U.S. patent application number 13/245442 was filed with the patent office on 2012-01-19 for method and apparatus associated with anisotropic shrink in sintered ceramic items.
Invention is credited to Michael D. Baldwin, Nina Bergan French, Michael Maguire, M. Eric Schlienger, Paul Withoy.
Application Number | 20120015797 13/245442 |
Document ID | / |
Family ID | 36203691 |
Filed Date | 2012-01-19 |
United States Patent
Application |
20120015797 |
Kind Code |
A1 |
Schlienger; M. Eric ; et
al. |
January 19, 2012 |
METHOD AND APPARATUS ASSOCIATED WITH ANISOTROPIC SHRINK IN SINTERED
CERAMIC ITEMS
Abstract
A manufacturing method for producing ceramic item from a
photocurable ceramic filled material by stereolithography. The
method compensates for the anisotropic shrinkage of the item during
firing to produce a dimensionally accurate item.
Inventors: |
Schlienger; M. Eric;
(American Canyon, CA) ; Bergan French; Nina;
(Napa, CA) ; Baldwin; Michael D.; (American
Canyon, CA) ; Maguire; Michael; (Napa, CA) ;
Withoy; Paul; (Derby, GB) |
Family ID: |
36203691 |
Appl. No.: |
13/245442 |
Filed: |
September 26, 2011 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
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12456766 |
Jun 22, 2009 |
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13245442 |
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11788286 |
Apr 19, 2007 |
7551977 |
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12456766 |
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PCT/US2005/037681 |
Oct 18, 2005 |
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11788286 |
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60620104 |
Oct 19, 2004 |
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Current U.S.
Class: |
501/1 ;
700/103 |
Current CPC
Class: |
C04B 38/00 20130101;
B29C 64/106 20170801; C04B 2235/77 20130101; Y10T 428/2982
20150115; C04B 2235/9615 20130101; C04B 35/63 20130101; C04B
35/6269 20130101; C04B 35/111 20130101; C04B 2111/00181 20130101;
C04B 2235/5436 20130101; B28B 1/001 20130101; B33Y 50/02 20141201;
C04B 2201/20 20130101; B33Y 80/00 20141201; C04B 38/0022 20130101;
B28B 1/00 20130101; C04B 2235/5445 20130101; B29C 64/135 20170801;
C04B 35/632 20130101; B33Y 70/00 20141201; C04B 35/6263 20130101;
B33Y 10/00 20141201; B33Y 30/00 20141201; C04B 38/00 20130101; C04B
35/10 20130101; C04B 38/0022 20130101; C04B 35/10 20130101 |
Class at
Publication: |
501/1 ;
700/103 |
International
Class: |
C04B 35/64 20060101
C04B035/64; G06F 17/00 20060101 G06F017/00; C04B 35/00 20060101
C04B035/00 |
Claims
1. A method, comprising: representing an item including its
dimensions relative to a three dimensional coordinate system, the
item adapted to be formed as a green ceramic item in a
stereolithography apparatus from a photo-polymerizable material
including ceramic particles; applying at least two unequal scaling
factors to the dimensions to compensate for the anisotropic
shrinkage of the green ceramic item relative to the axes of the
coordinate system upon the green ceramic item being sintered;
building the green ceramic item in the stereolithography apparatus
after said applying; and heating the green ceramic item to form a
sintered ceramic item substantially conforming to the
dimensions.
2. The method of claim 1, wherein in said applying the scaling
factors are all unequal.
3. The method of claim 1, wherein said building includes forming a
plurality of layers of the photo-polymerizable material; and which
further includes leveling at least one of the plurality of layers
of the photo-polymerizable material prior to forming the next of
the plurality of layers of the photo-polymerizable material; and
which further includes exposing the at least one of the plurality
of layers of the photo-polymerizable material with a dose of energy
prior to forming the next of the plurality of layers of the
photo-polymerizable material.
4. The method of claim 3, wherein said leveling including
mechanically wiping a surface of the at least one of the plurality
of layers of the photo-polymerizable material.
5. The method of claim 4, wherein said mechanically wiping changes
the homogeneity of the ceramic particles in at least two
dimensions.
6. The method of claim 4, wherein said leveling includes leveling
each of the plurality of layers of the photo-polymerizable
material; and which further includes exposing each of the plurality
of layers of the photo-polymerizable material with a dose of
energy.
7. The method of claim 1, wherein the stereolothography apparatus
includes a machine three dimensional coordinate system coextensive
with the three dimensional coordinate system.
8. The method of claim 1, wherein the sintered ceramic item is of a
near net shape.
9. The method of claim 1, wherein the sintered ceramic item is of a
net shape.
