U.S. patent application number 12/997188 was filed with the patent office on 2011-04-28 for fuel filling kit and fuel filling method.
This patent application is currently assigned to SONY CORPORATION. Invention is credited to Kazuaki Fukushima, Yoshiaki Inoue, Atsushi Sato, Jusuke Shimura, Yuto Takagi.
Application Number | 20110094617 12/997188 |
Document ID | / |
Family ID | 41433985 |
Filed Date | 2011-04-28 |
United States Patent
Application |
20110094617 |
Kind Code |
A1 |
Takagi; Yuto ; et
al. |
April 28, 2011 |
FUEL FILLING KIT AND FUEL FILLING METHOD
Abstract
A fuel filling kit 10 includes a filling nozzle capable of being
inserted into an opening of a fuel cartridge, a filling vessel
capable of filling liquid fuel reserved in the inside thereof into
the fuel cartridge through the filling nozzle, and an opening
sealing sheet for sealing the opening. The opening sealing sheet
has a methanol blocking portion having a resisting property to
liquid fuel and a sticking portion capable of being attached to the
fuel cartridge.
Inventors: |
Takagi; Yuto; (Kanagawa,
JP) ; Inoue; Yoshiaki; (Aichi, JP) ;
Fukushima; Kazuaki; (Kanagawa, JP) ; Shimura;
Jusuke; (Kanagawa, JP) ; Sato; Atsushi;
(Kanagawa, JP) |
Assignee: |
SONY CORPORATION
Tokyo
JP
|
Family ID: |
41433985 |
Appl. No.: |
12/997188 |
Filed: |
June 1, 2009 |
PCT Filed: |
June 1, 2009 |
PCT NO: |
PCT/JP2009/059950 |
371 Date: |
December 9, 2010 |
Current U.S.
Class: |
141/4 ;
141/63 |
Current CPC
Class: |
Y02E 60/50 20130101;
Y02E 60/523 20130101; H01M 8/04208 20130101; H01M 8/1011
20130101 |
Class at
Publication: |
141/4 ;
141/63 |
International
Class: |
B65B 31/00 20060101
B65B031/00 |
Foreign Application Data
Date |
Code |
Application Number |
Jun 18, 2008 |
JP |
P2008-157227 |
Claims
1-5. (canceled)
6. A fuel filling kit comprising: a filling nozzle capable of being
inserted into an opening of a fuel cartridge for reserving liquid
fuel to be supplied to a fuel cell main body; a filling vessel
capable of filling liquid fuel reserved in an inside thereof into
the fuel cartridge through said filling nozzle; and an opening
sealing member for sealing the opening; said opening sealing member
having a fuel resisting portion having a resisting property to
liquid fuel, and an attaching portion capable of being attached to
said fuel cartridge.
7. The fuel filling kit according to claim 6, wherein said filling
nozzle includes: a fuel supplying portion configured to supply the
liquid fuel in said filling vessel; a gas exhausting portion
configured to exhaust gas in said fuel cartridge; and a seal member
provided on the outer side of said filling nozzle for sealing, when
said filling nozzle is inserted into the opening, a space between
said filling nozzle and the opening.
8. The fuel filling kit according to claim 6, further comprising:
an opening forming member for forming an opening into which said
filling nozzle can be inserted on said fuel cartridge.
9. A fuel filling method comprising: a filling nozzle insertion
step of inserting a fuel nozzle into an opening of a fuel cartridge
for reserving liquid fuel to be supplied to a fuel cell main body;
a fuel filling step of filling, after the filling nozzle insertion
step, liquid fuel reserved in the inside of a filling vessel into
the fuel cartridge through the filling nozzle inserted in the
opening; and an opening sealing step of sealing, after the fuel
filling step, the opening of the fuel cartridge in which the liquid
fuel is filled with an opening sealing member having a fuel
resisting portion having a resisting property to liquid fuel.
10. The fuel filling method according to claim 9, further
comprising: an opening formation step of forming, before the
filling nozzle insertion step, an opening into which the filling
nozzle can be inserted on the fuel cartridge.
Description
CROSS REFERENCE TO RELATED APPLICATIONS
[0001] The present application is a National Stage of International
Application No. PCT/JP2009/059950 filed on Jun. 1, 2009 and which
claims priority to Japanese Patent Application No. 2008-157227
filed on Jun. 16, 2008, the entire contents of which are being
incorporated herein by reference.
BACKGROUND
[0002] The present disclosure relates to a fuel filling kit and a
fuel filling method for filling liquid fuel into a fuel cartridge
for reserving liquid fuel to be supplied to a fuel cell main body.
More particularly, the present disclosure relates to a technique
which makes re-utilization of a fuel cartridge possible, reduces
the running cost and makes it possible to implement resource
saving.
[0003] In recent years, together with enhancement of functions or
multi-functioning of portable electronic apparatus such as portable
telephone sets, notebook type personal computers, digital cameras
and camcorders, the power consumption of them has an increasing
tendency. Therefore, attention is paid to a fuel cell with regard
to which improvement in energy density and output power density can
be expected as a power supply for such portable electronic
apparatus.
[0004] In a fuel cell, fuel supplied to the anode side is oxidized
while the air or oxygen is supplied to the cathode side to reduce
the oxygen. And, chemical energy which the fuel has is converted
efficiently into electric energy, and the electric energy is
extracted and utilized. Therefore, if fuel continues to be supplied
to the fuel cell, then the fuel cell can continue to be used as a
power supply even if it is not charged.
[0005] Among such fuel cells as described above, solid polymer type
fuel cells (PEFC) which use a proton conductive polymer membrane as
an electrolyte have the highest possibility that it may become a
power supply for portable electronic apparatus. Among such polymer
type fuel cells, a direct methanol fuel cell (DMFC) which uses
methanol without modification as fuel supplies methanol of the fuel
as aqueous solution of methanol of a high concentration or a low
concentration to the anode side. And, the supplied methanol is
oxidized into carbon dioxide by a catalyst layer on the anode side.
