U.S. patent application number 13/933956 was filed with the patent office on 2014-01-16 for carpet comprising a propylene-based elastomer and methods of making the same.
The applicant listed for this patent is ExxonMobil Chemical Patents Inc.. Invention is credited to Ernest R. Anderson, Bruce R. Lundmark, Charles P. Siskovich, Willam G. Steve, Felix M. Zacarias.
Application Number | 20140017439 13/933956 |
Document ID | / |
Family ID | 48790672 |
Filed Date | 2014-01-16 |
United States Patent
Application |
20140017439 |
Kind Code |
A1 |
Siskovich; Charles P. ; et
al. |
January 16, 2014 |
Carpet Comprising A Propylene-Based Elastomer and Methods of Making
the Same
Abstract
Provided are carpets comprising at least one propylene-based
elastomer. The presence of the propylene-based elastomer provides
the carpet with improved properties, including good tuft bind
strength and tuft lock strength, and reliable construction.
Inventors: |
Siskovich; Charles P.;
(Massillon, OH) ; Anderson; Ernest R.;
(Garretsville, OH) ; Lundmark; Bruce R.; (Akron,
OH) ; Zacarias; Felix M.; (Akron, OH) ; Steve;
Willam G.; (Rocky Face, GA) |
|
Applicant: |
Name |
City |
State |
Country |
Type |
ExxonMobil Chemical Patents Inc. |
Baytown |
TX |
US |
|
|
Family ID: |
48790672 |
Appl. No.: |
13/933956 |
Filed: |
July 2, 2013 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
|
|
61669842 |
Jul 10, 2012 |
|
|
|
Current U.S.
Class: |
428/95 ;
156/72 |
Current CPC
Class: |
D06N 7/0076 20130101;
D06N 2209/067 20130101; D04H 11/00 20130101; D06N 2203/042
20130101; Y10T 428/23979 20150401 |
Class at
Publication: |
428/95 ;
156/72 |
International
Class: |
D06N 7/00 20060101
D06N007/00; D04H 11/00 20060101 D04H011/00 |
Claims
1. A carpet comprising: (a) a primary backing layer having a face
side and a back side; (b) a plurality of fibers attached to the
primary backing layer and extending from both the face side and the
back side of the primary backing layer; and (c) a second layer
attached to the back side of the primary backing layer, comprising
at least one propylene-based elastomer comprising at least about 60
wt% propylene-derived units and about 5 to about 25 wt%
ethylene-derived units, by weight of the propylene-based elastomer,
wherein the propylene-based elastomer has a heat of fusion of less
than about 75 J/g, wherein the second layer substantially locks in
the plurality of fibers extending from the back side of the primary
backing layer.
2. The carpet of claim 1, wherein the carpet comprises no more than
150 g/m.sup.2 of latex.
3. The carpet of claim 1, wherein the carpet comprises no more than
100 g/m.sup.2 of latex.
4. The carpet of claim 1, wherein the carpet comprises no more than
50 g/m.sup.2 of latex.
5. The carpet of claim 1, wherein the carpet comprises no more than
20 g/m.sup.2 of latex.
6. The carpet of claim 1, wherein the carpet comprises 0 g/m.sup.2
of latex.
7. The carpet of claim 1, wherein the fibers comprise at least one
of polypropylene, nylon, wool, cotton, acrylic, polyester, and
polyethylene terephthalate.
8. The carpet of claim 1, wherein the primary backing layer
comprises at least one thermoplastic polyolefin.
9. The carpet of claim 1, wherein the second layer further
comprises a filler.
10. The carpet of claim 9, wherein the filler is a flame
retardant.
11. The carpet of claim 9, wherein the filler is aluminum
trihydrate or calcium carbonate.
12. The carpet of claim 1, further comprising a third layer
attached to the second layer opposite to the primary backing
layer.
13. The carpet of claim 12, wherein the third layer comprises at
least one thermoplastic polyolefin.
14. The carpet of claim 13, wherein the third layer further
comprises a filler.
15. The carpet of claim 12, wherein a reinforcement layer is
present between the second layer and the third layer.
16. The carpet of claim 15, wherein the reinforcement layer
comprises at least one of thermoplastic fabrics and fiberglass.
17. The carpet of claim 15, wherein a middle layer is present
between the second layer and the reinforcement layer.
18. The carpet of claim 17, wherein the middle layer comprises at
least one thermoplastic polyolefin.
19. A method for making a carpet comprising the steps of: (a)
providing a primary backing layer having a face side and a back
side, with a plurality of fibers attached to the primary backing
layer and extending from both the face side and the back side of
the primary backing layer; (b) applying a second layer to the back
side of the primary backing layer, wherein the layer comprises at
least one propylene-based elastomer comprising at least about 60
wt% propylene-derived units and about 5 to about 25 wt%
ethylene-derived units, by weight of the propylene-based elastomer,
wherein the propylene-based elastomer has a heat of fusion of less
than about 75 J/g; and (c) forming a carpet, wherein the second
layer substantially locks in the plurality of fibers extending from
the back side of the primary backing layer.
20. The method of claim 19, wherein in (b) the second layer is
applied to the back side of the primary backing layer by extrusion
coating or sheet lamination.
21. A carpet comprising: (a) a primary backing layer having a face
side and a back side, wherein the primary backing layer comprises
at least one thermoplastic polyolefin; (b) a plurality of fibers
tufted into the primary backing layer and extending from both the
face side and the back side of the primary backing layer; (c) a
second layer attached to the back side of the primary backing
layer, comprising at least one propylene-based elastomer, wherein
the propylene-based elastomer comprises at least about 60 wt %
propylene-derived units and about 5 to about 25 wt %
ethylene-derived units, by weight of the propylene-based elastomer,
and wherein the propylene-based elastomer has a heat of fusion of
less than about 75 J/g; (d) a third layer attached to the second
layer opposite to the primary backing layer, wherein the third
layer comprises at least one thermoplastic polyolefin; and (e) a
reinforcement layer between the second layer and the third layer,
wherein the reinforcement layer comprises at least one of
thermoplastic fabrics and fiberglass, wherein the second layer
substantially locks in the plurality of fibers extending from the
back side of the primary backing layer, and wherein the carpet
comprises 0 g/m.sup.2 of latex.
Description
CROSS REFERENCE TO RELATED APPLICATIONS
[0001] This application claims priority to U.S. Provisional
Application Ser. No. 61/669,842 filed Jul. 10, 2012, the disclosure
of which is incorporated herein by reference.
FIELD OF THE INVENTION
[0002] This invention relates to carpets comprising propylene-based
elastomers and methods of making the same.
