U.S. patent application number 12/365973 was filed with the patent office on 2009-09-10 for method and composition for reducing the drying time of hair.
Invention is credited to Andreas Flohr, Sarah Maillefer, Jolanda Pluss.
Application Number | 20090226381 12/365973 |
Document ID | / |
Family ID | 39591221 |
Filed Date | 2009-09-10 |
United States Patent
Application |
20090226381 |
Kind Code |
A1 |
Maillefer; Sarah ; et
al. |
September 10, 2009 |
Method and Composition for Reducing the Drying Time of Hair
Abstract
The invention concerns to a method and composition for improving
the drying time of hair, for example, after bathing, shampooing,
swimming, and the like by impregnating it with a particular amino
functional silicon derivative. In a preferred embodiment the
invention concerns to hair styling compositions that are applied to
dry or wet hair as a leave-in treatment and that additionally
reduces the time to dry the hair during styling; further to
leave-in or rinse-out hair care compositions that additionally
reduces the time to dry the hair.
Inventors: |
Maillefer; Sarah;
(Villarimboud, CH) ; Pluss; Jolanda; (Steffisburg,
CH) ; Flohr; Andreas; (Kronberg, DE) |
Correspondence
Address: |
THE PROCTER & GAMBLE COMPANY;Global Legal Department - IP
Sycamore Building - 4th Floor, 299 East Sixth Street
CINCINNATI
OH
45202
US
|
Family ID: |
39591221 |
Appl. No.: |
12/365973 |
Filed: |
February 5, 2009 |
Current U.S.
Class: |
424/47 ;
424/70.12; 510/122; 8/405 |
Current CPC
Class: |
A61Q 5/00 20130101; A61K
8/898 20130101 |
Class at
Publication: |
424/47 ;
424/70.12; 510/122; 8/405 |
International
Class: |
A61K 9/12 20060101
A61K009/12; A61K 8/89 20060101 A61K008/89; A61Q 5/12 20060101
A61Q005/12; A61Q 5/02 20060101 A61Q005/02; A61Q 5/06 20060101
A61Q005/06; A61Q 5/10 20060101 A61Q005/10 |
Foreign Application Data
Date |
Code |
Application Number |
Feb 11, 2008 |
EP |
08151246.9 |
Claims
1. A hair treating composition comprising a combination of: (A) a
polydimethylsiloxane (P) having aminoalkyl groups and having an
amine number of at least 0.1 meq/g of polydimethylsiloxane (P), and
comprising units of the formula I
R.sup.1.sub.aR.sup.2.sub.bSiO.sub.(4-a-b)/2 (I), in which R.sup.1
are optionally halogen-substituted alkyl radicals having 1-40
carbon atoms, or are --OR or --OH radicals, R are optionally
halogen-substituted alkyl radicals having 1-40 carbon atoms,
R.sup.2 are aminoalkyl radicals of the formula II
--R.sup.3--NR.sup.4R.sup.5 (II), R.sup.3 are divalent hydrocarbon
radicals having 1-40 carbon atoms, R.sup.4 are monovalent
hydrocarbon radicals having 1-40 carbon atoms or are H, R.sup.5 is
a radical of the formula III --(R.sup.6--NR.sup.4).sub.xR.sup.4
(III), R.sup.6 is a divalent radical of the formula IV
--(CR.sup.4R.sup.4--).sub.y (IV), x is 0 or a value from 1 to 40, y
is 1 or 2, a is 0, 1, 2 or 3, b is 0, 1, 2 or 3 and a+b on average
is from 1.5 to 2.5, not more than 9 mol % of the radical R.sup.1
being OH or OR, (B) at least one protonating agent, (C) water, (D)
from 0 to 95 parts by weight of at least one emulsifier and/or
surfactant, and (E) at least one cosmetic hair treatment agent,
selected from the group consisting of hair styling polymers and/or
hair conditioning agents.
2. A composition according to claim 1, in form of an oil-in-water
emulsion or a dispersion.
3. A composition according to claim 1, wherein the
polydimethylsiloxane (P) is present in an amount of from 0.001 to
50% by weight of the total weight of the hair treating
composition.
4. A composition according to claim 1, wherein the composition is a
hair styling composition and comprises 0.1 to 10% by weight of at
least one hair styling polymer.
5. A composition according claim 1, wherein the hair styling
polymer is a nonionic polymer selected from the group consisting
of: polyvinylpyrrolidone, polyvinylcaprolactam,
vinylpyrrolidone/vinyl acetate copolymers, polyvinyl alcohol,
isobutylene/ethylmaleimide-/hydroxyethylmaleimide copolymer;
terpolymer of vinylpyrrolidone, methacrylamide and vinylimidazole;
copolymers of vinylpyrrolidone, vinyl acetate and vinyl
propionate.
6. A composition according to claim 1, characterized in that the
hair styling polymer is a polymer with anionic or anionizable
groups selected from the group consisting of: terpolymers of
acrylic acid, ethyl acrylate and N-tert-butylacrylamide;
crosslinked or uncrosslinked vinyl acetate/crotonic acid
copolymers; terpolymers of tert-butyl acrylate, ethyl acrylate and
methacrylic acid; sodium polystyrenesulfonate; copolymers of vinyl
acetate, crotonic acid and vinyl propionate; copolymers of vinyl
acetate, crotonic acid and vinyl neodecanoate; aminomethylpropanol
acrylate copolymers; copolymers of vinyl-pyrrolidone and at least
one further monomer chosen from acrylic acid, methacrylic acid,
acrylic esters and methacrylic esters; copolymers of methyl vinyl
ether and maleic monoalkyl esters; aminomethylpropanol salts of
copolymers of allyl methacrylate and at least one further monomer
chosen from acrylic acid, methacrylic acid, acrylic esters and
methacrylic esters; crosslinked copolymers of ethyl acrylate and
methacrylic acid; copolymers of vinyl acetate, mono-n-butyl maleate
and isobornyl acrylate; copolymers of two or more monomers chosen
from acrylic acid, methacrylic acid, acrylic esters and methacrylic
esters, copolymers of octylacrylamide and at least one monomer
chosen from acrylic acid, methacrylic acid, acrylic esters and
methacrylic esters; polyesters of diglycol, cyclohexanedimethanol,
isophthalic acid and sulfoisophthalic acid.
7. A composition according to claim 1, wherein the hair styling
polymer is a polymer with cationic or cationizable groups selected
from the group consisting of: cationic cellulose derivatives of
hydroxyethylcellulose and diallyldimethylammonium chloride;
cationic cellulose derivatives of hydroxyethylcellulose and with
trimethylammonium substituted epoxide; poly(dimethyldiallylammonium
chloride); copolymers of acrylamide and dimethyldiallylammonium
chloride; quaternary ammonium polymers formed by the reaction of
diethyl sulfate and a copolymer of vinylpyrrolidone and
dimethylaminoethyl methacrylate; quaternary ammonium polymers of
methylvinylimidazolium chloride and vinylpyrrolidone;
polyquaternium-35; polymer of trimethylammonium-ethyl methacrylate
chloride; polyquaternium-57; dimethylpolysiloxanes terminally
substituted by quaternary ammonium groups; copolymer of
vinylpyrrolidone, dimethylaminopropylmethacrylamide and
methacryloylaminopropyllauryldimethylammonium chloride; chitosan
and salts thereof, hydroxyalkylchitosans and salts thereof,
alkylhydroxyalkylchitosans and salts thereof,
N-hydroxyalkylchitosan alkyl ethers; N-hydroxyalkylchitosan benzyl
ethers; copolymer of vinylcaprolactam, vinylpyrrolidone and
dimethylaminoethyl methacrylate; copolymers of vinylpyrrolidone and
dimethylaminoethyl methacrylate, copolymers of vinylpyrrolidone,
vinylcaprolactam and dimethylaminopropylacrylamide; polyesters or
oligoesters constructed from at least one first monomer type which
is chosen from hydroxy acid substituted by at least one quaternary
ammonium group.
8. A composition according to claim 1, wherein the hair styling
polymer is a zwitterionic and/or an amphoteric polymer selected
from the group consisting of: copolymers of octylacrylamide,
acrylic acid, butylaminoethyl methacrylate, methyl methacrylate and
hydroxypropyl methacrylate; copolymers of lauryl acrylate, stearyl
acrylate, ethylamine oxide methacrylate and at least one monomer
chosen from acrylic acid, methacrylic acid, acrylic esters and
methacrylic esters; copolymers of methacryloylethylbetaine and at
least one monomer chosen from methacrylic acid and methacrylic
esters; copolymers of acrylic acid, methyl acrylate and
methacrylamidepropyltrimethylammonium chloride; oligomers or
polymers preparable from quaternary croton betaines or quaternary
croton betaine esters.
9. A composition according to claim 1, being a hair care
composition and comprising from 0.01 to 50% by weight of at least
one hair conditioning agent.
10. A composition according to claim 9, wherein the hair care
composition is a leave-on product selected from the group
consisting of mousse, gel or emulsion.
11. A composition according to claim 9, wherein the hair care
composition is a hair rinse or a hair shampoo.
12. A composition according to claim 1, wherein the hair
conditioning agent is selected from the group consisting of cyclic
dimethylsiloxanes, linear polydimethylsiloxanes, block polymers of
polydimethyllsiloxane and polyethylene oxide and/or polypropylene
oxide, polydimethylsiloxanes with terminal or lateral polyethylene
oxide or polypropylene oxide radicals, phenyl-substituted
polydimethylsiloxanes, silicone waxes and silicone gums.
13. A composition according to claim 1, wherein the hair
conditioning agent is selected from the group consisting of
paraffin waxes, polyolefin waxes, wool wax, wool wax alcohols,
candelilla wax, olive wax, carnauba wax, Japan wax, apple wax,
hydrogenated fats, fatty alcohols, fatty acid esters, fatty acid
glycerides, fatty acid triglycerides, conditioning emulsifiers,
conditioning surfactants, conditioning thickeners, mineral oils,
isoparaffin oils, paraffin oils, squalane, sunflower oil, coconut
oil, castor oil, lanolin oil, jojoba oil, corn oil or soybean
oil.
14. A composition according to claim 1, wherein the hair
conditioning agent is selected from the group consisting of
betaine, panthenol, panthenyl ethyl ether, sorbitol, protein
hydrolysates, plant extracts.
15. A composition according to claim 11, wherein the hair care
composition is a hair shampoo and comprises 2 to 30% by weight of a
surfactant.
16. A composition according to claim 15, wherein the surfactant is
selected from the group consisting of: addition products of from 2
to 30 mol of ethylene oxide and/or 1 to 5 mol of propylene oxide
onto C8- to C22-fatty alcohols, addition products of from 2 to 30
mol of ethylene oxide and/or 1 to 5 mol of propylene oxide onto
C12- to C22-fatty acids, addition products of from 2 to 30 mol of
ethylene oxide and/or 1 to 5 mol of propylene oxide onto alkyl
phenols having 8 to 15 carbon atoms in the alkyl group, C12- to
C22-fatty acid mono- and diesters of addition products of from 1 to
30 mol of ethylene oxide onto glycerol, addition products of from 5
to 60 mol of ethylene oxide onto castor oil or onto hydrogenated
castor oil, mono-, di- or triesters of phosphoric acid with
addition products of from 2 to 30 mol of ethylene oxide onto C8- to
C22-fatty alcohols, esters of sucrose and one or two C8- to
C22-fatty acids, esters of sorbitan and one, two or three C8- to
C22-fatty acids and a degree of ethoxylation of from 4 to 20,
polyglyceryl fatty acid esters of one, two or more C8- to C22-fatty
acids and polyglycerol having 2 to 20 glyceryl units, alkyl
glycosides, C8-22-alkyldimethylbenzylammonium compounds,
C8-22-alkyltrimethyl-ammonium compounds,
C8-22-alkyldimethylhydroxyethylammonium compounds,
di(C8-22-alkyl)dimethylammonium compounds, C8-22-alkylpyridinium
salts, C.sub.8-22-alkylamidoethyltrimethylammonium ether sulfates,
C8-22-alkylmethylamine oxides, C8-22-alkylaminoethyldimethylamine
oxides.
17. A composition according to claim 1, whereby it has the form of
a gel, a viscous lotion or a spray gel which is sprayed with a
mechanical device, comprises at least one thickening polymer and
has a viscosity of at least 250 mPas (measured using a Bohlin
rheometer CS, measurement body C25 at 25.degree. C. and a shear
rate of 50 s.sup.-1).
18. A composition according to claim 1, wherein it is in the form
of an O/W emulsion, a W/O emulsion or a microemulsion, and
comprises at least one oil or wax according to claim 17, and at
least one surfactant according to claim 20.
19. A composition according to claims 1, wherein it is in the form
of a spray product and is either in combination with a mechanical
pump spray device or in combination with at least one propellant
chosen from propane, butane, dimethyl ether and fluorinated
hydrocarbons.
20. A composition according to claim 1, characterized in that it is
in the form of a foamable product in combination with a device for
foaming, comprises at least one foam-forming surfactant or at least
one foam-forming polymer and is either in combination with a
mechanical pump foam device or in combination with at least one
propellant chosen from propane, butane, dimethyl ether and
fluorinated hydrocarbons.
21. A method for treating human hair on the scalp of a person while
simultaneously reducing the time to dry the hair, comprising the
steps of applying to dry or wet hair the composition of claim 1 and
subsequently drying the hair.
22. A method for styling human hair on the scalp of a person while
simultaneously reducing the time to dry the hair, comprising the
steps of applying to dry or wet hair the composition of claim 1 and
subsequently drying the hair.
23. A method according to claim 22, whereby before or during the
drying step, the hair is mechanically processed to help water to
sheet from the hair by brushing, combing or towelling.
24. A method for dying the hair on the head of a person while
simultaneously reducing the time to dry said hair and to protect
the hair dye on said hair from being washed out, comprising the
steps of: (a) applying a hair dying composition onto the hair to be
dyed, (b) leaving the hair dying composition on the hair for a time
required to dye said hair, (c) optionally rinsing said hair with
water or an aqueous acidic composition, (d) optionally towelling
and/or drying said hair, (e) applying to said hair a compound
according to claim 1 or a hair treating composition as defined in
claim 1 and (f) subsequently drying said hair.
25. A method for enhancing the durability of a hair shape against
humidity, water and hair washings while simultaneously reducing the
time to dry said hair, comprising the steps of: (a) shaping the
hair, (b) optionally rinsing said hair with water or an aqueous
acidic composition, (c) optionally towelling and/or drying said
hair, (d) applying to said hair a compound according to claim 1 or
a hair treating composition as defined in claim 1 and (e)
subsequently drying said hair.
26. A method for enhancing the durability of a hair shape against
humidity, water and hair washings while simultaneously reducing the
time to dry said hair, comprising the steps of: (a) washing said
hair, (b) optionally towelling and/or drying said hair, (c)
applying to said hair a compound according to claim 1 or a hair
treating composition as defined in claim 1 and (d) subsequently
drying and simultaneously shaping said hair.
Description
FIELD OF THE INVENTION
[0001] The invention concerns to a method and composition for
improving the drying time of hair, for example, after bathing,
shampooing, swimming, and the like by impregnating it with a
particular amino functional silicon derivative. In a preferred
embodiment the invention concerns to hair styling compositions that
are applied to dry or wet hair as a leave-in treatment and that
additionally reduces the time to dry the hair during styling;
further to leave-in or rinse-out hair care compositions that
reduces the time to dry the hair.
BACKGROUND OF THE INVENTION
[0002] In order to set and give hold to human hair in order to
stabilize a created hairstyle, in order to improve the styling
properties or the hair structure, hair-treatment compositions in
the form of setting lotions, aerosol and non-aerosol sprays,
setting foams, gels etc. are used. The cosmetic, hair-setting or
haircare polymers usually used for these purposes exhibit good
setting and/or care properties in aqueous, alcoholic or
aqueous-alcoholic media. However, not all requirements such as, for
example, gloss, shine, combability, durability of setting etc. are
often still not satisfied in an entirely satisfactory manner.
[0003] It would be however especially desirable to provide further
decreased drying time for hair styling compositions without any
substantial loss of hair hold performance once the composition is
dried to completion. It would further be desirable to even increase
the hair hold performance of films formed by hair styling
polymers.
[0004] To solve this problem many attempts were made to enhance the
drying time of hair by adding silicone containing materials,
particularly amino functional silicone polymers to the cosmetic
compositions. For example it is known from the prior art, e.g. U.S.
Pat. No. 6,451,747 B1, U.S. Pat. No. 4,673,568, U.S. Pat. No.
4,973,476 and U.S. Pat. No. 5,567,428 that silicone containing
materials, particularly amino functional silicone polymers, known
as "Amodimethicone" may be used as drying aids for cosmetic
compositions.
[0005] These known silicone containing materials however display
the disadvantage that the formed coating on hair is less water
repellent and therefore less efficient in decreasing time to dry
hair; also the coating is less resistant towards washing with
shampoo and gets degraded more rapidly.
[0006] US 2006/0041026 A1 discloses an oil-in-water emulsion
comprising an amino functional silicone polymer that may be used
for the water repellent treatment of porous or nonporous surfaces
like glass, metal, stones, paper, natural and/or synthetic textile
fibers, mineral building materials, plasctics, wood, laminate,
cork, rubber and leather.
[0007] One object of the present invention is to make available a
cosmetic composition, preferably a hair styling composition, which
enhances the drying time of hair.
[0008] A further object is to provide a new hair treatment
composition that reduces the time to dry wet hair and that also
style the hair.
[0009] A further object of the present invention is a hair styling
composition and a method that decrease the drying time for hair
styling compositions without any substantial loss of hair hold
performance.
[0010] Still another object of the invention is to provide hair
treatment compositions that reduce the time to dry wet hair and
that also condition the hair.
[0011] It is an object of the present invention to provide a method
to improve the drying of hair following showering, bathing,
swimming, shampooing, or the like, by changing the hydrophobicity
of the hair shaft to cause de-wetting of the hair.
