U.S. patent application number 12/161506 was filed with the patent office on 2011-07-28 for pesticidal mixtures.
This patent application is currently assigned to BASF Aktiengesellschaft. Invention is credited to Douglas D. Anspaugh, Nigel Armes, Henricus Maria Martinus Bastiaans, Joachim Dickhaut, Markus Gewehr, David G. Kuhn, Hassan Oloumi-Sadeghi, Michael Puhl.
Application Number | 20110183012 12/161506 |
Document ID | / |
Family ID | 38180408 |
Filed Date | 2011-07-28 |
United States Patent
Application |
20110183012 |
Kind Code |
A1 |
Gewehr; Markus ; et
al. |
July 28, 2011 |
Pesticidal Mixtures
Abstract
Pesticidal mixtures comprising, as active components, 1) an
anthranilamid compound of the formula I ##STR00001## wherein Q is
H, Cl, Cr, I, CN or methyl; B.sup.1 is halogen, alkyl, haloalkyl,
or haloalkoxy; B.sup.2 is halogen, haloalkyl, alkoxy, haloalkoxy,
alkenyloxy, alkynyloxy, alkylthio, haloalkylthio, alkylsulfinyl,
haloalkylsulfinyl, alkylsulfonyl, haloalkylsulfonyl,
alkyl-S(.dbd.O).sub.x--O-- or haloalkyl S(O).sub.x--O--, wherein x
is 1 or 2 and the alkoxy radical may be substituted, or
C(R.sup.i).dbd.N--OR.sup.j, C(R.sup.i).dbd.N(R.sup.jR.sup.k),
wherein R.sup.i, R.sup.j and R.sup.k are alkyl; R is hydrogen,
alkyl, alkenyl, alkynyl, cycloalkyl, alkylene-cycloalkyl, wherein
these groups are optionally substituted; R.sup.1 is F, Cl, Br,
methyl or trifluoromethyl; or the enantiomers or salts or N-oxides
thereof, n is 1, 2 or 3; and 2) one or more compounds II selected
from group A consisting of organo(thio)-phosphates, carbamates,
pyrethroids, growth regulators, nicotinic receptor
agonists/antagonists compounds, GABA antagonist compounds,
macrocyclic lactone insecticides, METI I acaricides, METI II and
III compounds, uncoupler compounds, oxidative phosphorylation
inhibitor compounds, mixed function oxidase inhibitor compounds,
sodium channel blocker compounds and others, all as defined in the
description, in synergistically effective amounts, use of these
mixture for combating insects, arachnids or nematodes in and on
plants and for the protection of seeds, and for treating,
controlling, preventing or protecting a warm-blooded animal or a
fish against infestation or infection by parasites.
Inventors: |
Gewehr; Markus; (Kastellaun,
DE) ; Puhl; Michael; (Lampertheim, DE) ;
Dickhaut; Joachim; (Heidelberg, DE) ; Bastiaans;
Henricus Maria Martinus; (Usingen, DE) ; Anspaugh;
Douglas D.; (Apex, NC) ; Kuhn; David G.;
(Apex, NC) ; Oloumi-Sadeghi; Hassan; (Raleigh,
NC) ; Armes; Nigel; (Raleigh, NC) |
Assignee: |
BASF Aktiengesellschaft
Ludwigshafen
DE
|
Family ID: |
38180408 |
Appl. No.: |
12/161506 |
Filed: |
January 12, 2007 |
PCT Filed: |
January 12, 2007 |
PCT NO: |
PCT/EP07/50280 |
371 Date: |
October 16, 2008 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
|
|
60760532 |
Jan 20, 2006 |
|
|
|
Current U.S.
Class: |
424/703 ;
514/120; 514/128; 514/132; 514/229.2; 514/247; 514/275; 514/28;
514/341; 514/342; 514/345; 514/355; 514/357; 514/407; 514/53;
514/80 |
Current CPC
Class: |
A61P 33/14 20180101;
A61P 43/00 20180101; A01N 43/56 20130101; A01N 43/56 20130101; A01N
2300/00 20130101 |
Class at
Publication: |
424/703 ;
514/341; 514/407; 514/132; 514/342; 514/120; 514/275; 514/80;
514/128; 514/345; 514/53; 514/247; 514/357; 514/28; 514/229.2;
514/355 |
International
Class: |
A01N 59/02 20060101
A01N059/02; A01N 43/40 20060101 A01N043/40; A01N 43/56 20060101
A01N043/56; A01N 57/14 20060101 A01N057/14; A01N 57/12 20060101
A01N057/12; A01N 43/54 20060101 A01N043/54; A01N 57/16 20060101
A01N057/16; A01N 43/16 20060101 A01N043/16; A01N 43/58 20060101
A01N043/58; A01N 43/24 20060101 A01N043/24; A01N 43/88 20060101
A01N043/88; A01P 5/00 20060101 A01P005/00; A01P 7/00 20060101
A01P007/00; A01P 7/02 20060101 A01P007/02; A01P 7/04 20060101
A01P007/04 |
Claims
1. Pesticidal mixtures comprising, as active components, 1) an
anthranilamid compound of the formula I ##STR00007## wherein Q is
hydrogen, chloro, bromo, iodo, cyano, or methyl; B.sup.1 is
halogen, C.sub.1-C.sub.4-alkyl, C.sub.1-C.sub.4-haloalkyl, or
C.sub.1-C.sub.4-haloalkoxy; B.sup.2 is halogen,
C.sub.1-C.sub.4-haloalkyl, C.sub.1-C.sub.4-alkoxy,
C.sub.1-C.sub.4-haloalkoxy, C.sub.1-C.sub.4-alkenyloxy,
C.sub.1-C.sub.4-alkynyloxy, C.sub.1-C.sub.4-alkylthio,
C.sub.1-C.sub.4-haloalkylthio, C.sub.1-C.sub.4-alkylsulfinyl,
C.sub.1-C.sub.4-haloalkylsulfinyl, C.sub.1-C.sub.4alkylsulfonyl,
C.sub.1-C.sub.4-haloalkylsulfonyl,
C.sub.1-C.sub.4-alkyl-S(.dbd.O).sub.x--O-- or
C.sub.1-C.sub.4haloalkyl S(O).sub.x--O--, wherein x is 1 or 2 and
the C.sub.1-C.sub.4-alkoxy radical may be substituted with 1-6
groups selected from halogen, cyano, C.sub.1-C.sub.4-alkoxy,
C.sub.1-C.sub.4-alkoxycarbonyl, or C(R.sup.i).dbd.N--OR.sup.j,
C(R.sup.i)=N(R.sup.jR.sup.k), wherein R.sup.i, R.sup.j and R.sup.k
are each independently hydrogen or C.sub.1-C.sub.4-alkyl; R is
hydrogen, C.sub.1-C.sub.6-alkyl, C.sub.2-C.sub.6-alkenyl,
C.sub.2-C.sub.6-alkynyl, C.sub.3-C.sub.6-cycloalkyl,
C.sub.1-C.sub.4-alkylene-C.sub.3-C.sub.6-cycloalkyl, wherein these
groups are unsubstituted or substituted with from 1 to 3 groups
selected from halogen, cyano, nitro,
C.sub.1-C.sub.6-alkyloxycarbonyl, amino,
C.sub.1-C.sub.6-alkylamino, di(C.sub.1-C.sub.6-alkyl)amino,
C.sub.1-C.sub.6-alkoxy, C.sub.1-C.sub.6-thioalkyl,
C.sub.1-C.sub.6-alkylsulfinyl, C.sub.1-C.sub.6-alkylsulfonyl;
R.sup.1 is fluoro, chloro, bromo, methyl, or trifluoromethyl; n is
1, 2 or 3; or the enantiomers or salts or N-oxides thereof, and 2)
one or more compounds II selected from group A consisting of A.1.
Organo(thio)phosphates: acephate, azamethiphos, azinphos-methyl,
chlorpyrifos, chlorpyrifos-methyl, chlorfenvinphos, diazinon,
dichlorvos, dicrotophos, dimethoate, disulfoton, ethion,
fenitrothion, fenthion, isoxathion, malathion, methamidophos,
methidathion, methyl-parathion, mevinphos, monocrotophos,
oxydemeton-methyl, paraoxon, parathion, phenthoate, phosalone,
phosmet, phosphamidon, phorate, phoxim, pirimiphos-methyl,
profenofos, prothiofos, sulprophos, tetrachlorvinphos, terbufos,
triazophos, trichlorfon; A.2. Carbamates: alanycarb, aldicarb,
bendiocarb, benfuracarb, carbaryl, carbofuran, carbosulfan,
fenoxycarb, furathiocarb, methiocarb, methomyl, oxamyl, pirimicarb,
propoxur, thiodicarb, triazamate; A.3. Pyrethroids: allethrin,
bifenthrin, cyfluthrin, cyhalothrin, cyphenothrin, cypermethrin,
alpha-cypermethrin, beta-cypermethrin, zeta-cypermethrin,
deltamethrin, esfenvalerate, etofenprox, fenpropathrin,
fenvalerate, imiprothrin, lambda-cyhalothrin, permethrin,
prallethrin, pyrethrin I and II, resmethrin, silafluofen,
tau-fluvalinate, tefluthrin, tetramethrin, tralomethrin,
transfluthrin, profluthrin, dimefluthrin; A.4. Growth regulators:
a) chitin synthesis inhibitors: benzoylureas: chlorfluazuron,
cyramazin, diflubenzuron, flucycloxuron, flufenoxuron,
hexaflumuron, lufenuron, novaluron, teflubenzuron, triflumuron;
buprofezin, diofenolan, hexythiazox, etoxazole, clofentazine; b)
ecdysone antagonists: halofenozide, methoxyfenozide, tebufenozide,
azadirachtin; c) juvenoids: pyriproxyfen, methoprene, fenoxycarb;
d) lipid biosynthesis inhibitors: spirodiclofen, spiromesifen,
spirotetramat; A.5. Nicotinic receptor agonists/antagonists
compounds: clothianidin, dinotefuran, imidacloprid, thiamethoxam,
nitenpyram, acetamiprid, thiacloprid; A.6. GABA antagonist
compounds: acetoprole, endosulfan, ethiprole, fipronil,
vaniliprole, pyrafluprole, pyriprole, the phenylpyrazole compound
of formula .GAMMA..sup.1 ##STR00008## A.7. Macrocyclic lactone
insecticides: abamectin, emamectin, milbemectin, lepimectin,
spinosad; A.8. METI I acaricides: fenazaquin, pyridaben,
tebufenpyrad, tolfenpyrad, flufenerim; A.9. METI II and III
compounds: acequinocyl, fluacyprim, hydramethylnon; A.10. Uncoupler
compounds: chlorfenapyr; A.11. Oxidative phosphorylation inhibitor
compounds: cyhexatin, diafenthiuron, fenbutatin oxide, propargite;
A.12. Moulting disruptor compounds: cryomazine; A.13. Mixed
Function Oxidase inhibitor compounds: piperonyl butoxide; A.14.
Sodium channel blocker compounds: indoxacarb, metaflumizone, A.15.
Various: benclothiaz, bifenazate, cartap, flonicamid, pyridalyl,
pymetrozine, sulfur, thiocyclam, flubendiamide, cyenopyrafen,
flupyrazofos, cyflumetofen, amidoflumet,
N--R'-2,2-dihalo-1-R''cyclo-propanecarboxamide-2-(2,6-dichloro-.alpha.,.a-
lpha.,.alpha.-tri-fluoro-p-tolyl)hydrazone or
N--R'-2,2-di(R''')propionamide-2-(2,6-dichloro-.alpha.,.alpha.,.alpha.-tr-
ifluoro-p-tolyl)-hydrazone, wherein R' is methyl or ethyl, halo is
chloro or bromo, R'' is hydrogen or methyl and R''' is methyl or
ethyl, wherein R.sup.i is --CH.sub.2OCH.sub.2CH.sub.3 or H and
R.sup.ii is CF.sub.2CF.sub.2CF.sub.3 or CH.sub.2CH(CH.sub.3).sub.3,
anthranilamide compounds of formula .GAMMA..sup.2 ##STR00009##
wherein B.sup.1 is hydrogen, CN or a chlorine atom, B.sup.2 is a
bromine or chlorine atom, CF.sub.3, OCH.sub.2CF.sub.3OCF.sub.2H,
CH.dbd.N--OCH.sub.3, CH.dbd.NOCH.sub.2CH.sub.3,
C(CF.sub.3).dbd.N--OCH.sub.3, or
C(CF.sub.3).dbd.N--OCH.sub.2CH.sub.3, and R.sup.B is hydrogen,
CH.sub.3 or CH(CH.sub.3).sub.2, and malononitrile compounds as
described in JP 2002 284608, WO 02/89579, WO 02/90320, WO 02/90321,
WO 04/06677, WO 04/20399, or JP 2004 99597, in synergistically
effective amounts.
2. Pesticidal mixtures as claimed in claim 1, wherein the compound
of formula I is a compound of formula I.1 ##STR00010## wherein Q is
chloro, bromo, iodo or cyano; B.sup.1 is chloro, bromo, iodo, or
methyl; B.sup.2 is chloro, bromo, trifluoromethyl,
2,2,2-trifluoroethoxy, difluoromethyl, CH.dbd.N--OCH.sub.3, or
C(CF.sub.3).dbd.N--OCH.sub.3; R is hydrogen or
C.sub.1-C.sub.4-alkyl which may be substituted with CN or
SCH.sub.3; X is fluoro, chloro or bromo; Y is hydrogen, fluoro or
chloro; V is hydrogen, fluoro or chloro; or the enantiomers or
salts or N-oxides thereof.
3. Pesticidal mixtures as claimed in claim 1, wherein the compound
of formula II is selected from the group A-1 consisting of
acetoprole, ethiprole, fipronil, vaniliprole, indoxacarb,
metaflumizone, flonicamid, and pyridalyl.
4. Pesticidal mixtures as claimed in claim 1, wherein the compound
of formula II is fipronil.
5. Pesticidal mixtures as claimed in claim 1, wherein the compound
of formula II is indoxacarb.
6. Pesticidal mixtures as claimed in claim 1, wherein the compound
of formula II is metaflumizone.
7. Pesticidal mixtures as claimed in claim 1, wherein the compound
of formula II is flonicamid.
8. Pesticidal mixtures as claimed in claim 1, wherein the compound
of formula II is pyridalyl.
9. Pesticidal mixtures as claimed in claim 1, comprising the
compound of the formula I and the compound of the formula II in a
weight ratio of from 500:1 to 1:100.
10. (canceled)
11. A method for protecting plants from attack or infestation by
insects, acarids or nematodes comprising contacting the plant, or
the soil or water in which the plant is growing, with a mixture as
defined in claim 1 in pesticidally effective amounts.
12. A method for controlling insects, arachnids or nematode
comprising contacting an insect, acarid or nematode or their food
supply, habitat, breeding grounds or their locus with a mixture as
defined in claim 1 in pesticidally effective amounts.
13. A method as claimed in claim 11, wherein the mixture as claimed
in claim 1 is applied in an amount of from 5 g/ha to 2000 g/ha.
14. A method of protection of seed comprising contacting the seeds
before sowing and/or after pregermination with a mixture as defined
in claim 1 in pesticidally effective amounts.
15. A method as claimed in claim 14 wherein the mixture as claimed
in claim 1 is applied in an amount of from 0.1 g to 10 kg per 100
kg of seeds.
16. Seed, comprising the mixture as claimed in claim 1 in an amount
of from 0.1 g to 10 kg per 100 kg of seeds.
17. A method as claimed in claim 11, wherein the compounds I and II
as defined in claim 1 are applied simultaneously, that is jointly
or separately, or in succession.
18. A method for treating, controlling, preventing or protecting a
warm-blooded animal or a fish against infestation or infection by
parasites which comprises orally, topically or parenterally
administering or applying to said animal or fish a parasiticidally
effective amount of a mixture as defined in claim 1.
19. A process for the preparation of a composition for treating,
controlling, preventing or protecting a warm-blooded animal or a
fish against infestation or infection by insects or acarids which
comprises a pesticidally effective amount of a mixture as defined
in claim 1.
20. A pesticidal or parasiticidal composition, comprising a liquid
or solid carrier and a mixture as claimed in claim 1.
Description
[0001] The present invention relates to pesticidal mixtures
comprising, as active components
[0002] Pesticidal mixtures comprising, as active components,
[0003] 1) an anthranilamid compound of the formula I
##STR00002##
[0004] wherein
[0005] Q is hydrogen, chloro, bromo, iodo, cyano or methyl;
[0006] B.sup.1 is halogen, C.sub.1-C.sub.4-alkyl,
C.sub.1-C.sub.4-haloalkyl, or C.sub.1-C.sub.4haloalkoxy;
[0007] B.sup.2 is halogen, C.sub.1-C.sub.4-haloalkyl,
C.sub.1-C.sub.4-alkoxy, C.sub.1-C.sub.4-haloalkoxy,
C.sub.1-C.sub.4-alkenyloxy, C.sub.1-C.sub.4alkynyloxy,
C.sub.1-C.sub.4-alkylthio, C.sub.1-C.sub.4-haloalkylthio,
C.sub.1-C.sub.4-alkylsulfinyl, C.sub.1-C.sub.4-haloalkylsulfinyl,
C.sub.1-C.sub.4-alkylsulfonyl, C.sub.1-C.sub.4-haloalkylsulfonyl,
C.sub.1-C.sub.4-alkyl-S(.dbd.O).sub.x--O-- or
C.sub.1-C.sub.4-haloalkyl S(O).sub.x--O--, wherein x is 1 or 2 and
the C.sub.1-C.sub.4-alkoxy radical may be substituted with 1-6
groups selected from halogen, cyano, C.sub.1-C.sub.4-alkoxy,
C.sub.1-C.sub.4-alkoxycarbonyl or C(R.sup.i).dbd.N--OR.sup.j,
C(R.sup.i).dbd.N(R.sup.jR.sup.k), wherein R.sup.i, R.sup.j and
R.sup.k are each independently C.sub.1-C.sub.4-alkyl;
[0008] R is hydrogen, C.sub.1-C.sub.6-alkyl,
C.sub.2-C.sub.6-alkenyl, C.sub.2-C.sub.6-alkynyl,
C.sub.3-C.sub.6-cycloalkyl,
C.sub.1-C.sub.4-alkylene-C.sub.3-C.sub.6-cycloalkyl, wherein these
groups are unsubstituted or substituted with from 1 to 3 groups
selected from halogen, cyano, nitro,
C.sub.1-C.sub.6-alkyloxycarbonyl, amino,
C.sub.1-C.sub.6-alkylamino, di(C.sub.1-C.sub.6-alkyl)amino,
C.sub.1-C.sub.6-alkoxy, C.sub.1-C.sub.6-thioalkyl,
C.sub.1-C.sub.6-alkylsulfinyl, C.sub.1-C.sub.6-alkylsulfonyl;
[0009] R.sup.1 is fluoro, chloro, bromo, methyl, or
trifluoromethyl;
[0010] n is 1, 2 or 3;
[0011] or the enantiomers or salts or N-oxides thereof, and
[0012] 2) one or more compounds II selected from group A consisting
of
[0013] A.1. Organo(thio)phosphates: acephate, azamethiphos,
azinphos-methyl, chlorpyrifos, chlorpyrifos-methyl,
chlorfenvinphos, diazinon, dichlorvos, dicrotophos, dimethoate,
disulfoton, ethion, fenitrothion, fenthion, isoxathion, malathion,
methamidophos, methidathion, methyl-parathion, mevinphos,
monocrotophos, oxydemeton-methyl, paraoxon, parathion, phenthoate,
phosalone, phosmet, phosphamidon, phorate, phoxim,
pirimiphos-methyl, profenofos, prothiofos, sulprophos,
tetrachlorvinphos, terbufos, triazophos, trichlorfon;
[0014] A.2. Carbamates: alanycarb, aldicarb, bendiocarb,
benfuracarb, carbaryl, carbofuran, carbosulfan, fenoxycarb,
furathiocarb, methiocarb, methomyl, oxamyl, pirimicarb, propoxur,
thiodicarb, triazamate;
[0015] A.3. Pyrethroids: allethrin, bifenthrin, cyfluthrin,
cyhalothrin, cyphenothrin, cypermethrin, alpha-cypermethrin,
beta-cypermethrin, zeta-cypermethrin, deltamethrin, esfenvalerate,
etofenprox, fenpropathrin, fenvalerate, imiprothrin,
lambda-cyhalothrin, permethrin, prallethrin, pyrethrin I and II,
resmethrin, silafluofen, tau-fluvalinate, tefluthrin, tetramethrin,
tralomethrin, transfluthrin, profluthrin, dimefluthrin;
[0016] A.4. Growth regulators: a) chitin synthesis inhibitors:
benzoylureas: chlorfluazuron, cyramazin, diflubenzuron,
flucycloxuron, flufenoxuron, hexaflumuron, lufenuron, novaluron,
teflubenzuron, triflumuron; buprofezin, diofenolan, hexythiazox,
etoxazole, clofentazine; b) ecdysone antagonists: halofenozide,
methoxyfenozide, tebufenozide, azadirachtin; c) juvenoids:
pyriproxyfen, methoprene, fenoxycarb; d) lipid biosynthesis
inhibitors: spirodiclofen, spiromesifen, spirotetramat;
[0017] A.5. Nicotinic receptor agonists/antagonists compounds:
clothianidin, dinotefuran, imidacloprid, thiamethoxam, nitenpyram,
acetamiprid, thiacloprid;
[0018] A.6. GABA antagonist compounds: acetoprole, endosulfan,
ethiprole, fipronil, vaniliprole, pyrafluprole, pyriprole, the
phenylpyrazole compound of formula .GAMMA..sup.1
##STR00003##
[0019] A.7. Macrocyclic lactone insecticides: abamectin, emamectin,
milbemectin, lepimectin, spinosad;
[0020] A.8. METI I acaricides: fenazaquin, pyridaben, tebufenpyrad,
tolfenpyrad, flufenerim;
[0021] A.9. METI II and III compounds: acequinocyl, fluacyprim,
hydramethylnon;
[0022] A.10. Uncoupler compounds: chiorfenapyr;
[0023] A.11. Oxidative phosphorylation inhibitor compounds:
cyhexatin, diafenthiuron, fenbutatin oxide, propargite;
[0024] A.12. Moulting disruptor compounds: cryomazine;
[0025] A.13. Mixed Function Oxidase inhibitor compounds: piperonyl
butoxide;
[0026] A.14. Sodium channel blocker compounds: indoxacarb,
metaflumizone,
[0027] A.15. Various: benclothiaz, bifenazate, cartap, flonicamid,
pyridalyl, pymetrozine, sulfur, thiocyclam, flubendiamide,
cyenopyrafen, flupyrazofos, cyflumetofen, amidoflumet,
N--R'-2,2-dihalo-1-R''cyclo-propanecarboxamide-2-(2,6-dichloro-.alpha.,.a-
lpha.,.alpha.-tri-fluoro-p-tolyl)hydrazone or
N--R'-2,2-di(R''')propionamide-2-(2,6-dichloro-.alpha.,.alpha.,.alpha.-tr-
ifluoro-p-tolyl)-hydrazone, wherein R' is methyl or ethyl, halo is
chloro or bromo, R'' is hydrogen or methyl and R''' is methyl or
ethyl, wherein R.sup.i is --CH.sub.2OCH.sub.2CH.sub.3 or H and
R.sup.ii is CF.sub.2CF.sub.2CF.sub.3 or CH.sub.2CH(CH.sub.3).sub.3,
anthranilamide compounds of formula .GAMMA..sup.2
##STR00004##
[0028] wherein B.sup.1 is hydrogen, CN or a chlorine atom, B.sup.2
is a bromine or chlorine atom, CF.sub.3, OCH.sub.2CF.sub.3 or
OCF.sub.2H, and R.sup.B is hydrogen, CH.sub.3 or
CH(CH.sub.3).sub.2, and malononitrile compounds as described in JP
2002 284608, WO 02/89579, WO 02/90320, WO 02/90321, WO 04/06677, WO
04/20399, or JP 2004 99597,
[0029] in synergistically effective amounts.
