U.S. patent application number 14/581317 was filed with the patent office on 2015-04-23 for adhesive composition, optical member, and surface protective sheet.
The applicant listed for this patent is Hiroshi OGAWA, Cheong Hun SONG, Tatsuhiro SUWA. Invention is credited to Hiroshi OGAWA, Cheong Hun SONG, Tatsuhiro SUWA.
Application Number | 20150111033 14/581317 |
Document ID | / |
Family ID | 40667677 |
Filed Date | 2015-04-23 |
United States Patent
Application |
20150111033 |
Kind Code |
A1 |
SONG; Cheong Hun ; et
al. |
April 23, 2015 |
ADHESIVE COMPOSITION, OPTICAL MEMBER, AND SURFACE PROTECTIVE
SHEET
Abstract
An adhesive composition includes a copolymer (A), the copolymer
(A) being a copolymer of: a hydroxyl group-containing
(meth)acrylamide (a1), the hydroxyl group-containing
(meth)acrylamide (a1) including at least one of a hydroxyl
group-containing acrylamide and a hydroxyl group-containing
methacrylamide, and a (meth)acrylate (a2), the (meth)acrylate (a2)
including at least one of an acrylic ester and a methacrylic ester;
and an antistatic agent (B), the antistatic agent (B) including an
ionic compound.
Inventors: |
SONG; Cheong Hun;
(Uiwang-si, KR) ; SUWA; Tatsuhiro; (Yokohamashi,
JP) ; OGAWA; Hiroshi; (Yokohamashi, JP) |
|
Applicant: |
Name |
City |
State |
Country |
Type |
SONG; Cheong Hun
SUWA; Tatsuhiro
OGAWA; Hiroshi |
Uiwang-si
Yokohamashi
Yokohamashi |
|
KR
JP
JP |
|
|
Family ID: |
40667677 |
Appl. No.: |
14/581317 |
Filed: |
December 23, 2014 |
Related U.S. Patent Documents
|
|
|
|
|
|
Application
Number |
Filing Date |
Patent Number |
|
|
12801109 |
May 24, 2010 |
|
|
|
14581317 |
|
|
|
|
PCT/KR2008/006501 |
Nov 4, 2008 |
|
|
|
12801109 |
|
|
|
|
Current U.S.
Class: |
428/354 ;
428/355CN; 524/106; 524/555; 524/99 |
Current CPC
Class: |
C08K 5/49 20130101; G02B
5/305 20130101; Y10T 428/2848 20150115; Y10T 428/2887 20150115;
C08K 5/3432 20130101; C09J 133/08 20130101; C09J 11/06 20130101;
G02B 1/16 20150115; C08K 5/3435 20130101; C09J 133/26 20130101 |
Class at
Publication: |
428/354 ;
524/555; 524/106; 524/99; 428/355.CN |
International
Class: |
C09J 11/06 20060101
C09J011/06; G02B 1/16 20060101 G02B001/16; C08K 5/3435 20060101
C08K005/3435; C08K 5/3432 20060101 C08K005/3432; C09J 133/08
20060101 C09J133/08; C08K 5/49 20060101 C08K005/49 |
Foreign Application Data
Date |
Code |
Application Number |
Nov 22, 2007 |
JP |
2007-302702 |
Claims
1-21. (canceled)
22. An optical member, comprising: an optical sheet; and an
adhesive layer formed on one or both sides of the optical sheet
from an adhesive composition that includes: a copolymer (A), the
copolymer (A) being a copolymer of: a hydroxyl group-containing
(meth)acrylamide (a1), the hydroxyl group-containing
(meth)acrylamide (a1) including at least one of a hydroxyl
group-containing acrylamide and a hydroxyl group-containing
methacrylamide, and a (meth)acrylate (a2), the (meth)acrylate (a2)
including at least one of an acrylic ester and a methacrylic ester;
an antistatic agent (B), the antistatic agent (B) including an
ionic compound; and a crosslinking agent, wherein the adhesive
layer has a gel fraction, at 3 days at 23.degree. C. under a
relative humidity of 50%, of about 50 to about 80% as a
crosslinking degree.
23. The optical member as claimed in claim 22, wherein the hydroxyl
group-containing (meth)acrylamide (a1) is represented by the
following formula: H.sub.2C.dbd.C(R1)ACONHCH.sub.2CH.sub.2OH, in
which: R1 is H or CH.sub.3, A is a linking group, the linking group
being (COOCH.sub.2CH.sub.2).sub.n,
COOCH.sub.2CH.sub.2OOC--CH.sub.2CH.sub.2, a single bond, or
Compound 1 represented by Chemical Formula 1: ##STR00003## and n is
1 or 2.
24. The optical member as claimed in claim 22, wherein the
copolymer (A) includes about 0.1 to about 5% by weight of the
hydroxyl group-containing (meth)acrylamide (a1) based on a total
weight of the copolymer (A).
25. The optical member as claimed in claim 22, wherein the
copolymer (A) includes about 50 to about 99.1% by weight of the
(meth)acrylate (a2) based on a total weight of the copolymer
(A).
26. The optical member as claimed in claim 22, wherein the
(meth)acrylate (a2) includes at least one of methyl (meth)acrylate,
ethyl (meth)acrylate, n-butyl (meth)acrylate, t-butyl
(meth)acrylate, isobutyl (meth)acrylate, hexyl (meth)acrylate,
2-ethylhexyl (meth)acrylate, n-octyl (meth)acrylate, isooctyl
(meth)acrylate, n-nonyl (meth)acrylate, isononyl (meth)acrylate,
n-decyl (meth)acrylate, isodecyl (meth)acrylate, n-dodecyl
(meth)acrylate, n-tridecyl (meth)acrylate, n-tetradecyl
(meth)acrylate, methoxyethyl (meth)acrylate, ethoxyethyl
(meth)acrylate, butoxyethyl (meth)acrylate, cyclohexyl
(meth)acrylate, t-butylcyclohexyl (meth)acrylate, phenoxyethyl
(meth)acrylate, nonylphenoxy polyethylene glycol (meth)acrylate,
benzyl (meth)acrylate, isobornyl (meth)acrylate, and
tetrahydrofurfuryl (meth)acrylate.
27. The optical member as claimed in claim 22, wherein the
copolymer (A) includes about 80 to about 99.89% by weight of
n-butyl acrylate as the (meth)acrylate (a2) based on a total weight
of the copolymer (A).
28. The optical member as claimed in claim 22, wherein the
copolymer (A) includes about 0.1 to about 5% by weight of
hydroxyethylacrylamide as the hydroxyl group-containing
(meth)acrylamide (a1) based on a total weight of the copolymer
(A).
29. The optical member as claimed in claim 22, wherein the
copolymer (A) has a polystyrene conversion weight-average molecular
weight of about 1,000,000 to about 2,000,000 as determined by gel
permeation chromatography.
30. The optical member as claimed in claim 22, wherein the
copolymer (A) has a glass transition temperature (Tg) of about
0.degree. C. or less.
31. The optical member as claimed in claim 22, wherein the ionic
compound includes at least one of an imidazolium salt, a pyridinium
salt, an alkyl ammonium salt, an alkyl pyrrolidium salt, and an
alkyl phosphonium salt.
32. The optical member as claimed in claim 22, wherein the
copolymer (A) is crosslinked.
33. The optical member as claimed in claim 22, wherein the gel
fraction has a stabilizing period of about 3 days or less.
34. The optical member as claimed in claim 22, wherein the adhesive
composition includes about 0.01 to about 2.0% by weight of the
antistatic agent (B).
35. The optical member as claimed in claim 22, wherein the adhesive
layer has a sheet resistance of about 1.times.10.sup.8 to about
1.times.10.sup.11 .OMEGA./cm.sup.2.
36. A surface protection sheet, comprising: a protective film; and
an adhesive layer formed on one or both sides of the protective
film from an adhesive composition that includes: a copolymer (A),
the copolymer (A) being a copolymer of: a hydroxyl group-containing
(meth)acrylamide (a1), the hydroxyl group-containing
(meth)acrylamide (a1) including at least one of a hydroxyl
group-containing acrylamide and a hydroxyl group-containing
methacrylamide, and a (meth)acrylate (a2), the (meth)acrylate (a2)
including at least one of an acrylic ester and a methacrylic ester;
an antistatic agent (B), the antistatic agent (B) including an
ionic compound; and a crosslinking agent, wherein the adhesive
layer has a gel fraction, at 3 days at 23.degree. C. under a
relative humidity of 50%, of about 90 to about 100% as a
crosslinking degree.
37. The surface protection sheet as claimed in claim 36, wherein
the hydroxyl group-containing (meth)acrylamide (a1) is represented
by the following formula:
H.sub.2C.dbd.C(R1)ACONHCH.sub.2CH.sub.2OH, in which: R1 is H or
CH.sub.3, A is a linking group, the linking group being
(COOCH.sub.2CH.sub.2).sub.n,
COOCH.sub.2CH.sub.2OOC--CH.sub.2CH.sub.2, a single bond, or
Compound 1 represented by Chemical Formula 1: ##STR00004## and n is
1 or 2.
38. The surface protection sheet as claimed in claim 36, wherein
the copolymer (A) includes about 0.1 to about 10% by weight of the
hydroxyl group-containing (meth)acrylamide (a1) based on a total
weight of the copolymer (A).
39. The surface protection sheet as claimed in claim 36, wherein
the copolymer (A) includes about 50 to about 99.1% by weight of the
(meth)acrylate (a2) based on a total weight of the copolymer
(A).
