U.S. patent application number 13/061993 was filed with the patent office on 2011-07-07 for conditioning composition for hair.
Invention is credited to Mustafa Grit, Michael Molenda, Ilka Tietjen.
Application Number | 20110165103 13/061993 |
Document ID | / |
Family ID | 40340866 |
Filed Date | 2011-07-07 |
United States Patent
Application |
20110165103 |
Kind Code |
A1 |
Molenda; Michael ; et
al. |
July 7, 2011 |
CONDITIONING COMPOSITION FOR HAIR
Abstract
The present invention is related to an aqueous conditioning
composition for hair comprising at least one alkyl ester/amido
alkyl amine or alkyl ester/amido alkyl quaternary amine and an
aqueous emulsion of divinyldimethicone/dimethicone copolymer with
an internal phase viscosity of more than 1.times.10.sup.8
mm.sup.2/s measured at 0.01 Hz and at approximately 25.degree.
C.
Inventors: |
Molenda; Michael;
(Frankfurt, DE) ; Tietjen; Ilka; (Ilvesheim,
DE) ; Grit; Mustafa; (Gernsheim, DE) |
Family ID: |
40340866 |
Appl. No.: |
13/061993 |
Filed: |
September 2, 2009 |
PCT Filed: |
September 2, 2009 |
PCT NO: |
PCT/EP2009/006342 |
371 Date: |
March 23, 2011 |
Current U.S.
Class: |
424/70.9 ;
132/202; 424/70.12; 8/405 |
Current CPC
Class: |
A61Q 5/12 20130101; A61K
8/41 20130101; A61K 8/34 20130101; A61Q 5/065 20130101; A61K 8/895
20130101; A61K 8/416 20130101; A61K 8/342 20130101; A61K 8/355
20130101; A61Q 5/004 20130101; A61K 8/42 20130101; A61Q 5/02
20130101 |
Class at
Publication: |
424/70.9 ;
424/70.12; 8/405; 132/202 |
International
Class: |
A61K 8/92 20060101
A61K008/92; A61K 8/891 20060101 A61K008/891; A61K 8/895 20060101
A61K008/895; A61Q 5/12 20060101 A61Q005/12; A61Q 5/02 20060101
A61Q005/02; A61Q 17/04 20060101 A61Q017/04; A61Q 5/10 20060101
A61Q005/10 |
Foreign Application Data
Date |
Code |
Application Number |
Sep 5, 2008 |
EP |
08015672.2 |
Claims
1. Aqueous conditioning composition for hair comprising at least
one at least one compound according to general structure
R.sub.1-A-R.sub.2--B wherein R.sub.1 is a saturated or unsaturated,
straight or branched alkyl group with 8 to 24 C atoms, R.sub.2 is a
straight or branched alkyl group with 1 to 4 C atoms, A is a group
selected from O, ##STR00011## and B is selected from ##STR00012##
wherein R.sub.3 and R.sub.4 are the same or different is H or an
alkyl with 1 to 4 C atoms, hydroxyl alkyl with 1 to 4 C atoms and
di hydroxyl alkyl with 2 to 4 C atoms, ##STR00013## R.sub.5, and
R.sub.6 are the same or different, an alkyl with 1 to 4 C atoms,
hydroxyl alkyl with 1 to 4 C atoms and di hydroxyl alkyl with 2 to
4 C atoms, R.sub.7 is an alkyl with 1 to 4 C atoms, hydroxyl alkyl
with 1 to 4 C atoms or di hydroxyl alkyl with 2 to 4 C atoms and
--R.sub.2-A-R.sub.1 wherein R.sub.1, A and R.sub.2 have the above
meaning and X is chloride, bromide, methosulfate and an aqueous
emulsion of divinyldimethicone/dimethicone copolymer with an
internal phase viscosity of more than 1.times.10.sup.8 mm.sup.2/s
measured at 0.01 Hz at 25.degree. C.
2. Composition according to claim 1, wherein aqueous emulsion of
divinyldimethicone/dimethicone copolymer has a viscosity of higher
than 1.1.times.10.sup.8 mm.sup.2/s, and more preferably higher than
1.2.times.10.sup.8 mm.sup.2/s measure at 0.01 Hz at 25.degree.
C.
3. Composition according to claim 1, wherein amine and ammonium
compounds are present at a total concentration in the range of 0.01
to 20% by weight and calculated to total composition,
divinyldimethicone/dimethicone copolymer is comprised at a
concentration of 0.01 to 10% by weight, calculated to total
composition as Divinyldimethicone/dimethicone copolymer.
4. Composition according to claim 1, wherein at least one
conditioning agent is selected from oily substances, nonionic
substances, cationic amphiphilic ingredients and cationic polymers
or their mixtures.
5. Composition according to claim 4, wherein at least one
conditioning agent is selected from cationic surfactants according
to general formula ##STR00014## where R.sub.10 is a saturated or
unsaturated, branched or non-branched alkyl chain with 8-24 C atoms
and R.sub.11 is unsaturated or saturated, branched or non-branched
alkyl chain with 1-24 C atoms and R.sub.12 and R.sub.13 are lower
alkyl chain with 1 to 4 carbon atoms which may be substituted with
one or more hydroxyl groups, and X is anion such as chloride,
bromide, and methosulfate, cationic polymers and a silicone
oil.
6. Composition according to claim 1, comprising at least one
compound according to the formula ##STR00015## where n is a number
between 1 and 10, and/or at least one UV filter and/or at least one
polyphenol.
7. Composition according to claim 1, comprising at least one
organic solvent.
8. Composition according to claim 1, comprising at least one direct
dye.
9. Composition according to claim 1, wherein the compositions are
cleansing and conditioning composition (shampoo) and comprising at
least one surfactant selected from anionic, nonionic and amphoteric
or zwitterionic surfactants at a concentration of 5 to 50% by
weight calculated to the total composition.
10. Composition according to claim 1, comprising at least one
anionic surfactant and/or at least one non-ionic surfactant and/or
at least one amphoteric surfactant.
11. Composition according to claim 1, comprising at least one
compound according to general formula ##STR00016## wherein R.sub.14
is straight or branched, saturated or unsaturated alkyl chain with
4 to 24 C atoms, and R.sub.15 is H, or straight or branched,
saturated or unsaturated alkyl chain with 4 to 24 C atoms.
12. Composition according to claim 1, wherein it has a pH in the
range of 2.0 to 8.0.
13. Composition according to claim 1, wherein an emulsion and
comprises at least one fatty alcohol according to general formula
R.sub.20--OH where R.sub.20 is a saturated or unsaturated, branched
or non-branched fatty acyl chain with 8-24 C atoms.
14. (canceled)
15. Method of conditioning hair wherein a composition according to
claim 1 is applied onto hair and optionally rinsed off from hair
after a processing time of 1 to 30 min.
Description
[0001] The present invention is related to an aqueous conditioning
composition for hair comprising at least one alkyl ester/amido
alkyl amine or alkyl ester/amido alkyl quaternary amine and an
aqueous emulsion of divinyldimethicone/dimethicone copolymer.
Conditioning composition of the present invention can be in the
form of a shampoo, cleansing--conditioning composition, or in the
form of a conditioner used after washing hair with cleansing
compositions.
[0002] Conditioning compositions for hair have been known for ages.
Various types of conditioners are available on the market and new
ones are being introduced almost every day. Although this extremely
developed conditioner market for keratin fibers and especially
human hair, there is still need for improvements.
[0003] Generally, use of divinyldimethicone/dimethicone copolymer
type of compounds is known in the cosmetic art. For example EP
1093805 A1, EP 1093806 A1, EP 1093807 A1, EP 1093808 A1, EP 1093809
A1, and EP 1108416 A1 disclose compositions for keratin fibres
comprising divinyldimethicone/dimethicone copolymer with an
internal viscosity up to 1.times.10.sup.8 mm.sup.2/s and an
additional ingredient.
[0004] EP 874 017 A2 discloses process for producing
divinyldimethicone/dimethicone copolymer.
[0005] In addition from number of patent or non-patent literature
it has generally been known to use silicone compounds of various
chemical natures in hair conditioning and also hair cleansing
compositions. Recently, in EP 1676 567 it has been proposed to use
in shampoo compositions highly polymerised silicone compounds
existing as dispersed particles having certain average diameter.
Moreover, EP 1862160 discloses cleansing compositions based on
cationic polymer and dimethylsiloxane.
[0006] US 2003/0147822 A1 discloses compositions comprising alkyl
ether alkyl amine and an acid for hair conditioning which imparts
hair smoothness during wetting and after drying. The document does
not disclose a composition with an emulsion comprising high
viscosity silicone compound.
[0007] Consumers with damaged hair often are not satisfied with
hair conditioning effect of known conditioners because in case they
chose a rich conditioner the hair is afterwards does not have any
volume and/or body and after a lighter conditioner use hair is not
conditioned enough so that not combable, does not appear shiny, not
manageable, etc. In other words for consumers with damaged hair
which is not homogeneous in degree of damage, it is very hard to
find a correct conditioner. Therefore, there is a great need for a
conditioner which homogeneously conditions damaged and healthy
hair.