[0012] A further object of the present invention is to provide a
method for treating hair, preferably for styling hair, which makes
the treated hair water repellent even after one hair wash,
preferably even after more than 2 hair washes.
[0013] Yet another object of the invention is to provide a method
of reducing damage to hair by reducing the time to dry the
hair.
[0014] A further object of the invention is to improve the
flexibility and manageability of hair by maintaining hair hydrated
by locking water inside the hair.
[0015] A further object of the invention is to decrease the drying
time for hair and simultaneously enhance the durability of a hair
shape against hair humidity, water and washings.
[0016] A further object of the invention is to enhance the
durability of colour of dyed hair by preventing colour molecules of
dyed hair to be washed out of the hair during a hair wash.
[0017] The objects of this invention are to provide compositions
and methods for fulfilling these goals. These objects and other
benefits as may be apparent to those skilled in the art can be
achieved through the present invention, which is described in the
following Summary of the Invention and Detailed Description of the
Invention and which is defined in the claims which follow.
SUMMARY OF THE INVENTION
[0018] It has now been found that the objects are achieved by the
use of
(i) a polydimethylsiloxane (P) having aminoalkyl groups and having
an amine number of at least 0.1 meq/g of polydimethylsiloxane (P),
and comprising units of the formula
R.sup.1.sub.aR.sup.2.sub.bSiO.sub.(4-a-b)/2 (I),
in which R.sup.1 are optionally halogen-substituted alkyl radicals
having 1-40 carbon atoms, or are --OR or --OH radicals, R are
optionally halogen-substituted alkyl radicals having 1-40 carbon
atoms, R.sup.2 are aminoalkyl radicals of the formula
--R.sup.3--NR.sup.4R.sup.5 (II),
R.sup.3 are divalent hydrocarbon radicals having 1-40 carbon atoms,
R.sup.4 are monovalent hydrocarbon radicals having 1-40 carbon
atoms or are H, R.sup.5 is a radical of the formula
--(R.sup.6--NR.sup.4).sub.xR.sup.4 (III),
R.sup.6 is a divalent radical of the formula
--(CR.sup.4R.sup.4--).sub.y (IV),
x is 0 or a value from 1 to 40, y is 1 or 2, a is 0, 1, 2 or 3, b
is 0, 1, 2 or 3 and a+b on average is from 1.5 to 2.5, not more
than 9 mol % of the radical R.sup.1 being OH or OR, and (ii) a
protonating agent, for treating human hair.
DETAILED DESCRIPTION OF THE INVENTION
[0019] One aspect of the invention is therefore the use of (i) a
polydimethylsiloxane (P) having aminoalkyl groups and having an
amine number of at least 0.1 meq/g of polydimethylsiloxane (P), and
comprising units of the formula
R.sup.1.sub.aR.sup.2.sub.bSiO.sub.(4-a-b)/2 (I),
in which R.sup.1 are optionally halogen-substituted alkyl radicals
having 1-40 carbon atoms, or are --OR or --OH radicals, R are
optionally halogen-substituted alkyl radicals having 1-40 carbon
atoms, R.sup.2 are aminoalkyl radicals of the formula
--R.sup.3--NR.sup.4R.sup.5 (II),
R.sup.3 are divalent hydrocarbon radicals having 1-40 carbon atoms,
R.sup.4 are monovalent hydrocarbon radicals having 1-40 carbon
atoms or are H, R.sup.5 is a radical of the formula
--(R.sup.6--NR.sup.4).sub.xR.sup.4 (III),
R.sup.6 is a divalent radical of the formula
--(CR.sup.4R.sup.4--).sub.y (IV),
x is 0 or a value from 1 to 40, y is 1 or 2, a is 0, 1, 2 or 3, b
is 0, 1, 2 or 3 and a+b on average is from 1.5 to 2.5, not more
than 9 mol % of the radical R.sup.1 being OH or OR, and (ii) a
protonating agent, for treating human hair.
[0020] The alkyl radicals R.sup.1 and R may be linear, cyclic,
branched, saturated or unsaturated. The alkyl radicals R.sup.1 and
R preferably have 1-18 carbon atoms, in particular 1-6 carbon
atoms, and the methyl radical or ethyl radical is particularly
preferred. Preferred halogen substituents are fluorine and
chlorine. Particularly preferred radicals R.sup.1 are the methyl
radical, methoxy radical, ethoxy radical or --OH.
[0021] The divalent hydrocarbon radicals R.sup.3 may be
halogen-substituted, linear, cyclic, branched, aromatic, saturated
or unsaturated. The radicals R.sup.3 preferably have 1 to 6 carbon
atoms, and alkylene radicals are particularly preferred, in
particular propylene. Preferred halogen substituents are fluorine
and chlorine.
[0022] The monovalent hydrocarbon radicals R.sup.4 may be
halogen-substituted, linear, cyclic, branched, aromatic, saturated
or unsaturated. The radicals R.sup.4 preferably have 1 to 6 carbon
atoms, and alkyl radicals are particularly preferred. Preferred
halogen substituents are fluorine and chlorine. Particularly
preferred substituents R.sup.4 are methyl, ethyl, cyclohexyl and
H.
[0023] In the polydimethylsiloxanes, b preferably has the value 0
or 1, and a+b preferably has an average value of from 1.9 to 2.2.
In the polydimethylsiloxanes, x is preferably 0 or a value from 1
to 18, most preferably from 1 to 6.
[0024] Particularly preferred radicals R.sup.2 are
--CH.sub.2N(R.sup.4).sub.2, --(CH.sub.2).sub.3N(R.sup.4).sub.2 and
--(CH.sub.2).sub.3N(R)(CH.sub.2).sub.2N(R.sup.4).sub.2.
[0025] The polydimethylsiloxane (P) is composed of at least 3, in
particular at least 10, units of the general formula (I).
[0026] The ratio of a to b is chosen so that the
polydimethylsiloxane (P) has an amine number of at least 0.1 meq/g
of polydimethylsiloxane (P), preferably at least 0.6 meq/g of
polydimethylsiloxane (P). The amine number of the
polydimethylsiloxane (P) is preferably not more than 7 meq/g of
polydimethylsiloxane (P).
[0027] The viscosity of the polydimethylsiloxane (P) is preferably
from 1 to 100,000 mPas, in particular from 10 to 10,000 mPas, at
25.degree. C.
[0028] The protonating agent is preferably a monoprotic or
polyprotic, water-soluble or water-insoluble, organic or inorganic
acid, most preferably formic acid, acetic acid, sulfuric acid,
hydrochloric acid or citric acid. The protonating agent is
preferably added in an amount of from 0.05 to 2 mol of acidic
proton per mole of basic nitrogen atom of the radicals R.sup.2.
[0029] The above polydimethylsiloxane (P) in combination with the
protonating agent can advantageously be used for manufacturing a
cosmetic composition for treating human hair.
[0030] By treating of said hair with said polydimethylsiloxane (P)
together with the protonating agent the treated hair becomes water
repellent. This allows to use said polydimethylsiloxane (P) and the
protonating agent for reducing the drying time of human hair. This
also allows to use said polydimethylsiloxane (P) and the
protonating agent as disclosed above and the compositions as
disclosed below, for reducing the drying time of human hair and
simultaneously protect the hair dye of a previously dyed hair from
being washed out.
[0031] Another object of the invention is therefore a hair treating
composition comprising a combination of:
(A) a polydimethylsiloxane (P) having aminoalkyl groups and having
an amine number of at least 0.1 meq/g of polydimethylsiloxane (P),
and comprising units of the formula I
R.sup.1.sub.aR.sup.2.sub.bSiO.sub.(4-a-b)/2 (I),
in which R.sup.1 are optionally halogen-substituted alkyl radicals
having 1-40 carbon atoms, or are --OR or --OH radicals, R are
optionally halogen-substituted alkyl radicals having 1-40 carbon
atoms, R.sup.2 are aminoalkyl radicals of the formula II
--R.sup.3--NR.sup.4R.sup.5 (II),
R.sup.3 are divalent hydrocarbon radicals having 1-40 carbon atoms,
R.sup.4 are monovalent hydrocarbon radicals having 1-40 carbon
atoms or are H, R.sup.5 is a radical of the formula III
--(R.sup.6--NR.sup.4).sub.xR.sup.4 (III),
R.sup.6 is a divalent radical of the formula IV
--(CR.sup.4R.sup.4--).sub.y (IV),
x is 0 or a value from 1 to 40, y is 1 or 2, a is 0, 1, 2 or 3, b
is 0, 1, 2 or 3 and a+b on average is from 1.5 to 2.5, not more
than 9 mol % of the radical R.sup.1 being OH or OR, (B) at least
one protonating agent, (C) water, (D) from 0 to 95 parts by weight
of at least one emulsifier and/or surfactant, and (E) at least one
cosmetic hair treatment agent, selected from the group consisting
of hair styling polymers and/or hair conditioning agents.
[0032] If the composition is an emulsion it is homogeneous, stable
and stable to dilution without further addition of other
stabilizing ingredients, such as emulsifiers or silicone/polyether
copolymers. It preferably contains not more than 5, more preferably
not more than 3, and in particular not more than 0.5, parts by
weight of emulsifier or surfactant. The composition is preferably
free of an emulsifier and a surfactant.
[0033] If the composition is an emulsion or dispersion it
preferably contains auxiliaries which are selected from mono- or
polyalcohols and ethers thereof, which have a boiling point or
boiling range of not more than 260.degree. C. at 0.10 MPa. The
composition is preferably an oil-in-water emulsion or
dispersion.
[0034] The water in the composition of the invention is
demineralized or non-demineralized water, preferably demineralized
water. The water is preferably present in an amount of from 0.1 to
99% by weight, more preferred in an amount of from 1 to 99% by
weight, more preferred in an amount of from 10 to 99% by weight and
most preferred in an amount of from 30 to 99% by weight of the
total weight of the hair treating composition.
[0035] The polydimethylsiloxanes (P) and emulsions or dispersions
thereof are described in US 2006/0041026 A1 which is hereby
included by reference. An oil-in-water emulsion of
polydimethylsiloxanes (P) suitable for the invention is sold for
example under the trademark Wacker.RTM. HC 303 VP by the company
Wacker-Chemie AG, D-81737 Munchen, Germany.
[0036] In a preferred embodiment, the composition is an emulsion
and contains a MQ silicone resin. The MQ silicone resin preferably
contains at least 80 mol %, preferably at least 95 mol %, of units
of the general formulae (V) and (VI)
R.sup.7.sub.3SiO.sub.1/2 (V),
SiO.sub.4/2 (VI),
in which R.sup.7 are optionally halogen-substituted hydrocarbon
radicals having 1-40 carbon atoms or H, --OR or --OH radicals, and
the ratio of the units of the general formulae (V) and (VI) is from
0.5 to 2.0, preferably from 0.5 to 1.5, and not more than 3% by
weight, preferably not more than 2.5% by weight, of the radicals
R.sup.7 are --OR and--OH.
[0037] The remaining units of the MQ silicone resin are preferably
units of the general formulae (VII) and (VIII)
R.sup.7.sub.2SiO.sub.2/2 (VII),
R.sup.7SiO.sub.3/2 (VIII).
The monovalent hydrocarbon radicals R.sup.7 may be
halogen-substituted, linear, cyclic, branched, aromatic, saturated
or unsaturated. The radicals R.sup.7 preferably have 1 to 6 carbon
atoms, and alkyl radicals and phenyl radicals are particularly
preferred. Further halogen substituents are fluorine and chlorine.
Particularly preferred substituents R.sup.7 are methyl, ethyl,
phenyl and H. The emulsions preferably contain from 1 to 200 parts
by weight, particularly preferably from 5 to 100 parts by weight,
of MQ silicone resin.
[0038] The term "hair conditioning agent" according to the present
invention means any cosmetically acceptable compound having a
cosmetic effect on hair, preferably selected from the group
consisting of: conditioning surfactants and emulsifiers,
conditioning thickeners, silicon compounds, oils, waxes, fatty
alcohols, hydrogenated fats, fatty acid esters, conditioning
thickeners, lanoline, amino acids, casein, ceresin, paraffines,
betaine, panthenol, sorbitol, protein hydrolysates, ceramids, plant
extracts, zein, silk, squalene, urea and hinokitiol.
[0039] Preferrred hair conditioning agents are paraffin waxes,
polyolefin waxes, wool wax, wool wax alcohols, candelilla wax,
olive wax, carnauba wax, Japan wax, apple wax, hydrogenated fats,
fatty alcohols, fatty acid esters, fatty acid glycerides, fatty
acid triglycerides, conditioning emulsifiers, conditioning
surfactants, conditioning thickeners, mineral oils, isoparaffin
oils, paraffin oils, squalane, sunflower oil, coconut oil, castor
oil, lanolin oil, jojoba oil, corn oil or soybean oil.
[0040] This is further specified thereafter.
[0041] In another aspect of the present invention there is to
provide a composition and method for styling the hair while
simultaneously reducing the time to dry the hair. As previously
recited, the method for reducing the time to dry wet hair, for
example, drying wet hair following showering, shampooing, bathing,
swimming, and the like, comprises applying to wet hair an aqueous,
aqueous-alcoholic or aqueous-organic-solvent hair styling
composition of the invention, a styling component, water and
optionally another solvent, and subsequently drying the hair.
Before or during the drying step, the hair may be mechanically
processed to help water to sheet from the hair. Such processing
includes brushing, combing, towelling, and the like.
[0042] In the case of towelling, it is seen that mechanical action
is typically combined with absorbing of the water present on the
hair. In this embodiment, the composition of the invention in an
aqueous or partially aqueous vehicle. Surprisingly, the time to dry
the hair is reduced, notwithstanding the application to hair of
additional water present in the composition.
[0043] The composition according to the invention can be used in
various application forms, such as, for example, as lotion, as
non-aerosol spray lotion, which is used by means of a mechanical
device for spraying, as aerosol spray which is sprayed by means of
a propellant, as aerosol foam or as non-aerosol foam which is
present in combination with a suitable mechanical device for
foaming the composition, as a mousse, as hair cream, as hair wax,
as gel, as liquid gel, as sprayable gel or as foam gel, pump,
putty, spray wax, pomade, brilliantine, balm, stick, strip,
dispersion or emulsion. A use in the form of a lotion thickened
with a customary thickener is also possible.
[0044] The composition of the invention has preferably the form of
an oil-in-water emulsion or a dispersion.
[0045] The products are leave-in products that are applied to wet
or dry hair, any may be used to treat the hair, for example,
styling products and fixative products or products to condition
hair.
[0046] The term "hair conditioning agent" according to the present
invention means an agent that provides gloss to hair, makes hair
more manageable, improve hair touch, improve combability and/or
give hair more volume.
[0047] In the composition according to the invention the
polydimethylsiloxane (P) is preferably present in an amount of from
0.001 to 50% by weight, more preferred in an amount of from 0.01 to
30% by weight, still more preferred in an amount of from 0.1 to
20%, still more preferred in an amount of from 0.1 to 10% and most
preferred in an amount of from 0.1 to 5% by weight of the total
weight of the hair treating composition.
[0048] When the composition according to the invention is a hair
styling composition it preferably comprises from 0.1 to 10% by
weight, more preferred from 0.5 to 8% and most preferred from 1 to
5% by weight of at least one hair styling polymer.
The Hair Treatment Agent
[0049] The hair treatment agents for use in the hair treatment
compositions of the present invention are hair styling polymers,
hair conditioning agents, and mixtures thereof. The hair treatment
agents permit the consumer to style the hair in conjunction with
combing or brushing, and especially coincidental to drying with a
blow dryer or other device that supplies heat to the hair. The hair
treatment compositions are especially applied to damp hair.
[0050] The hair fixative agents are preferably nonionic polymers,
but may also be cationic, anionic, and amphoteric polymers.
Suitable hair fixative agents are identified in the International
Cosmetic Ingredient Dictionary and Handbook, v. 3, p. 2227-8 (10th
Edition 2004) published by the Cosmetics, Toiletries and Fragrance
Association (CTFA) (hereinafter referred to as "INCI").
[0051] The hair conditioning agents are typically cationic polymers
that provide softness to the hair or that repair damaged hair. The
conditioning polymers generally provide a film on the hair that is
smooth and not tacky.
[0052] Typically, the conditioning polymers are cationic but may
also be nonionic, zwitterionic, and amphoteric. The hair
conditioning agents may also be oils, as described in greater
detail below.
[0053] As known in the art, there is some overlap between polymers
that provide hair conditioning benefit and hair fixative benefits,
depending often on the concentration of the polymer and the other
components present in the formulation.
Hairstyling Polymers
Nonionic Hair Styling Polymers
[0054] Suitable synthetic, nonionic film-forming, hair-styling
polymers are homopolymers or copolymers which are constructed from
at least one of the following monomers: vinylpyrrolidone,
vinylcaprolactam, vinyl esters, such as, for example, vinyl
acetate, vinyl alcohol, acrylamide, methacrylamide, alkyl- and
dialkylacrylamide, alkyl- and dialkylmethacrylamide, alkyl
acrylate, alkyl methacrylate, propylene glycol or ethylene glycol,
where the alkyl groups of these monomers are preferably C1- to
C7-alkyl groups, particularly preferably C1- to C3-alkyl groups.
Homopolymers of vinylcaprolactam, of vinylpyrrolidone or of
N-vinylformamide, for example are suitable. Further suitable
synthetic film-forming, nonionic, hair-setting polymers are, for
example, copolymers of vinylpyrrolidone and vinyl acetate,
terpolymers of vinylpyrrolidone, vinyl acetate and vinyl
propionate, polyacrylamide; polyvinyl alcohols, and polyethylene
glycol/polypropylene glycol copolymers. Suitable natural
film-forming polymers are, for example, cellulose derivatives, e.g.
hydroxyalkylcellulose.
[0055] Among the suitable nonionic hairstyling polymers, mention
may be made of homo- and copolymers of vinylpyrrolidone,
especially, copolymers of vinylacetate, in particular those sold
under the trade name Luviskol.RTM., e.g. homopolymers Luviskol.RTM.