40. The surface protection sheet as claimed in claim 36, wherein
the (meth)acrylate (a2) includes at least one of methyl
(meth)acrylate, ethyl (meth)acrylate, n-butyl (meth)acrylate,
t-butyl (meth)acrylate, isobutyl (meth)acrylate, hexyl
(meth)acrylate, 2-ethylhexyl (meth)acrylate, n-octyl
(meth)acrylate, isooctyl (meth)acrylate, n-nonyl (meth)acrylate,
isononyl (meth)acrylate, n-decyl (meth)acrylate, isodecyl
(meth)acrylate, n-dodecyl (meth)acrylate, n-tridecyl
(meth)acrylate, n-tetradecyl (meth)acrylate, methoxyethyl
(meth)acrylate, ethoxyethyl (meth)acrylate, butoxyethyl
(meth)acrylate, cyclohexyl (meth)acrylate, t-butylcyclohexyl
(meth)acrylate, phenoxyethyl (meth)acrylate, nonylphenoxy
polyethylene glycol (meth)acrylate, benzyl (meth)acrylate,
isobornyl (meth)acrylate, and tetrahydrofurfuryl
(meth)acrylate.
41. The surface protection sheet as claimed in claim 36, wherein
the copolymer (A) includes about 50 to about 99.89% by weight of
2-ethylhexylacrylate as the (meth)acrylate (a2) based on a total
weight of the copolymer (A).
42. The surface protection sheet as claimed in claim 36, wherein
the copolymer (A) has a polystyrene conversion weight-average
molecular weight of about 300,000 to about 1,000,000 as determined
by gel permeation chromatography.
43. The surface protection sheet as claimed in claim 36, wherein
the copolymer (A) has a glass transition temperature (Tg) of about
0.degree. C. or less.
44. The surface protection sheet as claimed in claim 36, wherein
the ionic compound includes at least one of an imidazolium salt, a
pyridinium salt, an alkyl ammonium salt, an alkyl pyrrolidium salt,
and an alkyl phosphonium salt.
45. The surface protection sheet as claimed in claim 36, wherein
the copolymer (A) is crosslinked.
46. The surface protection sheet as claimed in claim 36, wherein
the adhesive composition includes about 0.01 to about 2.0% by
weight of the antistatic agent (B).
47. The surface protection sheet as claimed in claim 36, wherein
the adhesive layer has a sheet resistance of about 1.times.10.sup.8
to about 1.times.10.sup.11 .OMEGA./cm.sup.2.
48. The surface protection sheet as claimed in claim 36, wherein
the gel fraction has a stabilizing period of about 3 days or less.
Description
CROSS-REFERENCE TO RELATED APPLICATIONS
[0001] This application is a continuation of pending U.S. patent
application Ser. No. 12/801,109, filed on May 24, 2010, which in
turn is a continuation of International Application No.
PCT/KR2008/006501, entitled "Adhesive Composition, and Optical
Member, Surface Protective Sheet," which was filed on Nov. 4, 2008,
the entire contents of all of which are hereby incorporated by
reference.
BACKGROUND
1. Field
[0002] The present invention relates to adhesive compositions,
optical members, and surface protective sheet.
2. Related Art
[0003] As in cathode ray tubes, a surface of a flat display panel
also tends to be charged with static electricity. When the surface
of the flat display panel is charged with the static electricity,
dust in air can often be attracted to a display plane of the panel.
Further, the static electricity can have a negative influence on a
display circuit of a substrate constituting the flat display panel
or on orientation of liquid crystal molecules in the panel, thereby
causing display malfunction.
[0004] When examining display performance of the flat display
panel, it is necessary to remove a surface protective film which
can cause optical obstruction. To remove the surface protective
film, the surface protective film is peeled off at a rate of about
10 m/min to reduce a process time. Such a relatively high rate of
peeling off the surface protective film causes the display plane to
be easily charged with the static electricity.
SUMMARY
[0005] It is a feature of an embodiment to provide an adhesive
composition, which may have a short aging time resulting in high
productivity and permit the formation of an adhesive layer
exhibiting good antistatic performance, and an optical member and
surface protective film comprising the same.
[0006] It is another feature of an embodiment to provide an optical
member that includes the adhesive composition coated on one or both
sides of an optical sheet, thereby providing a short aging time
resulting in high productivity, while exhibiting good antistatic
performance.
[0007] It is another feature of an embodiment to provide a surface
protection sheet that includes a protective film and an adhesive
layer comprising the adhesive composition on one or both sides of
the protective film, thereby providing a short aging time resulting
in high productivity, while exhibiting good antistatic
performance.
[0008] At least one of the above and other features and advantages
may be realized by providing an adhesive composition, including: a
copolymer (A), the copolymer (A) being a copolymer of: a hydroxyl
group-containing (meth)acrylamide (a1), the hydroxyl
group-containing (meth)acrylamide (a1) including at least one of a
hydroxyl group-containing acrylamide and a hydroxyl
group-containing methacrylamide, and a (meth)acrylate (a2), the
(meth)acrylate (a2) including at least one of an acrylic ester and
a methacrylic ester; and an antistatic agent (B), the antistatic
agent (B) including an ionic compound.
[0009] The hydroxyl group-containing (meth)acrylamide (a1) may be
represented by the following formula:
H.sub.2C.dbd.C(R1)ACONHCH.sub.2CH.sub.2OH, in which R1 is H or
CH.sub.3, A is a linking group, the linking group being
(COOCH.sub.2CH.sub.2).sub.n,
COOCH.sub.2CH.sub.2OOC--CH.sub.2CH.sub.2, a single bond, or
Compound 1 represented by Chemical Formula 1:
##STR00001##
and
[0010] n is 1 or 2.
[0011] The adhesive composition may be for an optical member, and
the copolymer (A) may include about 0.1 to about 5% by weight of
the hydroxyl group-containing (meth)acrylamide (a1) based on a
total weight of the copolymer (A).
[0012] The adhesive composition may be for a surface protection
sheet, and the copolymer (A) may include about 0.1 to about 10% by
weight of the hydroxyl group-containing (meth)acrylamide (a1) based
on a total weight of the copolymer (A).
[0013] The copolymer (A) may include about 50 to about 99.1% by
weight of the (meth)acrylamide (a2) based on a total weight of the
copolymer (A).
[0014] The (meth)acrylamide (a2) may include at least one of methyl
(meth)acrylate, ethyl (meth)acrylate, n-butyl (meth)acrylate,
t-butyl (meth)acrylate, isobutyl (meth)acrylate, hexyl
(meth)acrylate, 2-ethylhexyl (meth)acrylate, n-octyl
(meth)acrylate, isooctyl (meth)acrylate, n-nonyl (meth)acrylate,
isononyl (meth)acrylate, n-decyl (meth)acrylate, isodecyl
(meth)acrylate, n-dodecyl (meth)acrylate, n-tridecyl
(meth)acrylate, n-tetradecyl (meth)acrylate, methoxyethyl
(meth)acrylate, ethoxyethyl (meth)acrylate, butoxyethyl
(meth)acrylate, cyclohexyl (meth)acrylate, t-butylcyclohexyl
(meth)acrylate, phenoxyethyl (meth)acrylate, nonylphenoxy
polyethylene glycol (meth)acrylate, benzyl (meth)acrylate,
isobornyl (meth)acrylate, and tetrahydrofurfuryl
(meth)acrylate.
[0015] The adhesive composition may be for an optical member, and
the copolymer (A) may include about 80 to about 99.89% by weight of
n-butyl acrylate as the (meth)acrylamide (a2) based on a total
weight of the copolymer (A).
[0016] The adhesive composition may be for an optical member, and
the copolymer (A) may include about 0.1 to about 5% by weight of
hydroxyethylacrylamide as the hydroxyl group-containing
(meth)acrylamide (a1) based on a total weight of the copolymer
(A).
[0017] The copolymer may be for a surface protective film, and the
copolymer (A) may include about 50 to about 99.89% by weight of
2-ethylhexylacrylate as the (meth)acrylamide (a2) based on a total
weight of the copolymer (A).
[0018] The adhesive composition may be for an optical member, and
the base polymer (A) may have a polystyrene conversion
weight-average molecular weight of about 1,000,000 to about
2,000,000 as determined by gel permeation chromatography.
[0019] The adhesive composition may be for a surface protection
sheet, and the base polymer (A) may have a polystyrene conversion
weight-average molecular weight of about 300,000 to about 1,000,000
as determined by gel permeation chromatography.
[0020] The base polymer (A) may have a glass transition temperature
(Tg) of about 0.degree. C. or less.
[0021] The ionic compound may include at least one of an
imidazolium salt, a pyridinium salt, an alkyl ammonium salt, an
alkyl pyrrolidium salt, and an alkyl phosphonium salt.
[0022] The copolymer (A) may be crosslinked.
[0023] The adhesive composition may be for an optical member, and
the copolymer (A) may have a gel fraction of about 50 to about 80%
as a crosslinking degree.
[0024] The adhesive composition may be for a surface protection
sheet, and the copolymer (A) may have a gel fraction of about 90 to
about 100% as a crosslinking degree.
[0025] The adhesive composition may include about 0.01 to about
2.0% by weight of the antistatic agent (B).
[0026] At least one of the above and other features and advantages
may also be realized by providing an optical member, including an
optical sheet, and an adhesive layer, the adhesive layer being
formed by coating the adhesive composition according to an
embodiment on one or both sides of the optical sheet.
[0027] The adhesive layer may have a sheet resistance of about
1.times.10.sup.8 to about 1.times.10.sup.11 .OMEGA./cm.sup.2.
[0028] At least one of the above and other features and advantages
may also be realized by providing a surface protection sheet,
including a protective film, and an adhesive layer formed on one or
both sides of the protective film, the adhesive layer including the
adhesive composition according to an embodiment.
