U.S. patent application number 14/702569 was filed with the patent office on 2016-01-28 for chromium free hardfacing materials.
The applicant listed for this patent is Scoperta, Inc.. Invention is credited to Justin Lee Cheney, Tianho Jiang.
Application Number | 20160024628 14/702569 |
Document ID | / |
Family ID | 55163687 |
Filed Date | 2016-01-28 |
United States Patent
Application |
20160024628 |
Kind Code |
A1 |
Cheney; Justin Lee ; et
al. |
January 28, 2016 |
CHROMIUM FREE HARDFACING MATERIALS
Abstract
Disclosed are embodiments of Fe-based alloys for use as a
hardfacing material having high hardness while avoiding the use of
chromium. The alloys can be twin arc or thermally sprayed as
coatings on different types of equipment. In some embodiments, the
alloys can be readable even after heating of the alloys.
Inventors: |
Cheney; Justin Lee;
(Encinitas, CA) ; Jiang; Tianho; (Temecula,
CA) |
|
Applicant: |
Name |
City |
State |
Country |
Type |
Scoperta, Inc. |
San Diego |
CA |
US |
|
|
Family ID: |
55163687 |
Appl. No.: |
14/702569 |
Filed: |
May 1, 2015 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
|
|
62028706 |
Jul 24, 2014 |
|
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|
Current U.S.
Class: |
428/34.1 ;
420/75; 428/389; 428/457 |
Current CPC
Class: |
C22C 38/44 20130101;
C22C 38/02 20130101; C23C 4/131 20160101; C22C 38/004 20130101;
C22C 38/58 20130101; C23C 4/067 20160101; C22C 38/08 20130101; C22C
38/46 20130101; C22C 38/50 20130101; C22C 38/12 20130101; C22C
45/02 20130101; C23C 4/06 20130101; C22C 38/14 20130101; C22C 38/04
20130101; C22C 38/002 20130101; C22C 38/48 20130101 |
International
Class: |
C22C 45/02 20060101
C22C045/02; C22C 38/12 20060101 C22C038/12; C22C 38/08 20060101
C22C038/08; C22C 38/04 20060101 C22C038/04; C22C 38/02 20060101
C22C038/02; C23C 4/06 20060101 C23C004/06; C22C 38/58 20060101
C22C038/58; C22C 38/50 20060101 C22C038/50; C22C 38/48 20060101
C22C038/48; C22C 38/46 20060101 C22C038/46; C22C 38/44 20060101
C22C038/44; C23C 4/12 20060101 C23C004/12; C22C 38/14 20060101
C22C038/14; C22C 38/00 20060101 C22C038/00 |
Claims
1. A work piece having at least one surface, the work piece
comprising: a coating applied to the at least one surface, the
coating comprising an Fe-based alloy having substantially no
chromium, having substantially no carbides, and having
substantially no borides; wherein the alloy comprises a Vickers
hardness of at least 500 and an adhesion strength of at least 5,000
psi.
2. The work piece of claim 1, wherein the coating comprises Fe and,
in weight percent: B: about 0-4; C: about 0-0.25; Si: about 0-15;
Mn: about 0 to 25; Mo: about 0-29; Nb: about 0-2; Ta: about 0-4;
Ti: about 0-4; V: about 0-10; W: about 0-6; Zr: about 0-10; wherein
B+C+Si is about 4-15; and wherein (Mo+Mn+Nb+Ta+Ti+V+W+Zr) is about
5 to 38.
3. The work piece of claim 1, wherein the coating comprises Fe and
in weight percent: C: about 0 to 0.25; Mn: about 5 to 19; Mo: about
7 to 23; Ni: about 0 to 4; and Si: about 5 to 10.
4. The work piece of claim 1, wherein the coating comprises one or
more of the following compositions in weight percent: Fe, Mn: about
5, Mo: about 13, Si: about 10, Al: about 2; or Fe, Mn: about 5, Mo:
about 7, Si: about 10, Al: about 2.
5. The work piece of claim 1, wherein the coating is non-magnetic
and the coating thickness can be accurately measured with an
Elcometer.TM. thickness gauge or similar device after it has been
exposed to temperatures exceeding about 1100 K for 2 hours or more
and then slow cooled at a rate of 10K/s or less.
6. The work piece of claim 1, wherein the coating is amorphous.
7. The work piece of claim 1, wherein the coating is
nanocrystalline, as defined by having a grain size of 100 nm or
less.
8. The work piece of claim 1, wherein the coating is applied via a
thermal spray process.
9. The work piece of claim 1, wherein the coating is applied via a
twin wire arc spray process.
10. The work piece of claim 1, wherein the work piece is a yankee
dryer.
11. The work piece of claim 1, wherein the work piece is a roller
used in a paper making machine.
12. An article of manufacture comprising: an Fe-based coating
having substantially no chromium; wherein the coating possesses a
melting temperature of 1500K or below; wherein the coating
possesses a large atom concentration of at least 5 atom %, large
atoms being of the group consisting of Mn, Mo, Nb, Ta, Ti, V, W,
and Zr; and wherein the coating is a primarily single phase
fine-grained structure of either martensite, ferrite, or
austenite.
13. The article of manufacture of claim 12, wherein the coating
comprises, in weight percent: B: about 0-4; C: about 0-0.25; Si:
about 0-15; Mn: about 0 to 25; Mo: about 0-29; Nb: about 0-2; Ta:
about 0-4; Ti: about 0-4; V: about 0-10; W: about 0-6; Zr: about
0-10; wherein B+C+Si is about 4-15; and wherein
(Mo+Mn+Nb+Ta+Ti+V+W+Zr) is about 5 to 38.
14. The article of manufacture of claim 12, wherein the coating
comprises Fe and in weight percent: C: about 0 to 0.25; Mn: about 5
to 19; Mo: about 7 to 23; Ni: about 0 to 4; and Si: about 5 to
10.
15. The work piece of claim 12, wherein the coating comprises one
or more of the following compositions in weight percent: Fe, Mn:
about 5, Mo: about 13, Si: about 10, Al: about 2; or Fe, Mn: about
5, Mo: about 7, Si: about 10, Al: about 2.
16. The article of manufacture of claim 12, wherein the coating is
non-magnetic and the coating thickness can be accurately measured
with an Elcometer.TM. thickness gauge or similar device after it
has been exposed to temperatures exceeding about 1100 K for 2 hours
or more and then slow cooled at a rate of 10K/s or less.
17. The article of manufacture of claim 12, wherein the coating
comprises a Vickers hardness of at least 500 and an adhesion
strength of at least 5,000 psi.
18. The article of manufacture of claim 12, wherein the coating is
applied via the twin wire arc spray process.
19. The article of manufacture of claim 12, wherein the coating is
amorphous.
20. The article of manufacture of claim 12, wherein the coating is
nanocrystalline, as defined by having a grain size of 100 nm or
less.
21. The article of manufacture of claim 12, wherein the coating is
applied via a thermal spray process.
22. The article of manufacture of claim 12, wherein the coating is
applied onto a roller used in a paper making machine.
23. The article of manufacture of claim 12, wherein the coating is
applied onto a Yankee Dryer.
24. The article of manufacture of claim 12, wherein the coating is
applied onto a boiler tube.
25. A work piece having at least one surface, the work piece
comprising: a coating applied to the at least one surface, the
coating comprising an Fe-based alloy having less than 1 wt. %
chromium, less than 5 vol. % carbides, and less than 5 vol. %
borides; wherein the alloy comprises a Vickers hardness of at least
500 and an adhesion strength of at least 5,000 psi.
26. The work piece of claim 25, wherein the alloy has less than 1
vol. % carbides and less than 1 vol. % borides.
Description
INCORPORATION BY REFERENCE TO ANY PRIORITY APPLICATIONS
[0001] Any and all applications for which a foreign or domestic
priority claim is identified in the Application Data Sheet as filed
with the present application are hereby incorporated by reference
under 37 CFR 1.57.
BACKGROUND
[0002] 1. Field
[0003] The disclosure generally relates to hardfacing materials
which can be deposited as hardfacing coatings without the
production of Cr, such as hexavalent Cr dust.
[0004] 2. Description of the Related Art
[0005] Thermal spray processing is a technique which can be
utilized to deposit a hard wear resistant and/or corrosion
resistant layer onto the surface of a component. Thermal spray
inherently creates a significant amount of dust due to the fact
that about 10-40% or more of the feedstock material does not stick
to the component of interest and rebounds of the surface in the
form a fine metallic dust. One particular class of thermal spray
materials which is used to form wear resistant layers is amorphous
and/or nanocrystalline materials. Fe-based amorphous and
nanocrystalline materials used in thermal spray contain chromium as
an alloying element. Chromium is effective in stabilizing the
fine-grained structure, can increase wear resistance through the
formation of chromium carbides and/or borides, and is useful in
providing a degree of corrosion resistance. However, chromium is
considered undesirable for use in thermal spray applications due to
the potential to form hexavalent chromium dust. Hexavalent chromium
dust is known to cause cancer.
[0006] There are several Fe-based chromium free thermal spray
materials which have been developed and are used by industry today.
Currently available Fe-based Cr-free materials have hardness levels
below 500 Vickers, as shown in Table 1, which can make them
inapplicable for many different industrial uses.
TABLE-US-00001 TABLE 1 Conventional Fe-based Cr-free materials and
reported hardness values Alloy Hardness 30T 97-100 FMB (~250
Vickers) 38T 23 HRC (~250 Vickers) 39T 34-47 HRC (~330-470 Vickers)
35 MXC 30-35 HRC (~290-330 Vickers)
[0007] There have also been efforts to specifically design Cr-free
hardfacing materials for welding processes, such as that shown in
2012/0097658. However, the alloys disclosed in the reference
require the formation of borides and carbides. Further, the
reference requires the use of boron.
SUMMARY
[0008] Disclosed herein are embodiments of alloy compositions used
to produce thermal spray coatings, methods of identifying these
compositions, the coatings themselves, and methods of making and
using the coatings. Thermal spray coatings according to certain
embodiments may be produced having a hardness above 500 Vickers
without the use of chromium as an alloying element. Some
embodiments are directed to a work piece having a coating on at
least a surface, the work piece comprising a metal surface onto
which a coating is applied, the coating comprising an Fe-based
alloy without any chromium, wherein the alloy comprises a Vickers
hardness of at least 500 and an adhesion strength of at least 5,000
psi.
[0009] In some embodiments, the coating can be applied via the twin
wire arc spray process.
[0010] In some embodiments, the coating can comprise, in weight
percent, B: about 0-4, C: about 0-0.25, Si: about 0-15, Mn: about 0
to 25, Mo: about 0-29, Nb: about 0-2, Ta: about 0-4, Ti: about 0-4,
V: about 0-10, W: about 0-6, Zr: about 0-10, wherein B+C+Si is
about 4-15, and wherein (Mo+Mn+Nb+Ta+Ti+V+W+Zr) is about 5 to
38.
[0011] In some embodiments, the coating can comprise Fe and, in
weight percent, C: about 0 to 0.25, Mn: about 5 to 19, Mo: about 7
to 23, Ni: about 0 to 4, and Si: about 5 to 10.
[0012] In some embodiments, the coating can be non-magnetic and
therefore the coating thickness can be accurately measured with an
Elcometer.TM. thickness gauge or similar device. In some
embodiments, the coating can be non-magnetic and therefore the
coating thickness can be accurately measured with an Elcometer.TM.
thickness gauge or similar device after it has been exposed to
temperatures exceeding about 1100 K for 2 hours or more and then
slow cooled at a rate of 10K/s or less.
[0013] In some embodiments, the coating can be amorphous. In some
embodiments, the coating can be nanocrystalline, as defined by
having a grain size of 100 nm or less.
[0014] Also disclosed herein are embodiments of an article of
manufacture comprising a coating which is Fe-based, without
chromium, and possesses a melting temperature of 1500K or below and
a large atom concentration of at least 5 atom %, large atoms being
of the group Mn, Mo, Nb, Ta, Ti, V, W, and Zr.
[0015] In some embodiments, the coating can comprise a Vickers
hardness of at least 400 and an adhesion strength of at least 5,000
psi. In some embodiments, the coating can be applied via the twin
wire arc spray process.
[0016] In some embodiments, the coating can comprise, in weight
percent, B: about 0-4, C: about 0-0.25, Si: about 0-15, Mn: about 0
to 25, Mo: about 0-29, Nb: about 0-2, Ta: about 0-4, Ti: about 0-4,
V: about 0-10, W: about 0-6, Zr: about 0-10, wherein B+C+Si is
about 4-15, and wherein (Mo+Mn+Nb+Ta+Ti+V+W+Zr) is about 5 to
38.
[0017] In some embodiments, the coating can comprise Fe and, in
weight percent, C: about 0 to 0.25, Mn: about 5 to 19, Mo: about 7
to 23, Ni: about 0 to 4, and Si: about 5 to 10.
[0018] In some embodiments, the coating can be non-magnetic and
therefore the coating thickness can be accurately measured with an
Elcometer.TM. thickness gauge or similar device. In some
embodiments, the coating can be non-magnetic and therefore the
coating thickness can be accurately measured with an Elcometer.TM.
thickness gauge or similar device after it has been exposed to
temperatures exceeding about 1100 K for 2 hours or more and then
slow cooled at a rate of 10K/s or less.
[0019] In some embodiments, the coating can be amorphous. In some
embodiments, the coating can be nanocrystalline, as defined by
having a grain size of 100 nm or less.
[0020] Disclosed herein are embodiments of a work piece having at
least one surface, the work piece comprising a coating applied to
the at least one surface, the coating comprising an Fe-based alloy
having substantially no chromium, having substantially no carbides,
and having substantially no borides, wherein the alloy comprises a
Vickers hardness of at least 500 and an adhesion strength of at
least 5,000 psi.
[0021] In some embodiments, the coating can comprise Fe and, in
weight percent, B: about 0-4, C: about 0-0.25, Si: about 0-15, Mn:
about 0 to 25, Mo: about 0-29, Nb: about 0-2, Ta: about 0-4, Ti:
about 0-4, V: about 0-10, W: about 0-6, Zr: about 0-10, wherein
B+C+Si is about 4-15, and wherein (Mo+Mn+Nb+Ta+Ti+V+W+Zr) is about
5 to 38. In some embodiments, the coating can comprise Fe and in
weight percent, C: about 0 to 0.25, Mn: about 5 to 19, Mo: about 7
to 23, Ni: about 0 to 4, and Si: about 5 to 10. In some
embodiments, the coating can comprise one or more of the following
compositions in weight percent: Fe, Mn: about 5, Mo: about 13, Si:
about 10, Al: about 2; or Fe, Mn: about 5, Mo: about 7, Si: about
10, Al: about 2.
[0022] In some embodiments, the coating can be non-magnetic and the
coating thickness can be accurately measured with an Elcometer.TM.
thickness gauge or similar device after it has been exposed to
temperatures exceeding about 1100 K for 2 hours or more and then
slow cooled at a rate of 10K/s or less.
[0023] In some embodiments, the coating can be amorphous. In some
embodiments, the coating can be nanocrystalline, as defined by
having a grain size of 100 nm or less.
[0024] In some embodiments, the coating can be applied via a
thermal spray process. In some embodiments, the coating can be
applied via a twin wire arc spray process. In some embodiments, the
work piece can be a yankee dryer. In some embodiments, the work
piece can be a roller used in a paper making machine.
[0025] Also disclosed herein are embodiments of an article of
manufacture comprising an Fe-based coating having substantially no
chromium, wherein the coating possesses a melting temperature of
1500K or below, wherein the coating possesses a large atom
concentration of at least 5 atom %, large atoms being of the group
consisting of Mn, Mo, Nb, Ta, Ti, V, W, and Zr, and wherein the
coating is a primarily single phase fine-grained structure of
either martensite, ferrite, or austenite.
[0026] In some embodiments, the coating can comprise, in weight
percent B: about 0-4, C: about 0-0.25, Si: about 0-15, Mn: about 0
to 25, Mo: about 0-29, Nb: about 0-2, Ta: about 0-4, Ti: about 0-4,
V: about 0-10, W: about 0-6, Zr: about 0-10, wherein B+C+Si is
about 4-15, and wherein (Mo+Mn+Nb+Ta+Ti+V+W+Zr) is about 5 to
38.
[0027] In some embodiments, the coating can comprise Fe and in
weight percent C: about 0 to 0.25, Mn: about 5 to 19, Mo: about 7
to 23, Ni: about 0 to 4, and Si: about 5 to 10.
[0028] In some embodiments, the coating can comprise one or more of
the following compositions in weight percent: Fe, Mn: about 5, Mo:
about 13, Si: about 10, Al: about 2; or Fe, Mn: about 5, Mo: about
7, Si: about 10, Al: about 2.
