U.S. patent application number 13/739806 was filed with the patent office on 2013-05-16 for power plant with co2 capture.
This patent application is currently assigned to ALSTOM TECHNOLOGY LTD. The applicant listed for this patent is ALSTOM Technology Ltd. Invention is credited to Hongtao Li, Celine Mahieux, Holger Nagel, Tjiptady Nugroho.
Application Number | 20130118179 13/739806 |
Document ID | / |
Family ID | 42288181 |
Filed Date | 2013-05-16 |
United States Patent
Application |
20130118179 |
Kind Code |
A1 |
Li; Hongtao ; et
al. |
May 16, 2013 |
POWER PLANT WITH CO2 CAPTURE
Abstract
A method is provided for operating a combined cycle power plant
having at least one gas turbine, a heat recovery steam generator
(HSRG), a steam turbine and a CO2 capture system. The method
includes recirculating a first partial flow of flue gases from the
HRSG. The method also includes capturing CO2 from a second partial
flow of flue gases from the HRSG; and operating a supplementary
firing to increase the net power output of the plant and to at
least partly compensate the power consumption of the CO2 capture
system. A combined cycle power plant is also provided. The plant
includes at least one gas turbine, at least one heat recovery steam
generator, at least one steam turbine at least one CO.sub.2 capture
system, and flue gas recirculation. The plant also includes a low
excess air supplementary firing.
Inventors: |
Li; Hongtao; (Aarau, CH)
; Nagel; Holger; (Stuttgart, DE) ; Nugroho;
Tjiptady; (Fislisbach, CH) ; Mahieux; Celine;
(Baden, CH) |
|
Applicant: |
Name |
City |
State |
Country |
Type |
ALSTOM Technology Ltd; |
Baden |
|
CH |
|
|
Assignee: |
ALSTOM TECHNOLOGY LTD
Baden
CH
|
Family ID: |
42288181 |
Appl. No.: |
13/739806 |
Filed: |
January 11, 2013 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
|
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13157897 |
Jun 10, 2011 |
8365537 |
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13739806 |
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PCT/EP2009/067674 |
Dec 21, 2009 |
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13157897 |
|
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Current U.S.
Class: |
60/772 ;
60/39.182 |
Current CPC
Class: |
Y02E 20/34 20130101;
F02C 6/18 20130101; F01K 23/105 20130101; Y02E 20/344 20130101;
Y02E 20/32 20130101; Y02E 20/16 20130101; Y02E 20/326 20130101 |
Class at
Publication: |
60/772 ;
60/39.182 |
International
Class: |
F02C 6/18 20060101
F02C006/18 |
Foreign Application Data
Date |
Code |
Application Number |
Dec 24, 2008 |
EP |
08172880.0 |
Claims
1. A method for operating a combined cycle power plant comprising
at least one gas turbine (6), having a compressor (1), a combustor
(4) and a turbine (7), a heat recovery steam generator (HSRG) (9),
a steam turbine (13), a CO2 capture system (18), a supplementary
firing (10), which is integrated into the heat recovery steam
generator (HSRG) (9) or installed as a duct firing (10) in the flue
duct from the gas turbine to the heat recovery steam generator
(HSRG) (9), and a flue gas recirculation line, the method
comprising: mixing ambient air (2) and the first partial (21) flow
of the flue gases (19); compressing the mixture of ambient air (2)
and first partial flow (21); combustion fuel (5) in the combustor
4; expanding the pressurized hot combustion gasses in a turbine
(7); passing the turbine's hot flue gases through a heat recovery
steam generator (HSRG) (9), which generates steam (30); splitting
the flue gas of the gas turbine into at least two partial flows
downstream of the heat recovery steam generator (HSRG) (9);
recirculating a first partial flow (21) of flue gases (19) from the
HRSG (9) via the recirculation line to the compressor inlet;
directing a second partial flow (20) of the flue gases (19) from
the heat recovery steam generator (HSRG) (9) to the CO2 capture
system (18); capturing CO2 from a second partial flow (20) of flue
gases (19) from the HRSG (9); operating the supplementary firing
(10) to increase the net power output of the plant and to at least
partly compensate the power consumption of the CO2 capture system
(18); wherein the supplementary firing (10) comprises burner boxes
(28) arranged traversal, spaced apart in arrays in a cross section
of the HRSG inlet (33) or inside the HRSG, and gas turbine flue gas
(8) passes past the burner boxes (28) through the passages between
burner boxes (28) while fuel and additional ambient air or oxygen
enriched air or oxygen are supplied to the burner boxes (28) and
the flame of the supplementary firing is stabilized in the burner
boxes (28).
2. The method according to claim 1, wherein the first partial flow
(21) is recirculated at recirculation rate, which is controlled at
a highest possible recirculation rate under the conditions at which
stable complete combustion in the gas turbine (6) can be maintained
and at which a residual oxygen concentration after the gas turbine
(GTO2) is sufficient to maintain stable complete combustion of the
supplementary firing (10).
