C.sub.1-C.sub.6 alkylthio,
C.sub.1-C.sub.6 alkylsulfinyl and C.sub.1-C.sub.6 alkylsulfonyl;
or
[0348] R.sub.5 is selected from A-, A-(C.sub.1-C.sub.6alkyl)-,
A-O--(C.sub.1-C.sub.6alkyl)-, A-(C.sub.3-C.sub.6alkenyl)-,
A-O--(C.sub.4-C.sub.6alkenyl)-, A-(C.sub.3-C.sub.6-alkynyl)-,
A-O--(C.sub.4-C.sub.6alkynyl)-, A-(C.sub.3-C.sub.8cycloalkyl)- and
A-O--(C.sub.3-C.sub.8cycloalkyl)-;
[0349] wherein A is a three- to ten-membered monocyclic or fused
bicyclic ring system which can be aromatic, partially saturated or
fully saturated and can contain 1 to 4 hetero atoms selected from
the group consisting of nitrogen, oxygen and sulphur, it not being
possible for each ring system to contain --O--O--, --S--S-- and
--O--S-- fragments, and it being possible for the three- to
ten-membered ring system to be itself mono- or polysubstituted
[0350] A1) by substituents independently selected from the group
consisting of
[0351] halogen, cyano, nitro, hydroxy, mercapto, nitro, azido,
formyl, carboxy, .dbd.O, .dbd.S, C.sub.1-C.sub.6 alkyl,
C.sub.2-C.sub.6 alkenyl, C.sub.2-C.sub.6 alkynyl, C.sub.3-C.sub.8
cycloalkyl, C.sub.1-C.sub.6 haloalkyl, C.sub.2-C.sub.6 haloalkenyl,
C.sub.2-C.sub.6 haloalkynyl, C.sub.3-C.sub.8 halocycloalkyl,
C.sub.1-C.sub.6 alkoxy, C.sub.1-C.sub.6 haloalkoxy, C.sub.3-C.sub.6
alkenyloxy, C.sub.3-C.sub.6 haloalkenyloxy, C.sub.3-C.sub.6
alkynyloxy, C.sub.3-C.sub.8 cycloalkyloxy, C.sub.3-C.sub.8
halocycloalkyloxy, C.sub.3-C.sub.8 cycloalkenyloxy, C.sub.3-C.sub.8
halocycloalkenyloxy, benzyl, benzyloxy, phenyl and phenoxy, where
the benzyl, benzyloxy, phenyl and phenoxy, in turn, may be mono- to
polysubstituted by substituents independently selected from the
group consisting of halogen, cyano, nitro, hydroxy, mercapto,
amino, C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6 haloalkyl,
C.sub.1-C.sub.6 alkoxy, C.sub.1-C.sub.6 haloalkoxy, C.sub.1-C.sub.6
alkylthio, C.sub.1-C.sub.6 alkylsulfinyl and C.sub.1-C.sub.6
alkylsulfonyl; or
[0352] A3) by substituents independently selected from the group
consisting of
[0353] formyl, C.sub.2-C.sub.7 alkylcarbonyl, C.sub.2-C.sub.7
haloalkylcarbonyl, C.sub.3-C.sub.7 alkenylcarbonyl, C.sub.3-C.sub.7
haloalkenylcarbonyl, C.sub.4-C.sub.9 cycloalkylcarbonyl,
C.sub.2-C.sub.7 alkoxycarbonyl, C.sub.4-C.sub.7 alkenyloxycarbonyl,
C.sub.4-C.sub.7 alkynyloxycarbonyl, C.sub.4-C.sub.9
cycloalkoxycarbonyl and benzyloxycarbonyl, and benzyloxycarbonyl
mono- to polysubstituted by substituents independently selected
from the group consisting of halogen, cyano, hydroxy,
C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6 haloalkyl and
C.sub.1-C.sub.6 alkoxy; or
[0354] A4) by substituents independently selected from the group
consisting of hydroxyl, C.sub.1-C.sub.4 alkyl, C.sub.2-C.sub.4
alkenyl, C.sub.2-C.sub.4 alkynyl, C.sub.1-C.sub.4 alkoxy, halogen,
C.sub.1-C.sub.4 haloalkyl, C.sub.2-C.sub.4 haloalkenyl, cyano,
benzyl, phenyl, .dbd.C(R.sup.36').sub.2, .dbd.N--OH,
.dbd.N--O--C.sub.1-C.sub.4-alkyl, .dbd.N--O--C.sub.3-C.sub.4
alkenyl, .dbd.N--O--C.sub.3-C.sub.4 alkynyl,
.dbd.N--O--C.sub.1-C.sub.4 haloalkyl, .dbd.N--O--C.sub.3-C.sub.4
haloalkenyl, .dbd.N--O-benzyl and .dbd.N--O-phenyl, wherein the
.dbd.N--O-benzyl and .dbd.N--O-phenyl are optionally substituted by
one or more group selected from the group consisting of halogen,
methyl, halomethyl; or
[0355] R.sub.5 is a C.sub.8-C.sub.11 spirobicyclic system
containing 0, 1 or 2 O, S or N atoms, wherein there are no adjacent
O atoms, which is optionally substituted by one or more groups
independently selected from halogen, CN, NO.sub.2, OH, SH, CHO,
COOH, tri(C.sub.1-C.sub.6-alkyl)silyl, C.sub.1-C.sub.6 alkyl,
--CH(CH.sub.3)--CH.sub.2--CH.sub.2--CH.sub.3,
--CH--CH(CH.sub.3)--CH.sub.2--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3)--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3).sub.2,
--CH(CH.sub.3)--CH(CH.sub.3).sub.2, C.sub.1-C.sub.6 haloalkyl,
C.sub.3-C.sub.6 cycloalkyl, C.sub.3-C.sub.6 halocycloalkyl,
C.sub.2-C.sub.6 alkenyl, C.sub.2-C.sub.6 haloalkenyl,
C.sub.1-C.sub.6 alkoxy, C.sub.1-C.sub.6 haloalkoxy,
C.sub.2-C.sub.7-alkylcarbonyl, C.sub.2-C.sub.7-alkoxycarbonyl,
C.sub.4-C.sub.7-alkenyloxycarbonyl,
C.sub.4-C.sub.7-alkynyloxycarbonyl, C.sub.1-C.sub.6 alkylthio,
C.sub.1-C.sub.6 alkylsulfinyl, C.sub.1-C.sub.6 alkylsulfonyl,
.dbd.O, --C(.dbd.O)NH.sub.2, --C(.dbd.O)NH(CH.sub.3),
--C(.dbd.O)N(CH.sub.3).sub.2 and --C(.dbd.S)NH.sub.2;
[0356] R.sub.6 is hydrogen;
[0357] R.sub.7 is hydrogen or C.sub.1-C.sub.4 alkyl.
[0358] In another group of compounds of formula I, R.sub.1 and
R.sub.2 are each independently selected from hydrogen or
C.sub.1-C.sub.4 alkyl;
[0359] or R.sub.1 and R.sub.2 together with the nitrogen atom to
which they are attached form a pyrrolidine or piperidine;
[0360] R.sub.3 represents hydrogen, halogen, cyano, C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 haloalkyl, C.sub.2-C.sub.4 alkenyl,
C.sub.2-C.sub.4 alkynyl, C.sub.1-C.sub.4 alkoxy, C.sub.3-C.sub.6
cycloalkyl, amino, C.sub.1-C.sub.2 alkylamino,
di(C.sub.1-C.sub.6alkyl)amino, pyrrolidino, imidazolino,
triazolino, formyl, phenyl, C.sub.2-C.sub.4 alkylcarbonyl,
C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6 alkylsulfinyl,
C.sub.1-C.sub.6 alkylsulfonyl or C.sub.1-C.sub.6 hydroxyalkyl;
[0361] R.sub.4 is selected from fluorine, chlorine, bromine,
C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 alkenyl, C.sub.1-C.sub.4
haloalkyl, C.sub.1-C.sub.4 alkoxy, and C.sub.3-C.sub.6
cycloalkyl;
[0362] R.sub.5 is selected from G.sup.1, G.sup.2, G.sup.3-G.sup.4,
G.sup.5, G.sup.6-G.sup.7, G.sup.8, G.sup.9, G.sup.10-G.sup.11,
G.sup.12, G.sup.13, G.sup.14, G.sup.15 and G.sup.16;
[0363] R.sub.6 is hydrogen;
[0364] R.sub.7 is selected from hydrogen or C.sub.1-C.sub.4
alkyl;
[0365] G.sup.1 is a C.sub.8-C.sub.10 fused bicyclic ring system
which may be saturated or comprise one carbon-carbon double bond
and is optionally substituted by one or more groups independently
selected from hydroxyl, C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4
alkoxy, halogen, C.sub.1-C.sub.4 haloalkyl and cyano;
[0366] G.sup.2 is C.sub.3-C.sub.6 cycloalkenyl, which is optionally
substituted by one or more groups independently selected from
halogen, CN, NO.sub.2, OH, SH, CHO, COOH,
tri(C.sub.1-C.sub.6-alkyl)silyl, ethyl, n-propyl, iso-propyl,
n-butyl, iso-butyl, sec-butyl, tert-butyl, n-pentyl,
--CH(CH.sub.3)--CH.sub.2--CH.sub.2--CH.sub.3,
--CH--CH(CH.sub.3)--CH.sub.2--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3)--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3).sub.2,
--CH(CH.sub.3)--CH(CH.sub.3).sub.2, C.sub.2-C.sub.6 haloalkyl,
C.sub.3-C.sub.6 cycloalkyl, C.sub.3-C.sub.6 halocycloalkyl,
C.sub.2-C.sub.6 alkenyl, C.sub.2-C.sub.6 haloalkenyl,
C.sub.1-C.sub.6 alkoxy, C.sub.1-C.sub.6 haloalkoxy, C.sub.2-C.sub.7
alkylcarbonyl, C.sub.2-C.sub.7 alkoxycarbonyl, C.sub.4-C.sub.7
alkenyloxycarbonyl, C.sub.4-C.sub.7 alkynyloxycarbonyl,
C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6 alkylsulfinyl,
C.sub.1-C.sub.6 alkylsulfonyl, --C(.dbd.O)NH.sub.2,
--C(.dbd.O)NH(CH.sub.3), --C(.dbd.O)N(CH.sub.3).sub.2 and
--C(.dbd.S)NH.sub.2;
[0367] G.sup.3 is phenyl, which is optionally substituted by one or
more groups independently selected from hydroxyl, C.sub.1-C.sub.4
alkyl, C.sub.2-C.sub.4 alkenyl, C.sub.2-C.sub.4 alkynyl,
C.sub.1-C.sub.4 alkoxy, halogen and cyano, wherein the alkyl groups
are optionally substituted by one or more halogen;
[0368] G.sup.4 is C.sub.3-C.sub.12 cycloalkyl which is optionally
substituted by one or more groups independently selected from
hydroxyl, C.sub.1-C.sub.4 alkyl, C.sub.2-C.sub.4 alkenyl,
C.sub.2-C.sub.4 alkynyl, C.sub.1-C.sub.4 alkoxy, halogen and cyano,
wherein the alkyl groups are optionally substituted by one or more
halogen;
[0369] G.sup.5 is C.sub.3-C.sub.7 cycloalkyl, which is optionally
substituted by one or more groups independently selected from
halogen, CN, NO.sub.2, OH, SH, CHO, COOH,
tri(C.sub.1-C.sub.6-alkyl)silyl, ethyl, n-propyl, iso-propyl,
n-butyl, iso-butyl, sec-butyl, tert-butyl, n-pentyl,
--CH(CH.sub.3)--CH.sub.2--CH.sub.2--CH.sub.3,
--CH--CH(CH.sub.3)--CH.sub.2--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3)--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3).sub.2,
--CH(CH.sub.3)--CH(CH.sub.3).sub.2, C.sub.2-C.sub.6 haloalkyl,
C.sub.3-C.sub.6 cycloalkyl, C.sub.3-C.sub.6 halocycloalkyl,
C.sub.2-C.sub.6 alkenyl, C.sub.2-C.sub.6 haloalkenyl,
C.sub.1-C.sub.6 alkoxy, C.sub.1-C.sub.6 haloalkoxy,
C.sub.3-C.sub.6-alkenyloxy, C.sub.2-C.sub.7 alkylcarbonyl,
C.sub.2-C.sub.7 alkoxycarbonyl, C.sub.4-C.sub.7 alkenyloxycarbonyl,
C.sub.4-C.sub.7 alkynyloxycarbonyl, C.sub.1-C.sub.6 alkylthio,
C.sub.1-C.sub.6 alkylsulfinyl, C.sub.1-C.sub.6 alkylsulfonyl,
phenoxy, --C(.dbd.O)NH.sub.2, --C(.dbd.O)NH(CH.sub.3),
--C(.dbd.O)N(CH.sub.3).sub.2 and --C(.dbd.S)NH.sub.2;
[0370] G.sup.6 is phenyl, which must be substituted by at least one
fluorine and is optionally further substituted by one or more
groups independently selected from halogen, CN, NO.sub.2, OH, SH,
CHO, C(.dbd.O)NH.sub.2, C(.dbd.O)NH(CH.sub.3),
C(.dbd.O)N(CH.sub.3).sub.2, C(.dbd.S)NH.sub.2,
C(.dbd.S)NH(CH.sub.3), C(.dbd.S)N(CH.sub.3).sub.2,
SO.sub.2NH.sub.2, SO.sub.2NH(CH.sub.3), SO.sub.2N(CH.sub.3).sub.2,
C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6 haloalkyl, C.sub.3-C.sub.6
cycloalkyl, C.sub.2-C.sub.6 alkenyl, C.sub.2-C.sub.6 haloalkenyl,
C.sub.2-C.sub.6 alkynyl, C.sub.2-C.sub.6 haloalkynyl,
C.sub.1-C.sub.6 alkoxy, C.sub.1-C.sub.6 haloalkoxy, C.sub.3-C.sub.6
alkenyloxy, C.sub.3-C.sub.6 haloalkenyloxy, C.sub.3-C.sub.6
alkynyloxy, C.sub.3-C.sub.6 cycloalkoxy, C.sub.3-C.sub.6
halocycloalkoxy, C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6
haloalkylthio, C.sub.1-C.sub.6 alkylsulfinyl, C.sub.1-C.sub.6
haloalkylsulfinyl, C.sub.1-C.sub.6 alkylsulfonyl and
C.sub.1-C.sub.6 haloalkylsulfonyl;
[0371] G.sup.7 is methylene;
[0372] G.sup.8 is
##STR00016##
[0373] G.sup.9 is
##STR00017##
[0374] G.sup.10 is phenyl, which is optionally substituted by one
or more groups independently selected from hydrogen, halogen, CN,
NO.sub.2, OH, SH, CHO, C(.dbd.O)NH.sub.2, C(.dbd.O)NH(CH.sub.3),
C(.dbd.O)N(CH.sub.3).sub.2, C(.dbd.S)NH.sub.2,
C(.dbd.S)NH(CH.sub.3), C(.dbd.S)N(CH.sub.3).sub.2,
SO.sub.2NH.sub.2, SO.sub.2NH(CH.sub.3), SO.sub.2N(CH.sub.3).sub.2,
C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6 haloalkyl, C.sub.3-C.sub.6
cycloalkyl, C.sub.2-C.sub.6 alkenyl, C.sub.2-C.sub.6 haloalkenyl,
C.sub.2-C.sub.6 alkynyl, C.sub.2-C.sub.6 haloalkynyl,
C.sub.1-C.sub.6 alkoxy, C.sub.1-C.sub.6 haloalkoxy, C.sub.3-C.sub.6
alkenyloxy, C.sub.3-C.sub.6 haloalkenyloxy, C.sub.3-C.sub.6
alkynyloxy, C.sub.3-C.sub.6 cycloalkoxy, C.sub.3-C.sub.6
halocycloalkoxy, phenyl, C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6
haloalkylthio, C.sub.1-C.sub.6 alkylsulfinyl, C.sub.1-C.sub.6
haloalkylsulfinyl, C.sub.1-C.sub.6 alkylsulfonyl, C.sub.1-C.sub.6
alkylsulfonyl, C.sub.1-C.sub.6 haloalkylsulfonyl, phenyl,
2-phenyl-ethynyl and 2-phenyl-ethyl;
[0375] G.sup.11 is methylene substituted by at least one group
independently selected from C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4
haloalkyl, CN, C.sub.1-C.sub.4 alkoxy and C.sub.1-C.sub.4
haloalkoxy;
[0376] G.sup.12 is
##STR00018##
[0377] G.sup.13 is a C.sub.8-C.sub.11 spirobicyclic system
containing 0, 1 or 2 O or N atoms, wherein there are no adjacent O
atoms, which is optionally substituted by one or more groups
independently selected from halogen, CN, NO.sub.2, OH, SH, CHO,
COOH, tri(C.sub.1-C.sub.6 alkyl)silyl, C.sub.1-C.sub.6 alkyl,
C.sub.1-C.sub.6 haloalkyl, C.sub.3-C.sub.6 cycloalkyl,
C.sub.3-C.sub.6 halocycloalkyl, C.sub.2-C.sub.6 alkenyl,
C.sub.2-C.sub.6 haloalkenyl, C.sub.1-C.sub.6 alkoxy,
C.sub.1-C.sub.6 haloalkoxy, C.sub.2-C.sub.7 alkylcarbonyl,
C.sub.2-C.sub.7 alkoxycarbonyl, C.sub.4 C.sub.7 alkenyloxycarbonyl,
C.sub.4 C.sub.7 alkynyloxycarbonyl, C.sub.1-C.sub.6 alkylthio,
C.sub.1-C.sub.6 alkylsulfinyl, C.sub.1-C.sub.6 alkylsulfonyl,
.dbd.O, --C(.dbd.O)NH.sub.2, --C(.dbd.O)NH(CH.sub.3),
--C(.dbd.O)N(CH.sub.3).sub.2 and --C(.dbd.S)NH.sub.2;
[0378] G.sup.14 is
##STR00019##
[0379] G.sup.15 is
##STR00020##
[0380] G.sup.16 is
##STR00021##
[0381] G.sup.17 is a five- to six-membered monocyclic
heteroaromatic ring system which can contain 1 to 4 members
selected from the group consisting of N, N(R.sup.69'), O and S (for
example, pyridine, pyrimidine, furan, pyrrole, thiazole, oxazole,
pyrazole, imidazole, oxadiazole, thiadiazole or tetrazole), it not
being possible for each ring system to contain --O--O--, --S--S--
and --O--S-- fragments, and it being possible for the five- to
six-membered ring system to be itself mono- or polysubstituted by
groups selected from the group consisting of halogen, CN, NO.sub.2,
OH, SH, CHO, C(.dbd.O)NH.sub.2, C(.dbd.O)NH(CH.sub.3),
C(.dbd.O)N(CH.sub.3).sub.2, C(.dbd.S)NH.sub.2,
C(.dbd.S)NH(CH.sub.3), C(.dbd.S)N(CH.sub.3).sub.2,
SO.sub.2NH.sub.2, SO.sub.2NH(CH.sub.3), SO.sub.2N(CH.sub.3).sub.2,
C.sub.1-C.sub.6alkyl, C.sub.1-C.sub.6 haloalkyl, C.sub.3-C.sub.6
cycloalkyl, C.sub.2-C.sub.6 alkenyl, C.sub.2-C.sub.6 haloalkenyl,
C.sub.2-C.sub.6 alkynyl, C.sub.2-C.sub.6 haloalkynyl,
C.sub.1-C.sub.6 alkoxy, C.sub.1-C.sub.6 haloalkoxy, C.sub.3-C.sub.6
alkenyloxy, C.sub.3-C.sub.6 haloalkenyloxy, C.sub.3-C.sub.6
alkynyloxy, C.sub.3-C.sub.6 cycloalkoxy, C.sub.3-C.sub.6
halocycloalkoxy, C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6
haloalkylthio, C.sub.1-C.sub.6 alkylsulfinyl, C.sub.1-C.sub.6
haloalkylsulfinyl, C.sub.1-C.sub.6 alkylsulfonyl and
C.sub.1-C.sub.6 haloalkylsulfonyl;
[0382] R.sup.1' is selected from the group consisting of hydrogen,
fluorine, C.sub.1-C.sub.4-alkyl, C.sub.1-C.sub.4-haloalkyl;
[0383] R.sup.2', R.sup.3', R.sup.4' and R.sup.5' are selected,
independently of each other, from the group consisting of hydrogen,
fluorine, C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 haloalkyl,
C.sub.1-C.sub.4 alkoxy and C.sub.1-C.sub.4 alkylthio;
[0384] R.sup.11', R.sup.12', R.sup.13' and R.sup.14' are selected,
independently of each other, from the group consisting of hydrogen,
halogen, CN, NO.sub.2, OH, SH, CHO, C(.dbd.O)NH.sub.2,
C(.dbd.O)NH(CH.sub.3), C(.dbd.O)N(CH.sub.3).sub.2,
C(.dbd.S)NH.sub.2, C(.dbd.S)NH(CH.sub.3),
C(.dbd.S)N(CH.sub.3).sub.2, SO.sub.2NH.sub.2, SO.sub.2NH(CH.sub.3),
SO.sub.2N(CH.sub.3).sub.2, C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6
haloalkyl, C.sub.3-C.sub.6 cycloalkyl, C.sub.2-C.sub.6 alkenyl,
C.sub.2-C.sub.6 haloalkenyl, C.sub.2-C.sub.6 alkynyl,
C.sub.2-C.sub.6 haloalkynyl, C.sub.1-C.sub.6 alkoxy,
C.sub.1-C.sub.6 haloalkoxy, phenyl, C.sub.3-C.sub.6 alkenyloxy,
C.sub.3-C.sub.6 haloalkenyloxy, C.sub.3-C.sub.6 alkynyloxy,
C.sub.3-C.sub.6 cycloalkoxy, C.sub.3-C.sub.6 halocycloalkoxy,
benzyloxy, C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6
haloalkylthio, C.sub.1-C.sub.6 alkylsulfinyl, C.sub.1-C.sub.6
haloalkylsulfinyl, C.sub.1-C.sub.6 alkylsulfonyl and
C.sub.1-C.sub.6 haloalkylsulfonyl;
[0385] R.sup.15' and R.sup.16' are independently selected from the
group consisting of hydrogen, halogen, cyano, C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 haloalkyl and C.sub.3-C.sub.6
cycloalkyl;
[0386] each R.sup.17', R.sup.18', R.sup.19', R.sup.20', R.sup.21'
and R.sup.22 are selected independently of each other, from the
group consisting of hydrogen, halogen, cyano, C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 haloalkyl, C.sub.1-C.sub.4 alkoxy,
C.sub.1-C.sub.4 haloalkoxy and C.sub.3-C.sub.6 cycloalkyl;
[0387] R.sup.23', R.sup.24' and R.sup.25' are independently
selected from the group consisting of hydrogen, halogen, cyano,
C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 haloalkyl, C.sub.1-C.sub.4
alkoxy, C.sub.3-C.sub.6 cycloalkyl, C.sub.3-C.sub.6 halocycloalkyl
and C.sub.1-C.sub.4 alkylthio;
[0388] R.sup.26' is C(R.sup.36').sub.2, N--OH,
N--O--C.sub.1-C.sub.4-alkyl, N--O--C.sub.2-C.sub.4-alkenyl,
N--O--C.sub.2-C.sub.4 alkynyl, N--O--C.sub.1-C.sub.4 haloalkyl,
N--O--C.sub.2-C.sub.4 haloalkenyl, N--O-benzyl, N--O-phenyl,
N--O-halophenyl, O wherein the N--O-benzyl and N--O-phenyl may be
substituted by one or more groups independently selected from the
group consisting of halogen, methyl and halomethyl;
[0389] R.sup.27', R.sup.28', R.sup.29', R.sup.30', R.sup.31',
R.sup.32', R.sup.33', R.sup.34' and R.sup.35' are each
independently selected from the group consisting of hydrogen,
hydroxyl, C.sub.1-C.sub.4 alkyl, C.sub.2-C.sub.4 alkenyl,
C.sub.2-C.sub.4 alkynyl, C.sub.1-C.sub.4 alkoxy, halogen,
C.sub.1-C.sub.4 haloalkyl, C.sub.2-C.sub.4 haloalkenyl, cyano,
benzyl and phenyl;
[0390] or R.sup.28' and R.sup.29' together with the two carbon
atoms to which they are attached form a double bond;
[0391] each R.sup.36' is independently selected from hydrogen,
halogen and C.sub.1-C.sub.4 alkyl;
[0392] R.sup.37' and R.sup.38' are selected independently of each
other from the group consisting of hydrogen, halogen, cyano,
C.sub.1-C.sub.4 alkyl and C.sub.1-C.sub.4 haloalkyl;
[0393] R.sup.39', R.sup.40', R.sup.41', R.sup.42', R.sup.43' and
R.sup.44' are selected independently of each other from the group
consisting of hydrogen, halogen, hydroxy, cyano, C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 haloalkyl, C.sub.1-C.sub.4 alkoxy,
C.sub.1-C.sub.4 haloalkoxy and C.sub.1-C.sub.4 alkylthio;
[0394] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, halogen, CN, NO.sub.2, OH, SH, CHO, C(.dbd.O)NH.sub.2,
C(.dbd.O)NH(CH.sub.3), C(.dbd.O)N(CH.sub.3).sub.2,
C(.dbd.S)NH.sub.2, C(.dbd.S)NH(CH.sub.3),
C(.dbd.S)N(CH.sub.3).sub.2, SO.sub.2NH.sub.2, SO.sub.2NH(CH.sub.3),
SO.sub.2N(CH.sub.3).sub.2, C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6
haloalkyl, C.sub.3-C.sub.6 cycloalkyl, C.sub.2-C.sub.6 alkenyl,
C.sub.2-C.sub.6 haloalkenyl, C.sub.2-C.sub.6 alkynyl,
C.sub.2-C.sub.6 haloalkynyl, C.sub.1-C.sub.6 alkoxy,
C.sub.1-C.sub.6 haloalkoxy, C.sub.3-C.sub.6 alkenyloxy,
C.sub.3-C.sub.6 haloalkenyloxy, C.sub.3-C.sub.6 alkynyloxy,
C.sub.3-C.sub.6 cycloalkoxy, C.sub.3-C.sub.6 halocycloalkoxy,
C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6 haloalkylthio,
C.sub.1-C.sub.6 alkylsulfinyl, C.sub.1-C.sub.6 haloalkylsulfinyl,
C.sub.1-C.sub.6 alkylsulfonyl and C.sub.1-C.sub.6
haloalkylsulfonyl;
[0395] R.sup.50' is selected from the group consisting of hydrogen,
fluorine, C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 haloalkyl;
[0396] R.sup.51', R.sup.52', R.sup.53', R.sup.54', R.sup.55' and
R.sup.56' are selected, independently of each other, from the group
consisting of hydrogen, fluorine, C.sub.1-C.sub.4 alkyl,
C.sub.1-C.sub.4 haloalkyl, C.sub.2-C.sub.4 alkoxy and
C.sub.1-C.sub.4 alkylthio;
[0397] R.sup.57', R.sup.58', R.sup.59' and R.sup.60' are selected,
independently of each other, from the group consisting of hydrogen,
halogen, CN, NO.sub.2, OH, SH, CHO, C(.dbd.O)NH.sub.2,
C(.dbd.O)NH(CH.sub.3), C(.dbd.O)N(CH.sub.3).sub.2,
C(.dbd.S)NH.sub.2, C(.dbd.S)NH(CH.sub.3),
C(.dbd.S)N(CH.sub.3).sub.2, SO.sub.2NH.sub.2, SO.sub.2NH(CH.sub.3),
SO.sub.2N(CH.sub.3).sub.2, C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6
haloalkyl, C.sub.3-C.sub.6 cycloalkyl, C.sub.2-C.sub.6 alkenyl,
C.sub.2-C.sub.6 haloalkenyl, C.sub.2-C.sub.6 alkynyl,
C.sub.2-C.sub.6 haloalkynyl, C.sub.2-C.sub.6 alkoxy,
C.sub.2-C.sub.6 haloalkoxy, phenyl, C.sub.3-C.sub.6 alkenyloxy,
C.sub.3-C.sub.6 haloalkenyloxy, C.sub.3-C.sub.6 alkynyloxy,
C.sub.3-C.sub.6 cycloalkoxy, C.sub.3-C.sub.6 halocycloalkoxy,
benzyloxy, C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6
haloalkylthio, C.sub.1-C.sub.6 alkylsulfinyl, C.sub.1-C.sub.6
haloalkylsulfinyl, C.sub.1-C.sub.6 alkylsulfonyl and
C.sub.1-C.sub.6 haloalkylsulfonyl;
[0398] provided that at least one of R.sup.57', R.sup.58',
R.sup.59' and R.sup.60' is not hydrogen;
[0399] R.sup.61' and R.sup.62' are selected independently of each
other from the group consisting of hydrogen, fluorine, cyano,
C.sub.1-C.sub.4 alkyl and C.sub.1-C.sub.4 haloalkyl;
[0400] R.sup.63', R.sup.64', R.sup.65', R.sup.66', R.sup.67 and
R.sup.68' are selected independently of each other from the group
consisting of hydrogen, halogen, hydroxy, cyano, C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 haloalkyl, C.sub.1-C.sub.4 alkoxy and
C.sub.1-C.sub.4 haloalkoxy and C.sub.1-C.sub.4 alkylthio;
[0401] R.sup.69' is selected from hydrogen, C.sub.1-C.sub.4 alkyl
and C.sub.1-C.sub.4 alkylcarboxy;
[0402] n is 0 or 1;
[0403] p and q are independently selected from 0 and 1;
[0404] r, s and t are independently selected from 0 and 1.
[0405] In another group of compounds of formula I, R.sub.1 and
R.sub.2 are each C.sub.1-C.sub.4 alkyl;
[0406] R.sub.3 represents hydrogen, halogen, cyano, C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 haloalkyl, C.sub.2-C.sub.4 alkenyl,
C.sub.2-C.sub.4 alkynyl, C.sub.1-C.sub.4 alkoxy, C.sub.3-C.sub.6
cycloalkyl, C.sub.1-C.sub.4 alkylthio, C.sub.1-C.sub.4
alkylsulfinyl or C.sub.1-C.sub.4 alkylsulfonyl;
[0407] R.sub.4 is selected from methyl, ethyl, methoxy, fluorine
and chlorine;
[0408] R.sub.6 is hydrogen;
[0409] R.sub.7 is hydrogen or C.sub.1-C.sub.4 alkyl.
[0410] In another group of compounds, R.sub.1 and R.sub.2 are each
independently selected from methyl, ethyl and isopropyl;
[0411] R.sub.3 represents hydrogen, halogen, C.sub.1-C.sub.4 alkyl,
C.sub.1-C.sub.4 haloalkyl, cyclopropyl, ethynyl or C.sub.1-C.sub.4
alkoxy;
[0412] R.sub.4 is selected from methyl, methoxy, fluorine and
chlorine;
[0413] R.sub.6 is hydrogen;
[0414] R.sub.7 is hydrogen.
[0415] In another group of compounds, R.sub.1 is methyl;
[0416] R.sub.2 is ethyl;
[0417] R.sub.3 is selected from hydrogen, bromine, iodine, methyl,
CHF.sub.2, cyclopropyl, ethynyl and methoxy;
[0418] R.sub.4 is methyl;
[0419] R.sub.6 is hydrogen;
[0420] R.sub.7 is hydrogen.
[0421] In another group of compounds, G.sup.1 is a C.sub.9-C.sub.10
fused bicyclic ring system which may be saturated or comprise one
carbon-carbon double bond and is optionally substituted by one or
more groups independently selected from C.sub.1-C.sub.4 alkyl,
fluorine, methoxy and C.sub.1-C.sub.4 fluoroalkyl;
[0422] G.sup.2 is C.sub.3-C.sub.6 cycloalkenyl, which is optionally
substituted by one or more groups independently selected from
halogen, ethyl, n-propyl, iso-propyl, n-butyl, iso-butyl,
sec-butyl, tert-butyl, n-pentyl,
--CH(CH.sub.3)--CH.sub.2--CH.sub.2--CH.sub.3,
--CH--CH(CH.sub.3)--CH.sub.2--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3)--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3).sub.2,
--CH(CH.sub.3)--CH(CH.sub.3).sub.2, C.sub.2-C.sub.6 haloalkyl,
C.sub.1-C.sub.6 alkoxy and C.sub.1-C.sub.6 alkylthio;
[0423] G.sup.3 is phenyl, which is optionally substituted by one or
more groups independently selected from hydroxyl, C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 fluoroalkyl, C.sub.1-C.sub.4 alkoxy and
halogen;
[0424] G.sup.4 is C.sub.5-C.sub.6 cycloalkyl which is optionally
substituted by one or more groups independently selected from
hydroxyl, C.sub.1-C.sub.4 alkyl, C.sub.2-C.sub.4 alkenyl,
C.sub.2-C.sub.4 alkynyl, C.sub.1-C.sub.4 alkoxy, halogen and cyano,
wherein the alkyl groups are optionally substituted by one or more
halogen;
[0425] G.sup.5 is C.sub.3-C.sub.7 cycloalkyl, which is substituted
by one or more groups independently selected from ethyl, n-propyl,
iso-propyl, n-butyl, iso-butyl, sec-butyl, tert-butyl, n-pentyl,
--CH(CH.sub.3)--CH.sub.2--CH.sub.2--CH.sub.3,
--CH--CH(CH.sub.3)--CH.sub.2--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3)--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3).sub.2,
--CH(CH.sub.3)--CH(CH.sub.3).sub.2, C.sub.2-C.sub.6 haloalkyl,
C.sub.1-C.sub.6 alkoxy, C.sub.3-C.sub.4-alkenyloxy, phenoxy and
C.sub.1-C.sub.6 alkylthio;
[0426] G.sup.6 is phenyl, which must be substituted by at least one
fluorine and is optionally further substituted by one or more
groups independently selected from halogen, CN, NO.sub.2, OH, SH,
CHO, C(.dbd.O)NH.sub.2, C(.dbd.O)NH(CH.sub.3),
C(.dbd.O)N(CH.sub.3).sub.2, C(.dbd.S)NH.sub.2,
C(.dbd.S)NH(CH.sub.3), C(.dbd.S)N(CH.sub.3).sub.2,
SO.sub.2NH.sub.2, SO.sub.2NH(CH.sub.3), SO.sub.2N(CH.sub.3).sub.2,
C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6 haloalkyl, C.sub.3-C.sub.6
cycloalkyl, C.sub.2-C.sub.6 alkenyl, C.sub.2-C.sub.6 haloalkenyl,
C.sub.2-C.sub.6 alkynyl, C.sub.1-C.sub.6 alkoxy, C.sub.1-C.sub.6
haloalkoxy, C.sub.3-C.sub.6 alkenyloxy, C.sub.3-C.sub.6 alkynyloxy,
C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6 alkylsulfinyl and
C.sub.1-C.sub.6 alkylsulfonyl;
[0427] G.sup.10 is phenyl, which is optionally substituted by one
or more groups independently selected from halogen, CN, OH, SH,
CHO, methyl, ethyl, n-propyl, iso-propyl, phenyl, CH.sub.2F,
CHF.sub.2, CF.sub.3, CHF--CH.sub.3, CF.sub.2--CH.sub.3,
CF.sub.2--CF.sub.3, cyclopropyl, CH.dbd.CH.sub.2,
C(CH.sub.3).dbd.CH.sub.2, CH.dbd.CH(CH.sub.3),
C(CH.sub.3).dbd.CH(CH.sub.3), CH.dbd.C(CH.sub.3)2,
C(CH.sub.3).dbd.C(CH.sub.3).sub.2, CH.dbd.CF.sub.2,
CH.dbd.CCl.sub.2, C.ident.CH, methoxy, ethoxy, iso-propyloxy,
OCHF.sub.2, OCH.sub.2--C.ident.CH, OCH(CH.sub.3)--C.ident.CH,
SCH.sub.3, SCH.sub.2CH.sub.3, S(.dbd.O)CH.sub.3,
S(.dbd.O)CH.sub.2CH.sub.3, S(.dbd.O).sub.2CH.sub.3 and
S(.dbd.O).sub.2CH.sub.2CH.sub.3;
[0428] G.sup.11 is methylene substituted by at least one group
independently selected from C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4
haloalkyl, CN, C.sub.1-C.sub.4 alkoxy and C.sub.1-C.sub.4
haloalkoxy;
[0429] G.sup.13 is a C.sub.8-C.sub.11 spirobicyclic system
containing 0, 1 or 2 O or N atoms, wherein there are no adjacent O
atoms, which is optionally substituted by one or more groups
independently selected from halogen, C.sub.1-C.sub.6 alkyl,
C.sub.1-C.sub.6 haloalkyl, C.sub.1-C.sub.6 alkoxy, C.sub.1-C.sub.6
alkylthio and .dbd.O;
[0430] G.sup.17 is a five- to six-membered monocyclic
heteroaromatic ring system which can contain 1 to 4 members
selected from the group consisting of N, N(R.sup.69'), O and S (for
example, pyridine, pyrimidine, furan, pyrrole, thiazole, oxazole,
pyrazole, imidazole, oxadiazole, thiadiazole or tetrazole), it not
being possible for each ring system to contain --O--O--, --S--S--
and --O--S-- fragments, and it being possible for the five- to
six-membered ring system to be itself mono- or polysubstituted by
groups selected from the group consisting of halogen, CN, NO.sub.2,
OH, SH, CHO, C(.dbd.O)NH.sub.2, C(.dbd.O)NH(CH.sub.3),
C(.dbd.O)N(CH.sub.3).sub.2, C(.dbd.S)NH.sub.2,
C(.dbd.S)NH(CH.sub.3), C(.dbd.S)N(CH.sub.3).sub.2,
SO.sub.2NH.sub.2, SO.sub.2NH(CH.sub.3), SO.sub.2N(CH.sub.3).sub.2,
C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6 haloalkyl, C.sub.3-C.sub.6
cycloalkyl, C.sub.2-C.sub.6 alkenyl, C.sub.2-C.sub.6 haloalkenyl,
C.sub.2-C.sub.6 alkynyl, C.sub.2-C.sub.6 haloalkynyl,
C.sub.1-C.sub.6 alkoxy, C.sub.1-C.sub.6 haloalkoxy, C.sub.3-C.sub.6
alkenyloxy, C.sub.3-C.sub.6 haloalkenyloxy, C.sub.3-C.sub.6
alkynyloxy, C.sub.3-C.sub.6 cycloalkoxy, C.sub.3-C.sub.6
halocycloalkoxy, C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6
haloalkylthio, C.sub.1-C.sub.6 alkylsulfinyl, C.sub.1-C.sub.6
haloalkylsulfinyl, C.sub.1-C.sub.6 alkylsulfonyl and
C.sub.1-C.sub.6 haloalkylsulfonyl;
[0431] R.sup.1' is selected from the group consisting of hydrogen,
fluorine, C.sub.1-C.sub.4 alkyl and C.sub.1-C.sub.4
fluoroalkyl;
[0432] R.sup.2', R.sup.3', R.sup.4' and R.sup.5' are selected,
independently of each other, from the group consisting of hydrogen,
fluorine, C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 haloalkyl,
C.sub.1-C.sub.4 alkoxy and C.sub.1-C.sub.4 alkylthio;
[0433] R.sup.11', R.sup.12', R.sup.13' and R.sup.14' are selected,
independently of each other, from the group consisting of hydrogen,
cyano, halogen, C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6 haloalkyl,
C.sub.1-C.sub.6 alkoxy and C.sub.1-C.sub.6 alkylthio;
[0434] R.sup.15', R.sup.16', R.sup.17', R.sup.18', R.sup.19',
R.sup.20', R.sup.21' and R.sup.22' are independently selected from
the group consisting of hydrogen, halogen, methyl, ethyl,
isopropyl, CH.sub.2F, CHF.sub.2, CF.sub.3, CHF--CH.sub.3,
CF.sub.2--CH.sub.3 and CF.sub.2CF.sub.3;
[0435] R.sup.23', R.sup.24' and R.sup.25' are independently
selected from the group consisting of hydrogen, halogen, cyano,
C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 haloalkyl, C.sub.1-C.sub.4
alkoxy, C.sub.3-C.sub.6 cycloalkyl, C.sub.3-C.sub.6 halocycloalkyl
and C.sub.1-C.sub.4 alkylthio;
[0436] R.sup.26' is N--OH, N--O--C.sub.1-C.sub.4 alkyl,
N--O--C.sub.2-C.sub.4 alkenyl, N--O--C.sub.2-C.sub.4 alkynyl,
N--O--C.sub.1-C.sub.4 haloalkyl, N--O--C.sub.2-C.sub.4 haloalkenyl,
N--O-benzyl, N--O-phenyl, N--O-halophenyl, O, or
C(R.sup.36').sub.2;
[0437] R.sup.27', R.sup.28', R.sup.29', R.sup.30', R.sup.31',
R.sup.32', R.sup.33', R.sup.34' and R.sup.35' are each
independently selected from the group consisting of hydrogen,
hydroxyl, C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 alkoxy and
halogen;
[0438] or R.sup.28' and R.sup.29' together with the two carbon
atoms to which they are attached form a double bond;
[0439] each R.sup.36' is independently selected from hydrogen,
halogen and C.sub.1-C.sub.4 alkyl;
[0440] R.sup.37', R.sup.38', R.sup.39', R.sup.40', R.sup.41',
R.sup.42', R.sup.43' and R.sup.44' are selected independently of
each other from a group consisting of hydrogen, halogen, methyl,
ethyl, isopropyl, monofluoromethyl, polyfluoromethyl,
monofluoroethyl, and polyfluoroethyl;
[0441] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
independently selected from the group consisting of hydrogen,
fluorine, chlorine, bromine, iodine, methyl, ethyl, isopropyl,
cyclopropyl, C.ident.CH, CH.dbd.CH.sub.2, C(CH.sub.3).dbd.CH.sub.2,
CF.sub.3, CHF.sub.2, CH.sub.2F, --CHF--CH.sub.3,
--CF.sub.2--CH.sub.3, methoxy, difluoromethoxy, trifluoromethoxy,
ethoxy, methlythio, methylsulfinyl and methylsulfonyl;
[0442] R.sup.50'is selected from the group consisting of hydrogen,
fluorine, C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 haloalkyl;
[0443] R.sup.51', R.sup.52', R.sup.53', R.sup.54', R.sup.55' and
R.sup.56' are selected, independently of each other, from the group
consisting of hydrogen, fluorine, C.sub.1-C.sub.4 alkyl,
C.sub.1-C.sub.4 haloalkyl, C.sub.2-C.sub.4 alkoxy and
C.sub.1-C.sub.4 haloalkoxy;
[0444] R.sup.57', R.sup.58', R.sup.59' and R.sup.60' are selected,
independently of each other, from the group consisting of hydrogen,
cyano, halogen, C.sub.1-C.sub.6 alkyl and C.sub.1-C.sub.6
haloalkyl; provided that at least one of R.sup.57', R.sup.58',
R.sup.59' and R.sup.60' is not hydrogen;
[0445] R.sup.61' and R.sup.62' are selected independently of each
other from the group consisting of hydrogen, fluorine, cyano,
C.sub.1-C.sub.4 alkyl and C.sub.1-C.sub.4 haloalkyl;
[0446] R.sup.63', R.sup.64', R.sup.65', R.sup.66', R.sup.67' and
R.sup.68' are selected independently of each other from the group
consisting of hydrogen, fluorine, cyano, C.sub.1-C.sub.4 alkyl,
C.sub.1-C.sub.4 haloalkyl, C.sub.1-C.sub.4 alkoxy and
C.sub.1-C.sub.4 haloalkoxy;
[0447] R.sup.69' is selected from hydrogen, C.sub.1-C.sub.4 alkyl
and C.sub.1-C.sub.4 alkylcarboxy;
[0448] n is 0 or 1;
[0449] p and q are independently selected from 0 and 1;
[0450] r and s are 0 and t is 1 or 0.
[0451] In another group of compounds, G.sup.1 is a saturated
C.sub.10 fused bicyclic ring system which is optionally substituted
by one or more groups independently selected from C.sub.1-C.sub.4
alkyl, fluorine, methoxy and C.sub.1-C.sub.4 fluoroalkyl;
[0452] G.sup.2 is a C.sub.5-C.sub.6 cycloalkenyl group optionally
substituted by one or more fluorine atoms;
[0453] G.sup.3 is phenyl, which is optionally substituted by one or
more groups independently selected from C.sub.1-C.sub.4 alkyl,
CHF.sub.2, CF.sub.3, C.sub.1-C.sub.4 alkoxy and halogen;
[0454] G.sup.4 is C.sub.5-C.sub.6 cycloalkyl which is optionally
substituted by one or more groups independently selected from
hydroxyl, C.sub.1-C.sub.4 alkyl, C.sub.2-C.sub.4 alkenyl,
C.sub.2-C.sub.4 alkynyl, C.sub.1-C.sub.4 alkoxy and halogen;
[0455] G.sup.5 is C.sub.5-C.sub.6 cycloalkyl, which is substituted
by one or more groups independently selected from ethyl, n-propyl,
iso-propyl, n-butyl, iso-butyl, sec-butyl, tert-butyl, n-pentyl,
--CH(CH.sub.3)--CH.sub.2--CH.sub.2--CH.sub.3,
--CH--CH(CH.sub.3)--CH.sub.2--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3)--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3).sub.2,
--CH(CH.sub.3)--CH(CH.sub.3).sub.2 and C.sub.2-C.sub.6
haloalkyl;
[0456] G.sup.6 is phenyl, which must be substituted by at least one
fluorine and is optionally further substituted by one or more
groups independently selected from halogen, ON, C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 haloalkyl and C.sub.1-C.sub.4 alkoxy.
[0457] G.sup.7 is methylene;
[0458] G.sup.10 is phenyl, which is optionally substituted by one
or more groups independently selected from hydrogen, halogen, ON,
OH, methyl, ethyl, n-propyl, iso-propyl, CH.sub.2F, CHF.sub.2,
CF.sub.3, CHF--CH.sub.3, CF.sub.2--CH.sub.3, CF.sub.2--CF.sub.3,
CH.dbd.CH.sub.2, C(CH.sub.3).dbd.CH.sub.2, CH.dbd.CH(CH.sub.3),
C(CH.sub.3).dbd.CH(CH.sub.3), CH.dbd.C(CH.sub.3).sub.2,
C(CH.sub.3).dbd.C(CH.sub.3).sub.2, CH.dbd.CF.sub.2,
CH.dbd.CCl.sub.2, C.ident.CH, methoxy, ethoxy, iso-propyloxy,
phenyl and OCHF.sub.2;
[0459] G.sup.11 is methylene substituted by at least one group
independently selected from C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4
haloalkyl and C.sub.1-C.sub.4 alkoxy;
[0460] G.sup.13 is a C.sub.8-C.sub.11 spirobicyclic system
containing 0, 1 or 2 O or N atoms, wherein there are no adjacent O
atoms, which is optionally substituted by one or more groups
independently selected from halogen, C.sub.1-C.sub.6 alkyl,
C.sub.1-C.sub.6 haloalkyl, C.sub.1-C.sub.6 alkoxy, C.sub.1-C.sub.6
alkylthio and .dbd.O;
[0461] G.sup.17 is a five- to six-membered monocyclic
heteroaromatic ring system which can contain 1 to 4 members
selected from the group consisting of N, N(R.sup.69'), O and S it
not being possible for each ring system to contain --O--O--,
--S--S-- and --O--S-- fragments, and it being possible for the
five- to six-membered ring system to be itself mono- or
polysubstituted by groups selected from the group consisting of
halogen, CN, C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 haloalkyl,
C.sub.1-C.sub.4 alkoxy, C.sub.1-C.sub.4 haloalkoxy, phenyl or
benzyl, wherein the phenyl or benzyl are optionally substituted by
halogen, CN, C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 haloalkyl;
[0462] R.sup.1' is selected from the group consisting of hydrogen,
fluorine, methyl, CH.sub.2F and CF.sub.3;
[0463] R.sup.2', R.sup.3', R.sup.4' and R.sup.5' are selected,
independently of each other, from the group consisting of hydrogen,
fluorine, methyl, CH.sub.2F, CF.sub.3 and methoxy;
[0464] R.sup.11', R.sup.12', R.sup.13' and R.sup.14' are selected,
independently of each other, from the group consisting of hydrogen,
halogen, cyano, C.sub.1-C.sub.4 alkyl, CHF.sub.2, CF.sub.3 and
C.sub.1-C.sub.4 alkoxy;
[0465] R.sup.15', R.sup.16', R.sup.17', R.sup.18', R.sup.19',
R.sup.20', R.sup.21' and R.sup.22 are each independently selected
from hydrogen, fluorine, methyl, ethyl, CH.sub.2F, CHF.sub.2,
CF.sub.3 and isopropyl;
[0466] R.sup.23', R.sup.24' and R.sup.25' are independently
selected from the group consisting of hydrogen, methyl, fluorine,
chlorine, bromine, ethyl, CH.sub.2F, CHF.sub.2 and CF.sub.3 and
isopropyl;
[0467] R.sup.26' is N--OH, N--O--C.sub.1-C.sub.4 alkyl,
N--O--C.sub.2-C.sub.4 alkenyl, N--O--C.sub.2-C.sub.4 alkynyl,
N--O--C.sub.1-C.sub.4 haloalkyl, N--O--C.sub.2-C.sub.4 haloalkenyl,
N--O-benzyl, N--O-phenyl, N--O-halophenyl, O, C.sub.2-C.sub.4
alkenyloxy or C(R.sup.36');
[0468] R.sup.27', R.sup.28', R.sup.29', R.sup.30', R.sup.31',
R.sup.32', R.sup.33', R.sup.34' and R.sup.35' are each
independently selected from the group consisting of hydrogen,
C.sub.1-C.sub.4 alkyl and halogen;
[0469] or R.sup.28' and R.sup.29' together with the two carbon
atoms to which they are attached form a double bond;
[0470] each R.sup.36' is independently selected from hydrogen,
halogen and C.sub.1-C.sub.4 alkyl;
[0471] R.sup.37', R.sup.38', R.sup.39', R.sup.40', R.sup.41',
R.sup.42', R.sup.43' and R.sup.44' are independently selected from
the group consisting of hydrogen, fluorine, methyl and
trifluoromethyl;
[0472] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
independently selected from the group consisting of hydrogen,
fluorine, chlorine, bromine, iodine, methyl, ethyl, isopropyl,
cyclopropyl, C.ident.CH, CH.dbd.CH.sub.2, C(CH.sub.3).dbd.CH.sub.2,
CF.sub.3, CHF.sub.2, CH.sub.2F, --CHF--CH.sub.3,
--CF.sub.2--CH.sub.3, methoxy, trifluoromethoxy, ethoxy,
methlythio, methylsulfinyl and methylsulfonyl;
[0473] R.sup.50, R.sup.51', R.sup.52', R.sup.53', R.sup.54',
R.sup.55' and R.sup.56' are selected, independently of each other,
from the group consisting of hydrogen, fluorine, methyl, CH.sub.2F
and CF.sub.3;
[0474] R.sup.57', R.sup.58', R.sup.59' and R.sup.60' are selected,
independently of each other, from the group consisting of hydrogen,
halogen, cyano, C.sub.1-C.sub.4 alkyl, CHF.sub.2 and CF.sub.3;
[0475] provided that at least one of R.sup.57', R.sup.58',
R.sup.59' and R.sup.60' is not hydrogen;
[0476] R.sup.61' and R.sup.62' are selected independently of each
other from the group consisting of hydrogen, fluorine, methyl,
ethyl, CHF.sub.2 and CF.sub.3;
[0477] R.sup.62', R.sup.63', R.sup.64', R.sup.65', R.sup.66',
R.sup.67' and R.sup.68' are selected independently of each other
from the group consisting of hydrogen, fluoro, methyl, ethyl,
methoxy, difluoromethoxy, trifluoromethoxy, CHF.sub.2 and
CF.sub.3;
[0478] R.sup.69' is selected from hydrogen and C.sub.1-C.sub.4
alkyl;
[0479] n is 0 or 1;
[0480] p and q are independently selected from 0 and 1;
[0481] r and s are 0 and t is 1 or 0.
[0482] In another group of compounds, G.sup.1 is a saturated
C.sub.10 fused bicyclic ring system;
[0483] G.sup.2 is a C.sub.5-C.sub.6 cycloalkenyl group;
[0484] G.sup.3 is phenyl;
[0485] G.sup.4 is cyclohexyl or cyclopentyl;
[0486] G.sup.5 is C.sub.6 cycloalkyl, which is substituted by one
or more groups independently selected from ethyl, n-propyl,
iso-propyl, n-butyl, iso-butyl, sec-butyl, tert-butyl, n-pentyl,
--CH(CH.sub.3)--CH.sub.2--CH.sub.2--CH.sub.3,
--CH--CH(CH.sub.3)--CH.sub.2--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3)--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3).sub.2 and
--CH(CH.sub.3)--CH(CH.sub.3).sub.2;
[0487] G.sup.6 is phenyl, which must be substituted by at least one
fluorine and is optionally further substituted by one or more
methyl, bromine, iodine or chlorine;
[0488] G.sup.7 is methylene;
[0489] G.sup.10 is phenyl, which is optionally substituted by one
or more groups independently selected from halogen, CN, methyl,
ethyl, n-propyl, iso-propyl, ethenyl, methoxy, ethoxy,
iso-propyloxy, phenyl, CHF.sub.2, CF.sub.3, CHF--CH.sub.3 and
OCHF.sub.2;
[0490] G.sup.11 is methylene substituted by at least one group
independently selected from methyl, CF.sub.3 and ethyl;
[0491] G.sup.13 is a C.sub.8-C.sub.11 spirobicyclic system
containing 0, 1 or 2 O or N atoms, wherein there are no adjacent O
atoms, which is optionally substituted by one or more groups
independently selected from halogen, C.sub.1-C.sub.4 alkyl,
C.sub.1-C.sub.4 alkoxy and =0;
[0492] G.sup.17 is a five- to six-membered monocyclic
heteroaromatic ring system which can contain 1 or 2 members
selected from the group consisting of N, O and S, it not being
possible for each ring system to contain --O--O--, --S--S-- and
--O--S-- fragments, and it being possible for the five- to
six-membered ring system to be itself mono- or polysubstituted by
groups selected from the group consisting of halogen, CN,
C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 haloalkyl, C.sub.1-C.sub.4
alkoxy, C.sub.1-C.sub.4 haloalkoxy, phenyl or fluorophenyl;
[0493] R.sup.1', R.sup.2', R.sup.3', R.sup.4' and R.sup.5' are each
hydrogen;
[0494] R.sup.11', R.sup.12', R.sup.13' and R.sup.14' are selected,
independently of each other, from the group consisting of hydrogen,
halogen, cyano, C.sub.1-C.sub.4 alkyl and C.sub.1-C.sub.4
alkoxy;
[0495] R.sup.15', R.sup.16', R.sup.17', R.sup.18', R.sup.19',
R.sup.20', R.sup.21', R.sup.22', R.sup.23', R.sup.24' and R.sup.25'
are each independently selected from hydrogen, methyl, ethyl and
isopropyl;
[0496] R.sup.23', R.sup.24' and R.sup.25' are each independently
selected from hydrogen, fluorine, chlorine, bromine, methyl, ethyl
and isopropyl;
[0497] R.sup.26' is N--OH, N--O--C.sub.1-C.sub.4 alkyl,
N--O--C.sub.2-C.sub.4 alkenyl, N--O--C.sub.2-C.sub.4 alkynyl,
N--O--C.sub.1-C.sub.4 haloalkyl, N--O--C.sub.2-C.sub.4 haloalkenyl,
N--O-benzyl, N--O-phenyl, N--O-halophenyl, O, C.sub.2-C.sub.4
alkenyloxy and C(R.sup.36');
[0498] R.sup.27', R.sup.28', R.sup.29', R.sup.30', R.sup.31',
R.sup.32', R.sup.33', R.sup.34' and R.sup.35' are each hydrogen or
methyl;
[0499] or R.sup.27' and R.sup.28' together with the two carbon
atoms to which they are attached form a double bond;
[0500] each R.sup.36' is independently selected from hydrogen,
halogen and C.sub.1-C.sub.4 alkyl;
[0501] R.sup.37', R.sup.38', R.sup.39', R.sup.40', R.sup.41',
R.sup.42', R.sup.43' and R.sup.44' are hydrogen;
[0502] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
independently selected from the group consisting of hydrogen,
fluorine, chlorine, methyl, CF.sub.3, CHF.sub.2, CH.sub.2F,
methoxy, difluoromethoxy and trifluoromethoxy;
[0503] R.sup.50', R.sup.51', R.sup.52', R.sup.53', R.sup.54',
R.sup.55' and R.sup.56' are each hydrogen;
[0504] R.sup.57', R.sup.58', R.sup.59' and R.sup.60' are selected,
independently of each other, from the group consisting of hydrogen
and halogen;
[0505] provided that at least one of R.sup.57', R.sup.58',
R.sup.59' and R.sup.60' is not hydrogen;
[0506] R.sup.61', R.sup.62', R.sup.63', R.sup.64', R.sup.65',
R.sup.66', R.sup.67' and R.sup.68' are hydrogen;
[0507] R.sup.69' is hydrogen;
[0508] n is 0 or 1;
[0509] p and q are independently selected from 0 and 1;
[0510] r, s and t are each 0.
[0511] In another preferred group of compounds, R.sup.5 is
G.sup.1.
[0512] In another preferred group of compounds, R.sup.5 is
G.sup.2.
[0513] In another preferred group of compounds, R.sup.5 is
G.sup.3-G.sup.4.
[0514] In another preferred group of compounds, R.sup.5 is
G.sup.5.
[0515] In another preferred group of compounds, R.sup.5 is
G.sup.6-G.sup.7.
[0516] In another preferred group of compounds, R.sup.5 is
G.sup.8.
[0517] In another preferred group of compounds, R.sup.5 is
G.sup.9.
[0518] In another preferred group of compounds, R.sup.5 is
G.sup.10-G.sup.11.
[0519] In another preferred group of compounds, R.sup.5 is
G.sup.12.
[0520] In another preferred group of compounds, R.sup.5 is
G.sup.13.
[0521] In another preferred group of compounds, R.sup.5 is
G.sup.14.
[0522] In another preferred group of compounds, R.sup.5 is
G.sup.15.
[0523] In another preferred group of compounds, R.sup.5 is
G.sup.16.