K 30, K 60 or K 90; copolymers Luviskol.RTM. VA 55, VA 64; and the
terpolymer vinylpyrrolidone-/vinylacetate/vinylpropionate copolymer
sold as Luviskol.RTM. V AP 343 all from BASF; terpolymer of
vinylpyrrolidone, methacrylamide and vinylimidazole (Luviset.RTM.
Clear of BASF); vinyl pyrrolidone/acrylates copolymer; vinyl
pyrrolidone/hexadecane copolymer, and vinyl pyrrolidone/vinyl
caprolactam/dimethylaminoethyl methacrylate acrylates
copolymer.
[0056] Other nonionic hairstyling polymers suitable as the hair
fixative agent include VP/acrylates/lauryl methacrylate copolymer;
adipic acid/diethylenetriamine copolymer; PEG-8/SMDI copolymer;
polyacrylamide-1; polyvinyl acetate; PPG-12/SMDI copolymer;
polyurethane-1, polyurethane-14; and polyimide-1 sold as Aquaflex
XL-30 by ISP.
[0057] Suitable hairstyling polymers with acid groups are, in
particular, homopolymers of acrylic acid or of methacrylic acid
which are uncrosslinked or crosslinked with polyfunctional agents,
copolymers of acrylic acid or methacrylic acid with monomers chosen
from acrylic or methacrylic esters, acrylamides, methacrylamides
and vinylpyrrolidone, homopolymers of crotonic acid, and copolymers
of crotonic acid with monomers chosen from vinyl esters, acrylic or
methacrylic esters, acrylamides and methacrylamides. A suitable
natural polymer is, for example, Shellac.
Preferred nonionic hairstyling polymers are:
[0058] Polyvinylpyrrolidone, polyvinylcaprolactam,
vinylpyrrolidone/vinyl acetate copolymers, polyvinyl alcohol,
isobutylene/ethylmaleimide/hydroxyethylmaleimide copolymer;
copolymers of vinylpyrrolidone, vinyl acetate and vinyl propionate.
Further preferred polymers are described in WO 03/092640, e.g.
example Nos. 61, 62, 64 and 65, and are commercially available
under the name Luviflex.RTM. Clear (BASF) (INCI name:
VP/Methacrylamide/Vinyl Imidazole Copolymer).
Anionic Hairstyling Polymers
[0059] Preferred Hairstyling Polymers with Acid Groups are:
[0060] Terpolymers of acrylic acid, alkyl acrylate and
N-alkylacrylamide (INCI name: Acrylates/Acrylamide Copolymer), in
particular terpolymers of acrylic acid, ethyl acrylate and
N-tert-butylacrylamide; crosslinked or uncrosslinked vinyl
acetate/crotonic acid copolymers (INCI name: VA/Crotonates
Copolymer); copolymers of one or more C1-C5-alkyl acrylates, in
particular C2-C4-alkyl acrylates and at least one monomer chosen
from acrylic acid or methacrylic acid (INCI name: Acrylates
Copolymer), e.g. terpolymers of tert-butyl acrylate, ethyl acrylate
and methacrylic acid; sodium polystyrenesulfonate; vinyl
acetate/crotonic acid/vinyl alkanoate copolymers, e.g. copolymers
of vinyl acetate, crotonic acid and vinyl propionate; copolymers of
vinyl acetate, crotonic acid and vinyl neodecanoate (INCI names:
VA/Crotonates/Vinyl Propionate Copolymer, VA/Crotonates/Vinyl
Neodecanoate Copolymer); aminomethylpropanol acrylate copolymers;
copolymers of vinylpyrrolidone and at least one further monomer
chosen from acrylic acid and methacrylic acid, and optionally
acrylic esters and methacrylic esters; copolymers of methyl vinyl
ether and maleic monoalkyl esters (INCI names: Ethyl ester of
PVM/MA Copolymer, Butyl ester of PVM/MA Copolymer);
aminomethylpropanol salts of copolymers of allyl methacrylate and
at least one further monomer chosen from acrylic acid, and
methacrylic acid, and optionally acrylic esters and methacrylic
esters; crosslinked copolymers of ethyl acrylate and methacrylic
acid; copolymers of vinyl acetate, mono-n-butyl maleate and
isobornyl acrylate; copolymers of two or more monomers chosen from
acrylic acid and methacrylic acid, and optionally acrylic esters
and methacrylic esters; copolymers of octylacrylamide and at least
one monomer chosen from acrylic acid and methacrylic acid, and
optionally acrylic esters and methacrylic esters; polyesters of
diglycol, cyclohexanedimethanol, isophthalic acid and
sulfoisophthalic acid, where the alkyl groups of the abovementioned
polymers generally have preferably 1, 2, 3 or 4 carbon atoms.
Preferred Zwitterionic or Amphoteric Hairstyling Polymers are:
[0061] Copolymers formed from alkylacrylamide, alkylaminoalkyl
methacrylate and two or more monomers of acrylic acid and
methacrylic acid, and optionally esters thereof, in particular
copolymers of octylacrylamide, acrylic acid, butylaminoethyl
methacrylate, methyl methacrylate and hydroxypropyl methacrylate
(INCI name: Octylacrylamide/Acrylates/Butylaminoethyl Methacrylate
Copolymer); copolymers which are formed from at least one first
monomer type which has quaternary amine groups, and at least one
second monomer type which has acid groups; copolymers of fatty
alcohol acrylates, of alkylamine oxide methacrylate and at least
one monomer chosen from acrylic acid and methacrylic acid, and
optionally acrylic esters and methacrylic esters, in particular
copolymers of lauryl acrylate, stearyl acrylate, ethylamine oxide
methacrylate and at least one monomer chosen from acrylic acid and
methacrylic acid, and optionally esters thereof, copolymers of
methacryloylethylbetaine and at least one monomer chosen from
methacrylic acid and methacrylic esters; copolymers of acrylic
acid, methyl acrylate and methacrylamidopropyltrimethylammonium
chloride (INCI name: Polyquaternium-47); copolymers of
acrylamidopropyltrimethylammonium chloride and acrylates or
copolymers of acrylamide, acrylamidopropyltrimethylammonium
chloride, 2-amidopropylacrylamidesulfonate and
dimethylaminopropylamine (INCI name: Polyquaternium-43); oligomers
or polymers, preparable from quaternary croton betaines or
quaternary croton betaine esters.
Cationic Hairstyling Polymers
[0062] The cationic polymers may be homopolymers or copolymers,
where the quaternary nitrogen groups are present either in the
polymer chain or preferably as substituent on one or more of the
monomers. The monomers containing ammonium groups may be
copolymerized with noncationic monomers. Suitable cationic monomers
are unsaturated, free-radically polymerizable compounds which carry
at least one cationic group, in particular ammonium-substituted
vinyl monomers, such as, for example,
trialkylmethacryloxyalkylammonium, trialkylacryloxyalkylammonium,
dialkyldiallylammonium and quaternary vinylammonium monomers with
cyclic, cationic nitrogen-containing groups, such as pyridinium,
imidazolium or quaternary pyrrolidones, e.g. alkylvinylimidazolium,
alkylvinylpyridinium, or alkylvinyl-pyrrolidone salts. The alkyl
groups of these monomers are preferably lower alkyl groups, such
as, for example, C1- to C7-alkyl groups, particularly preferably
C1- to C3-alkyl groups.
[0063] The monomers containing ammonium groups may be copolymerized
with noncationic monomers. Suitable comonomers are, for example,
acrylamide, methacrylamide, alkyl- and dialkylacrylamide, alkyl-
and dialkylmethacrylamide, alkyl acrylate, alkyl methacrylate,
vinylcaprolactone, vinylcaprolactam, vinylpyrrolidone, vinyl
esters, e.g. vinyl acetate, vinyl alcohol, propylene glycol or
ethylene glycol, where the alkyl groups of these monomers are
preferably C1- to C7-alkyl groups, particularly preferably C1- to
C3-alkyl groups.
[0064] Suitable hairstyling polymers with quaternary amine groups
are, for example, the polymers described in the CTFA Cosmetic
Ingredient Dictionary under the names Polyquaternium, such as
methylvinylimidazolium chloride/vinylpyrrolidone copolymer
(Polyquaternium-16) or quaternized
vinylpyrrolidone/dimethylaminoethyl methacrylate copolymer
(Polyquaternium-11), and quaternary silicone polymers and
oligomers, such as, for example, silicone polymers with quaternary
end groups (Quaternium-80).
Preferred Synthetic-Based Cationic Hair Styling Polymers:
[0065] Poly(dimethyldiallyammonium chloride); copolymers of
acrylamide and dimethyldiallylammonium chloride; quaternary
ammonium polymers formed by the reaction of diethyl sulfate and a
copolymer of vinylpyrrolidone and dimethylaminoethyl methacrylate,
in particular vinylpyrrolidone/dimethyllaminoethyl methacrylate
methosulfate copolymer (e.g. Gafquat.RTM. 755 N, Gafquat.RTM. 734);
quaternary ammonium polymers of methylvinylimidazolium chloride and
vinylpyrrolidone (e.g. LUVIQUAT.RTM. HM 550); Polyquaternium-35;
Polyquaternium-57; polymer of trimethylammonium ethyl methacrylate
chloride; terpolymers of dimethyldiallylammonium chloride, sodium
acrylate and acrylamide (e.g. Merquat.RTM. Plus 3300); copolymers
of vinylpyrrolidone, dimethylaminopropyl methacrylamide and
methacryloylamino-propyllauryldimethylammonium chloride;
terpolymers of vinylpyrrolidone, dimethylaminoethyl methacrylate
and vinylcaprolactam (e.g. Gaffix.RTM. VC 713);
vinylpyrrolidone/methacrylamide-propyltrimethylammonium chloride
copolymers (e.g. Gafquat.RTM. HS 100); copolymers of
vinylpyrrolidone and dimethylaminoethyl methacrylate; copolymers of
vinylpyrrolidone, vinylcaprolactam and
dimethylaminopropylacrylamide; polyesters or oligoesters
constructed from at least one first monomer type which is chosen
from hydroxy acid substituted by at least one quaternary ammonium
group; dimethylpolysiloxanes terminally substituted by quaternary
ammonium groups.
[0066] Preferred hairstyling polymers with amino groups are
copolymers of vinylpyrrolidone, vinylcaprolactam and a basic
acrylamide monomer, where the basic acrylamide monomer is
preferably chosen from dialkylaminoalkyl methacrylamide and
dialkylaminoalkyl acrylamide, where the alkyl groups consist of 1
to 4 carbon atoms. Particular preference is given to
dimethylaminopropyl methacrylamide. The preparation of such a
polymer is described in WO 96/19971 and is commercially available
under the name Aquaflex.RTM. SF 40 (ISP).
[0067] Suitable cationic hairstyling polymers which are derived
from natural polymers are, in particular, cationic derivatives of
polysaccharides, for example cationic derivatives of cellulose,
starch or guar. Also suitable are chitosan and chitosan
derivatives. Cationic polysaccharides have, for example, the
general formula
G-O--B--N.sup.+R.sup.aR.sup.bR.sup.cX.sup.-
G is an anhydroglucose radical, for example starch or cellulose
anhydroglucose; B is a divalent compound group, for example
alkylene, oxyalkylene, polyoxyalkylene or hydroxyalkylene; R.sup.a,
R.sup.b and R.sup.c, independently of one another, are alkyl, aryl,
alkylaryl, arylalkyl, alkoxyalkyl or alkoxyaryl in each case having
up to 18 carbon atoms, where the total number of the carbon atoms
in R.sup.a, R.sup.b and R.sup.c is preferably at least 20; X is a
customary counteranion, for example a halogen, acetate, phosphate,
nitrate or alkyl sulfate, preferably a chloride.
[0068] Cationic celluloses are, for example, those with the INCI
names Polyquaternium-10 or Polyquaternium-24. A suitable cationic
guar derivative has, for example, the INCI name Guar
Hydroxypropyltrimonium Chloride.
[0069] Preferred cationic cellulose compounds are those which have
at least one quaternary ammonium group, e.g. a copolymer of
hydroxyethylcellulose and diallyldimethylammonium chloride
(Polyquaternium-4) or the reaction product of hydroxyethylcellulose
and an epoxide substituted by a trialkylammonium group
(Polyquaternium-10), where the alkyl groups can have from 1 to 20
carbon atoms and are preferably methyl groups. The molecular weight
is preferably between 100 000 and 600 000, particularly preferably
between 200 000 and 400 000. The nitrogen content is preferably 0.5
to 4%, particularly preferably 1.5 to 3%. A preferred cellulose
derivative is Polyquaternium-4, which is sold under the trade names
Celquat.RTM. H100 and Celquat.RTM. L200, of which Celquat.RTM. L200
is particularly preferred.
[0070] Particularly preferred cation-active hairstyling polymers
are chitosan, chitosan salts and chitosan derivatives. The
chitosans to be used according to the invention are completely or
partially deacetylated chitins. The molecular weight can be spread
over a broad spectrum, for example from 20 000 to about 5 million
g/mol, e.g. from 30 000 to 70 000 g/mol. Preferably, however, the
molecular weight is more than 100 000 g/mol, particularly
preferably from 200 000 to 700 000 g/mol. The degree of
deacetylation is preferably 10 to 99%, particularly preferably 60
to 99%. A preferred chitosan salt is chitosonium
pyrrolidonecarboxylate, e.g. Kytamer.RTM. PC with a molecular
weight of from about 200 000 to 300 000 g/mol and deacetylation of
from 70 to 85%. Suitable chitosan derivatives are quaternized,
alkylated or hydroxyalkylated derivatives, e.g. hydroxyethyl-,
hydroxypropyl- or hydroxybutylchitosan. The chitosans or chitosan
derivatives are preferably in neutralized or partially neutralized
form. The degree of neutralization is preferably at least 50%,
particularly preferably between 70 and 100%, based on the number of
free base groups. Neutralizing agents which can be used are, in
principle, all cosmetically compatible inorganic or organic acids,
such as, for example, formic acid, tartaric acid, malic acid,
lactic acid, citric acid, pyrrolidonecarboxylic acid, hydrochloric
acid etc., of which pyrrolidonecarboxylic acid is particularly
preferred.
Preferred Natural-Based Cationic Hairstyling Polymers:
[0071] Cationic cellulose derivatives of hydroxyethylcellulose and
diallyldimethylammonium chloride; cationic cellulose derivatives of
hydroxyethylcellulose and epoxide substituted by trimethylammonium;
chitosan and salts thereof, hydroxyalkylchitosans and salts
thereof, alkylhydroxyalkylchitosans and salts thereof,
N-hydroxyalkylchitosan alkyl ethers; N-hydroxyalkylchitosan benzyl
ethers.
[0072] In a further preferred embodiment, the composition according
to the invention comprises 0.01 to 15% by weight, preferably 0.5 to
10% by weight, of at least one synthetic or natural nonionic
film-forming polymer. Natural polymers are also understood as
meaning chemically modified polymers of natural origin.
Film-forming polymers are understood as meaning those polymers
which, when used in 0.01 to 5% strength aqueous, alcoholic or
aqueous-alcoholic solution, are able to deposit a polymer film on
the hair.
[0073] If the hair treating composition is a hair styling
composition, the hair styling polymer is present in an amount of
from 0.1 to 10% by weight and preferred in an amount of from 0.5 to
6% by weight.
[0074] If the hair treating composition is a hair care composition,
the hair styling polymer is preferably present in an amount of from
0.01 to 3% by weight, and more preferred in an amount of from 0.1
to 2% by weight.
Hair Conditioning Agents
Cationic Surfactants
[0075] Hair conditioning agents in form of cationic surfactants
that can be preferably used in the cosmetic composition of the
present invention contain amino or quaternary ammonium
moieties.
[0076] Among the quaternary ammonium-containing cationic surfactant
materials useful herein are those of the general formula
[NR4,R5,R6,R7].sup.+.X.sup.-
wherein R4 to R7 are independently an aliphatic group of from about
1 to about 22 carbon atoms or an aromatic, alkoxy, polyoxyalkylene,
alkylamido, hydroxyalkyl, aryl or alkylaryl group having from about
1 to about 22 carbon atoms; and X.sup.- is a salt-forming anion
such as those selected from halogen, (e.g. chloride, bromide,
iodide), acetate, citrate, lactate, glycolate, phosphate nitrate,
sulfate, and alkylsulfate radicals.
[0077] The aliphatic groups may contain, in addition to carbon and
hydrogen atoms, either linkages, and other groups such as amino
groups. The longer chain aliphatic groups, e.g. those of about 12
carbons, or higher, can be saturated or unsaturated. Especially
preferred are di-long chain (e.g. di C12-C22, preferably C16-C18,
aliphatic, preferably alkyl) and di-short chain (e.g. C1-C3 alkyl,
preferably C1-C2 alkyl) ammonium salts. Salts of primary, secondary
and tertiary fatty amines are also suitable cationic surfactant
materials. The alkyl groups of such amines preferably have from
about 12 to about 22 carbon atoms, and may be substituted or
unsubstituted. Such amines, useful herein, include stearamido
propyl dimethyl amine, diethyl amino ethyl stearamide, dimethyl
stearamine, dimethyl soyamine, soyamine, myristyl amine, tridecyl
amine, ethyl stearylamine, N-tallowpropane diamine, ethoxylated (5
moles E.O.) stearylamine, dihydrorxy ethyl stearylamine, and
arachidylbehenylamine. Suitable amine salts include the halogen,
acetate, phosphate, nitrate, citrate, lactate, and alkyl sulfate
salts. Such salts include stearylamine hydrochloride, soyamine
chloride, stearylamine formate, N-tallowpropane diamine dichloride
and stearamidopropyl dimethylamine citrate. Preferred cationic
surfactants are cetyl trimethyl ammonium salts, as for example
Genamin.RTM. CTAC, i.e. cetyl trimethyl ammonium chloride, behenyl
trimethyl ammonium salts, e.g. behenyl trimethyl ammonium chloride;
dimethyl ditallow ammonium salts; stearyl amidopropyl
dimethylamine; esterquats as for example tetradecyl betainester
chloride, diesterquats as for example
dipalmitylethyl-dimethylammoniumchloride (Armocare.RTM. VGH70 of
Akzo, Germany), or a mixture of distearoylethyl hydroxyethylmonium
methosulfate and Cetearyl Alkohol (Dehyquart.RTM. F-75 of Henkel,
Germany).
