U.S. patent application number 10/579124 was filed with the patent office on 2007-11-08 for adhesion-promoting agent for a thermal insulation surface.
Invention is credited to Catherine Hedouin, Daniel Joubert, Roland Reeb.
Application Number | 20070256600 10/579124 |
Document ID | / |
Family ID | 34566272 |
Filed Date | 2007-11-08 |
United States Patent
Application |
20070256600 |
Kind Code |
A1 |
Hedouin; Catherine ; et
al. |
November 8, 2007 |
Adhesion-Promoting Agent for a Thermal Insulation Surface
Abstract
The present invention relates to a novel agent for promoting
adhesion to a heat-insulating surface and in particular to a
polystyrene surface, especially when wet or under the effect of a
large variation in temperature. The invention also relates to the
use of the said agent in a water-insoluble film-forming polymer
composition or in a mineral binder composition for applications in
the construction field and more particularly in external
heat-insulation systems.
Inventors: |
Hedouin; Catherine;
(Gouvieux, FR) ; Joubert; Daniel; (Vineuil Saint
Firmin, FR) ; Reeb; Roland; (Gressy, FR) |
Correspondence
Address: |
HEXION SPECIALTY CHEMICALS, INC.
1600 SMITH STREET, P.O. BOX 4500
HOUSTON
TX
77210-4500
US
|
Family ID: |
34566272 |
Appl. No.: |
10/579124 |
Filed: |
December 1, 2004 |
PCT Filed: |
December 1, 2004 |
PCT NO: |
PCT/FR04/03082 |
371 Date: |
May 2, 2007 |
Current U.S.
Class: |
106/696 ;
524/141; 558/70 |
Current CPC
Class: |
C04B 2111/28 20130101;
C04B 28/02 20130101; C04B 28/02 20130101; C04B 2111/00612 20130101;
C04B 28/02 20130101; C09J 5/02 20130101; Y10T 428/31855 20150401;
C08J 9/365 20130101; C04B 24/26 20130101; C04B 24/26 20130101; C04B
24/26 20130101; C04B 22/16 20130101; C04B 22/16 20130101; C04B
24/08 20130101; C04B 40/0039 20130101; C04B 22/16 20130101; C04B
28/06 20130101; Y10T 428/31551 20150401; C04B 2103/65 20130101;
Y10T 428/31989 20150401; C04B 28/021 20130101; C04B 2103/0057
20130101; C04B 40/0039 20130101; C04B 28/14 20130101 |
Class at
Publication: |
106/696 ;
524/141; 558/070 |
International
Class: |
C09J 5/02 20060101
C09J005/02; C08J 9/36 20060101 C08J009/36 |
Foreign Application Data
Date |
Code |
Application Number |
Dec 1, 2003 |
FR |
0314074 |
Claims
1. An adhesion promoting agent comprising a a phosphate monoester,
diester or triester represented by the formula:
O.dbd.P(OR1)(OR2)(OR3) wherein R1, R2 and R3, may be the same or
different and are a hydrogen atom, a linear, branched or cyclic,
saturated or unsaturated alkyl radical containing from 1 to 22
carbon atoms, optionally substituted with halogen atoms, hydroxyl
groups, ether groups containing between 1 and 12 carbon atoms,
thioether groups, ester groups, amide groups, carboxyl groups,
sulfonic acid groups, carboxylic anhydride groups, carbonyl groups,
an aryl radical containing from 6 to 22 carbon atoms, optionally
substituted with halogen atoms, provided however that at least one
of R1, R2 or R3 not a hydrogen atom.
2. Agent according to claim 1, characterized in that the said
phosphate monoester, diester or triester is a compound of formula
(I) below: O.dbd.P(OR1)(OR2)(OR3) (I) in which: R1, R2 and R3,
which may be identical or different, represent: a hydrogen atom, or
a linear, branched or cyclic, saturated or unsaturated alkyl
radical containing from 1 to 22 carbon atoms, preferably from 2 to
12 carbon atoms and even more preferentially from 2 to 8 carbon
atoms, optionally substituted with halogen atoms, such as fluorine
or chlorine, hydroxyl groups, ether groups containing between 1 and
12 carbon atoms and preferably between 1 and 6 carbon atoms,
thioether groups, ester groups, amide groups, carboxyl groups,
sulfonic acid groups, carboxylic anhydride groups and/or carbonyl
groups, or an aryl radical containing from 6 to 22 carbon atoms and
preferably from 6 to 8 carbon atoms, optionally substituted with
halogen atoms, such as fluorine or chlorine, hydroxyl groups, ether
groups containing between 1 and 12 carbon atoms and preferably
between 1 and 6 carbon atoms, thioether groups, ester groups, amide
groups, carboxyl groups, sulfonic acid groups, carboxylic anhydride
groups and/or carbonyl groups, it being understood that at least
one of the substituents R1, R2 or R3 is other than a hydrogen
atom.
3. The adhesion promoting agent of claim 1 wherein the phosphate
monoester, diester or triester of formula (I) is selected from the
group consisting of tris(2-ethylhexyl)phosphate,
tris(2-butoxyethyl)phosphate, di(2-ethylhexyl)phosphate,
mono(2-ethylhexyl)phosphate, tris(2-isooctyl)phosphate, tricresyl
phosphate, cresyl diphenyl phosphate, trixylyl phosphate, triphenyl
phosphate, tributyl phosphate, triethyl phosphate,
tris(2-chloroethyl)phosphate, and combinations thereof.
4. The adhesion promoting agent of claim 1 wherein the phosphate
monoester, diester or triester is adsorbed onto an inert mineral
support selected from the group consisting of silica, alumina,
silica-alumina, sodium silicoaluminate, calcium silicate, magnesium
silicate, zirconia, magnesium oxide, calcium oxide, cerium oxide
and titanium oxide.
5. A Water-insoluble film-forming polymer composition comprising
the phosphate monoester, diester or triester of claim 1.
6. The Water-insoluble film-forming polymer composition of claim 5
wherein the composition is in the form of an aqueous dispersion
(latex) or is in the form of a redispersible latex powder.
7. The Water-insoluble film-forming polymer composition of claim 6
wherein the phosphate monoester, diester or triester is present in
an amount between 0.02% and 25% by weight relative to the weight of
the latex powder.
8. The Water-insoluble film-forming polymer composition of claim 7
wherein the phosphate monoester, diester or triester is present in
an amount between 1% and 5% by weight relative to the weight of the
latex powder.
9. The Water-insoluble film-forming polymer composition of claim 5
wherein the polymer composition is obtained by polymerization of
monomers selected from the group consisting of vinyl esters of
branched or unbranched, saturated monocarboxylic acids containing
from 1 to 16 carbon atoms, alkyl acrylates and methacrylates, the
alkyl group of which contains from 1 to 10 carbon atoms,
vinylaromatic monomers, wherein the monomers are copolymerized with
each other or with other ethylenically unsaturated monomers.
