U.S. patent application number 13/894491 was filed with the patent office on 2014-11-20 for cartridge for ammunition.
The applicant listed for this patent is Robert J. Massey, Amnon Parizat. Invention is credited to Robert J. Massey, Amnon Parizat.
Application Number | 20140338556 13/894491 |
Document ID | / |
Family ID | 51894733 |
Filed Date | 2014-11-20 |
United States Patent
Application |
20140338556 |
Kind Code |
A1 |
Parizat; Amnon ; et
al. |
November 20, 2014 |
Cartridge for Ammunition
Abstract
A single ply barrier foil is provided between the propellant in
the cartridge casing and the pyrotechnic composition in the primer
to prevent nitroglycerin migration from the propellant into the
pyrotechnic composition. The single ply barrier foil is formed of
ethyl cellulose and a plasticizer and has a thickness of 190
um.+-.10 um.
Inventors: |
Parizat; Amnon; (Old
Westbury, NY) ; Massey; Robert J.; (Rochester,
NY) |
|
Applicant: |
Name |
City |
State |
Country |
Type |
Parizat; Amnon
Massey; Robert J. |
Old Westbury
Rochester |
NY
NY |
US
US |
|
|
Family ID: |
51894733 |
Appl. No.: |
13/894491 |
Filed: |
May 15, 2013 |
Current U.S.
Class: |
102/430 |
Current CPC
Class: |
F42B 5/025 20130101;
F42B 5/16 20130101 |
Class at
Publication: |
102/430 |
International
Class: |
F42B 5/02 20060101
F42B005/02 |
Claims
1. A cartridge comprising a casing; a double-base propellant
disposed in said casing, said propellant having nitroglycerin
therein; a primer disposed at one end of said casing and including
a pyrotechnic composition; and a single ply barrier foil disposed
between said propellant and said pyrotechnic composition to prevent
nitroglycerin migration from said propellant into said pyrotechnic
composition.
2. A cartridge as set forth in claim 1 wherein said pyrotechnic
composition is of a potassium chlorate type containing lead
sulfocyanide and trinitrotoluene and said propellant is a
powder.
3. A cartridge as set forth in claim 1 wherein said single ply
barrier foil is formed of cellulose.
4. A cartridge as set forth in claim 1 wherein said single ply
barrier foil is formed of ethyl cellulose and a plasticizer.
5. A cartridge as set forth in claim 1 wherein said single ply
barrier has a thickness of 190 um.+-.10 um.
6. A cartridge as set forth in claim 1 wherein said casing is sized
for a 20 millimeter ammunition cartridge.
Description
[0001] This invention relates to a cartridge. More particularly,
this invention relates to a cartridge for ammunition. Still more
particularly, this invention relates to an arrangement for
protecting the primer composition of ammunition from volatile
materials in a propellant charge.
BACKGROUND OF THE INVENTION
[0002] Modern smokeless powder used as a propellant in ammunition
contains various volatile substances and the particular effect they
have on the priming composition will depend on the ingredients of
the composition. If the primer is of the potassium chlorate type
containing in addition lead sulfocyanide and trinitrotoluene and
the propellant charge is double base powder containing
nitroglycerine, the primer will gradually become desensitized by
the nitroglycerine vapor. In fact, the certain volatiles from the
propellant powders will act deleteriously on certain priming
compositions.
[0003] As is known, ammunition cartridges are manufactured with a
casing; a double-base propellant having nitroglycerin in the casing
and a primer disposed at one end of the casing and including a
pyrotechnic composition.
[0004] It is also known that the potential for nitroglycerin
migration from the cartridge casing propellant into the pyrotechnic
material in the primer may affect the sensitivity of the
pyrotechnic primer material. The result of increased or decreased
sensitivity of the pyrotechnic material creates an uncertain
ignition of the cartridge propellant. This uncertainly must be
avoided to maintain safety to all persons.
[0005] In the past, use has been made of a membrane between the
primer and the cartridge propellant to block the migration of
nitroglycerin into the primer. For example, U.S. Pat. Nos.
2,340,284, 2,974,592, 3,062,146, and 4,386,567 describe the use of
a membrane material made from regenerated cellulose strip in a four
ply laminated structure. See also, the National Military
Establishment Specification JAN-C-677 dated 30 Sep. 1948 and
amended 30 Mar. 1951 and 11 Dec. 1951 for a further example of the
laminated membrane structure. A nitrocellulose lacquer is applied
to both sides of the regenerated cellulose as the only protection
against nitroglycerin migration from the cartridge double-base
propellant into the pyrotechnic composition in the primer. Any void
or lack of complete coverage of the nitrocellulose lacquer coating
onto the regenerated cellulose laminated strip would allow
nitroglycerin penetration and vapor migration, as regenerated
cellulose, in and by itself, is not nitroglycerin resistant. The
volatile constituents of the double-base propellant in the
cartridge can easily transfer into the pyrotechnic primer
composition compromising sensitivity of the ignition.
