U.S. patent application number 12/286467 was filed with the patent office on 2009-02-19 for benefit agent delivery compositions.
Invention is credited to Johan Smets, Pascale Claire Annick Van Steenwinckel.
Application Number | 20090048351 12/286467 |
Document ID | / |
Family ID | 39481855 |
Filed Date | 2009-02-19 |
United States Patent
Application |
20090048351 |
Kind Code |
A1 |
Smets; Johan ; et
al. |
February 19, 2009 |
Benefit agent delivery compositions
Abstract
Benefit agent delivery compositions, compositions, packaged
products and displays comprising such benefit agent delivery
compositions, and processes for making and using such benefit agent
delivery compositions, compositions, packaged products and
displays. Such compositions have improved deposition and retention
properties that may impart improved benefit characteristics to a
composition and/or situs.
Inventors: |
Smets; Johan; (Lubbeek,
BE) ; Van Steenwinckel; Pascale Claire Annick;
(Weerde, BE) |
Correspondence
Address: |
THE PROCTER & GAMBLE COMPANY;Global Legal Department - IP
Sycamore Building - 4th Floor, 299 East Sixth Street
CINCINNATI
OH
45202
US
|
Family ID: |
39481855 |
Appl. No.: |
12/286467 |
Filed: |
September 30, 2008 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
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12070093 |
Feb 15, 2008 |
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12286467 |
|
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60901569 |
Feb 15, 2007 |
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Current U.S.
Class: |
514/772.4 ;
510/475; 512/1; 512/4; 514/772.3 |
Current CPC
Class: |
A61L 9/01 20130101; C11D
3/502 20130101 |
Class at
Publication: |
514/772.4 ;
514/772.3; 510/475; 512/4; 512/1 |
International
Class: |
A01N 25/10 20060101
A01N025/10; C11D 3/37 20060101 C11D003/37; A61K 8/00 20060101
A61K008/00 |
Claims
1. A consumer product composition comprising: a.) from about 0.001%
to about 10% of a consumer benefit agent delivery composition
comprising: (i) from about 5% to about 95% by weight of a benefit
agent; (ii) from about 5% to about 70% by weight of a polymeric
compound; (iii) from about 0% to about 50% by weight of a
cross-linking agent; and b.) a consumer product ingredient.
2. A consumer product composition according to claim 1 comprising:
a.) from about 0.001% to about 10% of a consumer benefit agent
delivery composition comprising: (i) from about 30% to about 85% by
weight of a benefit agent; (ii) from about 20% to about 60% by
weight of a polymeric compound; (iii) from about 0% to about 10% by
weight of a cross-linking agent; and b.) a consumer product
ingredient.
3. A consumer product composition according to claim 2 comprising:
a.) from about 0.001% to about 10% of a consumer benefit agent
delivery composition comprising: (i) from about 40% to about 60% by
weight of a benefit agent; (ii) from about 30% to about 55% by
weight of a polymeric compound; (iii) from about 1% to about 7% by
weight of a cross-linking agent; and b.) a consumer product
ingredient.
4. The composition of claim 1, wherein said benefit agent is
selected from the group consisting of a perfume raw material, a
fragrance, a perfume, an essential oil, an insecticide, an insect
repellant, a pesticide, a herbicide, an odorant, a malodor
counteractant, an odor masking agent, a cooling agent, a vitamin,
softening agent, a skin care agent, a silicone, a softening agent,
an encapsulated perfume and combinations thereof.
5. The composition of claim 2, wherein said benefit agent is
selected from the group consisting of a fragrance, a perfume, an
essential oil, an insecticide, an insect repellant, a pesticide, a
herbicide, an odorant, a malodor counteractant, an odor masking
agent, a cooling agent, a vitamin, softening agent, a skin care
agent, a silicone, a softening agent, an encapsulated perfume and
combinations thereof.
6. The composition of claim 3, wherein said benefit agent is
selected from the group consisting of a fragrance, a perfume, an
essential oil, an insecticide, an insect repellant, a pesticide, a
herbicide, an odorant, a malodor counteractant, an odor masking
agent, a cooling agent, a vitamin, softening agent, a skin care
agent, a silicone, a softening agent, an encapsulated perfume and
combinations thereof.
7. The composition of claim 1, wherein said polymeric compound
comprises polybutadiene, polybutadiene-styrene, polyisoprene,
polybutadiene-acrylonitrile or mixtures thereof.
8. The composition of claim 2, wherein said polymeric compound
comprises polybutadiene, polybutadiene-styrene, polyisoprene,
polybutadiene-acrylonitrile or mixtures thereof.
9. The composition of claim 3, wherein said polymeric compound
comprises polybutadiene, polybutadiene-styrene, polyisoprene,
polybutadiene-acrylonitrile or mixtures thereof.
10. The composition of claim 1, wherein said polymeric compound
comprises, per polymeric compound, at least two moieties selected
from the moieties consisting of a carboxylic acid moiety, an amine
moiety, a hydroxyl moiety, and a nitrile moiety.
11. The composition of claim 2, wherein said polymeric compound
comprises, per polymeric compound, at least two moieties selected
from the moieties consisting of a carboxylic acid moiety, an amine
moiety, a hydroxyl moiety, and a nitrile moiety.
12. The composition of claim 3, wherein said polymeric compound
comprises, per polymeric compound, at least two moieties selected
from the moieties consisting of a carboxylic acid moiety, an amine
moiety, a hydroxyl moiety, and a nitrile moiety.
13. The composition of claim 1, wherein said cross-linking agent
comprises a polyamine.
14. The composition of claim 13 wherein said polyamine comprises
diethylenetriamine, ethylene diamine, polyethyleneimine,
polyvinylamine, bis(3-aminopropyl)piperazine,
N,N-Bis-(3-aminopropyl)methylamine, tris(2-aminoethyl)amine or
mixtures thereof.
15. A method for making a benefit agent delivery composition
comprising: a.) mixing a first mixture, wherein said first mixture
comprises: from about 15% to about 95% by weight of a volatile
hydrophobic liquid; and from about 3% to about 40% by weight of a
polymeric compound containing a carboxylic acid, until said first
mixture is completely mixed; and mixing into said first mixture,
from about 1.5% to about 40% by weight of a cross-linking agent; or
b.) mixing a first mixture, wherein said first mixture comprises:
from about 15% to about 95% by weight of a volatile hydrophobic
liquid; and from about 3% to about 40% by weight of a polymeric
compound containing a carboxylic acid, until said first mixture is
completely mixed; and mixing into said first mixture, from about 0%
to about 40% by weight of a cross-linking agent; or c.) mixing a
first mixture, wherein said first mixture comprises: from about 15%
to about 95% by weight of a volatile hydrophobic liquid; and from
about 3% to about 40% by weight of a polymeric compound containing
a carboxylic acid, until said first mixture is completely mixed;
and mixing into said first mixture a second mixture, wherein said
second mixture comprises: from 15% to about 95% by weight volatile
hydrophobic liquid; and from about 1.5% to about 40% by weight of a
cross-linking agent; or d.) combining from about 15% to about 95%
by weight of a volatile hydrophobic liquid; and from about 3% to
about 40% by weight of a polymeric compound containing a carboxylic
acid, until said first mixture is completely mixed; and mixing into
said first mixture, from about 0% to about 40% by weight of a
cross-linking agent; e.) optionally combining the mixtures produced
in a.), b.), c.) and/or d.) with a diluent and/or a surfactant;
and/or further processing the mixtures produced in a.), b.), c.)
and/or d.) to form a particle, bead and/or agglomerate.
16. The method of claim 15, wherein the hydrophobic liquid is
selected from the group consisting of fragrance, perfume, perfume
microcapsules, essential oil, insecticide, insect repellant,
pesticide, herbicide, odorant, malodor counteractant, odor masking
agent and mixtures thereof.
17. The method of claims 15, wherein the polymeric compound
comprises polybutadiene, polybutadiene-styrene, polyisoprene,
polybutadiene-acrylonitrile or mixtures thereof.
18. The method of claim 17, wherein said polymeric compound
contains at least 2.0 carboxylic acid, amine or hydroxyl groups per
groups per polymeric compound.
19. A consumer product comprising a composition according to any of
claim 1 and packaging, said composition being attached or adhered
to said packaging.
20. A display comprising a composition according to any of claim 1
and a display material, said composition being attached or adhered
to said display material.
21. A cleaning and/or treatment composition or fabric care
composition comprising a composition according to any one of claim
1 and at least one cleaning and/or treatment composition or fabric
care adjunct ingredient.
22. A method of treating and/or cleaning a situs, said method
comprising a.) optionally washing and/or rinsing said situs; b.)
contacting said situs with a composition according to any one of
claim 1 and/or 21; and c.) optionally washing and/or rinsing said
situs.
23. A situs treated with a composition according to any one of
claim 1 and/or 21.
Description
CROSS-REFERENCES TO RELATED APPLICATIONS
[0001] This application is a continuation of application Ser. No.
12/070,093, filed Feb. 15, 2008, which claims priority under 35
U.S.C. .sctn.119(e) to U.S. Provisional Application Ser. No.
60/901,569 filed Feb. 15, 2007.
FIELD OF INVENTION
[0002] The present application relates to benefit agent delivery
compositions, compositions, packaged products and displays
comprising such benefit agent delivery compositions, and processes
for making and using such benefit agent delivery compositions and
compositions, packaged products and displays comprising such
benefit agent delivery compositions.
BACKGROUND OF THE INVENTION
[0003] Benefit agents, such as perfumes, brighteners, insect
repellants, silicones, waxes, flavors, vitamins and fabric
softening agents, skin care agents are expensive and may be less
effective when employed at high levels in personal care
compositions, cleaning compositions, and fabric care compositions.
As a result, there is a desire to maximize the effectiveness of
such benefit agents. One method of achieving such objective is to
improve the delivery efficiencies of such benefit agents.
Unfortunately, it is difficult to improve the delivery efficiencies
of benefit agents as such agents may be lost do to the agents'
physical or chemical characteristics, such agents may be
incompatible with other compositional components or the situs that
is treated, or such agents may be lost during post application
processes such as rinsing or drying.
[0004] Accordingly, there is a need for a benefit agent delivery
composition that provides improved benefit agent delivery
efficiency. While not being bound by theory, applicants believe
that the benefit agent delivery compositions disclosed herein meet
such need as such compositions have increased deposition and
retention properties which result in the desired increase in
benefit agent delivery efficiency.
SUMMARY OF THE INVENTION
[0005] Benefit agent delivery compositions, compositions, packaged
products and displays comprising such benefit agent delivery
compositions, and processes for making and using such benefit agent
delivery compositions, and compositions, packaged products and
displays comprising such benefit agent delivery compositions.