[0524] In a further group of compounds, R.sub.1 is selected from
R.sup.1a and R.sup.1b;
[0525] R.sub.2 is methyl;
[0526] R.sub.3 is selected from R.sup.3a, R.sup.3b, R.sup.3c,
R.sup.3d, R.sup.3e, R.sup.3f, R.sup.3g, R.sup.3h, R.sup.3i,
R.sup.3j, R.sup.3k, R.sup.3l, R.sup.3m, R.sup.3n, R.sup.3o,
R.sup.3p, R.sup.3q, R.sup.3r, R.sup.3s, R.sup.3t;
[0527] R.sup.4 is selected from R.sub.4a, R.sub.4b, R.sub.4c,
R.sup.4d, R.sup.4e, R.sub.4f;
[0528] R.sub.5 is selected from R.sup.5a, R.sup.5b, R.sup.5c,
R.sup.5d, R.sup.5e, R.sup.5f, R.sup.5g, R.sup.5h, R.sup.5j,
R.sup.5k, R.sup.5l, R.sup.5m, R.sup.5n, R.sup.5o, R.sup.5p,
R.sup.5q, R.sup.5r, R.sup.5s, R.sup.5t, R.sup.5u, R.sup.5v,
R.sup.5x, R.sup.5y, R.sup.5z, R.sup.5ab, R.sup.5ac, R.sup.5ad,
R.sup.5ae, R.sup.5af, R.sup.5ag, R.sup.5ah, R.sup.5aj, R.sup.5ak,
R.sup.5al, R.sup.5am, R.sup.5aa, R.sup.5bb, R.sup.5cc, R.sup.5dd,
R.sup.5ee, R.sup.5ff, R.sup.5gg, R.sup.5hh, R.sup.5jj, R.sup.5kk,
R.sup.5ll, R.sup.5mm, R.sup.5nn, R.sup.5oo, R.sup.5pp, R.sup.5qq,
R.sup.5rr, R.sup.5ss, R.sup.5tt, R.sup.5uu, R.sup.5vv, R.sup.5ww,
R.sup.5xx, R.sup.5zz, R.sup.5ba, R.sup.5bc, R.sup.5bd, R.sup.5be,
R.sup.5bf, R.sup.5bg, R.sup.5bh, R.sup.5bi, R.sup.5bj, R.sup.5bk,
R.sup.5bl, R.sup.5bm, R.sup.5bn, R.sup.5bo, R.sup.5bp, R.sup.5bq,
R.sup.5br, R.sup.5bs, R.sup.5bt, R.sup.5bu, R.sup.5bv, R.sup.5bw,
R.sup.5bx, R.sup.5by, R.sup.5bz, R.sup.5ca, R.sup.5cb, R.sup.5cd,
R.sup.5ce, R.sup.5cf, R.sup.5cg, R.sup.5ch, R.sup.5ci, R.sup.5cj,
R.sup.5ck, R.sup.5cl, R.sup.5cm, R.sup.5cn, R.sup.5o, R.sup.5cq,
R.sup.5cr, R.sup.5cs, R.sup.5ct, R.sup.5cu, R.sup.5cv, R.sup.5cw,
R.sup.5cx, R.sup.5cy, R.sup.5cz, R.sup.5da, R.sup.5db, R.sup.5dc,
R.sup.5de, R.sup.5df, R.sup.5dg, R.sup.5dh, R.sup.5di, R.sup.5dj,
R.sup.5dk, R.sup.5dl, R.sup.5dm, R.sup.5dn, R.sup.5do, R.sup.5dp,
R.sup.5dq, R.sup.5dr, R.sup.5ds, R.sup.5dt, R.sup.5du, R.sup.5dv,
R.sup.5dw, R.sup.5dx, R.sup.5ea, R.sup.5eb, R.sup.5ec, R.sup.5ed,
R.sup.5ef, R.sup.5eg, R.sup.5eh, R.sup.5ei, R.sup.5ej, R.sup.5ek,
R.sup.5el, R.sup.5em, R.sup.5en, R.sup.5eo, R.sup.5ep, R.sup.5eq,
R.sup.5er, R.sup.5es, R.sup.5et, R.sup.5eu, R.sup.5ev, R.sup.5ex,
R.sup.5ey, R.sup.5ez, R.sup.5fa, R.sup.5fb, R.sup.5fc, R.sup.5fd,
R.sup.5fe, R.sup.5fg, R.sup.5fh, R.sup.5fi, R.sup.5fj, R.sup.5fk,
R.sup.5fl, R.sup.5fm, R.sup.5fn, R.sup.5fo, R.sup.5fp, R.sup.5fq,
R.sup.5fr, R.sup.5fs, R.sup.5ft, R.sup.5fu, R.sup.5fv,
R.sup.5fw;
[0529] R.sub.6 is selected from R.sup.6a, R.sup.6b and
R.sup.6c;
[0530] R.sub.7 is H;
[0531] R.sup.1a is selected from ethyl and isopropyl;
[0532] R.sup.1b is ethyl;
[0533] R.sup.3a is selected from hydrogen, halogen, CN, methyl,
ethyl, isopropyl, CCH, CH.dbd.CH.sub.2, H.sub.2C.dbd.C--(CH.sub.3),
cyclopropyl, halomethyl, haloethyl, methoxy, halomethoxy, ethoxy,
haloethoxy, methlythio, halomethylthio, methylsulfinyl,
halomethylsulfinyl, methylsulfonyl, halomethylsulfonyl, amino,
methylamino, dimethylamino, ethylamino, diethylamino,
ethylmethylamino, pyrrolidino, imidazolino, triazolino, CHO,
CH.sub.2OH, CH(OH)Me and CO-Me;
[0534] R.sup.3b is selected from hydrogen, F, Cl, Br, I, cyano,
methyl, ethyl, isopropyl, fluoromethyl, difluoromethyl,
trifluoromethyl, (H.sub.3C)--CHF, methoxy and ethoxy;
[0535] R.sup.3c is selected from hydrogen, F, Br, I, methyl, ethyl,
isopropyl, fluoromethyl, difluoromethyl, trifluoromethyl,
(H.sub.3C)--CHF, methoxy and ethoxy;
[0536] R.sup.3d is selected from hydrogen, halogen, cyano, methyl,
ethyl, isopropyl, C.ident.CH, CH.dbd.CH.sub.2,
H.sub.2C.dbd.C--(CH.sub.3), cyclopropyl, halomethyl, haloethyl,
methoxy, ethoxy, methlythio, halomethylthio, methylsulfinyl,
halomethylsulfinyl, methylsulfonyl, halomethylsulfonyl, amino,
methylamino, dimethylamino, ethylamino, diethylamino,
ethylmethylamino, pyrrolidino, imidazolino, triazolino, CHO and
CO-Me;
[0537] R.sup.3b is selected from hydrogen, F, Cl, Br, I, cyano,
methyl, ethyl, isopropyl, fluoromethyl, difluoromethyl,
trifluoromethyl, (H.sub.3C)--CHF, methoxy and ethoxy;
[0538] R.sup.3c is selected from hydrogen, F, Br, I, methyl, ethyl,
isopropyl, fluoromethyl, difluoromethyl, trifluoromethyl,
(H.sub.3C)--CHF, methoxy and ethoxy;
[0539] R.sup.3e is selected from hydrogen, halogen, CN, methyl,
ethyl, isopropyl, cyclopropyl, C.dbd.CH, CH.dbd.CH.sub.2,
C(CH.sub.3).dbd.CH.sub.2, halomethyl, haloethyl, methoxy, ethoxy,
methlythio, halomethylthio, methylsulfinyl, halomethylsulfinyl,
methylsulfonyl, halomethylsulfonyl, amino, methylamino,
dimethylamino, ethylamino, diethylamino, ethylmethylamino,
pyrrolidino, imidazolino, triazolino, CHO, CH.sub.2OH, CH(OH)Me and
CO-Me;
[0540] R.sup.3f is selected from hydrogen, halogen, CN, methyl,
ethyl, isopropyl, cyclopropyl, C.dbd.CH, CH.dbd.CH.sub.2,
C(CH.sub.3).dbd.CH.sub.2, halomethyl, haloethyl, methoxy, ethoxy,
methlythio, methylsulfinyl and methylsulfonyl;
[0541] R.sup.3g is selected from hydrogen, F, Br, I, methyl, ethyl,
isopropyl, cyclopropyl, C.ident.CH, CH.dbd.CH.sub.2,
C(CH.sub.3).dbd.CH.sub.2, CF.sub.3, CHF.sub.2, CH.sub.2F,
--CHF--CH.sub.3, --CF.sub.2--CH.sub.3, methoxy, ethoxy, methlythio,
methylsulfinyl and methylsulfonyl;
[0542] R.sup.3h is selected from hydrogen, Br, I, methyl, ethyl,
C.ident.CH, CH.dbd.CH.sub.2, C(CH.sub.3).dbd.CH.sub.2, CF.sub.3,
CHF.sub.2, CH.sub.2F and methoxy;
[0543] R.sup.3i is selected from hydrogen, halogen, CN, methyl,
ethyl, isopropyl, cyclopropyl, C.ident.CH, CH.dbd.CH.sub.2,
C(CH.sub.3).dbd.CH.sub.2, halomethyl, haloethyl, methoxy, ethoxy,
methlythio, halomethylthio, methylsulfinyl, halomethylsulfinyl,
methylsulfonyl, halomethylsulfonyl, amino, methylamino,
dimethylamino, ethylamino, diethylamino, ethylmethylamino,
pyrrolidino, imidazolino, triazolino, CHO and CO-Me;
[0544] R.sup.3' is selected from hydrogen, halogen, CN, methyl,
ethyl, isopropyl, halomethyl, haloethyl, methoxy and ethoxy;
[0545] R.sup.3k is selected from hydrogen, halogen, methyl, ethyl,
isopropyl, CH.sub.2F, CHF.sub.2, CF.sub.3, CHF--CH.sub.3,
CF.sub.2--CH.sub.3, methoxy and ethoxy;
[0546] R.sup.3l is selected from hydrogen, halogen, methyl, ethyl,
isopropyl, CH.sub.2F, CHF.sub.2, CF.sub.3, CHF--CH.sub.3,
CF.sub.2--CH.sub.3, methoxy and ethoxy;
[0547] R.sup.3m is selected from hydrogen, F, Br, I, methyl, ethyl,
CHF.sub.2 and methoxy;
[0548] R.sup.3n is selected from hydrogen, halogen, CN, methyl,
ethyl, isopropyl, cyclopropyl, C.ident.CH, CH.dbd.CH.sub.2,
C(CH.sub.3).dbd.CH.sub.2, halomethyl, haloethyl, methoxy, ethoxy,
methlythio, halomethylthio, methylsulfinyl, halomethylsulfinyl,
methylsulfonyl, halomethylsulfonyl, amino, methylamino,
dimethylamino, ethylamino, diethylamino, ethylmethylamino,
pyrrolidino, imidazolino, triazolino, CHO, CH.sub.2OH, CH(OH)Me and
CO-Me;
[0549] R.sup.30 is selected from hydrogen, halogen, CN, methyl,
ethyl, isopropyl, cyclopropyl, C.ident.CH, CH.dbd.CH.sub.2,
C(CH.sub.3).dbd.CH.sub.2, halomethyl, haloethyl, methoxy, ethoxy,
methlythio, halomethylthio, methylsulfinyl, halomethylsulfinyl,
methylsulfonyl and halomethylsulfonyl;
[0550] R.sup.3p is selected from hydrogen, F, Br, I, methyl, ethyl,
isopropyl, cyclopropyl, C.ident.CH, CH.dbd.CH.sub.2,
C(CH.sub.3).dbd.CH.sub.2, halomethyl, haloethyl, methoxy and
ethoxy;
[0551] R.sup.3q is selected from hydrogen, F, Br, I, methyl, ethyl,
isopropyl, cyclopropyl, C.ident.CH, CH.dbd.CH.sub.2,
C(CH.sub.3).dbd.CH.sub.2, CF.sub.3, CHF.sub.2, CH.sub.2F,
--CHF--CH.sub.3, --CF.sub.2--CH.sub.3, methoxy, ethoxy, methlythio,
methylsulfinyl and methylsulfonyl;
[0552] R.sup.3r is selected from hydrogen, Br, I, methyl,
cyclopropyl, C.ident.CH, CH.dbd.CH.sub.2, CF.sub.3, CHF.sub.2,
CH.sub.2F, --CHF--CH.sub.3, --CF.sub.2--CH.sub.3 and methoxy;
[0553] R.sup.3s is selected from hydrogen, halogen, CN, methyl,
ethyl, isopropyl, cyclopropyl, tert-butyl, C.ident.CH,
CH.dbd.CH.sub.2, C(CH.sub.3).dbd.CH.sub.2, halomethyl, haloethyl,
methoxy, halomethoxy, ethoxy, haloethoxy, methlythio,
halomethylthio, methylsulfinyl, halomethylsulfinyl, methylsulfonyl,
halomethylsulfonyl, amino, methylamino, dimethylamino, ethylamino,
diethylamino, ethylmethylamino, pyrrolidino, imidazolino,
triazolino, CHO and C(.dbd.O)Me;
[0554] R.sup.3t is selected from hydrogen, halogen, CN, methyl,
ethyl, isopropyl, cyclopropyl, tert-butyl, C.ident.CH,
CH.dbd.CH.sub.2, C(CH.sub.3).dbd.CH.sub.2, halomethyl, haloethyl,
methoxy, halomethoxy, ethoxy, haloethoxy, methlythio,
halomethylthio, methylsulfinyl, halomethylsulfinyl, methylsulfonyl,
halomethylsulfonyl, amino, methylamino, dimethylamino, ethylamino,
diethylamino, ethylmethylamino, pyrrolidino, imidazolino,
triazolino, CHO and C(.dbd.O)Me;
[0555] R.sub.4a is selected from F, Cl, Br, C.sub.1-C.sub.4 alkyl,
C.sub.1-C.sub.4 alkenyl, C.sub.1-C.sub.4 haloalkyl and
C.sub.1-C.sub.4 cycloalkyl;
[0556] R.sub.4b is selected from F, Cl, methyl, ethyl, ethenyl,
propyl, propenyl, isopropyl, isopropenyl, cyclopropanyl, methoxy,
ethoxy, monofluoromethyl, polyfluoromethyl, monofluoroethyl and
polyfluoromethyl
[0557] R.sub.4c is selected from methyl, ethyl, methoxy, F and
Cl;
[0558] R.sub.4d is selected from methyl, methoxy, F and Cl;
[0559] R.sub.4e is selected from methyl;
[0560] R.sub.4f is selected from methoxy, F and Cl;
[0561] R.sup.5a is a 3- to 6-membered cycloalkenyl group, or a 3-
to 6-membered cycloalkenyl group that can be mono- to
polysubstituted by substituents independently selected from the
group consisting of halogen, CN, NO.sub.2, OH, SH, CHO, COOH,
tri(C.sub.1-C.sub.6 alkyl)silyl, ethyl, n-propyl, iso-propyl,
n-butyl, iso-butyl, sec-butyl, tert-butyl, n-pentyl,
--CH(CH.sub.3)--CH.sub.2--CH.sub.2--CH.sub.3,
--CH--CH(CH.sub.3)--CH.sub.2--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3)--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3).sub.2,
--CH(CH.sub.3)--CH(CH.sub.3).sub.2, C.sub.1-C.sub.6 haloalkyl,
C.sub.3-C.sub.6 cycloalkyl, C.sub.3-C.sub.6 halocycloalkyl,
C.sub.2-C.sub.6 alkenyl, C.sub.2-C.sub.6 haloalkenyl,
C.sub.1-C.sub.6 alkoxy, C.sub.1-C.sub.6 haloalkoxy, C.sub.2-C.sub.7
alkylcarbonyl, C.sub.2-C.sub.7 alkoxycarbonyl, C.sub.4-C.sub.7
alkenyloxycarbonyl, C.sub.4 C.sub.7 alkynyloxycarbonyl,
C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6 alkylsulfinyl,
C.sub.1-C.sub.6 alkylsulfonyl, --C(.dbd.O)NH.sub.2,
--C(.dbd.O)NH(CH.sub.3), --C(.dbd.O)N(CH.sub.3).sub.2 and
--C(.dbd.S)NH.sub.2;
[0562] R.sup.5b is a 3- to 6-membered cycloalkenyl group, or a 3-
to 6-membered cycloalkenyl group that can be mono- to
polysubstituted by substituents independently selected from the
group consisting of halogen, ethyl, n-propyl, iso-propyl, n-butyl,
iso-butyl, sec-butyl, tert-butyl, n-pentyl,
--CH(CH.sub.3)--CH.sub.2--CH.sub.2--CH.sub.3,
--CH--CH(CH.sub.3)--CH.sub.2--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3)--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3).sub.2,
--CH(CH.sub.3)--CH(CH.sub.3).sub.2, C.sub.1-C.sub.6 haloalkyl,
C.sub.1-C.sub.6 alkoxy and C.sub.1-C.sub.6 alkylthio;
[0563] R.sup.5c is a 3- to 6-membered cycloalkenyl group, or a 3-
to 6-membered cycloalkenyl group that can be mono- to
polysubstituted by substituents independently selected from the
group consisting of halogen, ethyl, n-propyl, iso-propyl, n-butyl,
iso-butyl, sec-butyl, tert-butyl, n-pentyl,
--CH(CH.sub.3)--CH.sub.2--CH.sub.2--CH.sub.3,
--CH--CH(CH.sub.3)--CH.sub.2--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3)--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3).sub.2,
--CH(CH.sub.3)--CH(CH.sub.3).sub.2, C.sub.1-C.sub.6 fluoroalkyl,
C.sub.1-C.sub.6 alkoxy and C.sub.1-C.sub.6 alkylthio;
[0564] R.sup.5d is a 5-membered cycloalkenyl group, or a 5-membered
cycloalkenyl group that can be mono- to polysubstituted by
substituents independently selected from the group consisting of
halogen, CN, NO.sub.2, OH, SH, CHO, COOH, tri(C.sub.1-C.sub.6
alkyl)silyl, ethyl, n-propyl, iso-propyl, n-butyl, iso-butyl,
sec-butyl, tert-butyl, n-pentyl,
--CH(CH.sub.3)--CH.sub.2--CH.sub.2--CH.sub.3,
--CH--CH(CH.sub.3)--CH.sub.2--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3)--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3).sub.2,
--CH(CH.sub.3)--CH(CH.sub.3).sub.2, C.sub.1-C.sub.6 haloalkyl,
C.sub.3-C.sub.6 cycloalkyl, C.sub.3-C.sub.6 halocycloalkyl,
C.sub.2-C.sub.6 alkenyl, C.sub.2-C.sub.6 haloalkenyl,
C.sub.1-C.sub.6 alkoxy, C.sub.1-C.sub.6 haloalkoxy, C.sub.2-C.sub.7
alkylcarbonyl, C.sub.2-C.sub.7 alkoxycarbonyl, C.sub.4-C.sub.7
alkenyloxycarbonyl, C.sub.4-C.sub.7 alkynyloxycarbonyl,
C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6 alkylsulfinyl,
C.sub.1-C.sub.6 alkylsulfonyl, --C(.dbd.O)NH.sub.2,
--C(.dbd.O)NH(CH.sub.3), --C(.dbd.O)N(CH.sub.3).sub.2 and
--C(.dbd.S)NH.sub.2;
[0565] R.sup.5e is a 5-membered cycloalkenyl group, or a 5-membered
cycloalkenyl group that can be mono- to polysubstituted by
substituents independently selected from the group consisting of
halogen, ethyl, n-propyl, iso-propyl, n-butyl, iso-butyl,
sec-butyl, tert-butyl, n-pentyl,
--CH(CH.sub.3)--CH.sub.2--CH.sub.2--CH.sub.3,
--CH--CH(CH.sub.3)--CH.sub.2--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3)--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3).sub.2,
--CH(CH.sub.3)--CH(CH.sub.3).sub.2, C.sub.1-C.sub.6 haloalkyl,
C.sub.1-C.sub.6 alkoxy and C.sub.1-C.sub.6 alkylthio;
[0566] R.sup.5f is a 5-membered cycloalkenyl group, or a 5-membered
cycloalkenyl group that can be mono- to polysubstituted by
substituents independently selected from the group consisting of
halogen, ethyl, n-propyl, iso-propyl, n-butyl, iso-butyl,
sec-butyl, tert-butyl, n-pentyl,
--CH(CH.sub.3)--CH.sub.2--CH.sub.2--CH.sub.3,
--CH--CH(CH.sub.3)--CH.sub.2--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3)--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3).sub.2,
--CH(CH.sub.3)--CH(CH.sub.3).sub.2, C.sub.1-C.sub.6 fluoroalkyl,
C.sub.1-C.sub.6 alkoxy and C.sub.1-C.sub.6 alkylthio;
[0567] R.sup.59 is a 6-membered cycloalkenyl group, or a 6-membered
cycloalkenyl group that can be mono- to polysubstituted by
substituents independently selected from the group consisting of
halogen, CN, NO.sub.2, OH, SH, CHO, COOH, tri(C.sub.1-C.sub.6
alkyl)silyl, ethyl, n-propyl, iso-propyl, n-butyl, iso-butyl,
sec-butyl, tert-butyl, n-pentyl,
--CH(CH.sub.3)--CH.sub.2--CH.sub.2--CH.sub.3,
--CH--CH(CH.sub.3)--CH.sub.2--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3)--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3).sub.2,
--CH(CH.sub.3)--CH(CH.sub.3).sub.2, C.sub.1-C.sub.6 haloalkyl,
C.sub.3-C.sub.6 cycloalkyl, C.sub.3-C.sub.6 halocycloalkyl,
C.sub.2-C.sub.6 alkenyl, C.sub.2-C.sub.6 haloalkenyl,
C.sub.1-C.sub.6 alkoxy, C.sub.1-C.sub.6 haloalkoxy, C.sub.2-C.sub.7
alkylcarbonyl, C.sub.2-C.sub.7 alkoxycarbonyl, C.sub.4 C.sub.7
alkenyloxycarbonyl, C.sub.4 C.sub.7 alkynyloxycarbonyl,
C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6 alkylsulfinyl,
C.sub.1-C.sub.6 alkylsulfonyl, --C(.dbd.O)NH.sub.2,
--C(.dbd.O)NH(CH.sub.3), --C(.dbd.O)N(CH.sub.3).sub.2 and
--C(.dbd.S)NH.sub.2;
[0568] R.sup.5h is a 6-membered cycloalkenyl group, or a 6-membered
cycloalkenyl group that can be mono- to polysubstituted by
substituents independently selected from the group consisting of
halogen, ethyl, n-propyl, iso-propyl, n-butyl, iso-butyl,
sec-butyl, tert-butyl, n-pentyl,
--CH(CH.sub.3)--CH.sub.2--CH.sub.2--CH.sub.3,
--CH--CH(CH.sub.3)--CH.sub.2--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3)--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3).sub.2,
--CH(CH.sub.3)--CH(CH.sub.3).sub.2, C.sub.1-C.sub.6 haloalkyl,
C.sub.1-C.sub.6 alkoxy and C.sub.1-C.sub.6 alkylthio;
[0569] R.sup.5j is a 6-membered cycloalkenyl group, or a 6-membered
cycloalkenyl group that can be mono- to polysubstituted by
substituents independently selected from the group consisting of
halogen, ethyl, n-propyl, iso-propyl, n-butyl, iso-butyl,
sec-butyl, tert-butyl, n-pentyl,
--CH(CH.sub.3)--CH.sub.2--CH.sub.2--CH.sub.3,
--CH--CH(CH.sub.3)--CH.sub.2--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3)--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3).sub.2,
--CH(CH.sub.3)--CH(CH.sub.3).sub.2, C.sub.1-C.sub.6 fluoroalkyl,
C.sub.1-C.sub.6 alkoxy and C.sub.1-C.sub.6 alkylthio;
[0570] R.sup.5k is a 3- to 7-membered cycloalkyl group, or a 3- to
7-membered cycloalkyl group that can be mono- to polysubstituted by
substituents independently selected from the group consisting of
halogen, CN, NO.sub.2, OH, SH, CHO, COOH, tri(C.sub.1-C.sub.6
alkyl)silyl, ethyl, n-propyl, iso-propyl, n-butyl, iso-butyl,
sec-butyl, tert-butyl, n-pentyl,
--CH(CH.sub.3)--CH.sub.2--CH.sub.2--CH.sub.3,
--CH--CH(CH.sub.3)--CH.sub.2--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3)--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3).sub.2,
--CH(CH.sub.3)--CH(CH.sub.3).sub.2, C.sub.1-C.sub.6 haloalkyl,
C.sub.3-C.sub.6 cycloalkyl, C.sub.3-C.sub.6 halocycloalkyl,
C.sub.2-C.sub.6 alkenyl, C.sub.2-C.sub.6 haloalkenyl,
C.sub.1-C.sub.6 alkoxy, C.sub.1-C.sub.6 haloalkoxy, C.sub.2-C.sub.7
alkylcarbonyl, C.sub.2-C.sub.7 alkoxycarbonyl, C.sub.4-C.sub.7
alkenyloxycarbonyl, C.sub.4-C.sub.7 alkynyloxycarbonyl,
C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6 alkylsulfinyl,
C.sub.1-C.sub.6 alkylsulfonyl, --C(.dbd.O)NH.sub.2,
--C(.dbd.O)NH(CH.sub.3), --C(.dbd.O)N(CH.sub.3).sub.2 and
--C(.dbd.S)NH.sub.2;
[0571] R.sup.5l is a 3- to 7-membered cycloalkyl group, or a 3- to
7-membered cycloalkyl group that can be mono- to polysubstituted by
substituents independently selected from the group consisting of
halogen, ethyl, n-propyl, iso-propyl, n-butyl, iso-butyl,
sec-butyl, tert-butyl, n-pentyl,
--CH(CH.sub.3)--CH.sub.2--CH.sub.2--CH.sub.3,
--CH--CH(CH.sub.3)--CH.sub.2--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3)--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3).sub.2,
--CH(CH.sub.3)--CH(CH.sub.3).sub.2, C.sub.1-C.sub.6 haloalkyl,
C.sub.1-C.sub.6 alkoxy and C.sub.1-C.sub.6 alkylthio;
[0572] R.sup.5m is a 3- to 7-membered cycloalkyl group, or a 3- to
7-membered cycloalkyl group that can be mono- to polysubstituted by
substituents independently selected from the group consisting of
halogen, ethyl, n-propyl, iso-propyl, n-butyl, iso-butyl,
sec-butyl, tert-butyl, n-pentyl,
--CH(CH.sub.3)--CH.sub.2--CH.sub.2--CH.sub.3,
--CH--CH(CH.sub.3)--CH.sub.2--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3)--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3).sub.2,
--CH(CH.sub.3)--CH(CH.sub.3).sub.2, C.sub.1-C.sub.6 fluoroalkyl,
C.sub.1-C.sub.6 alkoxy and C.sub.1-C.sub.6 alkylthio;
[0573] R.sup.5n is a 3-membered cycloalkyl group, or a 3-membered
cycloalkyl group that can be mono- to polysubstituted by
substituents independently selected from the group consisting of
halogen, CN, NO.sub.2, OH, SH, CHO, COOH, tri(C.sub.1-C.sub.6
alkyl)silyl, ethyl, n-propyl, iso-propyl, n-butyl, iso-butyl,
sec-butyl, tert-butyl, n-pentyl,
--CH(CH.sub.3)--CH.sub.2--CH.sub.2--CH.sub.3,
--CH--CH(CH.sub.3)--CH.sub.2--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3)--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3).sub.2,
--CH(CH.sub.3)--CH(CH.sub.3).sub.2, C.sub.1-C.sub.6 haloalkyl,
C.sub.3-C.sub.6 cycloalkyl, C.sub.3-C.sub.6 halocycloalkyl,
C.sub.2-C.sub.6 alkenyl, C.sub.2-C.sub.6 haloalkenyl,
C.sub.1-C.sub.6 alkoxy, C.sub.1-C.sub.6 haloalkoxy, C.sub.2-C.sub.7
alkylcarbonyl, C.sub.2-C.sub.7 alkoxycarbonyl, C.sub.4 C.sub.7
alkenyloxycarbonyl, C.sub.4 C.sub.7 alkynyloxycarbonyl,
C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6 alkylsulfinyl,
C.sub.1-C.sub.6 alkylsulfonyl, --C(.dbd.O)NH.sub.2,
--C(.dbd.O)NH(CH.sub.3), --C(.dbd.O)N(CH.sub.3).sub.2 and
--C(.dbd.S)NH.sub.2;
[0574] R.sup.5o is a 3-membered cycloalkyl group, or a 3-membered
cycloalkyl group that can be mono- to polysubstituted by
substituents independently selected from the group consisting of
halogen, ethyl, n-propyl, iso-propyl, n-butyl, iso-butyl,
sec-butyl, tert-butyl, n-pentyl,
--CH(CH.sub.3)--CH.sub.2--CH.sub.2--CH.sub.3,
--CH--CH(CH.sub.3)--CH.sub.2--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3)--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3).sub.2,
--CH(CH.sub.3)--CH(CH.sub.3).sub.2, C.sub.1-C.sub.6 haloalkyl,
C.sub.1-C.sub.6 alkoxy and C.sub.1-C.sub.6 alkylthio;
[0575] R.sup.5p is a 3-membered cycloalkyl group, or a 3-membered
cycloalkyl group that can be mono- to polysubstituted by
substituents independently selected from the group consisting of
halogen, ethyl, n-propyl, iso-propyl, n-butyl, iso-butyl,
sec-butyl, tert-butyl, n-pentyl,
--CH(CH.sub.3)--CH.sub.2--CH.sub.2--CH.sub.3,
--CH--CH(CH.sub.3)--CH.sub.2--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3)--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3).sub.2,
--CH(CH.sub.3)--CH(CH.sub.3).sub.2, C.sub.1-C.sub.6 fluoroalkyl,
C.sub.1-C.sub.6 alkoxy and C.sub.1-C.sub.6 alkylthio;
[0576] R.sup.5q is a 4-membered cycloalkyl group, or a 4-membered
cycloalkyl group that can be mono- to polysubstituted by
substituents independently selected from the group consisting of
halogen, CN, NO.sub.2, OH, SH, CHO, COOH, tri(C.sub.1-C.sub.6
alkyl)silyl, ethyl, n-propyl, iso-propyl, n-butyl, iso-butyl,
sec-butyl, tert-butyl, n-pentyl,
--CH(CH.sub.3)--CH.sub.2--CH.sub.2--CH.sub.3,
--CH--CH(CH.sub.3)--CH.sub.2--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3)--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3).sub.2,
--CH(CH.sub.3)--CH(CH.sub.3).sub.2, C.sub.1-C.sub.6 haloalkyl,
C.sub.3-C.sub.6 cycloalkyl, C.sub.3-C.sub.6 halocycloalkyl,
C.sub.2-C.sub.6 alkenyl, C.sub.2-C.sub.6 haloalkenyl,
C.sub.1-C.sub.6 alkoxy, C.sub.1-C.sub.6 haloalkoxy, C.sub.2-C.sub.7
alkylcarbonyl, C.sub.2-C.sub.7 alkoxycarbonyl, C.sub.4 C.sub.7
alkenyloxycarbonyl, C.sub.4 C.sub.7 alkynyloxycarbonyl,
C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6 alkylsulfinyl,
C.sub.1-C.sub.6 alkylsulfonyl, --C(.dbd.O)NH.sub.2,
--C(.dbd.O)NH(CH.sub.3), --C(.dbd.O)N(CH.sub.3).sub.2 and
--C(.dbd.S)NH.sub.2;
[0577] R.sup.5r is a 4-membered cycloalkyl group, or a 4-membered
cycloalkyl group that can be mono- to polysubstituted by
substituents independently selected from the group consisting of
halogen, ethyl, n-propyl, iso-propyl, n-butyl, iso-butyl,
sec-butyl, tert-butyl, n-pentyl,
--CH(CH.sub.3)--CH.sub.2--CH.sub.2--CH.sub.3,
--CH--CH(CH.sub.3)--CH.sub.2--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3)--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3).sub.2,
--CH(CH.sub.3)--CH(CH.sub.3).sub.2, C.sub.1-C.sub.6 haloalkyl,
C.sub.1-C.sub.6 alkoxy and C.sub.1-C.sub.6 alkylthio;
[0578] R.sup.5s is a 4-membered cycloalkyl group, or a 4-membered
cycloalkyl group that can be mono- to polysubstituted by
substituents independently selected from the group consisting of
halogen, ethyl, n-propyl, iso-propyl, n-butyl, iso-butyl,
sec-butyl, tert-butyl, n-pentyl,
--CH(CH.sub.3)--CH.sub.2--CH.sub.2--CH.sub.3,
--CH--CH(CH.sub.3)--CH.sub.2--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3)--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3).sub.2,
--CH(CH.sub.3)--CH(CH.sub.3).sub.2, C.sub.1-C.sub.6 fluoroalkyl,
C.sub.1-C.sub.6 alkoxy and C.sub.1-C.sub.6 alkylthio;
[0579] R.sup.5t is a 5-membered cycloalkyl group, or a 5-membered
cycloalkyl group that can be mono- to polysubstituted by
substituents independently selected from the group consisting of
halogen, CN, NO.sub.2, OH, SH, CHO, COOH, tri(C.sub.1-C.sub.6
alkyl)silyl, ethyl, n-propyl, iso-propyl, n-butyl, iso-butyl,
sec-butyl, tert-butyl, n-pentyl,
--CH(CH.sub.3)--CH.sub.2--CH.sub.2--CH.sub.3,
--CH--CH(CH.sub.3)--CH.sub.2--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3)--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3).sub.2,
--CH(CH.sub.3)--CH(CH.sub.3).sub.2, C.sub.1-C.sub.6 haloalkyl,
C.sub.3-C.sub.6 cycloalkyl, C.sub.3-C.sub.6 halocycloalkyl,
C.sub.2-C.sub.6 alkenyl, C.sub.2-C.sub.6 haloalkenyl,
C.sub.1-C.sub.6 alkoxy, C.sub.1-C.sub.6 haloalkoxy, C.sub.2-C.sub.7
alkylcarbonyl, C.sub.2-C.sub.7 alkoxycarbonyl, C.sub.4 C.sub.7
alkenyloxycarbonyl, C.sub.4 C.sub.7 alkynyloxycarbonyl,
C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6 alkylsulfinyl,
C.sub.1-C.sub.6 alkylsulfonyl, --C(.dbd.O)NH.sub.2,
--C(.dbd.O)NH(CH.sub.3), --C(.dbd.O)N(CH.sub.3).sub.2 and
--C(.dbd.S)NH.sub.2;
[0580] R.sup.5u is a 5-membered cycloalkyl group, or a 5-membered
cycloalkyl group that can be mono- to polysubstituted by
substituents independently selected from the group consisting of
halogen, ethyl, n-propyl, iso-propyl, n-butyl, iso-butyl,
sec-butyl, tert-butyl, n-pentyl,
--CH(CH.sub.3)--CH.sub.2--CH.sub.2--CH.sub.3,
--CH--CH(CH.sub.3)--CH.sub.2--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3)--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3).sub.2,
--CH(CH.sub.3)--CH(CH.sub.3).sub.2, C.sub.1-C.sub.6 haloalkyl,
C.sub.1-C.sub.6 alkoxy and C.sub.1-C.sub.6 alkylthio;
[0581] R.sup.5v is a 5-membered cycloalkyl group, or a 5-membered
cycloalkyl group that can be mono- to polysubstituted by
substituents independently selected from the group consisting of
halogen, ethyl, n-propyl, iso-propyl, n-butyl, iso-butyl,
sec-butyl, tert-butyl, n-pentyl,
--CH(CH.sub.3)--CH.sub.2--CH.sub.2--CH.sub.3,
--CH--CH(CH.sub.3)--CH.sub.2--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3)--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3).sub.2,
--CH(CH.sub.3)--CH(CH.sub.3).sub.2, C.sub.1-C.sub.6 fluoroalkyl,
C.sub.1-C.sub.6 alkoxy and C.sub.1-C.sub.6 alkylthio;
[0582] R.sup.5x is a 6-membered cycloalkyl group, or a 6-membered
cycloalkyl group that can be mono- to polysubstituted by
substituents independently selected from the group consisting of
halogen, CN, NO.sub.2, OH, SH, CHO, COOH, tri(C.sub.1-C.sub.6
alkyl)silyl, ethyl, n-propyl, iso-propyl, n-butyl, iso-butyl,
sec-butyl, tert-butyl, n-pentyl,
--CH(CH.sub.3)--CH.sub.2--CH.sub.2--CH.sub.3,
--CH--CH(CH.sub.3)--CH.sub.2--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3)--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3).sub.2,
--CH(CH.sub.3)--CH(CH.sub.3).sub.2, C.sub.1-C.sub.6 haloalkyl,
C.sub.3-C.sub.6 cycloalkyl, C.sub.3-C.sub.6 halocycloalkyl,
C.sub.2-C.sub.6 alkenyl, C.sub.2-C.sub.6 haloalkenyl,
C.sub.1-C.sub.6 alkoxy, C.sub.1-C.sub.6 haloalkoxy, C.sub.2-C.sub.7
alkylcarbonyl, C.sub.2-C.sub.7 alkoxycarbonyl, C.sub.4-C.sub.7
alkenyloxycarbonyl, C.sub.4-C.sub.7 alkynyloxycarbonyl,
C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6 alkylsulfinyl,
C.sub.1-C.sub.6 alkylsulfonyl, --C(.dbd.O)NH.sub.2,
--C(.dbd.O)NH(CH.sub.3), --C(.dbd.O)N(CH.sub.3).sub.2 and
--C(.dbd.S)NH.sub.2;
[0583] R.sup.5y is a 6-membered cycloalkyl group, or a 6-membered
cycloalkyl group that can be mono- to polysubstituted by
substituents independently selected from the group consisting of
halogen, ethyl, n-propyl, iso-propyl, n-butyl, iso-butyl,
sec-butyl, tert-butyl, n-pentyl,
--CH(CH.sub.3)--CH.sub.2--CH.sub.2--CH.sub.3,
--CH--CH(CH.sub.3)--CH.sub.2--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3)--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3).sub.2,
--CH(CH.sub.3)--CH(CH.sub.3).sub.2, C.sub.1-C.sub.6 haloalkyl,
C.sub.1-C.sub.6 alkoxy and C.sub.1-C.sub.6 alkylthio;
[0584] R.sup.5z is a 6-membered cycloalkyl group, or a 6-membered
cycloalkyl group that can be mono- to polysubstituted by
substituents independently selected from the group consisting of
halogen, ethyl, n-propyl, iso-propyl, n-butyl, iso-butyl,
sec-butyl, tert-butyl, n-pentyl,
--CH(CH.sub.3)--CH.sub.2--CH.sub.2--CH.sub.3,
--CH--CH(CH.sub.3)--CH.sub.2--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3)--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3).sub.2,
--CH(CH.sub.3)--CH(CH.sub.3).sub.2, C.sub.1-C.sub.6 fluoroalkyl,
C.sub.1-C.sub.6 alkoxy and C.sub.1-C.sub.6 alkylthio;
[0585] R.sup.5ab is a 7-membered cycloalkyl group, or a 7-membered
cycloalkyl group that can be mono- to polysubstituted by
substituents independently selected from the group consisting of
halogen, CN, NO.sub.2, OH, SH, CHO, COOH, tri(C.sub.1-C.sub.6
alkyl)silyl, ethyl, n-propyl, iso-propyl, n-butyl, iso-butyl,
sec-butyl, tert-butyl, n-pentyl,
--CH(CH.sub.3)--CH.sub.2--CH.sub.2--CH.sub.3,
--CH--CH(CH.sub.3)--CH.sub.2--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3)--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3).sub.2,
--CH(CH.sub.3)--CH(CH.sub.3).sub.2, C.sub.1-C.sub.6 haloalkyl,
C.sub.3-C.sub.6 cycloalkyl, C.sub.3-C.sub.6 halocycloalkyl,
C.sub.2-C.sub.6 alkenyl, C.sub.2-C.sub.6 haloalkenyl,
C.sub.1-C.sub.6 alkoxy, C.sub.1-C.sub.6 haloalkoxy, C.sub.2-C.sub.7
alkylcarbonyl, C.sub.2-C.sub.7 alkoxycarbonyl, C.sub.4-C.sub.7
alkenyloxycarbonyl, C.sub.4-C.sub.7 alkynyloxycarbonyl,
C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6 alkylsulfinyl,
C.sub.1-C.sub.6 alkylsulfonyl, --C(.dbd.O)NH.sub.2,
--C(.dbd.O)NH(CH.sub.3), --C(.dbd.O)N(CH.sub.3).sub.2 and
--C(.dbd.S)NH.sub.2;
[0586] R.sup.5ac is a 7-membered cycloalkyl group, or a 7-membered
cycloalkyl group that can be mono- to polysubstituted by
substituents independently selected from the group consisting of
halogen, ethyl, n-propyl, iso-propyl, n-butyl, iso-butyl,
sec-butyl, tert-butyl, n-pentyl,
--CH(CH.sub.3)--CH.sub.2--CH.sub.2--CH.sub.3,
--CH--CH(CH.sub.3)--CH.sub.2--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3)--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3).sub.2,
--CH(CH.sub.3)--CH(CH.sub.3).sub.2, C.sub.1-C.sub.6 haloalkyl,
C.sub.1-C.sub.6 alkoxy and C.sub.1-C.sub.6 alkylthio;
[0587] R.sup.5ad is a 7-membered cycloalkyl group, or a 7-membered
cycloalkyl group that can be mono- to polysubstituted by
substituents independently selected from the group consisting of
halogen, ethyl, n-propyl, iso-propyl, n-butyl, iso-butyl,
sec-butyl, tert-butyl, n-pentyl,
--CH(CH.sub.3)--CH.sub.2--CH.sub.2--CH.sub.3,
--CH--CH(CH.sub.3)--CH.sub.2--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3)--CH.sub.3,
--CH.sub.2--CH.sub.2--CH(CH.sub.3).sub.2,
--CH(CH.sub.3)--CH(CH.sub.3).sub.2, C.sub.1-C.sub.6 fluoroalkyl,
C.sub.1-C.sub.6 alkoxy and C.sub.1-C.sub.6 alkylthio;
[0588] R.sup.5ae is G.sup.8 wherein R.sup.1', R.sup.2', R.sup.3',
R.sup.4' and R.sup.5' are each independently selected from
hydrogen, fluoro, C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 haloalkyl,
C.sub.1-C.sub.4 alkoxy and C.sub.1-C.sub.4 alkylthio;
[0589] and wherein R.sup.11', R.sup.12', R.sup.13' and R.sup.14'
are each independently selected from hydrogen, halogen, CN,
NO.sub.2, OH, SH, CHO, C(.dbd.O)NH.sub.2, C(.dbd.O)NH(CH.sub.3),
C(.dbd.O)N(CH.sub.3).sub.2, C(.dbd.S)NH.sub.2,
C(.dbd.S)NH(CH.sub.3), C(.dbd.S)N(CH.sub.3).sub.2,
SO.sub.2NH.sub.2, SO.sub.2NH(CH.sub.3), SO.sub.2N(CH.sub.3).sub.2,
C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6 haloalkyl, C.sub.3-C.sub.6
cycloalkyl, C.sub.2-C.sub.6 alkenyl, C.sub.2-C.sub.6 haloalkenyl,
C.sub.2-C.sub.6 alkynyl, C.sub.2-C.sub.6 haloalkynyl,
C.sub.1-C.sub.6 alkoxy, C.sub.1-C.sub.6 haloalkoxy, C.sub.3-C.sub.6
alkenyloxy, C.sub.3-C.sub.6 haloalkenyloxy, C.sub.3-C.sub.6
alkynyloxy, C.sub.3-C.sub.6 cycloalkoxy, C.sub.3-C.sub.6
halocycloalkoxy, C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6
haloalkylthio, C.sub.1-C.sub.6 alkylsulfinyl, C.sub.1-C.sub.6
haloalkylsulfinyl, C.sub.1-C.sub.6 alkylsulfonyl and
C.sub.1-C.sub.6 haloalkylsulfonyl;
[0590] R.sup.5af is G.sup.8 wherein R.sup.1', R.sup.2', R.sup.3',
R.sup.4' and R.sup.5' are each independently selected from
hydrogen, fluoro, C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 haloalkyl,
C.sub.1-C.sub.4 alkoxy and C.sub.1-C.sub.4 alkylthio;
[0591] and wherein R.sup.11', R.sup.12', R.sup.13' and R.sup.14'
are each independently selected from hydrogen, halogen,
C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6 haloalkyl, C.sub.1-C.sub.6
alkoxy and C.sub.1-C.sub.6 alkylthio;
[0592] R.sup.5ag is G.sup.8 wherein R.sup.1, R.sup.2, R.sup.3',
R.sup.4' and R.sup.5' are each independently selected from
hydrogen, fluoro, methyl, ethyl, CH.sub.2F, CHF.sub.2, CF.sub.3,
CHF--CH.sub.3, CF.sub.2--CH.sub.3, methoxy, ethoxy, S--CH.sub.3 and
S--CH.sub.2CH.sub.3;
[0593] and wherein R.sup.11', R.sup.12', R.sup.13' and R.sup.14'
are each independently selected from hydrogen, halogen,
C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 haloalkyl, C.sub.1-C.sub.4
alkoxy and C.sub.1-C.sub.4 alkylthio;
[0594] R.sup.5ah is G.sup.8 wherein R.sup.1', R.sup.2', R.sup.3',
R.sup.4' and R.sup.5' are each independently selected from
hydrogen, fluoro, methyl, CHF.sub.2, CF.sub.3 and methoxy;
[0595] and wherein R.sup.11', R.sup.12', R.sup.13' and R.sup.14'
are each independently selected from hydrogen, halogen, CN,
NO.sub.2, OH, SH, CHO, C(.dbd.O)NH.sub.2, C(.dbd.O)NH(CH.sub.3),
C(.dbd.O)N(CH.sub.3).sub.2, C(.dbd.S)NH.sub.2,
C(.dbd.S)NH(CH.sub.3), C(.dbd.S)N(CH.sub.3).sub.2,
SO.sub.2NH.sub.2, SO.sub.2NH(CH.sub.3), SO.sub.2N(CH.sub.3).sub.2,
C.sub.1--C alkyl, C.sub.1-C.sub.6 haloalkyl, C.sub.3-C.sub.6
cycloalkyl, C.sub.2-C.sub.6 alkenyl, C.sub.2-C.sub.6 haloalkenyl,
C.sub.2-C.sub.6 alkynyl, C.sub.2-C.sub.6 haloalkynyl,
C.sub.1-C.sub.6 alkoxy, C.sub.1-C.sub.6 haloalkoxy, C.sub.3-C.sub.6
alkenyloxy, C.sub.3-C.sub.6 haloalkenyloxy, C.sub.3-C.sub.6
alkynyloxy, C.sub.3-C.sub.6 cycloalkoxy, C.sub.3-C.sub.6
halocycloalkoxy, C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6
haloalkylthio, C.sub.1-C.sub.6 alkylsulfinyl, C.sub.1-C.sub.6
haloalkylsulfinyl, C.sub.1-C.sub.6 alkylsulfonyl and
C.sub.1-C.sub.6 haloalkylsulfonyl;
[0596] R.sup.5aj is G.sup.8 wherein R.sup.1', R.sup.2', R.sup.3',
R.sup.4' and R.sup.5' are each independently selected from
hydrogen, fluoro, methyl, CHF.sub.2, CF.sub.3 and methoxy;
[0597] and wherein R.sup.11', R.sup.12, R.sup.13' and R.sup.14' are
each independently selected from hydrogen, halogen, C.sub.1-C.sub.6
alkyl, C.sub.1-C.sub.6 haloalkyl, C.sub.1-C.sub.6 alkoxy and
C.sub.1-C.sub.6 alkylthio;
[0598] R.sup.5ak is G.sup.8 wherein R.sup.1', R.sup.2', R.sup.3',
R.sup.4' and R.sup.5' are each independently selected from
hydrogen, fluoro, methyl, CHF.sub.2, CF.sub.3 and methoxy;
[0599] and wherein R.sup.11', R.sup.12', R.sup.13' and R.sup.14'
are each independently selected from hydrogen, halogen,
C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 haloalkyl, C.sub.1-C.sub.4
alkoxy and C.sub.1-C.sub.4 alkylthio;
[0600] R.sup.5al is G.sup.8 wherein R.sup.1', R.sup.2', R.sup.3',
R.sup.4' and R.sup.5' are each hydrogen;
[0601] and wherein R.sup.11', R.sup.12', R.sup.13' and R.sup.14'
are each independently selected from hydrogen, halogen, CN,
NO.sub.2, OH, SH, CHO, C(.dbd.O)NH.sub.2, C(.dbd.O)NH(CH.sub.3),
C(.dbd.O)N(CH.sub.3).sub.2, C(.dbd.S)NH.sub.2,
C(.dbd.S)NH(CH.sub.3), C(.dbd.S)N(CH.sub.3).sub.2,
SO.sub.2NH.sub.2, SO.sub.2NH(CH.sub.3), SO.sub.2N(CH.sub.3).sub.2,
C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6 haloalkyl, C.sub.3-C.sub.6
cycloalkyl, C.sub.2-C.sub.6 alkenyl, C.sub.2-C.sub.6 haloalkenyl,
C.sub.2-C.sub.6 alkynyl, C.sub.2-C.sub.6 haloalkynyl,
C.sub.1-C.sub.6 alkoxy, C.sub.1-C.sub.6 haloalkoxy, C.sub.3-C.sub.6
alkenyloxy, C.sub.3-C.sub.6 haloalkenyloxy, C.sub.3-C.sub.6
alkynyloxy, C.sub.3-C.sub.6 cycloalkoxy, C.sub.3-C.sub.6
halocycloalkoxy, C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6
haloalkylthio, C.sub.1-C.sub.6 alkylsulfinyl, C.sub.1-C.sub.6
haloalkylsulfinyl, C.sub.1-C.sub.6 alkylsulfonyl and
C.sub.1-C.sub.6 haloalkylsulfonyl;
[0602] R.sup.5am is G.sup.8 wherein R.sup.1', R.sup.2', R.sup.3',
R.sup.4' and R.sup.5' are each hydrogen;
[0603] and wherein R.sup.11', R.sup.12, R.sup.13 and R.sup.14' are
each independently selected from hydrogen, halogen, C.sub.1-C.sub.6
alkyl, C.sub.1-C.sub.6 haloalkyl, C.sub.1-C.sub.6 alkoxy and
C.sub.1-C.sub.6 alkylthio;
[0604] R.sup.5aa is G.sup.8 wherein R.sup.1, R.sup.2', R.sup.3',
R.sup.4' and R.sup.5' are each hydrogen;
[0605] and wherein R.sup.11', R.sup.12, R.sup.13' and R.sup.14' are
each independently selected from hydrogen, halogen, C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 haloalkyl, C.sub.1-C.sub.4 alkoxy and
C.sub.1-C.sub.4 alkylthio;
[0606] R.sup.5bb is a benzyl group, wherein the phenyl ring is
substituted by at least one fluorine and optionally by one or more
groups independently selected from the group consisting of
hydrogen, halogen, CN, NO.sub.2, OH, SH, CHO, C(.dbd.O)NH.sub.2,
C(.dbd.O)NH(CH.sub.3), C(.dbd.O)N(CH.sub.3).sub.2,
C(.dbd.S)NH.sub.2, C(.dbd.S)NH(CH.sub.3),
C(.dbd.S)N(CH.sub.3).sub.2, SO.sub.2NH.sub.2, SO.sub.2NH(CH,
SO.sub.2NH(CH.sub.3), SO.sub.2N(CH.sub.3).sub.2, C.sub.1-C.sub.6
alkyl, C.sub.1-C.sub.6 haloalkyl, C.sub.3-C.sub.6 cycloalkyl,
C.sub.2-C.sub.6 alkenyl, C.sub.2-C.sub.6 haloalkenyl,
C.sub.2-C.sub.6 alkynyl, C.sub.2-C.sub.6 haloalkynyl,
C.sub.1-C.sub.6 alkoxy, C.sub.1-C.sub.6 haloalkoxy, C.sub.3-C.sub.6
alkenyloxy, C.sub.3-C.sub.6 haloalkenyloxy, C.sub.3-C.sub.6
alkynyloxy, C.sub.3-C.sub.6 cycloalkoxy, C.sub.3-C.sub.6
halocycloalkoxy, C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6
haloalkylthio, C.sub.1-C.sub.6 alkylsulfinyl, C.sub.1-C.sub.6
haloalkylsulfinyl, C.sub.1-C.sub.6 alkylsulfonyl and
C.sub.1-C.sub.6 haloalkylsulfonyl;
[0607] R.sup.5cc is a benzyl group, wherein the phenyl ring is
substituted by at least one fluorine and optionally by one or more
groups independently selected from the group consisting of
hydrogen, halogen, CN, NO.sub.2, OH, SH, CHO, C(.dbd.O)NH.sub.2,
C(.dbd.O)NH(CH.sub.3), C(.dbd.O)N(CH.sub.3).sub.2,
C(.dbd.S)NH.sub.2, C(.dbd.S)NH(CH.sub.3),
C(.dbd.S)N(CH.sub.3).sub.2, SO.sub.2NH.sub.2, SO.sub.2NH(CH,
SO.sub.2NH(CH.sub.3), SO.sub.2N(CH.sub.3).sub.2, C.sub.1-C.sub.6
alkyl, C.sub.1-C.sub.6 haloalkyl, C.sub.3-C.sub.6 cycloalkyl,
C.sub.2-C.sub.6 alkenyl, C.sub.2-C.sub.6 haloalkenyl,
C.sub.2-C.sub.6 alkynyl, C.sub.1-C.sub.6 alkoxy, C.sub.1-C.sub.6
haloalkoxy, C.sub.3-C.sub.6 alkenyloxy, C.sub.3-C.sub.6 alkynyloxy,
C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6 alkylsulfinyl and
C.sub.1-C.sub.6 alkylsulfonyl;
[0608] R.sup.5dd is a benzyl group, wherein the phenyl ring is
substituted by at least one fluorine and optionally by one or more
groups independently selected from the group consisting of
hydrogen, halogen, CN, C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6
haloalkyl, C.sub.3-C.sub.6 cycloalkyl, C.sub.2-C.sub.6 alkenyl,
C.sub.2-C.sub.6 alkynyl, C.sub.1-C.sub.6 alkoxy, C.sub.3-C.sub.6
alkenyloxy, C.sub.3-C.sub.6 alkynyloxy and C.sub.1-C.sub.6
alkylthio;
[0609] R.sup.5ee is a benzyl group, wherein the phenyl ring is
substituted by at least one fluorine and optionally by one or more
groups independently selected from the group consisting of
hydrogen, halogen, CN, C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4
haloalkyl, C.sub.2-C.sub.4 alkenyl, C.sub.3-C.sub.6 cycloalkyl and
C.sub.1-C.sub.4 alkoxy;
[0610] R.sup.5ff is a benzyl group, wherein the methylene portion
is substituted by at least one group independently selected from
the group consisting of hydrogen, C.sub.1-C.sub.4 alkyl,
C.sub.1-C.sub.4 haloalkyl, CN, C.sub.1-C.sub.4 alkoxy and
C.sub.1-C.sub.4 haloalkoxy;
[0611] and wherein the phenyl ring is optionally substituted by one
or more groups independently selected from the group consisting of
hydrogen, halogen, CN, NO.sub.2, OH, SH, CHO, C(.dbd.O)NH.sub.2,
C(.dbd.O)NH(CH.sub.3), C(.dbd.O)N(CH.sub.3).sub.2,
C(.dbd.S)NH.sub.2, C(.dbd.S)NH(CH.sub.3),
C(.dbd.S)N(CH.sub.3).sub.2, SO.sub.2NH.sub.2, SO.sub.2NH(CH.sub.3),
SO.sub.2N(CH.sub.3).sub.2, C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6
haloalkyl, C.sub.3-C.sub.6 cycloalkyl, C.sub.2-C.sub.6 alkenyl,
C.sub.2-C.sub.6 haloalkenyl, C.sub.2-C.sub.6 alkynyl,
C.sub.2-C.sub.6 haloalkynyl, C.sub.1-C.sub.6 alkoxy,
C.sub.1-C.sub.6 haloalkoxy, C.sub.3-C.sub.6 alkenyloxy,
C.sub.3-C.sub.6 haloalkenyloxy, C.sub.3-C.sub.6 alkynyloxy,
C.sub.3-C.sub.6 cycloalkoxy, C.sub.3-C.sub.6 halocycloalkoxy,
C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6 haloalkylthio,
C.sub.1-C.sub.6 alkylsulfinyl, C.sub.1-C.sub.6 haloalkylsulfinyl,
C.sub.1-C.sub.6 alkylsulfonyl and C.sub.1-C.sub.6
haloalkylsulfonyl;
[0612] R.sup.5gg is a benzyl group, wherein the methylene portion
is substituted by at least one group independently selected from
the group consisting of hydrogen, C.sub.1-C.sub.4 alkyl,
C.sub.1-C.sub.4 haloalkyl and C.sub.1-C.sub.4 alkoxy;
[0613] and wherein the phenyl ring is optionally substituted by one
or more groups independently selected from the group consisting of
hydrogen, halogen, CN, NO.sub.2, OH, SH, CHO, C(.dbd.O)NH.sub.2,
C(.dbd.O)NH(CH.sub.3), C(.dbd.O)N(CH.sub.3).sub.2,
C(.dbd.S)NH.sub.2, C(.dbd.S)NH(CH.sub.3),
C(.dbd.S)N(CH.sub.3).sub.2, SO.sub.2NH.sub.2, SO.sub.2NH(CH.sub.3),
SO.sub.2N(CH.sub.3).sub.2, C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6
haloalkyl, C.sub.3-C.sub.6 cycloalkyl, C.sub.2-C.sub.6 alkenyl,
C.sub.2-C.sub.6 haloalkenyl, C.sub.2-C.sub.6 alkynyl,
C.sub.1-C.sub.6 alkoxy, C.sub.1-C.sub.6 haloalkoxy, C.sub.3-C.sub.6
alkenyloxy, C.sub.3-C.sub.6 alkynyloxy, C.sub.3-C.sub.6
cycloalkoxy, C.sub.3-C.sub.6 halocycloalkoxy, C.sub.1-C.sub.6
alkylthio, C.sub.1-C.sub.6 haloalkylthio, C.sub.1-C.sub.6
alkylsulfinyl, C.sub.1-C.sub.6 haloalkylsulfinyl, C.sub.1-C.sub.6
alkylsulfonyl and C.sub.1-C.sub.6 haloalkylsulfonyl;
[0614] R.sup.5hh is a benzyl group, wherein the methylene portion
is substituted one group independently selected from the group
consisting of C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 haloalkyl and
C.sub.1-C.sub.4 alkoxy;
[0615] and wherein the phenyl ring is optionally substituted by one
or more groups independently selected from the group consisting of
hydrogen, halogen, CN, NO.sub.2, OH, SH, CHO, C(.dbd.O)NH.sub.2,
C(.dbd.O)NH(CH.sub.3), C(.dbd.O)N(CH.sub.3).sub.2,
C(.dbd.S)NH.sub.2, C(.dbd.S)NH(CH.sub.3),
C(.dbd.S)N(CH.sub.3).sub.2, SO.sub.2NH.sub.2, SO.sub.2NH(CH.sub.3),
SO.sub.2N(CH.sub.3).sub.2, C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6
haloalkyl, C.sub.3-C.sub.6 cycloalkyl, C.sub.2-C.sub.6 alkenyl,
C.sub.2-C.sub.6 haloalkenyl, C.sub.2-C.sub.6 alkynyl,
C.sub.2-C.sub.6 haloalkynyl, C.sub.1-C.sub.6 alkoxy,
C.sub.1-C.sub.6 haloalkoxy, C.sub.3-C.sub.6 alkenyloxy,
C.sub.3-C.sub.6 haloalkenyloxy, C.sub.3-C.sub.6 alkynyloxy,
C.sub.3-C.sub.6 cycloalkoxy, C.sub.3-C.sub.6 halocycloalkoxy,
C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6 haloalkylthio,
C.sub.1-C.sub.6 alkylsulfinyl, C.sub.1-C.sub.6 haloalkylsulfinyl,
C.sub.1-C.sub.6 alkylsulfonyl and C.sub.1-C.sub.6
haloalkylsulfonyl
[0616] R.sup.5jj is a benzyl group, wherein the methylene portion
is substituted by one group independently selected from the group
consisting of hydrogen, C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4
haloalkyl and C.sub.1-C.sub.4 alkoxy;
[0617] and wherein the phenyl ring is optionally substituted by one
or more groups independently selected from the group consisting of
hydrogen, halogen, CN, NO.sub.2, OH, SH, CHO, C(.dbd.O)NH.sub.2,
C(.dbd.O)NH(CH.sub.3), C(.dbd.O)N(CH.sub.3).sub.2,
C(.dbd.S)NH.sub.2, C(.dbd.S)NH(CH.sub.3),
C(.dbd.S)N(CH.sub.3).sub.2, SO.sub.2NH.sub.2, SO.sub.2NH(CH.sub.3),
SO.sub.2N(CH.sub.3).sub.2, C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6
haloalkyl, C.sub.3-C.sub.6 cycloalkyl, C.sub.2-C.sub.6 alkenyl,
C.sub.2-C.sub.6 haloalkenyl, C.sub.2-C.sub.6 alkynyl,
C.sub.1-C.sub.6 alkoxy, C.sub.1-C.sub.6 haloalkoxy, C.sub.3-C.sub.6
alkenyloxy, C.sub.3-C.sub.6 alkynyloxy, C.sub.3-C.sub.6
cycloalkoxy, C.sub.3-C.sub.6 halocycloalkoxy, C.sub.1-C.sub.6
alkylthio, C.sub.1-C.sub.6 haloalkylthio, C.sub.1-C.sub.6
alkylsulfinyl, C.sub.1-C.sub.6 haloalkylsulfinyl, C.sub.1-C.sub.6
alkylsulfonyl and C.sub.1-C.sub.6 haloalkylsulfonyl;
[0618] R.sup.5kk is a benzyl group, wherein the methylene portion
is substituted one group independently selected from the group
consisting of methyl, ethyl, CHF.sub.2, CF.sub.3 and methoxy;
[0619] and wherein the phenyl ring is optionally substituted by one
or more groups independently selected from the group consisting of
hydrogen, halogen, CN, NO.sub.2, OH, SH, CHO, C(.dbd.O)NH.sub.2,
C(.dbd.O)NH(CH.sub.3), C(.dbd.O)N(CH.sub.3).sub.2,
C(.dbd.S)NH.sub.2, C(.dbd.S)NH(CH.sub.3),
C(.dbd.S)N(CH.sub.3).sub.2, SO.sub.2NH.sub.2, SO.sub.2NH(CH.sub.3),
SO.sub.2N(CH.sub.3).sub.2, C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6
haloalkyl, C.sub.3-C.sub.6 cycloalkyl, C.sub.2-C.sub.6 alkenyl,
C.sub.2-C.sub.6 haloalkenyl, C.sub.2-C.sub.6 alkynyl,
C.sub.2-C.sub.6 haloalkynyl, C.sub.1-C.sub.6 alkoxy,
C.sub.1-C.sub.6 haloalkoxy, C.sub.3-C.sub.6 alkenyloxy,
C.sub.3-C.sub.6 haloalkenyloxy, C.sub.3-C.sub.6 alkynyloxy,
C.sub.3-C.sub.6 cycloalkoxy, C.sub.3-C.sub.6 halocycloalkoxy,
C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6 haloalkylthio,
C.sub.1-C.sub.6 alkylsulfinyl, C.sub.1-C.sub.6 haloalkylsulfinyl,
C.sub.1-C.sub.6 alkylsulfonyl and C.sub.1-C.sub.6
haloalkylsulfonyl;
[0620] R.sup.5ll is a benzyl group, wherein the methylene portion
is substituted by one group independently selected from the group
consisting of methyl, ethyl, CHF.sub.2, CF.sub.3 and methoxy;
[0621] and wherein the phenyl ring is optionally substituted by one
or more groups independently selected from the group consisting of
hydrogen, halogen, CN, NO.sub.2, OH, SH, CHO, C(.dbd.O)NH.sub.2,
C(.dbd.O)NH(CH.sub.3), C(.dbd.O)N(CH.sub.3).sub.2,
C(.dbd.S)NH.sub.2, C(.dbd.S)NH(CH.sub.3),
C(.dbd.S)N(CH.sub.3).sub.2, SO.sub.2NH.sub.2, SO.sub.2NH(CH.sub.3),
SO.sub.2N(CH.sub.3).sub.2, C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6
haloalkyl, C.sub.3-C.sub.6 cycloalkyl, C.sub.2-C.sub.6 alkenyl,
C.sub.2-C.sub.6 haloalkenyl, C.sub.2-C.sub.6 alkynyl,
C.sub.1-C.sub.6 alkoxy, C.sub.1-C.sub.6 haloalkoxy, C.sub.3-C.sub.6
alkenyloxy, C.sub.3-C.sub.6 alkynyloxy, C.sub.3-C.sub.6
cycloalkoxy, C.sub.3-C.sub.6 halocycloalkoxy, C.sub.1-C.sub.6
alkylthio, C.sub.1-C.sub.6 haloalkylthio, C.sub.1-C.sub.6
alkylsulfinyl, C.sub.1-C.sub.6 haloalkylsulfinyl, C.sub.1-C.sub.6
alkylsulfonyl and C.sub.1-C.sub.6 haloalkylsulfonyl;
[0622] R.sup.5mm is a benzyl group, wherein the methylene portion
is substituted by at least one group independently selected from
the group consisting of hydrogen, C.sub.1-C.sub.4 alkyl,
C.sub.1-C.sub.4 haloalkyl, CN, C.sub.1-C.sub.4 alkoxy and
C.sub.1-C.sub.4 haloalkoxy;
[0623] and wherein the phenyl ring is optionally substituted by one
or more groups independently selected from the group consisting of
hydrogen, halogen, CN, OH, SH, CHO C.sub.1-C.sub.6 alkyl,
C.sub.1-C.sub.6 haloalkyl, C.sub.3-C.sub.6 cycloalkyl,
C.sub.2-C.sub.6 alkenyl, C.sub.2-C.sub.6 haloalkenyl,
C.sub.2-C.sub.6 alkynyl, C.sub.1-C.sub.6 alkoxy, C.sub.1-C.sub.6
haloalkoxy, C.sub.3-C.sub.6 alkenyloxy, C.sub.3-C.sub.6 alkynyloxy,
C.sub.3-C.sub.6 cycloalkoxy, C.sub.1-C.sub.6 alkylthio,
C.sub.1-C.sub.6 alkylsulfinyl and C.sub.1-C.sub.6
alkylsulfonyl;
[0624] R.sup.5nn is a benzyl group, wherein the methylene portion
is substituted one group independently selected from the group
consisting of C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 haloalkyl and
C.sub.1-C.sub.4 alkoxy;
[0625] and wherein the phenyl ring is optionally substituted by one
or more groups independently selected from the group consisting of
hydrogen, halogen, CN, OH, SH, CHO C.sub.1-C.sub.6 alkyl,
C.sub.1-C.sub.6 haloalkyl, C.sub.3-C.sub.6 cycloalkyl,
C.sub.2-C.sub.6 alkenyl, C.sub.2-C.sub.6 haloalkenyl,
C.sub.2-C.sub.6 alkynyl, C.sub.1-C.sub.6 alkoxy, C.sub.1-C.sub.6
haloalkoxy, C.sub.3-C.sub.6 alkenyloxy, C.sub.3-C.sub.6 alkynyloxy,
C.sub.3-C.sub.6 cycloalkoxy, C.sub.1-C.sub.6 alkylthio,
C.sub.1-C.sub.6 alkylsulfinyl and C.sub.1-C.sub.6
alkylsulfonyl;
[0626] R.sup.5oo is a benzyl group, wherein the methylene portion
is substituted one group independently selected from the group
consisting of methyl, ethyl, CHF.sub.2, CF.sub.3 and methoxy;
[0627] and wherein the phenyl ring is optionally substituted by one
or more groups independently selected from the group consisting of
hydrogen, halogen, CN, OH, SH, CHO C.sub.1-C.sub.6 alkyl,
C.sub.1-C.sub.6 haloalkyl, C.sub.3-C.sub.6 cycloalkyl,
C.sub.2-C.sub.6 alkenyl, C.sub.2-C.sub.6 haloalkenyl,
C.sub.2-C.sub.6 alkynyl, C.sub.1-C.sub.6 alkoxy, C.sub.1-C.sub.6
haloalkoxy, C.sub.3-C.sub.6 alkenyloxy, C.sub.3-C.sub.6 alkynyloxy,
C.sub.3-C.sub.6 cycloalkoxy, C.sub.1-C.sub.6 alkylthio,
C.sub.1-C.sub.6 alkylsulfinyl and C.sub.1-C.sub.6
alkylsulfonyl;
[0628] R.sup.5pp is a benzyl group, wherein the methylene portion
is substituted by at least one group independently selected from
the group consisting of hydrogen, C.sub.1-C.sub.4 alkyl,
C.sub.1-C.sub.4 haloalkyl, CN, C.sub.1-C.sub.4 alkoxy and
C.sub.1-C.sub.4 haloalkoxy;
[0629] and wherein the phenyl ring is optionally substituted by one
or more groups independently selected from the group consisting of
hydrogen, halogen, CN, OH, SH, CHO, methyl, ethyl, n-propyl,
iso-propyl, CH.sub.2F, CHF.sub.2, CF.sub.3, CHF--CH.sub.3,
CF.sub.2--CH.sub.3, CF.sub.2--CF.sub.3, cyclopropyl,
CH.dbd.CH.sub.2, C(CH.sub.3).dbd.CH.sub.2, CH.dbd.CH(CH.sub.3),
C(CH.sub.3).dbd.CH(CH.sub.3), CH.dbd.C(CH.sub.3).sub.2,
C(CH.sub.3).dbd.C(CH.sub.3).sub.2, CH.dbd.CF.sub.2,
CH.dbd.CC.sub.2, C.ident.CH, methoxy, ethoxy, iso-propyloxy,
OCHF.sub.2, OCH.sub.2--C.ident.CH, OCH(CH.sub.3)--C.ident.CH,
SCH.sub.3, SCH.sub.2CH.sub.3, S(.dbd.O)CH.sub.3,
S(.dbd.O)CH.sub.2CH.sub.3, S(.dbd.O).sub.2CH.sub.3 and
S(.dbd.O).sub.2CH.sub.2CH.sub.3;
[0630] R.sup.5qq is a benzyl group, wherein the methylene portion
is substituted one group independently selected from the group
consisting of C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 haloalkyl and
C.sub.1-C.sub.4 alkoxy;
[0631] and wherein the phenyl ring is optionally substituted by one
or more groups independently selected from the group consisting of
hydrogen, halogen, CN, OH, SH, CHO, methyl, ethyl, n-propyl,
iso-propyl, CH.sub.2F, CHF.sub.2, CF.sub.3, CHF--CH.sub.3,
CF.sub.2--CH.sub.3, CF.sub.2--CF.sub.3, cyclopropyl,
CH.dbd.CH.sub.2, C(CH.sub.3).dbd.CH.sub.2, CH.dbd.CH(CH.sub.3),
C(CH.sub.3).dbd.CH(CH.sub.3), CH.dbd.C(CH.sub.3).sub.2,
C(CH.sub.3).dbd.C(CH.sub.3).sub.2, CH.dbd.CF.sub.2,
CH.dbd.CCl.sub.2, C.ident.CH, methoxy, ethoxy, iso-propyloxy,
OCHF.sub.2, OCH.sub.2--C.ident.CH, OCH(CH.sub.3)--C.ident.CH,
SCH.sub.3, SCH.sub.2CH.sub.3, S(.dbd.O)CH.sub.3,
S(.dbd.O)CH.sub.2CH.sub.3, S(.dbd.O).sub.2CH.sub.3 and
S(.dbd.O).sub.2CH.sub.2CH.sub.3;
[0632] R.sup.5rr is a benzyl group, wherein the methylene portion
is substituted one group independently selected from the group
consisting of methyl, ethyl, CHF.sub.2, CF.sub.3 and methoxy;
[0633] and wherein the phenyl ring is optionally substituted by one
or more groups independently selected from the group consisting of
hydrogen, halogen, CN, OH, SH, CHO, methyl, ethyl, n-propyl,
iso-propyl, CH.sub.2F, CHF.sub.2, CF.sub.3, CHF--CH.sub.3,
CF.sub.2--CH.sub.3, CF.sub.2--CF.sub.3, cyclopropyl,
CH.dbd.CH.sub.2, C(CH.sub.3).dbd.CH.sub.2, CH.dbd.CH(CH.sub.3),
C(CH.sub.3).dbd.CH(CH.sub.3), CH.dbd.C(CH.sub.3).sub.2,
C(CH.sub.3).dbd.C(CH.sub.3).sub.2, CH.dbd.CF.sub.2,
CH.dbd.CCl.sub.2, C.ident.CH, methoxy, ethoxy, iso-propyloxy,
OCHF.sub.2, OCH.sub.2--C.ident.CH, OCH(CH.sub.3)--C.ident.CH,
SCH.sub.3, SCH.sub.2CH.sub.3, S(.dbd.O)CH.sub.3,
S(.dbd.O)CH.sub.2CH.sub.3, S(.dbd.O).sub.2CH.sub.3 and
S(.dbd.O).sub.2CH.sub.2CH.sub.3;
[0634] R.sup.5ss is G.sup.9 wherein R.sup.15' and R.sup.16 are
selected independently of each other, from the group consisting of
hydrogen, halogen, cyano, C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4
haloalkyl and C.sub.3-C.sub.6 cycloalkyl;
[0635] each R.sup.17', R.sup.18', R.sup.19', R.sup.20', R.sup.21'
and R.sup.22' are selected independently of each other, from the
group consisting of hydrogen, halogen, cyano, C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 haloalkyl, C.sub.1-C.sub.4 alkoxy,
C.sub.1-C.sub.4 haloalkoxy and C.sub.3-C.sub.6 cycloalkyl;
[0636] R.sup.23', R.sup.24' and R.sup.25' are selected
independently of each other, from the group consisting of hydrogen,
halogen, cyano, C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 haloalkyl,
C.sub.1-C.sub.4 alkoxy, C.sub.3-C.sub.6 cycloalkyl, C.sub.3-C.sub.6
halocycloalkyl and C.sub.1-C.sub.4 alkylthio;
[0637] R.sup.5tt is G.sup.9 wherein each R.sup.15', R.sup.16',
R.sup.17', R.sup.18', R.sup.19', R.sup.20', R.sup.21' and R.sup.22'
are selected independently of each other, from the group consisting
of hydrogen, halogen, methyl, ethyl, isopropyl, monofluoromethyl,
polyfluoromethyl, monofluoroethyl, and polyfluoroethyl;
[0638] R.sup.23', R.sup.24' and R.sup.25' are selected
independently of each other, from the group consisting of hydrogen,
halogen, cyano, C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 haloalkyl,
C.sub.1-C.sub.4 alkoxy, C.sub.3-C.sub.6 cycloalkyl, C.sub.3-C.sub.6
halocycloalkyl and C.sub.1-C.sub.4 alkylthio;
[0639] n is either 0 or 1;
[0640] R.sup.5uu is G.sup.9 wherein each R.sup.15', R.sup.16',
R.sup.17', R.sup.18', R.sup.19', R.sup.20', R.sup.21' and R.sup.22'
are selected independently of each other, from the group consisting
of hydrogen, fluorine, methyl, ethyl, isopropyl, CH.sub.2F,
CHF.sub.2, CF.sub.3, CHF--CH.sub.3, CF.sub.2--CH.sub.3,
CH.sub.2--CH.sub.2F CH.sub.2--CHF.sub.2 and CH.sub.2--CF.sub.3;
[0641] R.sup.23', R.sup.24' and R.sup.25' are selected
independently of each other, from the group consisting of hydrogen,
halogen, cyano, C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 haloalkyl,
C.sub.1-C.sub.4 alkoxy, C.sub.3-C.sub.6 cycloalkyl, C.sub.3-C.sub.6
halocycloalkyl and C.sub.1-C.sub.4 alkylthio;
[0642] n is either 0 or 1;
[0643] R.sup.5vv is G.sup.9 wherein R.sup.15', R.sup.16',
R.sup.17', R.sup.18', R.sup.19', R.sup.20', R.sup.21' and R.sup.22'
are each hydrogen;
[0644] R.sup.23', R.sup.24' and R.sup.25' are selected
independently of each other, from the group consisting of hydrogen,
halogen, cyano, C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 haloalkyl,
C.sub.1-C.sub.4 alkoxy, C.sub.3-C.sub.6 cycloalkyl, C.sub.3-C.sub.6
halocycloalkyl and C.sub.1-C.sub.4 alkylthio;
[0645] n is either 0 or 1;
[0646] R.sup.5vv is G.sup.9 wherein R.sup.15' and R.sup.16' are
selected independently of each other, from the group consisting of
methyl, F and CF.sub.3;
[0647] each R.sup.17', R.sup.18', R.sup.19', R.sup.20', R.sup.21'
and R.sup.22 are selected independently of each other, from the
group consisting of hydrogen, halogen, cyano, C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 haloalkyl, C.sub.1-C.sub.4 alkoxy,
C.sub.1-C.sub.4 haloalkoxy and C.sub.3-C.sub.6 cycloalkyl;
[0648] R.sup.23', R.sup.24' and R.sup.25' are selected
independently of each other, from the group consisting of hydrogen,
halogen, cyano, C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 haloalkyl,
C.sub.1-C.sub.4 alkoxy, C.sub.3-C.sub.6 cycloalkyl, C.sub.3-C.sub.6
halocycloalkyl and C.sub.1-C.sub.4 alkylthio;
[0649] n is either 0 or 1;
[0650] R.sup.5xx is G.sup.9 wherein R.sup.15' is selected from the
group consisting of hydrogen, halogen, cyano, C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 haloalkyl and C.sub.3-C.sub.6
cycloalkyl;
[0651] each R.sup.16', R.sup.17, R.sup.18', R.sup.19', R.sup.20',
R.sup.21' and R.sup.22' are hydrogen;
[0652] R.sup.23', R.sup.24' and R.sup.25' are selected
independently of each other, from the group consisting of hydrogen,
halogen, cyano, C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 haloalkyl,
C.sub.1-C.sub.4 alkoxy, C.sub.3-C.sub.6 cycloalkyl, C.sub.3-C.sub.6
halocycloalkyl and C.sub.1-C.sub.4 alkylthio;
[0653] n is either 0 or 1;
[0654] R.sup.5zz is G.sup.9 wherein R.sup.15' and R.sup.16' are
selected independently of each other, from the group consisting of
hydrogen, halogen, cyano, C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4
haloalkyl and C.sub.3-C.sub.6 cycloalkyl;
[0655] each R.sup.17', R.sup.18', R.sup.19', R.sup.20', R.sup.21'
and R.sup.22 are selected independently of each other, from the
group consisting of hydrogen, halogen, cyano, C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 haloalkyl, C.sub.1-C.sub.4 alkoxy,
C.sub.1-C.sub.4 haloalkoxy and C.sub.3-C.sub.6 cycloalkyl;
[0656] R.sup.23', R.sup.24' and R.sup.25' are selected
independently of each other, from the group consisting of hydrogen,
cyano, halogen, methyl, ethyl, isopropyl, fluoromethyl and
fluoroethyl;
[0657] R.sup.5ba is G.sup.9 wherein each R.sup.15', R.sup.16',
R.sup.17', R.sup.18', R.sup.19', R.sup.20', R.sup.21' and R.sup.22'
are selected independently of each other, from the group consisting
of hydrogen, halogen, methyl, ethyl, isopropyl, monofluoromethyl,
polyfluoromethyl, monofluoroethyl, and polyfluoroethyl;
[0658] R.sup.23', R.sup.24' and R.sup.25' are selected
independently of each other, from the group consisting of hydrogen,
cyano, halogen, methyl, ethyl, isopropyl, monofluoromethyl,
polyfluoromethyl, monofluoroethyl, and polyfluoroethyl;
[0659] n is either 0 or 1;
[0660] R.sup.5bc is G.sup.9 wherein each R.sup.15', R.sup.16',
R.sup.17', R.sup.18', R.sup.19', R.sup.20', R.sup.21' and R.sup.22'
are selected independently of each other, from the group consisting
of hydrogen, fluorine, methyl, ethyl, isopropyl, CH.sub.2F,
CHF.sub.2, CF.sub.3, CHF--CH.sub.3, CF.sub.2--CH.sub.3,
CH.sub.2--CH.sub.2F CH.sub.2--CHF.sub.2 and CH.sub.2--CF.sub.3;
[0661] R.sup.23', R.sup.24' and R.sup.25' are selected
independently of each other, from the group consisting of hydrogen,
cyano, halogen, methyl, ethyl, isopropyl, monofluoromethyl,
polyfluoromethyl, monofluoroethyl, and polyfluoroethyl;
[0662] n is either 0 or 1;
[0663] R.sup.5bd is G.sup.9 wherein R.sup.15', R.sup.16',
R.sup.17', R.sup.18', R.sup.19', R.sup.20', R.sup.21' and R.sup.22'
are each hydrogen;
[0664] R.sup.22' to R.sup.24' are selected independently of each
other, from the group consisting of hydrogen, cyano, halogen,
methyl, ethyl, isopropyl, monofluoromethyl, polyfluoromethyl,
