U.S. patent application number 11/867118 was filed with the patent office on 2008-08-07 for preform and method of repairing nickel-base superalloys and components repaired thereby.
This patent application is currently assigned to GENERAL ELECTRIC COMPANY. Invention is credited to Sujith Sathian.
Application Number | 20080187777 11/867118 |
Document ID | / |
Family ID | 36571339 |
Filed Date | 2008-08-07 |
United States Patent
Application |
20080187777 |
Kind Code |
A1 |
Sathian; Sujith |
August 7, 2008 |
PREFORM AND METHOD OF REPAIRING NICKEL-BASE SUPERALLOYS AND
COMPONENTS REPAIRED THEREBY
Abstract
A process for repairing a turbine component of a turbomachine,
as well as a sintered preform used in the process and a
high-gamma-prime nickel-base superalloy component repaired thereby.
The sintered preform contains a sintered mixture of powders of a
cobalt-base braze alloy and a cobalt-base wear-resistant alloy. The
braze alloy constitutes at least about 10 up to about 35 weight
percent of the sintered preform and contains a melting point
depressant such as boron. The preform is formed by mixing powders
of the braze and wear-resistant alloys to form a powder mixture,
and then sintering the powder mixture. To use the preform, a
surface portion of the turbine component is removed to expose a
subsurface portion, followed by diffusion bonding of the preform to
the subsurface portion to form a wear-resistant repair material
containing the braze alloy dispersed in a matrix of the
wear-resistant alloy.
Inventors: |
Sathian; Sujith; (Greer,
SC) |
Correspondence
Address: |
HARTMAN & HARTMAN, P.C.
552 EAST 700 NORTH
VALPARAISO
IN
46383
US
|
Assignee: |
GENERAL ELECTRIC COMPANY
Schenectady
NY
|
Family ID: |
36571339 |
Appl. No.: |
11/867118 |
Filed: |
October 4, 2007 |
Related U.S. Patent Documents
|
|
|
|
|
|
Application
Number |
Filing Date |
Patent Number |
|
|
10905143 |
Dec 17, 2004 |
7335427 |
|
|
11867118 |
|
|
|
|
Current U.S.
Class: |
428/680 |
Current CPC
Class: |
Y10T 428/12944 20150115;
C23C 10/52 20130101; Y10T 428/12931 20150115; B22F 1/0003 20130101;
F05D 2230/232 20130101; Y10T 428/12042 20150115; C23C 26/00
20130101; B22F 7/062 20130101; C23C 10/28 20130101; B23P 6/005
20130101; Y10T 428/12861 20150115; F01D 5/005 20130101; Y10T
428/12181 20150115; Y10T 428/12063 20150115; F05D 2230/236
20130101 |
Class at
Publication: |
428/680 |
International
Class: |
B32B 15/01 20060101
B32B015/01 |
Claims
1. A repaired turbine component of a gas turbine, the turbine
component being formed of a nickel-base superalloy having a
composition and gamma-prime content that causes the turbine
component to crack if subjected to gas tungsten arc welding, the
turbine component having a repaired region with a wear-resistant
repair material diffusion bonded thereto, the wear-resistant repair
material consisting of a cobalt-base braze alloy dispersed in a
matrix material of a wear-resistant cobalt-base alloy.
2. The repaired turbine component according to claim 1, wherein the
gamma-prime content of the nickel-base superalloy is about 55 to 59
volume percent.
3. The repaired turbine component according to claim 1, wherein the
wear-resistant repair material has a nominal composition consisting
of, by weight, about 18.5% chromium, about 0.92% nickel, about
0.64% tungsten, about 0.34% tantalum, about 0.23% boron, about
0.12% carbon, about 0.021% titanium about 26.5% molybdenum about
3.2% silicon, and the balance cobalt and incidental impurities.
4. The repaired turbine component according to claim 1, wherein the
wear-resistant repair material has a nominal composition consisting
of, by weight, about 27.6% chromium, about 5.5% nickel, about 18.9%
tungsten, about 0.366% tantalum, about 0.24% boron, about 0.87%
carbon, about 0.023% titanium, about 2.7% iron, about 0.91%
vanadium, and the balance cobalt and incidental impurities.