DETAILED DESCRIPTION OF THE INVENTION
Definitions
[0006] As used herein "consumer product" means baby care, beauty
care, fabric & home care, family care, feminine care, health
care, snack and/or beverage products or devices intended to be used
or consumed in the form in which it is sold, and not intended for
subsequent commercial manufacture or modification. Such products
include but are not limited to diapers, bibs, wipes; products for
and/or methods relating to treating hair (human, dog, and/or cat),
including, bleaching, coloring, dyeing, conditioning, shampooing,
styling; deodorants and antiperspirants; personal cleansing;
cosmetics; skin care including application of creams, lotions, and
other topically applied products for consumer use; and shaving
products, products for and/or methods relating to treating fabrics,
hard surfaces and any other surfaces in the area of fabric and home
care, including: air care, car care, dishwashing, fabric
conditioning (including softening), laundry detergency, laundry and
rinse additive and/or care, hard surface cleaning and/or treatment,
and other cleaning for consumer or institutional use; products
and/or methods relating to bath tissue, facial tissue, paper
handkerchiefs, and/or paper towels; tampons, feminine napkins;
products and/or methods relating to oral care including
toothpastes, tooth gels, tooth rinses, denture adhesives, tooth
whitening; over-the-counter health care including cough and cold
remedies, pain relievers, RX pharmaceuticals, pet health and
nutrition, and water purification; processed food products intended
primarily for consumption between customary meals or as a meal
accompaniment (non-limiting examples include potato chips, tortilla
chips, popcorn, pretzels, corn chips, cereal bars, vegetable chips
or crisps, snack mixes, party mixes, multigrain chips, snack
crackers, cheese snacks, pork rinds, corn snacks, pellet snacks,
extruded snacks and bagel chips); and coffee.
[0007] As used herein, the term "cleaning and/or treatment
composition" includes, unless otherwise indicated, granular or
powder-form all-purpose or "heavy-duty" washing agents, especially
cleaning detergents; liquid, gel or paste-form all-purpose washing
agents, especially the so-called heavy-duty liquid types; liquid
fine-fabric detergents; hand dishwashing agents or light duty
dishwashing agents, especially those of the high-foaming type;
machine dishwashing agents, including the various tablet, granular,
liquid and rinse-aid types for household and institutional use;
liquid cleaning and disinfecting agents, including antibacterial
hand-wash types, cleaning bars, mouthwashes, denture cleaners,
dentifrice, car or carpet shampoos, bathroom cleaners; hair
shampoos and hair-rinses; shower gels and foam baths and metal
cleaners; as well as cleaning auxiliaries such as bleach additives
and "stain-stick" or pre-treat types, substrate-laden products such
as dryer added sheets, dry and wetted wipes and pads, nonwoven
substrates, and sponges; as well as sprays and mists.
[0008] As used herein, the term "fabric care composition" includes,
unless otherwise indicated, fabric softening compositions, fabric
enhancing compositions, fabric freshening compositions and
combinations there of.
[0009] As used herein, the term "amine" includes, unless otherwise
indicated, primary, secondary, tertiary, and quaternary amines.
[0010] As used herein, the articles such as "a" and "an" when used
in a claim, are understood to mean one or more of what is claimed
or described.
[0011] As used herein, the terms "include", "includes" and
"including" are meant to be synonymous with the phrase "including
but not limited to".
[0012] As used herein, the term "solid" includes granular, powder,
bar and tablet product forms.
[0013] As used herein, the term "situs" includes paper products,
fabrics, garments, hard surfaces, hair and skin.
[0014] Unless otherwise noted, all component or composition levels
are in reference to the active portion of that component or
composition, and are exclusive of impurities, for example, residual
solvents or by-products, which may be present in commercially
available sources of such components or compositions.
[0015] All percentages and ratios are calculated by weight unless
otherwise indicated. All percentages and ratios are calculated
based on the total composition unless otherwise indicated.
[0016] It should be understood that every maximum numerical
limitation given throughout this specification includes every lower
numerical limitation, as if such lower numerical limitations were
expressly written herein. Every minimum numerical limitation given
throughout this specification will include every higher numerical
limitation, as if such higher numerical limitations were expressly
written herein. Every numerical range given throughout this
specification will include every narrower numerical range that
falls within such broader numerical range, as if such narrower
numerical ranges were all expressly written herein.
Benefit Agent Delivery Compositions
[0017] In one aspect, benefit agent delivery compositions
comprising a benefit agent, a polymeric material and an optional
cross-linker are disclosed.
[0018] Such benefit agent delivery compositions may comprise from
about 5% to about 95%, from about 30% to about 85%, or even from
about 40% to about 60% of a benefit agent; from about 5% to about
70%, from about 20 to about 60%, or even from about 30% to about
55% of a polymeric compound containing a carboxylic acid moiety;
and from about 0% to about 50%, from about 0% to about 10%, or even
from about 1% to about 7% by weight of a cross-linking agent.
[0019] Suitable benefit agents include silicones, enzymes,
fragrances, perfumes, perfume raw materials, fragrance raw
materials, deodorants, odor counteractants, malodors, essential
oils, ethers, esters, ketones, alcohols, glycols, silicone
hydrocarbons, cyclic hydrocarbons, aldehydes, terpines, volatile or
nonvolatile insecticides, volatile or nonvolatile insect
repellants, volatile or nonvolatile pesticides, volatile or
nonvolatile antimicrobial agents, volatile or nonvolatile
fungicides, volatile or nonvolatile herbicides and mixtures
thereof. In one aspect, the inclusion of volatile or nonvolatile
acids is avoided to reduce the potential of the cross reaction of
the acid with the cross-linker.
[0020] In one aspect, the benefit agent comprises a perfume raw
material, a fragrance, a perfume, an essential oil, an insecticide,
an insect repellant, a pesticide, a herbicide, an odorant, a
malodor counteractant, an odor masking agent, a cooling agent, a
vitamin, softening agent, a skin care agent, a silicone, a
softening agent, an encapsulated perfume and combinations
thereof.
[0021] In one aspect, the benefit agent comprises a fragrance
and/or a perfume. Useful perfume materials include materials
selected from the group consisting of Table 1 Perfumes, Table 2
Perfumes, Table 3 Perfumes and mixtures thereof.
TABLE-US-00001 TABLE 1 Perfumes Number Registry Name Trade Name 1
Propanoic acid, ethyl ester Ethyl Propionate 2 Acetic acid,
2-methylpropyl ester Isobutyl Acetate 3 Butanoic acid, ethyl ester
Ethyl Butyrate 4 Butanoic acid, 2-methyl-, ethyl ester
Ethyl-2-Methyl Butyrate 5 2-Hexenal, (E)- 2-Hexenal 6 1-Butanol,
3-methyl-, acetate Iso Amyl-Acetate 7 2-Buten-1-ol, 3-methyl-,
acetate Prenyl Acetate 8 2-Hexen-1-ol Beta Gamma Hexenol 9
3-Hexen-1-ol Beta Gamma Hexenol 10 Benzaldehyde Benzaldehyde 11
3-Hexen-1-ol, acetate, (Z)- Cis 3 Hexenyl Acetate 12 Benzoic acid,
methyl ester Methyl Benzoate 13 Benzeneacetaldehyde Phenyl
Acetaldehyde 14 Benzeneacetic acid, methyl ester Methyl Phenyl
Acetate 15 1,3-Dioxolane-2-acetic acid, 2-methyl-, ethyl Fructone
ester 16 Benzeneacetaldehyde, .alpha.-methyl- Hydratropic Aldehyde
17 3-Cyclohexene-1-carboxaldehyde, 3,5-dimethyl- Cyclal C, 18
Acetic acid, (2-methylbutoxy)-, 2-propenyl ester Allyl Amyl
Glycolate 19 Benzenemethanol, .alpha.-methyl-, acetate Methyl
Phenyl Carbinyl Acetate 20 Acetic acid, (3-methylbutoxy)-,
2-propenyl ester Allyl Amyl Glycolate 21 Benzaldehyde, 4-methoxy-
Anisic Aldehyde 22 Benzeneacetic acid, ethyl ester Ethyl Phenyl
Acetate 23 2-Cyclohexen-1-one, 2-methyl-5-(1- Laevo Carvone
methylethenyl)-, (R)- 24 Ethanol, 2,2'-oxybis- Calone 161 25 Acetic
acid, 2-phenylethyl ester Phenyl Ethyl Acetate 26 Benzoic acid,
2-amino-, methyl ester Methyl Anthranilate 27
4,7-Methano-1H-inden-6-ol, 3a,4,5,6,7,7a- Flor Acetate hexahydro-,
acetate 28 Octanal, 7-hydroxy-3,7-dimethyl- Hydroxycitronellal 29
2(3H)-Furanone, 5-ethyldihydro- Gamma Hexalactone 30 Phenol,
4-methyl- Para Cresol 31 Bicyclo[2.2.1]heptan-2-one,
1,7,7-trimethyl-, Camphor Gum (1R)- 32 2H-Pyran,
3,6-dihydro-4-methyl-2-(2-methyl-1- Nerol Oxide propenyl)- 33
Benzeneethanol, .beta.-methyl- Hydratropic Alcohol 34
Benzeneethanol, .alpha.,.alpha.-dimethyl- Dimethyl Benzyl Carbinol
35 Benzoic acid, 2-(methylamino)-, methyl ester Dimethyl
Anthranilate 36 2-Propenal, 3-phenyl- Cinnamic Aldehyde 37
2-Propenoic acid, 3-phenyl-, methyl ester Methyl Cinnamate 38
4H-Pyran-4-one, 2-ethyl-3-hydroxy- Ethyl Maltol 39 Acetic acid
ethyl ester Ethyl Acetate 40 2-Heptanone Methyl Amyl Ketone 41
Acetic acid, pentyl ester Iso Amyl-Acetate 42 3-Octanone Ethyl Amyl
Ketone 43 2-Octanone Methyl Hexyl Ketone 44 Heptenone, methyl-
Methyl Heptenone 45 1-Heptanol Heptyl Alcohol 46 5-Hepten-2-one,
6-methyl- Methyl Heptenone 47 Butanoic acid, 3-oxo-, ethyl ester
Ethyl Acetoacetate 48 Ethanol, 2-(2-methoxyethoxy)- Veramoss Sps 49
Tricyclo[2.2.1.02,6]heptane, 1-ethyl-3-methoxy- Neoproxen 50
Benzene, 1,4-dimethoxy- Hydroquinone Dimethyl Ether 51 Carbonic
acid, 3-hexenyl methyl ester, (Z)- Liffarome 52 Oxirane,
2,2-dimethyl-3-(3-methyl-2,4- Myroxide pentadienyl)- 53 Ethanol,
2-(2-ethoxyethoxy)- Diethylene Glycol Mono Ethylether 54
Cyclohexaneethanol Cyclohexyl Ethyl Alcohol 55 3-Octen-1-ol, (Z)-
Octenol Dix 56 3-Cyclohexene-1-carboxaldehyde, 3,6-dimethyl-
Cyclovertal 57 1,3-Oxathiane, 2-methyl-4-propyl-, cis- Oxane 58
Acetic acid, 4-methylphenyl ester Para Cresyl Acetate 59 Benzene,
(2,2-dimethoxyethyl)- Phenyl Acetaldehyde Dimethyl Acetal 60
Ethanone, 1-(4-methylphenyl)- Para Methyl Acetophenone 61 Propanoic
acid, phenylmethyl ester Benzyl Propionate 62 Octanal,
7-methoxy-3,7-dimethyl- Methoxycitronellal Pq 63 Linalool oxide
Linalool Oxide 64 2H-1-Benzopyran-2-one, octahydro- Octahydro
Coumarin 65 Benzenepropanal, .beta.-methyl- Trifernal 66
4,7-Methano-1H-indenecarboxaldehyde, Formyltricyclodecan octahydro-
67 2-Butanone, 4-phenyl- Benzyl Acetone 68 Ethanone,
1-(4-methoxyphenyl)- Para Methoxy Acetophenone 69 Benzoic acid,
2-hydroxy-, methyl ester Methyl Salicylate USP 70 Propanenitrile,
3-(3-hexenyloxy)-, (Z)- Parmanyl 71
1,4-Methanonaphthalen-5(1H)-one, Tamisone 4,4a,6,7,8,8a-hexahydro-
72 Benzene, [2-(2-propenyloxy)ethyl]- LRA 220 73 Benzenepropanol
Phenyl Propyl Alcohol 74 Ethanol, 2-phenoxy- Phenoxyethanol 75
1H-Indole Indole 76 1,3-Dioxolane, 2-(phenylmethyl)- Ethylene
Glycol Acetal/Phenyl Acetaldehy 77 2H-1-Benzopyran-2-one,
3,4-dihydro- Dihydrocoumarin
[0022] In one aspect, suitable Table 1 perfume raw materials
include perfume raw materials from number 1 to number 39 and
mixtures thereof.
