U.S. patent application number 12/842183 was filed with the patent office on 2010-11-18 for float glass process for making thin flat glass and thin flat glass substrate made with same.
Invention is credited to Ulrich Lange, Andreas Langsdorf, Andreas Morstein, Andreas Roters, Armin Vogl.
Application Number | 20100291347 12/842183 |
Document ID | / |
Family ID | 36201739 |
Filed Date | 2010-11-18 |
United States Patent
Application |
20100291347 |
Kind Code |
A1 |
Langsdorf; Andreas ; et
al. |
November 18, 2010 |
FLOAT GLASS PROCESS FOR MAKING THIN FLAT GLASS AND THIN FLAT GLASS
SUBSTRATE MADE WITH SAME
Abstract
The thin flat glass substrate, especially for display
engineering, has a thickness of less than 1.5 mm, a length of at
least 1800 mm, a width of at least 1800 mm and a difference between
a smallest thickness and largest thickness of less than 50 .mu.m.
The float glass process for making the improved flat glass
substrate provides flags (9) in the molten metal bath in the
hot-spread region on both sides of the forming glass sheet to
minimize the variation in thickness of the thin flat glass
substrate formed by the process.
Inventors: |
Langsdorf; Andreas;
(Ingelheim, DE) ; Lange; Ulrich; (Mainz, DE)
; Vogl; Armin; (Jena, DE) ; Morstein; Andreas;
(Jena, DE) ; Roters; Andreas; (Mainz, DE) |
Correspondence
Address: |
STRIKER, STRIKER & STENBY
103 EAST NECK ROAD
HUNTINGTON
NY
11743
US
|
Family ID: |
36201739 |
Appl. No.: |
12/842183 |
Filed: |
July 23, 2010 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
|
|
11260605 |
Oct 27, 2005 |
|
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12842183 |
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Current U.S.
Class: |
428/141 |
Current CPC
Class: |
Y10T 428/24355 20150115;
C03B 18/06 20130101 |
Class at
Publication: |
428/141 |
International
Class: |
B32B 3/00 20060101
B32B003/00 |
Foreign Application Data
Date |
Code |
Application Number |
Oct 29, 2004 |
DE |
10 2004 052 568.4 |
Claims
1. A flat glass substrate, especially for display engineering, with
a thickness of less than 1.5 mm, a length of at least 1800 mm, a
width of at least 1800 mm and a difference between a smallest value
of said thickness and a largest value of said thickness of less
than 50 .mu.m; wherein said flat glass substrate is made by a float
glass process comprising the steps of: a) pouring a hot glass melt
(4) on a molten metal bath (2) contained in a float tank, so that
melted glass freely spreads out in a hot spread region (I) of the
molten metal bath, said hot spread region being a section of the
molten metal bath in which the melted glass freely spreads under
the influence of gravity; b) arranging flags (9), which do not
contact a glass sheet (3, 3') forming from the melted glass, in the
molten metal bath in the hot spread region on both sides of the
melted glass with a height, an orientation, and with a spacing from
a side wall of the float tank, a spacing from the melted glass, and
a spacing from a bottom (11) of the float tank, so that thickness
variations in the glass sheet forming from the melted glass are
minimized; c) engaging the glass sheet with top rollers in a region
of the metal bath that is downstream from the hot spread region to
further draw out the glass sheet; and d) imparting a final outlet
speed to the glass sheet (3, 3') by accelerating the glass
sheet.
2. The flat glass substrate as defined in claim 1, wherein said
thickness is from 0.4 mm to 1.1 mm.
3. The flat glass substrate as defined in claim 1, with an edge
length of up to 2500 mm.
4. The flat glass substrate as defined in claim 1, wherein said
difference is less than 30 .mu.m.
5. The flat glass substrate as defined in claim 1, wherein said
difference is less than 15 .mu.m.
6. The flat glass substrate as defined in claim 1, containing at
most 1000 ppm of sodium ions.
7. The flat glass substrate as defined in claim 1, wherein in said
float glass process each of the flags is a plate immersed in the
molten metal bath between the side wall of the float tank and an
outer edge of the glass sheet (3,3') without contacting the glass
sheet.
8. The flat glass substrate as defined in claim 1, wherein in said
float glass process said flag extends above the molten metal bath
in a side region adjacent to said side wall and is oriented
substantially transverse to a feed direction of the glass sheet on
the molten melt bath.
