U.S. patent application number 11/515783 was filed with the patent office on 2007-04-05 for optical film, optical compensation film, polarizing plate and liquid crystal display.
This patent application is currently assigned to FUJI PHOTO FILM CO., LTD.. Invention is credited to Hajime Nakayama, Yuta Takahashi, Hirofumi Toyama.
Application Number | 20070076155 11/515783 |
Document ID | / |
Family ID | 37901545 |
Filed Date | 2007-04-05 |
United States Patent
Application |
20070076155 |
Kind Code |
A1 |
Nakayama; Hajime ; et
al. |
April 5, 2007 |
Optical film, optical compensation film, polarizing plate and
liquid crystal display
Abstract
An optical film is provided and has retardations satisfying
relations (1) to (3): 0.ltoreq.Re(550).ltoreq.10; (1)
-25.ltoreq.Rth(550).ltoreq.25; and (2) |I|+|II|+|III|+|IV|>0.5
(nm), (3) with definitions: I=Re(450)-Re(550); II=Re(650)-Re(550);
III=Rth(450)-Rth(550); and IV=Rth(650)-Rth(550), wherein Re(450),
Re(550) and Re(650) are in-plane retardations measured with lights
of wavelength of 450, 550 and 650 nm, respectively; and Rth(450),
Rth(550) and Rth(650) are retardations in a thickness direction of
the optical film, which are measured with lights of wavelength of
450, 550 and 650 nm, respectively.
Inventors: |
Nakayama; Hajime;
(Minami-Ashigara-shi, JP) ; Toyama; Hirofumi;
(Minami-Ashigara-shi, JP) ; Takahashi; Yuta;
(Minami-Ashigara-shi, JP) |
Correspondence
Address: |
BUCHANAN, INGERSOLL & ROONEY PC
POST OFFICE BOX 1404
ALEXANDRIA
VA
22313-1404
US
|
Assignee: |
FUJI PHOTO FILM CO., LTD.
Minami-Ashigara-shi
JP
|
Family ID: |
37901545 |
Appl. No.: |
11/515783 |
Filed: |
September 6, 2006 |
Current U.S.
Class: |
349/118 |
Current CPC
Class: |
C08B 3/00 20130101; G02B
5/305 20130101; C08J 5/18 20130101; G02F 1/133531 20210101; C08J
2301/10 20130101; G02F 2202/40 20130101; G02F 1/133528 20130101;
G02B 1/04 20130101; G02F 1/1393 20130101; G02F 1/13363 20130101;
G02F 1/133637 20210101; C09K 2323/03 20200801; G02F 1/133638
20210101; G02F 2413/02 20130101; G02B 5/3083 20130101 |
Class at
Publication: |
349/118 |
International
Class: |
G02F 1/1335 20060101
G02F001/1335 |
Foreign Application Data
Date |
Code |
Application Number |
Sep 9, 2005 |
JP |
2005-262304 |
Mar 8, 2006 |
JP |
2006-63026 |
Claims
1. An optical film having retardations satisfying relations (1) to
(3): 0.ltoreq.Re(550).ltoreq.10; (1) -25.ltoreq.Rth(550).ltoreq.25;
and (2) |I|+|II|+|III|+|IV|>0.5 (nm), (3) with definitions:
I=Re(450)-Re(550); II=Re(650)-Re(550); III=Rth(450)-Rth(550); and
IV=Rth(650)-Rth(550), wherein Re(450), Re(550) and Re(650) are
in-plane retardations measured with lights of wavelength of 450,
550 and 650 nm, respectively; and Rth(450), Rth(550) and Rth(650)
are retardations in a thickness direction of the optical film,
which are measured with lights of wavelength of 450, 550 and 650
nm, respectively.
2. The optical film according to claim 1, wherein I, II, III and IV
satisfy relations (4-A) to (7-A): -50.ltoreq.I.ltoreq.0; (4-A)
0.ltoreq.II.ltoreq.50; (5-A) -50.ltoreq.III<0; and (6-A)
0<IV.ltoreq.50. (7-A)
3. The optical film according to claim 1, wherein I, II, III and IV
satisfy relations (4-B) to (7-B): -50.ltoreq.I<0; (4-B)
0<II.ltoreq.50; (5-B) 0.ltoreq.III.ltoreq.50; and (6-B)
-50.ltoreq.IV.ltoreq.0. (7-B)
4. The optical film according to claim 1, wherein I, II, III and IV
satisfy relations (4-C) to (7-C): 0.ltoreq.I.ltoreq.50; (4-C)
-50.ltoreq.II.ltoreq.0; (5-C) 0<III.ltoreq.50; and (6-C)
-50.ltoreq.IV<0. (7-C)
5. The optical film according to claim 1, wherein I, II, III and IV
satisfy relations (4-D) to (7-D): 0<I.ltoreq.50; (4-D)
-50.ltoreq.II<0; (5-D) -50.ltoreq.III.ltoreq.0; and (6-D)
0.ltoreq.IV.ltoreq.50. (7-D)
6. The optical film according to claim 1, which is formed from a
cellulose acylate a raw material polymer of the optical film.
7. The optical film according to claim 6, wherein the cellulose
acylate has an acyl substituent, the acyl substituent is
substantially only an acetyl group, and a total substitution degree
of the acyl substituent is from 2.56 to 3.00.
8. The optical film according to claim 6, wherein the cellulose
acylate has an acyl substituent, the acyl substituent is
substantially at least two of acetyl group, propionyl group and
butanoyl group, and a total substitution degree of the acyl
substituent is from 2.50 to 3.00.
9. The optical film according to claim 1, which comprises a
compound capable of reducing Rth(550) within a range satisfying
relations (8) and (9): (Rth(A)-Rth(0))/A.ltoreq.-1.0; and (8)
0.01.ltoreq.A.ltoreq.30, (9) wherein: Rth(A) means Rth(nm) at 550
nm of the optical film containing the compound capable of reducing
Rth(550) by A %; Rth(0) means Rth(nm) at 550 nm of the optical film
not containing the compound capable of reducing Rth(550); and A
means a weight % of the compound capable of reducing Rth(550) with
respect to a weight of a raw material polymer of the optical film,
which is taken as 100.
10. The optical film according to claim 1, which comprises a
compound capable of increasing .DELTA.Rth, which is represented by
a relation (10), within a range satisfying relations (11) and (12):
.DELTA.Rth=Rth(450)-Rth(650); (10)
(.DELTA.Rth(B)-.DELTA.Rth(0))/B.gtoreq.1.0; and (11)
0.01.ltoreq.B.ltoreq.30, (12) wherein: .DELTA.Rth(B) means
.DELTA.Rth(nm) of the optical film containing the compound capable
of increasing .DELTA.Rth by B %; .DELTA.Rth(0) means .DELTA.Rth(nm)
of thje optical film not containing the compound capable of
increasing .DELTA.Rth; and B means a weight (%) of the compound
capable of increasing .DELTA.Rth with respect to a weight of a raw
material polymer of the optical film, which is taken as 100.
11. The optical film according to claim 1, which has a thickness of
20 to 200 .mu.m.
12. An optical compensation film comprising: an optical film
according to claim 1; and an optically anisotropic layer satisfying
relations (13) and (14): 0.ltoreq.Re.ltoreq.400;and (13)
-400.ltoreq.Rth.ltoreq.400, (14) wherein Re and Rth are an in-plane
retardation and a retardation in a thickness direction of the
optically anisotropic layer, respectively, which are measured with
a light having a wavelength within a visible region.
13. A polarizing plate comprising: a polarizer; and an optical film
according to claim 1.
14. A liquid crystal display comprising an optical film according
to claim 1.
15. A liquid crystal display comprising: an optical film according
to claim 1; and an optically anisotropic layer satisfying relations
(15) and (16): 0.ltoreq.Re.ltoreq.400; and (15)
-400.ltoreq.Rth.ltoreq.400, (16) wherein Re and Rth are an in-plane
retardation and a retardation in a thickness direction of the
optically anisotropic layer, respectively, which are measured with
a light having a wavelength within a visible region.
16. The liquid crystal display according to claim 14, which further
comprises a liquid crystal cell containing liquid crystal molecules
aligned in one of a vertical alignment, a parallel alignment and a
bent alignment in a black display state of the liquid crystal
display.
17. The liquid crystal display according to claim 16, wherein the
liquid crystal molecules are aligned in the vertical alignment in
the black display state, and the liquid crystal display comprises
an optically anisotropic layer, the optically anisotropic layer
including a layer satisfying relations (17) and (18):
10.ltoreq.Re.ltoreq.150; and (17) 50.ltoreq.Rth.ltoreq.400, (18)
wherein Re and Rth are an in-plane retardation and a retardation in
a thickness direction of the optically anisotropic layer,
respectively, which are measured with a light having a wavelength
within a visible region.
18. The liquid crystal display according to claim 16, wherein the
liquid crystal molecules are aligned in the parallel alignment in
the black display state, and the liquid crystal display comprises
an optically anisotropic layer, the optically anisotropic layer
including a layer satisfying any one of relations from (19) to
(22): 100.ltoreq.Re.ltoreq.400, and -50.ltoreq.Rth.ltoreq.50; (19)
0.ltoreq.Re.ltoreq.20, and -400.ltoreq.Rth.ltoreq.-50; (20)
60.ltoreq.Re.ltoreq.200, and 20.ltoreq.Rth.ltoreq.120; and (21)
30.ltoreq.Re.ltoreq.150, and 100.ltoreq.Rth.ltoreq.400, (22)
wherein Re and Rth are an in-plane retardation and a retardation in
a thickness direction of the optically anisotropic layer,
respectively, which are measured with a light having a wavelength
within a visible region.
19. The liquid crystal display according to claim 16, wherein the
liquid crystal molecules are aligned in the bent alignment in the
black display state, and the liquid crystal display comprises an
optically anisotropic layer, the optically anisotropic layer
including a layer containing a discotic liquid crystal compound.
Description
BACKGROUND OF THE INVENTION
[0001] 1. Field of the Invention
[0002] The present invention relates to an optical film adapted for
use in a liquid crystal display, and an optical material such as an
optical compensation film or a polarizing plate, and a liquid
crystal display utilizing the same.
[0003] 2. Description of Background Art
[0004] Liquid crystal displays are widely utilized for a monitor of
a personal computer and a portable equipment, and for televisions,
because of various advantages such as a low voltage drive, a lower
electric power consumption and possibility for a compactification
and a thin structure. Such liquid crystal displays are proposed in
various modes depending on the liquid crystal molecules within a
liquid crystal cell, but a TN mode, in which the liquid crystal
molecules are twisted by about 90.degree. from a lower substrate to
an upper substrate of the liquid crystal cell, has been employed
principally.
[0005] In general, the liquid crystal display is constituted of a
liquid crystal cell, an optical compensation sheet, and a
polarizer. The optical compensation sheet is used for removing a
coloration on the image or expanding a view angle, and a stretched
birefringent film or a transparent film coated with a liquid
crystal material is used for this purpose. For example
JP-A-62-210423 discloses a technology of applying an optical
compensation film, which is prepared by coating, aligning and
fixing a discotic liquid crystal on a triacetyl cellulose film, to
a TN-mode liquid crystal cell, thereby expanding a viewing angle.
However, a liquid crystal display for a television use, having a
large image size and anticipated for observation from various
angles, involves strict requirements for the viewing angle
dependence of the image, and even the aforementioned method is
unable to meet such requirements. For this reason, liquid crystal
displays different from the TN mode are being investigated, such as
those of an IPS (in-plane switching) mode, an OCB (optically
compensatory bend) mode and a VA (vertically aligned) mode. In
particular, the VA mode is attracting attention for use in
television, because of a high contrast and a relatively high
production yield.
[0006] However the VA mode, though being capable of displaying an
almost complete black color in a normal direction to the panel,
causes a light leakage when the panel is observed from an inclined
direction, and thus results in a limited viewing angle. In order to
avoid such drawback, it is proposed to position a retardation
plate, having a refractive index anisotropy in which a refractive
index in a film thickness direction is sufficiently smaller than a
refractive index in an in-plane direction, between the liquid
crystal layer and at least one of the polarizing plates (for
example JP-A-62-210423). It is also proposed to reduce the light
leakage, by utilizing, in combination, a first retardation plate
having a positive monoaxial refractive index anisotropy and a
second retardation plate having a negative refractive index
anisotropy in which the refractive index in the film thickness
direction is sufficiently smaller than the refractive index in the
in-plane direction (for example Japanese Patent No. 3027805). It is
further proposed to improve the viewing angle characteristics of a
VA-mode liquid crystal display, utilizing an optically biaxial
retardation plate, having refractive indexes different in
three-dimensional directions of a film (for example Japanese Patent
No. 3330574).
[0007] On the other hand, also in the IPS mode, a slight light
leakage in a diagonally inclined incident direction in a black
display state is recognized as a cause of deterioration in the
display quality. For improving the displayed color and the viewing
angle in the black display state, it is being considered, also in
the IPS mode, to provide an optical compensation material with
birefringent characteristics, between the liquid crystal layer and
the polarizing plate. It is disclosed, for example, that the
coloration of the image, when a white display or a display of an
intermediate tone is observed from an inclined direction, can be
improved by positioning a birefringent medium, having mutually
orthogonal optical axes and capable of compensating a change in the
retardation of the liquid crystal layer in an inclined position,
between a substrate and a polarizing plate (see JP-A-9-80424).
There are also disclosed a method of utilizing an optical
compensation film, formed by a styrenic polymer or a discotic
liquid crystalline compound, having a negative intrinsic
birefringence (see JP-A-10-54982, JP-A-11-202323 and
JP-A-9-292522), a method of combining, as an optical compensation
film, a film having a positive birefringence and having an optical
axis in the plane of the film and a film having a positive
birefringence and having an optical axis in a normal direction to
the film (see JP-A-11-133408), a method of utilizing a biaxial
optical compensation sheet with a retardation of a half wavelength
(see JP-A-11-305217), and a method of utilizing a film having a
negative retardation as a protective film of a polarizing plate and
providing a surface of such film with an optical compensation layer
having a positive retardation (see JP-A-10-307291). Also disclosed
is an invention of utilizing a retardation film having Nz of from
0.4 to 0.6 and an in-plane retardation of from 200 to 350 nm
thereby suppressing a light leakage, caused by an aberration in a
crossing angle of the polarizing axes from an orthogonal
relationship, experienced when orthogonally disposed polarizing
plates are observed from an inclined direction (see
JP-A-2004-4642).
[0008] However, the aforementioned methods reduces the light
leakage only in a certain wavelength region (for example green
light around 550 nm), and do not take into consideration the light
leakage in other wavelength regions (for example blue light around
450 nm and red light around 650 nm). Therefore, so-called color
shift phenomenon, in which a black display is colored blue or red
when observed from an inclined direction, has not been
resolved.
SUMMARY OF THE INVENTION
[0009] An object of an illustrative, non-limiting embodiment of the
invention is to provide an optical film, having a high contrast
ratio over a wide range and capable of suppressing a color shift
(color shift when observed from an inclined direction), and to
provide an optical material such as an optical compensation film or
a polarizing plate and a liquid crystal display, utilizing such
optical film.
[0010] The above-mentioned object can be accomplished by following
means. [0011] 1. An optical film having retardations satisfying
relations (1) to (3): 0.ltoreq.Re(550).ltoreq.10; (1)
-25.ltoreq.Rth(550).ltoreq.25; and (2) |I|+|II|+|III|+|IV|>0.5
(nm), (3) with definitions: I=Re(450)-Re(550); II=Re(650)-Re(550);
III=Rth(450)-Rth(550); and IV=Rth(650)-Rth(550), wherein Re(450),
Re(550) and Re(650) are in-plane retardations measured with lights
of wavelength of 450, 550 and 650 nm, respectively; and Rth(450),
Rth(550) and Rth(650) are retardations in a thickness direction of
the optical film, which are measured with lights of wavelength of
450, 550 and 650 nm, respectively. [0012] 2. The optical film
according to the item 1, wherein I, II, III and IV satisfy
relations (4-A) to (7-A): -50.ltoreq.I.ltoreq.0; (4-A)
0.ltoreq.II.ltoreq.50; (5-A) -50.ltoreq.III.ltoreq.0; and (6-A)
0<IV.ltoreq.50. (7-A) [0013] 3. The optical film according to
the item 1, wherein I, II, III and IV satisfy relations (4-B) to
(7-B): -50.ltoreq.I<0; (4-B) 0<II.ltoreq.50; (5-B)
0.ltoreq.III.ltoreq.50; and (6-B) -50.ltoreq.IV.ltoreq.0. (7-B)
[0014] 4. The optical film according to the item 1, wherein I, II,
III and IV satisfy relations (4-C) to (7-C): 0.ltoreq.I.ltoreq.50;
(4-C) -50.ltoreq.I.ltoreq.0; (5-C) 0<III.ltoreq.50; and (6-C)
-50.ltoreq.IV<0. (7-C) [0015] 5. The optical film according to
the item 1, wherein I, II, III and IV satisfy relations (4-D) to
(7-D): 0<I.ltoreq.50; (4-D) -50.ltoreq.II<0; (5-D)
-50.ltoreq.III.ltoreq.0; and (6-D) 0.ltoreq.IV.ltoreq.50. (7-D)
[0016] 6. The optical film according to any one of the items 1 to
5, which is formed from a cellulose acylate a raw material polymer
of the optical film. [0017] 7. The optical film according to the
item 6, wherein the cellulose acylate has an acyl substituent, the
acyl substituent is substantially only an acetyl group, and a total
substitution degree of the acyl substituent is from 2.56 to 3.00.