[0008] The objective of the current invention is to provide
conditioning compositions for hair which conditions damaged and
healthy hair homogeneously, so that hair is combable, and other
properties of hair are maintained or also improved such as shine,
elasticity, volume, body and manageability.
[0009] It has surprisingly been found out that a composition
comprising at least one alkyl ether alkyl amine or alkyl ether
alkyl quaternary amine or ester/amido alkyl amine or alkyl
ester/amido alkyl quaternary ammonium compound and an aqueous
emulsion of divinyldimethicone/dimethicone copolymer with an
internal viscosity of higher than 1.times.10.sup.8 mm.sup.2/s
conditions damaged and healthy hair excellently homogeneously so
that hair becomes combabale, has shine, elasticity, volume, body
and manageable.
[0010] Accordingly, the first object of the present invention is a
conditioning composition for hair comprising at least one compound
according to general structure
R.sub.1-A-R.sub.2--B
wherein R.sub.1 is a saturated or unsaturated, straight or branched
alkyl group with 8 to 24 C atoms, R.sub.2 is a straight or branched
alkyl group with 1 to 4 C atoms, A is a group selected from O,
##STR00001##
and B is selected from
##STR00002##
wherein R.sub.3 and R.sub.4 are the same or different is H or an
alkyl with 1 to 4 C atoms, hydroxyl alkyl with 1 to 4 C atoms and
di hydroxyl alkyl with 2 to 4 C atoms,
##STR00003##
R.sub.5, and R.sub.6 are the same or different, an alkyl with 1 to
4 C atoms, hydroxyl alkyl with 1 to 4 C atoms and di hydroxyl alkyl
with 2 to 4 C atoms, R.sub.7 is an alkyl with 1 to 4 C atoms,
hydroxyl alkyl with 1 to 4 C atoms or di hydroxyl alkyl with 2 to 4
C atoms and
--R.sub.2-A-R.sub.1
wherein R.sub.1, A and R.sub.2 have the above meaning and X is
chloride, bromide, methosulfate and an aqueous emulsion of
divinyldimethicone/dimethicone copolymer with an internal phase
viscosity of more than 1.times.10.sup.8 mm.sup.2/s measured at 0.01
Hz and at approximately 25.degree. C.
[0011] Further object of the present invention is the use of the
composition of the present invention to condition hair and
especially to keep or improve shine, volume, body, elasticity and
manageability of hair.
[0012] Still further object of the present invention is the method
of conditioning hair wherein hair is treated with at least one
composition as mentioned above and optionally rinsed off from hair
after a processing time of 1 to 30 min.
[0013] Compositions of the present invention are suitable for
either rinse off or leave in applications. Further object of the
present invention is process for conditioning hair wherein a
composition according to present invention is applied onto hair and
not rinsed off.
[0014] The compositions of the present invention can be either a
conditioning--cleansing composition--shampoo--or a conditioning
composition typically used after use of cleansing compositions.
[0015] Compositions of the present invention comprise at least one
alkyl ether alkyl amine or alkyl ether alkyl quaternary amine or
alkyl ester/amide alkyl amine or alkyl ester/amide alkyl quaternary
amine according to the above general structures. In the preferred
embodiment of the present invention, R.sub.1 is saturated or
unsaturated, straight or branched alkyl group with 10 to 24C atoms,
more preferably 12 to 22 C atoms and R.sub.2 is straight or
branched alkyl group with 1 to 4 C atoms, A, B, R.sub.3 to R.sub.7
are same as above. Non-limiting suitable examples are
stearyloxypropyl amine, palmityloxypropyl amine,
stearyloxypropyldimethyl amine, stearyloxypropyldiethyl amine,
stearyloxyethylyldimethyl amine, stearyloxyethyl amine,
myristyloxypropyl amine, myristyloxypropyldimethyl amine,
palmitamidopropyl amine, palmitamidopropyl methylamine,
palmitamidopropyl diethylamine, palmitamidopropyl dibutylamine,
palmitamidopropyl buylamine, palmitamidopropyl dipropylamine,
palmitamidopropyl propylamine, palmitamidopropyl
dihydroxyethylamine, palmitamidopropyl hydroxyethylamine,
palmitamidopropyl dihydroxypropylamine, palmitamidopropyl
hydroxypropylamine, lauramidopropyl amine, lauramidopropyl
methylamine, lauramidopropyl diethylamine, lauramidopropyl
dibutylamine, lauramidopropyl buylamine, lauramidopropyl
dipropylamine, lauramidopropyl propylamine, lauramidopropyl
dihydroxyethylamine, lauramidopropyl hydroxyethylamine,
lauramidopropyl dihydroxypropylamine, lauramidopropyl
hydroxypropylamine, stearamidopropyl amine, stearamidopropyl
methylamine, stearamidopropyl diethylamine, stearamidopropyl
dibutylamine, stearamidopropyl butylamine, stearamidopropyl
dipropylamine, behenamidopropyl propylamine, behenamidopropyl
dihydroxyethylamine, behenamidopropyl hydroxyethylamine,
behenamidopropyl dihydroxypropylamine, behenamidopropyl
hydroxypropylamine, behenamidopropyl amine, behenamidopropyl
methylamine, behenamidopropyl diethylamine, behenamidopropyl
dibutylamine, behenamidopropyl butylamine, behenamidopropyl
dipropylamine, behenamidopropyl propylamine, behenamidopropyl
dihydroxyethylamine, behenamidopropyl hydroxyethylamine,
behenamidopropyl dihydroxypropylamine, behenamidopropyl
hydroxypropylamine, dipalmitamidopropyl methylamine,
dipalmitamidopropyl ethylamine, dipalmitamidopropyl butylamine,
dipalmitamidopropyl propylamine, dipalmitamidopropyl
hydroxyethylamine, dipalmitamidopropyl hydroxypropylamine,
dilauramidopropyl amine, dilauramidopropyl methylamine,
dilauramidopropyl buylamine, dilauramidopropyl hydroxyethylamine,
dilauramidopropyl hydroxypropylamine, distearamidopropyl amine,
distearamidopropyl methylamine, dibehenamidopropyl propylamine,
dibehenamidopropyl hydroxyethylamine, palmitoamidopropyl trimethyl
ammonium chloride, stearamidopropyl trimethylammonium chloride,
behenamidopropyl tri hydroxyethalmonium chloride,
distearylamidopropyl dimethyl ammonium chloride,
dicetylamidodihydroxyethyl ammonium chloride, palmitoylpropyl
amine, palmitoylpropyl methylamine, palmitoylpropyl diethylamine,
palmitoylpropyl dibutylamine, palmitoylpropyl buylamine,
palmitoylpropyl dipropylamine, palmitoylpropyl propylamine,
palmitoylpropyl dihydroxyethylamine, palmitoylpropyl
hydroxyethylamine, palmitoylpropyl dihydroxypropylamine,
palmitoylpropyl hydroxypropylamine, myristoylpropyl amine,
myristoylpropyl methylamine, myristoylpropyl diethylamine,
myristoylpropyl dibutylamine, myristoylpropyl buylamine,
myristoylpropyl dipropylamine, myristoylpropyl propylamine,
myristoylpropyl dihydroxyethylamine, myristoylpropyl
hydroxyethylamine, myristoylpropyl dihydroxypropylamine,
myristoylpropyl hydroxypropylamine, stearoylpropyl amine,
stearoylpropyl methylamine, stearoylpropyl diethylamine,
stearoylpropyl dibutylamine, stearoylpropyl butylamine,
stearoylpropyl dipropylamine, behenylpropyl propylamine,
behenylpropyl dihydroxyethylamine, behenylpropyl hydroxyethylamine,
behenylpropyl dihydroxypropylamine, behenylpropyl
hydroxypropylamine, behenylpropyl amine, behenylpropyl methylamine,
behenylpropyl diethylamine, behenylpropyl dibutylamine,
behenylpropyl butylamine, behenylpropyl dipropylamine,
behenylpropyl propylamine, behenylpropyl dihydroxyethylamine,
behenylpropyl hydroxyethylamine, behenylpropyl
dihydroxypropylamine, behenylpropyl hydroxypropylamine,
dipalmitoylpropyl methylamine, dipalmitoylpropyl ethylamine,
dipalmitylpropyl butylamine, dipalmitylpropyl propylamine,
dipalmitylpropyl hydroxyethylamine, dipalmitylpropyl
hydroxypropylamine, dilauroylpropyl amine, dilauroylpropyl
methylamine, dilauroylpropyl buylamine, dilauroylpropyl
hydroxyethylamine, dilauroylpropyl hydroxypropylamine,
distearylpropyl amine, distearylpropyl methylamine, dibehenylpropyl
propylamine, dibehenylpropyl hydroxyethylamine, palmitylpropyl
trimethyl ammonium chloride, stearylpropyl trimethylammonium
chloride, behenylpropyl tri hydroxyethalmonium chloride,
distearylpropyl dimethyl ammonium chloride, dicetyldihydroxyethyl
ammonium chloride, dioleoylethylhydroxyethylmonium methosulfate,
and dicocoylethylhydroxyethylmonium methosulfate.