[0030] The present invention also provides methods for the control
of insects, acarids or nematodes comprising contacting the insect,
acarid or nematode or their food supply, habitat, breeding grounds
or their locus with a pesticidally effective amount of mixtures of
the compound I with one or more compounds II.
[0031] Moreover, the present invention also relates to a method of
protecting plants from attack or infestation by insects, acarids or
nematodes comprising contacting the plant, or the soil or water in
which the plant is growing, with a pesticidally effective amount of
a mixture of the compound I with one or more compounds II.
[0032] This invention also provides a method for treating,
controlling, preventing or protecting an animal against infestation
or infection by parasites which comprises orally, topically or
parenterally administering or applying to the animals a
parasiticidally effective amount of a mixture of the compound I
with one or more compounds II.
[0033] The invention also provides a process for the preparation of
a composition for treating, controlling, preventing or protecting a
warm-blooded animal or a fish against infestation or infection by
insects, acarids or nematodes which comprises a pesticidally
effective amount of a mixture of the compound I with one or more
compounds II.
[0034] One typical problem arising in the field of pest control
lies in the need to reduce the dosage rates of the active
ingredient in order to reduce or avoid unfavorable environmental or
toxicological effects whilst still allowing effective pest
control.
[0035] Another problem encountered concerns the need to have
available pest control agents which are effective against a broad
spectrum of pests.
[0036] There also exists the need for pest control agents that
combine know-down activity with prolonged control, that is, fast
action with long lasting action.
[0037] Another difficulty in relation to the use of pesticides is
that the repeated and exclusive application of an individual
pesticidal compound leads in many cases to a rapid selection of
pests which have developed natural or adapted resistance against
the active compound in question. Therefore there is a need for pest
control agents that help prevent or overcome resistance.
[0038] It was therefore an object of the present invention to
provide pesticidal mixtures which solve the problems of reducing
the dosage rate and/or enhancing the spectrum of activity and/or
combining know-down activity with prolonged control and/or to
resistance management.
[0039] We have found that this object is in part or in whole
achieved by the combination of active compounds defined at the
outset. Moreover, we have found that simultaneous, that is joint or
separate, application of a compound I and one or more compounds II
or successive application of a compound I and one or more compounds
II allows enhanced control of pests compared to the control rates
that are possible with the individual compounds.
[0040] Compounds of the formula I, their preparation and their
action against insect and acarid pests are known from WO
05/118552.
[0041] The commercially available compounds of the group A may be
found in The Pesticide Manual, 13.sup.th Edition, British Crop
Protection Council (2003) among other publications. Thiamides of
formula .GAMMA..sup.2 and their preparation have been described in
WO 98/28279. Lepimection is known from Agro Project, PJB
Publications Ltd, November 2004. Benclothiaz and its preparation
have been described in EP-A1 454621. Methidathion and Paraoxon and
their preparation have been described in Farm Chemicals Handbook,
Volume 88, Meister Publishing Company, 2001. Acetoprole and its
preparation have been described in WO 98/28277. Metaflumizone and
its preparation have been described in EP-A1 462 456. Flupyrazofos
has been described in Pesticide Science 54, 1988, p. 237-243 and in
U.S. Pat. No. 4,822,779. Pyrafluprole and its preparation have been
described in JP 2002193709 and in WO 01/00614. Pyriprole and its
preparation have been described in WO 98/45274 and in U.S. Pat. No.
6,335,357. Amidoflumet and its preparation have been described in
U.S. Pat. No. 6,221,890 and in JP 21010907. Flufenerim and its
preparation have been described in WO 03/007717 and in WO
03/007718. Cyflumetofen and its preparation have been described in
WO 04/080180.
[0042] Mixtures, active against pests, of compounds of formula I
with some of the compounds of formula II are described in WO
05/118552. The favourable synergistic effect of these mixtures is
not mentioned in these documents but is described herein for the
first time.
[0043] With regard to their use in the pesticidal mixtures of the
present invention, compounds of formula I.1 are especially
preferred:
##STR00005##
[0044] wherein
[0045] Q is chloro, bromo, iodo or cyano;
[0046] B.sup.1 is chloro, bromo, iodo, or methyl;
[0047] B.sup.2 is chloro, bromo, trifluoromethyl,
2,2,2-trifluoroethoxy, difluoromethyl;
[0048] R is hydrogen or C.sub.1-C.sub.4-alkyl which may be
substituted with CN or SCH.sub.3;
[0049] X is fluoro, chloro or bromo;
[0050] Y is hydrogen, fluoro or chloro;
[0051] V is hydrogen, fluoro or chloro;
[0052] or the enantiomers or salts or N-oxides thereof.
[0053] Moreover, with regard to their use in the pesticidal
mixtures of the present invention, compounds of formula I.1 are
especially preferred wherein
[0054] Q is chloro or cyano;
[0055] B.sup.1 is chloro, bromo or methyl;
[0056] B.sup.2 is chloro, bromo or trifluoromethyl;
[0057] R is hydrogen, methyl, ethyl, isopropyl or tert.-butyl;
[0058] X is fluoro, chloro or bromo;
[0059] Y is hydrogen, fluoro or chloro;
[0060] V is hydrogen, fluoro or chloro;
[0061] or the enantiomers or salts or N-oxides thereof.
[0062] With respect to their use in the pesticidal mixtures of the
present invention, particular preference is given to the compounds
IA compiled in the tables below. Moreover, the groups mentioned for
a substituent in the tables are on their own, independently of the
combination in which they are mentioned, a particularly preferred
embodiment of the substituent in question.
[0063] Table 1
[0064] Compounds of the formula IA wherein Q is chlorine, X and Y
are fluorine, V is hydrogen and the combination of B.sup.1, B.sup.2
and R in each case corresponds to a row of Table A.
##STR00006##
[0065] Table 2
[0066] Compounds of the formula IA wherein Q is chlorine, X and Y
are chlorine, V is hydrogen and the combination of B.sup.1, B.sup.2
and R in each case corresponds to a row of Table A.
[0067] Table 3
[0068] Compounds of the formula IA wherein Q is chlorine, X and V
are chlorine, Y is hydrogen and the combination of B.sup.1, B.sup.2
and R in each case corresponds to a row of Table A.
[0069] Table 4
[0070] Compounds of the formula IA wherein Q is chlorine, X and V
are fluorine, Y is hydrogen and the combination of B.sup.1, B.sup.2
and R in each case corresponds to a row of Table A.
[0071] Table 5
[0072] Compounds of the formula IA wherein Q is chlorine, X is
fluorine, Y are chlorine, V is hydrogen and the combination of
B.sup.1, B.sup.2 and R in each case corresponds to a row of Table
A.
[0073] Table 6
[0074] Compounds of the formula IA wherein Q is chlorine, X is
chlorine, Y are fluorine, V is hydrogen and the combination of
B.sup.1, B.sup.2 and R in each case corresponds to a row of Table
A.
[0075] Table 7
[0076] Compounds of the formula IA wherein Q is chlorine, X is
fluorine and Y and V are hydrogen and the combination of B.sup.1,
B.sup.2 and R in each case corresponds to a row of Table A.
[0077] Table 8
[0078] Compounds of the formula IA wherein Q is chlorine, X is
chlorine and Y and V are hydrogen and the combination of B.sup.1,
B.sup.2 and R in each case corresponds to a row of Table A.
[0079] Table 9
[0080] Compounds of the formula IA wherein Q is chlorine, X is
bromine and Y and V are hydrogen and the combination of B.sup.1,
B.sup.2 and R in each case corresponds to a row of Table A.
[0081] Table 10
[0082] Compounds of the formula IA wherein Q is chlorine, X, Y and
V are chlorine and the combination of B.sup.1, B.sup.2 and R in
each case corresponds to a row of Table A.
[0083] Table 11
[0084] Compounds of the formula IA wherein Q is chlorine, X, Y and
V are fluorine and the combination of B.sup.1, B.sup.2 and R in
each case corresponds to a row of Table A.
[0085] Table 12
[0086] Compounds of the formula IA wherein Q is cyano, X and Y are
fluorine, V is hydrogen and the combination of B.sup.1, B.sup.2 and
R in each case corresponds to a row of Table A.
[0087] Table 13
[0088] Compounds of the formula IA wherein Q is cyano, X and Y are
chlorine, V is hydrogen and the combination of B.sup.1, B.sup.2 and
R in each case corresponds to a row of Table A.
[0089] Table 14
[0090] Compounds of the formula IA wherein Q is cyano, X and V are
chlorine, Y is hydrogen and the combination of B.sup.1, B.sup.2 and
R in each case corresponds to a row of Table A.
[0091] Table 15
[0092] Compounds of the formula IA wherein Q is cyano, X and V are
fluorine, Y is hydrogen and the combination of B.sup.1, B.sup.2 and
R in each case corresponds to a row of Table A.
[0093] Table 16
[0094] Compounds of the formula IA wherein Q is cyano, X is
fluorine, Y are chlorine, V is hydrogen and the combination of
B.sup.1, B.sup.2 and R in each case corresponds to a row of Table
A.
[0095] Table 17
[0096] Compounds of the formula IA wherein Q is cyano, X is
chlorine, Y are fluorine, V is hydrogen and the combination of
B.sup.1, B.sup.2 and R in each case corresponds to a row of Table
A.
[0097] Table 18
[0098] Compounds of the formula IA wherein Q is cyano, X is
fluorine and Y and V are hydrogen and the combination of B.sup.1,
B.sup.2 and R in each case corresponds to a row of Table A.
[0099] Table 19
[0100] Compounds of the formula IA wherein Q is cyano, X is
chlorine and Y and V are hydrogen and the combination of B.sup.1,
B.sup.2 and R in each case corresponds to a row of Table A.
[0101] Table 20
[0102] Compounds of the formula IA wherein Q is cyano, X is bromine
and Y and V are hydrogen and the combination of B.sup.1, B.sup.2
and R in each case corresponds to a row of Table A.
[0103] Table 21
[0104] Compounds of the formula IA wherein Q is cyano, X, Y and V
are chlorine and the combination of B.sup.1, B.sup.2 and R in each
case corresponds to a row of Table A.
[0105] Table 22
[0106] Compounds of the formula IA wherein Q is cyano, X, Y and V
are fluorine and the combination of B.sup.1, B.sup.2 and R in each
case corresponds to a row of Table A.
TABLE-US-00001 TABLE A No. B.sup.1 B.sup.2 R IA-1 Cl Br H IA-2 Cl
Cl H IA-3 Cl CF.sub.3 H IA-4 Cl OCH.sub.3 H IA-5 Cl
OCH.sub.2CH.sub.3 H IA-6 Cl OCH.sub.2CF.sub.3 H IA-7 Cl OCF.sub.3 H
IA-8 Cl OCFCF.sub.2 H IA-9 Cl OCH.sub.2CN H IA-10 Cl OCH.sub.2CCH H
IA-11 Cl OCH.sub.2CH.sub.2OCH.sub.3 H IA-12 Cl
OCH.sub.2CH.sub.2OCH.sub.2CH.sub.3 H IA-13 Cl SCH.sub.3 H IA-14 Cl
SCH.sub.2CH.sub.3 H IA-15 Cl SCF.sub.3 H IA-16 Cl S(.dbd.O)CH.sub.3
H IA-17 Cl S(.dbd.O)CH.sub.2CH.sub.3 H IA-18 Cl S(.dbd.O)CF.sub.3 H
IA-19 Cl S(.dbd.O).sub.2CH.sub.3 H IA-20 Cl
S(.dbd.O).sub.2CH.sub.2CH.sub.3 H IA-21 Cl S(.dbd.O).sub.2CF.sub.3
H IA-22 Cl --O--S(.dbd.O).sub.2CH.sub.3 H IA-23 Cl
--O--S(.dbd.O).sub.2CH.sub.2CH.sub.3 H IA-24 Cl
--OCH.sub.2C(.dbd.O)OCH.sub.3 H IA-25 Cl CH.dbd.N--OCH.sub.3 H
IA-26 Cl C(CF.sub.3).dbd.N--OCH.sub.3 H IA-27 CH.sub.3 Br H IA-28
CH.sub.3 Cl H IA-29 CH.sub.3 CF.sub.3 H IA-30 CH.sub.3 OCH.sub.3 H
IA-31 CH.sub.3 OCH.sub.2CH.sub.3 H IA-32 CH.sub.3 OCH.sub.2CF.sub.3
H IA-33 CH.sub.3 OCF.sub.3 H IA-34 CH.sub.3 OCFCF.sub.2 H IA-35
CH.sub.3 OCH.sub.2CN H IA-36 CH.sub.3 OCH.sub.2CCH H IA-37 CH.sub.3
OCH.sub.2CH.sub.2OCH.sub.3 H IA-38 CH.sub.3
OCH.sub.2CH.sub.2OCH.sub.2CH.sub.3 H IA-39 CH.sub.3 SCH.sub.3 H
IA-40 CH.sub.3 SCH.sub.2CH.sub.3 H IA-41 CH.sub.3 SCF.sub.3 H IA-42
CH.sub.3 S(.dbd.O)CH.sub.3 H IA-43 CH.sub.3
S(.dbd.O)CH.sub.2CH.sub.3 H IA-44 CH.sub.3 S(.dbd.O)CF.sub.3 H
IA-45 CH.sub.3 S(.dbd.O).sub.2CH.sub.3 H IA-46 CH.sub.3
S(.dbd.O).sub.2CH.sub.2CH.sub.3 H IA-47 CH.sub.3
S(.dbd.O).sub.2CF.sub.3 H IA-48 CH.sub.3
--O--S(.dbd.O).sub.2CH.sub.3 H IA-49 CH.sub.3
--O--S(.dbd.O).sub.2CH.sub.2CH.sub.3 H IA-50 CH.sub.3