[0018] 8. The optical film according to the item 6, wherein the
cellulose acylate has an acyl substituent, the acyl substituent is
substantially at least two of acetyl group, propionyl group and
butanoyl group, and a total substitution degree of the acyl
substituent is from 2.50 to 3.00. [0019] 9. The optical film
according to any one of the items 1 to 8, which comprises a
compound capable of reducing Rth(550) within a range satisfying
relations (8) and (9): (Rth(A)-Rth(0))/A.ltoreq.-1.0; and (8)
0.01.ltoreq.A.ltoreq.30, (9) wherein:
[0020] Rth(A) means Rth(nm) at 550 nm of the optical film
containing the compound capable of reducing Rth(550) by A %;
[0021] Rth(0) means Rth(nm) at 550 nm of the optical film not
containing the compound capable of reducing Rth(550); and
[0022] A means a weight % of the compound capable of reducing
Rth(550) with respect to a weight of a raw material polymer of the
optical film, which is taken as 100. [0023] 10. The optical film
according to the items 1 to 9, which comprises a compound capable
of increasing .DELTA.Rth, which is represented by a relation (10),
within a range satisfying relations (11) and (12):
.DELTA.Rth=Rth(450)-Rth(650); (10)
(.DELTA.Rth(B)-.DELTA.Rth(0))/B.gtoreq.1.0; and (11)
0.01.ltoreq.B.ltoreq.30, (12) wherein:
[0024] .DELTA.Rth(B) means .DELTA.Rth(nm) of the optical film
containing the compound capable of increasing .DELTA.Rth by B
%;
[0025] .DELTA.Rth(0) means .DELTA.Rth(nm) of thje optical film not
containing the compound capable of increasing .DELTA.Rth; and
[0026] B means a weight (%) of the compound capable of increasing
.DELTA.Rth with respect to a weight of a raw material polymer of
the optical film, which is taken as 100. [0027] 11. The optical
film according to the items 1 to 10, which has a thickness of 20 to
200 .mu.m. [0028] 12. An optical compensation film comprising: an
optical film according to any one of the items 1 to 11; and an
optically anisotropic layer satisfying relations (13) and (14):
0.ltoreq.Re.ltoreq.400;and (13) -400.ltoreq.Rth.ltoreq.400, (14)
wherein Re and Rth are an in-plane retardation and a retardation in
a thickness direction of the optically anisotropic layer,
respectively, which are measured with a light having a wavelength
within a visible region. [0029] 13. The optical compensation film
according to the item 12, wherein the optically anisotropic layer
contains a discotic liquid crystal. [0030] 14. The optical
compensation film according to the item 12 or 13, wherein the
optically anisotropic layer contains a cholesteric liquid crystal.
[0031] 15. The optical compensation film according to any one of
the items 12 to 14, wherein the optically anisotropic layer
contains a rod-shaped liquid crystal. [0032] 16. The optical
compensation film according to any one of the items 12 to 15,
wherein the optically anisotropic layer contains a polymer film.
[0033] 17. The optical compensation film according to any one of
the items 12 to 16, wherein the polymer compound constituting the
optically anisotropic layer contains at least a polymer material
selected from the group consisting of polyamide, polyimide,
polyester, polyether ketone, polyamidimide, polyesterimide, and
polyarylether ketone. [0034] 18. A polarizing plate comprising: a
polarizer; and an optical film according to any one of the items 1
to 11 or an optical compensation film according to any one of the
items 12 to 17. [0035] 19. A liquid crystal display comprising an
optical film according to any one of the items 1 to 11, at least
one optical compensation film according to any one of the items 12
to 17 or a polarizing plate according to the item 18. [0036] 20. A
liquid crystal display comprising: an optical film according to any
one of the items 1 to 11, at least one optical compensation film
according to any one of the items 12 to 17 or a polarizing plate
according to the item 18; and an optically anisotropic layer
satisfying relations (15) and (16): 0.ltoreq.Re.ltoreq.400;and (15)
-400.ltoreq.Rth.ltoreq.400, (16) wherein Re and Rth are an in-plane
retardation and a retardation in a thickness direction of the
optically anisotropic layer, respectively, which are measured with
a light having a wavelength within a visible region. [0037] 21. The
liquid crystal display according to the item 20, wherein the
optically anisotropic layer contains a discotic liquid crystal.
[0038] 22. The liquid crystal display according to the item 20 or
21, wherein the optically anisotropic layer contains a cholesteric
liquid crystal. [0039] 23. The liquid crystal display according to
any one of the items 20 to 22, wherein the optically anisotropic
layer contains a rod-shaped liquid crystal. [0040] 24. The liquid
crystal display according to any one of the items 20 to 23, wherein
the optically anisotropic layer contains a polymer film. [0041] 25.
The liquid crystal display according to any one of the items 20 to
24, wherein the polymer compound constituting the optically
anisotropic layer contains at least a polymer material selected
from the group consisting of polyamide, polyimide, polyester,
polyether ketone, polyamidimide, polyesterimide, and polyarylether
ketone. [0042] 26. The liquid crystal display according to any one
of the items 19 to 25, which further comprises a liquid crystal
cell containing liquid crystal molecules aligned in one of a
vertical alignment, a parallel alignment and a bent alignment in a
black display state of the liquid crystal display. [0043] 27. The
liquid crystal display according to the item 26, wherein the liquid
crystal molecules are aligned in the vertical alignment in the
black display state, and the liquid crystal display comprises an
optically anisotropic layer, the optically anisotropic layer
including a layer satisfying relations (17) and (18):
10.ltoreq.Re.ltoreq.150;and (17) 50.ltoreq.Rth.ltoreq.400, (18)
wherein Re and Rth are an in-plane retardation and a retardation in
a thickness direction of the optically anisotropic layer,
respectively, which are measured with a light having a wavelength
within a visible region. [0044] 28. The liquid crystal display
according to the item 26, wherein the liquid crystal molecules are
aligned in the parallel alignment in the black display state, and
the liquid crystal display comprises an optically anisotropic
layer, the optically anisotropic layer including a layer satisfying
any one of relations from (19) to (22): 100.ltoreq.Re.ltoreq.400,
and -50.ltoreq.Rth.ltoreq.50; (19) 0.ltoreq.Re.ltoreq.20, and
-400.ltoreq.Rth.ltoreq.-50; (20) 60.ltoreq.Re.ltoreq.200, and
20.ltoreq.Rth.ltoreq.120; and (21) 30.ltoreq.Re.ltoreq.150, and
100.ltoreq.Rth.ltoreq.400, (22) wherein Re and Rth are an in-plane
retardation and a retardation in a thickness direction of the
optically anisotropic layer, respectively, which are measured with
a light having a wavelength within a visible region. [0045] 29. The
liquid crystal display according to the item 26, wherein the liquid
crystal molecules are aligned in the bent alignment in the black
display state, and the liquid crystal display comprises an
optically anisotropic layer, the optically anisotropic layer
including a layer containing a discotic liquid crystal
compound.
BRIEF DESCRIPTION OF THE DRAWINGS
[0046] The features of the invention will appear more fully upon
consideration of the exemplary embodiments of the invention, which
are schematically set forth in the drawings, in which:
[0047] FIG. 1 is a schematic view showing an example of a liquid
crystal display of the background art;
[0048] FIG. 2 is a schematic view showing an example of a liquid
crystal display of the background art;
[0049] FIG. 3 is a schematic view showing an example of a liquid
crystal display of the background art;
[0050] FIG. 4 is a schematic view of a Poincare sphere, used for
explaining a change in a polarized state of an incident light in a
liquid crystal display of the background art;
[0051] FIG. 5 is a schematic view showing an example of a liquid
crystal display of the present invention;
[0052] FIG. 6 is a schematic view of a Poincare sphere, used for
explaining a change in a polarized state of an incident light in a
liquid crystal display of the present invention;
[0053] FIG. 7 is a graph showing optical characteristics in an
example of an optical film employed in the present invention;
[0054] FIG. 8 is a schematic view of a Poincare sphere, used for
explaining a polarized state;
[0055] FIG. 9 is a graph showing an example of a relationship
between an acyl substitution degree of cellulose acylate and Rth of
an optical film;
[0056] FIG. 10 is a graph showing an example of a relationship
between a concentration of an Rth reducing agent and Rth of an
optical film;
[0057] FIG. 11 is a graph showing an example of a relationship
between a concentration of a wavelength-dependent dispersion
regulating agent and .DELTA.Rth;
[0058] FIG. 12 is a schematic view of a Poincare sphere, used for
explaining a change in a polarized state in an incident light in a
liquid crystal display of the present invention (IPS-1 in Example
11); and
[0059] FIG. 13 is a schematic view of a Poincare sphere, used for
explaining a change in a polarized state in an incident light in a
liquid crystal display of the present invention (IPS-2 in Example
11).
DETAILED DESCRIPTION OF THE EXEMPLARY EMBODIMENTS
[0060] Although the invention will be described below with
reference to the exemplary embodiments thereof, the following
exemplary embodiments and modifications do not restrict the
invention.
[0061] An exemplary embodiment of the invention allows, through
suitable selection of materials and producing process, to
independently control a wavelength-dependent dispersion of an
in-plane retardation and a retardation in a thickness direction of
the optical compensation film and to determine optically optimum
values, thereby enabling a view angle compensation, at all the
wavelengths, in a black display state of the liquid display cell.
More specifically, as to the raw materials, selections are made on
a polymer raw material, and on a type and an amount of an additive
for controlling optical characteristics. As a result, a liquid
crystal display of an exemplary embodiment of the present invention
is improved in a light leakage in an inclined direction in a black
display state, with a significant improvement in a contrast over a
wide viewing angle. Also the liquid crystal display, being capable
of suppressing a light leakage in an inclined direction in a black
display state over the entire visible wavelength region, is
significantly improved on a color aberration on the black display
state, which is dependent on the viewing angle and which has been a
drawback in the prior technology.
[0062] In the following, an exemplary embodiment of the present
invention will be explained with reference to accompanying
drawings. One aspect of the present invention is effective in all
the liquid crystal modes, regardless of the driving system of the
liquid crystal display, but FIG. 1 shows, as an example, a
schematic view illustrating a structure of a liquid crystal display
of an ordinary VA mode. The liquid crystal display of VA mode
includes a liquid crystal cell 3 containing a liquid crystal layer,
in which liquid crystals are aligned perpendicularly to a substrate
surface in the absence of a voltage application, namely in a black
display state, and polarizing plates 1, 2 so positioned that the
liquid crystal cell 3 is sandwiched therebetween and that
directions of transmission axes thereof (indicated by stripes in
FIG. 1) are perpendicular each other. In FIG. 1, a light is assumed
to enter from the side of the polarizing plate 1. When a light
enters along z-axis in the absence of a voltage application, the
light transmitted by the polarizing plate 1 is transmitted by the
liquid crystal cell 3 while maintaining a linearly polarized state,
and is completely intercepted by the polarizing plate 2. As a
result, a high contrast image can be displayed.
[0063] However, the situation becomes different in case of an
inclined incident light, as shown in FIG. 2. When a light enters
from an inclined direction different from the direction of z-axis
and inclined with respect to the polarizing directions of the
polarizing plates 1, 2 (so-called off-axis direction), the incident
light is influenced, upon passing through the vertically aligned
liquid crystal layer of the liquid crystal cell 3, by a retardation
in an inclined direction thereby causing a change in the
polarization state. Also the apparent transmission axes of the
polarizing plates 1 and 2 are displaced from an orthogonal
relationship. Because of these two factors, the incident light from
an inclined off-axis direction is not completely intercepted by the
polarizing plate 2 to induce a light leakage in a black display
state, thereby reducing the contrast.
[0064] Now a polar angle and an azimuthal angle are defined as
follows. The polar angle means an inclination angle from a normal
direction to the film surface, namely from z-axis in FIGS. 1 and 2,
and, for example, a normal direction to the film surface is a
direction with a polar angle=0.degree.. The azimuthal angle means a
direction measured counterclockwise from a positive x-axis, and,
for example, the positive direction of x-axis has an azimuthal
angle=0.degree., and the positive direction of y-axis has an
azimuthal angle =90.degree.. The inclined off-axis direction
mentioned above means a case where the polar angle is non-zero, and
principally indicates a case where the azimuthal angle is 45, 135,
225 or 315.degree..
[0065] FIG. 3 is a schematic view showing a structure for
explaining the function of a polarized light in an ordinary liquid
crystal display. The structure shown in FIG. 3 includes, in
addition to the structure shown in FIG. 1, an optical compensation
film 4 between the liquid crystal cell 3 and the polarizing plate
1. In the VA-mode liquid crystal display of such structure, the
optical compensation film 4 generally has, at a wavelength of 550
nm, Re(550) of from about 20 to 100 nm and Rth(550) of from about
100 to 300 nm. Also when the optical compensation film 4 is
prepared from a material having a positive refractive index
anisotropy, it generally meets conditions of Re(450)
>Re(550).gtoreq.Re(650) and
Rth(450).gtoreq.Rth(550).gtoreq.Rth(650), thus having Re and Rth
larger at a shorter wavelength.
[0066] FIG. 4 explains the compensation mechanism shown in FIG. 3,
by a Poincare sphere. The Poincare sphere is a three-dimensional
map describing a polarization state, wherein a position on an
equator of the sphere indicates a linearly polarized light. The
light propagates in a direction with an azimuthal angle of
45.degree. and a polar angle of 34.degree.. In FIG. 4, an S2-axis
perpendicularly penetrates the plane of drawing from above to
below, and FIG. 4 shows a view of the Poincare sphere from the
positive side of the S2-axis. In FIG. 4 which is a planar
representation, a displacement between points before and after a
change in the polarization state is represented by a linear arrow
shown therein, but a change in the polarization state by passing
through the liquid crystal layer or the optical compensation film
is represented, on the actual Poincare sphere, by a rotation by a
specified angle about a specified axis determined according to the
optical characteristics.
[0067] A polarization state of the incident light, after passing
the polarizing plate 1 in FIG. 3, corresponds to a point (i) in
FIG. 4, and a polarization state to be intercepted by the
absorption axis of the polarizing plate 2 in FIG. 3 corresponds to
a point (ii) in FIG. 4. In the prior VA-mode liquid crystal
display, a light leakage in the inclined off-axis direction results
from a fact that the points (i) and (ii) are displaced each other.
The optical compensation film is generally used for changing the
polarization state of the incident light from the point (i) to the
point (ii), including a change in the polarization state in the
liquid crystal layer. Since the liquid crystal layer of the liquid
crystal cell 3 shows a positive refractive index anisotropy and has
a vertical alignment, a change in the polarization state of the
incident light, caused by passing the liquid crystal layer, is
represented, on the Poincare sphere, by a downward arrow in FIG. 4
or a rotation about an S1-axis.
[0068] A rotation angle about the S1-axis is proportional to a
value .DELTA.n'd'/.lamda. obtained by dividing an effective
retardation .DELTA.n'd' in an inclined direction of the liquid
crystal layer with the wavelength .lamda. of the light, so that the
rotation angle becomes different among the different wavelengths of
R, G and B. Therefore, after the rotation, a light of either of the
wavelengths R, G and B becomes displaced from the point (ii). The
light of such displaced wavelength is not intercepted by the
polarizing plate 2, thereby causing a light leakage. Since a color
of the light is defined by a sum of R, G and B, a light leakage of
a specified wavelength results in a change in the proportion, in
the sum of R, G and B, thereby causing a color shift. This
phenomenon is observed as a "color shift" when a liquid crystal
display is observed from an inclined direction.
[0069] In the present specification, the lights of R, G and B are
represented respectively by wavelengths of 650 nm for R, 550 nm for
G and 450 nm for B. These wavelengths may not necessarily represent
the lights or R, G and B, but are considered suitable for defining
optical characteristics providing the effects of the present
invention.
[0070] As explained above, when the optical compensation film 4 is
prepared from a material having a positive refractive index
anisotropy, it generally meet conditions of
Re(450).gtoreq.Re(550).gtoreq.Re(650) and
Rth(450).gtoreq.Rth(550).gtoreq.Rth(650), thus having Re and Rth
larger at a shorter wavelength, so that, when the liquid crystal
display is observed from an inclined direction, the effective
retardation becomes larger for a shorter wavelength
(R.ltoreq.G.ltoreq.B). As the displacement amount from the point
(i) is dependent on the magnitude of such effective retardation,
the displacement amounts become R.ltoreq.G.ltoreq.B so that the
three points do not match mutually.
[0071] Also as to the change in the polarization state of the light
upon passing through the liquid crystal cell, since the liquid
crystal molecules of the liquid crystal cell generally have a
positive intrinsic birefringence and have Re and Rth larger in a
shorter wavelength, the effective retardation when the liquid
crystal display is observed from an inclined direction becomes
larger for a shorter wavelength. Therefore the displacement to the
point (ii) becomes larger for a shorter wavelength and the lights
of R, G and B assume a positional relationship as shown in FIG.
4.
[0072] According to one aspect of the present invention, therefore,
an optical film 5 is employed for matching the positions of R, G
and B at the point (ii). FIG. 5 is a schematic view showing an
example of structure, for explaining a function of the present
invention. The optical film 5 of the invention is positioned
between the liquid crystal cell 3 and the polarizing plate 2, but
such position is not particularly restricted in the present
invention.
[0073] FIG. 6 is a view explaining a compensation mechanism in the
structure shown in FIG. 5, utilizing a Poincare sphere. Insertion
of an optical film 5 allows to match the lights of R, G and B at a
substantially same point. More specifically, optical compensations
are made on the lights of wavelengths R, G and B, entering in an
inclined direction, with a phase retarding axis and a retardation
respectively different for each wavelength. More specifically,
among R, G and B, a wavelength R (650 nm) is in a position at upper
right to the point (ii), and a left-downward displacement to the
point (ii) requires a positive Re(650) and a negative Rth(650) in
the optical film 5. Similarly, as a wavelength G (550 nm) need not
be displaced from the point (ii), Re(550) and Rth(550) may both be
zero. Also a wavelength B (450 nm) is in a position at lower left
to the point (ii), and a right-upward displacement to the point
(ii) requires a negative Re(450) and a positive Rth(450) in the
optical film 5. In the optical film 5 having such optical
characteristics, the wavelength dependences of Re and Rth are shown
in FIG. 7.
[0074] The foregoing discussion is applicable, in the optical
compensation in an ordinary liquid crystal display, to all the
cases where a central wavelength G (550 nm) is matched with the
point (ii) but wavelengths R and B are not matched with this point.
FIG. 8 is a magnified view of a peripheral area around the point
(ii) on the Poincare sphere, with points 1-9 displaced from the
point (ii), and Table 1 shows the properties required for the
optical film 5 for displacing these points 1-9 to the point (ii).
In FIG. 8 and Table 1, a point 5 is same as the point (ii).
TABLE-US-00001 TABLE 1 position Re Rth 1 negative negative 2 0
negative 3 positive negative 4 negative 0 5 0 0 6 positive 0 7
negative positive 8 0 positive 9 positive positive
[0075] The cases where, among the wavelengths R, G and B, the
wavelength G (550 nm) is matched with the target point 5 but
wavelengths R and B cannot be matched with the point 5, can be
divided into cases (1) to (8) in Table 2, utilizing the points 1 to
9 in FIG. 8, and these cases can be classified into four classes
A=(1) and (2), B=(3) and (4), C=(5) and (6) and D=(7) and (8) (cf.
