U.S. patent application number 14/081291 was filed with the patent office on 2014-04-17 for high efficiency photovoltaic cell for solar energy harvesting.
This patent application is currently assigned to Florida State University Research Foundation, Inc.. The applicant listed for this patent is Florida State University Research Foundation, Inc.. Invention is credited to Indranil BHATTACHARYA, Simon FOO.
Application Number | 20140102506 14/081291 |
Document ID | / |
Family ID | 43379407 |
Filed Date | 2014-04-17 |
United States Patent
Application |
20140102506 |
Kind Code |
A1 |
BHATTACHARYA; Indranil ; et
al. |
April 17, 2014 |
HIGH EFFICIENCY PHOTOVOLTAIC CELL FOR SOLAR ENERGY HARVESTING
Abstract
A photovoltaic cell comprising having improved absorption of
electromagnetic radiation is disclosed. The photovoltaic cell can
include a rear contact, a first cell having a first band-gap
energy, and a rear contact in electrical communication with an
electromechanical device. The first cell can include
In.sub.xGa.sub.ySb.sub.z, where x+y+z=1 and z ranges from 0.00001
to 0.025. the photovoltaic cell can also include a second cell
having a second band-gap energy, and a first tunnel disposed
between the first and second cells. The photovoltaic cell can
include at least a third cell and a second tunnel disposed between
the second and third cells. The uppermost cell can include GaP or
InP.
Inventors: |
BHATTACHARYA; Indranil;
(Tallahassee, FL) ; FOO; Simon; (Tallahassee,
FL) |
|
Applicant: |
Name |
City |
State |
Country |
Type |
Florida State University Research Foundation, Inc. |
Tallahassee |
FL |
US |
|
|
Assignee: |
Florida State University Research
Foundation, Inc.
Tallahassee
FL
|
Family ID: |
43379407 |
Appl. No.: |
14/081291 |
Filed: |
November 15, 2013 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
|
|
12822343 |
Jun 24, 2010 |
8609984 |
|
|
14081291 |
|
|
|
|
61219926 |
Jun 24, 2009 |
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Current U.S.
Class: |
136/244 ;
136/256 |
Current CPC
Class: |
H01L 31/03046 20130101;
H01L 31/0687 20130101; H01L 31/0693 20130101; Y02E 10/544
20130101 |
Class at
Publication: |
136/244 ;
136/256 |
International
Class: |
H01L 31/0687 20060101
H01L031/0687; H01L 31/0693 20060101 H01L031/0693 |
Claims
1. A photovoltaic cell comprising: a rear contact; and a first cell
having a first band-gap energy supported by said rear contact, said
first cell comprising In.sub.xGa.sub.ySb.sub.z, wherein x+y+z=1 and
z ranges from 0.00001 to 0.025.
2. The photovoltaic cell according to claim 1, further comprising:
a second cell having a second band-gap energy; and a first tunnel
disposed between said first cell and said second cell, wherein said
second cell is supported by said first cell.
3. The photovoltaic cell according to claim 2, wherein said first
band-gap energy is less than said second band-gap energy.
4. The photovoltaic cell according to claim 2, wherein said first
cell comprises an n.sup.+-doped In.sub.xGa.sub.ySb.sub.z
semiconductor layer and a p-doped In.sub.xGa.sub.ySb.sub.z
semiconductor layer.
5. A photovoltaic cell, comprising: a rear contact; a first cell
having a first band-gap energy; a second cell having a second
band-gap energy; a first tunnel disposed between said first cell
and said second cell; a third cell having a third band-gap energy;
and a second tunnel disposed between said second cell and said
third cell, wherein said first cell is over said rear contact, said
second cell is over said first cell, and said third cell is over
said second cell, and wherein said first cell comprises
In.sub.xGa.sub.ySb.sub.z, wherein x+y+z=1 and z ranges from 0.00001
to 0.025.
6. The photovoltaic cell according to claim 5, wherein said first
band-gap energy is less than said second band-gap energy, and said
second band-gap energy is less than said third band-gap energy.
7. The photovoltaic cell according to claim 6, wherein said first
bad-gap energy is between 0.25 eV and 0.55 eV.
8. The photovoltaic cell according to claim 5, wherein said first
cell comprises an n.sup.+-doped In.sub.xGa.sub.ySb.sub.z
semiconductor layer and a p-doped In.sub.xGa.sub.ySb.sub.z.
9. The photovoltaic cell according to claim 5, wherein said first
cell comprises a semiconductor layer comprising
In.sub.xGa.sub.ySb.sub.z, wherein: x ranges from 0.23 to 0.50, y
ranges from 0.50 to 0.77, and z ranges from 0.00001 to 0.025.
10. The photovoltaic cell according to claim 5, wherein said third
cell comprises one or more of InP, GaP, AlInP and InGaSb.
11. The photovoltaic cell according to claim 5, wherein said second
cell comprises one or more of InGaAs, InP and InGaP.
12. The photovoltaic cell according to claim 5, wherein said third
cell comprises one or more of InP, GaP, AlInP and InGaSb; and said
second cell comprises one or more of InGaAs, InP and InGaP.
13. The photovoltaic cell according to claim 12, wherein (i) said
first tunnel comprises a p.sup.++-type GaAs or a p.sup.++-type
AlGaAs semiconductor layer and an n.sup.++-type GaAs or
n.sup.++-type InGaAs semiconductor layer; (ii) said second tunnel
comprises a p.sup.++-type GaAs or a p.sup.++-type AlGaAs
semiconductor layer and an n.sup.+-type GaAs or a n.sup.++-type
InGaP semiconductor layer; or (iii) both.
14. The photovoltaic cell according to claim 5, wherein (i) said
first tunnel comprises a p.sup.++-type GaAs or a p.sup.++-type
AlGaAs semiconductor layer and an n.sup.++-type GaAs or
n.sup.++-type InGaAs semiconductor layer; (ii) said second tunnel
comprises a p.sup.++-type GaAs or a p.sup.++-type AlGaAs
semiconductor layer and an n.sup.+-type GaAs or a n.sup.++-type
InGaP semiconductor layer; or (iii) both.