monofluoroethyl, and polyfluoroethyl;
[0665] n is either 0 or 1;
[0666] R.sup.5be is G.sup.9 wherein R.sup.15' and R.sup.16 are
selected independently of each other, from the group consisting of
methyl, F and CF.sub.3;
[0667] each R.sup.17', R.sup.18', R.sup.19', R.sup.20', R.sup.21'
and R.sup.22 are selected independently of each other, from the
group consisting of hydrogen, halogen, cyano, C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 haloalkyl, C.sub.1-C.sub.4 alkoxy,
C.sub.1-C.sub.4 haloalkoxy and C.sub.3-C.sub.6 cycloalkyl;
[0668] R.sup.23', R.sup.24' and R.sup.25' are selected
independently of each other, from the group consisting of hydrogen,
cyano, halogen, methyl, ethyl, isopropyl, monofluoromethyl,
polyfluoromethyl, monofluoroethyl, and polyfluoroethyl;
[0669] n is either 0 or 1;
[0670] R.sup.5bf is G.sup.9 wherein R.sup.15' is selected from the
group consisting of hydrogen, halogen, cyano, C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 haloalkyl and C.sub.3-C.sub.6
cycloalkyl;
[0671] each R.sup.16', R.sup.17', R.sup.18', R.sup.19', R.sup.20',
R.sup.21' and R.sup.22' is hydrogen;
[0672] R.sup.23', R.sup.24' and R.sup.25' are selected
independently of each other, from the group consisting of hydrogen,
cyano, halogen, methyl, ethyl, isopropyl, monofluoromethyl,
polyfluoromethyl, monofluoroethyl, and polyfluoroethyl;
[0673] n is either 0 or 1;
[0674] R.sup.5bg is G.sup.9 wherein R.sup.15' and R.sup.16' are
selected independently of each other, from the group consisting of
hydrogen, halogen, cyano, C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4
haloalkyl and C.sub.3-C.sub.6 cycloalkyl;
[0675] each R.sup.17', R.sup.18', R.sup.19', R.sup.20', R.sup.21'
and R.sup.22' are selected independently of each other, from the
group consisting of hydrogen, halogen, cyano, C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 haloalkyl, C.sub.1-C.sub.4 alkoxy,
C.sub.1-C.sub.4 haloalkoxy and C.sub.3-C.sub.6 cycloalkyl;
[0676] R.sup.23', R.sup.24' and R.sup.25' are selected
independently of each other, from the group consisting of hydrogen,
F, Cl, Br, methyl, ethyl, isopropyl, CH.sub.2F, CHF.sub.2,
CF.sub.3, CHF--CH.sub.3, CF.sub.2--CH.sub.3, CH.sub.2--CH.sub.2F
CH.sub.2--CHF.sub.2 and CH.sub.2--CF.sub.3;
[0677] R.sup.5bh is G.sup.9 wherein each R.sup.15', R.sup.16',
R.sup.17', R.sup.18', R.sup.19', R.sup.20', R.sup.21' and R.sup.22
are selected independently of each other, from the group consisting
of hydrogen, halogen, methyl, ethyl, isopropyl, monofluoromethyl,
polyfluoromethyl, monofluoroethyl, and polyfluoroethyl;
[0678] R.sup.23', R.sup.24' and R.sup.25' are selected
independently of each other, from the group consisting of hydrogen,
F, Cl, Br, methyl, ethyl, isopropyl, CH.sub.2F, CHF.sub.2,
CF.sub.3, CHF--CH.sub.3, CF.sub.2--CH.sub.3, CH.sub.2--CH.sub.2F
CH.sub.2--CHF.sub.2 and CH.sub.2--CF.sub.3;
[0679] n is either 0 or 1;
[0680] R.sup.5bi is G.sup.9 wherein each R.sup.15', R.sup.16',
R.sup.17', R.sup.18', R.sup.19', R.sup.20', R.sup.21' and R.sup.22'
are selected independently of each other, from the group consisting
of hydrogen, fluorine, methyl, ethyl, isopropyl, CH.sub.2F,
CHF.sub.2, CF.sub.3, CHF--CH.sub.3, CF.sub.2--CH.sub.3,
CH.sub.2--CH.sub.2F CH.sub.2--CHF.sub.2 and CH.sub.2--CF.sub.3;
[0681] R.sup.23', R.sup.24' and R.sup.25' are selected
independently of each other, from the group consisting of hydrogen,
F, Cl, Br, methyl, ethyl, isopropyl, CH.sub.2F, CHF.sub.2,
CF.sub.3, CHF--CH.sub.3, CF.sub.2--CH.sub.3, CH.sub.2--CH.sub.2F
CH.sub.2--CHF.sub.2 and CH.sub.2--CF.sub.3;
[0682] n is either 0 or 1;
[0683] R.sup.5bj is G.sup.9 wherein R.sup.15', R.sup.16',
R.sup.17', R.sup.18', R.sup.19', R.sup.20', R.sup.21' and R.sup.22
are each hydrogen;
[0684] R.sup.23', R.sup.24' and R.sup.25' are selected
independently of each other, from the group consisting of hydrogen,
F, Cl, Br, methyl, ethyl, isopropyl, CH.sub.2F, CHF.sub.2,
CF.sub.3, CHF--CH.sub.3, CF.sub.2--CH.sub.3, CH.sub.2--CH.sub.2F
CH.sub.2--CHF.sub.2 and CH.sub.2--CF.sub.3;
[0685] n is either 0 or 1;
[0686] R.sup.5bk is G.sup.9 wherein R.sup.15' and R.sup.16' are
selected independently of each other, from the group consisting of
methyl, F and CF.sub.3;
[0687] each R.sup.17', R.sup.18', R.sup.19', R.sup.20', R.sup.21'
and R.sup.22' are selected independently of each other, from the
group consisting of hydrogen, halogen, cyano, C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 haloalkyl, C.sub.1-C.sub.4 alkoxy,
C.sub.1-C.sub.4 haloalkoxy and C.sub.3-C.sub.6 cycloalkyl;
[0688] R.sup.23', R.sup.24' and R.sup.25' are selected
independently of each other, from the group consisting of hydrogen,
F, Cl, Br, methyl, ethyl, isopropyl, CH.sub.2F, CHF.sub.2,
CF.sub.3, CHF--CH.sub.3, CF.sub.2--CH.sub.3, CH.sub.2--CH.sub.2F
CH.sub.2--CHF.sub.2 and CH.sub.2--CF.sub.3;
[0689] n is either 0 or 1;
[0690] R.sup.5bl is G.sup.9 wherein R.sup.15' is selected from the
group consisting of hydrogen, halogen, cyano, C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 haloalkyl and C.sub.3-C.sub.6
cycloalkyl;
[0691] each R.sup.16', R.sup.17', R.sup.18', R.sup.19', R.sup.20',
R.sup.21' and R.sup.22' is hydrogen;
[0692] R.sup.22' to R.sup.24' are selected independently of each
other, from the group consisting of hydrogen, F, Cl, Br, methyl,
ethyl, isopropyl, CH.sub.2F, CHF.sub.2, CF.sub.3, CHF--CH.sub.3,
CF.sub.2--CH.sub.3, CH.sub.2--CH.sub.2F CH.sub.2--CHF.sub.2 and
CH.sub.2--CF.sub.3;
[0693] n is either 0 or 1;
[0694] R.sup.5bm is G.sup.9 wherein R.sup.15' and R.sup.16' are
selected independently of each other, from the group consisting of
hydrogen, halogen, cyano, C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4
haloalkyl and C.sub.3-C.sub.6 cycloalkyl;
[0695] each R.sup.17', R.sup.18', R.sup.19', R.sup.20', R.sup.21'
and R.sup.22' are selected independently of each other, from the
group consisting of hydrogen, halogen, cyano, C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 haloalkyl, C.sub.1-C.sub.4 alkoxy,
C.sub.1-C.sub.4 haloalkoxy and C.sub.3-C.sub.6 cycloalkyl;
[0696] R.sup.23', R.sup.24' and R.sup.25' are selected
independently of each other, from the group consisting of hydrogen,
halogen, cyano, C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 haloalkyl,
C.sub.1-C.sub.4 alkoxy, C.sub.3-C.sub.6 cycloalkyl, C.sub.3-C.sub.6
halocycloalkyl and C.sub.1-C.sub.4 alkylthio;
[0697] n is 0;
[0698] R.sup.5bn is G.sup.9 wherein each R.sup.15', R.sup.16',
R.sup.17', R.sup.18', R.sup.19', R.sup.20', R.sup.21' and R.sup.22'
are selected independently of each other, from the group consisting
of hydrogen, halogen, methyl, ethyl, isopropyl, monofluoromethyl,
polyfluoromethyl, monofluoroethyl, and polyfluoroethyl;
[0699] R.sup.23', R.sup.24' and R.sup.25' are selected
independently of each other, from the group consisting of hydrogen,
halogen, cyano, C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 haloalkyl,
C.sub.1-C.sub.4 alkoxy, C.sub.3-C.sub.6 cycloalkyl, C.sub.3-C.sub.6
halocycloalkyl and C.sub.1-C.sub.4 alkylthio;
[0700] n is 0;
[0701] R.sup.5bo is G.sup.9 wherein each R.sup.15', R.sup.16',
R.sup.17', R.sup.18', R.sup.19', R.sup.20', R.sup.21' and R.sup.22'
are selected independently of each other, from the group consisting
of hydrogen, fluorine, methyl, ethyl, isopropyl, CH.sub.2F,
CHF.sub.2, CF.sub.3, CHF--CH.sub.3, CF.sub.2--CH.sub.3,
CH.sub.2--CH.sub.2F CH.sub.2--CHF.sub.2 and CH.sub.2--CF.sub.3;
[0702] R.sup.23', R.sup.24' and R.sup.25' are selected
independently of each other, from the group consisting of hydrogen,
halogen, cyano, C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 haloalkyl,
C.sub.1-C.sub.4 alkoxy, C.sub.3-C.sub.6 cycloalkyl, C.sub.3-C.sub.6
halocycloalkyl and C.sub.1-C.sub.4 alkylthio;
[0703] n is 0;
[0704] R.sup.5bp is G.sup.9 wherein R.sup.15', R.sup.16',
R.sup.17', R.sup.18', R.sup.19', R.sup.20', R.sup.21' and R.sup.22'
are each hydrogen;
[0705] R.sup.23', R.sup.24' and R.sup.25' are selected
independently of each other, from the group consisting of hydrogen,
halogen, cyano, C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 haloalkyl,
C.sub.1-C.sub.4 alkoxy, C.sub.3-C.sub.6 cycloalkyl, C.sub.3-C.sub.6
halocycloalkyl and C.sub.1-C.sub.4 alkylthio;
[0706] n is 0;
[0707] R.sup.5bq is G.sup.9 wherein R.sup.15' and R.sup.16' are
selected independently of each other, from the group consisting of
methyl, F and CF.sub.3;
[0708] each R.sup.17', R.sup.18', R.sup.19', R.sup.20', R.sup.21'
and R.sup.22' are selected independently of each other, from the
group consisting of hydrogen, halogen, cyano, C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 haloalkyl, C.sub.1-C.sub.4 alkoxy,
C.sub.1-C.sub.4 haloalkoxy and C.sub.3-C.sub.6 cycloalkyl;
[0709] R.sup.23', R.sup.24' and R.sup.25' are selected
independently of each other, from the group consisting of hydrogen,
halogen, cyano, C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 haloalkyl,
C.sub.1-C.sub.4 alkoxy, C.sub.3-C.sub.6 cycloalkyl, C.sub.3-C.sub.6
halocycloalkyl and C.sub.1-C.sub.4 alkylthio;
[0710] n is 0;
[0711] R.sup.5br is G.sup.9 wherein R.sup.15' is selected from the
group consisting of hydrogen, halogen, cyano, C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 haloalkyl and C.sub.3-C.sub.6
cycloalkyl;
[0712] each R.sup.16, R.sup.17, R.sup.18', R.sup.19, R.sup.20',
R.sup.21' and R.sup.22 is selected independently of each other,
from the group consisting of hydrogen;
[0713] R.sup.23', R.sup.24' and R.sup.25' are selected
independently of each other, from the group consisting of hydrogen,
halogen, cyano, C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 haloalkyl,
C.sub.1-C.sub.4 alkoxy, C.sub.3-C.sub.6 cycloalkyl, C.sub.3-C.sub.6
halocycloalkyl and C.sub.1-C.sub.4 alkylthio;
[0714] n is 0;
[0715] R.sup.5bs is G.sup.9 wherein R.sup.15' and R.sup.16 are
selected independently of each other, from the group consisting of
hydrogen, halogen, cyano, C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4
haloalkyl and C.sub.3-C.sub.6 cycloalkyl;
[0716] each R.sup.17', R.sup.18', R.sup.19', R.sup.20', R.sup.21'
and R.sup.22' are selected independently of each other, from the
group consisting of hydrogen, halogen, cyano, C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 haloalkyl, C.sub.1-C.sub.4 alkoxy,
C.sub.1-C.sub.4 haloalkoxy and C.sub.3-C.sub.6 cycloalkyl;
[0717] R.sup.23', R.sup.24' and R.sup.25' are selected
independently of each other, from the group consisting of hydrogen,
cyano, halogen, methyl, ethyl, isopropyl, monofluoromethyl,
polyfluoromethyl, monofluoroethyl, and polyfluoroethyl;
[0718] n is 0;
[0719] R.sup.5bt is G.sup.9 wherein each R.sup.15', R.sup.16',
R.sup.17', R.sup.18', R.sup.19', R.sup.20', R.sup.21' and R.sup.22'
are selected independently of each other, from the group consisting
of hydrogen, halogen, methyl, ethyl, isopropyl, monofluoromethyl,
polyfluoromethyl, monofluoroethyl, and polyfluoroethyl;
[0720] R.sup.23', R.sup.24' and R.sup.25' are selected
independently of each other, from the group consisting of hydrogen,
cyano, halogen, methyl, ethyl, isopropyl, monofluoromethyl,
polyfluoromethyl, monofluoroethyl, and polyfluoroethyl;
[0721] n is 0;
[0722] R.sup.5bu is G.sup.9 wherein each R.sup.15', R.sup.16',
R.sup.17', R.sup.18', R.sup.19', R.sup.20', R.sup.21' and R.sup.22'
are selected independently of each other, from the group consisting
of hydrogen, fluorine, methyl, ethyl, isopropyl, CH.sub.2F,
CHF.sub.2, CF.sub.3, CHF--CH.sub.3, CF.sub.2--CH.sub.3,
CH.sub.2--CH.sub.2F CH.sub.2--CHF.sub.2 and CH.sub.2--CF.sub.3;
[0723] R.sup.23', R.sup.24' and R.sup.25' are selected
independently of each other, from the group consisting of hydrogen,
cyano, halogen, methyl, ethyl, isopropyl, monofluoromethyl,
polyfluoromethyl, monofluoroethyl, and polyfluoroethyl;
[0724] n is 0;
[0725] R.sup.5bv is G.sup.9 wherein R.sup.15', R.sup.16',
R.sup.17', R.sup.18', R.sup.19', R.sup.20', R.sup.21' and R.sup.22'
are each hydrogen;
[0726] R.sup.23', R.sup.24' and R.sup.25' are selected
independently of each other, from the group consisting of hydrogen,
cyano, halogen, methyl, ethyl, isopropyl, monofluoromethyl,
polyfluoromethyl, monofluoroethyl, and polyfluoroethyl;
[0727] n is 0;
[0728] R.sup.5bw is G.sup.9 wherein R.sup.15' and R.sup.16' are
selected independently of each other, from the group consisting of
methyl, F and CF.sub.3;
[0729] each R.sup.17', R.sup.18', R.sup.19', R.sup.20', R.sup.21'
and R.sup.22 are selected independently of each other, from the
group consisting of hydrogen, halogen, cyano, C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 haloalkyl, C.sub.1-C.sub.4 alkoxy,
C.sub.1-C.sub.4 haloalkoxy and C.sub.3-C.sub.6 cycloalkyl;
[0730] R.sup.23', R.sup.24' and R.sup.25' are selected
independently of each other, from the group consisting of hydrogen,
cyano, halogen, methyl, ethyl, isopropyl, monofluoromethyl,
polyfluoromethyl, monofluoroethyl, and polyfluoroethyl;
[0731] n is 0;
[0732] R.sup.5bx is G.sup.9 wherein R.sup.15' is selected from the
group consisting of hydrogen, halogen, cyano, C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 haloalkyl and C.sub.3-C.sub.6
cycloalkyl;
[0733] each R.sup.16', R.sup.17, R.sup.18', R.sup.19', R.sup.20',
R.sup.21' and R.sup.22' is hydrogen;
[0734] R.sup.23', R.sup.24' and R.sup.25' are selected
independently of each other, from the group consisting of hydrogen,
cyano, halogen, methyl, ethyl, isopropyl, monofluoromethyl,
polyfluoromethyl, monofluoroethyl, and polyfluoroethyl;
[0735] n is 0;
[0736] R.sup.5by is G.sup.9 wherein R.sup.15' and R.sup.16' are
selected independently of each other, from the group consisting of
hydrogen, halogen, cyano, C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4
haloalkyl and C.sub.3-C.sub.6 cycloalkyl;
[0737] each R.sup.17', R.sup.18', R.sup.19', R.sup.20', R.sup.21'
and R.sup.22' are selected independently of each other, from the
group consisting of hydrogen, halogen, cyano, C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 haloalkyl, C.sub.1-C.sub.4 alkoxy,
C.sub.1-C.sub.4 haloalkoxy and C.sub.3-C.sub.6 cycloalkyl;
[0738] R.sup.23', R.sup.24' and R.sup.25' are selected
independently of each other, from the group consisting of hydrogen,
F, Cl, Br, methyl, ethyl, isopropyl, CH.sub.2F, CHF.sub.2,
CF.sub.3, CHF--CH.sub.3, CF.sub.2--CH.sub.3, CH.sub.2--CH.sub.2F
CH.sub.2--CHF.sub.2 and CH.sub.2--CF.sub.3;
[0739] n is 0;
[0740] R.sup.5bz is G.sup.9 wherein each R.sup.15', R.sup.16',
R.sup.17, R.sup.18', R.sup.19', R.sup.20', R.sup.21 and R.sup.22
are selected independently of each other, from the group consisting
of hydrogen, halogen, methyl, ethyl, isopropyl, monofluoromethyl,
polyfluoromethyl, monofluoroethyl, and polyfluoroethyl;
[0741] R.sup.23', R.sup.24' and R.sup.25' are selected
independently of each other, from the group consisting of hydrogen,
F, Cl, Br, methyl, ethyl, isopropyl, CH.sub.2F, CHF.sub.2,
CF.sub.3, CHF--CH.sub.3, CF.sub.2--CH.sub.3, CH.sub.2--CH.sub.2F
CH.sub.2--CHF.sub.2 and CH.sub.2--CF.sub.3;
[0742] n is 0;
[0743] R.sup.5ca is G.sup.9 wherein each R.sup.15', R.sup.16',
R.sup.17, R.sup.18', R.sup.19', R.sup.20', R.sup.21' and R.sup.22'
are selected independently of each other, from the group consisting
of hydrogen, fluorine, methyl, ethyl, isopropyl, CH.sub.2F,
CHF.sub.2, CF.sub.3, CHF--CH.sub.3, CF.sub.2--CH.sub.3,
CH.sub.2--CH.sub.2F CH.sub.2--CHF.sub.2 and CH.sub.2--CF.sub.3;
[0744] R.sup.23', R.sup.24' and R.sup.25' are selected
independently of each other, from the group consisting of hydrogen,
F, Cl, Br, methyl, ethyl, isopropyl, CH.sub.2F, CHF.sub.2,
CF.sub.3, CHF--CH.sub.3, CF.sub.2--CH.sub.3, CH.sub.2--CH.sub.2F
CH.sub.2--CHF.sub.2 and CH.sub.2--CF.sub.3;
[0745] n is 0;
[0746] R.sup.5cb is G.sup.9 wherein R.sup.15', R.sup.16',
R.sup.17', R.sup.18', R.sup.19', R.sup.20', R.sup.21' and R.sup.22
are each hydrogen;
[0747] R.sup.23', R.sup.24' and R.sup.25' are selected
independently of each other, from the group consisting of hydrogen,
F, Cl, Br, methyl, ethyl, isopropyl, CH.sub.2F, CHF.sub.2,
CF.sub.3, CHF--CH.sub.3, CF.sub.2--CH.sub.3, CH.sub.2--CH.sub.2F
CH.sub.2--CHF.sub.2 and CH.sub.2--CF.sub.3;
[0748] n is 0;
[0749] R.sup.5cd is G.sup.9 wherein R.sup.23', R.sup.24' and
R.sup.25' are selected independently of each other, from the group
consisting of methyl, F and CF.sub.3;
[0750] each R.sup.17', R.sup.18', R.sup.19', R.sup.20', R.sup.21'
and R.sup.22' are selected independently of each other, from the
group consisting of hydrogen, halogen, cyano, C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 haloalkyl, C.sub.1-C.sub.4 alkoxy,
C.sub.1-C.sub.4 haloalkoxy and C.sub.3-C.sub.6 cycloalkyl;
[0751] R.sup.23', R.sup.24' and R.sup.25' are selected
independently of each other, from the group consisting of hydrogen,
F, Cl, Br, methyl, ethyl, isopropyl, CH.sub.2F, CHF.sub.2,
CF.sub.3, CHF--CH.sub.3, CF.sub.2--CH.sub.3, CH.sub.2--CH.sub.2F
CH.sub.2--CHF.sub.2 and CH.sub.2--CF.sub.3;
[0752] n is 0;
[0753] R.sup.5ce is G.sup.9 wherein R.sup.15' is selected from the
group consisting of hydrogen, halogen, cyano, C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 haloalkyl and C.sub.3-C.sub.6
cycloalkyl;
[0754] each R.sup.16', R.sup.17', R.sup.18', R.sup.19', R.sup.20',
R.sup.21' and R.sup.22' is hydrogen;
[0755] R.sup.23', R.sup.24' and R.sup.25' are selected
independently of each other, from the group consisting of hydrogen,
F, Cl, Br, methyl, ethyl, isopropyl, CH.sub.2F, CHF.sub.2,
CF.sub.3, CHF--CH.sub.3, CF.sub.2--CH.sub.3, CH.sub.2--CH.sub.2F
CH.sub.2--CHF.sub.2 and CH.sub.2--CF.sub.3;
[0756] n is 0;
[0757] R.sup.5cf is G.sup.9 wherein R.sup.15' and R.sup.16' are
selected independently of each other, from the group consisting of
hydrogen, halogen, cyano, C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4
haloalkyl and C.sub.3-C.sub.6 cycloalkyl;
[0758] each R.sup.17', R.sup.18', R.sup.19', R.sup.20', R.sup.21'
and R.sup.22' are selected independently of each other, from the
group consisting of hydrogen, halogen, cyano, C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 haloalkyl, C.sub.1-C.sub.4 alkoxy,
C.sub.1-C.sub.4 haloalkoxy and C.sub.3-C.sub.6 cycloalkyl;
[0759] R.sup.23', R.sup.24' and R.sup.25' are selected
independently of each other, from the group consisting of hydrogen,
halogen, cyano, C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 haloalkyl,
C.sub.1-C.sub.4 alkoxy, C.sub.3-C.sub.6 cycloalkyl, C.sub.3-C.sub.6
halocycloalkyl and C.sub.1-C.sub.4 alkylthio;
[0760] n is 1;
[0761] R.sup.5cg is G.sup.9 wherein each R.sup.15', R.sup.16',
R.sup.17', R.sup.18', R.sup.19', R.sup.20', R.sup.21 and R.sup.22
are selected independently of each other, from the group consisting
of hydrogen, halogen, methyl, ethyl, isopropyl, monofluoromethyl,
polyfluoromethyl, monofluoroethyl, and polyfluoroethyl;
[0762] R.sup.23', R.sup.24' and R.sup.25' are selected
independently of each other, from the group consisting of hydrogen,
halogen, cyano, C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 haloalkyl,
C.sub.1-C.sub.4 alkoxy, C.sub.3-C.sub.6 cycloalkyl, C.sub.3-C.sub.6
halocycloalkyl and C.sub.1-C.sub.4 alkylthio;
[0763] n is 1;
[0764] R.sup.5ch is G.sup.9 wherein each R.sup.15', R.sup.16',
R.sup.17', R.sup.18', R.sup.19', R.sup.20', R.sup.21' and R.sup.22'
are selected independently of each other, from the group consisting
of hydrogen, fluorine, methyl, ethyl, isopropyl, CH.sub.2F,
CHF.sub.2, CF.sub.3, CHF--CH.sub.3, CF.sub.2--CH.sub.3,
CH.sub.2--CH.sub.2F CH.sub.2--CHF.sub.2 and CH.sub.2--CF.sub.3;
[0765] R.sup.23', R.sup.24' and R.sup.25' are selected
independently of each other, from the group consisting of hydrogen,
halogen, cyano, C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 haloalkyl,
C.sub.1-C.sub.4 alkoxy, C.sub.3-C.sub.6 cycloalkyl, C.sub.3-C.sub.6
halocycloalkyl and C.sub.1-C.sub.4 alkylthio;
[0766] n is 1;
[0767] R.sup.5ci is G.sup.9 wherein R.sup.15', R.sup.16',
R.sup.17', R.sup.18', R.sup.19', R.sup.20', R.sup.21' and R.sup.22
are each hydrogen;
[0768] R.sup.23', R.sup.24' and R.sup.25' are selected
independently of each other, from the group consisting of hydrogen,
halogen, cyano, C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 haloalkyl,
C.sub.1-C.sub.4 alkoxy, C.sub.3-C.sub.6 cycloalkyl, C.sub.3-C.sub.6
halocycloalkyl and C.sub.1-C.sub.4 alkylthio;
[0769] n is 1;
[0770] R.sup.5cj is G.sup.9 wherein R.sup.15' and R.sup.16' are
selected independently of each other, from the group consisting of
methyl, F and CF.sub.3;
[0771] each R.sup.17', R.sup.18', R.sup.19', R.sup.20', R.sup.21'
and R.sup.22 are selected independently of each other, from the
group consisting of hydrogen, halogen, cyano, C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 haloalkyl, C.sub.1-C.sub.4 alkoxy,
C.sub.1-C.sub.4 haloalkoxy and C.sub.3-C.sub.6 cycloalkyl;
[0772] R.sup.23', R.sup.24' and R.sup.25' are selected
independently of each other, from the group consisting of hydrogen,
halogen, cyano, C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 haloalkyl,
C.sub.1-C.sub.4 alkoxy, C.sub.3-C.sub.6 cycloalkyl, C.sub.3-C.sub.6
halocycloalkyl and C.sub.1-C.sub.4 alkylthio;
[0773] n is 1;
[0774] R.sup.5ck is G.sup.9 wherein R.sup.15' is selected from the
group consisting of hydrogen, halogen, cyano, C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 haloalkyl and C.sub.3-C.sub.6 cycloalkyl;
each R.sup.16', R.sup.17, R.sup.18', R.sup.19', R.sup.20',
R.sup.21' and R.sup.22' is selected independently of each other,
from the group consisting of hydrogen;
[0775] R.sup.23', R.sup.24' and R.sup.25' are selected
independently of each other, from the group consisting of hydrogen,
halogen, cyano, C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4 haloalkyl,
C.sub.1-C.sub.4 alkoxy, C.sub.3-C.sub.6 cycloalkyl, C.sub.3-C.sub.6
halocycloalkyl and C.sub.1-C.sub.4 alkylthio;
[0776] n is 1;
[0777] R.sup.5cl is G.sup.9 wherein R.sup.15' and R.sup.16' are
selected independently of each other, from the group consisting of
hydrogen, halogen, cyano, C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4
haloalkyl and C.sub.3-C.sub.6 cycloalkyl;
[0778] each R.sup.17', R.sup.18', R.sup.19', R.sup.20', R.sup.21'
and R.sup.22 are selected independently of each other, from the
group consisting of hydrogen, halogen, cyano, C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 haloalkyl, C.sub.1-C.sub.4 alkoxy,
C.sub.1-C.sub.4 haloalkoxy and C.sub.3-C.sub.6 cycloalkyl;
[0779] R.sup.23', R.sup.24' and R.sup.25' are selected
independently of each other, from the group consisting of hydrogen,
cyano, halogen, methyl, ethyl, isopropyl, monofluoromethyl,
polyfluoromethyl, monofluoroethyl, and polyfluoroethyl;
[0780] n is 1;
[0781] R.sup.5cm is G.sup.9 wherein each R.sup.15', R.sup.16',
R.sup.17', R.sup.18', R.sup.19', R.sup.20', R.sup.21' and R.sup.22'
are selected independently of each other, from the group consisting
of hydrogen, halogen, methyl, ethyl, isopropyl, monofluoromethyl,
polyfluoromethyl, monofluoroethyl, and polyfluoroethyl;
[0782] R.sup.23', R.sup.24' and R.sup.25' are selected
independently of each other, from the group consisting of hydrogen,
cyano, halogen, methyl, ethyl, isopropyl, monofluoromethyl,
polyfluoromethyl, monofluoroethyl, and polyfluoroethyl;
[0783] n is 1;
[0784] R.sup.5cn is G.sup.9 wherein each R.sup.15', R.sup.16',
R.sup.17', R.sup.18', R.sup.19', R.sup.20', R.sup.21' and R.sup.22'
are selected independently of each other, from the group consisting
of hydrogen, fluorine, methyl, ethyl, isopropyl, CH.sub.2F,
CHF.sub.2, CF.sub.3, CHF--CH.sub.3, CF.sub.2--CH.sub.3,
CH.sub.2--CH.sub.2F CH.sub.2--CHF.sub.2 and CH.sub.2--CF.sub.3;
[0785] R.sup.23', R.sup.24' and R.sup.25' are selected
independently of each other, from the group consisting of hydrogen,
cyano, halogen, methyl, ethyl, isopropyl, monofluoromethyl,
polyfluoromethyl, monofluoroethyl, and polyfluoroethyl;
[0786] n is 1;
[0787] R.sup.5co is G.sup.9 wherein R.sup.15', R.sup.16',
R.sup.17', R.sup.18', R.sup.19', R.sup.20', R.sup.21' and R.sup.22'
are each hydrogen;
[0788] R.sup.23', R.sup.24' and R.sup.25' are selected
independently of each other, from the group consisting of hydrogen,
cyano, halogen, methyl, ethyl, isopropyl, monofluoromethyl,
polyfluoromethyl, monofluoroethyl, and polyfluoroethyl;
[0789] n is 1;
[0790] R.sup.5cp is G.sup.9 wherein R.sup.15' and R.sup.16' are
selected independently of each other, from the group consisting of
methyl, F and CF.sub.3;
[0791] each R.sup.17', R.sup.18', R.sup.19', R.sup.20', R.sup.21'
and R.sup.22' are selected independently of each other, from the
group consisting of hydrogen, halogen, cyano, C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 haloalkyl, C.sub.1-C.sub.4 alkoxy,
C.sub.1-C.sub.4 haloalkoxy and C.sub.3-C.sub.6 cycloalkyl;
[0792] R.sup.23', R.sup.24' and R.sup.25' are selected
independently of each other, from the group consisting of hydrogen,
cyano, halogen, methyl, ethyl, isopropyl, monofluoromethyl,
polyfluoromethyl, monofluoroethyl, and polyfluoroethyl;
[0793] n is 1;
[0794] R.sup.5cq is G.sup.9 wherein R.sup.15' is selected from the
group consisting of hydrogen, halogen, cyano, C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 haloalkyl and C.sub.3-C.sub.6
cycloalkyl;
[0795] each R.sup.16', R.sup.17', R.sup.18', R.sup.19', R.sup.20',
R.sup.21' and R.sup.22' is hydrogen;
[0796] R.sup.23', R.sup.24' and R.sup.25' are selected
independently of each other, from the group consisting of hydrogen,
cyano, halogen, methyl, ethyl, isopropyl, monofluoromethyl,
polyfluoromethyl, monofluoroethyl, and polyfluoroethyl;
[0797] n is 1;
[0798] R.sup.5cr is G.sup.9 wherein R.sup.15' and R.sup.16' are
selected independently of each other, from the group consisting of
hydrogen, halogen, cyano, C.sub.1-C.sub.4 alkyl, C.sub.1-C.sub.4
haloalkyl and C.sub.3-C.sub.6 cycloalkyl;
[0799] each R.sup.17', R.sup.18', R.sup.19', R.sup.20', R.sup.21'
and R.sup.22' are selected independently of each other, from the
group consisting of hydrogen, halogen, cyano, C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 haloalkyl, C.sub.1-C.sub.4 alkoxy,
C.sub.1-C.sub.4 haloalkoxy and C.sub.3-C.sub.6 cycloalkyl;
[0800] R.sup.23', R.sup.24' and R.sup.25' are selected
independently of each other, from the group consisting of hydrogen,
F, Cl, Br, methyl, ethyl, isopropyl, CH.sub.2F, CHF.sub.2,
CF.sub.3, CHF--CH.sub.3, CF.sub.2--CH.sub.3, CH.sub.2--CH.sub.2F
CH.sub.2--CHF.sub.2 and CH.sub.2--CF.sub.3;
[0801] n is 1;
[0802] R.sup.5cs is G.sup.9 wherein each R.sup.15', R.sup.16',
R.sup.17', R.sup.18', R.sup.19', R.sup.20', R.sup.21' and R.sup.22'
are selected independently of each other, from the group consisting
of hydrogen, halogen, methyl, ethyl, isopropyl, monofluoromethyl,
polyfluoromethyl, monofluoroethyl, and polyfluoroethyl;
[0803] R.sup.23', R.sup.24' and R.sup.25' are selected
independently of each other, from the group consisting of hydrogen,
F, Cl, Br, methyl, ethyl, isopropyl, CH.sub.2F, CHF.sub.2,
CF.sub.3, CHF--CH.sub.3, CF.sub.2--CH.sub.3, CH.sub.2--CH.sub.2F
CH.sub.2--CHF.sub.2 and CH.sub.2--CF.sub.3;
[0804] n is 1;
[0805] R.sup.5ct is G.sup.9 wherein each R.sup.15', R.sup.16',
R.sup.17', R.sup.18', R.sup.19', R.sup.20', R.sup.21 and R.sup.22
are selected independently of each other, from the group consisting
of hydrogen, fluorine, methyl, ethyl, isopropyl, CH.sub.2F,
CHF.sub.2, CF.sub.3, CHF--CH.sub.3, CF.sub.2--CH.sub.3,
CH.sub.2--CH.sub.2F CH.sub.2--CHF.sub.2 and CH.sub.2--CF.sub.3;
[0806] R.sup.23', R.sup.24' and R.sup.25' are selected
independently of each other, from the group consisting of hydrogen,
F, Cl, Br, methyl, ethyl, isopropyl, CH.sub.2F, CHF.sub.2,
CF.sub.3, CHF--CH.sub.3, CF.sub.2--CH.sub.3, CH.sub.2--CH.sub.2F
CH.sub.2--CHF.sub.2 and CH.sub.2--CF.sub.3;
[0807] n is 1;
[0808] R.sup.5cu is G.sup.9 wherein R.sup.15', R.sup.16',
R.sup.17', R.sup.18', R.sup.19', R.sup.20', R.sup.21' and R.sup.22'
are each hydrogen;
[0809] R.sup.23', R.sup.24' and R.sup.25' are selected
independently of each other, from the group consisting of hydrogen,
F, Cl, Br, methyl, ethyl, isopropyl, CH.sub.2F, CHF.sub.2,
CF.sub.3, CHF--CH.sub.3, CF.sub.2--CH.sub.3, CH.sub.2--CH.sub.2F
CH.sub.2--CHF.sub.2 and CH.sub.2--CF.sub.3;
[0810] n is 1;
[0811] R.sup.5cv is G.sup.9 wherein R.sup.15' and R.sup.16' are
selected independently of each other, from the group consisting of
methyl, F and CF.sub.3;
[0812] each R.sup.17', R.sup.18', R.sup.19', R.sup.20', R.sup.21'
and R.sup.22' are selected independently of each other, from the
group consisting of hydrogen, halogen, cyano, C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 haloalkyl, C.sub.1-C.sub.4 alkoxy,
C.sub.1-C.sub.4 haloalkoxy and C.sub.3-C.sub.6 cycloalkyl;
[0813] R.sup.23', R.sup.24' and R.sup.25' are selected
independently of each other, from the group consisting of hydrogen,
F, Cl, Br, methyl, ethyl, isopropyl, CH.sub.2F, CHF.sub.2,
CF.sub.3, CHF--CH.sub.3, CF.sub.2--CH.sub.3, CH.sub.2--CH.sub.2F
CH.sub.2--CHF.sub.2 and CH.sub.2--CF.sub.3;
[0814] n is 1;
[0815] R.sup.5cw is G.sup.9 wherein R.sup.15' is selected from the
group consisting of hydrogen, halogen, cyano, C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 haloalkyl and C.sub.3-C.sub.6
cycloalkyl;
[0816] each R.sup.16', R.sup.17', R.sup.18', R.sup.19', R.sup.20',
R.sup.21' and R.sup.22' is hydrogen;
[0817] R.sup.23', R.sup.24' and R.sup.25' are selected
independently of each other, from the group consisting of hydrogen,
F, Cl, Br, methyl, ethyl, isopropyl, CH.sub.2F, CHF.sub.2,
CF.sub.3, CHF--CH.sub.3, CF.sub.2--CH.sub.3, CH.sub.2--CH.sub.2F
CH.sub.2--CHF.sub.2 and CH.sub.2--CF.sub.3;
[0818] n is 1;
[0819] R.sup.5cx is G.sup.14 wherein G.sup.14 is
##STR00022##
[0820] wherein R.sup.37' and R.sup.38' are selected independently
of each other from the group consisting of hydrogen, halogen,
cyano, C.sub.1-C.sub.4 alkyl and C.sub.1-C.sub.4 haloalkyl;
[0821] R.sup.39', R.sup.40', R.sup.41', R.sup.42', R.sup.43' and
R.sup.44' are selected independently of each other from the group
consisting of hydrogen, halogen, hydroxy, cyano, C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 haloalkyl, C.sub.1-C.sub.4 alkoxy and
C.sub.1-C.sub.4 haloalkoxy and C.sub.1-C.sub.4 alkylthio;
[0822] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, halogen, CN, NO.sub.2, OH, SH, CHO, C(.dbd.O)NH.sub.2,
C(.dbd.O)NH(CH.sub.3), C(.dbd.O)N(CH.sub.3).sub.2,
C(.dbd.S)NH.sub.2, C(.dbd.S)NH(CH.sub.3),
C(.dbd.S)N(CH.sub.3).sub.2, SO.sub.2NH.sub.2, SO.sub.2NH(CH.sub.3),
SO.sub.2N(CH.sub.3).sub.2, C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6
haloalkyl, C.sub.3-C.sub.6 cycloalkyl, C.sub.2-C.sub.6 alkenyl,
C.sub.2-C.sub.6 haloalkenyl, C.sub.2-C.sub.6 alkynyl,
C.sub.2-C.sub.6 haloalkynyl, C.sub.1-C.sub.6 alkoxy,
C.sub.1-C.sub.6 haloalkoxy, C.sub.3-C.sub.6 alkenyloxy,
C.sub.3-C.sub.6 haloalkenyloxy, C.sub.3-C.sub.6 alkynyloxy,
C.sub.3-C.sub.6 cycloalkoxy, C.sub.3-C.sub.6 halocycloalkoxy,
C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6 haloalkylthio,
C.sub.1-C.sub.6 alkylsulfinyl, C.sub.1-C.sub.6 haloalkylsulfinyl,
C.sub.1-C.sub.6 alkylsulfonyl and C.sub.1-C.sub.6
haloalkylsulfonyl;
[0823] p and q are independently selected from 0 and 1;
[0824] R.sup.5cy is G.sup.14 wherein R.sup.37, R.sup.38, R.sup.39,
R.sup.40, R.sup.41, R.sup.42', R.sup.43' and R.sup.44' are selected
independently of each other from the group consisting of hydrogen,
halogen, methyl, ethyl, isopropyl, monofluoromethyl,
polyfluoromethyl, monofluoroethyl and polyfluoroethyl;
[0825] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, halogen, CN, NO.sub.2, OH, SH, CHO, C(.dbd.O)NH.sub.2,
C(.dbd.O)NH(CH.sub.3), C(.dbd.O)N(CH.sub.3).sub.2,
C(.dbd.S)NH.sub.2, C(.dbd.S)NH(CH.sub.3),
C(.dbd.S)N(CH.sub.3).sub.2, SO.sub.2NH.sub.2, SO.sub.2NH(CH.sub.3),
SO.sub.2N(CH.sub.3).sub.2, C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6
haloalkyl, C.sub.3-C.sub.6 cycloalkyl, C.sub.2-C.sub.6 alkenyl,
C.sub.2-C.sub.6 haloalkenyl, C.sub.2-C.sub.6 alkynyl,
C.sub.2-C.sub.6 haloalkynyl, C.sub.1-C.sub.6 alkoxy,
C.sub.1-C.sub.6 haloalkoxy, C.sub.3-C.sub.6 alkenyloxy,
C.sub.3-C.sub.6 haloalkenyloxy, C.sub.3-C.sub.6 alkynyloxy,
C.sub.3-C.sub.6 cycloalkoxy, C.sub.3-C.sub.6 halocycloalkoxy,
C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6 haloalkylthio,
C.sub.1-C.sub.6 alkylsulfinyl, C.sub.1-C.sub.6 haloalkylsulfinyl,
C.sub.1-C.sub.6 alkylsulfonyl and C.sub.1-C.sub.6
haloalkylsulfonyl;
[0826] p and q are independently selected from 0 and 1;
[0827] R.sup.5cz is G.sup.14 wherein R.sup.37', R.sup.38',
R.sup.39', R.sup.40', R.sup.41', R.sup.42', R.sup.43' and R.sup.44'
are selected independently of each other from the group consisting
of hydrogen, fluorine, methyl, ethyl, isopropyl, CH.sub.2F,
CHF.sub.2, CF.sub.3, CHF--CH.sub.3, CF.sub.2--CH.sub.3,
CH.sub.2--CH.sub.2F CH.sub.2--CHF.sub.2 and CH.sub.2--CF.sub.3;
[0828] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, halogen, CN, NO.sub.2, OH, SH, CHO, C(.dbd.O)NH.sub.2,
C(.dbd.O)NH(CH.sub.3), C(.dbd.O)N(CH.sub.3).sub.2,
C(.dbd.S)NH.sub.2, C(.dbd.S)NH(CH.sub.3),
C(.dbd.S)N(CH.sub.3).sub.2, SO.sub.2NH.sub.2, SO.sub.2NH(CH.sub.3),
SO.sub.2N(CH.sub.3).sub.2, C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6
haloalkyl, C.sub.3-C.sub.6 cycloalkyl, C.sub.2-C.sub.6 alkenyl,
C.sub.2-C.sub.6 haloalkenyl, C.sub.2-C.sub.6 alkynyl,
C.sub.2-C.sub.6 haloalkynyl, C.sub.1-C.sub.6 alkoxy,
C.sub.1-C.sub.6 haloalkoxy, C.sub.3-C.sub.6 alkenyloxy,
C.sub.3-C.sub.6 haloalkenyloxy, C.sub.3-C.sub.6 alkynyloxy,
C.sub.3-C.sub.6 cycloalkoxy, C.sub.3-C.sub.6 halocycloalkoxy,
C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6 haloalkylthio,
C.sub.1-C.sub.6 alkylsulfinyl, C.sub.1-C.sub.6 haloalkylsulfinyl,
C.sub.1-C.sub.6 alkylsulfonyl and C.sub.1-C.sub.6
haloalkylsulfonyl;
[0829] p and q are independently selected from 0 and 1;
[0830] R.sup.5da is G.sup.14 wherein R.sup.37', R.sup.38',
R.sup.39', R.sup.40', R.sup.41', R.sup.42', R.sup.43' and R.sup.44'
are selected independently of each other from the group consisting
of methyl, ethyl, F and CF.sub.3;
[0831] R.sup.45', R.sup.46, R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, halogen, CN, NO.sub.2, OH, SH, CHO, C(.dbd.O)NH.sub.2,
C(.dbd.O)NH(CH.sub.3), C(.dbd.O)N(CH.sub.3).sub.2,
C(.dbd.S)NH.sub.2, C(.dbd.S)NH(CH.sub.3),
C(.dbd.S)N(CH.sub.3).sub.2, SO.sub.2NH.sub.2, SO.sub.2NH(CH.sub.3),
SO.sub.2N(CH.sub.3).sub.2, C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6
haloalkyl, C.sub.3-C.sub.6 cycloalkyl, C.sub.2-C.sub.6 alkenyl,
C.sub.2-C.sub.6 haloalkenyl, C.sub.2-C.sub.6 alkynyl,
C.sub.2-C.sub.6 haloalkynyl, C.sub.1-C.sub.6 alkoxy,
C.sub.1-C.sub.6 haloalkoxy, C.sub.3-C.sub.6 alkenyloxy,
C.sub.3-C.sub.6 haloalkenyloxy, C.sub.3-C.sub.6 alkynyloxy,
C.sub.3-C.sub.6 cycloalkoxy, C.sub.3-C.sub.6 halocycloalkoxy,
C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6 haloalkylthio,
C.sub.1-C.sub.6 alkylsulfinyl, C.sub.1-C.sub.6 haloalkylsulfinyl,
C.sub.1-C.sub.6 alkylsulfonyl and C.sub.1-C.sub.6
haloalkylsulfonyl;
[0832] p and q are independently selected from 0 and 1;
[0833] R.sup.5db is G.sup.14 wherein R.sup.37', R.sup.38',
R.sup.39', R.sup.40', R.sup.41', R.sup.42', R.sup.43' and R.sup.44'
are each hydrogen;
[0834] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, halogen, CN, NO.sub.2, OH, SH, CHO, C(.dbd.O)NH.sub.2,
C(.dbd.O)NH(CH.sub.3), C(.dbd.O)N(CH.sub.3).sub.2,
C(.dbd.S)NH.sub.2, C(.dbd.S)NH(CH.sub.3),
C(.dbd.S)N(CH.sub.3).sub.2, SO.sub.2NH.sub.2, SO.sub.2NH(CH.sub.3),
SO.sub.2N(CH.sub.3).sub.2, C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6
haloalkyl, C.sub.3-C.sub.6 cycloalkyl, C.sub.2-C.sub.6 alkenyl,
C.sub.2-C.sub.6 haloalkenyl, C.sub.2-C.sub.6 alkynyl,
C.sub.2-C.sub.6 haloalkynyl, C.sub.1-C.sub.6 alkoxy,
C.sub.1-C.sub.6 haloalkoxy, C.sub.3-C.sub.6 alkenyloxy,
C.sub.3-C.sub.6 haloalkenyloxy, C.sub.3-C.sub.6 alkynyloxy,
C.sub.3-C.sub.6 cycloalkoxy, C.sub.3-C.sub.6 halocycloalkoxy,
C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6 haloalkylthio,
C.sub.1-C.sub.6 alkylsulfinyl, C.sub.1-C.sub.6 haloalkylsulfinyl,
C.sub.1-C.sub.6 alkylsulfonyl and C.sub.1-C.sub.6
haloalkylsulfonyl;
[0835] p and q are independently selected from 0 and 1;
[0836] R.sup.5dc is G.sup.14 wherein R.sup.37' is selected
independently of each other from the group consisting of hydrogen,
halogen, cyano, C.sub.1-C.sub.4 alkyl and C.sub.1-C.sub.4
haloalkyl;
[0837] R.sup.38', R.sup.39', R.sup.40', R.sup.41', R.sup.42',
R.sup.43' and R.sup.44' are each hydrogen;
[0838] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, halogen, CN, NO.sub.2, OH, SH, CHO, C(.dbd.O)NH.sub.2,
C(.dbd.O)NH(CH.sub.3), C(.dbd.O)N(CH.sub.3).sub.2,
C(.dbd.S)NH.sub.2, C(.dbd.S)NH(CH.sub.3),
C(.dbd.S)N(CH.sub.3).sub.2, SO.sub.2NH.sub.2, SO.sub.2NH(CH.sub.3),
SO.sub.2N(CH.sub.3).sub.2, C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6
haloalkyl, C.sub.3-C.sub.6 cycloalkyl, C.sub.2-C.sub.6 alkenyl,
C.sub.2-C.sub.6 haloalkenyl, C.sub.2-C.sub.6 alkynyl,
C.sub.2-C.sub.6 haloalkynyl, C.sub.1-C.sub.6 alkoxy,
C.sub.1-C.sub.6 haloalkoxy, C.sub.3-C.sub.6 alkenyloxy,
C.sub.3-C.sub.6 haloalkenyloxy, C.sub.3-C.sub.6 alkynyloxy,
C.sub.3-C.sub.6 cycloalkoxy, C.sub.3-C.sub.6 halocycloalkoxy,
C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6 haloalkylthio,
C.sub.1-C.sub.6 alkylsulfinyl, C.sub.1-C.sub.6 haloalkylsulfinyl,
C.sub.1-C.sub.6 alkylsulfonyl and C.sub.1-C.sub.6
haloalkylsulfonyl;
[0839] p and q are independently selected from 0 and 1;
[0840] R.sup.5de is G.sup.14 wherein R.sup.37' and R.sup.38' are
selected independently of each other from the group consisting of
hydrogen, halogen, cyano, C.sub.1-C.sub.4 alkyl and C.sub.1-C.sub.4
haloalkyl;
[0841] R.sup.39', R.sup.40', R.sup.41', R.sup.42', R.sup.43', and
R.sup.44' are selected independently of each other from the group
consisting of hydrogen, halogen, hydroxy, cyano, C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 haloalkyl, C.sub.1-C.sub.4 alkoxy and
C.sub.1-C.sub.4 haloalkoxy and C.sub.1-C.sub.4 alkylthio;
[0842] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, F, Cl, Br, I, methyl, ethyl, isopropyl, cyclopropyl,
C.ident.CH, CH.dbd.CH.sub.2, C(CH.sub.3).dbd.CH.sub.2, CF.sub.3,
CHF.sub.2, CH.sub.2F, --CHF--CH.sub.3, --CF.sub.2--CH.sub.3,
methoxy, trifluoromethoxy, ethoxy, methlythio, methylsulfinyl and
methylsulfonyl;
[0843] p and q are independently selected from 0 and 1;
[0844] R.sup.5df is G.sup.14 wherein R.sup.37', R.sup.38',
R.sup.39', R.sup.40', R.sup.41', R.sup.42', R.sup.43' and R.sup.44'
are selected independently of each other from the group consisting
of hydrogen, halogen, methyl, ethyl, isopropyl, monofluoromethyl,
polyfluoromethyl, monofluoroethyl and polyfluoromethyl;
[0845] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, F, Cl, Br, I, methyl, ethyl, isopropyl, cyclopropyl,
C.ident.CH, CH.dbd.CH.sub.2, C(CH.sub.3).dbd.CH.sub.2, CF.sub.3,
CHF.sub.2, CH.sub.2F, --CHF--CH.sub.3, --CF.sub.2--CH.sub.3,
methoxy, trifluoromethoxy, ethoxy, methlythio, methylsulfinyl and
methylsulfonyl;
[0846] p and q are independently selected from 0 and 1;
[0847] R.sup.5dg is G.sup.14 wherein R.sup.37', R.sup.38',
R.sup.39', R.sup.40', R.sup.41', R.sup.42', R.sup.43' and R.sup.44'
are selected independently of each other from the group consisting
of hydrogen, fluorine, methyl, ethyl, isopropyl, CH.sub.2F,
CHF.sub.2, CF.sub.3, CHF--CH.sub.3, CF.sub.2--CH.sub.3,
CH.sub.2--CH.sub.2F CH.sub.2--CHF.sub.2 and CH.sub.2--CF.sub.3;
[0848] R.sup.45', R.sup.46, R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, F, Cl, Br, I, methyl, ethyl, isopropyl, cyclopropyl,
C.ident.CH, CH.dbd.CH.sub.2, C(CH.sub.3).dbd.CH.sub.2, CF.sub.3,
CHF.sub.2, CH.sub.2F, --CHF--CH.sub.3, --CF.sub.2--CH.sub.3,
methoxy, trifluoromethoxy, ethoxy, methlythio, methylsulfinyl and
methylsulfonyl;
[0849] p and q are independently selected from 0 and 1;
[0850] R.sup.5dh is G.sup.14 wherein R.sup.37', R.sup.38',
R.sup.39', R.sup.40', R.sup.41', R.sup.42', R.sup.43' and R.sup.44'
are selected independently of each other from the group consisting
of methyl, ethyl, F and CF.sub.3;
[0851] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, F, Cl, Br, I, methyl, ethyl, isopropyl, cyclopropyl,
C.ident.CH, CH.dbd.CH.sub.2, C(CH.sub.3).dbd.CH.sub.2, CF.sub.3,
CHF.sub.2, CH.sub.2F, --CHF--CH.sub.3, --CF.sub.2--CH.sub.3,
methoxy, trifluoromethoxy, ethoxy, methlythio, methylsulfinyl and
methylsulfonyl;
[0852] p and q are independently selected from 0 and 1;
[0853] R.sup.5di is G.sup.14 wherein R.sup.37', R.sup.38',
R.sup.39', R.sup.40', R.sup.41', R.sup.42', R.sup.43' and R.sup.44'
are each hydrogen;
[0854] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, F, Cl, Br, I, methyl, ethyl, isopropyl, cyclopropyl,
C.ident.CH, CH.dbd.CH.sub.2, C(CH.sub.3).dbd.CH.sub.2, CF.sub.3,
CHF.sub.2, CH.sub.2F, --CHF--CH.sub.3, --CF.sub.2--CH.sub.3,
methoxy, trifluoromethoxy, ethoxy, methlythio, methylsulfinyl and
methylsulfonyl;
[0855] p and q are independently selected from 0 and 1;
[0856] R.sup.5dj is G.sup.14 wherein R.sup.37' is selected
independently of each other from the group consisting of hydrogen,
halogen, cyano, C.sub.1-C.sub.4 alkyl and C.sub.1-C.sub.4
haloalkyl;
[0857] R.sup.38', R.sup.39', R.sup.40', R.sup.41', R.sup.42',
R.sup.43' and R.sup.44' are each hydrogen;
[0858] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, F, Cl, Br, I, methyl, ethyl, isopropyl, cyclopropyl,
C.ident.CH, CH.dbd.CH.sub.2, C(CH.sub.3).dbd.CH.sub.2, CF.sub.3,
CHF.sub.2, CH.sub.2F, --CHF--CH.sub.3, --CF.sub.2--CH.sub.3,
methoxy, trifluoromethoxy, ethoxy, methlythio, methylsulfinyl and
methylsulfonyl;
[0859] p and q are independently selected from 0 and 1;
[0860] R.sup.5dk is G.sup.14 wherein R.sup.37' and R.sup.38' are
selected independently of each other from the group consisting of
hydrogen, halogen, cyano, C.sub.1-C.sub.4 alkyl and C.sub.1-C.sub.4
haloalkyl;
[0861] R.sup.39', R.sup.40', R.sup.41', R.sup.42', R.sup.43' and
R.sup.44' are selected independently of each other from the group
consisting of hydrogen, halogen, hydroxy, cyano, C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 haloalkyl, C.sub.1-C.sub.4 alkoxy and
C.sub.1-C.sub.4 haloalkoxy and C.sub.1-C.sub.4 alkylthio;
[0862] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, F, Cl, methyl, CF.sub.3, CHF.sub.2, CH.sub.2F, methoxy
and trifluoromethoxy;
[0863] p and q are independently selected from 0 and 1;
[0864] R.sup.5dl is G.sup.14 wherein R.sup.37', R.sup.38',
R.sup.39', R.sup.40', R.sup.41', R.sup.42', R.sup.43' and R.sup.44'
are selected independently of each other from the group consisting
of hydrogen, halogen, methyl, ethyl, isopropyl, monofluoromethyl,
polyfluoromethyl, monofluoroethyl and polyfluoroethyl;
[0865] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, F, Cl, methyl, CF.sub.3, CHF.sub.2, CH.sub.2F, methoxy
and trifluoromethoxy;
[0866] p and q are independently selected from 0 and 1;
[0867] R.sup.5dm is G.sup.14 wherein R.sup.37', R.sup.38',
R.sup.39', R.sup.40', R.sup.41', R.sup.42', R.sup.43' and R.sup.44'
are selected independently of each other from the group consisting
of hydrogen, fluorine, methyl, ethyl, isopropyl, CH.sub.2F,
CHF.sub.2, CF.sub.3, CHF--CH.sub.3, CF.sub.2--CH.sub.3,
CH.sub.2--CH.sub.2F CH.sub.2--CHF.sub.2 and CH.sub.2--CF.sub.3;
[0868] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, F, Cl, methyl, CF.sub.3, CHF.sub.2, CH.sub.2F, methoxy
and trifluoromethoxy;
[0869] p and q are independently selected from 0 and 1;
[0870] R.sup.5dn is G.sup.14 wherein R.sup.37', R.sup.38',
R.sup.39', R.sup.40', R.sup.41', R.sup.42', R.sup.43' and R.sup.44'
are selected independently of each other from the group consisting
of methyl, ethyl, F and CF.sub.3;
[0871] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, F, Cl, methyl, CF.sub.3, CHF.sub.2, CH.sub.2F, methoxy
and trifluoromethoxy;
[0872] p and q are independently selected from 0 and 1;
[0873] R.sup.5do is G.sup.14 wherein R.sup.37', R.sup.38',
R.sup.39', R.sup.40', R.sup.41', R.sup.42', R.sup.43' and R.sup.44'
are each hydrogen;
[0874] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, F, Cl, methyl, CF.sub.3, CHF.sub.2, CH.sub.2F, methoxy
and trifluoromethoxy; p and q are independently selected from 0 and
1;
[0875] R.sup.5dp is G.sup.14 wherein R.sup.37' is selected from the
group consisting of hydrogen, halogen, cyano, C.sub.1-C.sub.4 alkyl
and C.sub.1-C.sub.4 haloalkyl;
[0876] R.sup.38', R.sup.39', R.sup.40, R.sup.41', R.sup.42',
R.sup.43' and R.sup.44' are each hydrogen;
[0877] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, F, Cl, methyl, CF.sub.3, CHF.sub.2, CH.sub.2F, methoxy
and trifluoromethoxy;
[0878] p and q are independently selected from 0 and 1;
[0879] R.sup.5dq is G.sup.14 wherein R.sup.37' and R.sup.38' are
selected independently of each other from the group consisting of
hydrogen, halogen, cyano, C.sub.1-C.sub.4 alkyl and C.sub.1-C.sub.4
haloalkyl;
[0880] R.sup.39', R.sup.40', R.sup.41', R.sup.42', R.sup.43' and
R.sup.44' are selected independently of each other from the group
consisting of hydrogen, halogen, hydroxy, cyano, C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 haloalkyl, C.sub.1-C.sub.4 alkoxy, and
C.sub.1-C.sub.4 haloalkoxy and C.sub.1-C.sub.4 alkylthio;
[0881] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, halogen, CN, NO.sub.2, OH, SH, CHO, C(.dbd.O)NH.sub.2,
C(.dbd.O)NH(CH.sub.3), C(.dbd.O)N(CH.sub.3).sub.2,
C(.dbd.S)NH.sub.2, C(.dbd.S)NH(CH.sub.3),
C(.dbd.S)N(CH.sub.3).sub.2, SO.sub.2NH.sub.2, SO.sub.2NH(CH.sub.3),
SO.sub.2N(CH.sub.3).sub.2, C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6
haloalkyl, C.sub.3-C.sub.6 cycloalkyl, C.sub.2-C.sub.6 alkenyl,
C.sub.2-C.sub.6 haloalkenyl, C.sub.2-C.sub.6 alkynyl,
C.sub.2-C.sub.6 haloalkynyl, C.sub.1-C.sub.6 alkoxy,
C.sub.1-C.sub.6 haloalkoxy, C.sub.3-C.sub.6 alkenyloxy,
C.sub.3-C.sub.6 haloalkenyloxy, C.sub.3-C.sub.6 alkynyloxy,
C.sub.3-C.sub.6 cycloalkoxy, C.sub.3-C.sub.6 halocycloalkoxy,
C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6 haloalkylthio,
C.sub.1-C.sub.6 alkylsulfinyl, C.sub.1-C.sub.6 haloalkylsulfinyl,
C.sub.1-C.sub.6 alkylsulfonyl and C.sub.1-C.sub.6
haloalkylsulfonyl;
[0882] p and q are each 0;
[0883] R.sup.5dr is G.sup.14 wherein R.sup.37', R.sup.38',
R.sup.39', R.sup.40', R.sup.41', R.sup.42', R.sup.43' and R.sup.44'
are selected independently of each other from the group consisting
of hydrogen, halogen, methyl, ethyl, isopropyl, monofluoromethyl,
polyfluoromethyl, monofluoroethyl and polyfluoroethyl;
[0884] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, halogen, CN, NO.sub.2, OH, SH, CHO, C(.dbd.O)NH.sub.2,
C(.dbd.O)NH(CH.sub.3), C(.dbd.O)N(CH.sub.3).sub.2,
C(.dbd.S)NH.sub.2, C(.dbd.S)NH(CH.sub.3),
C(.dbd.S)N(CH.sub.3).sub.2, SO.sub.2NH.sub.2, SO.sub.2NH(CH.sub.3),
SO.sub.2N(CH.sub.3).sub.2, C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6
haloalkyl, C.sub.3-C.sub.6 cycloalkyl, C.sub.2-C.sub.6 alkenyl,
C.sub.2-C.sub.6 haloalkenyl, C.sub.2-C.sub.6 alkynyl,
C.sub.2-C.sub.6 haloalkynyl, C.sub.1-C.sub.6 alkoxy,
C.sub.1-C.sub.6 haloalkoxy, C.sub.3-C.sub.6 alkenyloxy,
C.sub.3-C.sub.6 haloalkenyloxy, C.sub.3-C.sub.6 alkynyloxy,
C.sub.3-C.sub.6 cycloalkoxy, C.sub.3-C.sub.6 halocycloalkoxy,
C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6 haloalkylthio,
C.sub.1-C.sub.6 alkylsulfinyl, C.sub.1-C.sub.6 haloalkylsulfinyl,
C.sub.1-C.sub.6 alkylsulfonyl and C.sub.1-C.sub.6
haloalkylsulfonyl;
[0885] p and q are each 0;
[0886] R.sup.5ds is G.sup.14 wherein R.sup.37', R.sup.38',
R.sup.39', R.sup.40', R.sup.41', R.sup.42', R.sup.43' and R.sup.44'
are selected independently of each other from the group consisting
of hydrogen, fluorine, methyl, ethyl, isopropyl, CH.sub.2F,
CHF.sub.2, CF.sub.3, CHF--CH.sub.3, CF.sub.2--CH.sub.3,
CH.sub.2--CH.sub.2F CH.sub.2--CHF.sub.2 and CH.sub.2--CF.sub.3;
[0887] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, halogen, CN, NO.sub.2, OH, SH, CHO, C(.dbd.O)NH.sub.2,
C(.dbd.O)NH(CH.sub.3), C(.dbd.O)N(CH.sub.3).sub.2,
C(.dbd.S)NH.sub.2, C(.dbd.S)NH(CH.sub.3),
C(.dbd.S)N(CH.sub.3).sub.2, SO.sub.2NH.sub.2, SO.sub.2NH(CH.sub.3),
SO.sub.2N(CH.sub.3).sub.2, C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6
haloalkyl, C.sub.3-C.sub.6 cycloalkyl, C.sub.2-C.sub.6 alkenyl,
C.sub.2-C.sub.6 haloalkenyl, C.sub.2-C.sub.6 alkynyl,
C.sub.2-C.sub.6 haloalkynyl, C.sub.1-C.sub.6 alkoxy,
C.sub.1-C.sub.6 haloalkoxy, C.sub.3-C.sub.6 alkenyloxy,
C.sub.3-C.sub.6 haloalkenyloxy, C.sub.3-C.sub.6 alkynyloxy,
C.sub.3-C.sub.6 cycloalkoxy, C.sub.3-C.sub.6 halocycloalkoxy,
C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6 haloalkylthio,
C.sub.1-C.sub.6 alkylsulfinyl, C.sub.1-C.sub.6 haloalkylsulfinyl,
C.sub.1-C.sub.6 alkylsulfonyl and C.sub.1-C.sub.6
haloalkylsulfonyl;
[0888] p and q are each 0;
[0889] R.sup.5dt is G.sup.14 wherein R.sup.37', R.sup.38',
R.sup.39, R.sup.40', R.sup.41', R.sup.42', R.sup.43' and R.sup.44'
are selected independently of each other from the group consisting
of methyl, ethyl, F and CF.sub.3;
[0890] R.sup.45', R.sup.46, R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, halogen, CN, NO.sub.2, OH, SH, CHO, C(.dbd.O)NH.sub.2,
C(.dbd.O)NH(CH.sub.3), C(.dbd.O)N(CH.sub.3).sub.2,
C(.dbd.S)NH.sub.2, C(.dbd.S)NH(CH.sub.3),
C(.dbd.S)N(CH.sub.3).sub.2, SO.sub.2NH.sub.2, SO.sub.2NH(CH.sub.3),
SO.sub.2N(CH.sub.3).sub.2, C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6
haloalkyl, C.sub.3-C.sub.6 cycloalkyl, C.sub.2-C.sub.6 alkenyl,
C.sub.2-C.sub.6 haloalkenyl, C.sub.2-C.sub.6 alkynyl,
C.sub.2-C.sub.6 haloalkynyl, C.sub.1-C.sub.6 alkoxy,
C.sub.1-C.sub.6 haloalkoxy, C.sub.3-C.sub.6 alkenyloxy,
C.sub.3-C.sub.6 haloalkenyloxy, C.sub.3-C.sub.6 alkynyloxy,
C.sub.3-C.sub.6 cycloalkoxy, C.sub.3-C.sub.6 halocycloalkoxy,
C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6 haloalkylthio,
C.sub.1-C.sub.6 alkylsulfinyl, C.sub.1-C.sub.6 haloalkylsulfinyl,
C.sub.1-C.sub.6 alkylsulfonyl and C.sub.1-C.sub.6
haloalkylsulfonyl;
[0891] p and q are each 0;
[0892] R.sup.5du is G.sup.14 wherein R.sup.37', R.sup.38',
R.sup.39', R.sup.40', R.sup.41', R.sup.42', R.sup.43' and R.sup.44'
are each hydrogen;
[0893] R.sup.45', R.sup.46, R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, halogen, CN, NO.sub.2, OH, SH, CHO, C(.dbd.O)NH.sub.2,
C(.dbd.O)NH(CH.sub.3), C(.dbd.O)N(CH.sub.3).sub.2,
C(.dbd.S)NH.sub.2, C(.dbd.S)NH(CH.sub.3),
C(.dbd.S)N(CH.sub.3).sub.2, SO.sub.2NH.sub.2, SO.sub.2NH(CH.sub.3),
SO.sub.2N(CH.sub.3).sub.2, C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6
haloalkyl, C.sub.3-C.sub.6 cycloalkyl, C.sub.2-C.sub.6 alkenyl,
C.sub.2-C.sub.6 haloalkenyl, C.sub.2-C.sub.6 alkynyl,
C.sub.2-C.sub.6 haloalkynyl, C.sub.1-C.sub.6 alkoxy,
C.sub.1-C.sub.6 haloalkoxy, C.sub.3-C.sub.6 alkenyloxy,
C.sub.3-C.sub.6 haloalkenyloxy, C.sub.3-C.sub.6 alkynyloxy,
C.sub.3-C.sub.6 cycloalkoxy, C.sub.3-C.sub.6 halocycloalkoxy,
C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6 haloalkylthio,
C.sub.1-C.sub.6 alkylsulfinyl, C.sub.1-C.sub.6 haloalkylsulfinyl,
C.sub.1-C.sub.6 alkylsulfonyl and C.sub.1-C.sub.6
haloalkylsulfonyl;
[0894] p and q are each 0;
[0895] R.sup.5dv is G.sup.14 wherein R.sup.37' is selected from the
group consisting of hydrogen, halogen, cyano, C.sub.1-C.sub.4 alkyl
and C.sub.1-C.sub.4 haloalkyl;
[0896] R.sup.38', R.sup.39', R.sup.40', R.sup.41', R.sup.42',
R.sup.43' and R.sup.44' are each hydrogen;
[0897] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, halogen, CN, NO.sub.2, OH, SH, CHO, C(.dbd.O)NH.sub.2,
C(.dbd.O)NH(CH.sub.3), C(.dbd.O)N(CH.sub.3).sub.2,
C(.dbd.S)NH.sub.2, C(.dbd.S)NH(CH.sub.3),
C(.dbd.S)N(CH.sub.3).sub.2, SO.sub.2NH.sub.2, SO.sub.2NH(CH.sub.3),
SO.sub.2N(CH.sub.3).sub.2, C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6
haloalkyl, C.sub.3-C.sub.6 cycloalkyl, C.sub.2-C.sub.6 alkenyl,
C.sub.2-C.sub.6 haloalkenyl, C.sub.2-C.sub.6 alkynyl,
C.sub.2-C.sub.6 haloalkynyl, C.sub.1-C.sub.6 alkoxy,
C.sub.1-C.sub.6 haloalkoxy, C.sub.3-C.sub.6 alkenyloxy,
C.sub.3-C.sub.6 haloalkenyloxy, C.sub.3-C.sub.6 alkynyloxy,
C.sub.3-C.sub.6 cycloalkoxy, C.sub.3-C.sub.6 halocycloalkoxy,
C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6 haloalkylthio,
C.sub.1-C.sub.6 alkylsulfinyl, C.sub.1-C.sub.6 haloalkylsulfinyl,
C.sub.1-C.sub.6 alkylsulfonyl and C.sub.1-C.sub.6
haloalkylsulfonyl;
[0898] p and q are each 0;
[0899] R.sup.5dw is G.sup.14 wherein R.sup.37' and R.sup.37' are
selected independently of each other from the group consisting of
hydrogen, halogen, cyano, C.sub.1-C.sub.4 alkyl and C.sub.1-C.sub.4
haloalkyl;
[0900] R.sup.39', R.sup.40', R.sup.41', R.sup.42', R.sup.43' and
R.sup.44' are selected independently of each other from the group
consisting of hydrogen, halogen, hydroxy, cyano, C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 haloalkyl, C.sub.1-C.sub.4 alkoxy,
C.sub.1-C.sub.4 haloalkoxy and C.sub.1-C.sub.4 alkylthio;
[0901] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, F, Cl, Br, I, methyl, ethyl, isopropyl, cyclopropyl,
C.ident.CH, CH.dbd.CH.sub.2, C(CH.sub.3).dbd.CH.sub.2, CF.sub.3,
CHF.sub.2, CH.sub.2F, --CHF--CH.sub.3, --CF.sub.2--CH.sub.3,
methoxy, trifluoromethoxy, ethoxy, methlythio, methylsulfinyl and
methylsulfonyl;
[0902] p and q are each 0;
[0903] R.sup.5dx is G.sup.14 wherein R.sup.37', R.sup.38',
R.sup.39', R.sup.40', R.sup.41', R.sup.42', R.sup.43' and R.sup.44'
are selected independently of each other from the group consisting
of hydrogen, halogen, methyl, ethyl, isopropyl, monofluoromethyl,
polyfluoromethyl, monofluoroethyl and polyfluoroethyl;
[0904] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, F, Cl, Br, I, methyl, ethyl, isopropyl, cyclopropyl,
C.ident.CH, CH.dbd.CH.sub.2, C(CH.sub.3).dbd.CH.sub.2, CF.sub.3,
CHF.sub.2, CH.sub.2F, --CHF--CH.sub.3, --CF.sub.2--CH.sub.3,
methoxy, trifluoromethoxy, ethoxy, methlythio, methylsulfinyl and
methylsulfonyl;
[0905] p and q are each 0;
[0906] R.sup.5ea is G.sup.14 wherein R.sup.37', R.sup.38',
R.sup.39', R.sup.40', R.sup.41', R.sup.42', R.sup.43' and R.sup.44'
are selected independently of each other from the group consisting
of hydrogen, fluorine, methyl, ethyl, isopropyl, CH.sub.2F,
CHF.sub.2, CF.sub.3, CHF--CH.sub.3, CF.sub.2--CH.sub.3,
CH.sub.2--CH.sub.2F CH.sub.2--CHF.sub.2 and CH.sub.2--CF.sub.3;
[0907] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, F, Cl, Br, I, methyl, ethyl, isopropyl, cyclopropyl,
C.ident.CH, CH.dbd.CH.sub.2, C(CH.sub.3).dbd.CH.sub.2, CF.sub.3,
CHF.sub.2, CH.sub.2F, --CHF--CH.sub.3, --CF.sub.2--CH.sub.3,
methoxy, trifluoromethoxy, ethoxy, methlythio, methylsulfinyl and
methylsulfonyl;
[0908] p and q are each 0;
[0909] R.sup.5eb is G.sup.14 wherein R.sup.37', R.sup.38',
R.sup.39', R.sup.40', R.sup.41', R.sup.42', R.sup.43' and R.sup.44'
are selected independently from each other from the group
consisting of methyl, ethyl, F and CF.sub.3;
[0910] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, F, Cl, Br, I, methyl, ethyl, isopropyl, cyclopropyl,
C.ident.CH, CH.dbd.CH.sub.2, C(CH.sub.3).dbd.CH.sub.2, CF.sub.3,
CHF.sub.2, CH.sub.2F, --CHF--CH.sub.3, --CF.sub.2--CH.sub.3,
methoxy, trifluoromethoxy, ethoxy, methlythio, methylsulfinyl and
methylsulfonyl;
[0911] p and q are each 0;
[0912] R.sup.5ec is G.sup.14 wherein R.sup.37', R.sup.38',
R.sup.39', R.sup.40', R.sup.41', R.sup.42', R.sup.43' and R.sup.44'
are each hydrogen;
[0913] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, F, Cl, Br, I, methyl, ethyl, isopropyl, cyclopropyl,
C.ident.CH, CH.dbd.CH.sub.2, C(CH.sub.3).dbd.CH.sub.2, CF.sub.3,
CHF.sub.2, CH.sub.2F, --CHF--CH.sub.3, --CF.sub.2--CH.sub.3,
methoxy, trifluoromethoxy, ethoxy, methlythio, methylsulfinyl and
methylsulfonyl;
[0914] p and q are each 0;
[0915] R.sup.5ed is G.sup.14 wherein R.sup.37' is selected from the
group consisting of hydrogen, halogen, cyano, C.sub.1-C.sub.4 alkyl
and C.sub.1-C.sub.4 haloalkyl;
[0916] R.sup.38', R.sup.39', R.sup.40', R.sup.41', R.sup.42',
R.sup.43' and R.sup.44' are each hydrogen;
[0917] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, F, Cl, Br, I, methyl, ethyl, isopropyl, cyclopropyl,
C.ident.CH, CH.dbd.CH.sub.2, C(CH.sub.3).dbd.CH.sub.2, CF.sub.3,
CHF.sub.2, CH.sub.2F, --CHF--CH.sub.3, --CF.sub.2--CH.sub.3,
methoxy, trifluoromethoxy, ethoxy, methlythio, methylsulfinyl and
methylsulfonyl;
[0918] p and q are each 0;
[0919] R.sup.5ef is G.sup.14 wherein R.sup.37' and R.sup.38' are
selected independently of each other from the group consisting of
hydrogen, halogen, cyano, C.sub.1-C.sub.4 alkyl and C.sub.1-C.sub.4
haloalkyl;
[0920] R.sup.39', R.sup.40', R.sup.41', R.sup.42', R.sup.43' and
R.sup.44' are selected independently of each other from the group
consisting of hydrogen, halogen, hydroxy, cyano, C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 haloalkyl, C.sub.1-C.sub.4 alkoxy,
C.sub.1-C.sub.4 haloalkoxy and C.sub.1-C.sub.4 alkylthio;
[0921] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, F, Cl, methyl, CF.sub.3, CHF.sub.2, CH.sub.2F, methoxy
and trifluoromethoxy;
[0922] p and q are each 0;
[0923] R.sup.5eg is G.sup.14 wherein R.sup.37', R.sup.38',
R.sup.39', R.sup.40', R.sup.41', R.sup.42', R.sup.43' and R.sup.44'
are selected independently of each other from the group consisting
of hydrogen, halogen, methyl, ethyl, isopropyl, monofluoromethyl,
polyfluoromethyl, monofluoroethyl and polyfluoroethyl;
[0924] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, F, Cl, methyl, CF.sub.3, CHF.sub.2, CH.sub.2F, methoxy
and trifluoromethoxy;
[0925] p and q are each 0;
[0926] R.sup.5eh is G.sup.14 wherein R.sup.37', R.sup.38',
R.sup.39', R.sup.40', R.sup.41', R.sup.42', R.sup.43' and R.sup.44'
are selected independently of each other from the group consisting
of hydrogen, fluorine, methyl, ethyl, isopropyl, CH.sub.2F,
