U.S. patent application number 11/541678 was filed with the patent office on 2007-04-19 for oxidation process in fluidised bed reactor.
This patent application is currently assigned to BP Chemicals Limited. Invention is credited to Michele Fiorentino, David Newton, George Fredrick Salem, Bruce Leo Williams.
Application Number | 20070088175 11/541678 |
Document ID | / |
Family ID | 23309662 |
Filed Date | 2007-04-19 |
United States Patent
Application |
20070088175 |
Kind Code |
A1 |
Fiorentino; Michele ; et
al. |
April 19, 2007 |
Oxidation process in fluidised bed reactor
Abstract
A process for reacting in a fluid bed reactor at least one
oxidisable reactant with molecular oxygen in the presence of a
catalytically active fluidised bed of solid particles. In the
process a molecular oxygen-containing gas having an oxygen
concentration greater than that of air is introduced into the
fluidised bed whilst the fluidised bed is maintained in a turbulent
regime. The process is suitable for oxidation, ammoxidation and
carboxylation processes, including the production of maleic
anhydride, acrylonitrile, ethylene, acetic acid and vinyl
acetate.
Inventors: |
Fiorentino; Michele; (Aix en
Provence, FR) ; Newton; David; (Farnham, GB) ;
Salem; George Fredrick; (Aurora, IL) ; Williams;
Bruce Leo; (Brough, GB) |
Correspondence
Address: |
NIXON & VANDERHYE, PC
901 NORTH GLEBE ROAD, 11TH FLOOR
ARLINGTON
VA
22203
US
|
Assignee: |
BP Chemicals Limited
London
GB
|
Family ID: |
23309662 |
Appl. No.: |
11/541678 |
Filed: |
October 3, 2006 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
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11239137 |
Sep 30, 2005 |
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11541678 |
Oct 3, 2006 |
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10303769 |
Nov 26, 2002 |
7145033 |
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11239137 |
Sep 30, 2005 |
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60334970 |
Dec 4, 2001 |
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Current U.S.
Class: |
560/243 ;
562/549 |
Current CPC
Class: |
Y02P 20/582 20151101;
C07C 51/25 20130101; C07C 253/24 20130101; C07C 67/055 20130101;
C07C 51/215 20130101; Y02P 20/52 20151101; C07C 51/215 20130101;
C07C 53/08 20130101; C07C 51/25 20130101; C07C 53/08 20130101; C07C
67/055 20130101; C07C 69/01 20130101; C07C 67/055 20130101; C07C
69/15 20130101; C07C 253/24 20130101; C07C 255/08 20130101 |
Class at
Publication: |
560/243 ;
562/549 |
International
Class: |
C07C 67/05 20060101
C07C067/05; C07C 51/16 20060101 C07C051/16 |
Claims
1. A process for reacting in a fluid bed reactor, at least one
oxidisable reactant with molecular oxygen in the presence of a
catalytically active fluidised bed of solid particles in which
process a molecular oxygen-containing gas having an oxygen
concentration greater than that of air is introduced into said
fluidised bed whilst said fluidised bed is maintained in a
turbulent regime.
2. A process according to claim 1 wherein the turbulent regime has
the ratio of transition velocity (U.sub.k) : terminal velocity
(U.sub.t) in the range 0.1:1 to 25:1.
3. A process according to claim 1 or claim 2 wherein the solid
particles have a particle diameter in the range 20 to 300
microns.
4. A process according to claim 3 wherein the particle diameter
size distribution is at least 20 microns.
5. A process according to claim 1 or claim 2 wherein the fluidised
bed comprises solid particles having sizes according to one or more
of the following independent criteria: (i) at least 65% of the
particles have particle diameters in the range 20-120 microns; (ii)
less than 15% of the particles have a particle diameter less than
45 microns; and (iii) less than 5% of the particles have a particle
diameter greater than 105 microns.
6. A process according to claim 1 or claim 2 wherein the
concentration of oxygen in the molecular oxygen-containing gas is
in the range 50 to 100% by volume.
7. A process according to claim 1 or claim 2 wherein the at least
one oxidisable reactant is introduced into the fluidised bed as a
gas and/or liquid through one or more inlets.
8. A process according to claim 7 wherein the at least one
oxidisable reactant is introduced into the fluidised bed as a gas
and is a component of the fluidising gas.
9. A process according to claim 7 wherein the oxidisable reactant
is ethylene.
10. A process according to claim 8 wherein the oxidisable reactant
is ethylene.
11. A process according to claim 1 or claim 2 wherein the fluidised
bed has a particle density of at least 0.6 g/cm.sup.3.
12. A process according to claim 1 or claim 2 wherein the fluidised
bed has a settled bed density of at least 0.4 g/cm.sup.3.
13. A process according to claim 1 or claim 2 wherein the fluidised
bed is catalytically active for any one of oxidation, ammoxidation
and carboxylation processes.
14. A process according to claim 13 wherein the fluidised bed is
catalytically active for the ammoxidation of hydrocarbons by
reaction with molecular oxygen and ammonia.
15. A process according to claim 13 wherein the fluidised bed is
catalytically active for the oxidation of hydrocarbons by reaction
with molecular oxygen.
16. A process according to claim 15 wherein the hydrocarbon is
ethane and the ethane is reacted with molecular oxygen to produce
ethylene and/or acetic acid.
17. A process according to claim 15 wherein the hydrocarbon is
ethylene and the ethylene is reacted with molecular oxygen to
produce acetic acid.
18. A process according to claim 15 wherein the hydrocarbon is a
mixture of ethane and ethylene and the mixture is reacted with
molecular oxygen to produce acetic acid and optionally
ethylene.
19. A process according to claim 13 wherein the fluidised bed is
catalytically active for the carboxylation of alkenes to produce
unsaturated esters by reaction of a carboxylic acid, an olefin and
molecular oxygen.
20. A process according to claim 19 wherein the alkene is ethylene,
the carboxylic acid is acetic acid and the unsaturated ester is
vinyl acetate.
21. A process according to any one of claims 1 to 12 and claims 14
to 17 wherein the at least one oxidisable reactant is selected from
at least one of ethane and ethylene, the molecular-oxygen
containing gas is oxygen and the at least one of ethane and
ethylene are reacted with the oxygen to produce acetic acid and the
total linear gas flow through the fluidised bed is up to 50
cm/s.