15. The photovoltaic cell according to claim 5, wherein the third
cell comprises an In.sub.xGa.sub.ySb.sub.z semiconductor layer.
16. The photovoltaic cell according to claim 5, wherein said first
cell comprises an n-type InGaSb semiconductor layer and said third
cell comprises a p-type InGaSb semiconductor layer.
17. The photovoltaic cell according to claim 5, wherein said first
cell comprises an InGaAs semiconductor layer; said second cell
comprises one or more of an InGaAs semiconductor layer, an InP
semiconductor layer, and an InGaP semiconductor layer; and said
third cell comprises one or more of an InP semiconductor layer, a
GaP semiconductor layer, an AlInP semiconductor layer, and an
InGaSb semiconductor layer.
18. The photovoltaic cell according to claim 17, wherein (i) said
first tunnel comprises a p.sup.++-type GaAs or a p.sup.++-type
AlGaAs semiconductor layer and an n.sup.++-type GaAs or
n.sup.++-type InGaAs semiconductor layer; (ii) said second tunnel
comprises a p.sup.++-type GaAs or a p.sup.++-type AlGaAs
semiconductor layer and an n.sup.+-type GaAs or a n.sup.++-type
InGaP semiconductor layer; or (iii) both.
19. The photovoltaic cell according to claim 5, wherein said second
cell comprises an InGaAs semiconductor layer and an InGaP
semiconductor layer; and said third cell comprises an AlInP
semiconductor layer and an InP semiconductor layer, a GaP
semiconductor layer, or both.
20. A system for harvesting solar energy, comprising an
electromechanical device in electrical communication with at least
one photovoltaic cell according to claim 1.
Description
CROSS REFERENCE TO RELATED APPLICATIONS
[0001] This application claims priority to U.S. Provisional
Application No. 61/219,926, entitled "High Efficiency Photovoltaic
Cell for Solar Energy Harvesting," filed Jun. 24, 2009, the
entirety of which is incorporated herein by reference.
FIELD OF THE INVENTION
[0002] The invention is drawn to a high efficiency photovoltaic
cell for solar energy harvesting, in particular a high efficiency
photovoltaic cell that includes indium gallium antimonide.
BACKGROUND OF THE INVENTION
[0003] Sunlight is the most abundant renewable energy source
available on Earth, supplying over 1.5.times.10.sup.22J (15,000
Exajoules) of energy to the Earth's surface daily. This amount of
energy is 10,000 times greater than the 1.3EJ of energy consumed
daily by the Earth's population. However, the capital costs
involved with harvesting solar energy make supplying energy to the
electrical grid using photovoltaic ("PV") generation unfavorable
compared to existing standard technology, e.g., coal, nuclear, etc.
Thus, substantial improvements are necessary to justify a shift
from existing power generation technologies to
photovoltaic-generated energy.
[0004] The main challenge in the photovoltaic industry is making
solar cells more cost effective. Thus, it is desirable to produce
less expensive cells with higher efficiencies. To date, the
National Renewable Energy Lab (NREL) is believed to have achieved a
record efficiency of 40.7% (AM1.5D, low AOD, 240 suns, 25.degree.
C.) for metamorphic or lattice mismatched and 40.1% (AM1.5D, low
AOD, 135 suns, 25.degree. C.) for lattice matched three-junction
photovoltaic cells such as GaInP/GaInAs/Ge cells. However, this is
well below the desired efficiency of 60% or higher believed
necessary to make PV technology a feasible substitute for existing
power generation technologies, so additional improvements are
necessary.
SUMMARY OF THE INVENTION
[0005] In one embodiment, the invention is drawn to a photovoltaic
cell including a rear contact and a first cell, having a first
band-gap energy, supported by the rear contact layer. The first
cell includes In.sub.xGa.sub.ySb.sub.z, where x+y+z=1 and z ranges
from 0.00001 to 0.025.
[0006] The photovoltaic cell can also include a second cell, having
a second band-gap energy, and a first tunnel disposed between the
first cell and the second cell. The second cell can be supported by
the first cell. The first band-gap energy can be less than the
second band-gap energy. The first cell can include both an
n.sup.+-doped In.sub.xGa.sub.ySb.sub.z semiconductor layer and a
p-doped In.sub.xGa.sub.ySb.sub.z semiconductor layer.
[0007] The photovoltaic cell can also include a third cell, having
a third band-gap energy, and a second tunnel disposed between the
second cell and the third cell. The third cell can be over the
second cell and the second band-gap energy can be less than the
third band-gap energy.
[0008] The In.sub.xGa.sub.ySb.sub.z semiconductor layer can have
the following values for x, y and z: [0009] x ranges from 0.23 to
0.50, [0010] y ranges from 0.50 to 0.77, and [0011] z ranges from
0.00001 to 0.025.
[0012] The third cell can include one or more of InP, GaP, AlInP
and InGaSb, the second cell can include one or more of InGaAs, InP
and InGaP, or both. The first tunnel can include a p.sup.++-type
GaAs or a p.sup.++-type AlGaAs semiconductor layer and an
n.sup.++-type GaAs or n.sup.++-type InGaAs semiconductor layer; the
second tunnel can include a p.sup.++-type GaAs or a p.sup.++-type
AlGaAs semiconductor layer and an n.sup.+-type GaAs or a
n.sup.++-type InGaP semiconductor layer; or both.
[0013] In another embodiment, the invention is drawn to a system
for harvesting solar energy. The system can include an
electromechanical device in electrical communication with at least
one photovoltaic cell described herein.
[0014] These and other embodiments are described in more detail
below.
BRIEF DESCRIPTION OF THE DRAWINGS
[0015] A fuller understanding of the present invention and the
features and benefits thereof will be obtained upon review of the
following detailed description together with the accompanying
drawings, in which:
[0016] FIGS. 1A and 1B are cross-sectional views of single-cell
photovoltaic cells according to an embodiment of the invention.