CHF.sub.2, CF.sub.3, CHF--CH.sub.3, CF.sub.2--CH.sub.3,
CH.sub.2--CH.sub.2F CH.sub.2--CHF.sub.2 and CH.sub.2--CF.sub.3;
[0927] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, F, Cl, methyl, CF.sub.3, CHF.sub.2, CH.sub.2F, methoxy
and trifluoromethoxy;
[0928] p and q are each 0;
[0929] R.sup.5ei is G.sup.14 wherein R.sup.37', R.sup.38',
R.sup.39', R.sup.40', R.sup.41', R.sup.42', R.sup.43' and R.sup.44'
are selected independently of each other from the group consisting
of methyl, ethyl, F and CF.sub.3;
[0930] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, F, Cl, methyl, CF.sub.3, CHF.sub.2, CH.sub.2F, methoxy
and trifluoromethoxy;
[0931] p and q are each 0;
[0932] R.sup.5ej is G.sup.14 wherein R.sup.37', R.sup.38',
R.sup.39', R.sup.40, R.sup.41', R.sup.42', R.sup.43' and R.sup.44'
are each hydrogen;
[0933] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, F, Cl, methyl, CF.sub.3, CHF.sub.2, CH.sub.2F, methoxy
and trifluoromethoxy;
[0934] p and q are each 0;
[0935] R.sup.5ek is G.sup.14 wherein R.sup.37' is selected from the
group consisting of hydrogen, halogen, cyano, C.sub.1-C.sub.4 alkyl
and C.sub.1-C.sub.4 haloalkyl;
[0936] R.sup.38', R.sup.39', R.sup.40', R.sup.41', R.sup.42',
R.sup.43' and R.sup.44' are each hydrogen;
[0937] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, F, Cl, methyl, CF.sub.3, CHF.sub.2, CH.sub.2F, methoxy
and trifluoromethoxy;
[0938] p is 0;
[0939] q is 1;
[0940] R.sup.5el is G.sup.14 wherein R.sup.37' and R.sup.38' are
selected independently of each other from the group consisting of
hydrogen, halogen, cyano, C.sub.1-C.sub.4 alkyl and C.sub.1-C.sub.4
haloalkyl;
[0941] R.sup.39', R.sup.40', R.sup.41', R.sup.42', R.sup.43' and
R.sup.44' are selected independently of each other from the group
consisting of hydrogen, halogen, hydroxy, cyano, C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 haloalkyl, C.sub.1-C.sub.4 alkoxy,
C.sub.1-C.sub.4 haloalkoxy and C.sub.1-C.sub.4 alkylthio;
[0942] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, halogen, CN, NO.sub.2, OH, SH, CHO, C(.dbd.O)NH.sub.2,
C(.dbd.O)NH(CH.sub.3), C(.dbd.O)N(CH.sub.3).sub.2,
C(.dbd.S)NH.sub.2, C(.dbd.S)NH(CH.sub.3),
C(.dbd.S)N(CH.sub.3).sub.2, SO.sub.2NH.sub.2, SO.sub.2NH(CH.sub.3),
SO.sub.2N(CH.sub.3).sub.2, C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6
haloalkyl, C.sub.3-C.sub.6 cycloalkyl, C.sub.2-C.sub.6 alkenyl,
C.sub.2-C.sub.6 haloalkenyl, C.sub.2-C.sub.6 alkynyl,
C.sub.2-C.sub.6 haloalkynyl, C.sub.1-C.sub.6 alkoxy,
C.sub.1-C.sub.6 haloalkoxy, C.sub.3-C.sub.6 alkenyloxy,
C.sub.3-C.sub.6 haloalkenyloxy, C.sub.3-C.sub.6 alkynyloxy,
C.sub.3-C.sub.6 cycloalkoxy, C.sub.3-C.sub.6 halocycloalkoxy,
C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6 haloalkylthio,
C.sub.1-C.sub.6 alkylsulfinyl, C.sub.1-C.sub.6 haloalkylsulfinyl,
C.sub.1-C.sub.6 alkylsulfonyl and C.sub.1-C.sub.6
haloalkylsulfonyl;
[0943] p is 0;
[0944] q is 1;
[0945] R.sup.5em is G.sup.14 wherein R.sup.37', R.sup.38',
R.sup.39', R.sup.40', R.sup.41', R.sup.42', R.sup.43' and R.sup.44'
are selected independently of each other from the group consisting
of hydrogen, halogen, methyl, ethyl, isopropyl, monofluoromethyl,
polyfluoromethyl, monofluoroethyl and polyfluoroethyl;
[0946] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, halogen, CN, NO.sub.2, OH, SH, CHO, C(.dbd.O)NH.sub.2,
C(.dbd.O)NH(CH.sub.3), C(.dbd.O)N(CH.sub.3).sub.2,
C(.dbd.S)NH.sub.2, C(.dbd.S)NH(CH.sub.3),
C(.dbd.S)N(CH.sub.3).sub.2, SO.sub.2NH.sub.2, SO.sub.2NH(CH.sub.3),
SO.sub.2N(CH.sub.3).sub.2, C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6
haloalkyl, C.sub.3-C.sub.6 cycloalkyl, C.sub.2-C.sub.6 alkenyl,
C.sub.2-C.sub.6 haloalkenyl, C.sub.2-C.sub.6 alkynyl,
C.sub.2-C.sub.6 haloalkynyl, C.sub.1-C.sub.6 alkoxy,
C.sub.1-C.sub.6 haloalkoxy, C.sub.3-C.sub.6 alkenyloxy,
C.sub.3-C.sub.6 haloalkenyloxy, C.sub.3-C.sub.6 alkynyloxy,
C.sub.3-C.sub.6 cycloalkoxy, C.sub.3-C.sub.6 halocycloalkoxy,
C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6 haloalkylthio,
C.sub.1-C.sub.6 alkylsulfinyl, C.sub.1-C.sub.6 haloalkylsulfinyl,
C.sub.1-C.sub.6 alkylsulfonyl and C.sub.1-C.sub.6
haloalkylsulfonyl;
[0947] p is 0;
[0948] q is 1;
[0949] R.sup.5en is G.sup.14 wherein R.sup.37', R.sup.38',
R.sup.39', R.sup.40, R.sup.41', R.sup.42', R.sup.43' and R.sup.44'
are selected independently of each other from the group consisting
of hydrogen, fluorine, methyl, ethyl, isopropyl, CH.sub.2F,
CHF.sub.2, CF.sub.3, CHF--CH.sub.3, CF.sub.2--CH.sub.3,
CH.sub.2--CH.sub.2F CH.sub.2--CHF.sub.2 and CH.sub.2--CF.sub.3;
[0950] R.sup.45', R.sup.46, R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, halogen, CN, NO.sub.2, OH, SH, CHO, C(.dbd.O)NH.sub.2,
C(.dbd.O)NH(CH.sub.3), C(.dbd.O)N(CH.sub.3).sub.2,
C(.dbd.S)NH.sub.2, C(.dbd.S)NH(CH.sub.3),
C(.dbd.S)N(CH.sub.3).sub.2, SO.sub.2NH.sub.2, SO.sub.2NH(CH.sub.3),
SO.sub.2N(CH.sub.3).sub.2, C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6
haloalkyl, C.sub.3-C.sub.6 cycloalkyl, C.sub.2-C.sub.6 alkenyl,
C.sub.2-C.sub.6 haloalkenyl, C.sub.2-C.sub.6 alkynyl,
C.sub.2-C.sub.6 haloalkynyl, C.sub.1-C.sub.6 alkoxy,
C.sub.1-C.sub.6 haloalkoxy, C.sub.3-C.sub.6 alkenyloxy,
C.sub.3-C.sub.6 haloalkenyloxy, C.sub.3-C.sub.6 alkynyloxy,
C.sub.3-C.sub.6 cycloalkoxy, C.sub.3-C.sub.6 halocycloalkoxy,
C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6 haloalkylthio,
C.sub.1-C.sub.6 alkylsulfinyl, C.sub.1-C.sub.6 haloalkylsulfinyl,
C.sub.1-C.sub.6 alkylsulfonyl and C.sub.1-C.sub.6
haloalkylsulfonyl;
[0951] p is 0;
[0952] q is 1;
[0953] R.sup.5eo is G.sup.14 wherein R.sup.37', R.sup.38',
R.sup.39', R.sup.40', R.sup.41', R.sup.42, R.sup.43' and R.sup.44'
are independently selected of each other from the group consisting
of methyl, ethyl, F and CF.sub.3;
[0954] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, halogen, CN, NO.sub.2, OH, SH, CHO, C(.dbd.O)NH.sub.2,
C(.dbd.O)NH(CH.sub.3), C(.dbd.O)N(CH.sub.3).sub.2,
C(.dbd.S)NH.sub.2, C(.dbd.S)NH(CH.sub.3),
C(.dbd.S)N(CH.sub.3).sub.2, SO.sub.2NH.sub.2, SO.sub.2NH(CH.sub.3),
SO.sub.2N(CH.sub.3).sub.2, C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6
haloalkyl, C.sub.3-C.sub.6 cycloalkyl, C.sub.2-C.sub.6 alkenyl,
C.sub.2-C.sub.6 haloalkenyl, C.sub.2-C.sub.6 alkynyl,
C.sub.2-C.sub.6 haloalkynyl, C.sub.1-C.sub.6 alkoxy,
C.sub.1-C.sub.6 haloalkoxy, C.sub.3-C.sub.6 alkenyloxy,
C.sub.3-C.sub.6 haloalkenyloxy, C.sub.3-C.sub.6 alkynyloxy,
C.sub.3-C.sub.6 cycloalkoxy, C.sub.3-C.sub.6 halocycloalkoxy,
C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6 haloalkylthio,
C.sub.1-C.sub.6 alkylsulfinyl, C.sub.1-C.sub.6 haloalkylsulfinyl,
C.sub.1-C.sub.6 alkylsulfonyl and C.sub.1-C.sub.6
haloalkylsulfonyl;
[0955] p is 0;
[0956] q is 1;
[0957] R.sup.5ep is G.sup.14 wherein R.sup.37', R.sup.38',
R.sup.39', R.sup.40', R.sup.41, R.sup.42, R.sup.43' and R.sup.44'
are each hydrogen;
[0958] R.sup.45', R.sup.46, R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, halogen, CN, NO.sub.2, OH, SH, CHO, C(.dbd.O)NH.sub.2,
C(.dbd.O)NH(CH.sub.3), C(.dbd.O)N(CH.sub.3).sub.2,
C(.dbd.S)NH.sub.2, C(.dbd.S)NH(CH.sub.3),
C(.dbd.S)N(CH.sub.3).sub.2, SO.sub.2NH.sub.2, SO.sub.2NH(CH.sub.3),
SO.sub.2N(CH.sub.3).sub.2, C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6
haloalkyl, C.sub.3-C.sub.6 cycloalkyl, C.sub.2-C.sub.6 alkenyl,
C.sub.2-C.sub.6 haloalkenyl, C.sub.2-C.sub.6 alkynyl,
C.sub.2-C.sub.6 haloalkynyl, C.sub.1-C.sub.6 alkoxy,
C.sub.1-C.sub.6 haloalkoxy, C.sub.3-C.sub.6 alkenyloxy,
C.sub.3-C.sub.6 haloalkenyloxy, C.sub.3-C.sub.6 alkynyloxy,
C.sub.3-C.sub.6 cycloalkoxy, C.sub.3-C.sub.6 halocycloalkoxy,
C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6 haloalkylthio,
C.sub.1-C.sub.6 alkylsulfinyl, C.sub.1-C.sub.6 haloalkylsulfinyl,
C.sub.1-C.sub.6 alkylsulfonyl and C.sub.1-C.sub.6
haloalkylsulfonyl;
[0959] p is 0;
[0960] q is 1;
[0961] R.sup.5eq is G.sup.14 wherein R.sup.37' is selected from the
group consisting of hydrogen, halogen, cyano, C.sub.1-C.sub.4 alkyl
and C.sub.1-C.sub.4 haloalkyl;
[0962] R.sup.38', R.sup.39', R.sup.40', R.sup.41', R.sup.42',
R.sup.43' and R.sup.44' are each hydrogen;
[0963] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, halogen, CN, NO.sub.2, OH, SH, CHO, C(.dbd.O)NH.sub.2,
C(.dbd.O)NH(CH.sub.3), C(.dbd.O)N(CH.sub.3).sub.2,
C(.dbd.S)NH.sub.2, C(.dbd.S)NH(CH.sub.3),
C(.dbd.S)N(CH.sub.3).sub.2, SO.sub.2NH.sub.2, SO.sub.2NH(CH.sub.3),
SO.sub.2N(CH.sub.3).sub.2, C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6
haloalkyl, C.sub.3-C.sub.6 cycloalkyl, C.sub.2-C.sub.6 alkenyl,
C.sub.2-C.sub.6 haloalkenyl, C.sub.2-C.sub.6 alkynyl,
C.sub.2-C.sub.6 haloalkynyl, C.sub.1-C.sub.6 alkoxy,
C.sub.1-C.sub.6 haloalkoxy, C.sub.3-C.sub.6 alkenyloxy,
C.sub.3-C.sub.6 haloalkenyloxy, C.sub.3-C.sub.6 alkynyloxy,
C.sub.3-C.sub.6 cycloalkoxy, C.sub.3-C.sub.6 halocycloalkoxy,
C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6 haloalkylthio,
C.sub.1-C.sub.6 alkylsulfinyl, C.sub.1-C.sub.6 haloalkylsulfinyl,
C.sub.1-C.sub.6 alkylsulfonyl and C.sub.1-C.sub.6
haloalkylsulfonyl;
[0964] p is 0;
[0965] q is 1;
[0966] R.sup.5er is G.sup.14 wherein R.sup.37' and R.sup.38' are
selected independently of each other from the group consisting of
hydrogen, halogen, cyano, C.sub.1-C.sub.4 alkyl and C.sub.1-C.sub.4
haloalkyl;
[0967] R.sup.39', R.sup.40', R.sup.41', R.sup.42', R.sup.43' and
R.sup.44' are selected independently of each other from the group
consisting of hydrogen, halogen, hydroxy, cyano, C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 haloalkyl, C.sub.1-C.sub.4 alkoxy,
C.sub.1-C.sub.4 haloalkoxy and C.sub.1-C.sub.4 alkylthio;
[0968] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, F, Cl, Br, I, methyl, ethyl, isopropyl, cyclopropyl,
C.ident.CH, CH.dbd.CH.sub.2, C(CH.sub.3).dbd.CH.sub.2, CF.sub.3,
CHF.sub.2, CH.sub.2F, --CHF--CH.sub.3, --CF.sub.2--CH.sub.3,
methoxy, trifluoromethoxy, ethoxy, methlythio, methylsulfinyl and
methylsulfonyl;
[0969] p is 0;
[0970] q is 1;
[0971] R.sup.5es is G.sup.14 wherein R.sup.37', R.sup.38',
R.sup.39', R.sup.40', R.sup.41', R.sup.42', R.sup.43' and R.sup.44'
are selected independently of each other from the group consisting
of hydrogen, halogen, methyl, ethyl, isopropyl, monofluoromethyl,
polyfluoromethyl, monofluoroethyl and polyfluoroethyl;
[0972] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, F, Cl, Br, I, methyl, ethyl, isopropyl, cyclopropyl,
C.ident.CH, CH.dbd.CH.sub.2, C(CH.sub.3).dbd.CH.sub.2, CF.sub.3,
CHF.sub.2, CH.sub.2F, --CHF--CH.sub.3, --CF.sub.2--CH.sub.3,
methoxy, trifluoromethoxy, ethoxy, methlythio, methylsulfinyl and
methylsulfonyl;
[0973] p is 0;
[0974] q is 1;
[0975] R.sup.5et is G.sup.14 wherein R.sup.37', R.sup.38',
R.sup.39, R.sup.40', R.sup.41', R.sup.42', R.sup.43' and R.sup.44'
are selected independently of each other from the group consisting
of hydrogen, fluorine, methyl, ethyl, isopropyl, CH.sub.2F,
CHF.sub.2, CF.sub.3, CHF--CH.sub.3, CF.sub.2--CH.sub.3,
CH.sub.2--CH.sub.2F CH.sub.2--CHF.sub.2 and CH.sub.2--CF.sub.3;
[0976] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, F, Cl, Br, I, methyl, ethyl, isopropyl, cyclopropyl,
C.ident.CH, CH.dbd.CH.sub.2, C(CH.sub.3).dbd.CH.sub.2, CF.sub.3,
CHF.sub.2, CH.sub.2F, --CHF--CH.sub.3, --CF.sub.2--CH.sub.3,
methoxy, trifluoromethoxy, ethoxy, methlythio, methylsulfinyl and
methylsulfonyl;
[0977] p is 0;
[0978] q is 1;
[0979] R.sup.5eu is G.sup.14 wherein R.sup.37', R.sup.38',
R.sup.39', R.sup.40', R.sup.41', R.sup.42', R.sup.43' and R.sup.44'
are selected independently of each other from the group consisting
of methyl, ethyl, F and CF.sub.3;
[0980] R.sup.45', R.sup.46, R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, F, Cl, Br, I, methyl, ethyl, isopropyl, cyclopropyl,
C.ident.CH, CH.dbd.CH.sub.2, C(CH.sub.3).dbd.CH.sub.2, CF.sub.3,
CHF.sub.2, CH.sub.2F, --CHF--CH.sub.3, --CF.sub.2--CH.sub.3,
methoxy, trifluoromethoxy, ethoxy, methlythio, methylsulfinyl and
methylsulfonyl;
[0981] p is 0;
[0982] q is 1;
[0983] R.sup.5ev is G.sup.14 wherein R.sup.37', R.sup.38',
R.sup.39', R.sup.40', R.sup.41', R.sup.42', R.sup.43' and R.sup.44'
are each hydrogen;
[0984] R.sup.45', R.sup.46, R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, F, Cl, Br, I, methyl, ethyl, isopropyl, cyclopropyl,
C.ident.CH, CH.dbd.CH.sub.2, C(CH.sub.3).dbd.CH.sub.2, CF.sub.3,
CHF.sub.2, CH.sub.2F, --CHF--CH.sub.3, --CF.sub.2--CH.sub.3,
methoxy, trifluoromethoxy, ethoxy, methlythio, methylsulfinyl and
methylsulfonyl;
[0985] p is 0;
[0986] q is 1;
[0987] R.sup.5ex is G.sup.14 wherein R.sup.37' is selected from the
group consisting of hydrogen, halogen, cyano, C.sub.1-C.sub.4 alkyl
and C.sub.1-C.sub.4 haloalkyl;
[0988] R.sup.38', R.sup.39', R.sup.40', R.sup.41', R.sup.42',
R.sup.43' and R.sup.44' are each hydrogen;
[0989] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, F, Cl, Br, I, methyl, ethyl, isopropyl, cyclopropyl,
C.ident.CH, CH.dbd.CH.sub.2, C(CH.sub.3).dbd.CH.sub.2, CF.sub.3,
CHF.sub.2, CH.sub.2F, --CHF--CH.sub.3, --CF.sub.2--CH.sub.3,
methoxy, trifluoromethoxy, ethoxy, methlythio, methylsulfinyl and
methylsulfonyl;
[0990] p is 0;
[0991] q is 1;
[0992] R.sup.5ey is G.sup.14 wherein R.sup.37 and R.sup.38' are
selected independently of each other from the group consisting of
hydrogen, halogen, cyano, C.sub.1-C.sub.4 alkyl and C.sub.1-C.sub.4
haloalkyl;
[0993] R.sup.39', R.sup.40', R.sup.41', R.sup.42', R.sup.43' and
R.sup.44' are selected independently of each other from the group
consisting of hydrogen, halogen, hydroxy, cyano, C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 haloalkyl, C.sub.1-C.sub.4 alkoxy,
C.sub.1-C.sub.4 haloalkoxy and C.sub.1-C.sub.4 alkylthio;
[0994] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, F, Cl, methyl, CF.sub.3, CHF.sub.2, CH.sub.2F, methoxy
and trifluoromethoxy;
[0995] p is 0;
[0996] q is 1;
[0997] R.sup.5ez is G.sup.14 wherein R.sup.37', R.sup.38',
R.sup.39', R.sup.40', R.sup.41', R.sup.42', R.sup.43' and R.sup.44'
are selected independently of each other from the group consisting
of hydrogen, halogen, methyl, ethyl, isopropyl, monofluoromethyl,
polyfluoromethyl, monofluoroethyl and polyfluoromethyl;
[0998] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, F, Cl, methyl, CF.sub.3, CHF.sub.2, CH.sub.2F, methoxy
and trifluoromethoxy;
[0999] p is 0;
[1000] q is 1;
[1001] R.sup.5fa is G.sup.14 wherein R.sup.37', R.sup.38',
R.sup.39', R.sup.40', R.sup.41', R.sup.42', R.sup.43' and R.sup.44'
are selected independently of each other from the group consisting
of hydrogen, fluorine, methyl, ethyl, isopropyl, CH.sub.2F,
CHF.sub.2, CF.sub.3, CHF--CH.sub.3, CF.sub.2--CH.sub.3,
CH.sub.2--CH.sub.2F CH.sub.2--CHF.sub.2 and CH.sub.2--CF.sub.3;
[1002] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, F, Cl, methyl, CF.sub.3, CHF.sub.2, CH.sub.2F, methoxy
and trifluoromethoxy;
[1003] p is 0;
[1004] q is 1;
[1005] R.sup.5fb is G.sup.14 wherein R.sup.37', R.sup.38',
R.sup.39', R.sup.40', R.sup.41', R.sup.42', R.sup.43' and R.sup.44'
are selected independently of each other from the group consisting
of methyl, ethyl, F and CF.sub.3;
[1006] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, F, Cl, methyl, CF.sub.3, CHF.sub.2, CH.sub.2F, methoxy
and trifluoromethoxy;
[1007] p is 0;
[1008] q is 1;
[1009] R.sup.5fc is G.sup.14 wherein R.sup.37', R.sup.38',
R.sup.39', R.sup.40', R.sup.41', R.sup.42', R.sup.43' and R.sup.44'
are each hydrogen;
[1010] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, F, Cl, methyl, CF.sub.3, CHF.sub.2, CH.sub.2F, methoxy
and trifluoromethoxy;
[1011] p is 0;
[1012] q is 1;
[1013] R.sup.5fd is G.sup.14 wherein R.sup.37' is selected from the
group consisting of hydrogen, halogen, cyano, C.sub.1-C.sub.4 alkyl
and C.sub.1-C.sub.4 haloalkyl;
[1014] R.sup.38', R.sup.39', R.sup.40', R.sup.41', R.sup.42',
R.sup.43' and R.sup.44' are each hydrogen; R.sup.45', R.sup.46',
R.sup.47', R.sup.48' and R.sup.49' are selected, independently of
each other, from the group consisting of hydrogen, F, Cl, methyl,
CF.sub.3, CHF.sub.2, CH.sub.2F, methoxy and trifluoromethoxy;
[1015] p is 0;
[1016] q is 1;
[1017] R.sup.5fe is G.sup.14 wherein R.sup.37' and R.sup.38' are
selected independently of each other from the group consisting of
hydrogen, halogen, cyano, C.sub.1-C.sub.4 alkyl and C.sub.1-C.sub.4
haloalkyl;
[1018] R.sup.39', R.sup.40', R.sup.41', R.sup.42', R.sup.43' and
R.sup.44' are selected independently of each other from the group
consisting of hydrogen, halogen, hydroxy, cyano, C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 haloalkyl, C.sub.1-C.sub.4 alkoxy,
C.sub.1-C.sub.4 haloalkoxy and C.sub.1-C.sub.4 alkylthio;
[1019] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, halogen, CN, NO.sub.2, OH, SH, CHO, C(.dbd.O)NH.sub.2,
C(.dbd.O)NH(CH.sub.3), C(.dbd.O)N(CH.sub.3).sub.2,
C(.dbd.S)NH.sub.2, C(.dbd.S)NH(CH.sub.3),
C(.dbd.S)N(CH.sub.3).sub.2, SO.sub.2NH.sub.2, SO.sub.2NH(CH.sub.3),
SO.sub.2N(CH.sub.3).sub.2, C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6
haloalkyl, C.sub.3-C.sub.6 cycloalkyl, C.sub.2-C.sub.6 alkenyl,
C.sub.2-C.sub.6 haloalkenyl, C.sub.2-C.sub.6 alkynyl,
C.sub.2-C.sub.6 haloalkynyl, C.sub.1-C.sub.6 alkoxy,
C.sub.1-C.sub.6 haloalkoxy, C.sub.3-C.sub.6 alkenyloxy,
C.sub.3-C.sub.6 haloalkenyloxy, C.sub.3-C.sub.6 alkynyloxy,
C.sub.3-C.sub.6 cycloalkoxy, C.sub.3-C.sub.6 halocycloalkoxy,
C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6 haloalkylthio,
C.sub.1-C.sub.6 alkylsulfinyl, C.sub.1-C.sub.6 haloalkylsulfinyl,
C.sub.1-C.sub.6 alkylsulfonyl and C.sub.1-C.sub.6
haloalkylsulfonyl;
[1020] p is 1;
[1021] q is 1;
[1022] R.sup.5fg is G.sup.14 wherein R.sup.37', R.sup.38',
R.sup.39', R.sup.40', R.sup.41', R.sup.42', R.sup.43' and R.sup.44'
are selected independently of each other from the group consisting
of hydrogen, halogen, methyl, ethyl, isopropyl, monofluoromethyl,
polyfluoromethyl, monofluoroethyl and polyfluoroethyl;
[1023] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, halogen, CN, NO.sub.2, OH, SH, CHO, C(.dbd.O)NH.sub.2,
C(.dbd.O)NH(CH.sub.3), C(.dbd.O)N(CH.sub.3).sub.2,
C(.dbd.S)NH.sub.2, C(.dbd.S)NH(CH.sub.3),
C(.dbd.S)N(CH.sub.3).sub.2, SO.sub.2NH.sub.2, SO.sub.2NH(CH.sub.3),
SO.sub.2N(CH.sub.3).sub.2, C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6
haloalkyl, C.sub.3-C.sub.6 cycloalkyl, C.sub.2-C.sub.6 alkenyl,
C.sub.2-C.sub.6 haloalkenyl, C.sub.2-C.sub.6 alkynyl,
C.sub.2-C.sub.6 haloalkynyl, C.sub.1-C.sub.6 alkoxy,
C.sub.1-C.sub.6 haloalkoxy, C.sub.3-C.sub.6 alkenyloxy,
C.sub.3-C.sub.6 haloalkenyloxy, C.sub.3-C.sub.6 alkynyloxy,
C.sub.3-C.sub.6 cycloalkoxy, C.sub.3-C.sub.6 halocycloalkoxy,
C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6 haloalkylthio,
C.sub.1-C.sub.6 alkylsulfinyl, C.sub.1-C.sub.6 haloalkylsulfinyl,
C.sub.1-C.sub.6 alkylsulfonyl and C.sub.1-C.sub.6
haloalkylsulfonyl;
[1024] p is 1;
[1025] q is 1;
[1026] R.sup.5fh is G.sup.14 wherein R.sup.37', R.sup.38',
R.sup.39', R.sup.40', R.sup.41', R.sup.42', R.sup.43' and R.sup.44'
are selected independently of each other from the group consisting
of hydrogen, fluorine, methyl, ethyl, isopropyl, CH.sub.2F,
CHF.sub.2, CF.sub.3, CHF--CH.sub.3, CF.sub.2--CH.sub.3,
CH.sub.2--CH.sub.2F CH.sub.2--CHF.sub.2 and CH.sub.2--CF.sub.3;
[1027] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, halogen, CN, NO.sub.2, OH, SH, CHO, C(.dbd.O)NH.sub.2,
C(.dbd.O)NH(CH.sub.3), C(.dbd.O)N(CH.sub.3).sub.2,
C(.dbd.S)NH.sub.2, C(.dbd.S)NH(CH.sub.3),
C(.dbd.S)N(CH.sub.3).sub.2, SO.sub.2NH.sub.2, SO.sub.2NH(CH.sub.3),
SO.sub.2N(CH.sub.3).sub.2, C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6
haloalkyl, C.sub.3-C.sub.6 cycloalkyl, C.sub.2-C.sub.6 alkenyl,
C.sub.2-C.sub.6 haloalkenyl, C.sub.2-C.sub.6 alkynyl,
C.sub.2-C.sub.6 haloalkynyl, C.sub.1-C.sub.6 alkoxy,
C.sub.1-C.sub.6 haloalkoxy, C.sub.3-C.sub.6 alkenyloxy,
C.sub.3-C.sub.6 haloalkenyloxy, C.sub.3-C.sub.6 alkynyloxy,
C.sub.3-C.sub.6 cycloalkoxy, C.sub.3-C.sub.6 halocycloalkoxy,
C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6 haloalkylthio,
C.sub.1-C.sub.6 alkylsulfinyl, C.sub.1-C.sub.6 haloalkylsulfinyl,
C.sub.1-C.sub.6 alkylsulfonyl and C.sub.1-C.sub.6
haloalkylsulfonyl;
[1028] p is 1;
[1029] q is 1;
[1030] R.sup.5fi is G.sup.14 wherein R.sup.37', R.sup.38',
R.sup.39', R.sup.40', R.sup.41', R.sup.42', R.sup.43' and R.sup.44'
are selected independently of each other from the group consisting
of methyl, ethyl, F and CF.sub.3;
[1031] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, halogen, CN, NO.sub.2, OH, SH, CHO, C(.dbd.O)NH.sub.2,
C(.dbd.O)NH(CH.sub.3), C(.dbd.O)N(CH.sub.3).sub.2,
C(.dbd.S)NH.sub.2, C(.dbd.S)NH(CH.sub.3),
C(.dbd.S)N(CH.sub.3).sub.2, SO.sub.2NH.sub.2, SO.sub.2NH(CH.sub.3),
SO.sub.2N(CH.sub.3).sub.2, C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6
haloalkyl, C.sub.3-C.sub.6 cycloalkyl, C.sub.2-C.sub.6 alkenyl,
C.sub.2-C.sub.6 haloalkenyl, C.sub.2-C.sub.6 alkynyl,
C.sub.2-C.sub.6 haloalkynyl, C.sub.1-C.sub.6 alkoxy,
C.sub.1-C.sub.6 haloalkoxy, C.sub.3-C.sub.6 alkenyloxy,
C.sub.3-C.sub.6 haloalkenyloxy, C.sub.3-C.sub.6 alkynyloxy,
C.sub.3-C.sub.6 cycloalkoxy, C.sub.3-C.sub.6 halocycloalkoxy,
C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6 haloalkylthio,
C.sub.1-C.sub.6 alkylsulfinyl, C.sub.1-C.sub.6 haloalkylsulfinyl,
C.sub.1-C.sub.6 alkylsulfonyl and C.sub.1-C.sub.6
haloalkylsulfonyl;
[1032] p is 1;
[1033] q is 1;
[1034] R.sup.5fj is G.sup.14 wherein R.sup.37', R.sup.38',
R.sup.39', R.sup.40', R.sup.41', R.sup.42', R.sup.43' and R.sup.44'
are each hydrogen;
[1035] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, halogen, CN, NO.sub.2, OH, SH, CHO, C(.dbd.O)NH.sub.2,
C(.dbd.O)NH(CH.sub.3), C(.dbd.O)N(CH.sub.3).sub.2,
C(.dbd.S)NH.sub.2, C(.dbd.S)NH(CH.sub.3),
C(.dbd.S)N(CH.sub.3).sub.2, SO.sub.2NH.sub.2, SO.sub.2NH(CH.sub.3),
SO.sub.2N(CH.sub.3).sub.2, C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6
haloalkyl, C.sub.3-C.sub.6 cycloalkyl, C.sub.2-C.sub.6 alkenyl,
C.sub.2-C.sub.6 haloalkenyl, C.sub.2-C.sub.6 alkynyl,
C.sub.2-C.sub.6 haloalkynyl, C.sub.1-C.sub.6 alkoxy,
C.sub.1-C.sub.6 haloalkoxy, C.sub.3-C.sub.6 alkenyloxy,
C.sub.3-C.sub.6 haloalkenyloxy, C.sub.3-C.sub.6 alkynyloxy,
C.sub.3-C.sub.6 cycloalkoxy, C.sub.3-C.sub.6 halocycloalkoxy,
C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6 haloalkylthio,
C.sub.1-C.sub.6 alkylsulfinyl, C.sub.1-C.sub.6 haloalkylsulfinyl,
C.sub.1-C.sub.6 alkylsulfonyl and C.sub.1-C.sub.6
haloalkylsulfonyl;
[1036] p is 1;
[1037] q is 1;
[1038] R.sup.5fk is G.sup.14 wherein R.sup.37' is selected from the
group consisting of hydrogen, halogen, cyano, C.sub.1-C.sub.4 alkyl
and C.sub.1-C.sub.4 haloalkyl;
[1039] R.sup.38', R.sup.39', R.sup.40', R.sup.41', R.sup.42',
R.sup.43' and R.sup.44' are each hydrogen;
[1040] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, halogen, CN, NO.sub.2, OH, SH, CHO, C(.dbd.O)NH.sub.2,
C(.dbd.O)NH(CH.sub.3), C(.dbd.O)N(CH.sub.3).sub.2,
C(.dbd.S)NH.sub.2, C(.dbd.S)NH(CH.sub.3),
C(.dbd.S)N(CH.sub.3).sub.2, SO.sub.2NH.sub.2, SO.sub.2NH(CH.sub.3),
SO.sub.2N(CH.sub.3).sub.2, C.sub.1-C.sub.6 alkyl, C.sub.1-C.sub.6
haloalkyl, C.sub.3-C.sub.6 cycloalkyl, C.sub.2-C.sub.6 alkenyl,
C.sub.2-C.sub.6 haloalkenyl, C.sub.2-C.sub.6 alkynyl,
C.sub.2-C.sub.6 haloalkynyl, C.sub.1-C.sub.6 alkoxy,
C.sub.1-C.sub.6 haloalkoxy, C.sub.3-C.sub.6 alkenyloxy,
C.sub.3-C.sub.6 haloalkenyloxy, C.sub.3-C.sub.6 alkynyloxy,
C.sub.3-C.sub.6 cycloalkoxy, C.sub.3-C.sub.6 halocycloalkoxy,
C.sub.1-C.sub.6 alkylthio, C.sub.1-C.sub.6 haloalkylthio,
C.sub.1-C.sub.6 alkylsulfinyl, C.sub.1-C.sub.6 haloalkylsulfinyl,
C.sub.1-C.sub.6 alkylsulfonyl and C.sub.1-C.sub.6
haloalkylsulfonyl;
[1041] p is 1;
[1042] q is 1;
[1043] R.sup.5fl is G.sup.14 wherein R.sup.37' and R.sup.38' are
selected independently of each other from the group consisting of
hydrogen, halogen, cyano, C.sub.1-C.sub.4 alkyl and C.sub.1-C.sub.4
haloalkyl;
[1044] R.sup.39', R.sup.40', R.sup.41', R.sup.42', R.sup.43' and
R.sup.44' are selected independently of each other from the group
consisting of hydrogen, halogen, hydroxy, cyano, C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 haloalkyl, C.sub.1-C.sub.4 alkoxy,
C.sub.1-C.sub.4 haloalkoxy and C.sub.1-C.sub.4 alkylthio;
[1045] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, F, Cl, Br, I, methyl, ethyl, isopropyl, cyclopropyl,
C.ident.CH, CH.dbd.CH.sub.2, C(CH.sub.3).dbd.CH.sub.2, CF.sub.3,
CHF.sub.2, CH.sub.2F, --CHF--CH.sub.3, --CF.sub.2--CH.sub.3,
methoxy, trifluoromethoxy, ethoxy, methlythio, methylsulfinyl and
methylsulfonyl;
[1046] p is 1;
[1047] q is 1;
[1048] R.sup.5fm is G.sup.14 wherein R.sup.37', R.sup.38',
R.sup.39', R.sup.40', R.sup.41', R.sup.42', R.sup.43' and R.sup.44'
are selected independently of each other from the group consisting
of hydrogen, halogen, methyl, ethyl, isopropyl, monofluoromethyl,
polyfluoromethyl, monofluoroethyl and polyfluoroethyl;
[1049] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, F, Cl, Br, I, methyl, ethyl, isopropyl, cyclopropyl,
C.ident.CH, CH.dbd.CH.sub.2, C(CH.sub.3).dbd.CH.sub.2, CF.sub.3,
CHF.sub.2, CH.sub.2F, --CHF--CH.sub.3, --CF.sub.2--CH.sub.3,
methoxy, trifluoromethoxy, ethoxy, methlythio, methylsulfinyl and
methylsulfonyl;
[1050] p is 1;
[1051] q is 1;
[1052] R.sup.5fn is G.sup.14 wherein R.sup.37', R.sup.38',
R.sup.39', R.sup.40', R.sup.41', R.sup.42', R.sup.43' and R.sup.44'
are selected independently of each other from the group consisting
of hydrogen, fluorine, methyl, ethyl, isopropyl, CH.sub.2F,
CHF.sub.2, CF.sub.3, CHF--CH.sub.3, CF.sub.2--CH.sub.3,
CH.sub.2--CH.sub.2F CH.sub.2--CHF.sub.2 and CH.sub.2--CF.sub.3;
[1053] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, F, Cl, Br, I, methyl, ethyl, isopropyl, cyclopropyl,
C.ident.CH, CH.dbd.CH.sub.2, C(CH.sub.3).dbd.CH.sub.2, CF.sub.3,
CHF.sub.2, CH.sub.2F, --CHF--CH.sub.3, --CF.sub.2--CH.sub.3,
methoxy, trifluoromethoxy, ethoxy, methlythio, methylsulfinyl and
methylsulfonyl;
[1054] p is 1;
[1055] q is 1;
[1056] R.sup.5fo is G.sup.14 wherein R.sup.37', R.sup.38',
R.sup.39', R.sup.40', R.sup.41', R.sup.42', R.sup.43' and R.sup.44'
are selected independently of each other from the group consisting
of methyl, ethyl, F and CF.sub.3;
[1057] R.sup.45', R.sup.46, R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, F, Cl, Br, I, methyl, ethyl, isopropyl, cyclopropyl,
C.ident.CH, CH.dbd.CH.sub.2, C(CH.sub.3).dbd.CH.sub.2, CF.sub.3,
CHF.sub.2, CH.sub.2F, --CHF--CH.sub.3, --CF.sub.2--CH.sub.3,
methoxy, trifluoromethoxy, ethoxy, methlythio, methylsulfinyl and
methylsulfonyl;
[1058] p is 1;
[1059] q is 1;
[1060] R.sup.5fp is G.sup.14 wherein R.sup.37', R.sup.38',
R.sup.39', R.sup.40', R.sup.41', R.sup.42', R.sup.43' and R.sup.44'
are each hydrogen;
[1061] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, F, Cl, Br, I, methyl, ethyl, isopropyl, cyclopropyl,
C.ident.CH, CH.dbd.CH.sub.2, C(CH.sub.3).dbd.CH.sub.2, CF.sub.3,
CHF.sub.2, CH.sub.2F, --CHF--CH.sub.3, --CF.sub.2--CH.sub.3,
methoxy, trifluoromethoxy, ethoxy, methlythio, methylsulfinyl and
methylsulfonyl;
[1062] p is 1;
[1063] q is 1;
[1064] R.sup.5fq is G.sup.14 wherein R.sup.37' is selected from the
group consisting of hydrogen, halogen, cyano, C.sub.1-C.sub.4 alkyl
and C.sub.1-C.sub.4 haloalkyl;
[1065] R.sup.38', R.sup.39', R.sup.40', R.sup.41', R.sup.42',
R.sup.43' and R.sup.44' are hydrogen;
[1066] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, F, Cl, Br, I, methyl, ethyl, isopropyl, cyclopropyl,
C.ident.CH, CH.dbd.CH.sub.2, C(CH.sub.3).dbd.CH.sub.2, CF.sub.3,
CHF.sub.2, CH.sub.2F, --CHF--CH.sub.3, --CF.sub.2--CH.sub.3,
methoxy, trifluoromethoxy, ethoxy, methlythio, methylsulfinyl and
methylsulfonyl;
[1067] p is 1;
[1068] q is 1;
[1069] R.sup.5fr is G.sup.14 wherein R.sup.37' and R.sup.38' are
selected independently of each other from the group consisting of
hydrogen, halogen, cyano, C.sub.1-C.sub.4 alkyl and C.sub.1-C.sub.4
haloalkyl;
[1070] R.sup.39', R.sup.40', R.sup.41', R.sup.42', R.sup.43' and
R.sup.44' are selected independently of each other from the group
consisting of hydrogen, halogen, hydroxy, cyano, C.sub.1-C.sub.4
alkyl, C.sub.1-C.sub.4 haloalkyl, C.sub.1-C.sub.4 alkoxy,
C.sub.1-C.sub.4 haloalkoxy and C.sub.1-C.sub.4 alkylthio;
[1071] R.sup.45', R.sup.46, R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, F, Cl, methyl, CF.sub.3, CHF.sub.2, CH.sub.2F, methoxy
and trifluoromethoxy;
[1072] p is 1;
[1073] q is 1;
[1074] R.sup.5fs is G.sup.14 wherein R.sup.37', R.sup.38',
R.sup.39', R.sup.40, R.sup.41', R.sup.42', R.sup.43' and R.sup.44'
are selected independently of each other from the group consisting
of hydrogen, halogen, methyl, ethyl, isopropyl, monofluoromethyl,
polyfluoromethyl, monofluoroethyl and polyfluoroethyl;
[1075] R.sup.45', R.sup.46, R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, F, Cl, methyl, CF.sub.3, CHF.sub.2, CH.sub.2F, methoxy
and trifluoromethoxy;
[1076] p is 1;
[1077] q is 1;
[1078] R.sup.5ft is G.sup.14 wherein R.sup.37', R.sup.38',
R.sup.39', R.sup.40', R.sup.41', R.sup.42', R.sup.43' and R.sup.44'
are selected independently of each other from the group consisting
of hydrogen, fluorine, methyl, ethyl, isopropyl, CH.sub.2F,
CHF.sub.2, CF.sub.3, CHF--CH.sub.3, CF.sub.2--CH.sub.3,
CH.sub.2--CH.sub.2F CH.sub.2--CHF.sub.2 and CH.sub.2--CF.sub.3;
[1079] R.sup.45', R.sup.46, R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, F, Cl, methyl, CF.sub.3, CHF.sub.2, CH.sub.2F, methoxy
and trifluoromethoxy;
[1080] p is 1;
[1081] q is 1;
[1082] R.sup.5fu is G.sup.14 wherein R.sup.37', R.sup.38',
R.sup.39', R.sup.40', R.sup.41', R.sup.42', R.sup.43' and
R.sup.44'' are selected independently of each other from the group
consisting of methyl, ethyl, F and CF.sub.3;
[1083] R.sup.45', R.sup.46', R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, F, Cl, methyl, CF.sub.3, CHF.sub.2, CH.sub.2F, methoxy
and trifluoromethoxy;
[1084] p is 1;
[1085] q is 1;
[1086] R.sup.5fv is G.sup.14 wherein R.sup.37', R.sup.38',
R.sup.39', R.sup.40', R.sup.41', R.sup.42', R.sup.43' and R.sup.44'
are each hydrogen;
[1087] R.sup.45', R.sup.46, R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, F, Cl, methyl, CF.sub.3, CHF.sub.2, CH.sub.2F, methoxy
and trifluoromethoxy;
[1088] p is 1;
[1089] q is 1;
[1090] R.sup.5fw is G.sup.14 wherein R.sup.37' is selected from
hydrogen, halogen, cyano, C.sub.1-C.sub.4 alkyl and C.sub.1-C.sub.4
haloalkyl;
[1091] R.sup.38', R.sup.39', R.sup.40', R.sup.41', R.sup.42',
R.sup.43' and R.sup.44' are selected independently of each other
from the group consisting of hydrogen, fluorine, methyl, ethyl,
isopropyl, CH.sub.2F, CHF.sub.2, CF.sub.3, CHF--CH.sub.3,
CF.sub.2--CH.sub.3, CH.sub.2--CH.sub.2F CH.sub.2--CHF.sub.2 and
CH.sub.2--CF.sub.3;
[1092] R.sup.45', R.sup.46, R.sup.47', R.sup.48' and R.sup.49' are
selected, independently of each other, from the group consisting of
hydrogen, F, Cl, methyl, CF.sub.3, CHF.sub.2, CH.sub.2F, methoxy
and trifluoromethoxy;
[1093] p is 1;
[1094] q is 1;
[1095] R.sup.6a is selected from hydrogen and SH;
[1096] R.sup.6b is hydrogen;
[1097] R.sup.6c is SH.
[1098] Each line of Table N describes a preferred sub-group from
N1-N757 of this group. For reasons of clarity, note that in these
sub-groups, R.sub.2 is always methyl and R.sub.7 is always
hydrogen. For example, sub-group N1 is a group of compounds of
formula (I) wherein
[1099] R.sub.1 is R.sup.1b;
[1100] R.sub.2 is methyl;
[1101] R.sub.3 is R.sup.3a;
[1102] R.sub.4 is R.sup.4c;
[1103] R.sub.5 is R.sup.5a;
[1104] R.sub.6 is R.sup.6b;
[1105] R.sub.7 is H.
TABLE-US-00001 TABLE N R.sub.1 R.sub.3 R.sub.4 R.sub.5 R.sub.6 N1
R.sup.1b R.sup.3a R.sup.4c R.sup.5a R.sup.6b N2 R.sup.1b R.sup.3b
R.sup.4d R.sup.5a R.sup.6b N3 R.sup.1b R.sup.3c R.sup.4e R.sup.5a
R.sup.6b N4 R.sup.1b R.sup.3a R.sup.4c R.sup.5b R.sup.6b N5
R.sup.1b R.sup.3b R.sup.4d R.sup.5b R.sup.6b N6 R.sup.1b R.sup.3c
R.sup.4e R.sup.5b R.sup.6b N7 R.sup.1b R.sup.3a R.sup.4c R.sup.5c
R.sup.6b N8 R.sup.1b R.sup.3b R.sup.4d R.sup.5c R.sup.6b N9
R.sup.1b R.sup.3c R.sup.4e R.sup.5c R.sup.6b N10 R.sup.1b R.sup.3a
R.sup.4c R.sup.5d R.sup.6b N11 R.sup.1b R.sup.3b R.sup.4d R.sup.5d
R.sup.6b N12 R.sup.1b R.sup.3c R.sup.4e R.sup.5d R.sup.6b N13
R.sup.1b R.sup.3a R.sup.4c R.sup.5e R.sup.6b N14 R.sup.1b R.sup.3b
R.sup.4d R.sup.5e R.sup.6b N15 R.sup.1b R.sup.3c R.sup.4e R.sup.5e
R.sup.6b N16 R.sup.1b R.sup.3a R.sup.4c R.sup.5f R.sup.6b N17
R.sup.1b R.sup.3b R.sup.4d R.sup.5f R.sup.6b N18 R.sup.1b R.sup.3c
R.sup.4e R.sup.5f R.sup.6b N19 R.sup.1b R.sup.3a R.sup.4c R.sup.5g
R.sup.6b N20 R.sup.1b R.sup.3b R.sup.4d R.sup.5g R.sup.6b N21
R.sup.1b R.sup.3c R.sup.4e R.sup.5g R.sup.6b N22 R.sup.1b R.sup.3a
R.sup.4c R.sup.5h R.sup.6b N23 R.sup.1b R.sup.3b R.sup.4d R.sup.5h
R.sup.6b N24 R.sup.1b R.sup.3c R.sup.4e R.sup.5h R.sup.6b N25
R.sup.1b R.sup.3a R.sup.4c R.sup.5j R.sup.6b N26 R.sup.1b R.sup.3b
R.sup.4d R.sup.5j R.sup.6b N27 R.sup.1b R.sup.3c R.sup.4e R.sup.5j
R.sup.6b N28 R.sup.1b R.sup.3d R.sup.4c R.sup.5k R.sup.6b N29
R.sup.1b R.sup.3b R.sup.4d R.sup.5k R.sup.6b N30 R.sup.1b R.sup.3c
R.sup.4e R.sup.5k R.sup.6b N31 R.sup.1b R.sup.3d R.sup.4c R.sup.5l
R.sup.6b N32 R.sup.1b R.sup.3b R.sup.4d R.sup.5l R.sup.6b N33
R.sup.1b R.sup.3c R.sup.4e R.sup.5l R.sup.6b N34 R.sup.1b R.sup.3d
R.sup.4c R.sup.5m R.sup.6b N35 R.sup.1b R.sup.3b R.sup.4d R.sup.5m
R.sup.6b N36 R.sup.1b R.sup.3c R.sup.4e R.sup.5m R.sup.6b N37
R.sup.1b R.sup.3d R.sup.4c R.sup.5n R.sup.6b N38 R.sup.1b R.sup.3b
R.sup.4d R.sup.5n R.sup.6b N39 R.sup.1b R.sup.3c R.sup.4e R.sup.5n
R.sup.6b N40 R.sup.1b R.sup.3d R.sup.4c R.sup.5o R.sup.6b N41
R.sup.1b R.sup.3b R.sup.4d R.sup.5o R.sup.6b N42 R.sup.1b R.sup.3c
R.sup.4e R.sup.5o R.sup.6b N43 R.sup.1b R.sup.3d R.sup.4c R.sup.5p
R.sup.6b N44 R.sup.1b R.sup.3b R.sup.4d R.sup.5p R.sup.6b N45
R.sup.1b R.sup.3c R.sup.4e R.sup.5p R.sup.6b N46 R.sup.1b R.sup.3d
R.sup.4c R.sup.5q R.sup.6b N47 R.sup.1b R.sup.3b R.sup.4d R.sup.5q
R.sup.6b N48 R.sup.1b R.sup.3c F.sup.4e R.sup.5q R.sup.6b N49
R.sup.1b R.sup.3d R.sup.4c R.sup.5r R.sup.6b N50 R.sup.1b R.sup.3b
R.sup.4d R.sup.5r R.sup.6b N51 R.sup.1b R.sup.3c R.sup.4e R.sup.5r
R.sup.6b N52 R.sup.1b R.sup.3d R.sup.4c R.sup.5s R.sup.6b N53
R.sup.1b R.sup.3b R.sup.4d R.sup.5s R.sup.6b N54 R.sup.1b R.sup.3c
R.sup.4e R.sup.5s R.sup.6b N55 R.sup.1b R.sup.3d R.sup.4c R.sup.5t
R.sup.6b N56 R.sup.1b R.sup.3b R.sup.4d R.sup.5t R.sup.6b N57
R.sup.1b R.sup.3c R.sup.4e R.sup.5t R.sup.6b N58 R.sup.1b R.sup.3d
R.sup.4c R.sup.5u R.sup.6b N59 R.sup.1b R.sup.3b R.sup.4d R.sup.5u
R.sup.6b N60 R.sup.1b R.sup.3c R.sup.4e R.sup.5u R.sup.6b N61
R.sup.1b R.sup.3d R.sup.4c R.sup.5v R.sup.6b N62 R.sup.1b R.sup.3b
R.sup.4d R.sup.5v R.sup.6b N63 R.sup.1b R.sup.3c R.sup.4e R.sup.5v
R.sup.6b N64 R.sup.1b R.sup.3d R.sup.4c R.sup.5x R.sup.6b N65
R.sup.1b R.sup.3b R.sup.4d R.sup.5x R.sup.6b N66 R.sup.1b R.sup.3c
R.sup.4e R.sup.5x R.sup.6b N67 R.sup.1b R.sup.3d R.sup.4c R.sup.5y
R.sup.6b N68 R.sup.1b R.sup.3b R.sup.4d R.sup.5y R.sup.6b N69
R.sup.1b R.sup.3c R.sup.4e R.sup.5y R.sup.6b N70 R.sup.1b R.sup.3d
R.sup.4c R.sup.5z R.sup.6b N71 R.sup.1b R.sup.3b R.sup.4d R.sup.5z
R.sup.6b N72 R.sup.1b R.sup.3c R.sup.4e R.sup.5z R.sup.6b N73
R.sup.1b R.sup.3d R.sup.4c R.sup.5ab R.sup.6b N74 R.sup.1b R.sup.3b
R.sup.4d R.sup.5ab R.sup.6b N75 R.sup.1b R.sup.3c R.sup.4e
R.sup.5ab R.sup.6b N76 R.sup.1b R.sup.3d R.sup.4c R.sup.5ac
R.sup.6b N77 R.sup.1b R.sup.3b R.sup.4d R.sup.5ac R.sup.6b N78
R.sup.1b R.sup.3c R.sup.4e R.sup.5ac R.sup.6b N79 R.sup.1b R.sup.3d
R.sup.4c R.sup.5ad R.sup.6b N80 R.sup.1b R.sup.3b R.sup.4d
R.sup.5ad R.sup.6b N81 R.sup.1b R.sup.3c R.sup.4e R.sup.5ad
R.sup.6b N82 R.sup.1b R.sup.3e R.sup.4c R.sup.5bb R.sup.6b N83
R.sup.1b R.sup.3f R.sup.4c R.sup.5bb R.sup.6b N84 R.sup.1b R.sup.3g
R.sup.4e R.sup.5bb R.sup.6b N85 R.sup.1b R.sup.3h R.sup.4e
R.sup.5bb R.sup.6b N86 R.sup.1b R.sup.3e R.sup.4c R.sup.5cc
R.sup.6b N87 R.sup.1b R.sup.3f R.sup.4c R.sup.5cc R.sup.6b N88
R.sup.1b R.sup.3g R.sup.4e R.sup.5cc R.sup.6b N89 R.sup.1b R.sup.3h
R.sup.4e R.sup.5cc R.sup.6b N90 R.sup.1b R.sup.3e R.sup.4c
R.sup.5dd R.sup.6b N91 R.sup.1b R.sup.3f R.sup.4c R.sup.5dd
R.sup.6b N92 R.sup.1b R.sup.3g R.sup.4e R.sup.5dd R.sup.6b N93
R.sup.1b R.sup.3h R.sup.4e R.sup.5dd R.sup.6b N94 R.sup.1b R.sup.3e
R.sup.4c R.sup.5ee R.sup.6b N95 R.sup.1b R.sup.3f R.sup.4c
R.sup.5ee R.sup.6b N96 R.sup.1b R.sup.3g R.sup.4e R.sup.5ee
R.sup.6b N97 R.sup.1b R.sup.3h R.sup.4e R.sup.5ee R.sup.6b N98
R.sup.1b R.sup.3i R.sup.4c R.sup.5ae R.sup.6a N99 R.sup.1b R.sup.3j
R.sup.4c R.sup.5af R.sup.6b N100 R.sup.1b R.sup.3k R.sup.4c
R.sup.5ag R.sup.6a N101 R.sup.1b R.sup.3k R.sup.4c R.sup.5ag
R.sup.6b N102 R.sup.1b R.sup.3l R.sup.4c R.sup.5ag R.sup.6c N103
R.sup.1b R.sup.3i R.sup.4e R.sup.5ae R.sup.6a N104 R.sup.1b
R.sup.3j R.sup.4e R.sup.5af R.sup.6b N105 R.sup.1b R.sup.3k
R.sup.4e R.sup.5ag R.sup.6a N106 R.sup.1b R.sup.3k R.sup.4e
R.sup.5ag R.sup.6b N107 R.sup.1b R.sup.3l R.sup.4e R.sup.5ag
R.sup.6c N108 R.sup.1b R.sup.3i R.sup.4f R.sup.5ae R.sup.6a N109
R.sup.1b R.sup.3j R.sup.4f R.sup.5af R.sup.6b N110 R.sup.1b
R.sup.3k R.sup.4f R.sup.5ag R.sup.6a N111 R.sup.1b R.sup.3k
R.sup.4f R.sup.5ag R.sup.6b N112 R.sup.1b R.sup.3l R.sup.4f
R.sup.5ag R.sup.6c N113 R.sup.1b R.sup.3m R.sup.4c R.sup.5ae
R.sup.6a N114 R.sup.1b R.sup.3m R.sup.4c R.sup.5af R.sup.6b N115
R.sup.1b R.sup.3m R.sup.4c R.sup.5ag R.sup.6a N116 R.sup.1b
R.sup.3m R.sup.4c R.sup.5ag R.sup.6b N117 R.sup.1b R.sup.3m
R.sup.4c R.sup.5ag R.sup.6c N118 R.sup.1b R.sup.3m R.sup.4e
R.sup.5ae R.sup.6a N119 R.sup.1b R.sup.3m R.sup.4e R.sup.5af
R.sup.6b N120 R.sup.1b R.sup.3m R.sup.4e R.sup.5ag R.sup.6a N121
R.sup.1b R.sup.3m R.sup.4e R.sup.5ag R.sup.6b N122 R.sup.1b
R.sup.3m R.sup.4e R.sup.5ag R.sup.6c N123 R.sup.1b R.sup.3m
R.sup.4f R.sup.5ae R.sup.6a N124 R.sup.1b R.sup.3m R.sup.4f
R.sup.5af R.sup.6b N125 R.sup.1b R.sup.3m R.sup.4f R.sup.5ag
R.sup.6a N126 R.sup.1b R.sup.3m R.sup.4f R.sup.5ag R.sup.6b N127
R.sup.1b R.sup.3m R.sup.4f R.sup.5ag R.sup.6c N128 R.sup.1b
R.sup.3i R.sup.4c R.sup.5ah R.sup.6a N129 R.sup.1b R.sup.3j
R.sup.4c R.sup.5ai R.sup.6b N130 R.sup.1b R.sup.3k R.sup.4c
R.sup.5ak R.sup.6a N131 R.sup.1b R.sup.3k R.sup.4c R.sup.5ak
R.sup.6b N132 R.sup.1b R.sup.3l R.sup.4c R.sup.5ak R.sup.6c N133
R.sup.1b R.sup.3i R.sup.4e R.sup.5ah R.sup.6a N134 R.sup.1b
R.sup.3j R.sup.4e R.sup.5ai R.sup.6b N135 R.sup.1b R.sup.3k
R.sup.4e R.sup.5ak R.sup.6a N136 R.sup.1b R.sup.3k R.sup.4e
R.sup.5ak R.sup.6b N137 R.sup.1b R.sup.3l R.sup.4e R.sup.5ak
R.sup.6c N138 R.sup.1b R.sup.3i R.sup.4f R.sup.5ah R.sup.6a N139
R.sup.1b R.sup.3j R.sup.4f R.sup.5ai R.sup.6b N140 R.sup.1b
R.sup.3k R.sup.4f R.sup.5ak R.sup.6a N141 R.sup.1b R.sup.3k
R.sup.4f R.sup.5ak R.sup.6b N142 R.sup.1b R.sup.3l R.sup.4f
R.sup.5ak R.sup.6c N143 R.sup.1b R.sup.3m R.sup.4c R.sup.5ah
R.sup.6a N144 R.sup.1b R.sup.3m R.sup.4c R.sup.5ai R.sup.6b N145
R.sup.1b R.sup.3m R.sup.4c R.sup.5ak R.sup.6a N146 R.sup.1b
R.sup.3m R.sup.4c R.sup.5ak R.sup.6b N147 R.sup.1b R.sup.3m
R.sup.4c R.sup.5ak R.sup.6c N148 R.sup.1b R.sup.3m R.sup.4e
R.sup.5ah R.sup.6a N149 R.sup.1b R.sup.3m R.sup.4e R.sup.5ai
R.sup.6b N150 R.sup.1b R.sup.3m R.sup.4e R.sup.5ak R.sup.6a N151
R.sup.1b R.sup.3m R.sup.4e R.sup.5ak R.sup.6b N152 R.sup.1b
R.sup.3m R.sup.4e R.sup.5ak R.sup.6c N153 R.sup.1b R.sup.3m
R.sup.4f R.sup.5ah R.sup.6a N154 R.sup.1b R.sup.3m R.sup.4f
R.sup.5ai R.sup.6b N155 R.sup.1b R.sup.3m R.sup.4f R.sup.5ak
R.sup.6a N156 R.sup.1b R.sup.3m R.sup.4f R.sup.5ak R.sup.6b N157
R.sup.1b R.sup.3m R.sup.4f R.sup.5ak R.sup.6c N158 R.sup.1b
R.sup.3i R.sup.4c R.sup.5al R.sup.6a N159 R.sup.1b R.sup.3j
R.sup.4c R.sup.5am R.sup.6b N160 R.sup.1b R.sup.3k R.sup.4c
R.sup.5an R.sup.6a N161 R.sup.1b R.sup.3k R.sup.4c R.sup.5an
R.sup.6b N162 R.sup.1b R.sup.3l R.sup.4c R.sup.5an R.sup.6c N163
R.sup.1b R.sup.3i R.sup.4e R.sup.5al R.sup.6a N164 R.sup.1b
R.sup.3j R.sup.4e R.sup.5am R.sup.6b N165 R.sup.1b R.sup.3k
R.sup.4e R.sup.5an R.sup.6a N166 R.sup.1b R.sup.3k R.sup.4e
R.sup.5an R.sup.6b N167 R.sup.1b R.sup.3l R.sup.4e R.sup.5an
R.sup.6c N168 R.sup.1b R.sup.3i R.sup.4f R.sup.5al R.sup.6a N169
R.sup.1b R.sup.3j R.sup.4f R.sup.5am R.sup.6b N170 R.sup.1b
R.sup.3k R.sup.4f R.sup.5an R.sup.6a N171 R.sup.1b R.sup.3k
R.sup.4f R.sup.5an R.sup.6b N172 R.sup.1b R.sup.3l R.sup.4f
R.sup.5an R.sup.6c N173 R.sup.1a R.sup.3n R.sup.4c R.sup.5ff
R.sup.6a N174 R.sup.1b R.sup.3o R.sup.4c R.sup.5gg R.sup.6b N175
R.sup.1b R.sup.3o R.sup.4c R.sup.5gg R.sup.6c N176 R.sup.1b
R.sup.3p R.sup.4e R.sup.5ff R.sup.6b N177 R.sup.1b R.sup.3p
R.sup.4e R.sup.5gg R.sup.6b N178 R.sup.1b R.sup.3q R.sup.4e
R.sup.5ff R.sup.6b N179 R.sup.1b R.sup.3q R.sup.4e R.sup.5gg
R.sup.6b N180 R.sup.1b R.sup.3r R.sup.4e R.sup.5ff R.sup.6b N181
R.sup.1b R.sup.3r R.sup.4e R.sup.5gg R.sup.6b N182 R.sup.1a
R.sup.3n R.sup.4c R.sup.5hh R.sup.6a N183 R.sup.1b R.sup.3o
R.sup.4c R.sup.5jj R.sup.6b N184 R.sup.1b R.sup.3o R.sup.4c
R.sup.5jj R.sup.6c N185 R.sup.1b R.sup.3p R.sup.4e R.sup.5hh
R.sup.6b N186 R.sup.1b R.sup.3p R.sup.4e R.sup.5jj R.sup.6b N187
R.sup.1b R.sup.3q R.sup.4e R.sup.5hh R.sup.6b N188 R.sup.1b
R.sup.3q R.sup.4e R.sup.5jj R.sup.6b N189 R.sup.1b R.sup.3r
R.sup.4e R.sup.5hh R.sup.6b N190 R.sup.1b R.sup.3r R.sup.4e
R.sup.5jj R.sup.6b N191 R.sup.1a R.sup.3n R.sup.4c R.sup.5kk
R.sup.6a N192 R.sup.1b R.sup.3o R.sup.4c R.sup.5ll R.sup.6b N193
R.sup.1b R.sup.3o R.sup.4c R.sup.5ll R.sup.6c N194 R.sup.1b
R.sup.3p R.sup.4e R.sup.5kk R.sup.6b N195 R.sup.1b R.sup.3p
R.sup.4e R.sup.5ll R.sup.6b N196 R.sup.1b R.sup.3q R.sup.4e
R.sup.5kk R.sup.6b N197 R.sup.1b R.sup.3q R.sup.4e R.sup.5ll
R.sup.6b N198 R.sup.1b R.sup.3r R.sup.4e R.sup.5kk R.sup.6b N199
R.sup.1b R.sup.3r R.sup.4e R.sup.5ll R.sup.6b N200 R.sup.1a
R.sup.3n R.sup.4c R.sup.5mm R.sup.6a N201 R.sup.1b R.sup.3o
R.sup.4c R.sup.5nn R.sup.6b N202 R.sup.1b R.sup.3o R.sup.4c
R.sup.5nn R.sup.6c N203 R.sup.1b R.sup.3p R.sup.4e R.sup.5mm
R.sup.6b N204 R.sup.1b R.sup.3p R.sup.4e R.sup.5nn R.sup.6b N205
R.sup.1b R.sup.3q R.sup.4e R.sup.5mm R.sup.6b N206 R.sup.1b
R.sup.3q R.sup.4e R.sup.5nn R.sup.6b N207 R.sup.1b R.sup.3r
R.sup.4e R.sup.5mm R.sup.6b N208 R.sup.1b R.sup.3r R.sup.4e
R.sup.5nn R.sup.6b N209 R.sup.1a R.sup.3n R.sup.4c R.sup.5nn
R.sup.6a N210 R.sup.1b R.sup.3o R.sup.4c R.sup.5nn R.sup.6b N211
R.sup.1b R.sup.3o R.sup.4c R.sup.5nn R.sup.6c N212 R.sup.1b
R.sup.3p R.sup.4e R.sup.5nn R.sup.6b N213 R.sup.1b R.sup.3p
R.sup.4e R.sup.5nn R.sup.6b N214 R.sup.1b R.sup.3q R.sup.4e
R.sup.5nn R.sup.6b N215 R.sup.1b R.sup.3q R.sup.4e R.sup.5nn
R.sup.6b N216 R.sup.1b R.sup.3r R.sup.4e R.sup.5nn R.sup.6b N217
R.sup.1b R.sup.3r R.sup.4e R.sup.5nn R.sup.6b N218 R.sup.1a
R.sup.3n R.sup.4c R.sup.5oo R.sup.6a N219 R.sup.1b R.sup.3o
R.sup.4c R.sup.5oo R.sup.6b N220 R.sup.1b R.sup.3o R.sup.4c
R.sup.5oo R.sup.6c N221 R.sup.1b R.sup.3p R.sup.4e R.sup.5oo
R.sup.6b N222 R.sup.1b R.sup.3p R.sup.4e R.sup.5oo R.sup.6b N223
R.sup.1b R.sup.3q R.sup.4e R.sup.5oo R.sup.6b N224 R.sup.1b
R.sup.3q R.sup.4e R.sup.5oo R.sup.6b N225 R.sup.1b R.sup.3r
R.sup.4e R.sup.5oo R.sup.6b N226 R.sup.1b R.sup.3r R.sup.4e
R.sup.5oo R.sup.6b N227 R.sup.1a R.sup.3n R.sup.4c R.sup.5pp
R.sup.6a N228 R.sup.1b R.sup.3o R.sup.4c R.sup.5qq R.sup.6b N229
R.sup.1b R.sup.3o R.sup.4c R.sup.5qq R.sup.6c N230 R.sup.1b
R.sup.3p R.sup.4e R.sup.5qq R.sup.6b N231 R.sup.1b R.sup.3p
R.sup.4e R.sup.5qq R.sup.6b N232 R.sup.1b R.sup.3q R.sup.4e
R.sup.5qq R.sup.6b N233 R.sup.1b R.sup.3q R.sup.4e R.sup.5qq
R.sup.6b N234 R.sup.1b R.sup.3r R.sup.4e R.sup.5qq R.sup.6b N235
R.sup.1b R.sup.3r R.sup.4e R.sup.5qq R.sup.6b N236 R.sup.1a
R.sup.3n R.sup.4c R.sup.5pp R.sup.6a N237 R.sup.1b R.sup.3o
R.sup.4c R.sup.5qq R.sup.6b N238 R.sup.1b R.sup.3o R.sup.4c
R.sup.5qq R.sup.6c N239 R.sup.1b R.sup.3p R.sup.4e R.sup.5qq
R.sup.6b N240 R.sup.1b R.sup.3p R.sup.4e R.sup.5qq R.sup.6b N241
R.sup.1b R.sup.3q R.sup.4e R.sup.5qq R.sup.6b N242 R.sup.1b
R.sup.3q R.sup.4e R.sup.5qq R.sup.6b N243 R.sup.1b R.sup.3r
R.sup.4e R.sup.5qq R.sup.6b N244 R.sup.1b R.sup.3r R.sup.4e
R.sup.5qq R.sup.6b N245 R.sup.1a R.sup.3n R.sup.4c R.sup.5rr
R.sup.6a N246 R.sup.1b R.sup.3o R.sup.4c R.sup.5rr R.sup.6b
N247 R.sup.1b R.sup.3o R.sup.4c R.sup.5rr R.sup.6c N248 R.sup.1b
R.sup.3p R.sup.4e R.sup.5rr R.sup.6b N249 R.sup.1b R.sup.3p
R.sup.4e R.sup.5rr R.sup.6b N250 R.sup.1b R.sup.3q R.sup.4e
R.sup.5rr R.sup.6b N251 R.sup.1b R.sup.3q R.sup.4e R.sup.5rr
R.sup.6b N252 R.sup.1b R.sup.3r R.sup.4e R.sup.5rr R.sup.6b N253
R.sup.1b R.sup.3r R.sup.4e R.sup.5rr R.sup.6b N254 R.sup.1b
R.sup.3s R.sup.4a R.sup.5ss R.sup.6b N255 R.sup.1b R.sup.3t
R.sup.4b R.sup.5ss R.sup.6b N256 R.sup.1b R.sup.3g R.sup.4e
R.sup.5ss R.sup.6b N257 R.sup.1b R.sup.3h R.sup.4e R.sup.5ss
R.sup.6b N258 R.sup.1b R.sup.3s R.sup.4a R.sup.5tt R.sup.6b N259
R.sup.1b R.sup.3t R.sup.4b R.sup.5tt R.sup.6b N260 R.sup.1b
R.sup.3g R.sup.4e R.sup.5tt R.sup.6b N261 R.sup.1b R.sup.3h
R.sup.4e R.sup.5tt R.sup.6b N262 R.sup.1b R.sup.3s R.sup.4a
R.sup.5uu R.sup.6b N263 R.sup.1b R.sup.3t R.sup.4b R.sup.5uu
R.sup.6b N264 R.sup.1b R.sup.3g R.sup.4e R.sup.5uu R.sup.6b N265
R.sup.1b R.sup.3h R.sup.4e R.sup.5uu R.sup.6b N266 R.sup.1b
R.sup.3s R.sup.4a R.sup.5vv R.sup.6b N267 R.sup.1b R.sup.3t
R.sup.4b R.sup.5vv R.sup.6b N268 R.sup.1b R.sup.3g R.sup.4e
R.sup.5vv R.sup.6b N269 R.sup.1b R.sup.3h R.sup.4e R.sup.5vv
R.sup.6b N270 R.sup.1b R.sup.3s R.sup.4a R.sup.5ww R.sup.6b N271
R.sup.1b R.sup.3t R.sup.4b R.sup.5ww R.sup.6b N272 R.sup.1b
R.sup.3g R.sup.4e R.sup.5ww R.sup.6b N273 R.sup.1b R.sup.3h
R.sup.4e R.sup.5ww R.sup.6b N274 R.sup.1b R.sup.3s R.sup.4a
R.sup.5xx R.sup.6b N275 R.sup.1b R.sup.3t R.sup.4b R.sup.5xx
R.sup.6b N276 R.sup.1b R.sup.3g R.sup.4e R.sup.5xx R.sup.6b N277
R.sup.1b R.sup.3h R.sup.4e R.sup.5xx R.sup.6b N278 R.sup.1b
R.sup.3s R.sup.4a R.sup.5zz R.sup.6b N279 R.sup.1b R.sup.3t
R.sup.4b R.sup.5zz R.sup.6b N280 R.sup.1b R.sup.3g R.sup.4e
R.sup.5zz R.sup.6b N281 R.sup.1b R.sup.3h R.sup.4e R.sup.5zz
R.sup.6b N282 R.sup.1b R.sup.3s R.sup.4a R.sup.5ba R.sup.6b N283
R.sup.1b R.sup.3t R.sup.4b R.sup.5ba R.sup.6b N284 R.sup.1b
R.sup.3g R.sup.4e R.sup.5ba R.sup.6b N285 R.sup.1b R.sup.3h
R.sup.4e R.sup.5ba R.sup.6b N286 R.sup.1b R.sup.3s R.sup.4a
R.sup.5bc R.sup.6b N287 R.sup.1b R.sup.3t R.sup.4b R.sup.5bc
R.sup.6b N288 R.sup.1b R.sup.3g R.sup.4e R.sup.5bc R.sup.6b N289
R.sup.1b R.sup.3h R.sup.4e R.sup.5bc R.sup.6b N290 R.sup.1b
R.sup.3s R.sup.4a R.sup.5bd R.sup.6b N291 R.sup.1b R.sup.3t
R.sup.4b R.sup.5bd R.sup.6b N292 R.sup.1b R.sup.3g R.sup.4e
R.sup.5bd R.sup.6b N293 R.sup.1b R.sup.3h R.sup.4e R.sup.5bd
R.sup.6b N294 R.sup.1b R.sup.3s R.sup.4a R.sup.5be R.sup.6b N295
R.sup.1b R.sup.3t R.sup.4b R.sup.5be R.sup.6b N296 R.sup.1b
R.sup.3g R.sup.4e R.sup.5be R.sup.6b N297 R.sup.1b R.sup.3h
R.sup.4e R.sup.5be R.sup.6b N298 R.sup.1b R.sup.3s R.sup.4a
R.sup.5bf R.sup.6b N299 R.sup.1b R.sup.3t R.sup.4b R.sup.5bf
R.sup.6b N300 R.sup.1b R.sup.3g R.sup.4e R.sup.5bf R.sup.6b N301
R.sup.1b R.sup.3h R.sup.4e R.sup.5bf R.sup.6b N302 R.sup.1b
R.sup.3s R.sup.4a R.sup.5bg R.sup.6b N303 R.sup.1b R.sup.3t
R.sup.4b R.sup.5bg R.sup.6b N304 R.sup.1b R.sup.3g R.sup.4e
R.sup.5bg R.sup.6b N305 R.sup.1b R.sup.3h R.sup.4e R.sup.5bg
R.sup.6b N306 R.sup.1b R.sup.3s R.sup.4a R.sup.5bh R.sup.6b N307
R.sup.1b R.sup.3t R.sup.4b R.sup.5bh R.sup.6b N308 R.sup.1b
R.sup.3g R.sup.4e R.sup.5bh R.sup.6b N309 R.sup.1b R.sup.3h
R.sup.4e R.sup.5bh R.sup.6b N310 R.sup.1b R.sup.3s R.sup.4a
R.sup.5bi R.sup.6b N311 R.sup.1b R.sup.3t R.sup.4b R.sup.5bi
R.sup.6b N312 R.sup.1b R.sup.3g R.sup.4e R.sup.5bi R.sup.6b N313
R.sup.1b R.sup.3h R.sup.4e R.sup.5bi R.sup.6b N314 R.sup.1b
R.sup.3s R.sup.4a R.sup.5bj R.sup.6b N315 R.sup.1b R.sup.3t
R.sup.4b R.sup.5bj R.sup.6b N316 R.sup.1b R.sup.3g R.sup.4e
R.sup.5bj R.sup.6b N317 R.sup.1b R.sup.3h R.sup.4e R.sup.5bj
R.sup.6b N318 R.sup.1b R.sup.3s R.sup.4a R.sup.5bk R.sup.6b N319
R.sup.1b R.sup.3t R.sup.4b R.sup.5bk R.sup.6b N320 R.sup.1b
R.sup.3g R.sup.4e R.sup.5bk R.sup.6b N321 R.sup.1b R.sup.3h
R.sup.4e R.sup.5bk R.sup.6b N322 R.sup.1b R.sup.3s R.sup.4a
R.sup.5bl R.sup.6b N323 R.sup.1b R.sup.3t R.sup.4b R.sup.5bl
R.sup.6b N324 R.sup.1b R.sup.3g R.sup.4e R.sup.5bl R.sup.6b N325
R.sup.1b R.sup.3h R.sup.4e R.sup.5bl R.sup.6b N326 R.sup.1b
R.sup.3s R.sup.4a R.sup.5bm R.sup.6b N327 R.sup.1b R.sup.3t
R.sup.4b R.sup.5bm R.sup.6b N328 R.sup.1b R.sup.3g R.sup.4e
R.sup.5bm R.sup.6b N329 R.sup.1b R.sup.3h R.sup.4e R.sup.5bm
R.sup.6b N330 R.sup.1b R.sup.3s R.sup.4a R.sup.5bn R.sup.6b N331
R.sup.1b R.sup.3t R.sup.4b R.sup.5bn R.sup.6b N332 R.sup.1b
R.sup.3g R.sup.4e R.sup.5bn R.sup.6b N333 R.sup.1b R.sup.3h
R.sup.4e R.sup.5bn R.sup.6b N334 R.sup.1b R.sup.3s R.sup.4a
R.sup.5bo R.sup.6b N335 R.sup.1b R.sup.3t R.sup.4b R.sup.5bo
R.sup.6b N336 R.sup.1b R.sup.3g R.sup.4e R.sup.5bo R.sup.6b N337
R.sup.1b R.sup.3h R.sup.4e R.sup.5bo R.sup.6b N338 R.sup.1b
R.sup.3s R.sup.4a R.sup.5bp R.sup.6b N339 R.sup.1b R.sup.3t
R.sup.4b R.sup.5bp R.sup.6b N340 R.sup.1b R.sup.3g R.sup.4e
R.sup.5bp R.sup.6b N341 R.sup.1b R.sup.3h R.sup.4e R.sup.5bp
R.sup.6b N342 R.sup.1b R.sup.3s R.sup.4a R.sup.5bq R.sup.6b N343
R.sup.1b R.sup.3t R.sup.4b R.sup.5bq R.sup.6b N344 R.sup.1b
R.sup.3g R.sup.4e R.sup.5bq R.sup.6b N345 R.sup.1b R.sup.3h
R.sup.4e R.sup.5bq R.sup.6b N346 R.sup.1b R.sup.3s R.sup.4a
R.sup.5br R.sup.6b N347 R.sup.1b R.sup.3t R.sup.4b R.sup.5bq
R.sup.6b N348 R.sup.1b R.sup.3g R.sup.4e R.sup.5bq R.sup.6b N349
R.sup.1b R.sup.3h R.sup.4e R.sup.5bq R.sup.6b N350 R.sup.1b
R.sup.3s R.sup.4a R.sup.5bs R.sup.6b N351 R.sup.1b R.sup.3t
R.sup.4b R.sup.5bs R.sup.6b N352 R.sup.1b R.sup.3g R.sup.4e
R.sup.5bs R.sup.6b N353 R.sup.1b R.sup.3h R.sup.4e R.sup.5bs
R.sup.6b N354 R.sup.1b R.sup.3s R.sup.4a R.sup.5bt R.sup.6b N355
R.sup.1b R.sup.3t R.sup.4b R.sup.5bt R.sup.6b N356 R.sup.1b
R.sup.3g R.sup.4e R.sup.5bt R.sup.6b N357 R.sup.1b R.sup.3h
R.sup.4e R.sup.5bt R.sup.6b N358 R.sup.1b R.sup.3s R.sup.4a
R.sup.5bu R.sup.6b N359 R.sup.1b R.sup.3t R.sup.4b R.sup.5bu
R.sup.6b N360 R.sup.1b R.sup.3g R.sup.4e R.sup.5bu R.sup.6b N361
R.sup.1b R.sup.3h R.sup.4e R.sup.5bu R.sup.6b N362 R.sup.1b
R.sup.3s R.sup.4a R.sup.5bv R.sup.6b N363 R.sup.1b R.sup.3t
R.sup.4b R.sup.5bv R.sup.6b N364 R.sup.1b R.sup.3g R.sup.4e
R.sup.5bv R.sup.6b N365 R.sup.1b R.sup.3h R.sup.4e R.sup.5bv
R.sup.6b N366 R.sup.1b R.sup.3s R.sup.4a R.sup.5bw R.sup.6b N367
R.sup.1b R.sup.3t R.sup.4b R.sup.5bw R.sup.6b N368 R.sup.1b
R.sup.3g R.sup.4e R.sup.5bw R.sup.6b N369 R.sup.1b R.sup.3h
R.sup.4e R.sup.5bw R.sup.6b N370 R.sup.1b R.sup.3s R.sup.4a
R.sup.5bx R.sup.6b N371 R.sup.1b R.sup.3t R.sup.4b R.sup.5bx
R.sup.6b N372 R.sup.1b R.sup.3g R.sup.4e R.sup.5bx R.sup.6b N373
R.sup.1b R.sup.3h R.sup.4e R.sup.5bx R.sup.6b N374 R.sup.1b
R.sup.3s R.sup.4a R.sup.5by R.sup.6b N375 R.sup.1b R.sup.3t
R.sup.4b R.sup.5by R.sup.6b N376 R.sup.1b R.sup.3g R.sup.4e
R.sup.5by R.sup.6b N377 R.sup.1b R.sup.3h R.sup.4e R.sup.5by
R.sup.6b N378 R.sup.1b R.sup.3s R.sup.4a R.sup.5bz R.sup.6b N379
R.sup.1b R.sup.3t R.sup.4b R.sup.5bz R.sup.6b N380 R.sup.1b
R.sup.3g R.sup.4e R.sup.5bz R.sup.6b N381 R.sup.1b R.sup.3h
R.sup.4e R.sup.5bz R.sup.6b N382 R.sup.1b R.sup.3s R.sup.4a
R.sup.5ca R.sup.6b N383 R.sup.1b R.sup.3t R.sup.4b R.sup.5ca
R.sup.6b N384 R.sup.1b R.sup.3g R.sup.4e R.sup.5ca R.sup.6b N385
R.sup.1b R.sup.3h R.sup.4e R.sup.5ca R.sup.6b N386 R.sup.1b
R.sup.3s R.sup.4a R.sup.5cb R.sup.6b N387 R.sup.1b R.sup.3t
R.sup.4b R.sup.5cb R.sup.6b N388 R.sup.1b R.sup.3g R.sup.4e
R.sup.5cb R.sup.6b N389 R.sup.1b R.sup.3h R.sup.4e R.sup.5cb
R.sup.6b N390 R.sup.1b R.sup.3s R.sup.4a R.sup.5cd R.sup.6b N391
R.sup.1b R.sup.3t R.sup.4b R.sup.5cd R.sup.6b N392 R.sup.1b
R.sup.3g R.sup.4e R.sup.5cd R.sup.6b N393 R.sup.1b R.sup.3h
R.sup.4e R.sup.5cd R.sup.6b N394 R.sup.1b R.sup.3s R.sup.4a
R.sup.5ce R.sup.6b N395 R.sup.1b R.sup.3t R.sup.4b R.sup.5ce
R.sup.6b N396 R.sup.1b R.sup.3g R.sup.4e R.sup.5ce R.sup.6b N397
R.sup.1b R.sup.3h R.sup.4e R.sup.5ce R.sup.6b N398 R.sup.1b
R.sup.3s R.sup.4a R.sup.5cf R.sup.6b N399 R.sup.1b R.sup.3t
R.sup.4b R.sup.5cf R.sup.6b N400 R.sup.1b R.sup.3g R.sup.4e
R.sup.5cf R.sup.6b N401 R.sup.1b R.sup.3h R.sup.4e R.sup.5cf
R.sup.6b N402 R.sup.1b R.sup.3s R.sup.4a R.sup.5cg R.sup.6b N403
R.sup.1b R.sup.3t R.sup.4b R.sup.5cg R.sup.6b N404 R.sup.1b
R.sup.3g R.sup.4e R.sup.5cg R.sup.6b N405 R.sup.1b R.sup.3h
R.sup.4e R.sup.5cg R.sup.6b N406 R.sup.1b R.sup.3s R.sup.4a
R.sup.5ch R.sup.6b N407 R.sup.1b R.sup.3t R.sup.4b R.sup.5ch
R.sup.6b N408 R.sup.1b R.sup.3g R.sup.4e R.sup.5ch R.sup.6b N409
R.sup.1b R.sup.3h R.sup.4e R.sup.5ch R.sup.6b N410 R.sup.1b
R.sup.3s R.sup.4a R.sup.5ci R.sup.6b N411 R.sup.1b R.sup.3t
R.sup.4b R.sup.5ci R.sup.6b N412 R.sup.1b R.sup.3g R.sup.4e
R.sup.5ci R.sup.6b N413 R.sup.1b R.sup.3h R.sup.4e R.sup.5ci
R.sup.6b N414 R.sup.1b R.sup.3s R.sup.4a R.sup.5cj R.sup.6b N415
R.sup.1b R.sup.3t R.sup.4b R.sup.5cj R.sup.6b N416 R.sup.1b
R.sup.3g R.sup.4e R.sup.5cj R.sup.6b N417 R.sup.1b R.sup.3h
R.sup.4e R.sup.5cj R.sup.6b N418 R.sup.1b R.sup.3s R.sup.4a
R.sup.5ck R.sup.6b N419 R.sup.1b R.sup.3t R.sup.4b R.sup.5ck
R.sup.6b N420 R.sup.1b R.sup.3g R.sup.4e R.sup.5ck R.sup.6b N421
R.sup.1b R.sup.3h R.sup.4e R.sup.5ck R.sup.6b N422 R.sup.1b
R.sup.3s R.sup.4a R.sup.5cl R.sup.6b N423 R.sup.1b R.sup.3t
R.sup.4b R.sup.5cl R.sup.6b N424 R.sup.1b R.sup.3g R.sup.4e
R.sup.5cl R.sup.6b N425 R.sup.1b R.sup.3h R.sup.4e R.sup.5cl
R.sup.6b N426 R.sup.1b R.sup.3s R.sup.4a R.sup.5cm R.sup.6b N427
R.sup.1b R.sup.3t R.sup.4b R.sup.5cm R.sup.6b N428 R.sup.1b
R.sup.3g R.sup.4e R.sup.5cm R.sup.6b N429 R.sup.1b R.sup.3h
R.sup.4e R.sup.5cm R.sup.6b N430 R.sup.1b R.sup.3s R.sup.4a
R.sup.5cn R.sup.6b N431 R.sup.1b R.sup.3t R.sup.4b R.sup.5cn
R.sup.6b N432 R.sup.1b R.sup.3g R.sup.4e R.sup.5cn R.sup.6b N433
R.sup.1b R.sup.3h R.sup.4e R.sup.5cn R.sup.6b N434 R.sup.1b
R.sup.3s R.sup.4a R.sup.5co R.sup.6b N435 R.sup.1b R.sup.3t
R.sup.4b R.sup.5co R.sup.6b N436 R.sup.1b R.sup.3g R.sup.4e
R.sup.5co R.sup.6b N437 R.sup.1b R.sup.3h R.sup.4e R.sup.5co
R.sup.6b N438 R.sup.1b R.sup.3s R.sup.4a R.sup.5cp R.sup.6b N439
R.sup.1b R.sup.3t R.sup.4b R.sup.5cp R.sup.6b N440 R.sup.1b
R.sup.3g R.sup.4e R.sup.5cp R.sup.6b N441 R.sup.1b R.sup.3h
R.sup.4e R.sup.5cp R.sup.6b N442 R.sup.1b R.sup.3s R.sup.4a
R.sup.5cq R.sup.6b N443 R.sup.1b R.sup.3t R.sup.4b R.sup.5cq
R.sup.6b N444 R.sup.1b R.sup.3g R.sup.4e R.sup.5cq R.sup.6b N445
R.sup.1b R.sup.3h R.sup.4e R.sup.5cq R.sup.6b N446 R.sup.1b
R.sup.3s R.sup.4a R.sup.5cr R.sup.6b N447 R.sup.1b R.sup.3t
R.sup.4b R.sup.5cr R.sup.6b N448 R.sup.1b R.sup.3g R.sup.4e
R.sup.5cr R.sup.6b N449 R.sup.1b R.sup.3h R.sup.4e R.sup.5cr
R.sup.6b N450 R.sup.1b R.sup.3s R.sup.4a R.sup.5cs R.sup.6b N451
R.sup.1b R.sup.3t R.sup.4b R.sup.5cs R.sup.6b N452 R.sup.1b
R.sup.3g R.sup.4e R.sup.5cs R.sup.6b N453 R.sup.1b R.sup.3h
R.sup.4e R.sup.5cs R.sup.6b N454 R.sup.1b R.sup.3s R.sup.4a
R.sup.5ct R.sup.6b N455 R.sup.1b R.sup.3t R.sup.4b R.sup.5ct
R.sup.6b N456 R.sup.1b R.sup.3g R.sup.4e R.sup.5ct R.sup.6b N457
R.sup.1b R.sup.3h R.sup.4e R.sup.5ct R.sup.6b N458 R.sup.1b
R.sup.3s R.sup.4a R.sup.5cu R.sup.6b N459 R.sup.1b R.sup.3t
R.sup.4b R.sup.5cu R.sup.6b N460 R.sup.1b R.sup.3g R.sup.4e
R.sup.5cu R.sup.6b N461 R.sup.1b R.sup.3h R.sup.4e R.sup.5cu
R.sup.6b N462 R.sup.1b R.sup.3s R.sup.4a R.sup.5cv R.sup.6b N463
R.sup.1b R.sup.3t R.sup.4b R.sup.5cv R.sup.6b N464 R.sup.1b
R.sup.3g R.sup.4e R.sup.5cv R.sup.6b N465 R.sup.1b R.sup.3h
R.sup.4e R.sup.5cv R.sup.6b N466 R.sup.1b R.sup.3s R.sup.4a
R.sup.5cw R.sup.6b N467 R.sup.1b R.sup.3t R.sup.4b R.sup.5cw
R.sup.6b N468 R.sup.1b R.sup.3g R.sup.4e R.sup.5cw R.sup.6b N469
R.sup.1b R.sup.3h R.sup.4e R.sup.5cw R.sup.6b N470 R.sup.1b
R.sup.3s R.sup.4a R.sup.5cx R.sup.6b N471 R.sup.1b R.sup.3t
R.sup.4b R.sup.5cx R.sup.6b N472 R.sup.1b R.sup.3g R.sup.4e
R.sup.5cx R.sup.6b N473 R.sup.1b R.sup.3h R.sup.4e R.sup.5cx
R.sup.6b N474 R.sup.1b R.sup.3s R.sup.4a R.sup.5cy R.sup.6b N475
R.sup.1b R.sup.3t R.sup.4b R.sup.5cy R.sup.6b N476 R.sup.1b
R.sup.3g R.sup.4e R.sup.5cy R.sup.6b N477 R.sup.1b R.sup.3h
R.sup.4e R.sup.5cy R.sup.6b N478 R.sup.1b R.sup.3s R.sup.4a
R.sup.5cz R.sup.6b N479 R.sup.1b R.sup.3t R.sup.4b R.sup.5cz
R.sup.6b N480 R.sup.1b R.sup.3g R.sup.4e R.sup.5cz R.sup.6b N481
R.sup.1b R.sup.3h R.sup.4e R.sup.5cz R.sup.6b N482 R.sup.1b
R.sup.3s R.sup.4a R.sup.5da R.sup.6b N483 R.sup.1b R.sup.3t
R.sup.4b R.sup.5da R.sup.6b N484 R.sup.1b R.sup.3g R.sup.4e
R.sup.5da R.sup.6b N485 R.sup.1b R.sup.3h R.sup.4e R.sup.5da
R.sup.6b N486 R.sup.1b R.sup.3s R.sup.4a R.sup.5db R.sup.6b N487
R.sup.1b R.sup.3t R.sup.4b R.sup.5db R.sup.6b N488 R.sup.1b
R.sup.3g R.sup.4e R.sup.5db R.sup.6b N489 R.sup.1b R.sup.3h
R.sup.4e R.sup.5db R.sup.6b N490 R.sup.1b R.sup.3s R.sup.4a
R.sup.5dc R.sup.6b N491 R.sup.1b R.sup.3t R.sup.4b R.sup.5dc
R.sup.6b N492 R.sup.1b R.sup.3g R.sup.4e R.sup.5dc R.sup.6b N493
R.sup.1b R.sup.3h R.sup.4e R.sup.5dc R.sup.6b N494 R.sup.1b
R.sup.3s R.sup.4a R.sup.5de R.sup.6b N495 R.sup.1b R.sup.3t
R.sup.4b R.sup.5de R.sup.6b N496 R.sup.1b R.sup.3g R.sup.4e
R.sup.5de R.sup.6b N497 R.sup.1b R.sup.3h R.sup.4e R.sup.5de
R.sup.6b
N498 R.sup.1b R.sup.3s R.sup.4a R.sup.5df R.sup.6b N499 R.sup.1b
R.sup.3t R.sup.4b R.sup.5df R.sup.6b N500 R.sup.1b R.sup.3g
R.sup.4e R.sup.5df R.sup.6b N501 R.sup.1b R.sup.3h R.sup.4e
R.sup.5df R.sup.6b N502 R.sup.1b R.sup.3s R.sup.4a R.sup.5dg
R.sup.6b N503 R.sup.1b R.sup.3t R.sup.4b R.sup.5dg R.sup.6b N504
R.sup.1b R.sup.3g R.sup.4e R.sup.5dg R.sup.6b N505 R.sup.1b
R.sup.3h R.sup.4e R.sup.5dg R.sup.6b N506 R.sup.1b R.sup.3s
R.sup.4a R.sup.5dh R.sup.6b N507 R.sup.1b R.sup.3t R.sup.4b
R.sup.5dh R.sup.6b N508 R.sup.1b R.sup.3g R.sup.4e R.sup.5dh
R.sup.6b N509 R.sup.1b R.sup.3h R.sup.4e R.sup.5dh R.sup.6b N510
R.sup.1b R.sup.3s R.sup.4a R.sup.5di R.sup.6b N511 R.sup.1b
R.sup.3t R.sup.4b R.sup.5di R.sup.6b N512 R.sup.1b R.sup.3g
R.sup.4e R.sup.5di R.sup.6b N513 R.sup.1b R.sup.3h R.sup.4e
R.sup.5di R.sup.6b N514 R.sup.1b R.sup.3s R.sup.4a R.sup.5dj
R.sup.6b N515 R.sup.1b R.sup.3t R.sup.4b R.sup.5dj R.sup.6b N516
R.sup.1b R.sup.3g R.sup.4e R.sup.5dj R.sup.6b N517 R.sup.1b
