U.S. patent application number 14/993522 was filed with the patent office on 2016-05-05 for system and method for transfixing an aqueous ink in an image transfer system.
The applicant listed for this patent is Xerox Corporation. Invention is credited to Anthony S. Condello, Chu-heng Liu, David A. Mantell, Srinivas Mettu.
Application Number | 20160121600 14/993522 |
Document ID | / |
Family ID | 51176122 |
Filed Date | 2016-05-05 |
United States Patent
Application |
20160121600 |
Kind Code |
A1 |
Mantell; David A. ; et
al. |
May 5, 2016 |
System and Method for Transfixing an Aqueous Ink in an Image
Transfer System
Abstract
An image transfer medium for transferring an ink image onto a
substrate is provided on its surface with a layer of particles that
include an aggregation treatment agent capable of crashing out
colorants, latex and/or resin in the liquid ink. The particles can
include a surfactant or separate particles consisting essentially
of a surfactant can be mixed with particles consisting essentially
of the aggregation treatment agent.
Inventors: |
Mantell; David A.;
(Rochester, NY) ; Liu; Chu-heng; (Penfield,
NY) ; Mettu; Srinivas; (Essendon, AU) ;
Condello; Anthony S.; (Webster, NY) |
|
Applicant: |
Name |
City |
State |
Country |
Type |
Xerox Corporation |
Norwalk |
CT |
US |
|
|
Family ID: |
51176122 |
Appl. No.: |
14/993522 |
Filed: |
January 12, 2016 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
|
|
13943473 |
Jul 16, 2013 |
9242455 |
|
|
14993522 |
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Current U.S.
Class: |
347/103 ;
106/286.3; 106/287.18 |
Current CPC
Class: |
B41M 5/0017 20130101;
B41J 2/0057 20130101; B41M 5/0256 20130101; C09D 1/00 20130101;
B41M 5/03 20130101; B41M 5/5218 20130101 |
International
Class: |
B41J 2/005 20060101
B41J002/005; C09D 1/00 20060101 C09D001/00 |
Claims
1. An image transfer medium for transferring an ink image onto a
substrate, comprising: a surface adapted to receive liquid ink and
to engage the substrate to transfer an ink image thereto; and a
layer of particles affixed on said surface to receive the liquid
ink, each of said particles including a surfactant and an
aggregation treatment agent capable of crashing out colorants,
latex and/or resin in the liquid ink.
2. The image transfer medium of claim 1, wherein the aggregation
treatment agent includes a metal salt.
3. The image transfer medium of claim 2, wherein the metal salt
includes metal ions selected from the group Ca, Cu, Ni, Mg, Zn, Fe
and Al.
4. The method for transferring an ink image of claim 3, wherein the
particles include one or more of copper sulfate and iron
sulfate.
5. The image transfer medium of claim 1, wherein the aggregation
treatment agent includes an anion capable of crashing the colorant,
latex and/or resin.
6. The image transfer medium of claim 5, wherein the aggregation
treatment agent includes anions containing one or more of NO.sub.3,
SO.sub.4, I, Br, ClO.sub.3 and RCOO--, where R is an alkyl
group.
7. The image transfer medium of claim 1, wherein the particles are
distributed substantially uniformly with a density in the range of
5%-40% on the surface.
8. The image transfer medium of claim 1, wherein each of the
particles has a diameter of 1.0-10.0 .mu.m.
9. The image transfer medium of claim 1, wherein the particles are
affixed on the surface by one or more of the techniques including
triboelectric or ion charging, electrostatic precipitation and
adhesion dusting.
10. The image transfer medium of claim 1, wherein the surface is
roughened with the layer of particles disposed on the roughened
surface.
11. An image transfer medium for transferring an ink image onto a
substrate, comprising: a surface adapted to receive liquid ink and
to engage the substrate to transfer an ink image thereto; and a
layer of particles affixed on said surface to receive the liquid
ink, the layer of particles including particles consisting
essentially of a surfactant mixed with particles consisting
essentially of an aggregation treatment agent capable of crashing
out colorants, latex and/or resin in the liquid ink.
12. The image transfer medium of claim 11, wherein the aggregation
treatment agent includes a metal salt having metal ions selected
from the group Ca, Cu, Ni, Mg, Zn, Fe and Al.
