U.S. patent application number 14/232723 was filed with the patent office on 2014-06-12 for system and method for forming composite articles.
This patent application is currently assigned to PLASAN CARBON COMPOSITES, INC.. The applicant listed for this patent is Douglas L. Bartolotti, Gary R. Lownsdale, Robert W. Murch. Invention is credited to Douglas L. Bartolotti, Gary R. Lownsdale, Robert W. Murch.
Application Number | 20140159267 14/232723 |
Document ID | / |
Family ID | 46640776 |
Filed Date | 2014-06-12 |
United States Patent
Application |
20140159267 |
Kind Code |
A1 |
Murch; Robert W. ; et
al. |
June 12, 2014 |
SYSTEM AND METHOD FOR FORMING COMPOSITE ARTICLES
Abstract
A thermal system (20) for rapidly heating and cooling a mold
surface (24) of a tool (26) comprises a heater-subsystem (40) in
fluid communication with the tool (26). The heater-subsystem (40)
comprises a heater (42), a tank (44), and a three-way valve (46).
The tank (44) contains a mass of heated thermal fluid. The system
(20) further comprises an exchanger-subsystem (49) in fluid
communication with the heater-sub system (40) and the tool (26).
The exchanger-subsystem (49) comprises an exchanger (51) and a
three-way valve (53). The system (20) further comprises a
chiller-sub system (48) in fluid communication with the
exchanger-subsystem (49). The chiller-subsystem (48) comprises a
chiller (50), a tank (52), and a three-way valve (54). The tank
(52) contains a mass of cooled thermal fluid. A controller (56) can
be used to control and/or instruct the subsystems (40,48,49). The
system (20) and tool (26) can be used for forming a composite
article (22), such as a carbon fiber composite (CFC) article (22).
A method utilizing the system (20) is also provided.
Inventors: |
Murch; Robert W.; (Wixom,
MI) ; Lownsdale; Gary R.; (Loudon, TN) ;
Bartolotti; Douglas L.; (Grand Rapids, MI) |
|
Applicant: |
Name |
City |
State |
Country |
Type |
Murch; Robert W.
Lownsdale; Gary R.
Bartolotti; Douglas L. |
Wixom
Loudon
Grand Rapids |
MI
TN
MI |
US
US
US |
|
|
Assignee: |
PLASAN CARBON COMPOSITES,
INC.
Bennington
VT
|
Family ID: |
46640776 |
Appl. No.: |
14/232723 |
Filed: |
July 30, 2012 |
PCT Filed: |
July 30, 2012 |
PCT NO: |
PCT/US2012/048832 |
371 Date: |
January 14, 2014 |
Related U.S. Patent Documents
|
|
|
|
|
|
Application
Number |
Filing Date |
Patent Number |
|
|
61574151 |
Jul 28, 2011 |
|
|
|
Current U.S.
Class: |
264/40.6 ;
425/144 |
Current CPC
Class: |
B29C 35/007 20130101;
B29C 35/0294 20130101 |
Class at
Publication: |
264/40.6 ;
425/144 |
International
Class: |
B29C 35/00 20060101
B29C035/00; B29C 35/02 20060101 B29C035/02 |
Claims
1. A thermal system (20) for rapidly heating and cooling a mold
surface (24) of a tool (26) used for forming a composite article
(22), said thermal system (20) comprising: I) a heater-subsystem
(40) in fluid communication with the tool (26) and comprising; a
heater (42) for heating a first thermal fluid, a tank (44) in fluid
communication with said heater (42) and containing a mass of heated
first thermal fluid, and a three-way valve (46) in fluid
communication i) between said tank (44) and said heater (42) for
re-circulating the first thermal fluid from said tank (44) to said
heater (42) and ii) between said tank (44) and the tool (26) for
directing the first thermal fluid from said tank (44) to the tool
(26); II) an exchanger-subsystem (49) in fluid communication with
said heater-subsystem (40) and the tool (26) and comprising; an
exchanger (51) for cooling the first thermal fluid returning from
the tool (26), and a three-way valve (53) in fluid communication i)
between said exchanger (51) and said heater-subsystem (40) for
sending the first thermal fluid from the tool (26) back to the
heater-subsystem (40) and ii) between said exchanger (51) and the
tool (26) for directing the first thermal fluid from the tool (26)
to said exchanger (51); and III) a chiller-subsystem (48) in fluid
communication with said exchanger-subsystem (49) and comprising; a
chiller (50) to cool a second thermal fluid, a tank (52) in fluid
communication with said chiller (50) and containing a mass of
cooled second thermal fluid, and a three-way valve (54) in fluid
communication i) between said tank (52) and said chiller (50) for
re-circulating the second thermal fluid from said tank (52) to said
chiller (50) and ii) between said tank (52) and said
exchanger-subsystem (49) for directing the second thermal fluid
from said tank (52) to said exchanger (51).
2. The thermal system (20) as set forth in claim 1 further
comprising a controller (56) in communication with said subsystems
(40,48,49) and the tool (26) for directing the thermal fluids
within the thermal system (20) via control of the three-way valves
(46,53,54).
3. The thermal system (20) as set forth in claim 2 wherein said
controller (56) is programmed to instruct said three-way valve (46)
of said heater-subsystem (40) such that the first thermal fluid: i)
re-circulates between said heater (42) and said tank (44) and
bypasses the tool (26) to maintain the mass of heated first thermal
fluid in said heater-subsystem (40); or ii) is directed from said
heater-subsystem (40) to the tool (26) to heat the mold surface
(24) of the tool (26).
4. (canceled)
5. The thermal system (20) as set forth in claim 2 wherein said
controller (56) is programmed to instruct said three-way valve (54)
of said chiller-subsystem (48) such that the second thermal fluid:
i) re-circulates between said chiller (50) and said tank (52) and
bypasses said exchanger-subsystem (49) to maintain the mass of
cooled second thermal fluid in said chiller-subsystem (48); or ii)
is directed from said chiller-subsystem (48) to said
exchanger-subsystem (49) to cool the first thermal fluid returning
from the tool (26) and entering said exchanger-subsystem (49).
6. (canceled)
7. The thermal system (20) as set forth in claim 2 wherein said
controller (56) is programmed to instruct said three-way valve (53)
of said exchanger-subsystem (49) such that the first thermal fluid
returning from the tool (26) is directed to: i) said
heater-subsystem (40) and bypasses said exchanger-subsystem (49) to
reheat the first thermal fluid within said heater-subsystem (40);
or ii) said exchanger-subsystem (49) to cool the first thermal
fluid via the second thermal fluid from the chiller-subsystem
(48).
8. (canceled)
9. The thermal system (20) as set forth in claim 1 further
comprising: i) a pump (55) in fluid communication between the tool
(26), said heater-subsystem (40), and said exchanger-subsystem
(49), for directing the first thermal fluid from said subsystems
(40,49) to the tool (26); ii) at least one supplemental valve (58)
in fluid communication a) between said heater-subsystem (40) and
the tool (26) for directing the first thermal fluid to and from the
tool (26) and said heater-subsystem (40) and/or b) between said
exchanger-subsystem (49) and the tool (26) for directing the first
thermal fluid to and from the tool (26) and said
exchanger-subsystem (49); or iii) both i) and ii).
10. (canceled)
11. The thermal system (20) as set forth in claim 1 wherein; the
first thermal fluid is shared between said heater-subsystem (40)
and said exchanger-subsystem (49), the second thermal fluid is
shared between said chiller-subsystem (48) and said
exchanger-subsystem (49), and the first thermal fluid is kept
separate from the second thermal fluid.
12. The thermal system (20) as set forth in claim 1 wherein the
first thermal fluid is different from the second thermal fluid.
13-14. (canceled)
15. The thermal system (20) as set forth in claim 1 wherein; the
mold surface (24) of the tool (26) heats at a rate of greater than
about 33.degree. C. per minute (60.degree. F./min), alternatively
greater than about 39.degree. C. per minute (70.degree. F./min),
via the heater-subsystem (40), and the mold surface (24) of the
tool (26) cools at a rate of greater than about 22.degree. C. per
minute (40.degree. F./min), alternatively greater than about
28.degree. C. per minute (50.degree. F./min), via the
exchanger-subsystem (49) and the chiller-subsystem (48).
16. (canceled)
17. The thermal system (20) as set forth in claim 1 further
comprising: a tool-connection system (200) operatively connected to
said tool (26), and a press-connection system (218) in fluid
communication with said heater-subsystem (40) and said
exchanger-subsystem (49), wherein said connection systems (200,218)
couple together for feeding and receiving the first thermal fluid
to and from said tool (26).
18. The thermal system (20) as set forth in claim 17: i) wherein
said tool (26) includes tubing (28) opposite said mold surface (24)
and said press-connection system (218) is operatively connected to
said tubing (28) for heating and cooling said mold surface (24)
with the first thermal fluid; ii) further comprising a press (64)
having a platform (68) and a cover (70) facing said platform (68)
with said cover (70) operable to couple with said platform (68) to
define a cavity (72) operable to maintain a pressurized and/or
temperature controlled environment and wherein said
press-connection system (218) is operatively connected through said
cover (70) and/or said platform (68) into the cavity (72) for
coupling with said tool-connection system (200) while said tool
(26) is disposed within the cavity (70) of the press (64) for
heating and cooling said mold surface (26) with the first thermal
fluid; or iii) both i) and ii).
19-20. (canceled)
21. A method of rapidly heating and cooling a mold surface (24) of
a tool (26) used for forming a composite article (22), said method
comprising the steps of: providing a heater-subsystem (40) in fluid
communication with the tool (26) and comprising; a heater (42) for
heating a first thermal fluid, a tank (44) in fluid communication
with the heater (42) and containing a mass of heated first thermal
fluid, and a three-way valve (46) in fluid communication i) between
the tank (44) and the heater (42) for re-circulating the first
thermal fluid from the tank (44) to the heater (42) and ii) between
the tank (44) and the tool (26) for directing the first thermal
fluid from the tank (44) to the tool (26); providing an
exchanger-subsystem (49) in fluid communication with the
heater-subsystem (40) and the tool (26) and comprising; an
exchanger (51) for cooling the first thermal fluid returning from
the tool (26), and a three-way valve (53) in fluid communication i)
between the exchanger (51) and the heater-subsystem (40) for
sending the first thermal fluid from the tool (26) back to the
heater-subsystem (40) and ii) between the exchanger (51) and the
tool (26) for directing the first thermal fluid from the tool (26)
to the exchanger (51); and providing a chiller-subsystem (48) in
fluid communication with the exchanger-subsystem (49) and
comprising; a chiller (50) to cool a second thermal fluid, a tank
(52) in fluid communication with the chiller (50) and containing a
mass of cooled second thermal fluid, and a three-way valve (54) in
fluid communication i) between the tank (52) and the chiller (50)
for re-circulating the second thermal fluid from the tank (52) to
the chiller (50) and ii) between the tank (52) and the
exchanger-subsystem (49) for directing the second thermal fluid
from the tank (52) to the exchanger (51); providing a controller
(56) in communication with the tool (26) and the subsystems
(40,48,49) for instructing the subsystems (40,48,49); directing the
mass of heated first thermal fluid from the tank (44) of the
heater-subsystem (40) to the tool (26) via the controller (56) to
heat the mold surface (24) of the tool (26) from a first
temperature (T.sub.1) to a second temperature (T.sub.2) within a
first period of time (Tt.sub.1); directing the mass of heated first
thermal fluid from the tank (44) of the heater-subsystem (40) to
the mold surface (24) of the tool (26) via the controller (56) to
maintain the mold surface (24) at T.sub.2 for a second period of
time (Tt.sub.2); and directing the mass of cooled second thermal
fluid from the tank (52) of the chiller-subsystem (48) to the
exchanger-subsystem (49) via the controller (56) to cool the mold
surface (24) of the tool (26) from T.sub.2 to a third temperature
(T.sub.3) within a third period of time (Tt.sub.3); wherein the
mold surface (24) of the tool (26) heats at a rate of greater than
about 33.degree. C. per minute (60.degree. F./min) and cools at a
rate of greater than about 22.degree. C. per minute (40.degree.
F./min); and wherein Tt.sub.1+Tt.sub.2+Tt.sub.3 is no greater than
20 minutes.
22. (canceled)
23. The method as set forth in claim 21 wherein the controller (56)
instructs the three-way valve (46) of the heater-subsystem (40)
such that the first thermal fluid: i) re-circulates between the
heater (42) and the tank (44) and bypasses the tool (26) to
maintain the mass of heated first thermal fluid in the
heater-subsystem (40) at a temperature of T.sub.2 or higher; or ii)
is directed from the heater-subsystem (40) to the tool (26) to heat
the mold surface (24) of the tool (26) from T.sub.1 to T.sub.2.
24. (canceled)
25. The method as set forth in claim 21 wherein the controller (56)
instructs the three-way valve (54) of the chiller-subsystem (48)
such that the second thermal fluid: i) re-circulates between the
chiller (50) and the tank (52) and bypasses the exchanger-subsystem
(49) to maintain the mass of cooled second thermal fluid in the
chiller-subsystem (48) at a temperature of T.sub.3 or lower; or ii)
is directed from the chiller-subsystem (48) to the
exchanger-subsystem (49) to cool the first thermal fluid returning
from the tool (26) and entering the exchanger-subsystem (49) to a
temperature lower than T.sub.2.
26. (canceled)
27. The method as set forth in claim 21 wherein the controller (56)
instructs the three-way valve (53) of the exchanger-subsystem (49)
such that the first thermal fluid returning from the tool (26) is
directed to: i) the heater-subsystem (40) and bypasses the
exchanger-subsystem (49) to reheat the first thermal fluid within
the heater-subsystem (40) to a temperature of T.sub.2 or higher; or
ii) the exchanger-subsystem (49) to cool the first thermal fluid
via the second thermal fluid from the chiller-subsystem (48) to a
temperature lower than T.sub.2.
28. (canceled)
29. The method as set forth in claim 21 further comprising the step
of maintaining the mold surface (24) of the tool (26) at an
intermediate temperature (T.sub.1-2) of between T.sub.1 and T.sub.2
via the controller (56) for a portion of Tt.sub.1 (Tt.sub.<1)
prior to heating the mold surface (24) of the tool (26) to
T.sub.2.
30. The method as set forth in claim 29 wherein: i) T.sub.1-2 is
from about 38.degree. C. (100.degree. F.) to about 177.degree. C.
(350.degree. F.); ii) Tt.sub.<1 is from 1 to less than 10
minutes; or iii) both i) and ii).
31. (canceled)
32. The method as set forth in claim 21 wherein: i) T.sub.1 is from
about 10.degree. C. (50.degree. F.) to about 52.degree. C.
(125.degree. F.); and/or ii) T.sub.2 is from about 121.degree. C.
(250.degree. F.) to about 204.degree. C. (400.degree. F.); and/or
iii) T.sub.3 is from about 24.degree. C. (75.degree. F.) to about
66.degree. C. (150.degree. F.).
33-34. (canceled)
35. The method as set forth in claim 21 wherein Tt.sub.1 is from 1
to 10 minutes, Tt.sub.2 is from 1 to 10 minutes, and Tt.sub.3 is
from 1 to 10 minutes, provided that Tt.sub.1+Tt.sub.2+Tt.sub.3 is
no greater than 20 minutes.
36-37. (canceled)
38. The method as set forth in claim 21 wherein: i) the mass of
heated first thermal fluid in the tank (44) of the heater-subsystem
(40) is at a temperature of T.sub.2 or higher for heating the mold
surface (24) of the tool (26) with the mass of heated fluid; ii)
the mass of cooled second thermal fluid in the tank (52) of the
chiller-subsystem (48) is at a temperature of T.sub.3 or lower for
cooling the mold surface of the tool (26); or iii) both i) and
ii).