R.sup.3h R.sup.4e R.sup.5dj R.sup.6b N518 R.sup.1b R.sup.3s
R.sup.4a R.sup.5dk R.sup.6b N519 R.sup.1b R.sup.3t R.sup.4b
R.sup.5dk R.sup.6b N520 R.sup.1b R.sup.3g R.sup.4e R.sup.5dk
R.sup.6b N521 R.sup.1b R.sup.3h R.sup.4e R.sup.5dk R.sup.6b N522
R.sup.1b R.sup.3s R.sup.4a R.sup.5dl R.sup.6b N523 R.sup.1b
R.sup.3t R.sup.4b R.sup.5dl R.sup.6b N524 R.sup.1b R.sup.3g
R.sup.4e R.sup.5dl R.sup.6b N525 R.sup.1b R.sup.3h R.sup.4e
R.sup.5dl R.sup.6b N526 R.sup.1b R.sup.3s R.sup.4a R.sup.5dm
R.sup.6b N527 R.sup.1b R.sup.3t R.sup.4b R.sup.5dm R.sup.6b N528
R.sup.1b R.sup.3g R.sup.4e R.sup.5dm R.sup.6b N529 R.sup.1b
R.sup.3h R.sup.4e R.sup.5dm R.sup.6b N530 R.sup.1b R.sup.3s
R.sup.4a R.sup.5dn R.sup.6b N531 R.sup.1b R.sup.3t R.sup.4b
R.sup.5dn R.sup.6b N532 R.sup.1b R.sup.3g R.sup.4e R.sup.5dn
R.sup.6b N533 R.sup.1b R.sup.3h R.sup.4e R.sup.5dn R.sup.6b N534
R.sup.1b R.sup.3s R.sup.4a R.sup.5do R.sup.6b N535 R.sup.1b
R.sup.3t R.sup.4b R.sup.5do R.sup.6b N536 R.sup.1b R.sup.3g
R.sup.4e R.sup.5do R.sup.6b N537 R.sup.1b R.sup.3h R.sup.4e
R.sup.5do R.sup.6b N538 R.sup.1b R.sup.3s R.sup.4a R.sup.5dp
R.sup.6b N539 R.sup.1b R.sup.3t R.sup.4b R.sup.5dp R.sup.6b N540
R.sup.1b R.sup.3g R.sup.4e R.sup.5dp R.sup.6b N541 R.sup.1b
R.sup.3h R.sup.4e R.sup.5dp R.sup.6b N542 R.sup.1b R.sup.3s
R.sup.4a R.sup.5dq R.sup.6b N543 R.sup.1b R.sup.3t R.sup.4b
R.sup.5dq R.sup.6b N544 R.sup.1b R.sup.3g R.sup.4e R.sup.5dq
R.sup.6b N545 R.sup.1b R.sup.3h R.sup.4e R.sup.5dq R.sup.6b N546
R.sup.1b R.sup.3s R.sup.4a R.sup.5dr R.sup.6b N547 R.sup.1b
R.sup.3t R.sup.4b R.sup.5dr R.sup.6b N548 R.sup.1b R.sup.3g
R.sup.4e R.sup.5dr R.sup.6b N549 R.sup.1b R.sup.3h R.sup.4e
R.sup.5dr R.sup.6b N550 R.sup.1b R.sup.3s R.sup.4a R.sup.5ds
R.sup.6b N551 R.sup.1b R.sup.3t R.sup.4b R.sup.5ds R.sup.6b N552
R.sup.1b R.sup.3g R.sup.4e R.sup.5ds R.sup.6b N553 R.sup.1b
R.sup.3h R.sup.4e R.sup.5ds R.sup.6b N554 R.sup.1b R.sup.3s
R.sup.4a R.sup.5dt R.sup.6b N555 R.sup.1b R.sup.3t R.sup.4b
R.sup.5dt R.sup.6b N556 R.sup.1b R.sup.3g R.sup.4e R.sup.5dt
R.sup.6b N557 R.sup.1b R.sup.3h R.sup.4e R.sup.5dt R.sup.6b N558
R.sup.1b R.sup.3s R.sup.4a R.sup.5du R.sup.6b N559 R.sup.1b
R.sup.3t R.sup.4b R.sup.5du R.sup.6b N560 R.sup.1b R.sup.3g
R.sup.4e R.sup.5du R.sup.6b N561 R.sup.1b R.sup.3h R.sup.4e
R.sup.5du R.sup.6b N562 R.sup.1b R.sup.3s R.sup.4a R.sup.5dv
R.sup.6b N563 R.sup.1b R.sup.3t R.sup.4b R.sup.5dv R.sup.6b N564
R.sup.1b R.sup.3g R.sup.4e R.sup.5dv R.sup.6b N565 R.sup.1b
R.sup.3h R.sup.4e R.sup.5dv R.sup.6b N566 R.sup.1b R.sup.3s
R.sup.4a R.sup.5dw R.sup.6b N567 R.sup.1b R.sup.3t R.sup.4b
R.sup.5dw R.sup.6b N568 R.sup.1b R.sup.3g R.sup.4e R.sup.5dw
R.sup.6b N569 R.sup.1b R.sup.3h R.sup.4e R.sup.5dw R.sup.6b N570
R.sup.1b R.sup.3s R.sup.4a R.sup.5dx R.sup.6b N571 R.sup.1b
R.sup.3t R.sup.4b R.sup.5dx R.sup.6b N572 R.sup.1b R.sup.3g
R.sup.4e R.sup.5dx R.sup.6b N573 R.sup.1b R.sup.3h R.sup.4e
R.sup.5dx R.sup.6b N574 R.sup.1b R.sup.3s R.sup.4a R.sup.5ea
R.sup.6b N575 R.sup.1b R.sup.3t R.sup.4b R.sup.5ea R.sup.6b N576
R.sup.1b R.sup.3g R.sup.4e R.sup.5ea R.sup.6b N577 R.sup.1b
R.sup.3h R.sup.4e R.sup.5ea R.sup.6b N578 R.sup.1b R.sup.3s
R.sup.4a R.sup.5eb R.sup.6b N579 R.sup.1b R.sup.3t R.sup.4b
R.sup.5eb R.sup.6b N580 R.sup.1b R.sup.3g R.sup.4e R.sup.5eb
R.sup.6b N581 R.sup.1b R.sup.3h R.sup.4e R.sup.5eb R.sup.6b N582
R.sup.1b R.sup.3s R.sup.4a R.sup.5ec R.sup.6b N583 R.sup.1b
R.sup.3t R.sup.4b R.sup.5ec R.sup.6b N584 R.sup.1b R.sup.3g
R.sup.4e R.sup.5ec R.sup.6b N585 R.sup.1b R.sup.3h R.sup.4e
R.sup.5ec R.sup.6b N586 R.sup.1b R.sup.3s R.sup.4a R.sup.5ed
R.sup.6b N587 R.sup.1b R.sup.3t R.sup.4b R.sup.5ed R.sup.6b N588
R.sup.1b R.sup.3g R.sup.4e R.sup.5ed R.sup.6b N589 R.sup.1b
R.sup.3h R.sup.4e R.sup.5ed R.sup.6b N590 R.sup.1b R.sup.3s
R.sup.4a R.sup.5ef R.sup.6b N591 R.sup.1b R.sup.3t R.sup.4b
R.sup.5ef R.sup.6b N592 R.sup.1b R.sup.3g R.sup.4e R.sup.5ef
R.sup.6b N593 R.sup.1b R.sup.3h R.sup.4e R.sup.5ef R.sup.6b N594
R.sup.1b R.sup.3s R.sup.4a R.sup.5eg R.sup.6b N595 R.sup.1b
R.sup.3t R.sup.4b R.sup.5eg R.sup.6b N596 R.sup.1b R.sup.3g
R.sup.4e R.sup.5eg R.sup.6b N597 R.sup.1b R.sup.3h R.sup.4e
R.sup.5eg R.sup.6b N598 R.sup.1b R.sup.3s R.sup.4a R.sup.5eh
R.sup.6b N599 R.sup.1b R.sup.3t R.sup.4b R.sup.5eh R.sup.6b N600
R.sup.1b R.sup.3g R.sup.4e R.sup.5eh R.sup.6b N601 R.sup.1b
R.sup.3h R.sup.4e R.sup.5eh R.sup.6b N602 R.sup.1b R.sup.3s
R.sup.4a R.sup.5ei R.sup.6b N603 R.sup.1b R.sup.3t R.sup.4b
R.sup.5ei R.sup.6b N604 R.sup.1b R.sup.3g R.sup.4e R.sup.5ei
R.sup.6b N605 R.sup.1b R.sup.3h R.sup.4e R.sup.5ei R.sup.6b N606
R.sup.1b R.sup.3s R.sup.4a R.sup.5ej R.sup.6b N607 R.sup.1b
R.sup.3t R.sup.4b R.sup.5ej R.sup.6b N608 R.sup.1b R.sup.3g
R.sup.4e R.sup.5ej R.sup.6b N609 R.sup.1b R.sup.3h R.sup.4e
R.sup.5ej R.sup.6b N610 R.sup.1b R.sup.3s R.sup.4a R.sup.5ek
R.sup.6b N611 R.sup.1b R.sup.3t R.sup.4b R.sup.5ej R.sup.6b N612
R.sup.1b R.sup.3g R.sup.4e R.sup.5ej R.sup.6b N613 R.sup.1b
R.sup.3h R.sup.4e R.sup.5ej R.sup.6b N614 R.sup.1b R.sup.3s
R.sup.4a R.sup.5el R.sup.6b N615 R.sup.1b R.sup.3t R.sup.4b
R.sup.5el R.sup.6b N616 R.sup.1b R.sup.3g R.sup.4e R.sup.5el
R.sup.6b N617 R.sup.1b R.sup.3h R.sup.4e R.sup.5el R.sup.6b N618
R.sup.1b R.sup.3s R.sup.4a R.sup.5em R.sup.6b N619 R.sup.1b
R.sup.3t R.sup.4b R.sup.5em R.sup.6b N620 R.sup.1b R.sup.3g
R.sup.4e R.sup.5em R.sup.6b N621 R.sup.1b R.sup.3h R.sup.4e
R.sup.5em R.sup.6b N622 R.sup.1b R.sup.3s R.sup.4a R.sup.5en
R.sup.6b N623 R.sup.1b R.sup.3t R.sup.4b R.sup.5en R.sup.6b N624
R.sup.1b R.sup.3g R.sup.4e R.sup.5en R.sup.6b N625 R.sup.1b
R.sup.3h R.sup.4e R.sup.5en R.sup.6b N626 R.sup.1b R.sup.3s
R.sup.4a R.sup.5eo R.sup.6b N627 R.sup.1b R.sup.3t R.sup.4b
R.sup.5eo R.sup.6b N628 R.sup.1b R.sup.3g R.sup.4e R.sup.5eo
R.sup.6b N629 R.sup.1b R.sup.3h R.sup.4e R.sup.5eo R.sup.6b N630
R.sup.1b R.sup.3s R.sup.4a R.sup.5ep R.sup.6b N631 R.sup.1b
R.sup.3t R.sup.4b R.sup.5ep R.sup.6b N632 R.sup.1b R.sup.3g
R.sup.4e R.sup.5ep R.sup.6b N633 R.sup.1b R.sup.3h R.sup.4e
R.sup.5ep R.sup.6b N634 R.sup.1b R.sup.3s R.sup.4a R.sup.5eq
R.sup.6b N635 R.sup.1b R.sup.3t R.sup.4b R.sup.5eq R.sup.6b N636
R.sup.1b R.sup.3q R.sup.4e R.sup.5eq R.sup.6b N637 R.sup.1b
R.sup.3h R.sup.4e R.sup.5eq R.sup.6b N638 R.sup.1b R.sup.3s
R.sup.4a R.sup.5er R.sup.6b N639 R.sup.1b R.sup.3t R.sup.4b
R.sup.5er R.sup.6b N640 R.sup.1b R.sup.3g R.sup.4e R.sup.5er
R.sup.6b N641 R.sup.1b R.sup.3h R.sup.4e R.sup.5er R.sup.6b N642
R.sup.1b R.sup.3s R.sup.4a R.sup.5es R.sup.6b N643 R.sup.1b
R.sup.3t R.sup.4b R.sup.5es R.sup.6b N644 R.sup.1b R.sup.3g
R.sup.4e R.sup.5es R.sup.6b N645 R.sup.1b R.sup.3h R.sup.4e
R.sup.5es R.sup.6b N646 R.sup.1b R.sup.3s R.sup.4a R.sup.5et
R.sup.6b N647 R.sup.1b R.sup.3t R.sup.4b R.sup.5et R.sup.6b N648
R.sup.1b R.sup.3g R.sup.4e R.sup.5et R.sup.6b N649 R.sup.1b
R.sup.3h R.sup.4e R.sup.5et R.sup.6b N650 R.sup.1b R.sup.3s
R.sup.4a R.sup.5eu R.sup.6b N651 R.sup.1b R.sup.3t R.sup.4b
R.sup.5eu R.sup.6b N652 R.sup.1b R.sup.3g R.sup.4e R.sup.5eu
R.sup.6b N653 R.sup.1b R.sup.3h R.sup.4e R.sup.5eu R.sup.6b N654
R.sup.1b R.sup.3s R.sup.4a R.sup.5ev R.sup.6b N655 R.sup.1b
R.sup.3t R.sup.4b R.sup.5ev R.sup.6b N656 R.sup.1b R.sup.3g
R.sup.4e R.sup.5ev R.sup.6b N657 R.sup.1b R.sup.3h R.sup.4e
R.sup.5ev R.sup.6b N658 R.sup.1b R.sup.3s R.sup.4a R.sup.5ex
R.sup.6b N659 R.sup.1b R.sup.3t R.sup.4b R.sup.5ex R.sup.6b N660
R.sup.1b R.sup.3g R.sup.4e R.sup.5ex R.sup.6b N661 R.sup.1b
R.sup.3h R.sup.4e R.sup.5ex R.sup.6b N662 R.sup.1b R.sup.3s
R.sup.4a R.sup.5ey R.sup.6b N663 R.sup.1b R.sup.3t R.sup.4b
R.sup.5ey R.sup.6b N664 R.sup.1b R.sup.3g R.sup.4e R.sup.5ey
R.sup.6b N665 R.sup.1b R.sup.3h R.sup.4e R.sup.5ey R.sup.6b N666
R.sup.1b R.sup.3s R.sup.4a R.sup.5ez R.sup.6b N667 R.sup.1b
R.sup.3t R.sup.4b R.sup.5ez R.sup.6b N668 R.sup.1b R.sup.3g
R.sup.4e R.sup.5ez R.sup.6b N669 R.sup.1b R.sup.3h R.sup.4e
R.sup.5ez R.sup.6b N670 R.sup.1b R.sup.3s R.sup.4a R.sup.5fa
R.sup.6b N671 R.sup.1b R.sup.3t R.sup.4b R.sup.5fa R.sup.6b N672
R.sup.1b R.sup.3g R.sup.4e R.sup.5fa R.sup.6b N673 R.sup.1b
R.sup.3h R.sup.4e R.sup.5fa R.sup.6b N674 R.sup.1b R.sup.3s
R.sup.4a R.sup.5fb R.sup.6b N675 R.sup.1b R.sup.3t R.sup.4b
R.sup.5fb R.sup.6b N676 R.sup.1b R.sup.3g R.sup.4e R.sup.5fb
R.sup.6b N677 R.sup.1b R.sup.3h R.sup.4e R.sup.5fb R.sup.6b N678
R.sup.1b R.sup.3s R.sup.4a R.sup.5fc R.sup.6b N679 R.sup.1b
R.sup.3t R.sup.4b R.sup.5fc R.sup.6b N680 R.sup.1b R.sup.3g
R.sup.4e R.sup.5fc R.sup.6b N681 R.sup.1b R.sup.3h R.sup.4e
R.sup.5fc R.sup.6b N682 R.sup.1b R.sup.3s R.sup.4a R.sup.5fd
R.sup.6b N683 R.sup.1b R.sup.3t R.sup.4b R.sup.5fd R.sup.6b N684
R.sup.1b R.sup.3g R.sup.4e R.sup.5fd R.sup.6b N685 R.sup.1b
R.sup.3h R.sup.4e R.sup.5fd R.sup.6b N686 R.sup.1b R.sup.3s
R.sup.4a R.sup.5fe R.sup.6b N687 R.sup.1b R.sup.3t R.sup.4b
R.sup.5fe R.sup.6b N688 R.sup.1b R.sup.3g R.sup.4e R.sup.5fe
R.sup.6b N689 R.sup.1b R.sup.3h R.sup.4e R.sup.5fe R.sup.6b N690
R.sup.1b R.sup.3s R.sup.4a R.sup.5fg R.sup.6b N691 R.sup.1b
R.sup.3t R.sup.4b R.sup.5fg R.sup.6b N692 R.sup.1b R.sup.3g
R.sup.4e R.sup.5fg R.sup.6b N693 R.sup.1b R.sup.3h R.sup.4e
R.sup.5fg R.sup.6b N694 R.sup.1b R.sup.3s R.sup.4a R.sup.5fh
R.sup.6b N695 R.sup.1b R.sup.3t R.sup.4b R.sup.5fh R.sup.6b N696
R.sup.1b R.sup.3g R.sup.4e R.sup.5fh R.sup.6b N697 R.sup.1b
R.sup.3h R.sup.4e R.sup.5fh R.sup.6b N698 R.sup.1b R.sup.3s
R.sup.4a R.sup.5fh R.sup.6b N699 R.sup.1b R.sup.3t R.sup.4b
R.sup.5fi R.sup.6b N700 R.sup.1b R.sup.3g R.sup.4e R.sup.5fi
R.sup.6b N701 R.sup.1b R.sup.3h R.sup.4e R.sup.5fi R.sup.6b N702
R.sup.1b R.sup.3s R.sup.4a R.sup.5fj R.sup.6b N703 R.sup.1b
R.sup.3t R.sup.4b R.sup.5fj R.sup.6b N704 R.sup.1b R.sup.3g
R.sup.4e R.sup.5fj R.sup.6b N705 R.sup.1b R.sup.3h R.sup.4e
R.sup.5fj R.sup.6b N706 R.sup.1b R.sup.3s R.sup.4a R.sup.5fk
R.sup.6b N707 R.sup.1b R.sup.3t R.sup.4b R.sup.5fk R.sup.6b N708
R.sup.1b R.sup.3g R.sup.4e R.sup.5fk R.sup.6b N709 R.sup.1b
R.sup.3h R.sup.4e R.sup.5fk R.sup.6b N710 R.sup.1b R.sup.3s
R.sup.4a R.sup.5fl R.sup.6b N711 R.sup.1b R.sup.3t R.sup.4b
R.sup.5fl R.sup.6b N712 R.sup.1b R.sup.3g R.sup.4e R.sup.5fl
R.sup.6b N713 R.sup.1b R.sup.3h R.sup.4e R.sup.5fl R.sup.6b N714
R.sup.1b R.sup.3s R.sup.4a R.sup.5fm R.sup.6b N715 R.sup.1b
R.sup.3t R.sup.4b R.sup.5fm R.sup.6b N716 R.sup.1b R.sup.3g
R.sup.4e R.sup.5fm R.sup.6b N717 R.sup.1b R.sup.3h R.sup.4e
R.sup.5fm R.sup.6b N718 R.sup.1b R.sup.3s R.sup.4a R.sup.5fn
R.sup.6b N719 R.sup.1b R.sup.3t R.sup.4b R.sup.5fn R.sup.6b N720
R.sup.1b R.sup.3g R.sup.4e R.sup.5fn R.sup.6b N721 R.sup.1b
R.sup.3h R.sup.4e R.sup.5fn R.sup.6b N722 R.sup.1b R.sup.3s
R.sup.4a R.sup.5fo R.sup.6b N723 R.sup.1b R.sup.3t R.sup.4b
R.sup.5fo R.sup.6b N724 R.sup.1b R.sup.3g R.sup.4e R.sup.5fo
R.sup.6b N725 R.sup.1b R.sup.3h R.sup.4e R.sup.5fo R.sup.6b N726
R.sup.1b R.sup.3s R.sup.4a R.sup.5fp R.sup.6b N727 R.sup.1b
R.sup.3t R.sup.4b R.sup.5fp R.sup.6b N728 R.sup.1b R.sup.3g
R.sup.4e R.sup.5fp R.sup.6b N729 R.sup.1b R.sup.3h R.sup.4e
R.sup.5fp R.sup.6b N730 R.sup.1b R.sup.3s R.sup.4a R.sup.5fq
R.sup.6b N731 R.sup.1b R.sup.3t R.sup.4b R.sup.5fq R.sup.6b N732
R.sup.1b R.sup.3g R.sup.4e R.sup.5fq R.sup.6b N733 R.sup.1b
R.sup.3h R.sup.4e R.sup.5fq R.sup.6b N734 R.sup.1b R.sup.3s
R.sup.4a R.sup.5fr R.sup.6b N735 R.sup.1b R.sup.3t R.sup.4b
R.sup.5fr R.sup.6b N736 R.sup.1b R.sup.3g R.sup.4e R.sup.5fr
R.sup.6b N737 R.sup.1b R.sup.3h R.sup.4e R.sup.5fr R.sup.6b N738
R.sup.1b R.sup.3s R.sup.4a R.sup.5fs R.sup.6b N739 R.sup.1b
R.sup.3t R.sup.4b R.sup.5fs R.sup.6b N740 R.sup.1b R.sup.3g
R.sup.4e R.sup.5fs R.sup.6b N741 R.sup.1b R.sup.3h R.sup.4e
R.sup.5fs R.sup.6b N742 R.sup.1b R.sup.3s R.sup.4a R.sup.5ft
R.sup.6b N743 R.sup.1b R.sup.3t R.sup.4b R.sup.5ft R.sup.6b N744
R.sup.1b R.sup.3g R.sup.4e R.sup.5ft R.sup.6b N745 R.sup.1b
R.sup.3h R.sup.4e R.sup.5ft R.sup.6b N746 R.sup.1b R.sup.3s
R.sup.4a R.sup.5fu R.sup.6b N747 R.sup.1b R.sup.3t R.sup.4b
R.sup.5fu R.sup.6b N748 R.sup.1b R.sup.3g R.sup.4e R.sup.5fu
R.sup.6b
N749 R.sup.1b R.sup.3h R.sup.4e R.sup.5fu R.sup.6b N750 R.sup.1b
R.sup.3s R.sup.4a R.sup.5fv R.sup.6b N751 R.sup.1b R.sup.3t
R.sup.4b R.sup.5fv R.sup.6b N752 R.sup.1b R.sup.3g R.sup.4e
R.sup.5fv R.sup.6b N753 R.sup.1b R.sup.3h R.sup.4e R.sup.5fv
R.sup.6b N754 R.sup.1b R.sup.3s R.sup.4a R.sup.5fw R.sup.6b N755
R.sup.1b R.sup.3t R.sup.4b R.sup.5fw R.sup.6b N756 R.sup.1b
R.sup.3g R.sup.4e R.sup.5fw R.sup.6b N757 R.sup.1b R.sup.3h
R.sup.4e R.sup.5fw R.sup.6b
[1106] Compounds of formula I as well as intermediates and reagents
used can be prepared by the methods herein and as described in
WO2008/101682 as well as further methods known to a skilled chemist
in a variety of ways, or they are commercially available.
In a further preferred embodiment the component A is a specific
compound selected from Tables 1 to 164, a specific compound
selected from P.1 to P.372 or a specific compound selected from
Q.001 to Q.454 and the component B is Chlorothalonil. In a further
preferred embodiment the component A is a specific compound
selected from Tables 1 to 164, a specific compound selected from
P.1 to P.372 or a specific compound selected from Q.001 to Q.454
and the component B is Fludioxonil. In a further preferred
embodiment the component A is a specific compound selected from
Tables 1 to 164, a specific compound selected from P.1 to P.372 or
a specific compound selected from Q.001 to Q.454 and the component
B is Cyprodinil. In a further preferred embodiment the component A
is a specific compound selected from Tables 1 to 164, a specific
compound selected from P.1 to P.372 or a specific compound selected
from Q.001 to Q.454 and the component B is Fenpropidin. In a
further preferred embodiment the component A is a specific compound
selected from Tables 1 to 164, a specific compound selected from
P.1 to P.372 or a specific compound selected from Q.001 to Q.454
and the component B is Mandipropamid. In a further preferred
embodiment the component A is a specific compound selected from
Tables 1 to 164, a specific compound selected from P.1 to P.372 or
a specific compound selected from Q.001 to Q.454 and the component
B is Fluazinam. In a further preferred embodiment the component A
is a specific compound selected from Tables 1 to 164, a specific
compound selected from P.1 to P.372 or a specific compound selected
from Q.001 to Q.454 and the component B is Procymedone. In a
further preferred embodiment the component A is a specific compound
selected from Tables 1 to 164, a specific compound selected from
P.1 to P.372 or a specific compound selected from Q.001 to Q.454
and the component B is Carbendazim. In a further preferred
embodiment the component A is a specific compound selected from
Tables 1 to 164, a specific compound selected from P.1 to P.372 or
a specific compound selected from Q.001 to Q.454 and the component
B is Abamectin. In a further preferred embodiment the component A
is a specific compound selected from Tables 1 to 164, a specific
compound selected from P.1 to P.372 or a specific compound selected
from Q.001 to Q.454 and the component B is Clothianidin. In a
further preferred embodiment the component A is a specific compound
selected from Tables 1 to 164, a specific compound selected from
P.1 to P.372 or a specific compound selected from Q.001 to Q.454
and the component B is Emamectin benzoate. In a further preferred
embodiment the component A is a specific compound selected from
Tables 1 to 164, a specific compound selected from P.1 to P.372 or
a specific compound selected from Q.001 to Q.454 and the component
B is Imidacloprid. In a further preferred embodiment the component
A is a specific compound selected from Tables 1 to 164, a specific
compound selected from P.1 to P.372 or a specific compound selected
from Q.001 to Q.454 and the component B is Tefluthrin. In a further
preferred embodiment the component A is a specific compound
selected from Tables 1 to 164, a specific compound selected from
P.1 to P.372 or a specific compound selected from Q.001 to Q.454
and the component B is Mefenoxam. In a further preferred embodiment
the component A is a specific compound selected from Tables 1 to
164, a specific compound selected from P.1 to P.372 or a specific
compound selected from Q.001 to Q.454 and the component B is
Orocymedone. In a further preferred embodiment the component A is a
specific compound selected from Tables 1 to 164, a specific
compound selected from P.1 to P.372 or a specific compound selected
from Q.001 to Q.454 and the component B is Thiamethoxam. In a
further preferred embodiment the component A is a specific compound
selected from Tables 1 to 164, a specific compound selected from
P.1 to P.372 or a specific compound selected from Q.001 to Q.454
and the component B is Lambda-cyhalothrin. In a further preferred
embodiment the component A is a specific compound selected from
Tables 1 to 164, a specific compound selected from P.1 to P.372 or
a specific compound selected from Q.001 to Q.454 and the component
B is Gamma-cyhalothrin. In a further preferred embodiment the
component A is a specific compound selected from Tables 1 to 164, a
specific compound selected from P.1 to P.372 or a specific compound
selected from Q.001 to Q.454 and the component B is Profenofos. In
a further preferred embodiment the component A is a specific
compound selected from Tables 1 to 164, a specific compound
selected from P.1 to P.372 or a specific compound selected from
Q.001 to Q.454 and the component B is Lufenuron. In a further
preferred embodiment the component A is a specific compound
selected from Tables 1 to 164, a specific compound selected from
P.1 to P.372 or a specific compound selected from Q.001 to Q.454
and the component B is Diflubenzuron. In a further preferred
embodiment the component A is a specific compound selected from
Tables 1 to 164, a specific compound selected from P.1 to P.372 or
a specific compound selected from Q.001 to Q.454 and the component
B is Cypermethrin. In a further preferred embodiment the component
A is a specific compound selected from Tables 1 to 164, a specific
compound selected from P.1 to P.372 or a specific compound selected
from Q.001 to Q.454 and the component B is Novaluron. In a further
preferred embodiment the component A is a specific compound
selected from Tables 1 to 164, a specific compound selected from
P.1 to P.372 or a specific compound selected from Q.001 to Q.454
and the component B is Bifenthrin. In a further preferred
embodiment the component A is a specific compound selected from
Tables 1 to 164, a specific compound selected from P.1 to P.372 or
a specific compound selected from Q.001 to Q.454 and the component
B is Methomyl. In a further preferred embodiment the component A is
a specific compound selected from Tables 1 to 164, a specific
compound selected from P.1 to P.372 or a specific compound selected
from Q.001 to Q.454 and the component B is Chlopyrifos. In a
further preferred embodiment the component A is a specific compound
selected from Tables 1 to 164, a specific compound selected from
P.1 to P.372 or a specific compound selected from Q.001 to Q.454
and the component B is Methamidophos. In a further preferred
embodiment the component A is a specific compound selected from
Tables 1 to 164, a specific compound selected from P.1 to P.372 or
a specific compound selected from Q.001 to Q.454 and the component
B is Endosulfan. In a further preferred embodiment the component A
is a specific compound selected from Tables 1 to 164, a specific
compound selected from P.1 to P.372 or a specific compound selected
from Q.001 to Q.454 and the component B is Betacyfluthrin. In a
further preferred embodiment the component A is a specific compound
selected from Tables 1 to 164, a specific compound selected from
P.1 to P.372 or a specific compound selected from Q.001 to Q.454
and the component B is Triflumuron. In a further preferred
embodiment the component A is a specific compound selected from
Tables 1 to 164, a specific compound selected from P.1 to P.372 or
a specific compound selected from Q.001 to Q.454 and the component
B is Teflubenzuron. In a further preferred embodiment the component
A is a specific compound selected from Tables 1 to 164, a specific
compound selected from P.1 to P.372 or a specific compound selected
from Q.001 to Q.454 and the component B is Acephat. In a further
preferred embodiment the component A is a specific compound
selected from Tables 1 to 164, a specific compound selected from
P.1 to P.372 or a specific compound selected from Q.001 to Q.454
and the component B is Glyphosate. In a further preferred
embodiment the component A is a specific compound selected from
Tables 1 to 164, a specific compound selected from P.1 to P.372 or
a specific compound selected from Q.001 to Q.454 and the component
B is Glufosinate. In a further preferred embodiment the component A
is a specific compound selected from Tables 1 to 164, a specific
compound selected from P.1 to P.372 or a specific compound selected
from Q.001 to Q.454 and the component B is Mesotrione. In a further
preferred embodiment the component A is a specific compound
selected from Tables 1 to 164, a specific compound selected from
P.1 to P.372 or a specific compound selected from Q.001 to Q.454
and the component B is Bicyclopyrone. In a further preferred
embodiment the component A is a specific compound selected from
Tables 1 to 164, a specific compound selected from P.1 to P.372 or
a specific compound selected from Q.001 to Q.454 and the component
B is Tembotrione. In a further preferred embodiment the component A
is a specific compound selected from Tables 1 to 164, a specific
compound selected from P.1 to P.372 or a specific compound selected
from Q.001 to Q.454 and the component B is Sulcotrione. In a
further preferred embodiment the component A is a specific compound
selected from Tables 1 to 164, a specific compound selected from
P.1 to P.372 or a specific compound selected from Q.001 to Q.454
and the component B is 2,4-D. In a further preferred embodiment the
component A is a specific compound selected from Tables 1 to 164 or
a specific compound selected from P.1 to P.372 or a specific
compound selected from Q.001 to Q.454 and the component B is MCPA.
In a further preferred embodiment the component A is a specific
compound selected from Tables 1 to 164, a specific compound
selected from P.1 to P.372 or a specific compound selected from
Q.001 to Q.454 and the component B is Trinexapac-ethyl. In a
further preferred embodiment the component A is a specific compound
selected from Tables 1 to 164, a specific compound selected from
P.1 to P.372 or a specific compound selected from Q.001 to Q.454
and the component B is Prohexadione-Ca. In a further preferred
embodiment the component A is a specific compound selected from
Tables 1 to 164, a specific compound selected from P.1 to P.372 or
a specific compound selected from Q.001 to Q.454 and the component
B is Paclobutrazol. In a further preferred embodiment the component
A is a specific compound selected from Tables 1 to 164, a specific
compound selected from P.1 to P.372 or a specific compound selected
from Q.001 to Q.454 and the component B is Acibenzolar-S-methyl. In
a further preferred embodiment the component A is a specific
compound selected from Tables 1 to 164, a specific compound
selected from P.1 to P.372 or a specific compound selected from
Q.001 to Q.454 and the component B is Methyl-Jasmonate. In a
further preferred embodiment the component A is a specific compound
selected from Tables 1 to 164, a specific compound selected from
P.1 to P.372 or a specific compound selected from Q.001 to Q.454
and the component B is Cis-Jasmone. In a further preferred
embodiment the component A is a specific compound selected from
Tables 1 to 164, a specific compound selected from P.1 to P.372 or
a specific compound selected from Q.001 to Q.454 and the component
B is Manganese. In a further preferred embodiment the component A
is a specific compound selected from Tables 1 to 164, a specific
compound selected from P.1 to P.372 or a specific compound selected
from Q.001 to Q.454 and the component B is Cyflufenamid. In a
further preferred embodiment the component A is a specific compound
selected from Tables 1 to 164, a specific compound selected from
P.1 to P.372 or a specific compound selected from Q.001 to Q.454
and the component B is Tebufloquin. In a further preferred
embodiment the component A is a specific compound selected from
Tables 1 to 164, a specific compound selected from P.1 to P.372 or
a specific compound selected from Q.001 to Q.454 and the component
B is Copper. In a further preferred embodiment the component A is a
specific compound selected from Tables 1 to 164, a specific
compound selected from P.1 to P.372 or a specific compound selected
from Q.001 to Q.454 and the component B is Coumoxystrobin. In a
further preferred embodiment the component A is a specific compound
selected from Tables 1 to 164, a specific compound selected from
P.1 to P.372 or a specific compound selected from Q.001 to Q.454
and the component B is Dicloaminostrobin. In a further preferred
embodiment the component A is a specific compound selected from
Tables 1 to 164, a specific compound selected from P.1 to P.372 or
a specific compound selected from Q.001 to Q.454 and the component
B is Flufenoxystrobin. In a further preferred embodiment the
component A is a specific compound selected from Tables 1 to 164, a
specific compound selected from P.1 to P.372 or a specific compound
selected from Q.001 to Q.454 and the component B is
Pyrametostrobin. In a further preferred embodiment the component A
is a specific compound selected from Tables 1 to 164, a specific
compound selected from P.1 to P.372 or a specific compound selected
from Q.001 to Q.454 and the component B is Pyraoxystrobin. In a
further preferred embodiment the component A is a specific compound
selected from Tables 1 to 164, a specific compound selected from
P.1 to P.372 or a specific compound selected from Q.001 to Q.454
and the component B is Trifloxystrobin. In a further preferred
embodiment the component A is a specific compound selected from
Tables 1 to 164, a specific compound selected from P.1 to P.372 or
a specific compound selected from Q.001 to Q.454 and the component
B is Azoxystrobin. In a further preferred embodiment the component
A is a specific compound selected from Tables 1 to 164, a specific
compound selected from P.1 to P.372 or a specific compound selected
from Q.001 to Q.454 and the component B is Pyraclostrobin. In a
further preferred embodiment the component A is a specific compound
selected from Tables 1 to 164, a specific compound selected from
P.1 to P.372 or a specific compound selected from Q.001 to Q.454
and the component B is Picoxystrobin. In a further preferred
embodiment the component A is a specific compound selected from
Tables 1 to 164, a specific compound selected from P.1 to P.372 or
a specific compound selected from Q.001 to Q.454 and the component
B is Jiaxiangjunzhi. In a further preferred embodiment the
component A is a specific compound selected from Tables 1 to 164, a
specific compound selected from P.1 to P.372 or a specific compound
selected from Q.001 to Q.454 and the component B is Enoxastrobin.
In a further preferred embodiment the component A is a specific
compound selected from Tables 1 to 164, a specific compound
selected from P.1 to P.372 or a specific compound selected from
Q.001 to Q.454 and the component B is Triclopyricarb. In a further
preferred embodiment the component A is a specific compound
selected from Tables 1 to 164, a specific compound selected from
P.1 to P.372 or a specific compound selected from Q.001 to Q.454
and the component B is Fluoxastrobin. In a further preferred
embodiment the component A is a specific compound selected from
Tables 1 to 164, a specific compound selected from P.1 to P.372 or
a specific compound selected from Q.001 to Q.454 and the component
B is Dimoxystrobin. In a further preferred embodiment the component
A is a specific compound selected from Tables 1 to 164, a specific
compound selected from P.1 to P.372 or a specific compound selected
from Q.001 to Q.454 and the component B is Fenaminostrobin. In a
further preferred embodiment the component A is a specific compound
selected from Tables 1 to 164, a specific compound selected from
P.1 to P.372 or a specific compound selected from Q.001 to Q.454
and the component B is the compound of formula II. In a further
preferred embodiment the component A is a specific compound
selected from Tables 1 to 164, a specific compound selected from
P.1 to P.372 or a specific compound selected from Q.001 to Q.454
and the component B is Cyproconazole. In a further preferred
embodiment the component A is a specific compound selected from
Tables 1 to 164, a specific compound selected from P.1 to P.372 or
a specific compound selected from Q.001 to Q.454 and the component
B is Difenoconazole. In a further preferred embodiment the
component A is a specific compound selected from Tables 1 to 164, a
specific compound selected from P.1 to P.372 or a specific compound
selected from Q.001 to Q.454 and the component B is Metconazole. In
a further preferred embodiment the component A is a specific
compound selected from Tables 1 to 164, a specific compound
selected from P.1 to P.372 or a specific compound selected from
Q.001 to Q.454 and the component B is Propiconazole. In a further
preferred embodiment the component A is a specific compound
selected from Tables 1 to 164, a specific compound selected from
P.1 to P.372 or a specific compound selected from Q.001 to Q.454
and the component B is Epoxiconazole. In a further preferred
embodiment the component A is a specific compound selected from
Tables 1 to 164, a specific compound selected from P.1 to P.372 or
a specific compound selected from Q.001 to Q.454 and the component
B is Tebuconazole. In a further preferred embodiment the component
A is a specific compound selected from Tables 1 to 164, a specific
compound
selected from P.1 to P.372 or a specific compound selected from
Q.001 to Q.454 and the component B is Flutriafol. In a further
preferred embodiment the component A is a specific compound
selected from Tables 1 to 164, a specific compound selected from
P.1 to P.372 or a specific compound selected from Q.001 to Q.454
and the component B is Ipconazole. In a further preferred
embodiment the component A is a specific compound selected from
Tables 1 to 164, a specific compound selected from P.1 to P.372 or
a specific compound selected from Q.001 to Q.454 and the component
B is
1-(2-chlorophenyl)-2-(1-chlorocycloprop-1-yl)-3-(1,2,4-triazol-1-yl)propa-
n-2-ol [CAS number 120983-64-4]. In a further preferred embodiment
the component A is a specific compound selected from Tables 1 to
164, a specific compound selected from P.1 to P.372 or a specific
compound selected from Q.001 to Q.454 and the component B is
prothioconazole. In a further preferred embodiment the component A
is a specific compound selected from Tables 1 to 164, a specific
compound selected from P.1 to P.372 or a specific compound selected
from Q.001 to Q.454 and the component B is
(S)-[3-(4-chloro-2-fluoro-phenyl)-5-(2,4-difluoro-phenyl)-isoxazol-4-yl]--
pyridin-3-yl-methanol [CAS number 1229606-46-5]. In a further
preferred embodiment the component A is a specific compound
selected from Tables 1 to 164 or a specific compound selected from
P.1 to P.372 or a specific compound selected from Q.001 to Q.454
and the component B is
3-(4-Chloro-2-fluoro-phenyl)-5-(2,4-difluoro-phenyl)-isoxazol-4-yl]-pyrid-
in-3-yl-methanol [CAS number 1229605-96-2]. In a further preferred
embodiment the component A is a specific compound selected from
Tables 1 to 164, a specific compound selected from P.1 to P.372 or
a specific compound selected from Q.001 to Q.454 and the component
B is Pyrisoxazole. In a further preferred embodiment the component
A is a specific compound selected from Tables 1 to 164, a specific
compound selected from P.1 to P.372 or a specific compound selected
from Q.001 to Q.454 and the component B is
3-(difluoromethyl)-N-methoxy-1-methyl-N-[1-methyl-2-(2,4,6-trichloropheny-
l)ethyl]-1H-Pyrazole-4-carboxamide [CAS number 1228284-64-7]. In a
further preferred embodiment the component A is a specific compound
selected from Tables 1 to 164, a specific compound selected from
P.1 to P.372 or a specific compound selected from Q.001 to Q.454
and the component B is
N-[9-(dichloromethylene)-1,2,3,4-tetrahydro-1,4-methanonaphthalen-5-yl]-3-
-(difluoromethyl)-1-methyl-1H-pyrazole-4-carboxamide [CAS number
1072957-71-1]. In a further preferred embodiment the component A is
a specific compound selected from Tables 1 to 164, a specific
compound selected from P.1 to P.372 or a specific compound selected
from Q.001 to Q.454 and the component B is Isopyrazam. In a further
preferred embodiment the component A is a specific compound
selected from Tables 1 to 164, a specific compound selected from
P.1 to P.372 or a specific compound selected from Q.001 to Q.454
and the component B is Sedaxane. In a further preferred embodiment
the component A is a specific compound selected from Tables 1 to
164, a specific compound selected from P.1 to P.372 or a specific
compound selected from Q.001 to Q.454 and the component B is
Boscalid. In a further preferred embodiment the component A is a
specific compound selected from Tables 1 to 164, a specific
compound selected from P.1 to P.372 or a specific compound selected
from Q.001 to Q.454 and the component B is Fluxapyroxad. In a
further preferred embodiment the component A is a specific compound
selected from Tables 1 to 164, a specific compound selected from
P.1 to P.372 or a specific compound selected from Q.001 to Q.454
and the component B is Penthiopyrad. In a further preferred
embodiment the component A is a specific compound selected from
Tables 1 to 164, a specific compound selected from P.1 to P.372 or
a specific compound selected from Q.001 to Q.454 and the component
B is Penflufen. In a further preferred embodiment the component A
is a specific compound selected from Tables 1 to 164, a specific
compound selected from P.1 to P.372 or a specific compound selected
from Q.001 to Q.454 and the component B is Bixafen. In a further
preferred embodiment the component A is a specific compound
selected from Tables 1 to 164, a specific compound selected from
P.1 to P.372 or a specific compound selected from Q.001 to Q.454
and the component B is Fluopyram. In a further embodiment the
invention relates to a specific compound selected from Tables 1 to
164, a specific compound selected from P.1 to P.372 or a specific
compound selected from Q.001 to Q.454.
[1108] The compounds of formula I, and, where appropriate, the
tautomers thereof, can be present in the form of one of the isomers
which are possible or as a mixture of these, for example in the
form of pure isomers, such as antipodes and/or diastereomers, or as
isomer mixtures, such as structural isomer, stereo isomer,
diastereoisomer and enantiomer mixtures, for example racemates,
diastereomer mixtures or racemate mixtures, depending on the
number, absolute and relative configuration of asymmetric carbon
atoms which occur in the molecule and/or depending on the
configuration of non-aromatic double bonds which occur in the
molecule; the invention relates to the pure isomers and also to all
isomer mixtures which are possible and is to be understood in each
case in this sense hereinabove and hereinbelow, even when
stereochemical details are not mentioned specifically in each
case.
[1109] Likewise, where isomers are possible for compounds that may
be selected as component B, the invention relates to the pure
isomers and also to all isomer mixtures which are possible.
[1110] The compositions according to the invention have, for
practical purposes, a very advantageous spectrum of activities for
protecting useful plants against diseases that are caused by
phytopathogenic microorganisms, such as fungi, bacteria or
viruses.
[1111] The invention relates to a method of controlling or
preventing infestation of useful plants by phytopathogenic
microorganisms, wherein a composition of the invention is applied
to the plants, to parts thereof or the locus thereof. The
compositions according to the invention are distinguished by
excellent activity at low rates of application, by being well
tolerated by plants and by being environmentally safe. They have
very useful curative, preventive and systemic properties and are
used for protecting numerous useful plants. The compositions of the
invention can be used to inhibit or destroy the diseases that occur
on plants or parts of plants (fruit, blossoms, leaves, stems,
tubers, roots) of different crops of useful plants, while at the
same time protecting also those parts of the plants that grow later
e.g. from phytopathogenic microorganisms.
[1112] It is also possible to use compositions of the invention as
dressing agents for the treatment of plant propagation material, in
particular of seeds (fruit, tubers, grains) and plant cuttings
(e.g. rice), for the protection against fungal infections as well
as against phytopathogenic fungi occurring in the soil.
[1113] Furthermore the compositions of the invention may be used
for controlling fungi in related areas, for example in the
protection of technical materials, including wood and wood related
technical products, in food storage or in hygiene management.
[1114] The compositions of the invention are, for example,
effective against the phytopathogenic fungi of the following
classes: Fungi imperfecti (e.g. Botrytis, Pyricularia,
Helminthosporium, Fusarium, Septoria, Cercospora and Alternaria)
and Basidiomycetes (e.g. Rhizoctonia, Hemileia, Puccinia).
Additionally, they are also effective against the Ascomycetes
classes (e.g. Venturia and Erysiphe, Podosphaera, Monilinia,
Uncinula) and of the Oomycetes classes (e.g. Phytophthora, Pythium,
Plasmopara). Outstanding activity has been observed against powdery
mildew (Erysiphe spp.). Furthermore, the compositions of the
invention are effective against phytopathogenic bacteria and
viruses (e.g. against Xanthomonas spp, Pseudomonas spp, Erwinia
amylovora as well as against the tobacco mosaic virus). Good
activity has been observed against rust disease, like leaf rust
(Puccinia spp.) and soybean rust (Phakopsora pachyrhizi).
[1115] Within the scope of the invention, useful plants to be
protected typically comprise the following species of plants:
cereal (wheat, barley, rye, oat, rice, maize, sorghum and related
species); beet (sugar beet and fodder beet); pomes, drupes and soft
fruit (apples, pears, plums, peaches, almonds, cherries,
strawberries, raspberries and blackberries); leguminous plants
(beans, lentils, peas, soybeans); oil plants (rape, mustard, poppy,
olives, sunflowers, coconut, castor oil plants, cocoa beans,
groundnuts); cucumber plants (pumpkins, cucum-bers, melons); fiber
plants (cotton, flax, hemp, jute); citrus fruit (oranges, lemons,
grapefruit, mandarins); vegetables (spinach, lettuce, asparagus,
cabbages, carrots, onions, tomatoes, potatoes, paprika); lauraceae
(avocado, cinnamomum, camphor) or plants such as tobacco, nuts,
coffee, eggplants, sugar cane, tea, pepper, vines, hops, bananas
and natural rubber plants, as well as ornamentals and turf and
grass species.
[1116] The toxin contained in the transgenic plants imparts to the
plants tolerance to harmful insects. Such insects can occur in any
taxonomic group of insects, but are especially commonly found in
the beetles (Coleoptera), two-winged insects (Diptera) and
butterflies (Lepidoptera).
[1117] Transgenic plants containing one or more genes that code for
an insecticidal resistance and express one or more toxins are known
and some of them are commercially available. Examples of such
plants are: YieldGard.RTM. (maize variety that expresses a Cry1Ab
toxin); YieldGard Rootworm.RTM. (maize variety that expresses a
Cry3Bb1 toxin); YieldGard Plus.RTM. (maize variety that expresses a
Cry1Ab and a Cry3Bb1 toxin); Starlink.RTM. (maize variety that
expresses a Cry9C toxin); Herculex I.RTM. (maize variety that
expresses a Cry1Fa2 toxin and the enzyme phosphinothricine
N-acetyltransferase (PAT) to achieve tolerance to the herbicide
glufosinate ammonium); NuCOTN 33B.RTM. (cotton variety that
expresses a Cry1Ac toxin); Bollgard I.RTM. (cotton variety that
expresses a Cry1Ac toxin); Bollgard II.RTM. (cotton variety that
expresses a Cry1Ac and a Cry2Ab toxin); VipCot.RTM. (cotton variety
that expresses a Vip3A and a Cry1Ab toxin); NewLeaf.RTM. (potato
variety that expresses a Cry3A toxin); NatureGard.RTM.,
Agrisure.RTM. GT Advantage (GA21 glyphosate-tolerant trait),
Agrisure.RTM. CB Advantage (Bt11 corn borer (CB) trait) and
Protecta.RTM..
[1118] Further examples of such transgenic crops are:
[1119] 1. Bt11 Maize from Syngenta Seeds SAS, Chemin de I'Hobit 27,
F-31 790 St. Sauveur, France, registration number C/FR/96/05/10.
Genetically modified Zea mays which have been rendered resistant to
attack by the European corn borer (Ostrinia nubilalis and Sesamia
nonagrioides) by transgenic expression of a truncated Cry1Ab toxin.
Bt11 maize also transgenically expresses the enzyme PAT to achieve
tolerance to the herbicide glufosinate ammonium.
[1120] 2. Bt176 Maize from Syngenta Seeds SAS, Chemin de I'Hobit
27, F-31 790 St. Sauveur, France, registration number
C/FR/96/05/10. Genetically modified Zea mays which have been
rendered resistant to attack by the European corn borer (Ostrinia
nubilalis and Sesamia nonagrioides) by transgenic expression of a
Cry1Ab toxin. Bt176 maize also transgenically expresses the enzyme
PAT to achieve tolerance to the herbicide glufosinate ammonium.
[1121] 3. MIR604 Maize from Syngenta Seeds SAS, Chemin de I'Hobit
27, F-31 790 St. Sauveur, France, registration number
C/FR/96/05/10. Maize which has been rendered insect-resistant by
transgenic expression of a modified Cry3A toxin. This toxin is
Cry3A055 modified by insertion of a cathepsin-G-protease
recognition sequence. The preparation of such transgenic maize
plants is described in WO 03/018810.
[1122] 4. MON 863 Maize from Monsanto Europe S.A. 270-272 Avenue de
Tervuren, B-1150 Brussels, Belgium, registration number C/DE/02/9.
MON 863 expresses a Cry3Bb1 toxin and has resistance to certain
Coleoptera insects.
[1123] 5. IPC 531 Cotton from Monsanto Europe S.A. 270-272 Avenue
de Tervuren, B-1150 Brussels, Belgium, registration number
C/ES/96/02.
[1124] 6. 1507 Maize from Pioneer Overseas Corporation, Avenue
Tedesco, 7 B-1160 Brussels, Belgium, registration number
C/NL/00/10. Genetically modified maize for the expression of the
protein Cry1F for achieving resistance to certain Lepidoptera
insects and of the PAT protein for achieving tolerance to the
herbicide glufosinate ammonium.
[1125] 7. NK603.times.MON 810 Maize from Monsanto Europe S.A.
270-272 Avenue de Tervuren, B-1150 Brussels, Belgium, registration
number C/GB/02/M3/03. Consists of conventionally bred hybrid maize
varieties by crossing the genetically modified varieties NK603 and
MON 810. NK603.times.MON 810 Maize transgenically expresses the
protein CP4 EPSPS, obtained from Agrobacterium sp. strain CP4,
which imparts tolerance to the herbicide Roundup.RTM. (contains
glyphosate), and also a Cry1Ab toxin obtained from Bacillus
thuringiensis subsp. kurstaki which brings about tolerance to
certain Lepidoptera, include the European corn borer.
[1126] The term "locus" of a useful plant as used herein is
intended to embrace the place on which the useful plants are
growing, where the plant propagation materials of the useful plants
are sown or where the plant propagation materials of the useful
plants will be placed into the soil. An example for such a locus is
a field, on which crop plants are growing.
[1127] The term "plant propagation material" is understood to
denote generative parts of the plant, such as seeds, which can be
used for the multiplication of the latter, and vegetative material,
such as cuttings or tubers, for example potatoes. There may be
mentioned for example seeds (in the strict sense), roots, fruits,
tubers, bulbs, rhizomes and parts of plants. Germinated plants and
young plants which are to be transplanted after germination or
after emergence from the soil, may also be mentioned. These young
plants may be protected before transplantation by a total or
partial treatment by immersion. Preferably "plant propagation
material" is understood to denote seeds.
[1128] Components A and B can be used in unmodified form or,
preferably, together with carriers and adjuvants conventionally
employed in the art of formulation.
[1129] To this components A and B and inert carriers are
conveniently formulated in known manner to emulsifiable
concentrates, coatable pastes, directly sprayable or dilutable
solutions, dilute emulsions, wettable powders, soluble powders,
dusts, granulates, and also encapsulations e.g. in polymeric
substances. As with the type of the compositions, the methods of
application, such as spraying, atomizing, dusting, scattering,
coating or pouring, are chosen in accordance with the intended
objectives and the prevailing circumstances. The compositions may
also contain further adjuvants such as stabilizers, antifoams,
viscosity regulators, binders or tackifiers as well as fertilizers,
micronutrient donors or other formulations for obtaining special
effects.
[1130] Suitable carriers and adjuvants can be solid or liquid and
are substances useful in formulation technology, e.g. natural or
regenerated mineral substances, solvents, dispersants, wetting
agents, tackifiers, thickeners, binders or fertilizers. Such
carriers are for example described in WO 97/33890.
[1131] The compositions of the invention can be applied to the
locus of the plant or plant to be treated, simultaneously or in
succession with further compounds. These further compounds can be
e.g. fertilizers or micronutrient donors or other preparations
which influence the growth of plants. They can also be herbicides
as well as insecticides, fungicides, bactericides, nematicides,
molluscicides or mixtures of several of these preparations, if
desired together with further carriers, surfactants or application
promoting adjuvants customarily employed in the art of formulation.
Suitable further compounds are described in WO2008/101682.
[1132] A preferred method of the invention is foliar application.
The frequency of application and the rate of application will
depend on the risk of infestation by the corresponding pathogen.
However, the compositions of the invention can also penetrate the
plant through the roots via the soil (systemic action) by drenching
the locus of the plant with a liquid formulation, or by applying
the compounds in solid form to the soil, e.g. in granular form
(soil application). In crops of water rice such granulates can be
applied to the flooded rice field. The compositions of the
invention may also be applied to seeds (coating) by impregnating
the seeds or tubers either with a liquid formulation of the
fungicide or coating them with a solid formulation.
[1133] A formulation, i.e. a composition of the invention and, if
desired, comprising a solid or liquid adjuvant, is prepared in a
known manner, typically by intimately mixing and/or grinding the
compound with extenders, for example solvents, solid carriers and,
optionally, surface-active compounds (surfactants).
[1134] The agrochemical formulations will usually contain from 0.1
to 99% by weight, preferably from 0.1 to 95% by weight, of the
active ingredients, 99.9 to 1% by weight, preferably 99.8 to 5% by
weight, of a solid or liquid adjuvant, and from 0 to 25% by weight,
preferably from 0.1 to 25% by weight, of a surfactant.
[1135] Whereas it is preferred to formulate commercial products as
concentrates, the end user will normally use dilute
formulations.
[1136] Advantageous rates of application are normally from 1 g to 2
kg of active ingredient (a.i.) per hectare (ha), preferably from 10
g to 1 kg a.i./ha, most preferably from 20 g to 600 g a.i./ha. When
used as seed drenching agent, convenient rates of application are
from 10 mg to 1 g of active substance per kg of seeds. The rate of
application for the desired action can be determined by
experiments. It depends for example on the type of action, the
developmental stage of the useful plant, and on the application
(location, timing, application method) and can, owing to these
parameters, vary within wide limits.
[1137] Said methods are particularly effective against the
phytopathogenic organisms of the kingdom Fungi, phylum
Basidiomycot, class Uredinomycetes, subclass Urediniomycetidae and
the order Uredinales (commonly referred to as rusts). Species of
rusts having a particularly large impact on agriculture include
those of the family Phakopsoraceae, particularly those of the genus
Phakopsora, for example Phakopsora pachyrhizi, which is also
referred to as Asian soybean rust, and those of the family
Pucciniaceae, particularly those of the genus Puccinia such as
Puccinia graminis, also known as stem rust or black rust, which is
a problem disease in cereal crops and Puccinia recondita, also
known as brown rust.
[1138] The compositions of the invention are effective against
various microbial species able to cause a microbial infection in an
animal. Examples of such microbial species are those causing
Aspergillosis such as Aspergillus fumigatus, A. flavus, A. terrus,
A. nidulans and A. niger; those causing Blastomycosis such as
Blastomyces dermatitidis; those causing Candidiasis such as Candida
albicans, C. glabrata, C. tropicalis, C. parapsilosis, C. krusei
and C. lusitaniae; those causing Coccidioidomycosis such as
Coccidioides immitis; those causing Cryptococcosis such as
Cryptococcus neoformans; those causing Histoplasmosis such as
Histoplasma capsulatum and those causing Zygomycosis such as
Absidia corymbifera, Rhizomucor pusillus and Rhizopus arrhizus.
Further examples are Fusarium Spp such as Fusarium oxysporum and
Fusarium solani and Scedosporium Spp such as Scedosporium
apiospermum and Scedosporium prolificans. Still further examples
are Microsporum Spp, Trichophyton Spp, Epidermophyton Spp, Mucor
Spp, Sporothorix Spp, Phialophora Spp, Cladosporium Spp,
Petriellidium spp, Paracoccidioides Spp and Histoplasma Spp.
[1139] The following table provides a selection of compounds of the
invention
TABLE-US-00002 Cpd No. Structure P.01 ##STR00023## P.02
##STR00024## P.03 ##STR00025## P.04 ##STR00026## P.05 ##STR00027##
P.06 ##STR00028## P.07 ##STR00029## P.08 ##STR00030## P.09
##STR00031## P.10 ##STR00032## P.11 ##STR00033## P.12 ##STR00034##
P.13 ##STR00035## P.14 ##STR00036## P.15 ##STR00037## P.16
##STR00038## P.17 ##STR00039## P.18 ##STR00040## P.19 ##STR00041##
P.20 ##STR00042## P.21 ##STR00043## P.22 ##STR00044## P.23
##STR00045## P.24 ##STR00046## P.25 ##STR00047## P.26 ##STR00048##
P.27 ##STR00049## P.28 ##STR00050## P.29 ##STR00051## P.30
##STR00052## P.31 ##STR00053## P.32 ##STR00054## P.33 ##STR00055##
P.34 ##STR00056## P.35 ##STR00057## P.36 ##STR00058## P.37
##STR00059## P.38 ##STR00060## P.39 ##STR00061## P.40 ##STR00062##
P.41 ##STR00063## P.42 ##STR00064## P.43 ##STR00065## P.44
##STR00066## P.45 ##STR00067## P.46 ##STR00068## P.47 ##STR00069##
P.48 ##STR00070## P.49 ##STR00071## P.50 ##STR00072## P.51
##STR00073## P.52 ##STR00074## P.53 ##STR00075## P.54 ##STR00076##
P.55 ##STR00077## P.56 ##STR00078## P.57 ##STR00079## P.58
##STR00080## P.59 ##STR00081## P.60 ##STR00082## P.61 ##STR00083##
P.62 ##STR00084## P.63 ##STR00085## P.64 ##STR00086## P.65
##STR00087## P.66 ##STR00088## P.67 ##STR00089## P.68 ##STR00090##
P.69 ##STR00091## P.70 ##STR00092## P.71 ##STR00093## P.72
##STR00094## P.73 ##STR00095## P.74 ##STR00096## P.75 ##STR00097##
P.76 ##STR00098## P.77 ##STR00099## P.78 ##STR00100## P.79
##STR00101## P.80 ##STR00102## P.81 ##STR00103## P.82 ##STR00104##
P.83 ##STR00105## P.84 ##STR00106## P.85 ##STR00107## P.86
##STR00108## P.87 ##STR00109## P.88 ##STR00110## P.89 ##STR00111##
P.90 ##STR00112## P.91 ##STR00113## P.92 ##STR00114## P.93
##STR00115## P.94 ##STR00116## P.95 ##STR00117## P.96 ##STR00118##
P.97 ##STR00119## P.98 ##STR00120## P.99 ##STR00121## P.100
##STR00122## P.101 ##STR00123## P.101a ##STR00124## P.102
##STR00125## P.103 ##STR00126## P.104 ##STR00127## P.105
##STR00128## P.106 ##STR00129## P.107 ##STR00130## P.108
##STR00131## P.109 ##STR00132## P.110 ##STR00133## P.111
##STR00134## P.112 ##STR00135## P.113 ##STR00136## P.114
##STR00137## P.115 ##STR00138## P.116 ##STR00139## P.117
##STR00140## P.118 ##STR00141## P.119 ##STR00142## P.120
##STR00143## P.121 ##STR00144## P.122 ##STR00145##
P.123 ##STR00146## P.124 ##STR00147## P.125 ##STR00148## P.126
##STR00149## P.127 ##STR00150## P.128 ##STR00151## P.129
##STR00152## P.130 ##STR00153## P.131 ##STR00154## P.132
##STR00155## P.133 ##STR00156## P.134 ##STR00157## P.135
##STR00158## P.136 ##STR00159## P.137 ##STR00160## P.138
##STR00161## P.139 ##STR00162## P.140 ##STR00163## P.141
##STR00164## P.142 ##STR00165## P.143 ##STR00166## P.145
##STR00167## P.146 ##STR00168## P.147 ##STR00169## P.148
##STR00170## P.149 ##STR00171## P.150 ##STR00172## P.151
##STR00173## P.152 ##STR00174## P.153 ##STR00175## P.154
##STR00176## P.155 ##STR00177## P.156 ##STR00178## P.157
##STR00179## P.158 ##STR00180## P.159 ##STR00181## P.160
##STR00182## P.161 ##STR00183## P.162 ##STR00184## P.163
##STR00185## P.164 ##STR00186## P.165 ##STR00187## P.166
##STR00188## P.167 ##STR00189## P.168 ##STR00190## P.169
##STR00191## P.170 ##STR00192## P.171 ##STR00193## P.172
##STR00194## P.173 ##STR00195## P.174 ##STR00196## P.175
##STR00197## P.176 ##STR00198## P.177 ##STR00199## P.178
##STR00200## P.179 ##STR00201## P.180 ##STR00202## P.181
##STR00203## P.182 ##STR00204## P.183 ##STR00205## P.184
##STR00206## P.185 ##STR00207## P.186 ##STR00208## P.187
##STR00209## P.188 ##STR00210## P.189 ##STR00211## P.190
##STR00212## P.191 ##STR00213## P.192 ##STR00214## P.193
##STR00215## P.194 ##STR00216## P.195 ##STR00217## P.196
##STR00218## P.197 ##STR00219## P.198 ##STR00220## P.199
##STR00221## P.200 ##STR00222## P.201 ##STR00223## P.202
##STR00224## P.203 ##STR00225## P.204 ##STR00226## P.205
##STR00227## P.206 ##STR00228## P.207 ##STR00229## P.208
##STR00230## P.209 ##STR00231## P.210 ##STR00232## P.211
##STR00233## P.212 ##STR00234## P.213 ##STR00235## P.214
##STR00236## P.215 ##STR00237## P.216 ##STR00238## P.217
##STR00239## P.218 ##STR00240## P.219 ##STR00241## P.220
##STR00242## P.221 ##STR00243## P.222 ##STR00244## P.223
##STR00245## P.224 ##STR00246## P.225 ##STR00247## P.226
##STR00248## P.227 ##STR00249## P.228 ##STR00250## P.229
##STR00251## P.230 ##STR00252## P.231 ##STR00253## P.232
##STR00254## P.233 ##STR00255## P.234 ##STR00256## P.235
##STR00257## P.236 ##STR00258## P.237 ##STR00259## P.238
##STR00260## P.239 ##STR00261## P.240 ##STR00262## P.241
##STR00263## P.242 ##STR00264## P.243 ##STR00265## P.244
##STR00266## P.245 ##STR00267## P.246 ##STR00268## P.247
##STR00269## P.248 ##STR00270## P.249 ##STR00271##
P.250 ##STR00272## P.251 ##STR00273## P.252 ##STR00274## P.253
##STR00275## P.254 ##STR00276## P.255 ##STR00277## P.256
##STR00278## P.257 ##STR00279## P.258 ##STR00280## P.259
##STR00281## P.260 ##STR00282## P.261 ##STR00283## P.262
##STR00284## P.263 ##STR00285## P.264 ##STR00286## P.265
##STR00287## P.266 ##STR00288## P.267 ##STR00289## P.268
##STR00290## P.269 ##STR00291## P.270 ##STR00292## P.271
##STR00293## P.272 ##STR00294## P.273 ##STR00295## P.274
##STR00296## P.275 ##STR00297## P.276 ##STR00298## P.277
##STR00299## P.278 ##STR00300## P.279 ##STR00301## P.280
##STR00302## P.281 ##STR00303## P.282 ##STR00304## P.283
##STR00305## P.284 ##STR00306## P.285 ##STR00307## P.286
##STR00308## P.287 ##STR00309## P.288 ##STR00310## P.289
##STR00311## P.290 ##STR00312## P.291 ##STR00313## P.292
##STR00314## P.293 ##STR00315## P.294 ##STR00316## P.295
##STR00317## P.296 ##STR00318## P.297 ##STR00319## P.298
##STR00320## P.299 ##STR00321## P.300 ##STR00322## P.301
##STR00323## P.302 ##STR00324## P.303 ##STR00325## P.304
##STR00326## P.305 ##STR00327## P.306 ##STR00328## P.307
##STR00329## P.308 ##STR00330## P.309 ##STR00331## P.310
##STR00332## P.311 ##STR00333## P.312 ##STR00334## P.313
##STR00335## P.314 ##STR00336## P.315 ##STR00337## P.316
##STR00338## P.317 ##STR00339## P.318 ##STR00340## P.319
##STR00341## P.320 ##STR00342## P.321 ##STR00343## P.322
##STR00344## P.323 ##STR00345## P.324 ##STR00346## P.325
##STR00347## P.326 ##STR00348## P.327 ##STR00349## P.328
##STR00350## P.329 ##STR00351## P.330 ##STR00352## P.331
##STR00353## P.332 ##STR00354## P.333 ##STR00355## P.334
##STR00356## P.335 ##STR00357## P.336 ##STR00358## P.337
##STR00359## P.338 ##STR00360## P.339 ##STR00361## P.340
##STR00362## P.341 ##STR00363## P.342 ##STR00364## P.343
##STR00365## P.344 ##STR00366## P.345 ##STR00367## P.346
##STR00368## P.347 ##STR00369## P.348 ##STR00370## P.349
##STR00371## P.350 ##STR00372## P.351 ##STR00373## P.352
##STR00374## P.353 ##STR00375## P.354 ##STR00376## P.355
##STR00377## P.356 ##STR00378## P.357 ##STR00379## P.358
##STR00380## P.359 ##STR00381## P.360 ##STR00382## P.361
##STR00383## P.362 ##STR00384## P.363 ##STR00385## P.364
##STR00386## P.365 ##STR00387## P.366 ##STR00388## P.367
##STR00389## P.368 ##STR00390## P.369 ##STR00391## P.370
##STR00392## P.371 ##STR00393## P.372 ##STR00394##
[1140] Table A discloses 1201 sets of meanings of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 in a compound of formula
I.