10. (canceled)
11. A mineral binder composition comprising the phosphate
monoester, diester or triester of claim 1.
12. The composition of claim 11 wherein the mineral binder is a
hydraulic binder selected from the group consisting of cements,
aluminous or blast-furnace type, fly ash, calcined shales and
pozzolans and wherein the amount of phosphate monoester, diester or
triester is between 0.01% and 50% by dry weight of phosphate
monoester, diester or triester relative to the total weight of the
composition.
13. The composition of claim 12 wherein the amount of phosphate
monoester, diester or triester is between 0.02% and 2% by dry
weight of the phosphate monoester, diester or triester relative to
the total weight of the composition.
14. (canceled)
Description
[0001] The present invention relates to a novel agent for promoting
adhesion to a heat-insulating surface and in particular to a
polystyrene surface, especially when wet or under the effect of a
large variation in temperature. The invention also relates to the
use of the said agent in a water-insoluble film-forming polymer
composition or in a mineral binder composition for applications in
the construction field and more particularly in external
heat-insulation systems.
[0002] In general, polystyrene-based materials are increasingly
incorporated in the construction of new buildings, in particular in
Europe.
[0003] For example, covering components made of insulating
material, for instance polystyrene such as extruded or expanded
polystyrene or polyurethane constitute a support material for
laying ceramic tiles in a thin-bed process.
[0004] In addition, building components made of polystyrene
materials are suitable for interrupting thermal bridges, such as
those appearing, for example, where concrete or masonry meet.
[0005] The application of panels of polystyrene-based materials to
building facades, for the purpose of heat insulation, is also
used.
[0006] One common method consists, in the case of heat insulation,
in fixing onto the facade (for example made of masonry, concrete,
mineral rendering, etc.) the back of the polystyrene insulating
panels or another insulating material made of mineral wool using a
mortar or a cement. A mortar is also applied to the front face of
the polystyrene insulating panels or another insulating material
made of mineral wool, as a reinforcing rendering. This serves
especially for the inclusion of fibre reinforcements (for example
reinforcements made of glass fibre, polyester or polypropylene),
which are used to reinforce the mechanical properties of the
external heat-insulating system. Next, a reinforcing rendering is
usually applied again to the glass fibre trellis, for the total
inclusion of the trellis, the surface is evened out and, after
drying, a finish covering is applied, for example a mineral
rendering or a covering based on synthetic resin, such as a
roughcast, or a paint.
[0007] In general, according to the foregoing, there is an
increasing problem of obtaining a permanent adhesive bond between
materials based on insulators and in particular based on
polystyrene, and mineral building materials. In particular, this
adhesion should be satisfactory even under the effect of humidity
or of a large variation in temperature.
[0008] The drawback of the known mineral building materials is that
their adhesion to heat-insulating materials and in particular to
polystyrene-based materials, after consolidation, is
unsatisfactory.
[0009] Document EP 0 698 586 has disclosed the possibility of using
an additive based on aromatic polyether to improve the adhesion of
mineral building materials to polystyrene-based materials. However,
these compounds have the drawback especially of not sufficiently
improving the wet adhesion and of not sufficiently reducing the
water uptake by capillary action.
[0010] One of the aims of the present invention is to provide
mineral building materials that show, after consolidation,
increased adhesion, when wet or under the effect of a large
variation in temperature, to heat-insulating materials and in
particular to polystyrene-based materials.
[0011] This aim and others are achieved by the present invention,
one subject of which is a novel agent for promoting adhesion to a
heat-insulating surface and in particular to a polystyrene surface,
especially when wet or under the effect of a large variation in
temperature, based on a phosphate monoester, diester or triester or
a mixture thereof.
[0012] A subject of the invention is also a water-insoluble
film-forming polymer composition comprising a phosphate monoester,
diester or triester or a mixture thereof.
[0013] A subject of the invention is also the use of a
water-insoluble film-forming polymer composition comprising a
phosphate monoester, diester or triester or a mixture thereof, as
adhesion primer on a heat-insulating support and in particular a
polystyrene-based support.
[0014] A subject of the invention is also a mineral binder
composition comprising a phosphate monoester, diester or triester
or a mixture thereof.
[0015] A subject of the invention is also the use of the mineral
binder composition to increase the adhesion of a heat insulator and
in particular of polystyrene to a support material.
[0016] A subject of the invention is also a process for increasing
the adhesion properties to a heat-insulating support and in
particular a polystyrene support, especially when wet or under the
effect of a large variation in temperature, after consolidation, of
a hydraulic mineral binder composition, characterized in that a
sufficient amount of at least one phosphate monoester, diester or
triester or a mixture thereof is added to the said composition.
[0017] A first subject of the invention is thus a novel agent for
promoting the adhesion to a heat-insulating surface and in
particular a polystyrene surface, especially when wet or under the
effect of a large variation in temperature, based on a phosphate
monoester, diester or triester or a mixture thereof.
[0018] The term "heat-insulating support" especially means
polystyrene, polyurethane and mineral wools such as glass wool or
rock wool. Polystyrene is preferred.
[0019] The phosphate monoesters, diesters or triesters of the
invention may be in particular compounds corresponding to formula
(I) below: O.dbd.P(OR1)(OR2)(OR3) (I) in which: [0020] R1, R2 and
R3, which may be identical or different, represent: [0021] a
hydrogen atom, or [0022] a linear, branched or cyclic, saturated or
unsaturated alkyl radical containing from 1 to 22 carbon atoms,
preferably from 2 to 12 carbon atoms and even more preferentially
from 2 to 8 carbon atoms, optionally substituted with halogen
atoms, such as fluorine or chlorine, hydroxyl groups, ether groups
containing between 1 and 12 carbon atoms and preferably between 1
and 6 carbon atoms, thioether groups, ester groups, amide groups,
carboxyl groups, sulfonic acid groups, carboxylic anhydride groups
and/or carbonyl groups, or [0023] an aryl radical containing from 6
to 22 carbon atoms and preferably from 6 to 8 carbon atoms,
optionally substituted with halogen atoms, such as fluorine or
chlorine, hydroxyl groups, ether groups containing between 1 and 12
carbon atoms and preferably between 1 and 6 carbon atoms, thioether
groups, ester groups, amide groups, carboxyl groups, sulfonic acid
groups, carboxylic anhydride groups and/or carbonyl groups, [0024]
it being understood that at least one of the substituents R1, R2 or
R3 is other than a hydrogen atom.
[0025] Among the phosphate monoester, diester or triester compounds
of formula (I), mention may be made of the following compounds:
[0026] tris(2-ethylhexyl)phosphate, [0027]
tris(2-butoxyethyl)phosphate, [0028] di(2-ethylhexyl)phosphate,
[0029] mono(2-ethylhexyl)phosphate, [0030]
tris(2-isooctyl)phosphate, [0031] tricresyl phosphate, [0032]
cresyl diphenyl phosphate, [0033] trixylyl phosphate [0034]
triphenyl phosphate, [0035] tributyl phosphate, [0036] triethyl
phosphate, [0037] tris(2-chloroethyl)phosphate, or a mixture
thereof.