39-41. (canceled)
Description
CROSS REFERENCE TO RELATED APPLICATIONS
[0001] This application claims the benefit of U.S. Provisional
Patent Application Ser. No. 61/574,151, filed on Jul. 28, 2011 and
entitled "SYSTEM FOR FORMING COMPOSITE ARTICLES", which is
incorporated herein by reference in its entirety.
FIELD OF THE INVENTION
[0002] The present invention generally relates to a system and
method for forming composite articles, and more specifically to a
thermal system and method for forming carbon fiber composite
articles.
DESCRIPTION OF THE RELATED ART
[0003] Carbon fiber composite (CFC) articles typically comprise two
or more layers of a carbon fiber mat comprising carbon fiber
filaments, which are impregnated by a plastic resin, in a final
cured state. Conventional methods for forming CFC articles include
vacuum bag molding, pressure molding, Virtual Engineered Composites
(VEC) molding, autoclave molding, and resin transfer molding (RTM).
Newer automotive industry regulations, including the Corporate
Average Fuel Economy (CAFE), Head Impact Characteristic (HIC), and
Pedestrian Protection, represent a challenge to conventional
materials used in automobiles, such as steel. Relative to steel,
CFC articles include an excellent combination of physical
properties including strength, weight, and energy absorption. As
such, CFC articles are able to meet these newer requirements, such
as requirements for mass reduction and energy absorption.
[0004] Unfortunately, a major issue with conventional CFC articles
is the amount of time it takes to manufacture CFC articles relative
to conventional articles, such as those made out of steel. In
addition, it can be time consuming and difficult to achieve CFC
articles with aesthetically pleasing surfaces, such as "Class A"
surfaces. As such, there remains an opportunity to provide improved
methods and systems for forming CFC articles.
SUMMARY OF THE INVENTION AND ADVANTAGES
[0005] The present invention provides a thermal system for rapidly
heating and cooling a mold surface of a tool. The thermal system
comprises a heater-subsystem in fluid communication with the tool.
The heater-subsystem comprises a heater for heating a first thermal
fluid, a tank in fluid communication with the heater and containing
a mass of heated first thermal fluid, and a three-way valve. The
three-way valve is in fluid communication i) between the tank and
the heater for re-circulating the first thermal fluid from the tank
to the heater and ii) between the tank and the tool for directing
the first thermal fluid from the tank to the tool. The thermal
system further comprises an exchanger-subsystem in fluid
communication with the heater-subsystem and the tool. The
exchanger-subsystem comprises an exchanger for cooling the first
thermal fluid returning from the tool, and a three-way valve. The
three-way valve is in fluid communication i) between the exchanger
and the heater-subsystem for sending the first thermal fluid from
the tool back to the heater-subsystem and ii) between the exchanger
and the tool for directing the first thermal fluid from the tool to
the exchanger. The thermal system further comprises a
chiller-subsystem in fluid communication with the
exchanger-subsystem. The chiller-subsystem comprises a chiller to
cool a second thermal fluid, a tank in fluid communication with the
chiller and containing a mass of cooled second thermal fluid, and a
three-way valve. The three-way valve is in fluid communication i)
between the tank and the chiller for re-circulating the second
thermal fluid from the tank to the chiller and ii) between the tank
and the exchanger-subsystem for directing the second thermal fluid
from the tank to the exchanger. The tool can be used for forming a
composite article, such as a carbon fiber composite article.
[0006] The present invention also provides a method of rapidly
heating and cooling the mold surface of the tool. The method
comprises the steps of providing the heater-subsystem, providing
the exchanger-subsystem, providing the chiller-subsystem, and
providing a controller. The controller is in communication with the
tool and the subsystems for instructing the subsystems. The method
further comprises the step of directing the mass of heated first
thermal fluid from the tank of the heater-subsystem to the tool via
the controller to heat the mold surface of the tool from a first
temperature (T.sub.1) to a second temperature (T.sub.2) within a
first period of time (Tt.sub.1). The method further comprises the
step of directing the mass of heated first thermal fluid from the
tank of the heater-subsystem to the mold surface of the tool via
the controller to maintain the mold surface at T.sub.2 for a second
period of time (Tt.sub.2). The method further comprises the step of
directing the mass of cooled second thermal fluid from the tank of
the chiller-subsystem to the exchanger-subsystem via the controller
to cool the first thermal fluid returning from the tool from
T.sub.2 to a third temperature (T.sub.3) within a third period of
time (Tt.sub.3). The mold surface of the tool heats at a rate of
greater than about 60.degree. F. (.about.33.degree. C.) per minute
and cools at a rate of greater than about 40.degree. F.
(.about.22.degree. C.) per minute. Tt.sub.1+Tt.sub.2+Tt.sub.3 is no
greater than about 20 minutes.
[0007] The present invention provides various benefits over
conventional systems and methods for forming composite articles.
For example, conventional methods, such as autoclaving, generally
have cycle times that are well over an hour, typically cycle times
of 75 minutes or longer. Such cycle times are the times in which
the composite articles are formed within the autoclave (e.g. during
cure of a resin).
[0008] In a typical autoclave process, preforms are disposed on
tools, the tools are loaded into the autoclave, vacuum bags (or
other vacuum means) are attached to the tools, the autoclave is
closed, vacuum is applied, and the autoclave is heated and
pressurized with nitrogen gas (N.sub.2) for an extended period of
time, e.g. 75+ minutes, to form the composite articles. N.sub.2 is
generally required to prevent flash fires in the autoclave due to
exotherms. Additional time associated with loading, closing,
opening, and unloading the autoclave further decreases output.
[0009] The autoclave takes a long time to heat and requires the use
of N.sub.2 for safety reasons. As such, energy costs associated
with the autoclave tends to be high. In order to increase output of
composite articles, autoclaves tend to be large in size, thereby
having a large footprint. Such sizing of the autoclave also
requires a large number of heavy and expensive tools, further
adding to capital and manufacturing costs.
[0010] Autoclaves are also prone to making scrap parts. For
example, if vacuum fails (or is interrupted) on one (or more) of
the tools while in the autoclave, the composite article will cure
in an improper configuration, e.g. a non-consolidated form. The
vacuum cannot be reestablished until after the cure cycle is
complete, which is too late to save the composite article. As such,
the composite article(s) with vacuum problems must be scrapped
after being removed from the autoclave.
[0011] Composite articles formed in autoclaves also tend to suffer
from surfaces blemishes, such as pits of various location, diameter
and depth. Such surface blemishes must be removed during finishing
steps of the composite article, such as by filling and sanding,
further adding to manufacturing costs.
[0012] The thermal system and method of the present invention
provide one or more benefits over the prior art. The present
invention provides for excellent temperature control relative to
conventional autoclaving systems and methods. The present invention
can provide reduced cycle times relative to autoclave cycles, which
provides for increased output. Reduced energy costs may also be
appreciated. A reduced footprint may be provided by the thermal
system relative to large autoclaves. The same or similar
chemistries and/or materials generally used for conventional
autoclave methods, e.g. resins, may generally be used with the
present invention, therefore not requiring chemistry or material
redesign.
[0013] The present invention generally provides composite articles
which have excellent surface properties that generally match those
of carbon composite articles formed in an autoclave. For example,
surface blemishes (e.g. pits) are generally reduced in number
and/or severity. In addition or alternatively, the present
invention generally provides composite articles which have
excellent mechanical properties that match or exceed those of
carbon composite articles formed in an autoclave.
BRIEF DESCRIPTION OF THE DRAWINGS
[0014] Other advantages of the present invention will be readily
appreciated, as the same becomes better understood by reference to
the following detailed description when considered in connection
with the accompanying drawings wherein:
[0015] FIG. 1 is a schematic view of a thermal system having a
heater-subsystem, a valve, a controller, a press, a tool disposed
within the press, and a pressure tank;
[0016] FIG. 2 is a schematic view of another embodiment of the
thermal system having a heater-subsystem, a chiller-subsystem,
valves, the controller, the press, the tool disposed within the
press, and the pressure tank;
[0017] FIG. 3 is a partially exploded perspective view of the tool,
a vacuum canopy, and a preform of a composite article disposed
between the tool and vacuum canopy;
[0018] FIG. 4 is a cross-sectional end-view of the tool having a
mold surface and tubing, the vacuum canopy attached to the tool,
and the preform of the composite article disposed between the mold
surface and vacuum canopy;
[0019] FIG. 5 is a perspective view of a support table, the tool
disposed on the support table, the vacuum canopy disposed on the
tool, and the press having a platform and a cover;
[0020] FIG. 6 is an enlarged perspective view detailing portions of
the press and tool illustrated in FIG. 5, with the press including
a carrier and rams for moving the tool in and out of the press;
[0021] FIG. 7 is a partial cross-sectional end-view of the press
having a cavity defined between the platform and the cover, the
tool having the mold surface and tubing, the vacuum canopy attached
to the tool, and the preform of the composite article disposed
between the mold surface and vacuum canopy;
[0022] FIG. 8 is a perspective simplified environmental view of
another embodiment of the press, support tables, and composite
articles, with technicians disposing a preform of the composite
article on a mold surface of the tool disposed on one of the
support tables;
[0023] FIG. 9 is a cross-sectional side-view of a mandrel having a
mandrel surface and tubing, with pieces of a carbon fiber sheet
being disposed on the mandrel surface, and a vacuum sheet being
disposed over the pieces on the mandrel surface;
[0024] FIG. 10 is a flow chart generally illustrating additional,
optional, manufacturing steps for forming the composite
article;
[0025] FIG. 11 is a graph illustrating temperature, pressure,
vacuum and heater profiles over time for an invention example of
the composite article using the thermal system and press;
[0026] FIG. 12 is another graph illustrating temperature, pressure,
and vacuum profiles over time for another invention example of the
composite article using the thermal system and press;
[0027] FIG. 13 is another graph illustrating temperature, pressure,
and vacuum profiles over time for another invention example of the
composite article using the thermal system and press;
[0028] FIG. 14 is a graph illustrating temperature, pressure,
vacuum and heater profiles over time for a comparative example of a
composite article using a conventional autoclave;
[0029] FIG. 15 is a perspective view of a tool-connection system
operatively connected to the tool, with the tool-connection system
including connections for feed and return of thermal fluid to and
from the tubing of the tool, connections for a vacuum and static
line for pressure monitoring, and a connection for a resistive
thermal device (RTD) for temperature monitoring and providing
feedback;
[0030] FIG. 16 is a perspective view of a press-connection system
operatively connected to the cover of the press for coupling with
the tool-connection system shown in FIG. 15, with the
press-connection system including connections for feed and return
of thermal fluid through the cover of the press and to and from the
tubing of the tool, connections for a vacuum and static line for
pressure monitoring, and a connection for a RTD for temperature
monitoring and providing feedback;
[0031] FIG. 17 is a partial cross-sectional side-view of the press
having the cavity defined between the platform and the cover, with
the tool-connection system and the press-connection system coupled
together such that thermal fluid can be communicated to and from
the tool with the thermal system; and
[0032] FIG. 18 is a schematic view of another embodiment of the
thermal system having a heater-subsystem, a chiller-subsystem, an
exchanger-subsystem, valves, the controller, the press, the tool
disposed within the press, and the pressure tank.
DETAILED DESCRIPTION OF THE INVENTION
[0033] Referring to the Figures, wherein like numerals indicate
like parts throughout the several views, a thermal system is
generally shown at 20. The thermal system 20 is hereinafter simply
referred to as the system 20. The system 20 can be used for forming
various types of articles. The system 20 is useful for forming
composite articles 22, such as carbon fiber reinforced plastics 22
or carbon fiber composite (CFC) articles 22. CFC articles 22 are
useful in many industries, such as in the automotive, marine,
military defense, aeronautical, aerospace, and medical equipment
industries.
[0034] The system 20 is especially useful for forming "Class A" CFC
body panels 22 across entire vehicle platforms. Examples of body
panels 22 and related parts include hoods, fenders, roofs, rockers,
splitters, roof bows, dive planes, wings, mirror caps, deflectors,
etc. Further examples of CFC articles 22 include deck-lids, battery
applications, control arms, bumpers, cradles/sub-frames, and other
structural components. The system 20 is not limited to forming any
particular type of composite article 22, or composite articles 22
for a particular industry, and such composite articles 22 can be of
various sizes, shapes, and use. The composite articles 22 are
described further below.
[0035] The system 20 is useful for heating and cooling a mold
surface 24 of a tool 26. Specifically, the system 20 is useful for
heating and cooling a fluid, with the fluid used for directly (or
nearly directly) heating and cooling the mold surface 24 of the
tool 26. The system 20 can be used in combination with or separate
from the methods of the present invention. The invention methods
are described further below, and can be used in combination with or
separate from the system 20.
[0036] The tool 26 can be a portion of a mold (e.g. a two-piece
mold) where the tool 26 is a top mold and another tool is a bottom
mold, or vice versa. The tool 26 is typically a one-piece mold 26
(e.g. an open mold). The system 20 is generally associated with at
least one type of the tool 26, but may be associated with two or
more different types of tools 26, which can be the same as or
different from each other. The tool 26 can be of various types,
albeit possibly being modified for communicating with the system
20.
[0037] In certain embodiments, the tool 26 is of the type (or
similar to the type) generally used in conventional autoclaves.
However, the system 20 is not typically associated with an
autoclave. In other words, the system 20 is generally free of an
autoclave, as are the invention methods. In one embodiment, the
tool 26 is of the type generally used for vacuum molding (or
forming). In another embodiment, the tool 26 is of the type
generally used for resin transfer molding (RTM). It is to be
appreciated that other types of tools 26 can also be used.
[0038] The mold surface 24 and the tool 26 may be unitary, i.e., a
single body. In certain embodiments, the mold surface 24 and the
tool 26 are separate pieces joined together, e.g. by fasteners, by
welding, etc. As such, different mold surfaces 24 may be used with
different tools 26 or vice versa. This allows for
interchangeability between different mold surfaces 24 and/or
different tools 26 for forming different types of composite
articles 22.
[0039] The mold surface 24 of the tool 26 can be configured to have
various shapes. Typically, the mold surface 24 is configured in a
shape corresponding to a particular composite article 22 being
made, e.g. a hood, a fender, a spoiler, etc. The mold surface 24 is
not limited to any particular shape.
[0040] The mold surface 24 of the tool 26 is typically formed from
a metallic material, which is useful for heat transfer, such as
nickel, steel, etc. In certain embodiments, the mold surface 24
comprises a nickel alloy 22. In these embodiments, the mold surface
24 is generally rigid and inflexible (which is different from a
rubber or "bladder" type mold surface). Metallic mold surfaces 24
generally have a high thermal conductivity, which allows for rapid
heating and cooling of the mold surface 24. This is especially true
when utilized along with the system 20. The mold surface 24 can be
of various thicknesses, typically of from about 5 to about 20, from
about 7.5 to about 15, or from about 10 to about 12.5, mm. Suitable
mold surfaces 24 are commercially available from a variety of
suppliers. Specific examples of mold surfaces 24 include those
commercially available from Weber Manufacturing Team of Midland,
Ontario, Canada, such as nickel shell mold surfaces 24;
Visioneering Inc. of Fraser, Mich.; and Models & Tools Inc. of
Troy, Mich., such as mold surfaces 24 formed from Invar (or
"64FeNi").
[0041] Referring to FIG. 4, the tool 26 typically includes tubing
28 for communicating the fluid. The tubing 28 includes at least one
input 30 for communicating fluid to the tubing 28 and at least one
outlet 32 for communicating fluid from the tubing 28. The tubing 28
is proximal or directly in contact with the mold surface 24 to
expedite heat transfer between the tubing 28 and the mold surface
24. The tubing 28 is useful for direct (rather than indirect)
heating or cooling of the mold surface 24. The tubing 28 may be
formed into the tool 26 itself (such as by boring within the tool
26), or attached within the tool 26 proximal the mold surface 24,
either to the tool 26 and/or to the mold surface 24. The tubing 28
can be attached (e.g. to the mold surface 24) in various fashions,
such as by welding, fasteners, etc.