BACKGROUND OF THE INVENTION
[0003] As illustrated in FIG. 1a, typical carpets may be laminated
structures which include face yarn (which is also known as a fiber
bundle), a primary backing layer having a face side and a back
side, a precoat layer, a thermoplastic laminate layer, a
reinforcement layer, and a thermoplastic cap layer. To form the
face side of the carpet, yarn is typically tufted through the
primary backing layer such that two ends are exposed at both sides
of the primary backing layer, either left looped or cut on the face
side. Generally, the primary backing layer is made of a woven or
non-woven material.
[0004] The precoat layer is typically applied to the back side of
the primary backing layer to affix the yarn to the primary backing
layer. The extent or tenacity to which the yarn is affixed is
referred to as tuft lock or tuft bind strength. Carpets with
sufficient tuft bind strength and tuft lock strength exhibit
reliable construction, and, as such, have long service lives. Also,
the precoat layer may substantially penetrate the yarn (fiber
bundle) exposed on the backside of the primary backing layer and
may substantially consolidate individual fibers within the
yarn.
[0005] Known precoat materials include latex, urethane, and vinyl
systems, with latex systems being most popular. Styrene butadiene
rubbers (SBR) and vinyl acetate ethylene (VAE) are the most common
polymers used for latex adhesive backing materials. Typically, the
latex backing system is heavily filled with an inorganic filler
such as calcium carbonate or aluminum trihydrate and includes other
ingredients such as antioxidants, antimicrobials, flame retardants,
smoke suppressants, wetting agents, and froth aids.
[0006] The thermoplastic laminate layer is typically made of a
filled thermoplastic polymer. The thermoplastic laminate layer is
applied to the backside of the carpet onto the precoat layer,
primarily to provide enhanced dimensional stability to the carpet
structure as well as to provide more surface area for the
application of direct glue-down adhesives. Thermoplastic compounds
such as polyolefins have been suggested as additional backing
materials for use in the thermoplastic laminate layer due in part
to their low cost, good moisture stability, and no-cure
requirements. Various methods are available for applying polyolefin
backing materials, including roll coating, hot melt application,
extrusion coating, and extruded film or sheet lamination. For
example, to overcome the viscosity and recrystallization
deficiencies of ordinary polyolefins and extrusion coating
difficulties, ordinary polyolefins with sufficient flexibility can
be applied between the primary backing and the thermoplastic cap
layer as the thermoplastic laminate layer by extrusion coating or
sheet lamination techniques to insure adequate yarn-to-backing
adhesion.
[0007] A reinforcement layer can also be added between the laminate
layer and the thermoplastic cap layer, to achieve enhanced
dimensional stability.
[0008] The combination of tufted yarn and a primary backing layer
without the application of a precoat layer is referred to in the
carpet industry as raw tufted carpet or greige goods. Greige goods
become finished tufted carpet with the application of a precoat
layer and optionally a thermoplastic laminate layer to the back
side of the primary backing layer. Finished tufted carpet can be
prepared as broad-loomed carpet in rolls typically six or 12 feet
(1.83 or 3.66 m) wide. Alternatively, carpets can be prepared as
carpet tiles, typically 18 inches (about 45.7 cm) square or 24
inches (about 61.0 cm) square in the United States and 50 cm square
elsewhere.
[0009] U.S. Pat. No. 7,741,397 describes a filled polymer
composition comprising (i) an ethylene/a-olefin interpolymer, and
(ii) a filler. The ethylene/a-olefin interpolymer is a block
copolymer. The filled polymer composition can be used in automotive
floorings, roofings, wire and cable coating applications.
[0010] U.S. Patent Publication Nos. 2007/0095453 and 2008/0280093
relate to carpets and method of making carpets. The carpet includes
(a) a primary backing which has a face and a back surface, (b) a
plurality of fibers attached to the primary backing and extending
from the face of the primary backing and exposed at the back
surface of the primary backing, (c) an adhesive backing, (d) an
optional secondary backing adjacent to the adhesive backing, and
(e) at least one homogeneously branched linear ethylene polymer.
The method includes extrusion coating at least one homogeneously
branched linear ethylene polymer onto the back surface of a primary
backing to provide an adhesive backing.
[0011] Although there are various systems known in the art of
carpet backings, there remains a need for a carpet backing system
which provides adequate tuft bind strength and tuft lock strength,
reliable construction and enhanced flexibility. Preferably such a
carpet backing system could be used to replace latex backing
systems. Applicants have found that the above desirable properties
can be surprisingly achieved by using at least one layer comprising
propylene-based elastomers. In some embodiments, a layer comprising
propylene-based elastomers can act as a substitute for both the
current precoat layer, mainly comprising latex, and the
thermoplastic laminate layer. This can be advantageous in cases
where the carpet surface becomes wet, as the absence of latex
avoids latex decomposition which can significantly decrease the
performance for the carpet. Furthermore, the layer comprising
propylene-based elastomers may be filled with fillers, which can
also lead to additional advantages such as improved flame retardant
properties and reduced cost for carpet application.
SUMMARY OF THE INVENTION
[0012] Provided are carpets comprising a propylene-based elastomer,
and methods of making the same. In accordance with one embodiment
of the present invention, a carpet comprises: (a) a primary backing
layer having a face side and a back side; (b) a plurality of fibers
attached to the primary backing layer and extending from both the
face side and the back side of the primary backing layer; and (c) a
second layer attached to the back side of the primary backing
layer, comprising at least one propylene-based elastomer comprising
at least about 60 wt % propylene-derived units and about 5 to about
25 wt % ethylene-derived units, by weight of the propylene-based
elastomer, wherein the propylene-based elastomer has a heat of
fusion of less than about 75 J/g, wherein the second layer
substantially locks in the plurality of fibers extending from the
back side of the primary backing layer.
[0013] In another embodiment, the present invention relates to a
method for making a carpet comprising the steps of: (a) providing a
primary backing layer having a face side and a back side, with a
plurality of fibers attached to the primary backing layer and
extending from both the face side and the back side of the primary
backing layer; (b) applying a second layer to the back side of the
primary backing layer, wherein the layer comprises at least one
propylene-based elastomer comprising at least about 60 wt %
propylene-derived units and about 5 to about 25 wt %
ethylene-derived units, by weight of the propylene-based elastomer,
wherein the propylene-based elastomer has a heat of fusion of less
than about 75 J/g; and (c) forming a carpet, wherein the second
layer substantially locks in the plurality of fibers extending from
the back side of the primary backing layer.