9. The flat glass substrate as defined in claim 1, wherein in said
float glass process said flags (9) are made of graphite and
oriented at an angle of 90.degree. to 30.degree. to a feed
direction of the glass sheet (3, 3').
Description
CROSS-REFERENCE TO RELATED APPLICATIONS
[0001] This is a divisional, filed under 35 U.S.C. 120, of U.S.
patent application Ser. No. 11/260,605, filed on Oct. 27, 2005. The
invention described and claimed herein below is also described in
the aforesaid U.S. patent application, the entire content of which
is hereby expressly incorporated by reference thereto.
[0002] The invention described and claimed herein below is also
described in German Patent Application No. 10 2004 052 568.4, which
was filed on Oct. 29, 2004 in Germany, the entire content of which
is hereby expressly incorporated by reference. The aforesaid German
Patent Application provides the basis for a claim of priority of
invention for the invention described and claimed herein below
under 35 U.S.C. 119 (a) to (d).
BACKGROUND OF THE INVENTION
[0003] 1. The Field of the Invention
[0004] The present invention relates to thin flat glass substrates
with a thickness of less than 1.5 mm and, more particularly to thin
flat glass substrates for display engineering with reduced
thickness variations, and to a method of manufacturing these thin
flat glass substrates.
[0005] 2. The Description of the Related Art
[0006] Thin flat glass substrates are, among other things, used to
make flat display screens, e.g. plasma display panels (PDP), field
emission displays (FED), TFT liquid crystal display screens
(TFT=thin film transistor), STN-liquid crystal display screens
(STN=Super twisted nematic), PALC display screens (PALC=Plasma
assisted liquid crystal), EL displays (EL=electroluminescent) and
the like.
[0007] In flat display screens either a thin layer of liquid
crystal compound is placed between two glass panels or respective
dielectric layers are applied to the front and rear side of the
rear and/or front glass panels, from which cells are formed, in
which a phosphor is placed, according to the type of display.
[0008] It is important that the layer thickness of the liquid
crystal layer and/or the thickness of the dielectric layer is
maintained exactly so that especially in the case of display
screens with comparatively large dimensions no disturbing color
adulteration or brightness variations (shadows) occur. Since layer
thickness (currently about 30 microns) is always becoming smaller
and display screens are always becoming larger, these requirements
have attained increasing importance.
[0009] Although float glass is excellently suited for display
applications because of its fire polished surface, it has not been
possible to make display glass with thickness variations of less
than according to the float process with the currently required
large substrate format with edge lengths of above 1800 mm.
[0010] The presence of flows in the float bath, which usually
comprise melted tin, explains the presence of thickness variations
in float glass. These very complex flows are the result of opposing
mechanical and thermally induced flows, i.e. the flow dynamics and
thermal effects overlap or are superimposed on each other.
[0011] A flow in the motion direction of the glass sheet, i.e. a
flow of the hot section of the tin bath in the direction of the
cold section arises directly under the glass sheet due to the
motion of the glass sheet. In the free surface of the tin bath
beside the glass sheet a return flow, i.e. a flow in the opposite
direction, arises so that the colder tin flows in the direction of
the hotter front section of the tin bath. Temperature
non-uniformities, which are transferred to the hot forming glass
sheet and lead to viscosity non-uniformities, arise because of the
mixing of these flows. These viscosity changes can then lead to
undesired thickness fluctuations and waviness in the glass sheet.
These fluctuations are the more noticeable, the more strongly the
glass sheet is drawn out, i.e. the thinner the glass sheet becomes
during manufacture.
[0012] Attempts have already previously been made to prevent and/or
suppress these lateral return flows by building flow barriers,
so-called flags, e.g. as described in DE-PS 1771 762 or DE-PS 2146
063. According to DE-PS the return flow is channeled by means of
barriers or dam. The return flow formed between the lateral walls
of the float tank and the barriers is suppressed or prevented by
means of resistance bodies adjustable in their height and immersed
in the return flow. DE-PS 2146 063 describes a special bottom
structure for a float bath for guiding the underflow of bath liquid
at the bottom of the flow bath, which prevents the lateral return
flow by means of lateral baffle plates immersed in the flow bath
(FIG. 8 of this reference). EP 031 772 B1 describes the arrangement
and action of flags in great detail. In this reference it is also
shown that these flags can be arranged not only transversely to the
feed direction of the glass sheet, but also can be at an angle to
it. In JP 2000-313628 a flag is shown, which is arranged
substantially under the bath surface. The angle, at which this flag
is immersed in the molten metal, can be adjusted as well as the
distance between the flag and the glass sheet.
