U.S. patent application number 12/178383 was filed with the patent office on 2008-11-13 for solar heat reflective roofing membrane and process for making the same.
Invention is credited to Gregory F. Jacobs, Husnu M. Kalkanoglu, Ming Liang Shiao.
Application Number | 20080277056 12/178383 |
Document ID | / |
Family ID | 37830355 |
Filed Date | 2008-11-13 |
United States Patent
Application |
20080277056 |
Kind Code |
A1 |
Kalkanoglu; Husnu M. ; et
al. |
November 13, 2008 |
SOLAR HEAT REFLECTIVE ROOFING MEMBRANE AND PROCESS FOR MAKING THE
SAME
Abstract
A roofing membrane with high solar heat reflectance includes a
bituminous base sheet, a tie-layer with a reinforcement material,
and a solar heat-reflective upper layer formed from a powder
coating filled with a solar heat-reflective pigment.
Inventors: |
Kalkanoglu; Husnu M.;
(Swarthmore, PA) ; Shiao; Ming Liang;
(Collegeville, PA) ; Jacobs; Gregory F.; (Oreland,
PA) |
Correspondence
Address: |
PAUL AND PAUL
2000 MARKET STREET, SUITE 2900
PHILADELPHIA
PA
19103
US
|
Family ID: |
37830355 |
Appl. No.: |
12/178383 |
Filed: |
July 23, 2008 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
|
|
11162346 |
Sep 7, 2005 |
7422989 |
|
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12178383 |
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Current U.S.
Class: |
156/280 |
Current CPC
Class: |
B32B 2255/02 20130101;
B32B 27/00 20130101; B32B 2262/101 20130101; Y10T 442/184 20150401;
Y10T 442/2123 20150401; Y10T 442/60 20150401; B32B 5/022 20130101;
Y10T 442/2598 20150401; Y10T 442/20 20150401; B32B 2255/26
20130101; B32B 2255/28 20130101; B32B 2307/304 20130101; Y10T
442/2861 20150401; B32B 2264/102 20130101; B32B 11/00 20130101;
Y10T 442/198 20150401; Y10T 442/699 20150401; B32B 2260/021
20130101; Y10T 442/259 20150401; B32B 2419/06 20130101; B32B
2260/046 20130101; Y10T 442/2992 20150401; B32B 2307/416 20130101;
B32B 2262/02 20130101 |
Class at
Publication: |
156/280 |
International
Class: |
B32B 37/14 20060101
B32B037/14 |
Claims
1. (canceled)
2. (canceled)
3. (canceled)
4. (canceled)
5. (canceled)
6. (canceled)
7. (canceled)
8. (canceled)
9. (canceled)
10. (canceled)
11. A process for preparing a roofing membrane with high solar heat
reflectance, the process comprising: a) laminating a tie-layer to a
bituminous base sheet to form an intermediate sheet; b) depositing
a solar heat-reflective coating composition on the intermediate
sheet; and c) curing the solar heat-reflective coating
composition.
12. A process according to claim 11 wherein the tie-layer is
laminated to the bituminous base sheet by heating the surface of
the base sheet to above the softening temperature of the bituminous
material, and adhering the tie-layer to the base sheet by
contacting the base sheet with the tie-layer and permitting the
bituminous material to partially saturate the tie-layer.
13. A process according to claim 12 further comprising applying
pressure while fusing the solar heat-reflective coating
composition.
14. A process according to claim 11 wherein the tie-layer is
comprised of particulate material, and the particulate material is
bonded to the bituminous base sheet by heating the surface of the
base sheet to above the softening temperature of the bituminous
material, and adhering the tie-layer to the base sheet by
depositing the particulate material on the base sheet and
permitting the particulate material to at least partially penetrate
into the asphaltic surface such that a secure mechanical bond is
formed when the heated surface cools.
15. (canceled)
16. (canceled)
17. (canceled)
18. (canceled)
19. (canceled)
20. (canceled)
21. (canceled)
22. A method of constructing a roof having high solar heat
reflectance, the method comprising adhering to a roofing deck a
roofing membrane with high solar heat reflectance, the roofing
membrane comprising: a) a bituminous base sheet; b) a tie-layer
comprising a reinforcement material; and c) a solar heat-reflective
upper layer comprising a powder coating.
23. A method of constructing a roof according to claim 22 wherein
the reinforcement material comprises a non-woven web of fibers,
said web comprising fibers selected from the group of glass fibers,
polymeric fibers and combinations thereof.
24. A method of constructing a roof according to claim 22 wherein
the powder coating comprises at least one polymeric binder and at
least one solar heat reflective pigment.
25. A method of constructing a roof according to claim 24 wherein
the at least one polymeric binder is powder coating binder.
26. A method of constructing a roof according to claim 24 wherein
the polymeric binder is polyamide 11.
27. A method of constructing a roof according to claim 24 wherein
the polymeric binder is an acrylic copolymer.
28. A method of constructing a roof according to claim 24 wherein
the at least one solar heat reflective pigment is titanium dioxide.
Description
BACKGROUND OF THE INVENTION
[0001] 1. Field of the Invention
[0002] The present invention relates to bituminous roofing products
such as asphalt-based roofing membranes and processes for making
such roofing products.
[0003] 2. Brief Description of the Prior Art
[0004] Asphalt-based roofing membranes are excellent waterproofing
materials that have been extensively used in low-slope roofing
systems to provide long-lasting and satisfactory roof coverings.
