U.S. patent application number 11/534722 was filed with the patent office on 2008-03-27 for flame-retardant filament and method of manufacture thereof and protective sleeves constructed therefrom.
Invention is credited to Ming-Ming Chen.
Application Number | 20080075983 11/534722 |
Document ID | / |
Family ID | 39242360 |
Filed Date | 2008-03-27 |
United States Patent
Application |
20080075983 |
Kind Code |
A1 |
Chen; Ming-Ming |
March 27, 2008 |
FLAME-RETARDANT FILAMENT AND METHOD OF MANUFACTURE THEREOF AND
PROTECTIVE SLEEVES CONSTRUCTED THEREFROM
Abstract
A continuous halogen-free flame-retardant filament and method of
forming thereof includes providing MC, a phosphorus compound, and
PET, and then, forming a mixture of the MC, phosphorus compound,
and PET. And lastly, extruding the mixture to form the halogen-free
flame-retardant filament. The filament can be braided, woven or
knitted into a variety of fabric constructions, such as, for
example, sleeves for protecting wires.
Inventors: |
Chen; Ming-Ming; (West
Chester, PA) |
Correspondence
Address: |
Robert L. Stearns;Dickinson Wright PLLC
Ste. 2000, 38525 Woodward Avenue
Bloomfield Hills
MI
48304-2970
US
|
Family ID: |
39242360 |
Appl. No.: |
11/534722 |
Filed: |
September 25, 2006 |
Current U.S.
Class: |
428/296.1 ;
19/292; 428/920; 428/921; 442/301; 442/302; 442/304 |
Current CPC
Class: |
D01F 6/62 20130101; Y10T
442/3976 20150401; D01F 6/84 20130101; Y10T 442/3984 20150401; D02G
3/443 20130101; Y10T 428/249936 20150401; D01F 1/07 20130101; Y10T
442/40 20150401 |
Class at
Publication: |
428/920 ;
428/921; 442/304; 442/301; 442/302; 19/292 |
International
Class: |
D01H 5/72 20060101
D01H005/72; D03D 15/00 20060101 D03D015/00; D03D 15/12 20060101
D03D015/12; D04B 21/00 20060101 D04B021/00; D01H 5/74 20060101
D01H005/74; D04B 1/00 20060101 D04B001/00 |
Claims
1. An extruded halogen-free flame-retardant continuous elongate
filament, consisting of: melamine cyanurate; phosphorus compound;
and poly(ethylene terephthalate).
2. The filament of claim 1 wherein said phosphorus compound is
incorporated in a stage of polycondensation of a poly(ethylene
terephthalate) polymerization process to form P-FR-PET.
3. The filament of claim 2 wherein said melamine cyanurate is
compounded with said P-FR-PET.
4. The filament of claim 1 wherein said melamine cyanurate and said
phosphorous compound are incorporated in a stage of
polycondensation of a poly(ethylene terephthalate) polymerization
process to form MC-P-FR-PET.
5. A method of forming a halogen-free flame-retardant continuous
elongate filament, consisting of the steps of: providing melamine
cyanurate; providing a phosphorus compound; providing poly(ethylene
terephthalate); forming a compound of said melamine cyanurate, said
phosphorous compound and said poly(ethylene terephthalate); and
extruding said compound to form said filament.
6. The method of claim 5 wherein the forming a compound step
includes incorporating said phosphorus compound in a stage of
polycondensation of a poly(ethylene terephthalate) polymerization
process to form P-FR-PET.
7. The method of claim 6 wherein the forming a compound step
includes compounding said melamine cyanurate with said
P-FR-PET.
8. The method of claim 5 wherein the forming a compound step
includes incorporating said melamine cyanurate and said phosphorus
compound in a stage of polycondensation of a poly(ethylene
terephthalate) polymerization process to form MC-P-FR-PET.
9. A flexible, fire-resistant fabric sleeve for protecting elongate
members, comprising: at least one yarn, said yarn consisting of:
melamine cyanurate; a phosphorus compound; and poly(ethylene
terephthalate).
