U.S. patent application number 13/330189 was filed with the patent office on 2012-05-24 for solvent-based ink composition with ketone solvent and surface-modified pigment.
This patent application is currently assigned to Silverbrook Research Pty Ltd. Invention is credited to Adrian Bisson, Iain Blake, Simon Fielder, Alexander Grant, Kia Silverbrook.
Application Number | 20120127240 13/330189 |
Document ID | / |
Family ID | 43730862 |
Filed Date | 2012-05-24 |
United States Patent
Application |
20120127240 |
Kind Code |
A1 |
Grant; Alexander ; et
al. |
May 24, 2012 |
SOLVENT-BASED INK COMPOSITION WITH KETONE SOLVENT AND
SURFACE-MODIFIED PIGMENT
Abstract
A solvent-based ink composition for a thermal inkjet printhead.
The composition includes: (a) 10-80 wt. % of a compound of formula
(B): ##STR00001## wherein: R.sup.5 is a C.sub.1-6 alkyl group and
R.sup.6 is a C.sub.1-6 alkyl group; or R.sup.5 and R.sup.6 are
together joined to form a C.sub.3-12 cycloalkylene group; (b) 10-80
wt. % of a C.sub.1-6 alcohol; and (c) 0.01-25 wt. % of a
surface-modified pigment.
Inventors: |
Grant; Alexander; (Balmain,
AU) ; Bisson; Adrian; (Dublin, IE) ; Blake;
Iain; (Dublin, IE) ; Fielder; Simon; (Balmain,
AU) ; Silverbrook; Kia; (Balmain, AU) |
Assignee: |
Silverbrook Research Pty
Ltd
|
Family ID: |
43730862 |
Appl. No.: |
13/330189 |
Filed: |
December 19, 2011 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
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12613404 |
Nov 5, 2009 |
8080102 |
|
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13330189 |
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12557517 |
Sep 11, 2009 |
8101012 |
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12613404 |
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Current U.S.
Class: |
347/56 ;
106/31.86; 347/86; 428/319.3; 428/500 |
Current CPC
Class: |
Y10T 428/31855 20150401;
C09D 11/322 20130101; C09D 11/36 20130101; Y10T 428/24802 20150115;
Y10T 428/249991 20150401 |
Class at
Publication: |
347/56 ;
106/31.86; 428/319.3; 428/500; 347/86 |
International
Class: |
B41J 2/05 20060101
B41J002/05; B41J 2/175 20060101 B41J002/175; B32B 27/30 20060101
B32B027/30; C09D 11/02 20060101 C09D011/02; B32B 5/18 20060101
B32B005/18 |
Claims
1. A solvent-based ink composition for a thermal inkjet printhead
comprising: (a) 10-80 wt. % of a compound of formula (B);
##STR00015## wherein: R.sup.5 is a C.sub.1-6 alkyl group and
R.sup.6 is a C.sub.1-6 alkyl group; or R.sup.5 and R.sup.6 are
together joined to form a C.sub.3-12 cycloalkylene group; (b) 10-80
wt. % of a C.sub.1-6 alcohol; and (c) 0.01-25 wt. % of a
surface-modified pigment.
2. The ink composition of claim 1, wherein the compound of formula
(B) is methylethylketone.
3. The ink composition of claim 1, wherein the compound of formula
(B) is cyclohexanone.
4. The ink composition of claim 1, wherein said C.sub.1-6 alcohol
is ethanol.
5. The ink composition of claim 1, wherein said pigment has a
surface modified with an anionic or a cationic group.
6. The ink composition of claim 1, wherein said surface is modified
with a carboxylate group or a sulfonate group.
7. The ink composition of claim 1, comprising 0.001-10 wt. % of a
surfactant or dispersant.
8. The ink composition of claim 7, wherein said surfactant or
dispersant is nonionic.
9. The ink composition of claim 1, wherein said composition does
not comprise an acrylate polymer or copolymer.
10. The ink composition of claim 1, wherein said composition does
not comprise any polymers.
11. The ink composition of claim 1, consisting essentially of said
compound of formula (B), said C.sub.1-6 alcohol and said
colorant.
12. An ink cartridge for a thermal inkjet printhead, said ink
cartridge containing the solvent-based ink composition according to
claim 1.
13. A printhead cartridge comprising a thermal inkjet printhead
integrated therewith and an ink reservoir containing the ink
composition according to claim 1.
14. A substrate having an ink composition according to claim 1
disposed thereon.
15. The substrate of claim 14, which is a semi-porous or non-porous
substrate.
16. The substrate of claim 15, which is a vinyl substrate.
17. A method of ejecting ink from a thermal inkjet printhead, said
method comprising the steps of: (i) supplying an ink to at least
one nozzle chamber of the printhead; and (ii) actuating a heater
element in the nozzle chamber so as to heat a portion of the ink to
a temperature sufficient to form a bubble therein, thereby causing
a droplet of ink to be ejected from a nozzle opening associated
with the nozzle chamber, wherein the ink is the solvent-based ink
composition according to claim 1.
Description
CROSS REFERENCE TO RELATED APPLICATION
[0001] This application is a continuation of U.S. application Ser.
No. 12/613,404 filed Nov. 5, 2009, which is a continuation-in-part
of U.S. application Ser. No. 12/557,517 filed Sep. 11, 2009, all of
which is herein incorporated by reference.
FIELD OF THE INVENTION
[0002] This invention relates to inkjet inks for thermal inkjet
printers. It has been developed primarily to enable thermal inkjet
printing onto a wide range of substrates, including non-porous
substrates.
CROSS REFERENCES
[0003] The following patents or patent applications filed by the
applicant or assignee of the present invention are hereby
incorporated by cross-reference.