[0038] The phosphate monoester, diester or triester of the agent
according to the invention may be incorporated in liquid form or in
the form of a solid powder in a water-insoluble film-forming
polymer composition or in a mineral binder composition.
[0039] If the phosphate monoester, diester or triester of the
invention is in liquid form at room temperature, as is the case for
the particular compounds listed above with the exception of
triphenyl phosphate, which is solid at room temperature, it is
possible to adsorb them onto an inert mineral support to obtain a
solid powder.
[0040] The adsorption of the phosphate monoester, diester or
triester may be performed via any conventional process for the
adsorption of compounds onto inorganic mineral supports. Mention
may be made especially of the processes described in documents FR
74 27893 or FR 74 36083.
[0041] One preferred embodiment for preparing the solid phosphate
monoester, diester or triester powder is a process comprising a
step of dry impregnation of a mineral oxide with a sufficient
amount of phosphate monoester, diester or triester.
[0042] The mineral oxide may be chosen from silica, alumina,
silica-alumina, sodium silicoaluminate, calcium silicate, magnesium
silicate, zirconia, magnesium oxide, calcium oxide, cerium oxide
and titanium oxide. The mineral oxide may be partially or totally
hydroxylated or carbonated.
[0043] The mineral oxide should have a large porosity. This means
that its total pore volume should be at least 1 ml/g and preferably
at least 2 ml/g.
[0044] The total pore volume of the mineral oxide is measured via a
mercury porosimetry method using a Micromeritics Autopore III 9420
porosimeter.
[0045] The preparation of each sample is performed as follows: the
sample is predried for 2 hours in an oven at 200.degree. C. The
measurements are then taken according to the procedure described in
the manual supplied by the manufacturer.
[0046] The pore diameters are calculated by means of the Washburn
relationship with a head contact angle equal to 140.degree. and a
gamma surface tension equal to 485 dynes/cm.
[0047] Preferably, the mineral oxide has a working pore volume of
greater than or equal to 0.5 ml/g. The term "working volume" means
the volume of the pores with a diameter of less than 1 micron. This
volume is measured via the same method as the total pore
volume.
[0048] A silica is preferably used as mineral oxide. Even more
preferentially, an amorphous silica is used. This may be a natural
silica or a synthetic silica, for instance silica gels, combustion
silicas or, very preferably, precipitated silicas.
[0049] When the mineral oxide is precipitated silica, it may be,
for example, a Tixosil 38A, Tixosil 38D or Tixosil 365 silica from
the company Rhodia.
[0050] In particular, the precipitated silica may be in the form of
substantially spherical beads, especially with a mean size of at
least 80 microns, for example of at least 150 microns, obtained
using a nozzle sprayer, as described, for example, in document EP
0018866. It may be, for example, the silica known as Microperle.
This form makes it possible to optimize the impregnation capacity
and the flowability of the powder, as described, for example, in
document EP 0 966 207 or EP 0 984 772. It may be, for example, a
Tixosil 38X or Tixosil 68 silica from the company Rhodia.
[0051] This makes it possible especially to obtain a phosphate
monoester, diester or triester powder that flows well and does not
produce dust.
[0052] The precipitated silica may be a highly dispersible silica,
for instance the silicas described in documents EP 0 520 862, WO
95/09127 or WO 95/09128, which, in particular, facilitates its
dispersion in the water-insoluble film-forming polymer composition
or in the mineral binder composition. It may be, for example, a
Z1165 MP or Z1115 MP silica from the company Rhodia.
[0053] The amorphous silica may be a silica with a low water
uptake. The "water uptake" corresponds to the amount of water
incorporated into the sample relative to the dry mass of the
sample, after 24 hours at 20.degree. C. and 70% relative humidity.
The term "low water uptake" means a water uptake of less than 6%
and preferably less than 3%. These may be the precipitated silicas
described in patent application FR 01 16881 (in the name of the
company Rhodia), pyrogenic silicas or silicas that have been
partially dehydroxylated by calcinations or by surface
treatment.
[0054] A subject of the invention is also a water-insoluble
film-forming polymer composition comprising a phosphate monoester,
diester or triester or a mixture thereof.
[0055] This composition may be in the form of an aqueous dispersion
of water-insoluble film-forming polymer (latex) or in the form of a
redispersible latex powder. The term "redispersible latex powder"
means a latex powder that is redispersible in water.
[0056] The process for preparing this composition consists in
mixing a phosphate monoester, diester or triester or a mixture
thereof with a water-insoluble film-forming polymer (latex).
[0057] This mixture of the phosphate monoester, diester or triester
and of the latex may be prepared in the form of a mixture of solid
phosphate monoester, diester or triester powder with a
redispersible latex powder composition.
[0058] It is also possible to introduce the phosphate monoester,
diester or triester into the latex during the polymerization or
after polymerization. The supplemented latex in the form of an
aqueous dispersion may thus be obtained.
[0059] Drying of the aqueous dispersion thus obtained may also be
performed in order to obtain a redispersible latex powder
supplemented with phosphate monoester, diester or triester.
[0060] It is also possible to add the phosphate monoester, diester
or triester in powder form to the spraying tower of the latex, i.e.
at the time of drying of the latex.
[0061] Among all these possible forms of mixtures, the case in
which the phosphate monoester, diester or triester is introduced
into an aqueous dispersion of film-forming polymer (latex) after
polymerization is preferred. The latex may then be dried.
[0062] The amount of phosphate monoester, diester or triester added
to the water-insoluble film-forming polymer should be sufficient to
give the water-insoluble film-forming polymer composition good
properties of adhesion to polystyrene, even when wet.
[0063] The amount of phosphate monoester, diester or triester added
to the water-insoluble film-forming polymer is then generally
between 0.02% and 25% by weight of phosphate monoester, diester or
triester relative to the weight of the dry latex.
[0064] This amount is preferably between 0.5% and 8% by weight of
phosphate monoester, diester or triester relative to the weight of
the dry latex.
[0065] Even more preferentially, this amount is between 1% and 5%
by weight of phosphate monoester, diester or triester relative to
the weight of the dry latex.
[0066] Water-insoluble polymers that are particularly suitable are
homopolymers or copolymers in the form of an aqueous dispersion or
that may be converted into an aqueous dispersion, and can then be
converted into powder by spray-drying.
[0067] The mean particle size of the powder is preferably from 10
to 1000 .mu.m, more preferably from 20 to 700 .mu.m and
particularly from 50 to 500 .mu.m.
[0068] The preferred water-insoluble polymers are obtained by
polymerization of monomers chosen from: [0069] vinyl esters and
more particularly vinyl acetate; [0070] alkyl acrylates and
methacrylates, the alkyl group of which contains from 1 to 10
carbon atoms, for example methyl, ethyl, n-butyl or 2-ethylhexyl
acrylate or methacrylate; [0071] vinylaromatic monomers, in
particular styrene.