[0029] The adhesive layer may have a sheet resistance of about
1.times.10.sup.8 to about 1.times.10.sup.11 .OMEGA./cm.sup.2.
BRIEF DESCRIPTION OF THE DRAWINGS
[0030] The above and other features and advantages will become more
apparent to those of skill in the art by describing in detail
example embodiments with reference to the attached drawings, in
which:
[0031] FIGS. 1 through 8 illustrate Tables 1 through 8,
respectively.
DETAILED DESCRIPTION
[0032] Japanese Patent Application No. 2007-302702, filed on Nov.
22, 2007, in the Japanese Patent Office, and entitled: "Adhesive
Composition, and Optical Member, Surface Protective Sheet," is
incorporated by reference herein in its entirety.
[0033] Example embodiments will now be described more fully
hereinafter with reference to the accompanying drawings; however,
they may be embodied in different forms and should not be construed
as limited to the embodiments set forth herein. Rather, these
embodiments are provided so that this disclosure will be thorough
and complete, and will fully convey the scope of the invention to
those skilled in the art.
[0034] Adhesive Composition
[0035] According to an embodiment, an adhesive composition includes
a copolymer (A) and an antistatic agent (B). The copolymer (A) may
be formed by copolymerization of a hydroxyl group-containing
(meth)acrylamide (a1) and a (meth)acrylate (a2). The hydroxyl
group-containing (meth)acrylamide (a1) may include a hydroxyl
group-containing acrylamide, a hydroxyl group-containing
methacrylamide, or a combinations thereof. The (meth)acrylate (a2)
may include an acrylic ester, a methacrylic ester, or a combination
thereof. The antistatic agent (B) may include an ionic
compound.
[0036] The base polymer (A), i.e., the copolymer (A), may be
crosslinked by a crosslinking agent. In an example embodiment, the
antistatic agent may be added to the base polymer (A) so that an
adhesive layer formed by coating the adhesive composition on a
substrate such as optical sheets or protective films has a surface
resistance of, for example, about 1.times.10.sup.8 to about
1.times.10.sup.11 .OMEGA./cm.sup.2.
[0037] Base Polymer
[0038] According to this embodiment, the base polymer may be formed
by copolymerization of: (hereinafter, referred to as the "hydroxyl
group-containing (meth)acrylamide (a1)") hydroxyl group-containing
acrylamides, hydroxyl group-containing methacrylamides, or
combinations thereof; and (hereinafter, referred to as the
"(meth)acrylate (a2)") acrylic esters, methacrylic esters, or
combinations thereof.
[0039] When using the adhesive composition according to this
embodiment for an optical member, the base polymer (A) may contain
about 0.1 to about 5 wt. % of the hydroxyl group-containing
(meth)acrylamide (a1) based on a total weight of the base polymer
(A). If the amount of the hydroxyl group-containing
(meth)acrylamide (a1) is less than about 0.1 wt. % in the base
polymer (A), there is a possibility of insufficiently enhancing the
antistatic performance. If the amount of the hydroxyl
group-containing (meth)acrylamide (a1) exceeds about 0.5 wt. % in
the base polymer (A), there is a possibility of providing
insufficient durability.
[0040] Further, when using the adhesive composition according to
this embodiment for a surface protection sheet, the base polymer
(A) may contain about 0.1 to about 10 wt. % of the hydroxyl
group-containing (meth)acrylamide (a1) based on a total weight of
the base polymer (A).
[0041] If the amount of the hydroxyl group-containing
(meth)acrylamide (a1) is less than about 0.1 wt. % in the base
polymer (A), there is a possibility of insufficiently enhancing the
antistatic performance. If the amount of the hydroxyl
group-containing (meth)acrylamide (a1) exceeds about 10 wt. % in
the base polymer (A), there is a possibility of providing
insufficient adhesion to the protective film or insufficient
transparency to the adhesive layer.
[0042] Examples of the hydroxyl group-containing (meth)acrylamide
(a1) include H.sub.2C.dbd.C(R1)ACONHCH.sub.2CH.sub.2OH (where R1
represents H or CH.sub.3, and A represents a linking group). The
linking group may be, e.g., a single bond. The linking group may
be, e.g., (COOCH.sub.2CH.sub.2).sub.n or
COOCH.sub.2CH.sub.2OOC--CH.sub.2CH.sub.2, which may be bonded via
terminal carbons thereof, and in which n may be 1 or 2. The linking
group may be, e.g., Compound 1 represented by the following
Chemical Formula 1, which may be bonded via a terminal carbon and a
carbon of the aromatic ring.
##STR00002##
[0043] The hydroxyl group-containing (meth)acrylamide (a1) may
include hydroxyethyl acrylamide (HEAA) and the like.
[0044] The (meth)acrylate (a2) may be a main element of the base
polymer (A), e.g., it may be present in an amount of about 50 to
about 99.1 wt. % based on a total amount of the base polymer (A).
The base polymer (A) may include a single (meth)acrylate (a2), or
may include two or more (meth)acrylates (a2).
[0045] Examples of the (meth)acrylate (a2) include methyl
(meth)acrylate, ethyl (meth)acrylate, n-butyl (meth)acrylate,
t-butyl (meth)acrylate, isobutyl (meth)acrylate, hexyl
(meth)acrylate, 2-ethylhexyl (meth)acrylate, n-octyl
(meth)acrylate, isooctyl (meth)acrylate, n-nonyl (meth)acrylate,
isononyl (meth)acrylate, n-decyl (meth)acrylate, isodecyl
(meth)acrylate, n-dodecyl (meth)acrylate, n-tridecyl
(meth)acrylate, n-tetradecyl (meth)acrylate, methoxyethyl
(meth)acrylate, ethoxyethyl (meth)acrylate, butoxyethyl
(meth)acrylate, cyclohexyl (meth)acrylate, t-butylcyclohexyl
(meth)acrylate, phenoxyethyl (meth)acrylate, nonylphenoxy
polyethylene glycol (meth)acrylate, benzyl (meth)acrylate,
isobornyl (meth)acrylate, tetrahydrofurfuryl (meth)acryl ate, and
the like.
[0046] It is desirable that the base polymer (A) of the adhesive
composition for the optical member contain n-butyl acrylate as a
main element of the (meth)acrylate in order to realize high
adhesion.
[0047] Further, it is desirable that the base polymer (A) of the
adhesive composition for the surface protection sheet contain
2-ethylhexyl acrylate as a main element of the (meth)acrylate (a2)
to exhibit a degree of adhesion that allows easy separation of the
surface protection sheet.
[0048] The base polymer (A) may be an acrylate polymer that
includes one or more of the (meth)acrylates (a2) as main elements,
since the acrylate polymer has good compatibility with ionic
compounds and provides good adhesive properties.
[0049] When using the adhesive composition of this embodiment for
the optical member, the base polymer (A) may have a weight-average
molecular weight of about 1,000,000 to about 2,000,000. When the
weight-average molecular weight of the base polymer (A) is in the
range of about 1,000,000 to about 2,000,000, the adhesive
composition may provide a sufficient adhesive force as a
composition constituting an adhesive layer of the optical
member.
[0050] The weight-average molecular weight of the base polymer (A)
can be obtained by polystyrene conversion and gel permeation
chromatography.
[0051] Further, the base polymer (A) may have a glass transition
temperature Tg of about 0.degree. C. or less. In an implementation,
the base polymer (A) may have a glass transition temperature Tg of
about -100 to about -5.degree. C., and more advantageously a glass
transition temperature Tg of about -80 to about -10.degree. C. If
the glass transition temperature Tg is less than or equal to about
0.degree. C., the adhesive composition may provide a higher
adhesive force when containing an ionic compound.
[0052] In another implementation, the base polymer (A) may contain
other components besides, i.e., in addition to or instead of, the
hydroxyl group-containing (meth)acrylamide (a1) and the
(meth)acrylate (a2).
[0053] The other components of the base polymer may include
components for enhancing cohesive force and thermal resistance,
such as sulfonic acid group-containing monomers, phosphoric acid
group-containing monomers, cyano group-containing monomers, vinyl
esters, aromatic vinyl compounds, and the like, or components
having functional groups capable of enhancing the adhesive force or
capable of acting as a crosslink starter, such as carboxyl
group-containing monomers, acid anhydride group-containing
monomers, hydroxyl group-containing monomers, amide
group-containing monomers, amino group-containing monomers, epoxy
group-containing monomers, N-acryloyl morpholine, vinyl ethers, and
the like. The other components may be used alone or in combination
of two or more kinds of components.
[0054] Examples of the sulfonic acid group-containing monomers may
include styrene sulfonic acid, allyl sulfonic acid,
2-(meth)acrylamido-2-methylpropane sulfonic acid,
methacrylamidopropane sulfonic acid, sulfopropyl (meth)acrylate,
(meth)acryloyloxynaphthalene sulfonic acid, and the like.
[0055] An example of the phosphoric acid group-containing monomers
may include 2-hydroxyethyl acryloyl phosphate.
[0056] An example of the cyano group-containing monomers may
include acrylonitrile.
[0057] An example of the vinyl esters may include vinyl
acetate.
[0058] An example of the aromatic vinyl compounds may include
styrene.
[0059] Examples of the carboxyl group-containing monomers may
include (meth)acrylic acid, carboxyethyl(meth)acrylate,
carboxypentyl(meth)acrylate, itaconic acid, maleic acid, crotonic
acid, 2-carboxyethyl acrylate, and the like.
[0060] Examples of the acid anhydride group-containing monomers
include maleic anhydride, itaconic anhydride, and the like.
