U.S. patent application number 13/726291 was filed with the patent office on 2014-06-26 for self glazed ceramic/glass composite and method for manufacturing the same.
This patent application is currently assigned to King Abdul Aziz City for Science and Technology (KACST). The applicant listed for this patent is KING ABDUL AZIZ CITY FOR SCIENCE AND TECHNOLOGY (KACST). Invention is credited to Omar A Alharbi, Mohammed A Binhussain, Esmat M A Hamzawy.
Application Number | 20140179506 13/726291 |
Document ID | / |
Family ID | 47757495 |
Filed Date | 2014-06-26 |
United States Patent
Application |
20140179506 |
Kind Code |
A1 |
Binhussain; Mohammed A ; et
al. |
June 26, 2014 |
SELF GLAZED CERAMIC/GLASS COMPOSITE AND METHOD FOR MANUFACTURING
THE SAME
Abstract
The invention provides a glazed composite manufactured using
waste materials, wherein the waste materials are capable of
producing ceramic forming oxides, glass modifying oxides and
ceramic modifying oxides. The waste materials include ceramic waste
and colored glass waste. The invention also provides a method for
manufacturing composition of the glazed composite.
Inventors: |
Binhussain; Mohammed A;
(Riyadh, SA) ; Hamzawy; Esmat M A; (Cairo, EG)
; Alharbi; Omar A; (Riyadh, SA) |
|
Applicant: |
Name |
City |
State |
Country |
Type |
KING ABDUL AZIZ CITY FOR SCIENCE AND TECHNOLOGY (KACST) |
Riyadh |
|
SA |
|
|
Assignee: |
King Abdul Aziz City for Science
and Technology (KACST)
Riyadh
SA
|
Family ID: |
47757495 |
Appl. No.: |
13/726291 |
Filed: |
December 24, 2012 |
Current U.S.
Class: |
501/14 ;
65/28 |
Current CPC
Class: |
C04B 2235/3418 20130101;
C04B 35/62204 20130101; C04B 33/13 20130101; C04B 2235/602
20130101; Y02P 40/60 20151101; C04B 2235/5436 20130101; Y02P 40/69
20151101; C04B 2235/6562 20130101; C03B 1/02 20130101; C03C 8/00
20130101; C04B 2235/36 20130101; C04B 35/6261 20130101; C04B
33/1324 20130101; C04B 2235/77 20130101; C04B 2235/6567 20130101;
C04B 2235/96 20130101; C03B 32/02 20130101; C04B 2235/9692
20130101 |
Class at
Publication: |
501/14 ;
65/28 |
International
Class: |
C03C 8/00 20060101
C03C008/00 |
Claims
1. A method for manufacturing a glazed composite, the method
comprising: grinding each raw material of a set of raw materials
independently, wherein the set of raw materials comprises ceramic
waste and colored glass waste; sieving each raw material of the set
of raw materials independently to filter out particles having
diameter more than about 90 microns; mixing the set of raw
materials to obtain a homogenous mixture; sieving the homogenous
mixture for filtering out particles having diameter more than about
90 microns; pressing the homogenous mixture admixed with water in
response to sieving, wherein 1 ml of water is added per 10 g of the
homogenous mixture; and firing the homogenous mixture at a
temperature of about 700 degree C. (.degree. C.) to 1200.degree.
C.
2. The method of claim 1, wherein each raw material of the set of
raw materials is ground in a ball mill with a speed of about 400
revolutions per minute for a period of 30 minutes.
3. The method of claim 1, wherein each raw material and the
homogenous mixture are sieved for filtering out particles having
diameter more than about 50 microns.
4. The method of claim 1, wherein the set of raw materials is mixed
in a dry ball mill to obtain a homogenous mixture.
5. The method of claim 1, wherein the homogenous mixture is pressed
using one of uniaxially cold pressing, biaxial cold pressing, dry
pressing, semi-dry pressing, compacting, cold isostatic pressing,
hot pressing, extrusion molding, injection molding, compression
molding, gel casting, slip casting and tape casting.
6. The method of claim 1, wherein the homogenous mixture is fired
at a temperature of about 700.degree. C. to about 1200.degree. C.
with a rate of about 5.degree. C. per minute to about 20.degree. C.
per minute for a period of about 15 minutes to about 2 hours 30
minutes.