[0072] These monomers may be copolymerized together or with other
ethylenically unsaturated monomers, to form homopolymers,
copolymers or terpolymers.
[0073] As non-limiting examples of monomers that are
copolymerizable with vinyl acetate and/or acrylic esters and/or
styrene, mention may be made of ethylene and olefins, for instance
isobutene or (x-olefins containing from 6 to 20 carbon atoms and
preferably from 8 to 14 carbon atoms; vinyl esters of branched or
unbranched saturated monocarboxylic acids containing from 1 to 16
carbon atoms, for instance vinyl propionate, vinyl "Versatate"
(registered brand name for branched C.sub.9-C.sub.11 acid esters)
and in particular for the vinyl neodecanoate known as Veova 10,
vinyl pivalate, vinyl butyrate, vinyl 2-ethylhexylhexanoate or
vinyl laurate; esters of unsaturated monocarboxylic or dicarboxylic
acids containing from 3 to 6 carbon atoms with alkanols containing
1 to 10 carbon atoms, for instance methyl, ethyl, butyl or
ethylhexyl maleate or fumarate; vinylaromatic monomers such as
methylstyrenes and vinyltoluenes; vinyl halides such as vinyl
chloride or vinylidene chloride; diolefins, particularly butadiene;
(meth)allylic esters of (meth)acrylic acid, (meth)allylic esters of
maleic, fumaric, crotonic and itaconic acid monoesters and
diesters, and also alkene derivatives of acrylic and methacrylic
acid amides, such as N-methallylmaleimide.
[0074] It is especially possible to choose at least 2
copolymerizable monomers of different nature to obtain a
terpolymer.
[0075] An example that may be mentioned is a terpolymer of vinyl
acetate/vinyl versatate/dibutyl maleate type.
[0076] It is also possible to add to the monomers that are
copolymerizable with vinyl acetate and/or acrylic esters and/or
styrene at least one other monomer chosen from the following list:
[0077] acrylamide, ethylenically unsaturated carboxylic acids or
diacids, preferably acrylic acid, methacrylic acid or crotonic
acid, ethylenically unsaturated sulfonic acids and salts thereof,
preferably vinylsulfonic acid or
2-acrylamido-2-methylpropanesulfonic (AMPS) acid, or sodium
methallylsulfonate; [0078] crosslinking monomers bearing at least
two ethylenic unsaturations, such as diallyl phthalate, diallyl
maleate, allyl methacrylate, triallyl cyanurate, divinyl adipate or
ethylene glycol dimethacrylate; [0079] monomers with silane
functions such as vinyltrimethoxysilane or
vinyltriethoxysilane.
[0080] These monomers are added in an amount generally of between
0.05% and 10.0% by weight relative to the total weight of the
monomers. These monomers are added during the polymerization.
[0081] Generally, the polymerization of the monomers is performed
in an emulsion polymerization process in the presence of an
emulsifier and/or of a protective colloid, and of a polymerization
initiator.
[0082] The monomers used may be introduced as a mixture or
separately and simultaneously into the reaction medium, either
before the start of the polymerization in one go, or during the
polymerization in successive fractions or continuously.
[0083] The emulsifiers that may be used are anionic, cationic or
nonionic emulsifiers.
[0084] They are generally used in a proportion of from 0.01% to 5%
by weight relative to the total weight of the monomers.
[0085] Emulsifiers generally used include standard anionic agents
represented especially by alkyl sulfates, alkyl sulfonates,
alkylaryl sulfates, alkylaryl sulfonates, aryl sulfates, aryl
sulfonates, sulfosuccinates, alkali metal alkyl phosphates, and
salts of hydrogenated or non-hydrogenated abietic acid.
[0086] The emulsion polymerization initiator is more particularly
represented by hydroperoxides such as hydrogen peroxide, cumene
hydroperoxide, diisopropylbenzene hydroperoxide, para-menthane
hydroperoxide or tert-butyl hydroperoxide, and persulfates such as
sodium persulfate, potassium persulfate or ammonium persulfate. It
is used in an amount generally of between 0.05% and 3% by weight
relative to the total weight of the monomers. These initiators are
optionally combined with a reducing agent, such as sodium
bisulfite, hydrogen sulfite or thiosulfate, sodium
formaldehydesulfoxylate, polyethyleneamines, sugars (dextrose or
saccharose), ascorbic acid or isoascorbic acid, or metal salts. The
amount of reducing agent used usually ranges from 0 to 3% by weight
relative to the total weight of the monomers.
[0087] The reaction temperature, which depends on the initiator
used, is generally between 0 and 100.degree. C. and preferably
between 30 and 90.degree. C.
[0088] A transfer agent may be used in proportions ranging from 0
to 3% by weight relative to the monomer(s), generally chosen from
mercaptans such as N-dodecyl mercaptan, tert-dodecyl mercaptan and
2-mercaptoethanol, allylic derivatives such as allyl alcohol,
cyclohexene, and halogenated hydrocarbons such as chloroform,
bromoform and carbon tetrachloride. It allows the length of the
molecular chains to be regulated. It is added to the reaction
medium either before the polymerization or during
polymerization.
[0089] Protective colloids may also be used, at the start, during
or after polymerization.
[0090] The protective colloids that are particularly suitable are
polyvinyl alcohols and derivatives thereof, for example vinyl
alcohol/vinyl acetate copolymers, modified polyvinyl alcohols
comprising reactive functions such as silanols, mercaptans, amines
and formamides, and comprising hydrophobic comonomers such as
ethylene, vinyl versatate, vinyl 2-ethylhexylhexanoate,
polyvinylpyrrolidones (PVP), polysaccharides, for example starches
(amylose and amylopectin), cellulose, cellulose ethers, for
instance hydroxyethylcellulose, guar, tragacantic acid, dextran,
alginates and carboxymethyl, methyl, hydroxyethyl or hydroxypropyl
derivatives thereof, proteins, for example casein, soybean
proteins, gelatines, synthetic polymers, for example
poly(meth)acrylic acid, poly(meth)acrylamide, polyvinylsulfonic
acids, and water-soluble copolymers thereof, melamine-formaldehyde
sulfonates, naphthalene-formaldehyde sulfonates, styrene/maleic
acid copolymers, and vinyl ether/maleic acid copolymers. Polyvinyl
alcohol is particularly preferred as protective colloid for the
polymerization. A particular protective colloid used is a polyvinyl
alcohol with a degree of polymerization of from 200 to 3500 and a
degree of hydrolysis of from 80 mol % to 99 mol % and preferably
from 86 mol % to 92 mol %.
[0091] The protective colloids are added in proportions of between
0.5% and 15% by weight relative to the total weight of the monomers
and preferably between 2% and 10% by weight relative to the total
weight of the monomers.