[0023] In one aspect, suitable Table 1 perfume raw materials
include perfume raw materials from number 1 to number 29 and
mixtures thereof.
[0024] In one aspect, suitable perfume raw materials having boiling
point less than or equal to 250.degree. C. and a ClogP greater than
2.5 are those materials listed in Table 2 below and such materials
are defined as Table 2 perfume raw materials.
TABLE-US-00002 TABLE 2 Perfumes Number Registry Name Trade Name 1
Bicyclo[2.2.1]heptane, 2,2-dimethyl-3- Camphene methylene- 2
Bicyclo[3.1.1]heptane, 6,6-dimethyl-2- Beta Pinene methylene-,
(1S)- 3 Bicyclo[3.1.1]hept-2-ene, 2,6,6- Alpha Pinene trimethyl- 4
Propanoic acid, pentyl ester Amyl Propionate 5 1,6-Octadiene,
7-methyl-3-methylene- Myrcene 6 Cyclohexene, 1-methyl-4-(1-
Dipentene methylethenyl)- 7 Cyclohexene, 1-methyl-4-(1-
Terpineolene methylethenyl)- 8 Acetic acid, hexyl ester Hexyl
Acetate 9 Cyclohexene, 1-methyl-4-(1- Terpineolene
methylethylidene)- 10 Benzene, 1-methoxy-4-methyl- Para Cresyl
Methyl Ether 11 1-Octen-3-ol, acetate Amyl Vinyl Carbinyl Acetate
12 Octanal Octyl Aldehyde 13 2-Oxabicyclo[2.2.2]octane, 1,3,3-
Eucalyptol trimethyl- 14 Butanoic acid, pentyl ester Amyl Butyrate
15 Heptanoic acid, ethyl ester Ethyl Oenanthate 16 5-Heptenal,
2,6-dimethyl- Melonal 17 Hexanoic acid, 2-propenyl ester Allyl
Caproate 18 3-Cyclohexene-1-carboxaldehyde, Ligustral dimethyl- 19
3-Hexene, 1-(1-ethoxyethoxy)-, (Z)- Leaf Acetal 20 Octanal,
3,7-dimethyl- Dihydrocitronellal 21 2-Octynoic acid, methyl ester
Methyl Heptine Carbonate 22 2-Nonenal 2 Nonen-1-al 23
1,6-Octadien-3-ol, 3,7-dimethyl- Linalool 24 Benzoic acid, ethyl
ester Ethyl Benzoate 25 6-Octenal, 3,7-dimethyl- Citronellal 26
Cyclohexanol, 1-methyl-4-(1- Dihydroterpineol methylethyl)- 27
1-Hexanol, 3,5,5-trimethyl-, acetate Iso Nonyl Acetate 28
3,5-Octadien-2-ol, 2,6-dimethyl-, (?,Z)- Muguol 29 Cyclohexanone,
5-methyl-2-(1- Iso Menthone methylethyl)-, cis- 30 Heptanoic acid,
2-propenyl ester Allyl Heptoate 31 Butanoic acid, 3-hexenyl ester,
(Z)- Cis 3 Hexenyl Butyrate 32 1,6-Octadien-3-ol, 3,7-dimethyl-,
Linalyl Formate formate 33 3-Cyclohexen-1-ol, 4-methyl-1-(1-
Terpinenol methylethyl)- 34 Bicyclo[2.2.1]heptan-2-ol, 1,3,3-
Fenchyl Alcohol trimethyl- 35 Cyclohexanol, 2-(1,1-dimethylethyl)-,
Verdol cis- 36 3-Octanol, 3,7-dimethyl-, acetate Tetrahydro Linayl
Acetate 37 Bicyclo[2.2.1]heptan-2-ol, 1,7,7- Borneol Crystals
trimethyl-, (1S-endo)- 38 Decanal Decyl Aldehyde 39
3-Cyclohexene-1-methanol, Alpha Terpineol
.alpha.,.alpha.,4-trimethyl- 40 Cyclohexanol, 5-methyl-2-(1-
Menthol methylethyl)- 41 3-Cyclohexene-1-carboxaldehyde, Iso Cyclo
Citral 2,4,6-trimethyl- 42 7-Octen-2-ol, 2,6-dimethyl-, acetate
Dihydro Terpinyl Acetate 43 2H-Pyran-2-one, 6-butyltetrahydro-
Nonalactone 44 3-Hepten-2-one, 3,4,5,6,6-pentamethyl- Koavone 45
1,6-Nonadien-3-ol, 3,7-dimethyl- Ethyl Linalool 46 4-Decenal, (E)-
Decenal (Trans-4) 47 Terpineol Terpineol 48 7-Octen-2-ol,
2-methyl-6-methylene-, Myrcenyl Acetate acetate 49 2-Butenoic acid,
2-methyl-, 3-hexenyl Cis-3-Hexenyl Tiglate ester, (E,Z)- 50
1,6-Octadien-3-ol, 3,7-dimethyl-, Linalyl Acetate acetate 51
Benzene, 1-methoxy-4-(1-propenyl)-, Anethol Usp (E)- 52 2-Decenal 2
Decene-1-al 53 2,6-Octadienal, 3,7-dimethyl- Citral 54
6-Octen-1-ol, 3,7-dimethyl-, formate Citronellyl Formate 55
Cyclopentanone, 3-methyl-2-pentyl- Jasmylone 56 Undecenal Iso C-11
Aldehyde 57 6-Octen-1-ol, 3,7-dimethyl- Citronellol 58
Cyclohexanemethanol, .alpha.,.alpha.,4- Dihydro Terpinyl Acetate
trimethyl-, acetate 59 3-Cyclohexene-1-methanol, Terpinyl Acetate
.alpha.,.alpha.,4-trimethyl-, acetate 60 2,6-Octadien-1-ol,
3,7-dimethyl-, Geranyl Formate formate, (E)- 61
Bicyclo[2.2.1]heptan-2-ol, 1,3,3- Fenchyl Acetate trimethyl-,
acetate 62 Bicyclo[2.2.1]heptan-2-ol, 1,7,7- Iso Bornyl Acetate
trimethyl-, acetate, exo- 63 2,6-Octadien-1-ol, 3,7-dimethyl-, (E)-
Geraniol 64 2,6-Octadien-1-ol, 3,7-dimethyl-, (Z)- Nerol 65
Cyclohexanol, 2-(1,1-dimethylethyl)-, Verdox acetate 66 Undecanal,
2-methyl- Methyl Nonyl Acetaldehyde 67 Undecanal Undecyl Aldehyde
68 2H-Pyran-2-one, tetrahydro-6-pentyl- Delta Decalactone 69
6-Octen-1-ol, 3,7-dimethyl-, acetate Citronellyl Acetate 70
10-Undecenal Intreleven Aldehyde Sp 71 2(3H)-Furanone,
5-hexyldihydro- Gamma Decalactone 72 2,6-Octadien-1-ol,
3,7-dimethyl-, Geranyl Acetate acetate, (E)- 73 2H-Pyran-2-one,
tetrahydro-6-(3- Jasmolactone pentenyl)- 74 Cyclohexanol,
5-methyl-2-(1- Menthyl Acetate methylethyl)-, acetate,
(1.alpha.,2.beta.,5.alpha.)- 75 2-Undecenal 2-Undecene-1-Al 76
2H-Pyran-2-one, tetrahydro-6-(2- Jasmolactone pentenyl)-, (Z)- 77
2,6-Octadien-1-ol, 3,7-dimethyl-, Neryl Acetate acetate, (Z)- 78
Benzeneethanol, .alpha.,.alpha.- Dimethyl Benzyl Carbinyl Acetate
dimethyl-, acetate 79 4,9-Decadienal, 4,8-dimethyl- Floral Super 80
3-Octanol Octanol-3 81 2-Heptanol, 2,6-dimethyl-
Dimethyl-2,6-Heptan-2-ol 82 Propanoic acid, 2-methyl-, 1,3- Iso
Pentyrate dimethyl-3-butenyl ester 83 3-Nonanone Ethyl Hexyl Ketone
84 2,4,6-Octatriene, 2,6-dimethyl- Allo-Ocimene 85
Bicyclo[2.2.1]heptane, 2-ethyl-5- Neoproxen methoxy- 86 1-Octanol
Octyl Alcohol 87 3-Octanol, 3,7-dimethyl- Linacsol 88 Propanoic
acid, 2-methyl-, 3-hexenyl Verdural B Extra ester, (Z)- 89
2H-Pyran, tetrahydro-4-methyl-2-(2- Methyl Iso Butenyl Tetrahydro
Pyran methyl-1-propenyl)- 90 Nonanal Nonyl Aldehyde 91 Hexanoic
acid, 2-methylpropyl ester Iso Butyl Caproate 92 Cyclohexane,
3-ethoxy-1,1,5-trimethyl- Herbavert 93 7-Octen-2-ol,
2-methyl-6-methylene-, Dihydro Myrcenol dihydro deriv. 94 Ethanone,
1-(3,3-dimethylcyclohexyl)- Herbac 95 Propanoic acid,
2,2-dimethyl-, hexyl Hexyl Neo Pentanoate ester 96 3-Heptanone,
5-methyl-, oxime Stemone 97 Isononanol Iso Nonyl Alcohol 98
Cyclohexanone, 2-(1-methylpropyl)- 2-Sec-Butyl Cyclo Hexanone 99
Butanoic acid, 2-methyl-, hexyl ester Hexyl-2-Methyl Butyrate 100
1-Nonanol Nonyl Alcohol 101 Cyclohexaneethanol, acetate Cyclohexyl
Ethyl Acetate 102 1-Octanol, 3,7-dimethyl- Dimethyl Octanol 103
Cyclopentanone, 2-pentyl- Delphone 104 Cyclohexanemethanol, 4-(1-
Mayol methylethyl)-, cis- 105 6-Octen-1-ol, 3,7-dimethyl-, (S)-
Baranol 106 Benzaldehyde, 4-(1-methylethyl)- Cuminic Aldehyde 107
Propanoic acid, 2-methyl-, Benzyl Iso Butyrate phenylmethyl ester
108 Propanoic acid, 2-methyl-, 4- Para Cresyl Iso Butyrate
methylphenyl ester 109 Carbonic acid, 4-cycloocten-1-yl Violiff
methyl ester 110 1,6-Octadien-3-ol, 3,7-dimethyl-, Linalyl
Propionate propanoate 111 Cyclohexanemethanol, .alpha.-methyl-
Mugetanol 4-(1-methylethyl)- 112 Butanoic acid, phenylmethyl ester
Benzyl Butyrate 113 4,7-Methano-1H-inden-5-ol, octahydro-, Dihydro
Cyclacet acetate 114 2-Cyclopenten-1-one, 3-methyl-2-
Dihydrojasmone pentyl- 115 Bicyclo[2.2.1]heptan-2-ol, 1,7,7- Iso
Bornyl Propionate trimethyl-, propanoate, exo- 116
2,6-Octadienenitrile, 3,7-dimethyl- Geranyl Nitrile 117 Benzene,
ethenyl- Styrene 118 Benzene, methyl(1-methylethyl)- Cymene Coeur
119 Cyclohexanol, 3,3,5-trimethyl-, cis- Trimethylcyclohexanol 120
1-Hexanol, 5-methyl-2-(1-methylethyl)-, Tetrahydro Lavandulol (R)-
121 Cyclohexanol, 4-(1-methylethyl)- Roselea 122 7-Octen-2-ol,
2,6-dimethyl-, formate Dimyrcetol 123 Cyclohexanone, 5-methyl-2-(1-
Menthone Racemic methylethyl)-, trans- 124 1,3,5-Undecatriene
Galbanolene Super 125 5,7-Octadien-2-ol, 2,6-dimethyl- Ocimenol 126
2-Cyclohexene-1-carboxylic acid, Methyl Cyclogeranate
2,6,6-trimethyl-, methyl ester 127 Benzene, (2-bromoethenyl)- Brom
Styrol 128 Benzene, 1-methoxy-4-(2-propenyl)- Methyl Chavicol 129
2H-Pyran, 6-butyl-3,6-dihydro-2,4- Gyrane dimethyl- 130