5. The repaired turbine component according to claim 1, wherein the
nickel-base superalloy consists of, by weight about 9.5 to about 10
chromium, about 7 to about 8 cobalt, about 3.35 to about 3.65
titanium, about 4.1 to about 4.3 aluminum, about 5.75 to about 6.25
tungsten, about 1.30 to about 1.70 molybdenum, about 4.60 to about
5.0 tantalum, about 0.06 to about 0.1 carbon, about 0.0080 to about
0.010 zirconium, about 0.008 to about 0.0105 boron, and the balance
being nickel and incidental impurities.
Description
[0001] This is a division patent application of co-pending U.S.
patent application Ser. No. 10/905,143, filed Dec. 17, 2004.
BACKGROUND OF THE INVENTION
[0002] The present invention generally relates to superalloy
structures subject to excessive wear, such as components, of gas
turbines and other turbomachinery. More particularly, this
invention relates to a method of repairing worn surfaces of a gas
turbine bucket formed of nickel base superalloys, that are prone to
cracking when welded.
[0003] Superalloys are used in the manufacture of components that
must operate at high temperatures, such as buckets, nozzles,
combustors, and transition pieces of industrial gas turbines.
During the operation of such components under strenuous high
temperature conditions, various types of damage or deterioration
can occur. For example wear and cracks tend to develop on the angel
wings of latter stage buckets as a result of rubbing contact
between adjacent nozzles and buckets. Because the cost of
components formed from superalloys is relatively high, it is
typically more desirable to repair these components than to replace
them. For the same reason, new-make components that require repair
due to manufacturing flaws are also preferably repaired instead of
being scrapped.
[0004] Methods for repairing-nickel-base-superalloys have included
gas tungsten arc welding (GTAW) techniques. GTAW is known as a high
heat input process that can produce a heat-affected zone (HAZ) in
the base metal and cracking in the weld metal. A filler is
typically used in GTAW repairs with the choice of filler material
typically being a ductile filler or a filler whose chemistry
matches the base metal. An advantage of using a ductile filler is
the reduced tendency for cracking. An example, of weld repair with
a ductile filler is the use of IN617 and IN625 superalloys to
repair worn angel wings of buckets cast from IN738 and equiaxed
nickel base superalloys such as (GTD-111. A significant advantage
of using a filler whose chemistry matches the base metal is the
ability to more nearly maintain the desired properties of the
superalloy base material. An example of this approach is weld
repairing GTD-111 superalloy buckets with weld wires formed of
GTD-111 or Rene 80 superalloy. To reduce the likelihood of
cracking, the base, metal typically must be preheated to a high
temperature, e.g., about 700 to 930.degree. C. With either
approach, the GTAW process can distort the base metal due to the
build up, of high residual stresses. Components with complex
geometries, such as buckets of gas turbines, are less tolerant of
distortion, to the extent that GTAW may not be a suitable repair
method, particularly if a ductile filler cannot be used.
[0005] More advanced directionally-solidified (DS) nickel-base
superalloys are often not as readily weldable as the GTD-111
superalloy, further increasing the risk of cracking in the weld
metal and within the HAZ of the base metal. A notable example is
the nickel-base-superalloy GTD-444, which is finding use for latter
stage (e.g., second or third stage) buckets in advanced industrial
gas turbines due to its desirable creep resistance properties.
GTD-444 is not readily weldable primarily due to its higher gamma
prime (.gamma.') content (about 55 to 59%), and previous attempts
to weld it have produced unacceptable cracking in the base metal
HAZ and weld metal.
[0006] In view of the above, alternative repair methods are
required to repair high gamma-prime nickel-base superalloys that
will yield crack-free repairs. For repairing the wear-prone
surfaces of such superalloys it is also necessary that the repair
material also exhibit excellent wear properties. One such approach
is termed activated diffusion healing (ADH), examples of which are
disclosed fin commonly-assigned U.S. Pat. Nos. 5,902,421 and
6,530,971. The ADH process employs an alloy powder or mixtures of
powders that will melt at a lower temperature than the superalloy
component to be repaired. If two powders are combined, one of the
powders is formulated to melt at a much lower temperature than the
other powder, such that upon melting, a two-phase mixture is
formed. Vacuum brazing causes the braze powder mixture to melt and
alloy together and with the superalloy of the components being
repaired. A post-braze diffusion heat treatment cycle is then
performed to promote further interdiffusion, which raises the
remelt temperature of the braze mixture.