Table 2). The Re and Rth values required for the optical film 5 are
obtained from Table 1, and the wavelength dependences of Re and Rth
are summarized in Table 3. TABLE-US-00002 TABLE 2 Position class
case B (450 nm) G (550 nm) R (650 nm) A (1) 2 5 8 (2) 1 5 9 B (3) 4
5 6 (4) 7 5 3 C (5) 8 5 2 (6) 9 5 1 D (7) 6 5 4 (8) 3 5 7 Ideal 5 5
5
[0076] In the foregoing description, there is shown a case where,
among the wavelengths R, G and B, the central wavelength G (550 nm)
becomes an ideal point (ii), where both Re(550) and Rth(550) are
zero, but, in an actual liquid crystal display, it may be difficult
to realize a situation where both Re(550) and Rth(550) are
completely zero. Though it is desirable that Re(550) and Rth(550)
are both zero as far as possible, the present inventors find, as a
range where Re(550) and Rth(550) are close to zero and color shifts
are tolerable, that the optical film of the invention should have
optical performances of 0.ltoreq.Re(550).ltoreq.10 nm and
-25.ltoreq.Rth(550).ltoreq.25 (nm), preferably
0.ltoreq.Re(550).ltoreq.5 nm and -15.ltoreq.Rth(550).ltoreq.15
(nm).
[0077] Thus, according to one aspect of the present invention, the
wavelengths R, G and B, which are separated in front of the
polarizing plate at the exit side of the liquid crystal display,
may be made to coincide thereby avoiding the light leakage, by
utilizing an optical film of a wavelength dependence selected among
A, B, C and D classified in Table 3. Therefore, in any liquid
crystal mode or in the structure with any optical material or any
optical components, the optical film of the invention allows to
prevent a color shift in an observation from an inclined direction,
by wavelength dependences of Re and Rth selected among A, B, C and
D classified in Table 3. Thus the scope of the present invention is
not restricted by the display mode of the liquid crystal layer but
is applicable to the liquid crystal display with the liquid crystal
layer of any display mode, such as a VA mode, an IPS mode, an OCB
mode, a TN mode or an ECB mode.
[0078] An optical film of the present invention is characterized in
that a retardation thereof satisfies relations (1) to (3):
0.ltoreq.Re(550).ltoreq.10; (1) -25.ltoreq.Rth(550).ltoreq.25; and
(2) |I|+|II|+|III|+|IV|>0.5 (nm), (3) wherein:
I=Re(450)-Re(550); II=Re(650)-Re(550); III=Rth(450)-Rth(550); and
IV=Rth(650)-Rth(550).
[0079] The relations (1) and (2) indicate, as described above, that
Re(550) and Rth(550) have to be as close to zero as possible in the
optical film of the invention. The relation (3) indicates that
appropriate wavelength dependences are necessary for Re and Rth, in
order to match R, G and B on the liquid crystal display. A film of
an optical performance not satisfying the relation (3) has scarce
wavelength dependences for Re and Rth, and is incapable of reducing
the color shift found when the liquid crystal display is observed
from an inclined direction.
[0080] The relation (3) is preferably |I|+|II|+|III|+|IV|>2.0
(nm), more preferably |I|+|II|+|III|+|IV|>4.0 (nm).
[0081] The optical film of the invention can be classified into A,
B, C and D as described above, which respectively have following
optical performances.
[0082] Among the optical films of the invention, an optical film
belonging to the class A meets the relations (1) to (3) above and
preferably satisfies following relations (4-A) to (7-A):
-50.ltoreq.I.ltoreq.0; (4-A) 0.ltoreq.II.ltoreq.50; (5-A)
-50.ltoreq.III<0; and (6-A) 0<IV.ltoreq.50, (7-A) and more
preferably: -25.ltoreq.I.ltoreq.0; (4-A') 0.ltoreq.II.ltoreq.25;
(5-A') -25.ltoreq.III<0; and (6-A') 0<IV.ltoreq.25.
(7-A')
[0083] Among the optical films of the invention, an optical film
belonging to the class B meets the relations (1) to (3) above and
preferably satisfies following relations (4-B) to (7-B):
-50.ltoreq.I<0; (4-B) 0<II.ltoreq.50; (5-B)
0.ltoreq.III.ltoreq.50; and (6-B) -50.ltoreq.IV.ltoreq.0, (7-B) and
more preferably: -25.ltoreq.I<0; (4-B') 0<II.ltoreq.25;
(5-B') 0.ltoreq.III.ltoreq.25; and (6-B') -25.ltoreq.IV.ltoreq.0.
(7-B')
[0084] Among the optical films of the invention, an optical film
belonging to the class C meets the relations (1) to (3) above and
preferably satisfies following relations (4-C) to (7-C):
0.ltoreq.I.ltoreq.50; (4-C) -50.ltoreq.II.ltoreq.0; (5-C)
0<III.ltoreq.50; and (6-C) -50.ltoreq.IV<0, (7-C) and more
preferably: 0.ltoreq.I.ltoreq.25; (4-C') -25.ltoreq.II.ltoreq.0;
(5-C') 0<III.ltoreq.25; and (6-C') -25.ltoreq.IV<0.
(7-C')
[0085] Among the optical films of the invention, an optical film
belonging to the class D meets the relations (1) to (3) above and
preferably satisfies following relations (4-D) to (7-D):
0<I.ltoreq.50; (4-D) -50.ltoreq.II<0; (5-D)
-50.ltoreq.III.ltoreq.0; and (6-D) 0.ltoreq.IV.ltoreq.50, (7-D) and
more preferably: 10.ltoreq.I.ltoreq.50; (4-D')
-50.ltoreq.II.ltoreq.-10; (5-D') -50.ltoreq.III.ltoreq.-30; and
(6-D') 30.ltoreq.IV.ltoreq.50. (7-D') (Retardation and
Wavelength-Dependent Dispersion Thereof)
[0086] In the present specification, Re(.lamda.) and Rth(.lamda.)
respectively indicate an in-plane retardation and a retardation in
a thickness direction, at a wavelength .lamda.. Re(.lamda.) can be
measured, in an instrument KOBRA 21ADH (manufactured by Oji
Scientific Instruments Ltd.), by introducing a light of a
wavelength of .lamda. nm in a normal direction to the film surface.
Rth(.lamda.) can be obtained by measuring Re(.lamda.) at 11 points
with a light of a wavelength of .lamda. nm introduced with
inclination angles of from -50.degree. to +50.degree. at a pitch of
10.degree. with respect to the normal direction to the film
surface, taking an in-plane phase-retarding axis (judged by KOBRA
21ADH) as an inclination axis (rotation axis), and by a calculation
executed by KOBRA 21ADH based on thus measured retardations, an
assumed average refractive index and an entered film thickness. In
case of an IPS mode, Rth(.lamda.) is obtained by measuring
Re(.lamda.) at 6 points with a light of a wavelength of .lamda. nm
introduced with inclination angles of from a normal direction to
the film surface to 50.degree. at a pitch of 10.degree. with
respect to the normal direction, taking an in-plane phase-retarding
axis (judged by KOBRA 21ADH) as an inclination axis (rotation axis)
(in the absence of a phase-retarding axis, an arbitrary direction
in the film plane being taken as a rotary axis), and by a
calculation executed by KOBRA 21ADH based on thus measured
retardations, an assumed average refractive index and an entered
film thickness. It is also possible to measure retardations at two
arbitrary directions, taking the phase-retarding axis as an
inclination axis (rotation axis) (in the absence of a
phase-retarding axis, an arbitrary direction in the film plane
being taken as a rotary axis), and to calculate Rth based on thus
measured values, an assumed average refractive index and an entered
film thickness, according to following equations (1) and (2). The
assumed average refractive index may be obtained from Polymer
Handbook (John Wiley & Sons, Inc.) or from catalog values of
various optical films. An average refractive index, if not already
known, may be obtained by a measurement with Abbe's refractometer.
Examples of the average refractive index on principal optical films
are as follows: cellulose acylate 1.48, cycloolefin polymer 1.52,
polycarbonate 1.59, polymethyl methacrylate 1.49, and polystyrene
1.59. The KOBRA 21ADH calculates nx, ny and nz based on such
assumed average refractive index and a film thickness, and further
calculates Nz=(nx-nz)/(nx-ny) based on thus calculated nx, ny and
nz. Re .function. ( .theta. ) = .times. [ nx - ny .times. nz { ny
.times. .times. sin .function. ( sin - 1 .function. ( sin .times. (
- .theta. ) nx ) ) } 2 + { nx .times. .times. cos .times. ( sin - 1
.times. ( sin .function. ( - .theta. ) .times. nx ) ) } 2 ] .times.
.times. d cos .times. { sin - 1 .function. ( sin .function. ( -
.theta. ) nx ) } ( 1 ) ##EQU1## Note: Re(.theta.) indicates a
retardation in a direction inclined by an angle .theta. from the
normal direction. Rth=((nx+ny)/2-nz).times.d (2) In the equations
(1) and (2), d indicates a film thickness. (Material for Optical
Film)
[0087] A material constituting the optical film of the invention is
preferably a polymer satisfactory in optical performance,
transparency, mechanical strength, thermal stability, moisture
shielding property, isotropic property and the like, and may be any
material having Re and Rth within the ranges meeting the
aforementioned optical performances. Examples of such polymer
include a polycarbonate-type polymer, a polyester polymer such as
polyethylene terephthalate or polyethylene naphthalate, an acrylic
polymer such as polymethyl methacrylate, and a styrenic polymer
such as polystyrene or an acrylonitrile-styrene copolymer (AS
resin). Examples further include a polyolefin such as polyethylene
or polypropylene, a polyolefnic polymer such as an
ethylene-propylene copolymer, a vinyl chloride-based polymer, an
amide-based polymer such as nylon or an aromatic polyamide, an
imide-based polymer, a sulfone-based polymer, a
polyethersulfone-type polymer, a polyether ether ketone-type
polymer, a polyphenylene sulfide-type polymer, a vinylidene
chloride-based polymer, a vinyl alcohol-based polymer, a vinyl
butyral-based polymer, an allylate-based polymer, a
polyoxymethylene-type polymer, an epoxy polymer, and a polymer
mixture thereof.
[0088] Also as the material constituting the optical film of the
invention, a thermoplastic norbornene resin may be employed
preferably, such as Zeonex or Zeonor manufactured by Nippon Zeon
Ltd. or Arton manufactured by JSR Corp.
[0089] Also as the material constituting the optical film of the
invention, a cellulose-based polymer (hereinafter called cellulose
acylate), that has been employed as a transparent protective film
for a polarizing plate, may be employed particularly preferably.
Representative examples of cellulose acylate include triacetyl
cellulose. In the following, cellulose acylate will be explained in
detail.
(Raw Material Cotton for Cellulose Acylate)
[0090] Raw material cellulose for the cellulose acylate to be
employed in the optical film of the invention includes cotton
linter and wood pulp (broad-leaf pulp or needle-leaf pulp), and
cellulose acylate obtained from any raw material cellulose may be
usable, eventually as a mixture of plural kinds. Such raw material
cellulose is described in detail, for example, in Plastic Zairyo
Koza (17), cellulose fibers (Marusawa & Uda, Nikkan Kogyo
Shimbun, 1970) and in Japan Institute of Invention and Innovation,
Journal of Technical Disclosure 2001-1745 (p.7-8), and any
cellulose described therein may be utilized without any particular
restriction for the cellulose acylate film.
(Substitution Degree of Cellulose Acylate)
[0091] In the following, cellulose acylate produced from the
aforementioned cellulose will be explained. The cellulose acylate
is obtained by acylating hydroxyl groups of cellulose, with a
substituent that may be any one from an acetyl group containing 2
carbon atoms to a substituent containing 22 carbon atoms. Cellulose
acylate is not particularly restricted in a substitution degree in
the hydroxyl groups of cellulose, but a substitution degree can be
obtained by measuring and calculating a bonding degree of acetic
acid and/or a fatty acid containing 3 to 22 carbon atoms,
substituted on the hydroxyl groups of cellulose. The measurement
may be executed according to ASTM D-817-91.
[0092] In cellulose acylate, the substitution degree in the
hydroxyl groups of cellulose is not particularly restricted as
described above, but is preferably within a range of from 2.50 to
3.00, more preferably from 2.56 to 3.00 and further preferably from
2.75 to 3.00. A higher acyl substitution degree allows to reduce
the optical anisotropy of the film.
[0093] Among acetic acid and/or a fatty acid containing 3 to 22
carbon atoms, to be substituted on the hydroxyl groups of
cellulose, an acyl group containing 2 to 22 carbon atoms may be an
aliphatic group or an aryl group, and may be a single group or a
mixture of plural groups. Examples thereof include an alkyl
carbonyl ester, an alkenyl carbonyl ester, an aromatic carbonyl
ester or an aromatic alkyl carbonyl ester of cellulose, each of
which may further have a substituent. Preferred examples of such
acyl group include acetyl, propionyl, butanoyl, heptanoyl,
hexanoyl, octanoyl, decanoyl, dodecanoyl, tridecanoyl,
tetradecanoyl, hexadecanoyl, octadecanoyl, iso-butanoyl,
t-butanoyl, cyclohexanecarbonyl, oleoyl, benzoyl, naphthylcarbonyl,
and cinnamoyl. Among these, acetyl, propionyl, butanoyl,
dodecanoyl, octadecanoyl, t-butanoyl, oleoyl, benzoyl,
naphthylcarbonyl, and cinnamoyl are preferable, and acetyl,
propionyl and butanoyl are more preferable.
[0094] As a result of intensive investigations undertaken by the
present inventors, it is found that, in the case where the acyl
substituents on the hydroxyl groups of cellulose are substantially
at least two kinds selected from an acetyl group, a propionyl group
and a butanoyl group, the optical anisotropy of the cellulose
acylate film can be reduced when the total substitution degree is
within a range of from 2.50 to 3.00. The acyl substitution degree
is more preferably from 2.60 to 3.00, and further preferably from
2.65 to 3.00.
(Polymerization Degree of Cellulose Acylate)
[0095] The cellulose acylate advantageously employed in the
invention has a polymerization degree, in a viscosity-average
polymerization degree, of from 180 to 700, and, in the case of
cellulose acetate, it is more preferably from 180 to 550, further
preferably from 180 to 400 and particularly preferably from 180 to
350. An excessively high polymerization degree increases the
viscosity of a dope solution of cellulose acylate, whereby a film
preparation by a casting method may become difficult. Also an
excessively low polymerization degree reduces the strength of the
prepared film. An average polymerization degree can be measured by
a limit viscosity method proposed by Uda et al. (Kazuo Uda and
Hideo Saito, J. of Soc. of Fiber Science and Technology, vol. 18,
No. 1, p.105-120, 1962), and described in detail in JP-A-9-95538.
The optical film of the invention, prepared from cellulose acylate
in which acyl substituents are substantially constituted of acetyl
groups only and which has an average polymerization degree of from
180 to 550, can exhibit particularly satisfactory performances.
[0096] In cellulose acylate advantageously employed in the
invention, a molecular weight distribution is evaluated by gel
permeation chromatography, and preferably has a narrow distribution
with a small dispersion index Mw/Mn (Mw: weight-average molecular
weight, Mn: number-average molecular weight), preferably within a
range of from 2.0 to 4.0, more preferably from 2.0 to 3.5, and most
preferably from 2.3 to 3.3
[0097] Elimination of low-molecular components is effective as it
reduces the viscosity than in ordinary cellulose acylate, in spite
of an increase in the average molecular weight (polymerization
degree). Cellulose acylate with reduced low-molecular components
may be obtained by removing low-molecular components from cellulose
acylate synthesized by an ordinary method. The removal of the
low-molecular components may be executed by washing cellulose
acylate with an appropriate organic solvent. In case of producing
cellulose acylate with reduced low-molecular components, an amount
of sulfuric acid catalyst in the acylation reaction is preferably
regulated to 0.5 to 25 parts by weight, with respect to 100 parts
by weight of cellulose. The sulfuric acid catalyst, employed in an
amount of the aforementioned range, allows to synthesize cellulose
acylate that is preferable also in the molecular weight
distribution (having a uniform molecular weight distribution). At
the manufacture of cellulose acylate, it has a water content
preferably of 2 wt % or less, more preferably 1 wt % or less, and
particularly preferably 0.7 wt % or less. Cellulose acylate
generally contains water, normally about 2.5 to 5 wt %. In order to
realize the aforementioned water content in the invention, a drying
is necessary, and it may be executed by any method as long as a
desired water content is attained. For the cellulose acylate to be
employed in the invention, a raw material cotton and a synthesizing
method are described in detail in Japan Institute of Invention and
Innovation, Journal of Technical Disclosure (No. 2001-1745, issued
Mar. 15, 2001, JIII), p. 7-12.
[0098] Cellulose acylate, having substituents, a substitution
degree, a polymerization degree and a molecular weight distribution
within the aforementioned ranges, may be employed singly or in a
mixture of two or more different cellulose acylates.
(Additives to Optical Film)
[0099] In a solution for preparing the optical film of the
invention, various additives (such as a compound for reducing
optical anisotropy, a compound for increasing optical anisotropy,
an agent for regulating wavelength-dependent dispersion, an
ultraviolet absorber, a plasticizer, an anti-aging agent, fine
particles and an optical characteristics regulating agent) may be
added according to the purpose in each preparation step, and such
additives will be explained below. Also such addition may be
executed at any timing within a dope preparing process, or in an
additive-adding step, to be added after a final adjustment step in
the dope preparation process.
(Compound for Reducing Rth)
[0100] The optical film of the invention preferably contains at
least a compound capable of reducing a retardation Rth(550) in the
thickness direction of the film (such compound being hereinafter
referred to as Rth reducing agent), within a range capable of
meeting relations (8) and (9): (Rth(A)-Rth(0))/A.ltoreq.-1.0; and
(8) 0.01.ltoreq.A.ltoreq.30. (9)
[0101] The relations (8) and (9) are more preferably represented
as: (Rth(A)-Rth(0))/A.ltoreq.-2.0; and (8')
0.01.ltoreq.A.ltoreq.20, (9') and further preferably represented
as: (Rth(A)-Rth(0))/A.ltoreq.-3.0; and (8'')
0.01.ltoreq.A.ltoreq.15, (9'') wherein:
[0102] Rth(A) means Rth(nm) at 550 nm of an optical film containing
the compound capable of reducing Rth(550) by A %;
[0103] Rth(0) means Rth(nm) at 550 nm of an optical film not
containing the compound capable of reducing Rth(550); and
[0104] A means a weight (%) of the compound capable of reducing
Rth(550) with respect to the weight (taken as 100) of the raw
material polymer of the optical film.