Low-slope roofing systems are extensively used for commercial and
industrial buildings. Examples of low-slope roofing systems are
built-up roofs (BUR), modified bitumen roofs, and single-ply or
membrane roofing systems. Asphalt-based roofing membranes are
frequently used as waterproofing underlayment in low-rise roofing
systems, as well as the uppermost or finish layer in
built-up-roofs. Built-up roofs are sometimes covered with a layer
of gravel or granular mineral material to protect the roofing
membrane against mechanical damage.
[0005] Mineral-surfaced asphalt shingles, such as those described
in ASTM D225 or D3462, are generally used for steep-sloped roofs to
provide water-shedding function while adding aesthetically pleasing
appearance to the roofs. Conversely, roll goods such as
asphalt-based roofing membranes are generally used for low-slope
roofs. Pigment-coated mineral particles are commonly used as color
granules in roofing applications to provide aesthetic as well as
protective functions. Roofing granules are generally used in
asphalt shingles or in roofing membranes to protect asphalt from
harmful ultraviolet radiation.
[0006] Roofing products such as asphalt shingles and roll stock are
typically composite articles including a non-woven glass fiber or
felt web covered with a coating of water repellent bituminous
material, and optionally surfaced with protective mineral-based
roofing granules. The bituminous material is characteristically
black in color, and is strongly absorptive of incident solar
radiation. Thus, asphalt-based roofing membranes can absorb
significant amounts of solar radiation, which can result in
elevated roof temperatures. This can contribute to the increase of
energy usage for indoor air-conditioning, especially in a hot
climate.
[0007] Asphalt shingles are generally constructed from
asphalt-saturated roofing felts and surfaced by pigmented color
granules. Asphalt-based roofing membranes are similarly
constructed; except that roofing granules are not frequently
employed. However, both asphalt shingles and asphalt-based roofing
membranes are known to have low solar reflectivity and hence will
absorb solar heat especially through the near-infrared range of the
solar spectrum.
[0008] This phenomenon increases as the surface becomes dark in
color. For example, white-colored asphalt shingles with CIE L*
greater than 60 can have solar reflectance greater than 25% (ASTM
E1918 method), whereas non-white asphalt shingles with L* less than
60 typically have solar reflectance in the range of only 5-20%. As
a result, it is common to measure temperatures as high as 71-77
degrees C. (160-170 degrees F.) on the surface of dark roofing
shingles on a sunny day with 27 degree C. (80 degrees F.) ambient
temperature.
[0009] Reduced energy consumption is an important national goal.
For example, the State of California has a code requirement that
all commercial roofing materials in lows slope applications need to
exceed a minimum of 70% solar reflectance in order to meet
California's energy budget code. Also, in order to qualify as
Energy Star.RTM. roofing material, a roofing membrane needs to
exceed 65% solar reflectance.
[0010] Typically, even a white mineral-surfaced, asphalt-based
roofing membrane has only 30-35% solar reflectance.
[0011] In order to address this problem, externally applied
coatings have sometimes been applied directly onto the shingle or
membrane surface on the roof. White pigment-containing latex
coatings have been proposed. Similarly, aluminum-coated asphalt
roofing membranes have been employed to achieve solar heat
reflectivity. U.S. Pat. No. 6,245,850 discloses a reflective
asphalt emulsion for producing a reflective asphalt roofing
membrane.
[0012] The use of exterior-grade coatings colored by
infrared-reflective pigments has also been proposed for spraying
onto the roof in the field. U.S. Patent Application Publication No.
2003/0068469A1 discloses an asphalt-based roofing material
comprising a mat saturated with asphalt coating and a top coating
having a top surface layer that has a solar reflectance of at least
70%.
[0013] U.S. Patent Application Publication No. 2002/0160151A1
discloses an integrated granule product comprising a film having a
plurality of ceramic-coated granules bonded to the film by a cured
adhesive and the cured adhesive or the film can have pigments. Such
integrated granule product can be directly bonded to an
asphalt-based substrate as roofing products.
[0014] In order to increase solar reflectance of built-up roofs,
reflective coatings have been applied directly onto the surface of
the roofing membrane. For example, white pigment containing latex
coatings have been proposed and evaluated by various manufacturers.
In addition, white single-ply roofing membranes formed from
thermoplastic elastomers, PVC, or EPDM, etc., have been developed
to achieve the required solar reflectance. Performance Roof Systems
(Kansas City, Mo.) has also developed an asphalt-based roofing
membrane having a white acrylic pre-impregnated mat on the top
surface.
[0015] Laminated single-ply roofing membranes are known, such as
those disclosed in U.S. Pat. Nos. 6,502,360; 5,456,785; 5,620,554;
and 5,643,399. U.S. Pat. No. 6,296,912 discloses a roofing membrane
having a fibrous layer on top for providing a secure surface for
roof installation personnel.
[0016] There is a continuing need for roofing materials that have
improved resistance to thermal stresses while providing an
attractive appearance. Further, there is a continuing need to
develop asphalt-based roofing membranes with solar reflectance
greater than 70%.
SUMMARY OF THE INVENTION
[0017] The present invention provides a roofing membrane with high
solar heat reflectance. The roofing membrane comprises a bituminous
base sheet; a tie-layer comprising a reinforcement material; and a
solar heat-reflective upper layer comprising a powder coating.