[0007] Another alternative repair approach disclosed in
commonly-assigned U.S. Pat. No. 6,398,103 to Hasz et al. involves
brazing a wear-resistant foil to a worn surface of a component. The
foil is formed by thermal spraying a wear-resistant material on a
support sheet. Suitable wear-resistant materials include chromium
carbide materials and Co--Mo--Cr--Si alloys, such as the
commercially available TRIBALOY.RTM. T400 and T800 alloys. Still
another approach disclosed in commonly-assigned U.S. patent
application Ser. No. 10/708,205 involves the use of a braze tape
formed by firing a pliable sheet containing powders of a braze
material and a wear resistant alloy in a binder. The tape is
applied to the repair surface, after which a heat treatment is
performed to cause the braze tape to diffusion bond to the repair
surface so as to define a built-up surface, which, can then be
machined to the desired dimensions for the repair.
[0008] With the advent of more highly alloyed superalloys, improved
repair methods and materials are required that are specialized for
the particular surface being repaired, including the superalloy and
the strength and microstructure required by the repair. A notable
example is the need for materials and processes tailored to perform
repairs on components with complex-geometries and formed of
superalloys having high gamma-prime contents, such as GTD-444.
BRIEF SUMMARY OF THE INVENTION
[0009] The present invention provides a process capable of
repairing a surface of a turbine component of a turbomachine, as
well as a sintered preform used in the process and the turbine
component repaired by the process. The process and preform are
particularly well suited for repairing a turbine component formed
of a nickel-base superalloy having a high gamma prime content, a
particular example of which is the GTD-0444 superalloy. The process
of the invention can be carried out at temperatures that are
sufficiently low to minimize distortion, which is
particularly-advantageous when repairing complex geometries, such
as the angel wings of a bucket of an industrial gas turbine.
[0010] The sintered preform employed in the invention consists
essentially of a sintered mixture of powders of a cobalt-base braze
alloy and a cobalt-base wear-resistant alloy. The cobalt-base braze
alloy constitutes at least about 10 up to about 35 weight percent
of the sintered preform and contains a sufficient amount of boron
so that the cobalt-base braze alloy has a melting temperature of
about 200.degree. F. up to about 223.degree. F. (about 1090.degree.
C. up to about 1220.degree. C.).
[0011] A process for using the sintered preform to repair a turbine
component of a gas turbine involves preparing the sintered preform
by mixing powders of the above-noted cobalt-base braze alloy and
cobalt-base wear-resistant alloy to form a powder mixture, of which
at least about 10 up to about 35 weight percent is the cobalt-base
braze alloy, and then sintering the powder mixture to form the
sintered perform. Use of the preform involves removing a surface
portion of the turbine component to expose a subsurface portion of
the turbine component, and then diffusion bonding the sintered
preform to the subsurface portion of the turbine component to form
a wear-resistant repair material consisting of the cobalt-base
braze alloy dispersed in a matrix of the wear-resistant cobalt-base
alloy. Thereafter, machining of the repair material can the
performed to obtain desired final dimensional and surface
properties.
[0012] The resulting repaired turbine-component is, preferably a
nickel-base superalloy having a composition and gamma-prime content
that renders the turbine component prone to cracking if subjected
to gas tungsten arc welding. Such a repaired turbine component is
characterized by having a region with the wear-resistant repair
material diffusion bonded thereto, in which the wear-resistant
repair material consists of the cobalt-base braze alloy dispersed
in a matrix material of the wear-resistant cobalt-base alloy.
[0013] In view of the above it can be seen that the invention
provides a process and, material for repairing an advanced
nickel-base superalloy that is prone to cracking if an attempt were
made to weld repair the superalloy, particularly if using a filler
material with properties similar to the base metal. Instead of
welding, the invention employs a diffusion bonding cycle that voids
the thermal stresses and distortion induced by welding, yet yields
a repaired region whose properties are closer to that of the base
metal than would be possible if a weld repair was, performed with a
ductile filler material.
[0014] Other objects and advantages of this invention will be
better appreciated from the following detailed description.
BRIEF DESCRIPTION OF THE DRAWINGS
[0015] FIG. 1 is a side view of a casting for a third stage bucket
prepared for repair in accordance with a repair process of this
invention.