[0078] Preferred cationic surfactants include QUATERNIUM-8;
QUATERNIUM-14; QUATERNIUM-15; QUATERNIUM-18; QUATERNIUM-22;
QUARTERNIUM-24; QUATERNIUM-26; QUATERNIUM-27; QUATERNIUM-30;
QUATERNIUM-33; QUATERNIUM-37; QUATERNIUM-53; QUATERNIUM-60;
QUATERNIUM-61; QUATERNIUM-72; QUATERNIUM-78; QUATERNIUM-80;
QUATERNIUM-81; QUATERNIUM-82; QUATERNIUM-83; QUATERNIUM-84; AND
QUATERNIUM-91.
Nonionic Surfactants
[0079] Hair conditioning agents in form of nonionic surfactants
that can be used in the cosmetic composition of the present
invention are selected from the group of nonionic surfactants
having an HLB of less than 8.
[0080] The nonionic surfactant of HLB<8 can preferably be chosen
in particular from glyceryl esters, such as mono-, di- or
triglyceryl mono-, di- or triisostearate or -oleate, sugar esters,
such as sucrose or methyl glucose mono- or diisostearate or
-oleate, alkylpolyglucoside ethers, such as sorbitan isostearate,
oleyl- or isostearylpolyglucoside; polyoxyethylene (20) sorbitan
monostearate (CTFA: Polysorbat-60), and their mixtures. Sugar
esters and alkylpolyglucoside ethers are most preferred.
Silicone Conditioning Agents
[0081] The cosmetic compositions hereof can also include volatile
or nonvolatile, soluble or insoluble silicones as conditioning
agents. By soluble what is meant is that the silicone conditioning
agent is miscible with the aqueous carrier of the composition so as
to form part of the same phase. By insoluble what is meant is that
the silicone forms a separate, discontinuous phase from the aqueous
carrier, such as in the form of an emulsion or a suspension of
droplets of the silicone.
[0082] Soluble silicones include silicone copolyols, such as
dimethicone copolyols, e.g. polyether siloxane-modified polymers,
such as polypropylene oxide, polyethylene oxide modified
polydimethylsiloxane, wherein the level of ethylene and/or
propylene oxide sufficient to allow solubility in the
composition.
[0083] Preferred silicones are: Cyclic dimethylsiloxanes, linear
polydimethylsiloxanes, block polymers of polydimethylsiloxane and
polyethylene oxide and/or polypropylene oxide,
polydimethylsiloxanes with terminal or lateral polyethylene oxide
or polypropylene oxide radicals, polydimethylsiloxanes with
terminal hydroxyl groups, phenyl-substituted polydimethylsiloxanes,
silicone emulsions, silicone elastomers, silicone waxes, silicone
gums and amino-substituted silicones.
[0084] Preferred, however, are insoluble silicones. The insoluble
silicone hair conditioning agent for use herein will preferably
have viscosity of from about 1,000 to about 2,000,000 mPas at
25.degree. C., more preferably from about 10,000 to about
1,800,000, even more preferably from about 100,000 to about
1,500,000 mPas at 25.degree. C. The viscosity can be measured by
means of a glass capillary viscometer as set forth in Dow Corning
Corporate Test Method CTM0004, Jul. 20, 1970.
[0085] Suitable insoluble, nonvolatile silicone fluids include
polyalkyl siloxanes, polyaryl siloxanes, polyalkylaryl siloxanes,
polyether siloxane copolymers, dimethylpolysiloxane containing
terminal hydroxyl groups, methylphenyl polysiloxane containing
terminal hydroxyl groups and mixtures thereof. Specific examples
thereof include hexamethyldisiloxane, octamethyltrisiloxane,
decamethyltetrasiloxane and hexadecamethylheptasiloxane.
[0086] Other insoluble, nonvolatile silicone fluids having hair
conditioning properties can also be used. The term "nonvolatile" as
used herein shall mean that the silicone has a boiling point of at
least about 260.degree. C., preferably at least about 275.degree.
C., more preferably at least about 300.degree. C. Such materials
exhibit very low or no significant vapor pressure at ambient
conditions. The term "silicone fluid" shall mean flowable silicone
materials having a viscosity of less than 1,000,000 mPas at
25.degree. C. Generally, the viscosity of the fluid will be between
about 5 and 1,000,000 mPas at 25.degree. C., preferably between
about 10 and about 300,000 mPas at 25.degree..
[0087] The preferred silicones are polydimethyl siloxane,
polydiethylsiloxane, and polymethylphenylsiloxane.
Polydimethylsiloxane is especially preferred. The nonvolatile
polyalkylsiloxane fluids that may be used include, for example,
polydimethyl siloxanes. These siloxanes are available, for example,
from the General Electric Company in their Viscasil.RTM. and SF 96
series, and from Dow Corning in their Dow Corning 200.RTM.
series.
[0088] The polyalkylaryl siloxane fluids that may be used, also
include, for example, polymethylphenylsiloxanes. These siloxanes
are available, for example, from the General Electric Company as SF
1075 methyl phenyl fluid or from Dow Corning as 556 Cosmetic Grade
Fluid.
[0089] Suitable insoluble, volatile silicone fluids include low
molecular weight oligomeric polydimethylsiloxane or cyclic
polydimethylsiloxane, having a viscosity of no more than 10 mPas at
25.degree. C. and a boiling point under atmospheric pressure of no
more than 250.degree. C. Volatility can be achieved in linear
organopolysiloxanes by selection of oligomeric organopolysiloxanes
with at most 6 to 10 silicone atoms in the organopolysiloxanes
backbone, e.g. Dow Corning DC200 Fluid, having a viscosity of from
about 0.65 to about 2 mPas at 25.degree. C. Preferably cylclic
organopolysiloxanes having from 3 to 6 silicon atoms are utilized,
for example, hexamethyl-cyclotrisiloxane,
octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane,
dodecamethylcyclohexasiloxane (e.g. DC 244, DC 245, DC 345 of Dow
Corning).
[0090] Especially preferred, for enhancing the shine
characteristics of hair, are highly arylated silicones, such as
highly phenylated polyethyl silicone having refractive indices of
about 1.46 or higher, especially about 1.52 or higher. When these
high refractive index silicones are used, they should be mixed with
a spreading agent, such as a surfactant or a silicone resin, as
described below to decrease the surface tension and enhance the
film forming ability of the material.
[0091] The polyether siloxane copolymers that may be used include,
for example, a polypropylene oxide modified polydimethylsiloxane
(e.g. Dow Corning DC-1248.RTM.) although ethylene oxide or mixtures
of ethylene oxide and propylene oxide may also be used. The
ethylene oxide and polypropylene oxide level should be sufficiently
low to prevent solubility in the composition hereof.
[0092] Another silicone hair conditioning material that can be
especially useful in the silicone conditioning agents is insoluble
silicone gum. The term "silicone gum", as used herein, means
polyorganosiloxane materials having a viscosity at 25.degree. C. of
greater than or equal to 1,000,000 mPas. The "silicone gums" will
typically have a mass molecular weight in excess of about 200,000,
generally between about 200,000 and about 1,000,000. Specific
examples include polydimethylsiloxane, (polydimethylsiloxane)
(methylvinylsiloxane) copolymer, poly(dimethylsiloxane) (diphenyl
siloxane) (methylvinylsiloxane) copolymer and mixtures thereof.
Preferably the silicone hair treating agent comprises a mixture of
a polydimethylsiloxane gum, having a viscosity greater than about
1,000,000 mPas and polydimethylsiloxane fluid having a viscosity of
from about 10 mPas to about 100,000 mPas at 25.degree. C., wherein
the ratio of gum to fluid is from about 30:70 to about 70:30,
preferably from about 40:60 to about 60:40.
[0093] Silicone conditioning polymers that are specially preferred
are CTFA: DIMETHICONE BISAMINO HYDROXYPROPYL COPOLYOL, BISAMINO
PEG/PPG-41/3 AMINOETHYL PG-PROPYL DIMETHICONE,
dihydroxypolydimethylsiloxane (CTFA: DIMETHICONOL). Also preferred
are volatile silicones such as e.g. CTFA: DIMETHICONE, DIMETHICONE
COPOLYOL and CYCLOMETHICONE.
[0094] The silicone hair conditioning agent can be used in the
compositions hereof at levels of from about 0.1% to about 20% by
weight of the composition, preferably from about 0.1% to about 10%,
more preferably from about 0.1% to about 5% and most preferably
from about 0.2% to about 1% by weight.
Organic Oily Conditioning Agents
[0095] The compositions of the present invention can also comprise
a nonvolatile, water insoluble, organic, oil or fat as a
conditioning agent for hair or skin.
[0096] The hair conditioning oil can add shine and luster to the
hair. The conditioning oil is typically present in the compositions
at a level of from about 0.05% to about 5%, by weight of the
composition, preferably from about 0.2% to about 3%, more
preferably from about 0.5% to about 1%.
[0097] By "nonvolatile" what is meant is that the oily material
exhibits very low or no significant vapor pressure at ambient
conditions (e.g., 1 atmosphere, 25.degree. C.), as is understood in
the art. The nonvolatile oily materials preferably have a boiling
point at ambient pressure of about 250.degree. C. or higher.
[0098] By "water insoluble" what is meant is that the oily liquid
is not soluble in water (distilled or equivalent) at a
concentration of 0.1%, at 25.degree. C.
[0099] The conditioning oils hereof are liquids selected from the
group consisting of hydrocarbon oils and fatty esters. The fatty
esters hereof are characterized by having at least 10 carbon atoms,
and include esters with hydrocarbyl chains derived from fatty acids
or alcohols, e.g. mono-esters, polyhydric alcohol esters, and di-
and tri-carboxylic acid esters. The hydrocarbyl radicals of the
fatty esters hereof can also include or have covalently bonded
thereto other compatible functionalities, such as amides and alkoxy
moieties (e.g., ethoxy or ether linkages, etc.).
[0100] Hydrocarbon oils include cyclic hydrocarbons, straight chain
aliphatic hydrocarbons (saturated or unsaturated), and branched
chain aliphatic hydrocarbons (saturated or unsaturated). Straight
chain hydrocarbon oils will preferably contain from about 12 to
about 19 carbon atoms, although it is not necessarily meant to be
limit the hydrocarbons to this range. Branched chain hydrocarbon
oils can and typically may contain higher numbers of carbon atoms.
Also encompassed herein are polymeric hydrocarbons of alkenyl
monomers, such as C.sub.2-C.sub.6 alkenyl monomers. These polymers
can be straight or branched chain polymers. The straight chain
polymers will typically be relatively short in length, having a
total number of carbon atoms as described above for straight chain
hydrocarbons in general. The branched chain polymers can have
substantially higher chain length. The number average molecular
weight of such materials can vary widely, but will typically be up
to about 500, preferably from about 200 to about 400, more
preferably from about 300 to about 350.
[0101] Specific examples of suitable materials include paraffin
oil, mineral oil, saturated and unsaturated dodecane, saturated and
unsaturated tridecane, saturated and unsaturated tetradecane,
saturated and unsaturated pentadecane, saturated and unsaturated
hexadecane, and mixtures thereof. Branched-chain isomers of these
compounds, as well as of higher chain length hydrocarbons, can also
be used. Exemplary branched-chain isomers are highly branched
saturated or unsaturated alkanes, such as the permethyl-substituted
isomers, e.g., the permethyl-substituted isomers of hexadecane and
eicosane, such as 2,2,4,4,6,6,8,8-dimethyl-10-methylundecane and
2,2,4,4,6,6-dimethyl-8-methylnonane, sold by Permethyl Corporation.
A preferred hydrocarbon polymer is polybutene, such as the
copolymer of isobutylene and butene. A commercially available
material of this type is L-14 polybutene from Amoco Chemical Co.
(Chicago, Ill., U.S.A.).
[0102] Monocarboxylic acid esters hereof include esters of alcohols
and/or acids of the formula R'COOR wherein alkyl or alkenyl
radicals and the sum of carbon atoms in R' and R is at least 10,
preferably at least 20.
[0103] Fatty esters include, for example, alkyl and alkenyl esters
of fatty acids having aliphatic chains with from about 10 to about
22 carbon atoms, and alkyl and alkenyl fatty alcohol carboxylic
acid esters having an alkyl and/or alkenyl alcohol-derived
aliphatic chain with about 10 to about 22 carbon atoms, and
combinations thereof.
[0104] Examples include isopropyl isostearate, hexyl laurate,
isohexyl laurate, isohexyl palmitate, isopropyl palmitate, decyl
oleate, isodecyl oleate, hexadecyl stearate, decyl stearate,
isopropyl isostearate, dihexyldecyl adipate, lauryl lactate,
myristyl lactate, cetyl lactate, oleyl stearate, oleyl oleate,
oleyl myristate, lauryl acetate, cetyl propionate, and oleyl
adipate.
[0105] The mono-carboxylic acid ester however need not necessarily
contain at least one chain with at least 10 carbon atoms, so long
as the total number of aliphatic chain carbon atoms is at least 10.
Examples include diisopropyl adipate, diisohexyl adipate, and
diisopropyl sebacate.
[0106] Di- and tri-alkyl and alkenyl esters of carboxylic acids can
also be used. These include, for example, esters of C.sub.4-C.sub.8
dicarboxylic acids such as C.sub.1-C.sub.22 esters (preferably
C.sub.1-C.sub.6) of succinic acid, glutaric acid, adipic acid,
hexanoic acid, heptanoic acid, and octanoic acid. Specific examples
include isocetyl stearyol stearate, diisopropyl adipate, and
tristearyl citrate.
[0107] Polyhydric alcohol esters include alkylene glycol esters,
for example ethylene glycol mono and di-fatty acid esters,
diethylene glycol mono- and di-fatty acid esters, polyethylene
glycol mono- and di-fatty acid esters, propylene glycol mono- and
di-fatty acid esters, polypropylene glycol monooleate,
polypropylene glycol 2000 monostearate, ethoxylated propylene
glycol monostearate, glyceryl mono- and di-fatty acid esters,
polyglycerol poly-fatty acid esters, ethoxylated glyceryl
monostearate, 1,3-butylene glycol monostearate, 1,3-butylene glycol
distearate, polyoxyethylene polyol fatty acid ester, sorbitan fatty
acid esters, and polyoxyethylene sorbitan fatty acid esters are
satisfactory polyhydric alcohol esters for use herein.
[0108] Glycerides include mono-, di-, and tri-glycerides. More
specifically, included are the mono-, di-, and tri-esters of
glycerol and long chain carboxylic acids, such as C.sub.10-C.sub.22
carboxylic acids. Synthetic oils include triolein and tristearin
glyceryl dilaurate. Preferred glycerides are di-, and
tri-glycerides. Especially preferred are triglycerides.
[0109] A variety of these types of materials can be obtained from
vegetable and animal fats and oils, such as castor oil, safflower
oil, sunflower oil, cottonseed oil, corn oil, olive oil, cod liver
oil, almond oil, palm oil, sesame oil, lanolin and soybean oil,
avocado oil, tsubaki oil, turtle oil, macademia nuts oil, corn oil,
mink oil, olive oil, rape seed oil, yolk oil, sesame oil, parsic
oil, wheat germ oil, sasanqua oil, linseed oil, perilla oil,
soybean oil, peanut oil, tea seed oil, kaya oil, rice bran oil,
Chinese tung oil, Japanese tung oil, hohoba oil, germ oil,
triglycerine, trioctanoic acid glycerine, triisopalmitic acid
glycerine; solid fats such as cacao fat, coconut oil, horse fat,
hardened coconut fat, tallow, sheep fat, hardened tallow, palm
kernel oil, jojoba oil, lard, ox bone fat, wood wax kernel oil,
hardened castor oil; waxes such as beeswax, apple wax, canderilla
wax, cotton wax, carunauba wax, bayberry wax, insect wax, whale
wax, montan wax, rice bran wax, lanolin, kapok wax, lanolin
acetate, liquid lanolin, cane wax, isopropyl lanolin fatty acid,
hexyllaurate, reduced lanolin, jojoba wax, hard lanolin, shellac
wax, POE lanolin alcohol ether, POE lanolin alcohol acetate, POE
cholesterol ether, lanolin fatty acid polyethylene glycol, POE
hydrogenated lanolin alcohol ether; hydrocarbons, nonvolatile
hydrocarbons and hydrocarbon esters such as fluid paraffin, solid
paraffin, vaseline, ozocerite, squalane, pristan, ceresin,
squalane, petrolatum, isododecane, microcrystalline wax; fatty acid
oils, ester oils such as cetyl octanoate, isopropyl myristate;
betaine, camitin, camitin esters, creatine, amino acids, peptides,
proteines, vitamines, phospholipides, e.g. lecithines or ceramides.
Useful are also quaternary benzyl salts such as
lauryl-dimethyl-ethylbenzyl-ammonium chloride (QUATERNIUM-14);
imidazolidinyl derivatives as for example CTFA: QUATERNIUM-87
(Rewoquat.RTM. W 575 of Witco, Germany);
N-(3-chloroallyl)hexaminium chloride (QUARTERNIUM-15); a quaternary
ammonium compound sold under the trade name Finquat CT by the
company Finetex (CTFA: QUATERNIUM-75; see CTFA Tenth Edition, page
1604).
[0110] The amount of the above conditioning agents preferably
ranges from about 0.1% to 30% by weight, better still from about
0.1% to 15% by weight and most preferred from about 0.2% to 10% by
weight of the total weight of the cosmetic composition. These
ranges include all specific values and sub-ranges there between,
including 3, 8, 10, 15, 20, 25 and 30% by weight.