[0042] The tubing 28 can be arranged in various patterns and may be
of equal or varying diameters. For example, if the mold surface 24
is complex in shape, a portion of the tubing 28 can be concentrated
in more critical areas of the mold surface 24 to ensure proper
heating and cooling of those areas. As alluded to above, the mold
surface 24 may be of various configurations, and can be
substantially planar, three-dimensional, or a combination of
shapes. The tubing 28 can be configured likewise to provide for
direct heating of the mold surface 24. The tool 26 may have one or
more fasteners 34, e.g. clamps 34, for attaching a vacuum canopy 36
to the tool 26. Various types of fasteners 34 may be employed. The
vacuum canopy 36 is described further below. In other embodiments,
a conventional vacuum bag (not shown) can be utilized.
[0043] The tubing 28 of the tool 26 is connected to piping 38 of
the system 20 for communicating the fluid to and from the tool 26
and to and from the system 20 for heating and cooling the mold
surface 24. Various types of piping 38 can be employed. The piping
38 should be capable of handling the temperatures and pressures
present in the system 20. The piping 38 can be of various
diameters. For example, the piping 38 can have a diameter of from
about 0.5 to about 4, about 0.75 to about 3, about 1 to about 2, or
about 2, inches (or about 1.3 to about 10, about 1.9 to about 7.6,
about 2.5 to about 5, or about 5, cm), outer diameter (OD).
[0044] The tubing 28 may have more than one input 30 and output 32.
For example, there may be two or more sets of discrete tubing 28
arrangements within the tool 26 for better control of heating and
cooling of the mold surface 24. Suitable tools 26 are commercially
available from a variety of suppliers. Specific examples of tools
26 include those commercially available from Weber Manufacturing
Team, such as nickel shell tooling.
[0045] The fluid carried within the system 20 is typically a heat
transfer fluid, which may also be referred to as a thermal fluid.
Various types of fluids can be employed. Typically, the fluid used
within at least the tool 26 is an oil, e.g. thermal oil, (rather
than water) due to the temperatures reached in the system 20. Water
may be used elsewhere in the system 20, and combinations of thermal
oil and water may be used in certain embodiments. Suitable fluids
are commercially available from a variety of suppliers. Specific
examples of fluids include those commercially available from Mokon
of Buffalo, N.Y., including DELF450 and DELF600. Further examples
of fluids include those commercially available from Multitherm of
Malvern, Pa., including PG-1 and IG-4; from Paratherm Corp. of West
Conshohocken, Pa., including NF and HE; from Petro-Canada Products,
including Calflo.TM. FG and Calflo.TM. HTF; from Solutia Inc. of
St. Louis, Mo., including Therminol.RTM. 66; and from Duratherm of
Lewiston, N.Y., including Duratherm 450, Duratherm 600, and
Duratherm Lite (or LT). The fluid should be capable of handling the
temperatures of the system 20, and may include a blend of two or
more different fluids. Typically, the system 20 is closed-loop;
however, at times, the system 20 may have some amount of fluid
added thereto or withdrawn therefrom.
[0046] Referring to FIG. 1, which illustrates one embodiment of the
system 20, the system 20 comprises a heater-subsystem 40. The
heater-subsystem 40 is in fluid communication with the tool 26. The
heater-subsystem 40 is useful for heating the mold surface 24 of
the tool 26. In certain embodiments, the heater-subsystem 40 can
also be used for cooling the mold surface 24 of the tool 26.
[0047] The heater-subsystem 40 comprises a heater 42. The heater 42
is useful for heating the fluid within the system 20. Various types
of heaters 42 can be employed. The heater 42 should be capable of
heating the fluid to temperatures of at least about 3.degree. F.
(.about.-16.degree. C.) to about 350.degree. F. (.about.177.degree.
C.), or upwards of about 600.degree. F. (.about.315.degree. C.) to
about 650.degree. F. (.about.343.degree. C.). Generally, the hotter
the fluid coming into the tool 26, the quicker the mold surface 24
heats. The heater 42 should also be capable of delivering various
outputs of the fluid. Examples of suitable outputs are from about
10 to about 120, from about 20 to about 100, from about 40 to about
90, or about 60, gallons per minute (gpm) (or about 38 to about
454, about 76 to about 379, about 151 to about 341, or about 227,
liters per minute). Suitable heaters 42 are commercially available
from a variety of suppliers. Specific examples of heaters 42
include those commercially available from Mokon, including the HTF
Series, e.g. the HTF 500 Series, the HTF 600 Series, the HTF HF-2
Series, and the ST Series, heaters. Gas fired heaters, such as
those commercially available from Fulton Boiler Works, Inc. of
Pulaski, N.Y., can also be used, e.g. a Fulton FT-0320-C Thermal
Fluid Heater. As used herein, a tilde character (.about.) is meant
to represent an approximation based, for example, on unit
conversion from US to SI units.
[0048] The heater-subsystem 40 further comprises a tank 44. The
tank 44 of the heater-subsystem 40 is useful for containing a mass
of heated fluid. The tank 44 of the heater-subsystem 40 serves as a
heat buffer in the system 20, as described further below. The tank
44 of the heater-subsystem 40 is in fluid communication with the
heater 42. Various types of tanks can be employed as the tank 44 of
the heater-subsystem 40. The tank 44 of the heater-subsystem 40
should be capable of holding fluid at temperatures of at least
about 300.degree. F. (.about.157.degree. C.) to about 350.degree.
F. (.about.177.degree. C.), and upwards of about 600.degree. F.
(.about.315.degree. C.) to about 650.degree. F. (.about.343.degree.
C.). Typically, the tank 44 of the heater-subsystem 40 should be
rated for more than the highest temperature output of the heater
42. In certain embodiments, the heater-subsystem 40 comprises two
of more tanks (not shown). For example, the mass of fluid contained
in one tank 44 may be at a different temperature than that of
another tank 44. This may be useful for buffering the system 20
with masses of heated fluid at different temperatures. The tank 44
is typically separate from the heater 42, i.e., the tank 44 is
distinguishable from an "internal" tank of the heater 42, if
present.
[0049] Generally, the tank 44 of the heater-subsystem 40 is
insulated, either itself, and/or with a supplemental layer of
insulation, to prevent cooling of the mass of heated fluid
contained therein by the ambient environment. Various types of
insulation means can be employed. For example, the tank 44 of the
heater-subsystem 40 can be wrapped with an insulated jacket. Piping
38 of the system 20, or portions thereof, should also be wrapped or
covered for purposes of insulation and safety. For example, the
piping 38 running from the heater-subsystem 40 to the tool 26 can
be insulated to prevent heat loss, burns, fires, etc.
[0050] The tank 44 of the heater-subsystem 40 can be of various
sizes and shapes. It may be useful to reduce the surface area to
volume ratio (SA:V) of the tank 44 of the heater-subsystem 40 to
reduce heat loss; however, this is not required. The tank 44 of the
heater-subsystem 40 should be sized to hold of from about 50 to
about 250, from about 100 to about 225, from about 100 to about
200, or from about 100 to about 150, gallons of the fluid (or about
189 to about 946, from about 378 to about 852, from about 378 to
about 757, or from about 378 to about 568, liters of the fluid).
Generally, a larger size tank 44 provides for a greater heat buffer
in the system 20. Reference to the mass of heated fluid associated
with the tank 44 of the heater-subsystem 40 may refer to a portion
to an entirety of the heated fluid contained within the tank 44 at
a given instance. The masses of fluid described herein may also be
referred to as stored (thermal) energy masses.
[0051] The heater-subsystem 40 further comprises a valve 46 in
fluid communication between the tank 44 of the heater-subsystem 40
and the heater 42. Various types of valves 46 can be employed.
Typically, the valve 46 is a three-way valve 46. The three-way
valve 46 of the heater-subsystem 40 is useful for re-circulating
the fluid between the tank 44 of the heater-subsystem 40 and the
heater 42. This arrangement is useful for initially forming,
maintaining, and/or recharging the mass of heated fluid in the tank
44 of the heater-subsystem 40. For example, once a portion (or all)
of the mass of heated fluid is fed to the tool 26, fluid returning
from the tool 26 can be fed to the heater 42 and then to the tank
44 of the heater-subsystem 40 to maintain or recharge the mass of
heated fluid. The heated fluid may then be held or re-circulated in
one or more passes between the heater 42 and the tank 44 of the
heater-subsystem 40 to further increase or maintain temperature of
the mass of heated fluid. This is also useful if the heater 42
can't keep up with demands of the tool 26 and/or the system 20,
where the mass of heated fluid serves as a buffer for the heater 42
to catch-up or recover. This is also useful for maintaining a near
steady-state temperature of the fluid within the heater-subsystem
40 to meet ongoing demands of the tool 26 and the system 20.
[0052] The three-way valve 46 of the heater-subsystem 40 is also in
fluid communication between the tank 44 of the heater-subsystem 40
and the tool 26. As such, the three-way valve 46 of the
heater-subsystem 40 is also useful for directing the fluid from the
tank 44 of the heater-subsystem 40 to the tool 26. This is
especially useful for rapidly heating the mold surface 24 of the
tool 26 as further described below. For example, the mass of heated
fluid (or a portion thereof) can be fed to the tool 26 to rapidly
heat the mold surface 24. The mass of heated fluid provided by the
tank 44 of the heater-subsystem 40 provides for a rapid change in
temperature relative to what the heater 42 could achieve on its own
by providing only heated fluid on demand. For example, the heater
42 may be burdened during ramping up of the mold surface 24
temperature and will take time to recover. The mass of heated fluid
provides for a drastic change in temperature in a very short period
of time, i.e., a maximum .DELTA.T in the mold surface 24, without
putting the entire heating burden on the heater 42.
[0053] Referring to FIG. 18, another embodiment of the system 20 is
shown. The three-way valve 46 of the heater-subsystem 40 is in
fluid communication i) between the tank 44 and the heater 42 for
re-circulating a first thermal fluid from the tank 44 to the heater
42 and ii) between the tank 44 and the tool 26 for directing the
first thermal fluid from the tank 44 to the tool 26. Optionally,
the heater-subsystem 40 may include a tank bypass line 39 in this
or other embodiments.
[0054] Referring to FIG. 2, a related embodiment of the system 20
further comprises a chiller-subsystem 48. As such, in certain
embodiments, the system 20 comprises the heater- and
chiller-subsystems 40,48. In this embodiment, the chiller-subsystem
48 is in fluid communication with the tool 26. The
chiller-subsystem 48 is useful for cooling the mold surface 24 of
the tool 26. In embodiments where the heater-subsystem 40 may be
used for cooling the mold surface 24 of the tool 26, the
chiller-subsystem 48 can also be used for further cooling the mold
surface 24. In other certain embodiments, the heater-subsystem 40
is used only for heating the mold surface 24, and the
chiller-subsystem 48 is used only for cooling the mold surface 24.
Other embodiments of the system 20 are described below, where the
chiller-subsystem 48 is used in another location of the system 20.
In certain embodiments, the subsystems 40,48 are separate from each
other; however, in other embodiments, the subsystems 40,48 are in
fluid communication with each other, i.e., they share the fluid of
the system 20.
[0055] The chiller-subsystem 48 comprises a chiller 50. The chiller
50 is useful for cooling the fluid within the system 20. Various
types of chillers 50 can be employed. The chiller 50 should be
capable of cooling the fluid to temperatures of at least about
50.degree. F. (.about.10.degree. C.) to about 80.degree. F.
(.about.27.degree. C.), and downwards of about -10.degree. F.
(.about.-23.degree. C.) to about 20.degree. F. (.about.-7.degree.
C.). The chiller 50 should also be capable of delivering various
outputs of fluid, such as from about 10 to about 150, from about 20
to about 125, from about 30 to about 100, from about 40 to about
75, ton chilling (where 1 ton chilling is about 12,000 BTUs per
hour). Suitable chillers 50 are commercially available from a
variety of suppliers. Specific examples of chillers 50 include
those commercially available from Mokon, including the Iceman
Series, e.g. the Iceman SC Series, the Iceman LT Series, the Iceman
Dual Circuit, and the Iceman Full Range.
[0056] The chiller-subsystem 48 further comprises a tank 52. The
tank 52 of the chiller-subsystem 48 is useful for containing a mass
of cooled fluid. The tank 52 of the chiller-subsystem 48 is in
fluid communication with the chiller 50. Various types of tanks can
be employed as the tank 52 of the chiller-subsystem 48. The tank 52
of the chiller-subsystem 48 should be able to hold fluid at
temperatures of about -30.degree. F. (.about.-34.degree. C.) to
about -10.degree. F. (.about.-23.degree. C.), or upwards of about
20.degree. F. (.about.-7.degree. C.) to about 50.degree. F.
(.about.10.degree. C.). Typically, the tank 52 of the
chiller-subsystem 48 should be rated for less than the lowest
temperature output of the chiller 50. In certain embodiments, the
chiller-subsystem 48 comprises two of more tanks (not shown). For
example, the mass of fluid contained in one tank 52 may be at a
different temperature than that of another tank 52. This may be
useful for buffering the system 20 with masses of cooled fluid at
different temperatures.
[0057] Generally, the tank 52 of the chiller-subsystem 48 should be
insulated, either itself, and/or with a supplemental layer of
insulation, to prevent heating of the mass of cooled fluid
contained therein by the ambient environment. Various types of
insulation means can be employed as like described above with the
tank 44 of the heater-subsystem 40.
[0058] The tank 52 of the chiller-subsystem 48 can be of various
sizes and shapes. It may be useful to reduce the SA:V of the tank
52 of the chiller-subsystem 48 to reduce heat gain; however, this
is not required. The tank 52 of the chiller-subsystem 48 should be
of a size to hold of from about 50 to about 200, from about 75 to
about 150, or from about 100 to about 125, gallons of the fluid (or
about 189 to about 946, from about 378 to about 852, from about 378
to about 757, or from about 378 to about 568, liters of the fluid).
Generally, a larger size tank 52 provides for a greater cooling
buffer in the system 20. Reference to the mass of cooled fluid
associated with the tank 52 of the chiller-subsystem 48 may refer
to a portion to an entirety of the cooled fluid contained in the
tank 52 at a given instance. The tank 52 is typically separate from
the chiller 50, i.e., the tank 52 is distinguishable from an
"internal" tank of the chiller 50, if present.
[0059] The chiller-subsystem 48 further comprises a valve 54 in
fluid communication between the tank 52 of the chiller-subsystem 48
and the chiller 50. Various types of valves 54 can be employed.
Typically, the valve 54 is a three-way valve 54. The three-way
valve 54 of the chiller-subsystem 48 is useful for re-circulating
the fluid between the tank 52 of the chiller-subsystem 48 and the
chiller 50. This arrangement is useful for initially forming,
maintaining, and/or recharging the mass of cooled fluid in the tank
52 of the chiller-subsystem 48. For example, once a portion (or
all) of the mass of cooled fluid is fed to the tool 26, fluid
returning from the tool 26 can be fed to the chiller 50 and then to
the tank 52 of the chiller-subsystem 48 to maintain or recharge the
mass of cooled fluid. The cooled fluid may then be held or
re-circulated in one or more passes between the chiller 50 and the
tank 52 of the chiller-subsystem 48 to further decrease or maintain
temperature of the mass of cooled fluid. This is also useful if the
chiller 50 can't keep up with demands of the tool 26 and/or the
system 20, where the mass of cooled fluid serves as a buffer for
the chiller 50 to catch-up or recover. This is also useful for
maintaining a near steady-state temperature of the fluid within the
chiller-subsystem 48 to meet ongoing demands of the tool 26 and the
system 20.