[0013] In spite of the improvements in the flat glass manufacturing
process up to now it has not been possible to make large-area thin
flat glass substrates with a thickness of less than 1.5 mm, which
met high quality specifications.
SUMMARY OF THE INVENTION
[0014] It is an object of the present invention to provide a large
surface or large area thin flat glass substrate, especially for
display engineering, with a thickness of less than 1.5 mm, which
meets high quality requirements, especially regarding permitted
thickness variations.
[0015] It is also an object of the present invention to provide a
process for making large area thin flat glass substrates,
especially for display engineering, with a thickness of less than
1.5 mm and which have high quality, especially regarding thickness
variations.
[0016] According to the invention the flat glass substrate has a
thickness of less than 1.5 mm, a length of at least 1800 mm, a
width of at least 1800 mm and a difference between a smallest and
largest thickness of less than 50 .mu.m.
[0017] According to the invention the float glass process for
making this flat glass substrate includes the steps of:
[0018] a) pouring a hot glass melt on a molten metal bath so that
melted glass spreads out on the molten metal bath because of the
action of gravity to form a hot spread region;
[0019] b) arranging flags, which do not contact a glass sheet
forming from the melted glass, in the molten metal bath in the hot
spread region on both sides of the flowing melted glass; and
[0020] c) imparting a final outlet speed to the glass sheet by
accelerating the glass sheet.
[0021] The thin flat glass substrate according to the invention
fulfills the required high quality requirements as it comes from
the float plant, i.e. without subsequent polishing. If a polishing
is still required for any reason, it can be performed especially
economically and/or efficiently, since the polishing work is kept
very small because of the high surface quality of the product
coming from the float plant.
[0022] It was found that a flat glass substrate with a thickness of
less than 1.5 mm, respective edge lengths of more than 1800 mm and
with a difference between the smallest and largest thickness of
less than 50 .mu.m met the highest requirements of display
engineering applications. Because of weight saving considerations
the glass substrates with very large surface area should be made as
thin as possible. These substrates have a preferred thickness of
from 0.4 to 1.1 mm. If the thickness is less than 0.4 mm, the glass
substrates is of course always still suitable for making a display
however the handling of this sort of very thin substrate,
especially with large dimensions, requires a clearly greater effort
and/or expense. The thin flat glass substrates have a width of over
1800 mm; in practice from handling reasons alone they may only
infrequently exceed a width of from 3.5 to 4 m. Also when even
larger formats are made, they are produced in practice by long
divisions of the given width format. Widths up to about 2.5 m are
especially easily manipulated or handled and thus are preferred.
The length of the thin glass substrate is in the same size range as
the dimensions given for the width for the same reasons, namely to
provide easy handling. Theoretically the length of the substrate
has no limits because the manufacturing process is continuous.
However since very thin glass bends very easily, the substrate can
be marketed in a rolled-up form, i.e. as a roll, with a suitable
bending radius. Furthermore it is advantageous when the difference
between the smallest and the largest thickness is less than 30
.mu.m, especially less than 15 .mu.m, since the increasing
requirements of the processing industries are taken into
consideration. On account of the good surface quality of float
glass, which has the quality of fire-polished glass, a float glass
is preferred with the above-stated parameters. The glass according
to the invention is especially suitable for use in TFT displays.
For these applications a sodium-free glass except for unavoidable
trace sodium ion impurities is used. Sodium ion content may not
exceed 1000 ppm in these glasses.
[0023] In the known float glass process for making flat glass a
melt is poured onto a molten metal bath and the liquid glass
spreads on the metal melt, thus forming a hot spread region. The
spreading of the glass is subsequently assisted by so-called top
rollers, which engage at the edge of the glass sheet and draw the
glass sheet out further. A final outlet speed is imparted to the
glass sheet by acceleration in the flow direction of the glass
sheet behind the top rollers, which takes the molten metal
downstream under the glass sheet and leads to a colder return flow
in the upstream direction. The part of the return flow formed
beside the glass sheet in the drawing region in the free surface
(an additional part of the return flow occurs in the deeper layers
of the bath) is prevented or hindered by placing barriers (flags)
in the side surfaces of the tin bath in this region.