[0006] Multi-ply cellulose regenerated strips are also highly prone
to delamination during the end use application and therefore create
waste and loss of productivity.
[0007] Regenerated cellulose, also known as Cellophane, is
manufactured using carbon disulfide, a known toxin and
environmentally unfriendly chemical. Carbon disulfide must be
recovered and properly disposed of to prevent environmental
concerns. This environmental contamination concern requires
complicated recovery processes or remediation concerns for the
manufacturers of cellulose regenerated strip. Many have ceased the
manufacturing of this product making availability of the prior art
nitrocellulose lacquer coated regenerated cellulose strip difficult
if not impossible to find.
[0008] Accordingly, it is an object of the invention to provide an
improved barrier for preventing nitroglycerin migration from a
cartridge double-base propellant into a pyrotechnic composition in
a primer.
[0009] It is another object of the invention to provide an
environmentally friendly barrier for preventing nitroglycerin
migration from a cartridge double-base propellant.
[0010] Briefly, the invention is directed to a cartridge comprising
a casing, a double-base propellant disposed in the casing and
having nitroglycerin therein and a primer disposed at one end of
the casing and including a pyrotechnic composition.
[0011] In accordance with the invention a single ply barrier foil
is disposed between the propellant and the pyrotechnic composition
to prevent nitroglycerin migration from the propellant into the
pyrotechnic composition.
[0012] The foil is formed of ethyl cellulose.
[0013] Typically, the pyrotechnic composition is of a potassium
chlorate type containing lead sulfocyanide and trinitrotoluene and
the propellant is a powder.
[0014] These and other objects and advantages of the invention will
become more apparent from the following detailed description taken
in conjunction with the accompanying drawings wherein:
[0015] FIG. 1 illustrates a side view of a cartridge constructed in
accordance with the invention; and
[0016] FIG. 2 illustrates an enlarged cross-sectional view of a
primer employed in the cartridge of FIG. 1.
[0017] Referring to FIG. 1, the cartridge 1, for example, a 20
millimeter (mm) cartridge, is of conventional construction for
ammunition having a casing 2, a double-base propellant 3 disposed
in the casing and a primer 4 disposed at one end of the casing 2
and including a pyrotechnic composition 5.
[0018] The double-base propellant 3 typically includes
nitroglycerin while the pyrotechnic composition 5 is of a potassium
chlorate type containing lead sulfocyanide and trinitrotoluene.
[0019] In accordance with the invention, a single ply barrier foil
6 is disposed between the propellant 3 and the pyrotechnic
composition 5 to prevent nitroglycerin migration from the
propellant 3 into the pyrotechnic composition 5.
[0020] As illustrated in FIG. 2, the primer 4 is of conventional
structure being formed of a cup-shaped casing 7 with an open base
that houses an electrically conductive contact 8 between the
pyrotechnic composition 5 and the open base of the casing 7. In
addition, an insulating liner 9 separates the conductive contact 8
from the casing 7. The liner 9 is preferably formed from polymeric
material such as, polypropylenes, polycarbonates, polysulfones,
poly(ether imides), poly(amide imides), poly(ether sulfones),
poly(benzimide azoles), and poly(ether ether ketones).
[0021] The pyrotechnic composition 5 is sandwiched between the
conductive contact 8 and the single ply barrier foil 6. An anvil 10
of metal is press fit into the casing 7 over the top of the foil 6
to secure the foil 6 in place. As illustrated, the anvil 10 is of
cup shape with an open base to expose the center of the top surface
of the foil 6.
[0022] The single ply barrier foil 6 is uncoated and is made by
cast extrusion or solvent cast process. The foil 6 is of a color,
for example, red, in order to distinguish its presence for
ammunition assemblers. In other uses, the foil 6 is of a light tan
to dark tan color and a stack of such foils 6 may be sufficiently
transparent so that print may be read through the stack.
[0023] In the solvent cast process, a mixture of ethyl cellulose,
plasticizers, solvent(s) and dyes is distributed via a state of the
art distributor onto a highly polished belt, such as a stainless
steel belt. This process provides control of the foil thickness to
a very tight tolerance. The foil then passes into drying sections
to optimize the chemical structure and is finally wound onto cores
as a finished product.
[0024] By way of example, the ethyl cellulose mixture is made of
ethyl cellulose powder, medium viscosity Type 70 produced by Dow
Chemical of Midland, Mich. and others; a plasticizer, such as,
dibutyl phthylate, diphenyl phosphate, triphenyl phosphate,
substituted diphenyl ether, substituted phenols, and alkylated
diphenyl oxide; and a solvent, such as, 80:20 toluene:alcohol,
butyl acetate, ethanol, methylene chloride, or ethylene glycol
monobutyl ether, alone or in combination. Specifically, substituted
diphenyl ether is the preferred plasticizer and methylene chloride
is the preferred solvent. The foil 6 has a thickness of 190
um.+-.10 um.