Cyclohexanemethanol, .alpha.,3,3- Aphermate trimethyl-, formate 131
Cyclohexanol, 4-(1,1-dimethylethyl)- Patchon 132 Cyclohexanol,
5-methyl-2-(1- Menthol Natural methylethyl)-, [1R-
(1.alpha.,2.beta.,5.alpha.)]- 133 1,3-Dioxane,
2-butyl-4,4,6-trimethyl- Herboxane 134 2-Nonynoic acid, methyl
ester Methyl Octine Carbonate 135 6-Octenenitrile, 3,7-dimethyl-
Baranyl Nitrile 136 Decanal, 2-methyl- Methyl Octyl Acetaldehyde
137 2-Nonanol, 6,8-dimethyl- Nonadyl 138 Phenol,
4-(1,1-dimethylethyl)- Para Tertiary Butyl Phenol 139 1-Hexanol,
5-methyl-2-(1-methylethyl)-, Tetrahydro Lavandulyl Acetate acetate
140 Cyclohexanol, 5-methyl-2-(1- Iso Pulegol methylethenyl)-, [1R-
(1.alpha.,2.beta.,5.alpha.)]- 141 Cyclohexanone, 4-(1,1- Orivone
dimethylpropyl)- 142 2-Undecanone Methyl Nonyl Ketone 143
Cyclohexanemethanol, .alpha.,3,3- Rosamusk trimethyl-, acetate 144
3-Cyclohexene-1-methanol, 2,4,6- Isocyclogeraniol trimethyl- 145
2,6-Octadiene, 1,1-dimethoxy-3,7- Citral Dimethyl Acetal dimethyl-
146 1-Decanol Rhodalione 147 2-Cyclohexen-1-one, 3-methyl-5-
Livescone propyl- 148 Phenol, 2-methyl-5-(1-methylethyl)- Carvacrol
149 2-Naphthalenol, decahydro- Trans Deca Hydro Beta Naphthol 150
Cyclohexanol, 4-(1,1-dimethylethyl)-, Tertiary Butyl Cyclohexyl
Acetate acetate 151 9-Decen-1-ol Rosalva 152 Phenol,
5-methyl-2-(1-methylethyl)- Thymol Nf 153 Cyclohexanol,
5-methyl-2-(1- Iso Pulegol Acetate methylethenyl)-, acetate, [1R-
(1.alpha.,2.beta.,5.alpha.)]- 154 Benzene,
[(3-methylbutoxy)methyl]- Iso Amyl Benzyl Ether 155 2(3H)-Furanone,
5-hexyldihydro-5- Lactojasmon methyl- 156 Benzoic acid, butyl ester
Butyl Benzoate 157 Bicyclo[3.2.1]octan-8-one, 1,5- Buccoxime
dimethyl-, oxime 158 2-Cyclopenten-1-one, 2-methyl-3-(2- Iso
Jasmone pentenyl)-
[0025] In one aspect, suitable Table 2 perfume raw materials
include perfume raw materials from number 1 to number 116 and
mixtures thereof.
[0026] In one aspect, suitable Table 2 perfume raw materials
include perfume raw materials from number 1 to number 79 and
mixtures thereof.
[0027] In one aspect, suitable perfume raw materials having boiling
point greater than 250.degree. C. but less than or equal to
280.degree. C. are those materials listed in Table 3 below and such
materials are defined as Table 3 perfume raw materials.
TABLE-US-00003 TABLE 3 Perfumes Number Registry Name Trade Name 1
Dodecanenitrile Clonal 2 Cyclohexanepropanoic acid, 2-propenyl
ester Allyl Cyclohexane Propionate 3 2-Buten-1-one,
1-(2,6,6-trimethyl-2- Alpha Damascone cyclohexen-1-yl)- 4
1,4-Cyclohexanedicarboxylic acid, diethyl Fructalate ester 5
2(3H)-Furanone, 5-heptyldihydro- Undecalactone 6 Naphthalene,
2-methoxy- Beta Naphthol Methyl Ether 7 Benzenepropanal,
4-(1,1-dimethylethyl)- Bourgeonal 8 3-Cyclopentene-1-butanol,
.beta.,2,2,3- Brahmanol tetramethyl- 9 1H-3a,7-Methanoazulen-6-ol,
octahydro- Cedrol 3,6,8,8-tetramethyl-,[3R-
(3.alpha.,3a.beta.,6.alpha.,7.beta.,8a.alpha.)]- 10 2-Propen-1-ol,
3-phenyl-, acetate Cinnamyl Acetate 11 Benzenepropanal,
.alpha.-methyl-4-(1- Cymal methylethyl)- 12 2-Buten-1-one,
1-(2,6,6-trimethyl-1- Damascone Beta cyclohexen-1-yl)-, (Z)- 13
2-Buten-1-one, 1-(2,6,6-trimethyl-1,3- Damascenone
cyclohexadien-1-yl)- 14 2-Buten-1-one, 1-(2,6,6-trimethyl-3- Delta
Damascone cyclohexen-1-yl)- 15 Butanoic acid,
1,1-dimethyl-2-phenylethyl Dimethyl Benzyl Carbinyl ester Butyrate
16 2-Dodecenal 2 Dodecene-1-al 17 2H-Pyran-2-one,
6-heptyltetrahydro- Dodecalactone 18 Oxiranecarboxylic acid,
3-methyl-3-phenyl-, Ethyl Methyl Phenyl Glycidate ethyl ester 19
Oxiranecarboxylic acid, 3-phenyl-, ethyl ester Ethyl Phenyl
Glycidate 20 Phenol, 2-methoxy-4-(2-propenyl)- Eugenol 21
Benzenepropanal, .beta.-methyl-3-(1- Florhydral methylethyl)- 22
Benzenepropanal, 2-ethyl-.alpha.,.alpha.- Floralozone dimethyl- 23
4,7-Methano-1H-inden-6-ol, 3a,4,5,6,7,7a- Frutene hexahydro-,
propanoate 24 2,6-Octadienenitrile, 3,7-dimethyl-, (E)- Geranyl
Nitrile 25 1,3-Benzodioxole-5-carboxaldehyde Heliotropin 26 Ionone
Ionone Ab 27 3-Buten-2-one, 4-(2,6,6-trimethyl-2- Ionone Alpha
cyclohexen-1-yl)-, (E)- 28 3-Buten-2-one, 4-(2,6,6-trimethyl-1-
Ionone Beta cyclohexen-1-yl)- 29 3-Buten-2-one,
4-(2,6,6-trimethyl-1- Ionone Beta cyclohexen-1-yl)-, (E)- 30
3-Buten-2-one, 3-methyl-4-(2,6,6-trimethyl- Ionone Gamma Methyl
2-cyclohexen-1-yl)- 31 2-Buten-1-one, 1-(2,4,4-trimethyl-2-
Isodamascone N cyclohexen-1-yl)-, (E)- 32 Phenol,
2-methoxy-4-(1-propenyl)- Iso Eugenol 33 2H-Pyran-4-ol,
tetrahydro-3-pentyl-, acetate Jasmal 34
Bicyclo[3.1.1]hept-2-ene-2-ethanol, 6,6- Nopyl Acetate dimethyl-,
acetate 35 Benzenepropanol, .alpha.,.alpha.-dimethyl-, Phenyl Ethyl
Dimethyl Carbinyl acetate Acetate 36 Propanoic acid, 2-methyl-,
3a,4,5,6,7,7a- Cyclabute hexahydro-4,7-methano-1H- 37 Benzaldehyde,
4-hydroxy-3-methoxy- Vanillin 38 3-Cyclohexene-1-carboxaldehyde,
1-methyl- Vernaldehyde 4-(4-methylpentyl)- 39 Benzenemethanol,
ar-methoxy-, acetate Anisyl Acetate 40
Bicyclo[2.2.1]hept-5-ene-2-carboxylic acid, Herbanate Ci
3-(1-methylethyl)-,ethyl ester, (2-endo,3- exo)- 41 Butanoic acid,
3-methyl-, 2-phenylethyl ester Beta Phenyl Ethyl Isovalerate 42
Benzenepropanal, 4-methoxy-.alpha.-methyl- Canthoxal 43
Bicyclo[7.2.0]undec-4-ene, 4,11,11- Caryophyllene Extra
trimethyl-8-methylene-,[1R-(1R*,4E,9S*)]- 44 Cyclohexenebutanal,
.alpha.,2,2,6- Cetonal tetramethyl- 45 2-Propen-1-ol, 3-phenyl-
Cinnamic Alcohol 46 6-Octen-1-ol, 3,7-dimethyl-, propanoate
Citronellyl Propionate 47 Propanoic acid, decyl ester N-Decyl
Propionate 48 Phenol, 2-methoxy-4-propyl- Dihydro Eugenol 49
Cyclohexanol, 1-ethenyl-2-(1-methylpropyl)-, Dihydro Ambrate
acetate 50 2-Propenoic acid, 3-phenyl-, ethyl ester Ethyl Cinnamate
51 Butanoic acid, 3,7-dimethyl-2,6-octadienyl Geranyl Butyrate
ester, (E)- 52 2-Octanol, 8,8-dimethoxy-2,6-dimethyl-
Hydroxycitronellal Dimethyl Acetal 53 Cyclohexadieneethanol,
4-(1-methylethyl)-, Iso Bergamate formate 54 Dodecanal Lauric
Aldehyde 55 Propanoic acid, 2-methyl-, 1-ethenyl-1,5- Linalyl Iso
Butyrate dimethyl-4-hexenyl ester 56 Benzenepropanol,
.beta.,.beta.,3-trimethyl- Majantol 57 Benzene,
1,2-dimethoxy-4-(2-propenyl)- Methyl Eugenol 58 Propanoic acid,
2-methyl-, 2-phenylethyl Phenyl Ethyl Iso Butyrate ester 59
2-Propenenitrile, 3-phenyl- Cinnamalva 60 Benzene,
[2-(1-propoxyethoxy)ethyl]- Acetal R 61 9-Undecenal,
2,6,10-trimethyl- Adoxal 62 2-Naphthalenol,
1,2,3,4,4a,5,6,7-octahydro- Ambrinol 20t 2,5,5-trimethyl- 63
2-Naphthalenol, octahydro-2,5,5-trimethyl- Ambrinol 20t 64 Ethanol,
2-[(1,7,7- Arbanol trimethylbicyclo[2.2.1]hept-2-yl)oxy]-, exo- 65
1H-2-Benzopyran, 3,4,4a,5,8,8a(or Bigarade Oxide
3,4,4a,7,8,8a)-hexahydro-3,3,6,7- 66 Cyclohexene,
4-(1,5-dimethyl-4- Bisabolene hexenylidene)-1-methyl- 67
1H-3a,7-Methanoazulene, octahydro-6- Cedramber
methoxy-3,6,8,8-tetramethyl-,[3R-
(3.alpha.,3a.beta.,6.alpha.,7.beta.,8a.alpha.)]- 68 Phenol,
4-chloro-3,5-dimethyl- 4-Chloro 3,5 Xylenol 69 2,6-Octadiene,
1,1-diethoxy-3,7-dimethyl- Citrathal 70 Acetaldehyde,
[(3,7-dimethyl-6-octenyl)oxy]- Citronellyl Oxyacetaldehyde 71
Benzenepropanenitrile, .alpha.-ethenyl- Citrowanil B
.alpha.-methyl- 72 Cyclohexanol, 2-(1,1-dimethylpropyl)-, Coniferan
acetate 73 2H-1-Benzopyran-2-one Coumarin 74 1,3-Nonanediol,
monoacetate Diasmol 75 Benzene, 1,1'-methylenebis- Diphenyl Methane
76 Benzene, 1,1'-oxybis- Diphenyl Oxide 77 1,6-Octadiene,
3-(1-ethoxyethoxy)-3,7- Elinthal dimethyl- 78 Cyclopentanone,
2-heptyl- Fleuramone 79 5,8-Methano-2H-1-benzopyran-2-one, 6-
Florex ethylideneoctahydro- 80 Octanoic acid, 2-acetyl-, ethyl
ester Gelsone 81 Indeno[1,2-d]-1,3-dioxin, 4,4a,5,9b- Indoflor