Further, hydrogen ions generated thereupon move to the cathode side
past a proton conductive polymer electrolyte membrane sandwiched
between the anode and the cathode and reacts with oxygen in a
catalyst layer on the cathode side to produce water.
[0006] In this manner, in the direct methanol fuel cell (DMFC),
methanol which is liquid fuel is supplied to the anode side to
generate electric power. Further, the methanol is reserved in a
fuel cartridge which is, for example, removably mounted on a fuel
cell main body. Usually, remaining amount detection means for
detecting the remaining amount of methanol is provided. And, if it
is detected by the remaining detection means that the methanol is
used up, then the fuel cartridge is removed from the fuel main body
and is replaced with a new fuel cartridge (in which methanol is
reserved).
[0007] However, if the used up fuel cartridge after replaced by the
new fuel cartridge is thrown away, then this is a situation
undesirable from the aspect of the running cost, resource saving
and so forth. Further, the used up fuel cartridge is different only
in that liquid fuel such as methanol is not reserved therein, but
does not lose the function of supplying liquid fuel to the fuel
cell main body.
[0008] Therefore, a technique is known which can fill liquid fuel
into a fuel cartridge. In particular, the technique includes a
filling nozzle for being connected to a fuel cartridge, and a valve
which operates if the filling nozzle is connected to a fuel
cartridge (refer to, for example, Patent Document 1).
[0009] Further, in the field of ink jet printers, a technique
wherein ink can be filled into an ink cartridge which is removably
mounted on a printer main body is known. In particular, the
technique includes a jig for forming an opening in an ink
cartridge, and a re-filling vessel for re-filling ink from the
opening formed in the jig (refer to, for example, Patent Document
2).
[0010] Patent Document 1: Japanese Patent Laid-Open No.
2007-87777
[0011] Patent Document 2: Japanese Patent Laid-Open No.
2001-180004
SUMMARY
[0012] However, the technique disclosed in Patent Document 1 is
complicated in structure and does not allow a user of a portable
electronic apparatus or the like, which is driven by a fuel cell,
to fill liquid fuel easily. Meanwhile, the technique disclosed in
Patent Document 2 is not suitable for filling of liquid fuel such
as methanol because it is a technique for filling ink of an ink jet
printer. Particularly if the technique of Patent Document 2 is used
to fill liquid fuel for a fuel cell, then even if the opening is
sealed later, the liquid fuel leaks.
[0013] Accordingly, it is to enable a user to fill liquid fuel
easily into a fuel cartridge for reserving liquid fuel to be
supplied to a fuel cell main body and prevent leakage of the liquid
fuel after being filled.
[0014] According to an embodiment, there is provided a fuel filling
kit including a filling nozzle capable of being inserted into an
opening of a fuel cartridge for reserving liquid fuel to be
supplied to a fuel cell main body, a filling vessel capable of
filling liquid fuel reserved in the inside thereof into the fuel
cartridge through the filling nozzle, and an opening sealing member
for sealing the opening, the opening sealing member having a fuel
resisting portion having a resisting property to liquid fuel, and
an attaching portion capable of being attached to the fuel
cartridge.
[0015] According to another embodiment, there is provided a fuel
filling method including a filling nozzle insertion step of
inserting a fuel nozzle into an opening of a fuel cartridge for
reserving liquid fuel to be supplied to a fuel cell main body, a
fuel filling step of filling, after the filling nozzle insertion
step, liquid fuel reserved in the inside of a filling vessel into
the fuel cartridge through the filling nozzle inserted in the
opening, and an opening sealing step of sealing, after the fuel
filling step, the opening of the fuel cartridge in which the liquid
fuel is filled with an opening sealing member having a fuel
resisting portion having a resisting property to liquid fuel.
[0016] (Operation)
[0017] In the embodiments described above, the filling nozzle is
inserted into the opening of a fuel cartridge, and the liquid fuel
reserved in the inside of the filling vessel is filled into the
fuel cartridge through the filling nozzle. Therefore, a user of a
portable electronic apparatus which operates with the fuel cell can
fill liquid fuel easily into the fuel cartridge.
[0018] Further, in the embodiments described above, the opening of
the fuel cartridge is sealed with the opening sealing member having
the fuel resisting portion having a resisting property to the
liquid fuel. Therefore, after the liquid fuel is filled, even if
the liquid fuel is brought into contact with the opening sealing
member, since the opening sealing member is protected by the fuel
resisting portion, leakage of the liquid fuel after the filling can
be prevented.
[0019] With the embodiments described above, a user can fill liquid
fuel easily into a fuel cartridge for reserving liquid fuel to be
supplied to a fuel cell body, and also leakage after the filling
can be prevented. Therefore, re-utilization of the fuel cartridge
by the user is possible, and not only the running cost is reduced,
but resource saving can be implemented.
[0020] Additional features and advantages are described herein, and
will be apparent from, the following Detailed Description and the
figures.
BRIEF DESCRIPTION OF THE FIGURES
[0021] FIG. 1 is a perspective view and a sectional view showing a
fuel cartridge for reserving liquid fuel.
[0022] FIG. 2 is a concept diagram showing a fuel cell system which
uses liquid fuel to generate electric power.
[0023] FIG. 3 is a side elevational view and so forth showing a
fuel filling kit of a first embodiment.
[0024] FIG. 4 is explanatory views illustrating a fuel filling
method (an opening formation step) for filling methanol using the
fuel filling kit of the first embodiment.
[0025] FIG. 5 is views illustrating the fuel filling method (a
filling nozzle insertion step and a fuel filling step) for filling
methanol using the fuel filling kit of the first embodiment.
[0026] FIG. 6 is explanatory views illustrating the fuel filling
method (an opening sealing step) for filling methanol using the
fuel filling kit of the first embodiment.
[0027] FIG. 7 is a side elevational view and so forth showing a
fuel filling kit of a second embodiment.
[0028] FIG. 8 is explanatory views illustrating a fuel filling
method for filling methanol using the fuel filling kit of the
second embodiment.