10. The method of claim 1, wherein the sintered ceramic item is
dimensionally accurate with the dimensions within about 1.5%.
11. The method of claim 1, wherein the sintered ceramic item is
dimensionally accurate with the dimensions within about 0.5%.
12. The method of claim 1, wherein said heating includes burning
off a polymer in the green ceramic item.
13. The method of claim 2, wherein the three dimensional coordinate
system is a Cartesian coordinate system including a first axis
corresponding to the X axis and a second axis corresponding to the
Y axis and a third axis corresponding to the Z axis; wherein the
stereolothography apparatus includes a machine three dimensional
coordinate system coextensive with the three dimensional coordinate
system; which further includes selecting a build direction
corresponding to the Z axis; wherein said building includes forming
a plurality of layers from the photo-polymerizable material in the
build direction; and which further includes wiping an upper surface
of each of the plurality of layers of the photo-polymerizable
material prior to being exposed to an energy dose, said wiping in
the direction of one of the other axes.
14. The method of claim 1, wherein the photo-polymerizable material
includes ceramic particles within a range of 35% to 65% by
volume.
15. The method of claim 1, wherein said representing is associated
with any of electronic data, digital data, virtual data, computer
files, solid body modeling, computer modeling, computer aided
manufacturing.
16. The method of claim 1, wherein said heating is to a temperature
within a range of about 1100.degree. C. to 1700.degree. C.
17. A method, comprising: providing a data representation of an
item; selecting a build orientation for building the item in a
stereolithography apparatus from a photo-polymerizable material
including ceramic particles, wherein the stereolithography
apparatus including a three dimensional coordinate system with a
first axis, a second axis and a third axis; modifying the data
representation of the item to form a modified data representation
by applying a first expansion factor to increase the dimensions of
the item along the first axis and a second expansion factor to
increase the dimensions of the item along the second axis and a
third expansion factor to increase the dimensions of the item along
the third axis, wherein said expansion factors are not equal; and
forming a green state ceramic item conforming to the modified data
representation by controlling the delivery of energy to the
photo-polymerizable material.
18. The method of claim 17, wherein said forming including building
a plurality of layers from the photo-polymerizable material, and
wherein the photo-polymerizable material includes a monomer and a
photoinitator.
19. The method of claim 18, which further includes leveling each of
the plurality of layers of the photo-polymerizable material, and
wherein said forming includes exposing each of the plurality of
layers of the photo-polymerizable material to an energy dose.
20. The method of claim 19, wherein in said forming the item is
built in the direction of the third axis and said leveling
including mechanically wiping a surface of each of the plurality of
layers of the photo-polymerizable material with a wiper blade.
21. The method of claim 17, wherein the modified data
representation is one of an electronic data file, digital data
file, virtual data file, computer file, computer aided
manufacturing file and a computer aided engineering file, and the
data representation is a solid body model.
22. The method of claim 17, which further includes burning off a
polymer in the green state ceramic item after said forming, and
which further includes sintering the green state ceramic item to
define a sintered ceramic item.
23. The method of claim 22, wherein the sintered ceramic item is of
a near net shape.
24. The method of claim 22, wherein the sintered ceramic item is of
a net shape.
25. The method of claim 22, wherein a comparison of the data
representation of the item and the sintered ceramic item is
dimensionally accurate within about 1.5%.
26. The method of claim 22, wherein a comparison of the data
representation of the item and the sintered ceramic item is
dimensionally accurate within about 0.5%.
27. The method of 17, wherein the coordinate system is a Cartesian
coordinate system and the first axis corresponds to the X axis and
the second axis corresponds to the Y axis and the third axis
corresponds to the Z axis; which further includes selecting a build
direction corresponding to the Z axis; wherein said forming
includes building a plurality of layers from the
photo-polymerizable material in the build direction; and which
further includes wiping an upper surface of each of the plurality
of layers of the photo-polymerizable material prior to being
cured.
28. The method of claim 27, which further includes curing each of
the plurality of layers of the photo-polymerizable material,
wherein said curing is at least partial.
29. The method of claim 17, wherein the photo-polymerizable
material has a ceramic loading within a range of 35% to 65% by
volume.
30. A method, comprising: defining the original dimensions of an
item with reference to a three dimensional coordinate system
associated with a stereolithography apparatus, the coordinate
system including a first direction, a second direction and a third
direction; applying a first factor to increase the original
dimensions of the item defined relative to the first direction;
applying a second factor to increase the original dimensions of the
item defined relative to the second direction; applying a third
factor to increase the original dimensions of the item defined
relative to the third direction, wherein the factors are not equal;
building a green ceramic item by stereolithography from a
photo-polymerizable resin including ceramic particles, said
building utilizing the increased dimensions from said applying acts
to control the dimensions of the green ceramic item; and sintering
the green ceramic item to form a sintered ceramic item, wherein the
sintered ceramic item has dimensions corresponding substantially to
the original dimensions of the item.