Fatty Alcohols
[0111] The cosmetic compositions of the present invention may also
comprise as hair conditioning agent a nonvolatile low melting point
fatty alcohol. The fatty alcohols hereof have a melting point of
30.degree. C. or less, preferably about 25.degree. C. or less, more
preferably about 22.degree. C. or less. The unsaturated fatty
alcohols hereof are also nonvolatile. By nonvolatile what is meant
is they have a boiling point at 1.0 atmospheres of at least about
260.degree. C., preferably at least about 275.degree. C., more
preferably at least about 300.degree. C. Suitable fatty alcohols
include unsaturated monohydric straight chain fatty alcohols,
saturated branched chain fatty alcohols, saturated C.sub.8-C.sub.12
straight chain fatty alcohols, and mixtures thereof. The
unsaturated straight chain fatty alcohols will typically have one
degree of unsaturation. Di- and tri-unsaturated alkenyl chains may
be present at low levels, preferably less than about 5% by total
weight of the unsaturated straight chain fatty alcohol more
preferably less than about 2%, most preferably less than about 1%.
Preferably, the unsaturated straight chain fatty alcohols will have
an aliphatic chain size of from C12-C22, more preferably from
C12-C18, most preferably from C16-C18. Exemplary alcohols of this
type include oleyl alcohol, and palmitoleic alcohol. The branched
chain alcohols will typically have aliphatic chain sizes of from
C12-C22, preferably C14-C20, more preferably C16-C18.
[0112] Exemplary branched chain alcohols for use herein include
stearyl alcohol, cetyl alcohol, isostearyl alcohol, octyl
dodecanol, and octyl decanol.
[0113] Examples of saturated C8-C12 straight chain alcohols include
octyl alcohol, caprylic alcohol, decyl alcohol, and lauryl alcohol.
The low melting point fatty alcohols hereof are used at a level of
from about 0.1% to about 15%, by weight of the composition, more
preferably from about 0.2% to about 11%, most preferably from about
0.2% to about 3%.
[0114] It may be desirable to use waxy fatty alcohols for their
conditioning benefits. In the event that such saturated fatty
alcohols are present, the weight ratio of the liquid to waxy fatty
alcohols is preferably no greater than about 0.25, more preferably
no greater than about 0.15, more preferably than about 0.10.
[0115] The total amount of fatty alcohols in the composition is
preferably about 0.5 to about 15.0% by weight, more preferably from
about 1.0 to about 12.0% by weight, and most preferably from about
1.5 to about 11.0% by weight.
Other Ingredients
[0116] The cosmetic compositions herein can contain a variety of
other optional components suitable for rendering such compositions
more cosmetically or aesthetically acceptable or to provide them
with additional usage benefits. Such conventional optional
ingredients are well-known to those skilled in the art. The
composition of the invention may thus comprise lipophilic or
hydrophilic adjuvants which are standard in the cosmetics or
dermatological fields, such as surfactants, in particular foaming
surfactants, preservatives, antioxidants, sequestering agents,
solvents, fragrances, fillers, screening agents, odor absorbers,
coloring materials and lipid vesicles.
[0117] A wide variety of additional ingredients can be formulated
into the present cosmetic composition. These include: detersive
surfactants such as anionic, nonionic, amphoteric, and zwitterionic
surfactants; additional thickening agents and suspending agents,
such as xanthan gum, guar gum, starch and starch derivatives,
viscosity modifiers such as methanolamides of long chain fatty
acids, cocomonoethanol amide, salts such as sodium potassium
chloride and sulfate and crystalline suspending agents, and
pearlescent aids such as ethylene glycol distearate; UV-filters and
sunscreens, e.g. such as p-methoxy cinnamic acid isoamylester,
lipophilc cinnamic acid esters, salicylic acid esters, 4-amino
benzoic acid derivatives or hydrophilic sulfonic acid derivatives
of benzophenones or 3-benzyliden campher; antioxidants such as
tocopheroles; agents for combating free radicals; preservatives
such as benzyl alcohol, methyl paraben, propyl paraben and
imidazolidinyl urea; polyvinyl alcohol; pH adjusting agents, such
as citric acid, formic acid, glyoxylic acid, acetic acid, lactic
acid, pyruvic acid, sodium citrate, succinic acid, phosphoric acid,
sodium hydroxide, sodium carbonate; salts, in general, such as
potassium acetate and sodium chloride; coloring agents, such as any
of the FD&C or D&C dyes; perfumes, sequestering agents,
such as disodium ethylenediamine tetra-acetate, and polymer
plasticizing agents, such as glycerin, disobutyl adipate, butyl
stearate, and propylene glycol.
Solvents
[0118] The composition according to the invention is preferably
formulated in as aqueous, alcoholic or aqueous-alcoholic
composition with preferably at least 10% by weight of water. The
hair treating composition can therefore optionally include liquid
water-miscible or water-soluble solvents such as lower alkyl
alcohols, e.g. C.sub.1-C.sub.5 alkyl monohydric alcohols,
preferably C.sub.2-C.sub.3 alkyl alcohols. Alcohols which may be
present are in particular lower monohydric or polyhydric alcohols
having 1 to 4 carbon atoms customarily used for cosmetic purposes,
such as preferably ethanol and isopropanol.
[0119] The water-soluble polyhydric alcohols usable in the present
invention are also polyhydric alcohols having two or more hydroxyl
groups in the molecule. Typical examples of such polyhydric
alcohols are dihydric alcohols such as ethylene glycol, propylene
glycol, trimethylene glycol, 1,2-butylene glycol, 1,3-butylene
glycol, 1,4-butylene glycol, tetramethylene glycol, 2,3-butylene
glycol, pentamethylene glycol, 2-butene-1,4-diol, hexylene glycol,
octylene glycol; trihydric alcohols such as glycerine, trimethylol
propane, 1,2,6-hexanetriol and the like; tetrahydric alcohols such
as penthaerythritol; pentahydric alcohols such as xylytol, etc.;
hexahydric alcohols such as sorbitol, mannitol; polyhydric alcohol
polymers such as diethylene glycol, dipropylene glycol,
polyethylene glycol, polypropylene glycol, tetraethylene glycol,
diglycerine, polyethylene glycol, triglycerine, tetraglycerine,
polyglycerine; dihydric alcohol alkyl ethers such as ethylene
glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene
glycol monobutyl ether, ethylene glycol monophenyl ether, ethylene
glycol monohexyl ether, ethylene glycol mono-2-methylhexyl ether,
ethylene glycol isoamyl ether, ethylene glycol benzyl ether,
ethylene glycol isopropyl ether, ethylene glycol dimethyl ether,
ethylene glycol diethyl ether, ethylene glycol dibutyl ether;
dihydric alcohol alkyl ethers such as diethylene glycol monomethyl
ether, diethylene glycol monoethyl ether, diethylene glycol
monobutyl ether, diethylene glycol dimethyl ether, diethylene
glycol diethyl ether, diethylene glycol butyl ether, diethylene
glycol methyl ethyl ether, triethylene glycol monomethyl ether,
triethylene glycol monoethyl ether, propylene glycol monomethyl
ether, propylene glycol monoethyl ether, propylene glycol monobutyl
ether, propylene glycol isopropyl ether, dipropylene glycol methyl
ether, dipropylene glycol ethyl ether, dipropylene glycol butyl
ether; dihydric alcohol ether esters such as ethylene glycol
monomethyl ether acetate, ethylene glycol monoethyl ether acetate,
ethylene glycol monobutyl ether acetate, ethylene glycol monophenyl
ether acetate, ethylene glycol diadipate, ethylene glycol
disuccinate, diethylene glycol monoethyl ether acetate, diethylene
glycol monobutyl ether acetate, propylene glycol monomethyl ether
acetate, propylene glycol monoethyl ether acetate, propylene glycol
monopropyl ether acetate, propylene glycol monophenyl ether
acetate; glycerine monoalkyl ethers such as xyl alcohol, selachyl
alcohol, batyl alcohol; sugar alcohols such as sorbitol, maltitol,
maltotriose, mannitol, sucrose, erythritol, glucose, fructose,
starch sugar, maltose, xylytose, starch sugar reduced alcohol,
glysolid, tetrahydrofurfuryl alcohol, POE tetrahydrofurfuryl
alcohol, POP butyl ether, POP POE butyl ether, tripolyoxypropylene
glycerine ether, POP glycerine ether, POP glycerine ether
phosphoric acid, POP POE pentanerythritol ether.
[0120] Additional co-solvents which may be present are cosmetically
acceptable organic solvents or a mixture of solvents with a boiling
point below 400.degree. C. in an amount of from 0.1 to 15% by
weight, preferably from 1 to 10% by weight. Particularly suitable
additional co-solvents are unbranched or branched hydrocarbons,
such as pentane, hexane, isopentane and cyclic hydrocarbons, such
as cyclopentane and cyclohexane. Further, particularly preferred
water-soluble solvents are glycerol, ethylene glycol and propylene
glycol in an amount up to 30% by weight.
Direct Dyes
[0121] Preferred among the direct hair dyes are the following
compounds, alone or in combination with one another:
Hydroxyethyl-2-nitro-p-toluidine, 2-hydroxyethylpicramic acid,
4-nitrophenylaminourea, tri(4-amino-3-methylphenyl)carbenium
chloride (Basic Violet 2), 1,4-di-amino-9,10-anthracenedione
(Disperse Violet 1),
1-(2-hydroxy-ethyl)amino-2-nitro-4-[di(2-hydro-xyethyl)amino]benzene
(HC Blue No. 2),
4-[ethyl-(2-hydroxyethyl)amino]-1-[(2-hydroxy-ethyl)amino]-2-nitrobenzene
hydrochloride (HC Blue No. 12),
1-amino-4-[di(2-hydroxy-ethyl)amino]-2-nitrobenzene hydrochloride
(HC Red No. 13), 4-amino-1-[(2-hydroxyethyl)amino]-2-nitrobenzene
(HC Red No. 3), 4-amino-3-nitrophenol,
4-[(2-hydroxyethyl)amino]-3-nitrophenol,
1-amino-5-chloro-4-[(2,3-dihydroxypropyl)amino]-2-nitrobenzene (HC
Red No. 10),
5-chloro-1,4-[di(2,3-dihydroxypropyl)amino]-2-nitrobenzene (HC Red
No. 11), 2-chloro-6-ethylamino-4-nitro-phenol,
2-amino-6-chloro-4-nitrophenol,
4-[(2-hydroxyethyl)amino]-3-nitro-1-trifluoromethyl-benzene (HC
Yellow No. 13),
8-amino-2-bromo-5-hydroxy-4-imino-6-{[3-(trimethylammonio)-pheny-
l]amino}-1(4H)-naphthalenone chloride (C.I. 56059; Basic Blue No.
99), 1-[(4-amino-phenyl)azo]-7-(trimethylammonio)-2-naphthol
chloride (C.I. 12250; Basic Brown No. 16),
i-[(4-amino-2-nitrophenyl)azo]-7-(trimethylammonio)-2-naphthol
chloride (Basic Brown No. 17),
2-hydroxy-1-[(2-methoxyphenyl)azo]-7-(trimethylammonio)naphthalene
chloride (C.I. 12245; Basic Red No. 76),
3-methyl-1-phenyl-4-{[3-(trimethylammonio)phenyl]azo}pyrazol-5-one
chloride (C.I. 12719; Basic Yellow No. 57) and
2,6-diamino-3-[(pyridin-3-yl)azo]pyridine as well as the salts
thereof.
[0122] Particularly preferred among the aforesaid direct dyes are
the following compounds, alone or in combination with one another:
hydroxyethyl-2-nitro-p-toluidine, 2-hydroxyethylpicramic acid,
4-nitrophenylaminourea, tri(4-amino-3-methylphenyl)carbenium
chloride (Basic Violet 2), 1,4-di-amino-9,10-anthracenedione
(Disperse Violet 1),
1-(2-hydroxyethyl)amino-2-nitro-4-[di(2-hydro-xyethyl)amino]benzene
(HC Blue No. 2),
4-[ethyl-(2-hydroxyethyl)amino]-1-[(2-hydroxy-ethyl)amino]-2-nitrobenzene
hydrochloride (HC Blue No. 12),
1-amino-4-[di(2-hydroxy-ethyl)amino]-2-nitrobenzene hydrochloride
(HC Red No. 13), 4-amino-1-[(2-hydroxyethyl)amino]-2-nitrobenzene
(HC Red No. 3), 4-amino-3-nitrophenol,
4-[(2-hydroxyethyl)amino]-3-nitrophenol,
1-amino-5-chloro-4-[(2,3-dihydroxypropyl)amino]-2-nitrobenzene (HC
Red No. 10),
5-chloro-1,4-[di(2,3-dihydroxypropyl)-amino]-2-nitrobenzene (HC Red
No. 11), 2-chloro-6-ethylamino-4-nitro-phenol,
2-amino-6-chloro-4-nitrophenol,
4-[(2-hydroxyethyl)amino]-3-nitro-1-trifluoromethylben-zene (HC
Yellow No. 13),
8-amino-2-bromo-5-hydroxy-4-imino-6-{[3-(trimethylammonio)-pheny-
l]amino}-1(4H)-naphthalenone chloride (C.I. 56059; Basic Blue No.
99), 1-[(4-amino-phenyl)azo]-7-(trimethylammonio)-2-naphthol
chloride (C.I. 12250; Basic Brown No. 16),
1-[(4-amino-2-nitrophenyl)azo]-7-(trimethylammonio)-2-naphthol
chloride (Basic Brown No. 17),
2-hy-droxy-1-[(2-methoxyphenyl)azo]-7-(trimethylammonio)naphthalene
chloride (C.I. 12245; Basic Red No. 76),
3-methyl-1-phenyl-4-{[3-(trimethylammonio)phenyl]azo}pyrazol-5-one
chloride (C.I. 12719; Basic Yellow No. 57) and
2,6-diamino-3-[(pyridin-3-yl)azo]pyridine as well as the salts
thereof.
[0123] The total quantity of direct dyes in the composition of the
invention amounts to about 0.01 to 15% by weight, preferably 0.1 to
10% by weight, most preferred 0.5 to 8% by weight.
[0124] In one embodiment, the composition according to the
invention comprises at least one viscosity-modifying substance in
an amount of from preferably 0.01 to 20% by weight or 0.05 to 10%
by weight or particularly preferably from 0.1 to 5% by weight.
[0125] The viscosity-modifying substance is preferably a thickening
polymer, chosen from copolymers of at least one first monomer type,
which is chosen from acrylic acid and methacrylic acid, and at
least one second monomer type, which is chosen from esters of
acrylic acid and ethoxylated fatty alcohol; crosslinked polyacrylic
acid; crosslinked copolymers of at least one first monomer type,
which is chosen from acrylic acid and methacrylic acid, and at
least one second monomer type, which is chosen from esters of
acrylic acid with C10- to C30-alcohols; copolymers of at least one
first monomer type, which is chosen from acrylic acid and
methacrylic acid, and at least one second monomer type, which is
chosen from esters of itaconic acid and ethoxylated fatty alcohol;
copolymers of at least one first monomer type, which is chosen from
acrylic acid and methacrylic acid, at least one second monomer
type, which is chosen from esters of itaconic acid and ethoxylated
C10- to C30-alcohol and a third monomer type, chosen from C1- to
C4-aminoalkyl acrylates; copolymers of two or more monomers chosen
from acrylic acid, methacrylic acid, acrylic esters and methacrylic
esters; copolymers of vinyl-pyrrolidone and ammonium
acryloyldimethyltaurate; copolymers of ammonium
acryloyldimethyltaurate and monomers chosen from esters of
methacrylic acid and ethoxylated fatty alcohols;
hydroxyethylcellulose; hydroxypropylcellulose; hydroxypropylguar;
glyceryl polyacrylate; glyceryl polymethacrylate; copolymers of at
least one C2-, C3- or C4-alkylene and styrene; polyurethanes;
hydroxypropyl starch phosphate; polyacrylamide; copolymer of maleic
anhydride and methyl vinyl ether crosslinked with decadiene; carob
seed flour; guar gum; xanthan; dehydroxanthan; carrageenan; karaya
gum; hydrolyzed corn starch; copolymers of polyethylene oxide,
fatty alcohols and saturated methylenediphenyl diisocyanate (e.g.
PEG-150/stearyl alcohol/SMDI copolymer).
Surfactants:
[0126] In one embodiment, the composition according to the
invention comprises 0.01 to 50% by weight, particularly preferably
from 0.05 to 20% by weight, very particularly preferably from 0.1
to 15% by weight, of at least one emulsifier or surfactant. The
surfactant may be nonionic with HLB>8, anionic or
zwitterionic.
Nonionic Surfactants
[0127] From the nonionic surfactants optionally used those are
preferred having an HLB (Hydrophilic Lipophilic Balance) of greater
than 12. The nonionic surfactant of HLB>12 optionally present in
the composition may be, for example, an ethoxylated or
ethoxylated/propoxylated fatty alcohol with a fatty chain
comprising from 12 to 22 carbon atoms, ethoxylated sterols, such as
stearyl- or lauryl alcohol (EO-7); PEG-16 soya sterol or PEG-10
soya sterol, polyoxyethylene polyoxypropylene block polymers
(poloxamers) and their mixtures. Ethoxylated sterols and of
poloxamers are preferred.
[0128] Suitable nonionic surfactants are, for example, [0129]
ethoxylated fatty alcohols, fatty acids, fatty acid glycerides or
alkylphenols, in particular addition products of from 2 to 30 mol
of ethylene oxide and/or 1 to 5 mol of propylene oxide onto C8- to
C22-fatty alcohols, onto C12- to C22-fatty acids or onto alkyl
phenols having 8 to 15 carbon atoms in the alkyl group, [0130] C12-
to C22-fatty acid mono- and diesters of addition products of from 1
to 30 mol of ethylene oxide onto glycerol, [0131] addition products
of from 5 to 60 mol of ethylene oxide onto castor oil or onto
hydrogenated castor oil, [0132] fatty acid sugar esters, in
particular esters of sucrose and one or two C8- to C22-fatty acids,
INCI: Sucrose Cocoate, Sucrose Dilaurate, Sucrose Distearate,
Sucrose Laurate, Sucrose Myristate, Sucrose Oleate, Sucrose
Palmitate, Sucrose Ricinoleate, Sucrose Stearate, [0133] esters of
sorbitan and one, two or three C8- to C22-fatty acids and a degree
of ethoxylation of from 4 to 20, [0134] polyglyceryl fatty acid
esters, in particular of one, two or more C8- to C22-fatty acids
and polyglycerol having preferably 2 to 20 glyceryl units, [0135]
alkyl glucosides, alkyl oligoglucosides and alkyl polyglucosides
having C8 to C22-alkyl groups, e.g. decylglucoside or
laurylglucoside.