[0016] Concentration of at least one alkyl ester/amide alkyl amine
or alkyl ester/amide alkyl quaternary amine according to the above
general structure is in the range of 0.01 to 20%, preferably 0.02
to 15%, more preferably 0.05 to 10% and most preferably 0.1 to 7.5%
and in particular 0.25 to 5% by weight calculated to total
composition.
[0017] Composition of the present invention comprise aqueous
emulsion of divinyldimethicone/dimethicone copolymer with a
viscosity of higher than 1.times.10.sup.8 mm.sup.2/s, preferably
higher than 1.1.times.10.sup.8 mm.sup.2/s, and more preferably
higher than 1.2.times.10.sup.8 mm.sup.2/s measured at 0.01 Hz and
at approximately 25.degree. C. Divinyldimethicone/dimethicone
copolymer is comprised in compositions of the present invention at
a concentration of 0.01 to 10% by weight, preferably 0.02 to 7.5%,
more preferably 0.05 to 5% by weight and most preferably 0.1 to 4%
by weight calculated to total composition as
Divinyldimethicone/dimethicone copolymer.
[0018] In a preferred embodiment of the present invention, aqueous
divinyldimethicone/dimethicone copolymer emulsion comprises
non-ionic surfactants and dispersed droplet has an average droplet
size of smaller than 0.6 .mu.m. Suitable
divinyldimethicone/dimethicone copolymer emulsion with an internal
phase viscosity at 0.01 Hz and at approximately 25.degree. more
than 1.2.times.10.sup.8 is commercially available from Dow Corning
under the trade name Dow Corning HMW 2220. The non-ionic emulsion
comprises C12-13 Pareth-23 and C12-13 Pareth-3 as non-ionic
emulsifiers.
[0019] The composition of the present invention comprises
additionally other hair-conditioning agents in any type of
composition. Conditioning agents can be selected from oily
substances, non-ionic substances, other cationic amphiphilic
ingredients, cationic polymers or their mixtures.
[0020] Oily substances are selected from such as silicone oils,
eithervolatile or non-volatile, natural and synthetic oils. Among
silicone oils those can be added to the compositions include
dimethicone, dimethiconol, polydimethylsiloxane, DC fluid ranges
from Dow Corning, natural oils such as olive oil, almond oil,
avocado oil, wheatgerm oil, ricinus oil and the synthetic oils,
such as mineral oil, isopropyl myristate, palmitate, stearate and
isostearate, oleyl oleate, isocetyl stearate, hexyl laurate,
dibutyl adipate, dioctyl adipate, myristyl myristate and oleyl
erucate. Additional oily substances are selected from arylated
silicones. Non-limiting suitable examples are phenyl methicone,
phenyl trimethicone, diphenyl dimethicone, diphenylsiloxy phenyl
trimethicone, tetramethyl tetraphenyl trisiloxane, triphenyl
trimethicone, and trimethyl pentaphenyl trisiloxane.
[0021] Concentration of one or more oily substances is in the range
of 0.01 to 10%, preferably 0.05 to 7.5%, more preferably 0.1 to 5
and most preferably 0.1 to 3% by weight calculated to total
composition. The concentrations referred here are total
concentration of total concentration of all oily substances may be
present in the composition.
[0022] Non-ionic conditioning agents may be polyols such as
glycerin, glycol and derivatives, polyethyleneglycoles known with
trade names Carbowax PEG from Union Carbide and Polyox WSR range
from Amerchol, polyglycerin, polyethyleneglycol mono or di fatty
acid esters having general formula
R.sub.8CO(OCH.sub.2CH.sub.2).sub.nOH or
R.sub.8CO(OCH.sub.2CH.sub.2).sub.nOOCR.sub.9
where R.sub.8 and R.sub.9 are independent from each other
saturated, unsaturated or branched or non-branched alkyl chain with
7 to 21 C atoms and n is typically 2-100.
[0023] In one of the preferred from of the present invention,
conditioning compositions comprise at least one cationic polymer as
conditioning agent. Suitable cationic polymers are those of best
known with their CTFA category name Polyquaternium. Typical
examples of those are Polyquaternium 1, Polyquaternium 2,
Polyquaternium 4, Polyquaternium 5, Polyquaternium 6,
Polyquaternium 7, Polyquaternium 8, Polyquaternium 9,
Polyquaternium 10, Polyquaternium 11, Polyquaternium 12,
Polyquaternium 13, Polyquaternium 14, Polyquaternium 15,
Polyquaternium 16, Polyquaternium 17, Polyquaternium 18,
Polyquaternium 19, Polyquaternium 20, Polyquaternium 22,
Polyquaternium 24, Polyquaternium 27, Polyquaternium 28,
Polyquaternium 29, Polyquaternium 30, Polyquaternium 31,
Polyquaternium 32, Polyquaternium 33, Polyquaternium 34,
Polyquaternium 35 and Polyquaternium 36, Polyquaternium-37,
Polyquaternium 39, Polyquaternium 42, Polyquaternium 43,
Polyquaternium 44, Polyquaternium 45, Polyquaternium 46,
Polyquaternium 47, Polyquaternium 48, Polyquaternium-49,
Polyquaternium 50, Polyquaternium 51, Polyquaternium 52,
Polyquaternium 53, Polyquaternium 54, Polyquaternium 55,
Polyquaternium 56, Polyquaternium 57, Polyquaternium 58,
Polyquaternium 59, Polyquaternium 60, Polyquaternium 61,
Polyquaternium 62, Polyquaternium 63, Polyquaternium 64,
Polyquaternium 65, Polyquaternium 66, Polyquaternium 67,
Polyquaternium 68, Polyquaternium 69, Polyquaternium-70,
Polyquaternium 71, Polyquaternium 72, Polyquaternium 73,
Polyquaternium 74, Polyquaternium 75, Polyquaternium 76,
Polyquaternium 77, Polyquaternium 78, Polyquaternium-79,
Polyquaternium 80, Polyquaternium 81, Polyquaternium 82,
Polyquaternium 83, Polyquaternium 84, Polyquaternium 85,
Polyquaternium 86 and Polyquaternium 87 as well as silicone
quaternium-1, silicone quaternium-2, silicone quaternium-2
panthenol succinate, silicone quaternium-3, silicone quaternium-4,
silicone quaternium-5, silicone quaternium-6, silicone
quaternium-7, silicone quaternium-8, silicone quaternium-9,
silicone quaternium-10, silicone quaternium-11, silicone
quaternium-12, silicone quaternium-15, silicone quaternium-16,
silicone quaternium-16/Glycidoxy Dimethicone Crosspolymer, silicone
quaternium-17, silicone quaternium-18, silicone quaternium-20 and
silicone quaternium-21.
[0024] As well those polymers known with their CTFA category name
Quaternium are suitable. Those are for example Quaternium-8,
Quaternium-14, Quaternium-15, Quaternium-18, Quaternium-22,
Quaternium-24, Quaternium-26, Quaternium-27, Quaternium-30,
Quaternium-33, Quaternium-53, Quaternium-60, Quaternium-61,
Quaternium-72, Quaternium-78, Quaternium-80, Quaternium-81,
Quaternium-82, Quaternium-83 and Quaternium-84.
[0025] It has further been found out that especially those of
cationic cellulose type polymers known as Polymer JR type from
Amerchol such as Polyquaternium 10 or cationic galactomannans such
as cationic guar gum known with trade name Jaguar from
Rhone-Poulenc which are chemically for example Guar hydroxypropyl
trimonium chloride and cationic tara gum an its derivatives known
with INCI name Caesalpinia spinosa hydroxypropyltrimonium chloride,
are preferred ones. Furthermore, chitosan and chitin can also be
included in the compositions as cationic natural polymers. In this
context reference is also made to the cationic polymers disclosed
in DE 25 21 960, 28 11 010, 30 44 738 and 32 17 059, as well as to
the products described in EP-A 337 354 on pages 3 to 7. It is also
possible to use mixtures of various cationic polymers.
[0026] The most preferred cationic polymers are those of cationic
cellulose derivatives, cationic guar gum derivatives, cationic
Caesalpinia spinosa gum derivatives, polyquaternium 6,
polyquaternium 7, polyquaternium 67 and polyquaternium 70.
[0027] The cationic polymers also include the quaternized products
of graft polymers from organopolysiloxanes and polyethyl oxazolines
described in EP-A 524 612 and EP-A 640 643.
[0028] Conditioning compositions of the present invention can
comprise additionally one or more cationic surfactant(s) as
conditioner presented with the general formula
##STR00004##
where R.sub.10 is a saturated or unsaturated, branched or
non-branched alkyl chain with 8-24 C atoms and R.sub.11 is
unsaturated or saturated, branched or non-branched alkyl chain with
1-24 C atoms and R.sub.12 and R.sub.13 are lower alkyl chain with 1
to 4 carbon atoms which may be substituted with one or more
hydroxyl groups, and X is anion such as chloride, bromide,
methosulfate.