[0029] FIG. 9 is a sectional view showing a filling vessel of a
fuel filling kit of a third embodiment.
[0030] FIG. 10 is a sectional view showing a filling vessel of a
fuel filling kit of a fourth embodiment.
[0031] FIG. 11 is a sectional view showing a filling vessel of a
fuel filling kit of a fifth embodiment.
[0032] FIG. 12 is a sectional view showing a filling vessel of a
fuel filling kit of a sixth embodiment.
DETAILED DESCRIPTION
[0033] Embodiments are described below with reference to the
drawings.
[0034] FIG. 1 is a perspective view and a sectional view showing a
fuel cartridge 110 for reserving liquid fuel.
[0035] As shown in (a) of FIG. 1, the fuel cartridge 110 has a fuel
vessel section 111 and a fuel supply port 112.
[0036] The fuel vessel section 111 is a space having a high sealing
property for reserving methanol which is liquid fuel. And, the
outer profile of the fuel vessel section 111 is formed as a
parallelepiped removably mounted on a fuel cell main body 120 (not
shown) hereinafter described. Further, a remaining amount sensor
(not shown) for detecting the remaining amount of methanol is
attached to the inside of the fuel vessel section 111. Therefore,
when it is detected by the remaining amount sensor that the
methanol in the fuel vessel section 111 is used up, it is possible
to remove the fuel cartridge 110 from the fuel cell main body 120
and replace it with a new fuel cartridge 110 (in which methanol is
reserved). It is to be noted that, in (b) of FIG. 1, the fuel
cartridge 110 in a state in which the methanol in the fuel vessel
section 111 is used up is shown.
[0037] The fuel supply port 112 is an exit for supplying methanol
reserved in the fuel vessel section 111 therethrough, and is formed
in one side face of the fuel vessel section 111. And, an on-off
valve 112a (refer to (b) of FIG. 1) is provided so that the
methanol may not flow out inadvertently through the fuel supply
port 112. Therefore, upon transportation, storage, sales and so
forth of the fuel cartridge 110, the methanol in the fuel vessel
section 111 does not at all leak to the outside.
[0038] FIG. 2 is a concept diagram showing a fuel cell system 100
for generating electric power from liquid fuel.
[0039] The fuel cell system 100 shown in FIG. 2 is a direct
methanol fuel cell (DMFC) which uses methanol as fuel. The fuel
cell system 100 includes the fuel cartridge 110 and the fuel cell
main body 120 such that methanol is supplied from the fuel
cartridge 110 to the fuel cell main body 120.
[0040] Meanwhile, the fuel cell main body 120 has a power
generating apparatus 121, a control device 122, a fuel supply pump
123, and an auxiliary cell 124. Furthermore, the fuel cell main
body 120 has a fuel inlet port 125 for accepting methanol from the
fuel cartridge 110.
[0041] The power generating apparatus 121 generates electric power
from chemical energy which methanol has. In particular, the power
generating apparatus 121 includes a membrane-electrode assembly
(MEA) wherein a fuel electrode of the anode side and an oxygen
electrode of the cathode side are joined to the opposite faces of a
proton conductive polymer electrolyte membrane. And, the fuel
electrode has an oxidation catalyst layer formed on the surface of
a conductive porous substrate while the oxygen electrode has a
reduction catalyst layer formed on the surface of a conductive
porous substrate. It is to be noted that the conductive porous
substrate is formed using, for example, a carbon sheet or carbon
cloth. Further, the oxidation catalyst layer and the reduction
catalyst layer are formed, for example, from mixture of platinum or
the like, which is a catalyst, and proton conductor.
[0042] To the fuel electrode of such a membrane-electrode assembly
(MEA), methanol is supplied, and to the oxygen electrode, oxygen or
the air is supplied. And, the methanol supplied to the fuel
electrode on the anode side is oxidized into carbon dioxide by the
oxidation catalyst layer. Meanwhile, hydrogen ions (protons: H+)
from which electrons (e-) are separated are generated, and the
generated hydrogen ions move to the cathode side past the proton
conductive polymer electrolyte membrane and the electrons (e-) are
extracted from the fuel cell and supplied to a load. Furthermore,
the electrons (e-) passing through the load and the hydrogen ions
(protons: H+) passing through the proton conductive polymer
electrolyte membrane react with oxygen in the reduction catalyst
layer of the oxygen electrode to produce water.
[0043] In this manner, the power generating device 121 generates
electric power by an electro-chemical reaction, and as a by-product
other than the electric power, basically only water is produced.
And, the electromotive force to be supplied to the load relies upon
the amount of the methanol to be supplied to the fuel electrode of
the power generating device 121. Therefore, electric power can be
generated arbitrarily by controlling the fuel supplying pump 123 by
means of the control device 122 to adjust the supplying amount of
the methanol.
[0044] Here, the methanol is supplied from the fuel cartridge 110.
In particular, the entire fuel cartridge 110 including the fuel
vessel section 111 is formed so as to be removably mounted on the
fuel cell main body 120. And, methanol is reserved in the fuel
vessel section 111, and if the fuel cartridge 110 is mounted on the
fuel cell main body 120, then the fuel supplying port 112 and the
fuel accepting port 125 are registered with each other and the
on-off valve 112a (refer to (b) of FIG. 1) at the fuel supplying
port 112 is opened.
[0045] In this state, the fuel supply pump 123 is driven by
electric power of the auxiliary cell 124. Consequently, the
methanol of the fuel cartridge 110 is supplied to the power
generating apparatus 121 of the fuel cell main body 120 through the
fuel supply port 112 and the fuel inlet port 125. It is to be noted
that the auxiliary cell 124 is, for example, a secondary battery
such as, for example, a lithium polymer battery, and part of
electric power generated by the power generating device 121 is
supplied to and accumulated into the auxiliary cell 124.