[0092] In one particularly preferred embodiment, the latex
composition supplemented 30 with phosphate monoester, diester or
triester in the form of a redispersible powder comprises from 0 to
35% by weight and preferably 3% to 15% by weight of protective
colloid relative to the total weight of the water-insoluble
polymer.
[0093] The protective colloids that are particularly suitable are
the same as those mentioned above.
[0094] The preferred anticaking agents are aluminium silicates,
calcium carbonates, magnesium carbonates or mixtures thereof,
silicas, hydrated alumina, bentonite, talc, or mixtures of dolomite
and talc, or of calcite and talc, kaolin, barium sulfate, titanium
oxide or calcium sulfoaluminate (satin white).
[0095] The particle size of the anticaking agents is preferably
between 0.001 and 0.5 mm.
[0096] The water-insoluble film-forming polymer composition
comprising a phosphate monoester, diester or triester or a mixture
thereof may also comprise a water repellent chosen from fatty acids
or salts thereof such as calcium, magnesium or sodium stearate, or
sodium laurate, and fatty acid esters such as those described in
document WO 01/90023 (MBT).
[0097] Particular water repellents that may be mentioned include
methyl esters of C10-C16 fatty acids (containing from 10 to 16
carbon atoms), for instance those sold under the brand name Estorob
1214 by the company Novance, the methyl ester of erucic acid, the
methyl ester of linoleic acid, the ethylhexyl ester of lauric acid,
the butyl ester of oleic acid, the ethylhexyl ester of oleic acid
or the methyl ester of oleic acid.
[0098] Preferably, the water-insoluble film-forming polymer
composition comprising a phosphate monoester, diester or triester
or a mixture thereof comprises, as particularly advantageous water
repellent, the methyl ester of a C10-C16 fatty acid.
[0099] This water-insoluble film-forming polymer composition
comprising a phosphate monoester, diester or triester or a mixture
thereof especially has the advantage of being able to be used as
such or in combination with other additives, for instance adhesion
primer on a support made of a heat insulator and in particular on a
polystyrene support.
[0100] Thus, a subject of the invention is also the use of the
water-insoluble film-forming polymer composition comprising a
phosphate monoester, diester or triester or a mixture thereof as
adhesion primer on a support made of a heat insulator and in
particular a polystyrene support.
[0101] This water-insoluble film-forming polymer composition
comprising a phosphate monoester, diester or triester or a mixture
thereof also has the advantage of reducing the glass transition
temperature (Tg) and the minimum film-forming temperature (MFFT) of
the non-supplemented water-insoluble film-forming polymer
(latex).
[0102] A subject of the invention is also a mineral binder
composition comprising a phosphate monoester, diester or triester
or a mixture thereof.
[0103] The mineral binders may be aerial binders or hydraulic
binders. The term "aerial binder" means plaster-based binders.
[0104] The hydraulic mineral binders may be chosen from cements,
which may be of Portland, aluminous or blast-fumace type. Other
compounds often added as additives to the cement also have
hydraulic properties, for instance fly ash and calcined shales.
Mention may also be made of pozzolans which react with lime and
form calcium silicates.
[0105] The mineral binders are generally manufactured from natural
materials that are treated at very high temperature to remove the
water and convert the materials into mineral compounds capable of
reacting with water to produce a binder, which, after drying, forms
a compact mass with good mechanical properties.
[0106] The mineral binders may be in the form of grouts, mortars or
concretes; thus, fine or coarser granulates, such as sand or
pebbles, are thus generally added during the puddling with
water.
[0107] The phosphate monoester, diester or triester may be added
directly to the building composition, in an amount that may be
between 0.01% and 50% by dry weight of the phosphate monoester,
diester or triester relative to the total weight of the building
composition.
[0108] Preferably, this amount is between 0.05% and 20% by dry
weight of phosphate monoester, diester or triester relative to the
total weight of the building composition.
[0109] Even more preferentially, this amount is between 0.02% and
2% by dry weight of phosphate monoester, diester or triester
relative to the total weight of the building composition.
[0110] The phosphate monoester, diester or triester may also be
premixed in a sufficient amount with a water-insoluble film-forming
polymer in the form of an aqueous dispersion (latex) or in the form
of a redispersible latex powder before being added to the mineral
binder composition.
[0111] The binder composition thus comprises, besides the said
phosphate monoester, diester or triester, at least one
water-insoluble film-forming polymer.
[0112] The amounts of phosphate monoester, diester or triester or
mixture thereof generally introduced into the water-insoluble
film-forming polymer compositions are the same as those indicated
above.
[0113] The redispersible latex powder supplemented with phosphate
monoester, diester or triester used may be of very varied
nature.
[0114] A latex composition in the form of a redispersible powder
comprising: [0115] at least one water-insoluble polymer, [0116]
from 0 to 35% by weight and in particular from 3% to 15% by weight,
relative to the total weight of the polymer, of at least one
protective colloid, [0117] from 0 to 30% by weight and in
particular from 1% to 12% by weight, relative to the total weight
of the polymer, of an anticaking agent, and [0118] from 0.02% to
25% by weight and in particular from 0.5% to 8% by weight, relative
to the total weight of the polymer, of phosphate monoester, diester
or triester, is particularly preferred.
[0119] The redispersible latex powder supplemented with phosphate
monoester, diester or triester is preferably prepared by
spray-drying the aqueous polymer dispersion. This drying may be
performed in conventional spray-drying systems, using atomization
by means of simple, twin or multiple liquid nozzles or a rotary
disc. The selected product outlet temperature is generally in the
range from 50 to 100.degree. C. and preferably from 60 to
90.degree. C., depending on the system and on the desired glass
transition temperature of the latex and the desired degree of
drying.
[0120] In order to increase the stability on storage and the
flowability of the redispersible latex powder, it is preferable to
introduce an anticaking agent into the spraying tower together with
the aqueous polymer dispersion, which results in a preferable
deposition of the anticaking agent onto the particles of the
dispersion.
[0121] The mineral binder composition thus obtained has, after
consolidation, good properties of adhesion to heat insulators and
in particular to polystyrene, especially when wet or under the
effect of a large variation in temperature.
[0122] It also has good water-repellency properties and a reduction
in water uptake by capillary action.
[0123] Besides the mineral constituents, the mineral binder
compositions may also comprise organic additives, for example
hydrocolloids such as cellulose ethers or guars, plasticizers,
water repellents such as those mentioned previously in the
water-insoluble film-forming polymer compositions, mineral or
organic fibres such as fibres of polypropylene, polyethylene,
polyamide, cellulose or crosslinked polyvinyl alcohol type, or a
mixture thereof.
[0124] The mineral binder composition may also comprise mineral or
organic dyes. This is the case in particular when this mineral
binder composition is used as a finishing coat.
[0125] The mineral binder composition may also comprise any
additive usually used in mineral binder compositions.
[0126] The composition according to the invention, especially the
mineral binder composition according to the invention, may also
comprise a silicone, preferably chosen from polyorganosiloxanes, in
particular polyorganosiloxanes that are liquid at room temperature.
