U.S. patent application number 13/662242 was filed with the patent office on 2013-03-07 for bifacial solar cells with overlaid back grid surface.
This patent application is currently assigned to Silicor Material Inc.. The applicant listed for this patent is Silicor Material Inc.. Invention is credited to Alain Paul Blosse, Peter Borden, Martin Kaes, Fritz G. Kirscht, Andreas Kraenzl, Kamel Ounadjela.
Application Number | 20130056061 13/662242 |
Document ID | / |
Family ID | 43029508 |
Filed Date | 2013-03-07 |
United States Patent
Application |
20130056061 |
Kind Code |
A1 |
Kaes; Martin ; et
al. |
March 7, 2013 |
BIFACIAL SOLAR CELLS WITH OVERLAID BACK GRID SURFACE
Abstract
A simplified manufacturing process and the resultant bifacial
solar cell (BSC) are provided, the simplified manufacturing process
reducing manufacturing costs. The BSC includes an active region
located on the front surface of the substrate, formed for example
by a phosphorous diffusion step. After removing the PSG, assuming
phosphorous diffusion, and isolating the front junction, dielectric
layers are deposited on the front and back surfaces. Contact grids
are formed, for example by screen printing. Prior to depositing the
back surface dielectric, a metal grid may be applied to the back
surface, the back surface contact grid registered to, and alloyed
to, the metal grid during contact firing.
Inventors: |
Kaes; Martin; (Berlin,
DE) ; Borden; Peter; (San Mateo, CA) ;
Ounadjela; Kamel; (Belmont, CA) ; Kraenzl;
Andreas; (Radolfzell, DE) ; Blosse; Alain Paul;
(San Mateo, CA) ; Kirscht; Fritz G.; (Berlin,
DE) |
|
Applicant: |
Name |
City |
State |
Country |
Type |
Silicor Material Inc.; |
Palo Alto |
CA |
US |
|
|
Assignee: |
Silicor Material Inc.
Palo Alto
CA
|
Family ID: |
43029508 |
Appl. No.: |
13/662242 |
Filed: |
October 26, 2012 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
|
|
12456378 |
Jun 15, 2009 |
8298850 |
|
|
13662242 |
|
|
|
|
61215199 |
May 1, 2009 |
|
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Current U.S.
Class: |
136/256 |
Current CPC
Class: |
H01L 31/18 20130101;
H01L 31/1804 20130101; Y02E 10/547 20130101; H01L 31/022425
20130101; H01L 31/068 20130101; H01L 31/0684 20130101; Y02P 70/521
20151101; Y02P 70/50 20151101 |
Class at
Publication: |
136/256 |
International
Class: |
H01L 31/0224 20060101
H01L031/0224 |
Claims
1. A bifacial solar cell, comprising: a silicon substrate with a
front surface and a back surface; an active region of a first
conductivity type located on at least a portion of said front
surface of said silicon substrate; a first dielectric layer
deposited on said active region; a second dielectric layer
deposited on said back surface of said silicon substrate; a first
contact grid applied to said first dielectric layer, said first
contact grid comprised of a first metal, wherein after a firing
step said first contact grid is alloyed through said first
dielectric layer to said active region; and a second contact grid
applied to said second dielectric layer, said second contact grid
comprised of a second metal, wherein after said firing step said
second contact grid is alloyed through said second dielectric layer
to said back surface of said silicon substrate.
2. The bifacial solar cell of claim 1, further comprising a
floating junction of said first conductivity type located on at
least a portion of said back surface of said silicon substrate.
3. The bifacial solar cell of claim 1, wherein said silicon
substrate is comprised of a p-type silicon, said active region is
comprised of n.sup.+ material resulting from a phosphorous
diffusion step, and said first and second dielectric layers are
selected from the group consisting of silicon nitride, silicon
oxide and silicon oxynitride.