[0060] The three-way valve 54 of the chiller-subsystem 48 is also
in fluid communication between the tank 52 of the chiller-subsystem
48 and the tool 26. As such, the three-way valve 54 of the
chiller-subsystem 48 is also useful for directing the fluid from
the tank 52 of the chiller-subsystem 48 to the tool 26. This is
especially useful for rapidly cooling the mold surface 24 of the
tool 26 as further described below. For example, the mass of cooled
fluid (or a portion thereof) can be fed to the tool 26 to rapidly
cool the mold surface 24. The mass of cooled fluid provided by the
tank 52 of the chiller-subsystem 48 provides for a rapid change in
temperature relative to what the chiller 50 could achieve on its
own by providing only cooled fluid on demand. For example, the
chiller 50 may be burdened during ramping down of the mold surface
24 temperature and will take time to recover. The mass of cooled
fluid provides for a drastic change in temperature in a very short
period of time, i.e., a maximum .DELTA.T in the mold surface 24,
without putting the entire cooling burden on the chiller 50.
[0061] Referring to FIG. 18, the three-way valve 54 of the
chiller-subsystem 48 is in fluid communication i) between the tank
52 and the chiller 50 for re-circulating a second thermal fluid
from the tank 52 to the chiller 50 and ii) between the tank 52 and
an exchanger-subsystem 49 for directing the second thermal fluid
from the tank to an exchanger 51. Optionally, the chiller-subsystem
48 may include the tank bypass line 39 in this or other
embodiments. Typically, the second thermal fluid is water.
[0062] Referring to FIG. 18, the system 20 further comprises the
exchanger-subsystem 49. The exchanger-subsystem 49 comprises the
(heat) exchanger 51. The exchanger 51 can be of various types, such
as a shell-and-tube, a shell-and-plate, etc. The
exchanger-subsystem 49 further comprises a valve 53. Typically, the
valve 53 is a three-way valve 53. In this embodiment, the system 20
typically includes at least one pump 55. Various types of pumps can
be utilized. The pump 55 is useful for circulating the fluid within
the system 20 when the heater-subsystem 40 and chiller-subsystem 48
are closed off from the tool 26, such as when recharging.
Otherwise, the heater 42 can generally provide suitable pumping for
the system 20.
[0063] The exchanger 51 and three-way valve 53 of the
exchanger-subsystem are useful for indirectly introducing cooled
fluid to the tool 26. In this embodiment, cooled fluid does not go
directly to the tool 26, but to the exchanger 51 wherein the cooled
fluid is used to reduce the temperature of the heated fluid that is
in direct contact with the tool 26. In using the exchanger 51 to
introduce cooled fluid to the tool 26, this can provide for a
smaller closed loop to be established thereby allowing the closed
loop to be "set" to a fixed temperature via temperature feedback of
the fluid in the loop and control of the valves 46,53,54. For
example, the valves 46,53,54 can be set such that the fluid flows
through a check valve 57 via the pump 55 and around the smaller
closed loop. Additional aspects of this embodiment are described
further below.
[0064] As shown in FIG. 18, the three-way valve 53 is in fluid
communication i) between the exchanger 51 and the heater-subsystem
40 for sending the first thermal fluid from the tool 26 back to the
heater-subsystem 40 and ii) between the exchanger 51 and the tool
26 for directing the first thermal fluid from the tool 26 to the
exchanger 51.
[0065] In general, the first thermal fluid is shared between the
heater-subsystem 40 and the exchanger-subsystem 49, the second
thermal fluid is shared between the chiller-subsystem 48 and the
exchanger-subsystem 49, and the first thermal fluid is kept
separate from the second thermal fluid. Typically, the first
thermal fluid is thermal oil and the second thermal fluid is water,
i.e., they are different from one another.
[0066] The system 20 is typically in communication with a
controller 56. The controller 56 is typically in communication with
at least one of the subsystems 40,48,49 and the tool 26, more
typically in communication with all of the subsystems 40,48,49 and
the tool 26. Various types of controllers 56 can be employed.
Typically, the controller 56 is a programmable logic controller
(PLC) 56, which may also be referred to as a programmable
controller 56. The controller 56 can communicate to components of
the system 20 by various methods, such as by wire, by wireless,
etc.
[0067] In certain embodiments, the system 20 further comprises a
valve 58, which is in addition to the valves 46,53,54 of the
subsystems 40,48,49. Various types of valves 58 can be employed.
Typically, the valve 58 is a three-way valve 58. Referring to FIG.
2, the three-way valve 58 of the system 20 is in fluid
communication between the tool 26 and both of the subsystems 40,48.
The three-way valve 58 is also in communication with the controller
56. In this embodiment, the three-way valve 58 of the system 20 is
useful for directing the fluid to the heater-subsystem 40 or to the
chiller-subsystem 48 after returning from the tool 26. Said another
way, the controller 56 can direct fluid from the tool 26 to each of
the subsystems 40,48 by controlling the three-way valve 58 of the
system 20, along with the three-way valves 46,54 of each of the
subsystems 40,48. Referring to FIG. 18, the three-way valve 58 may
optionally be utilized, i.e., as a supplemental valve 58, such as
in place of the check valve 57.
[0068] It is to be appreciated that while "three-way" valves
46,53,54,58 may generally be referred to herein, the same flow
control may be achieved by a combination of different types of
valves and piping 38 arrangements which "mimic" a three-way valve.
For example, a combination of two-way valves and piping 38 may be
utilized to achieve the same flow control as achieved by a
three-way valve. As another example, a plugged four-way valve may
be utilized in place of a three-way valve. Such alternate
arrangements for achieving the same (or similar) flow control are
contemplated as being equivalent in function as the three-way
valves 46,53,54,58 described herein.
[0069] The controller 56 is also useful for controlling flow of
fluid in the system 20. For example, the controller 56 can control
a combination of the valves 58 of the system 20, the valves
46,53,54 of the subsystems 40,48,49 the heater 42, the chiller 50,
and/or the heat exchanger 49, to direct fluid at various
temperatures to and from the tool 26.
[0070] The controller 56 is especially useful for directing the
masses of the heated and cooled fluid from each of the subsystems
40,48. Specifically, the controller 56 is useful for directing the
mass of heated fluid from the tank 44 of the heater-subsystem 40 to
rapidly heat the mold surface 24 of the tool 26. The controller 56
is also useful for directing the mass of cooled fluid from the tank
52 of the chiller-subsystem 48 to rapidly cool the mold surface 24
of the tool 26 either directly to the tool 26, such as in FIG. 2,
or indirectly via the exchanger-subsystem 51, such as in FIG.
18.
[0071] In certain embodiments, the controller 56 controls the
three-way valves 46,53,54,58 to direct fluid from at least one of
the tanks 44,52 to the tool 26 to heat or cool the mold surface 24
of the tool 26. In further embodiments, the controller 56 controls
the three-way valves 46,53,54,58 to re-circulate fluid in the other
subsystem 40,48 to maintain the mass of heated or cooled fluid in
the tank 44,52 of the other subsystem 40,48. Re-circulating the
fluid in the subsystem 40,48 can start before, after, or during
heating or cooling of the mold surface 24 with the other subsystem
40,48. As introduced above, the controller 56 can also be used to
control fluid in the exchanger-subsystem 49. The controller 56 can
direct the fluid in the system 20 by opening and closing the
three-way valves 46,53,54,58 in particular orders and/or at
particular times. The three-way valves 46,53,54,58 may be opened
and/or closed simultaneously and/or concurrently. While not shown,
the controller 56 may also be in communication with other valves in
the system 20 to control flow of the fluid.
[0072] A specific embodiment will now be described in the following
few paragraphs. Referring to FIG. 18, the controller 56 can be
programmed to manipulate the subsystems 40,48,49 in various
manners. In this embodiment, the controller 56 is generally
programmed to instruct the three-way valve 46 of the
heater-subsystem 40 at certain times such that the first thermal
fluid re-circulates between the heater 42 and the tank 44 and
bypasses the tool 26 to maintain the mass of heated first thermal
fluid in the heater-subsystem 40. At other times, the controller 56
is generally programmed to instruct the three-way valve 46 of the
heater-subsystem 40 such that the first thermal fluid is directed
from the heater-subsystem 40 and to the tool 26 to heat the mold
surface 24 of the tool 26.
[0073] In addition, the controller 56 is generally programmed to
instruct the three-way valve 54 of the chiller-subsystem 48 at
certain times such that the second thermal fluid re-circulates
between the chiller 50 and the tank 52 and bypasses the
exchanger-subsystem 49 to maintain the mass of cooled second
thermal fluid in the chiller-subsystem 48. At other times, the
controller 56 is generally programmed to instruct the three-way
valve 54 of the chiller-subsystem 48 such that the second thermal
fluid is directed from the chiller-subsystem 48 to the
exchanger-subsystem 49 to cool the first thermal fluid returning
from the tool 26 and entering the exchanger-subsystem 51.
[0074] In addition, the controller 56 is generally programmed to
instruct the three-way valve 53 of the exchanger-subsystem 49 at
certain times such that the first thermal fluid returning from the
tool 26 is directed to the heater-subsystem 40 and bypasses the
exchanger-subsystem 51 to reheat the first thermal fluid within the
heater-subsystem 40. At other times, the controller 56 is generally
programmed to instruct the three-way valve 53 of the
exchanger-subsystem 49 such that the first thermal fluid returning
from the tool 26 is directed to the exchanger-subsystem to cool the
first thermal fluid via the second thermal fluid from the
chiller-subsystem 48.
[0075] In certain embodiments, the fluid may be directed into the
tool 26 in a countercurrent fashion relative to a coolest or
warmest area of the mold surface 24. For example, if one area of
the mold surface 24 is initially the coolest relative to the
remainder of the mold surface 24, and the tool 26 is being heated,
the controller 56 can direct heated fluid to this location to
expedite temperature change of the location based on a large
initial temperature gradient. It is to be appreciated that there
are also instances where concurrent flow arrangements can be
useful, such as for maintaining a temperature gradient across the
mold surface 24, or there may be instances where a combination of
countercurrent and concurrent flow arrangements can be used.
Typically, flow within the tubing 28 of the tool 26 is turbulent to
promote greater thermal transfer between the mold surface 24 and
the fluid within the tubing 28. Turbulence may be imparted by
various means, such as by use of helically corrugated piping 38
and/or tubing 28.
[0076] While not shown, the system 20 may include one or more
additional types of valves for regulating flow of the fluid within
the system 20. For example, one or more ball valves may be present
for stopping/starting flow of the fluid in a portion of the system
20. As another example, one or more gate valves and/or check valves
may be present for preventing backflow of the fluid in a portion of
the system 20. As another example, one or more globe valves may be
present for regulating flow rate of the fluid in a portion of the
system 20. If employed, the additional valves may be disposed in
various locations of the system 20. The valves of the system 20,
including the three-way valves 46,53,54,58, may be manipulated in
various ways, such as pneumatically, manually, electrically,
magnetically, etc. In certain embodiments, electrical control is
employed, pneumatic control is employed, or combinations
thereof.
[0077] The system 20 can further comprise a relief valve 60. The
relief valve 60 may also be referred to as a pressure relief valve
60, a pressure safety valve 60, or a safety valve 60. Various types
of relief valves 60 (and their related systems) can be employed.
The relief valve 60 is typically in fluid communication between the
subsystems 40,48,49 and the tool 26. The relief valve 60 is useful
for relieving pressure of the fluid in the system 20. For example,
an upset in the system 20 may increase pressure of the fluid to an
unsafe or undesirable level. As such, the relief valve 60 can
compensate for such an occurrence by releasing a portion of the
fluid in the system 20 to return the pressure of the fluid to a
safe or desired level. The controller 56 may be in communication
with the relief valve 60 to shut down the system 20 in the event
that the relief valve 60 activates to prevent damage to the system
20, press 64, etc.
[0078] The system 20 may further comprise a strainer (not shown).
Various types of strainers can be employed. The strainer useful for
straining the fluid to prevent clogging or other issues in the
system 20 over time. The strainer can also be useful for imparting
and/or maintaining turbulent flow of the fluid.
[0079] As introduced above, the system 20 may further comprise one
or more pumps 55. Various types of pumps can be employed, such as
those generally used for moving heat transfer fluids. In certain
embodiments, such as those lacking the exchanger-subsystem 51, the
heater 42 and chiller 50 generally provide sufficient pumping of
the fluid.
[0080] Utilizing the system 20, the mold surface 24 of the tool 26
can be heated at various rates. The rate of heating may be linear
or curvilinear. For example, the rate of heating can increase at a
decreasing rate, increase at an increasing rate, be substantially
constant, or combinations thereof. Typically, the mold surface 24
heats at a rate of greater than about 60, greater than about 70,
greater than about 80, greater than about 90, or greater than about
100, .degree. F. per minute (or greater than .about.33, greater
than .about.39, greater than .about.44, greater than .about.50, or
greater than .about.56, .degree. C. per minute). In certain
embodiments, the mold surface 24 can be heated at a rate upwards of
about 300, about 250, about 225, or about 200, .degree. F. per
minute (.about.167, .about.39, .about.125, or .about.111, .degree.
C. per minute).
[0081] Utilizing the system 20, the mold surface 24 of the tool 26
can be cooled at various rates. The rate of cooling may be linear
or curvilinear. For example, the rate of cooling can increase at a
decreasing rate, increase at an increasing rate, be substantially
constant, or combinations thereof. Typically, the mold surface 24
cools at a rate of greater than about 40, greater than about 50,
greater than about 60, greater than about 70, greater than about
80, greater than about 90, or greater than about 100, .degree. F.
per minute (or greater than .about.22, greater than .about.28,
greater than .about.33, greater than .about.39, greater than
.about.44, greater than .about.50, or greater than .about.56,
.degree. C. per minute). In certain embodiments, the mold surface
24 can be cooled at a rate upwards of about 200, about 175, or
about 150, .degree. F. per minute (.about.111, .about.97, or
.about.83, .degree. C. per minute).
[0082] The present invention further provides a method. The method
is useful for heating and cooling the mold surface 24 of the tool
26. The method comprises the step of providing the heater-subsystem
40. In certain embodiments, the method further comprises the step
of providing the chiller-subsystem 48. In various embodiments, the
method further comprises the step of providing the
exchanger-subsystem 49. In various embodiments, the method further
comprises the step of providing the controller 56. Typically, the
method further comprises the step of providing the tool 26. The
tool 26 can be provided manually or automatically. For example, the
tool 26 may be provided by a technician or by a robot (not shown).
The tool 26 and subsystems 40,48,49 can be as described above.
[0083] The method further comprises the step of directing the mass
of heated fluid from the tank 44 of the heater-subsystem 40 to the
tool 26. The mass of heated fluid can be directed by the controller
56 communicating with the subsystems 40,48,49 and the three-way
valve 58 of the system 20 as described above.
[0084] The mass of heated fluid heats the mold surface 24 of the
tool 26 from a first temperature (T.sub.1) to a second temperature
(T.sub.2) within a first period of time (Tt.sub.1). T.sub.1 can be
various temperatures. For example, T.sub.1 can be the temperature
of the mold surface 24 at startup, i.e., the mold surface 24 can be
at ambient (or room) temperature. Alternatively, T.sub.1 can be the
temperature of the mold surface 24 after a previous cycle of
heating and cooling. As such, the mold surface 24 may be hotter (or
cooler) than ambient temperature. Typically, T.sub.1 is from about
50 to about 125, from about 75 to about 125, from about 90 to about
125, or from about 100 to about 120, .degree. F. (.about.10 to
.about.52, .about.24 to .about.52, .about.32 to .about.52, or
.about.38 to .about.49, .degree. C.).