[0061] Examples of the hydroxyl group-containing monomers may
include 2-hydroxyethyl (meth)acrylate, 2-hydroxypropyl
(meth)acrylate, 4-hydroxybutyl (meth)acrylate, 6-hydroxyhexyl
(meth)acrylate, 8-hydroxyoctyl (meth)acrylate, 10-hydroxydecyl
(meth)acrylate, 12-hydroxylauryl (meth)acrylate,
(4-hydroxymethylcyclohexyl)methyl acrylate, N-methylol
(meth)acrylamide, vinyl alcohol, allyl alcohol, 2-hydroxyethyl
vinyl ether, 4-hydroxybutyl vinyl ether, diethyleneglycol monovinyl
ether, and the like.
[0062] Examples of the amide group-containing monomers may include
acrylamide, diethyl acrylamide, and the like.
[0063] Examples of the amino group-containing monomers may include
N,N-dimethylaminoethyl (meth)acrylate, N,N-dimethylaminopropyl
(meth)acrylate, and the like.
[0064] Examples of the epoxy group-containing monomers may include
glycidyl (meth)acrylate, allylglycidyl ether, and the like.
[0065] An example of the vinyl ethers may include vinyl ethyl
ether.
[0066] Examples of a method of polymerizing the base polymer (A)
may include solution polymerization, emulsion polymerization, bulk
polymerization, suspension polymerization, and the like.
[0067] For the polymerization of the base polymer (A), a
polymerization initiator may be used. Examples of the
polymerization initiator may include peroxides such as benzoyl
peroxide, lauroyl peroxide, and the like; and azobis compounds such
as azobisisobutyronitrile (AIBN), azobisvaleronitrile, and the
like.
[0068] Crosslinking Agent
[0069] In an example embodiment, the adhesive composition may be
crosslinked, which may provide an adhesive layer having excellent
thermal resistance. The base polymer (A) may be crosslinked, e.g.,
at the acrylic polymer (a2), which may be the main element of the
base polymer (A).
[0070] Crosslinking may be conducted by a method using a
crosslinking agent in which a compound containing a group is added
to react with a carboxyl group, a hydroxyl group, an amino group,
an amide group, or the like contained as a crosslinking starter in
an acrylic polymer such as one containing isocyanate compounds,
epoxy compounds, aziridine compounds, and/or metal chelate
compounds.
[0071] Examples of the isocyanate compounds may include aromatic
diisocyanates such as tolylene diisocyanate and xylene
diisocyanate; alicyclic diisocyanates such as isophoron
diisocyanate; and aliphatic isocyanates, such as hexamethylene
diisocyanate. In particular, the isocyanate compounds or the epoxy
compounds may be used in view of their cohesive properties. These
compounds may be used alone or in a combination of at least two
kinds.
[0072] More specifically, examples of the isocyanate compounds may
include: low aliphatic polyisocyanates such as butylene
diisocyanate and hexamethylene diisocyanate; alicyclic isocyanates
such as cyclopentylene diisocyanate, cyclohexylene diisocyanate,
and isophorone diisocyanate; aromatic isocyanates such as
2,4-tolylene diisocyanate, 4,4'-diphenylmethane diisocyanate, and
xylylene diisocyanate; and isocyanate adducts such as a
trimethylolpropane/tolylene diisocyanate trimer adduct (trademark:
Coronate L), a trimethylolpropane/hexamethylene diisocyanate trimer
adduct (trademark: Coronate HL), and an isocyanurate product of
hexamethylene diisocyanate (trademark: Coronate HX) (all
manufactured by Nippon Polyurethane Industry Co., Ltd.).
[0073] Examples of the epoxy compounds may include
N,N,N',N'-tetraglycidyl-m-xylenediamine (trademark: TETRAD-X) and
1,3-bis(N,N-diglycidylaminomethyl)cyclohexane (trademark: TETRAD-C)
(all manufactured by Mitsubishi Gas Chemical Co., Inc.).
[0074] These crosslinking agents may be used alone or in a
combination of two or more kinds. The content of the crosslinking
agent may be selected according to balance with a crosslinking
target base polymer, and according to applications of the optical
member. To achieve sufficient thermal resistance by the cohesive
force of the acrylate adhesive agent, the content of the
crosslinking agent may be about 0.01 parts by weight or more based
on 100 parts by weight of the base polymer. Further, in view of
flexibility and adhesion, the content of the crosslinking agent may
be about 0.05 parts by weight or less based on 100 parts by weight
of the base polymer.
[0075] When the adhesive composition according to this embodiment
is used for the optical member, the base polymer (A) of the
adhesive composition may have a gel fraction of about 50 to about
80% as a crosslinking degree, and more advantageously a gel
fraction of about 70% as a crosslinking degree, which may help
increase the adhesive force of the adhesive composition.
[0076] When the adhesive composition according to this embodiment
is used for the surface protection sheet, the base polymer (A) of
the adhesive composition may have a gel fraction of about 90 to
about 100% as a crosslinking degree, whereby the adhesive force of
the adhesive composition may be decreased so as to facilitate the
separation of the surface protection sheet.
[0077] The gel fraction may be obtained from an initial mass of the
adhesive composition (before digestion) and a mass thereof after
immersing and drying in the case where the adhesive composition is
immersed in ethyl acetate at 25.degree. C. for 1 day, as calculated
by Equation: Gel Fraction=[Mass after immersing and drying/Initial
Mass].times.100.
[0078] Antistatic Agent
[0079] The antistatic agent may include an ionic compound.
[0080] The ionic compound may be selected to have compatibility
with the base polymer and an organic solvent used in the
preparation of the adhesive composition, while allowing
transparency of the adhesive composition to be maintained when the
ionic compound is added to the base polymer. Further, the ionic
compound may be selected to have a surface resistance of about
1.times.10.sup.11 .OMEGA./cm.sup.2 or less when the adhesive
composition is applied to a substrate such as the optical sheet or
the protective film.
[0081] The ionic compound may include one or more of an imidazolium
salt, a pyridinium salt, an alkyl ammonium salt, an alkyl
pyrrolidium salt, and an alkyl phosphonium salt.
[0082] Examples of the imidazolium salt include
1,3-dimethylimidazolium chloride, 1-butyl-2,3-dimethylimidazolium
chloride, 1-butyl-3-methylimidazolium bromide,
1-butyl-3-methylimidazolium chloride, 1-butyl-3-methylimidazolium
methane sulfonate,
1-butyl-1-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)-imidazolium
hexafluorophosphate, 1-ethyl-3-methylimidazolium bromide,
1-ethyl-3-methylimidazolium chloride, 1-ethyl-3-methylimidazolium
hexafluorophosphate, 1-ethyl-3-methylimidazolium iodide,
1-ethyl-2,3-dimethylimidazolium chloride, 1-methylimidazolium
chloride, 1,2,3-trimethylimidazolium methyl sulfate,
1-methyl-3-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)-imidazolium
hexafluorophosphate, 1-aryl-3-methylimidazolium chloride,
1-benzyl-3-methylimidazolium chloride, 1-benzyl-3-methylimidazolium
hexafluorophosphate, 1-benzyl-3-methylimidazolium
tetrafluorophosphate, and the like.
[0083] Examples of the pyridinium salt include
1-butyl-3-methylpyridinium bromide, 1-butyl-4-methylpyridinium
bromide, 1-butyl-4-methylpyridinium chloride, 1-butylpyridinium
bromide, 1-butylpyridinium chloride, 1-butylpyridinium
hexafluorophosphate, 1-ethylpyridinium bromide, 1-ethylpyridinium
chloride, and the like.
[0084] Examples of the alkyl ammonium salt include
cyclohexyltrimethylammonium bis(trifluoromethylsulfonyl)imide,
tetra-n-butylammonium chloride, tetrabutylammonium bromide,
tributylmethylammonium methylsulfate, tetrabutylammonium
bis(trifluoromethylsulfonyl)imide, tetraethylammonium
trifluoromethanesulfonate, tetrabutylammonium benzoate,
tetrabutylammonium methanesulfate, tetrabutylammonium
nonafluorobutanesulfonate, tetra-n-butylammonium
hexafluorophosphate, tetrabutylammonium trifluoroacetate,
tetrahexylammonium tetrafluoroborate, tetrahexylammonium bromide,
tetrahexylammonium iodide, tetraoctylammonium chloride,
tetraoctylammonium bromide, tetraheptylammonium bromide,
tetrapentylammonium bromide, n-hexadecyltrimethylammonium
hexafluorophosphate, and the like.
[0085] Examples of the alkyl pyrrolidium salt include
1-butyl-3-methylpyrrolidium bromide, 1-butyl-1-methylpyrrolidium
chloride, 1-butyl-1-methylpyrrolidium tetrafluoroborate, and the
like.
[0086] Examples of the alkyl phosphonium salt include
tetrabutylphosphonium bromide, tetrabutylphosphonium chloride,
tetrabutylphosphonium tetrafluoroborate, tetrabutylphosphonium
methanesulfonate, tetrabutylphosphonium p-toluenesulfonate,
tributylhexadecylphosphonium bromide, and the like.
[0087] For the ionic compound, a nitrogen-containing onium salt, a
sulfur-containing onium salt, or a phosphorous-containing onium
salt may be used.