[0017] FIG. 2 is a cross-sectional view of a multi-junction
InP/InGaAs/InGaSb photovoltaic cell according to an embodiment of
the invention.
[0018] FIG. 3 is a cross-sectional view of a multi-junction
InP/InGaAs/InGaSb photovoltaic cell according to an embodiment of
the invention.
[0019] FIG. 4 is an electrical equivalent diagram representing a
photovoltaic cell having three cells and two tunnel junctions.
[0020] FIG. 5 is a cross-sectional view of a multi-junction
InP/InGaAs/InGaSb photovoltaic cell according to an embodiment of
the invention.
[0021] FIG. 6 is a cross-sectional view of a multi-junction
InP/InGaAs/InGaSb photovoltaic cell according to an embodiment of
the invention.
[0022] FIG. 7 is a cross-sectional view of a multi-junction
InP/InGaAs/InGaSb photovoltaic cell according to an embodiment of
the invention.
[0023] FIG. 8 is a cross-sectional view of a multi-junction
GaP/InGaAs/InGaSb photovoltaic cell according to an embodiment of
the invention.
[0024] FIG. 9 is a cross-sectional view of a multi-junction
GaP/InGaAs/InGaSb photovoltaic cell according to an embodiment of
the invention.
[0025] FIG. 10 is a schematic of a solar energy harvesting system
including an electromechanical device connected to the
multi-junction photovoltaic cell of FIG. 3.
[0026] FIG. 11 is a cross-sectional view of a multi-junction
GaP/InGaAs/InGaSb photovoltaic cell used to generate model
electromagnetic radiation absorption data.
[0027] FIG. 12 is a chart showing reflection, transmission and
absorption of 45.degree. incident electromagnetic radiation for a
GaP/InGaAs/InGaSb photovoltaic cell.
[0028] FIG. 13 is a chart comparing the data from FIG. 12 with
reflection, transmission and absorption of 45.degree. incident
electromagnetic radiation for a single-junction crystalline Si
photovoltaic cell.
[0029] FIG. 14 is a chart comparing the data from FIG. 12 with
reflection, transmission and absorption of 45.degree. incident
electromagnetic radiation for a double-junction AlGaAs/Si
photovoltaic cell.
[0030] FIG. 15 is a chart comparing the data from FIG. 12 with
reflection, transmission and absorption of 45.degree. incident
electromagnetic radiation for a double-junction InP/InGaAs
photovoltaic cell.
[0031] FIG. 16 is a chart comparing the data from FIG. 12 with
reflection, transmission and absorption of 45.degree. incident
electromagnetic radiation for a triple-junction AlGaAs/GaAs/InGaAs
photovoltaic cell.
[0032] FIG. 17 is a chart showing reflection, transmission and
absorption of 45.degree. incident electromagnetic radiation for a
InP/InGaAs/InGaSb photovoltaic cell.
DETAILED DESCRIPTION
[0033] Photovoltaic cells having improved absorption efficiency of
electromagnetic radiation over existing solar cells are described
herein. As shown in the accompanying figures, the photovoltaic cell
12 can include a rear contact 13, a first cell 14 having a first
band-gap energy, a second cell 20 having a second band-gap energy
and a first tunnel 18. The first tunnel 18 can be disposed between
the first cell 14 and the second cell 20. A buffer layer 16 can be
disposed between the first tunnel 18 and the first cell 14; between
the second cell and the first tunnel 18; or both. The first cell 14
can be over the rear contact 13 and the second cell 20 can be over
the first cell 14. The first cell 14 can include
In.sub.xGa.sub.ySb.sub.z, where x+y+z=1 and z ranges from 0.0025 to
0.00001. An anti-reflective coating ("ARC") 26 can be over or
disposed on the upper portion of the photovoltaic cell 12. For
example, the ARC 26 can be the uppermost layer of the photovoltaic
cell 12. The ARC 26 can include one or more of MgO.sub.2+TiO.sub.2,
Indium-Tin Oxide+MgF.sub.2, ZnS+MgF.sub.2 and
TiO.sub.2+Al.sub.2O.sub.3.
[0034] As shown in FIGS. 1A and 1B, the photovoltaic cell 12 can be
a single cell device, where the first cell 14 includes
In.sub.xGa.sub.ySb.sub.z, where x+y+z=1 and z ranges from 0.0025 to
0.00001. The single cell embodiment can include an anti-reflective
coating 26 supported or disposed on the first cell 14 and the first
cell 14 can be supported or disposed on the rear contact 13. The
rear contact layer 13 described herein can be any conductive or
semiconductor material, such as a metal, alloy, ceramic, or cermet,
and can be in electrical communication with an electromechanical
device 30 for usage or storage of the electromagnetic radiation
harvested by the photovoltaic cell 12. The rear contact 13 can also
be in electrical communication with the first layer 14.
[0035] As shown in FIGS. 2-3 and 5-9, the photovoltaic cell 12 can
also include a third cell 24, having a third band-gap energy, and a
second tunnel 22. The second tunnel 22 can be disposed between the
second cell 20 and the third cell 24. The third cell 24 can be over
the second cell 20. Although not shown, a buffer layer 16 can be
disposed between the second cell 20 and the second tunnel 22;
between the second tunnel 22 and the third cell 24; or both. Each
of the layers, cells and tunnels included in the photovoltaic cell
can be in electrical communication with one another.
[0036] As used herein, the terms "tunnel," "junction," and "tunnel
junction" are used interchangeably to describe heavily doped
p.sup.++-n.sup.++ junctions between cells. Tunnel junctions are
used to make electrical, optical and/or mechanical connections
between cells, electrochemical devices or both. Tunnels can be
formed of GaAs, AlGaAs, InGaP and/or InGaAs semiconductor layers or
other semiconductor layers.
[0037] As used herein, heavily doped layers are designated as
p.sup.++ or n.sup.++ layers and have doping levels of at least
10.sup.19 atoms/cm.sup.3 and less than 10.sup.24 atoms/cm.sup.3.