[0046] Further, if the methanol of the fuel cartridge 110 mounted
on the fuel cell main body 120 is used up, then the fuel cartridge
110 should be removed and a new fuel cartridge 110 (in which
methanol is reserved) may be mounted. Consequently, since methanol
is supplied from the new fuel cartridge 110 to the fuel cell main
body 120, the electric power generation by the power generating
apparatus 121 can be continued also after then.
[0047] However, to throw away the old fuel cartridge 110 (in which
the methanol is used up) is not preferable from the aspect of the
running cost, resource saving and so forth. Further, the old fuel
cartridge 110 is different only in that methanol is not reserved
therein but does not lose the function of supplying methanol to the
fuel cell main body 120. Therefore, if a user of the fuel cell
system 100 can personally re-fill methanol into the old fuel
cartridge 110, then re-utilization of the old fuel cartridge 110 is
permitted, and not only the running cost is reduced but also
resource saving can be implemented.
[0048] FIG. 3 is a side elevational view and so forth showing a
fuel filling kit 10 of a first embodiment for filling methanol into
the fuel cartridge 110 shown in FIG. 1.
[0049] As shown in (a) of FIG. 3, the fuel filling kit 10 of the
first embodiment is configured from a filling vessel 12 which
includes a filling nozzle 11, a opening forming pin 13 (which
corresponds to an opening forming member in the present invention),
and an opening sealing sheet 14 (which corresponds to an opening
sealing member in the present embodiment).
[0050] The filling nozzle 11 is provided for filling methanol
reserved in the inside of the filling vessel 12 into the fuel
cartridge 110 (refer to FIG. 1). To this end, the filling nozzle 11
has a form of an elongated cylindrical pipe and is provided on an
end face of the filling vessel 12 such that it is communicated with
the inside of the filling vessel 12. It is to be noted that the
filling nozzle 11 and the filling vessel 12 are formed integrally
with each other from a silicon-based or fluorocarbon-based resin
material having a resisting property to liquid fuel (ethanol,
formic acid and so forth can be used in addition to methanol),
polyethylene terephthalate (PET), cycloolefin polymer (COC),
polyetheretherketone (PEEK), polypropylene (PP)+aluminum coating,
polyethylene (PE)+aluminum coating or the like.
[0051] The filling vessel 12 has a form of bellows having methanol
reserved in the inside thereof and has such flexibility that it can
be pushed by a finger from the opposite side to the filling nozzle
11. Further, the filling vessel 12 is generally transparent or
translucent so that the remaining amount of the methanol reserved
in the inside thereof can be visually recognized readily.
[0052] The opening forming pin 13 is provided for forming a
through-hole in a side face of the fuel vessel section 111 (refer
to FIG. 1) so that the filling nozzle 11 can be inserted into the
fuel cartridge 110 (refer to FIG. 1). To this end, the opening
forming pin 13 is formed from a metal member having a form of a
needle which is pointed at a free end side thereof and having a
disk made of a resin and attached to the rear end side thereof such
that it can be pushed at the disk thereof.
[0053] The opening sealing sheet 14 is provided for closing up the
through-hole formed by the opening forming pin 13. To this end, the
opening sealing sheet 14 has a sticking portion 14a (which
corresponds to an attaching portion in the present embodiment) as
shown in (b) of FIG. 3. In particular, the opening sealing sheet 14
can be stuck to a portion of the fuel vessel section 111 (refer to
FIG. 1) at which the through-hole is formed by the sticking portion
14a. It is to be noted that the sticking portion 14a is provided on
the outer side of the opening sealing sheet 14 and is made of an
epoxy-based, acrylic-based, styrene rubber-based or vinyl
chloride-based material or the like which have a high adhesive
property to the fuel vessel section 111.
[0054] Further, the opening sealing sheet 14 has a methanol
blocking portion 14b (which corresponds to a fuel resisting portion
in the present invention). This methanol blocking portion 14b is
made of a resin material (polypropylene (PP), polyethylene
terephthalate (PET) or the like) on which a metal thin film of, for
example, aluminum is laminated so that the liquid fuel such as
methanol may not penetrate the same and a sufficient resisting
property to methanol and so forth may be provided.
[0055] Furthermore, the opening sealing sheet 14 has a seal portion
14c. This seal portion 14c has a circular shape greater a little
than the diameter of the through-hole formed by the opening forming
pin 13. And, the seal portion 14c is formed from a silicon-based or
fluorocarbon-based elastic member having a non-penetrating property
and a resisting property to methanol and so forth and is adhered to
a material, which configures the methanol blocking portion 14b, by
a silicon-based or fluorocarbon-based bonding agent.
[0056] In this manner, the opening sealing sheet 14 is provided at
a portion thereof, at which methanol or the like contacts, with a
resisting property by the methanol blocking portion 14b and
isolates the sticking portion 14a which has a low resisting
property to methanol and so forth by means of the seal portion 14c.
Therefore, if the through-hole formed by the opening forming pin 13
is closed up with the opening sealing sheet 14, then penetration
and so forth of methanol can be prevented with certainty. It is to
be noted that, while the opening sealing sheet 14 has the methanol
blocking portion 14b made of a resin material laminated with a
metal thin film as a base and includes the sticking portion 14a and
the seal portion 14c provided on the methanol blocking portion 14b,
the base material may be formed using a sheet of metal, resin,
rubber or the like.
[0057] FIGS. 4 to 6 are explanatory views illustrating a fuel
filling method for filling methanol by means of the fuel filling
kit 10 of the first embodiment shown in FIG. 3.
[0058] FIG. 4 illustrates an opening formation step of the fuel
filling method, FIG. 5 illustrates a filling nozzle insertion step
and a fuel filling step, and FIG. 6 illustrates an opening sealing
step.
[0059] In order to fill methanol by means of the fuel filling kit
10 of the first embodiment shown in FIG. 3, an opening 113 is
formed first in the fuel vessel section 111 of the fuel cartridge
110 by the opening formation step illustrated in FIG. 4. In
particular, as shown in (a) of FIG. 4, the needle-shaped end
portion of the opening forming pin 13 is directed to an opening
formation region of the fuel vessel section 111, and the disk
portion on the rear end side is pushed to push down the opening
forming pin 13 as indicated by an arrow mark. Consequently, the
needle-shaped end portion of the opening forming pin 13 penetrates
the fuel vessel section 111 to form an opening 113 as shown in (b)
of FIG. 4.