TABLE-US-00003 TABLE A Meanings for R.sub.1, R.sub.2, R.sub.5 and
R.sub.6: Line R.sub.1 R.sub.2 R.sub.6 R.sub.5 A.1.1 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00395## A.1.2 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00396## A.1.3 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00397## A.1.4
CH.sub.3 CH.sub.2CH.sub.3 H ##STR00398## A.1.5 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00399## A.1.6 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00400## A.1.7 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00401## A.1.8
CH.sub.3 CH.sub.2CH.sub.3 H ##STR00402## A.1.9 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00403## A.1.10 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00404## A.1.11 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00405## A.1.12
CH.sub.3 CH.sub.2CH.sub.3 H ##STR00406## A.1.13 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00407## A.1.14 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00408## A.1.15 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00409## A.1.16
CH.sub.3 CH.sub.2CH.sub.3 H ##STR00410## A.1.17 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00411## A.1.18 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00412## A.1.19 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00413## A.1.20
CH.sub.3 CH.sub.2CH.sub.3 H ##STR00414## A.1.21 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00415## A.1.22 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00416## A.1.23 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00417## A.1.24
CH.sub.3 CH.sub.2CH.sub.3 H ##STR00418## A.1.25 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00419## A.1.26 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00420## A.1.27 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00421## A.1.28
CH.sub.3 CH.sub.2CH.sub.3 H ##STR00422## A.1.29 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00423## A.1.30 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00424## A.1.31 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00425## A.1.32
CH.sub.3 CH.sub.2CH.sub.3 H ##STR00426## A.1.33 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00427## A.1.34 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00428## A.1.35 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00429## A.1.36
CH.sub.3 CH.sub.2CH.sub.3 H ##STR00430## A.1.37 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00431## A.1.38 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00432## A.1.39 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00433## A.1.40
CH.sub.3 CH.sub.2CH.sub.3 H ##STR00434## A.1.41 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00435## A.1.42 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00436## A.1.43 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00437## A.1.44
CH.sub.3 CH.sub.2CH.sub.3 H ##STR00438## A.1.45 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00439## A.1.46 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00440## A.1.47 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00441## A.1.48
CH.sub.3 CH.sub.2CH.sub.3 H ##STR00442## A.1.49 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00443## A.1.50 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00444## A.1.51 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00445## A.1.52
CH.sub.3 CH.sub.2CH.sub.3 H ##STR00446## A.1.53 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00447## A.1.54 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00448## A.1.55 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00449## A.1.56
CH.sub.3 CH.sub.2CH.sub.3 H ##STR00450## A.1.57 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00451## A.1.58 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00452## A.1.59 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00453## A.1.60
CH.sub.3 CH.sub.2CH.sub.3 H ##STR00454## A.1.61 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00455## A.1.62 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00456## A.1.63 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00457## A.1.64
CH.sub.3 CH.sub.2CH.sub.3 H ##STR00458## A.1.65 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00459## A.1.66 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00460## A.1.67 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00461## A.1.68
CH.sub.3 CH.sub.2CH.sub.3 H ##STR00462## A.1.69 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00463## A.1.70 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00464## A.1.71 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00465## A.1.72
CH.sub.3 CH.sub.2CH.sub.3 H ##STR00466## A.1.73 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00467## A.1.74 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00468## A.1.75 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00469## A.1.76
CH.sub.3 CH.sub.2CH.sub.3 H ##STR00470## A.1.77 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00471## A.1.78 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00472## A.1.79 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00473## A.1.80
CH.sub.3 CH.sub.2CH.sub.3 H ##STR00474## A.1.81 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00475## A.1.82 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00476## A.1.83 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00477## A.1.84
CH.sub.3 CH.sub.2CH.sub.3 H ##STR00478## A.1.85 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00479## A.1.86 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00480## A.1.87 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00481## A.1.88
CH.sub.3 CH.sub.2CH.sub.3 H ##STR00482## A.1.89 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00483## A.1.90 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00484## A.1.91 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00485## A.1.92
CH.sub.3 CH.sub.2CH.sub.3 H ##STR00486## A.1.93 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00487## A.1.94 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00488## A.1.95 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00489## A.1.96
CH.sub.3 CH.sub.2CH.sub.3 H ##STR00490## A.1.97 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00491## A.1.98 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00492## A.1.99 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00493##
A.1.100 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00494## A.1.101 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00495## A.1.102 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00496## A.1.103 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00497##
A.1.104 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00498## A.1.105 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00499## A.1.106 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00500## A.1.107 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00501##
A.1.108 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00502## A.1.109 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00503## A.1.110 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00504## A.1.111 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00505##
A.1.112 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00506## A.1.113 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00507## A.1.114 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00508## A.1.115 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00509##
A.1.116 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00510## A.1.117 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00511## A.1.118 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00512## A.1.119 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00513##
A.1.120 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00514## A.1.121 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00515## A.1.122 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00516##
A.1.123 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00517## A.1.124 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00518## A.1.125 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00519## A.1.126 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00520##
A.1.127 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00521## A.1.128 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00522## A.1.129 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00523## A.1.130 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00524##
A.1.131 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00525## A.1.132 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00526## A.1.133 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00527## A.1.134 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00528##
A.1.135 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00529## A.1.136 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00530## A.1.137 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00531## A.1.138 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00532##
A.1.139 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00533## A.1.140 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00534## A.1.141 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00535## A.1.142 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00536##
A.1.143 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00537## A.1.144 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00538## A.1.145 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00539## A.1.146 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00540##
A.1.147 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00541## A.1.148 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00542## A.1.149 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00543## A.1.150 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00544##
A.1.151 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00545## A.1.152 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00546## A.1.153 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00547## A.1.154 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00548##
A.1.155 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00549## A.1.156 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00550## A.1.157 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00551## A.1.158 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00552##
A.1.159 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00553## A.1.160 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00554## A.1.161 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00555## A.1.162 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00556##
A.1.163 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00557## A.1.164 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00558## A.1.165 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00559## A.1.166 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00560##
A.1.167 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00561## A.1.168 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00562## A.1.169 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00563## A.1.170 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00564##
A.1.171 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00565## A.1.172 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00566## A.1.173 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00567## A.1.174 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00568##
A.1.175 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00569## A.1.176 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00570## A.1.177 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00571## A.1.178 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00572##
A.1.179 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00573## A.1.180 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00574## A.1.181 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00575## A.1.182 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00576##
A.1.183 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00577## A.1.184 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00578## A.1.185 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00579## A.1.186 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00580##
A.1.187 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00581## A.1.188 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00582## A.1.189 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00583## A.1.190 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00584##
A.1.191 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00585## A.1.192 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00586## A.1.193 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00587## A.1.194 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00588##
A.1.195 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00589## A.1.196 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00590## A.1.197 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00591## A.1.198 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00592##
A.1.199 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00593## A.1.200 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00594## A.1.201 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00595## A.1.202 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00596##
A.1.203 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00597## A.1.204 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00598## A.1.205 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00599## A.1.206 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00600##
A.1.207 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00601## A.1.208 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00602## A.1.209 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00603## A.1.210 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00604##
A.1.211 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00605## A.1.212 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00606## A.1.213 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00607## A.1.214 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00608##
A.1.215 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00609## A.1.216 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00610## A.1.217 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00611## A.1.218 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00612##
A.1.219 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00613## A.1.220 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00614## A.1.221 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00615## A.1.222 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00616##
A.1.223 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00617## A.1.224 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00618## A.1.225 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00619## A.1.226 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00620##
A.1.227 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00621## A.1.228 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00622## A.1.229 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00623## A.1.230 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00624##
A.1.231 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00625## A.1.232 CH.sub.3
CH.sub.2CH.sub.3 H H-- A.1.233 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00626## A.1.234 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00627##
A.1.235 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00628## A.1.236 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00629## A.1.237 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00630## A.1.238 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00631##
A.1.239 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00632## A.1.240 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00633## A.1.241 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00634## A.1.242 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00635##
A.1.243 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00636## A.1.244 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00637## A.1.245 CH.sub.3 CH.sub.2CH.sub.3 H
H.sub.3C-- A.1.246 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00638## A.1.247
CH.sub.3 CH.sub.2CH.sub.3 H ##STR00639##
A.1.248 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00640## A.1.249 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00641## A.1.250 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00642## A.1.251 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00643##
A.1.252 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00644## A.1.253 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00645## A.1.254 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00646## A.1.255 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00647##
A.1.256 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00648## A.1.257 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00649## A.1.258 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00650## A.1.259 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00651##
A.1.260 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00652## A.1.261 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00653## A.1.262 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00654## A.1.263 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00655##
A.1.264 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00656## A.1.265 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00657## A.1.266 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00658## A.1.267 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00659##
A.1.268 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00660## A.1.269 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00661## A.1.270 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00662## A.1.271 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00663##
A.1.272 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00664## A.1.273 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00665## A.1.274 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00666## A.1.275 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00667##
A.1.276 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00668## A.1.277 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00669## A.1.278 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00670## A.1.279 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00671##
A.1.280 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00672## A.1.281 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00673## A.1.282 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00674## A.1.283 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00675##
A.1.284 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00676## A.1.285 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00677## A.1.286 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00678## A.1.287 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00679##
A.1.288 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00680## A.1.289 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00681## A.1.290 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00682## A.1.291 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00683##
A.1.292 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00684## A.1.293 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00685## A.1.294 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00686## A.1.295 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00687##
A.1.296 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00688## A.1.297 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00689## A.1.298 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00690## A.1.299 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00691##
A.1.300 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00692## A.1.301 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00693## A.1.302 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00694## A.1.303 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00695##
A.1.304 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00696## A.1.305 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00697## A.1.306 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00698## A.1.307 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00699##
A.1.308 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00700## A.1.309 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00701## A.1.310 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00702## A.1.311 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00703##
A.1.312 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00704## A.1.313 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00705## A.1.314 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00706## A.1.315 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00707##
A.1.316 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00708## A.1.317 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00709## A.1.318 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00710## A.1.319 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00711##
A.1.320 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00712## A.1.321 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00713## A.1.322 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00714## A.1.323 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00715##
A.1.324 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00716## A.1.325 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00717## A.1.326 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00718## A.1.327 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00719##
A.1.328 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00720## A.1.329 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00721## A.1.330 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00722## A.1.331 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00723##
A.1.332 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00724## A.1.333 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00725## A.1.334 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00726## A.1.335 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00727##
A.1.336 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00728## A.1.337 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00729## A.1.338 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00730## A.1.339 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00731##
A.1.340 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00732## A.1.341 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00733## A.1.342 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00734## A.1.343 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00735##
A.1.344 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00736## A.1.345 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00737## A.1.346 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00738## A.1.347 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00739##
A.1.348 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00740## A.1.349 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00741## A.1.350 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00742## A.1.351 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00743##
A.1.352 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00744## A.1.353 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00745## A.1.354 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00746## A.1.355 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00747##
A.1.356 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00748## A.1.357 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00749## A.1.358 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00750## A.1.359 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00751##
A.1.360 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00752## A.1.361 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00753## A.1.362 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00754## A.1.363 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00755##
A.1.364 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00756## A.1.365 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00757## A.1.366 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00758## A.1.367 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00759##
A.1.368 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00760## A.1.369 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00761## A.1.370 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00762## A.1.371 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00763##
A.1.372 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00764## A.1.373 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00765##
A.1.374 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00766## A.1.375 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00767## A.1.376 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00768## A.1.377 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00769##
A.1.378 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00770## A.1.379 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00771## A.1.380 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00772## A.1.381 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00773##
A.1.382 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00774## A.1.383 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00775## A.1.384 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00776## A.1.385 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00777##
A.1.386 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00778## A.1.387 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00779## A.1.388 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00780## A.1.389 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00781##
A.1.390 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00782## A.1.391 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00783## A.1.392 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00784## A.1.393 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00785##
A.1.394 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00786## A.1.395 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00787## A.1.396 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00788## A.1.397 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00789##
A.1.398 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00790## A.1.399 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00791## A.1.400 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00792## A.1.401 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00793##
A.1.402 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00794## A.1.403 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00795## A.1.404 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00796## A.1.405 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00797##
A.1.406 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00798## A.1.407 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00799## A.1.408 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00800## A.1.409 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00801##
A.1.410 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00802## A.1.411 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00803## A.1.412 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00804## A.1.413 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00805##
A.1.414 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00806## A.1.415 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00807## A.1.416 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00808## A.1.417 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00809##
A.1.418 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00810## A.1.419 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00811## A.1.420 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00812## A.1.421 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00813##
A.1.422 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00814## A.1.423 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00815## A.1.424 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00816## A.1.425 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00817##
A.1.426 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00818## A.1.427 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00819## A.1.428 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00820## A.1.429 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00821##
A.1.430 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00822## A.1.431 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00823## A.1.432 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00824## A.1.433 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00825##
A.1.434 CH.sub.3 CH.sub.2CH.sub.3 H ##STR00826## A.1.435 CH.sub.3
CH.sub.2CH.sub.3 H ##STR00827## A.1.436 CH.sub.3 CH.sub.2CH.sub.3 H
##STR00828## Line ##STR00829## R.sub.5 A.1.437 ##STR00830##
##STR00831## A.1.438 ##STR00832## ##STR00833## A.1.439 ##STR00834##
##STR00835## A.1.440 ##STR00836## ##STR00837## A.1.441 ##STR00838##
##STR00839## A.1.442 ##STR00840## ##STR00841## A.1.443 ##STR00842##
##STR00843## A.1.444 ##STR00844## ##STR00845## A.1.445 ##STR00846##
##STR00847## A.1.446 ##STR00848## ##STR00849## A.1.447 ##STR00850##
##STR00851## A.1.448 ##STR00852## ##STR00853## A.1.449 ##STR00854##
##STR00855## A.1.450 ##STR00856## ##STR00857## A.1.451 ##STR00858##
##STR00859## A.1.452 ##STR00860## ##STR00861## A.1.453 ##STR00862##
##STR00863## A.1.454 ##STR00864## ##STR00865## A.1.455 ##STR00866##
##STR00867## A.1.456 ##STR00868## ##STR00869## A.1.457 ##STR00870##
##STR00871## A.1.458 ##STR00872## ##STR00873## A.1.459 ##STR00874##
##STR00875## A.1.460 ##STR00876## ##STR00877## A.1.461 ##STR00878##
##STR00879## A.1.462 ##STR00880## ##STR00881## A.1.463 ##STR00882##
##STR00883## A.1.464 ##STR00884## ##STR00885## A.1.465 ##STR00886##
##STR00887## A.1.466 ##STR00888## ##STR00889## A.1.467 ##STR00890##
##STR00891## A.1.468 ##STR00892## ##STR00893## A.1.469 ##STR00894##
##STR00895## A.1.470 ##STR00896## ##STR00897## A.1.471 ##STR00898##
##STR00899## A.1.472 ##STR00900## ##STR00901## A.1.473 ##STR00902##
##STR00903## A.1.474 ##STR00904## ##STR00905## A.1.475 ##STR00906##
##STR00907## A.1.476 ##STR00908## ##STR00909## A.1.477 ##STR00910##
##STR00911## A.1.478 ##STR00912## ##STR00913## A.1.479 ##STR00914##
##STR00915## A.1.480 ##STR00916## ##STR00917## A.1.481 ##STR00918##
##STR00919## A.1.482 ##STR00920## ##STR00921## A.1.483 ##STR00922##
##STR00923## A.1.484 ##STR00924## ##STR00925## A.1.485 ##STR00926##
##STR00927## A.1.486 ##STR00928## ##STR00929## A.1.487 ##STR00930##
##STR00931## A.1.488 ##STR00932## ##STR00933## A.1.489 ##STR00934##
##STR00935## A.1.490 ##STR00936## ##STR00937## A.1.491 ##STR00938##
##STR00939## A.1.492 ##STR00940## ##STR00941## A.1.493 ##STR00942##
##STR00943## A.1.494 ##STR00944## ##STR00945## A.1.495 ##STR00946##
##STR00947## A.1.496 ##STR00948## ##STR00949## A.1.497 ##STR00950##
##STR00951##
A.1.498 ##STR00952## ##STR00953## A.1.499 ##STR00954## ##STR00955##
A.1.500 ##STR00956## ##STR00957## A.1.501 ##STR00958## ##STR00959##
A.1.502 ##STR00960## ##STR00961## A.1.503 ##STR00962## ##STR00963##
A.1.504 ##STR00964## ##STR00965## A.1.505 ##STR00966## ##STR00967##
A.1.506 ##STR00968## ##STR00969## A.1.507 ##STR00970## ##STR00971##
A.1.508 ##STR00972## ##STR00973## A.1.509 ##STR00974## ##STR00975##
A.1.510 ##STR00976## ##STR00977## A.1.511 ##STR00978## ##STR00979##
A.1.512 ##STR00980## ##STR00981## A.1.513 ##STR00982## ##STR00983##
A.1.514 ##STR00984## ##STR00985## A.1.515 ##STR00986## ##STR00987##
A.1.516 ##STR00988## ##STR00989## A.1.517 ##STR00990## ##STR00991##
A.1.518 ##STR00992## ##STR00993## A.1.519 ##STR00994## ##STR00995##
A.1.520 ##STR00996## ##STR00997## A.1.521 ##STR00998## ##STR00999##
A.1.522 ##STR01000## ##STR01001## A.1.523 ##STR01002## ##STR01003##
A.1.524 ##STR01004## ##STR01005## A.1.525 ##STR01006## ##STR01007##
A.1.526 ##STR01008## ##STR01009## A.1.527 ##STR01010## ##STR01011##
A.1.528 ##STR01012## ##STR01013## A.1.529 ##STR01014## ##STR01015##
A.1.530 ##STR01016## ##STR01017## A.1.531 ##STR01018## ##STR01019##
A.1.532 ##STR01020## ##STR01021## A.1.533 ##STR01022## ##STR01023##
A.1.534 ##STR01024## ##STR01025## A.1.535 ##STR01026## ##STR01027##
A.1.536 ##STR01028## ##STR01029## A.1.537 ##STR01030## ##STR01031##
A.1.538 ##STR01032## ##STR01033## A.1.539 ##STR01034## ##STR01035##
A.1.540 ##STR01036## ##STR01037## A.1.541 ##STR01038## ##STR01039##
A.1.542 ##STR01040## ##STR01041## A.1.543 ##STR01042## ##STR01043##
A.1.544 ##STR01044## ##STR01045## A.1.545 ##STR01046## ##STR01047##
A.1.546 ##STR01048## ##STR01049## A.1.547 ##STR01050## ##STR01051##
A.1.548 ##STR01052## ##STR01053## A.1.549 ##STR01054## ##STR01055##
A.1.550 ##STR01056## ##STR01057## A.1.551 ##STR01058## ##STR01059##
A.1.552 ##STR01060## ##STR01061## A.1.553 ##STR01062## ##STR01063##
A.1.554 ##STR01064## ##STR01065## A.1.555 ##STR01066## ##STR01067##
A.1.556 ##STR01068## ##STR01069## A.1.557 ##STR01070## ##STR01071##
A.1.558 ##STR01072## ##STR01073## A.1.559 ##STR01074## ##STR01075##
A.1.560 ##STR01076## ##STR01077## A.1.561 ##STR01078## ##STR01079##
A.1.562 ##STR01080## ##STR01081## A.1.563 ##STR01082## ##STR01083##
A.1.564 ##STR01084## ##STR01085## A.1.565 ##STR01086## ##STR01087##
A.1.566 ##STR01088## ##STR01089## A.1.567 ##STR01090## ##STR01091##
A.1.568 ##STR01092## ##STR01093## A.1.569 ##STR01094## ##STR01095##
A.1.570 ##STR01096## ##STR01097## A.1.571 ##STR01098## ##STR01099##
A.1.572 ##STR01100## ##STR01101## A.1.573 ##STR01102## ##STR01103##
A.1.574 ##STR01104## ##STR01105## A.1.575 ##STR01106## ##STR01107##
A.1.576 ##STR01108## ##STR01109## A.1.577 ##STR01110## ##STR01111##
A.1.578 ##STR01112## ##STR01113## A.1.579 ##STR01114## ##STR01115##
A.1.580 ##STR01116## ##STR01117## A.1.581 ##STR01118## ##STR01119##
A.1.582 ##STR01120## ##STR01121## A.1.583 ##STR01122## ##STR01123##
A.1.584 ##STR01124## ##STR01125## A.1.585 ##STR01126## ##STR01127##
A.1.586 ##STR01128## ##STR01129## A.1.587 ##STR01130## ##STR01131##
A.1.588 ##STR01132## ##STR01133## A.1.589 ##STR01134## ##STR01135##
A.1.590 ##STR01136## ##STR01137## A.1.591 ##STR01138## ##STR01139##
A.1.592 ##STR01140## ##STR01141## A.1.593 ##STR01142## ##STR01143##
A.1.594 ##STR01144## ##STR01145## A.1.595 ##STR01146## ##STR01147##
A.1.596 ##STR01148## ##STR01149## A.1.597 ##STR01150## ##STR01151##
A.1.598 ##STR01152## ##STR01153## A.1.599 ##STR01154## ##STR01155##
A.1.600 ##STR01156## ##STR01157## A.1.601 ##STR01158## ##STR01159##
A.1.602 ##STR01160## ##STR01161## A.1.603 ##STR01162## ##STR01163##
A.1.604 ##STR01164## ##STR01165## A.1.605 ##STR01166## ##STR01167##
A.1.606 ##STR01168## ##STR01169## A.1.607 ##STR01170## ##STR01171##
A.1.608 ##STR01172## ##STR01173## A.1.609 ##STR01174## ##STR01175##
A.1.610 ##STR01176## ##STR01177## A.1.611 ##STR01178## ##STR01179##
A.1.612 ##STR01180## ##STR01181## A.1.613 ##STR01182## ##STR01183##
A.1.614 ##STR01184## ##STR01185## A.1.615 ##STR01186## ##STR01187##
A.1.616 ##STR01188## ##STR01189## A.1.617 ##STR01190## ##STR01191##
A.1.618 ##STR01192## ##STR01193## A.1.619 ##STR01194## ##STR01195##
A.1.620 ##STR01196## ##STR01197## A.1.621 ##STR01198## ##STR01199##
A.1.622 ##STR01200## ##STR01201## A.1.623 ##STR01202##
##STR01203##
A.1.624 ##STR01204## ##STR01205## A.1.625 ##STR01206## ##STR01207##
A.1.626 ##STR01208## ##STR01209## A.1.627 ##STR01210## ##STR01211##
A.1.628 ##STR01212## ##STR01213## A.1.629 ##STR01214## ##STR01215##
A.1.630 ##STR01216## ##STR01217## A.1.631 ##STR01218## ##STR01219##
A.1.632 ##STR01220## ##STR01221## A.1.633 ##STR01222## ##STR01223##
A.1.634 ##STR01224## ##STR01225## A.1.635 ##STR01226## ##STR01227##
A.1.636 ##STR01228## ##STR01229## A.1.637 ##STR01230## ##STR01231##
A.1.638 ##STR01232## ##STR01233## A.1.639 ##STR01234## ##STR01235##
A.1.640 ##STR01236## ##STR01237## A.1.641 ##STR01238## ##STR01239##
A.1.642 ##STR01240## ##STR01241## A.1.643 ##STR01242## ##STR01243##
A.1.644 ##STR01244## ##STR01245## A.1.645 ##STR01246## ##STR01247##
A.1.646 ##STR01248## ##STR01249## A.1.647 ##STR01250## ##STR01251##
A.1.648 ##STR01252## ##STR01253## A.1.649 ##STR01254## ##STR01255##
A.1.650 ##STR01256## ##STR01257## A.1.651 ##STR01258## ##STR01259##
A.1.652 ##STR01260## ##STR01261## A.1.653 ##STR01262## ##STR01263##
A.1.654 ##STR01264## ##STR01265## A.1.655 ##STR01266## ##STR01267##
A.1.656 ##STR01268## ##STR01269## A.1.657 ##STR01270## ##STR01271##
A.1.658 ##STR01272## ##STR01273## A.1.659 ##STR01274## ##STR01275##
A.1.660 ##STR01276## ##STR01277## A.1.661 ##STR01278## ##STR01279##
A.1.662 ##STR01280## ##STR01281## A.1.663 ##STR01282## ##STR01283##
A.1.664 ##STR01284## ##STR01285## A.1.665 ##STR01286## ##STR01287##
A.1.666 ##STR01288## ##STR01289## A.1.667 ##STR01290## ##STR01291##
A.1.668 ##STR01292## ##STR01293## A.1.669 ##STR01294## ##STR01295##
A.1.670 ##STR01296## ##STR01297## A.1.671 ##STR01298## ##STR01299##
A.1.672 ##STR01300## ##STR01301## A.1.673 ##STR01302## ##STR01303##
A.1.674 ##STR01304## ##STR01305## A.1.675 ##STR01306## ##STR01307##
A.1.676 ##STR01308## ##STR01309## A.1.677 ##STR01310## ##STR01311##
A.1.678 ##STR01312## ##STR01313## A.1.679 ##STR01314## ##STR01315##
A.1.680 ##STR01316## ##STR01317## A.1.681 ##STR01318## ##STR01319##
A.1.682 ##STR01320## ##STR01321## A.1.683 ##STR01322## ##STR01323##
A.1.684 ##STR01324## ##STR01325## A.1.685 ##STR01326## ##STR01327##
A.1.686 ##STR01328## ##STR01329## A.1.687 ##STR01330## ##STR01331##
A.1.688 ##STR01332## ##STR01333## A.1.689 ##STR01334## ##STR01335##
A.1.690 ##STR01336## ##STR01337## A.1.691 ##STR01338## ##STR01339##
A.1.692 ##STR01340## ##STR01341## A.1.693 ##STR01342## ##STR01343##
A.1.694 ##STR01344## ##STR01345## A.1.695 ##STR01346## ##STR01347##
A.1.696 ##STR01348## ##STR01349## A.1.697 ##STR01350## ##STR01351##
A.1.698 ##STR01352## ##STR01353## A.1.699 ##STR01354## ##STR01355##
A.1.700 ##STR01356## ##STR01357## A.1.701 ##STR01358## ##STR01359##
A.1.702 ##STR01360## ##STR01361## A.1.703 ##STR01362## ##STR01363##
A.1.704 ##STR01364## ##STR01365## A.1.705 ##STR01366## ##STR01367##
A.1.706 ##STR01368## ##STR01369## A.1.707 ##STR01370## ##STR01371##
A.1.708 ##STR01372## ##STR01373## A.1.709 ##STR01374## ##STR01375##
A.1.710 ##STR01376## ##STR01377## A.1.711 ##STR01378## ##STR01379##
A.1.712 ##STR01380## ##STR01381## A.1.713 ##STR01382## ##STR01383##
A.1.714 ##STR01384## ##STR01385## A.1.715 ##STR01386## ##STR01387##
A.1.716 ##STR01388## ##STR01389## A.1.717 ##STR01390## ##STR01391##
A.1.718 ##STR01392## ##STR01393## A.1.719 ##STR01394## ##STR01395##
A.1.720 ##STR01396## ##STR01397## A.1.721 ##STR01398## ##STR01399##
A.1.722 ##STR01400## ##STR01401## A.1.723 ##STR01402## ##STR01403##
A.1.724 ##STR01404## ##STR01405## A.1.725 ##STR01406## ##STR01407##
A.1.726 ##STR01408## ##STR01409## A.1.727 ##STR01410## ##STR01411##
A.1.728 ##STR01412## ##STR01413## A.1.729 ##STR01414## ##STR01415##
A.1.730 ##STR01416## ##STR01417## A.1.731 ##STR01418## ##STR01419##
A.1.732 ##STR01420## ##STR01421## A.1.733 ##STR01422## ##STR01423##
A.1.734 ##STR01424## ##STR01425## A.1.735 ##STR01426## ##STR01427##
A.1.736 ##STR01428## ##STR01429## A.1.737 ##STR01430## ##STR01431##
A.1.738 ##STR01432## ##STR01433## A.1.739 ##STR01434## ##STR01435##
A.1.740 ##STR01436## ##STR01437## A.1.741 ##STR01438## ##STR01439##
A.1.742 ##STR01440## ##STR01441## A.1.743 ##STR01442## ##STR01443##
A.1.744 ##STR01444## ##STR01445## A.1.745 ##STR01446## ##STR01447##
A.1.746 ##STR01448## ##STR01449## A.1.747 ##STR01450## ##STR01451##
A.1.748 ##STR01452## ##STR01453##
A.1.749 ##STR01454## ##STR01455## A.1.750 ##STR01456## ##STR01457##
A.1.751 ##STR01458## ##STR01459## A.1.752 ##STR01460## ##STR01461##
A.1.753 ##STR01462## ##STR01463## A.1.754 ##STR01464## ##STR01465##
A.1.755 ##STR01466## ##STR01467## A.1.756 ##STR01468## ##STR01469##
A.1.757 ##STR01470## ##STR01471## A.1.758 ##STR01472## ##STR01473##
A.1.759 ##STR01474## ##STR01475## A.1.760 ##STR01476## ##STR01477##
A.1.761 ##STR01478## ##STR01479## A.1.762 ##STR01480## ##STR01481##
A.1.763 ##STR01482## ##STR01483## A.1.764 ##STR01484## ##STR01485##
A.1.765 ##STR01486## ##STR01487## A.1.766 ##STR01488## ##STR01489##
A.1.767 ##STR01490## ##STR01491## A.1.768 ##STR01492## ##STR01493##
A.1.769 ##STR01494## ##STR01495## A.1.770 ##STR01496## ##STR01497##
A.1.771 ##STR01498## ##STR01499## A.1.772 ##STR01500## ##STR01501##
A.1.773 ##STR01502## ##STR01503## A.1.774 ##STR01504## ##STR01505##
A.1.775 ##STR01506## ##STR01507## A.1.776 ##STR01508## ##STR01509##
A.1.777 ##STR01510## ##STR01511## A.1.778 ##STR01512## ##STR01513##
A.1.779 ##STR01514## ##STR01515## A.1.780 ##STR01516## ##STR01517##
A.1.781 ##STR01518## ##STR01519## A.1.782 ##STR01520## ##STR01521##
A.1.783 ##STR01522## ##STR01523## A.1.784 ##STR01524## ##STR01525##
A.1.785 ##STR01526## ##STR01527## A.1.786 ##STR01528## ##STR01529##
A.1.787 ##STR01530## ##STR01531## A.1.788 ##STR01532## ##STR01533##
A.1.789 ##STR01534## ##STR01535## A.1.790 ##STR01536## ##STR01537##
A.1.791 ##STR01538## ##STR01539## A.1.792 ##STR01540## ##STR01541##
A.1.793 ##STR01542## ##STR01543## A.1.794 ##STR01544## ##STR01545##
A.1.795 ##STR01546## ##STR01547## A.1.796 ##STR01548## ##STR01549##
A.1.797 ##STR01550## ##STR01551## A.1.798 ##STR01552## ##STR01553##
A.1.799 ##STR01554## ##STR01555## A.1.800 ##STR01556## ##STR01557##
A.1.801 ##STR01558## ##STR01559## A.1.802 ##STR01560## ##STR01561##
A.1.803 ##STR01562## ##STR01563## A.1.804 ##STR01564## ##STR01565##
A.1.805 ##STR01566## ##STR01567## A.1.806 ##STR01568## ##STR01569##
A.1.807 ##STR01570## ##STR01571## A.1.808 ##STR01572## ##STR01573##
A.1.809 ##STR01574## ##STR01575## A.1.810 ##STR01576## ##STR01577##
A.1.811 ##STR01578## ##STR01579## A.1.812 ##STR01580## ##STR01581##
A.1.813 ##STR01582## ##STR01583## A.1.814 ##STR01584## ##STR01585##
A.1.815 ##STR01586## ##STR01587## A.1.816 ##STR01588## ##STR01589##
A.1.817 ##STR01590## ##STR01591## A.1.818 ##STR01592## ##STR01593##
A.1.819 ##STR01594## ##STR01595## A.1.820 ##STR01596## ##STR01597##
A.1.821 ##STR01598## ##STR01599## A.1.822 ##STR01600## ##STR01601##
A.1.823 ##STR01602## ##STR01603## A.1.824 ##STR01604## ##STR01605##
A.1.825 ##STR01606## ##STR01607## A.1.826 ##STR01608## ##STR01609##
A.1.827 ##STR01610## ##STR01611## A.1.828 ##STR01612## ##STR01613##
A.1.829 ##STR01614## ##STR01615## A.1.830 ##STR01616## ##STR01617##
A.1.831 ##STR01618## ##STR01619## A.1.832 ##STR01620## ##STR01621##
A.1.833 ##STR01622## ##STR01623## A.1.834 ##STR01624## ##STR01625##
A.1.835 ##STR01626## ##STR01627## A.1.836 ##STR01628## ##STR01629##
A.1.837 ##STR01630## ##STR01631## A.1.838 ##STR01632## ##STR01633##
A.1.839 ##STR01634## ##STR01635## A.1.840 ##STR01636## ##STR01637##
A.1.841 ##STR01638## ##STR01639## A.1.842 ##STR01640## ##STR01641##
A.1.843 ##STR01642## ##STR01643## A.1.844 ##STR01644## ##STR01645##
A.1.845 ##STR01646## ##STR01647## A.1.846 ##STR01648## ##STR01649##
A.1.847 ##STR01650## ##STR01651## A.1.848 ##STR01652## ##STR01653##
A.1.849 ##STR01654## ##STR01655## A.1.850 ##STR01656## ##STR01657##
A.1.851 ##STR01658## ##STR01659## A.1.852 ##STR01660## ##STR01661##
A.1.853 ##STR01662## ##STR01663## A.1.854 ##STR01664## ##STR01665##
A.1.855 ##STR01666## ##STR01667## A.1.856 ##STR01668## ##STR01669##
A.1.857 ##STR01670## ##STR01671## A.1.858 ##STR01672## ##STR01673##
A.1.859 ##STR01674## ##STR01675## A.1.860 ##STR01676## ##STR01677##
A.1.861 ##STR01678## ##STR01679## A.1.862 ##STR01680## ##STR01681##
A.1.863 ##STR01682## ##STR01683## A.1.864 ##STR01684## ##STR01685##
A.1.865 ##STR01686## ##STR01687## A.1.866 ##STR01688## ##STR01689##
A.1.867 ##STR01690## ##STR01691## A.1.868 ##STR01692## ##STR01693##
A.1.869 ##STR01694## ##STR01695## A.1.870 ##STR01696## ##STR01697##
A.1.871 ##STR01698## ##STR01699## A.1.872 ##STR01700## ##STR01701##
A.1.873 ##STR01702## ##STR01703## A.1.874 ##STR01704##
##STR01705##
A.1.875 ##STR01706## ##STR01707## A.1.876 ##STR01708## ##STR01709##
A.1.877 ##STR01710## ##STR01711## A.1.878 ##STR01712## ##STR01713##
A.1.879 ##STR01714## ##STR01715## A.1.880 ##STR01716## ##STR01717##
A.1.881 ##STR01718## ##STR01719## A.1.882 ##STR01720## ##STR01721##
A.1.883 ##STR01722## ##STR01723## A.1.884 ##STR01724## ##STR01725##
A.1.885 ##STR01726## ##STR01727## A.1.886 ##STR01728## ##STR01729##
A.1.887 ##STR01730## ##STR01731## A.1.888 ##STR01732## ##STR01733##
A.1.889 ##STR01734## ##STR01735## A.1.890 ##STR01736## ##STR01737##
A.1.891 ##STR01738## ##STR01739## A.1.892 ##STR01740## ##STR01741##
A.1.893 ##STR01742## ##STR01743## A.1.894 ##STR01744## ##STR01745##
A.1.895 ##STR01746## ##STR01747## A.1.896 ##STR01748## ##STR01749##
A.1.897 ##STR01750## ##STR01751## A.1.898 ##STR01752## ##STR01753##
A.1.899 ##STR01754## ##STR01755## A.1.900 ##STR01756## ##STR01757##
A.1.901 ##STR01758## ##STR01759## A.1.902 ##STR01760## ##STR01761##
A.1.903 ##STR01762## ##STR01763## A.1.904 ##STR01764## ##STR01765##
A.1.905 ##STR01766## ##STR01767## A.1.906 ##STR01768## ##STR01769##
A.1.907 ##STR01770## ##STR01771## A.1.908 ##STR01772## ##STR01773##
A.1.909 ##STR01774## ##STR01775## A.1.910 ##STR01776## ##STR01777##
A.1.911 ##STR01778## ##STR01779## A.1.912 ##STR01780## ##STR01781##
A.1.913 ##STR01782## ##STR01783## A.1.914 ##STR01784## ##STR01785##
A.1.915 ##STR01786## ##STR01787## A.1.916 ##STR01788## ##STR01789##
A.1.917 ##STR01790## ##STR01791## A.1.918 ##STR01792## ##STR01793##
A.1.919 ##STR01794## ##STR01795## A.1.920 ##STR01796## ##STR01797##
A.1.921 ##STR01798## ##STR01799## A.1.922 ##STR01800## ##STR01801##
A.1.923 ##STR01802## ##STR01803## A.1.924 ##STR01804## ##STR01805##
A.1.925 ##STR01806## ##STR01807## A.1.926 ##STR01808## ##STR01809##
A.1.927 ##STR01810## ##STR01811## A.1.928 ##STR01812## ##STR01813##
A.1.929 ##STR01814## ##STR01815## A.1.930 ##STR01816## ##STR01817##
A.1.931 ##STR01818## ##STR01819## A.1.932 ##STR01820## ##STR01821##
A.1.933 ##STR01822## ##STR01823## A.1.934 ##STR01824## ##STR01825##
A.1.935 ##STR01826## ##STR01827## A.1.936 ##STR01828## ##STR01829##
A.1.937 ##STR01830## ##STR01831## A.1.938 ##STR01832## ##STR01833##
A.1.939 ##STR01834## ##STR01835## A.1.940 ##STR01836## ##STR01837##
A.1.941 ##STR01838## ##STR01839## A.1.942 ##STR01840## ##STR01841##
A.1.943 ##STR01842## ##STR01843## A.1.944 ##STR01844## ##STR01845##
A.1.945 ##STR01846## ##STR01847## A.1.946 ##STR01848## ##STR01849##
A.1.947 ##STR01850## ##STR01851## A.1.948 ##STR01852## ##STR01853##
A.1.949 ##STR01854## ##STR01855## A.1.950 ##STR01856## ##STR01857##
A.1.951 ##STR01858## ##STR01859## A.1.952 ##STR01860## ##STR01861##
A.1.953 ##STR01862## ##STR01863## A.1.954 ##STR01864## ##STR01865##
A.1.955 ##STR01866## ##STR01867## A.1.956 ##STR01868## ##STR01869##
A.1.957 ##STR01870## ##STR01871## A.1.958 ##STR01872## ##STR01873##
A.1.959 ##STR01874## ##STR01875## A.1.960 ##STR01876## ##STR01877##
A.1.961 ##STR01878## ##STR01879## A.1.962 ##STR01880## ##STR01881##
A.1.963 ##STR01882## ##STR01883## A.1.964 ##STR01884## ##STR01885##
A.1.965 ##STR01886## ##STR01887## A.1.966 ##STR01888## ##STR01889##
A.1.967 ##STR01890## ##STR01891## A.1.968 ##STR01892## ##STR01893##
A.1.969 ##STR01894## ##STR01895## A.1.970 ##STR01896## ##STR01897##
A.1.971 ##STR01898## ##STR01899## A.1.972 ##STR01900## ##STR01901##
A.1.973 ##STR01902## ##STR01903## A.1.974 ##STR01904## ##STR01905##
A.1.975 ##STR01906## ##STR01907## A.1.976 ##STR01908## ##STR01909##
A.1.977 ##STR01910## ##STR01911## A.1.978 ##STR01912## ##STR01913##
A.1.979 ##STR01914## ##STR01915## A.1.980 ##STR01916## ##STR01917##
A.1.981 ##STR01918## ##STR01919## A.1.982 ##STR01920## ##STR01921##
A.1.983 ##STR01922## ##STR01923## A.1.984 ##STR01924## ##STR01925##
A.1.985 ##STR01926## ##STR01927## A.1.986 ##STR01928## ##STR01929##
A.1.987 ##STR01930## ##STR01931## A.1.988 ##STR01932## ##STR01933##
A.1.989 ##STR01934## ##STR01935## A.1.990 ##STR01936## ##STR01937##
A.1.991 ##STR01938## ##STR01939## A.1.992 ##STR01940## ##STR01941##
A.1.993 ##STR01942## ##STR01943## A.1.994 ##STR01944## ##STR01945##
A.1.995 ##STR01946## ##STR01947## A.1.996 ##STR01948## ##STR01949##
A.1.997 ##STR01950## ##STR01951## A.1.998 ##STR01952## ##STR01953##
A.1.999 ##STR01954## ##STR01955##
A.1.1000 ##STR01956## ##STR01957## A.1.1001 ##STR01958##
##STR01959## A.1.1002 ##STR01960## ##STR01961## A.1.1003
##STR01962## ##STR01963## A.1.1004 ##STR01964## ##STR01965##
A.1.1005 ##STR01966## ##STR01967## A.1.1006 ##STR01968##
##STR01969## A.1.1007 ##STR01970## ##STR01971## A.1.1008
##STR01972## ##STR01973## A.1.1009 ##STR01974## ##STR01975##
A.1.1010 ##STR01976## ##STR01977## A.1.1011 ##STR01978##
##STR01979## A.1.1012 ##STR01980## ##STR01981## A.1.1013
##STR01982## ##STR01983## A.1.1014 ##STR01984## ##STR01985##
A.1.1015 ##STR01986## ##STR01987## A.1.1016 ##STR01988##
##STR01989## A.1.1017 ##STR01990## ##STR01991## A.1.1018
##STR01992## ##STR01993## A.1.1019 ##STR01994## ##STR01995##
A.1.1020 ##STR01996## ##STR01997## A.1.1021 ##STR01998##
##STR01999## A.1.1022 ##STR02000## ##STR02001## A.1.1023
##STR02002## ##STR02003## A.1.1024 ##STR02004## ##STR02005##
A.1.1025 ##STR02006## ##STR02007## A.1.1026 ##STR02008## H--#
A.1.1027 ##STR02009## H--# A.1.1028 ##STR02010## H--# A.1.1029
##STR02011## H--# A.1.1030 ##STR02012## H--# A.1.1031 ##STR02013##
H--# A.1.1032 ##STR02014## H--# A.1.1033 ##STR02015## H--# A.1.1034
##STR02016## ##STR02017## A.1.1035 ##STR02018## ##STR02019##
A.1.1036 ##STR02020## ##STR02021## A.1.1037 ##STR02022##
##STR02023## A.1.1038 ##STR02024## ##STR02025## A.1.1039
##STR02026## ##STR02027## A.1.1040 ##STR02028## ##STR02029##
A.1.1041 ##STR02030## ##STR02031## A.1.1042 ##STR02032##
##STR02033## A.1.1043 ##STR02034## ##STR02035## A.1.1044
##STR02036## ##STR02037## A.1.1045 ##STR02038## ##STR02039##
A.1.1046 ##STR02040## ##STR02041## A.1.1047 ##STR02042##
##STR02043## A.1.1048 ##STR02044## ##STR02045## A.1.1049
##STR02046## ##STR02047## A.1.1050 ##STR02048## ##STR02049##
A.1.1051 ##STR02050## ##STR02051## A.1.1052 ##STR02052##
##STR02053## A.1.1053 ##STR02054## ##STR02055## A.1.1054
##STR02056## ##STR02057## A.1.1055 ##STR02058## ##STR02059##
A.1.1056 ##STR02060## ##STR02061## A.1.1057 ##STR02062##
##STR02063## A.1.1058 ##STR02064## ##STR02065## A.1.1059
##STR02066## ##STR02067## A.1.1060 ##STR02068## ##STR02069##
A.1.1061 ##STR02070## ##STR02071## A.1.1062 ##STR02072##
##STR02073## A.1.1063 ##STR02074## ##STR02075## A.1.1064
##STR02076## ##STR02077## A.1.1065 ##STR02078## ##STR02079##
A.1.1066 ##STR02080## ##STR02081## A.1.1067 ##STR02082##
##STR02083## A.1.1068 ##STR02084## ##STR02085## A.1.1069
##STR02086## ##STR02087## A.1.1070 ##STR02088## ##STR02089##
A.1.1071 ##STR02090## ##STR02091## A.1.1072 ##STR02092##
##STR02093## A.1.1073 ##STR02094## ##STR02095## A.1.1074
##STR02096## ##STR02097## A.1.1075 ##STR02098## ##STR02099##
A.1.1076 ##STR02100## ##STR02101## A.1.1077 ##STR02102##
##STR02103## A.1.1078 ##STR02104## ##STR02105## A.1.1079
##STR02106## ##STR02107## A.1.1080 ##STR02108## ##STR02109##
A.1.1081 ##STR02110## ##STR02111## A.1.1082 ##STR02112##
##STR02113## A.1.1083 ##STR02114## ##STR02115## A.1.1084
##STR02116## ##STR02117## A.1.1085 ##STR02118## ##STR02119##
A.1.1086 ##STR02120## ##STR02121## A.1.1087 ##STR02122##
##STR02123## A.1.1088 ##STR02124## ##STR02125## A.1.1089
##STR02126## ##STR02127## A.1.1090 ##STR02128## ##STR02129##
A.1.1091 ##STR02130## ##STR02131## A.1.1092 ##STR02132##
##STR02133## A.1.1093 ##STR02134## ##STR02135## A.1.1094
##STR02136## ##STR02137## A.1.1095 ##STR02138## ##STR02139##
A.1.1096 ##STR02140## ##STR02141## A.1.1097 ##STR02142##
##STR02143## A.1.1098 ##STR02144## ##STR02145## A.1.1099
##STR02146## ##STR02147## A.1.1100 ##STR02148## ##STR02149##
A.1.1101 ##STR02150## ##STR02151## A.1.1102 ##STR02152##
##STR02153## A.1.1103 ##STR02154## ##STR02155## A.1.1104
##STR02156## ##STR02157## A.1.1105 ##STR02158## ##STR02159##
A.1.1106 ##STR02160## ##STR02161## A.1.1107 ##STR02162##
##STR02163## A.1.1108 ##STR02164## ##STR02165## A.1.1109
##STR02166## ##STR02167## A.1.1110 ##STR02168## ##STR02169##
A.1.1111 ##STR02170## ##STR02171## A.1.1112 ##STR02172##
##STR02173## A.1.1113 ##STR02174## ##STR02175## A.1.1114
##STR02176## ##STR02177## A.1.1115 ##STR02178## ##STR02179##
A.1.1116 ##STR02180## ##STR02181## A.1.1117 ##STR02182##
##STR02183## A.1.1118 ##STR02184## ##STR02185## A.1.1119
##STR02186## ##STR02187## A.1.1120 ##STR02188## ##STR02189##
A.1.1121 ##STR02190## ##STR02191## A.1.1122 ##STR02192##
##STR02193## A.1.1123 ##STR02194## ##STR02195## A.1.1124
##STR02196## ##STR02197## A.1.1125 ##STR02198## ##STR02199##
A.1.1126 ##STR02200## ##STR02201## A.1.1127 ##STR02202##
##STR02203## A.1.1128 ##STR02204## ##STR02205## A.1.1129
##STR02206## ##STR02207## A.1.1130 ##STR02208## ##STR02209##
A.1.1131 ##STR02210## ##STR02211## A.1.1132 ##STR02212##
##STR02213## A.1.1133 ##STR02214## ##STR02215## A.1.1134
##STR02216## ##STR02217## A.1.1135 ##STR02218## ##STR02219##
A.1.1136 ##STR02220## ##STR02221## A.1.1137 ##STR02222##
##STR02223## A.1.1138 ##STR02224## ##STR02225## A.1.1139
##STR02226## ##STR02227## A.1.1140 ##STR02228## ##STR02229##
A.1.1141 ##STR02230## ##STR02231## A.1.1142 ##STR02232##
##STR02233## A.1.1143 ##STR02234## ##STR02235## A.1.1144
##STR02236## ##STR02237## A.1.1145 ##STR02238## ##STR02239##
A.1.1146 ##STR02240## ##STR02241## A.1.1147 ##STR02242##
##STR02243## A.1.1148 ##STR02244## ##STR02245## A.1.1149
##STR02246## ##STR02247## A.1.1150 ##STR02248## ##STR02249##
A.1.1151 ##STR02250## ##STR02251## A.1.1152 ##STR02252##
##STR02253## A.1.1153 ##STR02254## ##STR02255## A.1.1154
##STR02256## ##STR02257## A.1.1155 ##STR02258## ##STR02259##
A.1.1156 ##STR02260## ##STR02261## A.1.1157 ##STR02262##
##STR02263## A.1.1158 ##STR02264## ##STR02265## A.1.1159
##STR02266## ##STR02267## A.1.1160 ##STR02268## ##STR02269##
A.1.1161 ##STR02270## ##STR02271## A.1.1162 ##STR02272##
##STR02273## A.1.1163 ##STR02274## ##STR02275## A.1.1164
##STR02276## ##STR02277## A.1.1165 ##STR02278## ##STR02279##
A.1.1166 ##STR02280## ##STR02281## A.1.1167 ##STR02282##
##STR02283## A.1.1168 ##STR02284## ##STR02285## A.1.1169
##STR02286## ##STR02287## A.1.1170 ##STR02288## ##STR02289##
A.1.1171 ##STR02290## ##STR02291## A.1.1172 ##STR02292##
##STR02293## A.1.1173 ##STR02294## ##STR02295## A.1.1174
##STR02296## ##STR02297## A.1.1175 ##STR02298## ##STR02299##
A.1.1176 ##STR02300## ##STR02301## A.1.1177 ##STR02302##
##STR02303## A.1.1178 ##STR02304## ##STR02305## A.1.1179
##STR02306## ##STR02307## A.1.1180 ##STR02308## ##STR02309##
A.1.1181 ##STR02310## ##STR02311## A.1.1182 ##STR02312##
##STR02313## A.1.1183 ##STR02314## ##STR02315## A.1.1184
##STR02316## ##STR02317## A.1.1185 ##STR02318## ##STR02319##
A.1.1186 ##STR02320## ##STR02321## A.1.1187 ##STR02322##
##STR02323## A.1.1188 ##STR02324## ##STR02325## A.1.1189
##STR02326## ##STR02327## A.1.1190 ##STR02328## ##STR02329##
A.1.1191 ##STR02330## ##STR02331## A.1.1192 ##STR02332##
##STR02333## A.1.1193 ##STR02334## ##STR02335## A.1.1194
##STR02336## ##STR02337## A.1.1195 ##STR02338## ##STR02339##
A.1.1196 ##STR02340## ##STR02341## A.1.1197 ##STR02342##
##STR02343## A.1.1198 ##STR02344## ##STR02345## A.1.1199
##STR02346## ##STR02347## A.1.1200 ##STR02348## ##STR02349##
A.1.1201 ##STR02350## ##STR02351##
[1141] The following tables T1 to T151 disclose preferred compounds
of formula I for inclusion as component A in compositions of the
invention.
TABLE-US-00004 TABLE 1 This table discloses the 1201 compounds
T1.1.1 to T1.1.1201 of the formula ##STR02352## (T1) in which, for
each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A. For example, the specific
compound T1.1.13 is the compound of the formula T1, in which each
of the variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the
specific meaning given in the line A.1.13 of Table A: ##STR02353##
(T1.1.13) According to the same system, also all of the other 1201
specific compounds disclosed in the Table 1 as well as all of the
specific compounds disclosed in the Tables 2 to T151 are specified
analogously.
TABLE-US-00005 TABLE 2 This table discloses the 1201 compounds
T2.1.1 to T2.1.1201 of the formula ##STR02354## (T2) in which, for
each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00006 TABLE 3 This table discloses the 1201 compounds
T3.1.1 to T3.1.1201 of the formula ##STR02355## (T3) in which, for
each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00007 TABLE 4 This table discloses the 1201 compounds
T4.1.1 to T4.1.1201 of the formula ##STR02356## (T4) in which, for
each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00008 TABLE 5 This table discloses the 1201 compounds
T5.1.1 to T5.1.1201 of the formula ##STR02357## (T5) in which, for
each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00009 TABLE 6 This table discloses the 1201 compounds
T6.1.1 to T6.1.1201 of the formula ##STR02358## (T6) in which, for
each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00010 TABLE 7 This table discloses the 1201 compounds
T7.1.1 to T7.1.1201 of the formula ##STR02359## (T7) in which, for
each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00011 TABLE 8 This table discloses the 1201 compounds
T8.1.1 to T8.1.1201 of the formula ##STR02360## (T8) in which, for
each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00012 TABLE 9 This table discloses the 1201 compounds
T9.1.1 to T9.1.1201 of the formula ##STR02361## (T9) in which, for
each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00013 TABLE 10 This table discloses the 1201 compounds
T10.1.1 to T10.1.1201 of the formula ##STR02362## (T10) in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00014 TABLE 11 This table discloses the 1201 compounds
T11.1.1 to T11.1.1201 of the formula ##STR02363## (T11) in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00015 TABLE 12 This table discloses the 1201 compounds
T12.1.1 to T12.1.1201 of the formula ##STR02364## (T12) in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00016 TABLE 13 This table discloses the 1201 compounds
T13.1.1 to T13.1.1201 of the formula ##STR02365## (T13) in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00017 TABLE 14 This table discloses the 1201 compounds
T14.1.1 to T14.1.1201 of the formula ##STR02366## (T14) in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00018 TABLE 15 This table discloses the 1201 compounds
T15.1.1 to T15.1.1201 of the formula ##STR02367## (T15) in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00019 TABLE 16 This table discloses the 1201 compounds
T16.1.1 to T16.1.1201 of the formula (T16) ##STR02368## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00020 TABLE 17 This table discloses the 1201 compounds
T17.1.1 to T17.1.1201 of the formula (T17) ##STR02369## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00021 TABLE 18 This table discloses the 1201 compounds
T18.1.1 to T18.1.1201 of the formula (T18) ##STR02370## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00022 TABLE 19 This table discloses the 1201 compounds
T19.1.1 to T19.1.1201 of the formula (T19) ##STR02371## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00023 TABLE 20 This table discloses the 1201 compounds
T20.1.1 to T20.1.1201 of the formula (T20) ##STR02372## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00024 TABLE 21 This table discloses the 1201 compounds
T21.1.1 to T21.1.1201 of the formula (T21) ##STR02373## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00025 TABLE 22 This table discloses the 1201 compounds
T22.1.1 to T22.1.1201 of the formula (T22) ##STR02374## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00026 TABLE 23 This table discloses the 1201 compounds
T23.1.1 to T23.1.1201 of the formula (T23) ##STR02375## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00027 TABLE 24 This table discloses the 1201 compounds
T24.1.1 to T24.1.1201 of the formula (T24) ##STR02376## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00028 TABLE 25 This table discloses the 1201 compounds
T25.1.1 to T25.1.1201 of the formula (T25) ##STR02377## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00029 TABLE 26 This table discloses the 1201 compounds
T26.1.1 to T26.1.1201 of the formula (T26) ##STR02378## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00030 TABLE 27 This table discloses the 1201 compounds
T27.1.1 to T27.1.1201 of the formula (T27) ##STR02379## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00031 TABLE 28 This table discloses the 1201 compounds
T28.1.1 to T28.1.1201 of the formula (T28) ##STR02380## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00032 TABLE 29 This table discloses the 1201 compounds
T29.1.1 to T29.1.1201 of the formula (T29) ##STR02381## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00033 TABLE 30 This table discloses the 1201 compounds
T30.1.1 to T30.1.1201 of the formula (T30) ##STR02382## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00034 TABLE 31 This table discloses the 1201 compounds
T31.1.1 to T31.1.1201 of the formula (T31) ##STR02383## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00035 TABLE 32 This table discloses the 1201 compounds
T32.1.1 to T32.1.1201 of the formula (T32) ##STR02384## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00036 TABLE 33 This table discloses the 1201 compounds
T33.1.1 to T33.1.1201 of the formula (T33) ##STR02385## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00037 TABLE 34 This table discloses the 1201 compounds
T34.1.1 to T34.1.1201 of the formula (T34) ##STR02386## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00038 TABLE 35 This table discloses the 1201 compounds
T35.1.1 to T35.1.1201 of the formula (T35) ##STR02387## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00039 TABLE 36 This table discloses the 1201 compounds
T36.1.1 to T36.1.1201 of the formula (T36) ##STR02388## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00040 TABLE 37 This table discloses the 1201 compounds
T37.1.1 to T37.1.1201 of the formula (T37) ##STR02389## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00041 TABLE 38 This table discloses the 1201 compounds
T38.1.1 to T38.1.1201 of the formula (T38) ##STR02390## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00042 TABLE 39 This table discloses the 1201 compounds
T39.1.1 to T39.1.1201 of the formula (T39) ##STR02391## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00043 TABLE 40 This table discloses the 1201 compounds
T40.1.1 to T40.1.1201 of the formula (T40) ##STR02392## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00044 TABLE 41 This table discloses the 1201 compounds
T41.1.1 to T41.1.1201 of the formula (T41) ##STR02393## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00045 TABLE 42 This table discloses the 1201 compounds
T42.1.1 to T42.1.1201 of the formula (T42) ##STR02394## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00046 TABLE 43 This table discloses the 1201 compounds
T43.1.1 to T43.1.1201 of the formula (T43) ##STR02395## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00047 TABLE 44 This table discloses the 1201 compounds
T44.1.1 to T44.1.1201 of the formula (T44) ##STR02396## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00048 TABLE 45 This table discloses the 1201 compounds
T45.1.1 to T45.1.1201 of the formula (T45) ##STR02397## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00049 TABLE 46 This table discloses the 1201 compounds
T46.1.1 to T46.1.1201 of the formula (T46) ##STR02398## in which,
for each of these 1201 specific compounds, each of the varia- bles
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the correspond- ing line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00050 TABLE 47 This table discloses the 1201 compounds
T47.1.1 to T47.1.1201 of the formula (T47) ##STR02399## in which,
for each of these 1201 specific compounds, each of the varia- bles
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the correspond- ing line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00051 TABLE 48 This table discloses the 1201 compounds
T48.1.1 to T48.1.1201 of the formula (T48) ##STR02400## in which,
for each of these 1201 specific compounds, each of the varia- bles
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the correspond- ing line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00052 TABLE 49 This table discloses the 1201 compounds
T49.1.1 to T49.1.1201 of the formula (T49) ##STR02401## in which,
for each of these 1201 specific compounds, each of the varia- bles
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the correspond- ing line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00053 TABLE 50 This table discloses the 1201 compounds
T50.1.1 to T50.1.1201 of the formula (T50) ##STR02402## in which,
for each of these 1201 specific compounds, each of the varia- bles
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the correspond- ing line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00054 TABLE 51 This table discloses the 1201 compounds
T51.1.1 to T51.1.1201 of the formula (T51) ##STR02403## in which,
for each of these 1201 specific compounds, each of the varia- bles
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the correspond- ing line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00055 TABLE 52 This table discloses the 1201 compounds
T52.1.1 to T52.1.1201 of the formula (T52) ##STR02404## in which,
for each of these 1201 specific compounds, each of the varia- bles
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the correspond- ing line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00056 TABLE 53 This table discloses the 1201 compounds
T53.1.1 to T53.1.1201 of the formula (T53) ##STR02405## in which,
for each of these 1201 specific compounds, each of the varia- bles
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the correspond- ing line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00057 TABLE 54 This table discloses the 1201 compounds
T54.1.1 to T54.1.1201 of the formula (T54) ##STR02406## in which,
for each of these 1201 specific compounds, each of the varia- bles
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the correspond- ing line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00058 TABLE 55 This table discloses the 1201 compounds
T55.1.1 to T55.1.1201 of the formula (T55) ##STR02407## in which,
for each of these 1201 specific compounds, each of the varia- bles
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the correspond- ing line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00059 TABLE 56 This table discloses the 1201 compounds
T56.1.1 to T56.1.1201 of the formula (T56) ##STR02408## in which,
for each of these 1201 specific compounds, each of the varia- bles
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the correspond- ing line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00060 TABLE 57 This table discloses the 1201 compounds
T57.1.1 to T57.1.1201 of the formula (T57) ##STR02409## in which,
for each of these 1201 specific compounds, each of the varia- bles
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the correspond- ing line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00061 TABLE 58 This table discloses the 1201 compounds
T58.1.1 to T58.1.1201 of the formula (T58) ##STR02410## in which,
for each of these 1201 specific compounds, each of the varia- bles
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the correspond- ing line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00062 TABLE 59 This table discloses the 1201 compounds
T59.1.1 to T59.1.1201 of the formula (T59) ##STR02411## in which,
for each of these 1201 specific compounds, each of the varia- bles
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the correspond- ing line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00063 TABLE 60 This table discloses the 1201 compounds
T60.1.1 to T60.1.1201 of the formula (T60) ##STR02412## in which,
for each of these 1201 specific compounds, each of the varia- bles
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the correspond- ing line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00064 TABLE 61 This table discloses the 1201 compounds
T61.1.1 to T61.1.1201 of the formula (T61) ##STR02413## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00065 TABLE 62 This table discloses the 1201 compounds
T62.1.1 to T62.1.1201 of the formula (T62) ##STR02414## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00066 TABLE 63 This table discloses the 1201 compounds
T63.1.1 to T63.1.1201 of the formula (T63) ##STR02415## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00067 TABLE 64 This table discloses the 1201 compounds
T64.1.1 to T64.1.1201 of the formula (T64) ##STR02416## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00068 TABLE 65 This table discloses the 1201 compounds
T65.1.1 to T65.1.1201 of the formula (T65) ##STR02417## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00069 TABLE 66 This table discloses the 1201 compounds
T66.1.1 to T66.1.1201 of the formula (T66) ##STR02418## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00070 TABLE 67 This table discloses the 1201 compounds
T67.1.1 to T67.1.1201 of the formula (T67) ##STR02419## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00071 TABLE 68 This table discloses the 1201 compounds
T68.1.1 to T68.1.1201 of the formula (T68) ##STR02420## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00072 TABLE 69 This table discloses the 1201 compounds
T69.1.1 to T69.1.1201 of the formula (T69) ##STR02421## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00073 TABLE 70 This table discloses the 1201 compounds
T70.1.1 to T70.1.1201 of the formula (T70) ##STR02422## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00074 TABLE 71 This table discloses the 1201 compounds
T71.1.1 to T71.1.1201 of the formula (T71) ##STR02423## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00075 TABLE 72 This table discloses the 1201 compounds
T72.1.1 to T72.1.1201 of the formula (T72) ##STR02424## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00076 TABLE 73 This table discloses the 1201 compounds
T73.1.1 to T73.1.1201 of the formula (T73) ##STR02425## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00077 TABLE 74 This table discloses the 1201 compounds
T74.1.1 to T74.1.1201 of the formula (T74) ##STR02426## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00078 TABLE 75 This table discloses the 1201 compounds
T75.1.1 to T75.1.1201 of the formula (T75) ##STR02427## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00079 TABLE 76 This table discloses the 1201 compounds
T76.1.1 to T76.1.1201 of the formula (T76) ##STR02428## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00080 TABLE 77 This table discloses the 1201 compounds
T77.1.1 to T77.1.1201 of the formula (T77) ##STR02429## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00081 TABLE 78 This table discloses the 1201 compounds
T78.1.1 to T78.1.1201 of the formula (T78) ##STR02430## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00082 TABLE 79 This table discloses the 1201 compounds
T79.1.1 to T79.1.1201 of the formula (T79) ##STR02431## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00083 TABLE 80 This table discloses the 1201 compounds
T80.1.1 to T80.1.1201 of the formula (T80) ##STR02432## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00084 TABLE 81 This table discloses the 1201 compounds
T81.1.1 to T81.1.1201 of the formula (T81) ##STR02433## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00085 TABLE 82 This table discloses the 1201 compounds
T82.1.1 to T82.1.1201 of the formula (T82) ##STR02434## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00086 TABLE 83 This table discloses the 1201 compounds
T83.1.1 to T83.1.1201 of the formula (T83) ##STR02435## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00087 TABLE 84 This table discloses the 1201 compounds
T84.1.1 to T84.1.1201 of the formula (T84) ##STR02436## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00088 TABLE 85 This table discloses the 1201 compounds
T85.1.1 to T85.1.1201 of the formula (T85) ##STR02437## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00089 TABLE 86 This table discloses the 1201 compounds
T86.1.1 to T86.1.1201 of the formula (T86) ##STR02438## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00090 TABLE 87 This table discloses the 1201 compounds
T87.1.1 to T87.1.1201 of the formula (T87) ##STR02439## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00091 TABLE 88 This table discloses the 1201 compounds
T88.1.1 to T88.1.1201 of the formula (T88) ##STR02440## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00092 TABLE 89 This table discloses the 1201 compounds
T89.1.1 to T89.1.1201 of the formula (T89) ##STR02441## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00093 TABLE 90 This table discloses the 1201 compounds
T90.1.1 to T90.1.1201 of the formula (T90) ##STR02442## in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00094 TABLE 91 This table discloses the 1201 compounds
T91.1.1 to T91.1.1201 of the formula ##STR02443## (T91) in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00095 TABLE 92 This table discloses the 1201 compounds
T92.1.1 to T92.1.1201 of the formula ##STR02444## (T92) in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00096 TABLE 93 This table discloses the 1201 compounds
T93.1.1 to T93.1.1201 of the formula ##STR02445## (T93) in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00097 TABLE 94 This table discloses the 1201 compounds
T94.1.1 to T94.1.1201 of the formula ##STR02446## (T94) in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00098 TABLE 95 This table discloses the 1201 compounds
T95.1.1 to T95.1.1201 of the formula ##STR02447## (T95) in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00099 TABLE 96 This table discloses the 1201 compounds
T96.1.1 to T96.1.1201 of the formula ##STR02448## (T96) in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00100 TABLE 97 This table discloses the 1201 compounds
T97.1.1 to T97.1.1201 of the formula ##STR02449## (T97) in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00101 TABLE 98 This table discloses the 1201 compounds
T98.1.1 to T98.1.1201 of the formula ##STR02450## (T98) in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00102 TABLE 99 This table discloses the 1201 compounds
T99.1.1 to T99.1.1201 of the formula ##STR02451## (T99) in which,
for each of these 1201 specific compounds, each of the variables
R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific meaning
given in the corresponding line, appropriately selected from the
1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00103 TABLE 100 This table discloses the 1201 compounds
T100.1.1 to T100.1.1201 of the formula ##STR02452## (T100) in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00104 TABLE 101 This table discloses the 1201 compounds
T101.1.1 to T101.1.1201 of the formula ##STR02453## (T101) in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00105 TABLE 102 This table discloses the 1201 compounds
T102.1.1 to T102.1.1201 of the formula ##STR02454## (T102) in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00106 TABLE 103 This table discloses the 1201 compounds
T103.1.1 to T103.1.1201 of the formula ##STR02455## (T103) in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00107 TABLE 104 This table discloses the 1201 compounds
T104.1.1 to T104.1.1201 of the formula ##STR02456## (T104) in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00108 TABLE 105 This table discloses the 1201 compounds
T105.1.1 to T105.1.1201 of the formula ##STR02457## (T105) in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00109 TABLE 106 This table discloses the 1201 compounds
T106.1.1 to T106.1.1201 of the formula ##STR02458## (T106) in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00110 TABLE 107 This table discloses the 1201 compounds
T107.1.1 to T107.1.1201 of the formula ##STR02459## (T107) in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00111 TABLE 108 This table discloses the 1201 compounds
T108.1.1 to T108.1.1201 of the formula ##STR02460## (T108) in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00112 TABLE 109 This table discloses the 1201 compounds
T109.1.1 to T109.1.1201 of the formula ##STR02461## (T109) in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00113 TABLE 110 This table discloses the 1201 compounds
T110.1.1 to T110.1.1201 of the formula ##STR02462## (T110) in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00114 TABLE 111 This table discloses the 1201 compounds
T111.1.1 to T111.1.1201 of the formula ##STR02463## (T111) in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00115 TABLE 112 This table discloses the 1201 compounds
T112.1.1 to T112.1.1201 of the formula ##STR02464## (T112) in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00116 TABLE 113 This table discloses the 1201 compounds
T113.1.1 to T113.1.1201 of the formula ##STR02465## (T113) in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00117 TABLE 114 This table discloses the 1201 compounds
T114.1.1 to T114.1.1201 of the formula ##STR02466## (T114) in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00118 TABLE 115 This table discloses the 1201 compounds
T115.1.1 to T115.1.1201 of the formula ##STR02467## (T115) in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00119 TABLE 116 This table discloses the 1201 compounds
T116.1.1 to T116.1.1201 of the formula ##STR02468## (T116) in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00120 TABLE 117 This table discloses the 1201 compounds
T117.1.1 to T117.1.1201 of the formula ##STR02469## (T117) in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00121 TABLE 118 This table discloses the 1201 compounds
T118.1.1 to T118.1.1201 of the formula ##STR02470## (T118) in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00122 TABLE 119 This table discloses the 1201 compounds
T119.1.1 to T119.1.1201 of the formula ##STR02471## (T119) in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00123 TABLE 120 This table discloses the 1201 compounds
T120.1.1 to T120.1.1201 of the formula ##STR02472## (T120) in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00124 TABLE 121 This table discloses the 1201 compounds
T121.1.1 to T121.1.1201 of the formula ##STR02473## (T121) in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00125 TABLE 122 This table discloses the 1201 compounds
T122.1.1 to T122.1.1201 of the formula ##STR02474## (T122) in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00126 TABLE 123 This table discloses the 1201 compounds
T123.1.1 to T123.1.1201 of the formula ##STR02475## (T123) in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00127 TABLE 124 This table discloses the 1201 compounds
T124.1.1 to T124.1.1201 of the formula ##STR02476## (T124) in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00128 TABLE 125 This table discloses the 1201 compounds
T125.1.1 to T125.1.1201 of the formula ##STR02477## (T125) in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00129 TABLE 126 This table discloses the 1201 compounds
T126.1.1 to T126.1.1201 of the formula ##STR02478## (T126) in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00130 TABLE 127 This table discloses the 1201 compounds
T127.1.1 to T127.1.1201 of the formula ##STR02479## (T127) in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00131 TABLE 128 This table discloses the 1201 compounds
T128.1.1 to T128.1.1201 of the formula ##STR02480## (T128) in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00132 TABLE 129 This table discloses the 1201 compounds
T129.1.1 to T129.1.1201 of the formula ##STR02481## (T129) in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00133 TABLE 130 This table discloses the 1201 compounds
T130.1.1 to T130.1.1201 of the formula ##STR02482## (T130) in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00134 TABLE 131 This table discloses the 1201 compounds
T131.1.1 to T131.1.1201 of the formula ##STR02483## (T131) in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00135 TABLE 132 This table discloses the 1201 compounds
T132.1.1 to T132.1.1201 of the formula ##STR02484## (T132) in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00136 TABLE 133 This table discloses the 1201 compounds
T133.1.1 to T133.1.1201 of the formula ##STR02485## (T133) in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00137 TABLE 134 This table discloses the 1201 compounds
T134.1.1 to T134.1.1201 of the formula ##STR02486## (T134) in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00138 TABLE 135 This table discloses the 1201 compounds
T135.1.1 to T135.1.1201 of the formula ##STR02487## (T135) in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00139 TABLE 136 This table discloses the 1201 compounds
T136.1.1 to T136.1.1201 of the formula (T136) ##STR02488## in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00140 TABLE 137 This table discloses the 1201 compounds
T137.1.1 to T137.1.1201 of the formula (T137) ##STR02489## in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00141 TABLE 138 This table discloses the 1201 compounds
T138.1.1 to T138.1.1201 of the formula (T138) ##STR02490## in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00142 TABLE 139 This table discloses the 1201 compounds
T139.1.1 to T139.1.1201 of the formula (T139) ##STR02491## in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00143 TABLE 140 This table discloses the 1201 compounds
T140.1.1 to T140.1.1201 of the formula (T140) ##STR02492## in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00144 TABLE 141 This table discloses the 1201 compounds
T141.1.1 to T141.1.1201 of the formula (T141) ##STR02493## in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00145 TABLE 142 This table discloses the 1201 compounds
T142.1.1 to T142.1.1201 of the formula (T142) ##STR02494## in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00146 TABLE 143 This table discloses the 1201 compounds
T143.1.1 to T143.1.1201 of the formula (T143) ##STR02495## in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00147 TABLE 144 This table discloses the 1201 compounds
T144.1.1 to T144.1.1201 of the formula (T144) ##STR02496## in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00148 TABLE 145 This table discloses the 1201 compounds
T145.1.1 to T145.1.1201 of the formula (T145) ##STR02497## in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00149 TABLE 146 This table discloses the 1201 compounds
T146.1.1 to T146.1.1201 of the formula (T146) ##STR02498## in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00150 TABLE 147 This table discloses the 1201 compounds
T147.1.1 to T147.1.1201 of the formula (T147) ##STR02499## in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00151 TABLE 148 This table discloses the 1201 compounds
T148.1.1 to T148.1.1201 of the formula (T148) ##STR02500## in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00152 TABLE 149 This table discloses the 1201 compounds
T149.1.1 to T149.1.1201 of the formula (T149) ##STR02501## in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00153 TABLE 150 This table discloses the 1201 compounds
T150.1.1 to T150.1.1201 of the formula (T150) ##STR02502## in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00154 TABLE 151 This table discloses the 1201 compounds
T151.1.1 to T151.1.1201 of the formula (T151) ##STR02503## in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00155 TABLE 152 This table discloses the 1201 compounds
T152.1.1 to T152.1.1201 of the formula (T152) ##STR02504## in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the coresponding line, appropriately selected from
the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00156 TABLE 153 This table discloses the 1201 compounds
T153.1.1 to T153.1.1201 of the formula (T153) ##STR02505## in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00157 TABLE 154 This table discloses the 1201 compounds
T154.1.1 to T154.1.1201 of the formula (T154) ##STR02506## in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00158 TABLE 155 This table discloses the 1201 compounds
T155.1.1 to T155.1.1201 of the formula (T155) ##STR02507## in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00159 TABLE 156 This table discloses the 1201 compounds
T156.1.1 to T156.1.1201 of the formula (T156) ##STR02508## in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00160 TABLE 157 This table discloses the 1201 compounds
T157.1.1 to T157.1.1201 of the formula (T157) ##STR02509## in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00161 TABLE 158 This table discloses the 1201 compounds
T158.1.1 to T158.1.1201 of the formula (T158) ##STR02510## in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00162 TABLE 159 This table discloses the 1201 compounds
T159.1.1 to T159.1.1201 of the formula (T159) ##STR02511## in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00163 TABLE 160 This table discloses the 1201 compounds
T160.1.1 to T160.1.1201 of the formula (T160) ##STR02512## in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00164 TABLE 161 This table discloses the 1201 compounds
T161.1.1 to T161.1.1201 of the formula (T161) ##STR02513## in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00165 TABLE 162 This table discloses the 1201 compounds
T162.1.1 to T162.1.1201 of the formula (T162) ##STR02514## in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00166 TABLE 163 This table discloses the 1201 compounds
T163.1.1 to T163.1.1201 of the formula (T163) ##STR02515## in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1.1 to A.1.1201 of Table A.