BRIEF DESCRIPTION OF THE DRAWINGS
[0014] FIG. 1a exemplifies a conventional laminated structure for a
tufted carpet tile.
[0015] FIG. 1b exemplifies an embodiment of the inventive laminated
structure for a tufted carpet tile.
[0016] FIG. 2 depicts the resulting appearances on the back and
front sides of Sample 1 and Sample 2 after a Velcro roller test. In
particular, FIGS. 2a and 2b illustrate the back and front,
respectively, of Sample 1 of the Examples after a Velcro roller
test. FIGS. 2c and 2d illustrate the back and front, respectively,
of Sample 2 of the Examples after a Velcro roller test.
DETAILED DESCRIPTION OF THE PRESENT INVENTION
[0017] Various specific embodiments, versions of the present
invention will now be described, including preferred embodiments
and definitions that are adopted herein. While the following
detailed description gives specific preferred embodiments, those
skilled in the art will appreciate that these embodiments are
exemplary only, and that the present invention can be practiced in
other ways. Any reference to the "invention" may refer to one or
more, but not necessarily all, of the present inventions defined by
the claims. The use of headings is for purposes of convenience only
and does not limit the scope of the present invention.
[0018] As used herein, a "polymer" may be used to refer to
homopolymers, copolymers, interpolymers, terpolymers, etc.
[0019] As used herein, when a polymer is referred to as comprising
a monomer, the monomer is present in the polymer in the polymerized
form of the monomer or in the derivative form of the monomer.
[0020] As used herein, when a polymer composition or blend is said
to comprise a certain percentage, wt %, of a monomer, that
percentage of monomer is based on the total amount of monomer units
of all the polymer components of the polymer composition or
blend.
[0021] As used herein, "elastomer" or "elastomeric composition"
refers to any polymer or composition of polymers (such as blends of
polymers) consistent with the ASTM D1566 definition. Elastomer
includes mixed blends of polymers such as melt mixing and/or
reactor blends of polymers. The terms may be used interchangeably
with the term "rubber(s)."
[0022] A "polyolefin" is a polymer comprising at least 50 wt % of
one or more olefin monomers. Preferably, a polyolefin comprises at
least 60 wt %, or at least 70 wt %, or at least is 80 w t%, or at
least 90 wt %, or at least 95 wt %, or 100 wt %, of one or more
olefin monomers.
[0023] Preferably, a polyolefin comprises 1-olefins, having carbon
numbers of 2 to 20, or 2 to 16, or 2 to 10, or 2 to 8, or 2 to
6.
[0024] As used herein, "primary backing" layer, "second" layer,
"third" layer, and "middle" layer are merely identifiers used for
convenience, and shall not be construed as limitation on individual
layers, their relative positions, or the laminated structure,
unless otherwise specified.
[0025] As used herein, when a layer is referred to as
"substantially" locking the plurality of fibers extending from the
back side of the primary backing layer in, it means that at least
about 90%, at least about 92%, at least about 94%, at least about
96%, or at least about 98% of the fibers are held in place after
being rolled over by a Velcro type tool for about 20 times in a
Velcro roller test. Preferably, no fuzzing is visible to the naked
eye.
[0026] As used herein, "carpet" also includes carpet tiles and
portions of a carpet.
[0027] The present invention relates to a carpet comprising a
propylene-based elastomer, and methods of making the same. In one
embodiment, a carpet comprises: (a) a primary backing layer having
a face side and a back side; (b) a plurality of fibers attached to
the primary backing layer and extending from both the face side and
the back side of the primary backing layer; and (c) a second layer
attached to the back side of the primary backing layer, comprising
at least one propylene-based elastomer comprising at least about 60
wt % propylene-derived units and about 5 to about 25 wt %
ethylene-derived units, by weight of the propylene-based elastomer,
wherein the propylene-based elastomer has a heat of fusion of less
than about 75 J/g, wherein the second layer substantially locks in
the plurality of fibers extending from the back side of the primary
backing layer.
Propylene-based elastomer
[0028] The carpets described herein comprise a propylene-based
elastomer. The propylene-based elastomer may be a copolymer of
propylene-derived units and units derived from at least one of
ethylene or a C.sub.4-10 alpha-olefin. The propylene-based
elastomer may contain at least about 60 wt % propylene-derived
units based on the weight of the propylene-based elastomer. The
propylene-based elastomer may have limited crystallinity due to
adjacent isotactic propylene units and a melting point as described
herein. The crystallinity and the melting point of the
propylene-based elastomer can be reduced compared to highly
isotactic polypropylene by the introduction of errors in the
insertion of propylene. The propylene-based elastomer is generally
devoid of any substantial intermolecular heterogeneity in tacticity
and comonomer composition, and also generally devoid of any
substantial heterogeneity in intramolecular composition
distribution.
[0029] The amount of propylene-derived units present in the
propylene-based elastomer may range from an upper limit of about 95
wt %, about 94 wt %, about 92 wt %, about 90 wt %, or about 85 wt
%, to a lower limit of about 60 wt %, about 65 wt %, about 70 wt %,
about 75 wt %, about 80 wt %, about 84 wt %, or about 85 wt % of
the propylene-based elastomer.
[0030] The units, or comonomers, derived from at least one of
ethylene or a C.sub.4-10 alpha-olefin may be present in an amount
of about 1 to about 35 wt %, or about 5 to about 35 wt %, or about
7 to about 32 wt %, or about 8 to about 25 wt %, or about 8 to
about 20 wt %, or about 8 to about 18 wt %, based on the weight of
the propylene-based elastomer.
[0031] In preferred embodiments, the comonomer is ethylene,
1-hexene, or 1-octene. In some embodiments, the propylene-based
elastomer comprises ethylene-derived units or consists essentially
of units derived from propylene and ethylene, i.e., the
propylene-based elastomer does not contain any other comonomer in
an amount other than that typically present as impurities in the
ethylene and/or propylene feedstreams used during polymerization,
or in an amount that would materially affect the heat of fusion,
melting point, crystallinity, or MI of the propylene-based
elastomer, or any other comonomer intentionally added to the
polymerization process. In such embodiments, the propylene-based
elastomer may comprise about 5 to about 25 wt %, or about 6 to
about 22 wt %, or about 7 to about 20 wt %, or about 8 to about 17
wt %, or about 9 to 16 wt % ethylene-derived units based on the
weight of the propylene-based elastomer.
[0032] The propylene-based elastomer may comprise more than one
comonomer. Preferred embodiments of a propylene-based elastomer
having more than one comonomer include propylene-ethylene-octene,
propylene-ethylene-hexene, and propylene-ethylene-butene polymers.