[0029] Typical examples of those ingredients are cetyltrimethyl
ammonium chloride, steartrimonium chloride, behentrimonium
chloride, myristyltrimethyl ammonium chloride, distearyldimethyl
ammonium chloride, and dibehenyldimethyl ammonium chloride. The
others known in the textbooks are included herewith by
reference.
[0030] The compositions according to the invention may also
comprise further conditioning substances such as protein
hydrolyzates and polypeptides, e.g., keratin hydrolyzates, collagen
hydrolyzates of the type "Nutrilan.sup.R" or elastin hydrolyzates,
as well as also in particular plant protein hydrolyzates,
optionally, cationized protein hydrolyzates, e.g.,
"Gluadin.sup.R".
[0031] Typical concentration range for any of those conditioners of
cationic polymers, silicon oil and derivatives and cationic
surfactants can be 0.01-10% by weight, preferably 0.01-7.5% by
weight, more preferably 0.05-5% and most preferably 0.1-3% by
weight calculated to the total composition. It should be noted that
especially non-cleansing conditioning type of the products contain
higher concentrations of the above mentioned concentrations of the
cationic surfactants which at the same time if desired can be
emulsifying agent. In cleansing and conditioning type of
preparations, concentration of cationic surfactants is lower.
[0032] Composition of the present invention can preferably comprise
at least one polyphenol. With the word polyphenol it is meant that
an organic molecule with at least 2 hydroxyl groups in its
molecule.
[0033] In the preferred from of the invention, at least one
polyphenol or mixture of polyhenols is included into compositions
of the present invention from a natural plant extract. In principal
any natural plant extract rich of polyphenols is suitable within
the meaning of the present invention. Within the meaning of the
present invention the extracts are liquid extracts and prepared by
mixing plant parts such as leaves, fruits, blossoms and roots with
a solvent such as water, alcohol, propyleneglycol or mixture of
more than one solvent and incubating for certain period of time and
filtrating the undissolved plant parts. Suitable aqueous (e.g.
steam-distilled) alcoholic or hydro-alcoholic plant extracts known
per se are in particular aloe, pineapple, artichoke, arnica,
avocado, valerian, bamboo, henbane, birch, stinging nettle,
echinacea, ivy, wild angelica, gentian, ferns, pine needles, silver
weed, ginseng, broom, oat, rose hip, hamamelis, hay flowers,
elderberry, hop, coltsfoot, currants, chamomile, carrots,
chestnuts, clover, burr root, cocoanut, cornflower, lime blossom,
lily of the valley, marine algae, balm, mistletoe, passion flower,
ratanhia, marigold, rosemary, horse chestnut, pink hawthorn, sage,
horsetail, yarrow, primrose, nettle, thyme, walnut, wine leaves,
white hawthorn, etc. Suitable trade products are, for example, the
various "Extrapon.RTM." products, "Herbasol.sup.R",
"Sedaplant.sup.R" and "Hexaplant.sup.R". Extracts and the
preparation thereof are also described in "Hagers Handbuch der
pharmazeutischen Praxis", 4.sup.th Ed. Preferred plant extracts are
prepared from Vitis vinifera, Malus domestica, Camelia sinensis,
Juglans regia Ribes Uva-Crispa, Ribes nigrum, Ribes rubrum and
Punica granatum. The above mentioned extracts may also be available
in the powder form and such are also suitable within the meaning of
the present invention.
[0034] The polyphenol comprising extracts are included into the
compositions of the present invention at a concentration of 0.001
to 10%, preferably0.005 to 7.5%, more preferably 0.01 to 5% and
most preferably 0.05 to 2.5% by weight, calculated to total
composition based on dry matter of the extract.
[0035] Further in preferred embodiment of the present invention,
compositions comprise at least one UV filter and at least one
ubichinone of the following formula
##STR00005##
where n is a number between 1 and 10. It should be noted that the
compositions of the present invention can certainly comprise more
than one ubichinone. Preferred ubichinones are the ones where n is
a number between 6 and 10 and especially preferred is Ubichinone 50
where n is 10, also known as Coenzyme Q10. Concentration ubichinone
of the above formula in the compositions is from 0.0001 to 1%,
preferably from 0.0002 to 0.75%, more preferably from 0.0002 to
0.5% and most preferably from 0.0005 to 0.5% by weight, calculated
to total composition.
[0036] Compositions of the present invention preferably comprise at
least one UV filter. Principally any substance known as UV filter
is suitable for the compositions of the present invention.
Non-limiting examples are 4-Aminobenzoic acid and the esters and
salts thereof, 2-phenyl benzimidazole-5-sulfonic acid and the
alkali and amine salts thereof, 4-dimethyl aminobenzoic acid and
the esters and salts thereof, cinnamic acid and the esters and
salts thereof, 4-methoxycinnamic acid and the esters and salts
thereof, salicylic acid and the esters and salts thereof,
2,4-dihydroxybenzophenone, 2,2',4,4'-tetrahydroxy-benzophenone,
2-hydroxy-4-methoxybenzophenone and its 5-sulfonic acid or the
sodium salt thereof, 2,2'-dihydroxy-4,4'-dimethoxybenzophenone,
2-hydroxy-5-chlorobenzophenone,
2,2'-dihydroxy-4-methoxybenzophenone,
2,2'-dihydroxy-4,4'-dimethoxy-5,5'-disulfobenzo-phenone or the
sodium salt thereof, 2-hydroxy-4-octyloxybenzophenone,
2-hydroxy-4-methoxy-4'-methylbenzophenone, 3-benzyl-idenecampher,
3-(4'-sulfo)-benzyl-idenebornane-2-one and the salts thereof,
3-(4'-methyl benzylidene)-DL-campher, and/or polysilicone-15. Above
mentioned UV filters are those oil and water soluble ones for the
purpose of protecting hair colour. In other words, anionic and
nonionic, oily, UV filters are suitably used in the compositions of
the present invention. In the preferred from of the invention the
compositions comprise at least one water soluble UV filter and at
least one oil soluble one. Further preferred that both UV filters
are present at a weight ratio in the range of oil soluble to water
soluble UV filter 1:10 to 10:1, preferably 1:5 to 5:1, more
preferably 1:3 to 3:1 and most preferably 1:1 in the compositions
of the present invention.
[0037] The amount of the UV-absorber as a total ranges typically
from about 0.01% to 5%, preferably 0.05 to 3%, more preferably from
0.05% to 2.5% and most preferably from 0.1% to 2% by weight,
calculated to the total composition.
[0038] In another preferred form of the invention, conditioning
composition can comprise one or more organic solvent such as
ethanol, propanol, isopropanol, benzyl alcohol, benzyloxyethanol,
ethoxydiglycol, alkylene carbonates such as ethylene carbonate and
propylene carbonate, phenoxyethanol, butanol, isobutanol,
cyclohexane, cyclohexanol, hexyleneglycol, ethylenecarbonate,
propyleneglycol, poypropyleneglycols, ethyleneglycol
monoethylether, ethylene glycol monobutyl ether, ethylene glycol
monophenyl ether, 1-phenylethylalcohol, 2-phenylethylalcohol,
o-methoxyphenol. The most preferred ones are benzylalcohol and
polypropylene glycols. Concentration of organic solvents should not
exceed 10% by weight, preferably in the range of 0.1 to 7.5%, more
preferably 0.1 to 5% by weight and most preferably 0.1 to 3% by
weight calculated to total composition.
[0039] Conditioning composition of the present invention comprises
at least one glyceryl ether of the following formula
##STR00006##
wherein R.sub.14 is straight or branched, saturated or unsaturated
alkyl chain with 4 to 24 C atoms, preferably 4 to 18 and more
preferably 4 to 12 C atoms and R.sub.15 is H, or straight or
branched, saturated or unsaturated alkyl chain with 4 to 24 C
atoms, preferably 4 to 18 and more preferably 4 to 12 C atoms and
most preferably R.sub.5 is H, at a concentration of 0.1 to 10%,
preferably 0.1 to 5% and more preferably 0.25 to 3% and most
preferably 0.5 to 2.5% by weight calculated to total
composition.
[0040] Suitable unlimited examples are glyceryl butyl ether,
glyceryl isobutyl ether, glyceryl tert-butyl ether, glyceryl pentyl
ether, glyceryl isopentyl ether, glyceryl hexyl ether, glyceryl
isohexyl ether, glyceryl heptyl ether, glyceryl octyl ether,
glyceryl ethylhexyl ether, glyceryl nonyl ether, glyceryl decyl
ether, glyceryl isodecyl ether, glyceryl lauryl ether, glyceryl
myristyl ether, glyceryl palmityl ether, glyceryl stearyl ether and
glyceryl behenyl ether and their mixtures. Most preferred are
glyceryl butyl ether, glyceryl isobutyl ether, glyceryl tert-butyl
ether, glyceryl pentyl ether, glyceryl isopentyl ether, glyceryl
hexyl ether, glyceryl isohexyl ether, glyceryl heptyl ether,
glyceryl octyl ether, glyceryl ethylhexyl ether, glyceryl nonyl
ether, glyceryl decyl ether, glyceryl isodecyl ether are glyceryl
lauryl ether, and their mixtures.