31. The method of claim 30, wherein said defining including
capturing the original dimensions in an electronic format.
32. The method of claim 30, which further includes selecting a
build orientation before said applying acts.
33. The method of claim 30, wherein in said sintering the sintered
ceramic item has a near net shape.
34. The method of claim 30, wherein in said sintering the sintered
ceramic item has a net shape.
35. The method of claim 30, wherein the sintered ceramic item is
dimensionally accurate with the dimensions within about 1.5%.
36. The method of claim 30, wherein the sintered ceramic item is
dimensionally accurate with the dimensions within about 0.5%.
37. The method of claim 30, wherein said building includes forming
a plurality of layers from the photo-polymerizable resin, and
wherein each of the plurality of layers of the photo-polymerizable
resin is mechanically leveled by a moveable wiper blade prior to
being cured.
38. The method of claim 37, wherein each of the plurality is at
least partially cured.
39. The method of claim 30, wherein the photo-polymerizable resin
has a ceramic loading within a range of 35% to 65% by volume.
40. The method of claim 30, which further includes selecting a
build direction corresponding to the third direction; wherein said
building includes forming a plurality of layers from the
photo-polymerizable resin; which further includes wiping an outer
surface of each of the plurality of layers of the
photo-polymerizable resin prior to being cured; and wherein said
three dimensional coordinate system is defined by the three
dimensional coordinate of the stereolithography apparatus.
41. A method comprising: defining an article in terms of first
reference data relative to the axes of a three dimensional
coordinate system, the first reference data including first X
components oriented with a first axis, first Y components oriented
with a second axis and first Z components oriented with a third
axis; building in a stereolithography apparatus a green ceramic
test item corresponding to the first reference data from a
photocurable ceramic filled resin; measuring the green ceramic test
item to obtain second reference data defining the test item
relative to the three dimensional coordinate system, the second
reference data including second X components oriented with the
first axis, second Y components oriented with the second axis and
second Z components oriented with the third axis; sintering the
green ceramic test item to form a sintered ceramic test item;
measuring the sintered ceramic test item to obtain third reference
data defining the sintered ceramic test item relative to the three
dimensional coordinate system, the third reference data including
third X components oriented with the first axis, third Y components
oriented with the second axis and third Z components oriented with
the third axis; calculating shrink rates by comparison of the
second reference data and the third reference data, the shrink
rates including a X component shrink rate, a Y component shrink
rate and a Z component shrink rate; and applying the respective
shrink rates to the first reference data, the X component shrink
rate being applied to the first X components, the Y component
shrink rate being applied to the first Y components and the Z
component shrink rate being applied to the first Z components.
42. The method of claim 41, wherein the three dimensional
coordinate system is coextensive with a coordinate system of a
stereolithography apparatus utilized in said building.
43. The method of claim 41; wherein said building includes building
a plurality of layers from the photocurable ceramic filled resin,
and wherein said photocurable ceramic filled resin includes a
monomer and a photoinitator.
44. The method of claim 43, wherein said building includes exposing
the photocurable ceramic filled resin to an energy dose; which
further includes leveling each of the plurality of layers of the
photocurable ceramic filled resin prior to being exposed to the
energy dose.
45. The method of claim 43, wherein said leveling includes wiping a
surface of the photocurable ceramic filled resin with a blade.
46. A method comprising: defining an article in terms of first
reference data relative to the axes of a three dimensional
coordinate system, the first reference data including first X
components, first Y components and first Z components; building in
a stereolithography apparatus a green ceramic test item
corresponding to the first reference data by stereolithography from
a photocurable ceramic loaded resin; sintering the green ceramic
test item to define a sintered ceramic item; measuring the sintered
ceramic test item to obtain second reference data defining the
sintered test item relative to the three dimensional coordinate
system, the second reference data including second X components,
second Y components and second Z components; calculating shrink
rates by comparison of the first reference data and the second
reference data, the shrink rates including a X component shrink
rate, a Y component shrink rate and a Z component shrink rate; and
applying the respective shrink rates to the first reference data,
the X component shrink rate being applied to the first X
components, the Y component shrink rate being applied to the first
Y components and the Z component shrink rate being applied to the
first Z components.
47. The method of claim 46, wherein the coordinate system is
coextensive with the coordinate system of the stereolithography
apparatus.
48. The method of claim 47, wherein said building includes building
a plurality of layers from the photocurable ceramic filled resin,
and wherein the photocurable ceramic filled resin includes a
monomer and a photoinitator.