In embodiments where more than one comonomer derived from at least
one of ethylene or a C.sub.4-10 alpha-olefin is present, the amount
of one comonomer may be less than about 5 wt % of the
propylene-based elastomer, but the combined amount of comonomers of
the propylene-based elastomer is about 5 wt % or greater.
[0033] In some embodiments, the propylene-based elastomer may
further comprise a diene. The optional diene may be any hydrocarbon
structure having at least two unsaturated bonds wherein at least
one of the unsaturated bonds is readily incorporated into a
polymer. For example, the optional diene may be selected from
straight chain acyclic olefins, such as 1,4-hexadiene and
1,6-octadiene; branched chain acyclic olefins, such as
5-methyl-1,4-hexadiene, 3,7-dimethyl-1,6-octadiene, and
3,7-dimethyl-1,7-octadiene; single ring alicyclic olefins, such as
1,4-cyclohexadiene, 1,5-cyclooctadiene, and 1,7-cyclododecadiene;
multi-ring alicyclic fused and bridged ring olefins, such as
tetrahydroindene, norbornadiene, methyl-tetrahydroindene,
dicyclopentadiene, bicyclo-(2.2.1)-hepta-2,5-diene, norbornadiene,
alkenyl norbornenes, alkylidene norbornenes, e.g., ethylidiene
norbornene ("ENB"), cycloalkenyl norbornenes, and cycloalkyliene
norbornenes (such as 5-methylene-2-norbornene,
5-ethylidene-2-norbornene, 5-propenyl-2-norbornene,
5-isopropylidene-2-norbomene, 5-(4-cyclopentenyl)-2-norbornene,
5-cyclohexylidene-2-norbornene, 5-vinyl-2-norbornene); and
cycloalkenyl-substituted alkenes, such as vinyl cyclohexene, allyl
cyclohexene, vinyl cyclooctene, 4-vinyl cyclohexene, allyl
cyclodecene, vinyl cyclododecene, and tetracyclo
(A-11,12)-5,8-dodecene. The amount of diene-derived units present
in the propylene-based elastomer may range from an upper limit of
about 15%, about 10%, about 7%, about 5%, about 4.5%, about 3%,
about 2.5%, or about 1.5%, to a lower limit of about 0%, about
0.1%, about 0.2%, about 0.3%, about 0.5%, or about 1%, based on the
total weight of the propylene-based elastomer. In some embodiments,
the propylene-based elastomer does not contain any diene-derived
units.
[0034] The propylene-based elastomer may have a triad tacticity of
three propylene units, as measured by 13C NMR, of at least about
75%, at least about 80%, at least about 82%, at least about 85%, or
at least about 90%. Preferably, the propylene-based elastomer has a
triad tacticity of about 50 to about 99%, about 60 to about 99%,
about 75 to about 99%, or about 80 to about 99%. In some
embodiments, the propylene-based elastomer may have a triad
tacticity of about 60 to 97%.
[0035] The propylene-based elastomer may have a heat of fusion
("H.sub.f"), as determined by DSC, of about 75 J/g or less, about
70 J/g or less, about 50 J/g or less, or about 45 J/g or less, or
about 35 J/g or less. The propylene-based elastomer may have a
lower limit H.sub.f of about 0.5 J/g, about 1 J/g, or about 5 J/g.
For example, the H.sub.f value may be anywhere from 1.0, 1.5, 3.0,
4.0, 6.0, or 7.0 J/g, to 30, 35, 40, 50, 60, 70, or 75 J/g.
[0036] The propylene-based elastomer may have a percent
crystallinity, as determined according to the DSC procedure
described herein, of about 2 to about 65%, about 0.5 to about 40%,
about 1 to about 30%, or about 5 to about 35%, of the crystallinity
of isotactic polypropylene. The thermal energy for the highest
order of propylene (i.e., 100% crystallinity) is estimated at 189
J/g. In some embodiments, the copolymer has crystallinity less than
40%, or in the range of about 0.25 to about 25%, or about 0.5 to
about 22%, of isotactic polypropylene. Embodiments of the
propylene-based elastomer may have a tacticity index m/r from a
lower limit of about 4 or about 6 to an upper limit of about 8 or
about 10 or about 12. In some embodiments, the propylene-based
elastomer has an isotacticity index greater than 0%, or within the
range having an upper limit of about 50% or about 25%, and a lower
limit of about 3% or about 10%.
[0037] The propylene-based elastomer may have a single peak melting
transition as determined by DSC. In one embodiment, the copolymer
has a primary peak transition of about 90.degree. C. or less, with
a broad end-of-melt transition of about 110.degree. C. or greater.
The peak "melting point" ("T.sub.m") is defined as the temperature
of the greatest heat absorption within the range of melting of the
sample. However, the copolymer may show secondary melting peaks
adjacent to the principal peak, and/or at the end-of-melt
transition. For the purposes of this disclosure, such secondary
melting peaks are considered together as a single melting point,
with the highest of these peaks being considered the Tm of the
propylene-based elastomer. The propylene-based elastomer may have a
T.sub.m of about 105.degree. C. or less, about 100.degree. C. or
less, about 90.degree. C. or less, about 80.degree. C. or less, or
about 70.degree. C. or less. In some embodiments, the
propylene-based elastomer has a Tm of about 25 to about 105.degree.
C., about 60 to about 105.degree. C., about 70 to about 105.degree.
C., or about 90 to about 105.degree. C.
[0038] The propylene-based elastomer may have a density of about
0.850 to about 0.920 g/cm3, or about 0.860 to about 0.880 g/cm3, at
room temperature as measured per ASTM D1505.
[0039] The propylene-based elastomer may have a MI, as measured per
ASTM D1238, 2.16 kg at 190.degree. C., of at least about 1 g/10
min. In some embodiments, the propylene-based elastomer may have an
MI of from a lower limit of about 25 g/10 min, about 40 g/10 min,
about 60 g/10 min, about 80 g/10 min, about 100 g/10 min, about 150
g/10 min, about 200 g/10 min, or about 300 g/10 min, to an upper
limit of about 15,000 g/10 min, 10,000 g/10 min, 5,000 g/10 min,
2,000 g/10 min, about 1500 g/10 min, about 1200 g/10 min, about
1000 g/10 min, about 800 g/10 min, about 600 g/10 min, about 500
g/10 min, or about 400 g/10 min.
[0040] The propylene-based elastomer may have an Elongation at
Break of less than about 2000%, less than about 1000%, or less than
about 900%, as measured per ASTM D412.