[0041] It should be noted that within the disclosure of the present
description, gylceryl decyl ether is used as synonym of decyl
glycerine. For the other compounds in the above paragraph the same
is valid.
[0042] Further in preferred embodiment of the present invention,
compositions comprise at least one direct dye. Suitable direct dyes
are of cationic, anionic and neutral nitro dyes. It should be noted
that they can also be used in combination with each other. In other
words a composition according to present invention can comprise an
anionic and a cationic dye as well as an anionic and a nitro dye or
a cationic and a nitro dye. Certainly the combination of all three
dyestuffs is also possible.
[0043] Any cationic direct dye is in principal suitable for the
compositions. Examples are Basic Blue 6, Basic Blue 7, Basic Blue
9, Basic Blue 26, Basic Blue 41, Basic Blue 99, Basic Brown 4,
Basic Brown 16, Basic Brown 17, Natural Brown 7, Basic Green 1,
Basic Orange 31, Basic Red 2, Basic Red 12 Basic Red 22, Basic Red
51, Basic Red 76, Basic Violet 1, Basic Violet 2, Basic Violet 3,
Basic Violet 10, Basic Violet 14, Basic Yellow 57 and Basic Yellow
87.
[0044] Any anionic dye is in principal suitable for the
compositions. Suitable examples are such as Acid Black 1, Acid Blue
1, Acid Blue 3, Food Blue 5, Acid Blue 7, Acid Blue 9, Acid Blue
74, Acid Orange 3, Acid Orange 6, Acid Orange 7, Acid Orange 10,
Acid Red 1, Acid Red 14, Acid Red 18, Acid Red 27, Acid Red 50,
Acid Red 52, Acid Red 73, Acid Red 87, Acid Red 88, Acid Red 92,
Acid Red 155, Acid Red 180, Acid Violet 9, Acid Violet 43, Acid
Violet 49, Acid Yellow 1, Acid Yellow 23, Acid Yellow 3, Food
Yellow No. 8, D&C Brown No. 1, D&C Green No. 5, D&C
Green No. 8, D&C Orange No. 4, D&C Orange No. 10, D&C
Orange No. 11, D&C Red No. 21, D&C Red No. 27, D&C Red
No. 33, D&C Violet 2, D&C Yellow No. 7, D&C Yellow No.
8, D&C Yellow No. 10, FD&C Red 2, FD&C Red 40, FD&C
Red No. 4, FD&C Yellow No. 6, FD&C Blue 1, Food Black 1,
Food Black 2, Disperse Black 9 and Disperse Violet 1 and their
alkali metal salts such as sodium, potassium.
[0045] Among those, the preferred anionic dyestuffs are Acid Red
52, Acid Violet 2, Acid Red 33, Acid Orange 4, Acid Red 27 and Acid
Yellow 10 and their salts. The most preferred anionic dyes are Acid
Red 52, Acid Violet 2, Acid Red 33, Acid Orange 4 and Acid Yellow
10, and their salts
[0046] Neutral dyes, so called nitro dyes for shading purposes are
also optionally contained in the compositions. Suitable ones are HC
Blue No. 2, HC Blue No. 4, HC Blue No. 5, HC Blue No. 6, HC Blue
No. 7, HC Blue No. 8, HC Blue No. 9, HC Blue No. 10, HC Blue No.
11, HC Blue No. 12, HC Blue No. 13, HC Brown No. 1, HC Brown No. 2,
HC Green No. 1, HC Orange No. 1, HC Orange No. 2, HC Orange No. 3,
HC Orange No. 5, HC Red BN, HC Red No. 1, HC Red No. 3, HC Red No.
7, HC Red No. 8, HC Red No. 9, HC Red No. 10, HC Red No. 11, HC Red
No. 13, HC Red No. 54, HC Red No. 14, HC Violet BS, HC Violet No.
1, HC Violet No. 2, HC Yellow No. 2, HC Yellow No. 4, HC Yellow No.
5, HC Yellow No. 6, HC Yellow No. 7, HC Yellow No. 8, HC Yellow No.
9, HC Yellow No. 10, HC Yellow No. 11, HC Yellow No. 12, HC Yellow
No. 13, HC Yellow No. 14, HC Yellow No. 15,
2-Amino-6-chloro-4-nitrophenol, picramic acid,
1,2-Diamino-4-nitrobenzol, 1,4-Diamino-2-nitrobenzol,
3-Nitro-4-aminophenol, 1-Hydroxy-2-amino-3-nitrobenzol and
2-hydroxyethylpicramic acid.
[0047] Concentration of one or more direct dyes in total is in the
range of 0.001 to 5% by weight, preferably 0.01 to 4% more
preferably 0.05 to 3% and most preferably 0.1 to 2.5% by weight
calculated to total composition.
[0048] Conditioning compositions of the present invention can be a
cleansing composition (cleansing-conditioning composition).
Cleansing conditioning compositions of the present invention
comprise at least one surfactant selected from anionic, non-ionic
and/or amphoteric or zwitterionic surfactants at a concentration
range of 5 to 50%, preferably 5 to 40% and more preferably 5 to
30%, and most preferably 5 to 25% by weight, calculated to the
total composition.
[0049] In an embodiment of the present invention cleansing
conditioning composition of the present invention, comprises at
least one anionic, at least one nonionic surfactant. More
preferably the compositions further comprise additionally at least
one amphoteric surfactant.
[0050] Anionic surfactants suitable within the scope of the
invention are preferably present in an amount from 1 to about 30%,
preferably 2 to 20% and most preferably 2-15%, by weight,
calculated to the total composition.
[0051] These are anionic surfactants of the sulfate, sulfonate,
carboxylate and alkyl phosphate type, especially, of course, those
customarily used in shampoo compositions, for example, the known
C.sub.10-C.sub.18-alkyl sulfates, and in particular the respective
ether sulfates, for example, C.sub.12-C.sub.14-alkyl ether sulfate,
lauryl ether sulfate, especially with 1 to 4 ethylene oxide groups
in the molecule, monoglyceride (ether) sulfates, fatty acid amide
sulfates obtained by ethoxylation and subsequent sulfatation of
fatty acid alkanolamides, and the alkali salts thereof, as well as
the salts of long-chain mono- and dialkyl phosphates constituting
mild, skin-compatible detergents.
[0052] Additional anionic surfactants useful within the scope of
the invention are .alpha.-olefin sulfonates or the salts thereof,
and in particular alkali salts of sulfosuccinic acid semiesters,
for example, the disodium salt of monooctyl sulfosuccinate and
alkali salts of long-chain monoalkyl ethoxysulfosuccinates.
[0053] Suitable surfactants of the carboxylate type are alkyl
polyether carboxylic acids and the salts thereof of the formula
R.sub.14--(C.sub.2H.sub.4O).sub.n--O--CH.sub.2COOX,
wherein R.sub.14 is a C.sub.8-C.sub.20-alkyl group, preferably a
C.sub.12-C.sub.14-alkyl group, n is a number from 1 to 20,
preferably 2 to 17, and X is H or preferably a cation of the group
sodium, potassium, magnesium and ammonium, which can optionally be
hydroxyalkyl-substituted, as well as alkyl amido polyether
carboxylic acids of the general formula
##STR00007##
wherein R.sub.16 and X have the above meanings, and n is in
particular a number from 1 to 10, preferably 2.5 to 5.
[0054] Such products have been known for some time and are on the
market, for example, under the trade name "AKYPO.RTM." and
"AKYPO-SOFT.RTM.".
[0055] Also useful are C.sub.8-C.sub.20-acyl isethionates, alone or
in admixture with other anionic surfactants, as well as sulfofatty
acids and the esters thereof.
[0056] It is also possible to use mixtures of several anionic
surfactants, for example an ether sulfate and a polyether
carboxylic acid or alkyl amidoether carboxylic acid.
[0057] An overview of the anionic surfactants used in liquid body
cleansing compositions can furthermore be found in the monography
of K. Schrader and A. Domsch, "osmetology--Theory and Practice",
2005, Verlag fur chemische Industrie, Augsburg--Germany, pp.
II-8-II-19.
[0058] Further suitable anionic surfactants are also
C.sub.8-C.sub.22-acyl aminocarboxylic acids or the water-soluble
salts thereof. Especially preferred is N-lauroyl glutamate, in
particular as sodium salt, as well as, for example, N-lauroyl
sarcosinate, N--C.sub.12-C.sub.18-acyl asparaginic acid,
N-myristoyl sarcosinate, N-oleoyl sarcosinate, N-lauroyl
methylalanine, N-lauroyl lysine and N-lauroyl aminopropyl glycine,
preferably in form of the water-soluble alkali or ammonium, in
particular the sodium salts thereof, preferably in admixture with
the above-named anionic surfactants.