22. A process according to claim 1 or claim 2 wherein the
oxidisable reactants are ethylene and acetic acid, the
molecular-oxygen containing gas is oxygen and the ethylene and
acetic acid are reacted with the oxygen to produce vinyl acetate
and the total linear gas flow through the fluidised bed is up to 30
cm/s.
23. A process for the production of vinyl acetate by the reaction
of ethylene and acetic acid with molecular oxygen in a fluid bed
reactor in the presence of a catalytically active fluidised bed of
solid particles having a particle diameter in the range 20 to 300
microns and having a particle diameter size distribution of at
least 20 microns, and in which process a molecular
oxygen-containing gas having an oxygen concentration greater than
that of air is introduced into the fluidised bed, and the fluidised
bed is maintained in a turbulent regime by using solid particles
having a particle density of at least 0.6 g/cm.sup.3 and a settled
bed density of at least 0.4 g/cm.sup.3 and by operating at a
pressure in the fluid bed reactor of at least 4 bara with a total
linear gas flow through the fluidised bed of from 2 to 30 cm/s
inclusive.
24. A process according to claim 23 wherein the total linear gas
flow through the fluidised bed is from 2 to 25 cm/s inclusive.
25. A process according to claim 23 or claim 24 wherein the solid
particles have a particle density in the range 1.1 to 1.5
g/cm.sup.3.
26. A process according to claim 23 or claim 24 wherein the solid
particles comprise a Group VIII metal, a catalyst promoter and an
optional co-promoter.
27. A process according to claim 26 wherein the Group VIII metal is
palladium and the catalyst promoter is selected from gold, copper,
cerium and mixtures thereof.
28. A process for the reaction of molecular oxygen with (a) ethane
to produce ethylene and/or acetic acid, (b) ethylene to produce
acetic acid or (c) mixtures of ethane and ethylene to produce
acetic acid, optionally with ethylene, in a fluid bed reactor in
the presence of a catalytically active fluidised bed of solid
particles having a particle diameter in the range 20 to 300 microns
and having a particle diameter size distribution of at least 20
microns, and in which process a molecular oxygen-containing gas
having an oxygen concentration greater than that of air is
introduced into the fluidised bed, and the fluidised bed is
maintained in a turbulent regime by using solid particles having a
particle density of at least 0.6 g/cm.sup.3 and a settled bed
density of at least 0.4 g/cm.sup.3 and by operating at a pressure
in the fluid bed reactor of at least 4 bara with a total linear gas
flow through the fluidised bed of from 2 to 35 cm/s, inclusive.
29. A process according to claim 28 wherein the solid particles
have a particle density of 1.25 to 3.5 g/cm.sup.3.
30. A process according to claim 28 or claim 29 wherein the solid
particles are of a composition comprising in combination with
oxygen the elements:
Mo.sub.a.W.sub.b.Ag.sub.c.Ir.sub.d.X.sub.e.Y.sub.f wherein X is the
elements Nb and V; Y is one or more elements selected from the
group consisting of: Cr, Mn, Ta, Ti, B, Al, Ga, In, Pt, Zn, Cd, Bi,
Ce, Co, Rh, Cu, Au, Fe, Ru, Os, K, Rb, Cs, Mg, Ca, Sr, Ba, Zr, Hf,
Ni, P, Pb, Sb, Si, Sn, Ti, U, Re and Pd; a, b, c, d, e and f
represent the gram atom ratios of the elements such that
0<a.ltoreq.1, 0.ltoreq.b<1 and a+b=1; 0<(c+d).ltoreq.0.1;
0<e.ltoreq.2; and 0<f.ltoreq.2.
31. A process according to claim 28 or claim 29 wherein the solid
particles are of a composition comprising in combination with
oxygen the elements: molybdenum, vanadium, niobium and gold in the
absence of palladium according to the empirical formula:
Mo.sub.aW.sub.bAu.sub.cV.sub.dNb.sub.eY.sub.f wherein Y is one or
more elements selected from the group consisting of: Cr, Mn, Ta,
Ti, B, Al, Ga, In, Pt, Zn, Cd, Bi, Ce, Co, Rh, Ir, Cu, Ag, Fe, Ru,
Os, K, Rb, Cs, Mg, Ca, Sr, Ba, Zr, Hf, Ni, P, Pb, Sb, Si, Sn, Ti,
U, Re, Te, and La; a, b, c, d, e and f represent the gram atom
ratios of the elements such that: 0<a.ltoreq.1;
0.ltoreq.b.ltoreq.1 and a+b=1; 10.sup.-5<c.ltoreq.0.02;
0<d.ltoreq.21 0<e.ltoreq.1; and 0<f.ltoreq.2.
32. A process according to claim 23 or claim 24 or claim 28 or
claim 29 wherein the fluidised bed of solid particles has a
particle diameter size distribution of at least 50 microns.
33. A process according to claim 23 or claim 24 or claim 28 or
claim 29 wherein the fluidised bed comprises catalyst particles
which have a particle size distribution in which (i) at least 65%
of the particles have particle diameters in the range 20-120
microns, (ii) less than 15% of the particles have a particle
diameter of less than 45 microns and (iii) less than 5% of the
particles have a particle diameter of greater than 105 microns.
34. A process according to claim 1 or claim 2 or claim 23 or claim
24 or claim 28 or claim 29 wherein the solid particles comprise a
support.
35. A process according to claim 34 wherein the support is selected
from silica, alumina, silica/alumina, titania, silica/titania,
zirconia and mixtures thereof.
36. A process according to claim 1 or claim 2 or claim 23 or claim
24 or claim 28 or claim 29 wherein the particle density of the
solid particles is modified by the use of a densifier during the
preparation of the particles.
37. A process according to claim 36 wherein the densifier is used
during preparation of the support.
38. A process according to claim 37 wherein the densifier is an
inert oxide.
39. A process according to claim 38 wherein the inert oxide is tin
oxide.
40. A process according to claim 36 wherein the particle density is
modified by substitution of at least one metal of the solid
particles by at least one metal having a higher atomic weight.
41. A process according to claim 40 wherein the at least one
substituting metal is chemically equivalent to the at least one
substituted metal.
42. A process according to claim 40 wherein the solid particles
comprise at least one of Mo, V and Nb, and the particle density of
the particles is modified by substituting at least one of Mo, V, Nb
by at least one of Sn, Te, La, Ta, W, Re, Pb, Bi, Ce, Pr, Gd and
Yb.