TABLE-US-00001 6,755,509 7,222,943 7,188,419 7,168,166 7,086,719
7,669,980 7,832,844 7,246,886 7,128,400 7,108,355 6,991,322
7,287,836 7,118,197 7,575,298 7,364,269 7,077,493 6,962,402
7,686,429 7,147,308 7,524,034 7,118,198 7,168,790 7,172,270
7,229,155 6,830,318 7,195,342 7,175,261 7,465,035 7,108,356
7,118,202 7,510,269 7,134,744 7,134,743 7,182,439 7,210,768
7,465,036 7,134,745 7,156,484 7,118,201 7,111,926 7,431,433
7,401,901 7,468,139 7,581,822 7,669,961 7,328,978 7,334,876
7,147,306 7,448,734 7,425,050 7,621,620 7,249,822 7,331,663
7,360,861 7,328,973 7,427,121 7,407,262 7,303,252 7,429,096
7,537,309 7,311,382 7,360,860 7,364,257 7,390,075 7,350,896
7,311,381 7,384,135 7,331,660 7,416,287 7,488,052 7,322,684
7,322,685 7,588,301 7,270,405 7,303,268 7,470,007 7,399,072
7,393,076 7,681,967 7,357,492 7,249,833 7,524,016 7,490,927
7,331,661 7,524,043 7,300,140 7,390,080 7,357,493 7,566,106
7,380,902 7,284,816 7,284,845 7,255,430 7,585,054 7,328,984
7,350,913 7,322,671 7,380,910 7,431,424 7,470,006 7,837,297
7,347,534 7,441,865 7,469,989 7,367,650 7,469,990 11/688,863
7,832,838 7,475,976 7,364,265 7,721,441 12/014,767 12/014,768
12/014,769 8,011,755 7,862,162 7,758,149 12/049,371 12/557,517
7,845,755 7,922,279 12/339,039
BACKGROUND OF THE INVENTION
[0004] Thermal bubble-forming inkjet printheads function by
generating a certain amount of heat in the printing fluid contained
in a nozzle chamber. This heat causes a bubble to form which
eventually collapses as the fluid is forced through a nozzle. The
collapse of the bubble then causes more fluid to enter the nozzle
chamber for the same process to begin again.
[0005] Due to the ability of water to form rapidly a bubble at
elevated temperature, printers equipped with such thermal inkjet
printheads typically use water-based ink formulations.
[0006] However, although it is possible to print directly onto
specially treated non-porous and semi-porous substrates,
water-based inkjet inks are essentially limited to applications
that use porous media, such as office papers and textiles.
Accordingly, most printers that use thermal inkjet printheads are
usually for the SOHO (small office home office) market.
[0007] In contrast, piezo printheads offer a wide degree of ink
formulation flexibility, since droplet ejection occurs through a
piezoelectric force rather than a bubble forming mechanism. Because
of this, many different ink chemistries can be used in piezo
printheads, such as UV curable, solvent-based, hot-melt and
oil-based, as well as water-based. The output from the piezo
printers is equally diverse, addressing a host of graphics market
segments including packaging, wide format displays, CD and glass
decoration. Taking wide-format printing as an example, there are a
large number of solvent-based printers on the market all of which
use piezo printheads. These print onto a range of media, including
low cost non-porous and semi-porous substrates such as uncoated
vinyls and polyesters.
[0008] Solvent-based inkjet inks comprising pigments, as used in
piezo printheads, contain high concentrations of polymer to help
form stable dispersions of appropriate particle size.
[0009] For example, commercially-available pigments for
solvent-based inkjet ink applications, such as those from the
Microlith range (Ciba), consist of pigments pre-dispersed in a
vinyl chloride/vinyl acetate copolymer binder. In order to
formulate a typical solvent-based inkjet ink, the
commercially-available pigment dispersions are "let-down" in
solvent and additional polymer. Incorporation of the additional
polymer improves film properties and helps maintain particle
stability. However, in thermal printheads, high concentrations of
polymer are undesirable because they tend to kogate on the heater
element, reduce ink latency and/or decrease drop velocity.
[0010] The Applicant has developed a range of bend-actuated
printheads, which do not rely on bubble formation for ink ejection
and, like piezo printheads, can be used with either aqueous or
non-aqueous inks. Some of the Applicant's bend-actuated inkjet
printheads are described in, for example, U.S. Pat. No. 7,416,280;
U.S. Pat. No. 6,902,255; US 2008/0129793; and US 2008/0225082, the
contents of which are herein incorporated by reference.
[0011] The present Applicant has also developed a range of thermal
bubble-forming printheads, as described in, for example, U.S. Pat.
No. 6,755,509; U.S. Pat. No. 7,246,886; and U.S. Pat. No.
7,401,910, the contents of which are incorporated herein by
reference.
[0012] The Applicant's thermal bubble-forming inkjet printers
currently offer high-resolution and high-speed printing (e.g. 60
pages per minute at 1600 dpi) of aqueous-based inks for SOHO
markets. These aqueous-based inks are suitable for printing onto
porous and semi-porous media. However, it would be desirable to
provide thermal bubble-forming inkjet printheads, which can print
ink onto a wider range of substrates, including non-porous media.
This would allow thermal inkjet printheads to compete fully with
piezo printers, offering high-resolution and high-speed inkjet
printing for a wide range of print media.
SUMMARY OF THE INVENTION
[0013] In a first aspect, there is provided a solvent-based (i.e.
non-aqueous) ink composition for a thermal inkjet printhead
comprising a surface-modified pigment. Optionally, the ink
composition comprises: [0014] (a) 10-80 wt. % of a compound of
formula (A);
##STR00002##
[0015] wherein:
[0016] R.sup.1 is C.sub.1-6 alkyl; and
[0017] each of R.sup.2, R.sup.3 and R.sup.4 is independently
selected from H, C.sub.1-6 alkyl, halogen, OH, and C.sub.1-6
alkoxy; [0018] (b) 10-80 wt. % of a C.sub.1-6 alcohol; [0019] (c)
0.01-25 wt. % of a surface-modified pigment.
[0020] Optionally, R.sup.1 is C.sub.1-6 alkyl; and each of R.sup.2,
R.sup.3 and R.sup.4 is H.
[0021] Optionally, the compound of formula (A) is
N-methyl-2-pyrrolidinone or N-ethyl-2-pyrollidinone.
[0022] Optionally, in all relevant aspects of the present
invention, the C.sub.1-6 alcohol is ethanol.
[0023] Optionally, in all relevant aspects of the present
invention, the ink composition comprises 0.001-10 wt. % of a
surfactant.
[0024] Optionally, in all relevant aspects of the present
invention, the surfactant is a nonionic surfactant.
[0025] Optionally, in all relevant aspects of the present
invention, the surfactant is non-polymeric.
[0026] Optionally, in all relevant aspects of the present
invention, the composition does not comprise an acrylate polymer or
copolymer.
[0027] Optionally, in all relevant aspects of the present
invention, the composition does not comprise any polymers.
[0028] Optionally, the ink composition consists essentially of or
consists only of the compound of formula (A), the C.sub.1-6 alcohol
and the surface-modified pigment.
[0029] Optionally, the ink composition consists only of the
compound of formula (A), the C.sub.1-6 alcohol, the
surface-modified pigment and 0.01-10 wt. % of a surfactant.