[0060] The opening 113 formed by the penetration of the
needle-shaped portion of the opening 113 down to the root portion
thereof by such an opening formation step as described above is a
through-hole of a size sufficient to allow the filling nozzle 11
(refer to (a) of FIG. 3) to be inserted therein. It is to be noted
that, after the formation of the opening 113, the opening forming
pin 13 is pulled off from the fuel vessel section 111.
[0061] Then, at the filling nozzle insertion step illustrated in
(a) of FIG. 5, the filling nozzle 11 is inserted into the opening
113. Consequently, the free end side of the filling nozzle 11
enters the inside of the fuel vessel section 111, and the filling
vessel 12 integrated with the filling nozzle 11 is placed on a side
face of the fuel vessel section 111. Then, at the fuel filling step
illustrated in (b) of FIG. 5, if the filling vessel 12 is pushed in
as indicated by an arrow mark from the opposite side of the filling
nozzle 11 by a finger, then the filling vessel 12 in the form of
bellows having flexibility is compressed. As a result, the volume
of the filling vessel 12 decreases, and the methanol reserved in
the inside of the filling vessel 12 is pushed out by a
corresponding amount from the filling nozzle 11 so that the
methanol is filled into the fuel cartridge 110.
[0062] In this manner, a user can fill methanol readily into the
fuel cartridge 110 only by compressing the filling vessel 12.
Further, since the remaining amount of the methanol in the filling
vessel 12 which is transparent (translucent) can be visually
confirmed readily from the outside, all of the methanol in the
filling vessel 12 can be used up. It is to be noted that, after the
filling of methanol, the filling vessel 12 (filling nozzle 11) is
pulled off from the fuel vessel section 111 (opening 113).
[0063] Finally, the opening 113 formed on the fuel vessel section
111 is sealed by the opening sealing step illustrated in FIG. 6. In
particular, the opening sealing sheet 14 is pasted to the fuel
vessel section 111 as indicated by an arrow mark in such a manner
as to close up the opening 113 as shown in (a) of FIG. 6.
Consequently, the opening 113 of the fuel cartridge 110 in which
methanol is filled is sealed with the opening sealing sheet 14 as
shown in (b) of FIG. 6. Therefore, the methanol filled in the fuel
cartridge 110 does not leak to the outside.
[0064] Particularly, the opening sealing sheet 14 has the methanol
blocking portion 14b at a portion thereof opposing to the opening
113, and the portion of the opening sealing sheet 14 has a
resisting property to methanol. Further, the seal portion (refer to
(b) of FIG. 3) which surrounds the opening 113 prevents the
methanol from contacting with the sticking portion 14a (refer to
(b) of FIG. 3) pasted to the fuel vessel section 111. Accordingly,
since the opening sealing sheet 14 is not deteriorated by the
methanol and does not peel off from the fuel vessel section 111,
leakage of the methanol can be prevented with certainty.
[0065] FIG. 7 is a side elevational view and so forth showing a
fuel filling kit 20 of a second embodiment.
[0066] As shown in (a) of FIG. 7, the fuel filling kit 20 of the
second embodiment is configured from a filling vessel 22 including
a filling nozzle 21, an opening forming pin 23 (which corresponds
to an opening forming member in the present invention), an opening
sealing sheet 24 (which corresponds to an opening sealing member in
the present invention), and a proximal seal 25.
[0067] The filling nozzle 21 has an elongated cylindrical shape
formed integrally on an end face of the filling vessel 22 such that
it is communicated with the inside of the filling vessel 22. And, a
proximal seal 25 in the form of a disk is attached to the root
portion of the filling nozzle 21. It is to be noted that the
filling nozzle 21, filling vessel 22 and proximal seal 25 are made
of a silicon-based or fluorocarbon-based resin material having a
resisting property to methanol and so forth.
[0068] The filling vessel 22 has a cylindrical shape having
methanol reserved in the inside thereof and has flexibility which
allows the belly of the filling vessel 22 to be pushed by fingers
as indicated by arrow marks from the opposite outer sides toward
the center of the cylinder. Further, the filling vessel 22 has a
filling vessel 22a so that the remaining amount of the methanol
reserved in the inside thereof can be visually confirmed readily
from the outside.
[0069] The opening forming pin 23 is provided for forming a
through-hole in one side face of the fuel vessel section 111 so
that the filling nozzle 21 can be inserted into the fuel cartridge
110. And, the opening forming pin 23 has a drilling portion 23a
made of metal so that formation of a through-hole may be
facilitated. Therefore, if the opening forming pin 23 is pushed
into the fuel vessel section 111 while being rotated, then a
through-hole can be formed safely and rapidly.
[0070] The opening sealing sheet 24 is similar to the opening
sealing sheet 14 of the fuel filling kit 10 of the first embodiment
shown in FIG. 3. In particular, as shown in (a) of FIG. 7, the
opening sealing sheet 24 has a sticking portion 24a (which
corresponds to an attaching portion in the present embodiment), a
methanol blocking portion 24b (which corresponds to a fuel
resisting portion in the present invention), and a seal portion
24c.
[0071] However, the methanol blocking portion 24b and the seal
portion 24c are disposed in a displaced relationship from the
center of the opening sealing sheet 24, and the sticking portion
24a is horizontally elongated. This is intended to make it possible
to paste the opening sealing sheet 24 so as to extend over two side
faces of the fuel vessel section 111. Therefore, the pasting area
increases and the sealing by the opening sealing sheet 24 becomes
stronger.