Other doping levels of interest include those designated as p,
p.sup.+, n or n.sup.+ layers and have doping levels ranging from
10.sup.16 to less than 10.sup.19 atoms/cm.sup.3. Layers with
n.sup.+ or p.sup.+ doping levels can range from 10.sup.16 to
greater than 10.sup.19 atoms/cm.sup.3; however, n.sup.+ or p.sup.+
layers generally have doping levels ranging from 10.sup.18 to less
than 10.sup.19 atoms/cm.sup.3. Layers with n or p doping levels
generally have doping levels ranging from 10.sup.16 to less than
10.sup.18 atoms/cm.sup.3. Lightly doped layers are indicated as
p.sup.- or p.sup.- layers and have doping levels of less than
10.sup.16 atoms/cm.sup.3. Exemplary p doping elements for use
herein include, but are not limited to, Zn, Be, Mg, Cd, Si, C and
Ge. Exemplary n doping elements for use herein include, but are not
limited to, Si, S, Se, Te, Sn, C and Ge.
[0038] As used herein, the terms "over" and "supported on" are used
to describe the relative position of two layers where one layer is
above or supported by the other in a multilayer stacked composite.
As used herein, the phrase "disposed on" is used to describe the
relative position of two layers where one layer is over a second
layer and in direct contact with the second layer. It is intended
that "over" encompasses "disposed on." Thus, where a first layer is
over a second layer, it is intended to cover embodiments where a
first layer is disposed on second layer. For example, in a three
layer structure where a tunnel is disposed between a first (bottom)
layer and a second (top) layer, the second layer is over, but not
disposed on, the first layer. However, the second layer can be
described as over the tunnel or disposed on the tunnel.
[0039] As used herein, the term "cell," e.g., "first cell," "second
cell," etc., is used to describe one or more semiconductor layers
for absorbing electromagnetic radiation having a targeted band-gap
energy. Cells can include or be bound above and below by an
antireflective coating, a tunnel junction, a window layer, a
nucleation layer, a BSF layer, a passivation layer, a confinement
layer, a buffer layer, a cladding layer, or some other functional
layer. The cells act to create electron-hole pairs when illuminated
by the sun.
[0040] As used herein, the phrase "photovoltaic cell" is used to
describe a layered composite including at least one cell and at
least one junction or rear contact for harvesting solar energy. A
photovoltaic cell will generally have an antireflective layer
applied as the uppermost layer, e.g., disposed on the uppermost
layer of the uppermost cell.
[0041] The second band-gap energy can be greater than the first
band-gap energy and the third band-gap energy can be greater than
the second band-gap energy. In some embodiments, the band-gap
energy of the third cell, e.g., comprising GaP or InP, can be
1.35eV, the band-gap energy of the second cell, e.g., comprising
InGaAs, can be 1.1eV and the band-gap energy of the first cell,
e.g., comprising InGaSb, can be in the range of 0.3 to 0.5eV.
[0042] The first band-gap energy can be 0.55 eV or less, or 0.50 eV
or less, or 0.45 eV or less, or 0.40 eV or less. The first band-gap
energy can be at least 0.2 eV, or at least 0.25 eV, or at least 0.3
eV, or at least 0.35 eV.
[0043] Any of the first, second, and third cells can include an
InGaSb semiconductor layer. The first cell can include at least one
InGaAs semiconductor layer and at least one
In.sub.xGa.sub.ySb.sub.z semiconductor layer. The first cell can
also include at least one n-doped or n.sup.+-doped semiconductor
layer and at least one p-doped or p.sup.+-doped semiconductor
layer. The InGaSb semiconductor layer can include
In.sub.xGa.sub.ySb.sub.z where:
[0044] x ranges from 0.23 to 0.50,
[0045] y ranges from 0.5 to 0.77,
[0046] z ranges from 0.00001 to 1, or 0.00001 to 0.01, or 0.00001
to 0.005, or 0.00001 to 0.00025, or 0.01 to 0.005, or 0.01 to
0.025, or 0.025 to 0.005, and
[0047] x+y+z=1.00.
[0048] The value of z can be at least 0.000025, at least 0.00005,
at least 0.0001, at least 0.005, or at least 0.01.
[0049] Although the notation used herein value shows x and y to two
significant figures and does not show the value of z, it should be
understood that z is a value ranging from 0.00001 to 0.001, and
that, although only show to two significant figures, the values of
x and y account for the value of z. Thus, where composition is
designated as In.sub.0.27Ga.sub.0.73Sb, if z=0.00025, then the true
value of x may be 0.26985 and the true value of y can be 0.72990.
Alternately, y can be 0.73000 and x can be 0.26975.
[0050] As shown in the Figures, the first cell can include
In.sub.xGa.sub.ySb.sub.z semiconductor layer(s) of one or more of
the p-type, p.sup.+-type, the n-type and the n.sup.+-type. The
first cell can also include InGaAs of one or more of the p-type,
p.sup.+-type, the n-type and the n.sup.+-type.
[0051] The second cell can include one or more layers of InGaAs,
InP and InGaP. The third cell can include one or more layers of
InP, GaP, AlInP and InGaSb. The InGaAs, InGaP, AlInP, InGaSb, InP
and/or GaP in the second or third cells can be semiconductor layers
of one or more of the p-type, the p.sup.+-type, the n-type and the
n.sup.+-type.
[0052] As shown in FIG. 2, the first and second tunnels can be
p.sup.+-n.sup.+ type junctions that include both a p.sup.+-type
semiconductor layer and an n.sup.+-type semiconductor layer
selected from GaAs, AlGaAs, InGaP and InGaAs. For each of the first
and second tunnels, the p.sup.+-type GaAs semiconductor layer can
be over the n.sup.+-type GaAs semiconductor layer or the
n.sup.+-type GaAs semiconductor layer can be over the p.sup.+-type
GaAs semiconductor layer. Similarly, any of the above tunnels can
rely on p.sup.++-n.sup.++ type junctions. Generally, the doping
levels of the tunnels will be higher that the doping levels of the
cells.