[0030] In a second aspect, there is provided a method of ejecting
ink from a thermal inkjet printhead, the method comprising the
steps of:
[0031] (i) supplying an ink to at least one nozzle chamber of the
printhead; and
[0032] (ii) actuating a heater element in the nozzle chamber and
heating the ink to a temperature sufficient to form a bubble
therein, thereby causing the ink to be ejected from a nozzle
opening associated with the nozzle chamber,
wherein the ink is a solvent-based ink composition comprising:
[0033] (a) 10-80 wt. % of a compound of formula (A);
##STR00003##
[0034] wherein:
[0035] R.sup.1 is C.sub.1-6 alkyl; and
[0036] each of R.sup.2, R.sup.3 and R.sup.4 is independently
selected from H, C.sub.1-6 alkyl, halogen, OH, and C.sub.1-6
alkoxy; [0037] (b) 10-80 wt. % of a C.sub.1-6 alcohol; [0038] (c)
0.01-25 wt. % of a surface-modified pigment.
[0039] Optionally, in all relevant aspects of the present
invention, the ink is ejected onto a non-porous or a semi-porous
substrate.
[0040] Optionally, in all relevant aspects of the present
invention, the ink adheres to the substrate.
[0041] Optionally, in all relevant aspects of the present
invention, the substrate is a plastics substrate.
[0042] Optionally, in all relevant aspects of the present
invention, the substrate is comprised of untreated vinyl or
polyester.
[0043] Optionally, in all relevant aspects of the present
invention, the heater element has a mass of less than 1
nanogram.
[0044] Optionally, in all relevant aspects of the present
invention, the heater element is suspended in the ink chamber, such
that the ink composition envelops the heater element.
[0045] Optionally, in all relevant aspects of the present
invention, an actuation energy for the heater element is less than
500 nJ.
[0046] Optionally, in all relevant aspects of the present
invention, the printhead is a stationary pagewidth printhead.
[0047] Optionally, in all relevant aspects of the present
invention, the printhead comprises at least 50,000 nozzles.
[0048] In a third aspect, there is provided a solvent-based ink
composition for a thermal inkjet printhead, the ink composition
comprising: [0049] (a) 10-80 wt. % of a compound of formula
(B);
##STR00004##
[0050] wherein: [0051] R.sup.5 is a C.sub.1-6 alkyl group and
R.sup.6 is a C.sub.1-6 alkyl group; or [0052] R.sup.5 and R.sup.6
are together joined to form a C.sub.3-12 cycloalkylene group;
[0053] (b) 10-80 wt. % of a C.sub.1-6 alcohol; [0054] (c) 0.01-25
wt. % of a surface-modified pigment.
[0055] Optionally, the compound of formula (B) is
methylethylketone.
[0056] Optionally, the compound of formula (B) is
cyclohexanone.
[0057] In a fourth aspect, there is provided a method of ejecting
ink from a thermal inkjet printhead, the method comprising the
steps of:
[0058] (i) supplying an ink to at least one nozzle chamber of the
printhead; and
[0059] (ii) actuating a heater element in the nozzle chamber and
heating the ink to a temperature sufficient to form a bubble
therein, thereby causing the ink to be ejected from a nozzle
opening associated with the nozzle chamber,
wherein the ink is a solvent-based ink composition comprising:
[0060] (a) 10-80 wt. % of a compound of formula (B);
##STR00005##
[0061] wherein: [0062] R.sup.5 is a C.sub.1-6 alkyl group and
R.sup.6 is a C.sub.1-6 alkyl group; or [0063] R.sup.5 and R.sup.6
are together joined to form a C.sub.3-12 cycloalkylene group;
[0064] (b) 10-80 wt. % of a C.sub.1-6 alcohol; [0065] (c) 0.01-25
wt. % of a surface-modified pigment.
[0066] In a fifth aspect, there is provided a solvent-based ink
composition for a thermal inkjet printhead, the ink composition
comprising: [0067] (a) 10-80 wt. % of a compound of formula
(C);
##STR00006##
[0068] wherein: [0069] R.sup.7 is a C.sub.2-12 alkyl group
interrupted with 0, 1, 2 or 3 oxygen atoms; [0070] (b) 10-80 wt. %
of a C.sub.1-6 alcohol; [0071] (c) 0.01-25 wt. % of a
surface-modified pigment.
[0072] Optionally, R.sup.7 is a C.sub.4-8 alkyl group interrupted
with 0, 1 or 2 oxygen atoms.
[0073] Optionally, the compound of formula (C) is selected from the
group consisting of: hexyl acetate; carbitol acetate; butyldiglycol
acetate; and methoxypropyl acetate.
[0074] In a sixth aspect, there is provided a method of ejecting
ink from a thermal inkjet printhead, the method comprising the
steps of:
[0075] (i) supplying an ink to at least one nozzle chamber of the
printhead; and
[0076] (ii) actuating a heater element in the nozzle chamber and
heating the ink to a temperature sufficient to form a bubble
therein, thereby causing the ink to be ejected from a nozzle
opening associated with the nozzle chamber,
wherein the ink is a solvent-based ink composition comprising:
[0077] (a) 10-80 wt. % of a compound of formula (C);
##STR00007##
[0078] wherein: [0079] R.sup.7 is a C.sub.2-12 alkyl group
interrupted with 0, 1, 2 or 3 oxygen atoms; [0080] (b) 10-80 wt. %
of a C.sub.1-6 alcohol; [0081] (c) 0.01-25 wt. % of a
surface-modified pigment.
[0082] In a seventh aspect, there is provided a solvent-based ink
composition for a thermal inkjet printhead, the ink composition
comprising: [0083] (a) 10-80 wt. % of a compound of formula
(D);
##STR00008##
[0084] wherein: [0085] each of R.sup.8 and R.sup.9 is independently
selected from a C.sub.1-12 alkyl group interrupted with 0, 1, 2 or
3 oxygen atoms; or [0086] R.sup.8 and R.sup.9 are together joined
to form a C.sub.3-12 cycloalkylene group; [0087] (b) 10-80 wt. % of
a C.sub.1-6 alcohol; [0088] (c) 0.01-25 wt. % of a surface-modified
pigment.
[0089] Optionally, at least one of R.sup.8 and R.sup.9 includes one
or more oxygen atom interruptions.
[0090] Optionally, the compound of formula (D) is selected from the
group consisting of: dipropylene glycol monomethyl ether;
dipropylene glycol dimethyl ether, diethylene glycol diethyl ether,
propylene glycol butyl ether, dipropylene glycol dimethyl ether,
dipropylene glycol butyl ether, diethylene glycol monopropyl ether,
propylene glycol propyl ether, tetraethylene glycol dimethyl ether,
methyl butyl ether, tripropylene glycol methyl ether,
tetrahydrofuran, and tetrahydropyran.