Preferably, the reinforcement material comprises a non-woven web of
fibers. Preferably, the nonwoven web comprises fibers selected from
the group of glass fibers, polymeric fibers and combinations
thereof. Preferably, the powder coating comprises at least one
polymeric binder, such as a powder coating binder, and at least one
solar heat reflective pigment.
[0018] The polymeric binder is preferably selected from the group
consisting of acrylic copolymers, polyesters, polyamides, epoxies,
nonacid-containing polyolefins, polyolefin alloys, polypropylene,
acid-containing polyolefins, polyvinyl chloride, polyester block
amide, ethylene-chlorotrifluorethylene, and polyvinylidene
fluoride. Preferably, the acid-containing polyolefin is selected
from polyethylene acrylic acid and polyethylene methacrylic acid.
In a presently preferred embodiment, the polymeric binder is
polyamide 11. In another presently preferred embodiment, the
polymeric binder is an acrylic copolymer. Preferably, the at least
one solar heat reflective pigment is titanium dioxide.
[0019] The present invention also provides a process for preparing
a roofing membrane with high solar heat reflectance. The
preparative process of the present invention comprises laminating a
tie-layer to a bituminous base sheet to form an intermediate sheet,
depositing a powder coating composition on the intermediate sheet;
and fusing the powder coating composition. Preferably, the
tie-layer is laminated to the bituminous base sheet by heating the
surface of the base sheet to above the softening temperature of the
bituminous material, and adhering the tie-layer to the base sheet
by contacting the base sheet with the tie-layer and permitting the
bituminous material to partially saturate the tie-layer.
Preferably, the preparative process further comprises applying
pressure while fusing the powder coating composition.
[0020] The present invention further provides a roof having high
solar heat resistance. The roof comprises a roofing deck and a
roofing membrane with high solar heat resistance according to the
present invention adhered to the roofing deck. In addition, the
present invention provides a method of constructing a roof having
high solar heat resistance. The construction method comprises
adhering to a roofing deck a roofing membrane with high solar heat
resistance according to the present invention.
BRIEF DESCRIPTION OF THE DRAWINGS
[0021] FIG. 1 is a schematic illustration of the structure of
solar-reflective roofing membrane according to a first embodiment
of the present invention.
[0022] FIG. 2 is a schematic illustration of the structure of
solar-reflective roofing membrane according to a second embodiment
of the present invention.
[0023] FIG. 3 is a schematic illustration of a process according to
the present invention for preparing a roofing membrane with high
solar reflectance.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS
[0024] In the process of the present invention, roofing membranes
with high solar heat reflectance are formed by combining a
reinforcement material as a tie-layer between the substrate of
suitable bituminous membrane and a solar heat-reflective upper
layer formed by melting or fusing a suitable powder coating
material in place during manufacturing.
[0025] Referring now to the figures in which like reference
numerals represent like elements in each of the several views,
there is shown in FIG. 1 a schematic illustration of a first
embodiment of a solar heat-reflective roofing membrane 10 according
to the present invention. The solar heat-reflective roofing
membrane 10 is comprised of three layers 12, 14, 16. The first
layer 16 is a bituminous membrane, such as an asphalt-based roofing
base sheet with a self-adhering backing. Adhered to the upper
surface of the base sheet 16 is a tie-layer 14 formed from a
reinforcement material such as mineral particles. A solar
heat-reflective coating 12, preferably formed from a powder coating
composition, is provided on the tie-layer 14, to form an upper
surface layer.
[0026] A schematic illustration of a second embodiment of a solar
heat-reflective roofing membrane 20 according to the present
invention is shown in FIG. 2. The solar heat-reflective roofing
membrane 20 is also comprised of three layers 22, 24, 26. The first
layer 26 is also bituminous membrane, such as an asphalt-based
roofing base sheet with a self-adhering backing. However, adhered
to the upper surface of the base sheet 26 is a tie-layer 24
comprising a fibrous mat, such as a non-woven glass fiber mat. A
solar heat-reflective coating 22, preferably formed from a powder
coating composition, is also provided on the tie-layer 24, to form
an upper surface layer.
[0027] The solar heat-reflective roofing products of the present
invention, such as solar-reflective roofing membranes, can be
manufactured using conventional roofing production processes, with
the addition of a powder coating process step. Typically,
bituminous roofing products are sheet goods that include a
non-woven base or scrim formed of a fibrous material, such as a
glass fiber scrim. The base is coated with one or more layers of a
bituminous material such as asphalt to provide water and weather
resistance to the roofing product. A self-adhering backing can also
be applied to the lower or rear surface of the base, and covered
with a suitable release sheet. The upper surface of the base layer
is covered with a tie-layer, and a powder coating is then applied
to the exposed surface of the tie-layer.
[0028] The solar heat-reflective roofing membrane is subsequently
employed in constructing a solar heat-reflective roof according to
the present invention. The roof is constructed by applying a
solar-reflective roofing membrane according to the present
invention to a suitable subroof in the case of new construction, or
a suitably prepared roofing surface in the case of an existing
structure. In constructing the roof, the upper surface of the
solar-reflective roofing membrane can be covered with mineral
granules to provide durability, reflect heat and solar radiation,
and to protect the powder coating binder from environmental
degradation. Optionally, a further protective coating (not shown)
could be applied over the heat reflective coating 22 to protect the
powder coating binder from the environment.