[0053] As shown in FIG. 2, the first cell can include an InGaSb
semiconductor layer. The first cell can include an n-type InGaSb
semiconductor layer and the third cell can include a p-type InGaSb
semiconductor layer. The first cell can include an n-type InGaSb
semiconductor layer but no p-type InGaSb semiconductor layer. The
third cell can include a p-type InGaSb semiconductor layer but no
n-type InGaSb semiconductor layer. The first cell can be free of
Ge, free of p-type InGaSb, or both. As used herein, "free of" can
mean that a cell or layer includes <1.0 atomic-% of a
composition based on the weight of the cell or layer, or <0.5
atomic-%, or less than 0.1 atomic-%, or less than 0.01 atomic-%, or
less than 0.001 atomic-%, or less than 0.0001 atomic-%, or less
than 0.00001 atomic-%.
[0054] As shown in FIG. 2, the photovoltaic cell can include an
antireflective coating ("ARC") on an upper surface. The ARC can be
disposed on a third cell, where the third cell includes an n-type
InP or GaP layer over a p-type InP or GaP layer over a p-type
InGaSb layer. The third layer can be over a second tunnel. The
second tunnel can be over a second cell, where the second cell
includes a p-type InP layer over an n-type InGaAs layer over a
p-type InGaAs layer over a p-type InP layer. The second cell can be
over a first tunnel, which can be over a first cell. The first cell
can include an n-type InGaAs layer over an n-type InGaSb layer over
a p-type GaAs rear contact. The first cell can be over a bottom
contact material. The first and second tunnels can include layers
of p.sup.+-type GaAs, n.sup.+-type GaAs, or both.
[0055] The photovoltaic cell can include three cells and two
junctions where the third, second and first cells comprise (i) InP
or GaP, (ii) InGaAs, and (iii) InGaSb, respectively. The third,
second and first cells can have band-gap energies in the range of
1.25-1.45eV, 1.00-1.20eV and 0.30-0.50eV, respectively. The third,
second and first cells can have band-gap energies of 1.35eV, 1.1eV
and 0.5eV, respectively.
[0056] Any and all of the layers described herein can be epitaxial
layers produced using accepted techniques. Exemplary techniques for
growing epitaxial layers include, but are not limited to,
vapor-phase epitaxy, liquid-phase epitaxy, solid-phase epitaxy,
molecular-beam epitaxy, chemical beam epitaxy, pulsed laser
deposition and metal organic chemical vapor deposition (MOCVD).
[0057] FIGS. 3 and 5-9 show exemplary embodiments of the
photovoltaic cells described herein, while FIG. 4 shows an
electrical circuit equivalent diagram showing the three junction
diodes and interconnecting upper and lower tunnel junctions of
these photovoltaic cells.
[0058] FIG. 3 shows a three cell configuration with tunnel
junctions disposed between each pair of adjacent cells. The
uppermost layer is an anti-reflective coating (ARC), which is
present to maximize the amount of impinging radiation that is
transmitted through to the underlying cells. The third (or "top")
cell includes an n.sup.+-type AlInP window layer disposed on an
n.sup.+-type InP emitter layer that is disposed on a p-type InP
base layer. Finally, the bottom layer of the third cell is a
p.sup.+-type InP back surface field ("BSF") layer. The BSF layer
functions like a filter and reflects electromagnetic radiation that
can be absorbed by the third cell, while transmitting
electromagnetic radiation that can be absorbed by subsequent cells,
e.g., the first and second cells. This causes the target wavelength
to pass through the relevant cell twice, thereby increasing the
absorption efficiency and limiting attenuation.
[0059] In FIG. 3, the third cell can be above or disposed on the
second (or "upper") tunnel junction. The second tunnel junction
includes a p.sup.++-type AlGaAs layer disposed on an n.sup.++-type
In.sub.0.5Ga.sub.0.5P layer. The second tunnel junction can be
above or disposed on the second cell.
[0060] In FIG. 3, the second (or "middle") cell can include an
n.sup.+-type In.sub.0.5Ga.sub.0.5P window layer over an
n.sup.+-type In.sub.0.1Ga.sub.0.9As emitter that is over a p-type
In.sub.0.1Ga.sub.0.9As base. The bottom layer of the second cell is
a p-type InGaAs BSF layer. The second cell can be over or disposed
on the first tunnel junction.
[0061] In FIG. 3, the first (or "lower") tunnel junction includes a
p.sup.++-type AlGaAs layer disposed on an n.sup.++-type
In.sub.0.5Ga.sub.0.5As layer. The first tunnel junction can be over
or disposed on a buffer layer of n-type In.sub.0.5Ga.sub.0.5As. The
buffer layer can be over or disposed on the first cell.
[0062] In FIG. 3, the first (or "bottom") cell can include an
n.sup.+ doped window and nucleation layer over an n.sup.+-type
In.sub.0.5Ga.sub.0.5Sb emitter that is over a p-type
In.sub.0.5Ga.sub.0.5Sb base. The base can also be the rear contact.
Finally, the photovoltaic cell can be completed with a rear
electrical contact.
[0063] The window layer is a high band-gap material selected for
transparency of light. Exemplary window layers can have a
composition of Al.sub.0.5In.sub.0.5P.sub.z, where z can have any of
z-range values disclosed herein, including ranging from 0.025 to
0.00001. The window layer is selected such that almost all incident
light is transmitted to the lower layers of the cell and to reduce
surface recombination of electron-hole pairs, cell series
resistance and dark current. Nucleation helps with surface
passivation.
[0064] In FIG. 3, Zn was used for p-doping, Si was used for
n-doping, and the doping levels were as follows: [0065] n-doping
and p-doping refer to additions of 1.5.times.10.sup.17
atoms/cm.sup.3, except in the buffer layer, where they referred to
2.times.10.sup.17 atoms/cm.sup.3; [0066] n.sup.+-doping and
p.sup.+-doping referred to 2.times.10.sup.18 atoms/cm.sup.3; and
[0067] n.sup.++-doping and p.sup.++-doping referred to
2.times.10.sup.19 atoms/cm.sup.3.