10. The fabric sleeve of claim 9 wherein said at least one yarn is
a monofilament.
11. The fabric sleeve of claim 9 wherein said at least one yarn is
a multifilament.
12. The fabric sleeve of claim 9 wherein said phosphorus compound
is incorporated in a stage of polycondensation of a poly(ethylene
terephthalate) polymerization process to form P-FR-PET.
13. The fabric sleeve of claim 12 wherein said melamine cyanurate
is compounded with said P-FR-PET.
14. The fabric sleeve of claim 9 wherein said melamine cyanurate
and said phosphorous compound are incorporated in a stage of
polycondensation of a poly(ethylene terephthalate) polymerization
process to form MC-P-FR-PET.
Description
BACKGROUND OF THE INVENTION
[0001] 1. Technical Field
[0002] This invention relates generally to flame-retardant
filaments, and more particularly to flame-retardant filaments used
as yarn for constructing elongate protective sleeves and to methods
of manufacture of the filaments.
[0003] 2. Related Art
[0004] It is known to manufacture fabrics from flame-retardant
yarns, wherein the fabrics are used to protect items from exposure
to flames. For example, it is known to construct braided, woven or
knitted sleeves from fire-retardant yarns to protect elongate
items, such as wires, contained within the sleeves. One known
compound which has desirable fire-retardant properties is melamine
cyanurate (MC).
[0005] The assignee herein is also the assignee of U.S. Pat. No.
6,828,365, wherein MC is compounded with a fire-retardant
polyphosphonate filler and a polymer selected from the group
consisting of poly(ethylene terephthalate) and poly(ethylene
naphthalate) and then extruded to form a fire-retardant
monofilament. The addition of the polyphosphonate filler to MC
increases the flame-retardancy of the monofilament. Since
polyphosphonate is fire-retardant as well, it provides the
resulting monofilament with additional fire-retardant
properties.
[0006] Current commercially available halogen-free flame-retardant
poly(ethylene terephthalate) (FR-PET) is made by adding an
organo-phosphorous compound in the polycondensation stage of the
PET polymerization process, such as in U.S. Pat. No. 4,086,208,
which is incorporated herein by reference in its entirety.
Unfortunately, the flame-retardant properties of this
phosphorus-containing PET (P-FR-PET) does not meet the most
stringent flame test requirements. In particular, the burn time and
flame spread distance are too long, and it emits flaming drips.
SUMMARY OF THE INVENTION
[0007] An extruded halogen-free flame-retardant filament consists
of melamine cyanurate and phosphorus containing fire-retardant
poly(ethylene terephthalate) (MC-P-FR-PET). The filament can be
braided, woven or knitted into a variety of fabric constructions,
such as, for example, sleeves for protecting wires. The combination
of the MC and P-FR-PET provides the fabric constructed therefrom
with excellent flame-retardant properties while remaining pliable,
and thus, the fabrics can be used in tight quarters around
relatively sharp bends.
[0008] Another aspect of the invention includes a method of forming
a halogen-free flame-retardant filament. The method consists of:
providing MC and P-FR-PET. Then, introducing the MC with the
P-FR-PET to form (MC-P-FR-PET). And lastly, extruding the
(MC-P-FR-PET) to form the halogen-free flame-retardant
filament.
[0009] In one presently preferred construction, the P-FR-PET is
made in a polymerization process, and the MC and P-FR-PET are
compounded to form a homogenous compound, and then extruded to form
a continuous filament. In another presently preferred construction,
the MC can be introduced with an organo-phosphorous compound during
a PET polymerization process to form a polymerized FR-PET with
(MC+phosphorus) composition, and then extruded to form a continuous
filament.
[0010] Another aspect of the invention includes a flexible,
fire-resistant fabric sleeve for protecting elongate members. The
sleeve is constructed at least in part from fire-resistant yarn
consisting of (MC-P-FR-PET).