[0029] FIG. 3 schematically illustrates a presently preferred
process according to the present invention for preparing a roofing
membrane 50 with high solar reflectance. A continuous web of
bituminous membrane 30, such as an asphalt-based roofing base sheet
with a self-adhering backing, is provided as the base layer of the
roofing membrane 50. The web of bituminous membrane 30 is fed to
the processing apparatus in the direction shown by the arrows 32. A
tie-layer web 34, such as a non-woven web of glass fiber, is fed to
the processing apparatus in the direction shown by the arrow 35.
The tie-layer web 34 is adhered to the upper surface of the base
layer 30 by pressure applied by a first set of heated pressure
rollers 36 to form an intermediate web 37. Next, a solar
heat-reflective coating composition powder 38 is deposited from a
hopper 40 on the upper surface of the intermediate web 37.
Alternatively, other methods of applying the coating composition
powder 38 to the intermediate web 37, such as spray application,
can be employed (not shown). As the intermediate web 37 next passes
under an infrared heater 42, the powder 38 is fused to form a
continuous coating 43 on the top of the intermediate web 37. The
intermediate web 37 then passes through a second set of heated
pressure rollers 44 which press the coating composition 43 and
tie-layer 34 and bituminous membrane 30 to provide a uniform,
predetermined thickness to the roofing membrane 50.
[0030] Bituminous roofing products, such as the base sheet 30, are
typically manufactured in continuous processes in which a
continuous substrate sheet of a fibrous material such as a
continuous felt sheet or glass fiber mat is immersed in a bath of
hot, fluid bituminous coating material so that the bituminous
material saturates the substrate sheet and coats at least one side
of the substrate. The reverse side of the substrate sheet can be
coated with an anti-stick material such as a suitable mineral
powder or a fine sand. Alternatively, the reverse side of the
substrate sheet can be coated with an adhesive material, such as a
layer of a suitable bituminous material, to render the sheet
self-adhering. In this case the adhesive layer is preferably
covered with a suitable release sheet.
[0031] The solar-reflective roofing membrane can be formed into
roll goods for commercial or industrial roofing applications.
Alternatively, the solar-reflective roofing membrane can be cut
into conventional shingle sizes and shapes (such as one foot by
three feet rectangles), slots can be cut in the shingles to provide
a plurality of "tabs" for ease of installation or for aesthetic
effects, additional bituminous adhesive can be applied in strategic
locations and covered with release paper to provide for securing
successive courses of shingles during roof installation, and the
finished shingles can be packaged.
[0032] The bituminous material used in manufacturing roofing
products according to the present invention is derived from a
petroleum processing by-product such as pitch, "straightrun"
bitumen, or "blown" bitumen. The bituminous material can be
modified with extender materials such as oils, petroleum extracts,
and/or petroleum residues. The bituminous material can include
various modifying ingredients including polymeric materials such
as, for example, SBS (styrene-butadiene-styrene) block copolymers,
resins, flame-retardant materials, oils, stabilizing materials,
anti-static compounds, and the like. Preferably, the total amount
by weight of such modifying ingredients is not more than about 15
percent of the total weight of the bituminous material. The
bituminous material can also include amorphous polyolefins, up to
about 25 percent by weight. Examples of suitable amorphous
polyolefins include atactic polypropylene, ethylene-propylene
rubber, etc. Preferably, the amorphous polyolefins employed have a
softening point of from about 130 degrees C. to about 160 degrees
C. The bituminous composition can also include a suitable filler,
such as calcium carbonate, talc, carbon black, stone dust, or fly
ash, preferably in an amount from about 10 percent to 70 percent by
weight of the bituminous composite material.
[0033] Examples of suitable bituminous membranes for use as base
sheets in the process of the present invention include asphalt
roofing membranes such as asphalt-based, self-adhering roofing base
sheet available from CertainTeed Corporation, Valley Forge, Pa.,
for example, WinterGuard.TM. shingle underlayment, a base sheet
which is impregnated with rubberized asphalt.
[0034] Preferably, the reinforcement material comprises a non-woven
web of fibers. Preferably, the nonwoven web comprises fibers
selected from the group of glass fibers, polymeric fibers and
combinations thereof. Examples of suitable reinforcement material
for use as a tie-layer include, but not limited to, non-woven glass
fiber mats, non-woven polyester mats, composite non-woven mats of
various fibers, composite woven fabrics of various fibers,
industrial fabrics such as papermaker's forming fabrics and
papermaker's canvasses, polymer netting, screen, and mineral
particles. The fibers employed in preparing the reinforcing
material can be spun, blown or formed by other processes known in
the art. Yarn for forming the reinforcement material can include
mono-filament yarn, multi-filament yarn, spun yarn, processed yarn,
textured yarn, bulked yarn, stretched yarn, crimped yarn, chenille
yarn, and combinations thereof. The cross-section of the yarn
employed can be circular, oval, rectangular, square, or
star-shaped. The yarn can be solid, or hollow. The yarn can be
formed from natural fibers such as wool and cotton; synthetic
materials such as polyester, nylon, polyethylene, polypropylene,
polyvinylidene fluoride, ethylene tetrafluoroethylene copolymer,
polyethylene terephthalate, polybutylene terephthalate,
polytrimethylene terephthalate, poly(meth)acrylates, aramide,
polyetherketone, polyethylene naphthalate, and the like, as well as
non-organic materials such as spun glass fibers and metallic
materials, or combinations thereof.