49. The method of claim 48, wherein said building includes exposing
the photocurable ceramic filled resin to an energy dose; and which
further includes leveling each of the plurality of layers of the
photocurable ceramic filled resin prior to being exposed to the
energy dose.
50. The method of claim 49, wherein said leveling includes wiping a
surface of the photocurable ceramic filled resin with a blade.
51. A method, comprising: preparing a representation of an item to
be built in a stereolothography apparatus from a photocurable
ceramic filled material, the representation defining the item in
terms of reference data relative to a three dimensional coordinate
system having a 1.sup.st, 2.sup.nd, 3.sup.rd axis; adjusting the
reference data to compensate for the anisotropic shrinkage of a
green ceramic item upon sintering; building the green ceramic item
in the stereolithography apparatus utilizing the reference data
after said adjusting, the green ceramic item being built from the
photocurable ceramic filled material; and sintering the green
ceramic item to define a sintered ceramic item that is
substantially dimensionally accurate with the reference data.
52. The method of claim 51, wherein said building includes building
a plurality of layers from the photocurable ceramic filled
material, and wherein the photocurable ceramic filled material
includes a monomer and a photoinitator; and which further includes
leveling each of the plurality of layers of the photocurable
ceramic filled material prior to forming the next layer, and
wherein said building includes exposing each of the plurality of
layers of the photocurable ceramic filled material to an energy
dose.
53. The method of claim 51, wherein the sintered ceramic item is
dimensionally accurate with the reference data within about
1.5%.
54. The method of claim 51, wherein the sintered ceramic item is
dimensionally accurate with the reference data within about
0.5%.
55. The method of claim 51, wherein the photocurable ceramic filled
material has a ceramic loading within a range of 35% to 65%.
56. A ceramic product, comprising: a sintered ceramic body having
at least a near net shape, the ceramic body formed by: representing
the ceramic body including its dimensions relative to a three
dimensional coordinate system, the body adapted to be formed as a
green ceramic item in a stereolithography apparatus from a
photo-polymerizable material including ceramic particles; applying
unequal scaling factors to the dimensions to compensate for
anisotropic shrinkage of the green ceramic body relative to the
axes of the coordinate system upon the green ceramic body being
sintered; building the green ceramic body in the stereolithography
apparatus after said adjusting; and heating the green ceramic body
to form a sintered ceramic body substantially conforming to the
dimensions.
Description
CROSS-REFERENCE TO RELATED APPLICATIONS
[0001] This application claims the benefit of U.S. Provisional
Patent Application Ser. No. 60/620,104 filed Oct. 19, 2004, which
is incorporated herein by reference.
BACKGROUND OF THE INVENTION
[0002] The present invention relates generally to a method for
producing ceramic items utilizing ceramic stereolithography. More
specifically, in one form the invention relates to a method for
compensating for the anisotropic shrinkage of a ceramic item to
produce dimensionally accurate ceramic stereolithography items.
[0003] Engineers and scientists are working in the field of
stereolithography to develop additional processes for the
production of components. In the area of non-ceramic
stereolithography the scientific community is mainly concerned with
shrinkage associated with the curing of the polymeric material. The
types of materials used in non-ceramic stereolithography generally
have very small shrink rates associated with post cure processing;
such as by ultraviolet lamps.
[0004] In the area of ceramic stereolithography, there presently
does not appear to be significant developmental activity going on
associated with the study of dimensional accuracy of sintered
ceramic stereolithography items. An interest in producing
dimensionally accurate parts through ceramic stereolithography
provided motivation for the development of the present inventions.
The present invention satisfies this need and others in a novel and
unobvious way.
SUMMARY OF THE INVENTION
[0005] The present inventions are set forth literally in the
claims. The invention generally can be summarized as a method for
compensating for the anisotropic shrinkage of a ceramic item when
it is sintered.
[0006] One object of the present invention is to provide a unique
method for producing a ceramic item.
[0007] Related objects and advantages of the present invention will
be apparent from the following description.
BRIEF DESCRIPTION OF THE DRAWINGS
[0008] FIG. 1 is an illustrative view of one form of an item being
fabricated by a stereolithography process.
[0009] FIG. 2 is an illustrative view of the layer built item of
FIG. 1.
[0010] FIG. 3 is an illustrative top plan view of a portion of one
of the layers of the item of FIG. 2.
[0011] FIG. 4 is a perspective view of one embodiment of a
shrinkage measurement test item.