[0072] Further, the opening 113 (refer to FIG. 6) may be formed
already or the opening 113 may be formed from the beginning as in a
case wherein methanol is filled again into the same fuel cartridge
110, and the opening 113 may be closed up with the opening sealing
sheet 24. In this instance, although the time and labor for forming
the opening 113 newly can be omitted, it becomes necessary to
remove the opening sealing sheet 24 with which the opening 113 is
closed up. In such an instance as just described, if a bent portion
(refer to (b) of FIG. 7) of the opening sealing sheet 24 is
utilized to be pulled up, then the opening sealing sheet 24 can be
exfoliated simply.
[0073] FIG. 8 is an explanatory view illustrating a fuel filling
method for filling methanol by means of the fuel filling kit 20
(filling vessel 22) of the second embodiment shown in FIG. 7.
[0074] In order to fill methanol, the filling nozzle 21 is inserted
into the opening 113 formed in the fuel vessel section 111 as shown
in FIG. 8. Then, the belly of the filling vessel 22 is compressed
from the opposite sides thereof as indicated by arrow marks.
Consequently, the methanol reserved in the inside of the filling
vessel 22 is filled into the fuel vessel section 111 through the
filling nozzle 21.
[0075] Here, if the filling nozzle 21 is inserted to the interior
through the opening 113, then the proximal seal 25 is closely
contacted with the fuel vessel section 111. In particular, if, upon
filling, the filling vessel 22 is pressed against the fuel vessel
section 111, then the opening 113 is closed up fully with the
proximal seal 25 except the portion thereof at the filling nozzle
21. Therefore, an accident that the methanol leaks from the opening
113 can be prevented with certainty.
[0076] Further, in the fuel cartridge 110a shown in (a) of FIG. 8,
a vent hole 114 is provided in the fuel vessel section 111. In
particular, not only the opening 113 but a second opening (the vent
hole 114) is formed on the fuel vessel section 111 by the opening
forming pin 23 (refer to (a) of FIG. 7). Consequently, since the
air in the fuel vessel section 111 is exhausted from the vent hole
114 together with filling of methanol, even if the opening 113 is
closed up with the proximal seal 25, the filling is carried out
smoothly. It is to be noted that, after the methanol is filled, not
only the opening 113 but also the vent hole 114 are sealed with the
opening sealing sheet 24 (refer to FIG. 7).
[0077] Furthermore, a fuel cartridge 110b in which a porous member
115 (for example, silicon-based or fluorocarbon-based resin foam)
is inserted in the inside of the fuel vessel section 111 as shown
in (b) of FIG. 8 is available. In such a fuel cartridge 110b as
just described, the opening 113 is formed keeping away from the
portion at the porous member 115 into which methanol cannot be
filled readily. Consequently, not only methanol can be filled
efficiently, but also damage to the porous member 115 by the
opening forming pin 23 (refer to (a) of FIG. 7) can be
prevented.
[0078] FIG. 9 is a sectional view showing a filling vessel 32 of a
fuel filling kit 30 of a third embodiment.
[0079] As shown in FIG. 9, the fuel filling kit 30 of the third
embodiment uses a piston 33 to fill methanol. In particular, the
filling vessel 32 is a transparent or translucent vessel of the
injector type and not only has a filling nozzle 31 at a free end
side thereof but also has the piston 33 in the inside thereof. And,
methanol is reserved in the filling vessel 32 between the filling
nozzle 31 and the piston 33. Therefore, if a handle 34 projecting
to the outside of the filling vessel 32 is pushed in as indicated
by an arrow mark, then pressure acts upon the methanol in the
filling vessel 32 by movement of the piston 33 and the methanol can
be filled into the fuel cartridge 110.
[0080] Further, the filling nozzle 31 is configured from a coaxial
double cylinder. The inside of the inner side cylinder which
configures the filling nozzle 31 forms a fuel supplying portion 31a
for supplying methanol in the filling vessel 32, and a portion
between the inner side cylinder and the outer side cylinder serves
as a gas exhausting portion 31b for exhausting gas in the fuel
cartridge 110. It is to be noted that the gas exhausting portion
31b is connected to a space in the filling vessel 32, which is
formed on the opposite face side to the face by which the piston 33
exerts pressure to act upon the methanol, by a transparent or
translucent vent pipe 35.
[0081] Furthermore, the filling nozzle 31 has a seal rubber member
36 (which corresponds to a seal member in the present invention) on
the outer side thereof. This seal rubber member 36 is made of a
silicon-based or fluorocarbon-based rubber material having a
resisting property to liquid fuel such as methanol. And, when the
filling nozzle 31 is inserted into an opening 113a, the seal rubber
member 36 closes up to seal to the opening 113a. It is to be noted
that, while the filling nozzle 31 has the fuel supplying portion
31a and the gas exhausting portion 31b, since it has a form of a
double cylinder, there is an advantage that only one opening 113a
may be used if it has a size conforming to the outer diameter of
the filling nozzle 31 and only one seal rubber member 36 may be
used similarly.
[0082] With the fuel filling kit 30 of the third embodiment having
such a configuration as described above, a positive pressure
generated by movement of the piston 33 toward the filling nozzle 31
fills the methanol in the filling vessel 32 into the fuel cartridge
110 through the fuel supplying portion 31a of the filling nozzle
31. Simultaneously, the space in the filling vessel 32 formed on
the opposite face side to the face on which the piston 33 causes
the methanol to exert the positive pressure to act is expanded to
produce a negative pressure. Therefore, as the filling of methanol
proceeds, the internal gas of the fuel cartridge 110 is sucked into
the gas exhausting portion 31b. Consequently, not only the filling
amount of methanol can be adjusted arbitrarily by the amount of
movement of the piston 33, but the movement of the piston 33
(filling of methanol) is smoothened.
[0083] Further, because the opening 113a is closed up with the seal
rubber member 36, not only leakage of methanol upon fitting is
prevented, but all of the internal gas of the fuel cartridge 110 is
exhausted through the gas exhausting portion 31b. Then, the
internal gas is accumulated into the internal space of the filling
vessel 32 through a vent pipe 35. Therefore, even if the internal
gas contains evaporated methanol, the methanol can be recovered
safely without leaking to the outside.