[0035] Non-woven glass fiber mats for use in the process of the
present invention preferably have a weight per unit area of from
about 40 to 150 g/m.sup.2, more preferably form about 70 to 120
g/m.sup.2, and still more preferably from about 80 to 100
g/m.sup.2, and a thickness of from about 0.01 to 1 mm. Non-woven
glass mats having a weight per unit area of about 90 g/m.sup.2
(0.018 lb/ft.sup.2) are typically employed.
[0036] Preferably, the tie-layer has sufficient thickness so that
an adequately thick layer of solar heat-reflective coating
composition can be adhered thereto to provide effective solar heat
reflectance. Preferably, the tie layer has a thickness of from
about 0.001 cm to about 0.1 cm, more preferably from about 0.001 cm
to about 0.03 cm.
[0037] Examples of mineral particles that can be used as tie layer
materials include conventional roofing granules. In the present
invention, colored, infrared-reflective granules, such as disclosed
in U.S. patent application Ser. No. 10/679,898, filed Oct. 6, 2003,
can be mixed with conventional roofing granules. Alternatively,
colored, infrared-reflective granules can be substituted for
conventional roofing granules to enhance the solar-heat reflectance
of the solar-reflective roofing membranes of the present invention.
When mineral particles are employed as the reinforcement material,
it is preferred that the mineral particles have an average particle
size of from about 180 to about 850 .mu.m. Mineral particles may
function as a tie layer for holding the powder coating on the
roofing sheet. For example, the powder coat may adhere better to
the granules than to the bituminous base sheet and the mineral
particles may adhere to both the bituminous base sheet and to the
powder coating. In this sense the tie layer is not necessarily a
reinforcement material in the sense of reinforcing the sheet, but
rather the tie layer tends to enhance the holding power of the
powder coat to the surface of the bituminous sheet.
[0038] In contrast to conventional liquid coating materials, powder
coating materials are typically dry, solid powder materials that
include a polymeric resinous binder with a melting temperature
above ambient temperature and optional pigments, extenders, flow
control agents, and/or other additives. Powder coating materials or
compositions for use in the present invention preferably include
both a polymeric binder and a solar-reflective pigment.
[0039] Suitable powder coating material should have excellent
outdoor durability; a melting temperature for application of
between 66 degrees C.-204 degrees C. (150 degrees F.-400 degrees
F.); and low viscosity upon melting to completely impregnate the
tie-layer in a relatively short period of time. By "low viscosity"
is meant a viscosity of from about 50 centipoise to 3000
centipoise.
[0040] Examples of suitable powder coating compositions include
thermoplastic and thermoset powder coating compositions.
Thermoplastic powder coating compositions are frequently employed
to provide coating of at least about 250 microns. Thermosetting
powder coating compositions are frequently employed to provide
thinner coatings, such as coatings with a thickness of from about
20 to 80 microns. Suitable powder coating polymeric materials
include, but are not limited to, acrylic and related copolymers,
polyesters, polyamides, epoxies, polyolefin and its alloys,
polypropylene, acid containing polyolefins such as polyethylene
acrylic acid or polyethylene methacrylic acid, polyvinyl chloride,
polyester block amide, ethylene chlorotrifluorethylene, or
polyvinylidene fluoride. Examples of thermosetting materials
include epoxy, polyester, and acrylic thermosetting materials.
Examples of thermoplastic materials include polyamide,
polyethylene, polypropylene, polyvinyl chloride, polyester, and
polyvinylidene fluoride thermoplastic materials.
[0041] Preferably, a powder coating composition having good
exterior durability and weatherability characteristics is employed.
Examples of powder coating compositions providing coatings with
good exterior durability include thermoplastic polyester
compositions, thermoplastic polyvinylidene fluoride compositions,
thermosetting polyester compositions such as hydroxyalkylamide
polyesters, thermosetting epoxy resin compositions, thermosetting
epoxy-polyester hybrid coating compositions, thermosetting
polyester-triglycydyl isocyanurate compositions, thermosetting GMA
acrylic compositions, thermosetting acrylic urethane compositions,
and thermosetting polyester urethane compositions.
[0042] Powder coating compositions for use in the present invention
are preferably pigmented with solar heat-reflective pigments or
fillers in order to produce an upper surface coating of high solar
reflectance. Examples of suitable heat-reflective pigments have
been disclosed in the commonly assigned U.S. patent application
Ser. No. 10/679,898, filed Oct. 6, 2003, incorporated herein by
reference.
[0043] In addition, powder coating compositions for use in the
preparative process of the present invention can include other
components, such as curing agents or hardeners, extenders, and
additives such as thixotropes, flow modifiers, and the like.
[0044] Examples of heat- or infrared-reflective pigments that can
be employed include colored infrared-reflective pigments and white
infrared-reflective pigments.
[0045] Upper surface coatings for use in preparing roofing
membranes according to the present invention preferably include at
least one infrared-reflective pigment. The at least one
infrared-reflective pigment can be a colored infrared-reflective
pigment, a white infrared-reflective pigment, or a mixture of two
or more infrared-reflective pigments.
[0046] Preferably, the at least one colored infrared-reflective
pigment is selected from the group consisting of (1)
infrared-reflective pigments comprising a solid solution including
iron oxide and (2) near infrared-reflecting composite pigments.
[0047] Preferably, in the upper surface coating composition, when a
colored infrared-reflective pigment is employed, the colored
infrared-reflective pigment comprises from about 2 percent by
weight to about 40 percent by weight of the coating composition.