This silicone may be introduced after polymerization, or in the
form of powder.
[0127] A subject of the invention is also a process for increasing
the properties of adhesion to a heat insulator and in particular to
polystyrene, especially when wet or under the effect of a large
variation in temperature, after consolidation, of a mineral binder
composition, characterized in that a sufficient amount of at least
one phosphate monoester, diester or triester or a mixture thereof
is added to the said composition.
[0128] A subject of the present invention is also the use of this
mineral binder composition to increase the adhesion of a heat
insulator and in particular of polystyrene to a support
material.
[0129] The support materials may be composed of concrete, bricks,
cellular concrete, agglomerated concrete (breeze block),
fibrocement, masonry or wall rendering.
[0130] Other advantages of the compositions or processes of the
invention are indicated in the examples that follow, which are
given as non-limiting illustrations.
[0131] The proportions and percentages indicated in the examples
are on a weight basis, unless otherwise indicated.
[0132] The particle sizes (d50) are measured using a Coulter LS 230
laser scattering granulometer.
EXAMPLES
Description of the Tests
1--Test of Adhesion to Polystyrene
[0133] Mortar is spread onto the insulator to a thickness of 3 mm
15 minutes after puddling. After drying the mortar for 28 days (at
23.+-.2.degree. C. and 50.+-.5% RH (relative humidity)), eight
circles 50 mm in diameter are cut out of the mortar down to the
insulator, using a borer. Round metal pellets of appropriate size
are attached to these areas using an araldite adhesive.
[0134] The peel test is performed under the following conditions:
[0135] without additional conditioning (in the dry state), [0136]
after immersing the mortar in water for 2 days and drying for 2
hours (at 23.+-.2.degree. C. and 50.+-.5% RH).
[0137] The mean peel value is based on the results of eight tests.
The individual and mean values are recorded and the results
expressed as MPa.
2--Test of Water Uptake by Capillary Action on Stone
[0138] Three ceramic tiles are prepared for each formulation.
[0139] The rendering (thickness 3 mm) is applied using a trowel to
one face of the ceramic tile. The ceramic tile thus prepared is
conditioned for 28 days (at 23.+-.2.degree. C. and 50.+-.5% RH).
The side faces of the ceramic tile are made waterproof so as to
ensure that only the face covered with the coat of rendering is
subjected to water uptake during the test.
[0140] The face covered with the ceramic tile rendering is placed
in contact with a sponge (a filter paper is placed beforehand
between the ceramic tile and the sponge) placed in a tank
containing water.
[0141] The ceramic tiles are weighed before immersion (reference
weight) and then after 30 minutes, 1 hour, 2 hours, 4 hours, 6
hours and 24 hours. Before the second and the subsequent weighings,
the surface of the ceramic tiles is wiped using an absorbent
paper.
[0142] The calculation is directed towards determining the mean
water uptake per square metre over time.
Example 1
Preparation of a Latex Emulsion Supplemented with a Vinyl
Acetate/Vinyl Neodecanoate Copolymer (Sold under the Brand Name
Veova 10 by the Company Resolution) and with
tris(2-butoxyethyl)phosphate
[0143] A latex composed of a copolymer of vinyl acetate/vinyl
versatate composed of 50% vinyl acetate and 50% vinyl versatate
(Veova 10) by weight is used as control binder. This latex is
synthesized via an emulsion polymerization process using polyvinyl
alcohol with a degree of hydrolysis of about 88% as protective
colloid and potassium persulfate as free-radical initiator.
[0144] The characteristics of this latex: TABLE-US-00001 Dry
extract: .sup. 50.73% pH: 4.7 MFFT: 7.6.degree. C. Tg: 16.degree.
C. Brookefield viscosity at 50 rpm: 2420 mPa s. Granulometry: d50:
2 .mu.m
[0145] Additive: Amgard TBEP (Rhodia)=tris(2-butoxyethyl)phosphate
(CAS=78-51-3)
[0146] Physical form: liquid
Preparation of the Latex Forming the Subject of the Invention
[0147] 801.7 grams of control latex are introduced into a 1-litre
reactor equipped with an anchor-type stirrer. This latex is heated
to a temperature of between 60 and 70.degree. C., and 16.3 grams of
Amgard TBEP are added over a period of about 20 minutes. After the
end of addition of the Amgard TBEP, the mixture is maintained at
this temperature for a further 20 to 30 minutes and is then cooled
to room temperature.
[0148] This latex may then be formulated in its present form or may
be atomized in the presence of an anticaking agent (for example
kaolin or silica) to obtain a water-redispersible powder.
[0149] Characteristics of the Latex Forming the Subject of the
Invention TABLE-US-00002 Content of Amgard TBEP/dry latex: .sup. 4%
Dry extract: 51.91% pH: 4.7 MFFT: 0.degree. C. Tg: 7.degree. C.
Brookfield viscosity at 50 rpm: 2068 mPa s Granulometry: d50: 2
.mu.m
[0150] Composition of the Formulation of the Rendering Used for
Bonding and the Polystyrene-Based Rendering TABLE-US-00003 Grey
cement CPA CEMI 42.5: 600 g Sand HN38 (0.4-4 mm) 1296 g Cellulose
ether Culminal 9101: 1 g Cellulose ether Culminal 9104: 3 g Lime:
40 g Latex emulsion supplemented with Amgard TBEP: 115.6 g Grey
cement CPA CEMI 42.5: 600 g Sand HN38 (0.4-4 mm) 1296 g Cellulose
ether Culminal 9101: 1 g Cellulose ether Culminal 9104: 3 g Lime:
40 g Control latex emulsion: 118.3 g Water/powder ratio = 0.22
[0151] Physicochemical Properties of the Control and Supplemented
Emulsions TABLE-US-00004 TABLE 1 Reference Viscosity Tg MFFT
Control latex 2436 mPa s 16.degree. C. 7.6.degree. C. Control latex
supplemented 2068 mPa s 7.degree. C. .sup. 0.degree. C. with Amgard
TBEP (4%)
[0152] The addition of the phosphate ester is reflected by a
plasticizing effect on the polymer, with a consequent large drop in
its Tg (glass transition temperature) and in its MFFT (minimum
film-forming temperature).
Test of Adhesion to Polystyrene of the Supplemented Control
Latex
[0153] The results of the test of adhesion to polystyrene of the
control latex supplemented with Amgard TBEP are given in Table 2.
TABLE-US-00005 TABLE 2 Adhesion 28 days Adhesion 28 days + 2 days
Reference (N/mm.sup.2) in water (N/mm.sup.2) Control emulsion 0.012
0.045 Control emulsion 0.012 0.063 supplemented with Amgard
TBEP
[0154] The mortar containing the control latex supplemented with
Amgard TBEP has an adhesion to polystyrene (0.065 N/mm.sup.2) after
immersion in water for 2 days and drying for 2 hours (at 23.degree.
C..+-.2.degree. C.) higher than the mortar containing the
non-supplemented control latex (0.045 N/mm.sup.2).