--OCH.sub.2C(.dbd.O)OCH.sub.3 H IA-51 CH.sub.3 CH.dbd.N--OCH.sub.3
H IA-52 CH.sub.3 C(CF.sub.3).dbd.N--OCH.sub.3 H IA-53 Cl Br
CH.sub.3 IA-54 Cl Cl CH.sub.3 IA-55 Cl CF.sub.3 CH.sub.3 IA-56 Cl
OCH.sub.3 CH.sub.3 IA-57 Cl OCH.sub.2CH.sub.3 CH.sub.3 IA-58 Cl
OCH.sub.2CF.sub.3 CH.sub.3 IA-59 Cl OCF.sub.3 CH.sub.3 IA-60 Cl
OCFCF.sub.2 CH.sub.3 IA-61 Cl OCH.sub.2CN CH.sub.3 IA-62 Cl
OCH.sub.2CCH CH.sub.3 IA-63 Cl OCH.sub.2CH.sub.2OCH.sub.3 CH.sub.3
IA-64 Cl OCH.sub.2CH.sub.2OCH.sub.2CH.sub.3 CH.sub.3 IA-65 Cl
SCH.sub.3 CH.sub.3 IA-66 Cl SCH.sub.2CH.sub.3 CH.sub.3 IA-67 Cl
SCF.sub.3 CH.sub.3 IA-68 Cl S(.dbd.O)CH.sub.3 CH.sub.3 IA-69 Cl
S(.dbd.O)CH.sub.2CH.sub.3 CH.sub.3 IA-70 Cl S(.dbd.O)CF.sub.3
CH.sub.3 IA-71 Cl S(.dbd.O).sub.2CH.sub.3 CH.sub.3 IA-72 Cl
S(.dbd.O).sub.2CH.sub.2CH.sub.3 CH.sub.3 IA-73 Cl
S(.dbd.O).sub.2CF.sub.3 CH.sub.3 IA-74 Cl
--O--S(.dbd.O).sub.2CH.sub.3 CH.sub.3 IA-75 Cl
--O--S(.dbd.O).sub.2CH.sub.2CH.sub.3 CH.sub.3 IA-76 Cl
--OCH.sub.2C(.dbd.O)OCH.sub.3 CH.sub.3 IA-77 Cl CH.dbd.N--OCH.sub.3
CH.sub.3 IA-78 Cl C(CF.sub.3).dbd.N--OCH.sub.3 CH.sub.3 IA-79
CH.sub.3 Br CH.sub.3 IA-80 CH.sub.3 Cl CH.sub.3 IA-81 CH.sub.3
CF.sub.3 CH.sub.3 IA-82 CH.sub.3 OCH.sub.3 CH.sub.3 IA-83 CH.sub.3
OCH.sub.2CH.sub.3 CH.sub.3 IA-84 CH.sub.3 OCH.sub.2CF.sub.3
CH.sub.3 IA-85 CH.sub.3 OCF.sub.3 CH.sub.3 IA-86 CH.sub.3
OCFCF.sub.2 CH.sub.3 IA-87 CH.sub.3 OCH.sub.2CN CH.sub.3 IA-88
CH.sub.3 OCH.sub.2CCH CH.sub.3 IA-89 CH.sub.3
OCH.sub.2CH.sub.2OCH.sub.3 CH.sub.3 IA-90 CH.sub.3
OCH.sub.2CH.sub.2OCH.sub.2CH.sub.3 CH.sub.3 IA-91 CH.sub.3
SCH.sub.3 CH.sub.3 IA-92 CH.sub.3 SCH.sub.2CH.sub.3 CH.sub.3 IA-93
CH.sub.3 SCF.sub.3 CH.sub.3 IA-94 CH.sub.3 S(.dbd.O)CH.sub.3
CH.sub.3 IA-95 CH.sub.3 S(.dbd.O)CH.sub.2CH.sub.3 CH.sub.3 IA-96
CH.sub.3 S(.dbd.O)CF.sub.3 CH.sub.3 IA-97 CH.sub.3
S(.dbd.O).sub.2CH.sub.3 CH.sub.3 IA-98 CH.sub.3
S(.dbd.O).sub.2CH.sub.2CH.sub.3 CH.sub.3 IA-99 CH.sub.3
S(.dbd.O).sub.2CF.sub.3 CH.sub.3 IA-100 CH.sub.3
--O--S(.dbd.O).sub.2CH.sub.3 CH.sub.3 IA-101 CH.sub.3
--O--S(.dbd.O).sub.2CH.sub.2CH.sub.3 CH.sub.3 IA-102 CH.sub.3
--OCH.sub.2C(.dbd.O)OCH.sub.3 CH.sub.3 IA-103 CH.sub.3
CH.dbd.N--OCH.sub.3 CH.sub.3 IA-104 CH.sub.3
C(CF.sub.3).dbd.N--OCH.sub.3 CH.sub.3 IA-105 Cl Br CH.sub.2CH.sub.3
IA-106 Cl Cl CH.sub.2CH.sub.3 IA-107 Cl CF.sub.3 CH.sub.2CH.sub.3
IA-108 Cl OCH.sub.3 CH.sub.2CH.sub.3 IA-109 Cl OCH.sub.2CH.sub.3
CH.sub.2CH.sub.3 IA-110 Cl OCH.sub.2CF.sub.3 CH.sub.2CH.sub.3
IA-111 Cl OCF.sub.3 CH.sub.2CH.sub.3 IA-112 Cl OCFCF.sub.2
CH.sub.2CH.sub.3 IA-113 Cl OCH.sub.2CN CH.sub.2CH.sub.3 IA-114 Cl
OCH.sub.2CCH CH.sub.2CH.sub.3 IA-115 Cl OCH.sub.2CH.sub.2OCH.sub.3
CH.sub.2CH.sub.3 IA-116 Cl OCH.sub.2CH.sub.2OCH.sub.2CH.sub.3
CH.sub.2CH.sub.3 IA-117 Cl SCH.sub.3 CH.sub.2CH.sub.3 IA-118 Cl
SCH.sub.2CH.sub.3 CH.sub.2CH.sub.3 IA-119 Cl SCF.sub.3
CH.sub.2CH.sub.3 IA-120 Cl S(.dbd.O)CH.sub.3 CH.sub.2CH.sub.3
IA-121 Cl S(.dbd.O)CH.sub.2CH.sub.3 CH.sub.2CH.sub.3 IA-122 Cl
S(.dbd.O)CF.sub.3 CH.sub.2CH.sub.3 IA-123 Cl
S(.dbd.O).sub.2CH.sub.3 CH.sub.2CH.sub.3 IA-124 Cl
S(.dbd.O).sub.2CH.sub.2CH.sub.3 CH.sub.2CH.sub.3 IA-125 Cl
S(.dbd.O).sub.2CF.sub.3 CH.sub.2CH.sub.3 IA-126 Cl
--O--S(.dbd.O).sub.2CH.sub.3 CH.sub.2CH.sub.3 IA-127 Cl
--O--S(.dbd.O).sub.2CH.sub.2CH.sub.3 CH.sub.2CH.sub.3 IA-128 Cl
--OCH.sub.2C(.dbd.O)OCH.sub.3 CH.sub.2CH.sub.3 IA-129 Cl
CH.dbd.N--OCH.sub.3 CH.sub.2CH.sub.3 IA-130 Cl
C(CF.sub.3).dbd.N--OCH.sub.3 CH.sub.2CH.sub.3 IA-131 CH.sub.3 Br
CH.sub.2CH.sub.3 IA-132 CH.sub.3 Cl CH.sub.2CH.sub.3 IA-133
CH.sub.3 CF.sub.3 CH.sub.2CH.sub.3 IA-134 CH.sub.3 OCH.sub.3
CH.sub.2CH.sub.3 IA-135 CH.sub.3 OCH.sub.2CH.sub.3 CH.sub.2CH.sub.3
IA-136 CH.sub.3 OCH.sub.2CF.sub.3 CH.sub.2CH.sub.3 IA-137 CH.sub.3
OCF.sub.3 CH.sub.2CH.sub.3 IA-138 CH.sub.3 OCFCF.sub.2
CH.sub.2CH.sub.3 IA-139 CH.sub.3 OCH.sub.2CN CH.sub.2CH.sub.3
IA-140 CH.sub.3 OCH.sub.2CCH CH.sub.2CH.sub.3 IA-141 CH.sub.3
OCH.sub.2CH.sub.2OCH.sub.3 CH.sub.2CH.sub.3 IA-142 CH.sub.3
OCH.sub.2CH.sub.2OCH.sub.2CH.sub.3 CH.sub.2CH.sub.3 IA-143 CH.sub.3
SCH.sub.3 CH.sub.2CH.sub.3 IA-144 CH.sub.3 SCH.sub.2CH.sub.3
CH.sub.2CH.sub.3 IA-145 CH.sub.3 SCF.sub.3 CH.sub.2CH.sub.3 IA-146
CH.sub.3 S(.dbd.O)CH.sub.3 CH.sub.2CH.sub.3 IA-147 CH.sub.3
S(.dbd.O)CH.sub.2CH.sub.3 CH.sub.2CH.sub.3 IA-148 CH.sub.3
S(.dbd.O)CF.sub.3 CH.sub.2CH.sub.3 IA-149 CH.sub.3
S(.dbd.O).sub.2CH.sub.3 CH.sub.2CH.sub.3 IA-150 CH.sub.3
S(.dbd.O).sub.2CH.sub.2CH.sub.3 CH.sub.2CH.sub.3 IA-151 CH.sub.3
S(.dbd.O).sub.2CF.sub.3 CH.sub.2CH.sub.3 IA-152 CH.sub.3
--O--S(.dbd.O).sub.2CH.sub.3 CH.sub.2CH.sub.3 IA-153 CH.sub.3
--O--S(.dbd.O).sub.2CH.sub.2CH.sub.3 CH.sub.2CH.sub.3 IA-154
CH.sub.3 --OCH.sub.2C(.dbd.O)OCH.sub.3 CH.sub.2CH.sub.3 IA-155
CH.sub.3 CH.dbd.N--OCH.sub.3 CH.sub.2CH.sub.3 IA-156 CH.sub.3
C(CF.sub.3).dbd.N--OCH.sub.3 CH.sub.2CH.sub.3 IA-157 Cl Br
CH(CH.sub.3).sub.2 IA-158 Cl Cl CH(CH.sub.3).sub.2 IA-159 Cl
CF.sub.3 CH(CH.sub.3).sub.2 IA-160 Cl OCH.sub.3 CH(CH.sub.3).sub.2
IA-161 Cl OCH.sub.2CH.sub.3 CH(CH.sub.3).sub.2 IA-162 Cl
OCH.sub.2CF.sub.3 CH(CH.sub.3).sub.2 IA-163 Cl OCF.sub.3
CH(CH.sub.3).sub.2 IA-164 Cl OCFCF.sub.2 CH(CH.sub.3).sub.2 IA-165
Cl OCH.sub.2CN CH(CH.sub.3).sub.2 IA-166 Cl OCH.sub.2CCH
CH(CH.sub.3).sub.2 IA-167 Cl OCH.sub.2CH.sub.2OCH.sub.3
CH(CH.sub.3).sub.2 IA-168 Cl OCH.sub.2CH.sub.2OCH.sub.2CH.sub.3
CH(CH.sub.3).sub.2 IA-169 Cl SCH.sub.3 CH(CH.sub.3).sub.2 IA-170 Cl
SCH.sub.2CH.sub.3 CH(CH.sub.3).sub.2 IA-171 Cl SCF.sub.3
CH(CH.sub.3).sub.2 IA-172 Cl S(.dbd.O)CH.sub.3 CH(CH.sub.3).sub.2
IA-173 Cl S(.dbd.O)CH.sub.2CH.sub.3 CH(CH.sub.3).sub.2 IA-174 Cl
S(.dbd.O)CF.sub.3 CH(CH.sub.3).sub.2 IA-175 Cl
S(.dbd.O).sub.2CH.sub.3 CH(CH.sub.3).sub.2 IA-176 Cl
S(.dbd.O).sub.2CH.sub.2CH.sub.3 CH(CH.sub.3).sub.2 IA-177 Cl
S(.dbd.O).sub.2CF.sub.3 CH(CH.sub.3).sub.2 IA-178 Cl
--O--S(.dbd.O).sub.2CH.sub.3 CH(CH.sub.3).sub.2 IA-179 Cl
--O--S(.dbd.O).sub.2CH.sub.2CH.sub.3 CH(CH.sub.3).sub.2 IA-180 Cl
--OCH.sub.2C(.dbd.O)OCH.sub.3 CH(CH.sub.3).sub.2 IA-181 Cl
CH.dbd.N--OCH.sub.3 CH(CH.sub.3).sub.2 IA-182 Cl
C(CF.sub.3).dbd.N--OCH.sub.3 CH(CH.sub.3).sub.2 IA-183 CH.sub.3 Br
CH(CH.sub.3).sub.2 IA-184 CH.sub.3 Cl CH(CH.sub.3).sub.2 IA-185
CH.sub.3 CF.sub.3 CH(CH.sub.3).sub.2 IA-186 CH.sub.3 OCH.sub.3
CH(CH.sub.3).sub.2 IA-187 CH.sub.3 OCH.sub.2CH.sub.3
CH(CH.sub.3).sub.2 IA-188 CH.sub.3 OCH.sub.2CF.sub.3
CH(CH.sub.3).sub.2 IA-189 CH.sub.3 OCF.sub.3 CH(CH.sub.3).sub.2
IA-190 CH.sub.3 OCFCF.sub.2 CH(CH.sub.3).sub.2 IA-191 CH.sub.3
OCH.sub.2CN CH(CH.sub.3).sub.2 IA-192 CH.sub.3 OCH.sub.2CCH
CH(CH.sub.3).sub.2 IA-193 CH.sub.3 OCH.sub.2CH.sub.2OCH.sub.3
CH(CH.sub.3).sub.2 IA-194 CH.sub.3
OCH.sub.2CH.sub.2OCH.sub.2CH.sub.3 CH(CH.sub.3).sub.2 IA-195
CH.sub.3 SCH.sub.3 CH(CH.sub.3).sub.2 IA-196 CH.sub.3
SCH.sub.2CH.sub.3 CH(CH.sub.3).sub.2 IA-197 CH.sub.3 SCF.sub.3
CH(CH.sub.3).sub.2 IA-198 CH.sub.3 S(.dbd.O)CH.sub.3
CH(CH.sub.3).sub.2 IA-199 CH.sub.3 S(.dbd.O)CH.sub.2CH.sub.3
CH(CH.sub.3).sub.2 IA-200 CH.sub.3 S(.dbd.O)CF.sub.3
CH(CH.sub.3).sub.2 IA-201 CH.sub.3 S(.dbd.O).sub.2CH.sub.3
CH(CH.sub.3).sub.2 IA-202 CH.sub.3 S(.dbd.O).sub.2CH.sub.2CH.sub.3
CH(CH.sub.3).sub.2 IA-203 CH.sub.3 S(.dbd.O).sub.2CF.sub.3
CH(CH.sub.3).sub.2 IA-204 CH.sub.3 --O--S(.dbd.O).sub.2CH.sub.3
CH(CH.sub.3).sub.2 IA-205 CH.sub.3
--O--S(.dbd.O).sub.2CH.sub.2CH.sub.3 CH(CH.sub.3).sub.2 IA-206
CH.sub.3 --OCH.sub.2C(.dbd.O)OCH.sub.3 CH(CH.sub.3).sub.2 IA-207
CH.sub.3 CH.dbd.N--OCH.sub.3 CH(CH.sub.3).sub.2 IA-208 CH.sub.3
C(CF.sub.3).dbd.N--OCH.sub.3 CH(CH.sub.3).sub.2 IA-209 Cl Br
C(CH.sub.3).sub.3 IA-210 Cl Cl C(CH.sub.3).sub.3 IA-211 Cl CF.sub.3
C(CH.sub.3).sub.3 IA-212 Cl OCH.sub.3 C(CH.sub.3).sub.3 IA-213 Cl
OCH.sub.2CH.sub.3 C(CH.sub.3).sub.3 IA-214 Cl OCH.sub.2CF.sub.3
C(CH.sub.3).sub.3 IA-215 Cl OCF.sub.3 C(CH.sub.3).sub.3 IA-216 Cl
OCFCF.sub.2 C(CH.sub.3).sub.3 IA-217 Cl OCH.sub.2CN
C(CH.sub.3).sub.3 IA-218 Cl OCH.sub.2CCH C(CH.sub.3).sub.3 IA-219
Cl OCH.sub.2CH.sub.2OCH.sub.3 C(CH.sub.3).sub.3 IA-220 Cl
OCH.sub.2CH.sub.2OCH.sub.2CH.sub.3 C(CH.sub.3).sub.3 IA-221 Cl
SCH.sub.3 C(CH.sub.3).sub.3 IA-222 Cl SCH.sub.2CH.sub.3
C(CH.sub.3).sub.3 IA-223 Cl SCF.sub.3 C(CH.sub.3).sub.3 IA-224 Cl
S(.dbd.O)CH.sub.3 C(CH.sub.3).sub.3 IA-225 Cl
S(.dbd.O)CH.sub.2CH.sub.3 C(CH.sub.3).sub.3 IA-226 Cl
S(.dbd.O)CF.sub.3 C(CH.sub.3).sub.3 IA-227 Cl
S(.dbd.O).sub.2CH.sub.3 C(CH.sub.3).sub.3 IA-228 Cl
S(.dbd.O).sub.2CH.sub.2CH.sub.3 C(CH.sub.3).sub.3 IA-229 Cl
S(.dbd.O).sub.2CF.sub.3 C(CH.sub.3).sub.3 IA-230 Cl
--O--S(.dbd.O).sub.2CH.sub.3 C(CH.sub.3).sub.3 IA-231 Cl
--O--S(.dbd.O).sub.2CH.sub.2CH.sub.3 C(CH.sub.3).sub.3 IA-232 Cl
--OCH.sub.2C(.dbd.O)OCH.sub.3 C(CH.sub.3).sub.3 IA-233 Cl
CH.dbd.N--OCH.sub.3 C(CH.sub.3).sub.3 IA-234 Cl
C(CF.sub.3).dbd.N--OCH.sub.3 C(CH.sub.3).sub.3 IA-235 CH.sub.3 Br
C(CH.sub.3).sub.3 IA-236 CH.sub.3 Cl C(CH.sub.3).sub.3 IA-237
CH.sub.3 CF.sub.3 C(CH.sub.3).sub.3 IA-238 CH.sub.3 OCH.sub.3
C(CH.sub.3).sub.3 IA-239 CH.sub.3 OCH.sub.2CH.sub.3
C(CH.sub.3).sub.3 IA-240 CH.sub.3 OCH.sub.2CF.sub.3
C(CH.sub.3).sub.3 IA-241 CH.sub.3 OCF.sub.3 C(CH.sub.3).sub.3
IA-242 CH.sub.3 OCFCF.sub.2 C(CH.sub.3).sub.3 IA-243 CH.sub.3
OCH.sub.2CN C(CH.sub.3).sub.3 IA-244 CH.sub.3 OCH.sub.2CCH
C(CH.sub.3).sub.3 IA-245 CH.sub.3 OCH.sub.2CH.sub.2OCH.sub.3
C(CH.sub.3).sub.3 IA-246 CH.sub.3
OCH.sub.2CH.sub.2OCH.sub.2CH.sub.3 C(CH.sub.3).sub.3
IA-247 CH.sub.3 SCH.sub.3 C(CH.sub.3).sub.3 IA-248 CH.sub.3
SCH.sub.2CH.sub.3 C(CH.sub.3).sub.3 IA-249 CH.sub.3 SCF.sub.3
C(CH.sub.3).sub.3 IA-250 CH.sub.3 S(.dbd.O)CH.sub.3
C(CH.sub.3).sub.3 IA-251 CH.sub.3 S(.dbd.O)CH.sub.2CH.sub.3
C(CH.sub.3).sub.3 IA-252 CH.sub.3 S(.dbd.O)CF.sub.3
C(CH.sub.3).sub.3 IA-253 CH.sub.3 S(.dbd.O).sub.2CH.sub.3
C(CH.sub.3).sub.3 IA-254 CH.sub.3 S(.dbd.O).sub.2CH.sub.2CH.sub.3
C(CH.sub.3).sub.3 IA-255 CH.sub.3 S(.dbd.O).sub.2CF.sub.3
C(CH.sub.3).sub.3 IA-256 CH.sub.3 --O--S(.dbd.O).sub.2CH.sub.3
C(CH.sub.3).sub.3 IA-257 CH.sub.3
--O--S(.dbd.O).sub.2CH.sub.2CH.sub.3 C(CH.sub.3).sub.3 IA-258
CH.sub.3 --OCH.sub.2C(.dbd.O)OCH.sub.3 C(CH.sub.3).sub.3 IA-259
CH.sub.3 CH.dbd.N--OCH.sub.3 C(CH.sub.3).sub.3 IA-260 CH.sub.3
C(CF.sub.3).dbd.N--OCH.sub.3 C(CH.sub.3).sub.3 IA-261 Cl Br
CH.sub.2CHCH.sub.2 IA-262 Cl Cl CH.sub.2CHCH.sub.2 IA-263 Cl
CF.sub.3 CH.sub.2CHCH.sub.2 IA-264 Cl OCH.sub.3 CH.sub.2CHCH.sub.2
IA-265 Cl OCH.sub.2CH.sub.3 CH.sub.2CHCH.sub.2 IA-266 Cl
OCH.sub.2CF.sub.3 CH.sub.2CHCH.sub.2 IA-267 Cl OCF.sub.3
CH.sub.2CHCH.sub.2 IA-268 Cl OCFCF.sub.2 CH.sub.2CHCH.sub.2 IA-269
Cl OCH.sub.2CN CH.sub.2CHCH.sub.2 IA-270 Cl OCH.sub.2CCH
CH.sub.2CHCH.sub.2 IA-271 Cl OCH.sub.2CH.sub.2OCH.sub.3
CH.sub.2CHCH.sub.2 IA-272 Cl OCH.sub.2CH.sub.2OCH.sub.2CH.sub.3
CH.sub.2CHCH.sub.2 IA-273 Cl SCH.sub.3 CH.sub.2CHCH.sub.2 IA-274 Cl
SCH.sub.2CH.sub.3 CH.sub.2CHCH.sub.2 IA-275 Cl SCF.sub.3
CH.sub.2CHCH.sub.2 IA-276 Cl S(.dbd.O)CH.sub.3 CH.sub.2CHCH.sub.2
IA-277 Cl S(.dbd.O)CH.sub.2CH.sub.3 CH.sub.2CHCH.sub.2 IA-278 Cl
S(.dbd.O)CF.sub.3 CH.sub.2CHCH.sub.2 IA-279 Cl
S(.dbd.O).sub.2CH.sub.3 CH.sub.2CHCH.sub.2 IA-280 Cl
S(.dbd.O).sub.2CH.sub.2CH.sub.3 CH.sub.2CHCH.sub.2 IA-281 Cl
S(.dbd.O).sub.2CF.sub.3 CH.sub.2CHCH.sub.2 IA-282 Cl
--O--S(.dbd.O).sub.2CH.sub.3 CH.sub.2CHCH.sub.2 IA-283 Cl
--O--S(.dbd.0).sub.2CH.sub.2CH.sub.3 CH.sub.2CHCH.sub.2 IA-284 Cl
--OCH.sub.2C(.dbd.O)OCH.sub.3 CH.sub.2CHCH.sub.2 IA-285 Cl
CH.dbd.N--OCH.sub.3 CH.sub.2CHCH.sub.2 IA-286 Cl
C(CF.sub.3).dbd.N--OCH.sub.3 CH.sub.2CHCH.sub.2 IA-287 CH.sub.3 Br
CH.sub.2CHCH.sub.2 IA-288 CH.sub.3 Cl CH.sub.2CHCH.sub.2 IA-289
CH.sub.3 CF.sub.3 CH.sub.2CHCH.sub.2 IA-290 CH.sub.3 OCH.sub.3
CH.sub.2CHCH.sub.2 IA-291 CH.sub.3 OCH.sub.2CH.sub.3
CH.sub.2CHCH.sub.2 IA-292 CH.sub.3 OCH.sub.2CF.sub.3
CH.sub.2CHCH.sub.2 IA-293 CH.sub.3 OCF.sub.3 CH.sub.2CHCH.sub.2
IA-294 CH.sub.3 OCFCF.sub.2 CH.sub.2CHCH.sub.2 IA-295 CH.sub.3
OCH.sub.2CN CH.sub.2CHCH.sub.2 IA-296 CH.sub.3 OCH.sub.2CCH
CH.sub.2CHCH.sub.2 IA-297 CH.sub.3 OCH.sub.2CH.sub.2OCH.sub.3
CH.sub.2CHCH.sub.2 IA-298 CH.sub.3
OCH.sub.2CH.sub.2OCH.sub.2CH.sub.3 CH.sub.2CHCH.sub.2 IA-299
CH.sub.3 SCH.sub.3 CH.sub.2CHCH.sub.2 IA-300 CH.sub.3
SCH.sub.2CH.sub.3 CH.sub.2CHCH.sub.2 IA-301 CH.sub.3 SCF.sub.3
CH.sub.2CHCH.sub.2 IA-302 CH.sub.3 S(.dbd.O)CH.sub.3
CH.sub.2CHCH.sub.2 IA-303 CH.sub.3 S(.dbd.O)CH.sub.2CH.sub.3
CH.sub.2CHCH.sub.2 IA-304 CH.sub.3 S(.dbd.O)CF.sub.3