(Structural Characteristics of Rth Reducing Agent)
[0105] A structure and a function of the Rth reducing agent, in the
optical film of the invention, will be explained below. In order to
sufficiently reduce the optical anisotropy and to bring both Re and
Rth close to zero, it is preferable to utilize a compound capable
of suppressing the high-molecular polymer in the optical film from
being aligned in the in-plane direction and in the thickness
direction. Also the compound for reducing optical anisotropy is
preferably sufficiently soluble mutually with the high-molecular
polymer and is preferably free from a rod-shaped structure or a
planar structure in the compound itself. More specifically, when
the compound has plural planar functional groups such as aromatic
groups, such functional groups preferably are not positioned on a
common plane but are provided in a non-planar structure.
[0106] The Rth reducing agent may or may not include an aromatic
group. Also the Rth reducing agent has a molecular weight
preferably within a range of from 150 to 3,000, more preferably
from 170 to 2,000, and particularly preferably from 200 to 1,000.
Within such molecular weight range, it may have a specified monomer
structure, or an oligomer structure or a polymer structure in which
a plurality of such monomer units are bonded.
[0107] (Log P Value)
[0108] In the preparation of an optical film of the invention, in
case of employing a hydrophilic polymer such as cellulose acylate
as a raw material, it is preferable to utilize, as the Rth reducing
agent for suppressing the high-molecular polymer in the film from
being aligned in the in-plane direction and in the thickness
direction, a compound having an octanol-water distribution
coefficient (log p value) within a range of from 0 to 7. A compound
having a log P value of 7 or less shows an excellent mutual
solubility with the high-molecular polymer, thus not causing
drawbacks such as white turbidity or dusty surface in the film.
Also a compound having a log P value of 0 or more does not become
excessively hydrophilic, thus not causing a drawback such as a
deteriorated water resistance of the cellulose acetate film. The
log P value is more preferably within a range of from 1 to 6, and
particularly preferably from 1.5 to 5.
[0109] The octanol-water distribution coefficient (log P value) can
be measured by a flask shaking method described in JIS
Z-7260-107(2000). Also the octanol-water distribution coefficient
(log P value) may be estimated, instead of an actual measurement,
by a chemical calculational method or an empirical method. The
preferred calculational methods include Crippen's fragmentation
method {J. Chem. Inf. Comput. Sci., vol. 27, p. 21(1987)},
Viswanadhan's fragmentation method {J. Chem. Inf. Comput. Sci.,
vol. 29, p. 163(1989)}, and Broto's fragmentation method {Eur. J.
Med. Chem.--Chim. Theor., vol. 19, p. 71(1984)}, among which
Crippen's fragmentation method is more preferable. When a compound
shows different log P values by the measuring method and the
calculational method, whether such compound is within the scope of
the invention is to be judged by Crippen's fragmentation
method.
[0110] (Physical Properties of Rth Reducing Agent)
[0111] The Rth reducing agent is preferably a liquid at 25.degree.
C. or a solid having a melting point of from 25 to 250.degree. C.,
and more preferably a liquid at 25.degree. C. or a solid having a
melting point of from 25 to 200.degree. C. Also the Rth reducing
agent preferably does not evaporate in the steps of dope casting
and drying in preparing the high-molecular polymer film.
[0112] The Rth reducing agent is preferably added in an amount of
from 0.01 to 30 wt % of the high-molecular polymer, more preferably
from 0.05 to 25 wt % and particularly preferably from 0.1 to 20 wt
%.
[0113] The Rth reducing agent may be employed singly or in a
mixture of two or more compounds in an arbitrary ratio. The Rth
reducing agent may be added at any step in the dope preparing
process, or at the end of the dope preparing process.
[0114] For such Rth reducing agent, compounds disclosed in
JP-A-2005-139304 may be employed advantageously. Among these,
preferred is a compound represented by a following formula (1),
which will be explained below: ##STR1##
[0115] In the formula (1), R.sup.11 represents an alkyl group or an
aryl group; and R.sup.12 and R.sup.13 each independently represents
a hydrogen atom, an alkyl group or an aryl group. R.sup.11,
R.sup.12 and R.sup.13 particularly preferably contain 10 or more
carbon atoms in total, and the alkyl group or the aryl group may
further have a substituent.
[0116] The substituent is preferably a fluorine atom, an alkyl
group, an aryl group, an alkoxy group, a sulfone group or a
sulfonamide group, and particularly preferably an alkyl group, an
aryl group, an alkoxy group, a sulfone group or a sulfonamide
group.
[0117] The alkyl group may be linear, branched or cyclic, and
preferably contains 1 to 25 carbon atoms, more preferably 6 to 25
carbon atoms and particularly preferably 6 to 20 carbon atoms (such
as methyl, ethyl, propyl, isopropyl, butyl, isobutyl, t-butyl,
amyl, isoamyl, t-amyl, hexyl, cyclohexyl, heptyl, octyl,
bicyclooctyl, nonyl, adamantyl, decyl, t-octyl, undecyl, dodecyl,
tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecyl,
nonadecyl or didecyl).
[0118] The aryl group preferably contains 6 to 30 carbon atoms, and
particularly preferably 6 to 24 carbon atoms (such as phenyl,
biphenyl, terphenyl, naphthyl, binaphthyl or triphenylphenyl).
Preferable examples of the compound represented by the formula (1)
are shown below, but the present invention is not limited to such
specific examples. ##STR2## ##STR3## ##STR4## ##STR5## ##STR6##
##STR7## ##STR8##
[0119] Other examples of the Rth reducing agent include a compound
represented by a following formula (2): ##STR9##
[0120] In the formula (2), R.sup.21 represents an alkyl group or an
aryl group; and R.sup.22 and R.sup.23 each independently represents
a hydrogen atom, an alkyl group or an aryl group. The alkyl group
may be linear, branched or cyclic, and preferably contains 1 to 20
carbon atoms, more preferably 1 to 15 carbon atoms and most
preferably 1 to 12 carbon atoms. The cyclic alkyl group is
particularly preferably a cyclohexyl group. The aryl group
preferably contains 6 to 36 carbon atoms, and more preferably 6 to
24 carbon atoms. Also R.sup.21 and R.sup.22 preferably contain 10
or more carbon atoms in total, and the alkyl group or the aryl
group may further have a substituent.
[0121] The alkyl group or aryl group may have a substituent, and
such substituent is preferably a halogen atom (such as chlorine,
bromine, fluorine or iodine), an alkyl group, an aryl group, an
alkoxy group, an aryloxy group, an acyl group, an alkoxycarbonyl
group, an aryloxycarbonyl group, an acyloxy group, a sulfonylamino
group, a hydroxyl group, a cyano group, an amino group or an
acylamino group, more preferably a halogen atom, an alkyl group, an
aryl group, an alkoxy group, an aryloxy group, a sulfonylamino
group or an acylamino group, and particularly preferably an alkyl
group, an aryl group, a sulfonylamino group or an acylamino
group.
[0122] Preferable examples of the compound represented by the
formula (2) are shown below, but the present invention is not
limited to such specific examples. ##STR10## ##STR11## ##STR12##
##STR13## ##STR14## ##STR15## ##STR16## ##STR17## ##STR18##
##STR19## ##STR20## ##STR21## ##STR22## (Wavelength-Dependent
Dispersion Regulating Agent)
[0123] The optical film of the invention preferably contains, in
case of increasing the optical anisotropy at the shorter wavelength
side, at least a compound capable of increasing .DELTA.Rth and
represented by a following formula (10) (such compound being
hereinafter called a wavelength-dependent dispersion regulating
agent), within a range capable of meeting relations (11) and (12).
Though depending on the type of polymer employed as the raw
material for the optical film and on a combination with other
additives such as the Rth reducing agent, it is preferable, in case
of increasing Rth at the shorter wavelength side (class B or C in
Table 3 above), to increase the amount of the wavelength-dependent
dispersion regulating agent with respect to a unit amount of the
raw material polymer for the film. On the other hand, in case of
decreasing Rth at the shorter wavelength side (class A or D in
Table 3 above), it is preferable to decrease the amount of the
wavelength-dependent dispersion regulating agent or not to use the
same: .DELTA.Rth=Rth(450)-Rth(650); (10)
(.DELTA.Rth(B)-.DELTA.Rth(0))/B.gtoreq.1.0; and (11)
0.01.ltoreq.B.ltoreq.30. (12)
[0124] The relations (11) and (12) are more preferably represented
as: (.DELTA.Rth(B)-.DELTA.Rth(0))/B.gtoreq.5.0; and (11')
0.05.ltoreq.B.ltoreq.20, (12') and further preferably represented
as: (.DELTA.Rth(B)-.DELTA.Rth(0))/B.gtoreq.10.0; and (11'')
0.1.ltoreq.B.ltoreq.10, (12'') wherein:
[0125] .DELTA.Rth(B) means .DELTA.Rth(nm) of an optical film
containing the compound capable of increasing .DELTA.Rth, by B
%;
[0126] .DELTA.Rth(0) means .DELTA.Rth(nm) of an optical film not
containing the compound capable of increasing .DELTA.Rth; and
[0127] B means a weight (%) of the compound capable of increasing
.DELTA.Rth with respect to the weight (taken as 100) of the raw
material polymer of the optical film.
[0128] As the wavelength-dependent dispersion regulating agent, it
is preferable to use at least a compound having an absorption
within an ultraviolet region of from 200 to 400 nm. A compound
having an absorption within an ultraviolet region of from 200 to
400 nm has wavelength-dependent dispersion characteristics showing
an absorbance larger in a shorter wavelength side than in a longer
wavelength side. When such compound is isotropically present inside
the optical film, the wavelength-dependent dispersion of the
birefringence of the compound itself and also of the optical
characteristics is estimated to be larger in the shorter wavelength
side, as in the wavelength-dependent dispersion of the
absorbance.
[0129] Therefore, the aforementioned compound, which has an
absorption in the ultraviolet region of from 200 to 400 nm and
which is assumed to have a wavelength-dependent dispersion of the
optical characteristics of the compound itself larger at the
shorter wavelength side, allows to regulate the
wavelength-dependent dispersion of the optical characteristics of
the optical film. For this purpose, the compound for regulating the
wavelength-dependent dispersion is required to be sufficiently
soluble mutually with the raw material polymer of the film. In such
compound, the absorption range in the ultraviolet region is
preferably from 200 to 400 nm, more preferably from 220 to 395 nm,
and further preferably from 240 to 390 nm.
[0130] In recent liquid crystal displays for use in a television, a
notebook personal computer or a mobile terminal, optical members to
be employed therein are being required to have a high transmittance
in order to obtain a higher luminance with a lower electric power.
In consideration of this fact, the wavelength-dependent dispersion
regulating agent, to be added in the optical film, is required to
have a satisfactory spectral transmittance. In the optical film of
the invention, it preferably has a spectral transmittance, at a
wavelength of 380 nm, of from 45 to 95%, and a spectral
transmittance, at a wavelength of 350 nm, of 10% or less.
[0131] The aforementioned wavelength-dependent dispersion
regulating agent, advantageously employed in the invention,
preferably has a molecular weight of from 250 to 1,000 in
consideration of volatility, more preferably from 260 to 800,
further preferably from 270 to 800, and particularly preferably
from 300 to 800. Within such molecular weight range, it may have a
specified monomer structure, or an oligomer structure or a polymer
structure in which a plurality of such monomer units are
bonded.
[0132] The aforementioned wavelength-dependent dispersion
regulating agent, advantageously employed in the invention, is
preferably employed in an amount of from 0.01 to 30 wt % with
respect to the raw material polymer of the film, more preferably
from 0.1 to 20 wt % and particularly preferably from 0.2 to 10 wt
%.
[0133] (Method of Addition of Wavelength-Dependent Dispersion
Regulating Agent)
[0134] The wavelength-dependent dispersion regulating agent may be
employed singly or in a mixture of two or more compounds in an
arbitrary ratio. The wavelength-dependent dispersion regulating
agent may be added at any step in the dope preparing process, or at
the end of the dope preparing process.
[0135] Specific examples of the wavelength-dependent dispersion
regulating agent, advantageously employed in the invention, include
a benzotriazole compound, a benzophenone compound, a cyano
group-containing compound, an oxybenzophenone compound, a
salicylate ester compound and a nickel complex salt compound, but
the present invention is not limited to such compounds.
[0136] Among the benzotriazole compounds, those represented by a
following formula (3) are preferably employed as the
wavelength-dependent dispersion regulating agent of the invention:
Q.sup.31-Q.sup.32-OH Formula (3) wherein Q.sup.31 represents a
nitrogen-containing aromatic heterocycle; and Q.sup.32 represents
an aromatic ring.
[0137] Q.sup.31 represents a nitrogen-containing aromatic
heterocycle, preferably a 5- to 7-membered nitrogen-containing
aromatic heterocycle, and more preferably a 5- to 6-membered
nitrogen-containing aromatic heterocycle, such as imidazole,
pyrrazole, triazole, tetrazole, thiazole, oxazole, selenazole,
benzotriazole, benzothiazole, benzoxazole, benzoselenazole,
thiadiazole, oxadiazole, naphthothiazole, naphthooxazole,
azabenzimidazole, purin, pyridine, pyrazine, pyrimidine,
pyridazine, triazine, triazaindene or tetrazaindene, and further
preferably a 5-membered nitrogen-containing aromatic heterocycle,
such as imidazole, pyrrazole, triazole, tetrazole, thiazole,
oxazole, benzotriazole, benzothiazole, benzoxazole, thiadiazole, or
oxadiazole, and particularly preferably benzotriazole.
[0138] The nitrogen-containing aromatic heterocycle represented by
Q.sup.31 may further have a substituent, to which applicable is a
substituent T to be explained later. Also when plural substituents
are present, they may be mutually condensed to further form a
ring.
[0139] An aromatic ring represented by Q.sup.32 may be an aromatic
hydrocarbon ring or an aromatic heterocycle. Also it may be a
single ring or may constitute condensed rings with another ring.
The aromatic hydrocarbon ring is preferably a single- or two-ringed
aromatic hydrocarbon ring containing 6 to 30 carbon atoms (such as
a benzene ring or a naphthalene ring), more preferably an aromatic
hydrocarbon ring containing 6 to 20 carbon atoms, further
preferably an aromatic hydrocarbon ring containing 6 to 12 carbon
atoms, and most preferably a benzene ring.
[0140] The aromatic hetorocycle is preferably an aromatic
hetorocycle containing a nitrogen atom or a sulfur atom. Specific
examples of the heterocycle include thiophene, imidazole,
pyrrazole, pyridine, pyrazine, pyridazine, triazole, triazine,
indole, indazole, purin, thiazoline, thiazole, thiadiazole,
oxazoline, oxazole, oxadiazole, quinoline, isoquinoline,
phthalazine, naphthylidine, quinoxaline, quinazoline, cinnoline,
pteridine, acridine, phenanthroline, phenazine, tetrazole,
benzimidazole, benzoxazole, benzothiazole, benzotriazole and
tetrazaindene. The aromatic heterocycle is preferably pyridine,
triazine or quinoline.
[0141] The aromatic ring represented by Q.sup.32 is preferably an
aromatic hydrocarbon ring, more preferably a naphthalene ring or a
benzene ring, and particularly preferably a benzene ring. Q.sup.32
may further have a substituent, preferably a substituent T shown
below.