3. The method according to claim 2, wherein a sufficient ambient
air flow, and/or oxygen enriched air flow, and/or oxygen flow (11)
is injected into the supplementary firing (lo), such that the
recirculation rate can be controlled independently of the oxygen
concentration required for stable complete combustion of the
supplementary firing (10).
4. The method according to claim 3, wherein the additional ambient
air flow, and/or oxygen enriched air flow, and/or oxygen flow (11)
is a function of the recirculation rate.
5. The method according to claim 3, wherein the additional ambient
air flow, and or oxygen enriched air flow, and/or oxygen flow (11)
is a function of the residual oxygen concentration after the gas
turbine (GTO2).
6. The method according to claim 1, wherein the additional ambient
air flow, and or oxygen enriched air flow, and/or oxygen flow (11)
is a function of the supplementary firing load.
7. The method according to claim 3, wherein the additional ambient
air flow, and or oxygen enriched air flow, and/or oxygen flow (11)
is a function of the recirculation rate and or a function of the
residual oxygen concentration after the gas turbine and or a
function of the supplementary firing load.
8. The method according to claim 1, wherein the additional ambient
air flow, and or oxygen enriched air flow, and/or oxygen flow (11)
is preheated by low grade heat from a water steam cycle of the
combined cycle power plant, and or the CO2 capture system (1a),
and/or the flue gases.
9. The method according to claim 1, wherein the supplementary
firing (10) is operated to increase the power output for power
augmentation during peak demand and to increase its operational
flexibility.
10. A combined cycle power plant comprising at least one gas
turbine (6), a compressor (1) for compressing inlet gas (3), a
combustor (4) for combustion of fuel (5) in with the compressed
gas, and a turbine (7) for expanding pressurized hot gases
combustion gas, at least one heat recovery steam generator (9),
downstream of the turbine at least one steam turbine (13) at least
one CO2 capture system (18), downstream of the heat recovery steam
generator (HSRG) (9), and flue gas recirculation line from heat
recovery steam generator (HSRG) (9) to a compressor inlet, wherein
a low excess air supplementary firing (10), which can be operated
in a gas flow with less than 10% oxygen concentration with a
stoichiometric ratio below 2, is integrated into the heat recovery
steam generator (HSRG) (9) or installed as a duct firing (10) in a
flue duct from the gas turbine to the heat recovery steam generator
(HSRG) (9) is provided, wherein the supplementary firing (10)
comprises burner boxes (28), arranged traversal, spaced apart in
arrays in a cross section of the HRSG inlet (33) or inside the
HRSG, such that gas turbine flue gas (8) can pass past the burner
boxes (28) through the passages between burner boxes (28), and
wherein the burner boxes (28) have an u-shaped cross section which
is open do a downstream direction and comprise a fuel gas supply
(12) and additional ambient air or oxygen or oxygen enriched air
supply (11) to the inside of the burner boxes (28) such that the
supplementary firing is stabilized in the burner boxes (28).
11. The combined cycle power plant according to claim 10, wherein
ambient air supply lines, and or oxygen enriched air supply lines,
and/or oxygen supply lines to the low excess air supplementary
firing (10) are provided.
12. The combined cycle power plant according to claim 10, further
comprising an oxygen enrichment plant and or an air separation
unit.
13. The combined cycle power plant according to claim 10, wherein
at least one oxygen measurement device is installed to measure
oxygen concentrations of inlet gases of a compressor inlet gas (2)
and/or to measure a residual oxygen concentration of hot flue gases
of a gas turbine (8) and/or to measure a residual oxygen
concentration of flue gases (19) from the heat recovery steam
generator (9).
14. The combined cycle power plant according to claim 10, wherein
at least one CO2 measurement device is installed to measure a CO2
concentration of inlet gases of a compressor inlet gas (2) and/or
to measure a CO2 concentration of hot flue gases of a gas turbine
(8) and/or to measure a CO2 concentration of flue gases (19) from
the heat recovery steam generator (19).
Description
INCORPORATION BY REFERENCE
[0001] The following documents are incorporated herein by reference
as if fully set forth: U.S. patent application Ser. No. 13/157,897,
filed Jun. 10, 2011; International Application No.
PCT/EP2009/067674 filed Dec. 21, 2009; and European Patent
Application No. 08172880.0, filed Dec. 24, 2008.
FIELD OF INVENTION
[0002] The invention relates to combined cycle power plants with
integrated CO.sub.2 capture and supplementary firing as well as to
their operation.