[0085] Tt.sub.1 can be various time periods. Typically, Tt.sub.1 is
short relative to subsequent time periods of heating and cooling.
However, Tt.sub.1 may also be longer than or equal to one or more
subsequent time periods of heating and cooling. Typically, Tt.sub.1
is from about 1 to about 25, from about 1 to about 20, from about 1
to about 15, from about 1 to about 10, from about 2.5 to about 10,
from about 2.5 to about 7.5, or from about 4 to about 6,
minutes.
[0086] T.sub.2 can be various temperatures. For example, T.sub.2
can be the maximum temperature of the mold surface 24 reached
during heating. Typically, T.sub.2 is from about 250 to about 400,
from about 250 to about 375, from about 275 to about 375, from
about 300 to about 375, or from about 325 to about 350, .degree. F.
(.about.121 to .about.204, .about.121 to .about.191, .about.135 to
.about.191, .about.149 to .about.191, or .about.163 to .about.177,
.degree. C.).
[0087] In general, the mass of heated fluid in the tank 44 of
heater-subsystem 40 is at a temperature of about T.sub.2 or higher.
It is useful when the mass of the heated fluid is at least about
50.degree. F. (10.degree. C.) higher than T.sub.2 to facilitate
heat transfer between the mass and the mold surface 24 of the tool
26, and more typically much higher than T.sub.2. In certain
embodiments, the mass of heated fluid in the tank 44 of the
heater-subsystem 40 is at a temperature of from about 250 to about
600, from about 300 to about 550, from about 350 to about 500, or
from about 400 to about 450, .degree. F. (.about.121 to .about.316,
.about.149 to .about.288, .about.177 to .about.260, or .about.204
to .about.232, .degree. C.). Due to the mass of heated fluid, the
system 20 can rapidly heat the mold surface 24 of the tool 26 as
described above.
[0088] The method further comprises the step of directing fluid
from the heater-subsystem 40 to the mold surface 24 of the tool 26.
The fluid can be directed by the controller 56 communicating with
the subsystems 40,48 and the three-way valve 58 of the system 20.
The fluid maintains the mold surface 24 at about T.sub.2 for a
second period of time (Tt.sub.2). The mold surface 24 can be
maintained at T.sub.2 or at an acceptable tolerance level, e.g.
Tt.sub.2.+-.15.degree. F. (.+-.-9.degree. C.). Maintaining the mold
surface 24 at about T.sub.2 for Tt.sub.2 is useful for curing resin
of the composite article 22. It is also believed to be useful for
increasing surface properties of the composite article 22.
Thermostat modulation can be used for staying within the tolerance
level.
[0089] Tt.sub.2 can be various time periods. Typically, Tt.sub.2 is
shorter than Tt.sub.1. However, Tt.sub.2 may also be longer than or
equal to Tt.sub.1 or a subsequent time period. Typically, Tt.sub.2
is from about 1 to about 25, from about 1 to about 20, from about 1
to about 15, from about 1 to about 10, from about 1 to about 7.5,
from about 1 to about 5, or from about 1 to about 2.5, minutes.
[0090] In certain embodiments, the method further comprises the
step of maintaining the mold surface 24 of the tool 26 at an
intermediate temperature (T.sub.1-2) of between T.sub.1 and
T.sub.2. Typically, this step occurs prior to heating the mold
surface 24 of the tool 26 to T.sub.2. T.sub.1-2 can be maintained
by only feeding a portion of the mass of heated fluid to the mold
surface 24 and/or by controlling overall temperature of the
heater-subsystem 40.
[0091] The fluid maintains the mold surface 24 at about T.sub.1-2
for a portion of Tt.sub.1 (Tt.sub.<1). The fluid can be directed
by the controller 56 communicating with the subsystems 40,48 and
the three-way valve 58 of the system 20. The mold surface 24 can be
maintained at T.sub.1-2 or at an acceptable tolerance level, e.g.
T.sub.1-2.+-.15.degree. F. (.+-.-9.degree. C.). It is believed that
maintaining the mold surface 24 at about T.sub.1-2 for Tt.sub.2 is
useful for consolidating the composite article 22. For example,
resin of the composite article 22 reaches its minimum viscosity
and/or thins to more readily flow into the carbon fiber mat of the
composite article 22. Such consolidation is believed to be useful
for achieving mechanical properties and improving the Class A
surface of body panels of the composite article 22, if formed.
Thermostat modulation can be used for staying within the tolerance
level.
[0092] T.sub.1-2 can be various temperatures. For example,
T.sub.1-2 can be in the middle of T.sub.1 and T.sub.2, closer to
T.sub.1, or closer to T.sub.2. Typically, T.sub.1-2 is from about
100 to about 350, from about 150 to about 325, from about 200 to
about 300, from about 225 to about 275, or from about 235 to about
265, .degree. F. (.about.38 to .about.177, .about.66 to .about.163,
.about.93 to .about.149, .about.107 to .about.135, or .about.113 to
.about.129, .degree. C.).
[0093] Tt.sub.<1 can be various time periods, provided it is
less than Tt.sub.1. Typically, Tt.sub.1-2 is longer than Tt.sub.2.
However, Tt.sub.1-2 may also be shorter than or equal to Tt.sub.2
or a subsequent time period. Typically, Tt.sub.<1 is from about
1 to less than about 25, from about 1 to about 20, from about 1 to
about 15, from about 1 to about 10, from about 1 to about 7.5, from
about 1 to about 5, or from about 1 to about 2.5, minutes. In
certain embodiments, Tt.sub.<1 is from 1 to less than 10
minutes.
[0094] In certain embodiments, such as the one of FIG. 2, the
method further comprises the step of directing the mass of cooled
fluid from the tank 52 of the chiller-subsystem 48 to the tool 26
to cool the mold surface 24 of the tool 26 from about T.sub.2 to a
third temperature (T.sub.3) within a third period of time
(Tt.sub.3). In other embodiments, the heater-subsystem 40 is used
to cool the mold surface 24 in a similar manner. Typically, either
one of these steps occurs after maintaining the mold surface 24 of
the tool 26 at T.sub.2 for Tt.sub.2. The mass of cooled fluid can
be directed by the controller 56 communicating with the subsystems
40,48 and the three-way valve 58 of the system 20. In other
embodiments, such as the one of FIG. 18, the method further
comprises the step of directing the mass of cooled second thermal
fluid from the tank 52 of the chiller-subsystem 48 to the
exchanger-subsystem 49 via the controller 56 to cool the mold
surface 24 of the tool 26 from T.sub.2 to T.sub.3 within
Tt.sub.3.
[0095] T.sub.3 can be various temperatures. For example, T.sub.3
can be the temperature of the mold surface 24 at startup, i.e., the
mold surface 24 can be at ambient (or room) temperature. T.sub.3 is
generally higher than ambient temperature. Typically, T.sub.3 is
from about 75 to about 150, from about 85 to about 140, from about
90 to about 130, or from about 100 to about 120, .degree. F.
(.about.24 to .about.66, .about.29 to .about.60, .about.32 to
.about.54, or .about.38 to .about.49, .degree. C.).
[0096] Tt.sub.3 can be various time periods. Typically, Tt.sub.3 is
long relative to previous time periods of heating. However,
Tt.sub.3 may also be longer than or equal to one or more previous
time periods of heating. Typically, Tt.sub.3 is from about 1 to
about 25, from about 1 to about 20, from about 1 to about 15, from
about 1 to about 10, from about 2.5 to about 10, from about 2.5 to
about 7.5, or from about 4 to about 6, minutes.
[0097] In general, the mass of cooled fluid in the tank 52 of
chiller-subsystem 48 is at a temperature of about T.sub.3 or lower.
It is useful when the mass of the cooled fluid is at least about
50.degree. F. lower than T.sub.3 to facilitate heat transfer
between the mold surface 24 of the tool 26 and the mass. In certain
embodiments, the mass of the cooled fluid in the tank 52 of the
chiller-subsystem 48 is at a temperature of from about 35 to about
70, about 40 to about 60, about 45 to about 55, or about 50,
.degree. F. (.about.1.7 to .about.21, .about.4.4 to .about.16,
.about.7 to .about.13, or .about.10, .degree. C.). As such, the
system 20 can rapidly cool the mold surface 24 of the tool 26 with
the mass of cooled fluid.
[0098] As described above, the method is useful for heating the
mold surface 24 of the tool 26. Typically, the mold surface 24 of
the tool 26 heats at a rate of greater than about 60, about 70,
about 80, about 90, about 100, about 110, about 120, about 130,
about 140, about 150, about 160, about 170, or about 180, .degree.
F. per minute (greater than .about.33, greater than .about.39,
greater than .about.44, greater than .about.50, greater than
.about.56, greater than .about.61, greater than .about.67, greater
than .about.72, greater than .about.78, greater than .about.83,
greater than .about.89, greater than .about.94, or greater than
.about.100, .degree. C. per minute).
[0099] As also described above, the method is useful for cooling
the mold surface 24 of the tool 26. Typically, the mold surface 24
of the tool 26 cools at a rate of greater than about 40, about 50,
about 60, about 70, about 80, about 90, about 100, about 110, about
120, about 130, about 140, about 150, about 160, about 170, or
about 180, .degree. F. per minute (greater than .about.33, greater
than .about.39, greater than .about.44, greater than .about.50,
greater than .about.56, greater than .about.61, greater than
.about.67, greater than .about.72, greater than .about.78, greater
than .about.83, greater than .about.89, greater than .about.94, or
greater than .about.100, .degree. C. per minute).
[0100] As introduced above, the controller 56 can be programmed
with various control schemes to heat and cool the mold surface 24
using the subsystems 40,48,49 and three-way valve 58 of the system
20, if utilized. For example, the controller 56 can be programmed
to open or close one or more of the three-way valves 46,53,54,58 at
certain times and/or at certain temperatures of the mold surface
24. Such control methodology is useful for directing the fluid to
the tool 26 and/for re-circulating the fluid as described above. As
a starting point, control schemes of the controller 56 may be
modeled off of control schemes generally used with autoclaves.
[0101] In certain embodiments, the controller 56 is programmed such
that Tt.sub.1.ltoreq.Tt.sub.2 or Tt.sub.1.gtoreq.Tt.sub.2. In
further embodiments, the controller 56 is programmed such that
Tt.sub.1.gtoreq.Tt.sub.3 or Tt.sub.1.ltoreq.Tt.sub.3. Typically,
Tt.sub.1+Tt.sub.2+Tt.sub.3 is no greater than about 30, about 25,
about 20, about 19, about 18, about 17.5, about 17, about 15, about
14, about 13.5, about 13, about 12.5, about 12, about 11, about 10,
about 7.5, about 5, about 2.5, or about 2, minutes. In certain
embodiments, Tt.sub.1+Tt.sub.2+Tt.sub.3 is no greater than about 20
minutes, no greater than about 19 minutes, no greater than about 18
minutes, or no greater than about 17 minutes, and can be downwards
of about 15, about 10, or about 5, minutes. Due to the direct
heating and cooling of the mold surface 24 of the tool 26 via the
system 20, cycle time of making the composite articles 22 is
greatly reduced relative to conventional methods, such as
autoclaving.
[0102] The controller 56 typically measures temperature of the mold
surface 24 by feedback from one or more resistive thermal device
(RTD) (not shown) disposed proximal the mold surface 24. The
controller 56 can also measure temperature of the fluid by one or
more RTDs disposed in or proximal the piping 38 at one or more
locations and/or by one or more RTDs disposed in or proximal the
subsystems 40,48,49. Various types of RTDs can be employed.
[0103] The present invention further provides a method of forming
the composite article 22. The method comprises the step of
providing the tool 26. The tool 26 can be as described above. The
method further comprises the step of providing a preform 62. The
preform 62 can be provided manually or automatically.
[0104] The preform 62 comprises a carbon fiber mat and a resin.
Various types of carbon fiber mat can be employed, such as a
continuous fiber mat. The carbon fiber mat may also be referred to
as a fabric or a braid. The carbon fiber mat can include one or
more layers of fibers, typically at least two layers of fibers. The
carbon fibers can be of various types, such as standard modulus,
intermediate modulus, high modulus, or high strength, carbon
fibers. In certain embodiments, the carbon fibers are
unidirectional.
[0105] The carbon fiber mat can be substantially dry and/or a
pre-preg. In certain embodiments, the carbon fiber mat is a carbon
fiber pre-preg, which may also be referred to as a prepreg.
Suitable carbon fiber mats are commercially available from a
variety of suppliers. Specific examples of carbon fiber mats
include those commercially available from Toray Carbon Fibers
America, Inc. of Flower Mound, Tex., including the TORAYCA.RTM.
Series, e.g. TORAYCA.RTM. T700S; and from Toray Composites
(America), Inc., of Tacoma, Wash. Further specific examples of
carbon fiber mats include those commercially available from
Advanced Composites Group of Tulsa, Okla.; and from Grafil, Inc. of
Sacramento, Calif., including the GRAFIL Series and the PYROFIL.TM.
Series, e.g. PYROFIL.TM. TR30S.
[0106] Various types of resins can be employed, including both
thermoplastic and/or thermosetting resins. Typically, the resin is
a thermosetting resin. Examples of suitable thermosetting resins
include epoxy resins. In certain embodiments, the resin comprises
an epoxy resin. The resin can include (or be mixed) with one or
more hardeners to promote cure of the resin. Various types of
hardeners can be employed. The resin should be capable of curing in
the time periods described above to utilize the rapid heating and
cooling provided by the system 20. Suitable resins are commercially
available from a variety of suppliers. Specific examples of resins
include those commercially available from Huntsman International
LLC of Salt Lake City, Utah; from Toray Carbon Fibers America,
Inc.; from Toray Composites (America), Inc., including G83 pre-preg
resin; and from Advanced Composites Group, including MTM57 pre-preg
resin.
[0107] As introduced above, the composite article 22 may be formed
from a pre-preg, which is a carbon fiber mat previously infused
with a resin, being either wet or dry, typically slightly wet. It
is to be appreciated that if the pre-preg is employed, additional
resin being the same or different from that of the pre-preg may be
employed to form the composite article 22. Alternatively, just the
resin provided with the pre-preg can be employed as the resin.
Various types of pre-pregs can be employed. Specific examples of
pre-pregs or pre-preg systems include those commercially available
from Toray Composites (America), Inc., such as PC7831-190-1000; and
from Advanced Composites Group, such as MTM57/CF3238.
[0108] The method further comprises the step of disposing the
preform 62 on the mold surface 24 of the tool 26. The preform 62
may be disposed manually or automatically. The method further
comprises the step of heating the mold surface 24 of the tool 26
from T.sub.1 to T.sub.2 within Tt.sub.1. T.sub.1, T.sub.2, and
Tt.sub.1 can be as described above. Heating the mold surface 24 is
useful for thinning the resin of the preform 62. As such, the resin
is better able to flow around, into, and within the carbon fiber
mat. The mold surface 24, and therefore, the preform 62, can be
heated with the system 20 as described above.
[0109] The method further comprises the step of applying pressure
to the preform 62. Pressure may be applied by various means.
Typically, pressure is applied by a press 64, as described further
below. The pressure is applied from a first pressure (P.sub.1) to a
second pressure (P.sub.2).
[0110] Pressure can be applied at various rates. The rate of
pressurizing may be linear or curvilinear. For example, the rate of
pressurizing can increase at a decreasing rate, increase at an
increasing rate, be substantially constant, or combinations
thereof. Typically, pressure is applied at a rate of greater than
about 0.1, greater than about 0.2, greater than about 0.3, greater
than about 0.4, greater than about 0.5, greater than about 0.6,
greater than about 0.7, greater than about 0.8, greater than about
0.9, greater than about 1, greater than about 1.1, greater than
about 1.2, greater than about 1.3, greater than about 1.4, greater
than about 1.5, or greater than about 2, pounds per square inch
(psi) per second (sec) (where 1 psi/sec is .about.2.07
kPa/sec).