7. The method of claim 1, wherein the set of raw materials
comprises about 35 wt % to about 65 wt % of ceramic waste and about
15 wt % to about 85 wt % of colored glass waste.
8. The method of claim 1, wherein the set of raw materials further
comprises silica sand.
9. The method of claim 8, wherein the set of raw materials
comprises about 25 weight percent (wt %) to about 46 wt % of silica
sand, about 10 wt % to about 47 wt % of ceramic waste and about 25
wt % to about 46 wt % of colored glass waste.
10. A composition of a glazed composite comprises about 62 wt % to
about 90 wt % of silicon dioxide (SiO.sub.2), about 2 wt % to about
17 wt % of alumina (Al.sub.2O.sub.3), about 5 wt % to about 10 wt %
of calcium oxide (CaO), about 2 wt % to about 14 wt % of sodium
oxide (Na.sub.2O), about 2 wt % to about 4 wt % of potassium oxide
(K.sub.2O), about 0. 5 wt % to about 1. 0 wt % of titanium dioxide
(TiO.sub.2) and about 0.1 wt % to about 5 wt % of ferric oxide
(Fe.sub.2O.sub.3).
11. The composition of claim 10, wherein raw materials for
preparing the composition of the glazed composite comprises about
35 wt % to about 65 wt % of ceramic waste and about 15 wt % to
about 85 wt % of colored glass waste.
12. The composition of claim 10, wherein raw materials for
preparing the composition of the glazed composite comprises about
25 wt % to about 46 wt % of silica sand, about 10 wt % to about 47
wt % of ceramic waste and about 25 wt % to about 46 wt % of colored
glass waste.
Description
FIELD OF THE INVENTION
[0001] The invention generally relates to a self glazed composite
and a method for manufacturing the self glazed composite. More
specifically, the invention relates to a self glazed composite
manufactured using waste materials such as ceramic and colored
glass with an optional addition of vitrification aids such as
silica.
BACKGROUND OF THE INVENTION
[0002] Glazed ceramic composite are widely used in various
industries. The glazed composite are mainly used for manufacturing
tiles due to outstanding mechanical properties such as, but not
limited to, high strength, toughness, translucency or opacity, low
thermal expansion, high temperature resistance and high chemical
durability. Glazes are widely used for coating ceramics in various
industries. Glazes are generally used to color, decorate,
strengthen and waterproof the ceramics. The glazes also exhibit
properties of excellent scratch resistance and glossiness.
[0003] Generally, the glazes are prepared using raw materials such
as, but not limited to, silica, zircon, kaolin, feldspar, dolomite,
magnesium carbonate, boric acid and potassium nitrate in an
industrial grade. A selected set of raw materials are thoroughly
mixed and melted in a furnace at very high temperature to prepare
molten raw materials. The molten raw materials are poured into
water to obtain glass frits. The glass frits are ground in a mill,
which are then used as glazes. These glazes are applied on ceramic
bodies and fired at high temperature to obtain glazed ceramic
bodies. Thus, the glazes are prepared separately and applied on the
ceramic substrates. Further, the temperature used for firing and
melting the raw materials are very high and consumes high amount of
energy.
[0004] Additionally, wastes of ceramic and glass are immobilized by
disposal in land-fills, used in road fills as a partial substitute
for natural aggregate in concrete, or immobilized in cement
industries as a substitute in varying proportions for cement in
mortar and concrete. The ceramic wastes are also used in vitreous
ceramic wastes which are used as immobile carrier for spent nuclear
fuel and surplus plutonium. Economic justification for capital and
operational costs of implementing such procedures for disposal of
such waste tends to be very high.
[0005] Therefore, there is a need to develop a method for
manufacturing glazed composite which is environment friendly, cost
effective and has superior mechanical and chemical properties.
BRIEF DESCRIPTION OF THE FIGURE
[0006] The accompanying figure together with the detailed
description below forms part of the specification and serves to
further illustrate various embodiments and to explain various
principles and advantages all in accordance with the present
invention.
[0007] FIG. 1 illustrates a flow diagram of a method for
manufacturing a glazed composite in accordance with an embodiment
of the invention.
[0008] FIG. 2 illustrates sample X-ray diffraction of as received
ceramic wastes.
[0009] FIG. 3 illustrates glazed composite samples sintered at
different temperatures up to 1200.degree. C.
[0010] FIG. 4 illustrates self glazed composite samples sintered at
different temperatures up to 1200.degree. C.