43. A process according to claim 1 or claim 2 or claim 23 or claim
24 or claim 28 or claim 29 wherein the particle density of the
solid particles is modified by the use of a fluidising gas.
44. A process according to claim 43 wherein the fluidising gas
comprises ethylene.
45. A process according to claim 44 wherein the concentration of
ethylene in the fluidising gas is at least 30 mol % by volume.
46. A process according to claim 45 wherein the concentration of
ethylene is at least 30 mol % to 85 mol %.
Description
CROSS-REFERENCES TO RELATED APPLICATIONS
[0001] This application is a continuation of application Ser. No.
11/239,137, filed Sep. 30, 2005, which is a divisional of
application Ser. No. 10/303,769, filed Nov. 26, 2002, the entire
content of which is hereby incorporated by reference in this
application.
OXIDATION PROCESS IN FLUIDISED BED REACTOR
[0002] The present invention relates to a process for reacting at
least one oxidisable reactant with molecular oxygen and in
particular to reaction in a fluid bed reactor.
BACKGROUND OF THE INVENTION
[0003] Reactions of molecular oxygen with oxidisable reactants in
the presence of fluidised beds of catalyst are known. For example,
the acetoxylation of ethylene to produce vinyl acetate by reaction
of acetic acid, ethylene and an oxygen-containing gas in a fluid
bed reactor is known from EP-A-0672453, EP-A-0685449 and
EP-A-0847982. The reaction of oxygen with ethane to produce acetic
acid in a fluid bed reactor is known from EP-A-0546677.
[0004] EP-A-0685449 discloses a process for manufacturing vinyl
acetate in a fluid bed reactor comprising feeding ethylene and
acetic acid into the fluid bed reactor through one or more inlets,
feeding an oxygen-containing gas into the fluid bed reactor through
at least one further inlet, co-joining the oxygen-containing gas,
ethylene and acetic acid in the fluid bed reactor while in contact
with a fluid bed catalyst material to enable the ethylene, acetic
acid and oxygen to react to produce vinyl acetate and recovering
the vinyl acetate from the fluid bed reactor. According to
EP-A-0685449, the oxygen may be added in pure form or as an
admixture with inert gas such as nitrogen or carbon dioxide. Since
the oxygen and hydrocarbons are not mixed until they are both
inside the reactor, catalyst is present when they meet and reaction
proceeds immediately, causing the oxygen partial pressure to drop.
Thus, an advantage of feeding an oxygen-containing gas to the
reactor through at least one further inlet in addition to the
ethylene and acetic acid reactants is that it allows significantly
higher levels of oxygen to be safely employed without a high
inventory of flammable gas mixtures.
[0005] Bubbling bed operation is not appropriate for reactions
using molecular oxygen-containing gas because of the possibility of
a plume or bubbles of oxygen forming in the bed, which can be
unsafe.
[0006] There remains a need for an improved fluid bed process in
which molecular oxygen is reacted with at least one oxidisable
reactant.
SUMMARY OF THE INVENTION
[0007] It has now been found that if a molecular oxygen-containing
gas having an oxygen concentration greater than that of air is to
be fed into a fluidised bed comprising catalyst particles in a
reactor, the fluidised bed should be maintained in a turbulent
regime.
[0008] Thus, according to one aspect of the present invention there
is provided a process for reacting in a fluid bed reactor, at least
one oxidisable reactant with molecular oxygen in the presence of a
catalytically active fluidised bed of solid particles in which
process a molecular oxygen-containing gas having an oxygen
concentration greater than that of air is introduced into said
fluidised bed whilst said fluidised bed is maintained in a
turbulent regime.
[0009] Fluidised beds comprising solid particles may be operated in
various regimes --for example, as spouting beds, fast fluidisation
(transporting) beds, bubbling beds and turbulent beds etc.
[0010] A turbulent regime for a fluidised bed of solid particles is
a fluidised bed in which large discrete bubbles or voids are
generally absent and the bed is substantially uniform. Clusters and
strands of particles move about violently within the bed making for
a general lack of distinction between continuous and discontinuous
phases in the bed. In a turbulent fluidised bed, the upper surface
is considerably more diffuse than in a bubbling bed because of
greater freeboard activity.
[0011] A turbulent regime has a linear velocity of the fluidising
gas (linear gas velocity) which is greater than the transition
velocity (U.sub.k) which is, the gas velocity at which there is a
transition from bubbling to turbulent regimes.
[0012] Preferably the ratio of transition velocity (U.sub.k)
terminal velocity (U.sub.t) is in the range 0.1:1 to 25:1.
Typically, at a pressure in the range 1 to 30 bara, the ratio
U.sub.k: U.sub.t maybe in the range 0.1:1 to 25:1, preferably in
the range 0.3:1 to 13:1. For small solid particles (for example, in
the range 30 to 150 microns diameter), the turbulent regime has a
transition velocity U.sub.k which is much greater than the terminal
velocity (U.sub.t) of the mean particle size of bed material. As
pressure in the fluid bed is increased, the ratio U.sub.k:U.sub.t
decreases, for example from 3:1 to 1:1 or from 3.5:1 to 0.5:1.
[0013] U.sub.k:U.sub.t is greater for smaller particles than for
larger particles.
[0014] The use of a turbulent fluid bed provides good mass
transfer. Thus, one advantage is that large bubbles of molecular
oxygen-containing gas are not formed or present in the bed.
Therefore, the potential for gas bubbles forming in the bed having
a molecular oxygen concentration in an explosive region is reduced
which has increased safety implications. Also, at the oxygen
injection point, there is reduced tendency for discrete jet or
plume formation because of the greater mixing, so the potential for
adverse consequences in the event of an ignition is reduced or
eliminated. Furthermore, the mixing of a turbulent fluid bed can
produce a more homogeneous temperature profile. There is good heat
transfer and low tendency for hot spots to form.
[0015] The process of the present invention is suitable for the
carboxylation of alkenes to produce unsaturated esters by reaction
of a carboxylic acid, an olefin and molecular oxygen in the
presence of an effective amount of an active catalyst, such as for
example the reaction of acetic acid, ethylene and oxygen to produce
vinyl acetate.
[0016] The process of the present invention is also suitable for
the reaction in the presence of an effective amount of an active
catalyst, of molecular oxygen with (a) ethane to produce ethylene
and/or acetic acid, (b) with ethylene to produce acetic acid and
(c) mixtures of ethane and ethylene to produce acetic acid,
optionally with ethylene.