[0136] The amount of nonionic surfactant in the emulsion and the
cosmetic composition preferably can range from about 0.1% to about
50% by weight and more preferably from about 0.1% to about 10% by
weight of the total weight of the emulsion.
Anionic Surfactants
[0137] Suitable anionic surfactants are, for example, salts and
esters of carboxylic acids, alkyl ether sulfates and alkyl
sulfates, fatty alcohol ester sulfates, sulfonic acid and its salts
(e.g. sulfosuccinates or fatty acid isethienates), phosphoric
esters and their salts, acylamino acids and their salts. A detailed
description of these anionic surfactants is to be found in the
publication "FIEDLER--Lexikon der Hilfsstoffe [Lexikon of
auxiliaries]", Volume 1, 5th Edition (2002), pages 97 to 102, to
which reference is hereby expressly made. Preferred surfactants are
mono-, di- and/or triesters of phosphoric acid whose addition
products are from 2 to 30 mol of ethylene oxide onto C8- to
C22-fatty alcohols.
Amphoteric Surfactants
[0138] Suitable amphoteric surfactants are, for example,
derivatives of aliphatic quaternary ammonium, phosphonium and
sulfonium compounds of the formula
##STR00001##
where R.sup.1 is a straight-chain or branched-chain alkyl, alkenyl
or hydroxyalkyl group having 8 to 18 carbon atoms and 0 to about 10
ethylene oxide units and 0 to 1 glycerol unit; Y is a N-, P- or
S-containing group; R.sup.2 is an alkyl or monohydroxyalkyl group
having 1 to 3 carbon atoms; X is 1 if Y is a sulfur atom and X is 2
if Y is a nitrogen atom or a phosphorus atom; R.sup.3 is an
alkylene or hydroxyalkylene group having 1 to 4 carbon atoms and
Z.sup.(-) is a carboxylate, sulfate, phosphonate or phosphate
group.
[0139] Other amphoteric surfactants such as betaines are likewise
suitable. Examples of betaines includes C8- to C18-alkylbetaines,
such as cocodimethylcarboxymethylbetaine,
lauryldimethylcarboxymethylbetaine,
lauryldimethylalphacarboxyethylbetaine,
cetyldimethylcarboxymethylbetaine,
oleyldimethylgammacarboxypropylbetaine and
laurylbis(2-hydroxypropyl)alphacarboxyethylbetaine; C8- to
C18-sulfobetaines, such as cocodimethylsulfopropylbetaine,
stearyldimethylsulfopropylbetaine,
lauryldimethyl-sulfoethylbetaine,
laurylbis(2-hydroxyethyl)sulfopropylbetaine; the carboxyl
derivatives of imidazole, the C8- to C18-alkyldimethylammonium
acetates, the C8- to C18-alkyldimethylcarbonylmethylammonium salts,
and the C8- to C18-fatty acid alkylamidobetaines, such as, for
example, coconut fatty acid amidopropylbetaine and N-coconut fatty
acid amidoethyl-N-[2-(carboxymethoxy)ethyl]glycerol (CTFA name:
Cocoamphocarboxyglycinate).
Pigments
[0140] In one preferred embodiment, the composition according to
the invention comprises at least one pigment. These may be colored
pigments which impart color effects to the product mass or to the
hair, or they may be luster effect pigments which impart luster
effects to the product mass or to the hair. The color or luster
effects on the hair are preferably temporary, i.e. they last until
the next hair wash and can be removed again by washing the hair
with customary shampoos. The pigments are present in the product
mass in undissolved form and may be present in an amount of from
0.01 to 25% by weight, particularly preferably from 5 to 15% by
weight. The preferred particle size is 1 to 200 .mu.m, in
particular 3 to 150 .mu.m, particularly preferably 10 to 100 .mu.m.
The pigments are colorants which are virtually insoluble in the
application medium, and may be inorganic or organic.
Inorganic-organic mixed pigments are also possible. Preference is
given to inorganic pigments. The advantage of inorganic pigments is
their excellent resistance to light, weather and temperature. The
inorganic pigments may be of natural origin, for example produced
from chalk, ocher, umber, green earth, burnt sienna or graphite.
The pigments may be white pigments, such as, for example, titanium
dioxide or zinc oxide, black pigments, such as, for example, iron
oxide black, colored pigments, such as, for example, ultramarine or
iron oxide red, luster pigments, metal effect pigments, pearlescent
pigments, and fluorescent or phosphorescent pigments, where
preferably at least one pigment is a colored, nonwhite pigment. Of
suitability are metal oxides, hydroxides and oxide hydrates, mixed
phase pigments, sulfur-containing silicates, metal sulfides,
complex metal cyanides, metal sulfates, chromates and molybdates,
and the metals themselves (bronze pigments). Of particular
suitability are titanium dioxide (CI 77891), black iron oxide (CI
77499), yellow iron oxide (CI 77492), red and brown iron oxide (CI
77491), manganese violet (CI 77742), ultramarine (sodium aluminum
sulfosilicates, CI 77007, Pigment Blue 29), chromium oxide hydrate
(CI 77289), Prussian blue (ferric ferrocyanide, CI 77510), carmine
(cochineal).
[0141] Particular preference is given to pearlescent and colored
pigments based on mica which are coated with a metal oxide or a
metal oxychloride, such as titanium dioxide or bismuth oxychloride,
and optionally further color-imparting substances, such as iron
oxides, Prussian blue, ultramarine, carmine etc. and where the
color can be determined by varying the layer thickness. Such
pigments are sold, for example, under the trade names Rona.RTM.,
Colorona.RTM., Dichrona.RTM. and Timiron.RTM. by Merck,
Germany.
[0142] Organic pigments are, for example, the natural pigments
sepia, gamboge, bone charcoal, Cassel brown, indigo, chlorophyll
and other plant pigments. Synthetic organic pigments are, for
example, azo pigments, anthraquinoids, indigoids, dioxazine,
quinacridone, phthalocyanine, isoindolinone, perylene and perinone,
metal complex, alkali blue and diketopyrrolopyrrole pigments.
Solid Particles
[0143] In another embodiment, the composition according to the
invention comprises from 0.01 to 10% by weight, particularly
preferably from 0.05 to 5% by weight, of at least one particulate
substance. Suitable substances are, for example, substances which
are solid at room temperature (25.degree. C.) and are in the form
of particles. For example, silica, silicates, aluminates, clay
earths, mica, insoluble salts, in particular insoluble inorganic
metal salts, metal oxides, e.g. titanium dioxide, minerals and
insoluble polymer particles are suitable.
[0144] The particles are present in the composition in undissolved,
preferably stably dispersed form, and, following application to the
hair and evaporation of the solvent, can deposit on the hair in
solid form. A stable dispersion can be achieved by providing the
composition A with a yield point which is large enough to prevent
the solid particles from sinking. An adequate yield point can be
established using suitable gel formers in a suitable amount.
[0145] Preferred particulate substances are silica (silica gel,
silicon dioxide) and metal salts, in particular inorganic metal
salts, where silica is particularly preferred. Metal salts are, for
example, alkali metal or alkaline earth metal halides, such as
sodium chloride or potassium chloride; alkali metal or alkaline
earth metal sulfates, such as sodium sulfate or magnesium
sulfate.
[0146] The additives are used in quantities usual for such
purposes; for example, the wetting agents and emulsifiers in
concentrations of a total of 0.2% to 30% by weight, the alcohols in
a total quantity of 0.1% to 70% by weight, the opacifiers, perfume
oils and dyes in a quantity of 0.01% to 1% by weight each, the
buffer substances in a total quantity of 0.1% to 10% by weight, and
sugars, solubilizers, stabilizers, while the thickeners and
solubilizers may be contained in this composition in a total
quantity of 0.1 to 20% by weight. Surfactants are preferably
contained at levels of from about 0.1% to about 5%, more preferably
from about 0.1% to about 1.5%, most preferably from about 0.1% to
about 0.8%, by weight of the composition.
[0147] In another preferred embodiment, the composition according
to the invention comprises a cosmetically acceptable non aqueous
volatile solvent. As used herein, the term "volatile" refers to
liquids having a boiling point at one atmosphere of 260.degree. C.
or less, preferably 250.degree. C., more preferably 230.degree. C.
or less, most preferably 225.degree. C. or less. In general, the
boiling point of the volatile solvents will be at least about
50.degree. C., preferably at least about 100.degree. C.
[0148] The cosmetically acceptable volatile solvent is preferably a
glycol ether of a mono-alcohol of 2 to 6 carbon atoms, more
preferred an ethylene glycol or an propylene glycol ether of a
mono-alcohol of 2 to 6 carbon atoms, more preferred of a
mono-alcohol of 3 to 5 carbon atoms, most preferred it is ethylene
glycol mono butyl ether.
[0149] The volatile solvent is preferably present in an amount of
from 0.1 to 98% by weight, more preferred in an amount of from 1 to
60% by weight and most preferred in an amount of from 2 to 10% by
weight of the total weight of the hair treating composition.
UV-Absorbers
[0150] In one embodiment, the composition according to the
invention comprises a photoprotective substance in an amount of
from preferably 0.01 to 10% by weight or from 0.1 to 5% by weight,
particularly preferably from 0.2 to 2% by weight. The
photoprotective substances include, in particular, all of the
photoprotective substances specified in EP 1 084 696. Preference is
given to: 2-ethylhexyl 4-methoxycinnamate, methyl methoxycinnamate,
2-hydroxy-4-methoxybenzophenone-5-sulfonic acid and polyethoxylated
p-aminobenzoates.
Preservatives
[0151] In one embodiment, the composition according to the
invention comprises 0.01 to 5% by weight, particularly preferably
from 0.05 to 1% by weight, of at least one preservative. Suitable
preservatives are the substances listed in the International
Cosmetic Ingredient Dictionary and Handbook, 9th Edition with the
function "preservatives", e.g. phenoxyethanol, benzyl paraben,
butyl paraben, ethyl paraben, isobutyl paraben, isopropyl paraben,
methyl paraben, propyl paraben, iodopropynyl butylcarbamate,
methyldibromoglutaronitrile and DMDM hydantoin.
Viscosity
[0152] The hair shaping composition of the present invention
preferably has a viscosity at 25.degree. C. of about 0.1 mPas to
about 1,000,000 mPas, preferably from about 1 mPas to about 80,000
mPas, more preferably from about 5 mPas to about 3,500 mPas.
Viscosity is determined--if not otherwise defined--by HAAKE
Rotation Viscometer VT 550 with cooling/heating vessel and sensor
systems according to DIN 53019 (MV-DIN, SV-DIN), shear rate is 12.9
s.sup.-1.
pH-Value
[0153] By varying the pH value, a composition can be made available
that is universally suitable for every hair structure, optionally
with the additional application of heat.
[0154] The hair treating composition preferably has a pH value of
from 2.0 to 12.0, more preferred from 3.0 to 9.0 and most preferred
from 4.5 to 7.5. As an alkalizing agent or agent for adjusting the
pH value, ammonia or caustic soda is especially suitable, but
water-soluble, physiologically tolerable salts of organic and
inorganic bases can also be considered, such as ammonium hydrogen
carbonate, ammonia, monoethanolamine, ammonium carbonate. Further
suitable alkalizing agents may be selected from the group
consisting of 2-amino-2-methyl-1-propanol,
2-amino-2-methyl-1,3-propanediol, 2-amino-2-ethyl-1,3-propanediol,
tris(hydroxyl-methyl)-aminomethane, 2-amino-1-butanole,
tris-(2-hydroxypropyl)-amine, 2,2-iminobisethanol, lysine,
iminourea (guanidine carbonate), tetrahydro-1,4-oxazine,
2-amino-5-guanidin-valeric acid, 2-aminoethansulfonic acid,
diethanolamine, triethanolamine, N-methyl ethanolamine,
isopropanolamine, diisopropanolamine, triisopropanolamine,
glucamine, sodium hydroxide, potassium hydroxide, lithium hydroxide
and magnesium oxide.
[0155] To establish an acidic pH value, hydrochloric acid,
phosphoric acid, acetic acid, formic acid, sulfuric acid,
hydrochloric acid or citric acid can be used in particular. The
acidic pH can be also adjusted with a buffer such as a phosphate
buffer, a TRIS buffer or a citric buffer. The buffers may be used
alone or in combination with an acid.
Packaging
[0156] The composition may be sold in single- or dual- or
triple-component packages.
[0157] In another embodiment, the composition according to the
invention is in the form of a gel, in the form of a viscous lotion
or in the form of a spray gel which is sprayed with a mechanical
device and comprises at least one of the above mentioned thickening
polymers in an amount of from preferably 0.05 to 10% by weight,
particularly preferably from 0.1 to 2% by weight and has a
viscosity of at least 250 mPas (measured using a Bohlin rheometer
CS, measurement body C25 at 25.degree. C. and a shear rate of 50
s.sup.-1). The viscosity of the gel is preferably from 500 to
50,000 mPas, particularly preferably from 1,000 to 15,000 mPas at
25.degree. C.
[0158] In another embodiment, the composition according to the
invention is in the form of an O/W emulsion, a W/O emulsion or a
micro emulsion, and comprises at least one of the above-mentioned
oils or waxes emulsified in water, and at least one of the
abovementioned surfactants.
[0159] In another embodiment, the composition according to the
invention is in the form of a spray product, either in combination
with a mechanical pump spray device or in combination with at least
one propellant chosen from propane, butane, dimethyl ether and
fluorinated hydro-carbons. If the composition is an aerosol spray
it additionally comprises preferably 15 to 85% by weight,
particularly preferably 25 to 75% by weight, of a propellant and is
bottled in a pressurized container. Suitable propellants are, for
example, lower alkanes, such as, for example, n-butane, isobutane
and propane, or mixtures thereof, and dimethyl ether or fluorinated
hydrocarbons, such as F 152a (1,1-difluoroethane) or F 134
(tetrafluoroethane), and also propellants which are in gaseous form
at the pressures under consideration, such as, for example,
N.sub.2, N.sub.2O and CO.sub.2, and mixtures of the abovementioned
propellants.
[0160] If the composition of the invention is formulated as a
non-aerosol hairspray it is sprayed out from the container with the
help of a suitable mechanically operated spraying device.
Mechanical spraying devices are understood as meaning those devices
which permit the spraying of a composition without use of a
propellant. A suitable mechanical spray device used may, for
example, be a spray pump or an elastic container provided with a
spray valve in which the cosmetic composition according to the
invention is bottled under pressure, where the elastic container
expands and from which the composition is continuously dispensed as
a result of the elastic container contracting upon opening the
spray valve.
[0161] In another embodiment, the composition according to the
invention is in the form of a foamable product (mousse) in
combination with a devices for foaming, comprises at least one
customary foam-imparting substance known for this purpose, e.g. at
least one foam-forming surfactant or at least one foam-forming
polymer. Devices for foaming are understood as meaning those
devices which enable the foaming of a liquid with or without use of
a propellant. A suitable mechanical foaming device which can be
used is, for example, a standard commercial pump foamer or an
aerosol foaming head. The product is either in combination with a
mechanical pump foaming device (pump foam) or in combination with
at least one propellant (aerosol foam) in an amount of from
preferably 1 to 20% by weight, in particular from 2 to 10% by
weight. Propellants are chosen, for example, from propane, butane,
dimethyl ether and fluorinated hydrocarbons. The composition is
foamed directly prior to application and incorporated into the hair
as foam and can then be rinsed out or left in the hair without
rinsing.
[0162] The foamable product comprise, as active ingredients or
additives, preferably polymers which are chosen from chitosan,
chitosan salts, chitosan derivatives, cationic cellulose compounds,
copolymers of vinylpyrrolidone, vinylcaprolactam and a basic
acrylamide monomer or mixtures of these polymers. Suitable chitosan
salts, chitosan derivatives, cationic cellulose derivatives are,
for example, those mentioned above. Preferred cationic cellulose
compounds are copolymers of hydroxyethylcellulose and
diallyldimethylammonium chloride (polyquaternium-4) and reaction
products of hydroxyethylcellulose and epoxides substituted by a
trialkylammonium group (Polyquaternium-10). Preferred chitosan
salts are the salts with formic acid, lactic acid and
pyrrolidonecarboxylic acid. Preferred copolymers of
vinylpyrrolidone, vinylcaprolactam and a basic acrylamide monomer
are those in which the acrylamide monomer is
dimethylaminopropylacrylamide. Also preferred are foamable products
which comprise copolymers of hydroxyethylcellulose and
diallyldimethylammonium chloride (polyquaternium-4) and copolymers
of vinylpyrrolidone, vinylcaprolactam and
dimethylaminopropylacrylamide, and foamable products which comprise
copolymers of hydroxyethylcellulose and diallyldimethylammonium
chloride (polyquaternium-4) and copolymers of vinylpyrrolidone,
vinylcaprolactam and dimethylaminopropylacrylamide, and at least
one chitosan salt.
[0163] In another embodiment, the composition according to the
invention is in the form of a hair wax, i.e. it has a wax-like
consistency and comprises at least one of the above-mentioned waxes
in an amount of from preferably 0.5 to 30% by weight, and
optionally further water-insoluble substances. The wax-like
consistency is preferably characterized in that the needle
penetration number (unit of measurement 0.1 mm, test weight 100 g,
test time 5 s, test temperature 25.degree. C.; according to DIN 51
579) is greater than or equal to 10, particularly preferably
greater than or equal to 20 and that the solidification point of
the product is preferably greater than or equal to 30.degree. C.
and less than or equal to 70.degree. C., particularly preferably in
the range from 40 to 55.degree. C. Suitable waxes and
water-insoluble substances are, in particular, emulsifiers with an
HLB value below 7, silicone oils, silicone waxes, waxes (e.g. wax
alcohols, wax acids, wax esters, and in particular natural waxes
such as beeswax, carnauba wax, etc.), fatty alcohols, fatty acids,
fatty acid esters or hydrophilic waxes, such as, for example, high
molecular weight polyethylene glycols with a molecular weight of
from 800 to 20,000 g/mol, preferably from 2,000 to 10,000
g/mol.