More preferably, the colored infrared-reflective pigment comprises
about 5 percent by weight to about 35 percent by weight of the
coating composition.
[0048] Preferably, in the upper surface coating composition, when a
white infrared pigment, such as titanium dioxide, is employed, the
white infrared-reflective pigment comprises from about 2 percent by
weight to about 40 percent by weight of the coating composition.
More preferably, the white infrared-reflective pigment comprises
about 10 percent by weight to about 35 percent by weight of the
coating composition. Still more preferably, the white
infrared-reflective pigment comprises from about 25 percent by
weight to about 35 percent by weight of the coating
composition.
[0049] Preferably, in the upper surface coating composition, when a
combination of a white infrared-reflective pigment, such as
titanium dioxide, and a colored infrared-reflective pigment, is
employed, the combination of the white infrared-reflective pigment
and the colored infrared-reflective pigment comprises form about 2
percent by weight to about 40 percent by weight of the coating
composition. Preferably, the colored infrared-reflective pigment
comprises from about 2 percent by weight to about 10 percent by
weight of the coating composition, and the white
infrared-reflective pigment comprises from about 25 percent by
weight to about 35 percent by weight of the coating
composition.
[0050] Preferably, the upper surface coating composition further
comprises at least one infrared-reflective functional pigment
selected from the group consisting of light-interference platelet
pigments including mica, light-interference platelet pigments
including titanium dioxide, mirrorized silica pigments based upon
metal-doped silica, and alumina.
[0051] When alumina is employed as the at least one
infrared-reflective pigment, the alumina (aluminum oxide)
preferably has a particle size less than #40 mesh (425 microns),
preferably between 0.1 micron and 5 microns, and more preferably
between 0.3 micron and 2 microns. It is preferred that the alumina
includes greater than 90 percent by weight Al.sub.2O.sub.3, and
more preferably, greater than 95% by weight Al.sub.2O.sub.3.
[0052] Optionally, the upper surface coating composition can
include at least one coloring material selected from the group
consisting of granule coloring pigments and UV-stabilized dyes.
[0053] Preferably, the at least one colored, infrared-reflective
pigment comprises a solid solution including iron oxide, such as
disclosed in U.S. Pat. No. 6,174,360, incorporated herein by
reference. The colored infrared-reflective pigment can also
comprise a near infrared-reflecting composite pigment such as
disclosed in U.S. Pat. No. 6,521,038, incorporated herein by
reference. Composite pigments are composed of a near-infrared
non-absorbing colorant of a chromatic or black color and a white
pigment coated with the near infrared-absorbing colorant.
Near-infrared non-absorbing colorants that can be used in the
present invention are organic pigments such as organic pigments
including azo, anthraquinone, phthalocyanine, perinone/perylene,
indigo/thioindigo, dioxazine, quinacridone, isoindolinone,
isoindoline, diketopyrrolopyrrole, azomethine, and azomethine-azo
functional groups. Preferred black organic pigments include organic
pigments having azo, azomethine, and perylene functional
groups.
[0054] Examples of near infrared-reflective pigments available from
the Shepherd Color Company, Cincinnati, Ohio, include Arctic Black
10C909 (chromium green-black), Black 411 (chromium iron oxide),
Brown 12 (zinc iron chromite), Brown 8 (iron titanium brown
spinel), and Yellow 193 (chrome antimony titanium).
[0055] Light-interference platelet pigments are known to give rise
to various optical effects when incorporated in coatings, including
opalescence or pearlescence. Surprisingly, light-interference
platelet pigments have been found to provide or enhance
infrared-reflectance of roofing granules coated with compositions
including such pigments.
[0056] Examples of light-interference platelet pigments that can be
employed in the process of the present invention include pigments
available from Wenzhou Pearlescent Pigments Co., Ltd., No. 9 Small
East District, Wenzhou Economical and Technical Development Zone,
Peoples Republic of China, such as Taizhu TZ5013 (mica, rutile
titanium dioxide and iron oxide, golden color), TZ5012 (mica,
rutile titanium dioxide and iron oxide, golden color), TZ4013 (mica
and iron oxide, wine red color), TZ4012 (mica and iron oxide, red
brown color), TZ4011 (mica and iron oxide, bronze color), TZ2015
(mica and rutile titanium dioxide, interference green color),
TZ2014 (mica and rutile titanium dioxide, interference blue color),
TZ2013 (mica and rutile titanium dioxide, interference violet
color), TZ2012 (mica and rutile titanium dioxide, interference red
color), TZ2011 (mica and rutile titanium dioxide, interference
golden color), TZ1222 (mica and rutile titanium dioxide, silver
white color), TZ1004 (mica and anatase titanium dioxide, silver
white color), TZ4001/600 (mica and iron oxide, bronze appearance),
TZ5003/600 (mica, titanium oxide and iron oxide, gold appearance),
TZ1001/80 (mica and titanium dioxide, off-white appearance),
TZ2001/600 (mica, titanium dioxide, tin oxide, off-white/gold
appearance), TZ2004/600 (mica, titanium dioxide, tin oxide,
off-white/blue appearance), TZ2005/600 (mica, titanium dioxide, tin
oxide, off-white/green appearance), and TZ4002/600 (mica and iron
oxide, bronze appearance).