[0029] In some embodiments, the coating can be non-magnetic and the
coating thickness can be accurately measured with an Elcometer.TM.
thickness gauge or similar device after it has been exposed to
temperatures exceeding about 1100 K for 2 hours or more and then
slow cooled at a rate of 10K/s or less. In some embodiments, the
coating can comprise a Vickers hardness of at least 500 and an
adhesion strength of at least 5,000 psi.
[0030] In some embodiments, the coating can be applied via the twin
wire arc spray process. In some embodiments, the coating can be
applied via a thermal spray process.
[0031] In some embodiments, the coating can be amorphous. In some
embodiments, the coating can be nanocrystalline, as defined by
having a grain size of 100 nm or less.
[0032] In some embodiments, the coating can be applied onto a
roller used in a paper making machine. In some embodiments, the
coating can be applied onto a Yankee Dryer. In some embodiments,
the coating can be applied onto a boiler tube.
[0033] Also disclosed herein are embodiments of a work piece having
at least one surface, the work piece comprising a coating applied
to the at least one surface, the coating comprising an Fe-based
alloy having less than 1 wt. % chromium, less than 5 vol. %
carbides, and less than 5 vol. % borides, wherein the alloy
comprises a Vickers hardness of at least 500 and an adhesion
strength of at least 5,000 psi. In some embodiments, the alloy can
have less than 1 vol. % carbides and less than 1 vol. %
borides.
DETAILED DESCRIPTION
[0034] Disclosed herein are embodiments of chromium free, iron
based alloys, and methods of manufacturing the alloys. In some
embodiments, the alloys can have high hardness and can be used as,
for example, coatings. In some embodiments, computational
metallurgy can be used to explore alloy compositional ranges where
an alloy is likely to form an amorphous or nanocrystalline coating
without the use of chromium as an alloying element. Prior to this
disclosure, Fe-based thermal spray coatings with a hardness above
500 Vickers have used chromium as an alloying element. This
disclosure demonstrates embodiments of alloy compositions which can
produce thermal spray coatings with hardness values above 500
Vickers, in addition to describing the design techniques
successfully used to identify them.
[0035] Specifically, disclosed herein are embodiments of alloys
which can achieve high hardness levels through mechanisms other
than the use of chromium or the formation of carbides and/or
borides. Rather, in some embodiments, a very fine-grain structure
can be achieved due to melting temperature and large atom criteria
disclosed herein.
Metal Alloy Composition
[0036] In some embodiments, the alloy can be described by a
composition in weight percent comprising the following elemental
ranges at least partially based on the ranges disclosed in Table 2
and Table 3: [0037] Fe: BAL [0038] B: 0-4 (or about 0 to about 4),
C: 0-0.25 (or about 0 to about 0.25), and Si: 0-15 (or about 0 to
about 15), where B+C+Si is 4-15 (or about 4 to about 15) [0039] Mn:
0-25 (or about 0 to about 25), Mo: 0-29 (or about 0 to about 29),
Nb: 0-2 (or about 0 to about 2), Ta: 0-4 (or about 0 to about 4),
Ti: 0-4 (or about 0 to about 4), V: 0-10 (or about 0 to about 10),
W: 0-6 (or about 0 to about 6), Zr: 0-10 (about 0 to about 10),
where (Mo+Mn+Nb+Ta+Ti+V+W+Zr) is 5-38 (or about 5 to about 38) 0 Cr
(or about 0 Cr)
[0040] Generally, embodiments of an alloy can be designed using any
of the large elements as long as the other elemental ratios are
controlled properly. The following atomic sizes, in picometers,
were used for the large elements, large atoms defined as atoms
which are larger than iron atoms: Mn: 161, Mo: 190, Nb, 198, Ta:
200, Ti: 176, V: 171, W: 193, Zr: 206. Fe has an atomic size of 156
pm. A large atom can be an atom that is larger than Fe. These large
atoms can be advantageous as they can increase the viscosity of an
alloy in liquid form and thus slow down the crystallization rate of
the alloy. As the crystallization rate decreases, the probability
of forming an amorphous, nanocrystalline, or fine-grained structure
can increase.
[0041] In some embodiments, the coating can be amorphous. In some
embodiments, the coating can be nanocrystalline, as defined by
having a grain size of 100 nm or less. In some embodiments, the
coating can be nanocrystalline, as defined by having a grain size
of 50 nm or less. In some embodiments, the coating can be
nanocrystalline, as defined by having a grain size of 20 nm or
less.
[0042] In some embodiments, the alloy can be described by a
composition in weight percent comprising the following elemental
ranges at least partially based on a range composed form the alloys
selected for manufacture into experimental ingots: [0043] Fe: BAL,
C: 0-0.25 (or about 0 to about 0.25), Mn: 5-19 (or about 5 to about
19), Mo: 7-23 (or about 7 to about 23), Ni: 0-4 (or about 0 to
about 4), Si: 5-10 (or about 5 to about 10)
[0044] In some embodiments, the alloy can be described by the
specific compositions, which have been produced and experimentally
demonstrated amorphous formation potential, in weight percent,
comprising the following elements. [0045] 1. Fe: BAL, Mn: 5 (or
about 5), Mo: 23 (or about 23), Si: 10 (or about 10) [0046] 2. Fe:
BAL, Mn: 5 (or about 5), Mo: 19 (or about 19), Si: 10 (or about 10)
[0047] 3. Fe: BAL, Mn: 5 (or about 5), Mo: 11 (or about 11), Si: 10
(or about 10) [0048] 4. Fe: BAL, Mn: 5 (or about 5), Mo: 13 (or
about 13), Si: 10 (or about 10) [0049] 5. Fe: BAL, Mn: 5 (or about
5), Mo: 7 (or about 7), Si: 10 (or about 10) [0050] 6. Fe: BAL, Al:
2 (or about 2), Mn: 5 (or about 5), Mo: 5 (or about 5), Si: 13 (or
about 13) [0051] 7. Fe: BAL, Al: 2 (or about 2), Mn: 5 (or about
5), Mo: 7 (or about 7), Si: 15 (or about 15) [0052] 8. Fe: BAL, C:
0.25 (or about 0.25), Mn: 19 (or about 19), Mo: 7 (or about 7), Si:
(5 or about 5) [0053] 9. Fe: BAL, C: 0.25 (or about 0.25), Mn: 5
(or about 5), Mo: 7 (or about 7), Ni: (4 or about 4), Si: 5 (or
about 5) [0054] 10. Fe: BAL, Mn: 19 (or about 19), Mo: 7 (or about
7), Si: 7 (or about 7) [0055] 11. Fe: BAL, Mn: 19 (or about 19),
Mo: 7 (or about 7), Ni: 2 (or about 2), Si: 5 (or about 5) [0056]
12. Fe: BAL, Mn: 19 (or about 19), Mo: 15 (or about 15), Si: 6 (or
about 6) [0057] 13. Fe: BAL, Mn: 19 (or about 19), Mo: 7 (or about
7), Ni: 2 (or about 2), Si: 5 (or about 5)
[0058] In some embodiments, aluminum can be further added to the
above alloy ranges and chemistries to improve coating adhesion in
the range of up to 5 (or about 5) wt. %. Some exemplary examples of
aluminum additions, based upon the #4 and #5 base chemistries, are:
[0059] 14. Fe: BAL, Mn: 5 (or about 5), Mo: 13 (or about 13), Si:
10 (or about 10), Al: 2 (or about 2) [0060] 15. Fe: BAL, Mn: 5 (or
about 5), Mo: 7 (or about 7), Si: 10 (or about 10), Al: 2 (or about
2)
[0061] In some embodiments, the alloy may contain boron, such as
between 0-4 wt. % (including 1, 2, and 3 wt. %) as indicated above.
In some embodiments, the alloy may not contain any boron. In some
embodiments, boron may act as an impurity and does not exceed 1 wt.
%.
[0062] The Fe content identified in the composition above may be
the balance of the composition as indicated above, or
alternatively, the balance of the composition may comprise Fe and
other elements. In some embodiments, the balance may consist
essentially of Fe and may include incidental impurities. In some
embodiments, the above alloys may not contain any chromium. In some
embodiments, chromium may act as an impurity and does not exceed 1
wt. %.
Thermodynamic and Kinetic Criteria
[0063] In some embodiments, the alloy can be described by
thermodynamic and kinetic criteria. In some embodiments, the
thermodynamic criteria can relate to the stability of the liquid
phase, e.g., the melting temperature of the alloy. The melting
temperature can be calculated via thermodynamic models and is
defined as the highest temperature at which liquid is less than
100% of the mole fraction in the material. The kinetic criterion
can be related to the viscosity of the liquid and the concentration
in atom percent of large atoms. Large atoms are defined as atoms
which are larger than iron atoms. Either or both criteria can be
used to predict the tendency towards amorphous formation in thermal
spray materials. In some embodiments, the alloys can have a
microstructure of ferritic iron. In some embodiments, a primarily
single phase fine-grained structure of either martensite, ferrite,
or austenite can be formed. In some embodiments, <5% (or
<about 5%) borides and carbides are formed. In some embodiments,
<1% (or <about 1%) borides and carbides are formed. In some
embodiments, <0.1% (or <about 0.1%) borides and carbides are
formed. In some embodiments, no borides or carbides are formed.
[0064] In some embodiments, the melting temperature can be below
1500 K (or below about 1500K). In some embodiments, the melting
temperature can be below 1450K (or below about 1450K). In some
embodiments, the melting temperature can be below 1400K (or below
about 1400K). In general, amorphous formation is encouraged with
lower melting temperatures because, typically, as grain size
decreases, hardness increases (known as the Hall-Petch
relationship). Amorphous alloys effectively have zero grain size,
and thus can be the hardest form of the alloy. As amorphous
formation potential increases, the alloy, even if it doesn't always
become amorphous in every process, will tend towards a smaller
grain size. Thus, amorphous forming alloys of the disclosure, even
if they form fine-grained or nanocrystalline structures and not
actually an amorphous structure, will tend to be harder. For