BACKGROUND
[0003] In recent years it has become obvious that the generation of
greenhouse gases leads to global warming and that further increase
in greenhouse gas production will accelerate global warming. Since
CO.sub.2 (carbon dioxide) is identified as a main greenhouse gas,
CCS (carbon capture and storage) is considered as one of the
potential major means to reduce the release of greenhouse gases
into the atmosphere and to control global warming. In this context
CCS is defined as the process of CO.sub.2 capture, compression,
transport and storage. Capture is defined as a process, in which
CO.sub.2 is removed either from the flue gases after combustion of
a carbon based fuel or the removal of and processing of carbon
before combustion. Regeneration of any absorbents, adsorbents or
other means to remove CO.sub.2 from a flue gas or fuel gas flow is
considered to be part of the capture process.
[0004] Backend CO.sub.2 capture, also called post-combustion
capture, is a commercially promising technology for fossil fueled
power plants including CCPP (combined cycle power plants). In
post-combustion capture the CO.sub.2 is removed from a flue gas.
The remaining flue gas is released to the atmosphere and the
CO.sub.2 is compressed for transportation, and storage. There are
several technologies known to remove CO.sub.2 from a flue gas such
as absorption, adsorption, membrane separation, and cryogenic
separation. Power plants with post combustion capture are the
subject of this invention.
[0005] All known technologies for CO.sub.2 capture require
relatively large amounts of energy. Due to the relatively low
CO.sub.2 concentration of only about 4% in the flue gases of a
conventional CCPP, the CO.sub.2 capture system (also called
CO.sub.2 capture plant or CO.sub.2 capture equipment) for a
conventional CCPP will be more costly and energy consuming per kg
of captured CO.sub.2 than one for other types of power plants,
which have flue gas flows at higher CO.sub.2 concentrations.
[0006] The CO.sub.2 concentration in the CCPP flue gas depends on
the fuel composition, the gas turbine type and load and may vary
substantially depending on the operating conditions of the gas
turbine. This variation in CO.sub.2 concentration can be
detrimental to the performance, efficiency, and operatability of
the CO.sub.2 capture system.
[0007] To increase the CO.sub.2 concentration in the flue gases of
a CCPP two main concepts are known. One is the recirculation of
flue gases as for example described by O. Bolland and S. Saether in
"NEW CONCEPTS FOR NATURAL GAS FIRED POWER PLANTS WHICH SIMPLIFY THE
RECOVERY OF CARBON DIOXIDE" (Energy Convers. Mgmt Vol. 33, No. 5-8,
pp. 467-475, 1992)). Another one is the so called tandem
arrangement of plants, where the flue gas of a first CCPP is cooled
down and used as inlet gas for a second CCPP to obtain a flue gas
with increased CO.sub.2 concentration in the flue gas of the second
CCPP. Such an arrangement is for example described in
US20080060346. These methods reduce the total flue gas flow,
increase the CO.sub.2 concentration, and thereby reduce the
required flow capacity of absorber and power consumption of the
capture system.
[0008] These methods, as well as many further published methods for
the optimization of the different process steps, and the reduction
of the power and efficiency penalties by integrating these
processes into a power plant, aim to reduce the capital expenditure
and the power requirements of CO.sub.2 capture system.
SUMMARY
[0009] The present disclosure is directed to a method for operating
a combined cycle power plant having at least one gas turbine, a
heat recovery steam generator (HSRG), a steam turbine and a
CO.sub.2 capture system. The method includes recirculating a first
partial flow of flue gases from the HRSG. The method also includes
capturing CO.sub.2 from a second partial flow of flue gases from
the HRSG; and operating a supplementary firing to increase the net
power output of the plant and to at least partly compensate the
power consumption of the CO.sub.2 capture system.
[0010] In another aspect, the present disclosure is directed to a
combined cycle power plant. The plant includes at least one gas
turbine, at least one heat recovery steam generator, at least one
steam turbine at least one CO.sub.2 capture system, and flue gas
recirculation. The plant also includes a low excess air
supplementary firing.
BRIEF DESCRIPTION OF THE DRAWINGS
[0011] The invention, its nature as well as its advantages, shall
be described in more detail below with the aid of the accompanying
drawings. Referring to the drawings.
[0012] FIG. 1 schematically shows a CCPP with backend CO.sub.2
absorption including flue gas recirculation and low excess air
ratio supplementary firing.
[0013] FIG. 2 schematically shows a low excess air ratio
supplementary firing burner for application in a HRSG of a CCPP
with flue gas recirculation.
[0014] FIG. 3 schematically shows the normalized residual oxygen
concentration of the gas turbine flue gas GT.sub.O2 required for
supplementary firing as a function of the relative load of the
supplementary firing SF.sub.load without additional ambient air or
oxygen supply.
[0015] FIG. 4 schematically shows the normalized residual oxygen
concentration of the gas turbine flue gas GT.sub.O2 required for
supplementary firing as a function of relative load of the
supplementary firing SF.sub.load with additional ambient air or
oxygen supply F.sub.air and the residual oxygen concentration after
supplementary firing SF.sub.O2.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS
Introduction to the Embodiments
[0016] An objective of the present invention is to provide a
combined cycle power plant (CCPP) comprising at least one gas
turbine, one heat recovery steam generator (HRSG), one steam
turbine, and carbon dioxide (CO.sub.2) capture system with enhanced
operational flexibility, and to reduce capacity penalties for
CO.sub.2 capture as well as an operating method for such a
CCPP.