[0041] The propylene-based elastomer may have a weight average
molecular weight (Mw) of about 5,000 to about 5,000,000 g/mole,
about 10,000 to about 1,000,000 g/mole, about 20,000 to about
750,000 g/mole, about 30,000 to about 400,000 g/mole.
[0042] The propylene-based elastomer may have a number average
molecular weight (Mn) of about 2,500 to about 250,000 g/mole, about
10,000 to about 250,000 g/mole, or about 25,000 to about 200,000
g/mole.
[0043] The propylene-based elastomer may have a z-average molecular
weight (Mz) of about 10,000 to about 7,000,000 g/mole, about 80,000
to about 700,000 g/mole, or about 100,000 to about 500,000
g/mole.
[0044] The propylene-based elastomer may have a molecular weight
distribution ("MWD") of about 1.5 to about 20, or about 1.5 to
about 15, preferably about 1.5 to about 5, and more preferably
about 1.8 to about 3, and most preferably about 1.8 to about
2.5.
[0045] The comonomer content may be adjusted so that the
propylene-based elastomer has a heat of fusion of less than about
75 J/g, a melting point of about 105.degree. C. or less, and a
crystallinity of about 2% to about 65% of the crystallinity of
isotactic polypropylene, and a melt index (MI) of at least about 25
g/10 min. The propylene-based elastomer may comprise copolymers
prepared according to the procedures described in WO 02/36651, U.S.
Patent No. 6,992,158, and/or WO 00/01745, the contents of which are
incorporated herein by reference. Preferred methods for producing
the propylene-based elastomer may be found in U.S. Pat. Nos.
7,232,871 and 6,881,800, the contents of which are incorporated
herein by reference. The invention is not limited by any particular
polymerization method for preparing the propylene-based elastomer,
and the polymerization processes are not limited by any particular
type of reaction vessel.
[0046] Suitable propylene-based elastomers may be available
commercially under the trade names VISTAMAXX.TM. (ExxonMobil
Chemical Company, Tex., USA), VERSIFY.TM. (The Dow Chemical
Company, Mich., USA), certain grades of TAFMER.TM. XM or NOTIO.TM.
(Mitsui Company, Japan), and certain grades of SOFTEL.TM. (Basell
Polyolefins of the Netherlands). The particular grade(s) of
commercially available propylene-based elastomer suitable for use
in the invention can be readily determined using methods commonly
known in the art.
Thermoplastic polyolefin
[0047] In some embodiments of the present invention, the primary
backing layer, middle, and/or third layer of the carpet may
comprise at least one thermoplastic polyolefin. The thermoplastic
polyolefin in the third layer and the middle layer may be the same
as or different from the propylene-based elastomer in the primary
backing layer. Depending on the type and amount of the
thermoplastic polyolefin, the final structure comprising the
thermoplastic olefin may have thermoplastic, elastomeric, or
thermoplastic elastomeric properties.
[0048] Thermoplastic polyolefins suitable for use in the carpet
include thermoplastic, crystalline polyolefin homopolymers and
copolymers. They are desirably prepared from monoolefin monomers
having 2 to 7 carbon atoms, such as ethylene, propylene, 1-butene,
isobutylene, 1-pentene, 1-hexene, 1-octene, 3-methyl-1 -pentene,
4-methyl-1-pentene, 5-methyl-1-hexene, mixtures thereof and
copolymers thereof with (meth)acrylates and/or vinyl acetates.
Preferred, however, are monomers having 3 to 6 carbon atoms, with
propylene being most preferred.
[0049] In some embodiments the thermoplastic polyolefin may be a
functionalized ethylene copolymer, preferably a maleic anhydride
functionalized elastomeric ethylene copolymer, e.g., those
commercially available under the trade name EXXELOR.TM. (ExxonMobil
Chemical Company, Tex., USA).
[0050] As used in the specification and claims the term
polypropylene includes homopolymers of propylene as well as
copolymers comprising propylene. Copolymers comprising propylene
refer to reactor copolymers of polypropylene (reacted blends) and
random copolymers containing more than 94% by weight of propylene,
the remainder being selected from the comonomers (other than
propylene) mentioned above, preferably ethylene. Typically, the
random copolymers of polypropylene with ethylene contain about 1 to
about 6 wt %, preferably less than about 6 wt % of ethylene and/or
about 1 to about 30 wt % of an alpha-olefin comonomer of 4 to 16
carbon atoms, and mixtures thereof The polypropylene can be highly
crystalline isotactic or syndiotactic polypropylene. Commercially
available polyolefins may be used in the practice of the present
invention. Further polyolefins which can be used in terms of the
invention are high, low, linear-low, very low-density polyethylenes
and copolymers of ethylene with (meth)acrylates and/or vinyl
acetates.
[0051] The thermoplastic polyolefins mentioned above can be made by
conventional Ziegler-Natta catalyst systems or by single-site
catalyst systems, including polyolefins such as polyethylene
copolymers obtained by metallocene catalysis with butene, hexene or
octene as the comonomer. The amount of comonomer present in a
polyethylene copolymer determines the density of the copolymer.
Metallocene polymers or plastomers refer to polymers or plastomers
prepared using a class of well-known highly active olefin catalysts
known as metallocenes. These catalysts, particularly those based on
group IV B transition metals such as zirconium, titanium and
hafnium, show high activity in ethylene polymerization. The
metallocene catalysts are also flexible in that, by manipulation of
catalyst composition and reaction conditions, they can provide
polyolefins with controllable molecular weights, as low as about
200 up to about 1 million or higher, and molecular weight
distribution, from extremely narrow to broad. Metallocene catalysts
are useful in making controlled ultra-uniform and super random
specialty copolymers. For example, if a lower density ethylene
copolymer is made with a metallocene catalyst, such as very low
density polyethylene (VLDPE), an ultra-uniform and super random
copolymerization will occur, as contrasted with the polymer
produced by copolymerization using a conventional Ziegler
catalyst.
Filler
[0052] One or more layers of the carpet of the present invention
may include a filler. In another embodiment, the second and/or
third layers may include a filler. The classes of materials
described herein that are useful as fillers can be utilized alone
or admixed to obtain desired properties. In any of the embodiments,
the filler may be present at up to about 80 wt %, preferably up to
about 70 wt %, more preferably from about 60 wt % to about 65 wt %,
based on the total weight of the layer.
[0053] Desirable fillers can be organic fillers and/or inorganic
fillers. Useful fillers include such materials as carbon black, fly
ash, graphite, cellulose, starch, flour, wood flour, and polymeric
fibers like polyester-based, polyamide-based materials, etc.