example, in some embodiments, while there is the potential for an
amorphous structure, the alloy may end up being crystalline,
specifically nanocrystalline, upon application, such as through
thermal spray, while still achieving the high hardness levels
disclosed herein.
[0065] In some embodiments, the large atom atomic fraction can be
above 5 atom % (or above about 5 atom %). In some embodiments, the
large atom atomic fraction can be above 7.5 atom % (or above about
7.5 atom %). In some embodiments, the large atom atomic fraction
can be above 10 atom % (or above about 10 atom %). In some
embodiments, the higher large atom atomic fraction can encourage
amorphous formation and increase amorphous formation potential.
[0066] Table 2 lists the alloy compositions, all Fe-based, in
weight percent which can meet the thermodynamic criteria detailed
in this disclosure. In some embodiments, the Fe-based alloys can
have a composition that is predominantly iron, e.g., at least 50
wt. % iron.
[0067] Combining the alloys in Table 2 and Table 3 yields 1,141
compositions which meet the criteria. These alloys were compiled
through computational searching tools which evaluated 16,362 alloys
according to the disclosed criteria. Thus, the alloys disclosed
cover only 6.9% of the total explored space explicitly investigated
to design an alloy with the disclosed performance parameters.
TABLE-US-00002 TABLE 2 List of alloy compositions with
thermodynamic and kinetic parameters which meet disclosed criteria.
Large atom % is the total atom % of elements larger than iron and
melt T is the melting temperature of the alloy. Large Melt No B Mn
Mo Nb Si Ta Ti V W Zr Atom % T M1 0 0 10 1 10 0 0 0 0 0 6.1% 1500
M2 0 0 15 1 9 0 0 0 0 0 9.1% 1500 M3 0 0 15 1 10 0 0 0 0 0 9.0%
1500 M4 0 0 20 0 7 0 0 0 0 0 11.8% 1500 M5 0 0 20 0 8 0 0 0 0 0
11.7% 1500 M6 0 0 20 0 9 0 0 0 0 0 11.6% 1450 M7 0 0 20 0 10 0 0 0
0 0 11.5% 1450 M8 0 0 20 1 7 0 0 0 0 0 12.5% 1500 M9 0 0 20 1 8 0 0
0 0 0 12.3% 1500 M10 0 0 20 1 9 0 0 0 0 0 12.2% 1500 M11 0 0 20 1
10 0 0 0 0 0 12.1% 1500 M12 0 1 10 0 10 0 0 0 0 0 6.5% 1500 M13 0 1
10 1 10 0 0 0 0 0 7.1% 1500 M14 0 1 15 1 8 0 0 0 0 0 10.2% 1500 M15
0 1 15 1 9 0 0 0 0 0 10.1% 1500 M16 0 1 15 1 10 0 0 0 0 0 10.0%
1450 M17 0 1 20 0 7 0 0 0 0 0 12.8% 1500 M18 0 1 20 0 8 0 0 0 0 0
12.7% 1500 M19 0 1 20 0 9 0 0 0 0 0 12.6% 1450 M20 0 1 20 0 10 0 0
0 0 0 12.5% 1450 M21 0 1 20 1 7 0 0 0 0 0 13.5% 1500 M22 0 1 20 1 8
0 0 0 0 0 13.4% 1450 M23 0 1 20 1 9 0 0 0 0 0 13.2% 1500 M24 0 1 20
1 10 0 0 0 0 0 13.1% 1500 M25 0 2 10 0 10 0 0 0 0 0 7.4% 1500 M26 0
2 10 1 9 0 0 0 0 0 8.1% 1500 M27 0 2 10 1 10 0 0 0 0 0 8.0% 1500
M28 0 2 15 1 8 0 0 0 0 0 11.2% 1500 M29 0 2 15 1 9 0 0 0 0 0 11.1%
1500 M30 0 2 15 1 10 0 0 0 0 0 11.0% 1450 M31 0 2 20 0 7 0 0 0 0 0
13.9% 1500 M32 0 2 20 0 8 0 0 0 0 0 13.7% 1450 M33 0 2 20 0 9 0 0 0
0 0 13.6% 1450 M34 0 2 20 0 10 0 0 0 0 0 13.5% 1400 M35 0 2 20 1 6
0 0 0 0 0 14.7% 1500 M36 0 2 20 1 7 0 0 0 0 0 14.5% 1500 M37 0 2 20
1 8 0 0 0 0 0 14.4% 1450 M38 0 2 20 1 9 0 0 0 0 0 14.2% 1500 M39 0
2 20 1 10 0 0 0 0 0 14.1% 1500 M40 0 3 10 0 9 0 0 0 0 0 8.5% 1500
M41 0 3 10 0 10 0 0 0 0 0 8.4% 1500 M42 0 3 10 1 9 0 0 0 0 0 9.1%
1500 M43 0 3 10 1 10 0 0 0 0 0 9.0% 1500 M44 0 3 15 1 7 0 0 0 0 0
12.3% 1500 M45 0 3 15 1 8 0 0 0 0 0 12.2% 1500 M46 0 3 15 1 9 0 0 0
0 0 12.1% 1450 M47 0 3 15 1 10 0 0 0 0 0 12.0% 1500 M48 0 3 20 0 6
0 0 0 0 0 15.0% 1500 M49 0 3 20 0 8 0 0 0 0 0 14.7% 1450 M50 0 3 20
1 6 0 0 0 0 0 15.7% 1500 M51 0 3 20 1 8 0 0 0 0 0 15.4% 1450 M52 0
3 20 1 10 0 0 0 0 0 15.1% 1500 M53 0 4 5 1 10 0 0 0 0 0 7.1% 1500
M54 0 4 10 0 9 0 0 0 0 0 9.4% 1500 M55 0 4 10 0 10 0 0 0 0 0 9.3%
1500 M56 0 4 10 1 8 0 0 0 0 0 10.1% 1500 M57 0 4 10 1 9 0 0 0 0 0
10.0% 1500 M58 0 4 10 1 10 0 0 0 0 0 10.0% 1500 M59 0 4 15 1 7 0 0
0 0 0 13.4% 1500 M60 0 4 15 1 8 0 0 0 0 0 13.2% 1500 M61 0 4 15 1 9
0 0 0 0 0 13.1% 1450 M62 0 4 15 1 10 0 0 0 0 0 13.0% 1500 M63 0 4
15 2 6 0 0 0 0 0 14.1% 1500 M64 0 4 20 0 6 0 0 0 0 0 16.1% 1500 M65
0 4 20 0 7 0 0 0 0 0 15.9% 1450 M66 0 4 20 0 8 0 0 0 0 0 15.8% 1450
M67 0 4 20 0 9 0 0 0 0 0 15.6% 1400 M68 0 4 20 0 10 0 0 0 0 0 15.5%
1400 M69 0 4 20 1 5 0 0 0 0 0 16.9% 1500 M70 0 4 20 1 6 0 0 0 0 0
16.8% 1500 M71 0 4 20 1 7 0 0 0 0 0 16.6% 1450 M72 0 4 20 1 8 0 0 0
0 0 16.4% 1450 M73 0 4 20 1 9 0 0 0 0 0 16.3% 1500 M74 0 4 20 1 10
0 0 0 0 0 16.1% 1500 M75 0 4 20 2 5 0 0 0 0 0 17.6% 1500 M76 0 5 5
1 10 0 0 0 0 0 8.0% 1500 M77 0 5 10 0 8 0 0 0 0 0 10.5% 1500 M78 0
5 10 0 9 0 0 0 0 0 10.4% 1500 M79 0 5 10 0 10 0 0 0 0 0 10.3% 1500
M80 0 5 10 1 8 0 0 0 0 0 11.1% 1500 M81 0 5 10 1 9 0 0 0 0 0 11.0%
1500 M82 0 5 10 1 10 0 0 0 0 0 10.9% 1450 M83 0 5 15 1 6 0 0 0 0 0
14.5% 1500 M84 0 5 15 1 7 0 0 0 0 0 14.4% 1500 M85 0 5 15 1 8 0 0 0
0 0 14.2% 1450 M86 0 5 15 1 9 0 0 0 0 0 14.1% 1450 M87 0 5 15 1 10
0 0 0 0 0 14.0% 1500 M88 0 5 15 2 6 0 0 0 0 0 15.2% 1500 M89 0 5 20
0 5 0 0 0 0 0 17.3% 1500 M90 0 5 20 0 6 0 0 0 0 0 17.1% 1500 M91 0
5 20 0 7 0 0 0 0 0 17.0% 1450 M92 0 5 20 0 8 0 0 0 0 0 16.8% 1450
M93 0 5 20 0 9 0 0 0 0 0 16.6% 1400 M94 0 5 20 0 10 0 0 0 0 0 16.5%
1400 M95 0 5 20 1 5 0 0 0 0 0 18.0% 1500 M96 0 5 20 1 6 0 0 0 0 0
17.8% 1500 M97 0 5 20 1 7 0 0 0 0 0 17.6% 1450 M98 0 5 20 1 8 0 0 0
0 0 17.5% 1500 M99 0 5 20 1 9 0 0 0 0 0 17.3% 1500 M100 0 5 20 1 10
0 0 0 0 0 17.1% 1500 M101 0 5 20 2 5 0 0 0 0 0 18.7% 1500 M102 4 0
0 0 0 0 0 2 0 6 5.1% 1350 M103 4 0 0 0 0 0 0 2 2 6 5.7% 1400 M104 4
0 0 0 0 0 0 2 4 4 5.2% 1500 M105 4 0 0 0 0 0 0 2 4 6 6.3% 1450 M106
4 0 0 0 0 0 0 4 0 4 5.9% 1350 M107 4 0 0 0 0 0 0 4 0 6 7.0% 1350
M108 4 0 0 0 0 0 0 4 2 2 5.4% 1400 M109 4 0 0 0 0 0 0 4 2 4 6.5%
1400 M110 4 0 0 0 0 0 0 4 2 6 7.6% 1350 M111 4 0 0 0 0 0 0 4 4 2
6.0% 1450 M112 4 0 0 0 0 0 0 4 4 4 7.1% 1450 M113 4 0 0 0 0 0 0 4 4
6 8.3% 1450 M114 4 0 0 0 0 0 0 6 0 0 5.6% 1350 M115 4 0 0 0 0 0 0 6
0 2 6.7% 1350 M116 4 0 0 0 0 0 0 6 0 4 7.8% 1350 M117 4 0 0 0 0 0 0
6 0 6 8.9% 1400 M118 4 0 0 0 0 0 0 6 2 0 6.2% 1400 M119 4 0 0 0 0 0
0 6 2 2 7.3% 1400 M120 4 0 0 0 0 0 0 6 2 4 8.4% 1350 M121 4 0 0 0 0
0 0 6 2 6 9.6% 1400 M122 4 0 0 0 0 0 0 6 4 0 6.8% 1450 M123 4 0 0 0
0 0 0 6 4 2 7.9% 1450 M124 4 0 0 0 0 0 0 6 4 4 9.1% 1450 M125 4 0 0
0 0 0 0 6 4 6 10.2% 1450 M126 4 0 0 0 0 0 0 6 6 0 7.4% 1500 M127 4
0 0 0 0 0 0 6 6 2 8.6% 1500 M128 4 0 0 0 0 0 0 6 6 4 9.7% 1500 M129
4 0 0 0 0 0 0 6 6 6 10.9% 1500 M130 4 0 0 0 0 0 0 6 6 8 12.1% 1500
M131 4 0 0 0 0 0 0 6 6 10 13.3% 1500 M132 4 0 0 0 0 0 0 8 6 6 12.9%
1500 M133 4 0 0 0 0 0 0 8 6 8 14.1% 1500 M134 4 0 0 0 0 0 0 8 6 10
15.3% 1500 M135 4 0 0 0 0 0 0 10 6 6 14.8% 1500 M136 4 0 0 0 0 0 0
10 6 8 16.0% 1500 M137 4 0 0 0 0 0 0 10 6 10 17.3% 1500 M138 0 3 20
0 10 0 0 0 0 0 14.5% 1400 M139 0 3 20 0 10 0 0 0 0 2 15.8% 1350
M140 0 3 20 0 10 0 0 0 0 4 17.1% 1350 M141 0 3 20 0 10 0 0 0 2 0
15.3% 1400 M142 0 3 20 0 10 0 0 0 2 2 16.6% 1400 M143 0 3 20 0 10 0
0 0 2 4 18.0% 1400 M144 0 3 20 0 10 0 0 0 4 0 16.1% 1450 M145 0 3
20 0 10 0 0 0 4 2 17.5% 1450 M146 0 3 20 0 10 0 0 0 4 4 18.9% 1450
M147 0 3 20 0 10 0 0 2 0 0 16.6% 1400 M148 0 3 20 0 10 0 0 2 0 2
17.9% 1350 M149 0 3 20 0 10 0 0 2 0 4 19.3% 1350 M150 0 3 20 0 10 0
0 2 2 0 17.4% 1400 M151 0 3 20 0 10 0 0 2 2 2 18.8% 1400 M152 0 3
20 0 10 0 0 2 2 4 20.2% 1400 M153 0 3 20 0 10 0 0 2 4 0 18.3% 1450
M154 0 3 20 0 10 0 0 2 4 2 19.7% 1450 M155 0 3 20 0 10 0 0 2 4 4
21.1% 1450 M156 0 3 20 0 10 0 0 4 0 0 18.7% 1400 M157 0 3 20 0 10 0
0 4 0 2 20.1% 1350 M158 0 3 20 0 10 0 0 4 0 4 21.4% 1350 M159 0 3
20 0 10 0 0 4 2 0 19.6% 1400 M160 0 3 20 0 10 0 0 4 2 2 20.9% 1400
M161 0 3 20 0 10 0 0 4 2 4 22.4% 1400 M162 0 3 20 0 10 0 0 4 4 0
20.5% 1450 M163 0 3 20 0 10 0 0 4 4 2 21.9% 1450 M164 0 3 20 0 10 0
0 4 4 4 23.3% 1450 M165 0 3 20 0 10 0 2 0 0 0 16.7% 1400 M166 0 3
20 0 10 0 2 0 0 2 18.0% 1350 M167 0 3 20 0 10 0 2 0 0 4 19.4% 1350
M168 0 3 20 0 10 0 2 0 2 0 17.5% 1450 M169 0 3 20 0 10 0 2 0 2 2
18.9% 1450 M170 0 3 20 0 10 0 2 0 2 4 20.3% 1450 M171 0 3 20 0 10 0
2 0 4 0 18.4% 1500 M172 0 3 20 0 10 0 2 0 4 2 19.8% 1500 M173 0 3
20 0 10 0 2 0 4 4 21.2% 1500 M174 0 3 20 0 10 0 2 2 0 0 18.8% 1400
M175 0 3 20 0 10 0 2 2 0 2 20.2% 1350 M176 0 3 20 0 10 0 2 2 0 4
21.5% 1350 M177 0 3 20 0 10 0 2 2 2 0 19.7% 1450 M178 0 3 20 0 10 0
2 2 2 2 21.1% 1450 M179 0 3 20 0 10 0 2 2 2 4 22.5% 1450 M180 0 3
20 0 10 0 2 2 4 0 20.6% 1500 M181 0 3 20 0 10 0 2 2 4 2 22.0% 1500
M182 0 3 20 0 10 0 2 2 4 4 23.4% 1500 M183 0 3 20 0 10 0 2 4 0 0
20.9% 1400 M184 0 3 20 0 10 0 2 4 0 2 22.3% 1350 M185 0 3 20 0 10 0
2 4 0 4 23.7% 1350 M186 0 3 20 0 10 0 2 4 2 0 21.8% 1450 M187 0 3
20 0 10 0 2 4 2 2 23.2% 1450 M188 0 3 20 0 10 0 2 4 2 4 24.6% 1400
M189 0 3 20 0 10 0 2 4 4 0 22.7% 1450 M190 0 3 20 0 10 0 2 4 4 2
24.2% 1450 M191 0 3 20 0 10 0 2 4 4 4 25.6% 1450 M192 0 3 20 0 10 0
4 0 0 0 18.9% 1400 M193 0 3 20 0 10 0 4 0 0 2 20.3% 1400 M194 0 3
20 0 10 0 4 0 0 4 21.7% 1400 M195 0 3 20 0 10 0 4 0 2 0 19.8% 1450
M196 0 3 20 0 10 0 4 0 2 2 21.2% 1450 M197 0 3 20 0 10 0 4 0 2 4
22.6% 1450 M198 0 3 20 0 10 0 4 0 4 0 20.7% 1500 M199 0 3 20 0 10 0
4 0 4 2 22.1% 1500 M200 0 3 20 0 10 0 4 0 4 4 23.5% 1500 M201 0 3
20 0 10 0 4 2 0 0 21.0% 1400 M202 0 3 20 0 10 0 4 2 0 2 22.4% 1400
M203 0 3 20 0 10 0 4 2 0 4 23.8% 1400 M204 0 3 20 0 10 0 4 2 2 0
21.9% 1450 M205 0 3 20 0 10 0 4 2 2 2 23.3% 1450 M206 0 3 20 0 10 0
4 2 2 4 24.7% 1450 M207 0 3 20 0 10 0 4 2 4 0 22.8% 1500 M208 0 3
20 0 10 0 4 2 4 2 24.3% 1500 M209 0 3 20 0 10 0 4 2 4 4 25.7% 1500
M210 0 3 20 0 10 0 4 4 0 0 23.1% 1400 M211 0 3 20 0 10 0 4 4 0 2
24.5% 1400 M212 0 3 20 0 10 0 4 4 0 4 25.9% 1400 M213 0 3 20 0 10 0
4 4 2 0 24.1% 1450 M214 0 3 20 0 10 0 4 4 2 2 25.5% 1450 M215 0 3
20 0 10 0 4 4 2 4 26.9% 1450 M216 0 3 20 0 10 0 4 4 4 0 25.0% 1500
M217 0 3 20 0 10 0 4 4 4 2 26.4% 1500 M218 0 3 20 0 10 0 4 4 4 4
27.9% 1500 M219 0 3 20 0 10 2 0 0 0 0 15.3% 1400 M220 0 3 20 0 10 2