[0068] As used herein, semiconductor layer descriptions that do not
include subscripts are intended to include all possible positive
ratios of the elements included in the description. Thus, a general
reference to ABC semiconductor layer is intended to refer to
A.sub.xB.sub.yC.sub.z where x+y+z=1 and x, y and z are positive
decimal fractions less than 1. A reference to ABC (rel.) indicates
that the actual A:B:C ratio is 1:1:1, and ABC (rel.) is intended to
be encompassed by all references to an ABC semiconductor layer.
[0069] FIG. 5 is identical to FIG. 3, with the exception that the
atomic percentages of some of the layers are different. In
particular, in FIG. 5 the InGaAs in the second cell emitter and
base layers is In.sub.0.23Ga.sub.0.77As and the InGaSb in the first
cell emitter and base layers is In.sub.0.23Ga.sub.0.77Sb.
[0070] FIG. 6 is identical to FIG. 3, with the exception that the
buffer layer is over or disposed on the first tunnel junction
instead of the first tunnel junction being over or disposed on the
buffer layer. In addition, the buffer layer is a step graded buffer
layer. Any of the buffer layers described herein can be step graded
buffer layers. Step graded buffer layers can be used in lattice
mismatched or metamorphic (MM) solar cells to release the strain
and misfit dislocations between the lattice constant of a
particular layer, e.g., the rear contact, on which the buffer layer
is disposed relative to that of a layer above or disposed on the
buffer layer.
[0071] FIG. 7 is identical to FIG. 3, with the exception of the
compositions of a few layers of the photovoltaic cell. In FIG. 7,
the bottom layer of the second tunnel junction and the window layer
of the second cell are InGaP. In addition, the bottom layer of the
first tunnel junction and the buffer layer are InGaAs. Finally, the
photovoltaic cell 12 includes a separate substrate 15 including
GaAs. The first cell 14 is over or disposed on the GaAs substrate
15, which is over or disposed on the rear contact 13. FIGS. 3 and
5-9 demonstrates that the substrate 15 can either be a separate
layer having a composition different from the base layer of the
first cell 14 (as in FIG. 7), or the active base layer of the first
cell 14 can also serve as the substrate (as in FIGS. 3, 5, 6, 8 and
9).
[0072] FIG. 8 is identical to FIG. 3, with the exception that the
third cell is based on GaP rather than InP. In particular, the
emitter, base and BSF layers of the third cell are GaP.
[0073] Finally, FIG. 9 is identical to FIG. 8, with the exception
that the atomic percentages of some of the layers are different. In
particular, the InGaSb in the first cell emitter and base layers is
In.sub.0.23Ga.sub.0.77Sb.
[0074] As shown in FIG. 10, the invention also includes a system 10
for harvesting solar energy, comprising at least one of the
photovoltaic cells 12 described above in electrical communication
with an electromechanical device 30. The electrical connections can
be made using electrically conducting wires 28 running between the
electromechanical device 30 and at least one of the rear contact 13
and the tunnel junctions 18, 22, independently. Unexpectedly, the
combination of the layers described above enables improved
absorption of solar radiation across the solar spectrum range for
delivering higher efficiency energy harvesting.
[0075] As used herein, the term "electromechanical device" is used
to describe both electromechanical energy consuming devices and
electromechanical storage devices. Exemplary electromechanical
energy consuming devices include, but are not limited to,
electrical motors, consumer electronics (computers, televisions,
calculators, cell phones, etc.), actuators, and residential and
commercial power supplies (e.g., internal wiring supplying energy
to outlets). Exemplary electromechanical energy storage devices
include, but are not limited to, batteries and capacitors.
EXAMPLES
[0076] The following examples are based on comparisons of modeled
results for efficiency of a photovoltaic cell according to the
embodiments disclosed herein with the modeled efficiency of a
variety of other known photovoltaic cells.
GaP/InGaAs/InGaSb Cell Configuration
[0077] The solar cell design in FIG. 11 is a homogeneous tandem
design GaP/InGaAs/InGaSb multijunction solar cell
("GaP/InGaAs/InGaSb Cell"). The cell includes three cells with a
tunnel disposed between each pair of adjacent cells. The third cell
includes a GaP semiconductor material having a band-gap energy of
2.26 eV, the second cell includes an InGaAs semiconductor having
band-gap energy of 1.1 eV, and the first cell includes an InGaSb
semiconductor with a band-gap energy or 0.3 -0.5 eV depending upon
the doping concentration.
[0078] As demonstrated by the results to follow, the GaP layer has
substantially increased the photon absorption efficiency in the 400
nm-598 nm wavelength range, while the InGaSb layer has
substantially increased the photon absorption efficiency in the
wavelength range from 598 nm and higher, e.g., 800 nm.
[0079] Bright light, e.g., intense sunlight, can provide irradiance
levels of 1 kW/m.sup.2. Of this energy, 527 Watts is infrared (IR)
radiation, 445 Watts visible light and 32 Watts UV radiation. The
InGaSb material disclosed herein helps enhance absorption of light
in the infrared region compared with state of art solar cells. The
higher the photon absorption efficiency, the more electron-hole
pairs are created in the cell, which promotes to higher current
generation and overall efficiency of the solar cell.
[0080] As shown in FIG. 11, an efficient back surface field (BSF)
layer is introduced at the bottom of each of the three cells. The
primary importance of the BSF layer is to confine the
photo-generated minority carriers so that they can be efficiently
collected by the tunnel junctions. The BSF layer can provide this
confining function without increasing the series resistance of the
PV cell. An AlGaAs/GaAs Bragg-Reflector is also included toward the
bottom of the photovoltaic cell. The Bragg-Reflector is disposed on
a buffer layer that is disposed on the rear contact, a GaAs rear
contact in this case. The thickness of the BSF layer and the
Bragg-Reflector should be a quarter wavelength for the wavelength
being absorbed by the respective cell.