[0017] In particular the impact of CO.sub.2 capture on the capacity
of a CCPP is to be minimized, i.e. the electric power delivered to
the power grid by the plant including the CO.sub.2 capture system
is to be maximized.
[0018] To this end an operating method for a CCPP with flue gas
recirculation, CO.sub.2 capture and supplementary firing is
proposed as well as a plant to carry out such a method. The essence
of the invention is an operating method for a CCPP with flue gas
recirculation, which allows operation of a supplementary firing
burner in flue gases of a CCPP with flue gas recirculation, which
at least partially compensates for the power requirements of the
CO.sub.2 capture system. The supplementary firing burner can be
installed in the HRSG of the CCPP or as a duct firing in the flue
duct from the gas turbine to the HRSG.
[0019] For flue gas recirculation, the flue gas flow of a gas
turbine is split into at least two partial flows downstream of the
HRSG. A first partial flow is returned to the inlet of the gas
turbine via a flue gas recirculation line, and a second partial
flow is directed via the CO.sub.2 capture system to the stack for
release to the environment. Further, a bypass around the CO.sub.2
capture system for direct release of flue gases to the environment
can be provided to increase the operational flexibility. This
allows any combination of recirculation rate, of flue gas flow to
CO.sub.2 capture unit, and direct flue gas flow to the stack
without CO.sub.2 capture.
[0020] Flue gas recirculation is applied to minimize the CO.sub.2
capture system's size, its costs, and its power requirements. For
optimized CO.sub.2 capture the flue gas recirculation rate should
be maximized. The recirculation rate is defined as the ratio of
flue gas mass flow from the gas turbine, which is recirculated to
the compressor inlet, to the total flue gas mass flow of the gas
turbine.
[0021] For high CO.sub.2 capture efficiency and to minimize the
flue gas mass flow, the oxygen concentration in the flue gas would
ideally be 0%. Due to cooling air, which bypasses the gas turbine's
combustion chamber, and excess oxygen needed to assure complete
combustion, recirculation is limited and some residual oxygen
remains in the exhaust gas even with recirculation. Typical
recirculation rates determined by the operational requirements of
the gas turbine are in the order of 30% to 50% for base load
operation.
[0022] Conventional supplementary firing burners are designed for
residual oxygen concentration of 10% or more in the flue gas. The
residual oxygen concentration after a gas turbine with flue gas
recirculation is typically lower than 10% and is not sufficient for
conventional supplementary firing burner. In order to enable
operation under the boundary conditions of flue gases from a gas
turbine with flue gas recirculation, the use of a low excess air
supplementary firing burner is proposed. In this context a low
excess air supplementary firing burner is a burner, which can be
operated in a gas flow with less than 10% oxygen concentration with
a low stoichiometric ratio. The stoichiometric ratio for this kind
of a low excess air supplementary firing burner should be below 2,
preferably below 1.5 or even below 1.2. Ideally this kind of burner
can operate with a stoichiometric ratio as close as possible to
1.
[0023] A conventional duct burner or an interstage burner could be
used with additional air supply at a high excess air ratio.
However, this would dilute the CO.sub.2 concentration in the flue
gas and increase the flue gas flow. It is therefore not an adequate
solution for this application.
[0024] Instead of using CO.sub.2 concentration or oxygen
concentration the CO.sub.2 content, respectively the oxygen content
can also be used in the context of this invention.
[0025] In one embodiment, the recirculation rate can be controlled
by at least one control body. This can for example be a
controllable damper or a fixed splitter with a control body like a
flap or valve in one or both of the flue gas lines downstream of
the splitter.
[0026] This allows for example to control the recirculation rate to
the highest possible rate under the conditions, that stable
complete combustion in the gas turbine can be maintained, and that
the residual oxygen concentration after the gas turbine is
sufficient to maintain stable complete combustion of the
supplementary firing.
[0027] Stable complete combustion in this context means, that CO
and unburned hydrocarbon emissions stay below the required level,
which is in the order of ppm or single digit ppms and that the
combustion pulsations stay within the normal design values.
Emission levels are typically prescribed by guarantee values.
Design values for pulsation depend on the gas turbine, operating
point, and combustor design, as well as on the pulsation frequency.
They should remain well below 10% of the combustor pressure.
Typically they stay below 1 or 2% of the combustor pressure.
[0028] The recirculation rate can for example also be used to
control the oxygen concentration of the compressor inlet gases
after mixing ambient air with the recirculation flow. The target
oxygen concentration of the inlet gasses can for example be a fixed
value, which is sufficient to assure stable, complete combustion in
the gas turbine under all operating conditions.