CH.sub.2CHCH.sub.2 IA-305 CH.sub.3 S(.dbd.O).sub.2CH.sub.3
CH.sub.2CHCH.sub.2 IA-306 CH.sub.3 S(.dbd.O).sub.2CH.sub.2CH.sub.3
CH.sub.2CHCH.sub.2 IA-307 CH.sub.3 S(.dbd.O).sub.2CF.sub.3
CH.sub.2CHCH.sub.2 IA-308 CH.sub.3 --O--S(.dbd.O).sub.2CH.sub.3
CH.sub.2CHCH.sub.2 IA-309 CH.sub.3
--O--S(.dbd.O).sub.2CH.sub.2CH.sub.3 CH.sub.2CHCH.sub.2 IA-310
CH.sub.3 --OCH.sub.2C(.dbd.O)OCH.sub.3 CH.sub.2CHCH.sub.2 IA-311
CH.sub.3 CH.dbd.N--OCH.sub.3 CH.sub.2CHCH.sub.2 IA-312 CH.sub.3
C(CF.sub.3).dbd.N--OCH.sub.3 CH.sub.2CHCH.sub.2 IA-313 Cl Br
CH.sub.2CCH IA-314 Cl Cl CH.sub.2CCH IA-315 Cl CF.sub.3 CH.sub.2CCH
IA-316 Cl OCH.sub.3 CH.sub.2CCH IA-317 Cl OCH.sub.2CH.sub.3
CH.sub.2CCH IA-318 Cl OCH.sub.2CF.sub.3 CH.sub.2CCH IA-319 Cl
OCF.sub.3 CH.sub.2CCH IA-320 Cl OCFCF.sub.2 CH.sub.2CCH IA-321 Cl
OCH.sub.2CN CH.sub.2CCH IA-322 Cl OCH.sub.2CCH CH.sub.2CCH IA-323
Cl OCH.sub.2CH.sub.2OCH.sub.3 CH.sub.2CCH IA-324 Cl
OCH.sub.2CH.sub.2OCH.sub.2CH.sub.3 CH.sub.2CCH IA-325 Cl SCH.sub.3
CH.sub.2CCH IA-326 Cl SCH.sub.2CH.sub.3 CH.sub.2CCH IA-327 Cl
SCF.sub.3 CH.sub.2CCH IA-328 Cl S(.dbd.O)CH.sub.3 CH.sub.2CCH
IA-329 Cl S(.dbd.O)CH.sub.2CH.sub.3 CH.sub.2CCH IA-330 Cl
S(.dbd.O)CF.sub.3 CH.sub.2CCH IA-331 Cl S(.dbd.O).sub.2CH.sub.3
CH.sub.2CCH IA-332 Cl S(.dbd.O).sub.2CH.sub.2CH.sub.3 CH.sub.2CCH
IA-333 Cl S(.dbd.O).sub.2CF.sub.3 CH.sub.2CCH IA-334 Cl
--O--S(.dbd.O).sub.2CH.sub.3 CH.sub.2CCH IA-335 Cl
--O--S(.dbd.O).sub.2CH.sub.2CH.sub.3 CH.sub.2CCH IA-336 Cl
--OCH.sub.2C(.dbd.O)OCH.sub.3 CH.sub.2CCH IA-337 Cl
CH.dbd.N--OCH.sub.3 CH.sub.2CCH IA-338 Cl
C(CF.sub.3).dbd.N--OCH.sub.3 CH.sub.2CCH IA-339 CH.sub.3 Br
CH.sub.2CCH IA-340 CH.sub.3 Cl CH.sub.2CCH IA-341 CH.sub.3 CF.sub.3
CH.sub.2CCH IA-342 CH.sub.3 OCH.sub.3 CH.sub.2CCH IA-343 CH.sub.3
OCH.sub.2CH.sub.3 CH.sub.2CCH IA-344 CH.sub.3 OCH.sub.2CF.sub.3
CH.sub.2CCH IA-345 CH.sub.3 OCF.sub.3 CH.sub.2CCH IA-346 CH.sub.3
OCFCF.sub.2 CH.sub.2CCH IA-347 CH.sub.3 OCH.sub.2CN CH.sub.2CCH
IA-348 CH.sub.3 OCH.sub.2CCH CH.sub.2CCH IA-349 CH.sub.3
OCH.sub.2CH.sub.2OCH.sub.3 CH.sub.2CCH IA-350 CH.sub.3
OCH.sub.2CH.sub.2OCH.sub.2CH.sub.3 CH.sub.2CCH IA-351 CH.sub.3
SCH.sub.3 CH.sub.2CCH IA-352 CH.sub.3 SCH.sub.2CH.sub.3 CH.sub.2CCH
IA-353 CH.sub.3 SCF.sub.3 CH.sub.2CCH IA-354 CH.sub.3
S(.dbd.O)CH.sub.3 CH.sub.2CCH IA-355 CH.sub.3
S(.dbd.O)CH.sub.2CH.sub.3 CH.sub.2CCH IA-356 CH.sub.3
S(.dbd.O)CF.sub.3 CH.sub.2CCH IA-357 CH.sub.3
S(.dbd.O).sub.2CH.sub.3 CH.sub.2CCH IA-358 CH.sub.3
S(.dbd.O).sub.2CH.sub.2CH.sub.3 CH.sub.2CCH IA-359 CH.sub.3
S(.dbd.O).sub.2CF.sub.3 CH.sub.2CCH IA-360 CH.sub.3
--O--S(.dbd.O).sub.2CH.sub.3 CH.sub.2CCH IA-361 CH.sub.3
--O--S(.dbd.O).sub.2CH.sub.2CH.sub.3 CH.sub.2CCH IA-362 CH.sub.3
CH.dbd.N--OCH.sub.3 CH.sub.2CCH IA-363 CH.sub.3
C(CF.sub.3).dbd.N--OCH.sub.3 CH.sub.2CCH IA-364 Cl Br CH.sub.2CCH
IA-365 Cl Cl CH.sub.2CCH IA-366 Cl CF.sub.3 CH.sub.2CCH IA-367 Cl
OCH.sub.3 CH.sub.2CCH IA-368 Cl OCH.sub.2CH.sub.3 CH.sub.2CCH
IA-369 Cl OCH.sub.2CF.sub.3 CH.sub.2CCH IA-370 Cl OCF.sub.3
CH.sub.2CCH IA-371 Cl OCFCF.sub.2 CH.sub.2CCH IA-372 Cl OCH.sub.2CN
CH.sub.2CCH IA-373 Cl OCH.sub.2CCH CH.sub.2CCH IA-374 Cl
OCH.sub.2CH.sub.2OCH.sub.3 CH.sub.2CCH IA-375 Cl
OCH.sub.2CH.sub.2OCH.sub.2CH.sub.3 CH.sub.2CCH IA-376 Cl SCH.sub.3
CH.sub.2CCH IA-377 Cl SCH.sub.2CH.sub.3 CH.sub.2CCH IA-378 Cl
SCF.sub.3 CH.sub.2CCH IA-379 Cl S(.dbd.O)CH.sub.3 CH.sub.2CCH
IA-380 Cl S(.dbd.O)CH.sub.2CH.sub.3 CH.sub.2CCH IA-381 Cl
S(.dbd.O)CF.sub.3 CH.sub.2CCH IA-382 Cl S(.dbd.O).sub.2CH.sub.3
CH.sub.2CCH IA-383 Cl S(.dbd.O).sub.2CH.sub.2CH.sub.3 CH.sub.2CCH
IA-384 Cl S(.dbd.O).sub.2CF.sub.3 CH.sub.2CCH IA-385 Cl
--O--S(.dbd.O).sub.2CH.sub.3 CH.sub.2CCH IA-386 Cl
--O--S(.dbd.O).sub.2CH.sub.2CH.sub.3 CH.sub.2CCH IA-387 Cl
--OCH.sub.2C(.dbd.O)OCH.sub.3 CH.sub.2CCH IA-388 Cl
CH.dbd.N--OCH.sub.3 CH.sub.2CCH IA-389 Cl
C(CF.sub.3).dbd.N--OCH.sub.3 CH.sub.2CCH IA-390 CH.sub.3 Br
CH.sub.2CCH IA-391 CH.sub.3 Cl CH.sub.2CCH IA-392 CH.sub.3 CF.sub.3
CH.sub.2CCH IA-393 CH.sub.3 OCH.sub.3 CH.sub.2CCH IA-394 CH.sub.3
OCH.sub.2CH.sub.3 CH.sub.2CCH IA-395 CH.sub.3 OCH.sub.2CF.sub.3
CH.sub.2CCH IA-396 CH.sub.3 OCF.sub.3 CH.sub.2CCH IA-397 CH.sub.3
OCFCF.sub.2 CH.sub.2CCH IA-398 CH.sub.3 OCH.sub.2CN CH.sub.2CCH
IA-399 CH.sub.3 OCH.sub.2CCH CH.sub.2CCH IA-400 CH.sub.3
OCH.sub.2CH.sub.2OCH.sub.3 CH.sub.2CCH IA-401 CH.sub.3
OCH.sub.2CH.sub.2OCH.sub.2CH.sub.3 CH.sub.2CCH IA-402 CH.sub.3
SCH.sub.3 CH.sub.2CCH IA-403 CH.sub.3 SCH.sub.2CH.sub.3 CH.sub.2CCH
IA-404 CH.sub.3 SCF.sub.3 CH.sub.2CCH IA-405 CH.sub.3
S(.dbd.O)CH.sub.3 CH.sub.2CCH IA-406 CH.sub.3
S(.dbd.O)CH.sub.2CH.sub.3 CH.sub.2CCH IA-407 CH.sub.3
S(.dbd.O)CF.sub.3 CH.sub.2CCH IA-408 CH.sub.3
S(.dbd.O).sub.2CH.sub.3 CH.sub.2CCH IA-409 CH.sub.3
S(.dbd.O).sub.2CH.sub.2CH.sub.3 CH.sub.2CCH IA-410 CH.sub.3
S(.dbd.O).sub.2CF.sub.3 CH.sub.2CCH IA-411 CH.sub.3
--O--S(.dbd.O).sub.2CH.sub.3 CH.sub.2CCH IA-412 CH.sub.3
--O--S(.dbd.O).sub.2CH.sub.2CH.sub.3 CH.sub.2CCH IA-413 CH.sub.3
--OCH.sub.2C(.dbd.O)OCH.sub.3 CH.sub.2CCH IA-414 CH.sub.3
--OCH.sub.2C(.dbd.O)OCH.sub.3 CH.sub.2CCH IA-415 CH.sub.3
CH.dbd.N--OCH.sub.3 CH.sub.2CCH IA-416 CH.sub.3
C(CF.sub.3).dbd.N--OCH.sub.3 CH.sub.2CCH IA-417 Cl Br CH.sub.2CN
IA-418 Cl Cl CH.sub.2CN IA-419 Cl CF.sub.3 CH.sub.2CN IA-420 Cl
OCH.sub.3 CH.sub.2CN IA-421 Cl OCH.sub.2CH.sub.3 CH.sub.2CN IA-422
Cl OCH.sub.2CF.sub.3 CH.sub.2CN IA-423 Cl OCF.sub.3 CH.sub.2CN
IA-424 Cl OCFCF.sub.2 CH.sub.2CN IA-425 Cl OCH.sub.2CN CH.sub.2CN
IA-426 Cl OCH.sub.2CCH CH.sub.2CN IA-427 Cl
OCH.sub.2CH.sub.2OCH.sub.3 CH.sub.2CN IA-428 Cl
OCH.sub.2CH.sub.2OCH.sub.2CH.sub.3 CH.sub.2CN IA-429 Cl SCH.sub.3
CH.sub.2CN IA-430 Cl SCH.sub.2CH.sub.3 CH.sub.2CN IA-431 Cl
SCF.sub.3 CH.sub.2CN IA-432 Cl S(.dbd.O)CH.sub.3 CH.sub.2CN IA-433
Cl S(.dbd.O)CH.sub.2CH.sub.3 CH.sub.2CN IA-434 Cl S(.dbd.O)CF.sub.3
CH.sub.2CN IA-435 Cl S(.dbd.O).sub.2CH.sub.3 CH.sub.2CN IA-436 Cl
S(.dbd.O).sub.2CH.sub.2CH.sub.3 CH.sub.2CN IA-437 Cl
S(.dbd.O).sub.2CF.sub.3 CH.sub.2CN IA-438 Cl
--O--S(.dbd.O).sub.2CH.sub.3 CH.sub.2CN IA-439 Cl
--O--S(.dbd.O).sub.2CH.sub.2CH.sub.3 CH.sub.2CN IA-440 Cl
--OCH.sub.2C(.dbd.O)OCH.sub.3 CH.sub.2CN IA-441 Cl
CH.dbd.N--OCH.sub.3 CH.sub.2CN IA-442 Cl
C(CF.sub.3).dbd.N--OCH.sub.3 CH.sub.2CN IA-443 CH.sub.3 Br
CH.sub.2CN IA-444 CH.sub.3 Cl CH.sub.2CN IA-445 CH.sub.3 CF.sub.3
CH.sub.2CN IA-446 CH.sub.3 OCH.sub.3 CH.sub.2CN IA-447 CH.sub.3
OCH.sub.2CH.sub.3 CH.sub.2CN IA-448 CH.sub.3 OCH.sub.2CF.sub.3
CH.sub.2CN IA-449 CH.sub.3 OCF.sub.3 CH.sub.2CN IA-450 CH.sub.3
OCFCF.sub.2 CH.sub.2CN IA-451 CH.sub.3 OCH.sub.2CN CH.sub.2CN
IA-452 CH.sub.3 OCH.sub.2CCH CH.sub.2CN IA-453 CH.sub.3
OCH.sub.2CH.sub.2OCH.sub.3 CH.sub.2CN IA-454 CH.sub.3
OCH.sub.2CH.sub.2OCH.sub.2CH.sub.3 CH.sub.2CN IA-455 CH.sub.3
SCH.sub.3 CH.sub.2CN IA-456 CH.sub.3 SCH.sub.2CH.sub.3 CH.sub.2CN
IA-457 CH.sub.3 SCF.sub.3 CH.sub.2CN IA-458 CH.sub.3
S(.dbd.O)CH.sub.3 CH.sub.2CN IA-459 CH.sub.3
S(.dbd.O)CH.sub.2CH.sub.3 CH.sub.2CN IA-460 CH.sub.3
S(.dbd.O)CF.sub.3 CH.sub.2CN IA-461 CH.sub.3
S(.dbd.O).sub.2CH.sub.3 CH.sub.2CN IA-462 CH.sub.3
S(.dbd.O).sub.2CH.sub.2CH.sub.3 CH.sub.2CN IA-463 CH.sub.3
S(.dbd.O).sub.2CF.sub.3 CH.sub.2CN IA-464 CH.sub.3
--O--S(.dbd.O).sub.2CH.sub.3 CH.sub.2CN IA-465 CH.sub.3
--O--S(.dbd.O).sub.2CH.sub.2CH.sub.3 CH.sub.2CN IA-466 CH.sub.3
--OCH.sub.2C(.dbd.O)OCH.sub.3 CH.sub.2CN IA-467 CH.sub.3
CH.dbd.N--OCH.sub.3 CH.sub.2CN IA-468 CH.sub.3
C(CF.sub.3).dbd.N--OCH.sub.3 CH.sub.2CN IA-469 Cl Br
CH.sub.2C(.dbd.O)OCH.sub.3 IA-470 Cl Cl CH.sub.2C(.dbd.O)OCH.sub.3
IA-471 Cl CF.sub.3 CH.sub.2C(.dbd.O)OCH.sub.3 IA-472 Cl OCH.sub.3
CH.sub.2C(.dbd.O)OCH.sub.3 IA-473 Cl OCH.sub.2CH.sub.3
CH.sub.2C(.dbd.O)OCH.sub.3 IA-474 Cl OCH.sub.2CF.sub.3
CH.sub.2C(.dbd.O)OCH.sub.3 IA-475 Cl OCF.sub.3
CH.sub.2C(.dbd.O)OCH.sub.3 IA-476 Cl OCFCF.sub.2
CH.sub.2C(.dbd.O)OCH.sub.3 IA-477 Cl OCH.sub.2CN
CH.sub.2C(.dbd.O)OCH.sub.3 IA-478 Cl OCH.sub.2CCH
CH.sub.2C(.dbd.O)OCH.sub.3 IA-479 Cl OCH.sub.2CH.sub.2OCH.sub.3
CH.sub.2C(.dbd.O)OCH.sub.3 IA-480 Cl
OCH.sub.2CH.sub.2OCH.sub.2CH.sub.3 CH.sub.2C(.dbd.O)OCH.sub.3
IA-481 Cl SCH.sub.3 CH.sub.2C(.dbd.O)OCH.sub.3 IA-482 Cl
SCH.sub.2CH.sub.3 CH.sub.2C(.dbd.O)OCH.sub.3 IA-483 Cl SCF.sub.3
CH.sub.2C(.dbd.O)OCH.sub.3 IA-484 Cl S(.dbd.O)CH.sub.3
CH.sub.2C(.dbd.O)OCH.sub.3 IA-485 Cl S(.dbd.O)CH.sub.2CH.sub.3
CH.sub.2C(.dbd.O)OCH.sub.3 IA-486 Cl S(.dbd.O)CF.sub.3
CH.sub.2C(.dbd.O)OCH.sub.3 IA-487 Cl S(.dbd.O).sub.2CH.sub.3
CH.sub.2C(.dbd.O)OCH.sub.3 IA-488 Cl
S(.dbd.O).sub.2CH.sub.2CH.sub.3 CH.sub.2C(.dbd.O)OCH.sub.3 IA-489
Cl S(.dbd.O).sub.2CF.sub.3 CH.sub.2C(.dbd.O)OCH.sub.3 IA-490 Cl
--O--S(.dbd.O).sub.2CH.sub.3 CH.sub.2C(.dbd.O)OCH.sub.3 IA-491 Cl
--O--S(.dbd.O).sub.2CH.sub.2CH.sub.3 CH.sub.2C(.dbd.O)OCH.sub.3
IA-492 Cl --OCH.sub.2C(.dbd.O)OCH.sub.3 CH.sub.2C(.dbd.O)OCH.sub.3
IA-493 Cl CH.dbd.N--OCH.sub.3 CH.sub.2C(.dbd.O)OCH.sub.3 IA-494 Cl
C(CF.sub.3).dbd.N--OCH.sub.3 CH.sub.2C(.dbd.O)OCH.sub.3 IA-495
CH.sub.3 Br CH.sub.2C(.dbd.O)OCH.sub.3 IA-496 CH.sub.3 Cl
CH.sub.2C(.dbd.O)OCH.sub.3
IA-497 CH.sub.3 CF.sub.3 CH.sub.2C(.dbd.O)OCH.sub.3 IA-498 CH.sub.3
OCH.sub.3 CH.sub.2C(.dbd.O)OCH.sub.3 IA-499 CH.sub.3
OCH.sub.2CH.sub.3 CH.sub.2C(.dbd.O)OCH.sub.3 IA-500 CH.sub.3
OCH.sub.2CF.sub.3 CH.sub.2C(.dbd.O)OCH.sub.3 IA-501 CH.sub.3
OCF.sub.3 CH.sub.2C(.dbd.O)OCH.sub.3 IA-502 CH.sub.3 OCFCF.sub.2
CH.sub.2C(.dbd.O)OCH.sub.3 IA-503 CH.sub.3 OCH.sub.2CN
CH.sub.2C(.dbd.O)OCH.sub.3 IA-504 CH.sub.3 OCH.sub.2CCH
CH.sub.2C(.dbd.O)OCH.sub.3 IA-505 CH.sub.3
OCH.sub.2CH.sub.2OCH.sub.3 CH.sub.2C(.dbd.O)OCH.sub.3 IA-506
CH.sub.3 OCH.sub.2CH.sub.2OCH.sub.2CH.sub.3
CH.sub.2C(.dbd.O)OCH.sub.3 IA-507 CH.sub.3 SCH.sub.3
CH.sub.2C(.dbd.O)OCH.sub.3 IA-508 CH.sub.3 SCH.sub.2CH.sub.3
CH.sub.2C(.dbd.O)OCH.sub.3 IA-509 CH.sub.3 SCF.sub.3
CH.sub.2C(.dbd.O)OCH.sub.3 IA-510 CH.sub.3 S(.dbd.O)CH.sub.3
CH.sub.2C(.dbd.O)OCH.sub.3 IA-511 CH.sub.3
S(.dbd.O)CH.sub.2CH.sub.3 CH.sub.2C(.dbd.O)OCH.sub.3 IA-512
CH.sub.3 S(.dbd.O)CF.sub.3 CH.sub.2C(.dbd.O)OCH.sub.3 IA-513
CH.sub.3 S(.dbd.O).sub.2CH.sub.3 CH.sub.2C(.dbd.O)OCH.sub.3 IA-514
CH.sub.3 S(.dbd.O).sub.2CH.sub.2CH.sub.3 CH.sub.2C(.dbd.O)OCH.sub.3
IA-515 CH.sub.3 S(.dbd.O).sub.2CF.sub.3 CH.sub.2C(.dbd.O)OCH.sub.3
IA-516 CH.sub.3 --O--S(.dbd.O).sub.2CH.sub.3
CH.sub.2C(.dbd.O)OCH.sub.3 IA-517 CH.sub.3
--O--S(.dbd.O).sub.2CH.sub.2CH.sub.3 CH.sub.2C(.dbd.O)OCH.sub.3
IA-518 CH.sub.3 --OCH.sub.2C(.dbd.O)OCH.sub.3
CH.sub.2C(.dbd.O)OCH.sub.3 IA-519 CH.sub.3 CH.dbd.N--OCH.sub.3
CH.sub.2C(.dbd.O)OCH.sub.3 IA-520 CH.sub.3
C(CF.sub.3).dbd.N--OCH.sub.3 CH.sub.2C(.dbd.O)OCH.sub.3
[0107] With regard to their use in the pesticidal mixtures of the
present invention, the compounds II of group A.3 as defined above,
especially beta-cyfluthrin, alpha-cypermethrin, deltamethrin,
fenvalerate and lambda-cyhalothrin, are especially preferred.
[0108] Especially preferred are pesticidal mixtures containing
alpha-cypermethrin as compound II.
[0109] With regard to their use in the pesticidal mixtures of the
present invention, the compounds II of group A.4 as defined above,
especially flufenoxuron, etoxazole, tebufenozide, pyriproxyfen,
fenoxycarb, spirodiclofen, spiromesifen and spirotetramat are
especially preferred.
[0110] Especially preferred are pesticidal mixtures containing
spirodiclofen, spiromesifen and spirotetramat as compound(s)
II.
[0111] With regard to their use in the pesticidal mixtures of the
present invention, the compounds II of group A.5 as defined above,
are especially preferred.
[0112] Especially preferred are pesticidal mixtures containing
clothianidine as compound II.
[0113] Especially preferred are pesticidal mixtures containing
dinetofuran as compound II.
[0114] Especially preferred are pesticidal mixtures containing
imidacloprid as compound II.
[0115] Especially preferred are pesticidal mixtures containing
thiamethoxam as compound II.
[0116] Especially preferred are pesticidal mixtures containing
nitenpyram as compound II.
[0117] Especially preferred are pesticidal mixtures containing
acetamiprid as compound II.
[0118] Especially preferred are pesticidal mixtures containing
thiacloprid as compound II.
[0119] With regard to their use in the pesticidal mixtures of the
present invention, the compounds II of group A.6 as defined above,
especially endosulfan and fipronil, most preferably fipronil, are
especially preferred.