4. The bifacial solar cell of claim 1, further comprising a grid
pattern of a third metal deposited directly on said back surface of
said silicon substrate and interposed between said back surface of
said silicon substrate and said second dielectric layer, wherein
said second screen printed contact grid is registered to said grid
pattern, and wherein after said firing step said second screen
printed contact grid is alloyed through said second dielectric
layer to said grid pattern of said third metal.
5. The bifacial solar cell of claim 1, further comprising a groove
on said front surface of said silicon substrate, said groove
isolating a front junction formed by said active region and said
silicon substrate.
6. A bifacial solar cell, comprising: a silicon substrate with a
front surface and a back surface; an active region of a first
conductivity type located on at least a portion of said front
surface of said silicon substrate; a first dielectric layer
deposited on said active region; a second dielectric layer
deposited on said back surface of said silicon substrate; a first
metal contact grid on the first dielectric layer; a second metal
contact grid on the second dielectric layer; and a back surface
contact grid aligned with the second metal contact grid.
7. The bifacial solar cell of claim 6, wherein the active region of
the first conductivity type includes an n-type active region.
8. The bifacial solar cell of claim 6, wherein the active region
has a depth between approximately 0.3 and 0.6 microns.
9. The bifacial solar cell of claim 6, wherein the first dielectric
layer includes silicon oxynitride.
10. The bifacial solar cell of claim 6, wherein the second
dielectric layer includes silicon oxynitride.
11. The bifacial solar cell of claim 6, wherein the first
dielectric layer includes a laminate of more than one dielectric
material.
12. The bifacial solar cell of claim 6, wherein the laminate
includes approximately 10 nanometers of silicon dioxide and
approximately 70 nanometers of silicon nitride.
13. The bifacial solar cell of claim 6, wherein the first metal
contact grid includes silver.
14. The bifacial solar cell of claim 6, wherein the second metal
contact grid includes aluminum.
15. A bifacial solar cell, comprising: a silicon substrate with a
front surface and a back surface; an active region of a first
conductivity type located on at least a portion of said front
surface of said silicon substrate; a first dielectric layer
deposited on said active region; a second dielectric layer
deposited on said back surface of said silicon substrate; a first
metal contact grid on the first dielectric layer; and a second
metal contact grid on the second dielectric layer, wherein the
first metal contact grid is aligned to the second metal contact
grid, and the second metal contact grid uses a finer spacing than
the first metal contact grid.
16. The bifacial solar cell of claim 15, wherein the second metal
contact grid includes aluminum.
17. The bifacial solar cell of claim 16, wherein the second metal
contact grid includes a silver-aluminum alloy.
18. The bifacial solar cell of claim 15, further including a back
surface contact grid aligned with the second metal contact
grid.
19. The bifacial solar cell of claim 18, wherein the back surface
contact grid is alloyed to the second metal contact grid.
Description
CROSS-REFERENCE TO RELATED APPLICATION
[0001] This application is a continuation of and claims the benefit
of priority to U.S. patent application Ser. No. No. 12/456,378,
filed Jun. 15, 2009, which claims the benefit of priority to U.S.
Provisional Application Ser. No. 61,215,199, filed May 1, 2009, the
benefit of priority of each of which is claimed hereby, and each of
which are incorporated by reference herein its entirety.
FIELD OF THE INVENTION
[0002] The present invention relates generally to solar cells and,
in particular, to an improved structure and manufacturing process
for a bifacial solar cell.
BACKGROUND OF THE INVENTION
[0003] Bifacial solar cells (BSC) may use any of a variety of
different designs to achieve higher efficiencies than those
typically obtained by a conventional, monofacial solar cell. One
such design is shown in U.S. Pat. No. 5,665,175 which discloses a
BSC configuration with first and second active regions formed on
the front and back surfaces of the BSC, respectively, the two
regions separated by a distance .lamda.. The distance .lamda.
allows a leakage current to flow between the first and second
active regions, thus allowing a solar cell panel utilizing such
bifacial cells to continue to operate even if one or more
individual solar cells become shaded or defective.