[0029] In a further embodiment, the target oxygen concentration of
the flue gases is a function of relative load of the supplementary
firing. It can be minimized according to the requirements of the
gas turbine as long as the supplementary firing is switched off.
Once supplementary firing is switched on, the requirements of the
gas turbine and of the supplementary firing have to be considered.
The larger one of the two requirements determines the target
residual oxygen concentration of the flue gas. The required
residual oxygen concentration for the supplementary firing itself
can be a fixed value or a function of the burner load of the
supplementary firing.
[0030] Further, in order to assure complete stable combustion of
the supplementary firing, introduction of additional air, and/or
oxygen enriched air, and/or oxygen into the burner or upstream of
the burner of the supplementary firing is proposed.
[0031] In a further embodiment the recirculation rate can be a
fixed rate or determined independently of the supplementary firing.
In order to assure complete stable combustion of the supplementary
firing under these conditions, the additional airflow, and/or
oxygen enriched airflow, and/or oxygen flow is controlled.
[0032] The additional airflow, and/or oxygen enriched airflow,
and/or oxygen flow can be a fixed flow. However, excess air or
oxygen should be avoided in the flue gases in order to keep the
efficiency of the CO.sub.2 capture high. Therefore a control of the
additional air, and/or oxygen enriched air, and/or oxygen flow is
proposed.
[0033] In one embodiment the additional airflow, and/or oxygen
enriched airflow, and/or oxygen flow is controlled as a function of
the flue gas recirculation rate.
[0034] In another embodiment the additional airflow, and/or oxygen
enriched airflow, and/or oxygen flow is controlled as a function of
residual oxygen concentration of the flue gases of the gas
turbine.
[0035] In a further embodiment the additional airflow, and/or
oxygen enriched airflow, and/or oxygen flow is controlled as a
function of the relative load of the supplementary firing.
[0036] Further parameters, such as the flue gas temperatures before
and after the supplementary firing, the flue gas flow velocity etc.
can be used.
[0037] A combination of the above control parameters and targets is
possible. For example good operation conditions for the
supplementary firing can be obtained with a combination of control
as function of residual oxygen concentration of the flue gases and
of load of supplementary firing.
[0038] To optimize the efficiency the additional ambient air flow,
and/or oxygen enriched airflow, and/or oxygen flow is preheated by
low-grade heat from a water steam cycle of the combined cycle power
plant, and/or the CO.sub.2 capture system, and/or the flue
gases.
[0039] Besides the method, a corresponding combined cycle power
plant (CCPP) is also part of the invention.
[0040] The CCPP comprises at least one gas turbine, one HRSG, one
steam turbine, CO.sub.2 capture system and a supplementary firing.
Further, it comprises one recirculation line and one flue gas line
to the CO.sub.2 capture system.
[0041] According to one embodiment a low excess air supplementary
firing is provided in the HRSG of the combined cycle power
plant.
[0042] In a further embodiment ambient air, and/or oxygen enriched
air, and/or oxygen supply lines to the low excess supplementary
firing is provided.
[0043] Additionally, an oxygen enrichment plant and/or an air
separation unit can be provided.
[0044] Further, at least one oxygen measurement or CO.sub.2
measurement device can be installed to measure the oxygen
concentration or CO.sub.2 concentration of the inlet gases of the
compressor inlet gas and/or to measure the residual oxygen
concentration of the hot flue gases of the gas turbine and/or to
measure the residual oxygen concentration of the flue gases from
the HRSG.
[0045] In addition to compensating power losses due to the CO.sub.2
capture, the supplementary firing can also be used to increase the
plant flexibility and to provide power to compensate the influence
of variations in the ambient conditions or to cover periods of peak
power demand.
[0046] Typically, the recirculated flue gas has to be further
cooled after the HRSG by a re-cooler before mixing it with ambient
air for reintroduction into the compressor of the gas turbine. In
one embodiment the control body for controlling the recirculation
rate is installed downstream of this re-cooler to reduce thermal
load on this control body.
DETAILED DESCRIPTION
[0047] A power plant for execution of the proposed method includes
a conventional CCPP, equipment for flue gas recirculation, a
supplementary firing 10, plus a CO.sub.2 capture system 18.
[0048] A typical arrangement with post combustion capture, flue gas
recirculation, and supplementary firing 10 is shown in FIG. 1. A
gas turbine 6, which drives a first generator 25, is supplied with
compressor inlet gas 3, and fuel 5. The compressor inlet gas 3 is a
mixture of ambient air 2, and a first partial flow 21 of the flue
gases, which is recirculated via a flue gas recirculation line. The
inlet gas is compressed in the compressor 1. The compressed gas is
used for combustion of fuel 5 in a combustor 4, and pressurized hot
gasses expand in a turbine 7. Its main outputs are electric power,
and hot flue gasses 8.
[0049] The gas turbine's hot flue gasses 8 pass through a HRSG 9,
which generates steam 30 for a steam turbine 13. In the HRSG 9 or
the flue gas duct from the gas turbine 6 to the HRSG 9
supplementary firing 10 is integrated. The supplementary firing is
supplied with fuel gas 12 and ambient air/oxygen 11.