[0012] FIG. 5 is a flow chart illustrating one embodiment of a
system for creating a build file that determines how the item is
built.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
[0013] For purposes of promoting an understanding of the principles
of the invention, reference will now be made to the embodiments
illustrated in the drawings and specific language will be used to
describe the same. It will nevertheless be understood that no
limitation of the scope of the invention is thereby intended, such
alterations and further modifications in the illustrated device,
and such further applications of the principles of the invention as
illustrated therein being contemplated as would normally occur to
one skilled in the art to which the invention relates.
[0014] The general field of ceramic stereolithography is believed
known to those of ordinary skill in the art. More specifically,
ceramic stereolithography utilizes a photo-polymerizable resin
containing ceramic particles that solidifies when exposed to an
appropriate energy dose. The present invention contemplates that
the photo-polymerizable material including ceramic particles can be
described in many ways including, but not limited to filled and
loaded. In one form of the present invention the
photo-polymerizable material includes ceramic particles within a
range of 35% to 65% by volume; however other relationships are
contemplated herein.
[0015] The photo-polymerizable ceramic resin after being dosed with
energy forms a green state ceramic item. The green state ceramic
item is subjected to a burning off act to remove the photo-polymer
and then a sintering act is applied to the ceramic material. During
the sintering of the ceramic material there is a volumetric change
in the item. Further, the inventors have recognized that there is
generally very little volumetric change occurring during the
burning off act of the photo-polymer. In one form ceramic
stereolithography is accomplished in a machine adapted for
stereolithography operations and available from 3D Systems of
Valencia, Calif. However, the present inventions are applicable
with virtually any type of apparatus or techniques for producing an
item by stereolithography. Further, information related to
selective laser activation and/or stereolithography is disclosed in
U.S. Pat. Nos. 5,256,340, 5,556,590, 5,571,471 and in pending U.S.
patent application Ser. No. 10/462,168, which are all incorporated
herein by reference.
[0016] With reference to FIG. 1, there is illustrated one
embodiment of an item 45 being formed by a ceramic
stereolithography process. Ceramic stereolithography as utilized
herein should be broadly construed and includes the utilization of
ceramic material within a photo-polymerizabele resin. The term item
is intended to be read broadly and includes, but is not limited to,
molds, parts, components and/or subcomponents. Item 45 is merely
illustrative and is shown being formed by the photo-polymerization
of the ceramic filled resin into layers (e.g. 50, 51, 52, 53) of
ceramic particles that are held together by a polymer binder. The
reader should understand that there is no intention herein to limit
the present application to any particular number of layers unless
specifically provided to the contrary.
[0017] Stereolithography apparatus 500 is illustrated in a
simplified manner to facilitate the explanation of one method of
making ceramic item 45. In one form the formation of the layers
(e.g. 50-53) utilizes a leveling technique to level each of the
layers of photo-polymerizable ceramic filled resin prior to
receiving a dose of energy. The present application contemplates
the following techniques to level the resin: ultrasonic processing;
time delay; and/or mechanically assisted sweep such a wiper blade.
However, the present application also contemplates an embodiment
that does not utilize express techniques for leveling each of the
layers prior to receiving a dose of energy. A three dimensional
coordinate system including a first axis, a second axis and a third
axis is utilized as a reference for the item being fabricated. In
one form the three dimensional coordinate system is a Cartesian
coordinate system. More preferably, the Cartesian coordinate system
includes an X, Y and Z axis utilized as a reference for the item
being fabricated correspond to the axis of the stereolithography
apparatus. However, other three dimensional coordinate systems are
contemplated herein, including but not limited to polar,
cylindrical, spherical. The text will generally describe the
present invention in terms of a Cartesian coordinate system,
however it is understood that it is equally applicable to other
three dimensional coordinate systems.
[0018] In one form stereolithography apparatus 500 includes a
fluid/resin containment reservoir 501, an elevation-changing member
502, and a laser 46. The reservoir 501 is filled with a quantity of
the photocurable ceramic filled resin from which the item 45 is
fabricated. Item 45 is illustrated being fabricated in layer by
layer fashion in the stereolithography apparatus 500 in the
direction of axis Z; which is referred to as the build direction.
The item 45 is built at a build orientation angle as measured from
the axis Z. The build orientation angle illustrated is
zero.degree.; however there is no limitation intended herein
regarding the build orientation angle as other build orientation
angles are fully contemplated herein. The three dimensional
coordinate system is aligned with the build orientation angle. More
specifically, in a preferred form the three dimensional coordinate
system of the item being fabricated and the stereolithography
apparatus' coordinate system are coextensive.