Preferred examples of fillers are calcium carbonate, aluminum
trihydrate, talc, glass fibers, marble dust, cement dust, clay,
feldspar, silica or glass, fumed silica, alumina, magnesium oxide,
antimony oxide, zinc oxide, barium sulfate, calcium sulfate,
aluminum silicate, calcium silicate, titanium dioxide, titanates,
clay, nanoclay, organo-modified clay or nanoclay, glass
microspheres and chalk. In some embodiments, the one or more layers
of the carpet comprise a filler for improving the flame retardant
properties of the carpet, such as aluminum trihydrate or calcium
carbonate.
Carpet Layers
[0054] The carpets described herein have a primary backing layer
having a face side and a back side with a plurality of fibers
attached to the primary backing layer and extending from both the
face side and the back side of the primary backing layer. A second
layer is attached to the back side of the primary backing layer and
locks in the plurality of fibers extending from the back side of
the primary backing layer. In some embodiments, the carpet further
comprises a third layer on the back side of the second layer
opposite to the primary backing layer. In some embodiments, the
carpet further comprises a reinforcement layer between the second
layer and the third layer.
[0055] In some embodiments, the primary backing layer may comprise
a thermoplastic polyolefin as described above. In other
embodiments, the primary backing layer may be a nonwoven layer
comprising bicomponent filaments. For example, the primary backing
layer may comprise bicomponent continuous filaments having a
polyethylene terephthalate core and a polyamide or polypropylene
skin/sheath.
[0056] The face yarn may comprise various materials including, but
not limited to, polypropylene, nylon, wool, cotton, acrylic,
polyester and polyethylene terephthalate (PET).
[0057] The second layer of the carpet may include one or more
different propylene-based elastomers as described above. For
example, the second layer of the carpet may comprise at least one
propylene-based elastomer comprising at least about 60 wt %
propylene-derived units and about 5 to about 25 wt %
ethylene-derived units, by weight of the propylene-based elastomer,
wherein the propylene-based elastomer has a heat of fusion of less
than about 75 J/g.
[0058] In some embodiments, the second layer may comprise more than
one propylene-based elastomers each having one or more different
properties such as, for example, different comonomer or comonomer
content. Such combinations of various propylene-based elastomers
are all within the scope of the invention.
[0059] In some embodiment, the third layer also comprises one or
more propylene-based elastomers. In other embodiments, the third
layer comprises at least one thermoplastic polyolefin. It is
preferred that the third layer is made from a thermoplastic
polyolefin to facilitate recycling, which can be the same as or
different from the propylene-based elastomer in the second
layer.
[0060] In some embodiments, the reinforcement layer may comprise at
least one of thermoplastic fabrics and fiberglass.
[0061] In some embodiments, the carpet may comprise a primary
backing layer having a face side and a back side with a plurality
of fibers attached to the primary backing layer and extending from
both the face side and the back side of the primary backing layer.
A second layer that acts as a precoat layer may be attached to the
back side of the primary backing layer and lock in the plurality of
fibers extending from the back side of the primary backing layer.
In such embodiments, the second layer may comprise latex. The
carpet further comprises a middle layer on the back side of the
second layer opposite to the primary backing layer and a third
layer on the back side of the middle layer opposite to the second
layer. The middle and third layers may comprise propylene-based
elastomers as described herein. The carpet may further comprise a
reinforcement layer between the middle layer and the third
layer.
[0062] In some embodiments, the carpet may comprise a primary
backing layer having a face side and a back side with a plurality
of fibers attached to the primary backing layer and extending from
both the face side and the back side of the primary backing layer.
A second layer may be attached to the back side of the primary
backing layer and lock in the plurality of fibers extending from
the back side of the primary backing layer. In such embodiments,
the second layer may comprise a propylene-based elastomer as
described herein. The carpet further comprises a middle layer on
the back side of the second layer opposite to the primary backing
layer and a third layer on the back side of the middle layer
opposite to the second layer. The middle and third layers may
comprise propylene-based elastomers as described herein. The carpet
may further comprise a reinforcement layer between the middle layer
and the third layer.
[0063] In some embodiments, the carpet may comprise a primary
backing layer having a face side and a back side with a plurality
of fibers attached to the primary backing layer and extending from
both the face side and the back side of the primary backing layer.
A second layer attached to the back side of the primary backing
layer and lock in the plurality of fibers extending from the back
side of the primary backing layer. The carpet further comprises a
third layer on the back side of the second layer opposite to the
second layer. The third layer may comprise propylene-based
elastomers as described herein. The carpet may further comprise a
reinforcement layer between the second layer and the third layer.
In such embodiments, the carpet may not comprise a middle
layer.
[0064] In some embodiments, compared to the conventional carpet
comprising a latex precoat layer present in an amount of 18-28 oz
/yd.sup.2 (about 612-952 g/m.sup.2 of latex), the inventive second
or middle layer containing a propylene-based elastomer may
substantially eliminate the need of using latex in the carpet. For
example, in such embodiments the carpet may comprise a trace amount
of no more than 150 g/m.sup.2 of latex, or no more than 100
g/m.sup.2 of latex, or no more than 50 g/m.sup.2 of latex, or no
more than 20 g/m.sup.2 of latex, or 0 g/m.sup.2 of latex.
Methods For Making the Carpet
[0065] Also provided are methods for making the carpet. The method
for making a carpet may comprise the steps of: (a) providing a
primary backing layer having a face side and a back side, with a
plurality of fibers attached to the primary backing layer and
extending from both the face side and the back side of the primary
backing layer; (b) applying a second layer to the back side of the
primary backing layer, wherein the layer comprises at least one
propylene-based elastomer comprising at least about 60 wt %
propylene-derived units and about 5 to about 25 wt %
ethylene-derived units, by weight of the propylene-based elastomer,
wherein the propylene-based elastomer has a heat of fusion of less
than about 75 J/g; and (c) forming a carpet, wherein the second
layer substantially locks in the plurality of fibers extending from
the back side of the primary backing layer.
[0066] Any conventional tufting or needle-punching apparatus and
stitch patterns can be used. Tufted yarn loops may be left uncut to
produce a loop pile; cut to make cut pile; or cut, partially cut
and uncut to make a face texture known as tip sheared.
[0067] After the yarn is tufted or needle-punched into the primary
backing layer, the greige good is typically rolled up with the back
side of the primary backing layer facing outward and held until it
is transferred to the backing line.