[0091] In an eighth aspect, there is provided a method of ejecting
ink from a thermal inkjet printhead, the method comprising the
steps of:
[0092] (i) supplying an ink to at least one nozzle chamber of the
printhead; and
[0093] (ii) actuating a heater element in the nozzle chamber and
heating the ink to a temperature sufficient to form a bubble
therein, thereby causing the ink to be ejected from a nozzle
opening associated with the nozzle chamber,
wherein the ink is a solvent-based ink composition comprising:
[0094] (a) 10-80 wt. % of a compound of formula (D);
##STR00009##
[0095] wherein: [0096] each of R.sup.8 and R.sup.9 is independently
selected from a C.sub.1-12 alkyl group interrupted with 0, 1, 2 or
3 oxygen atoms; or [0097] R.sup.8 and R.sup.9 are together joined
to form a C.sub.3-12 cycloalkylene group; [0098] (b) 10-80 wt. % of
a C.sub.1-6 alcohol; [0099] (c) 0.01-25 wt. % of a surface-modified
pigment.
[0100] In a further aspect, there is provided a printer comprising:
[0101] an ink reservoir containing a respective ink; and [0102] a
thermal inkjet printhead in fluid communication with the ink
reservoir, wherein the ink is any one of the solvent-based ink
compositions described above.
[0103] Optionally, the thermal inkjet printhead comprises a
plurality of nozzles, each of the plurality of nozzles
comprising:
[0104] a nozzle chamber containing the ink, the nozzle chamber
having a nozzle opening for ejection of the ink; and
[0105] a heater element in contact with the ink, the heater element
being configured for heating the ink to a temperature sufficient to
form a bubble therein and thereby cause ejection of the ink from
the nozzle opening.
[0106] In a further aspect, there is provided an ink cartridge for
a thermal inkjet printhead, the ink cartridge containing any one of
the solvent-based ink compositions described above.
[0107] Optionally, the ink cartridge comprises a thermal inkjet
printhead integrated therewith.
[0108] In a further aspect, there is provided a substrate having
any one of the ink compositions described above disposed
thereon.
[0109] Optionally, the substrate is a semi-porous or non-porous
substrate.
[0110] Optionally, the substrate is a vinyl substrate.
BRIEF DESCRIPTION OF THE DRAWINGS
[0111] Optional embodiments of the present invention will now be
described by way of example only with reference to the accompanying
drawings, in which:--
[0112] FIG. 1 is a perspective view of part of a thermal inkjet
printhead;
[0113] FIG. 2 is a side view of one of the nozzle assemblies shown
in FIG. 1;
[0114] FIG. 3 is a perspective of the nozzle assembly shown in FIG.
2; and
[0115] FIG. 4 is perspective view of a thermal inkjet print
engine.
DETAILED DESCRIPTION OF THE INVENTION
[0116] The present invention provides solvent-based ink
compositions, which may be jetted from a thermal inkjet printhead
of the type that rapidly generates a bubble in each nozzle chamber
in order to eject ink. The overwhelming preference of the prior art
is to eject aqueous ink compositions from thermal inkjet
printheads. However, as foreshadowed above, aqueous ink
compositions limit the number of applications in which thermal
inkjet printheads may be used. The present invention, which makes
use of non-aqueous ink compositions, expands the number of possible
applications for thermal inkjet printheads by enabling such
printheads to print ink which adheres to non-porous and semi-porous
print media. Hence, the use of thermal inkjet printheads in
wide-format and other markets is a realistic possibility using the
present invention.
[0117] The ink compositions according to the present invention are
characterized by their relative simplicity, especially when
compared to their solvent-based counterparts typically used in
piezo printheads. A typical solvent-based ink composition used in
piezo printheads has a solvent system comprised of about five or
more different solvents. Moreover, these solvent-based ink
compositions usually comprise a high concentration of polymers
(e.g. acrylate polymers) to stabilize the colorant(s) in the ink.
It is an advantage of the present invention that the solvent system
may only comprise two solvents and may be formulated with a low
polymer concentration or no polymers at all.
[0118] The minimization of polymers not only reduces cost, but also
minimizes the propensity for non-volatile residues to build up on
the thermal heater elements in the printheads (otherwise known as
"kogation"). It is surprising that relatively simple solvent-based
ink compositions can jet effectively and adhere to non-porous
substrates with a low polymer concentration and, in particular, a
low concentration or absence of acrylate polymers.
[0119] The ink compositions of the present invention generally
comprise three main components, each of which will be discussed in
more detail. The first component is a solvent, which promotes
adhesion of the ink to non-porous surfaces (e.g. vinyl surfaces).
The second component promotes bubble formation in the thermal
printhead. The third component is a surface-modified pigment.
[0120] Although inks may be formulated using only these three
components, a fourth component may additionally be present for
improving the film appearance of the ink on non-porous media and/or
aiding in initial dispersion of the surface-modified pigment.
[0121] The first and second components together typically make up
at least 70% wt. %, at least 80 wt. % or at least 90 wt. % of the
ink composition.
[0122] The amount of the first component ("adhesion-promoting
solvent") is in the range of 10 to 80 wt. %, based on the total
weight of the ink composition. Optionally, the amount of first
component is in the range of 30 to 60 wt. %, or optionally 40 to 50
wt. %.
[0123] The amount of the second component ("bubble-promoting
solvent") is in the range of 10 to 80 wt. %, based on the total
weight of the ink composition. Optionally, the amount of second
component is in the range of 30 to 60 wt. %, or optionally 40 to 50
wt. %.
[0124] The ratio of the first and second components may be in the
range of 3:1 to 1:3, optionally 2:1 to 1:2 or optionally 1.5:1 to
1:1.5. In a preferred ink composition, the first and second
components are present in approximately equal amounts i.e. about a
1:1 ratio.
[0125] The amount of the third component ("surface-modified
pigment") is in the range of 0.01 to 25 wt. %, based on the total
weight of the ink composition. The exact amount of third component
will usually depend on characteristics of the particular pigment
(e.g. optical density) and other printing parameters (e.g. droplet
size, dot density etc). Optionally, the amount of third component
is in the range of 0.1 to 10 wt. %, or optionally 1 to 5 wt. %.
[0126] The amount of fourth component ("surfactant"), when present
in the ink composition, is in the range of 0.01 to 10 wt. %.
Optionally, the amount of fourth component is in the range of 0.05
to 5 wt. %, or optionally 0.1 to 1 wt. %.
[0127] The ink composition may consist essentially of the first,
second and third components. In other words, the first, second and
third components together may comprise at least 90 wt. %, at least
95 wt. %, or least 98 wt. % of the ink composition.