[0024] It was surprisingly found that the placement of flags in a
region of the float bath, in which no return flow exists at the
surface and in which the flags should have scarcely any effect
according to the conventional understanding, still clearly reduce
the thickness variations in the product float glass. This region of
the float bath is the hot spread region, also the region, in which
the glass freely spreads further under the influence of gravity. It
is located upstream of the top rollers in the flow direction of the
glass sheet. The glass has a viscosity of less than 10.sup.6 dPas,
especially a viscosity of 10.sup.4 to 10.sup.6 dPas, in this
region.
BRIEF DESCRIPTION OF THE DRAWING
[0025] The objects, features and advantages of the invention will
now be illustrated in more detail with the aid of the following
description of the preferred embodiments, with reference to the
accompanying figures in which:
[0026] FIG. 1 is a schematic top plan view of a longitudinally
extending float glass tank according to the prior art;
[0027] FIG. 2 is a schematic top plan view of a longitudinally
extending float glass tank according to the present invention;
[0028] FIGS. 3a to 3c are respective cross-sectional views through
the float glass tank according to the invention showing a flag;
[0029] FIG. 4 is a graphical illustration showing the variation of
thickness versus time for a flat glass substrate made with the
float glass process of the prior art; and
[0030] FIG. 5 is a graphical illustration showing the variation of
thickness versus time for a flat glass substrate with the float
glass process of the present invention.
DETAILED DESCRIPTION OF THE INVENTION
[0031] FIG. 1 shows a longitudinally extended float glass tank
according to the prior art. The prior art float tank has sidewalls
1 and contains a bath 2 of melted tin. The glass sheet 3, which
moves in the direction of the arrow, floats on the tin bath. The
float tank has plural different sections or regions Ito IV, which
may differ from each other as follows.
[0032] In section I the fluid glass is poured on the tin bath and
spreads out on it (Hot spread region).
[0033] In section II longitudinal forces and forces directed toward
the outside are exerted under the influence of the top rollers and
the outlet rollers; the glass is already drawn out and is
thinner.
[0034] In section III the glass sheet attains its final form by
action of the outlet rollers. Section II and III together form the
drawing zone, i.e. the region, in which the glass is drawn out and
attains its final form.
[0035] In section IV the glass solidifies and its cooling takes
place. The liquid glass 4 is poured on the tin bath 2 at the
beginning of zone or section I and already spreads out there to its
equilibrium thickness of about 6 to 7 mm. Subsequently it forms the
finished glass sheet 3', which is drawn by the outlet rollers 5
from the float chamber. The desired thickness of the glass sheet is
attained by the joint action of the top rollers 6 and the outlet
rollers 5. The top rollers are driven with speeds adjusted to the
increasing speed of the glass sheet from the outside of the tank.
The top rollers are slightly inclined to the feed direction of the
glass sheet, are driven by means of the shafts 8 and unshown drive
motors and exert a pulling force from the outside on the glass, so
that a preliminary tapering of the glass sheet occurs. The motion
of the glass sheet in the drawing zone causes a flow of metal
directly under the glass sheet in the same direction. This flow
induces a corresponding reverse flow at the bottom and sides of the
bath. This lateral flow is prevented and/or suppressed by means of
lateral flags 7 projecting into the float bath.
[0036] The float tank according to the invention shown in FIG. 2
differs from the prior art float tank shown in FIG. 1 because flags
9 are introduced in the melted tin beside the melted glass
spreading out on the melted tin under the influence of gravitation
in the hot spread region, i.e. in the region upstream or in front
of the top rollers. The number of flags 9 depends on the size of
the float chamber and/or the hot spread region. For optimum results
one uses 1 to 3 flags on each side of the tank per meter of tank
length in the hot spread region. However a definite improvement is
already achieved with a respective flag 9 on each side of the tank.
The glass quality may be improved with the flags according to the
invention in the hot spread region in any float bath, even when no
flags are present in the drawing region (sections II and III in
FIGS. 1 and 2). All models conventionally used in float baths can
be used as flags 9. The flags are plates, which are immersed in the
bath between the walls of the float tank and the edge of the glass
sheet and which are arranged substantially transverse to the feed
direction of the glass sheet.