[0016] FIGS. 2 and 3 represent sintered preforms suitable for
repairing the bucket of FIG. 1.
DETAILED DESCRIPTION OF THE INVENTION
[0017] FIG. 1 represents a third stage turbine bucket 10 of a type
used within the turbine section of an industrial gas turbine. The
bucket 10 is represented as a casting prior to final machining, and
includes an airfoil 12 extending from a root portion 14. Various
high-temperature materials can be used to form the bucket 10,
notable examples of which include the commercially-known GTD-111
and GTD-444 nickel-base superalloys. The present invention is
particularly concerned with components formed of highly alloyed
nickel-base superalloys having high gamma-prime contents, such as
GTD-444, whose nominal composition, in weight percent, is about
9.5-10% chromium, about 7-8% cobalt, about 3.35-3.65% titanium,
about 4.1-4.3% aluminum, about 5.75-6.25% tungsten, about
1.30-1.705 molybdenum, about 4.60-5.0% tantalum, about 0.06-0.1%
carbon, about 0.0080-0.010% zirconium, about 0.008-0.0105% boron,
and the balance being nickel and incidental impurities. The GTD-444
is formulated as a directionally-solidified (DS) alloy, and has a
high, gamma-prime content (about 55 to 59%). The high gamma-prime
content of a superalloy such as GTD-444 renders the superalloy
susceptible to cracking when an attempt is made to perform a weld
repair. The invention also concerns the repair of nickel-base
superalloy components having complex geometries, and are therefore
susceptible to distortion if a weld repair is attempted. When
formed of GTD-444, the bucket 10 depicted in FIG. 1 is an example
of both complicating circumstances, particularly in the region
surrounding the angel wings 16, whose complex geometries can be
easily distorted by welding.
[0018] As known in the art, the angel wings 16 are configured for
sealing with adjacent nozzle stages (not shown) of the gas turbine
in which the bucket 10 is installed. Each wing 16 terminates in a
tip 18 that is subjected to damage from rubbing contact with seals
on the adjacent nozzles. Contact between the tips 18 and nozzle is
characterized by high compression forces and relative movement as a
result of manufacturing, tolerances, differing rates of thermal
expansion, and dynamic-effects during operation of the turbine. As
such, the angel wings 16 and their tips 18 are prone to damage that
necessitates repair. For this purpose, the bucket 10 is shown with
a surface region removed on its root portion 14, exposing, a
subsurface region 20 that encompasses both angel wings 16 on one
side of the bucket 10. As such, FIG. 1 represents a first step of a
process for repairing the bucket 10, by which worn or damaged
surface portions of the wings 16 have been removed.
[0019] FIG. 2 depicts a sintered preform 22 sized and shaped top
replace the base material that was removed to expose the subsurface
region 20 in FIG. 1. A preform 24 configured for repairing only the
tip 18 of an angel wing 16 is depicted in FIG. 3 (not shown to the
same scale as FIGS. 1 and 2). According to the present invention,
the preforms 22 and 24 contain up to about 90 weight percent of a
wear-resistant cobalt-base alloy, and the balance essentially a
cobalt-base braze alloy containing a melting point depressant,
preferably boron, to enable diffusion bonding of the preforms 22
and, 24 to the bucket 10 at temperatures below the
recrystallization temperature of the base superalloy, which is
about 1230.degree. C. for GTD-444. As used herein, the term
cobalt-base specifies an alloy whose predominant constituent is
cobalt. Preferred properties of the braze alloy include at melting
temperature of up to about 1220.degree. C., compatibility with
GTD-444, moderate wear properties hardness and oxidation
resistance, machinability and low tendency for cracking. A
preferred braze alloy is based on the commercially known superalloy
Mar M 509B, and has a nominal composition, by weight of about 24%
chromium, about 10.8% nickel, about 7.5% tungsten, about 4%
tantalum about 0.25% titanium, about 2.7% boron, about 0.6% carbon,
the balance, cobalt and incidental impurities. Suitable
compositional ranges for the constituents of the braze alloy of
this invention are by weight, about 22.00 to about 24.75$%
chromium, about 9.0 to about 11.0% nickel, about 6.5 to about 7.6%
tungsten, about 3.0 to 4.0% tantalum, about 2.60 to 3.16% boron,
about 0.55 to about 0.65% carbon, about 0.15 to 0.30% titanium,
about 0.30 to 0.60% zirconium, up to 1.3%, iron, up to 0.4%
silicon, up to 0.10% manganese, up to 0.015% sulfur, and the
balance cobalt and incidental impurities.