[0068] In a preferred embodiment, the greige good is scoured or
washed before it has a second layer extruded thereon. In
particular, yarn that is tufted or needle-punched to make carpet
often has varying quantities of processing materials, most commonly
oily or waxy chemicals, known as spin-finish chemicals, remaining
thereon from the yarn manufacturing processes. It has been found to
be preferable to remove or displace all or substantially all of
these processing materials prior to extruding the second layer
comprising the propylene-based elastomer onto the back surface of
the primary backing layer.
[0069] The second layer can be applied by various methods,
including extrusion coating and sheet lamination, with the
preferred method involving the use of an extruded sheet of a
propylene-based elastomer, onto which a third layer is extrusion
coated or sheet laminated. In particular, a molten propylene-based
elastomer is preferably extruded through a die so as to make a
sheet which is as wide as the carpet. The molten, extruded sheet is
applied to the back side of the primary carpet backing layer. Since
the sheet is molten, the sheet will conform to the shape of the
loops of yarn and further serve to fix the loops in the primary
backing.
[0070] Extrusion coating configurations include a monolayer T-type
die, single-lip die coextrusion coating, dual-lip die coextrusion
coating, and multiple stage extrusion coating.
[0071] The line speed of the extrusion process will depend on
factors such as the particular polymer being extruded, the exact
equipment being used, and the weight of polymer being applied. The
extrusion coating melt temperature principally depends on the
particular polymer being extruded.
[0072] Since the second layer may be relied on to encapsulate and
lock the yarn in place, this layer may have a MI high enough (melt
viscosity low enough), for example, of from a lower limit of about
25 g/10 min, about 40 g/10 min, about 60 g/10 min, about 80 g/10
min, about 100 g/10 min, about 150 g/10 min, about 200 g/10 min, or
about 300 g/10 min, to an upper limit of about 15000g/10 min, about
1500 g/10 min, about 1200 g/10 min, about 1000 g/10 min, about 800
g/10 min, about 600 g/10 min, about 500 g/10 min, or about 400 g/10
min, to promote encapsulation and locking of the yarn.
[0073] Auxiliary equipment such as a pre-heater can be used. In
particular, a heater, such as a convection oven or infrared panels
can be used to heat the back of the greige good before the second
layer is extruded thereon. In doing so, it has been found that the
encapsulation is and locking of the yarn bundles can be
enhanced.
[0074] The extruded polymer(s) can either be used neat, or can have
one or more additive included. A preferred additive is an inorganic
filler. Examples of such fillers include, but are not limited to,
calcium carbonate, aluminum trihydrate, talc, and barite. Inorganic
mineral fillers can improve yarn encapsulation and locking which in
turn improves the performance of the tuft bind strength and tuft
lock strength of extrusion coated carpet samples. Preferably,
filler is added at a level of up to about 80 wt %, preferably up to
about 70 wt %, more preferably from about 60 wt % to about 65 wt %,
based on the total weight of the extruded layer. For the second
layer of the present invention, fillers which may serve as flame
retardant are preferred, such as aluminum trihydrate or calcium
carbonate.
[0075] Other additives that may also be included include
antioxidants such as sterically hindered phenols, sterically
hindered amines and phospites may be used. Other possible additives
include antiblock additives, pigments and colorants, anti-static
agents, tackifiers (such as aromatic modified aliphatic hydrocarbon
resins, e.g., those commercially available under the trade name
ESCOREZ.TM. (ExxonMobil Chemical Company, Tex., USA)),
compatibilizers (functionalized ethylene copolymers, preferably
maleic anhydride functionalized elastomeric ethylene copolymers,
e.g., those commercially available under the trade name EXXELOR.TM.
(ExxonMobil Chemical Company, Tex., USA)), processing aids (such as
stearic acid), antimicrobial agents (such as quaternary ammonium
salts), chill roll release additives (such as fatty acid amides)
and other aids (such as metallocene-based homopolymers, e.g., those
commercially available under the trade name ACHIEVE.TM. (ExxonMobil
Chemical Company, Tex., USA)).
[0076] As noted above, the carpet may also include a third layer.
The third layer can be laminated in a later step by reheating
and/or remelting at least the outermost portion of the extruded
layer or by a coextrusion coating technique using at least two
dedicated extruders.
[0077] The extrusion backed carpet construction and the methods
described herein are particularly suited for making carpet tile. In
one embodiment, yarn is tufted into a primary backing layer, so as
to leave a carpet pile face on top of the primary backing layer and
back stitches below the primary backing. Applied to the back of the
primary backing layer and the back stitches is a second layer
comprising a propylene-based elastomer. Preferably, the second
layer further comprises a filler. The filler can be aluminum
trihydrate with a loading of about 60 wt %, based on the total
weight of the extruded layer.
[0078] In preferred embodiments, the carpet includes no more than
150 g/m.sup.2 of latex, no more than 100 g/m.sup.2 of latex, no
more than 50 g/m.sup.2 of latex, no more than 20 g/m.sup.2 of
latex, or 0 g/m.sup.2 of latex.
[0079] When making carpet tile, it is preferable to embed a
reinforcement layer between the second and third layers. An
important property of carpet tile is dimensional stability, i.e.,
the ability of the tile to maintain its size and flatness over
time. The inclusion of this layer of reinforcing material has been
found to enhance the dimensional stability of carpet tile made
according to this preferred embodiment. Suitable materials for the
reinforcement layer include dimensionally and thermally stable
fabrics such as fiberglass, as well as thermoplastic fabrics (e.g.,
polypropylene, nylon and polyester). Optionally, there is a middle
layer present between the second layer and the reinforcement layer,
preferably, also made from a thermoplastic polyolefin, which can be
the same as or different from the propylene-based elastomer in the
second layer.
[0080] Carpet tile is typically made by producing a length of
backed carpet and then cutting the carpet into the appropriate
sized squares. The most common sizes include 18 inches (45.7 cm)
square, 24 inches (about 61.0 cm) square, or 50 cm square.
[0081] The carpets described herein may have improved properties,
including tuft bind strength and tuft lock strength, and reliable
construction, by substantially locking face yarn in place with use
of a propylene-based elastomer, typically in a single layer
replacing both the current precoat primarily comprising latex and
the thermoplastic laminate layer. It can also be expected that the
carpet, preferably without latex, may show such improved yarn
adhesion when exposed to water, for there would be little latex
decomposition leading to loss of tuft bind and tuft lock as it
occurs in the conventional carpet. Meanwhile, the propylene-based
elastomer, if filled, may further impart enhanced flame retardant
properties of the carpet. Even when highly filled, the
propylene-based elastomer is still able to remain flexible and
durable, enhance adhesion and toughness to other carpet
components.
[0082] Exemplary embodiments can include those described in the
following paragraphs.