[0019] With reference to FIG. 2, there is illustrated an enlarged
view of a portion of the item 45. The item 45 includes a plurality
of cured layers 50, 51, 52 which define a portion of the item. The
present application contemplates that the term cured includes
partially or totally cured layers. The layers are contemplated as
having the same or different shapes, may be solid or contain voids
or holes, may have the same or differing thickness as required by
the design parameters. In one form the cured layers have a
thickness within a range of about 0.001 to about 0.008 inches. In
another form each of the layers has a thickness of about 0.002
inches. However, other cured layer thickness are contemplated
herein.
[0020] With reference to FIG. 3, there is set forth a purely
illustrative plan view of a portion of a layer 53. Layer 53
represents a portion of a layer formed in a stereolithography
apparatus 500 that utilized a wiper blade moved in the direction of
axis Y to level the photo-polymerizable ceramic filled resin prior
to receiving a dose of energy. The wiper blade interacts with the
photo-polymerizable ceramic filled material and affects the
homogeneity in at least two dimensions. The inventors have
discovered that the shrinkage in the item associated with a
subsequent sintering act is anisotropic in the three directions;
for example the X, Y and Z directions. Anisotropic shrinkage can be
considered to occur when isotropic shrinkage is not sufficient to
keep the sintered item within a predetermined geometric tolerance.
In the discussion of the anisotropic shrinkage relative to the X, Y
and Z axis the Z axis represents the build direction and the Y axis
represents the direction of the movement of the wiper blade. The
inventors have determined that shrinkage in the Z direction (build
direction) is greater than in the X and Y directions. Factors to
consider when evaluating the shrinkage are the solid loading in the
photo-polymerizable resin, the resin formulation, the build style
and orientation and how the item is sintered.
[0021] With reference to FIG. 4, there is illustrated one
embodiment of a shrinkage measurement test model 300. In one form
the shrinkage measurement test model 300 is created as a solid body
model and then generated as an STL file. In one form the item is
oriented such that the back corner represents the origin of a
Cartesian coordinate system X, Y, Z. The vertical direction of the
STL being aligned with the Z axis and the two sides 301 and 302
being aligned with the X and Y axis respectively. The item is than
built in a stereolithography apparatus with the Cartesian
coordinate system of the item aligned with the coordinate system of
the stereolithography apparatus. The present invention can be
utilized with any suitable file format and/or hardware.
[0022] The shrinkage measurement test model 300 in the green state
is then subjected to a comprehensive inspection to quantify
dimensions of the item. The measurements taken during inspection
can be obtained with known equipment such as, but not limited to
calipers and/or coordinate measuring machines. In one form the
shrinkage measurement test model has been designed so that all of
the inspection dimensions line up along the X, Y and/or Z axis. The
item is then subjected to a firing act to burn off the
photo-polymer and sinter the ceramic material. The comprehensive
inspection is repeated to quantify the dimensions of the item after
being sintered.
[0023] The measured values from the comprehensive inspection after
firing are than compared with the inspection values from the green
state item. In one form the comparison is done by plotting the
measured values of the fired item against the measured values from
the green state item. A least squares analysis is performed to
obtain a linear equation. The resulting slope of the equations is
the shrinkage factors for each of the X, Y and Z
direction/dimensions. The shrinkage for each of the X, Y and Z
directions/dimensions are applied to one of the STL file or the
solid body model to expand the dimensions in the respective
directions of the coordinate system. The process will modify one of
the STL file or the solid body model in the directions of the
coordinate system to account for the anisotropic shrinkage of the
item. In one non-limiting example the shrinkage factors to account
for shrinkage are 118%, 115% and 120% in the X, Y, Z direction
respectively for an item having a length of about two inches. The
present application contemplates a wide variety of shrinkage
factors and is not limited in any manner to these factors unless
specifically provided o the contrary.
[0024] The application of the present invention enables the
production of sintered ceramic items having substantially
conformity with the item's design parameters. In one form the
dimensional accuracy of the sintered ceramic item to the design
parameters is within a range of 0.0% to 1.5% and in another form
the dimensional accuracy is within a range of 0.0% to 0.5%.
Further, the present invention is also applicable to form sintered
ceramic items in either near net shape or net shape. Additionally,
other degrees of dimensional accuracy are contemplated herein.
[0025] In an alternate form the comparison utilized to calculate
the shrinkage factors of the shrinkage measurement test model is
between the inspection values of the fired test model and the
dimensional design values from the solid body model. The process as
described above is then continued to find the shrinkage factors for
the X, Y and Z dimensions/directions.