[0020] Because, of the presence of the braze alloy in the preforms
22 and 24, the wear-resistant alloy may have a melting temperature
that exceeds the melting temperature of the braze alloy though less
than the GTD-444 base metal, e.g., above 1090.degree. C. but less
than 1315.degree. C. Preferred propertied of the wear-resistant
alloy include compatibility with, GTD-444, low tendency for
cracking, moderate wear-properties, hardness, and oxidation
resistance, and machinability. Two cobalt alloys based on
commercially-known hardface materials are identified with this
invention as being suitable for use as the wear-resistant alloy. A
first is based on a cobalt-base alloy commercially available from
the Deloro Stellite Company, Inc., under the name TRIBALOY.RTM.
T800. The T800-type alloy contains, by weight, about, 27 to about
30% molybdenum, about 16.5 to about 18.5% chromium, about 3.0 to
about 3.8% silicon, up to 1.5% iron, up to 1.5% nickel, up to 0.15%
oxygen, up to 0.03% sulfur, up to 0.03% phosphorus, and up to 0.08%
carbon the balance cobalt and incidental impurities. A preferred
composition for a T800-type wear-resistant alloy for use in this
invention is, by weight, about 29% molybdenum about 18% chromium,
about 3.5% silicon, about 0.08% carbon, and the balance cobalt and
incidental impurities. The second alloy suitable for use as the
wear-resistant alloy of this invention is based on a cobalt alloy
commercially available from various sources under the name CM 64,
an example of which is available from the Deloro Stellite Company,
Inc., under the name STELLITE.RTM. 694. A suitable composition for
a CM 64-type wear-resistant alloy is, by weight, about 26.0 to
about, 30.0% chromium, about 18.0 to about 21.0% tungsten, about
4.0 to about 6.0% nickel, about 0.75 to about 1.25% vanadium, about
0.7 to about 1.0% carbon, up to 3.0% iron, up to 1.0% manganese, up
to 0.5% molybdenum up to 1.0% silicon up to 0.05% boron, and the
balance cobalt and incidental impurities. A preferred composition
for a CM 64-type alloy is, by weight, about 28% chromium, a bout
19.5% tungsten, about 5% nickel, about 1% vanadium, about 0.85%
carbon, and the balance-cobalt and incidental impurities.
[0021] The preforms 22 and 24 are formed by mixing powders of the
braze and wear-resistant alloys. Suitable particle-size ranges for
the braze, and wear-resistant alloy powders are -325 mesh, size.
The braze alloy is present in the preforms 22 and 24 in an amount
to achieve metallurgical bonding with the wear-resistant alloy and
the base metal of the bucket 10 by boron diffusion. A lower limit
for the braze alloy content in the preforms 22 and 24 is about 10
weight percent in order to limit porosity to an acceptable level
within the preform. In excess of about 35 weight percent of the
preforms 22 and 24, the braze alloy can undesirably reduce the
mechanical and environmental properties of the repair. In a
preferred embodiment, the braze, alloy content of the preform is
about 15 weight percent. Aside from the braze and wear-resistant
alloys, no other constituents are required in the making of the
performs 22 and 24.
[0022] After mixing the powders undergo sintering to yield preforms
22 and 24 with good structural strength and low porosity,
preferably under two volume percent. During sintering, the powders
are compressed to promote fusion and reduce porosity in the
preforms 22 and 24. Based on the preferred preform compositions
containing about fifteen weight percent braze alloy the preforms 22
and 24 (and therefore repairs formed by the preforms 22 and 24)
have the following nominal compositions (excluding incidental
impurities).