13. The image transfer medium of claim 11, wherein the aggregation
treatment agent includes anions containing one or more of NO.sub.3,
SO.sub.4, I, Br, ClO.sub.3 and RCOO--, where R is an alkyl
group.
14. The image transfer medium of claim 11, wherein the particles
including the aggregation treatment agent are distributed
substantially uniformly with a density in the range of 5%-40% on
the surface.
15. The image transfer medium of claim 11, wherein the particles
including the aggregation treatment agent have a diameter of
1.0-10.0 .mu.m.
16. The image transfer medium of claim 11, wherein the surface is
roughened with the layer of particles disposed on the roughened
surface.
17. A composition to be affixed on the surface of an image transfer
medium for transferring an ink image onto a substrate, the surface
adapted to receive liquid ink and to engage the substrate to
transfer an ink image thereto, the composition comprising: a
plurality of particles adapted to be affixed on said surface by one
of triboelectric or ion charging, electrostatic precipitation and
adhesion dusting, wherein either (a) each of said plurality of
particles includes a surfactant and an aggregation treatment agent
capable of crashing out colorants, latex and/or resin in the liquid
ink, or (b) said plurality of particles includes particles
consisting essentially of a surfactant mixed with particles
consisting essentially of an aggregation treatment agent capable of
crashing out colorants, latex and/or resin in the liquid ink.
18. The image transfer medium of claim 17, wherein the aggregation
treatment agent includes a metal salt having metal ions selected
from the group Ca, Cu, Ni, Mg, Zn, Fe and Al.
19. The image transfer medium of claim 17, wherein the aggregation
treatment agent includes anions containing one or more of NO.sub.3,
SO.sub.4, I, Br, ClO.sub.3 and RCOO--, where R is an alkyl
group.
20. The image transfer medium of claim 11, wherein each of the
plurality of particles has a diameter of 1.0-10.0 .mu.m.
Description
REFERENCE TO RELATED APPLICATION AND PRIORITY CLAIM
[0001] This application is a continuation of and claims priority to
co-pending application Ser. No. 13/943,473, entitled "System and
Method for Transfixing an Aqueous Ink in an Image Transfer System",
filed on Jul. 16, 2013, the entire disclosure of which is
incorporated herein by reference.
TECHNICAL FIELD
[0002] The present disclosure relates to printing, copying and
image transfer machines, marking engines and the like. In
particular the disclosure relates to liquid or aqueous ink transfer
systems and methods for such machines.
BACKGROUND
[0003] In certain indirect printing systems, an ink image is
applied onto an image transfer medium, and this image is then
transferred to a second substrate, typically without the
application of heat. The image can be transferred using minimal or
low pressure applied to the back surface of the transfer medium,
after which the medium is removed. The first step in the transfix
process requires printing the liquid ink onto the image transfer
medium, which typically occurs by directing ink droplets onto the
surface of the medium. In this step it is necessary for the ink to
sufficiently wet the surface of the transfer medium so that the ink
droplet does not drawback in an uncontrolled or random manner.
Excessive ink drawback significantly reduces transfixed image
quality since the droplet is either randomly spread onto the
substrate or fails to transfer properly.
[0004] Another aspect of the aqueous transfix process is that the
ink becomes partially dried before being transfixed, so the
partially dried ink must still be able to transfer easily and
completely from image transfer medium to substrate, leaving very
little residue behind. Thus, the surface of the image transfer
medium must juggle two generally mutually exclusive
characteristics--surfaces which are sufficiently wettable tend to
resist transfer of the ink to the substrate and surfaces that have
good transfer characteristics tend to resist wetting.
[0005] There is a need for an aqueous image transfer system and
method that balances these two important aspects of the image
transfer process for a liquid or aqueous ink system. The system and
method must also be capable of initiating and sustaining crashing,
aggregating or precipitating of colorants in the liquid or aqueous
ink after it is applied to the image transfer medium.
SUMMARY OF THE DISCLOSURE
[0006] In one aspect of the present disclosure, a method for
transfixing a liquid or aqueous ink image contemplates providing an
image transfer medium; applying a layer of particles to the image
transfer medium, the particles including an aggregation treatment
agent capable of crashing out, aggregating or precipitating
colorants, latex and/or resin in liquid ink; applying liquid ink
drops to the image transfer medium; initiating crashing aggregating
or precipitating of the colorant, latex and/or resin in the ink
drops upon contact with the particles; and upon a sufficient amount
of crashing aggregating or precipitating, contacting a second
substrate to the image transfer medium to transfer the ink from the
transfer medium to the second substrate.
