U.S. patent application number 15/072744 was filed with the patent office on 2016-07-07 for stable amorphous metal oxide semiconductor.
The applicant listed for this patent is Chan- Long Shieh, Gang Yu. Invention is credited to Chan- Long Shieh, Gang Yu.
Application Number | 20160197139 15/072744 |
Document ID | / |
Family ID | 41797888 |
Filed Date | 2016-07-07 |
United States Patent
Application |
20160197139 |
Kind Code |
A1 |
Shieh; Chan- Long ; et
al. |
July 7, 2016 |
STABLE AMORPHOUS METAL OXIDE SEMICONDUCTOR
Abstract
A thin film semiconductor device has a semiconductor layer
including a mixture of an amorphous semiconductor ionic metal oxide
and an amorphous insulating covalent metal oxide. A pair of
terminals is positioned in communication with the semiconductor
layer and define a conductive channel, and a gate terminal is
positioned in communication with the conductive channel and further
positioned to control conduction of the channel. The invention
further includes a method of depositing the mixture including using
nitrogen during the deposition process to control the carrier
concentration in the resulting semiconductor layer.
Inventors: |
Shieh; Chan- Long; (Paradise
Valley, AZ) ; Yu; Gang; (Santa Barbara, CA) |
|
Applicant: |
Name |
City |
State |
Country |
Type |
Shieh; Chan- Long
Yu; Gang |
Paradise Valley
Santa Barbara |
AZ
CA |
US
US |
|
|
Family ID: |
41797888 |
Appl. No.: |
15/072744 |
Filed: |
March 17, 2016 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
|
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12206615 |
Sep 8, 2008 |
9306078 |
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15072744 |
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Current U.S.
Class: |
252/519.1 ;
252/518.1; 252/519.5; 252/520.1; 252/521.3; 252/521.4 |
Current CPC
Class: |
H01L 21/02592 20130101;
H01L 29/7869 20130101; H01L 51/5012 20130101; H01L 21/02565
20130101; H01L 21/16 20130101; H01L 29/78693 20130101; H01L 21/00
20130101; H01L 21/28556 20130101; H01L 27/1214 20130101; H01L 29/04
20130101; H01L 27/1225 20130101; H01L 29/24 20130101; H01L 21/02554
20130101 |
International
Class: |
H01L 29/04 20060101
H01L029/04; H01L 29/24 20060101 H01L029/24; H01L 29/786 20060101
H01L029/786 |
Claims
1. A stable amorphous metal oxide material for use as a
semiconductor in semiconductor devices, the material comprising a
mixture of an amorphous semiconductor ionic metal oxide and an
amorphous insulating covalent metal oxide, wherein the amorphous
semiconductor ionic metal oxide material has a grain size equal to
or smaller than 100 nm.
2. A stable amorphous metal oxide material as claimed in claim 1
wherein the amorphous semiconductor ionic metal oxide is in an
amount much greater than the amorphous insulating covalent metal
oxide.
3. A stable amorphous metal oxide material as claimed in claim 1
wherein the amount of amorphous insulating covalent metal oxide is
sufficient to prevent the amorphous semiconductor ionic metal oxide
from becoming poly crystalline at process temperatures.
4. A stable amorphous metal oxide material as claimed in claim 3
wherein the amount of amorphous insulating covalent metal oxide is
sufficient to prevent the amorphous semiconductor ionic metal oxide
from becoming poly crystalline at process temperatures in a range
of approximately 250.degree. C. to approximately 700.degree. C.
5. A stable amorphous metal oxide material as claimed in claim 1
wherein the amount of amorphous insulating covalent metal oxide is
sufficiently small to allow a continuous network of the amorphous
semiconductor ionic metal oxide.
6. A stable amorphous metal oxide material as claimed in claim 5
wherein the amount of amorphous semiconductor ionic metal oxide is
greater than approximately 17% of the mixture.
7. A stable amorphous metal oxide material as claimed in claim 5
wherein the amorphous insulating covalent metal oxide is greater
than approximately 5% of the mixture.
8. A stable amorphous metal oxide material as claimed in claim 1
wherein the amorphous semiconductor ionic metal oxide includes one
of zinc oxide, indium oxide, tin oxide, gallium oxide, cadmium
oxide, or combinations thereof.