[0088] Examples may include 1-butylpyridinium tetrafluoroborate,
1-butylpyridinium hexafluorophosphate, 1-butyl-3-methylpyridinium
tetrafluoroborate, 1-butyl-3-methylpyridinium
trifluoromethanesulfonate, 1-butyl-3-methylpyridinium
bis(trifluoromethanesulfonyl)imide, 1-butyl-3-methylpyridinium
bis(pentafluoroethanesulfonyl)imide, 1-hexylpyridinium
tetrafluoroborate, 2-methyl-1-pyrrolin tetrafluoroborate,
1-ethyl-2-phenylindole tetrafluoroborate, 1,2-dimethylindole
tetrafluoroborate, 1-ethylcarbazole tetrafluoroborate,
1-ethyl-3-methylimidazolium tetrafluoroborate,
1-ethyl-3-methylimidazolium acetate, 1-ethyl-3-methylimidazolium
trifluoroacetate, 1-ethyl-3-methylimidazolium heptafluorobutyrate,
1-ethyl-3-methylimidazolium trifluoromethanesulfonate,
1-ethyl-3-methylimidazolium perfluorobutanesulfonate,
1-ethyl-3-methylimidazolium dicyanamide,
1-ethyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide,
1-ethyl-3-methylimidazolium bis(pentafluoroethanesulfonyl)imide,
1-ethyl-3-methylimidazolium tris(trifluoromethanesulfonyl)methide,
1-butyl-3-methylimidazolium tetrafluoroborate,
1-butyl-3-methylimidazolium hexafluorophosphate,
1-butyl-3-methylimidazolium trifluoroacetate,
1-butyl-3-methylimidazolium heptafluorobutyrate,
1-butyl-3-methylimidazolium trifluoromethanesulfonate,
1-butyl-3-methylimidazolium perfluorobutanesulfonate,
1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide,
1-hexyl-3-methylimidazolium bromide, 1-hexyl-3-methylimidazolium
chloride, 1-hexyl-3-methylimidazolium tetrafluoroborate,
1-hexyl-3-methylimidazolium hexafluorophosphate,
1-hexyl-3-methylimidazolium trifluoromethanesulfonate,
1-octyl-3-methylimidazolium tetrafluoroborate,
1-octyl-3-methylimidazolium hexafluorophosphate,
1-hexyl-2,3-dimethylimidazolium tetrafluoroborate,
1,2-dimethyl-3-propylimidazolium
bis(trifluoromethanesulfonyl)imide, 1-methylpyrazolium
tetrafluoroborate, 3-methylpyrazolium tetrafluoroborate,
tetrahexylammonium bis(trifluoromethanesulfonyl)imide,
diallyldimethylammonium tetrafluoroborate, diallyldimethylammonium
trifluoromethanesulfonate, diallyldimethylammonium
bis(trifluoromethanesulfonyl)imide, diallyldimethylammonium
bis(pentafluoroethanesulfonyl)imide,
N,N-diethyl-N-methyl-N-(2-methoxyethyl)ammonium tetrafluoroborate,
N,N-diethyl-N-methyl-N-(2-methoxyethyl)ammonium
trifluoromethanesulfonate,
N,N-diethyl-N-methyl-N-(2-methoxyethyl)ammonium
bis(trifluoromethanesulfonyl)imide,
N,N-diethyl-N-methyl-N-(2-methoxyethyl)ammonium
bis(pentafluoroethanesulfonyl)imide, glycidyltrimethylamonium
trifluoromethanesulfonate, glycidyltrimethylamonium
bis(trifluoromethanesulfonyl)imide, glycidyltrimethylammonium
bis(pentafluoroethanesulfonyl)imide, 1-butylpyridinium
(trifluoromethanesulfonyl)trifluoroacetamide,
1-butyl-3-methylpyridinium
(trifluoromethanesulfonyl)trifluoroacetamide,
1-ethyl-3-methylimidazolium
(trifluoromethanesulfonyl)trifluoroacetamide,
diallyldimethylammonium(trifluoromethanesulfonyl)trifluoroacetamide,
glycidyltrimethylammonium(trifluoromethanesulfonyl)trifluoroacetamide,
N,N-dimethyl-N-ethyl-N-propylammonium
bis(trifluoromethanesulfonyl)imide,
N,N-dimethyl-N-ethyl-N-butylammonium
bis(trifluoromethanesulfonyl)imide,
N,N-dimethyl-N-ethyl-N-pentylammonium
bis(trifluoromethanesulfonyl)imide,
N,N-dimethyl-N-ethyl-N-hexylammonium
bis(trifluoromethanesulfonyl)imide,
N,N-dimethyl-N-ethyl-N-heptylammonium
bis(trifluoromethanesulfonyl)imide,
N,N-dimethyl-N-ethyl-N-nonylamonium
bis(trifluoromethanesulfonyl)imide,
N,N-dimethyl-N,N-dipropylammonium
bis(trifluoromethanesulfonyl)imide,
N,N-dimethyl-N-propyl-N-butylammonium
bis(trifluoromethanesulfonyl)imide,
N,N-dimethyl-N-propyl-N-pentylammonium
bis(trifluoromethanesulfonyl)imide,
N,N-dimethyl-N-propyl-N-hexylammonium
bis(trifluoromethanesulfonyl)imide,
N,N-dimethyl-N-propyl-N-heptylammonium
bis(trifluoromethanesulfonyl)imide,
N,N-dimethyl-N-butyl-N-hexylammonium
bis(trifluoromethanesulfonyl)imide,
N,N-dimethyl-N-butyl-N-heptylammonium
bis(trifluoromethanesulfonyl)imide,
N,N-dimethyl-N-pentyl-N-hexylammonium
bis(trifluoromethanesulfonyl)imide,
N,N-dimethyl-N,N-dihexylammonium
bis(trifluoromethanesulfonyl)imide, trimethylheptylammonium
bis(trifluoromethanesulfonyl)imide,
N,N-diethyl-N-methyl-N-propylammonium
bis(trifluoromethanesulfonyl)imide,
N,N-diethyl-N-methyl-N-pentylammonium
bis(trifluoromethanesulfonyl)imide,
N,N-diethyl-N-methyl-N-heptylammonium
bis(trifluoromethanesulfonyl)imide,
N,N-diethyl-N-propyl-N-pentylammonium
bis(trifluoromethanesulfonyl)imide, triethylpropylammonium
bis(trifluoromethanesulfonyl)imide, triethylpentylammonium
bis(trifluoromethanesulfonyl)imide, triethylheptylammonium
bis(trifluoromethanesulfonyl)imide,
N,N-dipropyl-N-methyl-N-ethylammonium
bis(trifluoromethanesulfonyl)imide,
N,N-dipropyl-N-methyl-N-pentylammonium
bis(trifluoromethanesulfonyl)imide,
N,N-dipropyl-N-butyl-N-hexylammonium
bis(trifluoromethanesulfonyl)imide,
N,N-dipropyl-N,N-dihexylammonium
bis(trifluoromethanesulfonyl)imide,
N,N-dibutyl-N-methyl-N-pentylammonium
bis(trifluoromethanesulfonyl)imide,
N,N-dibutyl-N-methyl-N-hexylammonium
bis(trifluoromethanesulfonyl)imide, trioctylmethylammonium
bis(trifluoromethanesulfonyl)imide, and
N-methyl-N-ethyl-N-propyl-N-pentylammonium
bis(trifluoromethanesulfonyl)imide, and the like.
[0089] Ingredient Ratio of Base Polymer (A) and Antistatic Agent
(B)
[0090] An ingredient ratio of the antistatic agent (B) with respect
to a total amount of the base polymer (A) and antistatic agent (B)
may be about 0.01 wt. % to about 2 wt. %. If the ingredient ratio
is less than about 0.01 wt. %, a sufficient antistatic effect may
not be obtained, whereas if the ingredient ratio exceeds about 2
wt. %, there is a possibility of contamination of an attachment
target.
[0091] Other Additives
[0092] The adhesive composition may further contain other additives
for providing adhesive properties. For example, a surface
lubricant, a leveling agent, an antioxidant, an anti-corrosion
agent, a light stabilizer, an ultraviolet absorbing agent, a
polymerization inhibitor, a silane coupling agent, an inorganic or
organic filler, a metal powder, a pigment powder, or a particle or
foil-shaped material may be appropriately added according to
intended use.
[0093] Preparation Method of Adhesive Composition
[0094] Examples of a method of preparing the adhesive composition
according to an embodiment may include the following two
methods.
[0095] In one method, a variety of monomers, which are the raw
materials of the base polymer (A), are mixed with an organic
solvent having a boiling point of 120.degree. C. or less, such as
ethyl acetate, toluene, acetone, hexane, ketones, and alcohols, and
are polymerized by the addition of a polymerization initiator,
thereby preparing the base polymer. The base polymer may be, e.g.,
a random copolymer. The obtained base polymer may be in a dissolved
state or expanded in the organic solvent.
[0096] Next, an antistatic agent, which may include one or more
ionic compounds, is added to the organic solvent containing the
base polymer to be mixed with the base polymer.
[0097] Subsequently, a crosslinking agent is added to crosslink the
base polymer, and additives such as the silane coupling agent and
the like are further added as needed. As a result, the adhesive
composition may be prepared.
[0098] The adhesive composition obtained is applied to a substrate
such as the optical sheet or the surface protective film, and
dried, thereby forming an adhesive layer on the substrate.
[0099] In another method, a variety of monomers, which are the raw
materials of the base polymer (A), are mixed with an organic
solvent such as ethyl acetate while adding the antistatic agent
consisting of the ionic compounds thereto at the same time, and are
then polymerized by the addition of the polymerization initiator,
thereby preparing the base polymer containing the antistatic agent.
As in the above method, the base polymer obtained may be in a
dissolved state or expanded in the organic solvent.
[0100] Next, the crosslinking agent is added to the organic solvent
containing the base polymer and the antistatic agent to crosslink
the base polymer, and the additives such as the silane coupling
agent and the like are further added as needed. As a result, the
adhesive composition may be prepared.