[0026] With reference to FIG. 5, there is illustrated one
non-limiting embodiment of a system for creating a build file 1005
that determines how the item 45 is created in the stereolithography
apparatus. This process is representative of a technique that can
be utilized to produce the build file, but the present application
is not intended to be limited to the one embodiment in FIG. 5
unless specifically stated to the contrary. In act 1000 data
defining parameters of the item are collected and processed to
define a specification for the item design. The data from act 1000
is utilized in act 1001 to construct an item model using, for
example, a computer modeling system. In one embodiment the computer
modeling system creates an electronic model such as but not limited
to a solid body model. However, other modeling systems are
contemplated herein. The item model from act 1001 is then processed
in a modified item model act 1002 to create a model of the item
taking into account the anisotropic shrinkage. While the present
application discusses the process in terms of modification of the
item model it is understood that the same type of modification is
applicable to the STL/STC files to create a modified item file. The
modified item act 1002 utilizes an X shrinkage factor, a Y
shrinkage factor and a Z shrinkage factor. The shrinkage factors
are used to increase the respective underlaying dimensions to a
modified dimension. The X, Y and Z shrinkage factors will be
applied so that they correspond to the coordinate system of the
stereolithography apparatus.
[0027] In one form a conversion act 1003 is utilized to convert the
modified item model, produced in act 1002 to a file format, such as
STL or SLC. Next, the file from act 1003 is processed in act 1004
to create discrete two-dimensional slices appropriate for drawing
the layers of the item and any required supports. In act 1005 the
build file is completed, which will be utilized to drive the energy
source of the stereolithography apparatus and produce the green
ceramic item.
[0028] In one form the ceramic filled resin comprises a sinterable
ceramic material, a photocurable monomer, a photoinitiator and a
dispersant. The ceramic filled resin is adapted for use in
stereolithography to produce a green ceramic item. In one form the
filled resin is prepared by admixing the components to provide a
filled resin having viscosity within a range of about 300
centipoise to about 3,500 centipoise at a shear rate of about 0.4
per second; in another form the filled resin has a viscosity of
about 2,500 centipoise at a shear rate of about 0.4 per second.
However, the present application contemplates filled resins having
other viscosity values.
[0029] The loading of ceramic material within the resin is
contemplated within a range of 35% to 65% by volume. Another form
of the ceramic loading within the resin is contemplated as being
about 50.3% by volume. In one preferred resin the ceramic loading
has the volume percent of ceramic material substantially equal to
the weight percent of ceramic material within the resin. However,
resins having other ceramic loadings are fully contemplated herein.
More specifically, the present application contemplates that the
volume percent of the ceramic material in the resin may be equal to
the weight percent of the ceramic material in the resin or that the
volume percent of the ceramic material in the resin may be unequal
to the weight percent of the ceramic material in the resin. The
sinterable ceramic material can be selected from a wide variety of
ceramic materials. Specific examples include, but are not limited
to, alumina, yttria, magnesia, silicon nitride, silica and mixtures
thereof.
[0030] In one example alumina is selected as the sinterable ceramic
material. Alumina can be provided as a dry powder having an average
particle size suitable for sintering to provide an item having the
desired characteristics. In one form the powdered alumina has an
average particle size within a range of 0.1 microns to 5.0 microns.
In another form the powdered alumina is selected to have an average
particle size within a range of 0.5 microns to 1.0 microns.
However, other particle sizes for the alumina material are
contemplated herein.
[0031] The monomer is selected from any suitable monomer that can
be induced to polymerize when irradiated in the presence of a
photoinitiator. Examples of monomers include acrylate esters and
substituted acrylate esters. A combination of two or more monomers
may be used. Preferably at least one of the monomers is a
multifunctional monomer. By multifunctional monomer it is
understood that the monomer includes more than two functional
moieties capable of forming bonds with a growing polymer chain.
Specific examples of monomers that can be used with this invention
include 1,6-hexanediol diacrylate (HDDA) and 2-phenoxyethyl
acrylate (POEA). In one form the photocurable monomers are present
in an amount between about 10 wt % to about 40 wt %, and in another
form about 10 wt % to about 35 wt %, and in yet another form about
20 wt % to 35 wt % based upon the total weight of the filled resin.
However, the present application contemplates other amounts of
monomers.
[0032] The dispersant is provided in an amount suitable to maintain
a substantially uniform colloidal suspension of the alumina in the
filled resin. The dispersant can be selected from a wide variety of
known surfactants. Dispersants contemplated herein include, but are
not limited to, ammonium salts, more preferably tetraalkyl ammonium
salts. Examples of dispersants for use in this invention include,
but are not limited to: polyoxypropylene diethyl-2-hydroxyethyl
ammonium acetate, and ammonium chloride. In one form the amount of
dispersant is between about 1.0 wt % and about 10 wt % based upon
the total weight of the ceramic within the filled resin. However,
the present application contemplates other amounts of
dispersants.
[0033] The initiator is selected from a number of commercially
available photoinitiators believed known to those skilled in the
art. The photoinitiator is selected to be suitable to induce
polymerization of the desired monomer when irradiated. Typically
the selection of a photoinitiator will be dictated by the
wavelength of radiation used to induce polymerization.