[0081] The multilayer dielectric stacks including the BSF layers
selectively reflect a part of the unabsorbed photons providing a
second pass through the photoactive region, hence increases the
photocurrent and overall efficiency of the PV cell. Using multiple
layers composed of two materials with different refractive indices
nearly 100% reflectance can be obtained over a restricted
wavelength of the spectrum.
[0082] The BSF layer can be used to enhance localization of the
photo-generated minority carriers so that these carriers can be
efficiently collected by p/n junctions. The Bragg-reflector
selectively reflects a portion of the unabsorbed photons providing
a second pass through the photo active region of the cell, thereby
increasing the photo current collected by the p/n junctions.
[0083] The buffer layer disposed on the GaAs rear contact is
included to deal with the lattice mismatch between rear contact and
the epitaxial material supported thereon. The third cell in the
photovoltaic cell design of FIG. 11 is covered by a thin layer of
antireflective coating (ARC) material to reduce the reflection of
sunlight impinging on the third cell. The ARC layer is interposed
between the photovoltaic cell material and the surrounding
environment (air) and is designed to act as a quarter wavelength
impedance matching element between the characteristic impedance of
the environment and the photovoltaic material.
[0084] The tunnel junctions are made up of heavily doped
p.sup.+/n.sup.+ GaAs material. The doping density of these layers
is modeled as being .gtoreq.10.sup.19/cm.sup.3, e.g.,
2.0.times.10.sup.19 atoms/cm.sup.3. They are used to make better
electrical, optical and mechanical connections between different
cell layers. The PV cell is developed over a p-type or n-type GaAs
rear contact material. In FIG. 11, the n-doping material is Si and
the p-doping material is Zn. Doping levels were as follows: [0085]
BSF layers were doped with Zn at a level of 2.times.10.sup.18
atoms/cm.sup.3; [0086] Tunnel layers were doped at a level of
2.times.10.sup.19 atoms/cm.sup.3; [0087] Cell layers designated as
n or p were doped as a level of 2.times.10.sup.18 atoms/cm.sup.3;
[0088] Base layers were doped at a level of 1.5.times.10.sup.17
atoms/cm.sup.3; and [0089] Buffer layers were doped at a level of
2.times.10.sup.17 atoms/cm.sup.3.
[0090] The three-junction photovoltaic solar cell of FIG. 11
includes GaP/InGaAs/InGaSb semiconductor materials having band-gaps
of 1.35 eV, 1.1 eV, and 0.3-0.5 eV, respectively, and is compared
to the solar absorption efficiencies of some existing solar cells.
The solar cell can be formed in both lattice matched and lattice
mismatched configurations as well as mechanically stacking the
layers. As demonstrated by the model results, the GaP/InGaAs/InGaSb
cell exhibited extremely high efficiencies throughout the entire
light spectrum for light incident at 45.degree..
GaP/InGaAs/InGaSb Cell Absorption Data
[0091] FIG. 12 and Table 1 illustrate the modeled absorption of the
photovoltaic cell of FIG. 11 at 45.degree. incidence. In FIG. 12,
the top line represents absorption and lines in the middle and
bottom position at the far left of FIG. 12 represent reflection and
transmission, respectively. The data demonstrate that the
GaP/InGaAs/InGaSb cell has very good absorption throughout the
solar spectrum. Table 1 lists the absorption efficiency of the
triple-junction solar cell for a variety of wavelengths.
TABLE-US-00001 TABLE 1 Absorption Efficiency of GaP/InGaAs/InGaSb
solar cell Wavelength Absorption 400 nm 77.2% 500 nm 92.3% 600 nm
.sup. 82% 700 nm 63.1% 800 nm .sup. 68%
GaP/InGaAs/InGaSb Cell Comparison with Single-Junction
Crystalline-Si Cell
[0092] FIG. 13 illustrates the modeled performance of a single
junction crystalline-Si solar cell compared with the
GaP/InGaAs/InGaSb cell. The bold lines represent the performance of
the single-junction crystalline-Si solar cell, while the light
lines the performance of the triple-junction GaP/InGaAs/InGaSb
cell. Thus, the triple-junction GaP/InGaAs/InGaSb cell performs
better than the most popular single junction cell (c-Si) throughout
the solar spectrum. Table 2 provides the absorption data points for
specific wavelengths from FIG. 13.
TABLE-US-00002 TABLE 2 Comparison of Absorption Efficiency between
GaP/InGaAs/InGaSb solar cell and crystalline Si solar cell
Absorption of Absorption of Wavelength GaP/InGaAs/InGaSb c-Si 400
nm 77.2% .sup. 45% 500 nm 92.3% 11.6% 600 nm .sup. 82% 4.73% 700 nm
63.1% 3.34% 800 nm .sup. 68% 1.29%
GaP/InGaAs/InGaSb Cell Comparison with AlGaAs/Si Monolithic
Two-Junction Cell
[0093] An AlGaAs/Si monolithic two-junction cell is a prior art
cell with an attractive combination of materials for obtaining
high-efficiency multijunction cells. In addition to an ideal
combination of band-gaps the Si rear contact and cell technologies
are well developed and inexpensive. Umeno et al. (1998) fabricated
a solar cell comprised of Al.sub.0.15Ga.sub.0.85As/Si two-junction
solar cell by MOCVD process and reported an efficiency of 21.2%
under AMO. FIG. 14 shows a modeled comparison of the AlGaAs/Si
two-junction cell with the GaP/InGaAs/InGaSb triple-junction cell
disclosed herein. The bold lines illustrate the absorption
efficiency of the two-junction solar cell and the light lines for
the GaP/InGaAs/InGaSb cell. In addition, Table 3 shows the relative
improvements in absorption efficiency for the GaP/InGaAs/InGaSb
cell over the comparative cell.