[0101] As in the above method, the obtained adhesive composition is
applied to the substrate such as the optical sheet or the surface
protective film and dried, thereby forming the adhesive layer on
the substrate.
[0102] As described above, when preparing the adhesive composition
according to this embodiment, the antistatic agent may be added
after the preparation of the base polymer, or may be added while
preparing the base polymer. In order to uniformly add the
antistatic agent to the base polymer, the antistatic agent is
advantageously soluble in the organic solvent such as ethyl
acetate.
[0103] Optical Member
[0104] An optical member according to an embodiment may be formed
by coating the adhesive composition according to the embodiment of
the invention on one or both sides of an optical sheet. For the
optical member according to this embodiment, an adhesive layer
containing the adhesive composition may be formed to a thickness of
about 3 to about 200 .mu.m, and advantageously about 10 to about
100 .mu.m, on one or both sides of the optical sheet. The formation
of the adhesive layer may be achieved by directly coating the
adhesive composition on the optical sheet or by coating the
adhesive composition on a separate substrate (such as a separation
liner or the like) and transferring the coated adhesive composition
to the optical sheet.
[0105] As a method of forming the adhesive layer, any known method
used for preparing an adhesive tape may be used. Specifically,
examples of the method include roll coating, gravure coating,
reverse coating, roll brushing, spray coating, air-knife coating,
die-coat methods, and the like.
[0106] According this embodiment, a variety of optical sheets for
use in manufacture of a variety of displays may be used without
being limited to a specific optical sheet. Examples of the optical
sheet include a polarizer, a phase difference plate, a brightness
enhancing plate, and a glare reducing sheet. Further, the optical
sheet according to this embodiment may be obtained by stacking two
or more optical materials, such as a stack of the polarizer and the
phase difference plate, a stack of the polarizers, a stack of phase
difference plates, a stack of the polarizer and the brightness
enhancing plate or the glare reducing sheet, and the like.
[0107] The adhesive layer (adhesive composition) formed on the
optical sheet may have an adhesive force of about 1 (N/25 mm) to
about 15 (N/25 mm), and more advantageously an adhesive force of
about 5 (N/25 mm) to about 10 (N/25 mm). When the adhesive force is
in the range of 1 (N/25 mm) to about 15 (N/25 mm), it will be
sufficient for the adhesive layer of the optical member. The
adhesive force can be measured according to JIS Z0237, which
regulates a method for testing an adhesive tape and an adhesive
sheet. In more detail, an optical member having an adhesive layer
may be evaluated for adhesive force by the following process: the
optical member may be left for seven days at 23.degree. C. under a
relative humidity of 50%, cut into a width of 25 mm, autoclaved at
50.degree. C. and at 5 kg/cm.sup.2.times.20 min in a state of being
adhered to, for example, the polarizer; and measured for adhesive
force at 23.degree. C. under a relative humidity of 50% using a
tensile tester at a peeling angle of 180 degrees and at a peeling
rate of 0.3 m/min according to JIS Z0237.
[0108] Surface Protection Sheet
[0109] A surface protection sheet for an optical member according
to an embodiment may include a protective film and an adhesive
layer formed on one or both sides of the protective film, in which
the adhesive layer includes the adhesive composition according to
an embodiment. The adhesive layer of the adhesive composition may
be formed to a thickness of about 3 to about 200 .mu.m, and
advantageously about 10 to about 100 .mu.m, on one or both sides of
the protective film.
[0110] Examples of the protective film may include resin films,
such as polyethylene terephthalate, polyethylene, polypropylene,
ethylene-acetate vinyl copolymer, polyester, polyvinyl chloride,
polycarbonate, polyamide, polystyrene films, and combinations
thereof. Advantageously, a polyethylene terephthalate film may be
used. The protective film may have a thickness of, for example,
about 15 to about 20 .mu.m.
[0111] The formation of the adhesive layer on the protective film
may be achieved by directly coating the adhesive composition on the
protective film, or by coating the adhesive composition on a
separate substrate (such as a separation liner or the like) and
transferring the coated adhesive composition to the protective
film.
[0112] As a method of forming the adhesive layer, any known method
used for preparing an adhesive tape may be used. Specifically,
examples of the method include roll coating, gravure coating,
reverse coating, roll brushing, spray coating, air-knife coating,
die-coat methods, and the like.
[0113] The surface protection sheet according to this embodiment
may be used to protect an optical member attached to a typical flat
display panel such as a liquid display panel, a plasma display
panel, and the like.
[0114] The surface protection sheet according to this embodiment
may be used not only in the case where the optical member is
individually distributed in the market, but also in the case where
the optical member is distributed in the market in a state of being
attached to the flat display panel.
[0115] The adhesive layer (adhesive composition) formed on the
protective film may have an adhesive force of about 0.05 (N/25 mm)
to about 0.2 (N/25 mm), and more advantageously an adhesive force
of about 0.1 (N/25 mm). When the adhesive force is in the range of
about 0.05 to about 0.2 (N/25 mm), the surface protection sheet may
be relatively easily peeled from the optical member, such as a
polarizer, at a rate of, for example, about 10 m/min. The adhesive
force may be measured according to JIS Z0237, which is described
above.
[0116] The adhesive composition according to this embodiment may
include the copolymer (A), which may be formed by the
copolymerization of the hydroxyl group-containing (meth)acrylamide
(a1) (which may include a hydroxyl group-containing acrylamide, a
hydroxyl group-containing methacrylamide, and combinations thereof)
and the (meth)acrylate (a2) (which may include an acrylic ester, a
methacrylic ester, and combinations thereof); and an antistatic
agent (B) including an ionic compound. The adhesive composition
according to this embodiment may have a short aging time resulting
in high productivity and may enable the formation of an adhesive
layer exhibiting good antistatic performance.
[0117] Specifically, when the adhesive composition of this
embodiment is applied to the substrate such as the optical sheet or
the protective film to form an adhesive layer thereon, the adhesive
layer may have a sheet resistance of about 1.times.10.sup.8 to
about 1.times.10.sup.11 (.OMEGA./cm.sup.2), and may exhibit good
antistatic performance.
[0118] Without being bound by theory, it is believed that, in the
adhesive composition, the improvement of the antistatic performance
is achieved as movement of the ionic compound in the adhesive layer
is facilitated by the presence of lone electron pair of nitrogen
atoms contained in the hydroxyl group-containing acrylamide and/or
the methacrylamide. Also, the short aging time of the adhesive
composition of this embodiment is presumably attributed to
activation of the terminal hydroxyl group of the copolymer by the
hydroxyl group-containing acrylamide and/or the methacrylamide,
thereby increasing reactivity of the copolymer.
[0119] The adhesive composition of this embodiment may be very
transparent where the base polymer contains at least one kind of
(meth)acrylate as a main element.
[0120] When the base polymer of the adhesive composition has a
weight-average molecular weight of about 1,000,000 to about
2,000,000 and a gel fraction of about 50 to about 80%, the adhesive
composition may have a high adhesive force, and thus may be used to
form the adhesive layer of the optical member.
[0121] When the base polymer of the adhesive composition has a
weight-average molecular weight of about 300,000 to about 1,000,000
and a gel fraction of about 90 to about 100%, an adhesive layer on
a surface protection sheet formed by coating the adhesive
composition may exhibit a weak adhesive force. In this case, the
adhesive layer may be relatively easily peeled off, for example, at
a rate of 10 m/min, from a display surface of a polarizer on a flat
display panel.
EXAMPLES
[0122] Hereinafter, embodiments will be described with reference to
Examples 1 to 16.
[0123] Adhesive compositions according to Examples 1 to 16 were
prepared and applied to polarizers, thereby producing optical
members of Examples 1 to 16. Then, the optical members were tested
for performance. A detailed description follows.
Preparation of Copolymer Composition According to Example 1
[0124] 1 part by weight of hydroxyethylacrylamide as the
(meth)acrylamide having a hydroxyl group, 98.99 parts by weight of
butyl acrylate, and 120 parts by weight of ethyl acetate as a
solvent were introduced into a flask equipped with a reflux
condenser and an agitator, and were heated to 65.degree. C. while
conducting nitrogen substitution. Then, 0.04 parts by weight of
AIBN as a polymerization initiator was added thereto, followed by
polymerization for six hours at 65.degree. C. When the
polymerization was completed, 0.01 parts by weight of
1-hexyl-3-methylimidazolium hexafluorophosphate as an ionic
compound was added, and 280 parts by weight of ethyl acetate was
further added to adjust viscosity, followed by cooling to room
temperature, thereby producing a copolymer composition solution
containing the adhesive composition of Example 1.
[0125] The adhesive composition in the copolymer composition
solution had a concentration of 20 wt. %, and the copolymer
composition solution had a viscosity of 4,500 mPas. Table 1 shows
an ingredient ratio of the adhesive composition, a concentration of
the adhesive composition in the copolymer composition solution, and
a viscosity of the copolymer composition solution.
[0126] Further, the weight-average molecular weight of the base
polymer was measured by Gel Permeation Chromatography (GPC).
Results are shown in Table 1.
Preparation of Copolymer Composition Solutions According to
Examples 2 to 16
[0127] Copolymer composition solutions containing adhesive
compositions of Examples 2 to 16 were obtained by the same process
as that of Example 1, except for the following: at least one of
butylacrylate, 2-ethylhexyl acrylate, N,N-diethylacrylamide,
2-hydroxyethylacrylate, 4-hydroxybutylacrylate, acrylic acid and
acryl amide with hydroxyethylacrylamide combined (not combined)
therewith as the hydroxyl group-containing (meth)acrylamide was
appropriately combined with ethyl acetate as a solvent, while
combining (not combining) one of 1-hexyl-3-methylimidazolium
hexafluorophosphate, N-methyl-N-propylpiperidinium
bis(trifluoromethanesulfonyl)imide, 1-ethylpyridinium bromide,
1-butyl-3-methylpyridinium trifluoromethanesulfonate, and
1-butyl-3-methylpyridinium bis(trifluoromethanesulfonyl)imide as an
ionic compound therewith at the same time. Tables 1 and 2 show the
ingredient ratios of the adhesive compositions of Examples 2 to 16,
the viscosity of each copolymer composition solution, the
concentration of the adhesive composition in each copolymer
composition solution, and the average weight molecular weight of
the base polymer.