0 0 0 2 16.6% 1350 M221 0 3 20 0 10 2 0 0 0 4 18.0% 1350 M222 0 3
20 0 10 2 0 0 2 0 16.1% 1400 M223 0 3 20 0 10 2 0 0 2 2 17.5% 1400
M224 0 3 20 0 10 2 0 0 2 4 18.9% 1400 M225 0 3 20 0 10 2 0 0 4 0
17.0% 1450 M226 0 3 20 0 10 2 0 0 4 2 18.4% 1500 M227 0 3 20 0 10 2
0 0 4 4 19.8% 1500 M228 0 3 20 0 10 2 0 2 0 0 17.4% 1400 M229 0 3
20 0 10 2 0 2 0 2 18.8% 1350 M230 0 3 20 0 10 2 0 2 0 4 20.2% 1350
M231 0 3 20 0 10 2 0 2 2 0 18.3% 1400 M232 0 3 20 0 10 2 0 2 2 2
19.7% 1400 M233 0 3 20 0 10 2 0 2 2 4 21.1% 1400 M234 0 3 20 0 10 2
0 2 4 0 19.2% 1450 M235 0 3 20 0 10 2 0 2 4 2 20.6% 1450 M236 0 3
20 0 10 2 0 2 4 4 22.0% 1450 M237 0 3 20 0 10 2 0 4 0 0 19.6% 1400
M238 0 3 20 0 10 2 0 4 0 2 21.0% 1350 M239 0 3 20 0 10 2 0 4 0 4
22.4% 1350 M240 0 3 20 0 10 2 0 4 2 0 20.5% 1400 M241 0 3 20 0 10 2
0 4 2 2 21.9% 1400
M242 0 3 20 0 10 2 0 4 2 4 23.3% 1400 M243 0 3 20 0 10 2 0 4 4 0
21.4% 1450 M244 0 3 20 0 10 2 0 4 4 2 22.8% 1450 M245 0 3 20 0 10 2
0 4 4 4 24.3% 1450 M246 0 3 20 0 10 2 2 0 0 0 17.5% 1350 M247 0 3
20 0 10 2 2 0 0 2 18.9% 1350 M248 0 3 20 0 10 2 2 0 0 4 20.3% 1350
M249 0 3 20 0 10 2 2 0 2 0 18.4% 1450 M250 0 3 20 0 10 2 2 0 2 2
19.8% 1450 M251 0 3 20 0 10 2 2 0 2 4 21.2% 1450 M252 0 3 20 0 10 2
2 0 4 0 19.3% 1500 M253 0 3 20 0 10 2 2 0 4 2 20.7% 1500 M254 0 3
20 0 10 2 2 0 4 4 22.1% 1500 M255 0 3 20 0 10 2 2 2 0 0 19.7% 1350
M256 0 3 20 0 10 2 2 2 0 2 21.1% 1350 M257 0 3 20 0 10 2 2 2 0 4
22.5% 1350 M258 0 3 20 0 10 2 2 2 2 0 20.6% 1450 M259 0 3 20 0 10 2
2 2 2 2 22.0% 1450 M260 0 3 20 0 10 2 2 2 2 4 23.4% 1450 M261 0 3
20 0 10 2 2 2 4 0 21.5% 1500 M262 0 3 20 0 10 2 2 2 4 2 22.9% 1500
M263 0 3 20 0 10 2 2 2 4 4 24.4% 1500 M264 0 3 20 0 10 2 2 4 0 0
21.8% 1350 M265 0 3 20 0 10 2 2 4 0 2 23.2% 1350 M266 0 3 20 0 10 2
2 4 0 4 24.6% 1350 M267 0 3 20 0 10 2 2 4 2 0 22.7% 1450 M268 0 3
20 0 10 2 2 4 2 2 24.2% 1450 M269 0 3 20 0 10 2 2 4 2 4 25.6% 1450
M270 0 3 20 0 10 2 2 4 4 0 23.7% 1500 M271 0 3 20 0 10 2 2 4 4 2
25.1% 1500 M272 0 3 20 0 10 2 2 4 4 4 26.6% 1450 M273 0 3 20 0 10 2
4 0 0 0 19.8% 1400 M274 0 3 20 0 10 2 4 0 0 2 21.2% 1400 M275 0 3
20 0 10 2 4 0 0 4 22.6% 1400 M276 0 3 20 0 10 2 4 0 2 0 20.7% 1450
M277 0 3 20 0 10 2 4 0 2 2 22.1% 1450 M278 0 3 20 0 10 2 4 0 2 4
23.5% 1450 M279 0 3 20 0 10 2 4 0 4 0 21.6% 1500 M280 0 3 20 0 10 2
4 0 4 2 23.0% 1500 M281 0 3 20 0 10 2 4 0 4 4 24.5% 1500 M282 0 3
20 0 10 2 4 2 0 0 21.9% 1400 M283 0 3 20 0 10 2 4 2 0 2 23.3% 1400
M284 0 3 20 0 10 2 4 2 0 4 24.7% 1400 M285 0 3 20 0 10 2 4 2 2 0
22.9% 1450 M286 0 3 20 0 10 2 4 2 2 2 24.3% 1450 M287 0 3 20 0 10 2
4 2 2 4 25.7% 1450 M288 0 3 20 0 10 2 4 2 4 0 23.8% 1500 M289 0 3
20 0 10 2 4 2 4 2 25.2% 1500 M290 0 3 20 0 10 2 4 2 4 4 26.7% 1500
M291 0 3 20 0 10 2 4 4 0 0 24.1% 1400 M292 0 3 20 0 10 2 4 4 0 2
25.5% 1400 M293 0 3 20 0 10 2 4 4 0 4 26.9% 1400 M294 0 3 20 0 10 2
4 4 2 0 25.0% 1450 M295 0 3 20 0 10 2 4 4 2 2 26.4% 1450 M296 0 3
20 0 10 2 4 4 2 4 27.9% 1450 M297 0 3 20 0 10 2 4 4 4 0 26.0% 1500
M298 0 3 20 0 10 2 4 4 4 2 27.4% 1500 M299 0 3 20 0 10 2 4 4 4 4
28.9% 1500 M300 0 3 20 0 10 4 0 0 0 0 16.1% 1350 M301 0 3 20 0 10 4
0 0 0 2 17.5% 1350 M302 0 3 20 0 10 4 0 0 0 4 18.9% 1350 M303 0 3
20 0 10 4 0 0 2 0 17.0% 1400 M304 0 3 20 0 10 4 0 0 2 2 18.4% 1400
M305 0 3 20 0 10 4 0 0 2 4 19.8% 1450 M306 0 3 20 0 10 4 0 0 4 0
17.8% 1500 M307 0 3 20 0 10 4 0 0 4 2 19.3% 1500 M308 0 3 20 0 10 4
0 0 4 4 20.7% 1500 M309 0 3 20 0 10 4 0 2 0 0 18.3% 1350 M310 0 3
20 0 10 4 0 2 0 2 19.7% 1350 M311 0 3 20 0 10 4 0 2 0 4 21.1% 1350
M312 0 3 20 0 10 4 0 2 2 0 19.2% 1400 M313 0 3 20 0 10 4 0 2 2 2
20.6% 1400 M314 0 3 20 0 10 4 0 2 2 4 22.0% 1400 M315 0 3 20 0 10 4
0 2 4 0 20.1% 1450 M316 0 3 20 0 10 4 0 2 4 2 21.5% 1450 M317 0 3
20 0 10 4 0 2 4 4 23.0% 1450 M318 0 3 20 0 10 4 0 4 0 0 20.5% 1350
M319 0 3 20 0 10 4 0 4 0 2 21.9% 1350 M320 0 3 20 0 10 4 0 4 0 4
23.3% 1350 M321 0 3 20 0 10 4 0 4 2 0 21.4% 1400 M322 0 3 20 0 10 4
0 4 2 2 22.8% 1400 M323 0 3 20 0 10 4 0 4 2 4 24.3% 1400 M324 0 3
20 0 10 4 0 4 4 0 22.3% 1450 M325 0 3 20 0 10 4 0 4 4 2 23.8% 1450
M326 0 3 20 0 10 4 0 4 4 4 25.3% 1450 M327 0 3 20 0 10 4 2 0 0 0
18.4% 1350 M328 0 3 20 0 10 4 2 0 0 2 19.8% 1400 M329 0 3 20 0 10 4
2 0 0 4 21.2% 1400 M330 0 3 20 0 10 4 2 0 2 0 19.3% 1450 M331 0 3
20 0 10 4 2 0 2 2 20.7% 1450 M332 0 3 20 0 10 4 2 0 2 4 22.2% 1450
M333 0 3 20 0 10 4 2 0 4 0 20.2% 1500 M334 0 3 20 0 10 4 2 0 4 2
21.7% 1500 M335 0 3 20 0 10 4 2 0 4 4 23.1% 1500 M336 0 3 20 0 10 4
2 2 0 0 20.6% 1350 M337 0 3 20 0 10 4 2 2 0 2 22.0% 1350 M338 0 3
20 0 10 4 2 2 0 4 23.4% 1350 M339 0 3 20 0 10 4 2 2 2 0 21.5% 1450
M340 0 3 20 0 10 4 2 2 2 2 22.9% 1450 M341 0 3 20 0 10 4 2 2 2 4
24.4% 1450 M342 0 3 20 0 10 4 2 2 4 0 22.4% 1500 M343 0 3 20 0 10 4
2 2 4 2 23.9% 1500 M344 0 3 20 0 10 4 2 2 4 4 25.4% 1500 M345 0 3
20 0 10 4 2 4 0 0 22.7% 1350 M346 0 3 20 0 10 4 2 4 0 2 24.2% 1350
M347 0 3 20 0 10 4 2 4 0 4 25.6% 1350 M348 0 3 20 0 10 4 2 4 2 0
23.7% 1450 M349 0 3 20 0 10 4 2 4 2 2 25.1% 1450 M350 0 3 20 0 10 4
2 4 2 4 26.6% 1450 M351 0 3 20 0 10 4 2 4 4 0 24.7% 1500 M352 0 3
20 0 10 4 2 4 4 2 26.1% 1500 M353 0 3 20 0 10 4 2 4 4 4 27.6% 1450
M354 0 3 20 0 10 4 4 0 0 0 20.7% 1400 M355 0 3 20 0 10 4 4 0 0 2
22.1% 1400 M356 0 3 20 0 10 4 4 0 0 4 23.5% 1400 M357 0 3 20 0 10 4
4 0 2 0 21.6% 1500 M358 0 3 20 0 10 4 4 0 2 2 23.0% 1500 M359 0 3
20 0 10 4 4 0 2 4 24.5% 1450 M360 0 3 20 0 10 4 4 0 4 2 24.0% 1500
M361 0 3 20 0 10 4 4 0 4 4 25.5% 1500 M362 0 3 20 0 10 4 4 2 0 0
22.9% 1400 M363 0 3 20 0 10 4 4 2 0 2 24.3% 1400 M364 0 3 20 0 10 4
4 2 0 4 25.7% 1400 M365 0 3 20 0 10 4 4 2 2 0 23.8% 1450 M366 0 3
20 0 10 4 4 2 2 2 25.2% 1450 M367 0 3 20 0 10 4 4 2 2 4 26.7% 1450
M368 0 3 20 0 10 4 4 2 4 0 24.8% 1500 M369 0 3 20 0 10 4 4 2 4 2
26.2% 1500 M370 0 3 20 0 10 4 4 2 4 4 27.7% 1500 M371 0 3 20 0 10 4
4 4 0 0 25.0% 1400 M372 0 3 20 0 10 4 4 4 0 2 26.4% 1400 M373 0 3
20 0 10 4 4 4 0 4 27.9% 1400 M374 0 3 20 0 10 4 4 4 2 0 26.0% 1450
M375 0 3 20 0 10 4 4 4 2 2 27.4% 1450 M376 0 3 20 0 10 4 4 4 2 4
28.9% 1450 M377 0 3 20 0 10 4 4 4 4 0 27.0% 1500 M378 0 3 20 0 10 4
4 4 4 2 28.5% 1500 M379 0 3 20 0 7 0 0 0 0 0 14.9% 1500 M380 0 3 20
0 9 0 0 0 0 0 14.6% 1450 M381 0 3 20 0 11 0 0 0 0 0 14.3% 1400 M382
0 3 20 0 13 0 0 0 0 0 14.1% 1400 M383 0 3 20 0 15 0 0 0 0 0 13.8%
1450 M384 0 3 20 1 7 0 0 0 0 0 15.6% 1450 M385 0 3 20 1 9 0 0 0 0 0
15.3% 1500 M386 0 3 20 1 11 0 0 0 0 0 15.0% 1500 M387 0 3 20 2 5 0
0 0 0 0 16.6% 1500 M388 0 0 11 0 10 0 0 0 0 0 6.1% 1500 M389 0 0 13
0 10 0 0 0 0 0 7.2% 1500 M390 0 0 15 0 9 0 0 0 0 0 8.5% 1500 M391 0
0 15 0 10 0 0 0 0 0 8.4% 1500 M392 0 0 17 0 8 0 0 0 0 0 9.8% 1500
M393 0 0 17 0 9 0 0 0 0 0 9.7% 1500 M394 0 0 17 0 10 0 0 0 0 0 9.6%
1450 M395 0 0 19 0 8 0 0 0 0 0 11.1% 1500 M396 0 0 19 0 9 0 0 0 0 0
11.0% 1500 M397 0 0 19 0 10 0 0 0 0 0 10.8% 1450 M398 0 0 21 0 7 0
0 0 0 0 12.5% 1500 M399 0 0 21 0 8 0 0 0 0 0 12.3% 1500 M400 0 0 21
0 9 0 0 0 0 0 12.2% 1450 M401 0 0 21 0 10 0 0 0 0 0 12.1% 1450 M402
0 0 23 0 7 0 0 0 0 0 13.8% 1500 M403 0 0 23 0 8 0 0 0 0 0 13.6%
1450 M404 0 0 23 0 9 0 0 0 0 0 13.5% 1450 M405 0 0 23 0 10 0 0 0 0
0 13.3% 1400 M406 0 0 25 0 6 0 0 0 0 0 15.2% 1500 M407 0 0 25 0 7 0
0 0 0 0 15.1% 1500 M408 0 0 25 0 8 0 0 0 0 0 14.9% 1450 M409 0 0 25
0 9 0 0 0 0 0 14.8% 1400 M410 0 0 25 0 10 0 0 0 0 0 14.6% 1400 M411
0 0 27 0 6 0 0 0 0 0 16.6% 1500 M412 0 0 27 0 7 0 0 0 0 0 16.4%
1450 M413 0 0 27 0 8 0 0 0 0 0 16.3% 1450 M414 0 0 27 0 9 0 0 0 0 0
16.1% 1400 M415 0 0 27 0 10 0 0 0 0 0 15.9% 1400 M416 0 0 29 0 5 0
0 0 0 0 18.2% 1500 M417 0 0 29 0 6 0 0 0 0 0 18.0% 1500 M418 0 0 29
0 7 0 0 0 0 0 17.8% 1450 M419 0 0 29 0 8 0 0 0 0 0 17.6% 1400 M420
0 0 29 0 9 0 0 0 0 0 17.4% 1400 M421 0 0 29 0 10 0 0 0 0 0 17.3%
1400 M422 0 1 11 0 10 0 0 0 0 0 7.0% 1500 M423 0 1 13 0 9 0 0 0 0 0
8.3% 1500 M424 0 1 13 0 10 0 0 0 0 0 8.2% 1500 M425 0 1 15 0 9 0 0
0 0 0 9.5% 1500 M426 0 1 15 0 10 0 0 0 0 0 9.4% 1500 M427 0 1 17 0
8 0 0 0 0 0 10.8% 1500 M428 0 1 17 0 9 0 0 0 0 0 10.7% 1500 M429 0
1 17 0 10 0 0 0 0 0 10.6% 1450 M430 0 1 19 0 7 0 0 0 0 0 12.2% 1500
M431 0 1 19 0 8 0 0 0 0 0 12.1% 1500 M432 0 1 19 0 9 0 0 0 0 0
12.0% 1450 M433 0 1 19 0 10 0 0 0 0 0 11.8% 1450 M434 0 1 21 0 7 0
0 0 0 0 13.5% 1500 M435 0 1 21 0 8 0 0 0 0 0 13.4% 1450 M436 0 1 21
0 9 0 0 0 0 0 13.2% 1450 M437 0 1 21 0 10 0 0 0 0 0 13.1% 1400 M438
0 1 23 0 6 0 0 0 0 0 14.9% 1500 M439 0 1 23 0 7 0 0 0 0 0 14.8%
1500 M440 0 1 23 0 8 0 0 0 0 0 14.6% 1450 M441 0 1 23 0 9 0 0 0 0 0
14.5% 1450 M442 0 1 23 0 10 0 0 0 0 0 14.4% 1400 M443 0 1 25 0 6 0
0 0 0 0 16.3% 1500 M444 0 1 25 0 7 0 0 0 0 0 16.1% 1450 M445 0 1 25
0 8 0 0 0 0 0 16.0% 1450 M446 0 1 25 0 9 0 0 0 0 0 15.8% 1400 M447
0 1 25 0 10 0 0 0 0 0 15.7% 1400 M448 0 1 27 0 5 0 0 0 0 0 17.9%
1500 M449 0 1 27 0 6 0 0 0 0 0 17.7% 1500 M450 0 1 27 0 7 0 0 0 0 0
17.5% 1450 M451 0 1 27 0 8 0 0 0 0 0 17.3% 1400 M452 0 1 27 0 9 0 0
0 0 0 17.1% 1400 M453 0 1 27 0 10 0 0 0 0 0 17.0% 1400 M454 0 1 29
0 5 0 0 0 0 0 19.3% 1500 M455 0 1 29 0 6 0 0 0 0 0 19.1% 1450 M456
0 1 29 0 7 0 0 0 0 0 18.9% 1450 M457 0 1 29 0 8 0 0 0 0 0 18.7%
1400 M458 0 1 29 0 9 0 0 0 0 0 18.5% 1400 M459 0 1 29 0 10 0 0 0 0
0 18.3% 1400 M460 0 2 9 0 10 0 0 0 0 0 6.8% 1500 M461 0 2 11 0 9 0
0 0 0 0 8.1% 1500 M462 0 2 11 0 10 0 0 0 0 0 8.0% 1500 M463 0 2 13
0 9 0 0 0 0 0 9.3% 1500 M464 0 2 13 0 10 0 0 0 0 0 9.2% 1500 M465 0
2 15 0 8 0 0 0 0 0 10.6% 1500 M466 0 2 15 0 9 0 0 0 0 0 10.5% 1500
M467 0 2 15 0 10 0 0 0 0 0 10.4% 1450 M468 0 2 17 0 7 0 0 0 0 0
11.9% 1500 M469 0 2 17 0 8 0 0 0 0 0 11.8% 1500 M470 0 2 17 0 9 0 0
0 0 0 11.7% 1450 M471 0 2 17 0 10 0 0 0 0 0 11.6% 1450 M472 0 2 19
0 7 0 0 0 0 0 13.2% 1500 M473 0 2 19 0 8 0 0 0 0 0 13.1% 1500 M474
0 2 19 0 9 0 0 0 0 0 13.0% 1450 M475 0 2 19 0 10 0 0 0 0 0 12.8%
1450 M476 0 2 21 0 6 0 0 0 0 0 14.7% 1500 M477 0 2 21 0 7 0 0 0 0 0
14.5% 1500 M478 0 2 21 0 8 0 0 0 0 0 14.4% 1450 M479 0 2 21 0 9 0 0