Crist. tetrahydro- 82 Benzeneacetic acid, 2-methylpropyl ester Iso
Butyl Phenylacetate 83 2,6-Nonadienenitrile, 3,7-dimethyl- Lemonile
84 3-Decanone, 1-hydroxy- Methyl Lavender Ketone 85 Undecane,
1,1-dimethoxy-2-methyl- Methyl Nonyl Acetaldehyde Dimethyl Aceta 86
1-Propanone, 1-[2-methyl-5-(1-methylethyl)- Nerone
2-cyclohexen-1-yl]- 87 5,9-Undecadienal, 2,6,10-trimethyl- Oncidal
88 Quinoline, 6-methyl- Para Methyl Quinoline 89 Propanoic acid,
2-methyl-, 2-phenoxyethyl Phenoxy Ethyl Iso Butyrate ester 90
Ethanol, 2-phenoxy-, propanoate Phenoxy Ethyl Propionate Formerly
N-225 91 4,7-Methano-1H-indene-2-carboxaldehyde, Scentenal
octahydro-5-methoxy- 92 9-Undecen-2-one, 6,10-dimethyl- Tetra Hydro
Psuedo Ionone 93 Benzenemethanol, .alpha.-(trichloromethyl)-,
Trichloromethyl Phenyl acetate Carbinyl Acetate 94 Phenol,
2-methoxy-4-(methoxymethyl)- Vaniwhite 95
Bicyclo[2.2.2]oct-5-ene-2-carboxaldehyde, 6- Maceal
methyl-8-(1-methylethyl)- 96 Benzene, [2-(3-methylbutoxy)ethyl]-
Phenyl Ether Isamyl Ether (Aka Anther) 97
2-Cyclohexene-1-carboxylic acid, 2,3,6,6- Givescone tetramethyl-,
ethyl ester
[0028] In one aspect, suitable Table 3 perfume raw materials
include perfume raw materials from number 1 to number 58 and
mixtures thereof.
[0029] In one aspect, suitable Table 3 perfume raw materials
include perfume raw materials from number 1 to number 39 and
mixtures thereof.
[0030] In one aspect, suitable perfume raw materials may be
selected from the group consisting of 4-methoxybenzaldehyde;
4-phenylbutan-2-one; 3,7-dimethyl-2-methylene-6-octenal;
4-(2,6,6-trimethyl cyclohex-1-ene-1-yl) but-3-ene-2-one;
2,4-dimethylcyclohex-3-ene-1-carbaldehyde; 2-methyl-3-(para
isopropylphenyl)propionaldehyde; 2-Buten-1-one,
1-(2,6,6-trimethyl-1,3-cyclohexadien-1-yl)-;
1-cyclohexyl-ethylene-crotonate;
1-(2,6,6-trimethyl-3-cyclohexen-1-yl)-2-buten-1-one; 3-methyl
cyclopentadecenone; 4-(2,6,6-trimethyl-1-cyclohexenyl)butan-2-one;
2,5-Dimethyl-2-octen-6-one; dihydro-nor-cyclopentadienyl acetate;
3-(o-(and p-)ethylphenyl)-2,2-dimethylpropionaldehyde;
3-(3-isopropylphenyl) butanal; 3-Buten-2-one,
3-methyl-4-(2,6,6-trimethyl-2-cyclohexen-1-yl)-;
alpha-methyl-3,4(methylenedioxy)hydrocinnamaldehyde; n-hexyl ortho
hydroxy benzoate;
7-acetyl-1,2,3,4,5,6,7,8-octahydro-1,1,6,7,tetramethyl naphthalene;
4-(1-Ethoxyvinyl)-3,3,5,5-tetramethyl-cyclohexan-1-one;
2-Cyclohexen-1-one, 2-methyl-5-(1-methylethenyl)-, (R)--;
2,4-Dimethyl-3-cyclohexene-1-carboxaldehyde;
3,7-dimethyl-1,6-octadien-3-ol; 2,6-Dimethyl-5-Heptenal; Methyl
Dihydro Jasmonate; Methyl Nonyl Acetaldehyde;
6,6-dimethoxy-2,5,5-trimethylhex-2-ene; 2-Cyclohexen-1-one,
2-methyl-5-(1-methylethenyl)-, (R)--; Octaldehyde;
2-Cyclohexyl-1,6-heptadien-3-one and mixtures thereof.
[0031] Suitable polymeric materials may comprise at least two
moieties each of which may be independently selected from the group
consisting of carboxylic acid, hydroxyl, ester, amide, amine,
nitrile and thiol moieties.
[0032] In one aspect, said polymeric compound comprises, per
polymeric compound, at least two moieties selected from the
moieties consisting of a carboxylic acid moiety, an amine moiety, a
hydroxyl moiety, and a nitrile moiety. In one aspect, the polymeric
material contains two or more carboxylic acid moieties on each
polymeric molecule. In one aspect, polymeric materials may contain
a backbone of polybutadiene, polyisoprene, polybutadiene/styrene,
polybutadiene/acrylonitrile, carboxyl-terminated
polybutadiene/acrylonitrile or combinations thereof. In another
aspect, suitable polymeric materials encompass amine terminated,
epoxy terminated, or vinyl terminated polymers. Suitable molecular
weights for these polymers range from about 1,000 to about
10,000,000. In one aspect, the suitable polymers may have molecular
weights that range from about 1,000 to about 10,000,000 or from
about 2,000 to about 50,000. Suitable polymeric materials are
available from NOVEON (Cleveland, Ohio U.S.A) and SARTOMER
(Philadelphia, Pa. U.S.A.). Such materials include HYCAR.RTM.
materials CTB 2000x162, CTBNX 1300x18, CTBNX 1300x9, CTBN 1300x8,
CTBN 1300x31, ATB 2000x173, ATBN 1300x21, ATBN 1300x16, ATBN
1300x45, ATBN 1300x35, ATBN 1300x42, VTB 2000x168, VTBNX1300x33,
VTBNX1300x43, ETBN 1300x40, and ETBN 1300x44 from NOVEON or Emerald
Performance Materials of Cuyahoga Falls, Ohio U.S.A. and
Krasol.RTM. LBH 5000 from SARTOMER.
[0033] In one aspect, the benefit delivery composition may comprise
a cross-linker. In any aspect, such cross-linker may provide
covalent cross-linking and/or ionic cross-linking. In one aspect,
the benefit agent delivery composition comprises a cross-linker at
a concentration similar to the equivalence of the polymeric
material. In one aspect, the equivalence ratio of cross-linker
equivalence to the carboxylic acid equivalence within the
composition is from about 0.5 to about 2.0. In one aspect, the
equivalence ratio is from about 0.8 to about 1.2. The cross-linker
can be any material that provides cross-linking when placed in the
presence of the carboxylic acid containing polymer. Suitable
cross-linkers include polyamines, expoxides and polycarbodiimides.
In one aspect, the polycarbodiimide cross-linker compound may be
ZOLDINE.TM. XL-29SE manufactured by Angus Chemical Company, a
subsidiary of the Dow Chemical Company of Midland, Mich. U.S.A. In
one aspect, polyamines may comprise diethylenetriamine,
polyethyleneimines, polyvinylamines, and/or ethylene diamine
moieties.
[0034] In one aspect, the crosslinker comprises a polyamine that
may comprise diethylenetriamine, ethylene diamine,
polyethyleneimine, polyvinylamine, bis(3-aminopropyl)piperazine,
N,N-Bis-(3-aminopropyl)methylamine, tris(2-aminoethyl)amine or
mixtures thereof.
[0035] Suitable polyamines include Lupasol.RTM. WF, SK, PS, PO100,
P, HF, G500, G35, G20 water free, G20, G100, FG, FC, and PR8515
products supplied by BASF of Ludwigshaven, Germany.
[0036] Other materials may be added to the benefit agent delivery
compositions disclosed herein. For example, colorants can be added
to such benefit agent delivery compositions including dyes and
pigments. The colorant may be one or more oil soluble dyes. Such
dyes may be added to the benefit agent prior to the formation of
the benefit agent delivery compositions disclosed herein.
Antioxidants may be added to benefit agent delivery compositions
disclosed herein. Such antioxidants may protect benefit agents,
including fragrances from oxidation. Suitable antioxidants include
BHA supplied by Eastman Chemical Company of Kingsport Tenn. U.S.A.
UV inhibitors can be added to benefit agent delivery compositions
disclosed herein and may prevent discoloration. Suitable UV
inhibitors include TINUVIN.RTM. commercial products supplied by
Ciba.RTM. of Basel, Switzerland.
[0037] Other materials maybe added to the benefit agent delivery
compositions disclosed herein are materials that will help to
process the benefit agent delivery compositions like solvents,
diluents, surfactants, fatty acids, polymers, suitable materials
are diluents like benzylbenzoate, nonionic surfactants like TAE80,
fatty acids like coconut oil, polymers like PEG4000.
[0038] In one aspect, the benefit agent delivery compositions of
the present invention may be clear. However, such compositions may
also be opaque. Such compositions can be made opaque by the
addition of opacifying agents. Suitable opacifying agents include
titanium dioxide, zinc oxide, inorganic salts, waxes, water, and
other organic opacifiers that are well known to those of skilled in
the art.