[0057] Examples of light-interference platelet pigments that can be
employed in the process of the present invention also include
pigments available from Merck KGaA, Darmstadt, Germany, such as
Iriodin.RTM. pearlescent pigment based on mica covered with a thin
layer of titanium dioxide and/or iron oxide; Xirallic.TM. high
chroma crystal effect pigment based upon Al.sub.2O.sub.3 platelets
coated with metal oxides, including Xirallic T 60-10 WNT crystal
silver, Xirallic T 60-20 WNT sunbeam gold, and Xirallic F 60-50 WNT
fireside copper; Color Stream.TM. multi color effect pigments based
on SiO.sub.2 platelets coated with metal oxides, including
ColorStream F 20-00 WNT autumn mystery and Color Stream F 20-07 WNT
viola fantasy; and ultra interference pigments based on TiO.sub.2
and mica.
[0058] Examples of mirrorized silica pigments that can be employed
in the process of the present invention include pigments such as
Chrom Brite.TM. CB4500, available from Bead Brite, 400 Oser Ave,
Suite 600, Hauppauge, N.Y. 11788.
[0059] Upper surface coatings can include at least one
infrared-reflective white pigment. Examples of white pigments that
can be employed in the process of the present invention include
rutile titanium dioxide, anatase titanium dioxide, lithopone, zinc
sulfide, zinc oxide, lead oxide, and void pigments such as
spherical styrene/acrylic beads (Ropaque.RTM. beads, Rohm and Haas
Company), and hollow glass beads having pigmentary size for
increased light scattering. Preferably, the at least one reflective
white pigment is selected from the group consisting of titanium
dioxide, zinc oxide and zinc sulfide.
[0060] It is preferred that the at least one reflective white
pigment comprises from about 10 percent by weight to about 40
percent by weight of the upper surface coating composition. It is
more preferred that the at least one reflective white pigment
comprises from about 20 percent by weight to about 30 percent by
weight of the upper surface coating composition.
[0061] The powder coating compositions of the present invention are
prepared by admixing the solar heat-reflective pigment(s) with the
polymeric resinous binder and other optional additives and then
subsequently extruding and milling the mixture. Alternatively, the
powder coating compositions of the present invention can be
prepared by blending the solar heat-reflective pigment(s) with the
polymeric resinous binder after the binder and other optional
additives have been mixed, extruded and milled. In the alternative,
the powder coating compositions of the present invention can be
prepared by blending the solar heat-reflective pigment(s) with the
polymeric resinous binder after the powder and other optional
additives have been mixed, extruded and milled, and subsequently
subjecting the blend to compressive forces to bond the solar
heat-reflective-pigment(s) to the surface of the milled particles
of the polymeric resinous binder.
[0062] Preferably, the infrared-reflective upper surface coating is
provided in a thickness effective to render the coating opaque to
infrared radiation, such as a coating thickness of at least about
75 microns. However, advantageous properties of the present
invention can be realized with significantly lower coating
thicknesses, such as at a coating thickness of from about 2
micrometers to about 25 micrometers, including at a coating
thickness of about 5 micrometers.
[0063] Optionally, the upper surface coating composition includes
at least one extender pigment such as barium sulfate, wollastonite,
talc, calcium carbonate, or clay.
[0064] In a presently preferred process of the present invention, a
roofing membrane of the present invention is produced by first
laminating a tie-layer onto a hot asphaltic surface of a membrane
substrate to adhere the tie-layer.
[0065] In the case of a fibrous web tie-layer, the lamination to
the asphaltic surface serves to partially impregnate the tie-layer
with material from the substrate layer. It is preferred that the
tie-layer is well adhered to the substrate membrane and the asphalt
coating does not over-saturate the tie-layer in order that the
upper layer can be properly adhered to the tie-layer.
[0066] In another presently preferred process of the present
invention, a roofing membrane of the present invention is produced
by first forming a tie-layer comprised of particulate material on a
hot asphaltic surface of a membrane substrate to adhere the
tie-layer. The particulate material, such as roofing granules, is
deposited on the hot asphaltic surface such that the particulate
material at least partially penetrates into the asphaltic surface
such that a secure mechanical bond is formed when the heated
surface cools. It is preferred that the particles of the tie-layer
be well adhered to the substrate membrane and the asphalt coating
are not too far embedded in the asphaltic surface in order that the
upper layer can be properly adhered to the tie-layer.
[0067] Subsequently, a suitable amount of powder coating material
is deposited onto the upper surface of the tie-layer, followed by
heating to melt or fuse the powder coat in place. This can be
accomplished by direct infrared heat lamps, localized microwave
irradiation, direct application of hot air by passage through a
convection oven or the like, impingement heating, or by heated hot
press rolls, or a combination thereof.
[0068] In general, the method of application depends upon the
chemical and physical characteristics of the polymeric powder
coating composition. In the case of thermosetting polymer systems,
fine-particle sized powder can be applied to the tie-coat surface
by suitable spray equipment or by gravity deposition from a
suitable reservoir or hopper. In the case of thermoplastic
materials, fluidized bed application of the web can be used,
although in general it is preferred to coat only one side of the
bituminous membrane with the powder coating material.