Preparation of Optical Members of Examples 1 to 16
[0128] With respect to 100 parts by weight of the adhesive
composition in each of the copolymer composition solutions of
Examples 1 to 16 listed in Tables 1 and 2,
trimethylolpropane/tolylene diisocyanate (Trademark: Coronate L,
manufactured by Nippon Polyurethane Industry Co., Ltd) as a
crosslinking agent (B) and 3-glycidoxypropyltrimethoxysilane
(Trademark: Shin-Etsu Silicone KBM-403, manufactured by Shin-Etsu
Chemical Industry Co., Ltd.) as a silane coupling agent (C) were
added at the ratios listed in Tables 3 and 4 and sufficiently mixed
to prepare adhesive composition solutions. Each of the adhesive
composition solutions obtained was applied to a separable PET film
(Trademark: MRF 38, manufactured by Mitsubishi Polyester Film Co.,
Ltd.) to a thickness of 25 .mu.m after drying, and dried at
90.degree. C. for 3 minutes to form an adhesive layer consisting of
the adhesive composition. Then, the adhesive layers and the
separable PET films were attached to polarizers (Trademark: MLPH,
manufactured by Migwan Imaging Co., Ltd.), thereby producing
optical members of Examples 1 to 16, respectively.
[0129] Performance of each optical member was tested for surface
resistance, metal corrosiveness, light leakage, durability,
viscosity, adhesion to substrate, contamination of attachment
target, low temperature stability, and reworkability. The
performance test was carried out as described below.
[0130] Further, the concentration of the adhesive composition in
each adhesive composition solution and the viscosity of each
adhesive composition solution were measured. Furthermore, the gel
fraction and the period for obtaining a stabilized gel fraction
were evaluated. Results are shown in Tables 3 and 4.
[0131] Gel Fraction
[0132] Test samples 1 to 16 were prepared with polyester films
having been peeled off, instead of the polarizers used in the
preparation of the optical members of Examples 1 to 16, and left at
23.degree. C. under a relative humidity of 50%, followed by
measuring the gel fractions of the test samples after 1, 3, 5, 7,
10, and 15 days from application.
[0133] The gel fraction is calculated by Equation: Gel fraction
(wt. %)=[(W3-W2)/W1].lamda.100
[0134] In this equation, W1 indicates the weight (g) of an adhesive
layer obtained from a test sample. W2 indicates the weight (g) of a
stainless steel wire mesh mentioned below. W3 indicates the total
weight (g) of the stainless steel wire mesh and a layer on the wire
mesh (remnants after filtering), which was obtained by the
following process: 30 g of ethyl acetate was added to a sample
container having the adhesive layer obtained from the test sample,
and, after the adhesive layer was immersed therein overnight, the
contents in the sample container were filtered using a 200-mesh
stainless steel wire mesh, and dried at 90.degree. C. for one
hour.
[0135] Period for Obtaining a Stabilized Gel Fraction
[0136] As described above, the gel fraction of each test sample was
measured after a predetermined period from the application, and the
period for which the gel fraction became steady was defined as a
period for obtaining a stabilized gel fraction, or a gel fraction
stabilizing period.
[0137] <Method of Performance Test>
[0138] Surface Resistance
[0139] The adhesive layers of the optical members, which had been
left at 23.degree. C. under a relative humidity of 50% for seven
days, were measured for surface resistance by a micro-electrometer
(available from Kawaguchi Denki Manufacturing Co., Ltd.) at
23.degree. C. under a relative humidity of 50%.
[0140] Metal Corrosiveness
[0141] An aluminum foil was attached to the adhesive layer of each
optical member, which had been left at 23.degree. C. under a
relative humidity of 50% for seven days, and left at 60.degree. C.
under a relative humidity of 90% for two days. Then, the
corrosiveness was observed. 0 represents the aluminum foil
unchanged, and X represents the aluminum foil turned white.
[0142] Light Leakage
[0143] Each of the optical members, which had been left at
23.degree. C. under a relative humidity of 50% for seven days, was
cut into a piece of 120 mm (in the MD direction of the polarizer)
.lamda.60 mm and a piece of 120 mm (in the TD direction of the
polarizer).times.60 mm, which in turn were attached to both sides
of a glass substrate to overlap each other, followed by autoclaving
at 50.degree. C. and at 5 kg/cm.sup.2.times.20 min. Then, each
sample was left at 80.degree. C. for 120 hours and observed in
appearance. The sample where light leakage was not detected is
represented by O, and the sample where light leakage was detected
is represented by X.
[0144] Durability
[0145] Each of the optical members, which had been left at
23.degree. C. under a relative humidity of 50% for seven days, was
cut into a piece of 120 mm (in the MD direction of the
polarizers).times.60 mm, and attached to a glass substrate,
followed by autoclaving at 50.degree. C. and at 5
kg/cm.sup.2.times.20 min. Then, the sample was left at 80.degree.
C. and at 60.degree. C. under a relative humidity of 90% for 120
hours, and observed in appearance. The sample where foam,
looseness, or peeling was not found is represented by O, and the
sample where foam, looseness, or peeling was found is represented
by X.
[0146] Adhesive Force and Adhesion to Substrate
[0147] Each optical member, which had been left at 23.degree. C.
under a relative humidity of 50% for seven days, was cut into a
piece of a width of 25 mm and attached to a glass substrate,
followed by autoclaving at 50.degree. C. and at 5
kg/cm.sup.2.times.20 min. Then, the sample was measured for
adhesive force at 23.degree. C. under a relative humidity of 50%
using a tensile tester at a peeling angle of 180 degrees and at a
peeling rate of 0.3 m/min according to JIS Z0237, which regulates a
method for testing an adhesive tape and an adhesive sheet. Further,
the sample was also measured for adhesion to polarizer (substrate).
The sample where the adhesive layer was not completely peeled from
the polarizer is represented by O, and the sample where the
adhesive layer was peeled from the polarizer is represented by
X.
[0148] Contamination of Attachment Target
[0149] Before and after measuring the adhesive force, the contact
angle was measured on the surface of the glass substrate. The
sample where the contact angle of the glass substrate remained
unchanged before and after the measurement is represented by O, and
the sample where the contact angle of the glass substrate was
changed before and after the measurement is represented by X.
Meanwhile, the contact angle was measured according to JIS R3257,
which regulates a method for measuring wettability of a glass
substrate.
[0150] Low Temperature Stability
[0151] Each of the optical members, which had been left at
23.degree. C. under a relative humidity of 50% for seven days, was
cut into a piece of 120 mm (in the MD direction of the
polarizers).times.60 mm and attached to the glass substrate,
followed by autoclaving at 50.degree. C. and at 5
kg/cm.sup.2.times.20 min. Then, the sample was left at -40.degree.
C. for 120 hours and observed in appearance. The sample where foam,
looseness, peeling, or a precipitate was not found is represented
by O, while the sample where foam, looseness, peeling, or a
precipitate was found is represented by X.
[0152] Reworkability
[0153] A peeled state was observed during measurement of the
adhesive force. The sample where an interfacial fracture was
observed is represented by O, and the sample where cohesive
fracture and/or sticking to the glass substrate (attachment target)
were observed is represented by X.
[0154] As shown in Table 3, the adhesive layers of Examples 1 to 10
had a surface resistance of 10.sup.11 .OMEGA./cm.sup.2 or less, and
exhibited good antistatic properties. Additionally, Examples 1 to
10 had a short gel fraction stabilizing period of 3 days. Further,
the optical members of Examples 1 to 10 had a suitable adhesive
force of 4 to about 8 N/25 mm. Moreover, the optical members of
Examples 1 to 10 exhibited good properties in terms of all of metal
corrosiveness, light leakage, durability, adhesion to substrate,
contamination of attachment target, low temperature stability, and
reworkability.
[0155] On the other hand, as shown in Table 4, since Example 11
contained neither the hydroxyl group-containing (meth)acrylamide
nor the antistatic agent, it had a surface resistance of 10.sup.15
.OMEGA./cm.sup.2, thereby showing that Example 11 had lower
antistatic properties than Examples 1 to 10. Further, Example 11
had a gel fraction stabilizing period of 10 days, which was longer
than that of Examples 1 to 10.
[0156] Further, since Example 12 did not contain the hydroxyl
group-containing (meth)acrylamide, it had a gel fraction
stabilizing period of 10 days, which was longer than that of
Examples 1 to 10.
[0157] Further, since Example 13 had a lower amount of the hydroxyl
group-containing (meth)acrylamide, it had a surface resistance of
10.sup.14 .OMEGA./cm.sup.2, thereby showing that Example 13 had
lower antistatic properties than Examples 1 to 10. Further, Example
13 was evaluated as X in terms of durability and reworkability.
[0158] Further, since Example 14 had a higher amount of the
hydroxyl group-containing (meth)acrylamide, it was evaluated as X
in terms of durability.
[0159] Further, since Example 15 had a lower amount of the hydroxyl
group-containing (meth)acrylamide, it was evaluated as X in terms
of durability and reworkability.