[0039] Additional materials may be added to the benefit agent
delivery compositions disclosed herein. Such materials may or may
not be volatile. Such materials include solvents, oils, esters,
phthalates, fatty acids, triglycerides, ethers, oils, aliphatic
materials, hydrocarbons, plasticizers, and alcohols. Such materials
may or may not be hydrophilic. Suitable hydrophilic materials
include water, glycols, and alcohols. In one aspect, surfactants
may be added to the benefit agent delivery compositions disclosed
herein. Suitable surfactants include nonionic, anionic, cationic,
and amphoteric surfactants--examples of which will be well known to
those of skill in the art. The inclusion of surfactants may
facilitate the inclusion of hydrophilic materials into the benefit
agent delivery compositions disclosed herein.
Process of Making Benefit Agent Delivery Compositions
[0040] The benefit agent delivery compositions disclosed in the
present application may be made via the teachings of USPA
2006/0067963 A1, and the examples disclosed herein.
[0041] The benefit agent containing compositions disclosed in the
present application may be processed in accordance with the
teachings of U.S. Pat. Nos. 6,451,751 B1, 6,972,276 B1, 6,764,986
B1, 6,740,713 B1 and the examples disclosed herein. Suitable forms
for such benefit agent delivery compositions include, solids and
fluids including agglomerates, emulsions, solutions, prills, beads
and encapsulates. When employed to product a benefit agent delivery
composition the particle size of the benefit agent delivery
composition in said agglomerates, emulsions, solutions, prills,
beads and encapsulates may be from about 0.1 microns to about 100
microns, from about 1 micron to about 60 microns or even from about
5 to about 40 microns. In addition to the foregoing, the benefit
agent delivery compositions of the present invention may be further
processed in accordance with the teachings of published US Patent
Application No. 2007/0196502 A1 to yield a particle wherein the
benefit agent delivery composition comprises at least a portion or
even all of one or more layers of the resulting particle.
[0042] In one aspect, a method for making a benefit agent delivery
composition comprising: [0043] a.) mixing a first mixture, wherein
said first mixture comprises: from about 15% to about 95% by weight
of a volatile hydrophobic liquid; and from about 3% to about 40% by
weight of a polymeric compound containing a carboxylic acid, until
said first mixture is completely mixed; and mixing into said first
mixture, from about 1.5% to about 40% by weight of a cross-linking
agent; or [0044] b.) mixing a first mixture, wherein said first
mixture comprises: from about 15% to about 95% by weight of a
volatile hydrophobic liquid; and from about 3% to about 40% by
weight of a polymeric compound containing a carboxylic acid, until
said first mixture is completely mixed; and mixing into said first
mixture, from about 0% to about 40% by weight of a cross-linking
agent; or [0045] c.) mixing a first mixture, wherein said first
mixture comprises: from about 15% to about 95% by weight of a
volatile hydrophobic liquid; and from about 3% to about 40% by
weight of a polymeric compound containing a carboxylic acid, until
said first mixture is completely mixed; and mixing into said first
mixture a second mixture, wherein said second mixture comprises:
from 15% to about 95% by weight volatile hydrophobic liquid; and
from about 1.5% to about 40% by weight of a cross-linking agent; or
[0046] d.) combining from about 15% to about 95% by weight of a
volatile hydrophobic liquid; and from about 3% to about 40% by
weight of a polymeric compound containing a carboxylic acid, until
said first mixture is completely mixed; and mixing into said first
mixture, from about 0% to about 40% by weight of a cross-linking
agent; [0047] e.) optionally combining the mixtures produced in
a.), b.), c.) and/or d.) with a diluent and/or a surfactant; and/or
further processing the mixtures produced in a.), b.), c.) and/or
d.) to form a particle, bead and/or agglomerate is disclosed.
[0048] In one aspect, the benefit agent delivery composition is
pre-made and added to a consumer.
[0049] In one aspect the components of the benefit agent delivery
composition are added separately to a consumer product and the
benefit agent delivery composition may form in the consumer before,
during and/or after use by the consumer.
[0050] In one aspect, when additional benefit agent(s) and/or
benefit agent delivery system(s), for example perfume and/or
encapsulated perfume, are employed to form a particle, bead and/or
agglomerate, the benefit agent delivery composition of the present
invention may be added before, during or after said additional
benefit agent(s) and/or benefit agent delivery system(s) are added
to said a particle, bead and/or agglomerate.
[0051] In one aspect, when additional benefit agent(s) and/or
benefit agent delivery system(s), for example perfume and/or
encapsulated perfume, are employed, the benefit agent delivery
composition of the present invention may be added before, during or
after said additional benefit agent(s) and/or benefit agent
delivery system(s) are added to a consumer.
[0052] Suitable equipment for use in the processes disclosed herein
may include continuous stirred tank reactors, homogenizers, turbine
agitators, recirculating pumps, paddle mixers, ploughshear mixers,
ribbon blenders, vertical axis granulators, twin screw extruders
and drum mixers, both in batch and, where available, in continuous
process configurations, spray dryers, and extruders. Such equipment
can be obtained from Lodige GmbH (Paderborn, Germany), Littleford
Day, Inc. (Florence, Ky., U.S.A.), Forberg AS (Larvik, Norway),
Glatt Ingenieurtechnik GmbH (Weimar, Germany), Niro (Soeborg,
Denmark), Hosokawa Bepex Corp. (Minneapolis, Minn., USA), Arde
Barinco (New Jersey, USA), Wenger (Sabetha, Kans. USA).
Compositions Comprising Benefit Agent Delivery Compositions
[0053] Applicants' compositions comprise an embodiment of the
benefit agent delivery compositions disclosed in the present
application. In one aspect, such compositions may be a consumer
product. While the precise level of benefit agent delivery
composition that is employed depends on the type and end use of the
product comprising such composition, a products, including cleaning
and/or fabric treatment products, may comprise, based on total
product weight, from about 0.001% to about 25%, from about 0.01% to
about 5%, or even from about 0.05% to about 3% benefit agent
delivery composition.
[0054] In one aspect, a consumer product comprising at least one
embodiment of a benefit agent delivery composition disclosed herein
and a material selected from the group consisting of a surfactant,
an enzyme, a polymer, a dye, a neat perfume, a perfume delivery
system in addition to Applicants' benefit agent delivery system and
mixtures thereof is disclosed. Suitable perfume delivery systems
are described in published U.S. Patent Application No. 2007/0275866
A1
[0055] Aspects of the invention include the use of the benefit
agent delivery compositions of the present invention in laundry
detergent compositions (e.g., TIDE.TM.), hard surface cleaners
(e.g., MR CLEAN.TM.), automatic dishwashing liquids (e.g.,
CASCADE.TM.), dishwashing liquids (e.g., DAWN.TM.), and floor
cleaners (e.g., SWIFFER.TM.). Non-limiting examples of cleaning
compositions may include those described in U.S. Pat. Nos.
4,515,705; 4,537,706; 4,537,707; 4,550,862; 4,561,998; 4,597,898;
4,968,451; 5,565,145; 5,929,022; 6,294,514; 6,376,445, 7,169,741 B2
and 7,297,674 B2 as well as in U.S. Patent Application Publication
No. 2005/0130864 A1. The cleaning compositions disclosed herein may
be formulated such that, during use in aqueous cleaning operations,
the wash water will have a pH of between about 5 and about 12, or
between about 7.5 and 10.5. Liquid dishwashing product formulations
typically have a pH between about 6.8 and about 9.0. Cleaning
products are typically formulated to have a pH of from about 7 to
about 12. Techniques for controlling pH at recommended usage levels
include the use of buffers, alkalis, acids, etc., and are well
known to those skilled in the art.
[0056] Fabric treatment compositions disclosed herein typically
comprise a fabric softening active ("FSA"). Suitable fabric
softening actives, include, but are not limited to, materials
selected from the group consisting of quats, amines, fatty esters,
sucrose esters, silicones, dispersible polyolefins, clays,
polysaccharides, fatty oils, polymer latexes and mixtures
thereof.
Adjunct Materials
[0057] While not essential for the purposes of the present
invention, the non-limiting list of adjuncts illustrated
hereinafter are suitable for use in the instant compositions and
may be desirably incorporated in certain embodiments of the
invention, for example to assist or enhance performance, for
treatment of the substrate to be cleaned, or to modify the
aesthetics of the composition as is the case with perfumes,
colorants, dyes or the like. It is understood that such adjuncts
are in addition to the components that are supplied via Applicants'
delivery particles and FSAs. The precise nature of these additional
components, and levels of incorporation thereof, will depend on the
physical form of the composition and the nature of the operation
for which it is to be used. Suitable adjunct materials include, but
are not limited to, surfactants, builders, chelating agents, dye
transfer inhibiting agents, dispersants, enzymes, and enzyme
stabilizers, catalytic materials, bleach activators, polymeric
dispersing agents, clay soil removal/anti-redeposition agents,
brighteners, suds suppressors, dyes, additional perfume and perfume
delivery systems, structure elasticizing agents,
thickeners/structurants, fabric softeners, carriers, hydrotropes,
processing aids and/or pigments. In addition to the disclosure
below, suitable examples of such other adjuncts and levels of use
are found in U.S. Pat. Nos. 5,576,282, 6,306,812 B1 and 6,326,348
B1 that are incorporated by reference.
[0058] As stated, the adjunct ingredients are not essential to
Applicants' cleaning and fabric care compositions. Thus, certain
embodiments of Applicants' compositions do not contain one or more
of the following adjuncts materials: bleach activators,
surfactants, builders, chelating agents, dye transfer inhibiting
agents, dispersants, enzymes, and enzyme stabilizers, catalytic
metal complexes, polymeric dispersing agents, clay and soil
removal/anti-redeposition agents, brighteners, suds suppressors,
dyes, additional perfumes and perfume delivery systems, structure
elasticizing agents, thickeners/structurants, fabric softeners,
carriers, hydrotropes, processing aids and/or pigments. However,
when one or more adjuncts is present, such one or more adjuncts may
be present as detailed below:
[0059] Surfactants--The compositions according to the present
invention can comprise a surfactant or surfactant system wherein
the surfactant can be selected from nonionic and/or anionic and/or
cationic surfactants and/or ampholytic and/or zwitterionic and/or
semi-polar nonionic surfactants. The surfactant is typically
present at a level of from about 0.1%, from about 1%, or even from
about 5% by weight of the cleaning compositions to about 99.9%, to
about 80%, to about 35%, or even to about 30% by weight of the
cleaning compositions.
[0060] Builders--The compositions of the present invention can
comprise one or more detergent builders or builder systems. When
present, the compositions will typically comprise at least about 1%
builder, or from about 5% or 10% to about 80%, 50%, or even 30% by
weight, of said builder. Builders include, but are not limited to,
the alkali metal, ammonium and alkanolammonium salts of
polyphosphates, alkali metal silicates, alkaline earth and alkali
metal carbonates, aluminosilicate builders polycarboxylate
compounds. ether hydroxypolycarboxylates, copolymers of maleic
anhydride with ethylene or vinyl methyl ether,
1,3,5-trihydroxybenzene-2,4,6-trisulphonic acid, and
carboxymethyl-oxysuccinic acid, the various alkali metal, ammonium
and substituted ammonium salts of polyacetic acids such as
ethylenediamine tetraacetic acid and nitrilotriacetic acid, as well
as polycarboxylates such as mellitic acid, succinic acid,
oxydisuccinic acid, polymaleic acid, benzene 1,3,5-tricarboxylic
acid, carboxymethyloxysuccinic acid, and soluble salts thereof.