TABLE-US-00003 TABLE 3 Comparison of Absorption Efficiency between
Ga/InGaAs/InGaSb cell and AlGaAs/Si double-junction solar cell
Absorption of Absorption of Wavelength Ga/InGaAs/InGaSb AlGaAs/Si
400 nm 77.2% 65.4% 500 nm 92.3% 52.2% 600 nm .sup. 82% 20.3% 700 nm
63.1% 18.6% 800 nm .sup. 68% 1.18%
GaP/InGaAs/InGaSb Cell Comparison with InP/InGaAs Two-Junction
Cell
[0094] The combination of InP with a band-gap energy of 1.35 eV and
In.sub.0.53Ga.sub.0.47As with a band-gap energy of 0.75 eV is a
lattice-matched system having a theoretical conversion efficiency
of 37% under 500 Suns AM1.5G and 33% under 500 Suns AMO at
80.degree. C. (Wanlass et. al., 1989). The InP/InGaAs
double-junction cell is considered very high promising in space
applications because InP is more radiation resistant than any other
semiconductor materials (Yamaguchi et. al. 1984). An efficiency of
31.8% has been achieved using a metal interconnected
three-terminal, monolithic two-junction InP/InGaAs cell under 50
Suns AM1.5 at 25.degree. C. (Wanlass et. al., 1991). In FIG. 15,
the bold lines represent the properties of the InP/InGaAs
double-junction cell, while the light lines represent the
properties of the GaP/InGaAs/InGaSb three-junction cell disclosed
herein. The model data in FIG. 15 and Table 4 shows that the
GaP/InGaAs/InGaSb exhibits absorption that is superior to the
InP/InGaAs two-junction cell.
TABLE-US-00004 TABLE 4 Comparison of Absorption Efficiency between
GaP/InGaAs/InGaSb cell and InP/InGaAs double-junction solar cell
Absorption of Absorption of Wavelength Ga/InGaAs/InGaSb InP/InGaAs
400 nm 77.2% 67.4% 500 nm 92.3% 78.8% 600 nm .sup. 82% 61.9% 700 nm
63.1% 63.1% 800 nm .sup. 68% 47.9
GaP/InGaAs/InGaSb Cell Comparison with AlGaAs/GaAs/InGaAs
Three-Junction Cell
[0095] A comparative three-junction solar cell with 1.93 eV AlGaAs,
1.43 eV GaAs and 0.95 eV InGaAs(P) has predicted efficiencies of
37.5% at 1 Sun AM1.5 and 46% at 400 Suns AM1.5 (MacMillan et al.,
1989). This two-terminal three-junction solar cell with an AMO
efficiency of 25.2% has been reported (Chung et. al., 1991). The
AlGaAs/GaAs/InGaAs cell was mechanically stacked having AlGaAs/GaAs
metal-interconnection and InGaAsP as bottom cell. More recently a
mechanically stacked three-junction cell consisting of
monolithically grown InGaP/GaAs two-junction cell and InGaAs bottom
cell has reached 33.3% at 1 Sun AM1.5 (Takamoto et. al., 1997).
FIG. 16 and Table 5 show comparative absorption efficiency values
for the AlGaAs/GaAs/InGaAs triple-junction solar cell with the
GaP/InGaAs/InGaSb cell disclosed herein. The absorption date
demonstrates that the GaP/InGaAs/InGaSb solar cell disclosed herein
outperforms the comparative AlGaAs/GaAs/InGaAs cell. In FIG. 16,
the bold lines are for the AlGaAs/GaAs/InGaAs solar cell and the
light ones for the GaP/InGaAs/InGaSb design.
TABLE-US-00005 TABLE 5 Comparison of Absorption Efficiency between
GaP/InGaAs/InGaSb cell and triple-junction solar cell made up of
AlGaAs/GaAs/InGaAs Absorption of Absorption of Wavelength
GaP/InGaAs/InGaSb AlGaAs/GaAs/lnGaAs 400 nm 77.2% 65.8% 500 nm
92.3% 77.8% 600 nm .sup. 82% 71.3% 700 nm 63.1% 55.3% 800 nm .sup.
68% 34.5%
InP/InGaAs/InGaSb Cell Configuration
[0096] Data modeling the absorption data for the InP/InGaAs/InGaSb
cell configuration shown in FIG. 2 was also generated. The doping
levels were held constant for equivalent layers in the two
configurations (i.e., FIG. 2 and FIG. 11). The primary difference
between the two was the substitution of InP for GaP in the third
cell of the triple-junction cells disclosed herein. The absorption
results are summarized in FIG. 17 and Table 6. Again, these
absorption results are superior to the modeled absorption results
discussed above.
TABLE-US-00006 TABLE 6 Comparison of Absorption Efficiency between
InP/InGaAs/InGaSb cell and GaP/InGaAs/InGaSb cell Absorption of
Absorption of Wavelength InP/InGaAs/InGaSb GaP/InGaAs/InGaSb 400 nm
69% 77.2% 500 nm 81% 92.3% 600 nm 80.2%.sup. .sup. 82% 700 nm 71%
63.1% 800 nm 73% .sup. 68%
[0097] In summary, the model data demonstrates that, compared with
existing technology, the GaP/InGaAs/InGaSb triple-junction solar
cell disclosed herein exhibits far superior absorption efficiency
across the electromagnetic spectrum. In particular, the data
demonstrates that the inclusion of trace amounts of Sb (i.e.,
0.00001-0.00025 atomic-%) in an InGaSb semiconductor layer
substantially improve absorption of electromagnetic radiation in
the range from 598 to 800 nm. In addition, the data demonstrates
that, compared with InP, GaP provides improved absorption of
electromagnetic radiation in the range from 400 to 598 nm.
[0098] It is to be understood that while the invention in has been
described in conjunction with the preferred specific embodiments
thereof, that the foregoing description as well as the preceding
examples are intended to illustrate and not limit the scope of the
invention. Other aspects, advantages and modifications within the
scope of the invention will be apparent to those skilled in the art
to which the invention pertains.
* * * * *