[0084] Furthermore, because the remaining amount of the methanol in
the transparent (translucent) filling vessel 32 can be visually
confirmed readily from the outside, the methanol in the filling
vessel 32 can be filled into the fuel cartridge 110 so that all of
it can be used up. Besides, if methanol which remains in the form
of liquid flows in from the gas exhausting portion 31b of the
filling nozzle 31 by excessive filling of methanol or the like,
then the flowing in can be confirmed through the transparent
(translucent) vent pipe 35. Therefore, methanol can be filled
within an appropriate range (excessive filling and so forth can be
prevented). It is to be noted that, if the piston 33 in a state in
which it is pushed in the filling vessel 32 is pulled up, then
since new methanol can be sucked into the filling vessel 32,
filling into the fuel cartridge 110 can be carried out by any
number of times by the filling vessel 32.
[0085] FIG. 10 is a sectional view showing a filling vessel 42 of a
fuel filling kit 40 of a fourth embodiment.
[0086] As shown in FIG. 10, in the fuel filling kit 40 of the
fourth embodiment, methanol is filled by a piston 43 similarly as
in the fuel filling kit 30 of the third embodiment shown in FIG. 9.
In particular, if a handle 44 is pushed in as indicated by an arrow
mark, then methanol in the filling vessel 42 is filled into the
fuel cartridge 110 through a fuel supplying portion 41a of a
filling nozzle 41 by movement of the piston 43. It is to be noted
that the opening 113a in which the filling nozzle 41 is inserted is
closed up and sealed with a seal rubber member 47, leakage of the
methanol upon filling is prevented.
[0087] Further, as the filling of methanol proceeds, internal gas
of the fuel cartridge 110 enters a gas exhausting portion 41b of
the filling nozzle 41. And, in the fuel filling kit 40 of the
fourth embodiment, such a vent pipe 35 as in the fuel filling kit
30 of the third embodiment shown in FIG. 9 is not provided, but the
gas exhausting portion 41b has an exhaust port 45 above the seal
rubber member 47 as shown in FIG. 10. Therefore, the internal gas
entering the gas exhausting portion 41b is exhausted to the outside
of the fuel cartridge 110 through the exhaust port 45.
[0088] With the fuel filling kit 40 of the fourth embodiment having
such a configuration as described above, the filling vessel 42 is
formed in a reduced size and can be simplified in structure. It is
to be noted that the filling vessel 42 has a vent port 46 for
introducing, upon filling of methanol, the air into a space on the
opposite side to a face on which the piston 43 causes the methanol
to exert the positive pressure to act so that the movement of the
piston 43 may be smoothened.
[0089] FIG. 11 is a sectional view showing a filling vessel 52 of a
fuel filling kit 50 of a fifth embodiment.
[0090] As shown in FIG. 11, in the fuel filling kit 50 of the fifth
embodiment, a filling nozzle 51 is formed from two cylindrical
pipes. And, the inside of one (longer one) of the cylindrical pipes
which configure a filling nozzle 51 serves as a fuel supplying
portion 51a for supplying the methanol in the filling vessel 52,
and the inside of the other (shorter one) cylindrical pipe serves
as a gas exhausting portion 51b for exhausting the internal gas of
the fuel cartridge 110. It is to be noted that, in the fuel
cartridge 110, two openings 113a and 113b are formed so as to
correspond to the fuel supplying portion 51a and the gas exhausting
portion 51b of the filling nozzle 51, for example, by means of the
opening forming pin 13 (refer to FIG. 3).
[0091] Further, the fuel supplying portion 51a of the filling
nozzle 51 has a seal rubber member 56a made of a silicon-based or
fluorocarbon-based rubber material having a resisting property to
liquid fuel such as methanol, and the gas exhausting portion 51b
has a similar seal rubber member 56b. Therefore, if the filling
nozzle 51 is inserted, then the openings 113a and 113b are closed
up and sealed with the seal rubber members 56a and 56b.
[0092] Furthermore, the filling vessel 52 is transparent or
translucent and has a fuel reserving portion 52a, a gas
accommodating portion 52b and a space portion 52c. And, the fuel
reserving portion 52a is connected to the fuel supplying portion
51a of the filling nozzle 51 and has methanol reserved in the
inside thereof. Furthermore, the gas accommodating portion 52b is
connected to the gas exhausting portion 51b of the filling nozzle
51 and accommodates the internal gas of the fuel cartridge 110.
[0093] Also in the fuel filling kit 50 of the fifth embodiment
having such a configuration as described above, methanol is filled
by a piston 53 similarly as in the fuel filling kit 30 of the third
embodiment shown in FIG. 9. In particular, if a handle 54 is pushed
in as indicated by an arrow mark, then pressure acts upon the
methanol by movement of the piston 53, and the methanol reserved in
the fuel reserving portion 52a of the filling vessel 52 is filled
into the fuel cartridge 110 through the fuel supplying portion 51a
of the filling nozzle 51.
[0094] Here, methanol absorber 55 is disposed in the gas
accommodating portion 52b of the filling vessel 52. As this
methanol absorber 55, for example, activated carbon, silica gel,
zeolites such as molecular sieves and so forth are suitably
applied. And, the methanol absorber 55 absorbs methanol (liquid
methanol or evaporated methanol) entering the gas accommodating
portion 52b through the gas exhausting portion 51b of the filling
nozzle 51. It is to be noted that a catalyst for oxidizing alcohols
such as methanol (noble metal catalysts such as platinum (Pt) and
palladium (Pd)) may be used in place of the methanol absorber
55.
[0095] Further, the gas accommodating portion 52b of the filling
vessel 52 is connected to the space portion 52c which is formed on
the opposite face side to the face on which the piston 53 causes
the methanol to exert the positive pressure to act on the
downstream side with respect to the methanol absorber 55.