[0142] Examples of the substituent T include an alkyl group
(preferably containing 1 to 20 carbon atoms, more preferably
containing 1 to 12 carbon atoms and particularly preferably
containing 1 to 8 carbon atoms, such as methyl, ethyl, i-propyl,
t-butyl, n-octyl, n-decyl, n-hexadecyl, cyclopropyl, cyclopentyl or
cyclohexyl), an alkenyl group (preferably containing 2-20 carbon
atoms, more preferably containing 2 to 12 carbon atoms and
particularly preferably containing 2 to 8 carbon atoms, such as
vinyl, allyl, 2-butenyl or 3-pentenyl), an alkinyl group
(preferably containing 2-20 carbon atoms, more preferably
containing 2 to 12 carbon atoms and particularly preferably
containing 2 to 8 carbon atoms, such as propalgyl or 3-pentinyl),
an aryl group (preferably containing 6 to 30 carbon atoms, more
preferably containing 6 to 20 carbon atoms and particularly
preferably containing 6 to 12 carbon atoms, such as phenyl,
p-methylphenyl or naphthyl), a substituted or non-substituted amino
group (preferably containing 0 to 20 carbon atoms, more preferably
containing 0 to 10 carbon atoms and particularly preferably
containing 0 to 6 carbon atoms, such as amino, methylamino,
dimethylamino, diethylamino or dibenzylamino), an alkoxy group
(preferably containing 1 -20 carbon atoms, more preferably
containing 1 to 12 carbon atoms and particularly preferably
containing 1 to 8 carbon atoms, such as methoxy, ethoxy, or
butoxy), an aryloxy group (preferably containing 6-20 carbon atoms,
more preferably containing 6 to 16 carbon atoms and particularly
preferably containing 6 to 12 carbon atoms, such as phenyloxy, or
2-naphthyloxy), an acyl group (preferably containing 1 to 20 carbon
atoms, more preferably containing 1 to 16 carbon atoms and
particularly preferably containing 1 to 12 carbon atoms, such as
acetyl, benzoyl, formyl or pivaloyl), an alkoxycarbonyl group
(preferably containing 2 to 20 carbon atoms, more preferably
containing 2 to 16 carbon atoms and particularly preferably
containing 2 to 12 carbon atoms, such as methoxycarbonyl or
ethoxycarbonyl), an aryloxycarbonyl group (preferably containing 7
to 20 carbon atoms, more preferably containing 7 to 16 carbon atoms
and particularly preferably containing 7 to 10 carbon atoms, such
as phenoxycarbonyl), an acyloxy group (preferably containing 2 to
20 carbon atoms, more preferably containing 2 to 16 carbon atoms
and particularly preferably containing 2 to 10 carbon atoms, such
as acetoxy or benzoyloxy), an acylamino group (preferably
containing 2 to 20 carbon atoms, more preferably containing 2 to 16
carbon atoms and particularly preferably containing 2 to 10 carbon
atoms, such as acetylamino or benzoylamino), an alkoxycarbonylamino
group (preferably containing 2 to 20 carbon atoms, more preferably
containing 2 to 16 carbon atoms and particularly preferably
containing 2 to 12 carbon atoms, such as methoxycarbonylamino), an
aryloxycarbonylamino group (preferably containing 7 to 20 carbon
atoms, more preferably containing 7 to 16 carbon atoms and
particularly preferably containing 7 to 12 carbon atoms, such as
phenyloxycarbonylamino), a sulfonylamino group (preferably
containing 1 to 20 carbon atoms, more preferably containing 1 to 16
carbon atoms and particularly preferably containing 1 to 12 carbon
atoms, such as methanesulfonylamino or benzenesulfonylamino), a
sulfamoyl group (preferably containing 0 to 20 carbon atoms, more
preferably containing 0 to 16 carbon atoms and particularly
preferably containing 0 to 12 carbon atoms, such as sulfamoyl,
methylsulfamoyl, dimethylsulfamoyl or phenylsulfamoyl), a carbamoyl
group (preferably containing 1 to 20 carbon atoms, more preferably
containing 1 to 16 carbon atoms and particularly preferably
containing 1 to 12 carbon atoms, such as carbamoyl,
methylcarbamoyl, diethylcarbamoyl or phenylcarbamoyl), an alkylthio
group (preferably containing 1 to 20 carbon atoms, more preferably
containing 1 to 16 carbon atoms and particularly preferably
containing 1 to 12 carbon atoms, such as methylthio, or ethylthio),
an arylthio group (preferably containing 6 to 20 carbon atoms, more
preferably containing 6 to 16 carbon atoms and particularly
preferably containing 6 to 12 carbon atoms, such as phenylthio), a
sulfonyl group (preferably containing 1 to 20 carbon atoms, more
preferably containing 1 to 16 carbon atoms and particularly
preferably containing 1 to 12 carbon atoms, such as mesyl or
tosyl), a sulfinyl group (preferably containing 1 to 20 carbon
atoms, more preferably containing 1 to 16 carbon atoms and
particularly preferably containing 1 to 12 carbon atoms, such as
methanesulfinyl or benzenesulfinyl), an ureido group (preferably
containing 1 to 20 carbon atoms, more preferably containing 1 to 16
carbon atoms and particularly preferably containing 1 to 12 carbon
atoms, such as ureido, methylureido or phenylureido), a phosphoric
acid amide group (preferably containing 1 to 20 carbon atoms, more
preferably containing 1 to 16 carbon atoms and particularly
preferably containing 1 to 12 carbon atoms, such as
diethylphosphoric acid amide or phenylphosphoric acid amide), a
hydroxyl group, a mercapto group, a halogen atom (such as a
fluorine atom, a chlorine atom, a bromine atom or an iodine atom),
a cyano group, a sulfo group, a carboxyl group, a nitro group, a
hydroxamic acid group, a sulfino group, a hydrazino group, an imino
group, a heterocyclic group (preferably containing 1 to 30 carbon
atoms, and more preferably containing 1 to 12 carbon atoms, and
including a nitrogen atom, an oxygen atom, or a sulfur atom as a
hetero atom, such as imidazolyl, pyridyl, quinolyl, furyl,
piperidyl, morpholino, benzoxazolyl, benzimidazolyl or
benzothiazolyl), and a silyl group (preferably containing 3 to 40
carbon atoms, more preferably containing 3 to 30 carbon atoms and
particularly preferably containing 3 to 24 carbon atoms, such as
trimethylsilyl or triphenylsilyl). These substituents may be
further substituted. Also when two or more substituents are
present, they may be mutually same or different. Also they may be
mutually connected to form a ring, if possible.
[0143] The compound of the formula (3) is preferably represented by
a following formula (3-1). ##STR23##
[0144] In the formula (3-1), R.sup.31, R.sup.32, R.sup.33,
R.sup.34, R.sup.35, R.sup.36, R.sup.37 and R.sup.38 each
independently represent a hydrogen atom or a substituent, to which
the aforementioned substituent T is applicable. Also such
substituent may be further substituted with another substituent,
and substituents may be mutually condensed to form a ring
structure.
[0145] R.sup.31 and R.sup.33 each is preferably a hydrogen atom, an
alkyl group, an alkenyl group, an alkinyl group, an aryl group, a
substituted or non-substituted amino group, an alkoxy group, an
aryloxy group, a hydroxyl group, or a halogen atom, more preferably
a hydrogen atom, an alkyl group, an aryl group, an alkyloxy group,
an aryloxy group, or a halogen atom, further preferably a hydrogen
atom or an alkyl group containing 1 to 12 carbon atoms, and
particularly preferably an alkyl group containing 1 to 12 carbon
atoms (preferably containing 4 to 12 carbon atoms).
[0146] R.sup.32 and R.sup.34 each is preferably a hydrogen atom, an
alkyl group, an alkenyl group, an alkinyl group, an aryl group, a
substituted or non-substituted amino group, an alkoxy group, an
aryloxy group, a hydroxyl group, or a halogen atom, more preferably
a hydrogen atom, an alkyl group, an aryl group, an alkyloxy group,
an aryloxy group, or a halogen atom, further preferably a hydrogen
atom or an alkyl group containing 1 to 12 carbon atoms, and
particularly preferably a hydrogen atom or a methyl group, and most
preferably a hydrogen atom.
[0147] R.sup.35 and R.sup.38 each is preferably a hydrogen atom, an
alkyl group, an alkenyl group, an alkinyl group, an aryl group, a
substituted or non-substituted amino group, an alkoxy group, an
aryloxy group, a hydroxyl group, or a halogen atom, more preferably
a hydrogen atom, an alkyl group, an aryl group, an alkyloxy group,
an aryloxy group, or a halogen atom, further preferably a hydrogen
atom or an alkyl group containing 1 to 12 carbon atoms, and
particularly preferably a hydrogen atom or a methyl group, and most
preferably a hydrogen atom.
[0148] R.sup.36 and R.sup.37 each is preferably a hydrogen atom, an
alkyl group, an alkenyl group, an alkinyl group, an aryl group, a
substituted or non-substituted amino group, an alkoxy group, an
aryloxy group, a hydroxyl group, or a halogen atom, more preferably
a hydrogen atom, an alkyl group, an aryl group, an alkyloxy group,
an aryloxy group, or a halogen atom, further preferably a hydrogen
atom or a halogen atom, and particularly preferably a hydrogen atom
or a chlorine atom.
[0149] The compound of the formula (3) is more preferably
represented by a following formula (3-2). ##STR24##
[0150] In the formula, R.sup.31, R.sup.33, R.sup.36 and R.sup.37
have same meaning and same preferable range as those in the formula
(3-1).
[0151] Specific examples of the compound represented by the formula
(3) are shown below, but the present invention is not at all
restricted to such examples. ##STR25## ##STR26## ##STR27##
##STR28##
[0152] Among the triazole compounds cited above as examples, those
having a molecular weight of 320 or higher are advantageous in the
storage property and preferable for the preparation of the optical
film of the invention
[0153] Also the benzophenone compound, which is one of the
wavelength-dependent dispersion regulating agents to be employed in
the invention, is preferably that represented by a formula (4).
##STR29##
[0154] In the formula, Q.sup.41 and Q.sup.42 each independently
represents an aromatic ring; and X.sup.41 represents NR.sup.41
(R.sup.41 representing a hydrogen atom or a substituent), an oxygen
atom or a sulfur atom.
[0155] The aromatic ring represented by Q.sup.41 and Q.sup.42 may
be an aromatic hydrocarbon ring or an aromatic heterocycle. These
may be a single ring, or may form a condensed ring with another
ring.
[0156] The aromatic hydrocarbon ring represented by Q.sup.41 and
Q.sup.42 is preferably a monocyclic or bicyclic aromatic
hydrocarbon ring containing 6 to 30 carbon atoms (such as a benzene
ring or a naphthalene ring), more preferably an aromatic
hydrocarbon ring containing 6 to 20 carbon atoms, further
preferably an aromatic hydrocarbon ring containing 6 to 12 carbon
atoms, and still preferably a benzene ring.
[0157] The aromatic heterocycle represented by Q.sup.41 and
Q.sup.42 is preferably an aromatic heterocycle containing at least
one of either one of an oxygen atom, a nitrogen atom and a sulfur
atom. Specific examples of the heterocycle include furan, pyrrole,
thiophene, imidazole, pyrazole, pyridine, pyrazine, pyridazine,
triazole, triazine, indole, indazole, purin, thiazoline, thiazole,
thiadiazole, oxazoline, oxazole, oxadiazole, quinoline,
isoquinoline, phthalazine, naphthyridine, quinoxaline, quinazoline,
cinnoline, pteridine, acridine, phenanthroline, phenazine,
tetrazole, benzimidazole, benzoxazole, benzothiazole,
benzotriazole, and tetrazaindene. The aromatic heterocycle is
preferably pyridine, triazine or quinoline.
[0158] The aromatic ring represented by Q.sup.41 and Q.sup.42 is
preferably an aromatic hydrocarbon ring, more preferably an
aromatic hydrocarbon ring containing 6 to 10 carbon atoms, and
further preferably a substituted or non-substituted benzene
ring.
[0159] Q.sup.41 and Q.sup.42 may further have a substituent, which
is preferably the aforementioned substituent T, but the substituent
does not include a carboxylic acid, a sulfonic acid or a quaternary
ammonium salt. Also when possible, substituents may be linked each
other to form a cyclic structure.
[0160] X.sup.41 represents NR.sup.42 (R.sup.42 representing a
hydrogen atom or a substituent, to which the aforementioned
substituent T may be applicable), an oxygen atom or a sulfur atom,
and X.sup.41 is preferably NR.sup.42 (R.sup.42 being preferably an
acyl group, or a sulfonyl group, and such substituent may be
further substituted), or oxygen, and particularly preferably
oxygen.
[0161] The compounds represented by the formula (4) are preferably
those represented by a following formula (4-1). ##STR30##
[0162] In the formula, R.sup.411, R.sup.412, R.sup.413, R.sup.414,
R.sup.415, R.sup.416, R.sup.417, R.sup.418 and R.sup.419 each
independently represents a hydrogen atom or a substituent, to which
the aforementioned substituent T is applicable. Also these
substituents may be further substituted with another substituent,
or may be mutually condensed to form a cyclic structure.
[0163] R.sup.411, R.sup.413, R.sup.414, R.sup.415, R.sup.416,
R.sup.418 and R.sup.419 each is preferably a hydrogen atom, an
alkyl group, an alkenyl group, an alkinyl group, an aryl group, a
substituted or non-substituted amino group, an alkoxy group, an
aryloxy group, a hydroxyl group, or a halogen atom, more preferably
a hydrogen atom, an alkyl group, an aryl group, an alkyloxy group,
an aryloxy group, or a halogen atom, further preferably a hydrogen
atom or an alkyl group containing 1 to 12 carbon atoms,
particularly preferably a hydrogen atom or a methyl group, and most
preferably a hydrogen atom.
[0164] R.sup.412 is preferably a hydrogen atom, an alkyl group, an
alkenyl group, an alkinyl group, an aryl group, a substituted or
non-substituted amino group, an alkoxy group, an aryloxy group, a
hydroxyl group, or a halogen atom, more preferably a hydrogen atom,
an alkyl group containing 1 to 20 carbon atoms, an amino group
containing 0 to 20 carbon atoms, an alkoxy group containing 1 to 12
carbon atoms, an aryloxy group containing 6 to 12 carbon atoms, or
a hydroxyl group, further preferably an alkoxy group containing 1
to 20 carbon atoms, and particularly preferably an alkoxy group
containing 1 to 12 carbon atoms.
[0165] R.sup.417 is preferably a hydrogen atom, an alkyl group, an
alkenyl group, an alkinyl group, an aryl group, a substituted or
non-substituted amino group, an alkoxy group, an aryloxy group, a
hydroxyl group, or a halogen atom, more preferably a hydrogen atom,
an alkyl group containing 1 to 20 carbon atoms, an amino group
containing 0 to 20 carbon atoms, an alkoxy group containing 1 to 12
carbon atoms, an aryloxy group containing 6 to 12 carbon atoms, or
a hydroxyl group, further preferably a hydrogen atom, or an alkyl
group containing 1 to 20 carbon atoms (preferably containing 1 to
12 carbon atoms, more preferably containing 1 to 8 carbon atoms and
further preferably a methyl group), and particularly preferably a
methyl group or a hydrogen atom.
[0166] The compounds represented by the formula (4) are more
preferably those represented by a following formula (4-2).
##STR31##
[0167] In the formula, R.sup.420 represents a hydrogen atom, a
substituted or non-substituted alkyl group, a substituted or
non-substituted alkenyl group, a substituted or non-substituted
alkinyl group, or a substituted or non-substituted aryl group, and
the aforementioned substituent T is applicable as the substituent.
R.sup.420 is preferably a substituted or non-substituted alkyl
group, more preferably a substituted or non-substituted alkyl group
containing 5 to 20 carbon atoms, further preferably a substituted
or non-substituted alkyl group containing 5 to 12 carbon atoms
(such as an n-hexyl group, a 2-ethylhexyl group, an n-octyl group,
an n-decyl group, an n-dodecyl group, or a benzyl group), and
particularly preferably a substituted or non-substituted alkyl
group containing 6 to 12 carbon atoms (such as a 2-ethylhexyl
group, an n-octyl group, an n-decyl group, an n-dodecyl group or a
benzyl group).
[0168] The compounds represented by the formula (4) may be
synthesized by a known method, described in JP-A-11-12219.
[0169] Specific examples of the compound represented by the formula
(4) are shown below, but the present invention is not limited to
those specific examples. ##STR32## ##STR33## ##STR34##
[0170] Also the compound containing a cyano group, which is one of
the wavelength-dependent dispersion regulating agents to be
employed in the invention, is preferably that represented by a
formula (5). ##STR35##
[0171] In the formula, Q.sup.51 and Q.sup.52 each independently
represents an aromatic ring; and X.sup.51 and X.sup.52 each
represents a hydrogen atom or a substituent and at least either
represents a cyano group, a carbonyl group, a sulfonyl group or an
aromatic heterocycle. The aromatic ring represented by Q.sup.51 and
Q.sup.52 may be an aromatic hydrocarbon ring or an aromatic
heterocycle. These may be a single ring, or may form a condensed
ring with another ring.
[0172] The aromatic hydrocarbon ring is preferably a monocyclic or
bicyclic aromatic hydrocarbon ring containing 6 to 30 carbon atoms
(such as a benzene ring or a naphthalene ring), more preferably an
aromatic hydrocarbon ring containing 6 to 20 carbon atoms, further
preferably an aromatic hydrocarbon ring containing 6 to 12 carbon
atoms, and still preferably a benzene ring.
[0173] The aromatic heterocycle is preferably an aromatic
heterocycle containing a nitrogen atom or a sulfur atom. Specific
examples of the heterocycle include thiophene, imidazole, pyrazole,
pyridine, pyrazine, pyridazine, triazole, triazine, indole,
indazole, purin, thiazoline, thiazole, thiadiazole, oxazoline,
oxazole, oxadiazole, quinoline, isoquinoline, phthalazine,
naphthyridine, quinoxaline, quinazoline, cinnoline, pteridine,
acridine, phenanthroline, phenazine, tetrazole, benzimidazole,
benzoxazole, benzothiazole, benzotriazole, and tetrazaindene. The
aromatic heterocycle is preferably pyridine, triazine or
quinoline.
[0174] The aromatic ring represented by Q.sup.51 and Q.sup.52 is
preferably an aromatic hydrocarbon ring, and more preferably a
benzene ring. Q.sup.51 and Q.sup.52 may further have a substituent,
which is preferably the aforementioned substituent T.
[0175] X.sup.51 and X.sup.52 represents a hydrogen atom or a
substituent, and at least either one is a cyano group, a carbonyl
group, a sulfonyl group, or an aromatic heterocycle. The
aforementioned substituent T may be applicable to the substituent
represented by X.sup.51 and X.sup.52. Also the substituent
represented by X.sup.51 and X.sup.52 may be further substituted
with another substituent, and X.sup.51 and X.sup.52 may be mutually
condensed to form a cyclic structure.
[0176] X.sup.51 and X.sup.52 each is preferably a hydrogen atom, an
alkyl group, an aryl group, a cyano group, a nitro group, a
carbonyl group, a sulfonyl group or an aromatic heterocycle, more
preferably a cyano group, a carbonyl group, a sulfonyl group or an
aromatic heterocycle, further preferably a cyano group or a
carbonyl group, and particularly preferably a cyano group or an
alkoxycarbonyl group {--C(.dbd.O)}OR.sup.51 (R.sup.51 being an
alkyl group containing 1 to 20 carbon atoms, an aryl group
containing 6 to 12 carbon atoms or a combination thereof)}.
[0177] The compounds represented by the formula (5) are preferably
those represented by a following formula (5-1). ##STR36##
[0178] In the formula, R.sup.511, R.sup.512, R.sup.513, R.sup.514,
R.sup.515, R.sup.516, R.sup.517, R.sup.518, R.sup.519 and R.sup.520
each independently represents a hydrogen atom or a substituent, to
which the aforementioned substituent T is applicable. Also these
substituents may be further substituted with another substituent,
or may be mutually condensed to form a cyclic structure. X.sup.511
and X.sup.512 have same meanings as X.sup.51 and X.sup.52 in the
formula (5).
[0179] R.sup.511, R.sup.512, R.sup.514, R.sup.515, R.sup.516,
R.sup.517, R.sup.519 and R.sup.520 each is preferably a hydrogen
atom, an alkyl group, an alkenyl group, an alkinyl group, an aryl
group, a substituted or non-substituted amino group, an alkoxy
group, an aryloxy group, a hydroxyl group, or a halogen atom, more
preferably a hydrogen atom, an alkyl group, an aryl group, an
alkyloxy group, an aryloxy group, or a halogen atom, further
preferably a hydrogen atom or an alkyl group containing 1 to 12
carbon atoms, particularly preferably a hydrogen atom or a methyl
group, and most preferably a hydrogen atom.