[0017] The process of the present invention is suitable for the
oxidation of hydrocarbons by reaction with a molecular oxygen in
the presence of an effective amount of an active catalyst, such as
for example the reaction of C4's to produce maleic anhydride.
[0018] The process of the present invention is suitable for the
ammoxidation of hydrocarbons by reaction with a molecular oxygen
and ammonia in the presence of an effective amount of an active
catalyst, such as for example the ammoxidation of propene or
propane to produce acrylonitrile.
[0019] Preferably, the fluid bed comprises solid particles with a
relatively broad particle size distribution. Thus, for fluid beds
comprising solid particles having a particle diameter in the range
20 to 300 microns, the particle diameter size distribution is
preferably at least 20 microns, more preferably at least 50 microns
and most preferably at least 100 microns.
[0020] Suitably, the fluid bed comprises solid particles having
sizes according to one or more of the following independent
criteria: (i) at least 65% of the particles have particle diameters
in the range 20-120 microns; (ii) less than 15% of the particles
have a particle diameter less than 45 microns; and (iii) less than
5% of the particles have a particle diameter greater than 105
microns.
[0021] The total linear gas flow through the fluidised bed (also
referred to as the superficial velocity) is preferably up to 50
cm/s, more preferably up to 35 cm/s for the reaction of ethane
and/or ethylene with oxygen to produce acetic acid and/or ethylene
and more preferably up to 30 cm/s for the production of vinyl
acetate from ethylene, acetic acid and oxygen.
[0022] When the process of the present invention is used for the
production of vinyl acetate by the reaction of ethylene and acetic
acid with molecular oxygen in a fluid bed reactor in the presence
of a catalytically active fluidised bed of solid particles having a
particle diameter in the range 20 to 300 microns and having a
particle diameter size distribution of at least 20 microns,
preferably at least 50 microns and more preferably at least 100
microns, the fluidised bed may be maintained in a turbulent regime
by using solid particles having a particle density of at least 0.6
g/cm.sup.3 and a settled bed density of at least 0.4 g/cm.sup.3 and
by operating at a pressure in the fluid bed reactor of at least 4
bara with a total linear gas flow through the fluidised bed of from
2 to 30 cm/s inclusive, preferably 2-25 cm/s inclusive.
[0023] Thus, according to one aspect of the present invention there
is provided a process for the production of vinyl acetate by the
reaction of ethylene and acetic acid with molecular oxygen in a
fluid bed reactor in the presence of a catalytically active
fluidised bed of solid particles having a particle diameter in the
range 20 to 300 microns and having a particle diameter size
distribution of at least 20 microns, preferably at least 50 microns
and more preferably at least 100 microns, and in which process a
molecular oxygen-containing gas having an oxygen concentration
greater than that of air is introduced into the fluidised bed, and
the fluidised bed is maintained in a turbulent regime by using
solid particles having a particle density of at least 0.6
g/cm.sup.3 and a settled bed density of at least 0.4 g/cm.sup.3 and
by operating at a pressure in the fluid bed reactor of at least 4
bara with a total linear gas flow through the fluidised bed of from
2 to 30 cm/s inclusive, preferably 2-25 cm/s inclusive.
[0024] Preferably, in such a process for the production of vinyl
acetate, the fluid bed comprises catalyst particles which have a
particle size distribution in which (i) at least 65% of the
particles have particle diameters in the range 20-120 microns, (ii)
less than 15% of the particles have a particle diameter of less
than 45 microns and (iii) less than 5% of the particles have a
particle diameter of greater than 105 microns.
[0025] As the linear gas flow rate is increased, so increasingly
dense catalyst particles will be required to reduce transportation
of catalyst particles from the fluidised bed.
[0026] Suitably, the catalyst particles useful for the production
of vinyl acetate have a particle density in the range 1.1 to 1.5
g/cm.sup.3. The density of the particles may be changed by changing
the amount of liquid components such as acetic acid introduced into
the fluid bed of catalyst during the process.
[0027] When the process of the present invention is used for the
reaction of molecular oxygen with (a) ethane to produce ethylene
and/or acetic acid, (b) ethylene to produce acetic acid, or (c)
mixtures of ethane and ethylene to produce acetic acid, optionally
with ethylene, in a fluid bed reactor in the presence of a
catalytically active fluidised bed of solid particles having a
particle diameter in the range 20 to 300 microns and having a
particle diameter size distribution of at least 20 microns,
preferably at least 50 microns and more preferably at least 100
microns, the fluidised bed may be maintained in a turbulent regime
by using solid particles having a particle density of at least 0.6
g/cm.sup.3 and a settled bed density of at least 0.4 g/cm.sup.3 and
by operating at a pressure in the fluid bed reactor of at least 4
bara with a total linear gas flow through the fluidised bed of from
2 to 35 cm/s, inclusive.
[0028] Thus, according to one aspect of the present invention there
is provided a process for the reaction of molecular oxygen with (a)
ethane to produce ethylene and/or acetic acid, (b) ethylene to
produce acetic acid or (c) mixtures of ethane and ethylene to
produce acetic acid, optionally with ethylene, in a fluid bed
reactor in the presence of a catalytically active fluidised bed of
solid particles having a particle diameter in the range 20 to 300
microns and having a particle diameter size distribution of at
least 20 microns, preferably at least 50 microns and more
preferably at least 100 microns, and in which process a molecular
oxygen-containing gas having an oxygen concentration greater than
that of air is introduced into the fluidised bed, and the fluidised
bed is maintained in a turbulent regime by using solid particles
having a particle density of at least 0.6 g/cm.sup.3 and a settled
bed density of at least 0.4 g/cm.sup.3 and by operating at a
pressure in the fluid bed reactor of at least 4 bara with a total
linear gas flow through the fluidised bed of from 2 to 35 cm/s,
inclusive.
[0029] Preferably, in such a process for the reaction of ethane
and/or ethylene with molecular oxygen to produce ethylene and/or
acetic acid, the fluidised bed comprises particles in which (i) at
least 65% of the particles have particle diameters in the range
20-120 microns, (ii) less than 15% of the particles have a particle
diameter of less than 45 microns and (iii) less than 5% of the
particles have a particle diameter of greater than 105 microns.