[0007] In another aspect of the present disclosure, an image
transfer medium is provided with a layer of particles on the
surface of the medium. The particles includes an aggregation
treatment agent capable of crashing out, aggregating or
precipitating colorants, latex and/or resin in liquid ink. The
aggregation treatment agent may include a metal salt such as iron
sulfate or copper sulfate.
DESCRIPTION OF THE FIGURES
[0008] FIG. 1 is diagram of a liquid ink drop applied to a surface
of an image transfer medium with a layer of particles capable of
crashing aggregating or precipitating colorant in the ink.
[0009] FIG. 2 is a diagram of the ink drop as the colorant is
crashed aggregated or precipitated out of the ink.
[0010] FIG. 3 is a diagram of the ink drop after the colorant as
been substantially crashed aggregated or precipitated out of the
ink drop by the particles.
[0011] FIG. 4(a) is a photograph of ink drops applied in a linear
pattern to the surface of a conventional image transfer medium
showing the gaps between the drops.
[0012] FIG. 4(b) is a photograph of ink drops applied in a linear
pattern to the surface of an image transfer medium in which the
surface includes a layer of iron sulfate particles.
[0013] FIG. 4(c) is a photograph of ink drops applied in a linear
pattern to the surface of an image transfer medium in which the
surface includes a layer of copper sulfate particles.
[0014] FIG. 5(a) is a photograph of ink drops applied in a linear
pattern to the surface of a conventional image transfer medium in
which the surface is roughened, the photograph showing the gaps
between the drops.
[0015] FIG. 5(b) is a photograph of ink drops applied in a linear
pattern to the roughened surface of an image transfer medium in
which the surface includes a layer of iron sulfate particles.
[0016] FIG. 5(c) is a photograph of ink drops applied in a linear
pattern to the roughened surface of an image transfer medium in
which the surface includes a layer of copper sulfate particles.
DETAILED DESCRIPTION
[0017] The present disclosure contemplates a system and method for
transfixing a liquid or aqueous ink to a substrate. For purposes of
the present disclosure, the ink is an aqueous solution that
includes colorants and that is adapted for deposition as droplets
onto a surface through conventional means, such as by a plurality
of ink jet device controllable to apply the ink droplets in the
image pattern. The ink droplets are deposited onto the surface of
an image transfer medium or blanket. The blanket may be formed of
various materials that are suitable to retain small particles
deposited thereon, as explained in more detail herein. For
instance, the blanket may be a silicone plate or drum.
[0018] In a first step of the method disclosed herein, a large
number of small particles are deposited uniformly onto the blanket
surface. The particles include agents or compounds suitable to
crash out aggregate or precipitate the colorants in the liquid ink.
For the purposes of the present disclosure, the term "aggregation
treatment agent" is used to refer to these agents or compounds that
are capable of aggregating colorants, latex and/or resin out of an
ink drop by any suitable mechanism, including but not limited to
precipitation. The particles may be very small, on the order of
1.0-10.0 .mu.m in effective diameter and are distributed uniformly
and with uniform density onto the blanket surface. In one aspect,
the particle coverage or density is low enough (e.g., significantly
less than 50%) so that the particles do not form a contiguous large
patch of particles. On the other hand, the particle coverage is
high enough (e.g., greater than 5%) so that the average distance
between the particles is less than a few microns so that many
particles are within the range of impact for a drop of ink. Thus,
the particle distribution may be in a coverage range of between 5
and about 40%.
[0019] The particles may be deposited using a number of techniques,
including known electrostatic printing methods such as
electrostatically biased roll/brush/cloud development with
particles charged through triboelectric charging or ion charging.
Another suitable technique is electrostatic precipitation in which
an air flow of airborne particles is created across the blanket
surface. The particles capture charge from an ion flow
perpendicular to the surface generated, for example, by a corotron,
and then precipitate onto the blanket surface. Adhesion dusting can
be implemented in another approach in which the particles are
coarsely dusted onto the blanket surface and then excess particles
are removed by light brushing or air flow. Since the
particle-to-particle cohesion is weaker than the
particle-to-surface cohesion a dense and uniform layer of particles
can be produced. This latter method is particularly useful for the
particle coverage range set forth above since the method is robust
against the particle density being either too high or too low.