[0180] R.sup.513 and R.sup.518 each is preferably a hydrogen atom,
an alkyl group, an alkenyl group, an alkinyl group, an aryl group,
a substituted or non-substituted amino group, an alkoxy group, an
aryloxy group, a hydroxyl group, or a halogen atom, more preferably
a hydrogen atom, an alkyl group containing 1 to 20 carbon atoms, an
amino group containing 0 to 20 carbon atoms, an alkoxy group
containing 1 to 12 carbon atoms, an aryloxy group containing 6 to
12 carbon atoms, or a hydroxyl group, further preferably a hydrogen
atom, an alkyl group containing 1 to 12 carbon atoms, or an alkoxy
group containing 1 to 12 carbon atoms, and particularly preferably
a hydrogen atom.
[0181] The compounds represented by the formula (5) are more
preferably those represented by a following formula (5-2).
##STR37##
[0182] In the formula, R.sup.513 and R.sup.518 have same meanings
and same preferable range as those in the formula (5-1). X.sup.513
represents a hydrogen atom or a substituent, to which the
aforementioned substituent T is applicable and which may be
substituted further with another substituent, when possible.
[0183] X.sup.513 represents a hydrogen atom or a substituent, to
which the aforementioned substituent T is applicable and which may
be substituted further with another substituent, when possible.
X.sup.513 preferably represents a hydrogen atom, an alkyl group, an
aryl group, a cyano group, a nitro group, a carbonyl group, a
sulfonyl group, or an aromatic heterocycle, more preferably a cyano
group, a carbonyl group, a sulfonyl group, or an aromatic
heterocycle, further preferably a cyano group or a carbonyl group,
and particularly preferably a cyano group or an alkoxycarbonyl
group {--C(.dbd.O)}OR.sup.52 (R.sup.52 being an alkyl group
containing 1 to 20 carbon atoms, an aryl group containing 6 to 12
carbon atoms or a combination thereof)}.
[0184] The compounds represented by the formula (5) are further
preferably those represented by a following formula (5-3).
##STR38##
[0185] In the formula, R.sup.513 and R.sup.518 have same meanings
and same preferable range as those in the formula (5-1). R.sup.52
represents an alkyl group containing 1 to 20 carbon atoms. In a
case that R.sup.513 and R.sup.518 are both hydrogen atoms, R.sup.52
is preferably an alkyl group containing 2 to 12 carbon atoms, more
preferably an alkyl group containing 4 to 12 carbon atoms, further
preferably an alkyl group containing 6 to 12 carbon atoms,
particularly preferably an n-octyl group, a t-octyl group, a
2-ethylhexyl group, an n-decyl group, or an n-dodecyl group, and
most preferably a 2-ethylhexyl group.
[0186] In a case that R.sup.513 and R.sup.518 are other than
hydrogen ztoms, R.sup.52 is preferably an alkyl group providing the
compound of the formula (5-3) with a molecular weight of 300 or
higher and containing 20 or less carbon atoms.
[0187] In the invention, the compound represented by the formula
(5) can be synthesized by a method described in J. Am. Chem. Soc.,
63, p. 3452(1941).
[0188] Specific examples of the compound represented by the formula
(5) are shown below, but the present invention is not limited to
those specific examples. ##STR39## ##STR40## ##STR41## ##STR42##
##STR43##
[0189] The optical film of the invention may contain at least one
each of the compound reducing Rth(550) described above and the
compound increasing .DELTA.Rth which is represented by a formula
(10): .DELTA.Rth=Rth(450)-Rth(650). (Organic Solvent for Polymer
Solution)
[0190] In the invention, the producing method for the optical film
is not particularly restricted. Any known method may be usable,
including a melt film forming method or a solution film forming
method. The optical film formed by a polymer is preferably produced
by a solvent casting method, in which the film is produced by a
solution (dope) prepared by dissolving a raw material polymer in an
organic solvent. An organic solvent preferably employed as a
principal solvent in the invention is preferably selected from an
ester, a ketone or an ether, containing 3 to 12 carbon atoms, and a
halogenated hydrocarbon containing 1 to 7 carbon atoms. The ester,
ketone and ether may have a cyclic structure. Also a compound,
having any one of ester, ketone or ether functional group (namely
--O--, --CO-- or --COO--) in two or more units, may also be
employed as a principal solvent, and it may also have another
functional group such as an alcoholic hydroxyl group. In case of a
principal solvent having functional groups of two or more kinds, a
number of carbon atoms of such solvent may be within a range
defined for a compound having either one of such functional
groups.
[0191] For the optical film of the invention, a chlorine-containing
halogenated hydrocarbon may be employed as a principal solvent, or,
as described in the Japan Institute of Invention and Innovation,
Laid-open Technical Report 2001-1745 (p. 12-16), a chlorine-free
solvent may be employed as a principal solvent, and no particular
restriction is made for the optical film of the invention.
[0192] Also the solvents for a polymer solution and a film, usable
in the optical film of the invention, also including a solving
method, are described in following patent references and constitute
preferable embodiments. The references include, for example,
JP-A-2000-95876, JP-A-12-95877, JP-A-10-324774, JP-A-8-152514,
JP-A-10-330538, JP-A-9-95538, JP-A-9-95557, JP-A-10-235664,
JP-A-12-63534, JP-A-11-21379, JP-A-10-182853, JP-A-10-278056,
JP-A-10-279702, JP-A-10-323853, JP-A-10-237186, JP-A-11-60807,
JP-A-11-152342, JP-A-11-292988, JP-A-11-60752 and JP-A-11-60752.
These references include descriptions not only on solvents
preferable for the polymer of the invention but also on physical
properties of the solvent and co-existing substances to be made
present, thus providing preferable embodiments also in the present
invention.
(Producing Process of Optical Film)
(Dissolving Step)
[0193] Preparation of a polymer solution (dope) in the invention is
not particularly restricted in the dissolving method, and may be
executed at the room temperature, or by a cooled dissolving method,
a high-temperature dissolving method or a combination thereof. For
the preparation of the polymer solution in the invention and a
solution concentrating step and a filtering step associated with
the dissolving step, a producing method described in detail in the
Japan Institute of Invention and Innovation, Laid-open Technical
Report (2001-1745, issued Mar. 15, 2001), pages 22-25, may be
employed advantageously.
[0194] (Transparency of Dope Solution)
[0195] The polymer solution (dope) of the invention preferably has
a transparency of 85% or higher, more preferably 88% or higher, and
further preferably 90% or higher. In the invention, it is confirmed
that various additives are sufficiently dissolved in the polymer
dope solution. For calculating the dope transparency, the dope
solution is filled in a glass cell of 1 cm square, and subjected to
a measurement of an absorbance at 550 nm by a spectrophotometer
(UV-3150, manufactured by Shimadzu Corp.). A solvent alone is
measured in advance as a blank, and the transparency of the polymer
solution is calculated from a ratio to the blank absorbance.
(Casting, Drying and Winding Steps)
[0196] Then a film producing method utilizing the polymer solution
of the invention will be explained. As a method and an equipment
for producing the optical film of the invention, there are
preferably employed a film producing method by solution casting and
a film producing equipment by solution casting, that have been used
for producing a cellulose triacetate film. A preferred embodiment
of such method will be explained below.
[0197] A dope (polymer solution) prepared in a dissolver (pot) is
once stored in a storage pot, and is subjected to a final
preparation by a defoaming of bubbles contained in the dope. The
dope is fed, from a dope exit, to a pressurized die for example
through a pressurized constant-rate gear pump, capable of a
constant-rate feeding of a high precision by a revolution. The dope
is uniformly cast, from an aperture (slit) of the pressurized die,
onto a running endless metal support member, and a half-dried dope
film (also called a web) is peeled from the metal support member at
a peeling point after about a cycle of the metal support member.
The obtained web is supported at both ends thereof by clips, then
dried by conveying in a tenter under a maintained width, further
dried by conveying with rolls in a drying apparatus, and wound in a
predetermined length by a winder. A combination of the tenter and
the rolls in the drying apparatus is variable depending on the
purpose. After the dope film is peeled off as a film from the metal
support member, a step of stretching the film may be provided. In
such case, it is also possible to regulate a wavelength dependence
of the optical properties of the film, by suitably regulating a
stretching temperature and a stretching magnification. In the film
forming method by solution casting, to be employed for producing a
functional protective film as an optical member for an electronic
display, which is a principal purpose of the optical film of the
invention, and for producing a silver halide photographic material,
there is often provided, in addition to the film forming apparatus
by solution casting, a coating apparatus for forming an undercoat
layer, an antistatic layer, an antihalation layer, a protective
layer and the like onto the surface of the film. These matters are
described in detail in the Japan Institute of Invention and
Innovation, Laid-open Technical Report (2001-1745, issued Mar. 15,
2001), pages 25-30, under items of casting (including co-casting),
metal support member, drying, peeling etc., and may be employed
advantageously in the present invention.
[0198] The optical film of the invention preferably has a film
thickness of from 20 to 200 .mu.m, more preferably from 30 to 160
.mu.m, and further preferably from 40 to 120 .mu.m.
(Stacked-Type Optical Compensation Film)
[0199] The optical film of the invention may be stacked with an
optically anisotropic layer satisfying following relations (13) and
(14): 0.ltoreq.Re.ltoreq.400; and (13) -400.ltoreq.Rth.ltoreq.400,
(14) and preferably: 0.ltoreq.Re.ltoreq.300;and (13')
-300.ltoreq.Rth.ltoreq.300. (14')
[0200] In the relations (13) to (14'), Re and Rth are respectively
an in-plane retardation (unit: nm) and a retardation in thickness
direction (unit: nm), measured with a light of any wavelength
within a visible region. The measuring wavelength is preferably
from 400 to 700 nm, more preferably from 450 to 650 nm, and most
preferably from 500 to 600 nm.
[0201] In the invention, the optically anisotropic layer satisfying
the relations (13) and (14) is not limited to a single-layered
structure but may have a layered structure of plural layers. In an
embodiment of such layered structure, materials for the layers need
not be same, and for example optically anisotropic layers utilizing
a discotic liquid crystal, a cholesteric liquid crystal or a
rod-shaped liquid crystal may be employed singly or in a
combination. Also a stacked member of a polymer film and an
optically anisotropic layer of a liquid crystalline compound may be
utilized. In an embodiment of such layered structure, a coated-type
layered member including a layer formed by coating is preferable to
a stacked member of stretched polymer films, in consideration of
the thickness.
[0202] (Optical Compensation Film Formed by a Liquid Crystal
Compound)
[0203] In preparing an optically anisotropic layer meeting (13) and
(14) above, and in case of utilizing a liquid crystalline compound
for the preparation of such optically anisotropic layer, since the
liquid crystalline compound involves various alignment states, an
optically anisotropic layer prepared by fixing the liquid
crystalline compound at a specified alignment state can exhibit a
desired optical property, by a single layer or by a layered member
of plural layers. Thus, the optically anisotropic layer may assume
an embodiment formed by a substrate and one or more optically
anisotropic layers formed thereon. In such embodiment, a
retardation of the entire optically anisotropic layer may be
regulated by an optical anisotropy of the optically anisotropic
layer. The liquid crystalline compounds are classified, according
to a molecular shape thereof, into a discotic liquid crystal, a
cholesteric liquid crystal and a rod-shaped liquid crystal. Each
includes a low-molecular type and a high-molecular type, each of
which is usable.
[0204] (Optically Anisotropic Layer Formed by Polymer Film)
[0205] As described above, the optically anisotropic layer may be
formed by a polymer film. The polymer film is formed from a polymer
capable of expressing an optical anisotropy. Examples of such
polymer include polyolefin (such as polyethylene, polypropylene or
norbornene-type polymer), polycarbonate, polyallylate, polysulfone,
polyvinyl alcohol, polymethacrylate ester, polyacrylate ester and
cellulose ester (such as cellulose triacetate or cellulose
diacetate). Also a copolymer or a mixture of these polymers may be
employed.
[0206] The optical anisotropy of the polymer film is preferably
obtained by stretching. The stretching is preferably executed by a
monoaxial stretching method or a biaxial stretching method. More
specifically, a longitudinal monoaxial stretching utilizing a
peripheral speed difference in two or more rolls, a tenter
stretching in which the polymer film is gripped on both sides and
stretched in the transversal direction, or a biaxial stretching by
combining these, is preferable. Also it is possible to utilize two
or more polymer films in such a manner that the entire optical
properties of two or more films satisfy the aforementioned
conditions. The polymer film is preferably produced by a solvent
cast method, in order to reduce an unevenness in the birefringence.
The polymer film preferably has a thickness of from 20 to 500
.mu.m, and most preferably from 40 to 100 .mu.m.
[0207] Also there is advantageously employed a method of forming a
polymer film constituting the optically anisotropic layer, by
utilizing at least a polymer material selected from a group of
polyamide, polyimide, polyester, polyether ketone, polyamidimide,
polyesterimide, and polyallyl ether ketone, coating a solution
prepared by dissolving such polymer material in a solvent on a
substrate and drying the solvent to obtain a film. In such case, a
method of laminating the polymer film and a base material and then
stretching both together to express an optical anisotropy as an
optically anisotropic layer is also employable advantageously, and
the optical film of the invention is preferably employed as the
base material. It is also preferable to prepare the polymer film on
another base material, then peeling the polymer from the base
material and adhere it with the optical film of the invention, as
an optically anisotropic layer. Such method allows to reduce the
thickness of the polymer film, which is preferably 50 .mu.m or less
and more preferably from 1 to 20 .mu.m.
(Surface Treatment)
[0208] The optical film of the invention may be subjected to a
surface treatment, in certain cases, for achieving an improved
adhesion between the optical film and functional layers (for
example an undercoat layer and a back layer). The surface treatment
can be executed for example by a glow discharge treatment, an
ultraviolet irradiation treatment, a corona treatment, a flame
treatment, or an acid or alkali treatment. The glow discharge
treatment can be executed with a low-temperature plasma generated
in a low-pressure gas of 10.sup.-3-20 Torr, or can also be
advantageously executed by a plasma treatment under an atmospheric
pressure. A plasma exciting gas means a gas capable of exciting a
plasma under the aforementioned condition, and can be argon,
helium, neon, krypton, xenon, nitrogen, carbon dioxide, a
fluorinated gas such as tetrafluoromethane or a mixture thereof.
Details of such materials are detailedly described in Japan
Institute of Invention and Innovation, Laid-open Technical Report
(2001-1745, issued Mar. 15, 2001, JIII), pages 30-32, and may be
advantageously utilized in the invention.
(Contact Angle of Film Surface by Alkali Saponification
Treatment)
[0209] In case of utilizing the optical film of the invention as a
transparent protective film for a polarizing plate, an effective
surface treatment is an alkali saponification treatment. In such
case, the film surface after the alkali saponification treatment
preferably has a contact angle of 55.degree. or less, more
preferably 50.degree. or less and further preferably 45.degree. or
less. The contact angle can be evaluated by an ordinary method of
dropping a water drop of a diameter of 3 mm onto the film surface
after the alkali saponification treatment and measuring an angle
formed by the film surface and the water drop, and can be used as
an evaluation of hydrophilicity.
(Polarizing Plate)
[0210] The optical film of the invention is preferably employable
as a protective film of a polarizing plate. In case of use as a
protective film of a polarizing plate, the polarizing plate is not
particularly restricted in a producing method and can be prepared
by an ordinary producing method. For example there is known a
method of alkali treating an obtained optical film and adhering
such optical film, with an aqueous solution of a completely
saponified polyvinyl alcohol, on both sides of a polarizer prepared
by dipping and stretching a polyvinyl alcohol film in an iodine
solution. Instead of alkali treatment, there may be employed an
adhesion promoting treatment as described in JP-A Nos. 6-94915 and
6-118232.
[0211] An adhesive to be employed for adhering a treated surface of
the protective film and the polarizer can be, for example, a
polyvinyl alcohol-type adhesive such as polyvinyl alcohol or
polyvinyl butyral, or a vinylic latex such as butyl acrylate.
[0212] The polarizing plate is constituted of a polarizer and
protective films for protecting both sides thereof, and a
protecting film and a separation film may be adhered respectively
on one side and the other side of such polarizing plate. The
protecting film and the separation film are used for the purpose of
protecting the polarizing plate at a shipping or a product
inspection of the polarizing plate. In such case, the protecting
film is adhered for the purpose of protecting a surface of the
polarizing plate, opposite to the side of the polarizing plate
adhered to a liquid crystal panel, while the separation film is
employed for the purpose of covering an adhesive layer for adhesion
to the liquid crystal panel, on a side of the polarizing plate to
be adhered to the liquid crystal panel.
[0213] A liquid crystal display usually includes substrates,
containing liquid crystal, between two polarizing plates, and the
polarizing plate protective film, utilizing the optical film of the
invention, may be utilized in any position. For the purpose of the
present invention for achieving an optical compensation in all the
visible wavelength range, it is effective and preferable to utilize
the optical film of the invention as a polarizing plate protecting
film at the side of the liquid crystal cell.
(Polarizing Plate Integral with Optical Compensation Film)
[0214] In case of utilizing the optical film of the invention as an
optical compensation film, for example in case of coating or
adhering an optically anisotropic layer on one side of the optical
film of the invention, it is possible to adhere the optical
compensation film, with an adhesive, to a polarizing plate already
prepared by adhering protective films on both sides of a polarizer,
or to execute a surface treatment on the optical film of the
invention, on a side thereof not coated or adhered with the
optically anisotropic layer and to adhere such optical film
directly to the polarizer. In such case, for example a polyvinyl
alcohol-based polarizing plate is not restricted in a producing
method and may be prepared by an ordinary method. For example,
there may be employed a method of executing a surface modification
on a surface the optical film by an alkali saponification
treatment, a plasma treatment or a corona discharge treatment, and
applying such optical film on both surfaces of a polarizer prepared
by dipping and stretching a polyvinyl alcohol (PVA) film in an
iodine solution.
(Functional Layer)
[0215] In case of utilizing the optical film of the invention as a
protective film of a polarizing plate in a liquid crystal display,
various functional layers may be provided on the surface. These
include, for example, a cured resin layer (transparent hard coat
layer), an antiglare layer, an antireflective layer, an adhesion
promoting layer, an optical compensation layer, an alignment layer
and an antistatic layer for liquid crystal layer. These functional
layers in which the optical film of the invention is applicable,
and materials therefor include for example a surfactant, a
lubricant, a matting agent, an antistatic layer and a hard coat
layer, which are described in detail in Japan Institute of
Invention and Innovation, Journal of Technical Disclosure (No.