[0030] Suitably, the catalyst particles used for the oxidation of
ethane and/or ethylene to produce ethylene and/or acetic acid have
a particle density of 1.25 to 3.5 g/cm.sup.3, preferably 1.75 to
2.25 g/cm.sup.3.
[0031] It has been found that such a process according to the
present invention for the production of vinyl acetate can be
readily scaled up because data obtained on a small scale is
applicable to the full scale because both fluid beds operate in a
turbulent regime.
[0032] In the present invention it has been found that by operating
at high pressures (for example at least 4 bara), a turbulent regime
may be maintained in the fluid bed with a small amount (for example
less than 15%, preferably less than 5%) of solid particles having a
particle diameter of less than 45 microns, or even less than 20
microns (fines).
[0033] The use of low levels of fines provides an advantage of
reduced loss of the particles from the reactor and may thus provide
advantages of design of any cyclones to reduce loss of material
from the reactor.
[0034] In other processes according to the present invention, it
may be possible to maintain a turbulent regime in the fluid bed by
using a fluid bed comprising solid particles with greater than 15%
of the particles having a particle diameter of less than 45
microns, for example 30 to 40% inclusive and at the same time
operating at a lower pressure, for example at 0.5 to 1 barg,
inclusive and a higher fluidising gas velocity.
[0035] The density of the solid particles of the fluid bed may be
modified by the use of a densifier during preparation of the
particles. Densification of the particles may be achieved by
substitution of one or more metals of the catalyst by at least one
metal which is of higher atomic weight and, preferably, which is
also chemically equivalent, that is, has the same or similar
activity and/or selectivity to the substituted metal(s). For
example, a catalyst comprising the metals, Mo, V, Nb may be
densified by substituting one or more of Mo, V, or Nb by at least
one metal of higher atomic weight such as Sn, Sb, Te, La, Ta, W,
Re, Pb, Bi, Ce, Pr, Gd and Yb.
[0036] Alternatively, the density of the solid particles of the
fluid bed may be modified by the use of a fluidising gas, such as
ethylene. The fluidising gas may comprise at least 30 mol %
ethylene by volume, for example, at least 30 mol % to 85 mol %
ethylene.
[0037] Increasing the density of the fluid bed solid particles, for
example by using a densifier, may enable higher superficial gas
velocities to be used and/or higher levels of fines whilst
maintaining the fluid bed in a turbulent, non-transporting
regime.
[0038] The process of the present invention allows for the safe
introduction into a fluid bed, of a molecular oxygen-containing gas
having an oxygen concentration of up to almost pure molecular
oxygen. Suitably, molecular oxygen-containing gases for use in the
present invention include oxygen gas with minor amounts of
impurities such as argon and nitrogen which each may be present at
a concentration of less than 0.1% by volume. The concentration of
oxygen in the molecular oxygen-containing gas is suitably in the
range greater than 21% to 100%, preferably in the range 50 to 100%,
for example a concentration of greater than 99.5% by volume,
suitably a concentration of at least 99.6% by volume.
[0039] The means for introducing the molecular oxygen-containing
gas into the fluidised bed should recognise the hazards which may
have to be considered with such materials. Thus, for example, for
safety, the inlet(s) for the molecular oxygen-containing gas are
preferably located at a distance from the catalyst support means of
greater than any potential flame length. The potential flame length
is determined by factors such as the inlet pipe diameter and inlet
gas velocity. The inlets should be positioned and inlet pressures
and velocities selected, so that the molecular oxygen-containing
gas is dispersed and mixed in the region of the inlet. The inlets
should be positioned not too close to the reactor walls, in case
there is a shock wave following a detonation. The inlets should be
positioned so that the molecular oxygen-containing gas does not
impinge directly on surfaces or other structures in the reactor
such as inlets for other reactants.
[0040] In the process of the present invention the at least one
oxidisable reactant may be introduced into the fluidised bed as a
gas and/or liquid through one or more inlets.
[0041] One or more gaseous reactants may be introduced into the
fluidised bed together with or preferably at least in part,
separately from, the molecular oxygen-containing gas.
[0042] This gaseous reactant may be introduced as a component of
the fluidising gas. The fluidising gas may comprise fresh gaseous
reactants and/or recycle gases. The gaseous reactant introduced
into the reactor may be ethylene which may be used with acetic acid
to produce vinyl acetate. The gaseous reactant introduced into the
reactor may be ethane and/or ethylene which may be oxidised
respectively to ethylene and/or acetic acid and to acetic acid.
[0043] Ethylene used in the process of the present invention may be
used in substantially pure form or admixed with one or more of
nitrogen, methane, ethane, carbon dioxide and water in the form of
steam or one or more of hydrogen, C.sub.3/C.sub.4 alkenes or
alkanes. Ethane used in the process of the present invention may be
used in substantially pure form or admixed with one or more of
nitrogen, methane, ethylene, carbon dioxide and water in the form
of steam or one or more of hydrogen, C.sub.3/C.sub.4 alkenes or
alkanes.
[0044] The process of the present invention may suitably be
operated at a temperature from 100 to 500.degree. C., preferably
140 to 400.degree. C. The process may suitably be operated at a
pressure of 10 to 3000 kPa gauge (0.1 to 30 barg), preferably 20 to
2500 Pa gauge (0.2 to 25 barg).
[0045] The fluidised bed may comprise catalyst particles and
optionally catalytically inactive particles. The catalyst may be
any suitable fluidisable catalyst. The catalyst may be a supported
catalyst. Suitable catalyst supports include porous silica,
alumina, silica/alumina, titania, silica/titania, zirconia and
mixtures thereof. Preferably, the support is silica.
[0046] A typical catalyst composition useful in this invention, may
have the following particle size distribution: TABLE-US-00001 0 to
20 microns 0-30 wt % 20 to 44 microns 0-60 wt % 44 to 88 microns
10-80 wt % 88 to 106 microns 0-80 wt % >106 microns 0-40 wt %
>300 microns 0-5 wt %
[0047] Persons skilled in the art will recognise that support
particles sizes of 44, 88, 106 and 300 microns are arbitrary
measures in that they are based on standard size ranges such as may
be measured by an automated laser device such as a Microtrac
X100.