[0160] Further, since Example 16 contained N,N-diethyl acrylamide
which is a monomer containing a nitrogen group without containing a
hydroxyl group, it had a gel fraction stabilizing period of 10
days, which was longer than that of Examples 1 to 10, and was
evaluated as X in terms of light leakage and durability.
[0161] Next, embodiments will be described with reference to
Examples 17 to 32. First, adhesive compositions according to
Examples 17 to 32 were prepared and applied to protective films,
thereby producing surface protective films of Examples 17 to 32.
Then, performance of the surface protective films was tested. A
detailed description is as follows.
Preparation of Copolymer Composition According to Example 17
[0162] 1 part by weight of hydroxyethylacrylamide as the
(meth)acrylamide having a hydroxyl group, 40 parts by weight of
butyl acrylate, 58.99 parts by weight of 2-ethylhexyl acrylate, and
150 parts by weight of ethyl acetate as a solvent were introduced
into a flask equipped with a reflux condenser and an agitator, and
were heated to 65.degree. C. while conducting nitrogen
substitution. Then, 0.1 parts by weight of AIBN was added thereto
and 0.05 parts by weight of AIBN as a polymerization initiator was
added again thereto 1 hour thereafter, followed by polymerization
for six hours at 65.degree. C. When the polymerization was
completed, 0.01 parts by weight of 1-hexyl-3-methylimidazolium
hexafluorophosphate was added as an ionic compound, and 36 parts by
weight of ethyl acetate was further added to adjust the viscosity,
followed by cooling to room temperature, thereby producing a
copolymer composition solution containing the adhesive composition
of Example 16.
[0163] The adhesive composition in the copolymer composition
solution had a concentration of 35 wt. %, and the copolymer
composition solution had a viscosity of 3,500 mPas. Table 5 shows
an ingredient ratio of the adhesive composition, a concentration of
the adhesive composition in the copolymer composition solution, and
a viscosity of the copolymer composition solution.
[0164] Further, the weight-average molecular weight of the base
polymer was measured by Gel Permeation Chromatography (GPC).
Results are shown in Table 5.
Preparation of Copolymer Composition Solutions According to
Examples 18 to 32
[0165] Copolymer composition solutions containing adhesive
compositions of Examples 18 to 32 were obtained by the same process
as that of Example 17, except for the following: at least one of
butylacrylate, 2-ethylhexyl acrylate, 2-hydroxyethylacrylate,
4-hydroxybutylacrylate, acrylic acid and acryl amide with
hydroxyethylacrylamide combined (not combined) therewith as the
hydroxyl group-containing (meth)acrylamide was appropriately
combined with ethyl acetate as a solvent, while combining (not
combining) one of 1-hexyl-3-methylimidazolium hexafluorophosphate,
N-methyl-N-propylpiperidinium bis(trifluoromethanesulfonyl)imide,
1-ethylpyridinium bromide and 1-butyl-3-methylpyridinium
trifluoromethanesulfonate as the ionic compound therewith at the
same time. Tables 5 and 6 show the ingredient ratios of the
adhesive compositions of Examples 18 to 32, the viscosity of each
copolymer composition solution, the concentration of the adhesive
composition in each copolymer composition solution, and the average
weight molecular weight of the base polymer.
Preparation of Surface Protection Sheets of Examples 17 to 32
[0166] With respect to 100 parts by weight of the adhesive
composition in each of the copolymer composition solutions of
Examples 17 to 32 listed in Tables 5 and 6,
hexamethylenediisocyanate (isocyanate crosslinking agent, Coronate
HX.TM., obtained from Nippon Polyurethane Industry Co., Ltd) as a
crosslinking agent (B) was added at the ratios listed in Tables 7
and 8 and sufficiently mixed to prepare adhesive composition
solutions. Each of the adhesive composition solutions obtained was
applied to a separable PET film (Trademark: MRF 38, obtained from
Mitsubishi Polyester Film Co., Ltd.) to a thickness of 25 .mu.m
after drying, and dried at 90.degree. C. for 3 minutes to form an
adhesive layer consisting of the adhesive composition. Then, the
adhesive layers and the separable PET films were attached to PET
protective films (Trademark: Lumirror S10#25, obtained from Torre
Co., Ltd.), thereby producing surface protection sheets of Examples
17 to 32, respectively.
[0167] As in Example 1, performance of each surface protection
sheet was tested for surface resistance, metal corrosiveness,
contamination of attachment target, and low temperature stability.
Here, the performance test was carried out by replacing the glass
substrate with a polarizer as the attachment target. The
performance test was carried out for adhesive force, adhesion to
substrate, and transparency of adhesive layer as described
below.
[0168] Further, as in Example 1, the concentration of the adhesive
composition in each adhesive composition solution, and the
viscosity, gel fraction, and period for obtaining a stabilized gel
fraction for each adhesive composition solution were measured.
Results are shown in Tables 7 and 8.
[0169] Adhesive Force and Adhesion to Substrate
[0170] Each of the optical members, which had been left at
23.degree. C. under a relative humidity of 50% for seven days, was
cut into a piece of a width of 25 mm and attached to the polarizer,
followed by autoclaving at 50.degree. C. and at 5
kg/cm.sup.2.times.20 min. Then, the sample was measured for
adhesive force at 23.degree. C. under a relative humidity of 50%
using a tensile tester at a peeling angle of 180 degrees and at a
peeling rate of 0.3 m/min according to JIS Z0237 which regulates a
method for testing an adhesive tape and an adhesive sheet. Further,
the sample was also measured for adhesion to a protective film
(substrate). The sample where the adhesive layer was not completely
peeled from the protective film is represented by O, and the sample
where the adhesive layer was peeled from the protective film is
represented by X.
[0171] Transparency of Adhesive Layer
[0172] The transparency of each surface protection sheet, which had
been left at 23.degree. C. under a relative humidity of 50% for
seven days, was confirmed by the naked eye. The sample where the
adhesive layer exhibited good transparency is represented by O, and
the sample where the adhesive layer had an unclear portion is
represented by X.
[0173] As shown in Table 7, for the surface protection sheets of
Examples 17 to 26, the adhesive layers had a surface resistance of
10.sup.8 to about 10.sup.11 .OMEGA./cm.sup.2, and exhibited good
antistatic properties. Additionally, the surface protection sheets
of Examples 17 to 26 had a suitable adhesive force of 0.1 to about
0.15 N/25 mm. Moreover, the surface protection sheets of Examples
17 to 26 exhibited good properties in terms of all of metal
corrosiveness, adhesion to substrate, contamination of attachment
target, low temperature stability, and transparency of adhesive
layer.
[0174] On the other hand, as shown in Table 8, since the surface
protection sheet of Example 26 contained neither the hydroxyl
group-containing (meth)acrylamide nor the antistatic agent, it had
a surface resistance of 10.sup.15 .OMEGA./cm.sup.2, thereby showing
that Example 26 had lower antistatic properties than Examples 17 to
26. Further, Example 27 had a gel fraction stabilizing period of 10
days, which was longer than that of Examples 17 to 26.
[0175] Further, since Example 28 did not contain the hydroxyl
group-containing (meth)acrylamide, it had a gel fraction
stabilizing period of 10 days, which was longer than that of
Examples 17 to 26.
[0176] Further, since Example 29 had a lower amount of the hydroxyl
group-containing (meth)acrylamide, it had a surface resistance of
10.sup.14 .OMEGA./cm.sup.2, thereby showing that Example 29 had
lower antistatic properties than Examples 17 to 26.
[0177] Further, since Example 30 had a higher amount of the
hydroxyl group-containing (meth)acrylamide, it was evaluated as X
in terms of adhesion to substrate and transparency of adhesive
layer.
[0178] Further, since Example 31 had a lower amount of the hydroxyl
group-containing (meth)acrylamide, it was evaluated as X in terms
of contamination of attachment target.
[0179] Further, since Example 32 contained N,N-diethyl acrylamide,
which is a monomer containing a nitrogen group without containing a
hydroxyl group, it had a gel fraction stabilizing period of 10
days, which was longer than that of Examples 1 to 10, and was
evaluated as X in terms of adhesion to substrate and contamination
of attachment target.
[0180] As described above, embodiments may provide an adhesive
composition that has a short aging time resulting in high
productivity and permits the formation of an adhesive layer
exhibiting good antistatic performance, and an optical member and a
surface protective film including the same.
[0181] Embodiments may provide one or more advantages relative to
comparative approaches. A comparative approach might be to provide
a separate antistatic layer on a flat display panel, e.g., a
cholesteric liquid crystal layer may be provided with a
polarization member at one or either side thereof, the polarization
member including an antistatic layer, a dichromatic polarizer, and
a quarter wavelength plate. In an implementation, the flat display
panel may be provided with an antistatic adhesive sheet that
includes a base film, an antistatic layer containing a quaternary
ammonium salt, and an adhesive layer stacked in this sequence.
However, since the aforementioned techniques form the antistatic
layer and the adhesive layer through separate processes, such
techniques may have low productivity. On the other hand, if the
antistatic agent is contained in the adhesive layer of the optical
film or surface protective film, the adhesive layer may have
antistatic properties, thereby eliminating the separate formation
of the adhesive film and the antistatic layer. However, if a
general adhesive layer is formed by coating an adhesive composition
on the optical film or surface protective film, there can be
problems of insufficient antistatic properties and productivity
reduction resulting from a long aging time for forming the adhesive
layer.
[0182] Example embodiments have been disclosed herein, and although
specific terms are employed, they are used and are to be
interpreted in a generic and descriptive sense only and not for
purpose of limitation. Accordingly, it will be understood by those
of skill in the art that various changes in form and details may be
made without departing from the spirit and scope of the present
invention as set forth in the following claims.
* * * * *