[0111] P.sub.1 can be various pressures. For example, P.sub.1 can
be standard atmospheric pressure (.about.14.7 psi). Typically,
P.sub.1 is from about 0 to about 5, from about 0 to about 1, from
about 0 to about 0.5, from about 0 to about 0.25, or from about 0
to about 0.1, psi gauge (psig) (where 1 psig is .about.2.07 kPa
gauge).
[0112] P.sub.2 can be various pressures. For example, P.sub.2 can
be the maximum pressure reached during pressurizing. Typically,
P.sub.2 is from about 50 to about 150, from about 60 to about 140,
from about 70 to about 130, from about 80 to about 120, from about
90 to about 110, or about 100, psig.
[0113] The pressure is applied within a first period of time
(Pt.sub.1). Applying the pressure is useful for consolidating the
preform 62, especially after the resin has thinned via application
of heat. Pt.sub.1 can be various time periods. Typically, Pt.sub.1
is short relative to subsequent time periods of pressurizing or
depressurizing. However, Pt.sub.1 may also be longer than or equal
to one or more subsequent time periods of pressurizing or
depressurizing. Typically, Pt.sub.1 is from about 1 to about 25,
from about 1 to about 20, from about 1 to about 15, from about 1 to
about 10, from about 2.5 to about 10, from about 2.5 to about 7.5,
or from about 4 to about 6, minutes.
[0114] The method further comprises the step of maintaining
pressure at about P.sub.2 for a second period of time (Pt.sub.2).
The pressure can be maintained at P.sub.2 or at an acceptable
tolerance level, e.g. P.sub.2.+-.10 psi (wherein 1 psi is
.about.2.07 kPa). Maintaining the pressure at about P.sub.2 for
Pt.sub.2 is useful for further consolidation and curing the resin
of the composite article 22. Modulation can be used for staying
within the tolerance level.
[0115] Pt.sub.2 can be various time periods. Typically, Pt.sub.2 is
shorter than Pt.sub.1. However, Pt.sub.2 may also be longer than or
equal to Pt.sub.1 or a subsequent time period. Typically, Pt.sub.2
is from about 1 to about 25, from about 1 to about 20, from about 1
to about 15, from about 1 to about 10, from about 1 to about 7.5,
from about 1 to about 5, or from about 1 to about 2.5, minutes.
[0116] In certain embodiments, the method further comprises the
step of maintaining pressure at an intermediate pressure
(P.sub.1-2) of between P.sub.1 and P.sub.2 for a portion of
Pt.sub.1 (Pt.sub.<1) prior to P.sub.2. Typically, this step
occurs prior to pressurizing to P.sub.2. The pressure can be
maintained at P.sub.1-2 or at an acceptable tolerance level, e.g.
P.sub.1-2.+-.10 psi. It is believed that maintaining the pressure
at about P.sub.1-2 for Pt.sub.<1 is useful for consolidating the
composite article 22. For example, the resin can be at its minimum
viscosity or thinned to more readily flow within the carbon fiber
mat of the preform 62. Modulation can be used for staying within
the tolerance level.
[0117] P.sub.1-2 can be various pressures. For example, P.sub.1-2
can be in the middle of P.sub.1 and P.sub.2, closer to P.sub.1, or
closer to P.sub.2. Typically, P.sub.1-2 is from about 25 to about
125, from about 35 to about 115, from about 45 to about 105, from
about 50 to 100, from about 55 to about 95, from about 65 to about
85, or about 75, psig.
[0118] Pt.sub.<1 can be various time periods, provided it is
less than Pt.sub.1. Typically, Pt.sub.1-2 is longer than Pt.sub.2.
However, Pt.sub.1-2 may also be shorter than or equal to Pt.sub.2
or a subsequent time period. Typically, Pt.sub.<1 is from about
1 to less than about 25, from about 1 to about 20, from about 1 to
about 15, from about 1 to about 10, from about 1 to about 7.5, from
about 1 to about 5, or from about 1 to about 2.5, minutes.
[0119] The method further comprises the step of reducing pressure
on the composite article 22. The method further comprises the step
of cooling the mold surface 24 of the tool 26 to drop the mold
surface 24 from about T.sub.2 to T.sub.3 within Tt.sub.3. The mold
surface 24 of the tool 26 can be cooled with the system 20 as
described above. The method further comprises the step of removing
the composite article 22 from the mold surface 24 of the tool 26.
The composite article 22 may be removed manually or
automatically.
[0120] As described above, the system 20 can be used to heat and
cool the mold surface 24 of the tool 26. The controller 56 can be
programmed with various control schemes to heat and cool the mold
surface 24 using the subsystems 40,48,49 and three-way valve 58 of
the system 20, if utilized. The controller 56 can also be
programmed to apply and remove pressure to the composite article 22
at various times and/or at various temperatures.
[0121] As alluded to above, pressure can be applied by various
means. In certain embodiments, described further below, a pressure
tank 66 is used along with the press 64 to apply pressure to the
composite article 22. It is to be appreciated that reference to the
composite article 22 herein may also refer to the preform 62
depending on its degree of formation.
[0122] In certain embodiments, the controller 56 is programmed such
that Tt.sub.1.ltoreq.Tt.sub.2 or Tt.sub.1.gtoreq.Tt.sub.2. In
further embodiments, the controller 56 is programmed such that
Tt.sub.1.gtoreq.Tt.sub.3 or Tt.sub.1.ltoreq.Tt.sub.3. The total of
Tt.sub.1+Tt.sub.2+Tt.sub.3 is as described above. In certain
embodiments, the controller 56 is programmed such that
Pt.sub.1.ltoreq.Pt.sub.2 or Pt.sub.1.gtoreq.Pt.sub.2. In further
embodiments, the controller 56 is programmed such that
Pt.sub.1.ltoreq.Tt.sub.1 or Pt.sub.1.gtoreq.Tt.sub.1. In yet
further embodiments, the controller 56 is programmed such that
Pt.sub.2.ltoreq.Tt.sub.1 or Pt.sub.2.ltoreq.Tt.sub.1. Typically,
(Pt.sub.1+Pt.sub.2).ltoreq.(Tt.sub.1+Tt.sub.2+Tt.sub.3). Said
another way, the total time for heating and cooling generally
defines the total cycle time for forming the composite article
22.
[0123] Timing for each of the temperature and pressure time periods
can be changed to alter surface and/or mechanical properties of the
composite article 22. Specific heating, cooling, pressurizing, and
depressurizing profiles, for making different types of composite
articles 22, can be determined via routine experimentation.
Examples of specific profiles are illustrated in FIGS. 11, 12, and
13, which are described further below. As described above, due to
the direct heating and cooling of the mold surface 24 via the
system 20, cycle time of making the composite article 22 is greatly
reduced relative to conventional methods, e.g. autoclaving.
[0124] The present invention provides another method. The method is
useful for forming the composite article 22. The method comprises
the steps of providing the tool 26 and the preform 62. The tool 26
and preform 62 can be as described above.
[0125] The method further comprises the step of providing the press
64. The press 64 can be situated proximal or distal each of the
system 20, the pressure tank 66, and/or the controller 56.
[0126] The subsystems 40,48,49 of the system 20 can be situated
proximal or distal each other. If utilized, the exchanger-subsystem
49 is typically proximal the press 64. The controller 56 can be
situated proximal or distal each of the subsystems 40,48,49 and the
pressure tank 66. As such, the system 20 offers flexibility in
laying out each of its components.
[0127] Referring to FIGS. 5-7, the press 64 has a platform 68 and a
cover 70 facing the platform 68. The platform 68 of the press 64 is
useful for supporting the tool 26. The method further comprises the
step of contacting (or coupling) the platform 68 with the cover 70
to define a cavity 72 between the cover 70 and the platform 68. The
cavity 72 may also be referred to as a plenum. Typically, the cover
70 and/or the platform 68 include a peripheral seal 74, such as a
peripheral gasket 74, such that the cavity 72 is airtight. In this
way, the cavity 72 is operable to maintain a pressurized and/or
temperature controlled environment about the tool 26. Various types
of seals 74 can be employed. In these embodiments, the cover 70 is
generally rigid and inflexible (which is different from a rubber or
"bladder" type mold surface). Various types of presses 64 can be
employed. The press 64 should be capable of handling the pressures
described herein. Suitable presses 64 are commercially available
from a variety of suppliers. Specific examples of presses 64
include those available from Globe Machine Manufacturing Company of
Tacoma, Wash.
[0128] Referring to FIG. 3, the method further comprises the step
of disposing the preform 62 on the mold surface 24 of the tool 26.
The method further comprises the step of disposing the vacuum
canopy 36 on the tool 26 to define an envelope (not shown) between
the vacuum canopy 36 and the mold surface 24 of the tool 26. The
preform 62 and the vacuum canopy 36 may be disposed manually or
automatically.
[0129] The vacuum canopy 36 may also be referred to as a bag 36 or
a sheet 36. The vacuum canopy 36 can be formed from various
materials, such as a polymeric material, e.g. a silicone. The
vacuum canopy 36 can include a peripheral seal 78, e.g. a
peripheral gasket 78, to assist in forming the envelope. In
addition, or alternatively, putty 78 can be used. Various types of
seals 78 and/or putty 78 can be employed. Typically, the envelope
is airtight. The vacuum canopy 36 can include a peripheral frame 80
for adding rigidity and easing handling of the vacuum canopy 36.
Handles (not shown) may be attached to the peripheral frame 80 for
moving the vacuum canopy 36. Clasps 82 can also be attached to the
peripheral frame 80 to interact with the fasteners 34 of the tool
26. The clasps 82 and fasteners 34 are useful for maintaining
orientation of the vacuum canopy 36 on the tool 26.
[0130] A release sheet (not shown) may be disposed between the
vacuum canopy 36 and the preform 62 to prevent sticking. A release
sheet or coating (not shown) may also be applied to the mold
surface 24 to prevent the composite article 22 from sticking.
Various types of release sheets and/or coatings may be employed.
The release sheet may be formed from various materials, such as a
polymeric film.
[0131] The method further comprises the step of disposing the tool
26 under the cover 70 such that it is within the cavity 72 of the
press 64 once established. The tool 26 is generally disposed under
the cover 70 of the press 64 prior to contacting the cover 70 to
the platform 68 to establish the cavity 72. The tool 26 generally
takes up at least about 33%, at least about 50%, at least about
66%, at least about 75%, at least about 80%, at least about 85%, or
at least about 90%, of the overall volume of the cavity 72, when
disposed therein. As such, the remaining volume of the cavity 72 is
typically small relative to the overall volume when the tool 26 is
present. Inserts, partitions, or blocks (not shown) can be used to
take up additional volume in the cavity, if desired.
[0132] Referring to FIGS. 5 and 6, a support table 84 is disposed
next to the press 64. The support table 84 is useful for holding,
loading, and unloading the tool 26. Another support table 84 may be
used on an opposite side of the press 64 for unloading, or just one
support table 84 may be used.
[0133] A carrier 86 is disposed adjacent the platform 68. The
carrier 86 is generally on a chained track 88 and includes at least
one hook 90 to engage the tool 26, and typically includes one hook
90 for engaging each side of the tool 26. The carrier 86 is useful
for pulling the tool 26 from the support table 84 onto the platform
68 of the press 64, and under the cover 70 of the press 64.
[0134] After the carrier 86 moves the tool 26 a majority of the way
under the cover 70, the carrier 86 moves out of the way of the
cover 70. The cover 70 then lowers down over the platform 68 to
engage (or couple to) the platform 68 and define the cavity 72.
Pistons 92 and/or gears 94 can be used to move the cover 70 of the
press 64 up and down into place.
[0135] Once the cover 70 is in contact with the platform 68, rams
96 disposed on the cover 70, extend into the cover 70 and the
cavity 72. The rams 96 engage with receivers 98 on the tool 26 and
push the tool 26 further on the platform 68 to substantially center
the tool 26 within the cavity 72. At this point, the tool 26 is
generally aligned such that it is in fluid communication with the
system 20. Such fluid communication from the tool 26 to the system
20 can be routed through the cover 70 and/or through the platform
68 of the press 64. The press 64 can include one or more sensors
(not shown) to ensure proper location of the tool 26 prior to
lowering the cover 70 and/or prior to heating the mold surface
24.
[0136] In certain embodiments, the system 20 includes a connection
system for automatically coupling the press 64 and the tool 26. The
connection system is useful for communicating the thermal fluid to
and from the tool 26 via the system 20. Referring to FIG. 15, a
tool-connection system 200 for the tool 26 is shown. The
tool-connection system 200 includes a plurality of connections for
connecting various elements to the tool 26, such as fluid feeds,
fluid returns, and sensors. Said another way, the tool-connection
system 200 can provide various services to the tool 26, and
optionally, to the cavity 72 of the press 64. In general, the
elements provide services and communication with the tool 26. These
elements are generally in communication with the tool 26, such as
being in fluid communication with the tubing 28 of the tool 26.
[0137] The tool-connection system 200 includes a resistive thermal
device (RTD) male connector 202 for temperature monitoring and
feedback of the tool 26. The tool-connection system 200 also
includes a first alignment bushing 204, a thermal fluid intake
valve 206 for feeding thermal fluid to the tool 26 from the inlet
30, a male locking pin 208, a thermal fluid exhaust valve 210 for
returning the thermal fluid from the tool 26 out the outlet 32, a
second alignment bushing 212, and a vacuum connector 214 and static
connector 216 for pressure monitoring of the tool 26. In addition
to or alternate to an RTD, other forms of temperature measurement
of the tool 26 can also be utilized, such as thermocouples. These
forms include thermocouples, optical pyrometers and other like
systems. Certain embodiments may monitor the actual temperature or
the rate of change in the temperature.
[0138] Referring to FIG. 16, a press-connection system 218 for the
press 64 is shown. The press-connection system 218 includes a
plurality of connections for connecting various elements to the
press 64, such as fluid feeds, fluid returns, and sensors. These
elements are generally in communication with the system 20, such as
being in fluid communication with the piping 38 of the system 20.
The press-connection system 218 includes a RTD female connector 220
for temperature monitoring and feedback of the tool 26. The
press-connection system 218 also includes a thermal fluid exhaust
valve 222 for feeding thermal fluid to the tool 26 from the inlet
30, a thermal fluid intake valve 224 for returning the thermal
fluid from the tool 26 out the outlet 32, a first alignment pin
226, a vacuum connector 228 and a static connector 230 for pressure
monitoring of the tool 26, a female locking ring 230 operated by
hydraulic actuators, and a second alignment pin 232.
[0139] Referring to FIG. 17, the press 64 is depicted during a
press cycle to form a composite article 22. The press 64 and tool
26 have a pressure and temperature profile which is imparted in
part by the press-connection system 218 and the tool-connection
system 200 in combination with the system 20. Typically, connection
between the tool 26 and cover 70 of the press 64 is done
automatically after the cover 70 closes. Specifically, the
tool-connection system 200 and the press-connection system 218
couple and engage with one another after the tool 26 enters the
press 64. Typically, as like shown in FIG. 17, the rams 96 are used
to push the connection systems 200,218 together. The carrier 86 can
later be used to pull the connection systems 200,218 apart. Once
coupled, the tool 26 and the press 64 are in fluid (and, typically,
electrical communication) with one another as well as in
communication with the controller 56.
[0140] In a specific embodiment, the tool-connection system 200 is
operatively connected to the tool 26, and the press-connection
system 218 is in fluid communication with the heater-subsystem 40
and the exchanger-subsystem 49. As described above, the connection
systems 200,218 couple together for feeding and receiving the first
thermal fluid to and from the tool 26. The press-connection system
218 is operatively connected to the tubing 28 of the tool 26 for
heating and cooling the mold surface 26 with the first thermal
fluid. The press-connection system 218 is operatively connected
through the cover 70 and/or the platform 68 of the press 64 into
the cavity 72 for coupling with the tool-connection system 200
while the tool 26 is disposed within the cavity 70 of the press 64
for heating and cooling the mold surface 26 with the first thermal
fluid.