9. A stable amorphous metal oxide material as claimed in claim 1
wherein the amorphous insulating covalent metal oxide includes one
of aluminum oxide, silicon oxide, magnesium oxide, beryllium oxide,
boron oxide, or combinations thereof.
10. A stable amorphous metal oxide material as claimed in claim 1
wherein the mixture at least partially includes the amorphous
semiconductor ionic metal oxide (XO) and the amorphous insulating
covalent metal oxide (YO) according to the formula
XO.sub.aYO.sub.b, where `a` is the amount of amorphous
semiconductor ionic metal oxide in the composite mixture and `b` is
the amount of amorphous insulating covalent metal oxide in the
composite mixture.
11. A stable amorphous metal oxide material as claimed in claim 1
wherein the mixture comprises oxygen atoms bonded to both metal Y
and metal X in the form of X--O--Y, wherein metal X forms ionic
bond with the oxygen and metal Y forms covalent bond with the
oxygen.
12-30. (canceled)
31. A stable amorphous metal oxide material as claimed in claim 1
wherein the amorphous insulating covalent metal oxide has a grain
size equal to or smaller than 100 nm.
32. A stable amorphous metal oxide material as claimed in claim 1
wherein the amorphous semiconductor ionic metal oxide is
characterized by an energy gap less than approximately 4 ev in its
single phase and the amorphous insulating covalent metal oxide is
characterized by an energy gap greater than approximately 6 ev in
its single phase.
Description
FIELD OF THE INVENTION
[0001] This invention relates to metal oxide semiconductor material
for use in channel layers of semiconductor devices.
BACKGROUND OF THE INVENTION
[0002] In the semiconductor industry and especially thin film
semiconductor devices such as thin film transistors (TFTs), the
devices include spaced apart source and drain areas that conduct
through a channel layer positioned therebetween. At least one gate
insulator and gate electrode are positioned above and/or below the
channel layer, to control the conduction. In many applications TFTs
are used where high heat cannot be tolerated during fabrication
and, thus, a semiconductor must be used that can be deposited at
relatively low temperatures (e.g. room temperature) but which still
has relatively high mobility.
[0003] There is a strong interest in metal oxide semiconductor
because of its high carrier mobility, light transparency and low
deposition temperature. The high carrier mobility expands
applications to higher performance domains that require higher
frequency or higher current. The light transparency eliminates the
need for a light shield in display and sensor active matrices. The
low deposition temperature enables application to flexible
electronics on plastic substrates.
[0004] The unique features of metal oxide semiconductors are: (1)
carrier mobility is less dependent on grain size of films, that is,
high mobility amorphous metal oxide is possible; (2) density of
surface states is low and enables easy field effect for TFTs, this
is contrary to covalent semiconductors (such as Si or a-Si) where
surface states have to be passivated by hydrogen; and (3) mobility
strongly depends on the volume carrier density. In order to achieve
high mobility for high performance applications, the volume carrier
density of the metal oxide channel should be high and thickness of
the metal oxide film should be small (e.g. <100 nm and
preferably <50 nm).
[0005] However, a major deficiency of metal oxide semiconductors is
stability and the tendency to become polycrystalline at higher
process temperatures. Popular metal oxides, such as zinc oxide,
indium zinc oxide, and indium gallium zinc oxide, are not very
stable and become polycrystalline at moderate process temperatures
(e.g. greater than approximately 400.degree. C.). Polycrystalline
semiconductor metal oxides are not desirable in semiconductor
devices for several reasons. For example, the characteristics of
transistors formed in polycrystalline semiconductor metal oxides
can vary, even between adjacent devices in an array, because of the
variation in crystal size and position. To better understand this
problem, in a conduction area under a sub-micron gate each
different transistor can include from one or two poly-silicon
crystalline grains to several crystalline grains and the different
number of crystals in the conduction area will produce different
characteristics. The dimensions and their physical characteristics
among different grains are also different.
[0006] The stability of metal oxide thin film transistors (TFTs)
depends strongly on processing temperatures. At high temperatures,
the traps in the bulk semiconductor layer and at the interface or
interfaces between the gate insulator and the semiconductor layer
can be reduced. For applications, such as active matrix organic
light emitting devices (AMOLED), extreme stability is required. It
is advantageous to take the metal oxide TFTs to high temperatures,
generally between 250.degree. C. and 700.degree. C., during
processing. Meanwhile it is desirable to maintain the amorphous
nature of the metal oxide at these processing temperatures.