[0004] U.S. Pat. No. 7,495,167 discloses an n.sup.+pp.sup.+
structure and a method of producing the same. In the disclosed
structure, the p.sup.+ layer, formed by boron diffusion, exhibits a
lifetime close to that of the initial level of the substrate. In
order to achieve this lifetime, the '167 patent teaches that after
phosphorous gettering, the cell must be annealed at a temperature
of 600.degree. C. or less for one hour or more. In order to retain
the lifetime recovered by the phosphorous and low-temperature born
gettering steps, the cell then undergoes a final heat treatment
step in which the cell is fired at a temperature of around
700.degree. C. or less for one minute or less.
[0005] U.S. Patent Application Publication No. 2005/0056312
discloses an alternative technique for achieving two or more p-n
junctions in a single solar cell, the disclosed technique using
transparent substrates (e.g., glass or quartz substrates). In one
disclosed embodiment, the BSC includes two thin-film
polycrystalline or amorphous cells formed on opposing sides of a
transparent substrate. Due to the design of the cell, the high
temperature deposition of the absorber layers can be completed
before the low temperature deposition of the window layers, thus
avoiding degradation or destruction of the p-n junctions.
[0006] Although there are a variety of BSC designs and techniques
for fabricating the same, these designs and techniques tend to be
relatively complex, and thus expensive. Accordingly, what is needed
is a solar cell design that achieves the benefits associated with
bifacial solar cells while retaining the manufacturing simplicity
of a monofacial solar cell. The present invention provides such a
design.
SUMMARY OF THE INVENTION
[0007] The present invention provides a simplified manufacturing
process and the resultant bifacial solar cell (BSC), the simplified
manufacturing process reducing manufacturing costs. In at least one
embodiment of the invention, the manufacturing method is comprised
of the steps of simultaneously diffusing phosphorous onto the front
surface of a silicon substrate to form an n.sup.+ layer and a front
surface junction and onto the back surface of the silicon substrate
to form an n.sup.+ layer and a back surface junction, removing the
phosphor-silicate glass formed during the diffusion step (e.g., by
etching with HF), depositing passivation and AR dielectric layers
on the front and back surfaces, applying front and back surface
contact grids, and firing the front and back surface contact grids.
The front and back surface contact grid firing steps may be
performed simultaneously. Alternately, the back surface contact
grid applying and firing steps may be performed prior to, or after,
the front surface contact grid applying and firing steps. The
method may further include the step of firing the back surface
contact grid through the back junction, leaving a floating
junction. The method may further include the step of removing the
back surface junction and isolating the front surface junction,
this step performed prior to depositing the back surface
dielectric. A back surface metal grid may be applied, for example
by screen printing or deposition using a shadow mask, after
removing the back surface junction and prior to depositing the
dielectric layer on the back surface.
[0008] In at least one embodiment of the invention, the
manufacturing method is comprised of the steps of depositing a
dielectric layer on the back surface of a silicon substrate,
diffusing phosphorous onto the front surface of the substrate to
form an n.sup.+ layer and a front surface junction, removing the
phosphor-silicate glass formed during the diffusion step (e.g., by
etching with HF), isolating the front surface junction using a
laser scriber, depositing a front surface passivation and AR
dielectric layer, applying front and back surface contact grids,
firing the front and back surface contact grids, and isolating the
front surface junction, for example using a laser scriber. The
front and back surface contact grid firing steps may be performed
simultaneously. Alternately, the back surface contact grid applying
and firing steps may be performed prior to, or after, the front
surface contact grid applying and firing steps.
[0009] In at least one embodiment of the invention, a bifacial
solar cell (BSC) is provided that is comprised of a silicon
substrate with a front surface active region of a first
conductivity type, dielectric layers deposited on the front surface
active region and on the back surface of the silicon substrate, a
front surface contact grid applied to the front surface dielectric,
and a back surface contact grid applied to the back surface
dielectric, where the front surface contact grid alloys through the
front surface dielectric to the active region during firing, and
where the back surface contact grid alloys through the back surface
dielectric to the back surface of the silicon substrate during
firing. The silicon substrate may be comprised of p-type silicon,
the active region may be comprised of n.sup.+ material resulting
from a phosphorous diffusion step, and the dielectric layers may be
comprised of silicon nitride, silicon oxide and/or silicon
oxynitride. The BSC may further comprise a floating back surface
junction of the first conductivity type. The BSC may further
comprise a metal grid pattern deposited directly on the back
surface of the silicon substrate, where the back surface screen
printed contact grid fires through the back surface dielectric and
makes electrical contact with the metal grid pattern during firing.