[0050] The steam turbine 13 either is arranged in a single shaft
configuration with the gas turbine 6 and the first generator 25, or
is arranged in a multi shaft configuration to drive a second
generator 26. Further, steam is extracted from the steam turbine 13
and supplied via a steam line 15 to a CO.sub.2 capture system 18.
The steam is returned to the steam cycle as a condensate via a
return line 17 and is reintroduced into the steam cycle. The steam
cycle is simplified and shown schematically without different steam
pressure levels, feed water pumps, etc., as these are not subject
of the invention.
[0051] A first partial flow 21 of the flue gases 19 from the HRSG 9
is recirculated to the inlet of the compressor 1 of the gas turbine
6 where it is mixed with ambient air 2. The first partial flow 21
is cooled in the recirculation flue gas cooler 27 before mixing
with the ambient air 2.
[0052] A second partial flow 20 of the flue gases 19 from the HRSG
9 is directed to the CO.sub.2 capture system 18 by a damper 29.
[0053] A CO.sub.2 capture system 18 typically consists of a
CO.sub.2 absorption unit, in which CO.sub.2 is removed from the
flue gas by an absorbent, and a regeneration unit, in which the
CO.sub.2 is released from the absorbent. Depending on the
temperature of the second partial flow 20 of the flue gases, and
the operating temperature range of the CO.sub.2 absorption unit, a
flue gas cooler 23 might also be required.
[0054] The CO.sub.2 depleted flue gas 22 is released from the
CO.sub.2 capture system 18 to a stack 32. In case the CO.sub.2
capture system 18 is not operating, operating at part load, and to
increase operational flexibility, the flue gases from the HRSG can
be bypassed or partly bypassed via the flue gas bypass 24.
[0055] In normal operation the captured CO.sub.2 31 will be
compressed in a CO.sub.2 compressor and the compressed CO.sub.2
will be forwarded for storage or further treatment.
[0056] Measurement devices to measure the oxygen concentration
and/or CO.sub.2 concentration are proposed in order to better
control the residual oxygen concentration. For example, an inlet
air CO.sub.2 and/or O.sub.2 measurement device 36 can be applied
for better control of inlet gas composition for the gas turbine 6.
For the control of the gas turbine's flue gas composition a gas
turbine flue gas CO.sub.2 and/or O.sub.2 measurement device 37 can
for example be applied. To control the gas composition of the HRSG
flue gas 19 a HRSG flue gas CO.sub.2 and/or O.sub.2 measurement
device 38 can for example be applied.
[0057] An example of a supplementary firing 10 for burning fuel gas
12 with ambient air at low excess air ratio and with oxygen/oxygen
enriched air 11 in an HRSG 9 is shown in FIG. 2. In the shown
example burner boxes 28 for supplementary firing are arranged
traversal, spaced apart in arrays in a cross section of the HRSG
inlet 33 or inside the HRSG. Gas turbine flue gas 8 passes past the
burner boxes 28 through the passages between the boxes while the
flame of the supplementary firing is stabilized in them. Additional
ambient air or oxygen 11 as well as fuel gas 12 are supplied to the
burner boxes and injected via the fuel gas injection orifices 34
and the oxidizer injection orifices 35. Typically, oxygen is not
injected directly into burner boxes 28 but diluted with some
carrier gas like ambient air or recirculated flue gas before it
comes into contact with the fuel gas 12.
[0058] In a conventional CCPP with HRSG and supplementary firing
the oxygen concentration of the flue gases of the gas turbine 8 is
not controlled and independent of the operation of supplementary
firing. The supplementary firing typically is simply switched on,
after the gas turbine reaches base load and operated independently
of the gas turbine 8. Base load is typically the operating
condition with the lowest residual oxygen concentration in the flue
gases. The oxygen concentration stays practically constant at this
level and only slight changes due to changes in the ambient
conditions occur. However, this approach is not feasible with flue
gas recirculation and minimized residual oxygen concentration in
the hot flue gases from the gas turbine 8, as conventional
supplementary firing does not work properly under these
conditions.
[0059] In a first approach to maximize the CO.sub.2 concentration
of the flue gases 19 from the HRSG 9 with supplementary firing, the
residual oxygen concentration after gas turbine GT.sub.O2 is
controlled as a function of the relative load of the supplementary
firing as shown in FIG. 3. It is normalized with the minimum
residual oxygen concentration of the flue gas from the gas turbine
8, which would be reached if the gas turbine 6 were operated at the
recirculation limit of the gas turbines. For operation of the
supplementary firing the residual oxygen concentration after gas
turbine GT.sub.O2 is higher than the minimum residual oxygen
concentration of the flue gas required for the gas turbine
operation. Therefore the recirculation rate is restricted to allow
supplementary firing.