[0048] Preferably, the fluidised bed has a particle density of at
least 0.6 g/cm.sup.3. Catalyst for the production of vinyl acetate
may have a density in the range 1.1 to 1.5 g/cm.sup.3. Catalyst for
the oxidation of ethane and/or ethylene suitably may have a density
in the range 1.25 to 3.5 g/cm.sup.3, preferably in the range of
1.75 to 2.25 g/cm.sup.3. Suitably, the fluidised bed has a settled
bed density of at least 0.4 g/cm.sup.3.
[0049] Suitable catalysts for use in the present invention include
oxidation, ammoxidation and carboxylation catalysts.
[0050] A catalyst suitable for use in the production of vinyl
acetate by the acetoxylation of ethylene may comprise a Group VIII
metal, a catalyst promoter and an optional co-promoter. The
catalyst may be prepared by any suitable method, such as that
described in EP-A-0672453. The Group VIII metal is preferably
palladium. The Group VIII metal may be present in a concentration
of greater than 0.2% by weight, preferably greater than 0.5% by
weight based upon total weight of catalyst. The metal concentration
may be as high as 10% by weight. Suitable promoters include gold,
copper, cerium or mixtures thereof. A preferred promoter is gold.
The promoter metal may be present in an amount of from 0.1 to 10%
by weight in the finished catalyst. Suitable co-promoters include
Group I, Group II, lanthanide or transition metals, for example
selected from the group consisting of cadmium, barium, potassium,
sodium, manganese, antimony, lanthanum and mixtures thereof, which
are present in the finished catalyst as salts, e.g. an acetate
salt. The preferred salts are potassium or sodium acetate. The
co-promoter is preferably present in the catalyst composition in a
concentration of 0.1 to 15% by weight of catalyst, more preferably,
from 1 to 5% by weight. When a liquid acetic acid feed is used, the
preferred concentration of co-promoter salt is up to 6% by weight,
especially 2.5 to 5.5%. Where the acid is introduced in the vapour
phase the co-promoter salt is preferably present in a concentration
up to 11 wt %.
[0051] A catalyst composition suitable for the selective oxidation
of ethane and/or ethylene to acetic acid is described in
EP-A-1069945, the contents of which are hereby incorporated by
reference. This describes a catalyst composition comprising in
combination with oxygen the elements:
Mo.sub.a.W.sub.b.Ag.sub.c.Ir.sub.d.X.sub.e.Y.sub.f (I) wherein X is
the elements Nb and V; [0052] Y is one or more elements selected
from the group consisting of:
[0053] Cr, Mn, Ta, Ti, B, Al, Ga, In, Pt, Zn, Cd, Bi, Ce, Co, Rh,
Cu, Au, Fe, Ru, Os, K, Rb, Cs, Mg, Ca, Sr, Ba, Zr, Hf, Ni, P, Pb,
Sb, Si, Sn, TI, U, Re and Pd; [0054] a, b, c, d, e and f represent
the gram atom ratios of the elements such that
[0055] 0<a.ltoreq.1,0.ltoreq.b<1 and a+b=1;
[0056] 0<(c+d).ltoreq.0.1;
[0057] 0<e.ltoreq.2; and
[0058] 0.ltoreq.f.ltoreq.2.
[0059] Another catalyst composition suitable for the oxidation of
ethane to ethylene and/or acetic acid and/or for the oxidation of
ethylene to acetic acid is described in EP-A-1043064, the contents
of which are hereby incorporated by reference. This describes a
catalyst composition comprising in combination with oxygen the
elements molybdenum, vanadium, niobium and gold in the absence of
palladium according to the empirical formula:
Mo.sub.aW.sub.bAu.sub.cV.sub.dNb.sub.eY.sub.f (I) wherein Y is one
or more elements selected from the group consisting of: Cr, Mn, Ta,
Ti, B, Al, Ga, In, Pt, Zn, Cd, Bi, Ce, Co, Rh, Ir, Cu, Ag, Fe, Ru,
Os, K, Rb, Cs, Mg, Ca, Sr, Ba, Zr, Hf, Ni, P, Pb, Sb, Si, Sn, Ti,
U, Re, Te, and La; [0060] a, b, c, d, e and f represent the gram
atom ratios of the elements such that:
[0061] 0<a.ltoreq.1;0.ltoreq.b<1 and a+b=1;
[0062] 10.sup.-5<c.ltoreq.0.02;
[0063] 0<d.ltoreq.2;
[0064] 0<e.ltoreq.1; and
[0065] 0<f.ltoreq.2.
BRIEF DESCRIPTION OF THE DRAWINGS
[0066] The invention will now be illustrated by reference to the
following examples and FIGS. 1 to 4 in which FIG. 1 represents in
schematic form apparatus for measuring the fluidisation
characteristics of a fluid bed reactor by X-ray imaging, FIG. 2
represents in graph form the effect of the level of fines in the
fluid bed on the fluid bed density, FIG. 3 represents in graph form
the effect of fluidising gas velocity on the fluid bed bulk density
and FIG. 4 represents in graph form the effect of ethylene on the
fluid bed density.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS
Apparatus--X-ray Equipment
[0067] A series of experiments were performed to study the
fluidisation characteristics of a fluid bed using the apparatus
shown schematically in FIG. 1. The fluid bed was fluidised with
inert gas (nitrogen) rather than reactant gases to enable the
fluidisation characteristic of the bed to be studied. Referring to
FIG. 1, the apparatus comprised a 420 mm ID aluminum vessel (7), a
gas feed system (8) and recycle gas system (9). The vessel
contained a bed (1) of fluidisable solid particles supported on a
distributor plate (2) through which fluidising nitrogen gas was
passed from the gas feed (8) and recycled systems (9) was fluidised
with nitrogen from a distributor grid plate (2). The vessel was
connected to a positive displacement gas circulation pump (3),
heater (4) and gas metering/measuring system (not shown) in a
pressurised closed loop. Pressure tappings (5) were positioned
along the vessel wall to allow the bulk density of slices of the
bed to be derived from the differential pressure across portions of
the fluid bed. A section at the top of the bed (6) contained
cyclones to prevent solid particles escaping the vessel.
[0068] An X-ray gun (13) provided x-rays which passed through the
vessel to image intensifier (10), camera (11) and image processing
equipment (12).
[0069] Supported vinyl acetate catalysts were used in the
experiments and were prepared as follows:
a) Preparation of Catalyst Support
[0070] The support used for the catalyst preparation was prepared
by spray-drying a mixture of Nalco (Nalco Chemical Company) silica
sol 1060 and Degussa (Degussa Chemical Company) Aerosil.RTM.
silica. In the dried support, 80% of the silica came from the sol
and 20% of the silica came from the Aerosil. The spray-dried
microspheres were calcined in air at 640.degree. C. for 4 hours.