The BSC may further comprise a groove on the front surface of the
silicon substrate, the groove isolating the front surface
junction.
[0010] A further understanding of the nature and advantages of the
present invention may be realized by reference to the remaining
portions of the specification and the drawings.
BRIEF DESCRIPTION OF THE DRAWINGS
[0011] FIG. 1 illustrates a preferred embodiment of a BSC in
accordance with the invention;
[0012] FIG. 2 illustrates the process flow for the BSC of FIG.
1;
[0013] FIG. 3 illustrates an alternate process flow for the BSC of
FIG. 1;
[0014] FIG. 4 illustrates an alternate embodiment of a BSC in
accordance with the invention;
[0015] FIG. 5 illustrates the process flow for the BSC of FIG.
4;
[0016] FIG. 6 illustrates an alternate process flow for the BSC of
FIG. 4;
[0017] FIG. 7 illustrates an alternate embodiment of a BSC in
accordance with the invention; and
[0018] FIG. 8 illustrates the process flow for the BSC of FIG.
7.
DESCRIPTION OF THE SPECIFIC EMBODIMENTS
[0019] FIG. 1 illustrates a cross-sectional view of a preferred
bifacial solar cell (BSC) structure fabricated in accordance with
the procedure described in FIG. 2. Silicon substrate 101 may be of
either p- or n-type. In the illustrated device and process of FIGS.
1 and 2, a p-type substrate is used.
[0020] Initially, substrate 101 is prepared using any of a variety
of well-known substrate preparatory processes (step 201). In
general, during step 201 saw and handling induced damage is removed
via an etching process, for example using a nitric and hydrofluoric
(HF) acid mixture. After substrate preparation, phosphorous is
diffused onto the front surface of substrate 101, creating n.sup.+
layer 103 and a p-n junction at the interface of substrate 101 and
n.sup.+ layer 103. During this step, phosphorous is also diffused
onto the back surface of substrate 101, creating n.sup.+ layer 104
and a floating junction. Preferably n.sup.+ layer 103 is formed
using phosphoryl chloride (POCl.sub.3) with a diffusion temperature
in the range of 825.degree. C. to 890.degree. C., preferably at a
temperature of approximately 850.degree. C., for 10 to 20 minutes
in a nitrogen atmosphere (step 203). The phosphor-silicate glass
(PSG) formed during diffusion step 203 is then etched away,
preferably using an HF etch at or near room temperature for 1 to 5
minutes (step 205). In the preferred embodiment, the front and back
surface junctions have a depth of 0.3 to 0.6 microns and a surface
doping concentration of about 8.times.10.sup.21/cm.sup.3.
[0021] In step 207, a front surface passivation and anti-reflection
(AR) dielectric layer 105 is deposited as well as a back surface
passivation and AR dielectric layer 107, each layer preferably
being approximately 76 nanometers thick. In the exemplary
embodiment, layers 105 and 107 are comprised of silicon nitride
with an index of refraction of 2.07. In an alternate embodiment,
layers 105 and 107 are comprised of silicon oxynitride. In another
alternate embodiment, layers 105 and 107 are comprised of a stack
of two layers of different composition, for example 10 nanometers
of silicon dioxide and 70 nanometers of silicon nitride. Layers 105
and 107 are preferably deposited at a temperature of 300.degree. C.
to 400.degree. C.