[0060] In this case, no additional ambient air flow, and/or oxygen
enriched air flow, and/or oxygen flow 11 is supplied to the
supplementary firing 10. The amount of residual oxygen content and
concentration required to assure stable, complete combustion with
low CO and unburned hydrocarbon emissions depends on the
temperature level and amount of fuel gas, which needs to react. At
low relative load of the supplementary firing 10, the temperature
is low and a relatively high oxygen concentration is required to
assure complete combustion. This leads to a high residual oxygen
concentration after the supplementary firing SF.sub.O2. With
increasing load, the flame temperature increases and the required
oxygen concentration drops until it reaches a minimum. For high
relative load of the supplementary firing 10 the required oxygen
concentration increases again and is proportional to the injected
fuel gas flow. Depending on the design of the supplementary firing,
the required residual oxygen concentration varies as a function of
load. For example, a required oxygen concentration, which is
proportional to the load, is possible. Further, the load range
might be restricted to higher loads, e.g. 40% to 100% load. In any
case, in order to maximize the resulting CO.sub.2 after
supplementary firing, a variation of the residual oxygen
concentration of the flue gases from the gas turbine (GT) 8 is
needed. This increases the complexity of the control integration,
and can lead to combustion instabilities in the GT. Further, it
leads to variation in the second partial flow 20 of the flue gases,
which flows to the CO.sub.2 capture system 18, as a function of the
relative load of the supplementary firing. The required residual
oxygen concentration for the supplementary firing can limit the
recirculation ration and result in an increased maximum second
partial flow 20.
[0061] In a proposed second approach, supplementary firing with
additional ambient air, oxygen enriched air or oxygen flow
F.sub.air from an oxygen enrichment plant/air separation unit 40 is
applied. As schematically shown in FIG. 4, the normalized residual
oxygen concentration of the gas turbine flue gas GT.sub.O2 required
for supplementary firing over relative load of the supplementary
firing SF.sub.load can be kept constant independently of relative
load of the supplementary firing. Therefore no complex control
interface or logic between the gas turbine and supplementary firing
is needed.
[0062] In this proposed second approach, the fuel gas is burned in
the supplementary firing burner with an additional ambient airflow,
oxygen enriched airflow or oxygen flow F.sub.air. The supplementary
firing burner can thereby work independently from gas turbine flue
gas oxygen concentration and produces flue gas at low O.sub.2 and
high CO.sub.2 concentrations. With this method it can be assured
that after mixing the flue gases of the supplementary firing with
flue gases of the gas turbine flue, the CO.sub.2 concentration in
the resulting flue gas mixture will not be or only very slightly
diluted. Thus the flue gas recirculation rate could and shall be
designed at its maximum allowed value to keep the minimal oxygen
concentration i.e. the highest CO.sub.2 concentration in the gas
turbine flue gases while sending the minimum amount of flue gas
from CCPP to the CO.sub.2 capture plant.
[0063] Further, the normalized additional ambient air, oxygen
enriched air or oxygen flow F.sub.air required to assure stable and
complete combustion is also shown in FIG. 4. It is normalized with
the additional ambient air or oxygen flow required at 100% load. At
low relative load of the supplementary firing 10, the temperature
is low and a relatively high ambient airflow, oxygen enriched
airflow or oxygen flow F.sub.air is required to assure complete
combustion. It is typically well above stoichiometric and results
in high residual oxygen concentration SF.sub.O2 after the
supplementary firing. With increasing load the flame temperature
increases and the required additional ambient airflow, oxygen
enriched airflow or oxygen flow F.sub.air only increases at a low
rate. The fuel specific additional ambient airflow, oxygen enriched
airflow or oxygen flow F.sub.air can be reduced. Ideally almost
stoichiometric combustion can be realized. For high relative load
of the supplementary firing 10 the fuel specific additional ambient
airflow, oxygen enriched airflow or oxygen flow F.sub.air stays
almost constant. The required additional ambient airflow, oxygen
enriched airflow or oxygen flow F.sub.air is mainly needed to
assure a sufficient oxygen concentration for complete combustion
and increases at a higher rate, which is proportional to the
injected fuel gas flow. Depending on the design of the
supplementary firing this dependency of required residual oxygen
concentration as a function of load varies. Further, the load range
might be restricted to higher loads, e.g. 40% to 100% load.
[0064] The resulting normalized residual oxygen concentration after
supplementary firing SF.sub.O2 is also shown in this Figure. It is
normalized with the oxygen concentration after supplementary firing
SF.sub.O2 at 100% load. For this example it reaches a minimum at
100% load. At 100% load the combustion temperature is highest,
which facilitates a fast complete combustion down to very low
residual oxygen concentration and corresponding high CO.sub.2
concentration.
[0065] In general the CO.sub.2 concentration is inversely
proportional to the residual oxygen concentration, and low oxygen
concentration corresponds to a high CO.sub.2 concentration.