[0083] Embodiment A: A carpet comprising: (a) a primary backing
layer having a face side and a back side; (b) a plurality of fibers
attached to the primary backing layer and extending from both the
face side and the back side of the primary backing layer; and (c) a
second layer attached to the back side of the primary backing
layer, comprising at least one propylene-based elastomer comprising
at least about 60 wt% propylene-derived units and about 5 to about
25 wt% ethylene-derived units, by weight of the propylene-based
elastomer, wherein the propylene-based elastomer has a heat of
fusion of less than about 75 J/g, wherein the second layer
substantially locks in the plurality of fibers extending from the
back side of the primary backing layer.
[0084] Embodiment B: The carpet of Embodiment A, wherein the carpet
comprises no more than 150 g/m.sup.2 of latex.
[0085] Embodiment C: The carpet of Embodiments A or B, wherein the
carpet comprises no more than 100 g/m.sup.2 of latex.
[0086] Embodiment D: The carpet of any of Embodiments A to C,
wherein the carpet comprises no more than 50 g/m.sup.2 of
latex.
[0087] Embodiment E: The carpet of any of Embodiments A to D,
wherein the carpet comprises no more than 20 g/m.sup.2 of
latex.
[0088] Embodiment F: The carpet of any of Embodiments A to E,
wherein the carpet comprises 0 g/m.sup.2 of latex.
[0089] Embodiment G: The carpet of any of Embodiments A to F,
wherein the fibers comprise at least one of polypropylene, nylon,
wool, cotton, acrylic, polyester, and polyethylene
terephthalate.
[0090] Embodiment H: The carpet of any of Embodiments A to G,
wherein the primary backing layer comprises at least one
thermoplastic polyolefin.
[0091] Embodiment I: The carpet of any of Embodiments A to H,
wherein the second layer further comprises a filler.
[0092] Embodiment J: The carpet of Embodiment I, wherein the filler
is a flame retardant.
[0093] Embodiment K: The carpet of Embodiments I or J, wherein the
filler is aluminum trihydrate.
[0094] Embodiment L: The carpet of any of Embodiments A to K,
further comprising a third layer attached to the second layer
opposite to the primary backing layer.
[0095] Embodiment M: The carpet of Embodiment L, wherein the third
layer comprises at least one thermoplastic polyolefin.
[0096] Embodiment N: The carpet of Embodiment M, wherein the third
layer further comprises a filler.
[0097] Embodiment O: The carpet of any of Embodiments L to N,
wherein a reinforcement layer is present between the second layer
and the third layer.
[0098] Embodiment P: The carpet of Embodiment O, wherein the
reinforcement layer comprises at least one of thermoplastic fabrics
and fiberglass.
[0099] Embodiment Q: The carpet of Embodiments O to P, wherein a
middle layer is present between the second layer and the
reinforcement layer.
[0100] Embodiment R: The carpet of Embodiment Q, wherein the middle
layer comprises at least one thermoplastic polyolefin.
[0101] Embodiment S: A method for making a carpet comprising the
steps of: (a) providing a primary backing layer having a face side
and a back side, with a plurality of fibers attached to the primary
backing layer and extending from both the face side and the back
side of the primary backing layer; (b) applying a second layer to
the back side of the primary backing layer, wherein the layer
comprises at least one propylene-based elastomer comprising at
least about 60 wt % propylene-derived units and about 5 to about 25
wt % ethylene-derived units, by weight of the propylene-based
elastomer, wherein the propylene-based elastomer has a heat of
fusion of less than about 75 J/g; and (c) forming a carpet; wherein
the second layer substantially locks in the plurality of fibers
extending from the back side of the primary backing layer.
[0102] Embodiment T: The method of Embodiment S, wherein in (b) the
second layer is applied to the back side of the primary backing
layer by extrusion coating or sheet lamination.
[0103] Embodiment U: A carpet comprising: (a) a primary backing
layer having a face side and a back side, wherein the primary
backing layer comprises at least one thermoplastic polyolefin; (b)
a plurality of fibers attached to the primary backing layer and
extending from both the face side and the back side of the primary
backing layer; (c) a second layer attached to the back side of the
primary backing layer, comprising at least one propylene-based
elastomer and aluminum trihydrate, wherein the propylene-based
elastomer comprises at least about 60 wt % propylene-derived units
and about 5 to about 25 wt % ethylene-derived units, by weight of
the propylene-based elastomer, and wherein the propylene-based
elastomer has a heat of fusion of less than about 75 J/g; (d) a
third layer attached to the second layer opposite to the primary
backing layer, wherein the third layer comprises at least one
thermoplastic polyolefin; and (e) a reinforcement layer between the
second layer and the third layer, wherein the reinforcement layer
comprises at least one of thermoplastic fabrics and fiberglass;
wherein the second layer substantially locks in the plurality of
fibers extending from the back side of the primary backing layer,
and wherein the carpet comprises 0 g/m.sup.2 of latex.
EXAMPLES
[0104] The foregoing discussion can be further described with
reference to the following non-limiting Examples. The examples show
the effects of a propylene-based elastomer on yarn adhesion
property of a carpet by Samples 1 and 2 in a Velcro roller test.
Sample 1 is a carpet sample with a second layer made from 100 wt %
of Vistamaxx.TM. 2330 propylene-based elastomer and Sample 2 is one
with a second layer made from Vistamaxx.TM. 2330 propylene-based
elastomer filled with 60 wt % of aluminum trihydrate (ATH). Areas
covered with only yarn were set aside for comparison. Percentages
here are based on the total weight of the second layer. The test
was conducted by rolling a Velcro type tool back and forth against
the surface of Samples 1 and 2 for 20 times. The resulting
appearances on the back and front sides of the two samples were
examined.
[0105] It is shown in FIG. 2 that the surface appearance was
maintained well in the areas with coverage of the propylene-based
elastomer while fray or fuzz was formed in the areas with no
coverage of the propylene-based elastomer, reflecting good yarn
adhesion resulted from the second layer comprising the
propylene-based elastomer. It can also be seen by comparing Samples
1 and 2 that the presence of fillers does not produce noticeable
difference to the yarn adhesion.
[0106] All documents described herein are incorporated by reference
herein, including any priority documents and/or testing procedures.
When numerical lower limits and numerical upper limits are listed
herein, ranges from any lower limit to any upper limit are
contemplated. As is apparent from the foregoing general description
and the specific embodiments, while forms of the invention have
been illustrated and described, various modifications can be made
without departing from the spirit and scope of the invention.
Accordingly, it is not intended that the invention be limited
thereby.
* * * * *