This method of support preparation is described in
EP-A-0672453.
[0071] The particle size distribution of the support which was used
for the catalyst preparation is as follows: TABLE-US-00002 Particle
size % >300 microns 2 88-300 microns 30 44-88 microns 38 <44
microns 30
b) Preparation of Catalyst A
[0072] Silica support (54.4 kg) prepared as hereinbefore described
was impregnated with a solution of Na.sub.2PdCl.sub.4.xH.sub.2O
(containing 1 kg palladium) and AuCl.sub.4.xH.sub.2O (containing
400 g gold) in distilled water by the incipient wetness. The
resulting mixture was mixed thoroughly, left to stand for 1 hour
and dried overnight.
[0073] The impregnated material was added slowly to a 5% solution
of hydrazine in distilled water, and the mixture allowed to stand
overnight with occasional stirring. Thereafter the mixture was
filtered and washed with 4.times.400 L distilled water. The solid
was then dried overnight.
[0074] The material was impregnated with an aqueous solution of
potassium acetate (2.8 kg) by incipient wetness. The resulting
mixture was mixed thoroughly, left to stand 1 hour and dried
overnight.
[0075] The resulting catalyst comprised 1.6 wt % palladium, 0.6 wt
% gold and 5 wt % potassium on silica based on ICP analysis.
[0076] Several batches of catalyst were made according to this
method and combined. The catalyst was then screened to generate
specific size distributions as shown in Table 1. TABLE-US-00003
TABLE 1 Sample 1 Sample 2 Sample 3 Sample 4 <45 microns 10% 15%
20% 25% 45-111 microns 80% 77% 76% 72% >111 microns 10% 8% 4%
3%
c) Preparation of Catalyst B
[0077] Prior to use silica support prepared as hereinbefore
described was classified to reduce the amount of particles of<45
microns to less than 15%. The silica support (1124 kg) was
impregnated with a solution of Na.sub.2PdCl.sub.4.xH.sub.2O
(containing 11.4 kg palladium) and AuCl.sub.4.xH.sub.2O (containing
4.56 g gold) in distilled water by the incipient wetness technique.
The resulting mixture was mixed thoroughly and dried in a ribbon
blender with a mean wall temperature of 120.degree. C. During the
drying, a dry air purge was passed through the blender over the
agitated material to remove the evolved moisture. Following drying
the material was cooled to less than 35.degree. C. The impregnated
salts were reduced to metallic state by addition of the solid
material to a stirred aqueous solution of hydrazine (2200 litres,
5% by weight hydrazine). Thereafter, the material was then pumped
to a Nutsche pressure filter and filtered under nitrogen. The
filter cake was washed 3 times with about 1000 litres of
demineralised water in each wash.
[0078] The wet material (filter cake) was blended with solid
anhydrous potassium acetate (60 kg) in a ribbon blender and
thereafter dried under agitation by introducing steam into the
steam jacket of the blender to give a mean wall temperature of
120.degree. C. The evolved moisture was removed with a dry air
purge through the blender. Drying was stopped when the moisture
content of the material was in the range 20 to 25% by weight. The
partially dried material was transferred to a fluid bed drier
operated at an air inlet temperature of 150.degree. C. to remove
the remaining moisture and give a free flowing catalyst
material.
[0079] The resulting catalyst comprised 0.93 wt % palladium, 0.37%
gold and 2.11 wt % potassium based on ICP analysis.
[0080] The particle size distribution of the finished material was
as follows: TABLE-US-00004 Particle size % >110 microns 23
45-110 microns 68 <45 microns 9
c) Fluidisation Experiments
[0081] (i) Effect of Fines on Fluid Bed Density and Effect of
Fluidising Gas Velocity on the Fluid Bed Bulk Density.
[0082] 90 kg of catalyst A prepared as hereinbefore described was
loaded into the aluminum vessel and fluidised with nitrogen at 8
barg and 150-157.degree. C. over a range of gas velocities. Steady
state experiments were run (with the cyclones returning any
catalyst which reaches the top of the vessel to the catalyst bed).
Differential pressure readings were taken from which average bed
densities were calculated. The results are shown in Table 2 and
plotted in graph form in FIGS. 2 and 3. TABLE-US-00005 TABLE 2
VARIATION OF BED DENSITY.sup.a WITH FINES CONTENT AND VELOCITY
Velocity = Velocity = Velocity = 13 cm/s 17 cm/s 21 cm/s 10% <45
micron.sup.b 459 424 395 15% <45 micron.sup.b 409 432 409 20%
<45 micron.sup.b 375 303 239 25% <45 micron.sup.b 332 294 245
.sup.aBed density (in kg/m.sup.3) is the average of two density
measurements made in the first 1.0 m of the fluid bed (measured
from the grid plate upwards). .sup.bFines (defined as <45 micron
material) content of the catalyst as loaded into the reactor.
[0083] The velocity in Table 2 and in FIGS. 2 and 3 is the
superficial gas velocity of the fluidising gas and is defined as
gas flow rate (cm.sup.3/s)/fluid bed cross-section area
(cm.sup.2).
[0084] During these experiments, the x-ray images showed that the
bed was being maintained in a turbulent regime. Thus, the
experiments show that there is a range of operating conditions
under which a turbulent regime can be maintained.
[0085] Referring to FIG. 2, this shows the bed density as a
function of the amount of fines in the fluid bed at three different
superficial velocities. The data show that as the superficial gas
velocity is increased, the bed density decreases. Also, at any
given superficial gas velocity, as the amount of fines increases so
the bed density decreases. There is a sharp reduction in bed
density at the higher fines content (>20%) and high gas velocity
(>21 cm.sup.3/s) indicating that the bed is entering the
transport regime, where it occupies all the available space in the
vessel.
[0086] Referring to FIG. 3, this shows the bed density as a
function of the superficial gas velocity for the different amount
of fines in the fluid bed. The data show that as the superficial
gas velocity is increased, the bed density decreases. There is a
reduction in bed density as the fines content increases,
particularly at high gas velocity (>21 cm.sup.3/s). This
indicates that the level of fines should be kept at no greater than
15% to maintain a reasonable bed density and prevent transportation
at the higher gas velocity.