0 0 0 14.2% 1450 M480 0 2 21 0 10 0 0 0 0 0 14.1% 1400 M481 0 2 23
0 6 0 0 0 0 0 16.0% 1500 M482 0 2 23 0 7 0 0 0 0 0 15.8% 1450 M483
0 2 23 0 8 0 0 0 0 0 15.7% 1450 M484 0 2 23 0 9 0 0 0 0 0 15.5%
1400 M485 0 2 23 0 10 0 0 0 0 0 15.4% 1400 M486 0 2 25 0 5 0 0 0 0
0 17.5% 1500 M487 0 2 25 0 6 0 0 0 0 0 17.4% 1500 M488 0 2 25 0 7 0
0 0 0 0 17.2% 1450 M489 0 2 25 0 8 0 0 0 0 0 17.0% 1400 M490 0 2 25
0 9 0 0 0 0 0 16.8% 1400 M491 0 2 25 0 10 0 0 0 0 0 16.7% 1350 M492
0 2 27 0 5 0 0 0 0 0 18.9% 1500
M493 0 2 27 0 6 0 0 0 0 0 18.7% 1450 M494 0 2 27 0 7 0 0 0 0 0
18.6% 1450 M495 0 2 27 0 8 0 0 0 0 0 18.4% 1400 M496 0 2 27 0 9 0 0
0 0 0 18.2% 1400 M497 0 2 27 0 10 0 0 0 0 0 18.0% 1400 M498 0 2 29
0 5 0 0 0 0 0 20.4% 1500 M499 0 2 29 0 6 0 0 0 0 0 20.2% 1450 M500
0 2 29 0 7 0 0 0 0 0 19.9% 1400 M501 0 2 29 0 8 0 0 0 0 0 19.7%
1400 M502 0 2 29 0 9 0 0 0 0 0 19.5% 1400 M503 0 2 29 0 10 0 0 0 0
0 19.3% 1400 M504 0 3 7 0 10 0 0 0 0 0 6.7% 1500 M505 0 3 9 0 10 0
0 0 0 0 7.8% 1500 M506 0 3 11 0 9 0 0 0 0 0 9.1% 1500 M507 0 3 11 0
10 0 0 0 0 0 9.0% 1500 M508 0 3 13 0 8 0 0 0 0 0 10.4% 1500 M509 0
3 13 0 9 0 0 0 0 0 10.3% 1500 M510 0 3 13 0 10 0 0 0 0 0 10.2% 1450
M511 0 3 15 0 8 0 0 0 0 0 11.6% 1500 M512 0 3 15 0 9 0 0 0 0 0
11.5% 1500 M513 0 3 15 0 10 0 0 0 0 0 11.4% 1450 M514 0 3 17 0 7 0
0 0 0 0 13.0% 1500 M515 0 3 17 0 8 0 0 0 0 0 12.8% 1500 M516 0 3 17
0 9 0 0 0 0 0 12.7% 1450 M517 0 3 17 0 10 0 0 0 0 0 12.6% 1450 M518
0 3 19 0 6 0 0 0 0 0 14.4% 1500 M519 0 3 19 0 7 0 0 0 0 0 14.2%
1500 M520 0 3 19 0 8 0 0 0 0 0 14.1% 1450 M521 0 3 19 0 9 0 0 0 0 0
14.0% 1450 M522 0 3 19 0 10 0 0 0 0 0 13.8% 1400 M523 0 3 21 0 6 0
0 0 0 0 15.7% 1500 M524 0 3 21 0 7 0 0 0 0 0 15.6% 1500 M525 0 3 21
0 8 0 0 0 0 0 15.4% 1450 M526 0 3 21 0 9 0 0 0 0 0 15.2% 1400 M527
0 3 21 0 10 0 0 0 0 0 15.1% 1400 M528 0 3 23 0 5 0 0 0 0 0 17.2%
1500 M529 0 3 23 0 6 0 0 0 0 0 17.1% 1500 M530 0 3 23 0 7 0 0 0 0 0
16.9% 1450 M531 0 3 23 0 8 0 0 0 0 0 16.7% 1450 M532 0 3 23 0 9 0 0
0 0 0 16.5% 1400 M533 0 3 23 0 10 0 0 0 0 0 16.4% 1400 M534 0 3 25
0 5 0 0 0 0 0 18.6% 1500 M535 0 3 25 0 6 0 0 0 0 0 18.4% 1450 M536
0 3 25 0 7 0 0 0 0 0 18.2% 1450 M537 0 3 25 0 8 0 0 0 0 0 18.0%
1400 M538 0 3 25 0 9 0 0 0 0 0 17.9% 1400 M539 0 3 25 0 10 0 0 0 0
0 17.7% 1350 M540 0 3 27 0 5 0 0 0 0 0 20.0% 1500 M541 0 3 27 0 6 0
0 0 0 0 19.8% 1450 M542 0 3 27 0 7 0 0 0 0 0 19.6% 1400 M543 0 3 27
0 8 0 0 0 0 0 19.4% 1400 M544 0 3 27 0 9 0 0 0 0 0 19.2% 1350 M545
0 3 27 0 10 0 0 0 0 0 19.0% 1400 M546 0 3 29 0 4 0 0 0 0 0 21.7%
1500 M547 0 3 29 0 5 0 0 0 0 0 21.5% 1500 M548 0 3 29 0 6 0 0 0 0 0
21.2% 1450 M549 0 3 29 0 7 0 0 0 0 0 21.0% 1400 M550 0 3 29 0 8 0 0
0 0 0 20.8% 1400 M551 0 3 29 0 9 0 0 0 0 0 20.6% 1400 M552 0 3 29 0
10 0 0 0 0 0 20.4% 1400 M553 0 4 7 0 10 0 0 0 0 0 7.6% 1500 M554 0
4 9 0 9 0 0 0 0 0 8.8% 1500 M555 0 4 9 0 10 0 0 0 0 0 8.8% 1500
M556 0 4 11 0 9 0 0 0 0 0 10.0% 1500 M557 0 4 11 0 10 0 0 0 0 0
9.9% 1500 M558 0 4 13 0 8 0 0 0 0 0 11.3% 1500 M559 0 4 13 0 9 0 0
0 0 0 11.2% 1500 M560 0 4 13 0 10 0 0 0 0 0 11.1% 1450 M561 0 4 15
0 7 0 0 0 0 0 12.7% 1500 M562 0 4 15 0 8 0 0 0 0 0 12.6% 1500 M563
0 4 15 0 9 0 0 0 0 0 12.5% 1450 M564 0 4 15 0 10 0 0 0 0 0 12.3%
1450 M565 0 4 17 0 7 0 0 0 0 0 14.0% 1500 M566 0 4 17 0 8 0 0 0 0 0
13.8% 1450 M567 0 4 17 0 9 0 0 0 0 0 13.7% 1450 M568 0 4 17 0 10 0
0 0 0 0 13.6% 1400 M569 0 4 19 0 6 0 0 0 0 0 15.4% 1500 M570 0 4 19
0 7 0 0 0 0 0 15.3% 1500 M571 0 4 19 0 8 0 0 0 0 0 15.1% 1450 M572
0 4 19 0 9 0 0 0 0 0 15.0% 1450 M573 0 4 19 0 10 0 0 0 0 0 14.8%
1400 M574 0 4 21 0 6 0 0 0 0 0 16.8% 1500 M575 0 4 21 0 7 0 0 0 0 0
16.6% 1450 M576 0 4 21 0 8 0 0 0 0 0 16.4% 1450 M577 0 4 21 0 9 0 0
0 0 0 16.3% 1400 M578 0 4 21 0 10 0 0 0 0 0 16.1% 1400 M579 0 4 23
0 5 0 0 0 0 0 18.3% 1500 M580 0 4 23 0 6 0 0 0 0 0 18.1% 1500 M581
0 4 23 0 7 0 0 0 0 0 17.9% 1450 M582 0 4 23 0 8 0 0 0 0 0 17.7%
1400 M583 0 4 23 0 9 0 0 0 0 0 17.6% 1400 M584 0 4 23 0 10 0 0 0 0
0 17.4% 1350 M585 0 4 25 0 5 0 0 0 0 0 19.7% 1500 M586 0 4 25 0 6 0
0 0 0 0 19.5% 1450 M587 0 4 25 0 7 0 0 0 0 0 19.3% 1450 M588 0 4 25
0 8 0 0 0 0 0 19.1% 1400 M589 0 4 25 0 9 0 0 0 0 0 18.9% 1350 M590
0 4 25 0 10 0 0 0 0 0 18.7% 1350 M591 0 4 27 0 4 0 0 0 0 0 21.3%
1500 M592 0 4 27 0 5 0 0 0 0 0 21.1% 1500 M593 0 4 27 0 6 0 0 0 0 0
20.9% 1450 M594 0 4 27 0 7 0 0 0 0 0 20.7% 1400 M595 0 4 27 0 8 0 0
0 0 0 20.5% 1400 M596 0 4 27 0 9 0 0 0 0 0 20.2% 1350 M597 0 4 27 0
10 0 0 0 0 0 20.0% 1400 M598 0 4 29 0 4 0 0 0 0 0 22.8% 1500 M599 0
4 29 0 5 0 0 0 0 0 22.5% 1450 M600 0 4 29 0 6 0 0 0 0 0 22.3% 1450
M601 0 4 29 0 7 0 0 0 0 0 22.1% 1400 M602 0 4 29 0 8 0 0 0 0 0
21.8% 1400 M603 0 4 29 0 9 0 0 0 0 0 21.6% 1400 M604 0 4 29 0 10 0
0 0 0 0 21.4% 1400 M605 0 5 5 0 10 0 0 0 0 0 7.4% 1500 M606 0 5 7 0
10 0 0 0 0 0 8.6% 1500 M607 0 5 9 0 9 0 0 0 0 0 9.8% 1500 M608 0 5
9 0 10 0 0 0 0 0 9.7% 1500 M609 0 5 11 0 8 0 0 0 0 0 11.1% 1500
M610 0 5 11 0 9 0 0 0 0 0 11.0% 1500 M611 0 5 11 0 10 0 0 0 0 0
10.9% 1450 M612 0 5 13 0 7 0 0 0 0 0 12.5% 1500 M613 0 5 13 0 8 0 0
0 0 0 12.3% 1500 M614 0 5 13 0 9 0 0 0 0 0 12.2% 1450 M615 0 5 13 0
10 0 0 0 0 0 12.1% 1450 M616 0 5 15 0 7 0 0 0 0 0 13.7% 1500 M617 0
5 15 0 8 0 0 0 0 0 13.6% 1500 M618 0 5 15 0 9 0 0 0 0 0 13.4% 1450
M619 0 5 15 0 10 0 0 0 0 0 13.3% 1450 M620 0 5 17 0 6 0 0 0 0 0
15.1% 1500 M621 0 5 17 0 7 0 0 0 0 0 15.0% 1500 M622 0 5 17 0 8 0 0
0 0 0 14.8% 1450 M623 0 5 17 0 9 0 0 0 0 0 14.7% 1450 M624 0 5 17 0
10 0 0 0 0 0 14.6% 1400 M625 0 5 19 0 6 0 0 0 0 0 16.5% 1500 M626 0
5 19 0 7 0 0 0 0 0 16.3% 1450 M627 0 5 19 0 8 0 0 0 0 0 16.1% 1450
M628 0 5 19 0 9 0 0 0 0 0 16.0% 1400 M629 0 5 19 0 10 0 0 0 0 0
15.8% 1400 M630 0 5 21 0 5 0 0 0 0 0 18.0% 1500 M631 0 5 21 0 6 0 0
0 0 0 17.8% 1500 M632 0 5 21 0 7 0 0 0 0 0 17.6% 1450 M633 0 5 21 0
8 0 0 0 0 0 17.4% 1450 M634 0 5 21 0 9 0 0 0 0 0 17.3% 1400 M635 0
5 21 0 10 0 0 0 0 0 17.1% 1400 M636 0 5 23 0 5 0 0 0 0 0 19.4% 1500
M637 0 5 23 0 6 0 0 0 0 0 19.2% 1450 M638 0 5 23 0 7 0 0 0 0 0
19.0% 1450 M639 0 5 23 0 8 0 0 0 0 0 18.8% 1400 M640 0 5 23 0 9 0 0
0 0 0 18.6% 1400 M641 0 5 23 0 10 0 0 0 0 0 18.4% 1350 M642 0 5 25
0 4 0 0 0 0 0 21.0% 1500 M643 0 5 25 0 5 0 0 0 0 0 20.8% 1500 M644
0 5 25 0 6 0 0 0 0 0 20.5% 1450 M645 0 5 25 0 7 0 0 0 0 0 20.3%
1400 M646 0 5 25 0 8 0 0 0 0 0 20.1% 1400 M647 0 5 25 0 9 0 0 0 0 0
19.9% 1350 M648 0 5 25 0 10 0 0 0 0 0 19.7% 1350 M649 0 5 27 0 4 0
0 0 0 0 22.4% 1500 M650 0 5 27 0 5 0 0 0 0 0 22.2% 1450 M651 0 5 27
0 6 0 0 0 0 0 22.0% 1450 M652 0 5 27 0 7 0 0 0 0 0 21.7% 1400 M653
0 5 27 0 8 0 0 0 0 0 21.5% 1350 M654 0 5 27 0 9 0 0 0 0 0 21.3%
1350 M655 0 5 27 0 10 0 0 0 0 0 21.1% 1400 M656 0 5 29 0 4 0 0 0 0
0 23.9% 1500 M657 0 5 29 0 5 0 0 0 0 0 23.6% 1450 M658 0 5 29 0 6 0
0 0 0 0 23.4% 1400 M659 0 5 29 0 7 0 0 0 0 0 23.1% 1400 M660 0 5 29
0 8 0 0 0 0 0 22.9% 1400 M661 0 5 29 0 9 0 0 0 0 0 22.7% 1400 M662
0 5 29 0 10 0 0 0 0 0 22.4% 1400 M663 0 5 5 0 10 1 1 1 1 1 10.8%
1450 M664 0 5 5 0 10 0 0 0 1 0 7.7% 1500 M665 0 5 5 0 10 0 0 0 2 0
8.1% 1500 M666 0 5 5 0 10 0 0 0 3 0 8.4% 1500 M667 0 5 5 0 10 0 0 0
4 0 8.8% 1500 M668 0 5 5 0 10 0 0 1 0 0 8.4% 1500 M669 0 5 5 0 10 0
0 1 1 0 8.8% 1500 M670 0 5 5 0 10 0 0 1 2 0 9.1% 1500 M671 0 5 5 0
10 0 0 1 3 0 9.4% 1500 M672 0 5 5 0 10 0 0 1 4 0 9.8% 1500 M673 0 5
5 0 10 0 0 2 0 0 9.4% 1500 M674 0 5 5 0 10 0 0 2 1 0 9.8% 1500 M675
0 5 5 0 10 0 0 2 2 0 10.1% 1500 M676 0 5 5 0 10 0 0 2 3 0 10.5%
1500 M677 0 5 5 0 10 0 0 2 4 0 10.8% 1500 M678 0 5 5 0 10 0 0 3 0 0
10.4% 1500 M679 0 5 5 0 10 0 0 3 1 0 10.8% 1500 M680 0 5 5 0 10 0 0
3 2 0 11.1% 1500 M681 0 5 5 0 10 0 0 3 3 0 11.5% 1500 M682 0 5 5 0
10 0 0 3 4 0 11.9% 1500 M683 0 5 5 0 10 0 0 4 0 0 11.4% 1500 M684 0
5 5 0 10 0 0 4 1 0 11.8% 1500 M685 0 5 5 0 10 0 0 4 2 0 12.2% 1500
M686 0 5 5 0 10 0 0 4 3 0 12.5% 1500 M687 0 5 5 0 10 0 0 4 4 0
12.9% 1500 M688 0 5 5 0 10 0 1 0 0 0 8.5% 1500 M689 0 5 5 0 10 0 1
0 1 0 8.8% 1500 M690 0 5 5 0 10 0 1 0 2 0 9.2% 1500 M691 0 5 5 0 10
0 1 0 3 0 9.5% 1500 M692 0 5 5 0 10 0 1 0 4 0 9.9% 1500 M693 0 5 5
0 10 0 1 1 0 0 9.5% 1500 M694 0 5 5 0 10 0 1 1 1 0 9.8% 1500 M695 0
5 5 0 10 0 1 1 2 0 10.2% 1500 M696 0 5 5 0 10 0 1 1 3 0 10.5% 1500
M697 0 5 5 0 10 0 1 1 4 0 10.9% 1500 M698 0 5 5 0 10 0 1 2 0 0
10.5% 1500 M699 0 5 5 0 10 0 1 2 1 0 10.8% 1500 M700 0 5 5 0 10 0 1
2 2 0 11.2% 1500 M701 0 5 5 0 10 0 1 2 3 0 11.6% 1500 M702 0 5 5 0
10 0 1 2 4 0 11.9% 1500 M703 0 5 5 0 10 0 1 3 0 0 11.5% 1500 M704 0
5 5 0 10 0 1 3 1 0 11.8% 1500 M705 0 5 5 0 10 0 1 3 2 0 12.2% 1500
M706 0 5 5 0 10 0 1 3 3 0 12.6% 1500 M707 0 5 5 0 10 0 1 3 4 0
12.9% 1450 M708 0 5 5 0 10 0 1 4 0 0 12.5% 1500 M709 0 5 5 0 10 0 1
4 1 0 12.9% 1500 M710 0 5 5 0 10 0 1 4 2 0 13.2% 1500 M711 0 5 5 0
10 0 1 4 3 0 13.6% 1500 M712 0 5 5 0 10 0 1 4 4 0 14.0% 1450 M713 0
5 5 0 10 0 2 0 0 0 9.5% 1500 M714 0 5 5 0 10 0 2 0 1 0 9.9% 1500
M715 0 5 5 0 10 0 2 0 2 0 10.2% 1500 M716 0 5 5 0 10 0 2 0 3 0
10.6% 1450 M717 0 5 5 0 10 0 2 0 4 0 10.9% 1450 M718 0 5 5 0 10 0 2
1 0 0 10.5% 1500 M719 0 5 5 0 10 0 2 1 1 0 10.9% 1500 M720 0 5 5 0
10 0 2 1 2 0 11.3% 1500 M721 0 5 5 0 10 0 2 1 3 0 11.6% 1450 M722 0
5 5 0 10 0 2 1 4 0 12.0% 1450 M723 0 5 5 0 10 0 2 2 0 0 11.5% 1500
M724 0 5 5 0 10 0 2 2 1 0 11.9% 1500 M725 0 5 5 0 10 0 2 2 2 0
12.3% 1500 M726 0 5 5 0 10 0 2 2 3 0 12.6% 1450 M727 0 5 5 0 10 0 2
2 4 0 13.0% 1450 M728 0 5 5 0 10 0 2 3 0 0 12.5% 1500 M729 0 5 5 0
10 0 2 3 1 0 12.9% 1500 M730 0 5 5 0 10 0 2 3 2 0 13.3% 1450 M731 0
5 5 0 10 0 2 3 3 0 13.7% 1450 M732 0 5 5 0 10 0 2 3 4 0 14.0% 1450
M733 0 5 5 0 10 0 2 4 0 0 13.5% 1500 M734 0 5 5 0 10 0 2 4 1 0
13.9% 1500 M735 0 5 5 0 10 0 2 4 2 0 14.3% 1450 M736 0 5 5 0 10 0 2
4 3 0 14.7% 1450 M737 0 5 5 0 10 0 2 4 4 0 15.1% 1450 M738 0 5 5 0
10 0 3 0 0 0 10.6% 1500 M739 0 5 5 0 10 0 3 0 1 0 11.0% 1450 M740 0
5 5 0 10 0 3 0 2 0 11.3% 1450 M741 0 5 5 0 10 0 3 0 3 0 11.7% 1450