[0011] FIG. 5 illustrates X-ray diffraction analysis for developed
crystalline phases in samples prepared using ceramic waste and
color glass waste in addition to silica sand, sintered between
700.degree. C. and 1200.degree. C.
[0012] FIG. 6 illustrates X-ray diffraction analysis for developed
crystalline phases in samples prepared using ceramic waste and
color glass waste sintered between 700.degree. C. and 1200.degree.
C.
DETAILED DESCRIPTION OF THE INVENTION
[0013] Before describing in detail embodiments that are in
accordance with the invention, it should be observed that the
embodiments reside primarily for a glazed composite and in method
steps related to manufacturing the glazed composite.
[0014] In this document, relational terms such as first and second,
top and bottom, and the like may be used solely to distinguish one
entity or action from another entity or action without necessarily
requiring or implying any actual such relationship or order between
such entities or actions. The terms "comprises," "comprising," or
any other variation thereof, are intended to cover a non-exclusive
inclusion, such that a process, method, article or composition that
comprises a list of elements does not include only those elements
but may include other elements not expressly listed or inherent to
such process, method, article or composition. An element proceeded
by "comprises . . . a" does not, without more constraints, preclude
the existence of additional identical elements in the process,
method, article or composition that comprises the element.
[0015] Generally speaking, pursuant to various embodiments, the
invention provides a glazed composite and a method for
manufacturing the glazed composite. The glazed composite is
manufactured using waste materials such as ceramic wastes and
colored glass wastes. Additionally, silica sand can also be used as
raw material along with the waste materials. The waste materials,
which are capable of producing ceramic forming oxides, glass
modifying oxides and ceramic modifying oxides, are selected.
[0016] FIG. 1 illustrates a flow diagram of a method for
manufacturing a glazed composite in accordance with an embodiment
of the invention.
[0017] A specific set of raw materials are used to manufacture the
glazed composite. The set of raw materials includes waste materials
such as ceramic wastes and colored glass wastes. Additionally,
silica sand can also be used as raw material along with the waste
materials. The waste materials, which are capable of producing
ceramic forming oxides, glass modifying oxides and ceramic
modifying oxides, are selected. Other oxides such as, but not
limited to, aluminum oxide (Al.sub.2O.sub.3), titanium dioxide
(TiO.sub.2), zirconium dioxide(ZrO.sub.2), ferric oxide
(Fe.sub.2O.sub.3), and manganese dioxide (MnO.sub.2) can also be
produced in various degrees in final formulation of the glazed
composite. The waste materials are selected in such a way that the
selected waste materials provide high amount of crystallize phases
in the final formulation of the glazed composite. Colored glass
waste is very beneficial as use of the colored glass waste
decreases time and temperature required during the manufacturing
process of the glazed composites. The raw materials have
compositions which essentially includes components in weight
percent as shown in table below.
TABLE-US-00001 TABLE Typical Chemical Composition Materials
SiO.sub.2 Al.sub.2O.sub.3 Fe.sub.2O.sub.3 CaO MgO Na.sub.2O
K.sub.2O TiO.sub.2 Ceramic 63.80 17.40 6.10 6.55 1.90 1.27 3.05
0.80 waste glass 71.50 0.09 0.95 9.40 3.80 14.00 waste Silica 90.35
1.78 0.47 5.25 0.18 1.50 0.04 0.09 Sand
[0018] The ceramic wastes are collected from local ceramic factory,
mineralogically it contains alpha quartz and little anorthite. FIG.
2 illustrates X-ray diffraction of as received ceramic wastes.
[0019] At step 102, each raw materials of the set of raw materials
are ground into powder. Any suitable grinding machine such as, but
not limited to, a roll crusher, a ball mill or an impeller breaker
can be used for grinding each raw material of the set of raw
materials and as such those techniques would be apparent to those
ordinarily skilled in the art. In an embodiment, each raw material
of the set of raw materials is ground in a ball mill with a speed
of about 400 revolutions per minute for a period of 30 minutes.
[0020] In an embodiment, the set of raw materials includes about 35
weight percent (wt %) to about 65 wt % of ceramic waste and about
15 wt % to about 85 wt % of colored glass waste.
[0021] In another embodiment, the set of raw materials includes
about 25 wt % to about 46 wt % of silica sand, about 10 wt % to
about 47 wt % of ceramic waste and about 25 wt % to about 46 wt %
of colored glass waste.