[0059] Further surfactants in the conditioning--cleansing
compositions according to the invention are nonionic surfactants,
preferably in admixture with anionic surfactants.
[0060] These are described in Schrader, I.c., on pages 600-601 and
pp. 694-695. Especially suited are alkyl polyglucosides of the
general formula
R.sub.17--O--(R.sub.18O).sub.n--Z.sub.x,
wherein R.sub.17 is an alkyl group with 8 to 18 carbon atoms,
R.sub.18 is an ethylene or propylene group, Z is a saccharide group
with 5 to 6 carbon atoms, n is a number from 0 to 10 and x is a
number between 1 and 5.
[0061] These alkyl polyglucosides have recently become known in
particular as excellent skin-compatible, foam improving agents in
liquid detergents and body cleansing compositions, and are present
in an amount from about 1% to 15%, in particular from 1% to 10% by
weight, calculated to the total composition.
[0062] Mixtures of anionic surfactants and alkyl polyglucosides as
well as the use thereof in liquid body cleansing compositions are
already known, for example, from EP-A 70 074. The alkyl
polyglucosides disclosed therein are basically also suited within
the scope of the present invention; as well as the mixtures of
sulfosuccinates and alkyl polyglucosides disclosed in EP-A 358
216.
[0063] Further nonionic surfactant components are, for example,
long-chain fatty acid mono- and dialkanolamides, such as coco fatty
acid monoethanolamide and myristic fatty acid monoethanolamide,
which can also be used as foam enhancers, preferably in amounts
from about 1% to about 5% by weight.
[0064] Further additionally useful nonionic surfactants are, for
example, the various sorbitan esters, such as polyethylene glycol
sorbitan stearic acid ester, fatty acid polyglycol esters or
poly-condensates of ethyleneoxide and propyleneoxide, as they are
on the market, for example, under the trade name "Pluronics.sup.R",
as well as fatty alcohol ethoxylates.
[0065] Further suitable nonionic surfactants are amineoxides which
may be present in an amount from 0.25% to 5% by weight, calculated
to the total composition.
[0066] Such amineoxides are state of the art, for example
C.sub.12-C.sub.18-alkyl dimethyl amineoxides such as lauryl
dimethyl amineoxide, C.sub.12-C.sub.18-alkyl amidopropyl or--ethyl
amineoxides, C.sub.12-C.sub.18-alkyl di(hydroxyethyl) or
(hydroxypropyl) amineoxides, or also amineoxides with ethyleneoxide
and/or propyleneoxide groups in the alkyl chain. Such amineoxides
are on the market, for example, under the trade names
"Ammonyx.RTM.", "Aromox.RTM." or "Genaminox.RTM.".
[0067] Further nonionic surfactants useful in the cleansing
conditioning compositions according to invention are
C.sub.10-C.sub.22-fatty alcohol ethoxylates at a concentration of
0.5 to 10%, preferably 0.5 to 5% by weight, calculated to total
composition. Especially suited are C.sub.10-C.sub.22-fatty alcohol
ethers, the alkyl polyglycol ethers known by the generic terms
"Laureth", "Myristeth", "Oleth", "Ceteth", "Deceth", "Steareth" and
"Ceteareth" according to the CTFA nomenclature, including addition
of the number of ethylene oxide molecules, e.g., "Laureth-16":
[0068] The average degree of ethoxylation thereby ranges between
about 2.5 and about 25, preferably about 10 and about 20.
[0069] As further surfactant component, the cleansing conditioning
compositions according to the invention can also contain amphoteric
or zwitterionic surfactants, for example in an amount from about
0.5% to about 15%, preferably from about 1% to about 10%, by
weight, calculated to the total composition. It has especially been
found out that addition of zwitterionic or amphoteric surfactants
enhances foam feeling in terms of creaminess, foam volume and as
well as skin compatibility is improved. For achieving milder
formulations anionic surfactant, especially of sulphate types, to
amphoteric surfactant ratio should be in the range of 10:1 to 1:1,
preferably 5:1 to 1:1.
[0070] Useful as such are in particular the various known betaines
such as alkyl betaines, fatty acid amidoalkyl betaines and
sulfobetaines, for example, lauryl hydroxysulfobetaine; long-chain
alkyl amino acids, such as cocoaminoacetate, cocoaminopropionate
and sodium cocoamphopropionate and -acetate have also proven
suitable.
[0071] In detail, it is possible to use betaines of the
structure
##STR00008##
wherein R.sub.19 is a C.sub.8-C.sub.18-alkyl group and n is 1 to
3;
[0072] sulfobetaines of the structure
##STR00009##
wherein R.sub.19 and n are same as above;
[0073] and amidoalkyl betaines of the structure
##STR00010##
wherein R.sub.19 and n are same as above.
[0074] Solubilizers may be added to the compositions, in particular
cleansing compositions, especially when oily substances are chosen
as conditioning agents and fragrance oils with highly lipophilic
properties. Typical solubilizers may be hydrogenated castor oil
known with the trade mark Cremophor RO series from BASF. It should
be noted that as well the surfactant mixture can be a good
solubilizer for fragrance oils. Typical concentration of the
solubilizers can be in the range of 0.01-2% by weight, preferably
0.1-1% by weight, calculated to total composition.
[0075] Further conditioning additives are hair conditioning and/or
styling polymers into either cleansing or conditioning type. These
may be nonionic polymers, preferably alcohol- and/or water-soluble
vinyl pyrrolidone polymers, such as a vinyl pyrrolidone
homopolymers or copolymers, in particular with vinyl acetate.
Useful vinyl pyrrolidone polymers are, e.g., those known by the
trade name "Luviskol.RTM.", for example, the homopolymers
"Luviskol.RTM. K 30, K 60 and K 90", as well as the water-or
alcohol-soluble copolymers from vinyl pyrrolidone and vinyl
acetate, distributed by BASF AG under the trade name "Luviskol.RTM.
VA 55 respectively VA 64". Further possible nonionic polymers are
vinyl pyrrolidone/vinyl acetate/vinyl propionate copolymers such as
"Luviskol.RTM. VAP 343", vinyl pyrrolidone/(meth)acrylic acid ester
copolymers, as well as chitosan derivatives.
[0076] Amphoteric polymers are found to be useful in conditioning
composition of any type of the present invention. They are
incorporated alone or in admixture with at least one additional
cationic, nonionic or anionic polymer, particularly copolymers of
N-octyl acrylamide, (meth)acrylic acid and tert.-butyl aminoethyl
methacrylate of the type "Amphomer.RTM."; copolymers from
methacryloylethyl betaine and alkyl-methacrylates of the type
"Yukaformer.RTM.", e.g., the butyl methacrylate copolymer
"Yukaformer.RTM. Am75"; copolymers from monomers containing
carboxyl groups and sulfonic groups, e.g., (meth)acrylic acid and
itaconic acid, with monomers such as mono- or dialkyl amino
alkyl(meth)acrylates or mono- or
dialkyl-aminoalkyl(meth)acrylamides containing basic groups, in
particular amino groups; copolymers from N-octyl acrylamide, methyl
methacrylate, hydroxypropyl methacrylate, N-tert.-butyl aminoethyl
methacrylate and acrylic acid, as well as the copolymers known from
U.S. Pat. No. 3,927,199, are applicable.
[0077] Conditioning and cleansing composition of the present
invention can be transparent as well as pearly. Transparency of the
composition is judged by naked eye in a transparent shampoo bottle
with a thickness not more than 5 cm. In the case a transparent
appearance is wished, the following ingredients are not essential.
However, pearl-shiny appearance is achieved with those dispersed in
cleansing color-enhancing compositions in crystalline form, i.e. so
called pearl-shine or pearlizing agents. The preferred once are
PEG-3 distearate and ethylene glycol distearate. The concentration
of those can typically be from 0.1 to 3%, preferably 0.5 to 2% by
weight, calculated to the total composition. These compounds are
preferably added to the compositions in admixture with anionic,
nonionic and/or amphoteric surfactants. Such kind of mixtures is
available commercially.
[0078] Hair cleansing conditioning compositions of the present
invention can be in the form of conventional liquid thickened
shampoo, as well in the form of ready to use foam, delivered either
from a pump-foamer or from an aerosol bottle. In the case that an
aerosol foam preparation is preferred, propellant gas must be added
to the formulation. The suitable propellant gasses are
carbondioxide, dimethylether and alkanes such as butane propane or
their mixtures.
[0079] Conditioning compositions of the present invention can be in
the form of emulsions, solutions, gels and dispersions. In the case
that solutions and/or gels forms are preferred the appearance can
be either with a transparent or opaque. As a product form, foam is
as well suited when packed into a pressurized can or delivered
through a pump-foamer (non-aerosol). In the case that an aerosol
foam preparation is preferred, propellant gas must be added to the
formulation. The suitable propellant gasses are carbondioxide,
dimethylether and alkanes such as butane, propane, isobutane or
their mixtures.