[0061] Chelating Agents--The compositions herein may also
optionally contain one or more copper, iron and/or manganese
chelating agents. If utilized, chelating agents will generally
comprise from about 0.1% by weight of the compositions herein to
about 15%, or even from about 3.0% to about 15% by weight of the
compositions herein.
[0062] Dye Transfer Inhibiting Agents--The compositions of the
present invention may also include one or more dye transfer
inhibiting agents. Suitable polymeric dye transfer inhibiting
agents include, but are not limited to, polyvinylpyrrolidone
polymers, polyamine N-oxide polymers, copolymers of
N-vinylpyrrolidone and N-vinylimidazole, polyvinyloxazolidones and
polyvinylimidazoles or mixtures thereof. When present in the
compositions herein, the dye transfer inhibiting agents are present
at levels from about 0.0001%, from about 0.01%, from about 0.05% by
weight of the cleaning compositions to about 10%, about 2%, or even
about 1% by weight of the cleaning compositions.
[0063] Dispersants--The compositions of the present invention can
also contain dispersants. Suitable water-soluble organic materials
are the homo- or co-polymeric acids or their salts, in which the
polycarboxylic acid may comprise at least two carboxyl radicals
separated from each other by not more than two carbon atoms.
[0064] Enzymes--The compositions can comprise one or more detergent
enzymes which provide cleaning performance and/or fabric care
benefits. Examples of suitable enzymes include, but are not limited
to, hemicellulases, peroxidases, proteases, cellulases, xylanases,
lipases, phospholipases, esterases, cutinases, pectinases,
keratanases, reductases, oxidases, phenoloxidases, lipoxygenases,
ligninases, pullulanases, tannases, pentosanases, malanases,
.beta.-glucanases, arabinosidases, hyaluronidase, chondroitinase,
laccase, and amylases, or mixtures thereof. A typical combination
is a cocktail of conventional applicable enzymes like protease,
lipase, cutinase and/or cellulase in conjunction with amylase.
[0065] Enzyme Stabilizers--Enzymes for use in compositions, for
example, detergents can be stabilized by various techniques. The
enzymes employed herein can be stabilized by the presence of
water-soluble sources of calcium and/or magnesium ions in the
finished compositions that provide such ions to the enzymes.
[0066] Catalytic Metal Complexes--Applicants' compositions may
include catalytic metal complexes. One type of metal-containing
bleach catalyst is a catalyst system comprising a transition metal
cation of defined bleach catalytic activity, such as copper, iron,
titanium, ruthenium, tungsten, molybdenum, or manganese cations, an
auxiliary metal cation having little or no bleach catalytic
activity, such as zinc or aluminum cations, and a sequestrate
having defined stability constants for the catalytic and auxiliary
metal cations, particularly ethylenediaminetetraacetic acid,
ethylenediaminetetra (methyl-enephosphonic acid) and water-soluble
salts thereof. Such catalysts are disclosed in U.S. Pat. No.
4,430,243.
[0067] If desired, the compositions herein can be catalyzed by
means of a manganese compound. Such compounds and levels of use are
well known in the art and include, for example, the manganese-based
catalysts disclosed in U.S. Pat. No. 5,576,282.
[0068] Cobalt bleach catalysts useful herein are known, and are
described, for example, in U.S. Pat. Nos. 5,597,936 and 5,595,967.
Such cobalt catalysts are readily prepared by known procedures,
such as taught for example in U.S. Pat. Nos. 5,597,936, and
5,595,967.
[0069] Compositions herein may also suitably include a transition
metal complex of a macropolycyclic rigid ligand--abbreviated as
"MRL". As a practical matter, and not by way of limitation, the
compositions and cleaning processes herein can be adjusted to
provide on the order of at least one part per hundred million of
the benefit agent MRL species in the aqueous washing medium, and
may provide from about 0.005 ppm to about 25 ppm, from about 0.05
ppm to about 10 ppm, or even from about 0.1 ppm to about 5 ppm, of
the MRL in the wash liquor.
[0070] Suitable transition-metals in the instant transition-metal
bleach catalyst include manganese, iron and chromium. Suitable
MRL's herein are a special type of ultra-rigid ligand that is
cross-bridged such as
5,12-diethyl-1,5,8,12-tetraazabicyclo[6.6.2]hexa-decane.
[0071] Suitable transition metal MRLs are readily prepared by known
procedures, such as taught for example in WO 00/32601, and U.S.
Pat. No. 6,225,464.
[0072] Suitable thickeners/structurants and useful levels of same
are described in U.S. Patent Application Publication No.
2005/0130864 A1 and U.S. Pat. Nos. 7,169,741 B2 and 7,297,674
B2.
Processes of Making and Using Compositions
[0073] The compositions of the present invention can be formulated
into any suitable form and prepared by any process chosen by the
formulator, non-limiting examples of which are described in U.S.
Pat. No. 5,879,584; U.S. Pat. No. 5,691,297; U.S. Pat. No.
5,574,005; U.S. Pat. No. 5,569,645; U.S. Pat. No. 5,565,422; U.S.
Pat. No. 5,516,448; U.S. Pat. No. 5,489,392; U.S. Pat. No.
5,486,303 all of which are incorporated herein by reference.
Method of Use
[0074] Compositions containing the benefit agent delivery
composition disclosed herein can be used to clean or treat a situs
inter alia a surface or fabric. Typically at least a portion of the
situs is contacted with an embodiment of Applicants' composition,
in neat form or diluted in a liquor, for example, a wash liquor and
then the situs may be optionally washed and/or rinsed. In one
aspect, a situs is optionally washed and/or rinsed, contacted with
a particle according to the present invention or composition
comprising said particle and then optionally washed and/or rinsed.
For purposes of the present invention, washing includes but is not
limited to, scrubbing, and mechanical agitation. The fabric may
comprise most any fabric capable of being laundered or treated in
normal consumer use conditions. Liquors that may comprise the
disclosed compositions may have a pH of from about 3 to about 11.5.
Such compositions are typically employed at concentrations of from
about 500 ppm to about 15,000 ppm in solution. When the wash
solvent is water, the water temperature typically ranges from about
5.degree. C. to about 90.degree. C. and, when the situs comprises a
fabric, the water to fabric ratio is typically from about 1:1 to
about 30:1.
Packaging Comprising Benefit Agent Delivery Compositions
[0075] In one aspect, packaging comprising the benefit agent
delivery compositions is disclosed. Such packaging may be used to
package a product such as a consumer product. The benefit delivery
compositions of the present invention may be adhered or attached
any where on such packaging. Such packing may take any form
including wrapping, or a container. In one aspect, a benefit agent
delivery composition disclosed herein may be adhered or attached to
the exterior and/or the interior surface of such packaging. In one
aspect, said packaging may comprise a container comprising a cap
and said benefit agent delivery composition disclosed herein is
adhered or attached to the exterior or interior surface of said
cap.
Displays Comprising Benefit Agent Delivery Compositions
[0076] In one aspect, a display comprising the benefit agent
delivery compositions is disclosed. Such display may be used to
attract attention to, market and/or assist in whole or in part the
sale of a product such as a consumer product. The benefit delivery
compositions of the present invention may be adhered or attached
any where on such display. Such display may take any form including
posters, sales and/or marketing literature, or a container. In one
aspect, a benefit agent delivery composition disclosed herein is
adhered or attached to the exterior and/or the interior surface of
such display.
EXAMPLES
[0077] While particular embodiments of the present invention have
been illustrated and described, it would be obvious to those
skilled in the art that various other changes and modifications can
be made without departing from the spirit and scope of the
invention. It is therefore intended to cover in the appended claims
all such changes and modifications that are within the scope of
this invention.
Example 1
[0078] Equal amounts a perfume composition and amine-terminated
Hycar.RTM. ATBN1300X42 from Noveon are weighted and mixed for five
minutes using a Ultra-Turrax as needed. The ingredients are put at
60.degree. C. in warm water bath for 1 hour before use/mixing.
After mixing the mixture is put in a warm water bath at 60.degree.
C. for .+-.12 hours. A homogenous, viscous and sticky material is
obtained.
[0079] In the same way as described above different ratios between
the components can be used:
TABLE-US-00004 Weight % Perfume composition 40 50 60 70 80 Hycar
.RTM. 1300X42 60 50 40 30 20
Example 2
[0080] A mixture comprising 50% of a perfume composition, 40% of
carboxyl-terminated Hycar.RTM.1300X18 (CAS#0068891-50-9) from
Noveon, (put at 60.degree. C. in warm water bath for 1 hour before
mixing) and 10% of Lupasol.RTM. WF(CAS#09002-98-6) from BASF (put
at 60.degree. C. in warm water bath for 1 hour before mixing).
Mixing is achieved by mixing for five minutes using a Ultra-Turrax
T25 Basic equipment (from IKA). After mixing, the mixture is put in
a warm water bath at 60.degree. C. for .+-.12 hours. A homogenous,
viscous and sticky material is obtained.
[0081] In the same way as described above different ratios between
the components can be used:
TABLE-US-00005 Weight % Perfume composition 40 50 60 70 80 Lupasol
.RTM. WF 12 10 8 6 4 Hycar .RTM. 48 40 32 24 16 CTBN1300X18 Perfume
composition 50 50 50 50 50 50 50 50 Lupasol .RTM. WF 2.5 5 7.5 10
12.5 15 17.5 20 Hycar .RTM. CTBN 47.5 45 42.5 40 37.5 35 32.5 30
1300X18
Example 3
[0082] A mixture comprising 50% of a perfume composition, 40% of
carboxyl-terminated Hycar.RTM. CTBN 1300X18 from Noveon (put at
60.degree. C. in warm water bath for 1 hour before mixing) and 10%
of Lupasol.RTM. WF (CAS#09002-98-6) from BASF (put at 60.degree. C.
in warm water bath for 1 hour before use) is formed.
[0083] Mixing is achieved by mixing for five minutes using a
Ultra-Turrax T25 Basic equipment (from IKA). After mixing, the
mixture is put in a warm water bath at 60.degree. C. for .+-.12
hours. A homogenous, viscous and sticky material is obtained.
Example 4
[0084] In a first step of the preparation the Lupasol.RTM. WF
(CAS#09002-98-6) from BASF 15% is used in combination with 35% of
carboxyl-terminated Hycar.RTM. CTBN1300X18 and 17% of this polymer
mix is diluted with 83% of Benzyl Benzoate to make a workable
solution. The materials described above are put together, in the
ratio's described above, in a glass jar at 80.degree. C. on a hot
plate with stirring using a magnetic stirrer. Next the polymer
premix is mixed with a perfume composition in a 1:1 ratio. This
polymer-perfume mix is than added to a fabric enhancer
composition.
Example 5
Agglomeration of Benefit Agent Delivery Composition-Perfume System
for Use in Powder Detergents
[0085] Starting from any of Examples 1 to 3 as described above:
[0086] The resulting homogenous, viscous and sticky material is
held at 60.degree. for .+-.2 hours before starting the
agglomeration process. Next, a mixture comprising 40% of the
viscous, sticky sample and 60% of melted TAE80 is formed by
combining and mixing with an Ultra-Turrax T25 Basic equipment (from
IKA) for 5 to 10 minutes. Then, 1 part of the TAE80/sticky sample
is very slowly added to 0.6 parts of light soda ash using a Braun
kitchen robot to form agglomerates.