[0128] In some embodiments, the ink composition may consist of only
the first, second and third components. In other embodiments, the
ink composition may consist of only the first, second, third and
fourth components.
[0129] Typically, the ink composition does not contain any acrylate
polymers, which are usually used in solvent-based ink compositions
described in the prior art. Alternatively, the ink composition may
not contain any polymers whatsoever.
Adhesion-Promoting Solvent
[0130] The Applicant has observed that certain types of solvent
interact strongly with non-porous substrates, whilst also being
jettable from a thermal inkjet printhead. In particular, some
solvents adhere strongly with a vinyl print media and leave a film
impression, which cannot be easily removed. By contrast, water and
ethanol do not leave any impression on vinyl surfaces.
[0131] A first type of adhesion-promoting solvent is of formula
(A):
##STR00010##
wherein: R.sup.1 is C.sub.1-6 alkyl; and each of R.sup.2, R.sup.3
and R.sup.4 is independently selected from H, C.sub.1-6 alkyl,
halogen, OH, and C.sub.1-6 alkoxy.
[0132] Typical examples of a solvent of formula (A) are
N-methyl-2-pyrrolidinone (NMP) and N-ethyl-2-pyrollidinone
(NEP).
[0133] A second type of adhesion-promoting solvent is of formula
(B):
##STR00011##
[0134] wherein: [0135] R.sup.5 is a C.sub.1-6 alkyl group and
R.sup.6 is a C.sub.1-6 alkyl group; or [0136] R.sup.5 and R.sup.6
are together joined to form a C.sub.3-12 cycloalkylene group;
[0137] Typical examples of a solvent of formula (B) are methyl
ethyl ketone (MEK), methyl propyl ketone, methyl butyl ketone,
cyclohexanone, cyclopentanone, cycloheptanone, cyclooctanone and
isophorone.
[0138] A third type of adhesion-promoting solvent is of formula
(C):
##STR00012##
[0139] wherein: [0140] R.sup.7 is a C.sub.2-12 alkyl group
interrupted with 0, 1, 2 or 3 oxygen atoms.
[0141] Typical examples of a solvent of formula (C) are hexyl
acetate, ethyl acetate, butyl acetate, carbitol acetate
[2-(2-ethoxyethoxy)ethyl acetate], isooctyl acetate, butyl carbitol
acetate [2-(2-butoxyethoxy)ethyl acetate], butyldiglycol acetate
[2-(2-butoxyethoxy)ethyl acetate], and methoxypropyl acetate.
[0142] A fourth type of adhesion-promoting solvent is of formula
(D):
##STR00013##
[0143] wherein: [0144] each of R.sup.8 and R.sup.9 is independently
selected from a C.sub.1-12 alkyl group interrupted with 0, 1, 2 or
3 oxygen atoms; or [0145] R.sup.8 and R.sup.9 are together joined
to form a C.sub.3-12 cycloalkylene group.
[0146] Typical examples of a solvent of formula (D) are dipropylene
glycol monomethyl ether, dipropylene glycol dimethyl ether,
diethylene glycol diethyl ether, propylene glycol butyl ether,
dipropylene glycol dimethyl ether, dipropylene glycol butyl ether,
diethylene glycol monopropyl ether, propylene glycol propyl ether,
tetraethylene glycol dimethyl ether, methyl butyl ether,
tripropylene glycol methyl ether, tetrahydrofuran and
tetrahydropyran.
[0147] The term "alkyl" is used herein to refer to alkyl groups in
both straight and branched forms. Unless stated otherwise, the
alkyl group may be interrupted with 1, 2 or 3 heteroatoms selected
from O, NH or S. For example, an O atom interruption in a C--C bond
provides an ether. Alternatively, an O atom interruption in a C--H
bond provides an alcohol. Hence, ethers and alcohols are within the
ambit of "alkyl" as defined herein.
[0148] Unless stated otherwise, the alkyl group may also be
interrupted with 1, 2 or 3 double and/or triple bonds. However, the
term "alkyl" usually refers to alkyl groups having no double or
triple bond interruptions. Where alkenyl, ether, alkoxy etc. groups
are specifically mentioned, this is not intended to be construed as
a limitation on the definition of "alkyl" above.
[0149] Where reference is made to, for example, C.sub.1-6 alkyl, it
is meant the alkyl group may contain any number of carbon atoms
between 1 and 6. By way of example, C.sub.1-6 alkyl may encompass
groups, such as methyl, ethyl, propyl (including n-propyl,
isopropyl etc), butyl (including n-butyl, t-butyl etc), pentyl,
hexyl, butenyl, pentenyl, hexenyl, iso-propenyl, methoxypropyl,
ethoxyethyl, methoxymethyl, ethoxybutyl etc.
[0150] The term "alkyl" usually refers to acyclic alkyl groups, but
it may also include cycloalkyl groups.
[0151] As used herein, the term "cycloalkyl" includes cycloalkyl,
polycycloalkyl, and cycloalkenyl groups, as well as combinations of
these with linear alkyl groups (e.g. a cycloalkyl group including
alkyl substituent(s) attached to the ring). The cycloalkyl group
may be interrupted with 1, 2 or 3 heteroatoms selected from O, N or
S. Such cylcoalkyl groups may be in the form of a cycloalkyl ring
substituted with, for example, alkoxy group(s) or they may be in
the form of a heterocylocalkyl group. Examples of heterocycloalkyl
groups are pyrrolidino, morpholino, piperidino etc. However, the
term "cycloalkyl" usually refers to cycloalkyl groups having no
heteroatom interruptions. Examples of cycloalkyl groups include
cyclopentyl, cyclohexyl, cyclohexenyl, cyclohexylmethyl and
adamantyl groups.
[0152] The term "halogen" or "halo" is used herein to refer to any
of fluorine, chlorine, bromine and iodine. Usually, however,
halogen refers to chlorine or fluorine substituents.
Bubble-Forming Solvent
[0153] Although the adhesion-promoting solvents described above
have an inherent bubble-forming characteristic (as well as good
adhesion of vinyl substrates), the ability of these solvents to
form bubbles in a thermal inkjet device is improved markedly by the
addition of a C.sub.1-6 alcohol. For the avoidance of doubt, the
term "C.sub.1-6 alcohol" as used herein refers to alcohol compounds
having from 1 to 6 carbon atoms and only one hydroxyl group. The
term "C.sub.1-6 alcohol" also includes alkoxy alcohols, such as
methoxypropanol, ethoxyethanol etc. One or more C.sub.1-6 alcohols
may be present in the ink composition.