Photoinitiators contemplated herein include, but are not limited to
benzophenone, trimethyl benzophenone, 1-hydroxycyclohexyl phenyl
ketone, isopropylthioxanthone, 2-methyl-1-[4
(methylthio)phenyl]-2-morpholinoprophanone and mixtures thereof.
The photoinitiator is added in an amount sufficient to polymerize
the monomers when the filled resin is irradiated with radiation of
appropriate wavelength. In one form the amount of photoinitiator is
between about 0.05 wt % and about 5 wt % based upon the total
weight of the monomer within the filled resin. However, other
amounts of photoiniators are contemplated herein.
[0034] In an alternate form of the ceramic filled resin a quantity
of a nonreactive diluent is substituted for a quantity of the
monomer. In one form the amount of substituted nonreactive diluent
is equal to between about 5% and about 20% (by weight) of the
monomer in the resin. However, the present application contemplates
that other amounts of non-reactive diluents are considered herein.
An illustration of a given ceramic resin composition requires 100
grams of a monomer that in the alternate form will replace about
5-20 wt % of the monomer with a nonreactive diluent (i.e. 95-80
grams of monomer +5-20 grams of nonreactive diluent). The
nonreactive diluent includes but is not limited to a dibasic ester
or a decahydronaphthalene. Examples of dibasic esters include
dimethyl succinate, dimethyl glutarate, and dimethyl adipate, which
are available in a pure form or a mixture.
[0035] The filled resin is prepared by combining the monomer, the
dispersant and the sinterable ceramic to form a homogeneous
mixture. Although the order of addition is not critical to this
invention typically, the monomer and the dispersant are combined
first and then the sinterable ceramic is added. In one form the
sinterable ceramic material is added to the monomer/dispersant
combination in increments of about 5 to about 20 vol. %. Between
each incremental addition of the ceramic material, the resulting
mixture is thoroughly mixed by any suitable method, for example,
ball milling for about 5 to about 120 minutes. When all of the
sinterable ceramic material has been added, the resulting mixture
is mixed for an additional amount of time up to 10 hours or more.
The photoinitiator is added and blended into the mixture.
[0036] With reference to Table I there is set forth one example of
an alumina filled resin. However, the present application is not
intended to be limited to the specific composition set forth below
unless specifically stated to the contrary.
TABLE-US-00001 vol wt/g cc wt % vol % Alumina 1980 500 78.2 48.0
Monomer 510 500 20.1 48.0 Dispersant 39.6 38.8 1.56 3.73
Photoinitiator 2.55 2.32 0.101 0.223 Total 2532 1041 100% 100%
[0037] In one form the green ceramic item is sintered to a
temperature within a range of 1100.degree. C. to 1700.degree. C.
The present invention contemplates other sintering parameters.
Further, the present invention contemplates sintering to a variety
of theoretical densities, including but not limited to about 60% of
theoretical density. The density of the sintered material is
preferably greater than sixty percent of the theoretical density,
and densities equal to or greater than about ninety-four percent of
the theoretical density are more preferred. However, the present
invention contemplates other densities.
[0038] The present application contemplates the utilization of a
three dimensional coordinate system as a reference for an item
being fabricated from the photo-polymerizable ceramic filled resin.
As discussed above the inventors have discovered that the shrinkage
of the item in a subsequent sintering act is anisotropic in the
three directions. Therefore, in one form of the present invention
there are utilized three unequal scaling factors to take into
consideration the respective shrinkage in the dimensions of the
item in all three directions. In another form of the present
invention there are utilized only two unequal scaling factors to
account for the respective shrinkage in the dimensions of the item
in all three directions; that is the dimensions in two of the three
directions are adjusted by scaling factors having the same
value.
[0039] While the inventions have been illustrated and described in
detail in the drawings and foregoing description, the same is to be
considered as illustrative and not restrictive in character, it
being understood that only the preferred embodiment has been shown
and described and that all changes and modifications that come
within the spirit of the invention are desired to be protected. It
should be understood that while the use of the word preferable,
preferably or preferred in the description above indicates that the
feature so described may be more desirable, it nonetheless may not
be necessary and embodiments lacking the same may be contemplated
as within the scope of the invention, that scope being defined by
the claims that follow. In reading the claims it is intended that
when words such as "a," "an," "at least one," "at least a portion"
are used there is no intention to limit the claim to only one item
unless specifically stated to the contrary in the claim. Further,
when the language "at least a portion" and/or "a portion" is used
the item may include a portion and/or the entire item unless
specifically stated to the contrary.
* * * * *