[0007] It would be highly advantageous, therefore, to remedy the
foregoing and other deficiencies inherent in the prior art.
[0008] Accordingly, it is an object of the present invention to
provide a new and improved metal oxide semiconductor material.
[0009] Another object of the invention is to provide a new and
improved metal oxide semiconductor material with improved stability
and has less tendency to become polycrystalline at higher
processing temperatures.
[0010] Another object of the invention is to provide a new and
improved metal oxide semiconductor material with improved
stability, high carrier mobility, and good control of oxygen
vacancies and carrier density.
SUMMARY OF THE INVENTION
[0011] Briefly, to achieve the desired objects of the instant
invention in accordance with a preferred embodiment thereof, a
stable amorphous metal oxide material is provided for use as a
semiconductor in semiconductor devices, the material includes a
mixture of an amorphous semiconductor ionic metal oxide and an
amorphous insulating covalent metal oxide. The stable amorphous
metal oxide material is represented by one of the formula
XO.sub.aYO.sub.b, and X--O--Y, where YO is an amorphous insulating
covalent metal oxide and XO is an amorphous semiconductor ionic
metal oxide.
[0012] The desired objects of the instant invention are further
achieved in a thin film semiconductor device having a semiconductor
layer including a mixture of an amorphous semiconductor ionic metal
oxide and an amorphous insulating covalent metal oxide. A pair of
terminals is positioned in communication with the semiconductor
layer and define a conductive channel, and a gate terminal is
positioned in communication with the conductive channel and further
positioned to control conduction of the channel.
[0013] The invention further includes a method of depositing the
mixture including using nitrogen during the deposition process to
control the carrier concentration in the resulting semiconductor
layer.
BRIEF DESCRIPTION OF THE DRAWING
[0014] The foregoing and further and more specific objects and
advantages of the instant invention will become readily apparent to
those skilled in the art from the following detailed description of
a preferred embodiment thereof taken in conjunction with the
drawings, in which:
[0015] FIG. 1 is a simplified layer diagram of a TFT in accordance
with the present invention with overlying gate and underlying
source/drain;
[0016] FIG. 2 is a simplified layer diagram of a TFT in accordance
with the present invention with overlying gate and overlying
source/drain;
[0017] FIG. 3 is a simplified layer diagram of a TFT in accordance
with the present invention with underlying gate and underlying
source/drain; and
[0018] FIG. 4 is a simplified layer diagram of a TFT in accordance
with the present invention with underlying gate and overlying
source/drain.
DETAILED DESCRIPTION OF A PREFERRED EMBODIMENT
[0019] Turning now to FIG. 1, a simplified layer diagram of one
embodiment of a TFT 10, in accordance with the present invention,
is illustrated. TFT 10 includes a substrate 12, which may be a
flexible material, such as plastic, or any other convenient
material, such as glass, etc. A source 13 and a drain 14 are formed
in or on (hereinafter generically referred to as "on") the upper
surface of substrate 12 in a spaced apart orientation using any
well known method. A metal oxide film 16 is formed in partial
overlying relationship to both source 13 and drain 14 and the space
therebetween. It will be understood that metal oxide film 16 is the
active layer that conducts carriers between the source/drain
components. In a preferred embodiment, metal oxide layer 16 is less
than 100 nm thick and preferably less than 50 nm. A thin gate
dielectric layer 17 is formed in overlying relationship to metal
oxide film 16 and a gate stack 18 is positioned on gate dielectric
layer 17 in overlying relationship to the space between source 13
and drain 14. Thus, TFT 10 is a top gate, bottom source/drain type
of device.
[0020] Turning now to FIG. 2, a simplified layer diagram of another
embodiment of a TFT 20, in accordance with the present invention,
is illustrated. TFT 20 includes a substrate 22, which may be a
flexible material, such as plastic, or any other convenient
material, such as glass, etc. A metal oxide film 26 is deposited on
substrate 22 and a source 23 and a drain 24 are formed partially in
overlying relationship on the upper surface of metal oxide film 26
so as to form a spaced apart orientation on the upper surface. A
thin gate dielectric layer 27 is formed in overlying relationship
to metal oxide film 26 in the space between gate 23 and gate 24 and
to portions of gate 23 and gate 24 adjacent to the space. A gate
stack 28 is positioned on gate dielectric layer 27 in overlying
relationship to the space between source 23 and drain 24. Thus, TFT
20 is a top gate, top source/drain type of device.