[0080] The emulsion type of conditioning compositions comprise
additionally at least one fatty alcohol of the following
formula
R.sub.20--OH
where R.sub.20 is a saturated or unsaturated, branched or
non-branched fatty acyl chain with 8-24 C atoms. Concentration of
fatty alcohols is usually less than 20%, preferably less than 15%
by weight calculated to total composition. Typical examples to the
most useful fatty alcohols are myristyl alcohol, palmityl alcohol,
cetyl alcohol, stearyl alcohol, behenyl alcohol and their mixtures.
As a mixed fatty alcohol the mostly used one is the cetearyl
alcohol as well preferred in the compositions of the present
invention.
[0081] Conditioning compositions of the present invention can
comprise moisturizers, chelating agents, preservatives and
fragrance. The moisturizing agents are selected from panthenol,
polyols, such as glycerol, polyethylene glycols with molecular
weight 200 to 20,000. The moisturizing ingredients can be included
in the conditioner compositions at a concentration range of
0.01-2.5% by weight calculated to the total composition.
[0082] The sequestering agents are selected from polycarboxy acids.
The preferred one is ethylene diamine tetraacetic acid, EDTA.
Typical useful concentration range for sequestering agents is of
0.01-2.5% by weight calculated to the total composition.
[0083] The pH of the compositions according to the present
invention is suitably between 2 and 8 and preferably in the range
of 2.5 to 6.5, more preferably 3 to 5.5 and most preferably 3.5 to
5.
[0084] In principal pH of the compositions can be adjusted with any
organic and/or inorganic acids or their mixture. Some of them to
mention are phosphoric acid, hydrochloric acid as the inorganic
ones and to the organic acids the well known citric acid and lactic
acid, glycolic acid, hydroxyacrylic acid, glyceric acid, malic acid
and tartaric acid and of the dicarboxylic acids are malonic acid,
succinic acid, glutaric acid, adipic acid, maleic acid, fumaric
acid and phtalic acid. It has further been observed that improved
conditioning and brightening performance was observed when
compositions comprise at the same time at least one
hydroxycarboxylic and/or dicarboxylic acids.
[0085] The viscosity of the conditioning shampoo compositions
according to the invention is in the range of 500 and about 20,000
mPas at 20.degree. C., preferably 1,000 to 10,000, in particular
1,500 to 8,000 mPas at 20.degree. C., measured with Hoppler
viscosimeter.
[0086] Viscosity of shampoo compositions can be adjusted with known
viscosity enhancers. The preferred ones are glyceryl laurate,
PEG-55 propyleneglycol oleate and PEG-18 glyceryl oleate/cocoate
known with the trade names Antil.sup.R 141 and 171, respectively
and PEG-160 sorbitan triisostearate known with a trade name
Rheodol.sup.R. It should be noted that in the case that a
composition are delivered in the form of a foam from a pump-foamer
and/or aerosol can, those compositions should not be thickened and
have a viscosity value not more than 500 mPas, more preferably 250
mPas measured as mentioned above at room temperature.
[0087] Viscosity of the non-cleansing conditioning composition may
not be more than 50,000 mPas at 20.degree. C. measured with
Brookfield Rheometer at a shear rate of 10 sec.sup.-1.
[0088] The following examples are to illustrate the invention, but
not to limit. The compositions according to the invention are
prepared by mixing the individual components in water, whereby it
is also possible to use pre-mixtures of various ingredients.
EXAMPLE 1
TABLE-US-00001 [0089] Dioleoylethylhydroxyethylmonium methosulfate
1% by weight DC HMW 2220 1% Cetearyl alcohol 7 Ceteareth-20 3
Citric acid q.s. pH 4.0 Fragrance, preservative q.s. Water to
100
[0090] The above composition was prepared by emulsifying Cetearyl
alcohol and ceteareth-20 in water at approximately 70.degree. C.
and after cooling down to approximately 40.degree. C. the other
ingredients were added.
[0091] The composition improves combability, shine, elasticity,
volume and body of damaged hair. In addition it was observed that
the same properties of hair which tips were highly damaged and root
area were relatively healthy, were improved as well.
EXAMPLE 2
TABLE-US-00002 [0092] Stearamidopropyldimethylamine 0.5% by weight
DC HMW 2220 0.5% Cetearyl alcohol 7 Cetrimonium chloride 1.5 Citric
acid q.s. pH 4.0 Fragrance, preservative q.s. Water to 100
[0093] The above composition was prepared in the same way as of
Example 1.
[0094] The composition conditions inhomogeneously damaged hair
homogeneously so that hair is combabale, has shine, elasticity,
volume and it is manageable.
EXAMPLE 3
TABLE-US-00003 [0095] Dicocoylethylhydroxyethylmonium methosulfate
0.5% by weight DC HMW 2220 0.5% Behenyl alcohol 5 Ceteareth-20 2
Polyquaternium-10 1 Lactic acid q.s. pH 4.2 Fragrance, preservative
q.s. Water to 100
EXAMPLE 4
TABLE-US-00004 [0096] Dicocoylethylhydroxyethylmonium methosulfate
0.5% by weight DC HMW 2220 0.5% Polyquaternium-6 1 Lactic acid q.s.
pH 5.0 Fragrance, preservative q.s. Water to 100
[0097] The above composition was used as a leave-in conditioner
from a pump spray bottle on damaged hair which was freshly washed
and towel dried. In dry state it was observed that hair was easily
combable, had elasticity, volume and body.
EXAMPLE 5
TABLE-US-00005 [0098] Stearyloxypropyl amine 0.5% by weight DC HMW
2220 0.5% Polyquaternium-6 1 Lactic acid q.s. pH 5.0 Fragrance,
preservative q.s. Water to 100
[0099] The above composition was used as a leave-in conditioner
from a pump spray bottle on damaged hair which was freshly washed
and towel dried. In dry state it was observed that hair was easily
combable, had elasticity, volume and body.
EXAMPLE 6
TABLE-US-00006 [0100] Dioleoylethylhydroxyethylmonium methosulfate
1% by weight DC HMW 2220 1% Cetearyl alcohol 7 Ceteareth-20 3
Benzophenone-3 0.4 Panthenol 0.5 Phenyl trimethicone 0.3 Citric
acid q.s. pH 4.0 Fragrance, preservative q.s. Water to 100
[0101] The above composition was especially suitable for coloured
and/or highlighted hair. The coloured hair treated with the above
conditioner is exceptionally shiny, well combable and has
elasticity, volume and body.
EXAMPLE 7
TABLE-US-00007 [0102] Stearyloxypropyldimethyl amine 1% by weight
DC HMW 2220 1% Cetearyl alcohol 7 Ceteareth-20 3 Benzophenone-3 0.4
Panthenol 0.5 Phenyl trimethicone 0.3 Citric acid q.s. pH 4.0
Fragrance, preservative q.s. Water to 100
[0103] The above composition was especially suitable for coloured
and/or highlighted hair. The coloured hair treated with the above
conditioner is exceptionally shiny, well combable and has
elasticity, volume and body.
EXAMPLE 8
TABLE-US-00008 [0104] Dioleoylethylhydroxyethylmonium methosulfate
1% by weight DC HMW 2220 1 Cetearyl alcohol 7 Ceteareth-20 3
Benzophenone-3 0.4 Glycerin 3 Trimethyl pentaphenyl trisiloxane 0.3
Basic red 51 0.1 Citric acid q.s. pH 4.2 Fragrance, preservative
q.s. Water to 100
[0105] Above conditioner gives dark blonde hair red shimmer.
EXAMPLE 9
TABLE-US-00009 [0106] Dioleoylethylhydroxyethylmonium methosulfate
1% by weight DC HMW 2220 1 Cetearyl alcohol 7 Ceteareth-20 3
Octylmethoxy cinnamate 0.4 Glycerin 3 Trimethyl pentaphenyl
trisiloxane 0.3 Basic red 51 0.01 Basic yellow 87 0.1 Basic brown
16 0.02 Citric acid q.s. pH 4.2 Fragrance, preservative q.s. Water
to 100
[0107] Above conditioner gives light blonde hair additional blond
shine.
EXAMPLE 10
TABLE-US-00010 [0108] Dioleoylethylhydroxyethylmonium methosulfate
1% by weight DC HMW 2220 1 Cetearyl alcohol 7 Ceteareth-20 3
Octylmethoxy cinnamate 0.4 Glycerin 3 Phenyl trimethicone 0.3
Coenzyme Q10 0.08 Vitis vinifera (dry matter) 0.1 Ethyl hexyl
glycerin 0.5 Citric acid q.s. pH 4.2 Fragrance, preservative q.s.
Water to 100
[0109] Above conditioner enhances combability, shine, volume body
and elasticity. Hair treated with the above conditioner is
excellently manageable and easily styled.