[0087] The resulting agglomerates are then used in a powder
detergent.
Example 6
Liquid Application
[0088] Starting from any of Examples 1 to 3 as described above:
[0089] The resulting homogenous, viscous and sticky material is
held at 60.degree. for .+-.2 hours before starting the dilution
process.
TABLE-US-00006 Weight % Sticky sample 20 30 40 50 60 Benzyl
benzoate or 80 70 60 50 40 fatty acid
[0090] The viscous sticky material obtained as described in any of
Examples 1-3 above are mixed at different ratios for five minutes
using an Ultra-Turrax T25 Basic equipment (from IKA), at the levels
listed in the table above, with benzyl benzoate before the
resulting mixture is a added to a liquid detergent.
Example 7
Different Process Manner of Obtaining the Consumer Benefit Delivery
Agent System
[0091] Addition of the different ingredients without premixing of
the materials:
[0092] The following are mixed without premixing/premixtures being
formed.
TABLE-US-00007 Weight % Perfume composition 40 50 60 70 Lupasol
.RTM. wf 12 10 8 6 Via premix in H.sub.2O (50%/50%) Hycar .RTM.
CTBN 1300X18 48 40 32 24 Via premix in Benzyl Benzoate (20%/80%
Benzyl Benzoate)
Example 8
[0093] Non-limiting examples of product formulations containing a
benefit agent delivery composition are summarized in the following
table.
TABLE-US-00008 EXAMPLES (% wt) XI XII XIII XIV XV XVI XVII XVIII
XIX XX FSA.sup.a 14 16.47 14 12 12 16.47 -- -- 5 5 FSA.sup.b --
3.00 -- -- -- FSA.sup.c -- -- 6.5 -- -- Ethanol 2.18 2.57 2.18 1.95
1.95 2.57 -- -- 0.81 0.81 Isopropyl -- -- -- -- -- -- 0.33 1.22 --
-- Alcohol Starch.sup.d 1.25 1.47 2.00 1.25 -- 2.30 0.5 0.70 0.71
0.42 Benefit agent 0.6 0.75 0.6 0.75 0.37 0.60 0.37 0.6 0.37 0.37
delivery composition Phase 0.21 0.25 0.21 0.21 0.14 -- -- 0.14 --
-- Stabilizing Polymer.sup.f Suds -- -- -- -- -- -- -- 0.1 -- --
Suppressor.sup.g Calcium 0.15 0.176 0.15 0.15 0.30 0.176 --
0.1-0.15 -- -- Chloride DTPA.sup.h 0.017 0.017 0.017 0.017 0.007
0.007 0.20 -- 0.002 0.002 Preservative 5 5 5 5 5 5 -- 250.sup.j 5 5
(ppm).sup.i,j Antifoam.sup.k 0.015 0.018 0.015 0.015 0.015 0.015 --
-- 0.015 0.015 Dye 40 40 40 40 40 40 11 30-300 30 30 (ppm) Ammonium
0.100 0.118 0.100 0.100 0.115 0.115 -- -- -- -- Chloride HCl 0.012
0.014 0.012 0.012 0.028 0.028 0.016 0.025 0.011 0.011
Structurant.sup.l 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01
Neat 0.8 0.7 0.9 0.5 1.2 0.5 1.1 0.6 1.0 0.9 Perfume Deionized * *
* * * * * * * * Water * Balance
.sup.aN,N-di(tallowoyloxyethyl)-N,N-dimethylammonium chloride.
.sup.bMethyl bis(tallow amidoethyl)2-hydroxyethyl ammonium methyl
sulfate. .sup.cReaction product of Fatty acid with
Methyldiethanolamine in a molar ratio 1.5:1, quaternized with
Methylchloride, resulting in a 1:1 molar mixture of
N,N-bis(stearoyl-oxy-ethyl) N,N-dimethyl ammonium chloride and
N-(stearoyl-oxy-ethyl) N,-hydroxyethyl N,N dimethyl ammonium
chloride. .sup.dCationic high amylose maize starch available from
National Starch under the trade name CATO .RTM.. .sup.fCopolymer of
ethylene oxide and terephthalate having the formula described in
U.S. Pat. No. 5,574,179 at col. 15, lines 1-5, wherein each X is
methyl, each n is 40, u is 4, each R1 is essentially 1,4-phenylene
moieties, each R2 is essentially ethylene, 1,2-propylene moieties,
or mixtures thereof. .sup.gSE39 from Wacker
.sup.hDiethylenetriaminepentaacetic acid. .sup.iKATHON .RTM. CG
available from Rohm and Haas Co. "PPM" is "parts per million."
.sup.jGluteraldehyde .sup.kSilicone antifoam agent available from
Dow Corning Corp. under the trade name DC2310.
.sup.lHydrophobically-modified ethoxylated urethane available from
Rohm and Haas under the tradename Aculan 44.
Example 9
Benefit Agent Delivery Composition in Dry Laundry Formulations
TABLE-US-00009 [0094] % w/w granular laundry detergent composition
Component A B C D E F G Brightener 0.1 0.1 0.1 0.2 0.1 0.2 0.1 Soap
0.6 0.6 0.6 0.6 0.6 0.6 0.6 Ethylenediamine 0.1 0.1 0.1 0.1 0.1 0.1
0.1 disuccinic acid Acrylate/maleate 1.5 1.5 1.5 1.5 1.5 1.5 1.5
copolymer Hydroxyethane 0.4 0.4 0.4 0.4 0.4 0.4 0.4 di(methylene
phosphonic acid) Mono-C.sub.12-14 alkyl, 0.5 0.5 0.5 0.5 0.5 0.5
0.5 di-methyl, mono-hydroxyethyl quaternary ammonium chloride
Linear alkyl benzene 0.1 0.1 0.2 0.1 0.1 0.2 0.1 Linear alkyl
benzene 10.3 10.1 19.9 14.7 10.3 17 10.5 sulphonate Magnesium
sulphate 0.4 0.4 0.4 0.4 0.4 0.4 0.4 Sodium carbonate 19.5 19.2
10.1 18.5 29.9 10.1 16.8 Sodium sulphate 29.6 29.8 38.8 15.1 24.4
19.7 19.1 Sodium Chloride 0.1 0.1 0.1 0.1 0.1 0.1 0.1 Zeolite 9.6
9.4 8.1 18 10 13.2 17.3 Photobleach particle 0.1 0.1 0.2 0.1 0.2
0.1 0.2 Blue and red carbonate 1.8 1.8 1.8 1.8 1.8 1.8 1.8 speckles
Ethoxylated 1 1 1 1 1 1 1 Alcohol AE7 Tetraacetyl ethylene 0.9 0.9
0.9 0.9 0.9 0.9 0.9 diamine agglomerate (92 wt % active) Citric
acid 1.4 1.4 1.4 1.4 1.4 1.4 1.4 PDMS/clay 10.5 10.3 5 15 5.1 7.3
10.2 agglomerates (9.5% wt % active PDMS) Polyethylene oxide 0.2
0.2 0.2 0.2 0.2 0.2 0.2 Enzymes e.g. Protease 0.2 0.3 0.2 0.1 0.2
0.1 0.2 (84 mg/g active), Amylase (22 mg/g active) Suds suppressor
0.2 0.2 0.2 0.2 0.2 0.2 0.2 agglomerate (12.4 wt % active) Sodium
percarbonate 7.2 7.1 4.9 5.4 6.9 19.3 13.1 (having from 12% to 15%
active AvOx) Perfume oil 0.5 0.5 0.5 0.5 0.5 0.5 0.5 Solid perfume
particles 0.4 0 0.4 0.4 0.4 0.4 0.6 Benefit agent delivery 1.3 2.4
1 1.3 1.3 1.3 0.7 composition Water 1.4 1.4 1.4 1.4 1.4 1.4 1.4
Misc. 0.1 0.1 0.1 0.1 0.1 0.1 0.1 Total Parts 100 100 100 100 100
100 100
Example 10
Liquid Laundry Formulations (HDLs)
TABLE-US-00010 [0095] Ingredient HDL 1 HDL 2 HDL3 HDL4 HDL 5 HDL 6
Alkyl Ether 0.00 0.50 12.0 12.0 6.0 7.0 Sulphate Dodecyl 8.0 8.0
1.0 1.0 2.0 3.0 Benzene Sulphonic Acid Ethoxylated 8.0 6.0 5.0 7.0
5.0 3.0 Alcohol Citric Acid 5.0 3.0 3.0 5.0 2.0 3.0 Fatty Acid 3.0
5.0 5.0 3.0 6.0 5.0 Ethoxysulfated 1.9 1.2 1.5 2.0 1.0 1.0
hexamethylene diamine quaternized Diethylene 0.3 0.2 0.2 0.3 0.1
0.2 triamine penta methylene phosphonic acid Enzymes 1.20 0.80 0
1.2 0 0.8 Brightener 0.14 0.09 0 0.14 0.01 0.09 (disulphonated
diamino stilbene based FWA) Cationic 0 0 0.10 0 0.200 0.30
hydroxyethyl cellulose Poly 0 0 0 0.50 0.10 0 (acrylamide-co-
diallyldi- methylam- monium chloride) Hydrogenated 0.50 0.44 0.2
0.2 0.3 0.3 Castor Oil Structurant Boric acid 2.4 1.5 1.0 2.4 1.0
1.5 Ethanol 0.50 1.0 2.0 2.0 1.0 1.0 1,2 propanediol 2.0 3.0 1.0
1.0 0.01 0.01 Glutaraldehyde 0 0 19 ppm 0 13 ppm 0 Diethylene- 1.6
0 0 0 0 0 glycol (DEG) 2,3-Methyl-1, 1.0 1.0 0 0 0 0 3-propanediol
(M pdiol) Mono Ethanol 1.0 0.5 0 0 0 0 Amine NaOH Sufficient pH 8
pH 8 pH 8 pH 8 pH 8 pH 8 To Provide Formulation pH of: Sodium 2.00
0 0 0 0 0 Cumene Sulphonate (NaCS) Silicone 0.003 0.003 0.003 0.003
0.003 0.003 (PDMS) emulsion Perfume 0.7 0.5 0.8 0.8 0.6 0.6
Polyethyl- 0.01 0.10 0.00 0.10 0.20 0.05 eneimine Benefit Agent
1.00 5.00 1.00 2.00 0.10 0.80 Delivery Composition Water Balance
Balance Balance Balance Balance Balance to to to to to to 100% 100%
100% 100% 100% 100%
[0096] The dimensions and values disclosed herein are not to be
understood as being strictly limited to the exact numerical values
recited. Instead, unless otherwise specified, each such dimension
is intended to mean both the recited value and functionally
equivalent range surrounding that value. For example, a dimension
disclosed as "40 mm" is intended to mean "about 40 mm".
[0097] All documents cited in the Detailed Description of the
Invention are, in relevant part, incorporated herein by reference;
the citation of any document is not to be construed as an admission
that it is prior art with respect to the present invention. To the
extent that any meaning or definition of a term in this document
conflicts with any meaning or definition of the same term in a
document incorporated by reference, the meaning or definition
assigned to that term in this document shall govern.
[0098] While particular embodiments of the present invention have
been illustrated and described, it would be obvious to those
skilled in the art that various other changes and modifications can
be made without departing from the spirit and scope of the
invention. It is therefore intended to cover in the appended claims
all such changes and modifications that are within the scope of
this invention.
* * * * *