[0120] With regard to their use in the pesticidal mixtures of the
present invention, the compounds II of group A.7 as defined above,
especially abamectin, are especially preferred.
[0121] With regard to their use in the pesticidal mixtures of the
present invention, the compounds II of group A.8 as defined above,
especially fenazaquin, pyridaben and tebufenpyrad are especially
preferred.
[0122] With regard to their use in the pesticidal mixtures of the
present invention, the compounds II of group A.11 as defined above,
especially diafenthiuron and propargite are especially
preferred.
[0123] With regard to their use in the pesticidal mixtures of the
present invention, the compounds II of group A.13 as defined above,
especially indoxacarb and metaflumizone, are especially
preferred.
[0124] Moreover, with regard to its use in the pesticidal mixtures
of the present invention, indoxacarb is especially preferred.
[0125] Moreover, with regard to its use in the pesticidal mixtures
of the present invention, metaflumizone is especially
preferred.
[0126] With regard to their use in the pesticidal mixtures of the
present invention, the compounds II of group A.14 as defined above,
especially flonicamid and pyridalyl, are especially preferred.
[0127] Moreover, with regard to its use in the pesticidal mixtures
of the present invention, flonicamid is especially preferred.
[0128] Moreover, with regard to its use in the pesticidal mixtures
of the present invention, pyridalyl is especially preferred.
[0129] Especially preferred are the inventive mixtures wherein the
compound II of group A is alpha-cypermethrin and the compound of
formula I is a compound of Table 1.
[0130] Especially preferred are the inventive mixtures wherein the
compound II of group A is alpha-cypermethrin and the compound of
formula I is a compound of Table 2.
[0131] Especially preferred are the inventive mixtures wherein the
compound II of group A is alpha-cypermethrin and the compound of
formula I is a compound of Table 3.
[0132] Especially preferred are the inventive mixtures wherein the
compound II of group A is alpha-cypermethrin and the compound of
formula I is a compound of Table 4.
[0133] Especially preferred are the inventive mixtures wherein the
compound II of group A is alpha-cypermethrin and the compound of
formula I is a compound of Table 8.
[0134] Especially preferred are the inventive mixtures wherein the
compound II of group A is alpha-cypermethrin and the compound of
formula I is a compound of Table 10.
[0135] Especially preferred are the inventive mixtures wherein the
compound II of group A is alpha-cypermethrin and the compound of
formula I is a compound of Table 11.
[0136] Especially preferred are the inventive mixtures wherein the
compound II of group A is alpha-cypermethrin and the compound of
formula I is a compound of Table 12.
[0137] Especially preferred are the inventive mixtures wherein the
compound II of group A is alpha-cypermethrin and the compound of
formula I is a compound of Table 13.
[0138] Especially preferred are the inventive mixtures wherein the
compound II of group A is alpha-cypermethrin and the compound of
formula I is a compound of Table 14.
[0139] Especially preferred are the inventive mixtures wherein the
compound II of group A is alpha-cypermethrin and the compound of
formula I is a compound of Table 15.
[0140] Especially preferred are the inventive mixtures wherein the
compound II of group A is alpha-cypermethrin and the compound of
formula I is a compound of Table 19.
[0141] Especially preferred are the inventive mixtures wherein the
compound II of group A is alpha-cypermethrin and the compound of
formula I is a compound of Table 21.
[0142] Especially preferred are the inventive mixtures wherein the
compound II of group A is alpha-cypermethrin and the compound of
formula I is a compound of Table 22.
[0143] Especially preferred are the inventive mixtures wherein the
compound II of group A is spirodiclofen and the compound of formula
I is a compound of Table 1.
[0144] Especially preferred are the inventive mixtures wherein the
compound II of group A is spirodiclofen and the compound of formula
I is a compound of Table 2.
[0145] Especially preferred are the inventive mixtures wherein the
compound II of group A is spirodiclofen and the compound of formula
I is a compound of Table 3.
[0146] Especially preferred are the inventive mixtures wherein the
compound II of group A is spirodiclofen and the compound of formula
I is a compound of Table 4.
[0147] Especially preferred are the inventive mixtures wherein the
compound II of group A is spirodiclofen and the compound of formula
I is a compound of Table 8.
[0148] Especially preferred are the inventive mixtures wherein the
compound II of group A is spirodiclofen and the compound of formula
I is a compound of Table 10.
[0149] Especially preferred are the inventive mixtures wherein the
compound II of group A is spirodiclofen and the compound of formula
I is a compound of Table 11.
[0150] Especially preferred are the inventive mixtures wherein the
compound II of group A is spirodiclofen and the compound of formula
I is a compound of Table 12.
[0151] Especially preferred are the inventive mixtures wherein the
compound II of group A is spirodiclofen and the compound of formula
I is a compound of Table 13.
[0152] Especially preferred are the inventive mixtures wherein the
compound II of group A is spirodiclofen and the compound of formula
I is a compound of Table 14.
[0153] Especially preferred are the inventive mixtures wherein the
compound II of group A is spirodiclofen and the compound of formula
I is a compound of Table 15.
[0154] Especially preferred are the inventive mixtures wherein the
compound II of group A is spirodiclofen and the compound of formula
I is a compound of Table 19.
[0155] Especially preferred are the inventive mixtures wherein the
compound II of group A is spirodiclofen and the compound of formula
I is a compound of Table 21.
[0156] Especially preferred are the inventive mixtures wherein the
compound II of group A is spirodiclofen and the compound of formula
I is a compound of Table 22.
[0157] Especially preferred are the inventive mixtures wherein the
compound II of group A is spiromesifen and the compound of formula
I is a compound of Table 1.
[0158] Especially preferred are the inventive mixtures wherein the
compound II of group A is spiromesifen and the compound of formula
I is a compound of Table 2.
[0159] Especially preferred are the inventive mixtures wherein the
compound II of group A is spiromesifen and the compound of formula
I is a compound of Table 3.
[0160] Especially preferred are the inventive mixtures wherein the
compound II of group A is spiromesifen and the compound of formula
I is a compound of Table 4.
[0161] Especially preferred are the inventive mixtures wherein the
compound II of group A is spiromesifen and the compound of formula
I is a compound of Table 8.
[0162] Especially preferred are the inventive mixtures wherein the
compound II of group A is spiromesifen and the compound of formula
I is a compound of Table 10.
[0163] Especially preferred are the inventive mixtures wherein the
compound II of group A is spiromesifen and the compound of formula
I is a compound of Table 11.
[0164] Especially preferred are the inventive mixtures wherein the
compound II of group A is spiromesifen and the compound of formula
I is a compound of Table 12.
[0165] Especially preferred are the inventive mixtures wherein the
compound II of group A is spiromesifen and the compound of formula
I is a compound of Table 13.
[0166] Especially preferred are the inventive mixtures wherein the
compound II of group A is spiromesifen and the compound of formula
I is a compound of Table 14.
[0167] Especially preferred are the inventive mixtures wherein the
compound II of group A is spiromesifen and the compound of formula
I is a compound of Table 15.
[0168] Especially preferred are the inventive mixtures wherein the
compound II of group A is spiromesifen and the compound of formula
I is a compound of Table 19.
[0169] Especially preferred are the inventive mixtures wherein the
compound II of group A is spiromesifen and the compound of formula
I is a compound of Table 21.
[0170] Especially preferred are the inventive mixtures wherein the
compound II of group A is spiromesifen and the compound of formula
I is a compound of Table 22.
[0171] Especially preferred are the inventive mixtures wherein the
compound II of group A is spirotetramat and the compound of formula
I is a compound of Table 1.
[0172] Especially preferred are the inventive mixtures wherein the
compound II of group A is spirotetramat and the compound of formula
I is a compound of Table 2.
[0173] Especially preferred are the inventive mixtures wherein the
compound II of group A is spirotetramat and the compound of formula
I is a compound of Table 3.
[0174] Especially preferred are the inventive mixtures wherein the
compound II of group A is spirotetramat and the compound of formula
I is a compound of Table 4.
[0175] Especially preferred are the inventive mixtures wherein the
compound II of group A is spirotetramat and the compound of formula
I is a compound of Table 8.
[0176] Especially preferred are the inventive mixtures wherein the
compound II of group A is spirotetramat and the compound of formula
I is a compound of Table 10.
[0177] Especially preferred are the inventive mixtures wherein the
compound II of group A is spirotetramat and the compound of formula
I is a compound of Table 11.
[0178] Especially preferred are the inventive mixtures wherein the
compound II of group A is spirotetramat and the compound of formula
I is a compound of Table 12.
[0179] Especially preferred are the inventive mixtures wherein the
compound II of group A is spirotetramat and the compound of formula
I is a compound of Table 13.
[0180] Especially preferred are the inventive mixtures wherein the
compound II of group A is spirotetramat and the compound of formula
I is a compound of Table 14.
[0181] Especially preferred are the inventive mixtures wherein the
compound II of group A is spirotetramat and the compound of formula
I is a compound of Table 15.
[0182] Especially preferred are the inventive mixtures wherein the
compound II of group A is spirotetramat and the compound of formula
I is a compound of Table 19.
[0183] Especially preferred are the inventive mixtures wherein the
compound II of group A is spirotetramat and the compound of formula
I is a compound of Table 21.
[0184] Especially preferred are the inventive mixtures wherein the
compound II of group A is spirotetramat and the compound of formula
I is a compound of Table 22.
[0185] Especially preferred are the inventive mixtures wherein the
compound II of group A is clothianidine and the compound of formula
I is a compound of Table 1.
[0186] Especially preferred are the inventive mixtures wherein the
compound II of group A is clothianidine and the compound of formula
I is a compound of Table 2.
[0187] Especially preferred are the inventive mixtures wherein the
compound II of group A is clothianidine and the compound of formula
I is a compound of Table 3.
[0188] Especially preferred are the inventive mixtures wherein the
compound II of group A is clothianidine and the compound of formula
I is a compound of Table 4.
[0189] Especially preferred are the inventive mixtures wherein the
compound II of group A is clothianidine and the compound of formula
I is a compound of Table 8.
[0190] Especially preferred are the inventive mixtures wherein the
compound II of group A is clothianidine and the compound of formula
I is a compound of Table 10.
[0191] Especially preferred are the inventive mixtures wherein the
compound II of group A is clothianidine and the compound of formula
I is a compound of Table 11.
[0192] Especially preferred are the inventive mixtures wherein the
compound II of group A is clothianidine and the compound of formula
I is a compound of Table 12.
[0193] Especially preferred are the inventive mixtures wherein the
compound II of group A is clothianidine and the compound of formula
I is a compound of Table 13.
[0194] Especially preferred are the inventive mixtures wherein the
compound II of group A is clothianidine and the compound of formula
I is a compound of Table 14.
[0195] Especially preferred are the inventive mixtures wherein the
compound II of group A is clothianidine and the compound of formula
I is a compound of Table 15.
[0196] Especially preferred are the inventive mixtures wherein the
compound II of group A is clothianidine and the compound of formula
I is a compound of Table 19.
[0197] Especially preferred are the inventive mixtures wherein the
compound II of group A is clothianidine and the compound of formula
I is a compound of Table 21.
[0198] Especially preferred are the inventive mixtures wherein the
compound II of group A is clothianidine and the compound of formula
I is a compound of Table 22.
[0199] Especially preferred are the inventive mixtures wherein the
compound II of group A is dinetofuran and the compound of formula I
is a compound of Table 1.
[0200] Especially preferred are the inventive mixtures wherein the
compound II of group A is dinetofuran and the compound of formula I
is a compound of Table 2.
[0201] Especially preferred are the inventive mixtures wherein the
compound II of group A is dinetofuran and the compound of formula I
is a compound of Table 3.
[0202] Especially preferred are the inventive mixtures wherein the
compound II of group A is dinetofuran and the compound of formula I
is a compound of Table 4.
[0203] Especially preferred are the inventive mixtures wherein the
compound II of group A is dinetofuran and the compound of formula I
is a compound of Table 8.
[0204] Especially preferred are the inventive mixtures wherein the
compound II of group A is dinetofuran and the compound of formula I
is a compound of Table 10.
[0205] Especially preferred are the inventive mixtures wherein the
compound II of group A is dinetofuran and the compound of formula I
is a compound of Table 11.
[0206] Especially preferred are the inventive mixtures wherein the
compound II of group A is dinetofuran and the compound of formula I
is a compound of Table 12.
[0207] Especially preferred are the inventive mixtures wherein the
compound II of group A is dinetofuran and the compound of formula I
is a compound of Table 13.
[0208] Especially preferred are the inventive mixtures wherein the
compound II of group A is dinetofuran and the compound of formula I
is a compound of Table 14.
[0209] Especially preferred are the inventive mixtures wherein the
compound II of group A is dinetofuran and the compound of formula I
is a compound of Table 15.
[0210] Especially preferred are the inventive mixtures wherein the
compound II of group A is dinetofuran and the compound of formula I
is a compound of Table 19.
[0211] Especially preferred are the inventive mixtures wherein the
compound II of group A is dinetofuran and the compound of formula I
is a compound of Table 21.
[0212] Especially preferred are the inventive mixtures wherein the
compound II of group A is dinetofuran and the compound of formula I
is a compound of Table 22.
[0213] Especially preferred are the inventive mixtures wherein the
compound II of group A is imidacloprid and the compound of formula
I is a compound of Table 1.
[0214] Especially preferred are the inventive mixtures wherein the
compound II of group A is imidacloprid and the compound of formula
I is a compound of Table 2.
[0215] Especially preferred are the inventive mixtures wherein the
compound II of group A is imidacloprid and the compound of formula
I is a compound of Table 3.
[0216] Especially preferred are the inventive mixtures wherein the
compound II of group A is imidacloprid and the compound of formula
I is a compound of Table 4.
[0217] Especially preferred are the inventive mixtures wherein the
compound II of group A is imidacloprid and the compound of formula
I is a compound of Table 8.
[0218] Especially preferred are the inventive mixtures wherein the
compound II of group A is imidacloprid and the compound of formula
I is a compound of Table 10.
[0219] Especially preferred are the inventive mixtures wherein the
compound II of group A is imidacloprid and the compound of formula
I is a compound of Table 11.
[0220] Especially preferred are the inventive mixtures wherein the
compound II of group A is imidacloprid and the compound of formula
I is a compound of Table 12.
[0221] Especially preferred are the inventive mixtures wherein the
compound II of group A is imidacloprid and the compound of formula
I is a compound of Table 13.
[0222] Especially preferred are the inventive mixtures wherein the
compound II of group A is imidacloprid and the compound of formula
I is a compound of Table 14.
[0223] Especially preferred are the inventive mixtures wherein the
compound II of group A is imidacloprid and the compound of formula
I is a compound of Table 15.
[0224] Especially preferred are the inventive mixtures wherein the
compound II of group A is imidacloprid and the compound of formula
I is a compound of Table 19.
[0225] Especially preferred are the inventive mixtures wherein the
compound II of group A is imidacloprid and the compound of formula
I is a compound of Table 21.
[0226] Especially preferred are the inventive mixtures wherein the
compound II of group A is imidacloprid and the compound of formula
I is a compound of Table 22.
[0227] Especially preferred are the inventive mixtures wherein the
compound II of group A is thiamethoxam and the compound of formula
I is a compound of Table 1.
[0228] Especially preferred are the inventive mixtures wherein the
compound II of group A is thiamethoxam and the compound of formula
I is a compound of Table 2.
[0229] Especially preferred are the inventive mixtures wherein the
compound II of group A is thiamethoxam and the compound of formula
I is a compound of Table 3.
[0230] Especially preferred are the inventive mixtures wherein the
compound II of group A is thiamethoxam and the compound of formula
I is a compound of Table 4.
[0231] Especially preferred are the inventive mixtures wherein the
compound II of group A is thiamethoxam and the compound of formula
I is a compound of Table 8.
[0232] Especially preferred are the inventive mixtures wherein the
compound II of group A is thiamethoxam and the compound of formula
I is a compound of Table 10.
[0233] Especially preferred are the inventive mixtures wherein the
compound II of group A is thiamethoxam and the compound of formula
I is a compound of Table 11.
[0234] Especially preferred are the inventive mixtures wherein the
compound II of group A is thiamethoxam and the compound of formula
I is a compound of Table 12.
[0235] Especially preferred are the inventive mixtures wherein the
compound II of group A is thiamethoxam and the compound of formula
I is a compound of Table 13.
[0236] Especially preferred are the inventive mixtures wherein the
compound II of group A is thiamethoxam and the compound of formula
I is a compound of Table 14.
[0237] Especially preferred are the inventive mixtures wherein the
compound II of group A is thiamethoxam and the compound of formula
I is a compound of Table 15.
[0238] Especially preferred are the inventive mixtures wherein the
compound II of group A is thiamethoxam and the compound of formula
I is a compound of Table 19.
[0239] Especially preferred are the inventive mixtures wherein the
compound II of group A is thiamethoxam and the compound of formula
I is a compound of Table 21.
[0240] Especially preferred are the inventive mixtures wherein the
compound II of group A is thiamethoxam and the compound of formula
I is a compound of Table 22.
[0241] Especially preferred are the inventive mixtures wherein the
compound II of group A is nitenpyram and the compound of formula I
is a compound of Table 1.
[0242] Especially preferred are the inventive mixtures wherein the
compound II of group A is nitenpyram and the compound of formula I
is a compound of Table 2.
[0243] Especially preferred are the inventive mixtures wherein the
compound II of group A is nitenpyram and the compound of formula I
is a compound of Table 3.
[0244] Especially preferred are the inventive mixtures wherein the
compound II of group A is nitenpyram and the compound of formula I
is a compound of Table 4.
[0245] Especially preferred are the inventive mixtures wherein the
compound II of group A is nitenpyram and the compound of formula I
is a compound of Table 8.
[0246] Especially preferred are the inventive mixtures wherein the
compound II of group A is nitenpyram and the compound of formula I
is a compound of Table 10.
[0247] Especially preferred are the inventive mixtures wherein the
compound II of group A is nitenpyram and the compound of formula I
is a compound of Table 11.
[0248] Especially preferred are the inventive mixtures wherein the
compound II of group A is nitenpyram and the compound of formula I
is a compound of Table 12.
[0249] Especially preferred are the inventive mixtures wherein the
compound II of group A is nitenpyram and the compound of formula I
is a compound of Table 13.
[0250] Especially preferred are the inventive mixtures wherein the
compound II of group A is nitenpyram and the compound of formula I
is a compound of Table 14.
[0251] Especially preferred are the inventive mixtures wherein the
compound II of group A is nitenpyram and the compound of formula I
is a compound of Table 15.
[0252] Especially preferred are the inventive mixtures wherein the
compound II of group A is nitenpyram and the compound of formula I
is a compound of Table 19.
[0253] Especially preferred are the inventive mixtures wherein the
compound II of group A is nitenpyram and the compound of formula I
is a compound of Table 21.
[0254] Especially preferred are the inventive mixtures wherein the
compound II of group A is nitenpyram and the compound of formula I
is a compound of Table 22.
[0255] Especially preferred are the inventive mixtures wherein the
compound II of group A is acetamiprid and the compound of formula I
is a compound of Table 1.
[0256] Especially preferred are the inventive mixtures wherein the
compound II of group A is acetamiprid and the compound of formula I
is a compound of Table 2.
[0257] Especially preferred are the inventive mixtures wherein the
compound II of group A is acetamiprid and the compound of formula I
is a compound of Table 3.
[0258] Especially preferred are the inventive mixtures wherein the
compound II of group A is acetamiprid and the compound of formula I
is a compound of Table 4.
[0259] Especially preferred are the inventive mixtures wherein the
compound II of group A is acetamiprid and the compound of formula I
is a compound of Table 8.
[0260] Especially preferred are the inventive mixtures wherein the
compound II of group A is acetamiprid and the compound of formula I
is a compound of Table 10.
[0261] Especially preferred are the inventive mixtures wherein the
compound II of group A is acetamiprid and the compound of formula I
is a compound of Table 11.
[0262] Especially preferred are the inventive mixtures wherein the
compound II of group A is acetamiprid and the compound of formula I
is a compound of Table 12.
[0263] Especially preferred are the inventive mixtures wherein the
compound II of group A is acetamiprid and the compound of formula I
is a compound of Table 13.
[0264] Especially preferred are the inventive mixtures wherein the
compound II of group A is acetamiprid and the compound of formula I
is a compound of Table 14.
[0265] Especially preferred are the inventive mixtures wherein the
compound II of group A is acetamiprid and the compound of formula I
is a compound of Table 15.
[0266] Especially preferred are the inventive mixtures wherein the
compound II of group A is acetamiprid and the compound of formula I
is a compound of Table 19.
[0267] Especially preferred are the inventive mixtures wherein the
compound II of group A is acetamiprid and the compound of formula I
is a compound of Table 21.
[0268] Especially preferred are the inventive mixtures wherein the
compound II of group A is acetamiprid and the compound of formula I
is a compound of Table 22.
[0269] Especially preferred are the inventive mixtures wherein the
compound II of group A is thiacloprid and the compound of formula I
is a compound of Table 1.
[0270] Especially preferred are the inventive mixtures wherein the
compound II of group A is thiacloprid and the compound of formula I
is a compound of Table 2.
[0271] Especially preferred are the inventive mixtures wherein the
compound II of group A is thiacloprid and the compound of formula I
is a compound of Table 3.
[0272] Especially preferred are the inventive mixtures wherein the
compound II of group A is thiacloprid and the compound of formula I
is a compound of Table 4.
[0273] Especially preferred are the inventive mixtures wherein the
compound II of group A is thiacloprid and the compound of formula I
is a compound of Table 8.