Test of Water Uptake by Capillary Action on Stone of the
Supplemented Control Latex
[0155] The results of the test of water uptake by capillary action
on stone of the control latex supplemented with Amgard TBEP are
presented in Table 3. TABLE-US-00006 TABLE 3 Control emulsion
supplemented Control emulsion with Amgard TBEP Time h.sup.1/2 Water
absorption (kg/m.sup.2) Water absorption (kg/m.sup.2) 0.7 0.31 0.54
1 0.43 0.73 1.41 0.87 1.18 2 5.41 2.46 2.45 9.95 3.52 4.9 18.05
10.37
[0156] The amount of water adsorbed by capillary action measured
after 24 hours is less in the case where the mortar contains the
control latex supplemented with Amgard TBEP (7.1 kg/m.sup.2)
compared with the mortar containing the control latex (18.3
kg/m.sup.2).
Example 2
[0157] Amgard TOF=tris(2-ethylhexyl)phosphate (CAS 1806-54-8) sold
by the company Rhodia.
[0158] Amgard TBEP=tris(2-butoxyethyl)phosphate (CAS 78-51-3) sold
by the company Rhodia.
[0159] Physical form: liquid
Preparation of Latex Powders Forming the Subject of the
Invention
[0160] A latex composed of a vinyl acetate/vinyl versatate
copolymer with a weight composition of 50% vinyl acetate and 50%
vinyl versatate (Veova 10) is used as control binder. This latex is
synthesized via an emulsion polymerization process using polyvinyl
alcohol with a degree of hydrolysis of about 88% as protective
colloid and potassium persulfate as radical initiator. The
characteristics of this latex are: TABLE-US-00007 Dry extract:
50.0% pH: 4.8 MFFT: 7.5.degree. C. Tg: 15.5.degree. C. Brookfield
viscosity at 50 rpm: 3000 mPa s Granulometry: d50: 1.9 .mu.m
[0161] 11 kg of control latex are introduced into a 25-litre
reactor equipped with an anchor-type stirrer. This latex is heated
to a temperature of between 60 and 70.degree. C., and 220 grams of
Amgard TBEP or Amgard TOF are added over a period of about 20
minutes. After the end of addition of the Amgard, the mixture is
maintained at this temperature for a further 20 to 30 minutes and
is then cooled to room temperature.
[0162] The drying of the suspension was performed via a Niro-type
atomization process. The attack air temperature is between 110 and
160.degree. C. and preferably, herein, between 120 and 150.degree.
C., and the outlet temperature is between 50 and 90.degree. C. and
preferably, herein, between 60 and 80.degree. C. The spraying of
the polymer suspension is performed in the presence of mineral or
organic fillers that improve the flowability of the product and
prevent caking. These fillers may be, for example, carbonates,
silicates, silica, double salts (talc or kaolin) or mixtures of
these various fillers. The contents of these mineral fillers range
from 2% to 20% and preferably, herein, between 5% and 15%.
Characteristics of the Latex Powders Forming the Subject of the
Invention
[0163] Control Powder: TABLE-US-00008 % residual humidity: .sup. 1%
Mean content of mineral agent: 9.6% Mean granulometry d50: 74
.mu.m
[0164] Example of Latex Powder Supplemented with Ampard TBEP
TABLE-US-00009 Content of Amgard/dry latex: 4% Latex
characteristics: Dry extracts: 50.8% pH: 4.8 MFFT: 0.degree. C.
Brookfield viscosity at 50 rpm: 3024 mPa s Granulometry: d50: 1.9
.mu.m Powder characteristics: % residual humidity: 1.2% Mean
content of mineral agent: .sup. 12% Mean granulometry d50: 79
.mu.m
[0165] Example of Latex Powder Supplemented with Amgard TOF
TABLE-US-00010 Content of Amgard/dry latex: 4% Latex
characteristics: Dry extract: 51.1% pH: 4.8 MFFT: 0.degree. C.
Brookfield viscosity at 50 rpm: 2968 mPa s Granulometry: d50: 1.9
.mu.m Powder characteristics: % residual humidity: 0.83% Mean
content of mineral agent: .sup. 13% Mean granulometry d50: 62
.mu.m
[0166] Composition of the Formulation of the Rendering Used for the
Bonding Mortar and the Base Rendering on Polystyrene TABLE-US-00011
Grey cement 42.5 R: 600 g Sand HN38 (0.4-4 mm) 1295.7 g Cellulose
ether Culminal 9101: 1 g Cellulose ether Culminal 9104: 3 g Lime:
40 g Latex powder: 60 g Water/powder ratio = 0.22
Results
[0167] Adhesion to Polystyrene TABLE-US-00012 TABLE 4 Adhesion
Adhesion 28 days + 28 days 2 days in water Reference (N/mm.sup.2)
(N/mm.sup.2) Control powder 0.09 0.015 Control powder 0.128 0.035
supplemented with Amgard TBEP Control powder 0.108 0.029
supplemented with Amgard TOF
[0168] The adhesion measured after 28 days and after curing in
water is greater in the case of the mortars containing the control
powders supplemented with Amgard TBEP and Amgard TOF compared with
the mortar containing the non-supplemented control powder.
[0169] Water Uptake by Capillary Action on Stone TABLE-US-00013
TABLE 5 Control powder Control powder supplemented with
supplemented with Control powder Amgard TBEP Amgard TOF water
absorption Water absorption Water absorption Time h.sup.1/2
(kg/m.sup.2) (kg/m.sup.2) (kg/m.sup.2) 0.7 1.19 0.88 0.26 1 2.31
1.59 0.42 1.41 4.04 2.93 0.80 2 9.62 5.78 1.26 2.45 13.02 8.04 1.66
4.9 16.45 14.22 8.17
[0170] The amounts of water absorbed are less in the case of the
mortars containing the control powders supplemented with Amgard
TBEP and Amgard TOF compared with the mortar containing the
non-supplemented control powder.
Example 3 (Emulsion of Terpo+Additives)
[0171] Estorob 1214: methyl ester of C10-C16 acid (CAS=66762-40-7)
sold by the company Novance
[0172] Montasolve CLP: cresol propoxylated with about 6 units of
propylene oxide (CAS=9064-13-5) sold by the company SEPPIC
Preparation of the Latex Forming the Subject of the Invention
[0173] A latex composed of a copolymer of vinyl acetate/vinyl
versatate and dibutyl maleate having a weight composition of 50%
vinyl acetate, 50% vinyl versatate (Veova 10) and 25% dibutyl
maleate is used as control binder. This latex is synthesized via an
emulsion polymerization process using polyvinyl alcohol with a
degree of hydrolysis of about 88% as protective colloid and
potassium persulfate as free-radical initiator.
[0174] The characteristics of this latex are: TABLE-US-00014 Dry
extract: 50.73% pH: 4.7 MFFT: 5.degree. C. Tg: 16.degree. C.