[0022] After deposition of the dielectric layers, contact grids are
applied to the front and back surfaces of BSC 100 (step 209), for
example using a screen printing process. In the exemplary
embodiment, front contact grid 109 is comprised of silver while
back contact grid 111 is comprised of aluminum. In the preferred
embodiment, both the front and back contact grids are aligned and
use the same contact size and spacing, with electrodes being
approximately 100 microns wide, 15 microns thick and spaced
approximately 2.5 millimeters apart. In at least one alternate
embodiment, the back contact grid uses a finer spacing in order to
lessen resistance losses from lateral current flow in the
substrate. Lastly, a contact firing step 211 is performed,
preferably at a peak temperature of 750.degree. C. for 3 seconds in
air. As a result of this process, contacts 109 alloy through
passivation and AR dielectric coating 105 to n.sup.+ layer 103.
Contacts 111 alloy through passivation and AR dielectric coating
107 and back diffused layer 104 to form contact to substrate 101.
As aluminum is a p-type dopant, a diode forms between back diffused
layer 104 and contact 111 so that current does not flow from the
back diffused layer into the contact and the back diffusion is
floating. This isolates the back surface from the bulk 101 since
there is zero current into a floating junction.
[0023] FIG. 3 illustrates an alternate process for fabricating cell
100. As illustrated, in this process the front surface and back
surface contact grids are applied and fired separately, thereby
allowing different firing conditions to be used for each grid.
Preferably contact grid 111 is applied (step 301) and fired (step
303) first, followed by the application of contact grid 109 (step
305) and firing of the front contact grid (step 307).
[0024] FIGS. 4 and 5 illustrate an alternate embodiment in which
the floating junction on the back surface of the substrate is
removed. In structure 400, after formation of the front junction
and PSG etching, the back surface of substrate 101 is etched (step
501), thereby removing the back surface junction and providing
isolation for the front junction. In a preferred embodiment, step
501 uses an isotropic wet silicon etch such as a mixture of nitric
acid and HF acid. After removal of the back surface floating
junction, the process continues as previously described relative to
either FIGS. 2 and 3. Preferably in this embodiment the back
surface contact grid is comprised of an aluminum-silver
mixture.
[0025] FIG. 6 illustrates an alternate process for fabricating cell
400. In this process, after preparation of substrate 101 (step
201), dielectric layer 107 is applied to the back surface of
substrate 101 (step 601). As previously described, preferably
dielectric layer 107 is comprised of silicon nitride or silicon
oxynitride. Applying dielectric layer 107 prior to diffusing the
front surface n.sup.+ layer 103 (step 203) prevents the formation
of a back surface junction. After the front surface diffusion (step
203) and the PSG etch (step 205), the front surface passivation and
AR dielectric layer 105 is deposited (step 603), followed by
application (step 209) and firing (step 211) of the contact grids.
Lastly, the front junction is isolated (step 605), for example
using a laser scriber to form a groove on the front cell surface
around the periphery of the cell. This embodiment can also separate
the screen printing and firing of the front and back surface
contact grids as described relative to FIG. 3.
[0026] FIGS. 7 and 8 illustrate a variation of BFC 400. As shown in
the BFC cross-sectional view of BFC 700, a metal grid 701 is
applied directly onto the back surface of cell 101 (step 801),
thereby reducing contact resistance. Step 801 is preferably
performed after the back surface of substrate 101 has been etched
to remove the back surface junction and isolate the front junction
(step 501). Step 801 is performed using either a deposition process
with a shadow mask, or using a screen printing process. Preferably,
metal grid 701 is comprised of aluminum. After depositing
dielectric layers 105 and 107 (step 207), contact grids 109 and 111
are applied and fired, either together as shown in FIG. 6 and
described relative to FIG. 2, or separately as described relative
to FIG. 3. Regardless of whether the contact formation process
follows that shown in FIG. 2 or FIG. 3, it will be understood that
back surface contact grid 111 is registered to metal grid 501.
During the firing step, contact grid 111 alloys to metal grid
501.
[0027] As will be understood by those familiar with the art, the
present invention may be embodied in other specific forms without
departing from the spirit or essential characteristics thereof
Accordingly, the disclosures and descriptions herein are intended
to be illustrative, but not limiting, of the scope of the
invention.
* * * * *