[0274] Especially preferred are the inventive mixtures wherein the
compound II of group A is thiacloprid and the compound of formula I
is a compound of Table 10.
[0275] Especially preferred are the inventive mixtures wherein the
compound II of group A is thiacloprid and the compound of formula I
is a compound of Table 11.
[0276] Especially preferred are the inventive mixtures wherein the
compound II of group A is thiacloprid and the compound of formula I
is a compound of Table 12.
[0277] Especially preferred are the inventive mixtures wherein the
compound II of group A is thiacloprid and the compound of formula I
is a compound of Table 13.
[0278] Especially preferred are the inventive mixtures wherein the
compound II of group A is thiacloprid and the compound of formula I
is a compound of Table 14.
[0279] Especially preferred are the inventive mixtures wherein the
compound II of group A is thiacloprid and the compound of formula I
is a compound of Table 15.
[0280] Especially preferred are the inventive mixtures wherein the
compound II of group A is thiacloprid and the compound of formula I
is a compound of Table 19.
[0281] Especially preferred are the inventive mixtures wherein the
compound II of group A is thiacloprid and the compound of formula I
is a compound of Table 21.
[0282] Especially preferred are the inventive mixtures wherein the
compound II of group A is thiacloprid and the compound of formula I
is a compound of Table 22.
[0283] Especially preferred are the inventive mixtures wherein the
compound II of group A is endosulfan and the compound of formula I
is a compound of Table 1.
[0284] Especially preferred are the inventive mixtures wherein the
compound II of group A is endosulfan and the compound of formula I
is a compound of Table 2.
[0285] Especially preferred are the inventive mixtures wherein the
compound II of group A is endosulfan and the compound of formula I
is a compound of Table 3.
[0286] Especially preferred are the inventive mixtures wherein the
compound II of group A is endosulfan and the compound of formula I
is a compound of Table 4.
[0287] Especially preferred are the inventive mixtures wherein the
compound II of group A is endosulfan and the compound of formula I
is a compound of Table 8.
[0288] Especially preferred are the inventive mixtures wherein the
compound II of group A is endosulfan and the compound of formula I
is a compound of Table 10.
[0289] Especially preferred are the inventive mixtures wherein the
compound II of group A is endosulfan and the compound of formula I
is a compound of Table 11.
[0290] Especially preferred are the inventive mixtures wherein the
compound II of group A is endosulfan and the compound of formula I
is a compound of Table 12.
[0291] Especially preferred are the inventive mixtures wherein the
compound II of group A is endosulfan and the compound of formula I
is a compound of Table 13.
[0292] Especially preferred are the inventive mixtures wherein the
compound II of group A is endosulfan and the compound of formula I
is a compound of Table 14.
[0293] Especially preferred are the inventive mixtures wherein the
compound II of group A is endosulfan and the compound of formula I
is a compound of Table 15.
[0294] Especially preferred are the inventive mixtures wherein the
compound II of group A is endosulfan and the compound of formula I
is a compound of Table 19.
[0295] Especially preferred are the inventive mixtures wherein the
compound II of group A is endosulfan and the compound of formula I
is a compound of Table 21.
[0296] Especially preferred are the inventive mixtures wherein the
compound II of group A is endosulfan and the compound of formula I
is a compound of Table 22.
[0297] Especially preferred are the inventive mixtures wherein the
compound II of group A is fipronil and the compound of formula I is
a compound of Table 1.
[0298] Especially preferred are the inventive mixtures wherein the
compound II of group A is fipronil and the compound of formula I is
a compound of Table 2.
[0299] Especially preferred are the inventive mixtures wherein the
compound II of group A is fipronil and the compound of formula I is
a compound of Table 3.
[0300] Especially preferred are the inventive mixtures wherein the
compound II of group A is fipronil and the compound of formula I is
a compound of Table 4.
[0301] Especially preferred are the inventive mixtures wherein the
compound II of group A is fipronil and the compound of formula I is
a compound of Table 8.
[0302] Especially preferred are the inventive mixtures wherein the
compound II of group A is fipronil and the compound of formula I is
a compound of Table 10.
[0303] Especially preferred are the inventive mixtures wherein the
compound II of group A is fipronil and the compound of formula I is
a compound of Table 11.
[0304] Especially preferred are the inventive mixtures wherein the
compound II of group A is fipronil and the compound of formula I is
a compound of Table 12.
[0305] Especially preferred are the inventive mixtures wherein the
compound II of group A is fipronil and the compound of formula I is
a compound of Table 13.
[0306] Especially preferred are the inventive mixtures wherein the
compound II of group A is fipronil and the compound of formula I is
a compound of Table 14.
[0307] Especially preferred are the inventive mixtures wherein the
compound II of group A is fipronil and the compound of formula I is
a compound of Table 15.
[0308] Especially preferred are the inventive mixtures wherein the
compound II of group A is fipronil and the compound of formula I is
a compound of Table 19.
[0309] Especially preferred are the inventive mixtures wherein the
compound II of group A is fipronil and the compound of formula I is
a compound of Table 21.
[0310] Especially preferred are the inventive mixtures wherein the
compound II of group A is fipronil and the compound of formula I is
a compound of Table 22.
[0311] Especially preferred are the inventive mixtures wherein the
compound II of group A is abamectin and the compound of formula I
is a compound of Table 1.
[0312] Especially preferred are the inventive mixtures wherein the
compound II of group A is abamectin and the compound of formula I
is a compound of Table 2.
[0313] Especially preferred are the inventive mixtures wherein the
compound II of group A is abamectin and the compound of formula I
is a compound of Table 3.
[0314] Especially preferred are the inventive mixtures wherein the
compound II of group A is abamectin and the compound of formula I
is a compound of Table 4.
[0315] Especially preferred are the inventive mixtures wherein the
compound II of group A is abamectin and the compound of formula I
is a compound of Table 8.
[0316] Especially preferred are the inventive mixtures wherein the
compound II of group A is abamectin and the compound of formula I
is a compound of Table 10.
[0317] Especially preferred are the inventive mixtures wherein the
compound II of group A is abamectin and the compound of formula I
is a compound of Table 11.
[0318] Especially preferred are the inventive mixtures wherein the
compound II of group A is abamectin and the compound of formula I
is a compound of Table 12.
[0319] Especially preferred are the inventive mixtures wherein the
compound II of group A is abamectin and the compound of formula I
is a compound of Table 13.
[0320] Especially preferred are the inventive mixtures wherein the
compound II of group A is abamectin and the compound of formula I
is a compound of Table 14.
[0321] Especially preferred are the inventive mixtures wherein the
compound II of group A is abamectin and the compound of formula I
is a compound of Table 15.
[0322] Especially preferred are the inventive mixtures wherein the
compound II of group A is abamectin and the compound of formula I
is a compound of Table 19.
[0323] Especially preferred are the inventive mixtures wherein the
compound II of group A is abamectin and the compound of formula I
is a compound of Table 21.
[0324] Especially preferred are the inventive mixtures wherein the
compound II of group A is abamectin and the compound of formula I
is a compound of Table 22.
[0325] Especially preferred are the inventive mixtures wherein the
compound II of group A is fenazaquin and the compound of formula I
is a compound of Table 1.
[0326] Especially preferred are the inventive mixtures wherein the
compound II of group A is fenazaquin and the compound of formula I
is a compound of Table 2.
[0327] Especially preferred are the inventive mixtures wherein the
compound II of group A is fenazaquin and the compound of formula I
is a compound of Table 3.
[0328] Especially preferred are the inventive mixtures wherein the
compound II of group A is fenazaquin and the compound of formula I
is a compound of Table 4.
[0329] Especially preferred are the inventive mixtures wherein the
compound II of group A is fenazaquin and the compound of formula I
is a compound of Table 8.
[0330] Especially preferred are the inventive mixtures wherein the
compound II of group A is fenazaquin and the compound of formula I
is a compound of Table 10.
[0331] Especially preferred are the inventive mixtures wherein the
compound II of group A is fenazaquin and the compound of formula I
is a compound of Table 11.
[0332] Especially preferred are the inventive mixtures wherein the
compound II of group A is fenazaquin and the compound of formula I
is a compound of Table 12.
[0333] Especially preferred are the inventive mixtures wherein the
compound II of group A is fenazaquin and the compound of formula I
is a compound of Table 13.
[0334] Especially preferred are the inventive mixtures wherein the
compound II of group A is fenazaquin and the compound of formula I
is a compound of Table 14.
[0335] Especially preferred are the inventive mixtures wherein the
compound II of group A is fenazaquin and the compound of formula I
is a compound of Table 15.
[0336] Especially preferred are the inventive mixtures wherein the
compound II of group A is fenazaquin and the compound of formula I
is a compound of Table 19.
[0337] Especially preferred are the inventive mixtures wherein the
compound II of group A is fenazaquin and the compound of formula I
is a compound of Table 21.
[0338] Especially preferred are the inventive mixtures wherein the
compound II of group A is fenazaquin and the compound of formula I
is a compound of Table 22.
[0339] Especially preferred are the inventive mixtures wherein the
compound II of group A is pyridaben and the compound of formula I
is a compound of Table 1.
[0340] Especially preferred are the inventive mixtures wherein the
compound II of group A is pyridaben and the compound of formula I
is a compound of Table 2.
[0341] Especially preferred are the inventive mixtures wherein the
compound II of group A is pyridaben and the compound of formula I
is a compound of Table 3.
[0342] Especially preferred are the inventive mixtures wherein the
compound II of group A is pyridaben and the compound of formula I
is a compound of Table 4.
[0343] Especially preferred are the inventive mixtures wherein the
compound II of group A is pyridaben and the compound of formula I
is a compound of Table 8.
[0344] Especially preferred are the inventive mixtures wherein the
compound II of group A is pyridaben and the compound of formula I
is a compound of Table 10.
[0345] Especially preferred are the inventive mixtures wherein the
compound II of group A is pyridaben and the compound of formula I
is a compound of Table 11.
[0346] Especially preferred are the inventive mixtures wherein the
compound II of group A is pyridaben and the compound of formula I
is a compound of Table 12.
[0347] Especially preferred are the inventive mixtures wherein the
compound II of group A is pyridaben and the compound of formula I
is a compound of Table 13.
[0348] Especially preferred are the inventive mixtures wherein the
compound II of group A is pyridaben and the compound of formula I
is a compound of Table 14.
[0349] Especially preferred are the inventive mixtures wherein the
compound II of group A is pyridaben and the compound of formula I
is a compound of Table 15.
[0350] Especially preferred are the inventive mixtures wherein the
compound II of group A is pyridaben and the compound of formula I
is a compound of Table 19.
[0351] Especially preferred are the inventive mixtures wherein the
compound II of group A is pyridaben and the compound of formula I
is a compound of Table 21.
[0352] Especially preferred are the inventive mixtures wherein the
compound II of group A is pyridaben and the compound of formula I
is a compound of Table 22.
[0353] Especially preferred are the inventive mixtures wherein the
compound II of group A is tebufenpyrad and the compound of formula
I is a compound of Table 1.
[0354] Especially preferred are the inventive mixtures wherein the
compound II of group A is tebufenpyrad and the compound of formula
I is a compound of Table 2.
[0355] Especially preferred are the inventive mixtures wherein the
compound II of group A is tebufenpyrad and the compound of formula
I is a compound of Table 3.
[0356] Especially preferred are the inventive mixtures wherein the
compound II of group A is tebufenpyrad and the compound of formula
I is a compound of Table 4.
[0357] Especially preferred are the inventive mixtures wherein the
compound II of group A is tebufenpyrad and the compound of formula
I is a compound of Table 8.
[0358] Especially preferred are the inventive mixtures wherein the
compound II of group A is tebufenpyrad and the compound of formula
I is a compound of Table 10.
[0359] Especially preferred are the inventive mixtures wherein the
compound II of group A is tebufenpyrad and the compound of formula
I is a compound of Table 11.
[0360] Especially preferred are the inventive mixtures wherein the
compound II of group A is tebufenpyrad and the compound of formula
I is a compound of Table 12.
[0361] Especially preferred are the inventive mixtures wherein the
compound II of group A is tebufenpyrad and the compound of formula
I is a compound of Table 13.
[0362] Especially preferred are the inventive mixtures wherein the
compound II of group A is tebufenpyrad and the compound of formula
I is a compound of Table 14.
[0363] Especially preferred are the inventive mixtures wherein the
compound II of group A is tebufenpyrad and the compound of formula
I is a compound of Table 15.
[0364] Especially preferred are the inventive mixtures wherein the
compound II of group A is tebufenpyrad and the compound of formula
I is a compound of Table 19.
[0365] Especially preferred are the inventive mixtures wherein the
compound II of group A is tebufenpyrad and the compound of formula
I is a compound of Table 21.
[0366] Especially preferred are the inventive mixtures wherein the
compound II of group A is tebufenpyrad and the compound of formula
I is a compound of Table 22.
[0367] Especially preferred are the inventive mixtures wherein the
compound II of group A is diafenthiuron and the compound of formula
I is a compound of Table 1.
[0368] Especially preferred are the inventive mixtures wherein the
compound II of group A is diafenthiuron and the compound of formula
I is a compound of Table 2.
[0369] Especially preferred are the inventive mixtures wherein the
compound II of group A is diafenthiuron and the compound of formula
I is a compound of Table 3.
[0370] Especially preferred are the inventive mixtures wherein the
compound II of group A is diafenthiuron and the compound of formula
I is a compound of Table 4.
[0371] Especially preferred are the inventive mixtures wherein the
compound II of group A is diafenthiuron and the compound of formula
I is a compound of Table 8.
[0372] Especially preferred are the inventive mixtures wherein the
compound II of group A is diafenthiuron and the compound of formula
I is a compound of Table 10.
[0373] Especially preferred are the inventive mixtures wherein the
compound II of group A is diafenthiuron and the compound of formula
I is a compound of Table 11.
[0374] Especially preferred are the inventive mixtures wherein the
compound II of group A is diafenthiuron and the compound of formula
I is a compound of Table 12.
[0375] Especially preferred are the inventive mixtures wherein the
compound II of group A is diafenthiuron and the compound of formula
I is a compound of Table 13.
[0376] Especially preferred are the inventive mixtures wherein the
compound II of group A is diafenthiuron and the compound of formula
I is a compound of Table 14.
[0377] Especially preferred are the inventive mixtures wherein the
compound II of group A is diafenthiuron and the compound of formula
I is a compound of Table 15.
[0378] Especially preferred are the inventive mixtures wherein the
compound II of group A is diafenthiuron and the compound of formula
I is a compound of Table 19.
[0379] Especially preferred are the inventive mixtures wherein the
compound II of group A is diafenthiuron and the compound of formula
I is a compound of Table 21.
[0380] Especially preferred are the inventive mixtures wherein the
compound II of group A is diafenthiuron and the compound of formula
I is a compound of Table 22.
[0381] Especially preferred are the inventive mixtures wherein the
compound II of group A is propargite and the compound of formula I
is a compound of Table 1.
[0382] Especially preferred are the inventive mixtures wherein the
compound II of group A is propargite and the compound of formula I
is a compound of Table 2.
[0383] Especially preferred are the inventive mixtures wherein the
compound II of group A is propargite and the compound of formula I
is a compound of Table 3.
[0384] Especially preferred are the inventive mixtures wherein the
compound II of group A is propargite and the compound of formula I
is a compound of Table 4.
[0385] Especially preferred are the inventive mixtures wherein the
compound II of group A is propargite and the compound of formula I
is a compound of Table 8.
[0386] Especially preferred are the inventive mixtures wherein the
compound II of group A is propargite and the compound of formula I
is a compound of Table 10.
[0387] Especially preferred are the inventive mixtures wherein the
compound II of group A is propargite and the compound of formula I
is a compound of Table 11.
[0388] Especially preferred are the inventive mixtures wherein the
compound II of group A is propargite and the compound of formula I
is a compound of Table 12.
[0389] Especially preferred are the inventive mixtures wherein the
compound II of group A is propargite and the compound of formula I
is a compound of Table 13.
[0390] Especially preferred are the inventive mixtures wherein the
compound II of group A is propargite and the compound of formula I
is a compound of Table 14.
[0391] Especially preferred are the inventive mixtures wherein the
compound II of group A is propargite and the compound of formula I
is a compound of Table 15.
[0392] Especially preferred are the inventive mixtures wherein the
compound II of group A is propargite and the compound of formula I
is a compound of Table 19.
[0393] Especially preferred are the inventive mixtures wherein the
compound II of group A is propargite and the compound of formula I
is a compound of Table 21.
[0394] Especially preferred are the inventive mixtures wherein the
compound II of group A is propargite and the compound of formula I
is a compound of Table 22.
[0395] Especially preferred are the inventive mixtures wherein the
compound II of group A is indoxacarb and the compound of formula I
is a compound of Table 1.
[0396] Especially preferred are the inventive mixtures wherein the
compound II of group A is indoxacarb and the compound of formula I
is a compound of Table 2.
[0397] Especially preferred are the inventive mixtures wherein the
compound II of group A is indoxacarb and the compound of formula I
is a compound of Table 3.
[0398] Especially preferred are the inventive mixtures wherein the
compound II of group A is indoxacarb and the compound of formula I
is a compound of Table 4.
[0399] Especially preferred are the inventive mixtures wherein the
compound II of group A is indoxacarb and the compound of formula I
is a compound of Table 8.
[0400] Especially preferred are the inventive mixtures wherein the
compound II of group A is indoxacarb and the compound of formula I
is a compound of Table 10.
[0401] Especially preferred are the inventive mixtures wherein the
compound II of group A is indoxacarb and the compound of formula I
is a compound of Table 11.
[0402] Especially preferred are the inventive mixtures wherein the
compound II of group A is indoxacarb and the compound of formula I
is a compound of Table 12.
[0403] Especially preferred are the inventive mixtures wherein the
compound II of group A is indoxacarb and the compound of formula I
is a compound of Table 13.
[0404] Especially preferred are the inventive mixtures wherein the
compound II of group A is indoxacarb and the compound of formula I
is a compound of Table 14.
[0405] Especially preferred are the inventive mixtures wherein the
compound II of group A is indoxacarb and the compound of formula I
is a compound of Table 15.
[0406] Especially preferred are the inventive mixtures wherein the
compound II of group A is indoxacarb and the compound of formula I
is a compound of Table 19.
[0407] Especially preferred are the inventive mixtures wherein the
compound II of group A is indoxacarb and the compound of formula I
is a compound of Table 21.
[0408] Especially preferred are the inventive mixtures wherein the
compound II of group A is indoxacarb and the compound of formula I
is a compound of Table 22.
[0409] Especially preferred are the inventive mixtures wherein the
compound II of group A is metaflumizone and the compound of formula
I is a compound of Table 1.
[0410] Especially preferred are the inventive mixtures wherein the
compound II of group A is metaflumizone and the compound of formula
I is a compound of Table 2.
[0411] Especially preferred are the inventive mixtures wherein the
compound II of group A is metaflumizone and the compound of formula
I is a compound of Table 3.
[0412] Especially preferred are the inventive mixtures wherein the
compound II of group A is metaflumizone and the compound of formula
I is a compound of Table 4.
[0413] Especially preferred are the inventive mixtures wherein the
compound II of group A is metaflumizone and the compound of formula
I is a compound of Table 8.
[0414] Especially preferred are the inventive mixtures wherein the
compound II of group A is metaflumizone and the compound of formula
I is a compound of Table 10.
[0415] Especially preferred are the inventive mixtures wherein the
compound II of group A is metaflumizone and the compound of formula
I is a compound of Table 11.
[0416] Especially preferred are the inventive mixtures wherein the
compound II of group A is metaflumizone and the compound of formula
I is a compound of Table 12.
[0417] Especially preferred are the inventive mixtures wherein the
compound II of group A is metaflumizone and the compound of formula
I is a compound of Table 13.
[0418] Especially preferred are the inventive mixtures wherein the
compound II of group A is metaflumizone and the compound of formula
I is a compound of Table 14.
[0419] Especially preferred are the inventive mixtures wherein the
compound II of group A is metaflumizone and the compound of formula
I is a compound of Table 15.
[0420] Especially preferred are the inventive mixtures wherein the
compound II of group A is metaflumizone and the compound of formula
I is a compound of Table 19.
[0421] Especially preferred are the inventive mixtures wherein the
compound II of group A is metaflumizone and the compound of formula
I is a compound of Table 21.
[0422] Especially preferred are the inventive mixtures wherein the
compound II of group A is metaflumizone and the compound of formula
I is a compound of Table 22.
[0423] Especially preferred are the inventive mixtures wherein the
compound II of group A is flonicamid and the compound of formula I
is a compound of Table 1.
[0424] Especially preferred are the inventive mixtures wherein the
compound II of group A is flonicamid and the compound of formula I
is a compound of Table 2.
[0425] Especially preferred are the inventive mixtures wherein the
compound II of group A is flonicamid and the compound of formula I
is a compound of Table 3.
[0426] Especially preferred are the inventive mixtures wherein the
compound II of group A is flonicamid and the compound of formula I
is a compound of Table 4.
[0427] Especially preferred are the inventive mixtures wherein the
compound II of group A is flonicamid and the compound of formula I
is a compound of Table 8.
[0428] Especially preferred are the inventive mixtures wherein the
compound II of group A is flonicamid and the compound of formula I
is a compound of Table 10.
[0429] Especially preferred are the inventive mixtures wherein the
compound II of group A is flonicamid and the compound of formula I
is a compound of Table 11.
[0430] Especially preferred are the inventive mixtures wherein the
compound II of group A is flonicamid and the compound of formula I
is a compound of Table 12.
[0431] Especially preferred are the inventive mixtures wherein the
compound II of group A is flonicamid and the compound of formula I
is a compound of Table 13.
[0432] Especially preferred are the inventive mixtures wherein the
compound II of group A is flonicamid and the compound of formula I
is a compound of Table 14.