Brookfield viscosity at 50 rpm: 2420 mPa s Granulometry: d50: 2
.mu.m
Characteristics of the Latex Forming the Subject of the
Invention
[0175] Example of Terpo Control Latex TABLE-US-00015 Dry extract:
50.73% pH: 4.7 MFFT: 5.degree. C. Brookfield viscosity at 50 rpm:
2420 mPa s Granulometry: d50: 2 .mu.m
[0176] Example of Control Latex Supplemented with Amgard TBEP
TABLE-US-00016 Content of Amgard/dry latex: 4% Dry extract: 52.0%
pH: 4.8 MFFT: 0.degree. C. Brookfield viscosity at 50 rpm: 1320 mPa
s Granulometry: d50: 2 .mu.m
Comparative Example
Control Latex Supplemented with Propoxylated Cresol (Montasolve
CLP)
[0177] TABLE-US-00017 Content of propoxylated cresol/dry latex: 4%
Dry extract: 51.9% pH: 4.8 MFFT: 0.degree. C. Brookfield viscosity
at 50 rpm: 1390 mPa s Granulometry: d50: 2 .mu.m
[0178] Example of Control Latex Supplemented with Amgard TBEP and
Estorob 1214
[0179] Estorob 1214: CAS=66762-40-7 sold by the company Novance
TABLE-US-00018 Content of Amgard/dry latex: 2% Content of Estorob
1214: 2% Dry extract: 51.9% pH: 4.8 MFFT: 0.degree. C. Brookfield
viscosity at 50 rpm: 1216 mPa s Granulometry: d50: 2 .mu.m
Composition of the Rendering Formulation used for the Bonding
Mortar and the Base Rendering on the Polystyrene
[0180] Example of Control Latex TABLE-US-00019 Grey cement 42.5 R:
600 g Sand HN38 (0.4-4 mm) 1295.7 g Cellulose ether Culminal 9101:
1 g Cellulose ether Culminal 9104: 3 g Lime: 40 g Emulsion of
control latex: 118.3 g Water/powder ratio = 0.22
[0181] Example of Control Latex Supplemented with Amgard TBEP
TABLE-US-00020 Grey cement 42.5 R: 600 g Sand HN38 (0.4-4 mm)
1295.7 g Cellulose ether Culminal 9101: 1 g Cellulose ether
Culminal 9104: 3 g Lime: 40 g Emulsion of latex supplemented with
Amgard: 116.3 g Water/powder ratio = 0.22
Comparative Example
Control Latex Supplemented with Propoxylated Cresol (Montasolve
CLP)
[0182] TABLE-US-00021 Grey cement 42.5 R: 600 g Sand HN38 (0.4-4
mm) 1295.7 g Cellulose ether Culminal 9101: 1 g Cellulose ether
Culminal 9104: 3 g Lime: 40 g Emulsion of latex supplemented with
propoxylated 116.3 g cresol: Water/powder ratio = 0.22
[0183] Example of Control Latex Supplemented with Ampard TBEP and
Estorob 1214 TABLE-US-00022 Grey cement 42.5 R: 600 g Sand HN38
(0.4-4 mm) 1295.7 g Cellulose ether Culminal 9101: 1 g Cellulose
ether Culminal 9104: 3 g Lime: 40 g Emulsion of latex supplemented
with Amgard TBEP and 116 g Estorob 1214: Water/powder ratio -
0.22
Results
[0184] Adhesion to Polystyrene TABLE-US-00023 TABLE 6 Adhesion 28
days Adhesion 28 days + 2 Reference (N/mm.sup.2) days in water
(N/mm.sup.2) Control emulsion 0.061 0.006 Control emulsion 0.104
0.027 supplemented with propoxylated cresol (Montasolve CLP),
comparative example Control emulsion 0.132 0.052 supplemented with
Amgard TBEP Control emulsion 0.113 0.034 supplemented with Amgard
TBEP and Estorob 1214
[0185] The adhesion to polystyrene measured after 28 days and
curing in water in the case of the mortars containing the control
emulsion and the control emulsion supplemented with propoxylated
cresol is less than that measured in the case of the mortars
containing the control emulsion supplemented with Amgard TBEP and
the mixture Amgard TBEP plus Estorob 1214.
[0186] Water Uptake by Capillary Action on Stone TABLE-US-00024
TABLE 7 Control emulsion Control emulsion Control emulsion
supplemented with supplemented with supplemented with Amgard TBEP
and Control emulsion propoxylated cresol Amgard TBEP Estorob 1214
Water absorption Water absorption Water absorption Water absorption
Time h.sup.1/2 (kg/m.sup.2) (kg/m.sup.2) (kg/m.sup.2) (kg/m.sup.2)
0.7 1.92 0.40 0.58 0.15 1 3.44 0.55 0.76 0.21 1.41 6.56 1.17 1.32
0.29 2 11.71 3.89 2.92 0.42 2.45 14.60 7.08 4.57 0.58 4.9 16.78
15.47 12.70 2.46
[0187] The amounts of water absorbed are less in the case of the
mortar containing the control emulsion supplemented with the
mixture of Amgard TBEP and Estorob 1214.
Example 4 (Control/BEHPA Powder Mixture)
[0188] BEHPA: bis(2-ethylhexyl)phosphoric acid (CAS=298-07-7) sold
by the company Rhodia
Preparation of the Mixture
[0189] BEHPA (0.5% by weight/latex powder) is premixed with the
latex powder before introduction into the mixture containing the
various fillers.
[0190] Composition of the Rendering Formulation Used for the
Bonding Mortar and the Base Rendering on Polystyrene TABLE-US-00025
Grey cement 42.5 R: 600 g Sand HN38 (0.4-4 mm) 1295.4 g Cellulose
ether Culminal 9101: 1 g Cellulose ether Culminal 9104: 3 g Lime:
40 g Latex powder: 60 g BEHPA: 0.3 g Water/powder ratio = 0.22
Results
[0191] Adhesion to Polystyrene TABLE-US-00026 TABLE 8 Adhesion 28
days Adhesion 28 days + 2 Reference (N/mm.sup.2) days in water
(N/mm.sup.2) Control powder 0.127 0.014 Control powder mixed with
0.143 0.041 BEHPA
[0192] The adhesion to polystyrene measured after 28 days and after
curing in water is greater in the case of the mortar containing the
control powder mixed with BEHPA compared with the non-supplemented
control powder.
[0193] Water Uptake by Capillary Action on Stone TABLE-US-00027
TABLE 9 Control powder Control powder mixed Water absorption with
BEHPA Time h.sup.1/2 (kg/m.sup.2) Water absorption (kg/m.sup.2) 0.7
5.35 1.71 1 7.52 2.81 1.41 12.31 7.14 2 17.78 10.92 2.45 18.03
13.95 4.9 18.44 17.61
[0194] The amount of water absorbed is less in the case of the
mortar containing the control powder mixed with BEHPA compared with
the mortar containing the non-supplemented control powder.
* * * * *