EXAMPLE 11
TABLE-US-00011 [0110] Dioleoylethylhydroxyethylmonium methosulfate
1% by weight DC HMW 2220 1 Cetearyl alcohol 7 Steartrimonium
chloride 1 Glycerin 3 Phenyl trimethicone 0.3 Coenzyme Q10 0.08
Isopropyl myristate 0.2 Lactic acid q.s. pH 3.8 Fragrance,
preservative q.s. Water to 100
[0111] Above conditioner enhances combability, shine, volume body
and elasticity. Hair treated with the above conditioner is
excellently manageable and easily styled. Above conditioner was
also used as leave in conditioner and bodyfying effects was
especially enhanced.
EXAMPLE 12
TABLE-US-00012 [0112] Dioleoylethylhydroxyethylmonium methosulfate
1% by weight DC HMW 2220 1 Cocamidoproyl betaine 0.8 Steartrimonium
chloride 1 Glycerin 3 Coenzyme Q10 0.08 Isopropyl myristate 0.1
Lactic acid q.s. pH 3.8 Fragrance, preservative q.s. Water to
100
[0113] Above composition had a viscosity below 500 mPas and was
filled into a pump foamer and used as leave in conditioner on a
freshly washed and towel dried hair. Hair was excellently shiny and
bodified also excellently combable.
[0114] The above composition was also used as aerosol foam and
therefore filled inot an aerosol can with 10% propane-butane
mixture as a propellant. The above results were confirmed.
[0115] The above composition can also be used as a pump spray.
EXAMPLE 13
TABLE-US-00013 [0116] Cetylstearylalcohol 5.0 (% by weight)
Dioleoylethyldimethylammonium ethosulfate 1.0 Ceteareth 20 1.0
Panthenol 0.4 DC HMW 2220 0.75 Hydroxypropyl Guar
Hydroxypropyltrimonium 1.0 Chloride Ethylhexyl glycerin 0.8
Tetramethyl tetraphenyl trisiloxane 0.2 Ribes nigrum (dry matter)
0.1 Avocado extract 0.5 Fragrance, preservative q.s. Malic acid
q.s. to pH 3.5 Wasser ad 100.0
EXAMPLE 14
TABLE-US-00014 [0117] Cetylstearylalcohol 5.0 (% by weight)
Stearyltrimethylammoniumchlorid 1.0 DC HMW 2220 1.0
Stearamidopropyldimethyl amine 1.0 Benzylalcohol 2.5 Trimethyl
pentaphenyl trisiloxane 0.3 Ethylhexyl glycerin 0.9 Fragrance,
preservative q.s. Lactic acid q.s. pH 3.5 Wasser ad 100.0
[0118] Above composition is applied onto shampooed hair and
processed for 5 min and rinsed off from hair. It was observed that
wet hair is easily combable. In the dry state combability,
manageability, elasticity and shine were very much improved.
Furthermore into the above conditioner composition, hair direct dye
Basic red 51 was included. After use on dark blonde hair am
excellent red shine was observed on the hair.
EXAMPLE 15
[0119] Foam Conditioner
TABLE-US-00015 Quaternium-80 0.2 (Gew.-%) Polyquaternium-11 0.7
PEG-60-hydrogenated ricinus oil 0.5 Diphenylsiloxy phenyl
trimethicone 0.5 Ethylhexyl glycerin 1.2 DC HMW 2220 0.7
Stearamidopropyldimethyl amine 1.0 Malus domestica (dry matter) 0.1
Ubichinone 0.075 Benzophenone-3 0.3 Fragrance, preservative q.s.
Lactic acid q.s. to pH 3.4 Wasser ad 100.0
[0120] pH of the composition is adjusted to 3.4. The composition is
suitable for leave-in and rinse off. In leave-in application,
amount used is obviously less than in the case of a rinse of
application. The composition is packed into an aerosol can with
90/10 ratio, by weight, liquid composition to propellant. As
propellant propane, butane mixture is used.
[0121] Into the above composition 0.1% Acid red 52 was added. It
was possible to realize red shimmer onto dark blonde hair.
EXAMPLE 16
[0122] Foam Conditioner
TABLE-US-00016 Quaternium-80 0.2 (Gew.-%) Polyquaternium-11 0.7
PEG-60-hydrogenated ricinus oil 0.5 Diphenylsiloxy phenyl
trimethicone 0.5 Ethylhexyl glycerin 1.2 DC HMW 2220 0.7
Stearyloxypropyldimethyl amine 1.0 Malus domestica (dry matter) 0.1
Ubichinone 0.075 Benzophenone-3 0.3 Fragrance, preservative q.s.
Lactic acid q.s. to pH 3.4 Wasser ad 100.0
[0123] pH of the composition is adjusted to 3.4. The composition is
suitable for leave-in and rinse off. In leave-in application,
amount used is obviously less than in the case of a rinse of
application. The composition is packed into an aerosol can with
90/10 ratio, by weight, liquid composition to propellant. As
propellant propane, butane mixture is used.
[0124] Into the above composition 0.1% Acid red 52 was added. It
was possible to realize red shimmer onto dark blonde hair.
EXAMPLE 17
TABLE-US-00017 [0125] Cetylstearylalcohol 5.0 (% by weight)
Cetrimoniumchloride 1.0 Panthenol 0.4 DC HMW 2220 0.75
Hydroxypropyl Guar Hydroxypropyltrimonium 1.0 Chloride Trimethyl
pentaphenyl trisiloxane 0.5 Decyl glycerin 1.2 Stearamidopropyl
diethyl amine 1.0 Ubichinone 0.08 Avocado extract 0.5 Fragrance,
preservative q.s. Citric acid q.s. to pH 3.0 Wasser ad 100.0
[0126] The above composition can be used as both leave-in and rinse
off.
[0127] In the above composition decyl glycerin was replaced with
ethylhexyl glycerin at the same concentration. The replacement of
glyceryl ether did not change conditioning properties.
EXAMPLE 18
TABLE-US-00018 [0128] Sodium lauryl ether sulfate 11.0 (% by wt.)
Coco glucoside 4.0 Cocoamidopropyl betaine 1.5 Sodium cocyl
gluatamte 1.5 DC HMW 2220 0.3 Stearamidopropyl amine 0.3 Sodium
chloride 1.0 Citric acid q.s. pH 5.5 Perfume, preservative q.s
Water q.s. to 100.0
[0129] Hair washed with the above shampoo composition showed
excellent shine, volume, body, easily combable and improved
elasticity and manageability. Exclusion of Trimethyl pentaphenyl
trisiloxane and ethylhexyl glycerine resulted in loss of
effects.
[0130] Similar results are observed with the following shampoo
compositions.
EXAMPLE 19
TABLE-US-00019 [0131] Coco glucoside 8.0 Cocoamidopropyl betaine
8.0 Laureth-16 2.0 Cationic polymer (Polyquaternium-11) 0.5
Benzophenone-3 0.2 Etyh hexyl glycerin 0.8 PEG-3 distearate 0.8
Coenzyme Q10 0.1 DC HMW 2220 0.3 Stearmaidoprolydihydroethylamine
0.3 PEG-18 Glyceryl cocoate/oleate 0.80 Malus domestica (dry
matter) 0.1 Malic acid q.s. pH 5.5 Perfume, preservative q.s. Water
ad 100.0
[0132] To the above composition, 0.1% Basic orange 31 and 0.05%
Basic red 76 was mixed. Hair washed with this shampoo had excellent
warm blond shine.
EXAMPLE 20
TABLE-US-00020 [0133] Sodium lauryl ether sulfate 11.0 (% by wt.)
Coco glucoside 5.0 Cocoamidopropyl betaine 3.0 Sodium cocoyl
gluatamate 1.5 Stearoylpropylamine 0.5 Cationic polymer
(Polyquaternium-11) 0.5 Benzophenone-3 0.2 Benzylalcohol 0.5 DC HMW
2220 0.4 Ubichinone 0.05 Vitis vinifera (dry matter) 0.20 Lactic
acid q.s. to pH 5.0 Perfume, preservative q.s. Water ad 100.0
[0134] The above composition is a very low viscosity composition,
in any case a viscosity lower than 500 mPas measured at ambient
temperature and with Foppler viscosimeter, confectioned into a
pump-foamer as purchased from the company Air-Spray--Germany and
showed excellent shine effect
[0135] Similarly and aerosol foam shampoo was prepared by
confectioning the above composition at a weight ratio of
90/10--composition/propellant--using propane-butane mixture as a
propellant. The foam shampoo so obtained showed excellent cleansing
and shine effects.
[0136] Additionally, into the above shampoo 0.05% basic blue 99,
and 0.005% basic red 51 was added. Excellent warm silver shine was
observed on the washed gray hair. At the same time, excellent
anti-yellow effect is observed on the freshly bleached hair.
[0137] Furthermore the above cleansing and conditioning composition
was added 1% by weight sodium chloride and it became a thickened
shampoo without loss of any effects mentioned above.
* * * * *