[0011] Accordingly, a halogen-free flame-retardant filament
constructed according to the invention has excellent
flame-retardant properties, consists of minimal compound
ingredients, is economical in manufacture, is useful in
constructing sleeves, and has a long life in use.
BRIEF DESCRIPTION OF THE DRAWINGS
[0012] These and other features and advantages of the present
invention will become more readily apparent and appreciated when
considered in connection with the following detailed description of
presently preferred embodiments and best mode, appended claims and
accompanying drawings, in which:
[0013] FIG. 1 is a flow diagram for a process according to one
presently preferred embodiment of the invention for manufacturing a
halogen-free fire-retardant filament;
[0014] FIG. 2 is a flow diagram for a process according to another
presently preferred embodiment of the invention for manufacturing a
halogen-free fire-retardant filament and
[0015] FIG. 3 is a schematic perspective view of a sleeve
constructed at least in part from the filament constructed from the
method of FIG. 1.
DETAILED DESCRIPTION OF PRESENTLY PREFERRED EMBODIMENTS
[0016] Referring in more detail to the drawings, FIG. 1 diagrams a
method 100 for manufacturing a halogen-free flame-retardant
filament 102 according to one presently preferred embodiment of the
invention. The resulting halogen-free filament 102 consists of
melamine cyanurate (MC) 104 and phosphorus containing
fire-retardant poly(ethylene terephthalate) (P-FR-PET) 106. The
combination of MC 104 and P-FR-PET 106 provide the filament 102
with excellent fire-retardant properties. As such, the filament 102
is useful in the construction, such as by braiding, weaving or
knitting, of a fire-retardant fabric, wherein the resulting fabric
can be constructed in various forms to provide fire-retardant
protection to components. For example, the fabric is useful in
constructing a fire-retardant sleeve 108 (FIG. 3) for protecting
elongate members, such as wires, from exposure to flames. It should
be recognized that the sleeve 108 can be constructed in any
suitable fashion, such as an open construction, having a
longitudinal access opening, a closed construction, and in a
self-wrapping or wrappable construction, as desired. The sleeves
are widely useful in a broad array of environments and industries
requiring protection for wiring from flame, such as in automotive,
aircraft, railway, marine, and aerospace, for example.
[0017] The method of manufacture of the halogen-free filament 102
starts with steps 110 and 112 of providing MC and P-FR-PET. The MC
104 is preferably provided as commercially available MC, which is
generally available as a fine powder. A MC powder having a article
size of about 2 .mu.m is preferred, with the MC 104 having a
percent-by-weight content of about 5-10 percent relative to the
MC-P-FR-PET compound.
[0018] The P-FR-PET 106 is also commercially available. Preferably,
the phosphorus content is about 3000-8000 ppm in proportion to the
P-FR-PET.
[0019] In manufacture, the MC powder 104 and the polymerized
P-FR-PET 106 are combined in step 114 to form a substantially
homogeneous mixture 116. The mixture 116 of the MC and polymerized
P-FR-PET can be compounded together, such as in a twin screw
extruder, and then extruded into the continuous filament 102.
Accordingly, there are no additional fillers, fibers, or the like
added to the mixture 116, and thus, the finished filament 102
contains only MC 104 and polymerized P-FR-PET 106.
[0020] Otherwise, in another aspect of manufacture, rather than
compounding the MC with the polymerized P-FR-PET, the MC 104 can be
incorporated with an organo-phosphorous compound 118 during a
polycondensation stage 120 in a PET polymerization process to form
a polymerized FR-(MC+phosphorus) PET composition 116, designated
earlier as MC-P-FR-PET. Thereafter, as above, the MC-P-FR-PET
composition can be extruded to form the continuous filament
102.
[0021] Obviously, many modifications and variations of the present
invention are possible in light of the above teachings. It is,
therefore, to be understood that within the scope of the appended
claims, and any other claims allowed which stem from this
application, that the invention may be practiced otherwise than as
specifically described and shown.
* * * * *