M742 0 5 5 0 10 0 3 0 4 0 12.0% 1450 M743 0 5 5 0 10 0 3 1 0 0
11.6% 1500
M744 0 5 5 0 10 0 3 1 1 0 12.0% 1450 M745 0 5 5 0 10 0 3 1 2 0
12.3% 1450 M746 0 5 5 0 10 0 3 1 3 0 12.7% 1450 M747 0 5 5 0 10 0 3
1 4 0 13.1% 1450 M748 0 5 5 0 10 0 3 2 0 0 12.6% 1450 M749 0 5 5 0
10 0 3 2 1 0 13.0% 1450 M750 0 5 5 0 10 0 3 2 2 0 13.3% 1450 M751 0
5 5 0 10 0 3 2 3 0 13.7% 1450 M752 0 5 5 0 10 0 3 2 4 0 14.1% 1450
M753 0 5 5 0 10 0 3 3 0 0 13.6% 1450 M754 0 5 5 0 10 0 3 3 1 0
14.0% 1450 M755 0 5 5 0 10 0 3 3 2 0 14.3% 1450 M756 0 5 5 0 10 0 3
3 3 0 14.7% 1450 M757 0 5 5 0 10 0 3 3 4 0 15.1% 1450 M758 0 5 5 0
10 0 3 4 0 0 14.6% 1450 M759 0 5 5 0 10 0 3 4 1 0 15.0% 1450 M760 0
5 5 0 10 0 3 4 2 0 15.4% 1450 M761 0 5 5 0 10 0 3 4 3 0 15.7% 1450
M762 0 5 5 0 10 0 3 4 4 0 16.1% 1450 M763 0 5 5 0 10 0 4 0 0 0
11.7% 1450 M764 0 5 5 0 10 0 4 0 1 0 12.0% 1450 M765 0 5 5 0 10 0 4
0 2 0 12.4% 1450 M766 0 5 5 0 10 0 4 0 3 0 12.7% 1450 M767 0 5 5 0
10 0 4 0 4 0 13.1% 1450 M768 0 5 5 0 10 0 4 1 0 0 12.7% 1450 M769 0
5 5 0 10 0 4 1 1 0 13.0% 1450 M770 0 5 5 0 10 0 4 1 2 0 13.4% 1450
M771 0 5 5 0 10 0 4 1 3 0 13.8% 1450 M772 0 5 5 0 10 0 4 1 4 0
14.1% 1450 M773 0 5 5 0 10 0 4 2 0 0 13.7% 1450 M774 0 5 5 0 10 0 4
2 1 0 14.0% 1450 M775 0 5 5 0 10 0 4 2 2 0 14.4% 1450 M776 0 5 5 0
10 0 4 2 3 0 14.8% 1450 M777 0 5 5 0 10 0 4 2 4 0 15.2% 1450 M778 0
5 5 0 10 0 4 3 0 0 14.7% 1450 M779 0 5 5 0 10 0 4 3 1 0 15.0% 1450
M780 0 5 5 0 10 0 4 3 2 0 15.4% 1450 M781 0 5 5 0 10 0 4 3 3 0
15.8% 1450 M782 0 5 5 0 10 0 4 3 4 0 16.2% 1450 M783 0 5 5 0 10 0 4
4 0 0 15.6% 1450 M784 0 5 5 0 10 0 4 4 1 0 16.0% 1450 M785 0 5 5 0
10 0 4 4 2 0 16.4% 1450 M786 0 5 5 0 10 0 4 4 3 0 16.8% 1450 M787 0
5 5 0 10 0 4 4 4 0 17.2% 1450 M788 0 5 7 0 10 0 0 0 1 0 8.9% 1500
M789 0 5 7 0 10 0 0 0 2 0 9.2% 1500 M790 0 5 7 0 10 0 0 0 3 0 9.6%
1500 M791 0 5 7 0 10 0 0 0 4 0 9.9% 1500 M792 0 5 7 0 10 0 0 1 0 0
9.6% 1500 M793 0 5 7 0 10 0 0 1 1 0 9.9% 1500 M794 0 5 7 0 10 0 0 1
2 0 10.3% 1500 M795 0 5 7 0 10 0 0 1 3 0 10.6% 1500 M796 0 5 7 0 10
0 0 1 4 0 11.0% 1500 M797 0 5 7 0 10 0 0 2 0 0 10.6% 1500 M798 0 5
7 0 10 0 0 2 1 0 10.9% 1500 M799 0 5 7 0 10 0 0 2 2 0 11.3% 1500
M800 0 5 7 0 10 0 0 2 3 0 11.7% 1500 M801 0 5 7 0 10 0 0 2 4 0
12.0% 1450 M802 0 5 7 0 10 0 0 3 0 0 11.6% 1500 M803 0 5 7 0 10 0 0
3 1 0 12.0% 1500 M804 0 5 7 0 10 0 0 3 2 0 12.3% 1500 M805 0 5 7 0
10 0 0 3 3 0 12.7% 1500 M806 0 5 7 0 10 0 0 3 4 0 13.1% 1450 M807 0
5 7 0 10 0 0 4 0 0 12.6% 1500 M808 0 5 7 0 10 0 0 4 1 0 13.0% 1500
M809 0 5 7 0 10 0 0 4 2 0 13.3% 1500 M810 0 5 7 0 10 0 0 4 3 0
13.7% 1450 M811 0 5 7 0 10 0 0 4 4 0 14.1% 1450 M812 0 5 7 0 10 0 1
0 0 0 9.6% 1500 M813 0 5 7 0 10 0 1 0 1 0 10.0% 1500 M814 0 5 7 0
10 0 1 0 2 0 10.3% 1500 M815 0 5 7 0 10 0 1 0 3 0 10.7% 1450 M816 0
5 7 0 10 0 1 0 4 0 11.0% 1450 M817 0 5 7 0 10 0 1 1 0 0 10.6% 1500
M818 0 5 7 0 10 0 1 1 1 0 11.0% 1500 M819 0 5 7 0 10 0 1 1 2 0
11.4% 1450 M820 0 5 7 0 10 0 1 1 3 0 11.7% 1450 M821 0 5 7 0 10 0 1
1 4 0 12.1% 1450 M822 0 5 7 0 10 0 1 2 0 0 11.7% 1500 M823 0 5 7 0
10 0 1 2 1 0 12.0% 1500 M824 0 5 7 0 10 0 1 2 2 0 12.4% 1450 M825 0
5 7 0 10 0 1 2 3 0 12.7% 1450 M826 0 5 7 0 10 0 1 2 4 0 13.1% 1450
M827 0 5 7 0 10 0 1 3 0 0 12.7% 1500 M828 0 5 7 0 10 0 1 3 1 0
13.0% 1500 M829 0 5 7 0 10 0 1 3 2 0 13.4% 1450 M830 0 5 7 0 10 0 1
3 3 0 13.8% 1450 M831 0 5 7 0 10 0 1 3 4 0 14.2% 1450 M832 0 5 7 0
10 0 1 4 0 0 13.7% 1500 M833 0 5 7 0 10 0 1 4 1 0 14.0% 1450 M834 0
5 7 0 10 0 1 4 2 0 14.4% 1450 M835 0 5 7 0 10 0 1 4 3 0 14.8% 1450
M836 0 5 7 0 10 0 1 4 4 0 15.2% 1450 M837 0 5 7 0 10 0 2 0 0 0
10.7% 1500 M838 0 5 7 0 10 0 2 0 1 0 11.1% 1450 M839 0 5 7 0 10 0 2
0 2 0 11.4% 1450 M840 0 5 7 0 10 0 2 0 3 0 11.8% 1450 M841 0 5 7 0
10 0 2 0 4 0 12.1% 1450 M842 0 5 7 0 10 0 2 1 0 0 11.7% 1450 M843 0
5 7 0 10 0 2 1 1 0 12.1% 1450 M844 0 5 7 0 10 0 2 1 2 0 12.4% 1450
M845 0 5 7 0 10 0 2 1 3 0 12.8% 1450 M846 0 5 7 0 10 0 2 1 4 0
13.2% 1450 M847 0 5 7 0 10 0 2 2 0 0 12.7% 1450 M848 0 5 7 0 10 0 2
2 1 0 13.1% 1450 M849 0 5 7 0 10 0 2 2 2 0 13.5% 1450 M850 0 5 7 0
10 0 2 2 3 0 13.8% 1450 M851 0 5 7 0 10 0 2 2 4 0 14.2% 1450 M852 0
5 7 0 10 0 2 3 0 0 13.7% 1450 M853 0 5 7 0 10 0 2 3 1 0 14.1% 1450
M854 0 5 7 0 10 0 2 3 2 0 14.5% 1450 M855 0 5 7 0 10 0 2 3 3 0
14.9% 1450 M856 0 5 7 0 10 0 2 3 4 0 15.2% 1450 M857 0 5 7 0 10 0 2
4 0 0 14.7% 1450 M858 0 5 7 0 10 0 2 4 1 0 15.1% 1450 M859 0 5 7 0
10 0 2 4 2 0 15.5% 1450 M860 0 5 7 0 10 0 2 4 3 0 15.9% 1450 M861 0
5 7 0 10 0 2 4 4 0 16.3% 1450 M862 0 5 7 0 10 0 3 0 0 0 11.8% 1450
M863 0 5 7 0 10 0 3 0 1 0 12.1% 1450 M864 0 5 7 0 10 0 3 0 2 0
12.5% 1450 M865 0 5 7 0 10 0 3 0 3 0 12.9% 1450 M866 0 5 7 0 10 0 3
0 4 0 13.2% 1450 M867 0 5 7 0 10 0 3 1 0 0 12.8% 1450 M868 0 5 7 0
10 0 3 1 1 0 13.1% 1450 M869 0 5 7 0 10 0 3 1 2 0 13.5% 1450 M870 0
5 7 0 10 0 3 1 3 0 13.9% 1450 M871 0 5 7 0 10 0 3 1 4 0 14.3% 1450
M872 0 5 7 0 10 0 3 2 0 0 13.8% 1450 M873 0 5 7 0 10 0 3 2 1 0
14.2% 1450 M874 0 5 7 0 10 0 3 2 2 0 14.5% 1450 M875 0 5 7 0 10 0 3
2 3 0 14.9% 1450 M876 0 5 7 0 10 0 3 2 4 0 15.3% 1450 M877 0 5 7 0
10 0 3 3 0 0 14.8% 1450 M878 0 5 7 0 10 0 3 3 1 0 15.2% 1450 M879 0
5 7 0 10 0 3 3 2 0 15.6% 1450 M880 0 5 7 0 10 0 3 3 3 0 15.9% 1450
M881 0 5 7 0 10 0 3 3 4 0 16.3% 1450 M882 0 5 7 0 10 0 3 4 0 0
15.8% 1450 M883 0 5 7 0 10 0 3 4 1 0 16.2% 1450 M884 0 5 7 0 10 0 3
4 2 0 16.6% 1450 M885 0 5 7 0 10 0 3 4 3 0 17.0% 1450 M886 0 5 7 0
10 0 3 4 4 0 17.4% 1450 M887 0 5 7 0 10 0 4 0 0 0 12.8% 1450 M888 0
5 7 0 10 0 4 0 1 0 13.2% 1450 M889 0 5 7 0 10 0 4 0 2 0 13.6% 1450
M890 0 5 7 0 10 0 4 0 3 0 14.0% 1450 M891 0 5 7 0 10 0 4 0 4 0
14.3% 1450 M892 0 5 7 0 10 0 4 1 0 0 13.8% 1450 M893 0 5 7 0 10 0 4
1 1 0 14.2% 1450 M894 0 5 7 0 10 0 4 1 2 0 14.6% 1450 M895 0 5 7 0
10 0 4 1 3 0 15.0% 1450 M896 0 5 7 0 10 0 4 1 4 0 15.4% 1450 M897 0
5 7 0 10 0 4 2 0 0 14.8% 1450 M898 0 5 7 0 10 0 4 2 1 0 15.2% 1450
M899 0 5 7 0 10 0 4 2 2 0 15.6% 1450 M900 0 5 7 0 10 0 4 2 3 0
16.0% 1450 M901 0 5 7 0 10 0 4 2 4 0 16.4% 1450 M902 0 5 7 0 10 0 4
3 0 0 15.8% 1450 M903 0 5 7 0 10 0 4 3 1 0 16.2% 1450 M904 0 5 7 0
10 0 4 3 2 0 16.6% 1450 M905 0 5 7 0 10 0 4 3 3 0 17.0% 1400 M906 0
5 7 0 10 0 4 3 4 0 17.4% 1450 M907 0 5 7 0 10 0 4 4 0 0 16.8% 1450
M908 0 5 7 0 10 0 4 4 1 0 17.2% 1450 M909 0 5 7 0 10 0 4 4 2 0
17.6% 1450 M910 0 5 7 0 10 0 4 4 3 0 18.0% 1400 M911 0 5 7 0 10 0 4
4 4 0 18.4% 1450 M912 0 5 9 0 10 0 0 0 1 0 10.1% 1500 M913 0 5 9 0
10 0 0 0 2 0 10.4% 1450 M914 0 5 9 0 10 0 0 0 3 0 10.8% 1450 M915 0
5 9 0 10 0 0 0 4 0 11.2% 1450 M916 0 5 9 0 10 0 0 1 0 0 10.7% 1500
M917 0 5 9 0 10 0 0 1 1 0 11.1% 1500 M918 0 5 9 0 10 0 0 1 2 0
11.5% 1450 M919 0 5 9 0 10 0 0 1 3 0 11.8% 1450 M920 0 5 9 0 10 0 0
1 4 0 12.2% 1450 M921 0 5 9 0 10 0 0 2 0 0 11.8% 1500 M922 0 5 9 0
10 0 0 2 1 0 12.1% 1450 M923 0 5 9 0 10 0 0 2 2 0 12.5% 1450 M924 0
5 9 0 10 0 0 2 3 0 12.9% 1450 M925 0 5 9 0 10 0 0 2 4 0 13.2% 1450
M926 0 5 9 0 10 0 0 3 0 0 12.8% 1500 M927 0 5 9 0 10 0 0 3 1 0
13.2% 1450 M928 0 5 9 0 10 0 0 3 2 0 13.5% 1450 M929 0 5 9 0 10 0 0
3 3 0 13.9% 1450 M930 0 5 9 0 10 0 0 3 4 0 14.3% 1450 M931 0 5 9 0
10 0 0 4 0 0 13.8% 1500 M932 0 5 9 0 10 0 0 4 1 0 14.2% 1450
[0068] In some embodiments, the alloy can possess a low FCC-BCC
transition temperature. This criteria can be related to the
likelihood of the alloy to retain an austenitic structure when
deposited and thus be `readable` by certain measuring devices, as
discussed further below. Readable coatings can be non-magnetic and
thus the thickness can be measured with standard paint thickness
gauges. This can be advantageous for many thermal spray
applications.
Performance Criteria:
[0069] In some embodiments, the alloy can be described by
performance criteria. The performance criteria that can be
advantageous to the field of thermal spray hardfacing is the
hardness, wear resistance, coating adhesion, and corrosion
resistance.
[0070] In some embodiments, the Vickers hardness of the coating can
be 400 or above (or about 400 or above). In some embodiments, the
Vickers hardness of the coating can be 500 or above (or about 500
or above). In some embodiments, the Vickers hardness can be 550 or
above (or about 550 or above). In some embodiments, the Vickers
hardness can be 600 or above (or about 600 or above). The specific
microstructure disclosed herein can allow for embodiments of the
alloys to have high hardness.
[0071] In some embodiments, the adhesion strength of the coating
can be 5,000 psi or above (or about 5,000 psi or above). In some
embodiments, the adhesion strength of the coating can be 7,500 psi
or above (or about 7,500 psi or above). In some embodiments, the
adhesion strength of the coating can be 10,000 psi or above (or
about 10,000 psi or above).
[0072] In some embodiments, the abrasion resistance of the coating
as measured via ASTM G65B testing can be 0.8 grams loss or below
(or about 0.8 grams loss or below). In some embodiments, the
abrasion resistance of the coating as measured via ASTM G65B
testing can be 0.6 grams loss or below (or about 0.6 grams loss or
below). In some embodiments, the abrasion resistance of the coating
as measured via ASTM G65B testing can be 0.4 grams loss or below
(or about 0.4 grams loss or below).
[0073] In some embodiments, the adhesive wear resistance of the
coating as measured via ASTM G77 testing, hereby incorporated by
reference in its entirety, can be 2 mm.sup.3 volume loss or below
(or about 2 mm.sup.3 volume loss or below). In some embodiments,
the adhesive wear resistance of the coating as measured via ASTM
G77 testing can be 0.5 mm.sup.3 volume loss or below (or about 0.5
mm.sup.3 volume loss or below). In some embodiments, the adhesive
wear resistance of the coating as measured via ASTM G77 testing can
be 0.1 mm.sup.3 volume loss or below (or about 0.1 mm.sup.3 volume
loss or below).