[0022] At step 104, each raw materials sieved to filter out
particles of diameter more than about 90 microns (.mu.). The
processing characteristics are optimized due to the use of
particles of sizes of less than 90.mu.. In an embodiment, each raw
material is sieved to filter out particles of diameter more than
about 50 microns.
[0023] Thereafter, at step 106, the raw materials are mixed to
obtain a homogenous mixture. In an embodiment, the raw materials
are mixed in a dry ball mill to obtain a homogenous mixture. Moving
on, at step 108, the homogenous mixture is sieved in order to
filter out particles having diameter more than about 90
microns.
[0024] Thereafter, the homogenous mixture is admixed with water.
The water is added such that the homogenous mixture has 1
milliliter (ml) of water per 10 grams (g) of the homogenous
mixture. Subsequently, the homogenous mixture is pressed at step
110. In an embodiment, the homogenous mixture is pressed using one
of uniaxial cold pressing, biaxial cold pressing, dry pressing,
semi-dry pressing, compacting, cold isostatic pressing, hot
pressing, extrusion molding, injection molding, compression
molding, gel casting, slip casting and tape casting. Any other
suitable type of technique for pressing can be used at step 110 and
as such the techniques which can be used would be apparent to those
ordinarily skilled in the art. For example, the homogenous mixture
with the particles of sizes less than 90.mu. is uniaxially cold
pressed at a pressure of about 50 Megapascal (MPa) to about 100 MPa
in a mold.
[0025] Finally, at step 112, the homogenous mixture (green sample)
is sintered at a temperature of about 700.degree. C. to about
1200.degree. C. In accordance with the embodiment, the homogenous
mixture is fired at a temperature of about 700.degree. C. to about
1200.degree. C. with a rate of about 5.degree. C. per minute to
about 20.degree. C. per minute for a period of about 15 minutes to
about 2 hours 30 minutes.
[0026] In various embodiments of the invention, the glazed
composite includes about 62 wt % to about 90 wt % of silicon
dioxide (SiO.sub.2), about 2 wt % to about 17 wt % of alumina
(Al.sub.2O.sub.3), about 5 wt % to about 10 wt % of calcium oxide
(CaO), about 2 wt % to about 14 wt % of sodium oxide (Na.sub.2O),
about 2 wt % to about 4 wt % of potassium oxide (K.sub.2O), about
0.5 wt % to about 1.0 wt % of titanium dioxide (TiO.sub.2) and
about 0.1 wt % to about 5 wt % of ferric oxide
(Fe.sub.2O.sub.3).
[0027] The glazed composite is prepared using waste materials such
as ceramic wastes and colored glass wastes. Additionally, silica
sand can also be used as raw material along with the waste
materials. The waste materials, which are capable of producing
ceramic forming oxides, glass modifying oxides and ceramic
modifying oxides, are selected. Other oxides such as, but not
limited to, aluminum oxide (Al.sub.2O.sub.3), titanium dioxide
(TiO.sub.2), zirconium dioxide(ZrO.sub.2), ferric oxide
(Fe.sub.2O.sub.3), and manganese dioxide (MnO.sub.2) can also be
produced in various degrees in final formulation of the glazed
composites. The waste materials are selected in such a way that the
selected waste materials provide high amount of crystallize phases
in the final formulation of the composite.
[0028] In an embodiment, raw materials used to prepare the glazed
composite includes about 35 wt % to about 65 wt % of ceramic waste
and about 15 wt % to about 85 wt % of colored glass waste.
[0029] In another embodiment, raw materials used to prepare the
composite includes about 25 wt % to about 46 wt % of silica's sand,
about 10 wt % to about 47 wt % of ceramic waste and about 25 wt %
to about 46 wt % of colored glass waste.
[0030] Consider an exemplary case of ternary components, green
sample (homogenous mixture) with lowest ceramic waste is prepared
by mixing 10 wt % ceramic waste admixed with 45 wt % colored glass
and 45 wt % silica sand, while in case of highest ceramic waste,
44.45 wt % ceramic waste is admixed with 27.70 wt % colored glass
and 27.70 wt % silica sand. However, in case of binary components,
the green sample with lowest ceramic waste is prepared by mixing 10
wt % ceramic wastes admixed with 90 wt % colored glass, while the
green sample with highest ceramic wastes contain 90 wt % ceramic
wastes admixed with 10 wt % colored glass.