TABLE-US-00167 TABLE 164 This table discloses the 1201 compounds
T164.1.1 to T164.1.1201 of the formula (T164) ##STR02516## in
which, for each of these 1201 specific compounds, each of the
variables R.sub.1, R.sub.2, R.sub.5 and R.sub.6 has the specific
meaning given in the corresponding line, appropriately selected
from the 1201 lines A.1. to A.1.1201 of Table A.
[1142] In further embodiments the invention provides novel
intermediates to provide compounds according to formula (I) are
compounds of formula (IV)
##STR02517##
[1143] wherein R.sub.100 is wherein R.sub.100 is halogen, SH,
C.sub.1-C.sub.4-alkylthio, C.sub.1-C.sub.4-alkysulfinyl,
C.sub.1-C.sub.4-alkylsulfonyl and R.sub.1, R.sub.2, R.sub.3,
R.sub.4, R.sub.6 and R.sub.7 are as described herein for compounds
of formula (I).
[1144] The following table provides a selection of compounds of
formula (IV)
TABLE-US-00168 R.01 ##STR02518## R.02 ##STR02519## Mp: 168-
170.degree. C. R.03 ##STR02520## R.04 ##STR02521## R.05
##STR02522## R.06 ##STR02523## R.07 ##STR02524## R.08 ##STR02525##
R.09 ##STR02526## R.10 ##STR02527## R.11 ##STR02528## R.12
##STR02529## Mp: 85-87.degree. C. R.13 ##STR02530## R.14
##STR02531## R.15 ##STR02532## R.16 ##STR02533## R.17 ##STR02534##
R.18 ##STR02535## R.19 ##STR02536## R.20 ##STR02537## R.21
##STR02538## R.22 ##STR02539## Oil; (M + 1).sup.+ 300 R.23
##STR02540## R.24 ##STR02541## R.25 ##STR02542## R.26 ##STR02543##
R.27 ##STR02544## R.28 ##STR02545## R.29 ##STR02546## R.30
##STR02547## R.31 ##STR02548## R.32 ##STR02549## Oil; (M + 1).sup.+
290 R.33 ##STR02550## R.34 ##STR02551## R.35 ##STR02552## R.36
##STR02553## R.37 ##STR02554## R.38 ##STR02555## R.39 ##STR02556##
R.40 ##STR02557## R.41 ##STR02558## R.42 ##STR02559## R.43
##STR02560## R.44 ##STR02561## R.45 ##STR02562## R.46 ##STR02563##
R.47 ##STR02564## R.48 ##STR02565## R.49 ##STR02566## R.50
##STR02567## R.51 ##STR02568## R.52 ##STR02569## R.53 ##STR02570##
R.54 ##STR02571## R.55 ##STR02572## R.56 ##STR02573## R.57
##STR02574## R.58 ##STR02575## R.59 ##STR02576## R.60
##STR02577##
[1145] The active compounds of component B are known e.g. from the
Pesticide Manual (British Crop Protection Council).
N-[9-(dichloromethylene)-1,2,3,4-tetrahydro-1,4-methanonaphthalen-5-yl]-3-
-(difluoromethyl)-1-methyl-1H-pyrazole-4-carboxamide has the
Chemical Abstracts Registry Number [1072957-71-1]. The compound of
formula (II) has the Chemical Abstracts Registry Number
[173662-97-0]. The compounds
(S)-[3-(4-Chloro-2-fluoro-phenyl)-5-(2,4-difluoro-phenyl)-isoxazol-4-yl]--
pyridin-3-yl-methanol,
3-(4-Chloro-2-fluoro-phenyl)-5-(2,4-difluoro-phenyl)-isoxazol-4-yl]-pyrid-
in-3-yl-methanol are found in WO2010069881.
[1146] The active ingredient mixture of the compounds of formula I
selected from tables T1 to T164 or a specific compound selected
from P.1 to P.372 with active ingredients described above comprises
a compound selected from tables T1 to T164 and an active ingredient
as described above preferably in a mixing ratio of from 100:1 to
1:6000, especially from 50:1 to 1:500, more especially in a ratio
of from 20:1 to 1:200, even more especially from 10:1 to 1:100,
very especially from 5:1 and 1:50, special preference being given
to a ratio of from 3:1 to 1:10, and a ratio of from 3:1 to 1:5
being likewise preferred, above all in a ratio of 1:1, or 5:1, or
5:2, or 5:3, or 5:4, or 4:1, or 4:2, or 4:3, or 3:1, or 3:2, or
2:1, or 1:5, or 2:5, or 3:5, or 4:5, or 1:4, or 2:4, or 3:4, or
1:3, or 2:3, or 1:2, or 1:600, or 1:300, or 1:150, or 1:35, or
2:35, or 4:35, or 1:75, or 2:75, or 4:75, or 1:6000, or 1:3000, or
1:1500, or 1:350, or 2:350, or 4:350, or 1:750, or 2:750, or 4:750.
Those mixing ratios are understood to include, on the one hand,
ratios by weight and also, on other hand, molar ratios.
[1147] The mixtures comprising a compound of formula I e.g.
selected from tables T1 to T164 or a specific compound selected
from P.1 to P.372 and one or more active ingredients as described
above can be applied, for example, in a single "ready-mix" form, in
a combined spray mixture composed from separate formulations of the
single active ingredient components, such as a "tank-mix", and in a
combined use of the single active ingredients when applied in a
sequential manner, i.e. one after the other with a reasonably short
period, such as a few hours or days. The order of applying the
compounds of formula I e.g. those selected from tables T1 to T164
and the active ingredients as described above is not essential for
working the present invention.
[1148] A synergistic effect exists whenever the action of an active
ingredient combination is greater than the sum of the actions of
the individual components.
[1149] The action to be expected E for a given active ingredient
combination obeys the so-called COLBY formula and can be calculated
as follows (COLBY, S. R. "Calculating synergistic and antagonistic
responses of herbicide combination". Weeds, Vol. 15, pages 20-22;
1967):
[1150] ppm=milligrams of active ingredient (=a.i.) per liter of
spray mixture
[1151] X=% action by active ingredient A) using p ppm of active
ingredient
[1152] Y=% action by active ingredient B) using q ppm of active
ingredient.
[1153] According to COLBY, the expected (additive) action of active
ingredients A)+B) using p+q ppm of active ingredient is
E = X + Y - X Y 100 ##EQU00001##
[1154] If the action actually observed (O) is greater than the
expected action (E), then the action of the combination is
super-additive, i.e. there is a synergistic effect. In mathematical
terms the synergism factor SF corresponds to O/E. In the
agricultural practice an SF of .gtoreq.1.2 indicates significant
improvement over the purely complementary addition of activities
(expected activity), while an SF of .ltoreq.0.9 in the practical
application routine signals a loss of activity compared to the
expected activity.
EXAMPLES
Preparation of 1-(3,5-difluorophenyl)ethanol
##STR02578##
[1156] To a colorless stirred solution of
.sup.3',5'-difluoroacetophenone (50.00 g, 320.24 mmol) in methanol
(320 mL), sodium borohydride (3.41 g, 86.47 mmol, 0.27 eq) was
added portion wise over 20 minutes at room temperature under inert
atmosphere (Ar). Then the reaction mixture was stirred for 45 min
at room temperature and then quenched carefully by the addition of
a saturated aqueous ammonium chloride solution (150 mL). The
extraction was carried out with ethyl acetate (2.times.200 mL). The
combined organic layers were washed with brine (200 mL), dried over
anhydrous Na.sub.2SO.sub.4 and filtered. The solvent was removed in
vacuo to give the title compound (50.29 g, 99%) as a colorless oil.
The alcohol was used as such in the subsequent step.
[1157] TLC: Plates: Merck TLC-Plates, silica gel F.sub.254,
saturated atmosphere in developing tank, UV detection, eluent:
heptanes/ethyl acetate 4:1 (v/v); R.sub.f of the title
compound=0.27.
Preparation of (-)-(S)-1-(3,5-difluorophenyl)ethanol
##STR02579##
[1159] To a stirred solution of (-)-DIP-Cl
((--)-diisopinocampheylboron chloride) (2.67 g, 8.33 mmol, 1.3 eq)
in THF (20 mL) kept under inert atmosphere (Ar) and cooled to
-27.degree. C. to -25.degree. C., .sup.3',5'-difluoroacetophenone
(1.00 g, 6.40 mmol) was added drop wise over 2 min. The reaction
was maintained at this temperature for 17 h. The reaction mixture
was then treated with acetaldehyde (0.44 mL, 7.69 mmol, 1.2 eq).
Thereafter, the temperature was allowed to reach room temperature
and the reaction mixture was stirred at for 7 h. The solvent was
then removed in vacuo and the resulting residue was partitioned
between water (10 mL) and TBME (tert-butyl-methyl ether) (20 mL).
The aqueous phase was extracted again with TBME (20 mL). The
organic layer was washed with an aqueous 2 N NaOH solution (20 mL),
brine (20 mL), dried over anhydrous Na.sub.2SO.sub.4 and filtered.
The solvent was removed in vacuo to give a residue, which was
purified by two subsequent column chromatographic steps: First by
normal phase chromatography (silica gel, heptane/ethyl acetate,
v/v=1/0-9/1) followed by a reversed phase chromatography (90
C.sub.18-silica gel, acetonitrile for the second one). This gave
the title compound (0.40 g, 40%) as a colorless oil with a specific
rotation of [.alpha.].sup.25.sub.D=-26.66 (c=1.054 g/100 mL,
CH.sub.2Cl.sub.2, 589 nm).
Preparation of cis and trans 4-isopropylcyclohexanol
##STR02580##
[1161] To a stirred solution of 4-isopropylcyclohexanone (10.00 g,
68.46 mmol) in tert-butyl methyl ether (136 mL) cooled to 7.degree.
C. (cooling bath with a cyclohexane/liquid nitrogen slurry), a 1.00
M solution of lithium aluminium hydride in THF (23 mL, 22.59 mmol,
0.33 eq) was added drop wise over 35 minutes while keeping the
temperature in the range of 7 to 10.degree. C. Stirring was
continued under these conditions. The reaction mixture was then
allowed to reach room temperature and stirred at this temperature
for an additional 40 minutes. It was then carefully quenched by the
slow addition of water (20 mL), followed by a one molar aqueous
sulfuric acid solution (60 mL). The extraction was carried out with
tert-butyl methyl ether (2.times.50 mL). The organic layer was
washed with a saturated aqueous Na.sub.2CO.sub.3 solution (80 mL),
brine (80 mL), dried over anhydrous Na.sub.2SO.sub.4 and filtered.
The solvent was removed in vacuo to give a residue, which was
purified by column chromatography (silica gel, heptane/ethyl
acetate, v/v=1/0-9/1). Fractions containing the pure compounds were
collected and concentrated in vacuo to give pure trans (6.91 g,
71%) and the pure cis isomer (0.68 g, 5%) of
4-isopropyl-cyclohexanol both as colourless oils.
[1162] TLC: Plates: Merck TLC-Plates, silica gel F.sub.254,
saturated atmosphere in developing tank, detection by spraying with
Mo--Ce reagent, eluent: heptanes/ethyl acetate 4:1 (v/v); R.sub.f
of cis 4-isopropylcyclohexanol=0.20); R.sub.f of trans
4-isopropylcyclohexanol=0.15.
Preparation of
3-bromo-2-(cis-4-isopropylcyclohexoxy)-6-methyl-5-nitro-pyridine
##STR02581##
[1164] To a stirred suspension of
3-bromo-6-methyl-5-nitro-pyridin-2-ol (23.65 g, 101.5 mmol) in THF
(180 mL), trans isopropylcyclohexanol (14.44 g, 101.5 mmol, 1.0 eq)
and triphenylphosphine (32.27 g, 121.8 mmol, 1.2 eq) were added at
room temperature under inert atmosphere (Ar). To this mixture, DIAD
(diisopropyl diazodicarboxylate) (25.51 mL, 121.8 mmol, 1.2 eq) was
added drop wise over 45 min while keeping the temperature below
45.degree. C. Then, the reaction mixture was stirred for 5 h under
heating to reflux. TLC indicated that the starting material was
consumed. The reaction mixture was therefore allowed to reach room
temperature and it was quenched by the addition of water (250 mL).
The extraction was carried out with ethyl acetate (3.times.200 mL).
The organic layer was washed with brine (300 mL), dried over
anhydrous Na.sub.2SO.sub.4 and filtered. The solvent was removed in
vacuo to give a residue, which was purified by column
chromatography (silica gel, heptane/ethyl acetate, v/v=1/0-98/2).
Fractions containing the pure compound were collected and
concentrated in vacuo to give title compound (22.59 g, 62%) in the
form of an oil.
[1165] TLC: Plates: Merck TLC-Plates, silica gel F.sub.254,
saturated atmosphere in developing tank, UV detection, eluent:
heptanes/ethyl acetate 4:1 (v/v); R.sub.f of the title
compound=0.64.
Preparation of
5-bromo-6-(cis-4-isopropylcyclohexoxy)-2-methyl-pyridin-3-amine
##STR02582##
[1167] To a stirred solution of
3-bromo-2-(cis-4-isopropylcyclohexoxy)-6-methyl-5-nitro-pyridine
(22.59 g, 63.24 mmol) in EtOH/H.sub.2O (600 mL/150 mL, 4/1 v/v),
ammonium chloride (3.45 g, 63.24 mmol, 1.0 eq) and iron powder
(14.27 g, 253.0 mmol, 4 eq) were added at room temperature under
inert atmosphere (Ar). The reaction mixture was stirred for 3 h
under heating to reflux. As TLC indicated that the starting
material was consumed at this point in time, the reaction mixture
was cooled to room temperature and filtered through a pad of
celite. The resulting filtrate was concentrated in vacuo and the
residue partitioned between a 2 molar aqueous NaOH solution (100
mL) and ethyl acetate (150 mL). After phase separation, the aqueous
phase was extracted once more with ethyl acetate (2.times.100 mL).
The organic layer was washed with brine (400 mL), dried over
anhydrous Na.sub.2SO.sub.4 and filtered. The solvent was removed in
vacuo to afford the title compound (21.01 g, 101%) in the form of
an oil.
[1168] TLC: Plates: Merck TLC-Plates, silica gel F.sub.254,
saturated atmosphere in developing tank, UV detection, eluent:
heptanes/ethyl acetate 4:1 (v/v); R.sub.f of the title
compound=0.19.
Preparation of
N'-[5-bromo-6-(cis-4-isopropylcyclohexoxy)-2-methyl-3-pyridyl]-N-ethyl-N--
methyl formamidine
##STR02583##
[1170] The Vilsmeier reagent was freshly prepared by the slow
addition of phosphorus oxychloride (7.09 mL, 75.89 mmol, 1.2 eq) to
a solution of N,N-ethylmethylformamide (6.61 g, 75.89 mmol, 1.2 eq)
in dichloromethane (75 mL) at room temperature. After the addition
was complete, he reaction mixture was stirred at room temperature
for 1 h. The Vilsmeier reagent was then added drop wise over 40 min
to a solution of
5-bromo-6-(cis-4-isopropylcyclohexoxy)-2-methyl-pyridin-3-amine
(20.70 g, 63.24 mmol) in dichloromethane (225 mL) at room
temperature under inert atmosphere (Ar). Stirring was continued for
1.5 h at room temperature. The reaction mixture was then quenched
by the addition of water (100 mL) and the pH was adjusted to 14 by
the addition of a 2.0 molar aqueous NaOH solution (80 mL). The
phases were separated and the aqueous phase extracted with
dichloromethane (2.times.100 mL). The organic layer was washed with
brine (250 mL), dried over anhydrous Na.sub.2SO.sub.4 and filtered.
The solvent was removed in vacuo to give a residue, which was
purified by column chromatography (silica gel, heptane/ethyl
acetate, v/v=1/0-4/1). Fractions containing the pure compound were
collected and concentrated in vacuo to give the title compound
(20.23 g, 81%) as a yellow oil.
[1171] TLC: Plates: Merck TLC-Plates, silica gel F.sub.254,
saturated atmosphere in developing tank, UV detection, eluent:
heptanes/ethyl acetate 4:1 (v/v); R.sub.f of the title
compound=0.29.
[1172] .sup.1H NMR (400 MHz, CDCl.sub.3): .delta. (ppm)=7.45-7.30
(broad s, 1H), 7.23 (s, 1H), 5.32-5.28 (m, 1H), 3.55-3.24 (broad s,
2H), 2.98 (s, 3H), 2.35 (s, 3H), 2.04-2.01 (m, 2H), 1.63-1.46 (m,
7H), 1.20 (t, 3H), 1.18-1.10 (m, 1H), 0.91-0.89 (d, 6H).
Preparation of
3-bromo-2-(trans-4-isopropylcyclohexoxy)-6-methyl-5-nitro-pyridine
##STR02584##
[1174] To a stirred suspension of
3-bromo-6-methyl-5-nitro-pyridin-2-ol (2.00 g, 8.58 mmol) in THF
(8.6 mL), cis isopropylcyclohexanol (1.44 g, 8.58 mmol, 1.0 eq) and
triphenylphosphine (2.73 g, 10.30 mmol, 1.2 eq) were added at room
temperature under inert atmosphere (Ar). To this mixture, DIAD
(diisopropyl diazodicarboxylate) (2.16 mL, 10.30 mmol, 1.2 eq) was
added drop wise over 10 minutes while keeping the temperature below
40.degree. C. The reaction mixture was stirred for 1.5 h under
heating to. After this point in time, TLC indicted consumption of
the starting material and the reaction mixture was allowed to reach
room temperature and was quenched by adding water (20 mL). The
water phase was extracted with ethyl acetate (3.times.20 mL). The
organic layer was washed with brine (35 mL), dried over anhydrous
Na.sub.2SO.sub.4 and filtered. The solvent was removed in vacuo to
give a residue, which was purified by column chromatography (silica
gel, heptane/ethyl acetate, v/v=1/0-9/1). Fractions containing the
pure compound were collected and concentrated in vacuo to give the
title compound (0.94 g, 30%) as an oil.
[1175] TLC: Plates: Merck TLC-Plates, silica gel F.sub.254,
saturated atmosphere in developing tank, UV detection, eluent:
heptanes/ethyl acetate 4:1 (v/v); R.sub.f of the title
compound=0.65.
Preparation of
5-bromo-6-(trans-4-isopropylcyclohexoxy)-2-methyl-pyridin-3-amine
##STR02585##
[1177] To a stirred solution of
3-bromo-2-(trans-4-isopropylcyclohexoxy)-6-methyl-5-nitro-pyridine
(0.917 g, 2.00 mmol) in EtOH/H.sub.2O (24 mL/6 mL, 4/1 v/v),
ammonium chloride (0.109 g, 2.00 mmol, 1.0 eq) and iron powder
(0.452 g, 8.00 mmol, 4 eq) were added at room temperature under
inert atmosphere (Ar). The reaction mixture was stirred under
heating to reflux for 3 h. At this point in time, TLC indicated
that the starting material was consumed. Therefore, the reaction
mixture was allowed to reach room temperature and was filtered
through a pad of celite. The filtrate was concentrated under
reduced pressure and the residue partitioned between a 2 molar
aqueous NaOH solution (20 mL) and ethyl acetate (30 mL). The phases
were separated and the aqueous phase extracted with ethyl acetate
(2.times.20 mL). The organic layer was washed with brine (40 mL),
dried over anhydrous Na.sub.2SO.sub.4 and filtered. The solvent was
removed in vacuo to afford the title compound (0.658 g, 100%) as an
oil.
[1178] TLC: Plates: Merck TLC-Plates, silica gel F.sub.254,
saturated atmosphere in developing tank, UV detection, eluent:
heptanes/ethyl acetate 4:1 (v/v); R.sub.f of the title
compound=0.19.
Preparation of
5-bromo-6-(trans-4-isopropylcyclohexoxy)-2-methyl-pyridin-3-amine
##STR02586##
[1180] The Vilsmeier reagent was freshly prepared by the slow
addition of phosphorus oxychloride (0.101 mL, 1.08 mmol, 1.2 eq) to
a solution of N,N-ethylmethylformamide (0.094 g, 1.08 mmol, 1.2 eq)
in dichloromethane (0.5 mL) at room temperature. After the addition
was complete, the reaction mixture was stirred at room temperature
for 1 h. Then the Vilsmeier reagent thus obtained was added drop
wise to a solution of
5-bromo-6-(trans-4-isopropylcyclohexoxy)-2-methyl-pyridin-3-amine
(0.295 g, 0.90 mmol) in dichloromethane (1.0 mL) at room
temperature under inert atmosphere (Ar). Stirring was continued was
for 1.5 h at room temperature. The reaction was then quenched by
the addition of a 2 molar aqueous NaOH solution (5 mL). The phases
were separated and the aqueous phase extracted with dichlormethane
(2.times.10 mL). The organic layer was washed with brine (10 mL),
dried over anhydrous Na.sub.2SO.sub.4 and filtered. The solvent was
removed in vacuo to give a residue, which was purified by column
chromatography (silica gel, heptane/ethyl acetate, v/v=1/0-4/1).
Fractions containing the pure compound were collected and
concentrated in vacuo to give the title compound (0.191 g, 54%) as
a light yellow oil.
[1181] TLC: Plates: Merck TLC-Plates, silica gel F.sub.254,
saturated atmosphere in developing tank, UV detection, eluent:
heptanes/ethyl acetate 4:1 (v/v); R.sub.f of the title
compound=0.29.
[1182] .sup.1H NMR (400 MHz, CDCl.sub.3): .delta. (ppm)=7.45-7.30
(broad s, 1H), 7.22 (s, 1H), 4.93-4.85 (m, 1H), 3.55-3.22 (broad s,
2H), 2.98 (s, 3H), 2.35 (s, 3H), 2.19-2.15 (m, 2H), 1.80-1.77 (m,
2H), 1.50-1.09 (m, 5H), 1.28 (t, 3H), 0.88-0.86 (d, 6H).
Preparation of N-Ethyl-N-methyl-formamide
##STR02587##
[1184] 113 g (1.912 mol) of ethylmethylamine was dissolved in 500
mL of dry toluene. 75.86 mL of formic acid (92.2 g, 2.01 mol) was
added drop-wise over 20 minutes. Hereby, an exothermic reaction was
observed. The temperature was kept below 35.degree. C. by cooling
with an ice-water cooling bath. The turbid solution was stirred
under heating to reflux (bath temperature of 175.degree. C.) and
the water removed using a Dean and Stark separator. 46 mL of water
phase was thus separated. This water phase was extracted with 50 mL
of ethyl acetate. And this ethyl acetate solution was added to the
reaction mixture, after this one was allowed to reach room
temperature. After evaporation of the solvent, the resulting liquid
was subjected to a fractionating column distillation (Widmer
column) at 80 mbar. 138 g of a colourless liquid of
bp=95-96.degree. C. was collected. As this material was
contaminated with formic acid, the liquid was taken up in 1.0 L of
ethyl acetate and kept over K.sub.2CO.sub.3 (occasional stirring,
24 h overall). The solution was then filtered and washed with water
and the organic phase was again subjected to the distillation
procedure mentioned before. This gave 130.4 g of the title compound
as a liquid (bp=95-96.degree. C., 80 mbar).
Preparation of methoxyethylmethyl-methanaminium methyl sulfate
##STR02588##
[1186] 128 g of N-ethyl-N-methyl-formamide was added slowly to 139
mL (185 g, 1.469 mol) of dimethyl sulfate (the dimethyl sulfate
used was freshly distilled in vacuo after having been tried over
K.sub.2CO.sub.3). The colourless solution was warmed under stirring
to 50.degree. C. whereupon an exothermic reaction was starting up.
The heating bath was removed and the reaction mixture reached a
temperature of 86.degree. C. After the exothermicity came to an
end, the reaction mixture was stirred at a temperature of
80.degree. C. for an additional 3 hours. Thereafter, the reaction
mixture was allowed to reach room temperature. The resulting liquid
was then shaken in a separatory funnel first with 100 mL of toluene
and, after phase separation, with 100 mL of diethyl ether. Traces
of solvents were removed in vacuo (rotovapor) to give 294 g of the
title compound in the form of a colourless liquid. The compound was
used as such in the subsequent step.
Preparation of
5-Bromo-2-methyl-3-nitro-6-[2,2,2-trifluoro-1-(4-fluorophenyl)ethoxy]pyri-
dine
##STR02589##
[1188] To a stirred suspension of
3-bromo-6-methyl-5-nitro-pyridin-2-ol (0.10 g, 0.43 mmol) in THF (3
mL), 2,2,2-trifluoro-1-(4-fluorophenyl)ethanol (0.13 g, 0.64 mmol,
1.5 equiv) and triphenylphosphine (0.17 g, 0.64 mmol, 1.5 eq) were
added at room temperature under inert atmosphere (Ar). To this
mixture, DIAD (diisopropyl diazodicarboxylate) (0.13 mL, 0.64 mmol,
1.5 eq) was added dropwise over 10 minutes while keeping the
temperature below 40.degree. C. The reaction mixture was stirred
for 6 h under heating at 60.degree. C. After this time, TLC
indicted that the starting material had been consumed and the
reaction mixture was allowed to reach room temperature before
quenching with water (10 mL). The water phase was extracted with
ethyl acetate (3.times.15 mL). The organic layer was washed with
brine (20 mL), dried over anhydrous Na.sub.2SO.sub.4 and filtered.
The solvent was removed in vacuo to give a brown residue, which was
purified by combiflash column chromatography (silica gel,
heptane/ethyl acetate, v/v=95/5). Fractions containing the pure
compound were collected and concentrated in vacuo to give the title
compound (0.11 g, 62% yield) as a yellow oil.
[1189] TLC: Plates: Merck TLC-Plates, silica gel F.sub.254,
saturated atmosphere in developing tank, UV detection, eluent:
heptanes/ethyl acetate 4:1 (v/v); R.sub.f of the title
compound=0.65.
Preparation of
2,2,2-Trifluoro-1-[4-(trifluoromethyl)phenyl]ethanol
##STR02590##
[1191] In a 50 mL two-neck flask,
2,2,2-trifluoro-1-[4-(trifluoromethyl)phenyl]ethanone (2.0 g, 8.3
mmol) was dissolved in methanol (8 mL) and sodium borohydride (0.31
g, 8.3 mmol) was added carefully in portions with ice-bath cooling.
The resultant colourless solution was stirred at RT for 2 hours and
monitored by TLC. Upon the disappearance of all starting material,
5 mL of an aqueous saturated NH.sub.4Cl solution was slowly added
to the reaction mixture with additional stirring for 10 min. The
later was extracted 3 times with 20 mL of EtOAc and the organic
fractions were combined and washed with 10 mL of brine, dried over
Na.sub.2SO.sub.4, and filtered. The solvent was removed under
reduced pressure to give
2,2,2-trifluoro-1-[4-(trifluoromethyl)phenyl]ethanol (2.13 g,
quantitative) as a colourless oil which was used with no further
purification.
[1192] TLC: Plates: Merck TLC-Plates, silica gel F.sub.254,
saturated atmosphere in developing tank, UV detection, eluent:
heptanes/ethyl acetate 2:1 (v/v); R.sub.f of the title
compound=0.50.
Preparation of
5-Bromo-2-methyl-3-nitro-6-[2,2,2-trifluoro-1-[4-(trifluoromethyl)phenyl]-
ethoxyl]pyridine
##STR02591##
[1194] To a stirring suspension of
3-bromo-6-methyl-5-nitro-pyridin-2-ol (0.25 g, 1.07 mmol) in THF (7
mL), 2,2,2-trifluoro-1-[4-(trifluoromethyl)phenyl]ethanol (0.39 g,
1.61 mmol, 1.5 equiv) and triphenylphosphine (0.42 g, 1.61 mmol,
1.5 eq) were added at room temperature under inert atmosphere (Ar).
To this mixture, DIAD (diisopropyl diazodicarboxylate) (0.33 mL,
1.61 mmol, 1.5 eq) was added dropwise over 10 minutes while keeping
the temperature below 40.degree. C. The reaction mixture was
stirred for 6 h under heating at 60.degree. C. After this time, TLC
indicted that the starting material was consumed and the reaction
mixture was allowed to reach room temperature before quenching with
water (10 mL). The water phase was extracted with ethyl acetate
(2.times.50 mL). The organic layer was washed with brine (20 mL),
dried over anhydrous Na.sub.2SO.sub.4 and filtered. The solvent was
removed in vacuo to give a brown residue, which was purified by
combiflash column chromatography (silica gel, heptane/ethyl
acetate, v/v=95/5). Fractions containing the pure compound were
collected and concentrated in vacuo to give the title compound
(0.18 g, 41% yield) as a yellow oil.
[1195] TLC: Plates: Merck TLC-Plates, silica gel F.sub.254,
saturated atmosphere in developing tank, UV detection, eluent:
heptanes/ethyl acetate 2:1 (v/v); R.sub.f of the title
compound=0.74.
Preparation of 1,1,1-Trifluorohept-6-en-2-ol
##STR02592##
[1197] To a ice-bath cooled solution of hex-5-enal (500 mg, 4.331
mmol) and trimethyl(trifluoromethyl)silane (0.74 g, 5.13 mmol, 1.2
equiv.) in THF (10 mL) was added tetrabutylammonium hydrofluoride
(10 mg, 0.04 mmol). The ice bath was removed and the reaction
progress was monitored via GCMS and 1H NMR. Upon complete
transformation of the starting material the reaction mixture was
treated with 2M HCl and stirred for an additional 2 h. Then, 50 mL
of Et.sub.2O was introduced and the layers were separated. The
aqueous fraction was additionally extracted with Et.sub.2O and the
combined organic phases were washed sequentially with a saturated
aqueous NaHCO.sub.3 solution, water, and brine. After drying with
MgSO.sub.4 and filtration the solvent was removed under reduced
pressure and the resultant crude residue was purified by column
chromatography (silica gel, pentane/Et.sub.2O, v/v=8/2). Fractions
containing the pure compound were collected and concentrated in
vacuo to give 1,1,1-trifluorohept-6-en-2-ol (225 mg, 31% yield) as
a yellow oil.
[1198] Using techniques analogous to those above and further
techniques known to the person skilled in the art, for example as
found in WO 08/101682, the compounds found in Table Q were
prepared.
TABLE-US-00169 TABLE Q LC-Method: R.sub.t (min); MS-ESI (m/z; (M +
H).sup.+) Q.001 ##STR02593## Method 4: 1.42 min; 370 Q.002
##STR02594## Method 4: 1.46 min; 358 Q.003 ##STR02595## Method 4:
1.30 min; 328 Q.004 ##STR02596## Method 4: 1.33 min; 342 Q.005
##STR02597## Method 4: 1.17 min; 398 Q.006 ##STR02598## Gum Q.007
##STR02599## Method 4: 1.32 min; 292 Q.008 ##STR02600## Method 4:
1.39 min; 356 Q.009 ##STR02601## Mp 72-73.degree. C. Q.010
##STR02602## Method 4: 1.42 min; 356 Q.011 ##STR02603## Gum Q.012
##STR02604## Gum Q.013 ##STR02605## Gum Q.014 ##STR02606## Gum
Q.015 ##STR02607## Gum Q.016 ##STR02608## Gum Q.017 ##STR02609##
Gum Q.018 ##STR02610## Gum Q.019 ##STR02611## Gum Q.020
##STR02612## Gum Q.021 ##STR02613## Gum Q.022 ##STR02614## Gum
Q.023 ##STR02615## Gum Q.024 ##STR02616## Gum Q.025 ##STR02617##
Gum Q.026 ##STR02618## Gum Q.027 ##STR02619## Gum Q.028
##STR02620## Method 4: 1.32 min; 418 Q.029 ##STR02621## Liquid
Q.030 ##STR02622## Method 4: 1.53 min; 544 Q.031 ##STR02623## Gum
Q.032 ##STR02624## Liquid Q.033 ##STR02625## Method 4: 1.31 min;
444 Q.034 ##STR02626## Method 4: 1.22 min; 340 Q.035 ##STR02627##
Method 4: 0.99 min; 358 Q.036 ##STR02628## Method 4: 0.98 min; 388
Q.037 ##STR02629## Solid Q.038 ##STR02630## Liquid Q.039
##STR02631## Method 4: 1.48 min; 473 Q.040 ##STR02632## Liquid
Q.041 ##STR02633## Liquid Q.042 ##STR02634## Liquid Q.043
##STR02635## Liquid Q.044 ##STR02636## Method 4: 1.28 min; 446
Q.045 ##STR02637## Gum Q.046 ##STR02638## Gum Q.047 ##STR02639##
Gum Q.048 ##STR02640## Gum Q.049 ##STR02641## Gum Q.050
##STR02642## Gum Q.051 ##STR02643## Liquid Q.052 ##STR02644##
Method 4: 1.18 min; 360 Q.053 ##STR02645## Liquid Q.054
##STR02646## Liquid Q.055 ##STR02647## Liquid Q.056 ##STR02648##
Solid Q.057 ##STR02649## Method 4: 1.19 min; 276 Q.058 ##STR02650##
Method 4: 1.64 min; 348 Q.059 ##STR02651## Method 4: 1.00 min; 392
Q.060 ##STR02652## Method 4: 1.16 min; 420 Q.061 ##STR02653##
Liquid Q.062 ##STR02654## Method 4: 1.34 min; 388 Q.063
##STR02655## Method 4: 1.16 min; 338 Q.064 ##STR02656## Mp
77-78.degree. C. Q.065 ##STR02657## Liquid Q.066 ##STR02658##
Liquid Q.067 ##STR02659## Liquid Q.068 ##STR02660## Solid Q.069
##STR02661## Method 4: 1.30 min; 410 Q.070 ##STR02662## Liquid
Q.071 ##STR02663## Gum Q.072 ##STR02664## Solid Q.073 ##STR02665##
Solid Q.074 ##STR02666## Liquid Q.075 ##STR02667## Liquid Q.076
##STR02668## Liquid Q.077 ##STR02669## Liquid Q.078 ##STR02670##
Liquid Q.079 ##STR02671## Method 4: 1.39 min; 368 Q.080
##STR02672## Liquid Q.081 ##STR02673## Liquid Q.082 ##STR02674##
Liquid Q.083 ##STR02675## Liquid Q.084 ##STR02676## Liquid Q.085
##STR02677## Gum Q.086 ##STR02678## Liquid Q.087 ##STR02679##
Liquid Q.088 ##STR02680## Liquid Q.089 ##STR02681## Liquid Q.090
##STR02682## Liquid Q.091 ##STR02683## Liquid Q.092 ##STR02684##
Liquid Q.093 ##STR02685## Gum Q.094 ##STR02686## Liquid Q.095
##STR02687## Method 1: 13.577 min; 362 Q.096 ##STR02688## Mp
81-82.degree. C. Q.097 ##STR02689## Method 2: 11.956 min; 398 Q.098
##STR02690## Method 1: 11.773 min; 352 Q.099 ##STR02691## Method 1:
11.755 min; 376 Q.100 ##STR02692## Method 1: 12.320 min; 390 Q.101
##STR02693## Method 1: 12.207 min; 440 Q.102 ##STR02694## Method 1:
11.873 min; 376 Q.103 ##STR02695## Method 1: 13.153 min; 382 Q.104
##STR02696## Method 1: 6.418 min; 438 Q.105 ##STR02697## Method 1:
11.571 min; 400 Q.106 ##STR02698## Method 1: 12.115 min; 365 Q.107
##STR02699## Mp 107-108.degree. C. Q.108 ##STR02700## Method 2:
12.713 min; 523 Q.109 ##STR02701## Method 1: 12.881 min; 479 Q.110
##STR02702## Method 2: 12.214 min; 402 Q.111 ##STR02703## Mp
57-59.degree. C. Q.112 ##STR02704## Method 2: 12.236 min; 390 Q.113
##STR02705## Method 1: 12.030 min; 412 Q.114 ##STR02706## Method 2:
13.002 min; 404 Q.115 ##STR02707## Method 1: 9.589 min; 393 Q.116
##STR02708## Method 2: 11.625 min; 394 Q.117 ##STR02709## Method 2:
6.956 min; 377 Q.118 ##STR02710## Method 2: 12.577 min; 368 Q.119
##STR02711## Method 1: 13.850 min; 444 Q.120 ##STR02712## Method 2:
11.861 min; 354 Q.121 ##STR02713## Method 2: 12.977 min; 451 Q.122
##STR02714## Method 2: 13.353 min; 394
Q.123 ##STR02715## Mp 120-121.degree. C. Q.124 ##STR02716## Mp
98-99.degree. C. Q.125 ##STR02717## Mp 101-102.degree. C. Q.126
##STR02718## Method 1: 13.029 min; 480 Q.127 ##STR02719## Method 2:
13.168 min; 481 Q.128 ##STR02720## Mp 60-62.degree. C. Q.129
##STR02721## Mp 46-48.degree. C. Q.130 ##STR02722## Method 2: 3.41
min; 377 Q.131 ##STR02723## Method 2: 12.242 min; 408 Q.132
##STR02724## Method 1: 12.688 min; 368 Q.133 ##STR02725## Method 1:
12.522 min; 368 Q.134 ##STR02726## Method 2: 12.979 min; 380 Q.135
##STR02727## Method 3: 1.49 min; 396: Cis Q.136 ##STR02728## Method
1: 10.914 min; 431 Q.137 ##STR02729## Mp 43-45.degree. C. Q.138
##STR02730## Method 1: 13.065 min; 402 Q.139 ##STR02731## Method 1:
13.387 min; 370 Q.140 ##STR02732## Method 2: 12.176 min; 366 Q.141
##STR02733## Method 1: 12.712 min; 368 Q.142 ##STR02734## Method 1:
13.557 min; 466 Q.143 ##STR02735## Mp 71-73.degree. C. Q.144
##STR02736## Method 1: 11.879 min; 503 Q.145 ##STR02737## Mp
106-107.degree. C. Q.146 ##STR02738## Method 1: 11.862 min; 344
Q.147 ##STR02739## Method 1: 12.605 min; 404 Q.148 ##STR02740##
Method 1: 12.704 min; 405 Q.149 ##STR02741## Method 1: 12.642 min;
370 Q.150 ##STR02742## Method 1: 13.317 min; 372 Q.151 ##STR02743##
Liquid Q.152 ##STR02744## Mp 100-101.degree. C. Q.153 ##STR02745##
Mp 43-44.degree. C. Q.154 ##STR02746## Mp 53-57.degree. C. Q.155
##STR02747## Mp 75-78.degree. C. Q.156 ##STR02748## Mp
90-91.degree. C. Q.157 ##STR02749## Mp 125-127.degree. C. Q.158
##STR02750## Liquid Q.159 ##STR02751## Liquid Q.160 ##STR02752##
Liquid Q.161 ##STR02753## Liquid Q.162 ##STR02754## Liquid Q.163
##STR02755## Mp 90-95.degree. C. Q.164 ##STR02756## Mp
88-89.degree. C. Q.165 ##STR02757## Liquid Q.166 ##STR02758##
Liquid Q.167 ##STR02759## Liquid Q.168 ##STR02760## Liquid Q.169
##STR02761## Liquid Q.170 ##STR02762## Liquid Q.171 ##STR02763##
Liquid Q.172 ##STR02764## Mp 72-76.degree. C. Q.173 ##STR02765##
Liquid Q.174 ##STR02766## Liquid Q.175 ##STR02767## Liquid Q.176
##STR02768## Liquid Q.177 ##STR02769## Liquid Q.178 ##STR02770##
Method 2: 12.011 min; 460 Q.179 ##STR02771## Method 1: 13.777 min;
444; Trans Q.180 ##STR02772## Method 1: 13.653 min; 444; Cis Q.181
##STR02773## Method 2: 11.260 min; 334 Q.182 ##STR02774## Method 1:
13.163 min; 318; Trans Q.183 ##STR02775## Method 1: 14.926 min;
318; Cis Q.184 ##STR02776## Method 2: 12.116 min; 348 Q.185
##STR02777## Method 1: 14.256 min; 332; Trans Q.186 ##STR02778##
Method 1: 15.845 min; 332; Cis Q.187 ##STR02779## Method 2: 12.707
min; 426 Q.188 ##STR02780## Method 2: 12.145 min; 426 Q.189
##STR02781## Method 2: 11.943 min; 422 Q.190 ##STR02782## Method 1:
12.216 min; 436 Q.191 ##STR02783## Method 2: 12.769 min; 426 Q.192
##STR02784## Method 2: 12.121 min; 424 Q.193 ##STR02785## Method 2:
11.891 min; 424 Q.194 ##STR02786## Method 2: 11.881 min; 422 Q.195
##STR02787## Mp 52-54.degree. C. Q.196 ##STR02788## Method 1:
12.439 min; 466 Q.197 ##STR02789## Method 1: 11.886 min; 416 Q.198
##STR02790## Method 1: 11.886 min; 390 Q.199 ##STR02791## Method 1:
11.955 min; 418 Q.200 ##STR02792## Method 1: 12.096 min; 402 Q.201
##STR02793## Method 1: 12.796 min; 418 Q.202 ##STR02794## Method 1:
12.154 min; 496 Q.203 ##STR02795## Method 2: 13.148 min; 404 Q.204
##STR02796## Method 2: 11.780 min; 412 Q.205 ##STR02797## Method 1:
6.785 min; 444 Q.206 ##STR02798## Mp 75-78.degree. C. Q.207
##STR02799## Mp 57-58.degree. C. Q.208 ##STR02800## Method 1:
10.753 min; 368 Q.209 ##STR02801## Method 1: 7.472 min; 413 Q.210
##STR02802## Mp 134-135.degree. C. Q.211 ##STR02803## Method 1:
11.913 min; 440 Q.212 ##STR02804## Method 1: 11.392 min; 410 Q.213
##STR02805## Method 1: 8.301 min; 370 Q.214 ##STR02806## Method 1:
11.318 min; 364 Q.215 ##STR02807## Method 1: 12.017 min; 384 Q.216
##STR02808## Method 2: 12.660 min; 374 Q.217 ##STR02809## Method 1:
12.015 min; 426 Q.218 ##STR02810## Method 2: 12.403 min; 408 Q.219
##STR02811## Method 2: 13.469 min; 418 Q.220 ##STR02812## Method 1:
11.837 min; 354 Q.221 ##STR02813## Method 1: 13.221 min; 458 Q.222
##STR02814## Method 2: 11.427 min; 340 Q.223 ##STR02815## Method 1:
12.006 min; 390 Q.224 ##STR02816## Method 2: 12.567 min; 416 Q.225
##STR02817## Method 2: 13.408 min; 430 Q.226 ##STR02818## Method 1:
12.686 min; 416 Q.227 ##STR02819## Method 2: 13.431 min; 430 Q.228
##STR02820## Method 2: 13.346 min; 362 Q.229 ##STR02821## Method 2:
11.570 min; 358 Q.230 ##STR02822## Method 1: 12.261 min; 372 Q.231
##STR02823## Method 1: 13.535 min; 394 Q.232 ##STR02824## Method 1:
13.295 min; 394 Q.233 ##STR02825## Method 2: 11.937 min; 422 Q.234
##STR02826## Method 1: 14.173 min; 398 Q.235 ##STR02827## Mp
55-57.degree. C. Q.236 ##STR02828## Mp 40-42.degree. C. Q.237
##STR02829## Method 1: 8.524 min; 382 Q.238 ##STR02830## Method 1:
19.177 min; 430 Q.239 ##STR02831## Method 1: 18.583 min; 416 Q.240
##STR02832## Method 1: 10.070 min; 447 Q.241 ##STR02833## Method 1:
12.850 min; 446 Q.242 ##STR02834## Method 1: 8.079 min; 427 Q.243
##STR02835## Method 1: 12.200 min; 402 Q.244 ##STR02836## Method 1:
9.090 min; 356 Q.245 ##STR02837## Method 1: 8.672 min; 382 Q.246
##STR02838## Method 1: 11.718 min; 383 Q.247 ##STR02839## Method 1:
13.430 min; 368; Cis
Q.248 ##STR02840## Method 1: 13.051 min; 348; Cis Q.249
##STR02841## Method 1: 14.416 min; 358; Cis Q.250 ##STR02842##
Method 1: 13.413 min; 342; Cis Q.251 ##STR02843## Method 1: 14.420
min; 346; Cis Q.252 ##STR02844## Method 1: 13.397 min; 346; Trans
Q.253 ##STR02845## Method 2: 13.397 min; 342; Trans Q.254
##STR02846## Method 1: 13.300 min; 356 Q.255 ##STR02847## Mp
178-180.degree. C. Q.256 ##STR02848## Mp 165-168.degree. C.
##STR02849## Q.257 ##STR02850## Method 3: 1.42 min; 370 Q.258
##STR02851## Method 3: 1.55 min; 412 Q.259 ##STR02852## Method 3:
1.68 min; 454 Q.260 ##STR02853## Method 3: 1.34 min; 412; (S) Q.261
##STR02854## Method 3: 1.34 min; 412; (R) Q.262 ##STR02855## Ionic
liquid Q.263 ##STR02856## Method 3: 1.41 min; 410 Q.264
##STR02857## Method 3: 1.42 min; 428 Q.265 ##STR02858## Method 3:
1.40 min; 416 Q.266 ##STR02859## Method 3: 1.21 min; 411 Q.267
##STR02860## Method 3: 1.55 min: 452 Q.268 ##STR02861## Method 3:
1.52 min; 396; Trans Q.269 ##STR02862## Method 3: 1.43 min: 430;
Cis Q.270 ##STR02863## Mp 111-113.degree. C.; Trans Q.271
##STR02864## Method 1: 13.010 min; 372 Q.272 ##STR02865## Method 1:
11.512 min; 386 Q.273 ##STR02866## Method 1: 14.147 min; 400 Q.274
##STR02867## Method 1: 14.704 min; 414 Q.275 ##STR02868## Method 1:
12.441 min; 388 Q.276 ##STR02869## Method 1: 12.949 min; 402 Q.277
##STR02870## Method 1: 12.412 min; 388 Q.278 ##STR02871## Method 1:
12.930 min; 402 Q.279 ##STR02872## Method 1: 11.765 min; 390 Q.280
##STR02873## Method 1: 13.223 min; 376 Q.281 ##STR02874## Method 1:
9.144 min; 366 Q.282 ##STR02875## Method 1: 9.411 min; 380 Q.283
##STR02876## Method 1: 13.076 min; 404 Q.284 ##STR02877## Method 1:
13.397 min; 404 Q.285 ##STR02878## Method 1: 12.345 min; 390 Q.286
##STR02879## Method 1: 12.464 min; 390 Q.287 ##STR02880## Method 1:
13.376 min; 418 Q.288 ##STR02881## Method 2: 12.056 min; 354 Q.289
##STR02882## Method 1: 11.736 min; 412 Q.290 ##STR02883## Mp
81-85.degree. C. Q.291 ##STR02884## Method 1: 11.782 min; 408 Q.292
##STR02885## Method 1: 12.318 min; 422 Q.293 ##STR02886## Method 1:
12.503 min; 366 Q.294 ##STR02887## Method 1: 13.526 min; 438 Q.295
##STR02888## Mp 59-62.degree. C. Q.296 ##STR02889## Method 1:
11.641 min; 312 Q.297 ##STR02890## Method 1: 11.974 min; 326 Q.298
##STR02891## Mp 57-61.degree. C. Q.299 ##STR02892## Method 1:
12.313 min; 394 Q.300 ##STR02893## Mp 53-56.degree. C. Q.301
##STR02894## Method 1: 12.908 min; 410 Q.302 ##STR02895## Method 1:
12.267 min; 440 Q.303 ##STR02896## Method 1: 12.897 min; 454 Q.304
##STR02897## Mp 82-86.degree. C. Q.305 ##STR02898## Mp
77-81.degree. C. Q.306 ##STR02899## Method 1: 12.789 min; 404 Q.307
##STR02900## Method 1: 13.266 min; 418 Q.308 ##STR02901## Method 1:
13.998 min; 396 Q.309 ##STR02902## Method 1: 13.524 min; 466 Q.310
##STR02903## Method 1: 13.568 min; 462 Q.311 ##STR02904## Method 1:
13.806 min; 462 Q.312 ##STR02905## Method 1: 14.266 min; 476 Q.313
##STR02906## Method 1: 14.120 min; 476 Q.314 ##STR02907## Method 1:
14.042 min; 480 Q.315 ##STR02908## Method 1: 12.395 min; 366 Q.316
##STR02909## Method 1: 7.382 min; 352 Q.317 ##STR02910## Mp
78-81.degree. C. Q.318 ##STR02911## Method 1: 12.537 min; 430 Q.319
##STR02912## Method 1: 12.594 min; 416 Q.320 ##STR02913## Mp
27-30.degree. C. Q.321 ##STR02914## Method 1: 12.591 min; 390 Q.322
##STR02915## Mp 67-68.degree. C. Q.323 ##STR02916## Mp
83-84.degree. C. Q.324 ##STR02917## Method 1: 12.813 min; 390 Q.325
##STR02918## Mp 56-57.degree. C. Q.326 ##STR02919## Mp
61-62.degree. C. Q.327 ##STR02920## Method 1: 13.121 min; 426 Q.328
##STR02921## Liquid Q.329 ##STR02922## Method 1: 14.077 min; 480
Q.330 ##STR02923## Method 1: 11.439 min; 392 Q.331 ##STR02924##
Method 1: 11.711 min; 340 Q.332 ##STR02925## Method 1: 9.781 min;
382; Isomer 1 Q.333 ##STR02926## Method 1: 9.758 min; 382; Isomer 2
Q.334 ##STR02927## Method 6: 0.92 min; 396 Q.335 ##STR02928##
Method 1: 11.804 min; 408 Q.336 ##STR02929## Method 1: 8.965 min;
424 Q.337 ##STR02930## Mp 104-108.degree. C. Q.338 ##STR02931##
Method 1: 10.918 min; 331 Q.339 ##STR02932## Method 1: 11.312 min;
344 Q.340 ##STR02933## Method 1: 12.292 min; 366 Q.341 ##STR02934##
Method 1: 11.200 min; 290 Q.342 ##STR02935## Method 1: 11.930 min;
304 Q.343 ##STR02936## Method 1: 14.959 min; 360 Q.344 ##STR02937##
Method 1: 13.527 min; 418 Q.345 ##STR02938## Method 1: 12.808 min;
404 Q.346 ##STR02939## Method 1: 13.160 min; 404 Q.347 ##STR02940##
Method 1: 11.431 min; 312 Q.348 ##STR02941## Method 1: 11.698 min;
326 Q.349 ##STR02942## Method 1: 12.595 min; 390 Q.350 ##STR02943##
Method 1: 11.248 min; 312 Q.351 ##STR02944## Mp 110-114.degree. C.
Q.352 ##STR02945## Method 1: 11.715 min; 326 Q.353 ##STR02946##
Method 1: 12.754 min; 404 Q.354 ##STR02947## Method 1: 11.787 min;
326 Q.355 ##STR02948## Method 1: 12.370 min; 340 Q.356 ##STR02949##
Method 1: 12.096 min; 354 Q.357 ##STR02950## Method 1: 12.656 min;
368 Q.358 ##STR02951## Method 1: 11.887 min; 326 Q.359 ##STR02952##
Method 1: 12.700 min; 340 Q.360 ##STR02953## Method 1: 12.328 min;
340 Q.361 ##STR02954## Method 1: 12.882 min; 354 Q.362 ##STR02955##
Method 1: 15.320 min; 354 Q.363 ##STR02956## Method 1: 12.506 min;
341 Q.364 ##STR02957## Method 1: 12.385 min; 390 Q.365 ##STR02958##
Method 1: 13.743 min; 466 Q.366 ##STR02959## Method 1: 10.775 min;
328 Q.367 ##STR02960## Method 1: 10.377 min; 314 Q.368 ##STR02961##
Method 1: 11.191 min; 312 Q.369 ##STR02962## Mp 120-121.degree. C.
Q.370 ##STR02963## Method 1: 11.282 min; 423 Q.371 ##STR02964##
Method 1: 11.875 min; 272 Q.372 ##STR02965## Method 1: 10.334 min;
344
Q.373 ##STR02966## Method 1: 10.676 min; 358 Q.374 ##STR02967##
Method 1: 11.096 min; 372 Q.375 ##STR02968## Method 1: 11.418 min;
390 Q.376 ##STR02969## Method 1: 11.717 min; 413 Q.377 ##STR02970##
Method 1: 10.791 min; 358 Q.378 ##STR02971## Method 1: 12.258 min;
452 Q.379 ##STR02972## Mp 168-170.degree. C. Q.380 ##STR02973##
Method 1: 12.229 min; 304; Trans Q.381 ##STR02974## Method 1:
12.388 min; 305; Cis Q.382 ##STR02975## Method 1: 12.988 min; 368
Q.383 ##STR02976## Method 6: 0.61 min; 336 Q.384 ##STR02977##
Method 6: 0.67 min; 332 Q.385 ##STR02978## Method 3: 1.34 min; 338
Q.386 ##STR02979## Method 3: 1.34 min; 424 Q.387 ##STR02980##
Method 6: 0.55 min; 286 Q.388 ##STR02981## Method 6: 0.73 min; 314
Q.389 ##STR02982## Method 6: 0.79 min; 328 Q.390 ##STR02983##
Method 6: 0.79 min; 328 Q.391 ##STR02984## Method 6: 0.83 min; 342
Q.392 ##STR02985## Method 6: 0.88 min; 356 Q.393 ##STR02986##
Method 6: 0.69 min; 312 Q.394 ##STR02987## Method 6: 0.75 min; 326
Q.395 ##STR02988## Method 6: 0.79 min; 420 Q.396 ##STR02989##
Method 6: 0.60 min; 442 Q.397 ##STR02990## Method 6: 0.93 min; 442
Q.398 ##STR02991## Method 6: 0.86 min; 392 Q.399 ##STR02992##
Method 6: 0.89 min; 390 Q.400 ##STR02993## Method 6: 0.83 min; 404
Q.401 ##STR02994## Method 6: 0.89 min; 404 Q.402 ##STR02995##
Method 6: 0.88 min; 406 Q.403 ##STR02996## Method 6: 0.99 min; 369
Q.404 ##STR02997## Method 6: 0.92 min; 406 Q.405 ##STR02998##
Method 6: 0.54 min; 334 Q.406 ##STR02999## Method 1: 8.584 min; 396
Q.407 ##STR03000## Method 1: 12.363 min; 392 Q.408 ##STR03001##
Method 1: 12.632 min; 319; Trans Q.409 ##STR03002## Method 1:
12.533 min; 319; Cis Q.410 ##STR03003## Method 1: 11.796 min; 304
Q.411 ##STR03004## Method 1: 12.661 min; 318 Q.412 ##STR03005##
Method 1: 14.132 min; 348 Q.413 ##STR03006## Method 1: 14.531 min;
362 Q.414 ##STR03007## Method 1: 12.019 min; 304 Q.415 ##STR03008##
Mp 81-83.degree. C. Q.416 ##STR03009## Method 1: 14.621 min; 410
Q.417 ##STR03010## Method 1: 15.162 min; 404 Q.418 ##STR03011##
Method 1: 14.413 min; 340 Q.419 ##STR03012## Method 1: 13.860 min;
326 Q.420 ##STR03013## Method 1: 13.191 min; 418 Q.421 ##STR03014##
Method 1: 12.542 min; 354 Q.422 ##STR03015## Mp 61-63.degree. C.
Q.423 ##STR03016## Method 1: 12.785 min; 340 Q.424 ##STR03017##
Method 1: 12.041 min; 326 Q.425 ##STR03018## Method 1: 13.378 min;
418 Q.426 ##STR03019## Method 1: 13.958 min; 432 Q.427 ##STR03020##
Method 1: 8.845 min; 374 Q.428 ##STR03021## Method 1: 13.142 min;
370 Q.429 ##STR03022## Method 1: 10.416 min; 358 Q.430 ##STR03023##
Mp 122-124.degree. C. Q.431 ##STR03024## Method 1: 10.943 min; 310
Q.432 ##STR03025## Method 1: 11.341 min; 324 Q.433 ##STR03026##
Method 1: 12.746 min; 356 Q.434 ##STR03027## Method 1: 10.964 min;
278 Q.435 ##STR03028## Method 1: 10.497 min; 264 Q.436 ##STR03029##
Method 1: 12.277 min; 390 Q.437 ##STR03030## Method 1: 12.606 min;
368 Q.438 ##STR03031## Method 1: 9.727 min; 370 Q.439 ##STR03032##
Method 1: 12.860 min; 404 Q.440 ##STR03033## Method 1: 10.054 min;
262 Q.441 ##STR03034## Method 1: 12.781 min; 276 Q.442 ##STR03035##
Method 1: 13.922 min; 326 Q.443 ##STR03036## Method 1: 12.141 min;
342 Q.444 ##STR03037## Method 1: 12.715 min; 356 Q.445 ##STR03038##
Method 1: 11.909 min; 412 Q.446 ##STR03039## Method 1: 9.174 min;
356 Q.447 ##STR03040## Method 1: 9.174 min; 356 Q.448 ##STR03041##
Mp 106-107.degree. C. Q.449 ##STR03042## Method 1: 12.070 min; 354
Q.450 ##STR03043## Method 1: 12.652 min; 368 Q.451 ##STR03044##
Method 1: 10.212 min; 358 Q.452 ##STR03045## Method 1: 11.435 min;
324 Q.453 ##STR03046## Method 1: 11.704 min; 338 Q.454 ##STR03047##
Mp 85-87.degree. C.
Biological Examples
Blumeria qraminis f. sp. tritici (Erysiphe graminis f. sp.
tritici)/Wheat/Leaf Disc Preventative (Powdery Mildew on Wheat)
[1199] Wheat leaf segments cv. Kanzler were placed on agar in a
multiwell plate (24-well format) and sprayed with the formulated
test compound diluted in water. The leaf disks were inoculated by
shaking powdery mildew infected plants above the test plates 1 day
after application. The inoculated leaf disks were incubated at
20.degree. C. and 60% rh under a light regime of 24 h darkness
followed by 12 h light/12 h darkness in a climate chamber and the
activity of a compound was assessed as percent disease control
compared to untreated when an appropriate level of disease damage
appears on untreated check leaf segments (6-8 days after
application).
[1200] The following compounds gave at 200 ppm give at least 50%
disease control in this test when compared to untreated control
leaf disks under the same conditions, which show extensive disease
development:
Q.001, Q.004, Q.005, Q.006, Q.007, Q.010, Q.011, Q.012, Q.013,
Q.014, Q.015, Q.016, Q.017, Q.018, Q.019, Q.020, Q.021, Q.022,
Q.023, Q.024, Q.025, Q.026, Q.027, Q.028, Q.029, Q.030, Q.031,
Q.032, Q.033, Q.034, Q.035, Q.036, Q.037, Q.038, Q.039, Q.040,
Q.041, Q.042, Q.043, Q.044, Q.045, Q.046, Q.047, Q.048, Q.049,
Q.050, Q.051, Q.052, Q.053, Q.054, Q.055, Q.057, Q.058, Q.059,
Q.060, Q.062, Q.063, Q.064, Q.065, Q.066, Q.067, Q.068, Q.069,
Q.070, Q.071, Q.072, Q.073, Q.074, Q.075, Q.076, Q.077, Q.078,
Q.079, Q.080, Q.081, Q.082, Q.084, Q.085, Q.086, Q.087, Q.088,
Q.089, Q.090, Q.091, Q.092, Q.093, Q.094, Q.095, Q.097, Q.098,
Q.099, Q.100, Q.101, Q.102, Q.103, Q.104, Q.105, Q.106, Q.108,
Q.109, Q.110, Q.111, Q.112, Q.113, Q.114, Q.115, Q.116, Q.117,
Q.118, Q.119, Q.120, Q.121, Q.122, Q.123, Q.124, Q.125, Q.126,
Q.127, Q.128, Q.129, Q.130, Q.131, Q.132, Q.133, Q.134, Q.135,
Q.136, Q.140, Q.141, Q.142, Q.143, Q.144, Q.145, Q.146, Q.147,
Q.148, Q.149, Q.151, Q.152, Q.153, Q.154, Q.155, Q.156, Q.158,
Q.160, Q.161, Q.162, Q.163, Q.164, Q.165, Q.166, Q.167, Q.168,
Q.170, Q.171, Q.172, Q.174, Q.175, Q.176, Q.177, Q.178, Q.179,
Q.180, Q.181, Q.183, Q.184, Q.185, Q.186, Q.187, Q.188, Q.191,
Q.192, Q.193, Q.195, Q.196, Q.197, Q.198, Q.199, Q.200, Q.201,
Q.202, Q.203, Q.204, Q.205, Q.206, Q.207, Q.208, Q.209, Q.211,
Q.212, Q.213, Q.214, Q.215, Q.216, Q.217, Q.218, Q.219, Q.220,
Q.221, Q.222, Q.223, Q.224, Q.225, Q.226, Q.227, Q.228, Q.229,
Q.230, Q.231, Q.233, Q.235, Q.238, Q.239, Q.240, Q.241, Q.242,
Q.243, Q.244, Q.245, Q.246, Q.247, Q.248, Q.249, Q.250, Q.251,
Q.255, Q.256, Q.260, Q.261, Q.262, Q.263, Q.265, Q.267, Q.269,
Q.270, Q.271, Q.272, Q.273, Q.274, Q.275, Q.276, Q.277, Q.278,
Q.280, Q.281, Q.282, Q.283, Q.284, Q.285, Q.286, Q.287, Q.288,
Q.289, Q.290, Q.291, Q.292, Q.293, Q.294, Q.296, Q.297, Q.298,
Q.299, Q.300, Q.301, Q.302, Q.303, Q.304, Q.305, Q.306, Q.307,
Q.308, Q.309, Q.310, Q.312, Q.315, Q.316, Q.317, Q.318, Q.319,
Q.320, Q.321, Q.322, Q.323, Q.324, Q.325, Q.326, Q.327, Q.329,
Q.330, Q.331, Q.332, Q.333, Q.334, Q.335, Q.336, Q.337, Q.338,
Q.339, Q.340, Q.341, Q.342, Q.343, Q.344, Q.345, Q.346, Q.347,
Q.349, Q.350, Q.351, Q.352, Q.353, Q.354, Q.355, Q.356, Q.357,
Q.358, Q.359, Q.360, Q.361, Q.364, Q.365, Q.367, Q.368, Q.369,
Q.370, Q.371, Q.373, Q.374, Q.375, Q.376, Q.378, Q.380, Q.381,
Q.382, Q.383, Q.384, Q.385, Q.386, Q.388, Q.389, Q.390, Q.391,
Q.392, Q.393, Q.394, Q.397, Q.398, Q.400, Q.401
[1201] Puccinia recondita f. sp. tritici/Wheat/Leaf Disc
Preventative (Brown Rust)
[1202] Wheat leaf segments cv. Kanzler were placed on agar in
multiwell plates (24-well format) and sprayed with the formulated
test compound diluted in water. The leaf disks were inoculated with
a spore suspension of the fungus 1 day after application. The
inoculated leaf segments were incubated at 19.degree. C. and 75% rh
under a light regime of 12 h light/12 h darkness in a climate
cabinet and the activity of a compound was assessed as percent
disease control compared to untreated when an appropriate level of
disease damage appears in untreated check leaf segments (7-9 days
after application).
[1203] The following compounds gave at 200 ppm gave at least 50%
disease control in this test when compared to untreated control
leaf disks under the same conditions, which show extensive disease
development:
Q.001, Q.002, Q.003, Q.004, Q.005, Q.006, Q.007, Q.008, Q.009,
Q.010, Q.011, Q.012, Q.013, Q.014, Q.015, Q.016, Q.017, Q.018,
Q.019, Q.020, Q.021, Q.022, Q.023, Q.024, Q.025, Q.026, Q.027,
Q.028, Q.029, Q.030, Q.031, Q.032, Q.033, Q.034, Q.035, Q.036,
Q.037, Q.038, Q.039, Q.040, Q.041, Q.042, Q.043, Q.044, Q.045,
Q.046, Q.047, Q.048, Q.049, Q.050, Q.051, Q.052, Q.053, Q.054,
Q.055, Q.056, Q.057, Q.058, Q.059, Q.060, Q.061, Q.062, Q.063,
Q.064, Q.065, Q.066, Q.067, Q.068, Q.069, Q.070, Q.071, Q.072,
Q.073, Q.074, Q.075, Q.076, Q.077, Q.078, Q.079, Q.080, Q.081,
Q.082, Q.083, Q.084, Q.085, Q.086, Q.087, Q.088, Q.089, Q.090,
Q.091, Q.092, Q.093, Q.094, Q.095, Q.096, Q.097, Q.098, Q.099,
Q.100, Q.101, Q.102, Q.103, Q.104, Q.105, Q.106, Q.107, Q.108,
Q.109, Q.110, Q.111, Q.112, Q.113, Q.114, Q.115, Q.116, Q.117,
Q.118, Q.119, Q.120, Q.121, Q.122, Q.123, Q.124, Q.125, Q.126,
Q.127, Q.128, Q.129, Q.130, Q.131, Q.132, Q.133, Q.134, Q.135,
Q.136, Q.137, Q.138, Q.140, Q.141, Q.142, Q.143, Q.144, Q.145,
Q.146, Q.147, Q.148, Q.149, Q.150, Q.151, Q.152, Q.153, Q.154,
Q.155, Q.156, Q.157, Q.158, Q.159, Q.160, Q.161, Q.162, Q.163,
Q.164, Q.165, Q.166, Q.167, Q.168, Q.169, Q.170, Q.171, Q.172,
Q.173, Q.174, Q.175, Q.176, Q.177, Q.178, Q.179, Q.180, Q.181,
Q.182, Q.183, Q.184, Q.185, Q.186, Q.187, Q.188, Q.189, Q.190,
Q.191, Q.192, Q.193, Q.194, Q.195, Q.196, Q.197, Q.198, Q.199,
Q.200, Q.201, Q.202, Q.203, Q.204, Q.205, Q.206, Q.207, Q.208,
Q.209, Q.210, Q.211, Q.212, Q.213, Q.214, Q.215, Q.216, Q.217,
Q.218, Q.219, Q.220, Q.221, Q.222, Q.223, Q.224, Q.225, Q.226,
Q.227, Q.228, Q.229, Q.230, Q.231, Q.232, Q.233, Q.234, Q.235,
Q.236, Q.237, Q.238, Q.239, Q.240, Q.241, Q.242, Q.243, Q.244,
Q.245, Q.246, Q.247, Q.248, Q.249, Q.250, Q.251, Q.252, Q.253,
Q.254, Q.255, Q.256, Q.257, Q.258, Q.259, Q.260, Q.261, Q.262,
Q.263, Q.264, Q.265, Q.266, Q.267, Q.268, Q.269, Q.270, Q.271,
Q.272, Q.273, Q.274, Q.275, Q.276, Q.277, Q.278, Q.279, Q.280,
Q.281, Q.282, Q.283, Q.284, Q.285, Q.286, Q.287, Q.288, Q.289,
Q.290, Q.291, Q.292, Q.293, Q.294, Q.295, Q.296, Q.297, Q.298,
Q.299, Q.300, Q.301, Q.302, Q.303, Q.304, Q.305, Q.306, Q.307,
Q.308, Q.309, Q.310, Q.311, Q.312, Q.313, Q.314, Q.315, Q.316,
Q.317, Q.318, Q.319, Q.320, Q.321, Q.322, Q.323, Q.324, Q.325,
Q.326, Q.327, Q.328, Q.329, Q.330, Q.331, Q.332, Q.333, Q.334,
Q.335, Q.336, Q.337, Q.338, Q.339, Q.340, Q.341, Q.342, Q.343,
Q.344, Q.345, Q.346, Q.347, Q.348, Q.349, Q.350, Q.351, Q.352,
Q.353, Q.354, Q.355, Q.356, Q.357, Q.358, Q.359, Q.360, Q.361,
Q.362, Q.363, Q.364, Q.365, Q.366, Q.367, Q.368, Q.369, Q.370,
Q.371, Q.372, Q.373, Q.374, Q.375, Q.376, Q.377, Q.378, Q.379,
Q.380, Q.381, Q.382, Q.383, Q.384, Q.385, Q.386, Q.387, Q.388,
Q.389, Q.390, Q.391, Q.392, Q.393, Q.394, Q.397, Q.398, Q.400,
Q.401
[1204] Puccinia recondita f. sp. tritici/Wheat/Leaf Disc Curative
(Brown Rust)
[1205] Wheat leaf segments cv. Kanzler are placed on agar in
multiwell plates (24-well format). The leaf segments are inoculated
with a spore suspension of the fungus. Plates were stored in
darkness at 19.degree. C. and 75% rh. The formulated test compound
diluted in water was applied 1 day after inoculation. The leaf
segments were incubated at 19.degree. C. and 75% rh under a light
regime of 12 h light/12 h darkness in a climate cabinet and the
activity of a compound was assessed as percent disease control
compared to untreated when an appropriate level of disease damage
appears in untreated check leaf segments (6-8 days after
application).
[1206] The following compounds gave at 200 ppm gaive at least 50%
disease control in this test when compared to untreated control
leaf disks under the same conditions, which show extensive disease
development:
Q.001, Q.004, Q.005, Q.006, Q.007, Q.010, Q.011, Q.012, Q.013,
Q.014, Q.015, Q.016, Q.018, Q.019, Q.020, Q.021, Q.022, Q.023,
Q.024, Q.025, Q.026, Q.027, Q.028, Q.029, Q.030, Q.031, Q.032,
Q.033, Q.034, Q.035, Q.036, Q.037, Q.038, Q.039, Q.040, Q.041,
Q.042, Q.043, Q.044, Q.045, Q.046, Q.047, Q.048, Q.049, Q.050,
Q.051, Q.052, Q.053, Q.054, Q.055, Q.057, Q.058, Q.059, Q.060,
Q.062, Q.063, Q.064, Q.065, Q.066, Q.067, Q.068, Q.069, Q.070,
Q.071, Q.072, Q.073, Q.074, Q.075, Q.076, Q.077, Q.078, Q.079,
Q.080, Q.081, Q.082, Q.084, Q.085, Q.086, Q.087, Q.088, Q.089,
Q.090, Q.091, Q.092, Q.093, Q.094, Q.095, Q.096, Q.097, Q.098,
Q.099, Q.100, Q.101, Q.102, Q.103, Q.104, Q.105, Q.106, Q.109,
Q.110, Q.111, Q.112, Q.113, Q.114, Q.115, Q.116, Q.117, Q.118,
Q.119, Q.120, Q.121, Q.122, Q.123, Q.124, Q.126, Q.127, Q.128,
Q.129, Q.130, Q.131, Q.132, Q.133, Q.134, Q.135, Q.136, Q.140,
Q.141, Q.143, Q.144, Q.145, Q.146, Q.147, Q.148, Q.149, Q.151,
Q.152, Q.153, Q.154, Q.155, Q.156, Q.158, Q.159, Q.160, Q.161,
Q.162, Q.163, Q.164, Q.165, Q.166, Q.167, Q.168, Q.169, Q.170,
Q.171, Q.172, Q.174, Q.175, Q.176, Q.177, Q.178, Q.179, Q.180,
Q.181, Q.182, Q.183, Q.184, Q.185, Q.186, Q.188, Q.191, Q.192,
Q.193, Q.194, Q.195, Q.196, Q.197, Q.198, Q.199, Q.200, Q.201,
Q.203, Q.204, Q.205, Q.206, Q.207, Q.208, Q.209, Q.211, Q.212,
Q.213, Q.214, Q.215, Q.216, Q.217, Q.218, Q.219, Q.220, Q.221,
Q.222, Q.223, Q.224, Q.225, Q.226, Q.227, Q.228, Q.229, Q.230,
Q.231, Q.232, Q.233, Q.235, Q.236, Q.238, Q.239, Q.240, Q.241,
Q.242, Q.243, Q.244, Q.246, Q.247, Q.248, Q.249, Q.250, Q.251,
Q.253, Q.254, Q.255, Q.256, Q.257, Q.258, Q.260, Q.261, Q.262,
Q.263, Q.265, Q.269, Q.270, Q.271, Q.273, Q.274, Q.275, Q.276,
Q.277, Q.278, Q.279, Q.280, Q.281, Q.282, Q.283, Q.284, Q.285,
Q.286, Q.287, Q.288, Q.289, Q.290, Q.291, Q.292, Q.293, Q.294,
Q.296, Q.297, Q.298, Q.299, Q.300, Q.301, Q.302, Q.303, Q.304,
Q.305, Q.306, Q.307, Q.308, Q.309, Q.310, Q.311, Q.315, Q.316,
Q.317, Q.318, Q.319, Q.320, Q.321, Q.322, Q.323, Q.324, Q.325,
Q.326, Q.327, Q.329, Q.330, Q.331, Q.332, Q.333, Q.334, Q.335,
Q.336, Q.337, Q.338, Q.339, Q.340, Q.341, Q.342, Q.344, Q.345,
Q.346, Q.347, Q.348, Q.349, Q.350, Q.351, Q.352, Q.353, Q.354,
Q.355, Q.356, Q.357, Q.358, Q.359, Q.360, Q.361, Q.362, Q.363,
Q.364, Q.365, Q.366, Q.367, Q.368, Q.369, Q.370, Q.371, Q.372,
Q.373, Q.374, Q.375, Q.376, Q.377, Q.378, Q.380, Q.381, Q.382,
Q.383, Q.384, Q.385, Q.386, Q.388, Q.389, Q.390, Q.391, Q.392,
Q.393, Q.394, Q.397, Q.398, Q.400, Q.401
[1207] Pyrenophora teres/Barley/Leaf Disc Preventative (Net
Blotch)
[1208] Barley leaf segments cv. Hasso were placed on agar in a
multiwell plate (24-well format) and sprayed with the formulated
test compound diluted in water. The leaf segments were inoculated
with a spore suspension of the fungus 2 days after application. The
inoculated leaf segments were incubated at 20.degree. C. and 65% rh
under a light regime of 12 h light/12 h darkness in a climate
cabinet and the activity of a compound was assessed as disease
control compared to untreated when an appropriate level of disease
damage appears in untreated check leaf segments (5-7 days after
application).