[0433] Especially preferred are the inventive mixtures wherein the
compound II of group A is flonicamid and the compound of formula I
is a compound of Table 15.
[0434] Especially preferred are the inventive mixtures wherein the
compound II of group A is flonicamid and the compound of formula I
is a compound of Table 19.
[0435] Especially preferred are the inventive mixtures wherein the
compound II of group A is flonicamid and the compound of formula I
is a compound of Table 21.
[0436] Especially preferred are the inventive mixtures wherein the
compound II of group A is flonicamid and the compound of formula I
is a compound of Table 22.
[0437] Especially preferred are the inventive mixtures wherein the
compound II of group A is pyridalyl and the compound of formula I
is a compound of Table 1.
[0438] Especially preferred are the inventive mixtures wherein the
compound II of group A is pyridalyl and the compound of formula I
is a compound of Table 2.
[0439] Especially preferred are the inventive mixtures wherein the
compound II of group A is pyridalyl and the compound of formula I
is a compound of Table 3.
[0440] Especially preferred are the inventive mixtures wherein the
compound II of group A is pyridalyl and the compound of formula I
is a compound of Table 4.
[0441] Especially preferred are the inventive mixtures wherein the
compound II of group A is pyridalyl and the compound of formula I
is a compound of Table 8.
[0442] Especially preferred are the inventive mixtures wherein the
compound II of group A is pyridalyl and the compound of formula I
is a compound of Table 10.
[0443] Especially preferred are the inventive mixtures wherein the
compound II of group A is pyridalyl and the compound of formula I
is a compound of Table 11.
[0444] Especially preferred are the inventive mixtures wherein the
compound II of group A is pyridalyl and the compound of formula I
is a compound of Table 12.
[0445] Especially preferred are the inventive mixtures wherein the
compound II of group A is pyridalyl and the compound of formula I
is a compound of Table 13.
[0446] Especially preferred are the inventive mixtures wherein the
compound II of group A is pyridalyl and the compound of formula I
is a compound of Table 14.
[0447] Especially preferred are the inventive mixtures wherein the
compound II of group A is pyridalyl and the compound of formula I
is a compound of Table 15.
[0448] Especially preferred are the inventive mixtures wherein the
compound II of group A is pyridalyl and the compound of formula I
is a compound of Table 19.
[0449] Especially preferred are the inventive mixtures wherein the
compound II of group A is pyridalyl and the compound of formula I
is a compound of Table 21.
[0450] Especially preferred are the inventive mixtures wherein the
compound II of group A is pyridalyl and the compound of formula I
is a compound of Table 22.
[0451] When preparing the mixtures, it is preferred to employ the
pure active compounds I and II, to which further active compounds,
also against harmful fungi or else herbicidal or growth-regulating
active compounds or fertilizers can be added.
[0452] The mixtures of compounds I and II, or the compounds I and
II used simultaneously, that is jointly or separately, exhibit
outstanding action against pests from the following orders:
[0453] insects from the order of the lepidopterans (Lepidoptera),
for example Agrotis ypsilon, Agrotis segetum, Alabama argillacea,
Anticarsia gemmatalis, Argyresthia conjugella, Autographa gamma,
Bupalus piniarius, Cacoecia murinana, Capua reticulana, Chematobia
brumata, Choristoneura fumiferana, Choristoneura occidentalis,
Cirphis unipuncta, Cydia pomonella, Dendrolimus pini, Diaphania
nitidalis, Diatraea grandiosella, Earias insulana, Elasmopalpus
lignosellus, Eupoecilia ambiguella, Evetria bouliana, Feltia
subterranea, Galleria mellonella, Grapholitha funebrana,
Grapholitha molesta, Heliothis armigera, Heliothis virescens,
Heliothis zea, Hellula undalis, Hibernia defoliaria, Hyphantria
cunea, Hyponomeuta malinellus, Keiferia lycopersicella, Lambdina
fiscellaria, Laphygma exigua, Leucoptera coffeella, Leucoptera
scitella, Lithocolletis blancardefia, Lobesia botrana, Loxostege
sticticalis, Lymantria dispar, Lymantria monacha, Lyonetia
clerkella, Malacosoma neustria, Mamestra brassicae, Orgyia
pseudotsugata, Ostrinia nubilalis, Panolis flammea, Pectinophora
gossypiella, Peridroma saucia, Phalera bucephala, Phthorimaea
operculella, Phyllocnistis citrella, Pieris brassicae, Plathypena
scabra, Plutella xylostella, Pseudoplusia includens, Rhyacionia
frustrana, Scrobipalpula absoluta, Sitotroga cerealella,
Sparganothis pilleriana, Spodoptera frugiperda, Spodoptera
littoralis, Spodoptera litura, Thaumatopoea pityocampa, Tortrix
viridana, Trichoplusia ni and Zeiraphera canadensis,
[0454] beetles (Coleoptera), for example Agrilus sinuatus, Agriotes
lineatus, Agriotes obscurus, Amphimallus solstitialis, Anisandrus
dispar, Anthonomus grandis, Anthonomus pomorum, Aphthona
euphoridae, Athous haemorrhoidalis, Atomaria linearis, Blastophagus
piniperda, Blitophaga undata, Bruchus rufimanus, Bruchus pisorum,
Bruchus lentis, Byctiscus betulae, Cassida nebulosa, Cerotoma
trifurcata, Cetonia aurata, Ceuthorrhynchus assimilis,
Ceuthorrhynchus napi, Chaetocnema tibialis, Conoderus vespertinus,
Crioceris asparagi, Ctenicera ssp., Diabrotica longicornis,
Diabrotica semipunctata, Diabrotica 12-punctata Diabrotica
speciosa, Diabrotica virgifera, Epilachna varivestis, Epitrix
hirtipennis, Eutinobothrus brasiliensis, Hylobius abietis, Hypera
brunneipennis, Hypera postica, Ips typographus, Lema bilineata,
Lema melanopus, Leptinotarsa decemlineata, Limonius californicus,
Lissorhoptrus oryzophilus, Melanotus communis, Meligethes aeneus,
Melolontha hippocastani, Melolontha melolontha, Oulema oryzae,
Ortiorrhynchus sulcatus, Otiorrhynchus ovatus, Phaedon cochleariae,
Phyllobius pyri, Phyllotreta chrysocephala, Phyllophaga sp.,
Phyllopertha horticola, Phyllotreta nemorum, Phyllotreta striolata,
Popiffia japonica, Sitona lineatus and Sitophilus granaria,
[0455] flies, mosquitoes (Diptera), e.g. Aedes aegypti, Aedes
albopictus, Aedes vexans, Anastrepha ludens, Anopheles
maculipennis, Anopheles crucians, Anopheles albimanus, Anopheles
gambiae, Anopheles freeborni, Anopheles leucosphyrus, Anopheles
minimus, Anopheles quadrimaculatus, Calliphora vicina, Ceratitis
capitata, Chtysomya bezziana, Chrysomya hominivorax, Chrysomya
macellaria, Chrysops discalis, Chrysops silacea, Chrysops
atlanticus, Cochliomyia hominivorax, Contarinia sorghicola
Cordylobia anthropophaga, Culicoides furens, Culex pipiens, Culex
nigripalpus, Culex quinquefasciatus, Culex tarsalis, Culiseta
inornata, Culiseta melanura, Dacus cucurbitae, Dacus oleae,
Dasineura brassicae, Delia antique, Delia coarctata, Delia platura,
Delia radicum, Dermatobia hominis, Fannia canicularis, Geomyza
Tripunctata, Gasterophilus intestinalis, Glossina morsitans,
Glossina palpalis, Glossina fuscipes, Glossina tachinoides,
Haematobia irritans, Haplodiplosis equestris, Hippelates spp.,
Hylemyia platura, Hypoderma lineata, Leptoconops torrens, Liriomyza
sativae, Liriomyza trifolii, Lucilia cuprina, Lucilia cuprina,
Lucilia sericata, Lycoria pectoralis, Mansonia titillanus,
Mayetiola destructor, Musca domestica, Muscina stabulans, Oestrus
ovis, Opomyza florum, Oscinella frit, Pegomya hysocyami, Phorbia
antiqua, Phorbia brassicae, Phorbia coarctata, Phlebotomus
argentipes, Psorophora columbiae, Psila rosae, Psorophora discolor,
Prosimulium mixtum, Rhagoletis cerasi, Rhagoletis pomonella,
Sarcophaga haemorrhoidalis, Sarcophaga sp., Simulium vittatum,
Stomoxys calcitrans, Tabanus bovinus, Tabanus atratus, Tabanus
lineola, and Tabanus similis, Tipula oleracea, and Tipula
paludosa
[0456] thrips (Thysanoptera), e.g. Dichromothrips corbetti,
Dichromothrips ssp, Frankliniella fusca, Frankliniella
occidentalis, Frankliniella tritici, Scirtothrips citri, Thrips
oryzae, Thrips palmi and Thrips tabaci,
[0457] termites (Isoptera), e.g. Calotermes Leucotermes flavipes,
Heterotermes aureus, Reticulitermes flavipes, Reticulitermes
virginicus, Reticulitermes lucifugus, Termes natalensis, and
Coptotermes formosanus,
[0458] cockroaches (Blattaria-Blattodea), e.g. Blattella germanica,
Blattella asahinae, Periplaneta americana, Periplaneta japonica,
Periplaneta brunnea, Periplaneta fuligginosa, Periplaneta
australasiae, and Blatta orientalis,
[0459] true bugs (Hemiptera), e.g. Acrosternum hilare, Blissus
leucopterus, Cyrtopeltis notatus, Dysdercus cingulatus, Dysdercus
intermedius, Eurygaster integriceps, Euschistus impictiventris,
Leptoglossus phyllopus, Lygus lineolaris, Lygus pratensis, Nezara
viridula, Piesma quadrata, Solubea insularis, Thyanta perditor,
Acyrthosiphon onobrychis, Adelges Aphidula nasturtii, Aphis fabae,
Aphis forbesi, Aphis pomi, Aphis gossypii, Aphis grossulariae,
Aphis schneideri, Aphis spiraecola, Aphis sambuci, Acyrthosiphon
pisum, Aulacorthum solani, Bemisia argentifolii, Brachycaudus
cardui, Brachycaudus helichrysi, Brachycaudus persicae,
Brachycaudus prunicola, Brevicoryne brassicae, Capitophorus horni,
Cerosipha gossypii, Chaetosiphon fragaefolii, Cryptomyzus ribis,
Dreyfusia nordmannianae, Dreyfusia piceae, Dysaphis radicola,
Dysaulacorthum pseudosolani, Dysaphis plantaginea, Dysaphis pyri,
Empoasca fabae, Hyalopterus pruni, Hyperomyzus lactucae,
Macrosiphum avenae, Macrosiphum euphorbiae, Macrosiphon rosae,
Megoura viciae, Melanaphis pyrarius, Metopolophium dirhodum, Myzus
persicae, Myzus ascalonicus, Myzus cerasi, Myzus varians, Nasonovia
ribis-nigri, Nilaparvata lugens, Pemphigus bursarius, Perkinsiella
saccharicida, Phorodon humuli, Psylla mali, Psylla piri,
Rhopalomyzus ascalonicus, Rhopalosiphum maidis, Rhopalosiphum padi,
Rhopalosiphum insertum, Sappaphis mala, Sappaphis mali, Schizaphis
graminum, Schizoneura lanuginosa, Sitobion avenae, Trialeurodes
vaporariorum, Toxoptera aurantiiand, Viteus vitifolii, Cimex
lectularius, Cimex hemipterus, Reduvius senilis, Triatoma spp., and
Arilus critatus.
[0460] ants, bees, wasps, sawflies (Hymenoptera), e.g. Athalia
rosae, Atta cephalotes, Atta capiguara, Atta cephalotes, Atta
laevigata, Atta robusta, Atta sexdens, Atta texana, Crematogaster
spp., Hoplocampa minuta, Hoplocampa testudinea, Monomorium
pharaonis, Solenopsis geminata, Solenopsis invicta, Solenopsis
richteri, Solenopsis xyloni, Pogonomyrmex barbatus, Pogonomyrmex
californicus, Pheidole megacephala, Dasymutilla occidentalis,
Bombus spp. Vespula squamosa, Paravespula vulgaris, Paravespula
pennsylvanica, Paravespula germanica, Dolichovespula maculata,
Vespa crabro, Polistes rubiginosa, Camponotus floridanus, and
Linepithema humile,
[0461] crickets, grasshoppers, locusts (Orthoptera), e.g. Acheta
domestica, Gryllotalpa gryllotalpa, Locusta migratoria, Melanoplus
bivittatus, Melanoplus femurrubrum, Melanoplus mexicanus,
Melanoplus sanguinipes, Melanoplus spretus, Nomadacris
septemfasciata, Schistocerca americana, Schistocerca gregaria,
Dociostaurus maroccanus, Tachycines asynamorus, Oedaleus
senegalensis, Zonozerus variegatus, Hieroglyphus daganensis,
Kraussaria angulifera, Calliptamus italicus, Chortoicetes
terminifera, and Locustana pardalina,
[0462] Arachnoidea, such as arachnids (Acarina), e.g. of the
families Argasidae, Ixodidae and Sarcoptidae, such as Amblyomma
americanum, Amblyomma variegatum, Ambryomma maculatum, Argas
persicus, Boophilus annulatus, Boophilus decoloratus, Boophilus
microplus, Dermacentor silvarum, Dermacentor andersoni, Dermacentor
variabilis, Hyalomma truncatum, Ixodes ricinus, Ixodes rubicundus,
Ixodes scapularis, Ixodes holocyclus, Ixodes pacificus,
Ornithodorus moubata, Ornithodorus hermsi, Ornithodorus turicata,
Ornithonyssus bacoti, Otobius megnini, Dermanyssus gallinae,
Psoroptes ovis, Rhipicephalus sanguineus, Rhipicephalus
appendiculatus, Rhipicephalus evertsi, Sarcoptes scabiei, and
Eriophyidae spp. such as Aculus schlechtendali, Phyllocoptrata
oleivora and Eriophyes sheldoni; Tarsonemidae spp. such as
Phytonemus pallidus and Polyphagotarsonemus latus; Tenuipalpidae
spp. such as Brevipalpus phoenicis; Tetranychidae spp. such as
Tetranychus cinnabarinus, Tetranychus kanzawai, Tetranychus
pacificus, Tetranychus telarius and Tetranychus urticae, Panonychus
ulmi, Panonychus citri, and Oligonychus pratensis; Araneida, e.g.
Latrodectus mactans, and Loxosceles recluse,
[0463] fleas (Siphonaptera), e.g. Ctenocephalides felis,
Ctenocephalides canis, Xenopsylla cheopis, Pulex irritans, Tunga
penetrans, and Nosopsyllus fasciatus,
[0464] silverfish, firebrat (Thysanura), e.g. Lepisma saccharina
and Thermobia domestica,
[0465] centipedes (Chilopoda), e.g. Scutigera coleoptrata,
[0466] millipedes (Diplopoda), e.g. Narceus spp.,
[0467] Earwigs (Dermaptera), e.g. forficula auricularia,
[0468] lice (Phthiraptera), e.g. Pediculus humanus capitis,
Pediculus humanus corporis, Pthirus pubis, Haematopinus eurystemus,
Haematopinus suis, Linognathus vituli, Bovicola bovis, Menopon
gallinae, Menacanthus stramineus and Solenopotes capillatus.
[0469] Plant parasitic nematodes such as root-knot nematodes,
Meloidogyne arenaria, Meloidogyne chitwoodi, Meloidogyne exigua,
Meloidogyne hapla, Meloidogyne incognita, Meloidogyne javanica and
other Meloidogyne species; cyst nematodes, Globodera rostochiensis,
Globodera pallida, Globodera tabacum and other Globodera species,
Heterodera avenae, Heterodera glycines, Heterodera schachtii,
Heterodera trifolii, and other Heterodera species; seed gall
nematodes, Anguina funesta, Anguina tritici and other Anguina
species; stem and foliar nematodes, Aphelenchoides besseyi,
Aphelenchoides fragariae, Aphelenchoides ritzemabosi and other
Aphelenchoides species; sting nematodes, Belonolaimus longicaudatus
and other Belonolaimus species; pine nematodes, Bursaphelenchus
xylophilus and other Bursaphelenchus species; ring nematodes,
Criconema species, Criconemella species, Criconemoides species, and
Mesocriconema species; stem and bulb nematodes, Ditylenchus
destructor, Ditylenchus dipsaci, Ditylenchus myceliophagus and
other Ditylenchus species; awl nematodes, Dolichodorus species;
spiral nematodes, Helicotylenchus dihystera, Helicotylenchus
multicinctus and other Helicotylenchus species, Rotylenchus
robustus and other Rotylenchus species; sheath nematodes,
Hemicycliophora species and Hemicriconemoides species;
Hirshmanniella species; lance nematodes, Hoplolaimus columbus,
Hoplolaimus galeatus and other Hoplolaimus species; false root-knot
nematodes, Nacobbus aberrans and other Nacobbus species; needle
nematodes, Longidorus elongates and other Longidorus species; pin
nematodes, Paratylenchus species; lesion nematodes, Pratylenchus
brachyurus, Pratylenchus coffeae, Pratylenchus curvitatus,
Pratylenchus goodeyi, Pratylencus neglectus, Pratylenchus
penetrans, Pratylenchus scribneri, Pratylenchus vulnus,
Pratylenchus zeae and other Pratylenchus species; Radinaphelenchus
cocophilus and other Radinaphelenchus species; burrowing nematodes,
Radopholus similis and other Radopholus species; reniform
nematodes, Rotylenchulus reniformis and other Rotylenchulus
species; Scutellonema species; stubby root nematodes, Trichodorus
primitivus and other Trichodorus species; Paratrichodorus minor and
other Paratrichodorus species; stunt nematodes, Tylenchorhynchus
claytoni, Tylenchorhynchus dubius and other Tylenchorhynchus
species and Merlinius species; citrus nematodes, Tylenchulus
semipenetrans and other Tylenchulus species; dagger nematodes,
Xiphinema americanum, Xiphinema index, Xiphinema diversicaudatum
and other Xiphinema species; and other plant parasitic nematode
species.
[0470] Moreover, the inventive mixtures are especially useful for
the control of Lepidoptera, Coleoptera, Diptera, Thysanoptera and
Hymenoptera.
[0471] Moreover, the inventive mixtures are especially useful for
the control of non-crop pests (household, turf, ornamental).
[0472] For use according to the present invention, the compounds I
can be converted into the customary formulations.
[0473] The formulations are prepared in a known manner (see e.g.
for review U.S. Pat. No. 3,060,084, EP-A 707 445 (for liquid
concentrates), Browning, "Agglomeration", Chemical Engineering,
Dec. 4, 1967, 147-48, Perry's Chemical Engineer's Handbook, 4th
Ed., McGraw-Hill, New York, 1963, pages 8-57 and et seq. WO
91/13546, U.S. Pat. No. 4,172,714, U.S. Pat. No. 4,144,050, U.S.
Pat. No. 3,920,442, U.S. Pat. No. 5,180,587, U.S. Pat. No.
5,232,701, U.S. Pat. No. 5,208,030, GB 2,095,558, U.S. Pat. No.
3,299,566, Klingman, Weed Control as a Science, John Wiley and
Sons, Inc., New York, 1961, Hance et al., Weed Control Handbook,
8th Ed., Blackwell Scientific Publications, Oxford, 1989 and
Mollet, H., Grubemann, A., Formulation technology, Wiley VCH Verlag
GmbH, Weinheim (Germany), 2001, 2. D. A. Knowles, Chemistry and
Technology of Agrochemical Formulations, Kluwer Academic
Publishers, Dordrecht, 1998 (ISBN 0-7514-0443-8), for example by
extending the active compound with auxiliaries suitable for the
formulation of agrochemicals, such as solvents and/or carriers, if
desired emulsifiers, surfactants and dispersants, preservatives,
antifoaming agents, anti-freezing agents, for seed treatment
formulation also optionally colorants and binders.
[0474] Examples of suitable solvents are water, aromatic solvents
(for example Solvesso products, xylene), paraffins (for example
mineral oil fractions), alcohols (for example methanol, butanol,
pentanol, benzyl alcohol), ketones (for example cyclohexanone,
gamma-butyrolactone), pyrrolidones (NMP, NOP), acetates (glycol
diacetate), glycols, fatty acid dimethylamides, fatty acids and
fatty acid esters. In principle, solvent mixtures may also be
used.
[0475] Examples of suitable carriers are ground natural minerals
(for example kaolins, clays, talc, chalk) and ground synthetic
minerals (for example highly disperse silica, silicates).
[0476] Suitable emulsifiers are nonionic and anionic emulsifiers
(for example polyoxyethylene fatty alcohol ethers, alkylsulfonates
and arylsulfonates).
[0477] Examples of dispersants are lignin-sulfite waste liquors and
methylcellulose.
[0478] Suitable surfactants used are alkali metal, alkaline earth
metal and ammonium salts of lignosulfonic acid, naphthalenesulfonic
acid, phenolsulfonic acid, dibutylnaphthalenesulfonic acid,
alkylarylsulfonates, alkyl sulfates, alkylsulfonates, fatty alcohol
sulfates, fatty acids and sulfated fatty alcohol glycol ethers,
furthermore condensates of sulfonated naphthalene and naphthalene
derivatives with formaldehyde, condensates of naphthalene or of
naphthalenesulfonic acid with phenol and formaldehyde,
polyoxyethylene octylphenol ether, ethoxylated isooctylphenol,
octylphenol, nonylphenol, alkylphenol polyglycol ethers,
tributylphenyl polyglycol ether, tristearylphenyl polyglycol ether,
alkylaryl polyether alcohols, alcohol and fatty alcohol ethylene
oxide condensates, ethoxylated castor oil, polyoxyethylene alkyl
ethers, ethoxylated polyoxypropylene, lauryl alcohol polyglycol
ether acetal, sorbitol esters, lignosulfite waste liquors and
methylcellulose.