[0031] FIG. 3 illustrates glazed composite samples sintered at
different temperatures up to 1200.degree. C. FIG. 4 illustrates
self glazed composite samples (a, b, c, d and e) sintered at
different temperatures up to 1200.degree. C.
[0032] The glazed composite prepared using silica sand, ceramic
waste and color glass waste includes about 62 wt % to 80 wt %
quartz and cristobalite with low quartz crystalline phase. Other
crystalline material comprises wollastonite (CaSiO.sub.3). FIG. 5
illustrates X-ray diffraction analysis for developed crystalline
phases in samples prepared using silica sand, ceramic waste and
color glass waste and heated between 700.degree. C. and
1200.degree. C. The glazed composite sintered within the
temperature ranges between 700.degree. C. to 1200.degree. C. and
specified composition of the raw materials provides white ivory,
light creamy, brown, light brown and dark brown coloration. At
sintering temperature above 1000.degree. C. with high Al.sub.2O
content, interactions between constituents are evident. However
intense quartz peaks is accompanied by peaks related to
cristobalite and wollastonite. This may be a main factor which
affects color changes from dark brown to light brown.
[0033] The glazed composite prepared using ceramic waste and
colored glass waste contain about 62 wt % to 80 wt % quartz and
anorthite (CaAl.sub.2Si.sub.2O.sub.8) crystalline phase. Other
crystalline material comprising wollastonite (CaSiO.sub.3) and
cristobalite with low quartz. FIG. 6 illustrates X-ray diffraction
analysis for developed crystalline phases in samples prepared using
ceramic waste and color glass waste and heated between 700.degree.
C. and 1200.degree. C. The glazed composite sintered within the
temperature ranges between 700.degree. C. to 1200.degree. C. and
specified composition of the raw materials provides light creamy,
brown, light brown and dark brown coloration.
[0034] Various embodiments of the invention produce glazed
composite with significantly improved properties. The glazed
composite has improved micro-hardness and chemical durability. The
vickers microhardness (VH) values for the glazed composite of the
invention determined using procedures of ASTM E-384 ranges from
about 550 Kilogram per square millimeter (kg/mm.sup.2)to 650
kg/mm.sup.2 which is equivalent to 5 to 6 in MOH' scale. The
chemical durability is determined by weight loss of a test piece of
25.times.25.times.5 mm after 24hours immersion in 1% sulphuric acid
(H.sub.2SO.sub.4) solution at a temperature of 90.degree. C. The
chemical durability of the glazed composite in an acid medium is
between 0.0062 milligram per square centimeter (mg/cm.sup.2) to
0.1200 mg/cm.sup.2. The chemical durability of the glazed composite
was concluded from the developed phases such as quartz,
cristobalite and anorthite. The density of the glazed composite of
the invention ranges from 2.2382 grams per cubic centimeter
(g/cm.sup.3) to 2.0267 g/cm.sup.3. In comparison to the existing
composite products, the glazed composite produced by the invention
has improved micro-hardness, low density and good chemical
durability in the acid medium.
[0035] Various embodiments of the invention provides an environment
friendly glazed composite as ceramic waste and glass wastes are
used to manufacture the glazed composite. Further, the composite
obtained using the invention is self glazed and there is no need to
apply glazes separately. The glazed composite produced using the
invention is classified as sustainable green materials. If the
glazed composite is used in a building construction, the glazed
composite can be recycled and reused, as per international green
building criteria and standards. Thus, the environment friendly
glazed composite can be used to produce wall, floor tiles and for
cladding.
[0036] Those skilled in the art will realize that the above
recognized advantages and other advantages described herein are
merely exemplary and are not meant to be a complete rendering of
all of the advantages of the various embodiments of the
invention.
[0037] In the foregoing specification, specific embodiments of the
invention have been described. However, one of ordinary skill in
the art appreciates that various modifications and changes can be
made without departing from the scope of the invention as set forth
in the claims below. Accordingly, the specification is to be
regarded in an illustrative rather than a restrictive sense, and
all such modifications are intended to be included within the scope
of the invention. The benefits, advantages, solutions to problems,
and any element(s) that may cause any benefit, advantage, or
solution to occur or become more pronounced are not to be construed
as a critical, required, or essential features or elements of any
or all the claims. The invention is defined solely by the appended
claims including any amendments made during the pendency of this
application and all equivalents of those claims as issued.
* * * * *