[0037] FIGS. 3a and 3c show respective cutaway side cross-sectional
views of a float bath with sidewall 1 and bottom 11, tin bath 2 and
glass sheet 3 floating on the tin bath. A flag 9 is introduced
between the lateral edge of the glass sheet 3 and the tank wall 1,
which extends from above into the tin bath 2. The flag 9 preferably
extends to the bottom 11 of the float bath, however it can, as
shown in FIG. 3b, be arranged with some spacing from the bottom.
The spacing between the flag 9 and the sidewall 1 is kept as small
as possible in order to maximize the effect of the flag. A small
spacing of the flag from the container wall does not impair the
action of the flag. However that spacing should not be too large,
since otherwise the acting surface of the flag is reduced. The
lateral spacing of the flag to the edge of the glass sheet 3 should
similarly be as small as possible, however direct contact of the
flag with the glass is undesirable. Distances of about 10 to 50 cm
are preferred for reasons of easy handling and adjustment. The flag
9 can, as shown in FIGS. 3b and 3c, extend under the edge of the
glass sheet 3. In FIG. 3b that is caused by a step or shoulder in
the flag, while in FIG. 3c the flag has an inclined upper edge. The
flag 9 is attached to a handle 15, which is guided through the
container wall 1 and is attached there in a conventional not
illustrated manner. The flag 9 is usually arranged at an angle of
90.degree. to the feed direction of the glass sheet 3. However it
can be oriented at an angle to the feed direction for an especially
exact adjustment of the action of the flag. The angle can be up to
30.degree., however should usually not be less than 45.degree..
[0038] It is especially beneficial when the flag is equipped with
an adjusting device by which its height, angle and spacing from the
side wall 1, the glass sheet 3 and the spacing to the container
bottom 11 can be adjusted. This adjusting means is especially not
shown, since it can be set up with current engineering knowledge
without difficulty. The upper edge of the flag 9 should be above
the level of the bath in the side region. The use of completely
immersed flags, e.g. known from JP 2003313628, leads to a poor
action.
[0039] The material, from which the flag 9 is made, must be inert
to metal and the protective gas over the float bath and can resist
the high temperatures present in the gas chamber. For example,
graphite, mullite, sillimanite, fused quartz and composition
materials have proven suitable for the flag. The holder can be made
of materials like e.g. tempered steel.
[0040] Clearly reduced thickness variations of the thin glass
produced can be attained by the arrangement of the flags in the hot
spread region. Furthermore the stability of the glass sheet in
regard to its width and its positioning on the float bath could be
clearly improved.
Example
[0041] A thin flat glass sheet with a thickness of about 0.7 mm was
drawn in a conventional float plant according to the prior art. The
thickness of the glass sheet leaving the float plant of the prior
art was measured. This thickness is shown graphically in FIG. 4.
The measurement occurred by a double reflection method, in which a
laser contour line is projected on the glass sheet and the
thickness is calculated from the spacing of the received
reflections from the front side and the rear side of the glass
sheet respectively. The thickness variation is shown in FIG. 4.
Then a flag was inserted in the molten metal on both sides of the
forming glass sheet with a spacing of about 3.5 m from the front
side of the float bath (bath inlet) in each case. The angle of the
flag to the lateral wall amounted to 90.degree., the spacing to the
sidewall 0 cm and the spacing to the glass flow 20 cm. The flag had
a height of 70 cm and rests on the float tank bottom. The thickness
fluctuation attained according to this structure is shown in FIG.
5. The thickness variation of the prior art thin flat glass sheet
or substrate determined from FIG. 4 is about 57 .mu.m, while the
corresponding thickness variation for the thin flat glass sheet or
substrate according to the invention is about 18 .mu.m.
[0042] While the invention has been illustrated and described as
embodied in a float glass process for making thin flat glass and
thin flat glass substrate made with same, it is not intended to be
limited to the details shown, since various modifications and
changes may be made without departing in any way from the spirit of
the present invention.
[0043] Without further analysis, the foregoing will so fully reveal
the gist of the present invention that others can, by applying
current knowledge, readily adapt it for various applications
without omitting features that, from the standpoint of prior art,
fairly constitute essential characteristics of the generic or
specific aspects of this invention.
[0044] What is claimed is new and is set forth in the following
appended claims.
* * * * *