[0479] Substances which are suitable for the preparation of
directly sprayable solutions, emulsions, pastes or oil dispersions
are mineral oil fractions of medium to high boiling point, such as
kerosene or diesel oil, furthermore coal tar oils and oils of
vegetable or animal origin, aliphatic, cyclic and aromatic
hydrocarbons, for example toluene, xylene, paraffin,
tetrahydronaphthalene, alkylated naphthalenes or their derivatives,
methanol, ethanol, propanol, butanol, cyclohexanol, cyclohexanone,
isophorone, highly polar solvents, for example dimethyl sulfoxide,
N-methylpyrrolidone or water.
[0480] Also anti-freezing agents such as glycerin, ethylene glycol,
propylene glycol and bactericides such as can be added to the
formulation.
[0481] Suitable antifoaming agents are for example antifoaming
agents based on silicon or magnesium stearate.
[0482] Powders, materials for spreading and dustable products can
be prepared by mixing or concomitantly grinding the active
substances with a solid carrier.
[0483] Granules, for example coated granules, impregnated granules
and homogeneous granules, can be prepared by binding the active
compounds to solid carriers. Examples of solid carriers are mineral
earths such as silica gels, silicates, talc, kaolin, attaclay,
limestone, lime, chalk, bole, loess, clay, dolomite, diatomaceous
earth, calcium sulfate, magnesium sulfate, magnesium oxide, ground
synthetic materials, fertilizers, such as, for example, ammonium
sulfate, ammonium phosphate, ammonium nitrate, ureas, and products
of vegetable origin, such as cereal meal, tree bark meal, wood meal
and nutshell meal, cellulose powders and other solid carriers.
[0484] In general, the formulations comprise from 0.01 to 95% by
weight, preferably from 0.1 to 90% by weight, of the active
compound(s). In this case, the active compound(s) are employed in a
purity of from 90% to 100% by weight, preferably 95% to 100% by
weight (according to NMR spectrum).
[0485] The compounds of formula I can be used as such, in the form
of their formulations or the use forms prepared therefrom, for
example in the form of directly sprayable solutions, powders,
suspensions or dispersions, emulsions, oil dispersions, pastes,
dustable products, materials for spreading, or granules, by means
of spraying, atomizing, dusting, spreading or pouring. The use
forms depend entirely on the intended purposes; they are intended
to ensure in each case the finest possible distribution of the
active compound(s) according to the invention.
[0486] Aqueous use forms can be prepared from emulsion
concentrates, pastes or wettable powders (sprayable powders, oil
dispersions) by adding water. To prepare emulsions, pastes or oil
dispersions, the substances, as such or dissolved in an oil or
solvent, can be homogenized in water by means of a wetter,
tackifier, dispersant or emulsifier. However, it is also possible
to prepare concentrates composed of active substance, wetter,
tackifier, dispersant or emulsifier and, if appropriate, solvent or
oil, and such concentrates are suitable for dilution with
water.
[0487] The active compound concentrations in the ready-to-use
preparations can be varied within relatively wide ranges. In
general, they are from 0.0001 to 10%, preferably from 0.01 to 1%
per weight.
[0488] The active compound(s) may also be used successfully in the
ultra-low-volume process (ULV), it being possible to apply
formulations comprising over 95% by weight of active compound, or
even to apply the active compound without additives.
[0489] The following are examples of formulations: 1. Products for
dilution with water for foliar applications.
[0490] A) Water-Soluble Concentrates (SL, LS)
[0491] 10 parts by weight of the active compound(s) are dissolved
in 90 parts by weight of water or a water-soluble solvent. As an
alternative, wetters or other auxiliaries are added. The active
compound(s) dissolves upon dilution with water, whereby a
formulation with 10% (w/w) of active compound(s) is obtained.
[0492] B) Dispersible Concentrates (DC)
[0493] 20 parts by weight of the active compound(s) are dissolved
in 75 parts by weight of cyclohexanone with addition of 10 parts by
weight of a dispersant, for example polyvinylpyrrolidone. Dilution
with water gives a dispersion, whereby a formulation with 20% (w/w)
of active compound(s) is obtained.
[0494] C) Emulsifiable Concentrates (EC)
[0495] 15 parts by weight of the active compound(s) are dissolved
in 75 parts by weight of xylene with addition of calcium
dodecylbenzenesulfonate and castor oil ethoxylate (in each case 5
parts by weight). Dilution with water gives an emulsion, whereby a
formulation with 15% (w/w) of active compound(s) is obtained.
[0496] D) Emulsions (EW, EO, ES)
[0497] 40 parts by weight of the active compound(s) are dissolved
in 35 parts by weight of xylene with addition of calcium
dodecylbenzenesulfonate and castor oil ethoxylate (in each case 5
parts by weight). This mixture is introduced into 30 parts by
weight of water by means of an emulsifier machine (e.g.
Ultraturrax) and made into a homogeneous emulsion. Dilution with
water gives an emulsion, whereby a formulation with 25% (w/w) of
active compound(s) is obtained.
[0498] E) Suspensions (SC, OD, FS)
[0499] In an agitated ball mill, 20 parts by weight of the active
compound(s) are comminuted with addition of 10 parts by weight of
dispersants, wetters and 70 parts by weight of water or of an
organic solvent to give a fine active compound(s) suspension.
Dilution with water gives a stable suspension of the active
compound(s), whereby a formulation with 20% (w/w) of active
compound(s) is obtained.
[0500] F) Water-Dispersible Granules and Water-Soluble Granules
(WG, SG)
[0501] 50 parts by weight of the active compound(s) are ground
finely with addition of 50 parts by weight of dispersants and
wetters and made as water-dispersible or water-soluble granules by
means of technical appliances (for example extrusion, spray tower,
fluidized bed). Dilution with water gives a stable dispersion or
solution of the active compound(s), whereby a formulation with 50%
(w/w) of active compound(s) is obtained.
[0502] G) Water-dispersible powders and water-soluble powders (WP,
SP, WS)
[0503] 75 parts by weight of the active compound(s) are ground in a
rotor-stator mill with addition of 25 parts by weight of
dispersants, wetters and silica gel. Dilution with water gives a
stable dispersion or solution of the active compound(s) whereby a
formulation with 75% (w/w) of active compound(s) is obtained.
[0504] 2. Products to be applied undiluted for foliar
applications.
[0505] H) Dustable Powders (DP, DS)
[0506] 5 parts by weight of the active compound(s) are ground
finely and mixed intimately with 95 parts by weight of finely
divided kaolin. This gives a dustable product having 5% (w/w) of
active compound(s)
[0507] I) Granules (GR, FG, GG, MG)
[0508] 0.5 part by weight of the active compound(s) is ground
finely and associated with 95.5 parts by weight of carriers,
whereby a formulation with 0.5% (w/w) of active compound(s) is
obtained. Current methods are extrusion, spray-drying or the
fluidized bed. This gives granules to be applied undiluted for
foliar use.
[0509] J) ULV Solutions (UL)
[0510] 10 parts by weight of the active compound(s) are dissolved
in 90 parts by weight of an organic solvent, for example xylene.
This gives a product having 10% (w/w) of active compound(s), which
is applied undiluted for foliar use.
[0511] Various types of oils, wetters, adjuvants, herbicides,
fungicides, other pesticides, or bactericides may be added to the
active ingredients, if appropriate just immediately prior to use
(tank mix). These agents usually are admixed with the agents
according to the invention in a weight ratio of 1:10 to 10:1.
[0512] The compounds of formula I are effective through both
contact and ingestion.
[0513] According to a preferred embodiment of the invention, the
compounds of formula I are employed via soil application. Soil
application is especially favorable for use against ants, termites,
crickets, or cockroaches.
[0514] According to another preferred embodiment of the invention,
for use against non crop pests such as ants, termites, wasps,
flies, mosquitoes, crickets, locusts, or cockroaches the compounds
of formula I are prepared into a bait preparation.
[0515] The bait can be a liquid, a solid or a semisolid preparation
(e.g. a gel).
[0516] Compositions of this invention may also contain other active
ingredients, for example fungicides, herbicides, fertilizers such
as ammonium nitrate, urea, potash, and superphosphate,
phytotoxicants and plant growth regulators and safeners. These
additional ingredients may be used sequentially or in combination
with the above-described compositions, if appropriate also added
only immediately prior to use (tank mix). For example, the plant(s)
may be sprayed with a composition of this invention either before
or after being treated with other active ingredients.
[0517] The mixtures according to the invention can be applied to
any and all developmental stages, such as egg, larva, pupa, and
adult. The pests may be controlled by contacting the target pest,
its food supply, habitat, breeding ground or its locus with a
pesticidally effective amount of the inventive mixtures or of
compositions comprising the mixtures.
[0518] "Locus" means a plant, seed, soil, area, material or
environment in which a pest is growing or may grow.
[0519] In general, "pesticidally effective amount" means the amount
of the inventive mixtures or of compositions comprising the
mixtures needed to achieve an observable effect on growth,
including the effects of necrosis, death, retardation, prevention,
and removal, destruction, or otherwise diminishing the occurrence
and activity of the target organism. The pesticidally effective
amount can vary for the various mixtures/compositions used in the
invention. A pesticidally effective amount of the
mixtures/compositions will also vary according to the prevailing
conditions such as desired pesticidal effect and duration, weather,
target species, locus, mode of application, and the like.
[0520] The inventive mixtures or compositions of these mixtures can
also be employed for protecting plants from attack or infestation
by insects, acarids or nematodes comprising contacting a plant, or
soil or water in which the plant is growing.
[0521] In the context of the present invention, the term plant
refers to an entire plant, a part of the plant or the propagation
material of the plant, that is, the seed or the seedling.
[0522] Plants which can be treated with the inventive mixtures
include all genetically modified plants or transgenic plants, e.g.
crops which tolerate the action of herbicides or fungicides or
insecticides owing to breeding, including genetic engineering
methods, or plants which have modified characteristics in
comparison with existing plants, which can be generated for example
by traditional breeding methods and/or the generation of mutants,
or by recombinant procedures.
[0523] Some of the inventive mixtures have systemic action and can
therefore be used for the protection of the plant shoot against
foliar pests as well as for the treatment of the seed and roots
against soil pests. The term seed treatment comprises all suitable
seed treatment techniques known in the art, such as seed dressing,
seed coating, seed dusting, seed soaking and seed pelleting.
[0524] The compounds I and the one or more compound(s) II can be
applied simultaneously, that is jointly or separately, or in
succession, the sequence, in the case of separate application,
generally not having any effect on the result of the control
measures.
[0525] The compounds I and the one or more compound(s) II are
usually applied in a weight ratio of from 500:1 to 1:100,
preferably from 20:1 to 1:50, in particular from 5:1 to 1:20.
Depending on the desired effect, the application rates of the
mixtures according to the invention are from 5 g/ha to 2000 g/ha,
preferably from 50 to 1500 g/ha, in particular from 50 to 750
g/ha.
[0526] The inventive mixtures are also suitable for the protection
of the seed and the seedlings' roots and shoots, preferably the
seeds, against soil pests.
[0527] Conventional seed treatment formulations include for example
flowable concentrates FS, solutions LS, powders for dry treatment
DS, water dispersible powders WS or granules for slurry treatment,
water soluble powders SS and emulsion ES. Application to the seeds
is carried out before sowing, either directly on the seeds.
Preferred are FS formulations.
[0528] In the treatment of seed, the application rates of the
inventive mixture are generally from 0.1 to 10 kg per 100 kg of
seed. The separate or joint application of the compounds I and II
or of the mixtures of the compounds I and II is carried out by
spraying or dusting the seeds, the seedlings, the plants or the
soils before or after sowing of the plants or before or after
emergence of the plants.
[0529] The invention also relates to the propagation products of
plants, and especially the seed comprising, that is, coated with
and/or containing, a mixture as defined above or a composition
containing the mixture of two or more active ingredients or a
mixture of two or more compositions each providing one of the
active ingredients. The seed comprises the inventive mixtures in an
amount of from 0.1 g to 10 kg per 100 kg of seed.
[0530] The inventive mixtures are effective through both contact
(via soil, glass, wall, bed net, carpet, plant parts or animal
parts), and ingestion (bait, or plant part) and through
trophallaxis and transfer.
[0531] Preferred application methods are into water bodies, via
soil, cracks and crevices, pastures, manure piles, sewers, into
water, on floor, wall, or by perimeter spray application and
bait.
[0532] According to another preferred embodiment of the invention,
for use against non crop pests such as ants, termites, wasps,
flies, mosquitoes, crickets, locusts, or cockroaches the inventive
mixtures are prepared into a bait preparation.
[0533] The bait can be a liquid, a solid or a semisolid preparation
(e.g. a gel). The bait employed in the composition is a product
which is sufficiently attractive to incite insects such as ants,
termites, wasps, flies, mosquitoes, crickets etc. or cockroaches to
eat it. This attractant may be chosen from feeding stimulants or
para and/or sex pheromones readily known in the art.
[0534] Methods to control infectious diseases transmitted by
insects (e.g. malaria, dengue and yellow fever, lymphatic
filariasis, and leishmaniasis) with the inventive mixtures and
their respective compositions also comprise treating surfaces of
huts and houses, air spraying and impregnation of curtains, tents,
clothing items, bed nets, tsetse-fly trap or the like. Insecticidal
compositions for application to fibers, fabric, knitgoods,
nonwovens, netting material or foils and tarpaulins preferably
comprise a composition including the inventive mixtures, optionally
a repellent and at least one binder.
[0535] The inventive mixtures and the compositions comprising them
can be used for protecting wooden materials such as trees, board
fences, sleepers, etc. and buildings such as houses, outhouses,
factories, but also construction materials, furniture, leathers,
fibers, vinyl articles, electric wires and cables etc. from ants
and/or termites, and for controlling ants and termites from doing
harm to crops or human being (e.g. when the pests invade into
houses and public facilities).
[0536] In the case of soil treatment or of application to the pests
dwelling place or nest, the quantity of active ingredient ranges
from 0.0001 to 500 g per 100 m.sup.2, preferably from 0.001 to 20 g
per 100 m.sup.2.
[0537] Customary application rates in the protection of materials
are, for example, from 0.01 g to 1000 g of active compound per
m.sup.2 treated material, desirably from 0.1 g to 50 g per
m.sup.2.
[0538] Insecticidal compositions for use in the impregnation of
materials typically contain from 0.001 to 95 weight %, preferably
from 0.1 to 45 weight %, and more preferably from 1 to 25 weight %
of at least one repellent and/or insecticide.
[0539] For use in bait compositions, the typical content of active
ingredient is from 0.0001 weight % to 15 weight %, desirably from
0.001 weight % to 5% weight % of active compound. The composition
used may also comprise other additives such as a solvent of the
active material, a flavoring agent, a preserving agent, a dye or a
bitter agent. Its attractiveness may also be enhanced by a special
color, shape or texture.
[0540] For use in spray compositions, the content of the mixture of
the active ingredients is from 0.001 to 80 weights %, preferably
from 0.01 to 50 weight % and most preferably from 0.01 to 15 weight
%.
[0541] For use in treating crop plants, the rate of application of
the mixture of the active ingredients of this invention may be in
the range of 0.1 g to 4000 g per hectare, desirably from 25 g to
600 g per hectare, more desirably from 50 g to 500 g per
hectare.
[0542] It was also an object of the present invention to provide
mixtures suitable for treating, controlling, preventing and
protecting warm-blooded animals, including humans, and fish against
infestation and infection by pests. Problems that may be
encountered with pest control on or in animals and/or humans are
similar to those described at the outset, namely the need for
reduced dosage rates, and/or enhanced spectrum of activity and/or
combination of know-down activity with prolonged control and/or
resistance management.
[0543] This invention also provides a method for treating,
controlling, preventing and protecting warm-blooded animals,
including humans, and fish against infestation and infection by
pests of the orders Siphonaptera, Hymenoptera, Hemiptera,
Orthoptera, Acarina, Phthiraptera, and Diptera, which comprises
orally, topically or parenterally administering or applying to said
animals a pesticidally effective amount of mixtures according to
the invention.
[0544] The invention also provides a process for the preparation of
a composition for treating, controlling, preventing or protecting a
warm-blooded animal or a fish against infestation or infection by
pests of the Siphonaptera, Hymenoptera, Hemiptera, Orthoptera,
Acarina, Phthiraptera, and Diptera orders which comprises a
pesticidally effective amount of a mixture according to the
invention.
[0545] The above method is particularly useful for controlling and
preventing infestations and infections in warm-blooded animals such
as cattle, sheep, swine, camels, deer, horses, poultry, goats, dogs
and cats as well as humans.
[0546] Infestations in warm-blooded animals and fish including, but
not limited to, lice, biting lice, ticks, nasal bots, keds, biting
flies, muscoid flies, flies, myiasitic fly larvae, chiggers, gnats,
mosquitoes and fleas may be controlled, prevented or eliminated by
the mixtures according to the invention.
[0547] For oral administration to warm-blooded animals, the
mixtures according to the invention may be formulated as animal
feeds, animal feed premixes, animal feed concentrates, pills,
solutions, pastes, suspensions, drenches, gels, tablets, boluses
and capsules. In addition, the mixtures according to the invention
may be administered to the animals in their drinking water. For
oral administration, the dosage form chosen should provide the
animal with 0.01 mg/kg to 100 mg/kg of animal body weight per day
of the mixture.
[0548] Alternatively, the mixtures according to the invention may
be administered to animals parenterally, for example, by
intraruminal, intramuscular, intravenous or subcutaneous injection.
The mixtures according to the invention may be dispersed or
dissolved in a physiologically acceptable carrier for subcutaneous
injection. Alternatively, the mixtures according to the invention
may be formulated into an implant for subcutaneous administration.
In addition the mixtures according to the invention may be
transdermally administered to animals. For parenteral
administration, the dosage form chosen should provide the animal
with 0.01 mg/kg to 100 mg/kg of animal body weight per day of the
mixture.
[0549] The mixtures according to the invention may also be applied
topically to the animals in the form of dips, dusts, powders,
collars, medallions, sprays, spot-on and pour-on formulations. For
topical application, dips and sprays usually contain 0.5 ppm to
5,000 ppm and preferably 1 ppm to 3,000 ppm of the inventive
compounds. In addition, the mixtures according to the invention may
be formulated as ear tags for animals, particularly quadrupeds such
as cattle and sheep.
[0550] The pesticidal action of the compounds and the mixtures can
be demonstrated by the experiments below:
[0551] Southern armyworm (Spodoptera eridania), 2nd instar
larvae
[0552] The active compounds are formulated for testing the activity
against insects and arachnids as a 10.000 ppm solution in a mixture
of 35% acetone and water, which is diluted with water, if
needed.
[0553] A Sieva lima bean leaf expanded to 7-8 cm in length is
dipped in the test solution with agitation for 3 seconds and
allowed to dry in a hood. The leaf is then placed in a 100.times.10
mm petri dish containing a damp filter paper on the bottom and ten
2nd instar caterpillars. At 5 days, observations are made of
mortality, reduced feeding, or any interference with normal
molting.
[0554] Green Peach Aphid (Myzus persicae)
[0555] The active compounds are formulated in 50:50 acetone:water
and 100 ppm Kinetic.TM. surfactant.
[0556] Pepper plants in the 2.sup.nd leaf-pair stage (variety
`California Wonder`) are infested with approximately 40
laboratory-reared aphids by placing infested leaf sections on top
of the test plants. The leaf sections are removed after 24 hr. The
leaves of the intact plants are dipped into gradient solutions of
the test compound and allowed to dry. Test plants are maintained
under fluorescent light (24 hour photoperiod) at about 25.degree.
C. and 20-40% relative humidity. Aphid mortality on the treated
plants, relative to mortality on check plants, is determined after
5 days.
[0557] Activity Against Tobacco Budworm (Heliothis virescens)
[0558] Two-leaf cotton plants are utilized for bioassays. Excised
plant leaves are dipped into 1:1 acetone/water dilutions of the
active compounds. After the leaves have dried, they are
individually placed onto water-moistened filter paper on the
bottoms of Petri dishes. Each dish is infested with 5-7 larvae and
covered with a lid. Each treatment dilution is replicated 4 times.
Test dishes are held at approximately 27.degree. C. and 60%
humidity. Numbers of live and morbid larvae are assessed in each
dish at 5 days after treatment application, and percent mortality
is calculated.
[0559] Activity against Argentine ant, harvester ant, acrobat ant,
carpenter ant, fire ant, house fly, stable fly, flesh fly,
yellow-fever mosquito, house mosquito, malaria mosquito, German
cockroach, cat flea, and brown dog tick via glass contact
[0560] Glass vials (20 ml scintillation vials) are treated with 0.5
ml of a solution of active ingredient in acetone. Each vial is
rolled uncapped for ca. 10 minutes to allow the a.i. to completely
coat the vial and to allow for full drying of the acetone. Insects
or ticks are placed into each vial. The vials are kept at
22.degree. C. and are observed for treatment effects at various
time intervals.
[0561] To determine if an insecticidal mixture is synergistic,
Limpel's formula is used:
E=X+Y-XY/100
[0562] E=Expected % mortality of the mixture
[0563] X=% mortality of compound X, as measured independently
[0564] Y=% mortality of compound Y, as measured independently
[0565] Synergism is evident if the % observed mortality for the
mixture is greater than the % expected mortality.
[0566] The test results show that the mixtures according to the
invention show a considerable enhanced activity demonstrating
synergism compared to the calculated sum of the single
activities.
* * * * *