TABLE-US-00001 T800-type Preform CM 64-type Preform Cr 18.5% 27.6%
Ni 0.92 5.5 W 0.64 18.9 Ta 0.34 0.36 Ti 0.021 0.023 Mo 26.5 -- Si
3.2 -- Fe -- 2.7 V -- 0.91 B 0.23 0.24 C 0.12 0.87 Co Balance
Balance (about 49.5%) (about 42.8%)
[0023] In an investigation leading up to this inventions
directionally-solidified buckets essentially of the type shown in
FIG. 1 and formed of the GTD-444 superalloy were machined by
electrical-discharge machining (EDM) to a depth of about 0.1 inch
(about 2.5 mm) to remove a surface region of the root section,
essentially as represented in FIG. 1. Following EDM, the exposed
regions were ground to completely remove the recast layer formed
during EDM, and then cleaned with acetone. The exposed regions were
then subjected to grit blasting with a nickel-chromium-iron grit
commercially available under the name NicroBlast.RTM. from Wall
Colmonoy Corp. The grit blasting operation was performed to clean
the exposed regions create compressive stresses at the surface to
enhance brazeability) and deposit a smooth nickel coating that
enhances the wettability of the exposed regions. The
NicroBlast.RTM. powder had a particle size of -60 mesh, though
smaller and larger particle sizes could foreseeably be used.
[0024] For the investigation, two different preform formulations
were evaluated. The formulations contained either about 15 or about
10 weight percent of the braze alloy, with the balance the
above-noted T800-type or CM 64-type wear-resistant alloy,
respectively. More particularly, the braze alloy had a nominal
composition of, by weight, about 24% chromium, about 10.8% nickel,
about 7.5% tungsten, about 4% tantalum, about 0.25% titanium about
2.7% boron, about 0.6% carbon, the balance cobalt and incidental
impurities. The T800-type wear-resistant alloy used had a nominal
composition of by weight, about 29% molybdenum, about 18% chromium,
about 3.5% silicon, about 0.08% carbon, and the balance cobalt and
incidental impurities. The CM 64-type wear-resistant alloy had a
nominal composition of, by weight, about 28% chromium, about 20%
tungsten, about 5% nickel, about 3% iron, about 1% vanadium, about
0.9% carbon, and the balance cobalt and incidental impurities.
[0025] The powders were then mixed and underwent sintering in molds
to produce preforms having thicknesses of about 0.1 inch (about 2.5
mm), and a porosity of less than two volume percent. After cutting
the preforms by water jet and EDM to obtain shapes similar to that
shown in FIG. 2, the preforms were tack-welded to the exposed
surface regions of the buckets.
[0026] The preforms were diffusion bonded to the exposed surface
regions using one of two vacuum heat treatments. The heat treatment
for the preforms containing the T800-type wear resistant alloy
comprised heating at a rate of about 25.degree. F./min (about
14.degree. C./min) to a soak temperature of about 1200.degree. F.
(about 650.degree. C.) held for about thirty minutes heating at a
rate of about 25.degree. F./min to a soak temperature of about
1800.degree. F. (about 980.degree. C.) held for about thirty
minutes heating at a rate of about 35.degree. F./min (about
20.degree. C./min) to a maximum soak temperature of about
2210.degree. F. (about 1210.degree. C.) held for about twenty
minutes, furnace cooling to a temperature of about 2050.degree. F.
(about 1120.degree. C.) and holding for about sixty minutes,
furnace cooling toga temperatures of about 1500.degree. F. (about
815.degree. C.), and finally cooling to room temperature. The heat
treatment cycle for the preforms containing the CM 64-type
wear-resistant alloy was essentially identical except for the use
of a maximum soak temperature of about 2240.degree. F. (about
1227.degree. C.). All repairs were machined following heat
treatment to about the desired dimensional characteristics.
[0027] Metallographic sections of some of the repaired angel wings
showed the repairs to be very homogeneous and the entire bond
interface to be void free, yielding an excellent metallurgical
joint. Other repaired buckets were nondestructively examined by
fluorescent penetrant inspection (FPI) which evidenced that the
repair and the underlying superalloy base metal were free of
cracks.
[0028] In a subsequent investigation, the tips of buckets formed of
GTD-444 were repaired with a preform formulation containing about
15 weight percent of the braze alloy and the balance the T800-type
wear-resistant alloy. Following a braze heat treatment essentially
as described above for the previous preform formulation containing
the T800-type wear-resistant alloy, the blades were crack-free and
the resulting repairs exhibited better wear resistance than the
original GTD-444 material.
[0029] While the invention has been described in terms of
particular embodiments, it is apparent that other forms could be
adopted by one, skilled in the art. Therefore, the scope of the
invention is to be limited only by the following claims.
* * * * *