[0141] Such a "quick-connect/disconnect" configuration provides for
manufacturing versatility, such as allowing for multiple tool 26
variations to be utilized with no affiliated change over time. For
example, various configurations of tools 26 can be utilized and
simply "plugged into" the press 64 via the connection systems
200,218. This also allows for a fast change out of the tools 26 in
the system 20. Tool 26 changes can occur in a time frame of 5
minutes, as fast as 2 minutes and as long as 10 minutes. As a
comparison, typical tool changes in compression molding of fiber
reinforced plastic parts can take 4 hours.
[0142] As introduced above, operation of the system 20, including
positioning of the tool 26 and the applied temperature and pressure
is generally monitored and controlled by the controller 56. The
controller 56 may be implemented using shared processing devices
and/or individual processing devices. Processing devices may
include microprocessors, micro-controllers, digital signal
processors, microcomputers, central processing units, field
programmable gate arrays, programmable logic devices, state
machines, logic circuitry, analog circuitry, digital circuitry,
and/or any device that manipulates signals (analog and/or digital)
based on operational instructions. The memory may be a single
memory device or a plurality of memory devices.
[0143] Such a memory device may be a read-only memory, random
access memory, volatile memory, non-volatile memory, static memory,
dynamic memory, flash memory, and/or any device that stores digital
information. Note that when the baseband processing module
implements one or more of its functions via a state machine, analog
circuitry, digital circuitry, and/or logic circuitry, the memory
storing the corresponding operational instructions is embedded with
the circuitry comprising the state machine, analog circuitry,
digital circuitry, and/or logic circuitry.
[0144] Returning to the method, the method further comprises the
step of applying vacuum to the vacuum canopy 36 thereby evacuating
the envelope to retain the preform 62 adjacent the mold surface 24
of the tool 26. This is useful for keeping the preform 62 in
contact with the mold surface 24 for heating and cooling. Vacuum
may be applied by various methods. For example, a vacuum pump (not
shown) can be connected to the tool 26 which draws air from the
mold surface 24. Typically, vacuum is tested prior to disposing the
tool 26 within the cavity 72 to ensure a proper seal of the vacuum
canopy 36 on the tool 26. As described above, the fasteners 34 and
clasps 82 are useful for aligning the vacuum canopy 36 on the tool
26. The vacuum pump can be in fluid communication with the tool
through the cover 70 and/or through the platform 68 of the press
64. Vacuum can be applied at various pressures, such as from about
10 to about 35, or about 12.5 to about 32.5, or about 15 to about
30, in Hg.
[0145] The method further comprises the step of heating the mold
surface 24 of the tool 26 from T.sub.1 to T.sub.2 within Tt.sub.1.
This is useful for thinning the resin of the preform 62. T.sub.1,
T.sub.2, and Tt.sub.1 can be as described above. The system 20 can
be used for heating the mold surface 24.
[0146] The method further comprises the step of pressurizing the
cavity 72 of the press 64 from P.sub.1 to P.sub.2 within Pt.sub.1.
This is useful for consolidating the preform 62. P.sub.1, P.sub.2,
and Pt.sub.1 can be as described above. Typically, the method
further comprises the step of providing the pressure tank 66. The
pressure tank 66 is in fluid communication with the cavity 72 of
the press 64 to pressurize and/or depressurize the cavity 72 of the
press 64. Such fluid communication can be through the cover 70
and/or through the platform 68 of the press 64.
[0147] In certain embodiments, the gas is recycled from the cavity
72 after use. In other embodiments, the gas is vented from the
cavity 72 after use, rather than being recycled. The pressure tank
66 can contain various compressed gases. Typically, the pressure
tank 66 contains compressed air, such that the cavity 72 of the
press 64 is pressurized with air. In certain embodiments, the
pressure tank 66 is free of compressed nitrogen gas (N.sub.2). It
is to be appreciated that air can include .about.78% N.sub.2. While
air is typically used to pressurize the cavity 72, other types of
gases may also be used.
[0148] The pressure tank 66 may be a stand alone pressurized tank
containing the compressed gas or be part of an air compressor. The
pressure tank 66 and/or air compressor may be of various types. The
pressure tank 66 and/or air compressor should be capable of
handling and delivering the pressures associated with the cavity 72
of the press 64. For example, the pressure tank 66 should be able
to pressurize the cavity 72 of the press 64 to at least 150 psig in
no more than 120 seconds. Suitable pressure tanks 66 and air
compressors are commercially available from a variety of suppliers.
Specific examples of air compressors include those commercially
available from Sullair.RTM. of Michigan City, Ind., including the
Sullair.RTM. Stationary Air Power Systems, e.g. the Sullair.RTM.
2200, the Sullair.RTM. 3700, the Sullair.RTM. 4500, and the
Sullair.RTM. 7500.
[0149] The pressure tank 66 can be in fluid communication with a
dryer (not shown). The dryer is useful for removing moisture from
the compressed gas sent to or returned from the cavity 72 of the
press 64. The dryer may be of various types. Suitable dryers are
commercially available from a variety of suppliers. Specific
examples of dryers include those commercially available from BEKO
Technologies Corp. of Atlanta, Ga., including the Drypoint.RTM.
Series, e.g. the Drypoint.RTM. RA.
[0150] Typically, the method further comprises the steps of
providing the system 20 and providing the controller 56 for heating
and cooling of the mold surface 24 of the tool 26, as well as for
pressurizing and depressurizing the cavity 72. For example, the
controller 56 can be in communication with the pressure tank 66 and
the press 64 with the controller 56 controlling the pressure tank
66 and/or the press 64 to pressurize or depressurize the cavity 72.
The controller 56 typically measures pressure of the cavity 72 by
feedback from one or more pressure sensors (not shown) disposed
within the cavity 72. The controller 56 is typically programmed to
set certain pressures at certain times and/or temperatures.
[0151] The method further comprises the step of maintaining the
mold surface 24 of the tool 26 at about T.sub.2 for Tt.sub.2. This
is useful for curing the resin. The method can further comprise the
step of maintaining the mold surface 24 of the tool 26 at T.sub.1-2
for Tt.sub.<1 prior to heating the mold surface 24 of the tool
26 to T.sub.2.
[0152] The method further comprises the step of maintaining the
cavity 72 of the press 64 at about P.sub.2 for Pt.sub.2. This is
useful for further consolidating and curing of the composite
article 22. The method further comprises the step of cooling the
mold surface 24 of the tool 26 to drop the mold surface 24 from
about T.sub.2 to T.sub.3 within Tt.sub.3. The controller 56, the
system 20, and the pressure tank 66 can be used for these
steps.
[0153] The method further comprises the step of depressurizing the
cavity 72 of the press 64. Typically, the cavity 72 is
depressurized back to P.sub.1 over a third period to time
(Pt.sub.3). The cavity 72 of the press 64 can be depressurized at
various rates. The rate of depressurizing may be linear or
curvilinear. For example, the rate of depressurizing can increase
at a decreasing rate, increase at an increasing rate, be
substantially constant, or combinations thereof. Typically,
depressurizing is at a rate of greater than about 0.1, greater than
about 0.2, greater than about 0.3, greater than about 0.4, greater
than about 0.5, greater than about 0.6, greater than about 0.7,
greater than about 0.8, greater than about 0.9, greater than about
1, greater than about 1.1, greater than about 1.2, greater than
about 1.3, greater than about 1.4, or greater than about 1.5, psi
per second. In certain embodiments, the cavity 72 can be
depressurized at a rate upwards of about 100, about 75, about 50,
about 25, or about 10, psi per second.
[0154] Pt.sub.3 can be various time periods. Typically, Pt.sub.3 is
short relative to previous time periods of pressurizing. However,
Pt.sub.3 may also be longer than or equal to one or more previous
time periods of pressurizing. Typically, Pt.sub.3 is from about 1
to about 25, from about 1 to about 20, from about 1 to about 15,
from about 1 to about 12.5, from about 1 to about 10, from about 1
to about 7.5, from about 1 to about 5, or from about 1 to about 2,
minutes. Typically,
(Pt.sub.1+Pt.sub.2+Pt.sub.3).ltoreq.(Tt.sub.1+Tt.sub.2+Tt.sub.3).
[0155] The method can further comprise the step of maintaining the
cavity 72 of the press 64 at P.sub.1-2 for Pt.sub.<1 prior to
pressurizing the cavity 72 of the press 64 to P.sub.2. The method
further comprises the step of separating the cover 70 and the
platform 68 of the press 64. Typically, pressure in the cavity 72
is reduced prior to separating the cover 70 and platform 68 to
prevent damage to the peripheral seal 74 and/or composite article
22. As alluded to the above, the pressure tank 66 can be used to
depressurize the cavity 72. In addition or alternatively, the press
64 can vent the compressed gas to the atmosphere in a rapid or
controlled manner. The method can further comprise the step of
maintaining vacuum on the vacuum canopy 36. This is typically done
while the cavity 72 of the press 64 is pressurized.
[0156] The method further comprises the step of removing the tool
26 from the press 64. The carrier 86 can be used to push or pull
the tool 26 from the platform 68 back to the support table 84 or
another support table 84. Referring to FIG. 8, another embodiment
of the press 64 is shown. One support table 84 can be used for
loading and one support table 84 can be used for unloading. In this
configuration, different tools 26 can be used to load the press 64
rather than using the previously unloaded tool 26. This is not to
say that a previously unloaded tool 26 cannot be loaded into the
press 64 at a later time.
[0157] The method further comprises the step of removing the vacuum
canopy 36 from the tool 26. The vacuum canopy 36 may be removed
manually or automatically. The method further comprises the step of
removing the composite article 22 from the mold surface 24 of the
tool 26. The composite article 22 may be removed manually or
automatically. Typically, the composite article 22 is at a
temperature which can be handled by gloved (or bare) hand. The
total of Tt.sub.1+Tt.sub.2+Tt.sub.3 is as described above.
[0158] The present invention also provides a method of forming a
preform 62. The method may be referred to as a layup (or lay-up)
method. The preform 62 may be used with the system 20 and/or
invention methods described above to form the composite article
22.
[0159] Referring to FIG. 9, the method comprises the step of
providing a mandrel 100 having a mandrel surface 102. Various types
of mandrels 100 can be employed. Suitable mandrels 100 are
commercially available from a variety of suppliers. Specific
examples of mandrels 100 include those commercially available from
Models & Tools Inc.
[0160] Typically, the mandrel surface 102 of the mandrel 100 is
complimentary to the mold surface 24 of the tool 26. For example,
the surfaces 24,102 may be in a female/male configuration. The
mandrel 100 can be similar to the tool 26. For example, the mandrel
can have tubing 104 for conveying a fluid.
[0161] The tubing 104 includes at least one input 106 for
communicating fluid to the tubing 104 and at least one outlet 108
for communicating fluid from the tubing 104. The tubing 104 is
proximal or directly in contact with the mandrel surface 102 to
expedite heat transfer. The tubing 104 is useful for direct (rather
than indirect) heating or cooling of the mandrel surface 102. The
tubing 104 may be formed into the mandrel 100 itself (such as by
boring), or attached within the mandrel 100 proximal the mold
surface 24, either to the tool 26 and/or to the mold surface 24.
The tubing 104 can be arranged in various patterns and may be of
equal or varying diameters, as like described above for the tool
26.
[0162] The tubing 104 of the mandrel 100 is connected to piping
(not shown) for communicating the fluid to and from the mandrel
100. The mandrel 100 can be in fluid communication with the system
20 for heating or cooling the mandrel surface 102. Alternatively,
the mandrel 100 can be in fluid communication with another type of
system (not shown), such as a conventional oil- or water-based
heating and/or cooling system, typically a water-based system.
[0163] The method further comprises the steps of providing pieces
of a carbon fiber sheet 110 and providing the resin. The pieces of
carbon fiber sheet 110 can be of various types, such as pieces 110
comprising the pre-pregs and/or carbon fiber mats described above.
The resin can be of various types, such as the epoxies described
above. The resin has a "tack" temperature, which is described
further below.
[0164] The method further comprises the step of heating the mandrel
surface 102 to a first temperature. The first temperature promotes
adhesion of the resin to the mandrel surface 102 during preparation
of the preform 62. The first temperature generally corresponds to
the tack temperature of the resin, where the resin adheres to both
the mandrel surface 102 and to itself, such as adhesion between
layers of the pieces 110.
[0165] The tack temperature can be determined via testing or by
reference to technical literature of the resin, such as from MSDS
or technical data sheets. A typical test for determining tack
involves placing a gloved finger or tool on a layer of the resin,
and pulling the finger or tool away to determine at which point in
temperature the resin adheres to the finger or tool when pulled
away. The first temperature is typically of from about 100 to about
175, from about 110 to about 155, or from about 125 to about 140,
.degree. F. (.about.38 to .about.79, .about.43 to .about.68, or
.about.52 to .about.60, .degree. C.).
[0166] The method typically comprises the step of applying the
resin to the mandrel surface 102 of the mandrel 100 to form a resin
layer (not shown). The resin may be applied by various methods. For
example, the resin may be applied by hand or robotic spraying,
brushing, pouring, rolling, etc. Prior to applying the resin, a
release liner or coating may be applied to the mandrel surface 102
to prevent sticking of the preform 62.
[0167] The method further comprises the step of arranging the
pieces 110 on the resin layer to form a carbon fiber mat. The
pieces 110 may be laid in a uniform layer and/or may overlap one
another. Multiple layers of the pieces 110 can be arranged to build
up thickness of the carbon fiber mat, and optionally, additional
resin can be applied between the layers of the pieces 110. The
method typically comprises the step of applying additional resin on
top of the carbon fiber mat.
[0168] The method further comprises the step of disposing a vacuum
sheet 112 on the mandrel 100 to define an envelope (not shown)
between the vacuum sheet 112 and the mandrel surface 102 of the
mandrel 100. Typically, putty 114 is applied around a periphery of
the mandrel 100 for making the envelope airtight. The putty 114 may
be applied by various methods, such as by hand, robotic dispenser,
etc. A release liner or coating may be applied between the vacuum
sheet 112 and the preform 62 to prevent sticking. Rather than using
the putty 114, the vacuum sheet 112 may be configured similar to or
the same as the vacuum sheet 36 described above with the tool 26.
In other words, the vacuum sheet 112 may include a peripheral seal
(not shown).
[0169] The method further comprises the step of applying vacuum to
the vacuum sheet 112 thereby evacuating the envelope to retain the
preform 62 adjacent the mandrel surface 102 of the mandrel 100.
This is useful for consolidating the pieces 110 and further form
the preform 62. This is also useful for keeping the preform 62 in
contact with the mandrel surface 102 during heating and cooling.
Vacuum can be applied at various pressures, such as from about 10
to about 35, from about 12.5 to about 32.5, or from about 15 to
about 30, inches Hg.
[0170] The method further comprises the step of cooling the mandrel
surface 102 to a second temperature. The second temperature allows
the preform 62 to be released from the mandrel surface 102. The
second temperature is typically cooler than the first temperature,
and generally corresponds to either a non-tack or less tacky
temperature of the resin. The second temperature is typically from
about 35 to about 100, about 40 to about 75, or about 40 to about
50, .degree. F. (.about.1.7 to .about.38, .about.4 to .about.24, or
.about.4 to .about.10, .degree. C.). Heating and cooling of the
mandrel surface 102 can be controlled manually, or automatically,
such as by another controller (not shown). The method further
comprises the steps of removing the vacuum sheet 112 from the
mandrel 100 and removing the removing the preform 62 from the
mandrel surface 102. These steps can be manual or automatic.