[0087] (ii) Effect of Ethylene on the Fluid Bed Density
[0088] 5.1 kg of catalyst B prepared as hereinbefore described was
loaded into a 2.1 metre tall vessel with a diameter of 3.5 inches.
At the top of the vessel a cone shaped expansion section was fitted
followed by a straight sided freeboard section with a diameter of 6
inches. The vessel was equipped with a differential pressure
transmitter covering the lower 1.38 metres of height. Thus based on
the known volume of the lower section of the vessel and the mass of
catalyst in that section from the differential pressure transmitter
reading the density of the fluidised bed could be calculated. Two
experiments were carried out. The first experiment used nitrogen as
fluidising gas. The second experiment used ethylene with 10-20 vol
% nitrogen as fluidising gas. The experiments were carried out at
154.degree. C. and at a pressure range of 7.2 to 9.2 barg.
[0089] Referring to FIG. 4, this shows the bed density as a
function of the superficial gas velocity for the different
fluidizing gases. The data shows a higher bed density is achieved
when ethylene is used as a fluidising gas compared to the bed
density achieved when nitrogen is used as the fluidising gas. The
data also indicates that higher superficial gas velocities may be
achieved when using ethylene as the fluidising gas whilst still in
the turbulent regime. It is believed that the increased noise in
the nitrogen data above 19.5 cm/sec is due to the bed
transporting.
[0090] Further experiments were performed to investigate the effect
of bed density on the fluidisation characteristics.
Effect of Bed density on fluidisation.
[0091] Catalysts containing a densifier were prepared and tested as
follows.
a) Preparation of Support
EXAMPLES
Example 1 (Comparative)
[0092] The support was prepared by spray-drying a mixture of Nalco
(Nalco Chemical Company) silica sol 1060 and Degussa (Degussa
Chemical Company) Aerosil.RTM. silica. In the dried support, 80% of
the silica came from the sol and 20% of the silica came from the
Aerosil. The spray-dried microspheres were calcined in air at
640.degree. C. for 4 hours. This method of support preparation is
described in EP-A-0672453.
Example 2
[0093] The support was prepared as in Example 1 except that 90% of
the silica came from the sol and 10% came from the Aerosil
Example 3
[0094] The support was prepared as in Example 2 except that the
Aerosil was replaced by tin oxide.
[0095] The particle size distributions of the supports are as
follows: TABLE-US-00006 Particle size % Example 1 % Example 2 %
Example 3 >350 microns 0.8 0.3 0 88-350 microns 27.4 15.1 12.5
40-88 microns 33.8 31.5 31.5 <40 microns 38.0 53.1 56.0
b) Preparation of Catalyst
[0096] 30.0 g of microspheroidal support was impregnated with a
solution of Na.sub.2PdCl.sub.4.xH.sub.2O (1.84 g, 28.9% Pd) and
HAuCl.sub.4.xH.sub.2O (0.44, 49.0% Au) in distilled water (20.0
cm.sup.3) by incipient wetness. The resulting mixture was mixed
thoroughly, left to stand for 1 hour and then dried overnight.
[0097] The impregnated material was allowed to cool to room
temperature, and then was added to a solution of hydrazine (3.0 g
of a 55% aqueous solution of N.sub.2H.sub.4) in 80.0 cm.sup.3
distilled water, and the mixture allowed to stand overnight with
occasional stirring. Thereafter the mixture was filtered and washed
with 4.times.250 cm.sup.3 distilled water. The solid was then dried
overnight.
[0098] The material was impregnated with an aqueous solution of
potassium (1.64 g) by incipient wetness. The resulting mixture was
mixed thoroughly, left to stand for 1 hour and dried overnight.
[0099] The catalyst of Example 1 had a metal loading of 1.49% Pd,
0.44% Au and 3.64% potassium acetate. The catalyst of Example 2 had
a metal loading of 1.65% Pd, 0.53% Au and 4.54% potassium acetate.
The catalyst of Example 3 had a metal loading of 1.63% Pd, 0.54% Au
and 4.49% potassium acetate, 0.47% Sn.
c) Production of Vinyl Acetate
[0100] The catalysts were tested in a bench scale fluid bed reactor
with a maximum catalyst capacity of 40 cm.sup.3. For each
experiment 30 cm.sup.3 of catalyst-plus-diluent was loaded into the
reactor. Typically 2 g of catalyst was used. The inert diluent
consisted of silica loaded with gold and potassium acetate. The
reactor was equipped with two feed inlets. Ethylene, acetic acid,
and oxygen all entered the reactor through a lower inlet and
nitrogen only was fed through the second inlet which was located
2.5 inches above the first.
[0101] The reactor pressure was controlled at 8 barg and all lines
leading to and from the reactor were heat traced and maintained at
150-160.degree. C. in order to prevent condensation of liquid feeds
or products. The reactor was normally maintained at a temperature
of 150-160.degree. C.
[0102] The gaseous reactor effluent was analysed on-line using a
Hewlett Packard Model 5890 gas chromatograph equipped with both TCD
and FID detectors. Oxygen, nitrogen, ethylene and carbon dioxide
were separated on a 13.times. mole sieve column parallel with 10%
Carbowax 20M on 80/100 Chromosorb WAW and 23% SP2700 on 80/100
Chromosorb PAW, and quantified with the TCD. Vinyl acetate and
acetic acid and other organic by-products were separated on a
J&W DB1701 megabore capillary column and quantified with the
FID. Data was analysed via a customised Excel spreadsheet.
TABLE-US-00007 Settled Bulk Density Catalyst Activity Example of
Support g/cm.sup.3 gVA/kg-cat/hr Selectivity Example 1 run 1 0.66
1420 91.8 Example 1 run 2 0.66 1270 93.1 Example 2 0.80 1280 90.6
Example 3 run 1 0.94 1270 89.4 Example 3 run 2 0.94 1200 92.8
[0103] The data show that catalysts with higher densities can be
made by adding inert oxides during support preparation, and such
catalysts have similar intrinsic activity to catalysts made without
a densifier. Thus, in view of the fluidisation experiments, it can
be concluded that increasing the density of the fluid bed solid
particles, for example by using a densifier, may enable higher
superficial gas velocities to be used and/or higher levels of fines
whilst maintaining the fluid bed in a turbulent, non-transporting
regime.
* * * * *