Therefore, if the piston 53 is moved toward the filling nozzle 51
to cause the methanol in the fuel reserving portion 52a to generate
positive pressure to fill the methanol into the fuel cartridge 110,
then the space portion 52c is expanded by the movement of the
piston 53 to generate a negative pressure. Consequently, since also
the gas accommodating portion 52b is placed into a negative
pressure state, the internal gas of the fuel cartridge 110 is
absorbed into the gas exhausting portion 51b of the filling nozzle
51.
[0096] Besides, because the openings 113a and 113b are closed up
with the seal rubber members 56a and 56b, respectively, not only
leakage of methanol upon filling can be prevented, but all of the
internal gas of the fuel cartridge 110 is exhausted effectively
through the gas exhausting portion 51b. And, the internal gas is
accommodated into the gas accommodating portion 52b of the filling
vessel 52 through the methanol absorber 55.
[0097] As a result, the fuel filling kit 50 of the fifth embodiment
not only can smoothen filling of methanol but also can recover,
even if the internal gas contains evaporated methanol, the methanol
by absorbing the methanol into the methanol absorber 55. Therefore,
safety is further improved. It is to be noted that, where methanol
which remains in the form of liquid is sucked in from the gas
exhausting portion 51b of the filling nozzle 51, also the methanol
is recovered fully by the methanol absorber 55.
[0098] FIG. 12 shows a sectional view showing a filling vessel 62
of a fuel filling kit 60 of a sixth embodiment.
[0099] As shown in FIG. 12, also in the fuel filling kit 60 of the
sixth embodiment, a filling nozzle 61 is configured from two
cylindrical pipes of a fuel supplying portion 61a and a gas
exhausting portion 61b similarly as in the fuel filling kit 50 of
the fifth embodiment shown in FIG. 11. Further, openings 113a and
113b are closed up and sealed with seal rubber members 66a and 66b.
Furthermore, a transparent or translucent filling vessel 62 has a
fuel reserving portion 62a, a gas accommodating portion 62b and a
space portion 62c. And, methanol is filled by a piston 63.
[0100] However, the fuel reserving portion 62a of the filling
vessel 62 has a bag-like shape having flexibility, and methanol is
reserved in the bag. Further, the piston 63 is inserted in the gas
accommodating portion 62b. And, the gas accommodating portion 62b
has a vent port 65a on the opposite side thereof to the filling
nozzle 61 side and is communicated with the outside. Furthermore,
the space portion 62c has a vent port 65b on the opposite side
thereof to the filling nozzle 61 side and is communicated with the
outside.
[0101] With the fuel filling kit 60 of the sixth embodiment having
such a configuration as described above, if a handle 64 is pulled
as indicated by an arrow mark, then the piston 63 moves toward the
vent port 65a, and the gas accommodating portion 62b of the filling
vessel 62 is placed into a negative pressure. Therefore, the
internal gas of the fuel cartridge 110 is sucked in from the gas
exhausting portion 61b of the filling nozzle 61 and accommodated
into the gas accommodating portion 62b. Consequently, even if the
internal gas contains evaporated methanol, the methanol can be
recovered safely. It is to be noted that, since the air of the gas
accommodating portion 62b escapes from the vent port 65a, the
movement of the piston 63 is carried out smoothly.
[0102] Further, because the openings 113a and 113b are closed up
with the seal rubber members 66a and 66b, respectively, when the
internal gas is exhausted from the gas exhausting portion 61b of
the filling nozzle 61, the inside of the fuel cartridge 110 is
placed into a negative pressure state. Then, since the space
portion 62c of the filling vessel 62 is maintained in an
atmospheric pressure state through the vent port 65b, the fuel
reserving portion 62a in the form of a bag having flexibility is
contracted as indicated by an arrow mark and the methanol is sucked
out through the fuel supplying portion 61a of the filling nozzle
61. As a result, the methanol is filled into the fuel cartridge
110.
[0103] In this manner, in the fuel filling kit 60 of the sixth
embodiment, the inside of the fuel cartridge 110 is placed into a
negative pressure state to suck out methanol from the fuel
reserving portion 62a of the filling vessel 62. Therefore, even if
the handle 64 is pulled as indicated by an arrow mark to move the
piston 63 to the vent port 65a side, if the inside of the fuel
cartridge 110 is not placed into a negative pressure state by
pressure of the evaporated methanol or the like (if the inside of
the fuel cartridge 110 has a positive pressure), then methanol is
not filled. Accordingly, the safety upon filling is further
improved.
[0104] While, in the embodiments described above, methanol is used
as the fuel for electric power generation to be used in the fuel
cell system 100, the fuel for electric power generation is not
limited to the methanol only if it is liquid fuel which contains
hydrogen in composition thereof. In particular, also it is possible
to use alcohol type liquid fuel such as ethanol or butanol,
dimethyl ether or isobutane which assume a form of gas under a
room-temperature normal-pressure condition, and liquid obtained by
liquefying hydrocarbons such as natural gas.
[0105] While, in the embodiments described above (for example, in
the first embodiment), the filling nozzle 11 of the fuel filling
kit 10 is formed integrally with the filling vessel 12, a filling
nozzle as a separate member may be attached to a filling vessel
upon filling. Further, the piston 13 may be configured such that it
can be drawn out from the filling vessel 12 and methanol is
supplied into the filling vessel 12 from the opposite side to the
filling nozzle 11.
[0106] While, in the embodiments described above (for example, in
the first embodiment), the fuel filling kit 10 has the opening
forming pin 13, since the opening 113 may be provided in advance in
the fuel cartridge 110 or a removable opening sealing member may be
attached to the opening 113, an opening formation member may not
belong to the fuel filling kit. Further, the opening sealing member
may be a plug or the like which does not close up the opening by
pasting a sheet like the opening sealing sheet 14 but is fitted
into the opening or the like to seal the opening.
[0107] It should be understood that various changes and
modifications to the presently preferred embodiments described
herein will be apparent to those skilled in the art. Such changes
and modifications can be made without departing from the spirit and
scope of the present invention and without diminishing its intended
advantages. It is therefore intended that such changes and
modifications be covered by the appended claims.
* * * * *