[0021] Turning now to FIG. 3, a simplified layer diagram of another
embodiment of a TFT 30, in accordance with the present invention,
is illustrated. TFT 30 includes a substrate 32, which may be a
flexible material, such as plastic, or any other convenient
material, such as glass, etc. A gate stack 38 is formed in
substrate 32 by any convenient and established method. A thin gate
dielectric layer 37 is formed in overlying relationship to gate
stack 38 and the surrounding areas of substrate 32. A source 33 and
a drain 34 are formed in or on (hereinafter generically referred to
as "on") the upper surface of gate dielectric layer 37 in a spaced
apart orientation using any well known method. A metal oxide film
36 is formed in partial overlying relationship to both source 33
and drain 34 and the space therebetween. An optional passivation
layer 39 is formed over metal oxide film 36. Thus, TFT 30 is a
bottom gate, bottom source/drain type of device.
[0022] Turning now to FIG. 4, a simplified layer diagram of another
embodiment of a TFT 40, in accordance with the present invention,
is illustrated. TFT 40 includes a substrate 42, which may be a
flexible material, such as plastic, or any other convenient
material, such as glass, etc. A gate stack 48 is formed in
substrate 42 by any convenient and established method. A thin gate
dielectric layer 47 is formed in overlying relationship to gate
stack 48 and the surrounding areas of substrate 42. A metal oxide
film 46 is formed on gate dielectric layer 47 in overlying
relationship to gate stack 48 and the surrounding area. A source 43
and a drain 44 are formed partially in overlying relationship on
the upper surface of metal oxide film 46 so as to define a space
therebetween on the upper surface overlying gate stack 48. An
optional passivation layer 49 is formed over the exposed portion of
metal oxide film 46 and the surrounding portions of source 43 and
drain 44. Thus, TFT 40 is a bottom gate, top source/drain type of
device.
[0023] It will be understood that the above four examples of thin
film transistors illustrate only some of the possible embodiments.
For example, each of the above examples is a single gate
transistor. Double gate transistors, i.e. a gate above and below
the channel, are known in conjunction with virtually all of the
examples. It is intended that the present invention applies to all
possible or potential thin film transistors and other thin film
devices, e.g. diodes, etc. Further, for purposes of this disclosure
it will be understood that in all of the TFT examples the metal
oxide film is defined as being "deposited on the substrate", even
if a film is interposed therebetween.
[0024] Amorphous metal oxide semiconductor materials are desirable
for use in the channel layer of semiconductor devices because of
their high carrier mobility. For purposes of this disclosure, metal
oxide semiconductor materials include at least one of zinc oxide,
indium oxide, tin oxide, gallium oxide, cadmium oxide, or any
combinations thereof. However, metal oxide semiconductors are
relatively unstable and have a tendency to become polycrystalline
at higher temperatures. Polycrystalline semiconductor metal oxides
are not desirable in semiconductor devices because of the many
drawbacks in their structure, including the relatively large grain
size.
[0025] It is known in the art that the channel length of presently
standard thin film transistors is less than approximately 5
microns. For purposes of this disclosure the term "amorphous" is
defined as a material with grain size, along the channel length,
much less than the channel length of presently standard thin film
transistors, e.g. approximately 100 nanometers or less.
[0026] Some amorphous metal oxides, such as aluminum oxide, boron
oxide, silicon oxide, magnesium oxide, beryllium oxide, and
combinations thereof, are very stable and do not become
polycrystalline easily. However, these metal oxides are not good
semiconductors and cannot be used in semiconductor devices in their
normal state.
[0027] It has been found that the stability of amorphous metal
oxide semiconductor materials can be greatly improved by mixing
some amorphous insulating metal oxides with amorphous metal oxide
semiconductor materials. However, because the insulating amorphous
metal oxides are virtually non-conducting, it is necessary to
provide a continuous network of the amorphous metal oxide
semiconductor materials through the resulting mixture. Thus,
carrier flow is not interrupted by the amorphous metal oxide
insulating materials mixed with the amorphous metal oxide
semiconductor materials and mobility of the composite oxide can be
high. Thus, the stability of the composite oxides is enhanced by
the stable oxide component but the mobility remains high. Further,
it will be understood that several different types of insulating
amorphous metal oxides with different valences or other
characteristics may be included in a composite mixture to achieve
different results, at least one result being enhanced
stability.