[0066] The CO.sub.2 and the residual oxygen concentration at
different locations of the thermodynamic process of a CCPP can be
determined using main process parameters. Based on the inlet mass
flow, the recirculation rate, the fuel mass flows, mass flow of
ambient airflow, oxygen enriched airflow or oxygen flow F.sub.air
injected, and the combustion efficiency, the oxygen concentration
and CO.sub.2 concentration in the inlet gas, after the gas turbine,
and after the supplementary firing can be estimated. These
estimated values are used in one embodiment of the invention.
[0067] Since the inlet mass flow of a gas turbine is difficult to
measure one normally has to rely on compressor characteristics to
determine the inlet mass flow. Due to compressor ageing the real
inlet mass flow can differ from the value of the characteristics.
Further, the fuel's heating value depends on the fuel gas
composition, which can change over time. Therefore either
additional measurements like on line fuel gas analysis have to be
applied or considerable uncertainties have to be taken into
account. For practical reasons it is therefore often easier to
measure the gas compositions directly. These measurements are part
of a further embodiment. Corresponding measurement devices were
indicated in FIG. 1.
[0068] Besides conventional gas chromatography there are several
different methods, systems, and measurement devices to measure the
oxygen concentration and CO.sub.2 concentration of the different
gas streams. CO.sub.2 can for example easily be measured using
Nondispersive Infrared (NDIR) CO.sub.2 Sensors, or Chemical
CO.sub.2 Sensors. Oxygen concentration can, among others, be
measured using zirconia, electrochemical or Galvanic, infrared,
ultrasonic sensors, and laser technology. Fast online sensors can
be applied for optimized operation.
[0069] Exemplary embodiments described above and in the drawings
disclose to a person skilled in the art embodiments, which differ
from the exemplary embodiments and which are contained in the scope
of the invention.
[0070] For example, blowers might be advantageous for first partial
flow 21 of the flue gases, which is recirculation or for the second
partial flow 20 of the flue gases, which flows to the CO.sub.2
capture system 18. Without blowers the pipes and equipment size
needed to allow sufficient flow with existing pressure differences
might become prohibitive.
[0071] Further, when an additional ambient airflow, oxygen enriched
airflow or oxygen flow F.sub.air is used for the supplementary
firing this flow can be preheated by low grade heat from the water
steam cycle, and/or the CO.sub.2 capture system 18, and/or the flue
gases by a preheater 39. Return condensate from intermediate
pressure feed water can for example be utilized for this.
[0072] Further, one could replace dampers or other control bodies,
which inherently lead to a pressure drop, by controlled blowers.
These could for example be variable speed blowers or blowers with
controllable blade or guide vane angles.
LIST OF REFERENCE SYMBOLS
[0073] 1 Compressor [0074] 2 Ambient air [0075] 3 Compressor inlet
gas [0076] 4 Combustor [0077] 5 Fuel gas for GT [0078] 6 Gas
turbine (GT) [0079] 7 Turbine [0080] 8 Hot flue gas from gas
turbine [0081] 9 HRSG (heat recovery steam generator) [0082] 10 Low
excess air supplementary firing (SF) [0083] 11 Ambient air, and/or
oxygen enriched air, and/or oxygen [0084] 12 Fuel gas for
supplementary firing [0085] 13 Steam turbine [0086] 14 Condenser
[0087] 15 Steam extraction for CO.sub.2 capture [0088] 16 Feed
water [0089] 17 Condensate return line [0090] 18 CO.sub.2 capture
system [0091] 19 Flue gas from HRSG [0092] 20 Second partial flow
(Flue gas CO.sub.2 capture system) [0093] 21 First partial flow
(Flue gas recirculation) [0094] 22 CO.sub.2 depleted flue gas
[0095] 23 Flue gas cooler [0096] 24 Flue gas bypass to stack [0097]
25 First generator [0098] 26 Second generator [0099] 27
Recirculation flue gas cooler [0100] 28 Burner box [0101] 29 Damper
[0102] 30 Steam [0103] 31 Captured CO.sub.2 [0104] 32 Stack [0105]
33 Cross section of HRSG inlet [0106] 34 Fuel gas injection
orifices [0107] 35 Oxidizer injection orifices [0108] 36 Inlet air
CO.sub.2 and/or O.sub.2 measurement devices [0109] 37 Gas turbine
flue gas CO.sub.2 and/or O.sub.2 measurement devices [0110] 38 HRSG
flue gas CO.sub.2 and/or O.sub.2 measurement devices [0111] 39
Preheater [0112] 40 Oxygen enrichment plant/air separation unit
[0113] CCPP Combined cycle power plant [0114] SF.sub.load Relative
load of supplementary firing (SF) [0115] GT.sub.O2 Normalized
residual oxygen concentration after GT [0116] SF.sub.O2 Normalized
residual oxygen concentration after SF [0117] F.sub.air Normalized
supplementary air/oxygen enriched air/oxygen flow
* * * * *