[0164] If the hair-treatment composition according to the invention
is in the form of a hair lotion, then it has the form of an
essentially non-viscous or low-viscosity, flowable solution,
dispersion or emulsion with a content of at least 10% by weight,
preferably 20 to 95% by weight, of a cosmetically compatible
alcohol. Alcohols which can be used are, in particular, the lower
alcohols having 1 to 4 carbon atoms customarily used for cosmetic
purposes, e.g. ethanol and isopropanol.
[0165] If the hair-treatment composition according to the invention
is in the form of a hair cream, then it is preferably in the form
of an emulsion and comprises either additionally
viscosity-imparting ingredients in an amount of from 0.1 to 10% by
weight, or the required viscosity and creamy consistency is built
up in a customary manner through micelle formation with the help of
suitable emulsifiers, fatty acids, fatty alcohols, waxes etc.
[0166] In another aspect of the invention there is provided a
method for reducing the time to dry wet hair, for example, drying
wet hair following showering, shampooing, bathing, swimming, and
the like, or to shorten the drying time of an aqueous hair treating
composition comprising applying to dry or wet hair the above
specified hair treating composition containing the
polydimethylsiloxane (P) and subsequently drying the hair.
[0167] In a preferred embodiment of the invention a method to
shorten the drying time of an aqueous hair treating composition on
the head of a person and simultaneously to protect the hair dye on
said hair from being washed out is provided, comprising the steps
of: [0168] (a) applying a hair dying composition onto the hair to
be dyed on the head of a person, [0169] (b) leaving the hair dying
composition on the hair for a time required to dye said hair,
[0170] (c) optionally rinsing said hair with water or an aqueous
acidic composition, [0171] (d) optionally towelling and/or drying
said hair, [0172] (e) applying to said hair the above specified
polydimethylsiloxane (P) and the protonating agent or the above
specified hair treating composition containing the
polydimethylsiloxane (P) and the protonating agent and [0173] (f)
subsequently drying said hair.
[0174] In a further preferred embodiment it is provided a method
for dying the hair on the head of a person while simultaneously
reducing the time to dry said hair and to protect the hair dye on
said hair from being washed out, comprising the steps of:
(a) applying a hair dying composition onto the hair to be dyed, (b)
leaving the hair dying composition on the hair for a time required
to dye said hair, (c) optionally rinsing said hair with water or an
aqueous acidic composition, (d) optionally towelling and/or drying
said hair, (e) applying to said hair the above specified
polydimethylsiloxane (P) and the protonating agent or the above
specified hair treating composition containing the
polydimethylsiloxane (P) and the protonating agent and (f)
subsequently drying said hair.
[0175] Before or during the drying step, the hair may be
mechanically processed to help water to sheet from the hair. Such
processing includes brushing, combing, towelling, and the like. In
the case of towelling, it is seen that mechanical action is
typically combined with absorbing of the water present on the hair.
In the case of blow drying of the hair, it is seen that the force
of the hot air from the dryer will also cause the water to sheet
from the hair. Surprisingly, the time to dry the hair is reduced,
notwithstanding the application to hair of additional water.
[0176] In a further preferred embodiment of the invention a method
for enhancing the durability of a hair shape against humidity,
water and hair washings while simultaneously reducing the time to
dry said hair is provided, comprising the steps of:
(a) shaping the hair, (b) optionally rinsing said hair with water
or an aqueous acidic composition, (c) optionally towelling and/or
drying said hair, (d) applying to said hair the above specified
polydimethylsiloxane (P) and the protonating agent or the above
specified hair treating composition containing the
polydimethylsiloxane (P) and the protonating agent and (e)
subsequently drying said hair.
[0177] In a further preferred embodiment a method for enhancing the
durability of a hair shape against humidity, water and hair
washings while simultaneously reducing the time to dry said hair is
provided, comprising the steps of:
(a) washing said hair, (b) optionally towelling and/or drying said
hair, (c) applying to said hair the above specified
polydimethylsiloxane (P) and the protonating agent or the above
specified hair treating composition containing the
polydimethylsiloxane (P) and the protonating agent and (d)
subsequently drying and simultaneously shaping said hair.
[0178] The examples below serve to illustrate the subject matter of
the invention in more detail. Unless stated otherwise, the polymer
contents given in each case refer to the solids content.
EXAMPLES
Substances Used in the Examples
[0179] Amino-Functional Organopolysiloxanes Used:
Amine Oil 1:
[0180] Amine Oil 1 has a viscosity of about 1000 mm.sup.2/s at
25.degree. C., the functional radicals are
--CH.sub.2).sub.3NH(CH.sub.2).sub.2NH.sub.2 and has an amine number
of 0.6 meq/g of organopolysiloxane. In addition, the
organopolysiloxane contains about 0.75 mol % of reactive OMe/OH
radicals as terminal groups.
Amine Oil 2:
[0181] Amine Oil 2 has a viscosity of about 1000 mm.sup.2/s at
25.degree. C., the functional radicals are
--CH.sub.2).sub.3NH(CH.sub.2).sub.2NH.sub.2 and has an amine number
of 0.6 meq/g of organopolysiloxane. The terminal groups in this
case are Me.sub.3SiO radicals.
Amine Oil 3:
[0182] Amine oil 3 has a viscosity of about 230 mm.sup.2/s at
25.degree. C., the functional radicals are
--(CH.sub.2).sub.3NH(CH.sub.2).sub.2NH.sub.2, and an amine number
of 2.6 meq/g of organopolysiloxane. The terminal groups are
likewise Me.sub.3SiO radicals.
Emulsions
Emulsion A
[0183] 16 .g of Amine Oil 1 are added to 6 g of water, 6 g of
ethylene glycol monobutyl ether and 0.17 g of acetic acid at room
temperature while stirring, and the remaining water to a total
weight of 100 g is then also incorporated. A milky opaque emulsion
is obtained. The emulsion is added at room temperature as last
ingredient to the active solution/dispersion of the following
examples.
Emulsion B
[0184] 16 .g of a mixture of 11.1 g of Amine Oil 2 and 4.9 g of MQ
resin are added to 6 g of water, 6 g of ethylene glycol monobutyl
ether and 0.17 g of acetic acid at room temperature while stirring,
and the remaining water to a total weight of 100 g is then also
incorporated. A milky opaque emulsion is obtained. The emulsion is
added at room temperature as last ingredient to the active
solution/dispersion of the following examples.
Emulsion C
[0185] 16 .g of a mixture of 11.1 g of Amine Oil 3 and 4.9 g of MQ
resin are added to 6 g of water and 0.17 g of acetic acid at room
temperature while stirring, and the remaining water to a total
weight of 100 g is then also incorporated. A milky opaque emulsion
is obtained. The emulsion is added at room temperature as last
ingredient to the active solution/dispersion of the following
examples.
Trade Names Used in the Examples
[0186] Abilquat.RTM. 3270: Quaternium-80, 50% in propylene glycol
(Goldschmidt) [0187] Aculyn.RTM. 48: PEG-150/STEARYL ALCOHOL/SMDI
COPOLYMER, 19% in water (Rohm and Haas) [0188] AMP 95%
Aminomethylpropanol, 95% aqueous solution [0189] Amphomer.RTM.
OCTYLACRYLAMIDE/ACRYLATES/BUTYLAMINOETHYL-METHACRYLATE COPOLYMER
[0190] Aristoflex.RTM. AVC AMMONIUM ACRYLOYLDIMETHYLTAURATENVP
COPOLYMER [0191] Aquaflex.RTM. FX-64:
ISOBUTYLENE/ETHYLMALEIMIDE/HYDROXY-ETHYLMALEIMIDE COPOLYMER, 40%
strength in water/ethanol (ISP) [0192] Aquaflex.RTM. SF 40:
VPNVINYL CAPROLACTAM/DMAPA ACRYLATES COPOLYMER, 40% in ethanol
(ISP) [0193] Advantage.RTM. S VINYL
CAPROLACTAMNVP/DIMETHYLAMINOETHYL METHACRYLATE COPOLYMER [0194]
Carbomer (Carbopol) Acrylic acid homopolmer [0195] Celquat.RTM.
L200: Copolymer of hydroxyethylcellulose and
diallyldimethylammonium chloride; Polyquaternium-4 [0196] GENAMIN
CTAC 50 CTFA: Cetrimonium Chloride; Cetyltrimethylammonium chloride
[0197] Copolymer 845: VP/DIMETHYLAMINOETHYLMETHACRYLATE COPOLYMER,
20% in water (ISP) [0198] Dehydrol.RTM. LS 4 Lauryl alcohol
tetraoxyethylen ether [0199] Dekaben.RTM. LMB: IODOPROPYNYL
BUTYLCARBAMATE, 10% strength in butylene glycol [0200] Dekaben.RTM.
LMP: Phenoxyethanol and iodopropynyl butylcarbamate [0201]
Diaformer Z-711: ACRYLATES/LAURYL ACRYLATE/STEARYL
ACRYLATE/ETHYLAMINE OXIDE METHACRYLATE COPOLYMER, 40% (Clariant)
[0202] Dow Corning 1401: High molecular weight Dimethiconol, 13% in
cyclomethicone [0203] Eumulgin.RTM. L: INCI: PEG-1-PEG-9 LAURYL
GLYCOL ETHER Flexan.RTM. Sodium polystyrenesulfonate [0204]
GAFQUAT.RTM. 755 N CTFA: Polyquaternium-11 [0205] Jaguar C-17/162
CTFA: GUAR HYDROXYPROPYLTRIMONIUM CHLORIDE Laureth-4 Lauryl alcohol
tetraoxyethylen ether [0206] Luviset.RTM. Clear: Terpolymer of
vinylpyrrolidone, methacrylamide and vinylimidazole (BASF) [0207]
Luviskol.RTM. VA 64 Vinylpyrrolidone/vinylacetate copolymer
Luviskol.RTM. K 90 Powder Vinylpyrrolidone [0208] Luvimer.RTM. 100
P t-butyl acrylate/ethyl acrylate/methacrylic acid copolymer [0209]
Natrosol.RTM. G: Hydroxyethylcellulose [0210] Pemulen.RTM.:
ACRYLATES/C10-30 ALKYL ACRYLATE CROSSPOLYMER [0211] Structure.RTM.
3001: ACRYLATES/CETETH-20 ITACONATE COPOLYMER 30% strength in water
(National Starch) [0212] Surfactant 193: Ethoxylated
dimethylpolysiloxane; INCI: PEG-12 Dimethicone (Dow Corning) [0213]
Synthalen.RTM. W 2000: ACRYLATES/PALMETH-25 ACRYLATE COPOLYMER (31%
in water) [0214] Tego Betain L 5045 CTFA: COCAMIDOPROPYL
BETAINE
Example 1
Liquid Gel
TABLE-US-00001 [0215] Emulsion A 2.00 g Luviset .RTM. Clear 1.00 g
Surfactant 193 1.50 g Carbomer 0.30 g AMP 95% 0.30 g Emulgin L 0.20
g Perfume 0.15 g Natrosol .RTM. G 0.40 g Ethanol 16.50 g Water ad
100.00 g
Example 2
Liquid Gel
TABLE-US-00002 [0216] Emulsion B 3.00 g Luviset .RTM. Clear 1.00 g
Vinylpyrrolidone/vinyl acetate copolymer 1.00 g Direct dye 0.20 g
Surfactant 193 1.00 g Xanthan Gum 1.20 g Citric acid 0.10 g Perfume
0.15 g Ethanol 6.50 g DMDM Hydantoin 0.30 g Water ad 100.00 g
Example 3
Liquid Gel
TABLE-US-00003 [0217] Emulsion B 4.00 g Luviset .RTM. Clear 0.50 g
Glucose 7.00 g Direct dye 0.50 g Propylene glycol 3.80 g
Hydroxypropylguar 0.30 g AMP 95% 0.20 g PEG-25 PABA 0.50 g PEG-40
Hydrogenated Castor Oil 0.18 g PPG-1-PEG-9 Lauryl Glycol Ether 0.18
g Perfume 0.15 g Ethanol 16.50 g Water ad 100.00 g
Example 4
Spray Gel
TABLE-US-00004 [0218] Emulsion C 1.00 g Luviset .RTM. Clear 1.50 g
Luviskol .RTM. VA 64 3.00 g Ethanol 18.00 g Aminomethylpropanol 95%
aqueous solution 0.10 g PEG-40 Hydrogenated Castor Oil 0.20 g
Perfume 0.20 g Aculyn .RTM. 48 0.50 g Water ad 70.00 g
[0219] The composition is packaged in a packaging with pump spray
device.
Example 5
Rapidly Drying Gel
TABLE-US-00005 [0220] Emulsion A 1.00 g Luviset .RTM. Clear 3.00 g
Aquaflex .RTM. SF 40 2.80 g Surfactant 193 1.50 g Pemulen .RTM.
0.35 g AMP 95% 0.26 g Methylmethoxycinnamate 0.30 g Perfume 0.30 g
Ethanol 34.20 g Water ad 100.00 g
Example 6
Rapidly Drying Gel Spray
TABLE-US-00006 [0221] Emulsion A 0.80 g Luviset .RTM. Clear 1.00 g
Surfactant 193 1.00 g Carbomer (Carbopol) 0.23 g AMP 95% 0.22 g
Perfume 0.15 g Ethanol 6.50 g Water ad 100.00 g
[0222] The composition is packaged in a packaging with pump spray
device.
Example 7
Blow-Drying Gel
TABLE-US-00007 [0223] Emulsion A 1.80 g Luviset .RTM. Clear 1.00 g
Surfactant 193 1.00 g Hydroxypropylcellulose (Klucel .RTM. HF) 0.95
g Citric acid 0.10 g Perfume 0.15 g Ethanol 6.50 g Water ad 100.00
g
Example 8
Rapid Drying Gel
TABLE-US-00008 [0224] Emulsion B 2.90 g Luviset .RTM. Clear 1.00 g
Polyvinylpyrrolidone K 90 1.80 g Direct dye 1.00 g Surfactant 193
1.50 g Synthalen .RTM. W 2000 1.00 g AMP 95% 0.30 g PEG-25 PABA
(Uvinul .RTM. P 25) 0.30 g Panthenol 0.15 g Perfume 0.30 g Ethanol
34.20 g Keratin hydrolysate 0.10 g Water ad 100.00 g
Example 9
Gel--Strong Hold
TABLE-US-00009 [0225] Emulsion A 3.80 g Luviset .RTM. Clear 1.00 g
VA/CROTONATES COPOLYMER (Luviset .RTM. CA 66) 2.50 g Sorbitol 4.20
g Direct dye 0.?? g Carbomer (Tego Carbomer) 0.80 g AMP 95% 0.30 g
Methylparaben 0.20 g PEG-40 Hydrogenated Castor Oil 0.20 g
Panthenol 0.10 g Perfume 0.20 g Ethanol 5.00 g Water ad 100.00
g
Example 10
Gel--Strong Hold
TABLE-US-00010 [0226] Emulsion A 5.80 g Luviset .RTM. Clear 1.00 g
Aquaflex .RTM. SF 40 1.50 g Vinyl acetate/crotonic acid copolymer
1.20 g Sorbitol 4.20 g Structure .RTM. 3001 0.12 g AMP 95% 0.35 g
PEG-25 PABA 0.50 g Dekaben .RTM. LMB 0.20 g PEG-40 Hydrogenated
Castor Oil 0.20 g Panthenol 0.10 g Perfume 0.20 g Ethanol 5.00 g
Water ad 100.00 g
Example 11
Gel--Normal Hold
TABLE-US-00011 [0227] Emulsion B 3.80 g Luviset .RTM. Clear 1.50 g
Glycerol 5.20 g Propylene glycol 4.00 g Ammonium
Acryloyldimethyltaurate/VP Copolymer 0.35 g (Aristoflex .RTM. AVC)
AMP 95% 0.26 g Polysorbate-40 1.00 g Methylparaben 0.20 g PEG-25
PABA 0.50 g Perfume 0.20 g Ethanol 4.50 g Water ad 100.0 g
Example 12
Pump--Setting Foam
TABLE-US-00012 [0228] Emulsion A 0.20 g Luviset .RTM. Clear 1.30 g
Vinyl acetate/crotonic acid copolymer 0.30 g Cocamidopropyl
Hydroxysultaine 0.40 g Citric acid 0.10 g Ethanol 8.90 g Betaine
0.10 g Perfume 0.15 g Water ad 100.00 g
[0229] The composition is packaged in a packaging with mechanically
operated pump foaming device.
Example 13
Pump--Setting Foam
TABLE-US-00013 [0230] Emulsion A 1.20 g Luviset .RTM. Clear 1.50 g
Acrylic acid/ethyl acrylate/N-tert-butylacrylamide 0.40 g Copolymer
Direct dye 1.90 g Cocamidopropyl Hydroxysultaine 0.40 g Citric acid
0.10 g Dekaben .RTM. LMP 0.20 g Camomile blossom extract 0.10 g
Perfume 0.15 g Water ad 100.00 g
[0231] The composition is packaged in a packaging with mechanically
operated pump foaming device.
Example 14
Pump--Setting Foam
TABLE-US-00014 [0232] Emulsion A 7.20 g Luviset .RTM. Clear 1.20 g
Polyquaternium-6 0.35 g Cocamidopropyl Hydroxysultaine 0.40 g
Panthenol 0.10 g Ethanol 8.90 g Betaine 0.10 g Perfume 0.15 g Water
ad 100.00 g
[0233] The composition is packaged in a packaging with mechanically
operated pump foaming device.