[0020] In the next step of the method disclosed herein, ink
droplets are applied to the layer of particles, as illustrated
schematically in FIG. 1. When the droplet of ink strikes the
surface, the colorant or pigment begins to precipitate out of the
ink due to the aggregation treatment agent(s) within the particles,
as represented in FIG. 2. As the precipitation or crashing
continues, a coating of pigment and carrier (such as resin or
latex) is formed on the blanket surface. The particles further act
to pin the droplet to the blanket surface, which has a two-fold
impact. First, pinning the droplet to the surface allows the
aggregation treatment agent(s) in the particles to diffuse through
the droplet and cause further crashing of the ink, as illustrated
in FIG. 3.
[0021] Second, pinning the droplet to the surface prevents it from
drawing back, which ensures that the liquid ink is sufficiently
dispersed on the transfer medium or blanket so that the quality of
the transferred image is maintained. An example of this effect is
demonstrated in tests in which ink droplets of about 14 picoliters
are deposited on different surfaces, with the results shown in the
comparative diagrams of FIG. 4. The control strip of FIG. 4(a) is a
standard aqueous ink deposition onto a silicon plate. The ink
droplets draw back so that gaps (i.e., the space between droplets)
occupy about 51% of each strip. In contrast, the strips of FIGS.
4(b) and (c) were produced by the same aqueous ink applied to
surfaces treated as described above. The difference between the two
strips is in the aggregation treatment agent of the particles
applied to the plate surface. In one case, FIG. 4(b), the gaps
occupied only 39% of each strip, while in the other case, FIG.
4(c), the gaps were reduced to only 16% of the strip length.
[0022] A further benefit may be obtained by depositing the
particles on a roughened surface. In tests illustrated in the
comparative diagrams of FIG. 5, a silicon plate is roughened such
as by shot peening. As seen by comparing FIG. 5(a) with FIG. 4(a),
the roughened surface yields significantly smaller gaps, 21%, than
the smooth surface control test value of 51%. Similar improvements
are seen with the prepared surfaces of FIGS. 5(b), (c), with both
surfaces producing a small 12% gap.
[0023] The particle or powder layer described above may be applied
to the surface of an image transfer medium. The ink drops may be
applied using an ink jet or other known mechanism for applying ink
drops to a surface. When the ink drops strike the surface of the
transfer medium, the aggregation treatment agents immediately begin
dissolving in the ink and crashing out the pigment. Once the
pigment has sufficiently crashed out of the ink and the ink drop
has been adequately dried, the image transfer medium can be brought
into contact with a second substrate to transfer the color image
according to known techniques. Drying of the ink drops can be
hastened by applying heat, such as by flowing heated air across the
surface of the image transfer medium. The system and method
described herein improves the image transfer characteristics for an
aqueous color ink so that the resulting transferred image is
sharper and more complete than with prior systems and methods.
[0024] As indicated above, the particles or powder contain agents
or compounds that cause pigment and/or resin and/or latex to crash
out of the ink drop to produce a color drop on the receiving
substrate. In the tests documented in FIGS. 4-5 the particles were
iron sulfate and copper sulfate, with the copper sulfate showing
the narrower gaps in FIG. 4(c). It is contemplated that the
particle agents may include other metal salts with metal ions
selected from Ca, Cu, Ni, Mg, Zn, Fe and Al. It is further believed
that certain anions may also be suitable to crash out pigments,
resin and/or latex from an ink drop. These anions may include Cl,
NO.sub.3, SO.sub.4, I, Br, ClO.sub.3 and RCOO--, where R is an
alkyl group.
[0025] The aggregation treatment agents may be combined with other
additives to form the particles or powders described above. For
instance, a surfactant may be incorporated into the particles or
separate surfactant particles may be mixed with particles of the
aggregation treatment agent. The surfactant may dissolve in the ink
drop to reduce the surface tension of the drop at contact. Reducing
surface tension can improve surface wetting, thereby reducing the
gap between successive ink drops on the image transfer medium.
[0026] While the invention has been illustrated and described in
detail in the drawings and foregoing description, the same should
be considered as illustrative and not restrictive in character. It
is understood that only the preferred embodiments have been
presented and that all changes, modifications and further
applications that come within the spirit of the invention are
desired to be protected.
* * * * *