[0074] In some embodiments, the alloy can exhibit similar
performance to conventional Cr-bearing thermal spray materials used
for hardfacing. The most exemplary and well used thermal spray
hardfacing material possesses a chemical composition of Fe: BAL,
Cr: 29, Si: 1, Mn: 2, B: 4, which is generally referred to in the
industry as Armacor M. Armacor M possesses the following properties
which are relevant to thermal spray hardfacing: adhesion of about
8,000 psi, ASTM G65B mass loss of about 0.37 grams, ASTM G77 volume
loss of about 0.07 mm.sup.3, and position in the galvanic series in
saltwater of about -500 mV. Armacor M is primarily made of Fe, Cr,
and B, has a high melting temperature, and has no large atoms.
[0075] In some embodiments of this disclosure, the alloys can
exhibit similar coating adhesion and abrasive wear resistance as
Armacor, where `similar` equates to within 25% (or within about
25%) of the measured performance properties of Armacor M or better.
In some embodiments of this disclosure, the alloys can exhibit
similar coating adhesion, abrasive wear resistance, and adhesive
wear resistance as Armacor, where `similar` equates to within 25%
(or within about 25%) of the measured performance properties of
Armacor M or better. In some embodiments of this disclosure, the
alloys can exhibit similar coating adhesion, abrasive wear
resistance, adhesive wear resistance, and corrosion resistance as
Armacor, where `similar` equates to within 25% (or within about
25%) of the measured performance properties of Armacor M or
better.
[0076] In some embodiments of this disclosure, the alloys can
exhibit similar coating adhesion and abrasive wear resistance as
Armacor, where `similar` equates to within 10% (or within about
10%) of the measured performance properties of Armacor M or better.
In some embodiments of this disclosure, the alloys can exhibit
similar coating adhesion, abrasive wear resistance, and adhesive
wear resistance as Armacor, where `similar` equates to within 10%
(or within about 10%) of the measured performance properties of
Armacor M or better. In some embodiments of this disclosure, the
alloys can exhibit similar coating adhesion, abrasive wear
resistance, adhesive wear resistance, and corrosion resistance as
Armacor, where `similar` equates to within 10% (or within about
10%) of the measured performance properties of Armacor M or
better.
[0077] In some embodiments of this disclosure, the alloys can
exhibit similar coating adhesion and abrasive wear resistance as
Armacor, where `similar` equates to within 1% (or within about 1%)
of the measured performance properties of Armacor M or better. In
some embodiments of this disclosure, the alloys can exhibit similar
coating adhesion, abrasive wear resistance, and adhesive wear
resistance as Armacor, where `similar` equates to within 1% (or
within about 1%) of the measured performance properties of Armacor
M or better. In some embodiments of this disclosure, the alloys can
exhibit similar coating adhesion, abrasive wear resistance,
adhesive wear resistance, and corrosion resistance as Armacor,
where `similar` equates to within 1% (or within about 1%) of the
measured performance properties of Armacor M or better.
[0078] In some embodiments of this disclosure, the alloys can
exhibit similar coating adhesion and abrasive wear resistance as
Armacor, where `similar` equates to within 0% (or within about 0%)
of the measured performance properties of Armacor M or better. In
some embodiments of this disclosure, the alloys can exhibit similar
coating adhesion, abrasive wear resistance, and adhesive wear
resistance as Armacor, where `similar` equates to within 0% (or
within about 0%) of the measured performance properties of Armacor
M or better. In some embodiments of this disclosure, the alloys can
exhibit similar coating adhesion, abrasive wear resistance,
adhesive wear resistance, and corrosion resistance as Armacor,
where `similar` equates to within 0% (or within about 0%) of the
measured performance properties of Armacor M or better.
[0079] In some embodiments, the thermal spray coating can be
`readable`. A readable coating produces consistent thickness
measurements with an Elcometer.TM. thickness gauge, or similar
device, when properly calibrated. Armacor M is not a readable
alloy, unlike embodiments of the disclosure, as it is magnetic.
[0080] As a standard to verify `readability`, a 25 mil standard
thermal spray coupon is used for measurements. In some embodiments,
the coating thickness measurement can be accurate to within 5 mils
(or within about 5 mils) of the actual physical thickness. In some
embodiments, the coating thickness measurement can be accurate to
within 3.5 mils (or within about 3.5 mils) of the actual physical
thickness. In some embodiments, the coating thickness measurement
can be accurate to within 2 mils (or within about 2 mils) of the
actual physical thickness.
[0081] In some embodiments, consistent measurements according to
the above criteria, .+-.5 mils to actual physical thickness, can be
made after the coating has been exposed to heat for an extended
period of time. This can be advantageous because when the alloy is
heated, there is a potential for a magnetic phase to precipitate
out, which would make the alloy non-readable. This can be
especially true for amorphous alloys which may be readable in
amorphous form, but may crystallize in a different environment due
to heat. Thus, in some embodiments, the alloy can remain
non-magnetic even after being exposed to heat for a substantial
time period.
[0082] In some embodiments, the coating can be `readable` after
exposure to 1100K (or about 1100K) for 2 hours (or about 2 hours)
and cooled at a rate of less than 10K/S (or less than about 10K/S).
In some embodiments, the coating can be `readable` after exposure
to 1300K (or about 1300K) for 2 hours (or about 2 hours) and cooled
at a rate of less than 10K/S (or less than 10K/S). In some
embodiments, the coating can be `readable` after exposure to 1500K
(or about 1500K) for 2 hours (or about 2 hours) and cooled at a
rate of less than 10K/S (or less than about 10K/S). It is expected
that increased exposure times above 2 hours will not continue to
affect the final `readability` of these materials.
TABLE-US-00003 TABLE 3 List of alloy compositions and thermodynamic
and kinetic parameters which meet the criteria described in this
disclosure, including the criteria pertained to coating
non-magnetism and readability. Large atom % is the total atom % of
elements larger than iron, Trans T is the FCC-BCC transition
temperature and melt T is the melting temperature of the alloy. No.
C Mn Mo Ni Si Large Atom % Trans T Melt T M934 0 19 20 0 10 30%
1000 1300 M935 0 20 19 0 10 31% 1000 1300 M936 0 20 20 0 10 31% 900
1300 M937 0 13 11 4 5 20% 800 1500 M938 0 13 11 5 5 20% 800 1500
M939 0 13 13 3 5 21% 800 1500 M940 0 13 13 4 5 21% 800 1500 M941 0
13 13 5 5 21% 800 1500 M942 0 13 13 5 6 21% 850 1450 M943 0 13 15 2
5 22% 800 1500 M944 0 13 15 3 5 22% 800 1500 M945 0 13 15 4 5 22%
800 1500 M946 0 13 15 4 6 22% 850 1450 M947 0 13 15 5 5 22% 800
1500 M948 0 13 15 5 6 22% 850 1450 M949 0 16 7 1 6 20% 850 1500
M950 0 16 7 2 6 20% 850 1500 M951 0 16 7 3 6 20% 850 1500 M952 0 16
7 3 7 20% 900 1500 M953 0 16 7 4 6 20% 800 1500 M954 0 16 7 4 7 20%
900 1500 M955 0 16 7 5 6 20% 800 1500 M956 0 16 7 5 7 20% 900 1500
M957 0 16 9 1 6 21% 850 1500 M958 0 16 9 2 6 21% 800 1500 M959 0 16
9 2 7 21% 900 1450 M960 0 16 9 3 6 21% 800 1500 M961 0 16 9 3 7 21%
900 1450 M962 0 16 9 4 6 21% 800 1500 M963 0 16 9 4 7 21% 900 1450
M964 0 16 9 4 8 21% 1000 1450 M965 0 16 9 5 5 21% 750 1500 M966 0
16 9 5 6 21% 800 1500 M967 0 16 9 5 7 21% 850 1450 M968 0 16 9 5 8
21% 1000 1450 M969 0 16 11 0 5 23% 800 1500 M970 0 16 11 1 5 23%
800 1500 M971 0 16 11 1 6 22% 850 1500 M972 0 16 11 1 7 22% 900
1450 M973 0 16 11 2 5 23% 750 1500 M974 0 16 11 2 6 22% 800 1500
M975 0 16 11 2 7 22% 900 1450 M976 0 16 11 3 5 23% 750 1500 M977 0
16 11 3 6 22% 800 1500 M978 0 16 11 3 7 22% 850 1450 M979 0 16 11 3
8 22% 1000 1400 M980 0 16 11 4 5 23% 750 1500 M981 0 16 11 4 6 22%
800 1500 M982 0 16 11 4 7 22% 850 1450 M983 0 16 11 4 8 22% 950
1400 M984 0 16 11 5 5 23% 750 1500 M985 0 16 11 5 6 22% 800 1500
M986 0 16 11 5 7 22% 850 1450 M987 0 16 13 0 5 24% 800 1500 M988 0
16 13 1 5 24% 750 1500 M989 0 16 13 1 6 24% 800 1450 M990 0 16 13 1
7 23% 900 1450 M991 0 16 13 2 5 24% 750 1500 M992 0 16 13 2 6 24%
800 1450 M993 0 16 13 2 7 23% 850 1450 M994 0 16 13 2 8 23% 950
1400 M995 0 16 13 3 5 24% 750 1500 M996 0 16 13 3 6 24% 800 1450
M997 0 16 13 3 7 23% 850 1450 M998 0 16 13 4 5 24% 750 1500 M999 0
16 13 4 6 24% 750 1450 M1000 0 16 13 5 5 24% 750 1500 M1001 0 16 15
0 5 25% 750 1450 M1002 0 16 15 0 6 25% 800 1450 M1003 0 16 15 0 7
25% 900 1400 M1004 0 16 15 1 5 25% 750 1450 M1005 0 16 15 1 6 25%
800 1450 M1006 0 16 15 1 7 25% 850 1400 M1007 0 16 15 2 5 25% 750
1450 M1008 0 16 15 2 6 25% 750 1450 M1009 0 16 15 3 5 25% 750 1450
M1010 0 16 15 3 6 25% 750 1450 M1011 0 16 15 4 5 25% 750 1450 M1012
0 19 7 0 6 23% 800 1500 M1013 0 19 7 0 7 22% 900 1450 M1014 0 19 7
1 6 23% 800 1500 M1015 0 19 7 1 7 22% 900 1450 M1016 0 19 7 2 6 23%
750 1500 M1017 0 19 7 2 7 22% 850 1450 M1018 0 19 7 2 8 22% 1000
1450 M1019 0 19 7 3 6 23% 750 1500 M1020 0 19 7 3 7 22% 850 1450
M1021 0 19 7 3 8 22% 950 1450 M1022 0 19 7 4 6 23% 750 1500 M1023 0
19 7 4 7 22% 850 1450 M1024 0 19 7 4 8 22% 950 1450 M1025 0 19 7 5
5 23% 750 1500 M1026 0 19 7 5 6 23% 750 1500 M1027 0 19 7 5 7 22%
800 1450 M1028 0 19 7 5 8 22% 950 1450 M1029 0 19 9 0 5 24% 750
1500 M1030 0 19 9 0 6 24% 800 1500 M1031 0 19 9 0 7 24% 900 1450
M1032 0 19 9 1 5 24% 750 1500 M1033 0 19 9 1 6 24% 750 1500 M1034 0
19 9 1 7 24% 850 1450 M1035 0 19 9 1 8 24% 1000 1400 M1036 0 19 9 2
5 24% 750 1500 M1037 0 19 9 2 6 24% 750 1500 M1038 0 19 9 2 7 24%
800 1450 M1039 0 19 9 2 8 24% 950 1400 M1040 0 19 9 3 5 24% 700
1500 M1041 0 19 9 3 6 24% 750 1500 M1042 0 19 9 3 7 24% 800 1450
M1043 0 19 9 3 8 24% 900 1400 M1044 0 19 9 4 5 24% 700 1500 M1045 0
19 9 4 6 24% 750 1500 M1046 0 19 9 4 7 24% 800 1450 M1047 0 19 9 5
5 24% 700 1500 M1048 0 19 9 5 6 24% 750 1500 M1049 0 19 11 0 5 26%
700 1500 M1050 0 19 11 0 6 25% 750 1450 M1051 0 19 11 0 7 25% 850
1450 M1052 0 19 11 0 8 25% 1000 1400 M1053 0 19 11 1 5 26% 700 1500
M1054 0 19 11 1 6 25% 750 1450 M1055 0 19 11 1 7 25% 800 1450 M1056
0 19 11 1 8 25% 950 1400 M1057 0 19 11 2 5 26% 700 1500 M1058 0 19
11 2 6 25% 750 1450 M1059 0 19 11 2 7 25% 800 1450 M1060 0 19 11 3
5 26% 700 1500 M1061 0 19 11 3 6 25% 750 1450 M1062 0 19 11 3 7 25%
800 1450 M1063 0 19 11 4 5 26% 700 1500 M1064 0 19 11 4 6 25% 750
1450 M1065 0 19 11 5 5 26% 700 1500 M1066 0 19 13 0 5 27% 700 1500
M1067 0 19 13 0 6 27% 750 1450 M1068 0 19 13 0 7 26% 800 1400 M1069
0 19 13 1 5 27% 700 1450 M1070 0 19 13 1 6 27% 750 1450 M1071 0 19
13 2 5 27% 700 1450 M1072 0 19 13 3 5 27% 700 1450 M1073 0 19 15 0
5 28% 700 1450 M1074 0 19 15 0 6 28% 750 1400 M1075 0 19 15 1 5 28%
700 1450 M1076 0 22 7 0 5 26% 700 1500 M1077 0 22 7 0 6 26% 750
1500 M1078 0 22 7 0 7 25% 850 1450 M1079 0 22 7 0 8 25% 1000 1400
M1080 0 22 7 1 5 26% 700 1500 M1081 0 22 7 1 6 26% 700 1500 M1082 0
22 7 1 7 25% 800 1450 M1083 0 22 7 1 8 25% 950 1400 M1084 0 22 7 2
5 26% 700 1500 M1085 0 22 7 2 6 26% 700 1500 M1086 0 22 7 2 7 25%
800 1450 M1087 0 22 7 2 8 25% 900 1400 M1088 0 22 7 3 5 26% 700
1500 M1089 0 22 7 3 6 26% 700 1500 M1090 0 22 7 3 7 25% 750 1450
M1091 0 22 7 4 5 26% 700 1500 M1092 0 22 7 4 6 26% 700 1500 M1093 0
22 7 5 5 26% 700 1500 M1094 0 22 9 0 5 27% 700 1500 M1095 0 22 9 0
6 27% 700 1450 M1096 0 22 9 0 7 27% 800 1450 M1097 0 22 9 0 8 26%
950 1400 M1098 0 22 9 1 5 27% 700 1500 M1099 0 22 9 1 6 27% 700
1450 M1100 0 22 9 1 7 27% 750 1450 M1101 0 22 9 2 5 27% 700 1500
M1102 0 22 9 2 6 27% 700 1450 M1103 0 22 9 3 5 27% 700 1500 M1104 0
22 9 3 6 27% 700 1450 M1105 0 22 9 4 5 27% 700 1500 M1106 0 22 11 0
5 29% 700 1500 M1107 0 22 11 0 6 28% 700 1450 M1108 0 22 11 1 5 29%
650 1500 M1109 0 22 13 0 5 30% 650 1450 M1110 0 25 7 0 5 29% 650
1500 M1111 0 25 7 0 6 29% 700 1450 M1112 0 25 7 0 7 28% 750 1450
M1113 0 25 7 1 5 29% 650 1500 M1114 0 25 7 1 6 29% 650 1450 M1115 0
25 7 2 5 29% 650 1500 M1116 0 25 7 3 5 29% 650 1500 M1117 0 25 9 0
5 30% 650 1500 M1118 0 25 9 0 6 30% 650 1450 M1119 0 25 9 1 5 30%
650 1500 M1120 0.25 16 7 3 5 20% 750 1500 M1121 0.25 16 7 4 5 20%
750 1500 M1122 0.25 16 7 5 5 20% 750 1500 M1123 0.25 16 9 0 5 21%
800 1500 M1124 0.25 19 7 0 5 23% 750 1500 M1125 0.25 19 7 1 5 23%
750 1500 M1126 0.25 19 7 2 5 23% 750 1500 M1127 0.25 19 7 3 5 23%
750 1500 M1128 0.25 19 7 4 5 23% 700 1500 M1129 0.25 19 7 5 5 23%
700 1500 M1130 0.25 19 9 0 5 24% 750 1500 M1131 0.25 22 7 0 5 26%
700 1500 M1132 0.25 22 7 1 5 26% 700 1500 M1133 0.25 22 7 2 5 26%
700 1500 M1134 0.25 22 7 3 5 26% 700 1500 M1135 0.25 22 7 4 5 26%
700 1500 M1136 0.25 22 7 5 5 26% 700 1500 M1137 0.25 22 9 0 5 27%
700 1500 M1138 0.25 25 7 0 5 29% 650 1500 M1139 0.25 25 7 1 5 29%
650 1500 M1140 0.25 25 7 2 5 29% 650 1500 M1141 0.25 25 9 0 5 30%
650 1500
Applications and Processes for Use:
[0083] Embodiments of alloys disclosed herein can be used in a
variety of applications and industries. Some non-limiting examples
of applications of use include:
[0084] Surface mining applications including but not limited to the
following components and coatings for the following components:
wear resistant sleeves and/or wear resistant hardfacing for slurry
pipelines, mud pump components including pump housing or impeller
or hardfacing for mud pump components, ore feed chute components
including chute blocks or hardfacing of chute blocks, separation
screens including but not limited to rotary breaker screens, banana
screens, and shaker screens, liners for autogenous grinding mills
and semi-autogenous grinding mills, ground engaging tools and
hardfacing for ground engaging tools, wear plate for buckets and
dumptruck liners, heel blocks and hardfacing for heel blocks on
mining shovels, grader blades and hardfacing for grader blades,
stacker reclaimers, siazer crushers, general wear packages for
mining components and other communition components.