Example 15
Pump--Setting Foam
TABLE-US-00015 [0234] Emulsion A 1.20 g Luviset .RTM. Clear 2.50 g
Direct dye 3.00 g Ethanol 8.90 g Cocamidopropyl Hydroxysultaine
0.20 g Cetyltrimethylammonium chloride 0.20 g Perfume 0.15 g Silk
fibroin hydrolysate (Silkpro .RTM.) 0.10 g Water ad 100.00 g
[0235] The composition is packaged in a packaging with mechanically
operated pump foaming device.
Example 16
Pump--Setting Foam
TABLE-US-00016 [0236] Emulsion A 2.20 g Luviset .RTM. Clear 2.00 g
Celquat .RTM. L200 0.30 g Direct dye 0.80 g Ethanol 8.90 g
Cocamidopropyl Hydroxysultaine 0.20 g Cetyltrimethylammonium
chloride 0.20 g Perfume 0.15 g Citric acid 0.10 g Betaine 0.10 g
Water ad 100.00 g
[0237] The composition is packaged in a packaging with mechanically
operated pump foaming device.
Example 17
Pump--Setting Foam
TABLE-US-00017 [0238] Emulsion B 1.20 g Luviset .RTM. Clear 1.30 g
Polyquaternium-11 0.30 g Direct dye 0.20 g Cocamidopropyl
Hydroxysultaine 0.40 g Propylene glycol 1.00 g Methylparaben 0.20 g
Perfume 0.15 g Water ad 100.00 g
[0239] The composition is packaged in a packaging with mechanically
operated pump foaming device.
Example 18
Pump--Setting Foam
TABLE-US-00018 [0240] Emulsion C 1.20 g Luviset .RTM. Clear 1.80 g
Direct dye 1.90 g Cocamidopropyl Hydroxysultaine 0.40 g Rosemary
leaf extract (Extrapon .RTM. Rosemary) 0.10 g Ethanol 8.90 g
Extrapon .RTM. seven herbs-extract 0.10 g Panthenyl ethyl ether
0.10 g Perfume 0.15 g Water ad 100.00 g
[0241] The composition is packaged in a packaging with mechanically
operated pump foaming device.
Example 19
Aerosol--Setting Foam--Normal Hold
TABLE-US-00019 [0242] Emulsion A 4.20 g Luviset .RTM. Clear 1.50 g
Butyl monoester of methyl vinyl ether/maleic acid 0.50 g copolymer
Butane 4.00 g Propane 4.00 g Ethanol 8.90 g PEG-25 PABA 0.40 g
Betaine 0.15 g Perfume 0.15 g Laureth-4 0.20 g Cetrimonium bromide
0.05 g Amodimethicone 0.50 g Water ad 100.00 g
[0243] The composition is bottled in an aerosol can with foaming
head.
Example 20
Aerosol--Setting Foam--Normal Hold
TABLE-US-00020 [0244] Emulsion A 5.20 g Luviset .RTM. Clear 1.50 g
Polyquaternium-47 0.50 g Butane 4.00 g Propane 4.00 g Betaine 0.15
g Dow Corning 1401 0.25 g 2-Ethylhexyl 4-methoxycinnamate 0.20 g
Perfume 0.15 g Laureth-4 0.20 g Cetrimonium chloride 0.07 g Water
ad 100.00 g
[0245] The composition is bottled in an aerosol can with foaming
head.
Example 21
Aerosol--Setting Foam--Extra Strong Hold
TABLE-US-00021 [0246] Emulsion A 3.20 g Luviset .RTM. Clear 2.10 g
Copolymer 845 2.50 g Polyquaternium-4 1.00 g Butane 4.00 g Propane
4.00 g Panthenol 0.20 g Perfume 0.20 g Abilquat .RTM. 3270 0.70 g
Cetrimonium chloride 0.07 g Water ad 100.00 g
[0247] The composition is bottled in an aerosol can with foaming
head.
Example 22
Aerosol--Setting Foam--Extra Strong Hold
TABLE-US-00022 [0248] Emulsion A 1.20 g Luviset .RTM. Clear 2.10 g
Vinyl acetate/crotonic acid copolymer 0.60 g Polyquaternium-7 0.50
g Butane 4.00 g Propane 4.00 g Ethanol 510 8.90 g PEG-25 PABA 0.40
g Panthenol 0.20 g Perfume 0.20 g Laureth-4 0.20 g C9-C11 Pareth-8
0.07 g Water ad 100.00 g
[0249] The composition is bottled in an aerosol can with foaming
head.
Example 23
Setting Spray
TABLE-US-00023 [0250] Emulsion A 0.20 g Luviset .RTM. Clear 1.50 g
Aquaflex .RTM. FX-64 1.00 g Ethanol 2.70 g Polyquaternium-35 1.00 g
PEG-25 PABA 0.70 g Panthenol 0.35 g Perfume 0.25 g Cetrimonium
chloride 0.20 g PEG-40 Hydrogenated Castor Oil 0.21 g Water ad
100.00 g
[0251] The composition is bottled in a packaging with pump spray
device.
Example 24
Setting Spray
TABLE-US-00024 [0252] Emulsion B 1.20 g Luviset .RTM. Clear 2.50 g
Octylacrylamide/Acrylates/Butylaminoethylmethacrylate 2.00 g
Copolymer (Amphomer .RTM.) Ethanol 28.50 g Aminomethylpropanol 95%
0.60 g Perfume 0.25 g Cetyltrimethylammonium bromide 0.20 g Water
ad 60.00 g
[0253] The composition is bottled in a packaging with pump spray
device.
Example 25
Setting Spray
TABLE-US-00025 [0254] Emulsion B 2.20 g Luviset .RTM. Clear 1.00 g
Octylacrylamide/Acrylates/Butylaminoethylmethacrylate 0.65 g
Copolymer (Amphomer .RTM.) Celquat .RTM. L200 0.20 g Ethanol 28.5 g
Aminomethylpropanol 95% 0.60 g Perfume 0.25 g
Cetyltrimethylammonium chloride 0.20 g Water ad 60.00 g
[0255] The composition is bottled in a packaging with pump spray
device.
Example 26
Non-Aerosol Blow-Drying Lotion
TABLE-US-00026 [0256] Emulsion C 3.50 g Luviset .RTM. Clear 2.80 g
Vinyl Caprolactam/VP/Dimethylaminoethyl Methacrylate 2.00 g
Copolymer (Advantage .RTM. S) Ethanol 28.50 g Perfume 0.25 g
Cetyltrimethylammonium chloride 0.20 g Water ad 60.00 g
Example 27
Nonaerosol Blow-Drying Lotion
TABLE-US-00027 [0257] Emulsion C 1.50 g Luviset .RTM. Clear 3.10 g
Celquat .RTM. L200 0.05 g Diaformer .RTM. Z-711 0.50 g Ethanol
27.00 g Betaine 0.10 g Perfume 0.25 g PEG-40 Hydrogenated Castor
Oil 0.21 g Cetyltrimethylammonium bromide 0.20 g Water ad 100.00
g
Example 28
Nonaerosol Blow-Drying Lotion
TABLE-US-00028 [0258] Emulsion C 2.50 g Luviset .RTM. Clear 3.00 g
Sodium polystyrenesulfonate (Flexan .RTM.) 2.30 g Perfume 0.20 g
Phenyltrimethicone (Baysilon .RTM. oil PD 5) 0.02 g Water 10.00 g
Ethanol ad 100.00 g
[0259] The active ingredient solution is bottled in the ratio 45:55
with DME as propellant in an aerosol can.
Example 29
VOC 80 Pump Spray--Strong Hold
TABLE-US-00029 [0260] Emulsion A 1.50 g Luviset .RTM. Clear 6.50 g
t-Butyl acrylate/Ethyl acrylate/Methacrylic acid 0.50 g Copolymer
(Luvimer .RTM. 100 P) Perfume 0.20 g AMP 0.10 g Betaine 0.05 g
Ethanol 55.00 g Demineralized water ad 100.00 g
[0261] The composition is bottled in a packaging with pump spray
device.
Example 30
Aerosol--hairspray
TABLE-US-00030 [0262] Emulsion A 2.80 g Octylacrylamide/Acrylic
acid/Butylaminoethyl 3.00 g methacrylate/Methyl
methacrylate/hydroxypropyl methacrylate Copolymer (Amphomer .RTM.)
Luviset .RTM. Clear 1.50 g Phenyl trimethicone (Baysilon .RTM. oil
PD 5) 0.02 g Perfume 0.20 g Water 10.00 g AMP 95% 0.48 g Ethanol
510 ad 100.00 g
[0263] The active ingredient solution is bottled in the ratio 45:55
with DME as propellant in an aerosol can.
Example 31
Aerosol--Hairspray
TABLE-US-00031 [0264] Emulsion A 1.90 g t-Butyl acrylate/Ethyl
acrylate/Methacrylic acid 3.30 g Copolymer (Luvimer .RTM. 100 P)
Luviset .RTM. Clear 3.30 g VA/CROTONATES COPOLYMER (Luviset .RTM.
CA 66) 1.00 g Perfume 0.20 g Water 10.00 g AMP 95% 0.84 g Ethanol
ad 100.00 g
[0265] The active ingredient solution is bottled in the ratio 45:55
with DME as propellant in an aerosol can.
Example 32
Aerosol--Hairspray
TABLE-US-00032 [0266] Emulsion A 4.20 g Luviset .RTM. Clear 2.50 g
t-Butyl acrylate/Ethyl acrylate/Methacrylic acid 3.30 g Copolymer
(Luvimer .RTM. 100 P) Aminomethylpropanol 95% 0.85 g Perfume 0.20 g
Baysilon .RTM. oil PD 5 0.02 g Water 10.00 g Ethanol ad 100.00
g
[0267] The active ingredient solution is bottled in the ratio 45:55
with DME as propellant in an aerosol can.
Example 33
Volumizing Aerosol Foam
TABLE-US-00033 [0268] Emulsion B 7.20 g Luviset .RTM. Clear 1.90 g
Celquat .RTM. L200 0.90 g Aquaflex .RTM. SF 40 0.40 g Laureth-4
0.20 g Cetrimonium chloride 0.10 g Perfume 0.10 g Butane 2.20 g
Propane 3.00 g Isobutane 0.80 g Water ad 100.00 g
[0269] The composition is bottled in an aerosol can with foaming
head. Through use of the product on the hair, the hairstyle is
given long-lasting volume.
Example 34
Volumizing Aerosol Foam
TABLE-US-00034 [0270] Emulsion B 8.00 g Luviset .RTM. Clear 1.10 g
Chitosan 1.00 g Celquat .RTM. L200 0.90 g Aquaflex .RTM. SF 40 0.40
g Pyrrolidone carboxylic acid 0.85 g Laureth-4 0.20 g Cetrimonium
chloride 0.10 g Perfume 0.10 g Butane 2.20 g Propane 3.00 g
Isobutane 0.80 g Water ad 100.00 g
[0271] The composition is bottled in an aerosol can with foaming
head. Through use of the product on the hair, the hairstyle is
given long-lasting volume.
Example 35
Volumizing Aerosol Foam
TABLE-US-00035 [0272] Emulsion A 1.20 g Luviset .RTM. Clear 2.00 g
Chitosan 0.27 g Celquat .RTM. L200 1.00 g Pyrrolidone carboxylic
acid 0.23 g Direct dye 0.90 g Laureth-4 0.20 g Cetrimonium chloride
0.10 g Perfume, preservative 0.50 g Water ad 100.00 g
[0273] The composition is bottled with propane/butane 4.8 bar in
the ratio of active ingredient solution: propellant gas=94:6 in an
aerosol can with foaming head. Through use of the product on the
hair, the hairstyle is given long-lasting volume.
Example 36
Rinse Out Conditioner
TABLE-US-00036 [0274] Emulsion A 3.00 g cetyltrimethyl ammonium
chloride 1.00 g polymethylphenyl siloxane 1.00 g (CTFA:
OUATERNIUM-80; Abil Quat .RTM. 3272) phenoxy ethanol 0.40 g
PHB-methylester 0.20 g Copolymer of aminoethyl aminopropyl siloxane
1.00 g and dimethyl siloxane emulsion as a mixture with
polyethylenglycol ether of tridecyl alcohol and cetyl trimethyl
ammoniumchloride (CTFA: AMODIMETHICONE & TRIDECETH-12 &
CETRIMONIUM CHLORIDE; Dow Corning 949 Cationic Emulsion .RTM.)
isododecane 5.00 g perfume oil 0.40 g Water ad 100.00 g
Example 37
Leave in Conditioner
TABLE-US-00037 [0275] Emulsion B 1.00 g
2-hydroxy-3-(trimethylamonio)propylether 0.50 g chloride guar gum
sodium benzoate 0.50 g glyoxylic acid 0.10 g creatine 0.20 g
behenyl trimethylammonium chloride 0.80 g cetylstearyl alcohol 0.60
g stearic acid polyethylenglycol (20 EO) 0.10 g hydrolyzed silk
0.10 g perfume oil 0.20 g water ad 100.00 g
Example 38
Leave in Conditioner
TABLE-US-00038 [0276] Emulsion C 1.80 g vitamine E-acetate 0.10 g
polymethylphenyl siloxane 0.50 g (CTFA: OUATERNIUM-80; Abil
Quat.sup.(R) 3272) propylene glycol 10.00 g behenyl
trimethylammonium chloride 0.50 g sodium chloride 0.05 g
d-panthenol 0.30 g PHB-propylester 0.30 g isododecane 2.00 g
perfume oil 0.20 g water ad 100.00 g
Example 39
Split Ends Fluid
TABLE-US-00039 [0277] Emulsion A 3.50 g vitamine E-acetate 0.10 g
polymethylphenyl siloxane 0.50 g (CTFA: OUATERNIUM-80; Abil
Quat.sup.(R) 3272) cyclo penta siloxane (CTFA: CYCLOMETHICONE)
21.00 g dihydroxy polydimethyl siloxane (CTFA: 2.50 g DIMETHICONOL)
ethanol 1.50 g perfume oil 0.60 g water ad 100.00 g
Example 40
Styling Lotion
TABLE-US-00040 [0278] Luviskol VA64 1.00 g Emulsion C 20.00 g
Eumulgin L 0.20 g Perfume 0.15 g PHENOXYETHANOL 0.20 g
PHB-METHYLESTER 0.12 g DISODIUM EDTA 0.10 g Water ad 100.00 g
Example 41
Styling Gel
TABLE-US-00041 [0279] PVP (LUVISKOL K 90 PULVER) 2.00 g NATROSOL
250 HHR 0.50 g Emulsion C 20.00 g Eumulgin L 0.20 g Perfume 0.15 g
UVINUL P 25 0.10 g PHENOXYETHANOL 0.20 g PHB-METHYLESTER 0.12 g
DISODIUM EDTA 0.10 g Water ad 100.00 g
Example 42
Aerosol Styling mousse
TABLE-US-00042 [0280] Polyquaternium-11 (GAFQUAT 755 N) 15.00 g
Emulsion C 5.00 g Laureth-4 0.40 g Perfume 0.15 g PHENOXYETHANOL
0.20 g PHB-METHYLESTER 0.12 g DISODIUM EDTA 0.10 g Propane/Butane
6.00 g Water ad 100.00 g
Example 43
Aerosol Hairspray
TABLE-US-00043 [0281] LUVISKOL VA 37 E 8.00 g Ethanol 50.00 g
Surfactant 193 0.40 g Perfume 0.15 g Eumulsion C 5.00 g
Propane/Butane 30.0 g Water ad 100.00 g
Example 44
Spray Gel
TABLE-US-00044 [0282] Luviskol VA64 3.00 g NATROSOL 250 HHR 0.30 g
Emulsion C 20.00 g Eumulgin L 0.20 g Perfume 0.15 g PHENOXYETHANOL
0.20 g PHB-METHYLESTER 0.12 g DISODIUM EDTA 0.10 g Water ad 100.00
g
Example 45
Leave-on Conditioner
TABLE-US-00045 [0283] JAGUAR C-17 0.30 g NATROSOL 250 HHR 0.30 g
Emulsion C 20.00 g Eumulgin L 0.20 g Perfume 0.15 g PHENOXYETHANOL
0.20 g PHB-METHYLESTER 0.12 g DISODIUM EDTA 0.10 g Water ad 100.00
g
Example 46
Shampoo
TABLE-US-00046 [0284] JAGUAR C-162 0.20 g SODIUM LAURETH SULFATE
(LES 28%) 40.00 g COCAMIDOPROPYL BETAINE 5.00 g (TEGO BETAIN L
5045) DOW CORNING 200 FLUID/350 CS 2.00 g Perfume 0.15 g Emulsion C
6.00 g Water ad 100.00 g
Example 47
Rinse-off Conditioner
TABLE-US-00047 [0285] CETEARYL ALCOHOL 4.50 g CETRIMONIUM CHLORIDE
1.30 g (GENAMIN CTAC 50) Citric acid 0.30 g Perfume 0.15 g Emulsion
C 6.00 g Water ad 100.00 g
[0286] The dimensions and values disclosed herein are not to be
understood as being strictly limited to the exact numerical values
recited. Instead, unless otherwise specified, each such dimension
is intended to mean both the recited value and a functionally
equivalent range surrounding that value. For example, a dimension
disclosed as "40 mm" is intended to mean "about 40 mm".
[0287] Every document cited herein, including any cross referenced
or related patent or application, is hereby incorporated herein by
reference in its entirety unless expressly excluded or otherwise
limited. The citation of any document is not an admission that it
is prior art with respect to any invention disclosed or claimed
herein or that it alone, or in any combination with any other
reference or references, teaches, suggests or discloses any such
invention. Further, to the extent that any meaning or definition of
a term in this document conflicts with any meaning or definition of
the same term in a document incorporated by reference, the meaning
or definition assigned to that term in this document shall
govern.
[0288] While particular embodiments of the present invention have
been illustrated and described, it would be obvious to those
skilled in the art that various other changes and modifications can
be made without departing from the spirit and scope of the
invention. It is therefore intended to cover in the appended claims
all such changes and modifications that are within the scope of
this invention.
* * * * *