[0154] Examples of suitable C.sub.1-6 alcohols are methanol,
ethanol, propanol (e.g. isopropanol), methoxypropanol, butanol,
pentanol and hexanol. A preferred C.sub.1-6 alcohol for use as the
bubble-forming solvent in the present invention is ethanol.
Surface-Modified Pigment
[0155] Surface-modified pigments have been developed so as to
reduce the need for high amounts of stabilizing polymers in aqueous
inkjet inks. Kogation is a severe problem in pigment-based aqueous
inks and affect printhead performance. Although it is possible to
"overpower" heater elements to compensate for polymer kogation,
this is generally unsatisfactory especially as printheads (e.g.
Memjet.RTM. printheads) move towards lower drop ejection energies
(e.g. 50 to 200 nJ per nozzle). Hence, a new generation of
surface-modified pigments has emerged for formulating aqueous
inkjet inks. For example, the CAB-O-JET.RTM. range of aqueous
pigment dispersions comprise a black or colored pigment modified
with surface anionic groups, such as carboxylate groups and
sulfonate groups. Formula (I) shows a carboxylate-modified black
pigment, while formula (II) shows a sulfonate-modified color
pigment. However, other surface-modifying groups may also be used,
such as anionic phosphate groups or cationic ammonium groups.
##STR00014##
[0156] Surface-modified pigments, such as those described above,
have been developed for formulating aqueous inkjet inks. They are
sold as aqueous pigment dispersions, which are inherently
unsuitable for formulating solvent-based inks.
[0157] In the present invention, particles of surface-modified
pigments are prepared by drying an aqueous pigment dispersion to a
constant mass in an oven at 120.degree. C. Specific examples of
suitable aqueous surface-modified pigment dispersions for use in
the present invention are CAB-O-JET.RTM. 200, 300, 250C, 260M and
270Y, supplied by Cabot Corporation.
[0158] The surface-modified pigments may be used either
individually or as a combination of two or more pigments.
[0159] The average particle size of surface-modified pigment
particles is optionally in the range of 50 to 500 nm or optionally
50 to 250 nm.
Surfactant
[0160] A fourth component may be included in the ink compositions
of the present invention in order to aid dispersion of the
surface-modified pigment particles and/or improve the film
appearance of the ink when deposited on a non-porous substrate e.g.
vinyl or polyester substrate.
[0161] Optionally, the surfactant is contained in an amount of from
0.001 to 10 wt. %, from 0.01 to 5 wt. %, from 0.05 to 2 wt. %, or
from 0.1 to 1 wt. %. The surfactant, when present, is typically a
nonionic surfactant.
[0162] Surfactants suitable for use in the present invention
include fluorosurfactants (e.g. ethoxylated fluorosurfactants).
Some specific examples of fluorosurfactants suitable for improving
the film appearance of ink compositions according to the present
invention are Zonyl.RTM. FSO and Zonyl.RTM. FSO-100.
[0163] Other specific examples of surfactants suitable for
improving the film appearance of ink compositions according to the
present invention include Tego Wet.RTM. 450, Tegoglide.RTM. 410,
Twin.RTM. 400, Tego Wet.RTM. 270 and Tegoglide.RTM. 482.
[0164] An example of a surfactant suitable for aiding initial
dispersion of a surface-modified pigment in the solvent medium is
Solsperse.RTM. 32500.
[0165] Although ink compositions according to the present invention
advantageously provide excellent print quality and jettability in
the absence of polymer additives (especially acrylate polymers),
certain polymers may be used in low concentration to improve
initial dispersion during formulation to improve the film
appearance of the ink when printed. For example, vinyl polymers may
improve the film appearance of the ink when printed on vinyl
substrates. An example of a vinyl polymer additive is a high
molecular weight copolymer of vinyl chloride and vinyl acetate
(e.g. UCAR.TM. VYHH). Such polymer additives may be included in an
amount of from 0.01 to 5 wt. %, or from 0.05 to 2 wt. %, or from
0.1 to 1 wt. %. However, ink compositions according to the present
invention may, equally, be completely free of any polymer
additives.
Thermal Inkjet Printheads
[0166] The solvent-based ink compositions according to the present
invention are designed to be used with thermal inkjet printheads.
There now follows a brief description of one of the Applicant's
thermal inkjet printheads, as described in U.S. Pat. No. 7,303,930,
the contents of which is herein incorporated by reference.
[0167] Referring to FIG. 1, there is shown part of printhead
comprising a plurality of nozzle assemblies. FIGS. 2 and 3 show one
of these nozzle assemblies in side-section and cutaway perspective
views.
[0168] Each nozzle assembly comprises a nozzle chamber 24 formed by
MEMS fabrication techniques on a silicon wafer substrate 2. The
nozzle chamber 24 is defined by a roof 21 and sidewalls 22 which
extend from the roof 21 to the silicon substrate 2. As shown in
FIG. 1, each roof is defined by part of a nozzle plate 56, which
spans across an ejection face of the printhead. The nozzle plate 56
and sidewalls 22 are formed of the same material, which is
deposited by PECVD over a sacrificial scaffold of photoresist
during MEMS fabrication. Typically, the nozzle plate 56 and
sidewalls 21 are formed of a ceramic material, such as silicon
dioxide or silicon nitride. These hard materials have excellent
properties for printhead robustness, and their inherently
hydrophilic nature is advantageous for supplying ink to the nozzle
chambers 24 by capillary action.
[0169] Returning to the details of the nozzle chamber 24, it will
be seen that a nozzle opening 26 is defined in a roof of each
nozzle chamber 24. Each nozzle opening 26 is generally elliptical
and has an associated nozzle rim 25. The nozzle rim 25 assists with
drop directionality during printing as well as reducing, at least
to some extent, ink flooding from the nozzle opening 26. The
actuator for ejecting ink from the nozzle chamber 24 is a heater
element 29 positioned beneath the nozzle opening 26 and suspended
across a pit 8. Current is supplied to the heater element 29 via
electrodes 9 connected to drive circuitry in underlying CMOS layers
of the substrate 2. When a current is passed through the heater
element 29, it rapidly superheats surrounding ink to form a gas
bubble, which forces ink through the nozzle opening 26. By
suspending the heater element 29, it is completely immersed in ink
when the nozzle chamber 24 is primed. This improves printhead
efficiency, because less heat dissipates into the underlying
substrate 2 and more input energy is used to generate a bubble.
[0170] As seen most clearly in FIG. 1, the nozzles are arranged in
rows and an ink supply channel 27 extending longitudinally along
the row supplies ink to each nozzle in the row. The ink supply
channel 27 delivers ink to an ink inlet passage 15 for each nozzle,
which supplies ink from the side of the nozzle opening 26 via an
ink conduit 23 in the nozzle chamber 24.