[0171] In certain embodiments, the mandrel 100 can be attached to a
manual or robotic arm (not shown), such that the mandrel 100 can be
movable from a preparation position to a molding position. For
example, in the preparation position, the preform 62 is formed on
the mandrel 100, with the mandrel surface 102 set at the first
temperature to hold the preform 62 in place. After the preform 62
is formed, the mandrel 100 can then move to the molding position,
where the temperature of the mandrel surface 102 is set to the
second temperature, thereby allowing release of the preform 62 from
the mandrel surface 102. The preform 62 can then be disposed on the
mold surface 24 of the tool 26 for further processing, such as
directly moving or dropping the preform 62 from the mandrel 100
onto the mold surface 24. Alternatively, the preform 62 can be
stored or queued for later use in either the same or a different
location.
[0172] Referring to FIG. 10, various steps (or processes) may be
carried out before and/or after formation of the composite article
22 in the press 64. These steps can be used in various orders and
combinations. These additional steps are merely examples, and are
not to be construed as limitations of the present invention.
[0173] The pieces 110 for the preform 62 can be provided by a "kit
cut" process. For example, a pre-preg sheet can be cut into the
pieces 110 using computer driven cutting tables, which use data
from a computer aided drafting (CAD) system and/or from digitized
patterns and drawings. For precise cutting, the kit cut process may
utilize a computer numerically controlled (CNC) work cell, which
includes of a series of CNC and machining tools. Patterns and molds
can be made on-site, but may also be supplemented by 3.sup.rd
parties, if needed. Similar to other raw materials, the pieces 110
can be cold stored in a freezer to preserve them in advance of a
lay-up process.
[0174] The pieces 110 can be used to form preforms 62 with the
mandrel 100 as described above. While automation is possible, the
use of hand lay-up generally allows for designing composite
articles 22 with different strength requirements throughout the
composite article 22 by laying down a kit of the pieces 110 that is
unique to each mandrel 100. In addition, hand lay-up can reduce
material cost by eliminating unnecessary extra build-up of the
resin.
[0175] After formation of the composite articles 22 via the press
64 and after removal from the tool 24, they can be provided to a
trim process. The composite articles 22 may be mechanically trimmed
and/or drilled by a robotic router. The use of the robotic router
facilitates consistent accuracy as well as timely turnaround. The
composite articles 22 may then be provided to a sub-assembly and
bonding process. Composite articles 22 that may require bonding are
prepped following the trim process and placed in a bonding cell
where they are CNC bonded. The use of a robotic bonding cell
provides a consistent adhesive path for bond accuracy as well as
quick turnaround.
[0176] The composite articles 22 may then be provided to a
finishing process. Here, the composite articles 22 can be
robotically or hand sanded. It is believed that while automated
technology can streamline the finishing process, use of hand
sanding helps to ensure Class A surface quality, if desired.
Technicians identify and repair minor surface blemishes of the
composite articles 22, if present. The composite articles 22 may
then be provided to a prime process. The composite articles 22 can
enter a paint line system for a high volume low pressure (HVLP)
primer (or clear coat) application. The composite articles 22 may
be washed prior to prevent contamination. Composite articles 22
having exposed carbon fiber weave can be clear coated and shipped
directly to a customer, while composite articles 22 which require
color can be primed and may be sent to a 3.sup.rd party, e.g. an
OEM approved supplier, to be painted before reaching a customer.
The composite articles 22 may then be provided to a final
inspection process. The composite articles 22 can be gauged and
visually inspected to ensure dimensional quality. Clear coated
composite articles 22 can be provided to a finesse stage where they
are polished to a jewel like finish before a final visual
inspection prior to shipment to the customer.
[0177] The composite articles 22 formed from the invention methods
have excellent mechanical properties and/or surface properties. For
example, the composite articles 22 can have near Class A surfaces,
with little to no surface blemishes relative to composite articles
formed via conventional autoclaving methods. More specifics of the
composite articles 22 are described in the examples immediately
below.
[0178] Additional embodiments, aspects, and benefits of the present
invention may be appreciated with reference to the disclosures of:
U.S. Provisional Patent Application Ser. No. 61/410,753, entitled
"METHOD OF MAKING COMPOSITE PARTS BY USING MEMBRANE PRESS"; U.S.
Provisional Patent Application Ser. No. 61/495,661, entitled "RAPID
CURE SYSTEM FOR THE MANUFACTURE OF COMPOSITE PARTS"; U.S.
Provisional Patent Application Ser. No. 61/418,521, entitled
"SYSTEMS AND METHODS FOR FORMING COMPOSITE COMPONENTS";
International Application No. PCT/US2011/059434, entitled "THERMAL
PROCESSING AND CONSOLIDATION SYSTEM AND METHOD"; and International
Application No. PCT/US2011/062836, entitled "METHOD AND SYSTEM FOR
FORMING COMPOSITE ARTICLES"; all of which are incorporated herein
by reference in their entirety to the extent they do not conflict
with the general scope of the present invention.
[0179] The following examples, illustrating the system 20, methods,
and composite articles 22 of the present invention, are intended to
illustrate and not to limit the invention.
Examples
[0180] Comparative examples of composites articles are made by
using a conventional autoclave and autoclaving method. Invention
examples of composites articles are made by using and the system
and method of the present invention. Additional information
regarding these examples is provided in Table I below and the
subsequent description.
TABLE-US-00001 TABLE I Example No.: Comparative Example Invention
Example Preform Carbon Fiber Mat No.: 1 1 Resin No: 1 1 Tool No.: 1
1 Curing Method: Autoclave System (20) + Press (64) Heat Ramp Rate:
~5.degree. F./min ~180.degree. F./ (~2.8.degree. C./min) min
(~100.degree. C./min) Pressurize Ramp Rate: ~0.15 psi/sec ~1
psi/sec (~7 kPa/sec) (~1 kPa/sec) Depressurize Ramp Rate: ~0.3
psi/sec ~1 psi/sec (~7 kPa/sec) (~2 kPa/sec) Total Cycle Time: 72
mins 13 mins Temperature of Tool: ~180.degree. F. (~82.degree. C.)
~120.degree. F. (~49.degree. C.) (after Total Cycle Time) Energy
use in "X" units ~2X X Operating Costs in "X" ~5X X units
[0181] The preforms are formed by conventional lay-up methods. The
preforms are shaped into car hoods. The carbon fiber mat is an
exposed weave pre-preg, and the resin is a "quick cure" epoxy
resin, which are both commercially available from Toray Composites
(America), Inc. of Tacoma, Wash.
[0182] The preforms are loaded into tool and covered with a vacuum
sheet. The tools are the same in configuration and material. Vacuum
is established and confirmed. The tools are disposed into the
autoclave or press, respectively. The autoclave is closed and the
started. The press is closed and started. The press is in fluid
communication with the invention system.
[0183] Referring to FIG. 14, specific parameters including
temperature and pressure ramps and dwells for the autoclave can be
better appreciated. Each of the TCs in FIG. 14 refers to a
temperature at a specific point on the mold surface of the tool. As
can be appreciated, the autoclave fails to uniformly heat the mold
surface at constant temperatures. It is believed that this lack of
uniform heat soaking imparts the composite articles formed in the
autoclave with various problems, such as surface blemishes.
Referring to FIG. 11, specific parameters including temperature and
pressure ramps and dwells for the press can be better
appreciated.
[0184] FIG. 12 illustrates a second invention example (not shown in
Table I above). FIG. 13 illustrates a third invention example (also
not shown in Table I above). As can be appreciated with reference
to FIGS. 12 and 13, the invention system is capable of rapidly
heating the mold surface in a short period of time. In addition, a
dwell is not required to reach a peak temperature. Instead, the
peak temperature can be quickly reached within a very short period
of initial time based on the rapid heating capability of the
invention system.
[0185] Referring to FIG. 11, temperature of the mold surface of the
tool ramps from T.sub.1 to T.sub.1-2 using the heater-subsystem and
controller. Specifically, the controller directs a portion of the
mass of heated fluid from the tank of the heater-subsystem to the
tool using the valves until T.sub.1-2 is reached.
[0186] Once T.sub.1-2 is reached, the controller stops flow from
the tank by using the valves and the heater-subsystem begins to
re-circulate to recharge the mass of heated fluid. T.sub.1-2 is
maintained at an acceptable tolerance level by the controller
modulating additional flow of the mass of heated fluid to the tool,
as needed. During Tt.sub.<1, it is believed that the resin is at
or near its lowest viscosity. Having the resin at such a viscosity
allows any trapped air or resin byproducts created during cure of
the resin (e.g. steam) to evacuate from the composite article.
[0187] While the tool is being heated to temperature T.sub.1-2, the
cavity of the press is pressurized to P.sub.1-2. Specifically, the
controller directs the pressure tank to provide compressed air to
the cavity. Once P.sub.1-2 is reached, the controller stops flow
from the pressure tank. P.sub.1-2 is maintained at an acceptable
tolerance level by the controller modulating additional flow of
compressed air to the cavity, as needed.
[0188] Once Tt.sub.<1 passes, the controller directs another
portion (or all of) the mass of heated fluid to the tool until the
mold surfaces reaches T.sub.2. Once T.sub.2 is reached, the
controller stops flow from the tank by using the valves and the
heater-subsystem begins to re-circulate to recharge the mass of
heated fluid. T.sub.2 is maintained at an acceptable tolerance
level by the controller modulating additional flow of the mass of
heated fluid to the tool, as needed. During Tt.sub.2, it is
believed that the resin is at or near its cure temperature. It is
believed that having the resin at such a temperature imparts the
composite article with excellent surface and mechanical properties.
This temperature can be determined via testing or by reference to
technical literature of the resin, such as from MSDS or technical
data sheets.
[0189] While the tool is being heated to temperature T.sub.2, the
cavity of the press is pressurized to P.sub.2. Specifically, the
controller directs the pressure tank to provide compressed air to
the cavity. Vacuum is maintained while pressure is applied. Once
P.sub.2 is reached, the controller stops flow from the pressure
tank. P.sub.2 is maintained at an acceptable tolerance level by the
controller modulating additional flow of compressed air to the
cavity, as needed. Once Pt.sub.e passes, the controller directs the
press to depressurize. Specifically, the press begins to vent the
compressed air to the atmosphere over Pt.sub.3. The press may do a
complete "dump" of the air, i.e., air does not need to be released
at a controlled rate.
[0190] In certain examples utilizing systems as depicted in FIG. 2,
once Tt.sub.2 passes, the controller directs a portion of the mass
of cooled fluid from the tank of the chiller-subsystem to the tool
using the valves until T.sub.3 is reached. Prior to or while the
heater-subsystem was previously being used, the controller directed
the chiller-subsystem to form and maintain the mass of cooled fluid
using the valves, tank, and chiller. While the chiller-subsystem is
being used, the controller directs the heater-subsystem to recharge
and maintain the mass of heated fluid using the valves, tank, and
heater. As such, the system is ready for a subsequent cycle
immediately after a short period of time.
[0191] In other examples utilizing systems as depicted in FIG. 18,
once Tt.sub.2 passes, the controller directs a portion of the mass
of cooled fluid from the tank of the chiller-subsystem to the
exchanger-subsystem using the valves until T.sub.3 is reached.
Prior to or while the heater-subsystem was previously being used,
the controller directed the chiller-subsystem to form and maintain
the mass of cooled fluid using the valves, tank, and chiller. While
the chiller-subsystem is being used, the controller directs the
heater-subsystem to recharge and maintain the mass of heated fluid
using the valves, tank, and heater. As such, the system is ready
for a subsequent cycle immediately after a short period of
time.
[0192] After each of the cycles is complete, the tools are removed
from the autoclave and press. Performance of each cycle is
evaluated on an appearance basis of the composite articles formed
via each method. Specifically, the composite articles are removed
from the tools and their surfaces are wiped with white talcum
powder to highlight surface blemishes. Pits and/or dry-lines
present on the surface of the composite articles are highlighted by
the talcum powder. Specifically, such defects are seen as white
dots (pits) or white streaks (dry-lines). A pit or dry-line is
where the resin has not properly flowed during the cycle thereby
leaving a void on the surface.
[0193] The composite articles made by the invention system and
method have excellent surface properties relative to those made by
the autoclave. Specifically, the composite articles formed via the
invention system and method have an .about.85 to 90% reduction in
the amount of pits and dry-lines relative to those formed in the
autoclave. In addition, the composite articles formed via the
invention system and method have an .about.85% to 90% reduction in
the severity (depth/width) of pits and dry-lines relative to those
formed in the autoclave. Such defects have to be repaired (filled
and sanded) in order for the surface of the composite article to be
considered Class A.
[0194] Referring back to Table I above, the invention system and
method also has over an .about.80% reduction in cycle time relative
to the autoclave process (13 mins vs. 72 mins). In addition, the
tools are over 30% cooler in temperature after being removed from
the press relative to those removed from the autoclave:
.about.120.degree. F. (.about.49.degree. C.) vs. .about.180.degree.
F. (.about.82.degree. C.). As such, the invention system and method
allows for a significant reduction in cycle time and overall
manufacturing time while providing higher quality composite
articles, as compared to those formed using the autoclave.
[0195] It is to be understood that the appended claims are not
limited to express and particular compounds, compositions, or
methods described in the detailed description, which may vary
between particular embodiments which fall within the scope of the
appended claims. With respect to any Markush groups relied upon
herein for describing particular features or aspects of various
embodiments, it is to be appreciated that different, special,
and/or unexpected results may be obtained from each member of the
respective Markush group independent from all other Markush
members. Each member of a Markush group may be relied upon
individually and or in combination and provides adequate support
for specific embodiments within the scope of the appended
claims.
[0196] It is also to be understood that any ranges and subranges
relied upon in describing various embodiments of the present
invention independently and collectively fall within the scope of
the appended claims, and are understood to describe and contemplate
all ranges including whole and/or fractional values therein, even
if such values are not expressly written herein. One of skill in
the art readily recognizes that the enumerated ranges and subranges
sufficiently describe and enable various embodiments of the present
invention, and such ranges and subranges may be further delineated
into relevant halves, thirds, quarters, fifths, and so on. As just
one example, a range "of from 0.1 to 0.9" may be further delineated
into a lower third, i.e., from 0.1 to 0.3, a middle third, i.e.,
from 0.4 to 0.6, and an upper third, i.e., from 0.7 to 0.9, which
individually and collectively are within the scope of the appended
claims, and may be relied upon individually and/or collectively and
provide adequate support for specific embodiments within the scope
of the appended claims. In addition, with respect to the language
which defines or modifies a range, such as "at least," "greater
than," "less than," "no more than," and the like, it is to be
understood that such language includes subranges and/or an upper or
lower limit. As another example, a range of "at least 10"
inherently includes a subrange of from at least 10 to 35, a
subrange of from at least 10 to 25, a subrange of from 25 to 35,
and so on, and each subrange may be relied upon individually and/or
collectively and provides adequate support for specific embodiments
within the scope of the appended claims. Finally, an individual
number within a disclosed range may be relied upon and provides
adequate support for specific embodiments within the scope of the
appended claims. For example, a range "of from 1 to 9" includes
various individual integers, such as 3, as well as individual
numbers including a decimal point (or fraction), such as 4.1, which
may be relied upon and provide adequate support for specific
embodiments within the scope of the appended claims.
[0197] The present invention has been described herein in an
illustrative manner, and it is to be understood that the
terminology which has been used is intended to be in the nature of
words of description rather than of limitation. Many modifications
and variations of the present invention are possible in light of
the above teachings. The present invention may be practiced
otherwise than as specifically described within the scope of the
appended claims. The subject matter of all combinations of
independent and dependent claims, both singly and multiply
dependent, is herein expressly contemplated.
* * * * *