[0025] The single ply barrier foil 6 does not require a
nitrocellulose lacquer coating to prevent nitroglycerin migration.
Testing was conducted per the National Military Establishment
Specification JAN-C-677 section F-4C. According to the
specification, samples approximately 3 inches in length were
suspended horizontally by gripping the ends with a holder. Three
drops of nitroglycerin were placed approximately 3/4 of the inch
apart on each strip at a volume of .+-.0.06 ml via a class "A"
volumetric pipette. The samples were then placed into an oven being
held a 50 degree Celsius for 48 hours. At the end of that time, the
samples were removed from the oven, allowed to cool, and the
nitroglycerin was removed from the strips with blotting paper. The
samples were then removed from the holder and individually examined
for any swelling or signs that nitroglycerin had passed through the
strips.
[0026] The clear single ply barrier foil showed that nitroglycerin
did not pass through the barrier.
[0027] A single ply barrier foil formulated with a red dye was
included in this test to determine potential influence of the
required red color. Results of this testing indicate no influence
to prevent nitroglycerin migration resulting from the red color
addition.
[0028] During the pyrotechnic primer composition 5 loading process,
proper placement of an uncoated single ply barrier foil 6 into the
primer 4 will inhibit migration of the volatile constituent of the
cartridge double-base propellant 3, nitroglycerin, into the
pyrotechnic composition 5. This foil 6 need not rely on full
nitrocellulose lacquer coverage onto both surfaces of a cellulose
regenerated strip to prevent nitroglycerin intrusion into the
pyrotechnic composition 5 in the primer 4. The uncoated foil 6 is
sufficient, without any surface coatings, to withstand
nitroglycerin absorption, migration or vapor permeability through
its structure thus affecting the primer pyrotechnic composition 5
detonation timing.
[0029] The advantage of using an uncoated single ply barrier foil 6
as a membrane in the ammunition primer 4 is the simplicity of the
foil to perform as a nitroglycerin barrier. A single-ply uncoated
foil 6 will prevent nitroglycerin migration whereas a 4-ply
regenerated cellulose strip requires a nitrocellulose lacquer
coating applied to both sides. Any void in the application of the
nitrocellulose lacquer coating will provide exposed regenerated
cellulose strip insufficient, in and by itself, to prevent
nitroglycerin migration into the primer pyrotechnic composition. As
a single-ply foil, the foil 6 will not delaminate as the does the
multi-ply prior art during the end use application process.
[0030] Advantageously, the single ply foil 6 is environmentally
friendly as opposed to the process to produce lacquer coated
regenerated cellulose strip as described in U.S. Pat. No. 3,983,201
requiring carbon disulfide (CS.sub.2) as part of the manufacturing
process. Carbon disulfide (CS.sub.2) requires recovery or costly
remediation to protect the environment from hazard. Acute
(short-term) inhalation exposure of humans to carbon disulfide has
caused changes in breathing and chest pains. Nausea, vomiting,
dizziness, fatigue, headache, mood changes, lethargy, blurred
vision, delirium, and convulsions have also been reported in humans
acutely exposed by inhalation. Neurologic effects, including
behavioral and neurophysiological changes, have been observed in
chronic (long-term) human and animal inhalation studies.
Reproductive effects, such as decreased sperm count and menstrual
disturbances have been observed in humans exposed to carbon
disulfide by inhalation. Animal studies support these findings. EPA
has not classified carbon disulfide for human carcinogenicity.
[0031] The main sources of information are the Agency for Toxic
Substances and Disease Registry's (ATSDR's) Toxicological Profile
for Carbon disulfide and EPA's Integrated Risk Information System
(IRIS), which contains information on oral chronic toxicity and the
reference dose (RfD) and inhalation chronic toxicity and the
reference concentration (RfC).
[0032] The single ply foil 6 is particularly useful as a protective
barrier seal in 20 mm medium caliber ammunition preventing the
diffusion of nitroglycerin, an energetic double-base propellant
plasticizer, from contaminating the pyrotechnic composition 5 in
the primer 4. Such contamination can lead to premature ignition,
delayed ignition, referred to as a "hangfire", or zero ignition,
also known as "misfire", each creating a hazardous situation.
[0033] Nitroglycerin Resistance analytical testing of the single
ply barrier foil was conducted in January 2010 and repeated in
January 2012 in accordance with the National Military Establishment
Specification JAN-C-677, Amendment 2, dated Dec. 11, 1951, Section
F-4c. The results concluded that the foil conforms to the
requirements of Specification JAN-C-677 whereas clear cellulose
acetate strips failed.
[0034] The single ply barrier foil is manufactured as an
environmentally friendly product with no limitation of exposure or
personal protective equipment required. The foil is biologically
degradable under corresponding conditions of decomposition and can
be stored on disposal sites without cause of danger.
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