[0171] The MEMS fabrication process for manufacturing such
printheads was described in detail in U.S. Pat. No. 7,303,930, the
contents of which are herein incorporated by reference.
[0172] The operation of printheads having suspended heater elements
is described in detail in the Applicant's U.S. Pat. No. 7,278,717,
the contents of which are incorporated herein by reference.
[0173] The Applicant has also described thermal bubble-forming
inkjet printheads having embedded heater elements. Such printheads
are described in, for example, U.S. Pat. No. 7,246,876 and US
2006/0250453, the contents of which are herein incorporated by
reference.
[0174] The Applicant's thermal inkjet printheads may be generally
characterized by having one or more of the following features: (i)
suspended heater element; (ii) heater element having a mass of less
than 1 nanogram, optionally less than 500 picograms; (iii)
actuation energy of less than 500 nJ, optionally less than 200 nJ;
and (iv) titanium nitride or titanium aluminium nitride heater
element.
[0175] The solvent-based ink compositions of the present invention
work optimally in combination with the Applicant's thermal inkjet
printheads, as described above. However, their use is not limited
to the Applicant's thermal printheads. The solvent-based ink
compositions described herein may also be used in conventional
thermal bubble-forming inkjet printheads, such as those sold
commercially by Hewlett-Packard and Canon.
[0176] In the case of conventional scanning thermal inkjet
printheads (or, indeed, the Applicant's pagewidth printheads), the
present invention may relate to an ink cartridge for a inkjet
printer comprising any of the solvent-based ink compositions
described above. The ink cartridge may optionally comprise a
thermal inkjet printhead integrated with therewith.
[0177] For the sake of completeness, printers incorporating the
Applicant's thermal inkjet printheads are described in, for
example, U.S. Pat. No. 7,201,468; U.S. Pat. No. 7,360,861; U.S.
Pat. No. 7,380,910; and U.S. Pat. No. 7,357,496, the contents of
each of which are herein incorporated by reference.
[0178] FIG. 4 shows a print engine 103 for a thermal inkjet
printer, as described in Applicant's U.S. application Ser. No.
12/062,514, the contents of which is herein incorporated by
reference. The print engine 103 includes a removable print
cartridge 102, comprising a pagewidth printhead, and a bank of
user-replaceable ink cartridges 128. Each color channel typically
has its own ink reservoir 128 and a corresponding
pressure-regulating chamber 106 for regulation of a hydrostatic
pressure of ink supplied to the printhead. Hence, the print engine
103 has five ink reservoirs 128 and five corresponding
pressure-regulating chambers 106. Typical color channel
configurations for this five-channel print engine 103 are CMYKK or
CMYK(IR). Each ink cartridge 128 may comprise a solvent-based ink
composition as described herein. Accordingly, the printer is
suitable for printing onto non-porous (e.g. vinyl) substrates.
[0179] Although fluidic connections between the various components
are not shown in FIG. 4, it will be appreciated that these
connections are made with suitable hoses in accordance with the
fluidics system described in, for example, U.S. application Ser.
No. 12/062,514.
[0180] It will further be appreciated that, whilst ink compositions
according to the present invention were designed for use in thermal
inkjet printheads, they may also be useful in other types of inkjet
printhead, such as the Applicant's bend-actuated inkjet printheads
described in, for example, U.S. Pat. No. 7,416,280; U.S. Pat. No.
6,902,255; US 2008/0129793; and US 2008/0225082, the contents of
which are herein incorporated by reference.
Experimental
Evaluation of Bubble-Forming Solvents
[0181] Using an "open pool boiler" test apparatus, and after
evaluating a wide range of solvents, the solvents described in
Table A were shown to generate bubbles in a thermal inkjet device.
(An "open pool boiler" test apparatus essentially comprises one or
more inkjet nozzles as shown in FIG. 2 without the roof structure
21).
[0182] Some physical characteristics of each solvent are also
provided in Table A.
TABLE-US-00002 TABLE A Solvents generating bubbles in thermal
inkjet test device Evaporation Viscosity Surface tension Solvent
name Other name Bpt (.degree. C.) rate* (cP) (dynes/cm) MEK Methyl
ethyl ketone 80 4.03 0.43 24.18 Dipropylene glycol methyl ether
(DPM) Di(propylene glycol) methyl 187 0.02 3.44 28.25 ether,
mixture of isomers Butyl DiGlycol Acetate 2-(2-Butoxyethoxy) ethyl
245 0.001 3.6 30.5 acetate Methoxy Propyl Acetate Propylene glycol
monomethyl 145 0.33 1.2 28.2 ether acetate Cyclohexanone
Cydohexanone 155 0.3 2 34 Carbitol Acetate Diethylene glycol 219
0.008 2.67 31.4 monoethyl ether acetate Hexyl acetate Hexyl acetate
170 0.208 0.9 27.3 N-Methyl-2 Pyrrolidone 1-Methyl-2-pyrrolidone
202 0.03 1.65 40.1 Ethanol ethyl alcohol 78 1.7 1.1 22.18 Water
(comparative) 100 0.36 0.9 72 *relative to n-butyl acetate which
has a value of 1.
[0183] Although all solvents listed in Table A generated bubbles in
the test device, it was observed that the addition of ethanol to
each solvent significantly improved bubble formation.
[0184] A preferred solvent combination providing excellent bubble
formation was N-methyl-2-pyrrolidine (NMP) and ethanol in a 1:1
ratio.
Adhesion of Solvents to Vinyl
[0185] Each of the solvents listed in Table A was tested for
adhesion to a vinyl surface. Four large drops of solvent were
placed on uncoated vinyl and left for 60 seconds under ambient
conditions. The solvents were wiped gently with a tissue and any
mark on the vinyl surface was noted.
[0186] With the exception of water and ethanol, all solvents listed
in Table A left a film impression on vinyl. The solvents are listed
below in order of the severity with which a film impressions was
left on the vinyl surface. [0187]
MEK>NMP>Cyclohexanone>>Hexyl acetate=Carbitol
acetate=Butyldiglycol acetate=Methoxypropyl acetate>Dipropylene
glycol methyl ether
Film Properties of Single Solvent Ink Compositions
[0188] In a further adhesion test, ink compositions were formulated
consisting of a single solvent (from Table A) and a dye. Each ink
composition consisted of: 97 wt. % solvent and 3 wt. % Bricosol red
K10B (Solvent Red 8).
[0189] The inks were applied as 6 micron wet films to the vinyl
surface. Water rubs, adhesion and appearance were noted. In
general, all ink compositions had a good film appearance on the
vinyl surface before testing, with the exception of the carbitol
acetate and hexylacetate compositions, which exhibited some minor
irregularities.