[0028] Some typical insulating amorphous metal oxides that can be
used in a composite mixture include AlO, SiO, MgO, BeO, BO, and the
like, and combinations thereof. Generally, the insulating amorphous
metal oxides are more covalent in nature with a relatively high
energy gap that is E.sub.g greater than approximately 6 eV. For
ease of understanding, the insulating amorphous metal oxides may be
referred to generically as `covalent metal oxides`.
[0029] Generally, the amorphous metal oxide semiconductor materials
are more, or practically, ionic in nature with a relatively low
energy gap, that is E.sub.g less than approximately 4 eV. For ease
of understanding, the semiconducting amorphous metal oxides may be
referred to generically as `ionic metal oxides`.
[0030] Different valence metals, i.e. metals from different groups
in the periodic table, and mixtures thereof can be used to enhance
stability or desirable semiconductor characteristics in a composite
mixture. It will be understood that some covalent metal oxides will
add more stability because they have a greater tendency not to
crystallize (e.g. a higher energy gap). Also, the amount of stable
or covalent metal oxide added to the composite mixture is
determined by the necessity to maintain a continuous network of the
amorphous metal oxide semiconductor materials.
[0031] In the present composite mixture, the amorphous metal oxide
semiconductor materials are represented by XO and the insulating
amorphous metal oxides are represented by YO. Thus, a formula for
the composite mixture can be described as XO.sub.aYO.sub.b, where
`a` is the amount of amorphous metal oxide semiconductor material
(ionic metal oxide) in the composite mixture and `b` is the amount
of insulating amorphous metal oxide material (covalent metal oxide)
in the composite mixture. It should be understood that `a` and `b`
are non-zero (greater than zero) and to comply with the requirement
that the composite mixture include a continuous network of the
amorphous metal oxide semiconductor materials, `a` will generally
be larger than `b`. Preferably, b is larger than approximately 5%
of the total material. Also, the amount of amorphous semiconductor
ionic metal oxide is preferably greater than approximately 17% of
the mixture.
[0032] The amorphous semiconductor ionic metal (X) and amorphous
insulating covalent metal (Y) in the composite mixture, can in some
instances form an atomic bond directly with oxygen, represented as
X--O--Y herein. In such instances it should be understood that the
formula X--O--Y simply replaces the formula XO.sub.aYO.sub.b.
Further, it will be understood that in either instance a mixture of
an amorphous semiconductor ionic metal oxide and an amorphous
insulating covalent metal oxide is included in the stable amorphous
metal oxide material.
[0033] One other problem that arises from mixing a stable metal
oxide with an amorphous metal oxide semiconductor material is that
the stable metal oxide tends to reduce the oxygen vacancies. If
oxygen is used during deposition in the normal procedure (i.e. less
than 5%), the oxygen vacancies can be substantially reduced and the
conduction (mobility) of the composite material can become too low.
For example, it has been found that by using oxygen during the
deposition, carriers are decreased to less than 10.sup.18 carriers
per cm.sup.3. Thus, the use of oxygen to control the carrier
concentration in the composite mixture, while it is possible, is
very difficult and sensitive.
[0034] Instead of using oxygen to control the carrier concentration
during deposition, it has been found that nitrogen (N.sub.2) can
used to reduce the carrier concentration. The presence of N.sub.2
during deposition can reduce the carrier concentration, but not as
strongly as oxygen because nitrogen is less reactive compared to
oxygen. Thus, the use of nitrogen is less sensitive and it is
easier to achieve the desired result.
[0035] Thus, a new and improved metal oxide semiconductor material
has been disclosed that has improved stability and has less
tendency to become polycrystalline at higher temperatures. Also,
the new and improved metal oxide semiconductor material has high
carrier mobility and good control of oxygen vacancies.
[0036] Various changes and modifications to the embodiment herein
chosen for purposes of illustration will readily occur to those
skilled in the art. To the extent that such modifications and
variations do not depart from the spirit of the invention, they are
intended to be included within the scope thereof which is assessed
only by a fair interpretation of the following claims.
[0037] Having fully described the invention in such clear and
concise terms as to enable those skilled in the art to understand
and practice the same, the invention claimed is:
* * * * *