[1209] The following compounds gave at 200 ppm give at least 50%
disease control in this test when compared to untreated control
leaf disks under the same conditions, which show extensive disease
development:
Q.001, Q.004, Q.005, Q.007, Q.011, Q.012, Q.013, Q.014, Q.015,
Q.016, Q.018, Q.019, Q.020, Q.021, Q.022, Q.023, Q.024, Q.025,
Q.026, Q.027, Q.028, Q.029, Q.032, Q.033, Q.034, Q.035, Q.038,
Q.039, Q.041, Q.042, Q.043, Q.044, Q.046, Q.047, Q.052, Q.053,
Q.054, Q.055, Q.057, Q.059, Q.062, Q.063, Q.066, Q.067, Q.069,
Q.070, Q.071, Q.074, Q.075, Q.076, Q.079, Q.082, Q.086, Q.087,
Q.088, Q.089, Q.090, Q.091, Q.093, Q.095, Q.097, Q.099, Q.100,
Q.101, Q.102, Q.103, Q.105, Q.106, Q.110, Q.111, Q.113, Q.115,
Q.116, Q.117, Q.118, Q.119, Q.120, Q.121, Q.122, Q.124, Q.125,
Q.127, Q.128, Q.129, Q.131, Q.133, Q.136, Q.141, Q.143, Q.144,
Q.146, Q.148, Q.153, Q.154, Q.155, Q.158, Q.160, Q.161, Q.162,
Q.163, Q.164, Q.166, Q.167, Q.168, Q.169, Q.170, Q.174, Q.175,
Q.176, Q.178, Q.180, Q.183, Q.184, Q.186, Q.191, Q.193, Q.195,
Q.196, Q.197, Q.198, Q.199, Q.200, Q.201, Q.202, Q.203, Q.204,
Q.206, Q.207, Q.208, Q.209, Q.211, Q.212, Q.214, Q.215, Q.216,
Q.217, Q.218, Q.219, Q.220, Q.221, Q.222, Q.223, Q.224, Q.225,
Q.226, Q.227, Q.228, Q.229, Q.231, Q.232, Q.233, Q.235, Q.236,
Q.237, Q.238, Q.240, Q.241, Q.242, Q.243, Q.244, Q.245, Q.246,
Q.247, Q.248, Q.249, Q.250, Q.251, Q.252, Q.253, Q.255, Q.256,
Q.260, Q.261, Q.262, Q.269, Q.275, Q.277, Q.278, Q.280, Q.282,
Q.284, Q.285, Q.286, Q.289, Q.291, Q.292, Q.293, Q.298, Q.299,
Q.301, Q.302, Q.304, Q.308, Q.311, Q.315, Q.316, Q.320, Q.322,
Q.324, Q.326, Q.329, Q.334, Q.335, Q.336, Q.337, Q.340, Q.344,
Q.346, Q.349, Q.352, Q.353, Q.354, Q.355, Q.357, Q.358, Q.361,
Q.363, Q.364, Q.366, Q.370, Q.371, Q.375, Q.376, Q.377, Q.378,
Q.380, Q.382, Q.386, Q.389, Q.390, Q.391, Q.392, Q.393, Q.394,
Q.398, Q.400
[1210] In the following Tables `Activity (%)` means the assessed
experimental activity (% disease control in this test when compared
to untreated control leaf disks under the same conditions, which
show extensive disease development) and "P" is the expected value
calculated (expected) activity according to the COLBY formula (see
above). The column headed `S?` indicates whether or not synergy was
observed, with `y` meaning that synergy was observed.
[1211] In the following tables, compound (V) is
N-[9-(dichloromethylene)-1,2,3,4-tetrahydro-1,4-methanonaphthalen-5-yl]-3-
-(difluoromethyl)-1-methyl-1H-pyrazole-4-carboxamide, compound (VI)
is
3-(difluoromethyl)-N-methoxy-1-methyl-N-[1-methyl-2-(2,4,6-trichloropheny-
l)ethyl]-1H-pyrazole-4-carboxamide, compound (VII) is
[3-(4-chloro-2-fluoro-phenyl)-5-(2,4-difluoro-phenyl)-isoxazol-4-yl]-pyri-
din-3-yl-methanol.
[1212] Monocraphella nivalis (Syn. Microdochium nivale, Fusarium
Nivale), Snow Mould, Foot Rot of Cereals
[1213] Conidia of the fungus from cryogenic storage were directly
mixed into nutrient broth (PDB potato dextrose broth). After
placing a (DMSO) solution of the test compounds into a microtiter
plate (96-well format) the nutrient broth containing the fungal
spores was added. The test plates were incubated at 24.degree. C.
and activity was determined visually after 72 hrs
TABLE-US-00170 Q.135 Compound (V) rate ppm rate ppm Activity (%) P
S? 0.0625 20 0.03125 0 0.015625 0 0.0078125 0 0.0625 50 0.03125 0
0.0625 0.03125 50 20 y 0.03125 0.03125 50 0 y 0.03125 0.0625 70 50
y 0.015625 0.03125 20 0 y 0.015625 0.0625 70 50 y 0.0078125 0.03125
70 0 y Q.135 Flutriafol rate ppm rate ppm Activity (%) P S? 0.0625
70 0.25 0 0.125 0 0.0625 0 0.03125 0 0.0625 0.25 100 70 y 0.0625
0.125 90 70 y 0.0625 0.0625 90 70 y 0.0625 0.03125 90 70 y
TABLE-US-00171 Q.135 Metconazole rate ppm rate ppm Activity (%) P
S? 0.0625 70 0.03125 0 0.25 0 0.125 0 0.0625 0 0.03125 0 0.015625 0
0.0625 0.25 100 70 y 0.0625 0.125 100 70 y 0.0625 0.0625 100 70 y
0.0625 0.03125 100 70 y 0.0625 0.015625 100 70 y 0.03125 0.125 100
0 y 0.03125 0.0625 70 0 y 0.03125 0.03125 50 0 y 0.03125 0.015625
20 0 y Q.135 Trinexapac-ethyl rate ppm rate ppm Activity (%) P S?
0.0625 50 0.03125 0 2.5 0 1.25 0 0.625 0 0.3125 0 0.12625 0 0.0625
2.5 100 50 y 0.0625 1.25 90 50 y 0.0625 0.625 70 50 y 0.0625 0.3125
90 50 y 0.0625 0.15625 90 50 y 0.03125 1.25 20 0 y Q.135
Paclobutrazol rate ppm rate ppm Activity (%) P S? 0.0625 70 0.03125
0 0.015625 0 1.25 0 0.625 0 0.3125 0 0.15625 0 0.0625 1.25 100 70 y
0.0625 0.625 100 70 y 0.0625 0.3125 100 70 y 0.0625 0.15625 100 70
y 0.03125 1.25 100 0 y 0.03125 0.625 100 0 y 0.03125 0.3125 50 0 y
0.03125 0.15625 20 0 y 0.015625 0.625 20 0 y
TABLE-US-00172 Q.135 cis-Jasmone rate ppm rate ppm Activity (%) P
S? 0.0625 50 0.03125 0 1.25 0 0.625 0 0.3125 0 0.15625 0 0.0625
1.25 100 50 y 0.0625 0.625 90 50 y 0.0625 0.3125 100 50 y 0.0625
0.15625 100 50 y 0.03125 1.25 100 0 y 0.03125 0.625 50 0 y 0.03125
0.3125 20 0 y Q.135 2,4-D rate ppm rate ppm Activity (%) P S? 0.625
50 0.3125 0 2.5 0 1.25 0 0.625 0 0.3125 0 0.625 2.5 100 50 y 0.625
1.25 90 50 y 0.625 0.625 90 50 y 0.625 0.3125 90 50 y 0.625 0.15625
100 50 y 0.3125 1.25 20 0 y Q.135 Azoxystrobin rate ppm rate ppm
Activity (%) P S? 0.125 70 0.0625 0 0.00625 70 0.003125 20
0.0015625 0 0.125 0.003125 90 70 y 0.0625 0.00625 100 70 y 0.0625
0.0015625 20 0 y Q.135 Pyraclostrobin rate ppm rate ppm Activity
(%) P S? 0.125 70 0.0625 0 0.003125 0 0.0015625 0 0.125 0.003125 90
70 y 0.0625 0.003125 20 0 y 0.0625 0.0015625 20 0 y Q.135
Mandipropamid rate ppm rate ppm Activity (%) P S? 0.125 70 0.0625
20 0.03125 0 0.0625 0 0.03125 0 0.125 0.0625 90 70 y 0.125 0.03125
90 70 y 0.0625 0.0625 20 20 y 0.03125 0.0625 50 0 y Q.135
Carbendazim rate ppm rate ppm Activity (%) P S? 0.125 70 0.0625 20
0.0625 0 0.03125 0 0.0015625 0 0.125 0.0625 90 70 y 0.0625 0.03125
50 20 y 0.0625 0.0015625 50 20 y
TABLE-US-00173 Q.135 Fenpropimorph rate ppm rate ppm Activity (%) P
S? 0.03125 20 0.125 0 0.0625 0 0.03125 0 0.015625 0 0.0078125 0
0.03125 0.125 100 20 y 0.03125 0.0625 90 20 y 0.03125 0.03125 90 20
y 0.03125 0.015625 70 20 y 0.03125 0.0078125 90 20 y Q.135
Bicyclopyrone rate ppm rate ppm Activity (%) P S? 0.0625 20 0.03125
0 0.3125 0 0.15625 0 0.078125 0 0.0625 0.15625 90 20 y 0.03125
0.078125 20 0 y 0.0625 0.3125 70 20 y Q.135 Copper hydroxide rate
ppm rate ppm Activity (%) P S? 0.125 70 0.0625 20 5 0 2.5 0 1.25 0
0.625 0 0.3125 0 0.15625 0 0.125 0.3125 100 70 y 0.125 0.625 100 70
y 0.125 1.25 100 70 y 0.0625 0.15625 70 20 y 0.0625 0.3125 70 20 y
0.125 2.5 100 70 y 0.125 5 100 70 y Q.135 Manganese oxide rate ppm
rate ppm Activity (%) P S? 0.0625 20 2.5 0 1.25 0 0.625 0 0.3125 0
0.15625 0 0.0625 0.15625 70 20 y 0.0625 0.3125 50 20 y 0.0625 0.625
20 20 0.0625 1.25 70 20 y 0.0625 2.5 90 20 y
TABLE-US-00174 Q.135 Abamectin rate ppm rate ppm Activity (%) P S?
0.0625 20 2.5 0 1.25 0 0.625 0 0.3125 0 0.15625 0 0.0625 0.15625 70
20 y 0.0625 0.3125 50 20 y 0.0625 0.625 20 20 y 0.0625 1.25 50 20 y
0.0625 2.5 100 20 y Q.135 Thiamethoxam rate ppm rate ppm Activity
(%) P S? 0.125 70 0.0625 20 5 0 2.5 0 0.625 0 0.3125 0 0.125 0.3125
100 70 y 0.125 0.625 90 70 y 0.0625 0.3125 50 20 y 0.125 0.25 90 70
y 0.125 0.5 100 70 y 0.0625 0.25 70 20 y Q.135 Mesotrione rate ppm
rate ppm Activity (%) P S? 0.0625 20 0.03125 0 2.5 0 1.25 0 0.625 0
0.3125 0 0.15625 0 0.078125 0 0.0625 0.15625 70 20 y 0.0625 0.3125
70 20 y 0.0625 0.625 50 20 y 0.03125 0.078125 20 0 y 0.03125
0.15625 20 0 y 0.03125 0.3125 0 0 y 0.0625 1.25 70 20 y 0.03125
0.625 20 0 y 0.0625 2.5 90 20 y 0.03125 1.25 20 0 y Q.135
Prothioconazole rate ppm rate ppm Activity (%) P S? 0.0625 70
0.03125 0 0.0125 0 0.00625 0 0.003125 0 0.0015625 0 0.0625
0.0015625 100 70 y 0.0625 0.003125 100 70 y 0.0625 0.00625 100 70 y
0.03125 0.0015625 20 0 y 0.03125 0.003125 20 0 y 0.0625 0.0125 100
70 y 0.03125 0.00625 100 0 y 0.03125 0.0125 100 0 y
TABLE-US-00175 Q.135 Propiconazole rate ppm rate ppm Activity (%) P
S? 0.0625 70 0.03125 0 0.25 0 0.125 0 0.0625 0 0.03125 0 0.015625 0
0.0625 0.015625 90 70 y 0.0625 0.03125 100 70 y 0.0625 0.0625 100
70 y 0.03125 0.015625 50 0 y 0.03125 0.03125 20 0 y 0.0625 0.125
100 70 y 0.03125 0.0625 50 0 y 0.0625 0.25 100 70 y 0.03125 0.125
70 0 y Q.135 Glufosinate rate ppm rate ppm Activity (%) P S? 0.0625
70 0.03125 0 2.5 0 1.25 0 0.625 0 0.3125 0 0.0625 0.3125 90 70 y
0.0625 0.625 70 70 0.0625 1.25 90 70 y 0.03125 0.625 20 0 y 0.0625
2.5 90 70 y 0.03125 1.25 20 0 y Q.113 Flutriafol rate ppm rate ppm
Activity (%) P S? 2 70 1 20 0.5 20 0.25 0 2 0 1 0 0.5 0 0.25 0 2 2
100 70 y 2 1 100 70 y 2 0.5 90 70 y 1 2 90 20 y 1 1 70 20 y 1 0.5
70 20 y 1 0.25 50 20 y 0.5 2 50 20 y 0.25 1 20 0 y
TABLE-US-00176 Q.113 Metconazole rate ppm rate ppm Activity (%) P
S? 1 50 0.5 20 0.25 0 0.125 0 1 20 0.5 0 0.25 0 0.125 0 1 1 100 60
y 1 0.5 100 50 y 1 0.25 100 50 y 0.5 1 100 36 y 0.5 0.5 100 20 y
0.5 0.25 90 20 y 0.5 0.125 50 20 y 0.25 1 100 20 y 0.25 0.5 70 0 y
0.25 0.25 50 0 y 0.25 0.125 20 0 y 0.125 0.5 50 0 y 0.125 0.25 20 0
y 0.125 0.125 20 0 y Q.113 Paclobutrazol rate ppm rate ppm Activity
(%) P S? 1 50 0.5 20 0.25 0 0.125 0 10 0 5 0 2.5 0 1.25 0 1 10 100
50 y 1 5 100 50 y 1 2.5 90 50 y 0.5 10 70 20 y 0.5 5 70 20 y 0.5
2.5 50 20 y 0.5 1.25 50 20 y 0.25 10 50 0 y 0.25 5 50 0 y 0.25 2.5
50 0 y 0.25 1.25 20 0 y 0.125 5 20 0 y 0.125 2.5 20 0 y Q.113
Azoxystrobin rate ppm rate ppm Activity (%) P S? 0.25 0 0.125 0
0.0625 0 0.03125 0 0.00625 50 0.25 0.00625 70 50 y 0.125 0.00625 70
50 y 0.0625 0.00625 50 50 0.03125 0.00625 100 50 y
TABLE-US-00177 Q.113 Penflufen rate ppm rate ppm Activity (%) P S?
1 20 0.5 2 0.25 2 0.125 2 1 20 0.5 0 1 1 50 36 y 0.5 1 50 20 y 0.5
0.5 20 0 y 0.25 1 50 20 y 0.25 0.5 20 0 y 0.125 0.5 20 0 y Q.113
Bixafen rate ppm rate ppm Activity (%) P S? 0.25 0 0.125 0 0.0625 0
0.25 20 0.25 0.25 50 20 y 0.125 0.25 50 20 y 0.0625 0.25 50 20 y
Q.113 Fenpropimorph rate ppm rate ppm Activity (%) P S? 0.5 20 0.25
0 1 20 0.5 0 0.25 0 0.125 0 0.0625 0 0.5 1 700 36 y 0.5 0.5 100 20
y 0.5 0.25 100 20 y 0.5 0.125 100 20 y 0.25 1 100 20 y 0.25 0.5 90
0 y 0.25 0.25 70 0 y 0.25 0.125 20 0 y 0.25 0.0625 20 0 y Q.113
Cyprodinil rate ppm rate ppm Activity (%) P S? 0.015625 0 0.0078125
0 0.00390625 0 0.003125 20 0.0015625 0 0.015625 0.003125 50 20 y
0.0078125 0.0015625 20 0 y 0.0078125 0.003125 50 20 y 0.00390625
0.0015625 20 0 y Q.113 Abamectin rate ppm rate ppm Activity (%) P
S? 2 70 1 20 0.5 0 20 50 10 0 5 0 2 10 100 70 y 1 5 50 20 y 2 20
100 85 y 1 10 50 20 y 1 20 100 60 y 0.5 10 20 0 y 0.5 20 70 50 y
Q.113 Mesotrione rate ppm rate ppm Activity (%) P S? 1 20 0.5 0 5 0
2.5 0 1 2.5 50 20 y 1 5 50 20 y 0.5 2.5 20 0 y
TABLE-US-00178 Q.113 Prothioconazole rate ppm rate ppm Activity (%)
P S? 0.5 0 0.25 0 0.125 0 0.0125 0 0.5 0.0125 90 0 y 0.25 0.0125 50
0 y 0.125 0.0125 20 0 y Q.113 Propiconazole rate ppm rate ppm
Activity (%) P S? 2 70 1 20 0.5 0 0.25 0 1 20 0.5 0 0.25 0 0.125 0
2 0.5 100 70 y 2 1 100 76 y 1 0.25 90 20 y 1 0.5 100 20 y 1 1 100
36 y 0.5 0.125 20 0 y 0.5 0.25 50 0 y 0.5 0.5 90 0 y 0.25 0.125 20
0 y 0.25 0.25 20 0 y 0.5 1 100 20 y 0.25 0.5 50 0 y 0.25 1 90 20 y
Q.062 Compound (V) rate ppm rate ppm Activity (%) P S? 0.0625 0
0.03125 0 0.015625 0 0.125 70 0.0625 50 0.03125 0 0.0625 0.125 100
70 y 0.03125 0.0625 70 50 y 0.015625 0.03125 20 0 y 0.03125 0.125
90 70 y 0.015625 0.0625 70 50 y Q.062 Compound (VI) rate ppm rate
ppm Activity (%) P S? 0.03125 0 0.015625 0 0.125 50 0.0625 0
0.03125 0.125 70 50 y 0.03125 0.0625 20 0 y 0.015625 0.0625 20 0 y
Q.062 Chlorothalonil rate ppm rate ppm Activity (%) P S? 0.5 50
0.25 20 0.125 0 0.125 70 0.0625 20 0.03125 0 0.25 0.0625 50 36 y
0.5 0.125 100 85 y 0.125 0.0625 50 20 y 0.125 0.03125 20 0 y
TABLE-US-00179 Q.062 Flutriafol rate ppm rate ppm Activity (%) P S?
0.5 50 0.25 20 0.125 0 0.5 0 0.25 0 0.125 0 0.0625 0 0.5 0.5 90 50
y 0.5 0.25 90 50 y 0.5 0.125 90 50 y 0.25 0.5 50 20 y 0.25 0.25 50
20 y 0.25 0.125 50 20 y 0.25 0.0625 50 20 y 0.125 0.5 20 0 y 0.125
0.25 20 0 y 0.125 0.125 20 0 y 0.125 0.0625 20 0 y Q.062
Metconazole rate ppm rate ppm Activity (%) P S? 0.5 50 0.25 20
0.125 0 0.0625 0 1 20 0.5 0 0.25 0 0.125 0 0.0625 0 0.5 1 100 60 y
0.5 0.5 100 50 y 0.5 0.25 70 50 y 0.5 0.125 100 50 y 0.25 1 100 36
y 0.25 0.5 100 20 y 0.25 0.25 90 20 y 0.25 0.125 20 20 y 0.25
0.0625 50 20 y 0.125 0.5 90 0 y 0.125 0.25 50 0 y 0.125 0.125 20 0
y 0.0625 0.25 20 0 y Q.062 Trinexapac-ethyl rate ppm rate ppm
Activity (%) P S? 0.5 70 0.25 20 0.125 0 5 0 2.5 0 1.25 0 0.625 0
0.5 5 90 70 y 0.5 2.5 90 70 y 0.5 1.25 90 70 y 0.25 5 50 20 y 0.25
1.25 50 20 y 0.25 0.625 50 20 y 0.125 5 20 0 y 0.125 2.5 20 0 y
TABLE-US-00180 Q.062 Paclobutrazol rate ppm rate ppm Activity (%) P
S? 0.5 70 0.25 20 0.125 0 10 0 5 0 2.5 0 1.25 0 0.625 0 0.5 10 100
70 y 0.5 5 100 70 y 0.5 2.5 100 70 y 0.5 1.25 100 70 y 0.25 10 100
20 y 0.25 5 100 20 y 0.25 2.5 90 20 y 0.25 1.25 70 20 y 0.25 0.625
70 20 y 0.125 5 70 0 y 0.125 2.5 70 0 y 0.125 1.25 50 0 y 0.125
0.625 20 0 y Q.062 cis-Jasmone rate ppm rate ppm Activity (%) P S?
0.25 20 0.125 0 5 0 2.5 0 1.25 0 0.625 0 0.25 5 50 20 y 0.25 2.5 50
20 y 0.25 1.25 50 20 y 0.25 0.625 50 20 y 0.125 5 50 0 y 0.125 2.5
50 0 y 0.125 1.25 50 0 y Q.062 2,4-D rate ppm (%) Activity (%) P S?
0.5 70 0.25 20 0.125 0 10 0 5 0 2.5 0 1.25 0 0.625 0 0.5 10 90 70 y
0.5 5 90 70 y 0.5 2.5 90 70 y 0.5 1.25 90 70 y 0.25 10 50 20 y 0.25
5 50 20 y 0.25 2.5 50 20 y 0.25 1.25 50 20 y 0.25 0.625 50 20 y
0.125 5 20 0 y 0.125 2.5 20 0 y 0.125 1.25 20 0 y Q.062
Pyraclostrobin rate ppm rate ppm Activity (%) P S? 0.0625 0 0.03125
0 0.015625 0 0.0125 50 0.00625 0 0.0625 0.0125 70 50 y 0.03125
0.0125 70 50 y 0.03125 0.00625 20 0 y 0.015625 0.00625 20 0 y
TABLE-US-00181 Q.062 Penflufen Activity rate ppm rate ppm (%) P S?
2 20 1 0 0.5 0 0.25 0 1 20 0.5 0 2 1 50 36 y 1 0.5 20 0 y 0.5 1 50
20 y 0.25 0.5 20 0 y Q.062 Fenpropimorph Activity rate ppm rate ppm
(%) P S? 2 20 1 0 2 20 1 0 0.5 0 0.25 0 2 2 100 36 y 2 1 90 20 y 2
0.5 70 20 y 1 2 70 20 y 1 1 50 0 y 1 0.5 20 0 y 1 0.25 20 0 y Q.062
Abamectin Activity rate ppm rate ppm (%) P S? 1 70 0.5 50 20 50 10
0 5 0 1 5 90 70 y 1 10 100 70 y 1 20 100 85 y 0.5 10 70 50 y 0.5 20
100 75 y Q.062 Mesotrione Activity rate ppm rate ppm (%) P S? 1 70
20 0 10 0 5 0 1 5 90 70 y 1 10 90 70 y 1 20 90 70 y Prothio- Q.062
conazole Activity rate ppm rate ppm (%) P S? 0.5 50 0.25 20 0.125 0
0.0625 0 0.0125 0 0.5 0.0125 100 50 y 0.25 0.0125 100 20 y 0.125
0.0125 50 0 y 0.0625 0.0125 20 0 y
TABLE-US-00182 Q.062 Propiconazole Activity rate ppm rate ppm (%) P
S? 0.5 50 0.25 20 0.125 0 0.0625 0 1 20 0.5 0 0.25 0 0.125 0 0.0625
0 0.5 0.125 70 50 y 0.5 0.25 100 50 y 0.5 0.5 100 50 y 0.25 0.125
50 20 y 0.25 0.25 70 20 y 0.5 1 100 60 y 0.125 0.0625 20 0 y 0.125
0.125 20 0 y 0.25 0.5 100 20 y 0.125 0.25 50 0 y 0.0625 0.125 20 0
y 0.25 1 100 36 y 0.125 0.5 70 0 y 0.0625 0.25 20 0 y Q.062
Glufosinate Activity rate ppm rate ppm (%) P S? 0.125 0 5 0 2.5 0
1.25 0 0.125 1.25 20 0 y 0.125 2.5 20 0 y 0.125 5 20 0 y
[1214] Botrytis cinerea (Gray Mould)
[1215] Conidia of the fungus from cryogenic storage were directly
mixed into nutrient broth (PDB potato dextrose broth). After
placing a (DMSO) solution of the test compounds into a microtiter
plate (96-well format) the nutrient broth containing the fungal
spores was added. The test plates were incubated at 24.degree. C.
and the activity was determined visually after 72 hrs.
TABLE-US-00183 Fluxa- Q.135 pyroxad Activity rate ppm rate ppm (%)
P S? 0.03125 0 0.015625 0 0.0078125 0 0.00390625 0 0.0625 50
0.03125 20 0.015625 20 0.0078125 0 0.03125 0.0625 70 50 y 0.015625
0.03125 50 20 y 0.0078125 0.015625 50 20 y 0.00390625 0.0078125 20
0 y 0.015625 0.0625 70 50 y 0.0078125 0.03125 50 20 y 0.00390625
0.015625 50 20 y Compound Q.135 (V) Activity rate ppm rate ppm (%)
P S? 0.03125 0 0.015625 0 0.0078125 0 0.125 70 0.0625 70 0.03125 50
0.015625 20 0.015625 0.03125 70 50 y 0.0078125 0.015625 50 20 y
0.03125 0.125 90 70 y 0.015625 0.0625 70 70 0.0078125 0.03125 70 50
y Q.135 Chlorotalonil Activity rate ppm rate ppm (%) P S? 0.5 20
0.25 0 0.125 0 0.0625 0 0.25 20 0.125 0 0.0625 0 0.5 0.25 90 36 y
0.5 0.125 50 20 y 0.25 0.25 90 20 y 0.25 0.125 50 0 y 0.25 0.0625
20 0 y 0.125 0.25 50 20 y 0.125 0.125 50 0 y 0.125 0.0625 20 0 y
0.0625 0.25 50 20 y 0.0625 0.125 20 0 y 0.0625 0.0625 20 0 y
TABLE-US-00184 Q.135 Flutriafol Activity rate ppm rate ppm (%) P S?
1 5 0.5 20 0.25 0 0.125 0 1 0 0.5 0 0.25 0 0.125 0 1 1 100 50 y 1
0.5 100 50 y 1 0.25 100 50 y 0.5 1 90 20 y 0.5 0.5 90 20 y 0.5 0.25
90 20 y 0.5 0.125 70 20 y 0.25 1 70 0 y 0.25 0.5 50 0 y 0.25 0.25
50 0 y 0.25 0.125 50 0 y 0.125 0.5 20 0 y Q.135 Metconazole
Activity rate ppm rate ppm (%) P S? 0.125 0 0.0625 0 0.03125 0
0.03125 0 0.015625 0 0.125 0.03125 70 0 y 0.0625 0.03125 50 0 y
0.0625 0.015625 20 0 y 0.03125 0.03125 50 0 y Trinexapac- Q.135
ethyl Activity rate ppm rate ppm (%) P S? 1 50 0.5 20 0.25 0 20 0
10 0 5 0 2.5 0 1.25 0 1 20 90 50 y 1 10 90 50 y 1 5 90 50 y 1 2.5
90 50 y 0.5 20 70 20 y 0.5 10 50 20 y 0.5 5 50 20 y 0.5 2.5 50 20 y
0.5 1.25 50 20 y 0.25 10 20 0 y 0.25 5 20 0 y 0.25 1.25 20 0 y
Paclobutr- Q.135 azol Activity rate ppm rate ppm (%) P S? 0.5 20
0.25 0 0.125 0 0.0625 0 2.5 0 1.25 0 0.625 0 0.5 2.5 100 20 y 0.5
1.25 100 20 y 0.25 2.5 100 0 y 0.25 1.25 90 0 y 0.25 0.625 70 0 y
0.125 2.5 100 0 y 0.125 1.25 70 0 y 0.125 0.625 50 0 y 0.0625 2.5
100 0 y 0.0625 1.25 50 0 y
TABLE-US-00185 cis- Q.135 Jasmone Activity rate ppm rate ppm (%) P
S? 1 50 0.5 20 0.25 0 5 0 2.5 0 1.25 0 0.625 0 1 5 90 50 y 1 2.5 90
50 y 0.5 2.5 50 20 y 0.5 1.25 50 20 y 0.25 1.25 20 0 y 0.25 0.625
20 0 y Q.135 2,4-D Activity rate ppm rate ppm (%) P S? 1 50 0.5 20
10 0 5 0 2.5 0 1 10 90 50 y 1 5 100 50 y 1 2.5 90 50 y 0.5 10 50 20
y 0.5 5 50 20 y 0.5 2.5 50 20 y 0.5 1.25 50 20 y Azoxy- Q.135
strobin Activity rate ppm rate ppm (%) P S? 2 50 1 20 0.5 0 0.25 0
0.2 20 0.1 0 0.05 0 0.025 0 2 0.1 90 50 y 2 0.05 70 50 y 1 0.2 70
36 y 1 0.1 50 20 y 1 0.05 50 20 y 1 0.025 50 20 y 0.5 0.2 50 20 y
0.5 0.1 50 0 y 0.5 0.05 20 0 y 0.5 0.025 20 0 y 0.25 0.1 50 0 y
0.25 0.05 20 0 y 0.25 0.025 20 0 y
TABLE-US-00186 Pyraclo- Q.135 strobin Activity rate ppm rate ppm
(%) P S? 1 20 0.5 0 0.25 0 0.2 20 0.1 0 0.05 0 0.025 0 1 0.2 70 36
y 1 0.1 50 20 y 1 0.05 50 20 y 1 0.025 50 20 y 0.5 0.2 50 20 y 0.5
0.1 50 0 y 0.5 0.05 20 0 y 0.5 0.025 20 0 y 0.25 0.1 20 0 y 0.25
0.05 20 0 y Picoxy- Q.135 strobin Activity rate ppm rate ppm (%) P
S? 1 20 0.5 0 0.25 0 0.125 0 2 50 1 50 0.5 50 0.25 50 1 2 90 60 y 1
1 90 60 y 1 0.5 90 60 y 0.5 2 90 50 y 0.5 1 70 50 y 0.5 0.5 70 50 y
0.5 0.25 70 50 y 0.25 1 70 50 y 0.25 0.58 70 50 y 0.25 0.25 70 50 y
0.125 0.5 70 50 y 0.125 0.25 70 50 y Trifloxy- Q.135 strobin
Activity rate ppm rate ppm (%) P S? 0.5 20 0.25 0 0.1 50 0.05 50
0.025 20 0.0125 0 0.5 0.025 50 36 y 0.5 0.0125 50 20 y 0.25 0.1 70
50 y 0.25 0.05 50 50 0.25 0.025 50 20 y 0.25 0.0125 20 0 y Q.135
Fludioxonil Activity rate ppm rate ppm (%) P S? 0.25 0 0.125 0
0.0625 0 0.03125 0 0.0625 70 0.03125 0 0.25 0.0625 100 70 y 0.125
0.0625 100 70 y 0.125 0.03125 50 0 y 0.0625 0.0625 100 70 y 0.0625
0.03125 50 0 y 0.03125 0.0625 100 70 y 0.03125 0.03125 50 0 y
TABLE-US-00187 Fenpropi- Q.135 morph Activity rate ppm rate ppm (%)
P S? 1 50 0.5 20 0.25 0 0.125 0 0.0625 0 0.25 0 0.125 0 0.0625 0 1
0.25 100 50 y 0.5 0.25 100 20 y 0.5 0.125 100 20 y 0.25 0.25 100 0
y 0.25 0.125 100 0 y 0.25 0.0625 90 0 y 0.125 0.25 100 0 y 0.125
0.125 100 0 y 0.125 0.0625 70 0 y 0.0625 0.25 90 0 y 0.0625 0.125
70 0 y 0.0625 0.0625 20 0 y Bicyclo- Q.135 pyrone Activity rate ppm
rate ppm (%) P S? 1 50 0.5 20 5 0 2.5 0 1.25 0 1 2.5 70 50 y 1 5 70
50 y 0.5 1.25 50 20 y 0.5 2.5 50 20 y Copper Q.135 hydroxide
Activity rate ppm rate ppm (%) P S? 1 50 0.5 20 5 0 2.5 0 1.25 0 1
2.5 70 50 y 1 5 70 50 y 0.5 1.25 50 20 y 0.5 2.5 50 20 y Q.135
Abamectin Activity rate ppm rate ppm (%) P S? 1 50 0.5 20 0.25 0 20
0 10 0 5 0 2.5 0 1.25 0 1 2.5 90 50 y 1 5 90 50 y 1 10 70 50 y 0.5
1.25 50 20 y 0.5 2.5 70 20 y 0.5 5 50 20 y 1 20 70 50 y 0.25 1.25
20 0 y 0.25 2.5 20 0 y 0.5 10 50 20 y 0.25 5 50 0 y 0.5 20 50 20 y
0.25 10 50 0 y
TABLE-US-00188 Thia- Q.135 methoxam Activity rate ppm rate ppm (%)
P S? 1 50 0.5 20 0.25 0 2.5 0 1.25 0 0.625 0 1 2.5 70 50 y 0.5 1.25
50 20 y 0.25 0.625 20 0 y Q.135 Mesotrione Activity rate ppm rate
ppm (%) P S? 1 50 0.5 20 0.25 0 10 0 5 0 2.5 0 1.25 0 0.625 0 1 2.5
70 50 y 1 5 70 50 y 0.5 1.25 50 20 y 0.5 2.5 50 20 y 0.25 0.625 20
0 y 0.25 1.25 20 0 y 0.5 10 50 20 y Prothio- Q.135 conazole
Activity rate ppm rate ppm (%) P S? 0.5 20 0.25 0 0.125 0 0.05 50
0.025 0 0.0125 0 0.00625 0 2 0.05 100 85 y 1 0.025 100 20 y 1 0.05
100 60 y 0.5 0.0125 90 20 y 0.5 0.025 100 20 y 0.5 0.05 100 60 y
0.25 0.00625 50 0 y 0.25 0.0125 70 0 y 0.25 0.025 90 0 y 0.125
0.00625 20 0 y 0.125 0.0125 50 0 y 0.125 0.05 100 50 y 0.125 0.025
70 0 y 0.125 0.05 100 50 y
TABLE-US-00189 Propi- Q.135 conazole Activity rate ppm rate ppm (%)
P S? 2 70 1 50 0.5 20 0.25 0 0.125 0 0.5 50 0.25 0 0.125 0 0.0625 0
2 0.5 100 85 y 1 0.25 100 20 y 1 0.5 100 60 y 0.5 0.125 70 20 y 0.5
0.25 90 20 y 0.5 0.5 100 60 y 0.25 0.0625 50 0 y 0.25 0.125 70 0 y
0.25 0.25 70 0 y 0.125 0.0625 20 0 y 0.125 0.125 20 0 y 0.25 0.5 90
50 y 0.125 0.25 50 0 y 0.125 0.5 70 50 y Q.135 Glufosinate Activity
rate ppm rate ppm (%) P S? 1 20 0.5 0 0.25 0 20 0 10 0 5 0 2.5 0 1
2.5 50 20 y 1 5 50 20 y 0.5 2.5 20 0 y 1 20 50 20 y 0.5 10 20 0 y
0.5 20 20 0 y 0.5 10 20 0 y Pro- Q.135 cymidone Activity rate ppm
rate ppm (%) P S? 1 20 0.5 0 0.25 0 2.5 50 1.25 0 1 2.5 100 60 y
0.5 1.25 50 0 y 0.25 2.5 90 50 y
TABLE-US-00190 Mandi- Q.135 propamid Activity rate ppm rate ppm (%)
P S? 2 70 1 20 0.5 0 20 0 10 0 5 0 2 10 90 70 y 2 20 90 70 y 1 5 50
20 y 1 10 50 20 y 0.5 5 20 0 y 1 20 50 20 y 0.5 10 20 0 y 0.5 20 20
0 y Fluxa- Q.113 pyroxad Activity rate ppm rate ppm (%) P S?
0.03125 0 0.015625 0 0.0078125 0 0.00390625 0 0.0625 50 0.03125 50
0.015625 20 0.0078125 20 0.03125 0.0625 70 50 y 0.015625 0.03125 70
50 y 0.0078125 0.015625 50 20 y 0.00390625 0.0078125 20 20 0.015625
0.0625 70 50 y 0.0078125 0.03125 70 50 y 0.00390625 0.015625 50 20
y Compound Q.113 (VI) Activity rate ppm rate ppm (%) P S? 0.25 0
0.125 0 0.0625 0 0.03125 0 0.015625 0 0.0078125 0 0.0625 70 0.03125
70 0.015625 50 0.0078125 20 0.25 0.0625 90 70 y 0.125 0.0625 90 70
y 0.0625 0.0625 90 70 y 0.03125 0.0625 90 70 y 0.015625 0.0625 90
70 y 0.015625 0.015625 70 50 y 0.015625 0.03125 70 70 0.0078125
0.0078125 50 20 y 0.0078125 0.015625 70 50 y Azoxy- Q.113 strobin
Activity rate ppm rate ppm (%) P S? 0.5 0 0.25 0 0.125 0 0.0625 0
0.03125 0 0.25 20 0.125 0 0.5 0.125 20 0 y 0.25 0.125 20 0 y 0.125
0.125 20 0 y 0.125 0.25 50 20 y 0.0625 0.125 20 0 y 0.0625 0.25 50
20 y 0.03125 0.125 20 0 y
TABLE-US-00191 Pyraclo- Q.113 strobin Activity rate ppm rate ppm
(%) P S? 2 0 1 0 0.5 0 2 70 0.25 50 2 2 90 70 y 1 2 90 70 y 1 0.25
70 50 y 0.5 2 90 70 y Chloro- Q.113 talonil Activity rate ppm rate
ppm (%) P S? 1 0 0.5 0 0.25 0 0.25 20 1 0.25 50 20 y 0.5 0.25 70 20
y 0.25 0.25 70 20 y Q.113 Flutriafol Activity rate ppm rate ppm (%)
P S? 2 0 1 0 2 0 1 0 2 2 50 0 y 2 1 20 0 y 1 2 20 0 y Picoxy- Q.113
strobin Activity rate ppm rate ppm (%) P S? 2 0 1 0 0.5 0 2 50 1 50
0.5 50 2 2 70 50 y 2 1 70 50 y 2 0.5 70 50 y 1 2 70 50 y 1 1 70 50
y 0.5 2 70 50 y Trifloxy- Q.113 strobin Activity rate ppm rate ppm
(%) P S? 2 0 1 0 0.5 0 2 50 1 50 0.5 50 2 2 70 50 y 2 1 70 50 y 2
0.5 70 50 y 1 2 70 50 y 1 1 70 50 y 0.5 2 70 50 y
TABLE-US-00192 Q.113 Fludioxonil Activity rate ppm rate ppm (%) P
S? 0.25 0 0.125 0 0.0625 0 0.03125 0 0.0625 70 0.03125 0 0.25
0.03125 70 70 0.125 0.0625 20 0 y 0.125 0.03125 90 70 y 0.0625
0.0625 90 70 y 0.0625 0.03125 20 0 y 0.03125 0.0625 20 0 y
Fenpropi- Q.113 morph Activity rate ppm rate ppm (%) P S? 2 0 1 0
0.5 0 0.25 0 0.125 0 0.5 70 0.25 0 0.125 0 2 0.5 100 70 y 1 0.5 100
70 y 1 0.25 100 0 y 0.5 0.5 100 70 y 0.5 0.25 70 0 y 0.5 0.125 20 0
y 0.25 0.5 100 70 y 0.25 0.25 70 0 y 0.125 0.5 90 70 y 0.125 0.25
20 0 y Propi- Q.113 conazole Activity rate ppm rate ppm (%) P S? 2
0 1 0 0.5 0 0.25 0 0.125 0 0.05 70 0.025 0 2 0.05 90 70 y 1 0.025
50 0 y 1 0.05 90 70 y 0.5 0.025 20 0 y 0.5 0.05 90 70 y 0.25 0.025
0 0 0.25 0.05 100 70 y 0.125 0.025 20 0 y 0.125 0.05 90 70 y
Prothio- Q.113 conazole Activity rate ppm rate ppm (%) P S? 2 0 1 0
0.5 0 0.25 0 0.125 0 0.5 50 0.25 0 2 0.5 70 50 y 1 0.25 20 0 y 1
0.5 70 50 y 0.5 0.25 20 0 y 0.5 0.5 70 50 y 0.25 0.25 0 0 0.25 0.5
70 50 y 0.125 0.25 20 0 y
TABLE-US-00193 Fluxa- Q.062 pyroxad Activity rate ppm rate ppm (%)
P S? 0.03125 0 0.015625 0 0.0078125 0 0.00390625 0 0.125 70 0.0625
50 0.03125 50 0.015625 20 0.03125 0.0625 70 50 y 0.03125 0.125 90
70 y 0.015625 0.0625 70 50 y 0.0078125 0.03125 70 50 y 0.00390625
0.015625 50 20 y 0.0078125 0.015625 50 20 y Pyraclo- Q.062 strobin
Activity rate ppm rate ppm (%) P S? 2 0 1 0 0.5 0 2 70 2 2 90 70 y
1 2 90 70 y 0.5 2 90 70 y Chloro- Q.062 talonil Activity rate ppm
rate ppm (%) P S? 1 0 0.5 0 0.25 0 0.25 20 1 0.25 50 20 y 0.5 0.25
50 20 y 0.25 0.25 50 20 y Q.062 Flutriafol Activity rate ppm rate
ppm (%) P S? 2 0 1 0 0.5 0 2 0 1 0 0.5 0 2 2 50 0 y 2 1 20 0 y 2
0.5 20 0 y 1 2 20 0 y 0.5 2 20 0 y Paclobutr- Q.062 azol Activity
rate ppm rate ppm (%) P S? 1 0 0.5 0 0.25 0 0.125 0 5 70 2.5 0 1.25
0 1 5 100 70 y 1 2.5 70 0 y 0.5 5 100 70 y 0.5 2.5 20 0 y 0.5 1.25
20 0 y 0.25 5 100 70 y 0.125 5 100 70 y 0.125 2.5 100 0 y
TABLE-US-00194 Picoxy- Q.062 strobin Activity rate ppm rate ppm (%)
P S? 2 0 1 0 0.5 0 2 50 1 50 0.5 50 2 2 70 50 y 2 1 70 50 y 2 0.5
70 50 y 1 2 70 50 y 1 1 70 50 y 1 0.5 70 50 y 0.5 2 70 50 y 0.5 1
70 50 y Q.062 Fludioxonil Activity rate ppm rate ppm (%) P S? 0.25
0 0.1258 0 0.0625 0 0.03125 0 0.0625 50 0.03125 0 0.25 0.03125 90
50 y 0.125 0.0625 20 0 y 0.125 0.03125 90 50 y 0.0625 0.0625 100 50
y 0.0625 0.03125 20 0 y 0.03125 0.0625 20 0 y Fenpropi- Q.062 morph
Activity rate ppm rate ppm (%) P S? 2 0 1 0 0.5 0 0.25 0 0.125 0
0.5 70 0.25 0 0.125 0 2 0.5 100 70 y 1 0.5 100 70 y 1 0.25 100 0 y
0.5 0.5 100 70 y 0.5 0.25 70 0 y 0.5 0.125 20 0 y 0.25 0.5 100 70 y
0.25 0.25 70 0 y 0.125 0.5 90 70 y 0.125 0.25 20 0 y Pro- Q.062
cymidone Activity rate ppm rate ppm (%) P S? 0.125 0 0.0625 0
0.03125 0 0.015625 0 1.25 0 0.625 0 0.3125 0 0.125 1.25 70 0 y
0.0625 1.25 100 0 y 0.03125 1.25 90 0 y 0.015625 0.625 70 0 y
0.015625 0.3125 50 0 y
TABLE-US-00195 Prothio- .062 conazole Activity rate ppm rate ppm
(%) P S? 2 0 1 0 0.5 0 0.25 0 0.125 0 0.05 50 0.025 0 2 0.05 100 50
y 1 0.025 50 0 y 1 0.05 100 50 y 0.5 0.025 50 0 y 0.5 0.05 90 50 y
0.25 0.025 20 0 y 0.25 0.05 90 50 y 0.125 0.025 20 0 y 0.125 0.05
90 50 y Propicon- Q.062 azole Activity rate ppm rate ppm (%) P S? 2
0 1 0 0.5 0 0.25 0 0.125 0 0.5 50 0.25 0 2 0.5 90 50 y 1 0.25 50 0
y 1 0.5 70 50 y 0.5 0.25 20 0 y 0.5 0.5 70 50 y 0.25 0.25 0 0 0.25
0.5 70 50 y 0.125 0.25 20 0 y
[1216] Septoria tritici (Leaf Blotch)
[1217] Conidia of the fungus from cryogenic storage were directly
mixed into nutrient broth (PDB potato dextrose broth). After
placing a (DMSO) solution of the test compounds into a microtiter
plate (96-well format) the nutrient broth containing the fungal
spores was added. The test plates were incubated at 24.degree. C.
and the activity was determined visually after 72 hrs.
TABLE-US-00196 Fluxa- Q.135 pyroxad Activity rate ppm rate ppm (%)
P S? 0.03125 0 0.015625 0 0.0078125 0 0.00390625 0 0.0625 20
0.03125 0 0.015625 0 0.03125 0.0625 70 20 y 0.015625 0.03125 20 0 y
0.015625 0.0625 90 20 y 0.0078125 0.03125 50 0 y 0.00390625
0.015625 20 0 y Q.135 Flutriafol Activity rate ppm rate ppm (%) P
S? 2 0 1 0 0.5 0 1 0 0.5 0 2 1 90 0 y 2 0.5 50 0 y 1 1 70 0 y 1 0.5
20 0 y 0.5 1 50 0 y 0.5 0.5 20 0 y
TABLE-US-00197 Met- Q.135 conazole % rate ppm rate ppm Activity P
S? 0.25 0 0.125 0 0.0625 0 0.03125 0 0.0625 70 0.03125 0 0.25
0.0625 90 70 y 0.125 0.0625 90 70 y 0.125 0.03125 50 0 y 0.0625
0.0625 100 70 y 0.0625 0.03125 20 0 y 0.03125 0.03125 20 0 y Paclo-
Q.135 butrazol Activity rate ppm rate ppm (%) P S? 1 0 0.5 0 0.25 0
0.125 0 5 50 2.5 0 1.25 0 0.625 0 1 2.5 50 0 y 1 5 70 50 y 0.5 5 90
50 y 0.5 2.5 50 0 y 0.5 1.25 20 0 y 0.25 5 70 50 y 0.25 2.5 50 0 y
0.25 1.25 20 0 y 0.25 0.625 20 0 y 0.125 5 70 50 y 0.125 2.5 50 0 y
0.125 1.25 20 0 y 0.125 0.625 20 0 y Mandi- Q.135 propamid % rate
ppm rate ppm Activity P S? 2 0 1 0 0.5 0 0.25 0 0.5 70 2 0.5 700 70
y 1 0.5 90 70 y 0.5 0.5 70 70 0.25 0.5 90 70 y Q.135 Penflufen
Activity rate ppm rate ppm (%) P S? 2 0 1 0 0.5 0 0.5 70 0.25 20
0.125 0 2 0.5 100 70 y 1 0.5 90 70 y 1 0.25 70 20 y 0.5 0.25 50 20
y 0.5 0.125 20 0 y Fluaz- Q.135 inam Activity rate ppm rate ppm (%)
P S? 0.015625 0 0.0078125 0 0.00390625 0 0.03125 20 0.015625 0
0.015625 0.03125 50 20 y 0.0078125 0.03125 50 20 y 0.0078125
0.015625 20 0 y 0.00390625 0.015625 20 0 y
TABLE-US-00198 Fluo- Q.135 pyram Activity rate ppm rate ppm (%) P
S? 1 0 0.5 0 0.25 0 0.25 50 1 0.25 90 50 y 0.5 0.25 70 50 y 0.25
0.25 70 50 y Prothio- Q.135 conazole Activity rate ppm rate ppm (%)
P S? 0.5 0 0.25 0 0.125 0 0.0625 0 0.03125 0 0.0125 70 0.5 0.0125
90 70 y 0.25 0.0125 90 70 y 0.125 0.0125 90 70 y 0.0625 0.0125 90
70 y 0.03125 0.0125 90 70 y Propi- Q.135 conazole Activity rate ppm
rate ppm (%) P S? 0.5 0 0.25 0 0.125 0 0.0625 0 0.03125 0 0.125 50
0.5 0.125 90 50 y 0.25 0.125 90 50 y 0.125 0.125 90 50 y 0.0625
0.125 90 50 y 0.03125 0.125 90 50 y Fluxa- Q.113 pyroxad Activity
rate ppm rate ppm (%) P S? 0.03125 0 0.015625 0 0.0078125 0
0.00390625 0 0.0625 20 0.03125 0 0.015625 0 0.03125 0.0625 70 20 y
0.015625 0.03125 20 0 y 0.015625 0.0625 90 20 y 0.0078125 0.03125
50 0 y 0.00390625 0.015625 20 0 y Q.113 Flutriafol Activity rate
ppm rate ppm (%) P S? 2 0 1 0 0.5 0 1 0 0.5 0 2 1 70 0 y 2 0.5 20 0
y 1 1 70 0 y 1 0.5 20 0 y 0.5 1 70 0 y 0.5 0.5 20 0 y
TABLE-US-00199 Paclo- Q.113 butrazol Activity rate ppm rate ppm (%)
P S? 0.5 0 0.125 0 0.0625 0 0.03125 0 0.015625 0 2.5 50 0.625 0
0.3125 20 0.15625 0 0.5 2.5 90 50 y 0.125 2.5 70 0 y 0.0625 0.625
70 50 y 0.03125 0.15625 20 0 y 0.015625 0.3125 70 20 y Picoxy-
Q.113 strobin Activity rate ppm rate ppm (%) P S? 0.0078125 0
0.00390625 0 0.03125 90 0.015625 70 0.0078125 50 0.0078125 0.03125
90 70 y 0.0078125 0.015625 90 70 y 0.00390625 0.0078125 70 50 y
Q.113 Fluazinam Activity rate ppm rate ppm (%) P S? 0.015625 0
0.0078125 0 0.00390625 0 0.03125 20 0.015625 0 0.015625 0.03125 50
20 y 0.0078125 0.03125 50 20 y 0.0078125 0.015625 20 0 y 0.00390625
0.015625 20 0 y Q.113 Fludioxonil Activity rate ppm rate ppm (%) P
S? 1 0 0.5 0 0.25 0 0.25 70 1 0.25 90 70 y 0.5 0.25 90 70 y 0.25
0.25 90 70 y Prothio- Q.113 conazole Activity rate ppm rate ppm (%)
P S? 0.5 0 0.25 0 0.125 0 0.0625 0 0.03125 0 0.0125 70 0.5 0.0125
90 70 y 0.25 0.0125 90 70 y 0.125 0.0125 90 70 y 0.0625 0.0125 90
70 y 0.03125 0.0125 90 70 y Propi- Q.113 conazole Activity rate ppm
rate ppm (%) P S? 0.5 0 0.25 0 0.125 0 0.0625 0 0.03125 0 0.125 50
0.5 0.125 90 50 y 0.25 0.125 70 50 y 0.125 0.125 70 50 y 0.0625
0.125 70 50 y 0.03125 0.125 70 50 y
TABLE-US-00200 Iso- Q.062 pyrazam Activity rate ppm rate ppm (%) P
S? 0.0078125 0 0.00390625 0 0.03125 20 0.015625 0 0.0078125 0.03125
70 20 y 0.00390625 0.015625 70 0 y Fluxa- Q.062 pyroxad Activity
rate ppm rate ppm (%) P S? 0.03125 0 0.015625 0 0.0078125 0
0.00390625 0 0.0625 20 0.03125 0 0.015625 0 0.03125 0.0625 70 20 y
0.015625 0.03125 20 0 y 0.015625 0.0625 90 20 y 0.0078125 0.03125
70 0 y 0.00390625 0.015625 20 0 y Q.062 Flutriafol Activity rate
ppm rate ppm (%) P S? 2 0 1 0 0.5 0 1 0 0.5 0 2 1 70 0 y 2 0.5 20 0
y 1 1 70 0 y 1 0.5 20 0 y 0.5 1 70 0 y Met- Q.062 conazole Activity
rate ppm rate ppm (%) P S? 0.25 0 0.125 0 0.0625 0 0.03125 0 0.0625
50 0.25 0.0625 70 50 y 0.125 0.0625 70 50 y 0.0625 0.0625 70 50 y
0.03125 0.0625 70 50 y Paclo- Q.062 butrazol Activity rate ppm rate
ppm (%) P S? 1 0 0.5 0 0.25 0 10 70 5 70 2.5 20 1.25 0 0.625 0 1
2.5 50 20 y 0.5 10 100 70 y 0.5 2.5 70 20 y 0.5 1.25 20 0 y 0.25 10
100 70 y 0.25 5 100 70 y 0.25 2.5 70 20 y 0.25 0.625 90 0 y
TABLE-US-00201 Picoxy- Q.062 strobin Activity rate ppm rate ppm (%)
P S? 0.03125 0 0.015625 0 0.0078125 0 0.00390625 0 0.015625 70
0.0078125 20 0.03125 0.0078125 50 20 y 0.015625 0.0078125 20 20
0.0078125 0.0078125 70 20 y 0.0078125 0.0015625 100 70 y 0.00390625
0.0078125 90 20 y Q.062 Fluazinam Activity rate ppm rate ppm (%) P
S? 0.03125 0 0.015625 0 0.0078125 0 0.00390625 0 0.0625 70 0.03125
20 0.015625 0 0.03125 0.0625 90 70 y 0.015625 0.0625 90 70 y
0.015625 0.03125 50 20 y 0.0078125 0.03125 50 20 y 0.0078125
0.015625 20 0 y 0.00390625 0.015625 20 0 y Fluo- Q.062 pyram
Activity rate ppm rate ppm (%) P S? 0.125 0 0.0625 0 0.03125 0 0.25
50 0.125 0 0.125 0.25 70 50 y 0.0625 0.25 70 50 y 0.0625 0.125 20 0
y 0.03125 0.125 20 0 y Prothio- Q.062 conazole Activity rate ppm
rate ppm (%) P S? 0.5 0 0.25 0 0.125 0 0.0625 0 0.03125 0 0.0125 70
0.5 0.0125 90 70 y 0.25 0.0125 90 70 y 0.125 0.0125 90 70 y 0.0625
0.0125 90 70 y 0.03125 0.0125 90 70 y Propi- Q.062 conazole
Activity rate ppm rate ppm (%) P S? 0.5 0 0.25 0 0.125 0 0.0625 0
0.03125 0 0.125 50 0.5 0.125 90 50 y 0.25 0.125 90 50 y 0.125 0.125
90 50 y 0.0625 0.125 70 50 y 0.03125 0.125 70 50 y
[1218] Gaeumannomyces araminis (Take-All of Cereals)
[1219] Mycelial fragments of the fungus from cryogenic storage were
directly mixed into nutrient broth (PDB potato dextrose broth).
After placing a (DMSO) solution of the test compounds into a
microtiter plate (96-well format) the nutrient broth containing the
fungal spores was added. The test plates were incubated at
24.degree. C. and the activity was determined visually after 48
hrs
TABLE-US-00202 Compound Q.113 (V) Activity rate ppm rate ppm (%) P
S? 0.25 0 0.125 0 0.0625 0 0.03125 0 0.015625 0 0.0625 70 0.03125
20 0.015625 0 0.25 0.0625 90 70 y 0.125 0.03125 50 20 y 0.0625
0.015625 20 0 y 0.0625 0.03125 50 20 y 0.03125 0.0625 90 70 y
0.015625 0.03125 50 20 y Compound Q.062 (V) Activity rate ppm rate
ppm (%) P S? 0.015625 0 0.0078125 0 0.00390625 0 0.0625 70 0.03125
20 0.015625 0 0.015625 0.03125 50 20 y 0.0078125 0.015625 20 0 y
0.015625 0.0625 100 70 y 0.0078125 0.03125 70 20 y 0.00390625
0.015625 20 0 y
[1220] Pythium ultimum (Damping Off):
[1221] Mycelial fragments of the fungus, prepared from a fresh
liquid culture, were directly mixed into nutrient broth (PDB potato
dextrose broth). After placing a (DMSO) solution of the test
compounds into a microtiter plate (96-well format) the nutrient
broth containing the fungal spores was added. The test plates were
incubated at 24.degree. C. and the activity was determined visually
after 48 hrs
TABLE-US-00203 Q.135 Mefenoxam Activity rate ppm rate ppm (%) P S?
0.0625 0 0.03125 0 0.015625 0 0.0078125 0 0.03125 50 0.0625 0.03125
70 50 y 0.03125 0.03125 50 50 0.015625 0.03125 70 50 y 0.0078125
0.03125 70 50 y
[1222] Mycosphaerella arachidis (y. Cercospora arachidicola), Brown
leaf spot of groundnut (peanut): Conidia of the fungus from
cryogenic storage were directly mixed into nutrient broth (PDB
potato dextrose broth). After placing a (DMSO) solution of the test
compounds into a microtiter plate (96-well format) the nutrient
broth containing the fungal spores was added. The test plates were
incubated at 24.degree. C. and activity was determined visually
after 5-6 days.
TABLE-US-00204 Q.135 Sedaxan Activity rate ppm rate ppm (%) P S?
0.0625 50 0.03125 50 0.015625 20 0.0078125 0 0.03125 0 0.015625 0
0.00390625 0 0.0625 0.03125 70 50 y 0.0625 0.015625 70 50 y 0.03125
0.031215 50 50 0.015625 0.00390625 50 20 y 0.0078125 0.00390625 20
0 y Q.135 Fluazinam Activity rate ppm rate ppm (%) P S? 0.0625 50
0.03125 50 0.15625 0 0.0078125 0 0.03125 0 0.015625 0 0.0078125 0
0.00390625 0 0.0625 0.015625 70 50 y 0.03125 0.015625 50 50 y
0.015625 0.03125 20 0 y 0.015625 0.015625 20 0 y 0.015625 0.0078125
50 0 y 0.015625 0.00390625 50 0 y 0.0078125 0.03125 20 0 y
0.0078125 0.00390625 20 0 y Q.135 Fludioxonil Activity rate ppm
rate ppm (%) P S? 0.03125 50 0.015625 20 0.0625 0 0.03125 0
0.015625 0 0.0078125 0 0.00390625 0 0.03125 0.015625 70 50 y
0.015625 0.0625 50 20 y 0.015625 0.03125 50 20 y 0.015625 0.015625
50 20 y 0.015625 0.0078125 50 20 y 0.015625 0.00390625 50 20 y
Fenpropi- Q.135 morph Activity rate ppm rate ppm (%) P S? 0.0625 70
0.03125 70 0.015625 70 0.0078125 20 0.00390625 0 0.03125 70
0.015625 50 0.0078125 20 0.00390625 20 0.0625 0.015625 100 85 y
0.03125 0.015625 100 85 y 0.015625 0.0078125 90 76 y 0.015625
0.00390625 90 76 y 0.0078125 0.03125 100 76 y 0.0078125 0.0078125
50 36 y 0.0078125 0.00390625 50 36 y 0.00390625 0.015625 70 50 y
0.00390625 0.0078125 50 20 y
TABLE-US-00205 Q.135 Cyprodinil % rate ppm rate ppm Activity P S?
0.03125 50 0.015625 20 0.00125 0 0.0625 0 0.003125 0 0.0015625 0
0.00078125 0 0.03125 0.00078125 90 50 y 0.03125 0.0015625 70 50 y
0.03125 0.003125 70 50 y 0.03125 0.00625 70 50 y 0.03125 0.0125 70
50 y 0.015625 0.00078125 50 20 y Q.113 Sedaxan Activity rate ppm
rate ppm (%) P S? 0.125 20 0.0625 0 0.125 0 0.0625 0 0.03125 0
0.015625 0 0.125 0.125 50 20 y 0.0625 0.125 20 0 y 0.0625 0.0625 20
0 y 0.0625 0.03125 20 0 y 0.0625 0.015625 20 0 y Q.113 Fluazinam
Activity rate ppm rate ppm (%) P S? 0.03125 0 0.015625 0 0.0078125
0 0.0625 20 0.03125 0 0.03125 0.0625 50 20 y 0.015625 0.0625 50 20
y 0.0078125 0.03125 20 0 y Q.113 Fludioxonil Activity rate ppm rate
ppm (%) P S? 0.5 70 0.25 70 0.125 50 0.0625 20 0.03125 0 0.5 70
0.25 0 0.125 0 0.5 0.25 100 70 y 0.25 0.25 90 70 y 0.125 0.5 100 85
y 0.125 0.25 70 50 y 0.0625 0.25 50 20 y 0.03125 0.125 20 0 y
Fenpropi- Q.113 morph Activity rate ppm rate ppm (%) P S? 0.125 50
0.0625 50 0.03125 20 0.015625 0 0.0625 70 0.03125 50 0.125 0.0625
100 85 y 0.125 0.03125 100 75 y 0.0625 0.03125 90 75 y 0.03125
0.0625 100 76 y 0.015625 0.03125 70 50 y Q.062 Bixafen Activity
rate ppm rate ppm (%) P S? 0.0625 0 0.03125 0 0.015625 0 0.0625 70
0.03125 50 0.0625 0.0625 90 70 y 0.03125 0.0625 90 70 y 0.015625
0.0625 100 70 y 0.015625 0.03125 70 50 y
TABLE-US-00206 Q.062 Fludioxonil Activity rate ppm rate ppm (%) P
S? 2 70 1 70 0.5 0 0.25 0 0.125 0 0.5 50 0.25 0 0.125 0 2 0.5 100
85 y 1 0.5 100 85 y 0.5 0.5 100 50 y 0.5 0.25 50 0 y 0.5 0.125 20 0
y 0.25 0.5 70 50 y 0.25 0.25 20 0 y 0.125 0.25 20 0 y Q.062
Cyprodinil Activity rate ppm rate ppm (%) P S? 1 70 0.2 0 0.1 0
0.05 0 0.025 0 1 0.025 90 70 y 1 0.1 90 70 y 1 0.2 90 70 y
[1223] Septoria tritici (Leaf Blotch):
[1224] After placing solutions of the test compounds (containing
0.2% DMSO) into a microtiter plate (96-well format), an equal
amount of the nutrient broth (YBG) was added to each of the well.
Finally the fungal spore solution was added. The test plates were
incubated at 20.degree. C. The inhibition of growth was determined
photometrically after 6 days and the activity calculated in
relation to untreated control.
TABLE-US-00207 Tebu- Q.135 conazole Activity rate ppm rate ppm (%)
P S? 1.25 24 0.625 25 0.3125 35 1.25 0 1.25 1.25 59 24 y 0.625 1.25
51 25 y 0.3125 1.25 54 35 y Epoxi- Q.135 conazole (%) rate ppm rate
ppm Activity P S? 1.25 22 0.625 32 0.3125 34 0.15625 29 0.3125 78
0.15625 65 1.25 0.3125 95 83 y 0.625 0.3125 98 85 y 0.625 0.15625
94 76 y 0.3125 0.3125 100 86 y 0.15625 0.3125 100 85 y 0.15625
0.15625 98 75 y
TABLE-US-00208 Q.113 Cyproconazole Activity rate ppm rate ppm (%) P
S? 10 63 1 84 0.5 64 0.25 0 10 1 100 94 y 10 0.5 100 87 y 10 0.25
86 63 y Prothio- Q.113 conazole Activity rate ppm rate ppm (%) P S?
0.15625 42 0.078125 31 0.0390625 28 0.01953125 15 0.0390625 63
0.01953125 69 0.15625 0.0390625 96 78 y 0.078125 0.0390625 100 74 y
0.078125 0.01953125 100 79 y 0.0390625 0.0390625 99 73 y 0.01953125
0.0390625 100 68 y 0.01953125 0.01953125 93 74 y Epoxi- Q.113
conazole Activity rate ppm rate ppm (%) P S? 1.25 42 0.625 39
0.3125 34 0.15625 34 0.078125 33 0.3125 50 1.25 0.3125 97 71 y
0.625 0.3125 100 70 y 0.3125 0.3125 99 67 y 0.15625 0.3125 99 67 y
0.078125 0.3125 98 67 y Cypro- Q.062 conazole Activity rate ppm
rate ppm (%) P S? 5 64 2.5 49 1.25 48 2.5 76 1.25 39 5 1.25 96 78 y
2.5 2.5 100 88 y 2.5 1.25 86 69 y 1.25 2.5 98 88 y 1.25 1.25 87 69
y Prothio- Q.062 conazole Activity rate ppm rate ppm (%) P S?
0.3125 33 0.15625 38 0.0078125 31 0.0625 63 0.03125 9 0.3125 0.0625
88 75 y 0.15625 0.0625 98 77 y 0.078125 0.03125 63 73 y Tebu- Q
.062 conazole Activity rate ppm rate ppm (%) P S? 5 57 2.5 41 1.25
51 5 73 2.5 47 5 5 100 89 y 5 2.5 96 77 y 2.5 5 100 84 y 2.5 2.5 81
69 y 1.25 5 99 87 y
TABLE-US-00209 Q.062 Prochloraz Activity rate ppm rate ppm (%) P S?
0.625 35 0.3125 37 0.03125 80 0.015625 48 0.625 0.03125 98 87 y
0.625 0.015625 79 66 y 0.3125 0.03125 97 87 y Epoxi- Q.062 conazole
Activity rate ppm rate ppm (%) P S? 2.5 48 1.25 51 0.625 48 0.3125
42 0.625 71 0.3125 33 2.5 0.625 98 85 y 1.25 0.3125 77 67 y 0.625
0.3125 79 65 y 0.3125 0.3125 71 61 y Difeno- Q.062 conazole
Activity rate ppm rate ppm (%) P S? 0.625 40 0.3125 36 0.15625 39
0.078125 29 0.00390625 32 0.15625 48 0.625 0.15625 89 69 y 0.3125
0.15625 81 67 y 0.15625 0.15625 77 68 y 0.078125 0.15625 81 63 y
0.00390625 0.15625 84 64 y Compound Q.062 (S)-(VII) Activity rate
ppm rate ppm (%) P S? 0.625 26 0.3125 22 0.125 62 0.0625 44 0.03125
0
[1225] Sclerotinia sclerotiorum on Oilseed Rape, Preventive
Treatment
[1226] The compound activity was tested under 1 day preventive
conditions. Oilseed rape plants with 3 unfolded leafs were sprayed
with a track sprayer and 200 I/ha spray volume with the test
compounds, either solo or in tankmix as shown in the table
below.
[1227] 1 day after application the plants were infested with a
solution of Sclerotinia sclerotiorum mycelium. The plants were
placed under plastic hoods and high humidity conditions in a
climate chamber at 14 h day/10 h night cycle and 15.degree. C.
Disease infestation was evaluated visually 11 days after
application and average activity calculated in relation to disease
severity on untreated check.
TABLE-US-00210 Q.135 Boscalid Activity rate ppm rate g a.i./ha (%)
P S? 100 15 50 0 25 0 100 25 50 8 100 100 59 36 y 50 50 49 8 y 25
100 76 25 y 100 50 62 21 y 50 50 92 10 y 25 100 83 25 y 100 50 93
32 y Q.113 Boscalid Activity rate ppm rate g a.i./ha (%) P S? 100
39 50 2 25 2 100 25 50 8 100 100 83 54 y 50 50 89 10 y 25 100 83 26
y 100 50 86 44 y Q.062 Boscalid Activity rate ppm rate g a.i./ha
(%) P S? 100 26 50 2 25 0 100 25 50 8 100 100 91 44 y 50 50 92 10 y
25 100 83 25 y 100 50 93 32 y
[1228] Sphaerotheca fuliginea (Powdery Mildew) on Cucumber,
Preventive Treatment
[1229] The compound activity was tested under 2 days preventive
conditions. Cucumber plants with unfolded cotyledons were sprayed
with a roomsprayer and 40 ml/4 plants spray volume with the test
compounds, either solo or in tankmix as shown in the table
below.
[1230] 2 days after application the plants were infested with
spores of Sphaerotheca fuliginea. The plants were placed in a
climate chamber under 70% rel. humidity, 22.degree. C. and 14 h
day/10 h night cycle. Disease infestation was evaluated visually 10
days after application and average activity calculated in relation
to disease severity on untreated check.
TABLE-US-00211 Acibenzolar-s- Q.135 methyl Activity rate ppm rate
ppm (%) P S? 2 0 0.6 0 0.2 0 20 4 6 0 2 0 0.6 0 2 20 49 4 y 2 6 16
0 y 0.6 6 15 0 y 0.6 2 4 0 0.2 2 3 0 Acibenzolar-s- Q.113 methyl
Activity rate ppm rate ppm (%) P S? 2 0 0.6 0 0.2 0 20 4 6 0 2 0
0.6 0 2 20 18 4 y 2 6 12 0 y 0.6 6 5 0 0.6 2 7 0 0.2 2 9 0 y
Acibenzolar-s- Q.062 methyl Activity rate ppm rate ppm (%) P S? 2 7
0.6 0 0.2 0 20 4 6 0 2 0 0.6 0 2 20 11 11 2 6 4 7 0.6 6 9 0 y 0.6 2
5 0 0.2 2 9 0 y
[1231] Fusarium Spp. on Wheat, Preventive Treatment
[1232] The compound activity was tested under 1 day preventive
condition. Flowering wheat plants were sprayed with a track sprayer
and 220 I/ha spray volume with the test compounds, either solo or
in tankmix as shown in the table below. The compounds were
formulated as standard EC100 and diluted into water to the given
spray-dosis.
[1233] 1 day after application the flowering ears were infested
with a mix of spores of Fusarium graminearum and Fusarium culmorum.
The plants were placed in a climate chamber under 60% rel.
humidity, and 14 h day/10 h night cycle with 23/21.degree. C.
Disease infestation was evaluated visually 9 days after application
and average activity calculated in relation to disease severity on
untreated check.
TABLE-US-00212 Activity Compound g a.i./ha (%) P S? Prothioconazole
(PTZ) 50 55 Q.062 200 17 Q.135 200 28 Q.113 200 23 Q.151 200 3 PTZ
+ Q.062 200 + 50 83 63 y PTZ + Q.135 200 + 50 86 68 y PTZ + Q.113
200 + 50 85 65 y PTZ + Q.151 200 + 50 88 56 y
[1234] Phakopsora pachyrhizi on Soybean, Preventive Treatment
[1235] The compound activity was tested under 1 day preventive
conditions. Soybean plants with a fully enfolded first trifoliate
leaf were sprayed with a track sprayer and 50 I/ha spray volume
with the test compounds, either solo or in tankmix as shown in the
table below. 1 day after application leaf discs were cutted from
the first trifoliate leaf and placed in multiwell plates on
water-agar. 5 leaf discs per treatment where infested with spores
of a triazole tolerant soybeanrust strain. The multiwell plates
where sealed and placed in an incubator 48 h in darkness and 12 h
light/dark cycle afterwards. Rust infestation on leaf discs was
evaluated visually 11 days after application and average activity
calculated in relation to disease severity on untreated check leaf
discs.
TABLE-US-00213 Rate Activity Compound (g ai/ha) (%) P S?
Cyproconazole 2 53 N/A N/A Cyproconazole 0.5 38 N/A N/A Q.062 2 13
N/A N/A Q.062 0.5 0 N/A N/A Q.063 2 0 N/A N/A Q.063 0.5 0 N/A N/A
Q.113 2 25 N/A N/A Q.113 0.5 1 N/A N/A Q.135 2 41 N/A N/A Q.135 0.5
13 N/A N/A Q.062 + 2 + 2 99 59 Yes Cyproconazole Q.062 + .sup. 2 +
0.5 78 46 Yes Cyproconazole Q.062 + 0.5 + 2.sup. 96 53 Yes
Cyproconazole Q.063 + 2 + 2 100 53 Yes Cyproconazole Q.063 + .sup.
2 + 0.5 98 38 Yes Cyproconazole Q.063 + 0.5 + 2.sup. 98 53 Yes
Cyproconazole Q.113 + 2 + 2 100 65 Yes Cyproconazole Q.113 + .sup.
2 + 0.5 94 54 Yes Cyproconazole Q.113 + 0.5 + 2.sup. 96 54 Yes
Cyproconazole Q.135 + 2 + 2 95 72 Yes Cyproconazole Q.135 + .sup. 2
+ 0.5 98 72 Yes Cyproconazole Q.135 + 0.5 + 2.sup. 97 46 Yes
Cyproconazole
[1236] Septoria tritici on Wheat, Preventive Treatment
[1237] Four pots per treatment with 4 plants of the wheat variety
Riband in each of 6.5 cm pots have been treated 14 days after
sowing with the compounds given in the results table. The compounds
were formulated as standard EC100 and diluted into water to the
given spray-dosis. One day after application of the compounds solo
and in mixture, the plants were infested with spores of Septoria
tritici. To enable a good infestation, the plants were covered with
a plexiglas hood for 48 h after inoculation. The plants grew in a
controlled environment for 14 h at 21.degree. C. during day and 10
h at 19.degree. C. during night. 18 days after application the
infestation of the 2.sup.nd leaf of each of the plants and of the
untreated, infested check was evaluated visually. The activity data
in the table then derived from a calculation of the infestation of
the means of the 4 plants of 4 repetitions of each of the solo or
mixture treatments with the mean of the of the 4 plants of 4
repetitions of the untreated infested check.
TABLE-US-00214 Activity ga/ha (%) P S? compound (VII) 27 96 N/A N/A
9 20 3 0 Q.062 27 71 N/A N/A 9 8 3 6 Q.135 27 82 N/A N/A 9 33 3 0
Q.113 27 16 N/A N/A 9 0 3 0 Q.151 27 0 N/A N/A 9 0 3 0 compound
(VII) + 9 + 27 98 77 Y Q.062 3 + 9 36 8 Y compound (VII) + 27 + 27
99 99 Q.062 9 + 9 93 26 Y compound (VII) + 27 + 9 97 97 Q.062 9 + 3
58 25 Y compound (VII) + 9 + 27 98 47 Y Q.135 3 + 9 47 0 Y compound
(VII) + 27 + 27 100 99 Q.135 9 + 9 92 47 Y compound (VII) + 27 + 9
100 98 Q.135 9 + 3 91 20 Y compound (VII) + 9 + 27 97 33 Y Q.113 3
+ 9 38 0 Y compound (VII) + 27 + 27 100 97 Q.113 9 + 9 76 20 Y
compound (VII) + 27 + 9 99 96 Q.113 9 + 3 70 20 Y compound (VII) +
9 + 27 97 20 Y Q.151 3 + 9 69 0 Y compound (VII) + 27 + 27 99 96
Q.151 9 + 9 96 20 Y compound (VII) + 27 + 9 99 96 Q.151 9 + 3 71 20
Yes Activity Compound g a.i./ha (%) P S? Difenoconazole 27 5 (DFZ)
9 3 3 0 1 0 0.33 0 Q.062 81 61 27 50 9 26 3 8 1 2 Q.135 81 70 27 52
9 43 3 9 1 0 Q.113 81 53 27 61 9 29 3 0 1 1 Q.151 81 43 27 13 9 0 3
4 1 0 DFZ + 27 + 81 97 63 Y Q.062 9 + 27 49 51 27 + 27 85 52 Y 9 +
9 21 28 27 + 9 61 30 Y 9 + 3 0 10 DFZ + 27 + 81 100 71 Y Q.135 9 +
27 92 54 Y 27 + 27 90 55 Y 9 + 9 42 45 27 + 9 68 46 Y 9 + 3 41 12 Y
DFZ + 27 + 81 98 56 Y Q.113 9 + 27 94 62 Y 27 + 27 95 63 Y 9 + 9 69
31 Y 27 + 9 91 32 Y 9 + 3 50 3 Y DFZ + 27 + 81 94 46 Y Q.151 9 + 27
68 15 Y 27 + 27 97 17 Y 9 + 9 64 3 Y 27 + 9 85 5 Y 9 + 3 28 7 Y
* * * * *