2001-1745, issued March 15, 2001, JIII), p. 32-45, and are
advantageously employable in the invention.
(Liquid Crystal Display)
[0216] A liquid crystal display of the present invention an optical
film (optical compensation film), a liquid crystal cell and
polarizing plates in combination. The optical film (optical
compensation film), the liquid crystal cell and the polarizing
plates are preferably contacted closely, and a tacky material or an
adhesive material already known may be employed for such close
contact.
[0217] The optical film of the invention, and the optical
compensation film or the polarizing plate utilizing the same may be
applied to liquid crystal displays of various display modes.
Representative display modes proposed include VA (vertically
aligned), IPS (in-plane switching), TN (twisted nematic), OCB
(optically compensatory bend), STN (super twisted nematic), ECB
(electrically controlled birefringence), FLC (ferroelectric liquid
crystal), AFLC (anti-ferroelectric liquid crystal), and HAN (hybrid
aligned nematic). Also there is proposed a display mode with an
alignment division in the above-mentioned display modes. Effects
obtained by the optical film of the invention are conspicuous
particularly in a liquid crystal display of a large image size, so
that it is particularly preferable to utilize the optical film of
the invention in the liquid crystal display of VA mode, IPS mode or
OCB mode, utilized in large-size televisions.
[0218] The optical film of the invention is preferably employed in
a display mode in which the liquid crystal molecules are vertically
aligned in a black display state, such as VA mode, a display mode
in which the liquid crystal molecules are parallel aligned in a
black display state, such as IPS or FFS mode, and an OCB mode in
which the liquid crystal molecules are bend aligned.
[0219] For example, in case of utilizing at least either of the
optical film, the optical compensation film and the polarizing
plate of the invention in a liquid crystal display, the liquid
crystal display may include at least an optically anisotropic
layer. Such optically anisotropic layer preferably satisfies
following relations (15) and (16): 0.ltoreq.Re.ltoreq.400,and (15)
-400.ltoreq.Rth.ltoreq.400. (16)
[0220] In the relations (15) and (16), Re and Rth are respectively
an in-plane retardation (unit: nm) and a retardation in thickness
direction (unit: nm), measured with a light of any wavelength
within a visible region. The measuring wavelength is preferably
from 400 to 700 nm, more preferably from 450 to 650 nm, and most
preferably from 500 to 600 nm.
[0221] The optically anisotropic layer is not limited to a
single-layer structure, but may have a layered structure formed by
laminating plural layers. In an embodiment of such layered
structure, materials for the layers need not be same, and for
example optically anisotropic layers utilizing a discotic liquid
crystal, a cholesteric liquid crystal or a rod-shaped liquid
crystal may be employed singly or in a combination. Also a
laminated member of a polymer film and an optically anisotropic
layer of a liquid crystalline compound may be utilized. In an
embodiment of such layered structure, a coated-type layered member
including a layer formed by coating is preferable to a laminated
member of stretched polymer films, in consideration of the
thickness.
[0222] The optically anisotropic layer may be those cited in the
explanation of the laminated optical compensation film.
[0223] When the liquid crystal display includes a liquid crystal
cell in which the liquid crystal molecules are vertically aligned
in a black display state, in order to obtain viewing angle
chracteristics showing little light leakage and little color shift
in the inclined direction, the apparatus preferably includes at
least an optically anisotropic layer satisfying
10.ltoreq.Re.ltoreq.150 and 50.ltoreq.Rth.ltoreq.400. Such
optically anisotropic layer more preferably satisfies
20.ltoreq.Re.ltoreq.120 and 60.ltoreq.Rth.ltoreq.350, and most
preferably 30.ltoreq.Re.ltoreq.100 and
80.ltoreq.Rth.ltoreq.300.
[0224] When the liquid crystal display includes a liquid crystal
cell in which the liquid crystal molecules are parallel aligned in
a black display state, in order to obtain viewing angle
chracteristics showing little light leakage and little color shift
in the inclined direction, the apparatus preferably includes at
least an optically anisotropic layer satisfying either one of
relations (19) to (22). A more preferable embodiment of the liquid
crystal display of the invention includes an optically anisotropic
layer satisfying the relation (20) and an optically anisotropic
layer satisfying the relation (21). Another further preferable
embodiment includes an optically anisotropic layer satisfying the
relation (20) and an optically anisotropic layer satisfying the
relation (22): 100.ltoreq.Re.ltoreq.400, and
-50.ltoreq.Rth.ltoreq.50; (19) 0.ltoreq.Re.ltoreq.20, and
-400.ltoreq.Rth.ltoreq.-50; (20) 60.ltoreq.Re.ltoreq.200, and
20.ltoreq.Rth.ltoreq.120; (21) 30.ltoreq.Re.ltoreq.150, and
100.ltoreq.Rth.ltoreq.400. (22)
[0225] When the liquid crystal display includes a liquid crystal
cell in which the liquid crystal molecules are bend aligned in a
black display state, in order to obtain viewing angle
chracteristics showing little light leakage and little color shift
in the inclined direction, the apparatus preferably includes at
least an optically anisotropic layer containing a discotic liquid
crystal compound. An alignment state of the discotic liquid crystal
compound is preferably such that a disk face is inclined with
respect to the surface of the optically anisotropic layer, and more
preferably is a hybrid alignment in which an angle of such
inclination changes along the thickness direction of the optically
anisotropic layer.
[0226] In each optically anisotropic layer, Re and Rth are
respectively an in-plane retardation (unit: nm) and a retardation
in thickness direction (unit: nm), measured with a light of any
wavelength within a visible region. The measuring wavelength is
preferably from 400 to 700 nm, more preferably from 450 to 650 nm,
and most preferably from 500 to 600 nm.
EXAMPLES
[0227] In the following, the present invention will be further
clarified by examples, but the present invention is not limited to
such examples.
[0228] In executing the present invention, in case of employing
cellulose acylate as a polymer material as a reference for
selecting the raw material, it is found that a larger acyl
substitution degree is effective for reducing the retardation.
Rth(550) as a function of acyl substitution degree of cellulose
triacetate is shown in FIG. 9.
[0229] Also in the present invention, it is found that, as one of
additives for controlling the optical characteristics of the
optical film of the invention, a larger amount of the Rth reducing
agent is effective for reducing the retardation of the film.
Rth(550) as a function of the amount of compound 119 is shown in
FIG. 10.
[0230] Also in the present invention, it is found that, as one of
additives for controlling the optical characteristics of the
optical film of the invention, a larger amount of the
wavelength-dependent dispersion regulating agent is effective for
increasing .DELTA.Rth of the film. Rth(550) as a function of the
amount of compound UV102 is shown in FIG. 11.
[0231] In the optical film of the invention, a kind of the polymer
material, and kinds and amounts of the additives for controlling
the optical characteristics were suitably selected. FIGS. 9 to 11
show mere examples, and the effects are variable depending for
example on the combination of materials, but these concepts were
employed as design principles for preparing the optical film.
[0232] In the present example, the compounds indicated as the Rth
reducing agent and the wavelength-dependent dispersion regulating
agent are those described in the specification.
Example 1
[0233] (Preparation of Cellulose Acylate Solution CA-1)
[0234] A following composition was charged in a mixing tank, and
agitated to dissolve components thereby obtaining a cellulose
acylate solution CA-1. TABLE-US-00003 (Composition of cellulose
acylate solution CA-1) cellulose acylate with Ac substitution
degree: 2.92 100.0 parts by weight Rth reducing agent: compound 119
14.0 parts by weight methylene chloride (1st solvent) 402.0 parts
by weight methanol (2nd solvent) 60.0 parts by weight
[0235] (Preparation of Matting Agent Solution MT-1)
[0236] 20 parts by weight of silica particles of an average
particle size of 16 nm (AEROSIL R972, manufactured by Nippon
Aerosil Co.) and 80 parts by weight of methanol were well mixed
under agitation for 30 minutes to obtain a silica particle
dispersion. The dispersion was charged in a disperser together with
the following composition and agitated for 30 minutes or longer to
dissolve the components, thereby obtaining a matting agent solution
MT-1. TABLE-US-00004 (Composition of matting agent solution MT-1)
dispersion of silica particles of 10.0 parts by weight average
particle size: 16 nm methylene chloride (1st solvent) 76.3 parts by
weight methanol (2nd solvent) 3.4 parts by weight cellulose acylate
solution CA-1 10.3 parts by weight
[0237] (Preparation of Additive Solution)
[0238] Following composition was charged in a mixing tank and
agitated under heating to dissolve the components, thereby
obtaining an additive solution AD-1. TABLE-US-00005 (Composition of
additive solution AD-1) wavelength-dependent dispersion 7.6 parts
by weight regulating agent: UV-208 methylene chloride (1st solvent)
58.4 parts by weight methanol (2nd solvent) 8.7 parts by weight
cellulose acylate solution CA-1 12.8 parts by weight
[0239] (Preparation of Optical Film Sample 001)
[0240] 94.6 parts by weight of the cellulose acylate solution CA-1,
1.3 parts by weight of the matting agent solution MT-1, and 2.3
parts by weight of the additive solution AD-1, after each being
filtered, were mixed and cast by a band casting machine. In the
above-described composition, the Rth reducing agent and the
wavelength-dependent dispersion regulating agent had weight ratios,
with respect to cellulose acylate, respectively of 14.0% and 1.0%.
A prepared film with a residual solvent amount of 30% was peeled
off from the band, and was dried at 135.degree. C. for 20 minutes
to obtain a cellulose acylate film. The completed optical film 001
had a residual solvent amount of 0.2% and a film thickness of 80
.mu.m.
[0241] The prepared film was subjected to a moisture adjustment for
2 hours or more in an environment of 25.degree. C. and 60% RH, and
was subjected to a measurement of three-dimensional birefringence
with an auto birefringence meter KOBRA 21ADH (manufactured by Oji
Scientific Instruments Ltd.) at wavelengths of 450, 550 and 650 nm
in an environment of 25.degree. C. and 60% RH, to obtain an
in-plane retardation Re and a retardation Rth in the thickness
direction, obtained by Re measurements at different inclination
angles, thereby obtaining optical characteristics shown in Table
4.
Example 2
[0242] An optical film 002, having a thickness of 80 .mu.m and
optical characteristics shown in Table 4, was obtained in the same
manner as in Example 1, except that the amount of the compound 119
in the cellulose acylate solution CA-1 in Example 1 was changed to
12.0 parts by weight and the amount of UV-208 in the additive
solution AD-1 was changed to 3.0 parts by weight.
Example 3
[0243] An optical film 003, having a thickness of 80 .mu.m and
optical characteristics shown in Table 4, was obtained in the same
manner as in Example 1, except that the amount of the compound 119
in the cellulose acylate solution CA-1 in Example 1 was changed to
10.0 parts by weight and the amount of UV-208 in the additive
solution AD-1 was changed to 1.5 parts by weight.
Example 4
[0244] An optical film 004, having a thickness of 80 .mu.m and
optical characteristics shown in Table 4, was obtained in the same
manner as in Example 1, except that UV-208 in the additive solution
AD-1 in Example 1 was changed to UV-20.
Example 5
[0245] An optical film 005, having a thickness of 80 .mu.m and
optical characteristics shown in Table 4, was obtained in the same
manner as in Example 1, except that UV-208 in the additive solution
AD-1 in Example 1 was changed to UV-3.
Example 6
[0246] An optical film 006, having a thickness of 80 .mu.m and
optical characteristics shown in Table 4, was obtained in the same
manner as in Example 1, except that the amount of the compound 119
in the cellulose acylate solution CA-1 in Example 1 was changed to
16.0 parts by weight, that UV-208 in the additive solution AD-1 was
changed to UV-3 and that the amount of UV-3 was changed to 15.2
parts by weight.
Example 7
[0247] An optical film 007, having a thickness of 80 .mu.m and
optical characteristics shown in Table 4, was obtained in the same
manner as in Example 1, except that the amount of UV-3 in the
additive solution in Example 6 was changed to 12.2 parts by
weight.
Example 8
[0248] An optical film 008, having a thickness of 80 .mu.m and
optical characteristics shown in Table 4, was obtained in the same
manner as in Example 1, except that the amount of the compound 119
in the cellulose acylate solution CA-1 in Example 1 was changed to
12.0 parts by weight, that UV-208 in the additive solution AD-1 was
changed to UV-102 and that the amount of UV-102 was changed to 9.1
parts by weight.
Comparative Example 1
[0249] As a comparative example, a commercially available cellulose
acylate film FUJITAC TD80UL (film thickness 80 .mu.m, manufactured
by Fuji Photo Film Co.) was prepared. This film had optical
characteristics as shown in Table 4.
Comparative Example 2
[0250] As a comparative example, a commercially available
cycloolefin film Zeonor ZF-14 (film thickness 100 .mu.m,
manufactured by Nippon Zeon Ltd.) was prepared. This film had
optical characteristics as shown in Table 4. TABLE-US-00006 TABLE 4
Ex. 1 Ex. 2 Ex. 3 Ex. 4 Ex. 5 Ex. 6 Ex. 7 Ex. 8 Comp. Ex. 1 Comp.
Ex. 2 sample name 001 002 003 004 005 006 007 008 TD80UL ZF-14 raw
material polymer Ac2.92 Ac2.92 Ac2.92 Ac2.92 Ac2.92 Ac2.92 Ac2.92
Ac2.92 -- Zeonor Rth reducing agent 119 119 119 119 119 119 119 119
-- -- (wt %) (14%) (12%) (10%) (14%) (14%) (16%) (16%) (12%)
wavelength-dependent dispersion reg. UV-208 UV-208 UV-208 UV-208
UV-3 UV-3 UV-3 UV-102 -- -- agent (wt %) (1.0%) (0.4%) (0.2%)
(1.0%) (1.0%) (2.0%) (1.6%) (1.2%) Re(nm) 450 1.0 -3.2 -9.5 -5.3
1.3 5.3 5.8 5.3 -0.8 6.1 550 1.0 1.0 0.8 0.8 1.2 1.2 1.0 1.0 2.9
6.0 650 1.0 5.1 6.8 5.3 1.2 -1.6 -3.2 -1.8 5.0 6.0 I = 450-550 0.0
-4.2 -10.3 -6.1 0.1 4.1 4.8 4.3 -3.7 0.1 II = 650-550 0.0 4.1 6.0
4.5 0.0 -2.8 -4.2 -2.8 2.1 0.0 Rth(nm) 450 -10.5 -8.0 -0.4 5.6 9.3
8.3 -1.9 -13.2 32.8 6.8 550 0.5 0.4 -0.5 -0.7 2.0 2.1 -1.8 -2.0
42.4 6.9 650 7.7 7.3 -0.5 -3.2 -1.3 -3.5 -1.8 2.8 48.5 6.9 III =
450-550 -11.0 -8.4 0.1 6.3 7.3 6.2 -0.1 -11.2 -9.6 -0.1 IV =
650-550 7.2 6.9 0.0 -2.5 -3.3 -5.6 0.0 4.8 6.1 0.0 |I| + |II| +
|III| + |IV| 18.2 23.6 16.4 19.4 10.7 18.7 9.1 23.1 21.5 0.2 class
(Tabs. 2, 3) A A B B C C D D -- -- case (Tables 2, 3) (1) (2) (3)
(4) (5) (6) (7) (8) -- -- Ex. 10A (VA color shift) (+) (+) (-) (-)
Ex. 10B (VA color shift) (+) (+) (-) (-) Ex. 10C (VA color shift)
(+) (+) (-) (-) Ex. 10D (VA color shift) (+) (+) (-) (-) Ex. 11
(IPS color shift) (+) (-) Ex. 12A (IPS view angle) (+) (-) (-) Ex.
12B (IPS view angle) (+) (-) (-) Ex. 12C (IPS view angle) (+) (-)
(-) Ex. 12D (IPS view angle) (+) (-) (-) Ex. 13 (OCB color shift)
(+) (.+-.) (-)
Example 9
[0251] (Working of Polarizing Plate)
[0252] (Preparation of Polarizing Plate)
[0253] Surfaces of the optical film 001 of the invention were
subjected to an alkali saponification process. It was immersed in a
1.5N aqueous solution of sodium hydroxide at 55.degree. C. for 2
minutes, then rinsed in a water rinsing tank of room temperature,
and was neutralized with 0.1N sulfuric acid of 30.degree. C. It was
rinsed again in a water rinsing tank of room temperature, and was
dried with warm air of 100.degree. C. Then a rolled polyvinyl
alcohol film of a thickness of 80 .mu.m was continuously stretched
5 times in an aqueous solution of iodine and dried to obtain a
polarizing film of a thickness of 20 .mu.m. The alkali-saponified
optical film 001 and a similarly alkali-saponified FUJITAC TD80UL
(manufactured by Fuji Photo Film Co.) were prepared and adhered,
utilizing a 3% aqueous solution of polyvinyl alcohol (PVA-117H,
manufactured by Kuraray Co.) as an adhesive, with the polarizing
film therebetween, in such a manner that the alkali-saponified
surfaces are at the side of the polarizing film, thereby obtaining
a polarizing plate 101 in which the optical film 001 and TD80UL
constitute protective films of the polarizing film. The adhesion
was made in such a manner that the phase retarding axes of the
optical film 001 and TD80UL are parallel to the absorption axis of
the polarizing film. Similarly the optical films 002-008 of the
invention were used to prepare polarizing plates, which will be
hereinafter called polarizing plates 102-108. These polarizing
plates had sufficient polarizing ability.
[0254] Also TD80UL of Comparative Example 1 was used, in a similar
manner, to prepare a polarizing plate 201. The polarizing plate 201
is a polarizing plate protected on both sides by TD80UL. Also
Zeonor film ZF-14 of Comparative Example 2 was subjected to a
corona discharge treatment as a surface treatment instead of alkali
saponification, and was otherwise processed similarly to obtain a
polarizing plate 202. These polarizing plates 201, 202 had a
sufficient polarizing ability.
Example 10
[0255] (Mounting on VA Panel)
[0256] Evaluation of mounting on a VA panel was conducted in
following four classes A to D, according to the type of the optical
characteristics of the optical compensation film employed on the
liquid crystal display.