[0069] Conventional powder coating application equipment can be
used to apply the polymeric powder, such as electrostatic spray
equipment employing corona charging or triboelectric charging of
the powder coating particles. Alternatively, an air spray system
that delivers the powder onto the substrate having sufficient heat
to soften the polymeric powder for enabling sticking onto the
surface can be used. Preferably, the application equipment includes
provisions for precision application of the powder coating
composition to the tie layer, and collection and recycling of
excess powder coating composition in order to increase the
efficiency and lower the cost of the process. When electrostatic
spray equipment is employed to deliver the polymeric powder
composition to the tie layer, it is preferred that a suitable
electrical charge be provided on the tie layer or that the tie
layer be electrically grounded so as to increase electrostatic
attraction between the tie layer and the polymeric powder
composition. For example, the tie layer can be formed from a
non-woven material that includes electrically conductive
fibers.
[0070] Preferably, the powder coating is applied to the
intermediate web or substrate in sufficient quantity so as to
completely cover the surface, while forming a thin coating film
after the powder coating is fused. Preferably, the powder coating
material is applied to the intermediate substrate in sufficient
quantity to provide a coating of from about 25 to about 300 microns
in thickness, more preferably from about 50 to about 200 microns,
with a thickness of from about 75 to about 175 microns being
especially preferred.
[0071] The method of fusing and/or curing the powder coating
composition depends on the chemical and physical properties of the
polymeric powder, including the average particle size of the powder
and particle size distribution, and the chemical properties of the
crosslinking agent, if any, present in the material. If the powder
coating composition includes a suitable heat-activated crosslinking
agent, infrared heat can be used. Similarly, if the powder coating
composition includes a UV-activated crosslinking agent or
photoinitiator, ultraviolet radiation can be used to cure the
powder coating composition. In some other instances, a higher
energy actinic radiation source such as an electron beam or gamma
source can be used to impart cure to the powder coating
composition.
[0072] A protective overcoat can also be applied over the powder
coating composition. The solar heat-reflective upper layer in this
case thus comprises an overcoat applied to the powder coating. For
example, in order to help protect the fused powder coating
composition from environmental degradation, an overcoat of a
suitable coating material can be applied to the fused powder
coating composition. Examples of protective overcoat compositions
include fluoropolymer coating, acrylic modified fluoropolymer
emulsion, all-acrylic coating materials, and in particular
solvent-based and water-based acrylic coating materials with good
adhesion to the powder coating composition employed. The overcoat
composition includes a suitable binder, and optional pigment, such
as a suitable infrared-reflective pigment.
[0073] The present invention also provides an improved roof having
high solar heat resistance. The roof comprises a roofing deck, and
a roofing membrane with high solar heat resistance, according to
the present invention, adhered to the roofing deck. Conventional
roofing decks, such as decks formed from plywood, steel, cement, et
al. can be covered with a roofing membrane according to the present
invention. In addition, the present invention provides a method of
constructing a roof having high solar heat resistance. The roof
construction method comprises adhering to a roofing deck a roofing
membrane with high solar heat resistance according to the present
invention.
[0074] The following examples are provided to better disclose and
teach processes and compositions of the present invention. They are
for illustrative purposes only, and it must be acknowledged that
minor variations and changes can be made without materially
affecting the spirit and scope of the invention as recited in the
claims that follow.
Example 1
[0075] A 12.7 cm by 12.7 cm (5 inch.times.5 inch) piece of an
asphalt-based, self-adhering roofing base sheet (WinterGuard,
commercially available from CertainTeed Corporation, Valley Forge,
Pa.) is first heated to about 50 degree C. and then a non-woven
glass fiber mat (1.8 lb. mat available from Johns Manville Corp.)
is laminated onto the self-adhering side of the base sheet using a
12.3 kg (27 lb.) roller. A white powder coat mixture consisting of
6.05 g clear acrylic powder (Ultra Detail from Mark Enterprises,
Anaheim, Calif.) and 2.66 g of TiO.sub.2 white pigment (TiPure
R-102 from DuPont Corp.) is then deposited onto the surface of the
glass fiber mat using a perforated hand shaker until the surface is
covered with a uniform layer of the power coat. The resultant sheet
is then heated under infrared heat lamps to a surface temperature
of 116-121 degrees C. (240-250 degrees F.) until the powder coat is
completely melted and the tie-layer filled to form a uniform white
coating. The resultant sample of roofing membrane has an averaged
solar reflectance of 76.5% as measured by the ASTM C-1549
method.
Example 2
[0076] A 12.7 cm by 12.7 cm (5 inch.times.5 inch) of an
asphalt-based, self-adhering roofing base sheet (WinterGuard,
commercially available from CertainTeed) is first heated to about
50.degree. C. and then a non-woven glass fiber mat (1.81 lb. mat
available from Johns Manville Corp.) is laminated onto the
self-adhering side of the base sheet using a 12.3 kg (27 lb)
roller. A white powder coat of nylon 11 with melting temperature of
about 186 degrees C. (Rilsan 11 polyamide from Atofina Chemicals,
Inc., Philadelphia, Pa.) is then deposited onto the surface of the
glass mat using a perforated hand shaker until the surface is
covered by a uniform layer of the powder coat. The resultant sheet
is then pressed under a hot plate with the top plate set at 193
degrees C. (380 degrees F.) and bottom plate set at room
temperature using pressing load of 3630 kg (8000 lb.), holding time
of 15 seconds, and a gauge bar of 0.24 cm ( 3/16 inch) to prevent
over-press. The resultant sample of roofing membrane has a very
smooth surface finish and an averaged solar reflectance of
77.6%.
[0077] Various modifications can be made in the details of the
various embodiments of the processes, compositions and articles of
the present invention, all within the scope and spirit of the
invention and defined by the appended claims.
* * * * *