[0190] Water rubs were performed using cotton buds dipped in water,
which were then rubbed across the films. The number of rubs needed
to damage the film was noted or, if no damage observed, stopped at
100 rubs. All ink compositions showed excellent resistance to the
water rub test, having no significant change after >100 water
rubs. (Usually, a number of rubs >50 is considered to be
excellent).
[0191] Adhesion tests were made by using a razor blade to mark six
vertical lines crossed by six horizontal lines in a grid (cross
hatch). Scotch.RTM. tape was then placed over the grid and removed
rapidly. The damage (if any) to the film was noted and a given an
adhesion rating: 0 (poor)-5 (excellent). All ink compositions had
an adhesion rating of 5.
[0192] The drying time of each film at room temperature was also
noted and the results are shown in Table B:
TABLE-US-00003 TABLE B Drying time of various single solvent ink
compositions on vinyl Ink Composition Solvent Drying Time 1
cyclohexanone <10 s 2 dipropyleneglycol methyl ether >120 s 3
butyldiglycol acetate >120 s 4 methoxypropyl acetate 20 s 5
carbitol acetate >120 s 6 hexyl acetate <20 s 7 N-methyl
pyrrolidinone <10 s
[0193] By way of comparison, a standard solvent-based piezo cyan
ink was measured to have a drying time of >120 s under the same
test conditions.
[0194] In all ink compositions prepared, the water resistance and
adhesion to vinyl were excellent, and performed at least as well as
a piezo solvent-based standard.
[0195] On the basis of bubble formation and film properties, an ink
composition comprising NMP and ethanol in a 1:1 ratio was
considered to be an excellent composition for thermal inkjets.
However, all ink compositions comprising an adhesion-promoting
solvent and ethanol were considered to be suitable for ejection
using a thermal inkjet device and, indeed, showed good drop
ejection characteristics from such a device.
Addition of Film Appearance Improvers
[0196] Several ink compositions were prepared using the preferred
solvent system of NMP and ethanol, and additionally including a
nonionic surfactant (Zonyl.RTM. FSO). These ink compositions are
described in Table C.
TABLE-US-00004 TABLE C Ink compositions comprising NMP, ethanol,
colorant and surfactant With Zonyl FSO SBOB1-17-1 SBOB1-17-2
SBOB1-17-3 SBOB1-17-4 Code Other name Function Blue Red Yellow
Black N-Methyl- 2 Pyrrolidone 1-Methyl-2-pyrrolidone Solvent 48.4
48.4 48.4 48.4 Ethanol Solvent 48.4 48.4 48.4 48.4 Zonyl FSO
Surfactant 0.2 0.2 0.2 0.2 Bricasol red K10B Solvent red 8 dye
colourant 3 Bricosol blue K2GV Solvent blue 70 dye colourant 3
Bricosol yellow KRV Solvent yellow 82 dye colourant 3 Bricosol
black NB Solvent black 27 dye colourant 3 Total 100 100 100 100
[0197] Each ink composition was placed in a suitable ink reservoir
and printed onto vinyl using a thermal inkjet printhead of the type
described above, having suspended beam heater elements. All
printouts had excellent film appearance, water resistance and
adhesion to the vinyl surface.
[0198] The addition of surfactant improved the film appearance of
the ink on vinyl, compared to ink compositions in which the
surfactant was absent.
[0199] Other surfactants shown to have a beneficial effect in
improving the film appearance of printouts on vinyl were Tego
Wet.RTM. 450, Tegoglide.RTM. 410, Twin.RTM. 400, Tego Wet.RTM. 270
and Tegoglide.RTM. 482.
[0200] Similarly, incorporation of a vinyl polymer into the ink
composition showed some improvement in the film appearance of
printouts. For example, the addition of UCAR.TM. VYHH (a high
molecular weight copolymer of vinyl chloride and vinyl acetate) to
the ink compositions improved the film appearance of printouts onto
a vinyl substrate. However, polymer additives were not considered
to be essential for acceptable film appearance on vinyl print
media.
Surface-Modified Pigment Formulations
[0201] A CMYK set of inks was prepared using surface-modified
pigment dispersions. CaboJet.RTM. aqueous pigment dispersions were
dried to constant mass in an oven at 120.degree. C. over-night. The
dried pigment powders were stirred into a solution of NMP and
Solsperse.RTM. 32500 dispersant at high speed using a Silverson
mixer. (Any suitable mixer, such as a sonic probe or a bead mill
may alternatively be used). The resultant pigment dispersions are
shown in Table D. Although a standard dispersant was used in these
examples to aid with initial dispersion, ink compositions in
accordance with the present invention may be formulated without
such dispersants.
TABLE-US-00005 TABLE D Composition of pigment dispersions Black
Cyan Magenta Yellow SBOB1- SBOB1- SBOB1- SBOB1- Book code 93-1 95-1
97-1 99-2 Dried CaboJet 300 20 Dried CaboJet 250C 10 Dried CaboJet
260M 10 Dried CaboJet 270Y 10 Solsperse 32500 50 25 25 25 NMP 30 65
65 65 Total 100 100 100 100
[0202] The pigment dispersions were then let down in solvent. In
the case of yellow, methoxypropanol was used; for the others,
NMP/EtOH was used (Table E).
TABLE-US-00006 TABLE E Composition of surface-modified pigment inks
Black Cyan Magenta Yellow SBOB1- SBOB1- SBOB1- SBOB1- Book code
93-2 95-2 97-5 99-3 SBOB1-93-1 31.25 SBOB1-95-1 30 SBOB1-97-1 33.33
SBOB1-99-2 30 EtOH 11.12 NMP/EtOH (80/20) 68.75 70 55.55
Methoxypropanol 70 Total 100 100 100 100
[0203] Each ink was filtered through 0.8 micron nylon filter and
printed onto a vinyl substrate using the thermal inkjet nozzles
shown in FIGS. 1-3.
[0204] Each ink jetted from the nozzles and adhered well to vinyl
without any drying step. Good water resistance was also observed.
Furthermore, the inks could be left uncapped overnight in the
device and, following a single purge and wipe, good nozzle recovery
was noted.
[0205] It was concluded that solvent-based ink compositions
comprising surface-modified pigments were excellent candidates for
printing onto non-porous substrates using a thermal bubble-forming
inkjet printhead.
[0206] It will, of course, be appreciated that the present
invention has been described by way of example only and that
modifications of detail may be made within the scope of the
invention, which is defined in the accompanying claims.
* * * * *