[0085] Upstream oil and gas applications including but not limited
to the following components and coatings for the following
components: Downhole casing and downhole casing, drill pipe and
coatings for drill pipe including hardbanding, mud management
components, mud motors, fracking pump sleeves, fracking impellers,
fracking blender pumps, stop collars, drill bits and drill bit
components, directional drilling equipment and coatings for
directional drilling equipment including stabilizers and
centralizers, blow out preventers and coatings for blow out
preventers and blow out preventer components including the shear
rams, oil country tubular goods and coatings for oil country
tubular goods.
[0086] Downstream oil and gas applications including but not
limited to the following components and coatings for the following
components: Process vessels and coating for process vessels
including steam generation equipment, amine vessels, distillation
towers, cyclones, catalytic crackers, general refinery piping,
corrosion under insulation protection, sulfur recovery units,
convection hoods, sour stripper lines, scrubbers, hydrocarbon
drums, and other refinery equipment and vessels.
[0087] Pulp and paper applications including but not limited to the
following components and coatings for the following components:
Rolls used in paper machines including yankee dryers and other
dryers, calendar rolls, machine rolls, press rolls, digesters, pulp
mixers, pulpers, pumps, boilers, shredders, tissue machines, roll
and bale handling machines, doctor blades, evaporators, pulp mills,
head boxes, wire parts, press parts, M.G. cylinders, pope reels,
winders, vacuum pumps, deflakers, and other pulp and paper
equipment.
[0088] Power generation applications including but not limited to
the following components and coatings for the following components:
boiler tubes, precipitators, fireboxes, turbines, generators,
cooling towers, condensers, chutes and troughs, augers, bag houses,
ducts, ID fans, coal piping, and other power generation
components.
[0089] Agriculture applications including but not limited to the
following components and coatings for the following components:
chutes, base cutter blades, troughs, primary fan blades, secondary
fan blades, augers and other agricultural applications.
[0090] Construction applications including but not limited to the
following components and coatings for the following components:
cement chutes, cement piping, bag houses, mixing equipment and
other construction applications.
[0091] Machine element applications including but not limited to
the following components and coatings for the following components:
Shaft journals, paper rolls, gear boxes, drive rollers, impellers,
general reclamation and dimensional restoration applications and
other machine element applications.
[0092] Steel applications including but not limited to the
following components and coatings for the following components:
cold rolling mills, hot rolling mills, wire rod mills, galvanizing
lines, continue pickling lines, continuous casting rolls and other
steel mill rolls, and other steel applications.
[0093] Embodiments of alloys disclosed herein can be produced and
or deposited in a variety of techniques effectively. Some
non-limiting examples of processes include:
[0094] Thermal spray process including but not limited to those
using a wire feedstock such as twin wire arc, spray, high velocity
arc spray, combustion spray and those using a powder feedstock such
as high velocity oxygen fuel, high velocity air spray, plasma
spray, detonation gun spray, and cold spray. Wire feedstock can be
in the form of a metal core wire, solid wire, or flux core wire.
Powder feedstock can be either a single homogenous alloy or a
combination of multiple alloy powder which result in the desired
chemistry when melted together.
[0095] Welding processes including but not limited to those using a
wire feedstock including but not limited to metal inert gas (MIG)
welding, tungsten inert gas (TIG) welding, arc welding, submerged
arc welding, open arc welding, bulk welding, laser cladding, and
those using a powder feedstock including but not limited to laser
cladding and plasma transferred arc welding. Wire feedstock can be
in the form of a metal core wire, solid wire, or flux core wire.
Powder feedstock can be either a single homogenous alloy or a
combination of multiple alloy powder which result in the desired
chemistry when melted together.
[0096] Casting processes including but not limited to processes
typical to producing cast iron including but not limited to sand
casting, permanent mold casting, chill casting, investment casting,
lost foam casting, die casting, centrifugal casting, glass casting,
slip casting and process typical to producing wrought steel
products including continuous casting processes.
[0097] Post processing techniques including but not limited to but
not limited to rolling, forging, surface treatments such as
carburizing, nitriding, carbonitriding, heat treatments including
but not limited to austenitizing, normalizing, annealing, stress
relieving, tempering, aging, quenching, cryogenic treatments, flame
hardening, induction hardening, differential hardening, case
hardening, decarburization, machining, grinding, cold working, work
hardening, and welding.
[0098] One of the more applicable uses of this technology is in
applications where coatings are deposited on-site, in the field, or
in locations where proper ventilation, dust collection, and other
safety measures cannot be easily met. Some well-known non-limiting
examples of these applications include power generation
applications such as the coating of boiler tubes, upstream refinery
applications such as the coating of refinery vessels, and pulp and
paper applications such as the coating and grinding of yankee
dryers.
EXAMPLES
[0099] The following examples are intended to be illustrative and
non-limiting.
Example 1
[0100] The previously disclosed alloy #4, Fe: BAL, Mn: about 5, Mo:
about 13, Si: about 10 was produced in the form of a 40 gram trial
ingot to verify hardness and thermal spray vitrification potential.
The ingot hardness was measured to be 534 Vickers (converting from
a Rockwell C measurement). The microstructure of the ingot showed a
fully eutectic structure indicating a strong possibility for
amorphous or nanocrystalline structure under the rapid cooling rate
of the spray process. This material has been selected for
manufacture into 1/16'' cored thermal spray wire for twin wire arc
spray trials after slight modification to the alloy #14, Fe: BAL,
Mn: about 5, Mo: about 13, Si: about 10, Al: about 2.
Example 2
[0101] The previously presented alloy #5, Fe: BAL, Mn: about 5, Mo:
about 7, Si: about 10 was produced in the form of a 40 gram trial
ingot to verify hardness and thermal spray vitrification potential.
The ingot hardness was measured to be 534 Vickers (converting from
a Rockwell C measurement). The microstructure of the ingot showed a
fully eutectic structure indicating a strong possibility for
amorphous or nanocrystalline structure under the rapid cooling rate
of the spray process. This material has been selected for
manufacture into 1/16'' cored thermal spray wire for twin wire arc
spray trials after slight modification to alloy #15, Fe: BAL, Mn:
about 5, Mo: about 7, Si: about 10, Al: about 2.
Example 3
[0102] The previously disclosed alloy #8, Fe: BAL, C: about 0.25,
Mn: about 19, Mo: about 7, Si: about 5 was produced in the form of
a 40 gram ingot to verify hardness, thermal spray vetrification
potential and magnetic permeability. In this example, the alloy
candidate is being developed as a `readable` coating which requires
the alloy to be non-magnetic in the sprayed form. The ingot
hardness was measured to be 300 Vickers (converting from a Rockwell
C measurement). While this is below the desired hardness threshold,
it is well known by those skilled in the art that the rapid cooling
process achieved in thermal spray will increase the hardness of the
alloy in this form. Thus, it is not unreasonable to expect an
increase in hardness in the sprayed form up to the desired level of
400 Vickers. The relative magnetic permeability was measured via a
Low-Mu Magnetic Permeability Tester and was determined to be less
than 1.01, well below the threshold required to ensure
`readability`.
Example 4
[0103] The previously disclosed alloy #5, Fe: BAL, Mn: about 5, Mo:
about 7, Si: about 10 was produced in the form of a cored thermal
spray wire. This alloy was sprayed using the twin wire arc spray
technique, specifically using the parameters shown in
[0104] Table 3. A series of tests were run to evaluate the alloys
performance in reference to standard Cr-bearing thermal spray
materials used for hardfacing. The specific alloy of reference is
known by the commercial names, Armacor M, TAFA 95MXC, PMet 273,
etc. and has an alloy composition of about Fe: BAL, Cr: 29, Si: 1,
Mn: 2, B: 4. Table 2 highlights the result of the testing. As shown
in Table 4, Alloy #5 has comparable adhesion and abrasion
resistance as measure via ASTM G65B testing.
TABLE-US-00004 TABLE 2 List of properties of disclosed alloys in
relation to Armacor M Alloy Adhesion ASTM G65B ASTM G77 Armacor M
8,000 .+-. 500 psi 0.37 0.07 Alloy #4 8,000 .+-. 500 psi 0.37 0.07
Alloy #5 8,000 .+-. 500 psi 0.46 1.55
TABLE-US-00005 TABLE 3 Spray parameters used in Example 4 and 5
testing Air pressure 60 psi Voltage 38 V Amperage 125 A
Example 5
[0105] The previously disclosed alloy #4, Fe: BAL, Mn: about 5, Mo:
about 7, Si: about 10 was produced in the form of a cored thermal
spray wire. This alloy was sprayed using the twin wire arc spray
technique using the parameters shown in
[0106] Table 3. Yankee dryers are typically sprayed using this
parameter set. A series of tests were run to evaluate the alloys
performance in reference to standard Cr-bearing thermal spray
materials used for hardfacing similar to that described in Example
4. The preliminary results of this testing are shown in Table
2.
[0107] As shown, Alloy #4 replicates the key performance criteria
of Armacor M in all key criteria. As Alloy #4 represents an
exemplary embodiment of this disclosure, additional testing was
performed in order to compare other performance criteria
specifically as it relates to the coating of yankee dryers, a
specific article of manufacture used in paper machines. This
testing including corrosion testing, grinding studies, spray
characteristics, thorough metallographic evaluation, and evaluation
of surface properties as related to surface tension. In all cases,
alloy #4 was deemed to have similar or better performance than the
Armacor M coating.
[0108] Corrosion testing was conducted by exposing the coating to
saltwater and measuring the voltage against a reference bare steel
plate, which could be then used to place the material on the
Galvanic Series. Both the Armacor M and Alloy #4 coatings showed
significant rust on the coating surface after the 2 week test
exposure. The position of the Armacor M coating on the galvanic
series is -450 to -567 and the position of Alloy #4 is -510 to
-640. Increasingly negative values reflect more active potentials,
which is less desirable as it indicates reduced corrosion
resistance. This represents a `similarity` in that the quantified
performance does not vary by more than 25%.
[0109] Grinding studies were performed due to its specific
relevance to the yankee dryer application. In this application it
is desirable for the coating to exhibit faster grinding times, as
it reduces the downtime of the paper machine. Grinding times were
quantified by removing a specific material thickness and measuring
the tie to do so, as shown in
[0110] Table 4. As shown, Alloy #4 showed reduced grinding time,
which is advantageous.
TABLE-US-00006 TABLE 4 Grinding Study Measurements Thickness Time
to Grind (sec) Removed Alloy #4 ARM-M % Change 5 mil 140 s 150 s
7.14% 10 mil 210 s 210 s 0% 15 mil 310 s 345 s 11.29% 20 mil 398 s
488 s 22.61%
[0111] The characteristics of the spray for both materials was also
studied. It was evident that Alloy #4 produced significantly less
dust during spraying than Armacor M, which is desirable.
Metallographic examination also showed that less oxides were
present in the Alloy #4 coating, 7% versus 13% in the Armacor M
coating.
[0112] Finally the surface tension properties of each coating were
evaluated. In the Yankee dryer application it is desirable for the
coating to be hydrophilic, which enables the adsorption of water
based organic compounds used in paper making into the surface. The
contact angle that a water droplet makes on the surface can be used
to quantify the surface tension of the material. The Armacor M
water droplet formed a 63.9.degree. angle, and Alloy #4 formed a
41.5.degree. angle. A smaller angle indicates increased
hydrophillicity, which is advantageous because in Yankee dryer
applications, a monoammonium phosphate (MAP) water-based solution
is typically sprayed onto the coating for paper release properties.
It can be advantageous for this water-based solution to immerse
itself into the coating structure and stick well to the coating
surface, which can be enhanced by having a hydrophilic coating.
[0113] From the foregoing description, it will be appreciated that
an inventive chromium free hardfacing alloy and method of
manufacturing are disclosed. While several components, techniques
and aspects have been described with a certain degree of
particularity, it is manifest that many changes can be made in the
specific designs, constructions and methodology herein above
described without departing from the spirit and scope of this
disclosure.
[0114] Certain features that are described in this disclosure in
the context of separate implementations can also be implemented in
combination in a single implementation. Conversely, various
features that are described in the context of a single
implementation can also be implemented in multiple implementations
separately or in any suitable subcombination. Moreover, although
features may be described above as acting in certain combinations,
one or more features from a claimed combination can, in some cases,
be excised from the combination, and the combination may be claimed
as any subcombination or variation of any subcombination.
[0115] Moreover, while methods may be depicted in the drawings or
described in the specification in a particular order, such methods
need not be performed in the particular order shown or in
sequential order, and that all methods need not be performed, to
achieve desirable results. Other methods that are not depicted or
described can be incorporated in the example methods and processes.
For example, one or more additional methods can be performed
before, after, simultaneously, or between any of the described
methods. Further, the methods may be rearranged or reordered in
other implementations. Also, the separation of various system
components in the implementations described above should not be
understood as requiring such separation in all implementations, and
it should be understood that the described components and systems
can generally be integrated together in a single product or
packaged into multiple products. Additionally, other
implementations are within the scope of this disclosure.
[0116] Conditional language, such as "can," "could," "might," or
"may," unless specifically stated otherwise, or otherwise
understood within the context as used, is generally intended to
convey that certain embodiments include or do not include, certain
features, elements, and/or steps. Thus, such conditional language
is not generally intended to imply that features, elements, and/or
steps are in any way required for one or more embodiments.
[0117] Conjunctive language such as the phrase "at least one of X,
Y, and Z," unless specifically stated otherwise, is otherwise
understood with the context as used in general to convey that an
item, term, etc. may be either X, Y, or Z. Thus, such conjunctive
language is not generally intended to imply that certain
embodiments require the presence of at least one of X, at least one
of Y, and at least one of Z.
[0118] Language of degree used herein, such as the terms
"approximately," "about," "generally," and "substantially" as used
herein represent a value, amount, or characteristic close to the
stated value, amount, or characteristic that still performs a
desired function or achieves a desired result. For example, the
terms "approximately", "about", "generally," and "substantially"
may refer to an amount that is within less than or equal to 10% of,
within less than or equal to 5% of, within less than or equal to 1%
of, within less than or equal to 0.1% of, and within less than or
equal to 0.01% of the stated amount. If the stated amount is 0
(e.g., none, having no), the above recited ranges can be specific
ranges, and not within a particular % of the value. For example,
within less than or equal to 10 wt./vol. % of, within less than or
equal to 5 wt./vol. % of, within less than or equal to 1 wt./vol. %
of, within less than or equal to 0.1 wt./vol. % of, and within less
than or equal to 0.01 wt./vol. % of the stated amount.
[0119] Some embodiments have been described in connection with the
accompanying drawings. The figures are drawn to scale, but such
scale should not be limiting, since dimensions and proportions
other than what are shown are contemplated and are within the scope
of the disclosed inventions. Distances, angles, etc. are merely
illustrative and do not necessarily bear an exact relationship to
actual dimensions and layout of the devices illustrated. Components
can be added, removed, and/or rearranged. Further, the disclosure
herein of any particular feature, aspect, method, property,
characteristic, quality, attribute, element, or the like in
connection with various embodiments can be used in all other
embodiments set forth herein. Additionally, it will be recognized
that any methods described herein may be practiced using any device
suitable for performing the recited steps.
[0120] While a number of embodiments and variations thereof have
been described in detail, other modifications and methods of using
the same will be apparent to those of skill in the art.
Accordingly, it should be understood that various applications,
modifications, materials, and substitutions can be made of
equivalents without departing from the unique and inventive
disclosure herein or the scope of the claims.
* * * * *