(Class A)
[0257] The optical film of the invention was evaluated by mounting
on a liquid crystal display of VA mode. A VA-mode liquid crystal
television (LC-20C5, manufactured by Sharp Inc.) was used, after
removing the front and rear polarizing plates and the retardation
plate, as a liquid crystal cell for mounting. A polarizing film was
prepared in the same manner as in Example 9. An optical
compensation film 4-A, subjected to a saponification treatment on a
surface, was adhered on a surface of the polarizing film, and a
cellulose triacetate film (FUJITAC TD80UL, manufactured by Fuji
Photo Film Co.), subjected to a saponification treatment on a
surface, was adhered on the other surface of the polarizing film,
utilizing a polyvinyl alcohol-based adhesive, thereby obtaining a
polarizing plate 4-A. The optical characteristics of the optical
compensation film 4-A are shown in Table 5. In a structure shown in
FIG. 5, there were employed the polarizing plate 4-A as an optical
compensation film 4 and a polarizing plate 1, the aforementioned
VA-mode liquid crystal cell as a liquid crystal cell 3, and the
polarizing plate 101 prepared in Example 9 as an optical film 5 and
a polarizing plate 2, and these were adhered with a tacky adhesive
material. The adhesion was made in such a manner that the optical
compensation film 4-A of the polarizing plate 4-A was positioned at
the side of the liquid crystal cell, and that the optical film 001
of the polarizing plate 101 was positioned at the side of the
liquid crystal cell. The adhesion was also made in such a manner
that a phase retarding axis of the optical compensation film 4-A
was perpendicular to the absorbing axis of the polarizing plate 1.
Also a mounting was executed by adhering each of the polarizing
plate 102 obtained in Example 9, and the polarizing plate 201 and
202 utilizing Comparative Example 1 and 2, in combination with the
optical compensation film 4-A shown in Table 5. TABLE-US-00007
TABLE 5 wavelength (nm) Re(nm) Rth(nm) 450 48 264 550 75 228 650 91
217
(Class B)
[0258] In a structure similar to that of Example 10 (class A), a
mounting was executed by employing the polarizing plate 103, 104,
201 or 202 instead of the polarizing plate 101, and employing an
optical compensation film 4-B of the optical characteristics shown
in Table 6 instead of the optical compensation film 4-A.
TABLE-US-00008 TABLE 6 wavelength (nm) Re(nm) Rth(nm) 450 45 215
550 59 242 650 62 258
(Class C)
[0259] In a structure similar to that of Example 10 (class A), a
mounting was executed by employing the polarizing plate 105, 106,
201 or 202 instead of the polarizing plate 101, and employing an
optical compensation film 4-C of the optical characteristics shown
in Table 7 instead of the optical compensation film 4-A.
TABLE-US-00009 TABLE 7 wavelength (nm) Re(nm) Rth(nm) 450 68 242
550 63 224 650 61 217
(Class D)
[0260] In a structure similar to that of Example 10 (class A), a
mounting was executed by employing the polarizing plate 107, 108,
201 or 202 instead of the polarizing plate 101, and employing an
optical compensation film 4-D of the optical characteristics shown
in Table 8 instead of the optical compensation film 4-A.
TABLE-US-00010 TABLE 8 wavelength (nm) Re(nm) Rth(nm) 450 73 205
550 65 228 650 63 234
[0261] The optical compensation films 4-A, 4-B, 4-C and 4-D shown
in Tables 5-8 were prepared in the following manner.
[0262] (Preparation of Optical Compensation Film)
[0263] (Preparation of Cellulose Acylate Solution CA-2)
[0264] A following composition was charged in a mixing tank, and
agitated to dissolve components thereby obtaining a cellulose
acylate solution CA-2. TABLE-US-00011 (Composition of cellulose
acylate solution CA-2) cellulose acylate with Ac substitution
degree: 2.81 100.0 parts by weight TPP (triphenyl phosphate) 7.8
parts by weight BDP (biphenyldiphenyl phosphate) 3.9 parts by
weight methylene chloride (1st solvent) 402.0 parts by weight
methanol (2nd solvent) 60.0 parts by weight
[0265] (Preparation of Matting Agent Solution MT-2)
[0266] 20 parts by weight of silica particles of an average
particle size of 16 nm (AEROSIL R972, manufactured by Nippon
Aerosil Co.) and 80 parts by weight of methanol were well mixed
under agitation for 30 minutes to obtain a silica particle
dispersion. The dispersion was charged in a disperser together with
the following composition and agitated for 30 minutes or longer to
dissolve the components, thereby obtaining a matting agent solution
MT-2. TABLE-US-00012 (Composition of matting agent solution MT-2)
dispersion of silica particles of 10.0 parts by weight average
particle size: 16 nm methylene chloride (1st solvent) 76.3 parts by
weight methanol (2nd solvent) 3.4 parts by weight cellulose acylate
solution CA-2 10.3 parts by weight
[0267] (Preparation of Additive Solution)
[0268] Following composition was charged in a mixing tank and
agitated under heating to dissolve the components, thereby
obtaining an additive solution AD-2. TABLE-US-00013 (Composition of
additive solution AD-2) following retardation expressing agent X
11.5 parts by weight methylene chloride (1st solvent) 58.4 parts by
weight methanol (2nd solvent) 8.7 parts by weight cellulose acylate
solution CA-2 12.8 parts by weight Retardation expressing agent X
##STR44##
[0269] (Preparation of Cellulose Acylate Film Sample 401)
[0270] 94.6 parts by weight of the cellulose acylate solution CA-2,
1.3 parts by weight of the matting agent solution MT-2, and 2.3
parts by weight of the additive solution AD-2, after each being
filtered, were mixed and cast by a band casting machine. In the
above-described composition, the retardation expressing agent had a
weight ratio, with respect to cellulose acylate, of 1.0%. A
prepared film with a residual solvent amount of 30% was peeled off
from the band, and was dried at 140.degree. C. for 40 minutes to
obtain a cellulose acylate film. The completed cellulose acylate
film 401 had a residual solvent amount of 0.2% and a film thickness
of 140 .mu.m.
[0271] (Preparation of Optical Compensation Film 4-A)
[0272] The cellulose acylate film 401 obtained above was fed to a
stretching apparatus, including a step of stretching a continuous
web film in a transversal direction by means of a tenter of a
structure in which a longitudinal pitch of tenter clips becomes
narrower in the course of holding and conveying of the film, and, a
stretching was started after setting the film temperature at
180.degree. C. and at 30 seconds after passing a heating zone, for
contracting the film under relaxation by 0.72 times in the
longitudinal direction and for stretching the film by 1.23 times in
the transversal direction by means of the tenter clips, thereby
obtaining an optical compensation film 4-A having a thickness of
182 .mu.m after the stretching.
[0273] (Preparation of Optical Compensation Film 4-B)
[0274] A process was executed in the same manner as in the
preparation of the optical compensation film 4-A, except that the
cellulose acetate of Ac substitution degree of 2.81, in the
composition of the cellulose acylate solution CA-2, was replaced by
cellulose acetate of Ac substitution degree of 2.92, thereby
obtaining a cellulose acylate film sample 402. It was used in a
process similar to that for preparing the optical compensation film
4-A to obtain an optical compensation film 4-B.
[0275] (Preparation of Optical Compensation Film 4-C)
[0276] A process was executed in the same manner as in the
preparation of the optical compensation film 4-A, except that the
cellulose acetate of Ac substitution degree of 2.81, in the
composition of the cellulose acylate solution CA-2, was replaced by
cellulose acetate of Ac substitution degree of 2.86, thereby
obtaining a cellulose acylate film sample 403. It was subjected to
a fixed biaxial stretching, which was started after setting the
film temperature at 180.degree. C. and at 30 seconds after passing
a heating zone, to stretch the film by 1.2 times in the
longitudinal direction and by 1.1 times in the transversal
direction, thereby obtaining an optical compensation film 4-C
having a thickness of 180 .mu.m after the stretching.
[0277] (Preparation of Optical Compensation Film 4-D)
[0278] A process was executed in the same manner as in the
preparation of the optical compensation film 4-A, except that the
amount of the retardation expressing compound X in the composition
of the additive solution AD-2, was changed from 11.5 parts by
weight to 8.6 parts by weight, thereby obtaining a cellulose
acylate film sample 404. It was subjected to a fixed biaxial
stretching, which was started after setting the film temperature at
180.degree. C. and at 30 seconds after passing a heating zone, to
stretch the film by 1.2 times in the longitudinal direction and by
1.1 times in the transversal direction, thereby obtaining an
optical compensation film 4-D having a thickness of 180 .mu.m after
the stretching.
[0279] (Evaluation of Viewing Angle-Dependent Color of Panel)
[0280] Each of the mounted VA-mode panels prepared in (class A) to
(class D) above was used as a liquid crystal display of the
structure shown in FIG. 5, with a backlight provided at the side of
the polarizing plate 1, and, for each sample, a color shift in an
inclined direction with an azimuthal angle of 45.degree. and a
polar angle of 60.degree. in a black image display state. Results
are shown in Table 4. In the color evaluation, a case without any
color shift (yellowish or reddish color) is represented by (+),
while a case, where a color shift is observed at a polar angle of
60.degree. but is removed when the polar angle is reduced from
60.degree. to 30.degree., is represented by (.+-.), and a case
where a color shift is observed at any polar angle is represented
by (-). Results are shown in Table 4. Any of the samples prepared
in Examples utilizing the optical films 001-008 of the invention
did not show a color shift nor a light leakage when observed in an
inclined direction. On the other hand, in liquid crystal panels
utilizing the films of Comparative Examples 1 and 2, a light
leakage was observed in an observation from an inclined direction,
and a coloration (slightly reddish) in the leaking light was
confirmed. This is because the optical characteristics Re, Rth of
TD80UL in Comparative Example 1, particularly a large absolute
value of Rth, do not provide a sufficient optical compensation.
Also Zeonor ZF-14 in Comparative Example 2 lacks wavelength
dependence in contrast to the optical film of the invention, so
that the polarized lights of wavelengths of R, G and B, having
moved to different points after passing the liquid crystal cell as
shown in FIG. 6, cannot be matched by the optical film 5 shown in
FIG. 5. Measurements were also made in a white image display state
to determine a contrast ratio to the black display state, and it
was confirmed that the optical films of the invention had an
excellent contrast ratio.
[0281] Based on the foregoing, it was confirmed that the optical
film of the invention, having desired Re and Rth, was capable of
suppressing a color shift and had a high contrast ratio over a wide
range, and that the polarizing plate and the liquid crystal
display, utilizing the same had excellent performance.
Example 11
[0282] (Mounting on IPS Panel)
[0283] In a structure shown in FIG. 2, there were employed the
polarizing plate 108 prepared in Example 9 as a polarizing plate 1,
the polarizing plate 201 prepared in Example 9 as a polarizing
plate 2, and a commercial IPS-mode liquid crystal cell as a liquid
crystal cell 3, and these were adhered with a tacky adhesive
material to prepare a liquid crystal display (IPS-1). In this
operation, the liquid crystal cell was adhered with the side of the
optical 008 of the polarizing plate 108. Also the transmission axes
of the upper and lower polarizing plates were made perpendicular
each other, and the transmission axis of the upper polarizing plate
was made parallel to the direction of the molecular longer axis of
the liquid crystal cell (namely the phase retarding axis of the
optical compensation layer and the direction of the molecular
longer axis of the liquid crystal cell being perpendicular each
other). The liquid crystal cell, electrodes and substrates may be
those used in the prior IPS mode. The liquid crystal cell had a
horizontal alignment, and the liquid crystal had a positive
dielectric anisotropy. As an example, a liquid crystal cell,
obtained by removing polarizing plates and other components from a
commercial IPS-mode liquid crystal television (TH-32LX500,
manufactured by Matsushita Electric Industrial Co.), may be
employed advantageously.
[0284] As a Comparative Example, a liquid crystal display (IPS-2)
was prepared, in a structure shown in FIG. 2, employing the
polarizing plate 201 prepared in Example 9 as polarizing plates 1
and 2, and the commercial IPS-mode liquid crystal cell as a liquid
crystal cell 3, and adhering these with a tacky adhesive
material.
[0285] On thus prepared liquid crystal display IPS-1 and IPS-2, a
light leak rate in a black display state was measured in an
evaluation method similar to that in Example 10 and in a direction
of an azimuthal angle of 45.degree. and a polar angle of 60.degree.
from a frontal direction to the apparatus. Results are shown in
Table 4. The liquid crystal display IPS-1, employing the polarizing
plate 108 utilizing the optical film of the invention, showed
little light leakage and no color shift in the observation from the
inclined direction, while the liquid crystal display IPS-2,
employing the polarizing plate 201 utilizing the optical film of
Comparative Example 1, showed a light leakage and a color shift. It
was also found that IPS-1 was superior in the viewing angle
property of contrast.
[0286] The Example 11 and Comparative Example are represented, on a
Poincare sphere, as shown in FIGS. 12 and 13. In FIG. 12, T.sub.in
indicates an incident light at the side of the polarizing plate 1,
and P.sub.out indicates an emergent light at the side of the
polarizing plate 2. As an ideal point for the emergent light is
A.sub.put, a smaller distance between P.sub.out and A.sub.out is
closer to the ideal state. This distance corresponds to the light
leakage in the black display state. In FIG. 13, a movement from
T.sub.in to P.sub.1 is caused by the retardation of the film of
Comparative Example, employed in the polarizing plate 201. Also a
movement from P.sub.1 to P.sub.2 is an arc about A.sub.out, caused
by the retardation of the liquid crystal cell. Also a movement from
P.sub.2 to P.sub.out is caused by the retardation of the film of
Comparative Example, employed in the polarizing plate 2. On the
other hand, in FIG. 12, there is scarce movement from T.sub.in to
P.sub.1, because the optical film 108 of the invention has scarce
retardation. Because of this fact, the movement from P.sub.1 to
P.sub.2 has a smaller arc radius, whereby the distance between
P.sub.out and A.sub.out becomes smaller than in the case of FIG.
13. This fact also explains the smaller light leakage in case of
employing the optical film of the invention.
Example 12
[0287] (Preparation of Optical Compensation Film 5-A)
[0288] A solution containing cellulose acylate was prepared in the
same manner as in Example 10. 100 parts by weight of the cellulose
acylate solution CA-2 and 1.3 parts by weight of the matting agent
solution MT-2 were mixed, and the additive solution AD-2 was mixed
in such a manner that the retardation expressing agent X was
present in 6 parts by weight, with respect to 100 parts by weight
of cellulose acetate, thereby obtaining a film forming dope.
[0289] The obtained dope was cast with a casting machine, having a
band of a width of 2 m and a length of 65 m. A film with a residual
solvent amount of 15 wt % was transversally stretched by a tenter
with a stretching magnification of 20% under a condition of
130.degree. C., then maintained at a width after stretching for 30
seconds at 50.degree. C. and then unclipped to obtain a cellulose
acetate film. After the stretching, it was further dried to a
residual solvent amount less than 0.1 wt %, thereby obtaining a
cellulose acetate film (T1). The cellulose acylate employed had Tg
of 140.degree. C.
[0290] The prepared film was passed through induction heated rolls
of a temperature of 60.degree. C. to elevate the film surface
temperature to 40.degree. C., then coated with an alkali solution
of a following composition in an amount of 14 ml/m.sup.2 by a bar
coater, then made to stay for 10 seconds under a steam-type far
infrared heater (manufactured by Noritake Company) heated at
110.degree. C., and was further coated with purified water in an
amount of 3 ml/m.sup.2 by a bar coater. In this state, the film had
a temperature of 40.degree. C. It was then subjected to a water
rinsing by a fountain coater and a water removal by an air-knife,
repeated 3 cycles, and was dried by staying in a drying zone of
70.degree. C. for 2 seconds. In this manner the surface of the
cellulose acetate film was subjected to a saponification treatment.
TABLE-US-00014 (Composition of alkali solution) potassium hydroxide
4.7 parts by weight water 15.7 parts by weight isopropanol 64.8
parts by weight propylene glycol 14.9 parts by weight
C.sub.16H.sub.33O(CH.sub.2CH.sub.2O).sub.10H (surfactant) 1.0 part
by weight
[0291] The obtained cellulose acetate film T1 had a width of 1340
mm and a thickness of 88 .mu.m. An auto birefringence meter KOBRA
21ADH (manufactured by Oji Scientific Instruments Ltd.) was used to
measure the optical characteristics of the prepared cellulose
acetate film (T1). At 590 nm, the in-plane retardation (Re) was 60
nm, and the retardation in thickness direction (Rth) was 190 nm. In
the optically anisotropic layer, an average direction of the phase
retarding axis was substantially perpendicular to the longitudinal
direction of the film.
[0292] On a saponified surface of thus prepared continuous web
cellulose acetate film (T1), an alignment film coating liquid of a
following composition was continuously coated with a wired bar of
#14. An alignment film was formed by drying with a warm air of
60.degree. C. for 60 seconds and with a warm air of 100.degree. C.
for 120 seconds. TABLE-US-00015 (Composition of alignment film
coating liquid) following denatured polyvinyl alcohol 10 parts by
weight water 371 parts by weight methanol 119 parts by weight
glutaraldehyde 0.5 parts by weight Denatured polyvinyl alcohol
##STR45##
[0293] A coating liquid of a following composition, containing a
rod-shaped liquid crystal compound, was continuously coated with a
wired bar of #5.0 on the prepared alignment film. The film was
conveyed at a speed of 20 m/min. The solvent was removed in a step
of continuously heating from the room temperature to 80.degree. C.,
and a heating was then conducted in a drying zone of 80.degree. C.
for 90 seconds thereby aligning the rod-shaped liquid crystal
compound. Subsequently, the film was maintained at a temperature of
60.degree. C., and the alignment of the liquid crystal compound was
fixed by a UV irradiation to obtain an optically anisotropic layer
B1. Subsequently, the prepared film was immersed in a 1.5 mol/L
aqueous solution of sodium hydroxide of 55.degree. C. for 2
minutes, and then was immersed in water to sufficiently wash off
sodium hydroxide. Then it was immersed in a 5 mmol/L aqueous
solution of sulfuric acid of 35.degree. C. for 1 minute, and then
was immersed in water to sufficiently wash off the dilute aqueous
solution of sulfuric acid. Finally, the sample was sufficiently
dried at 120.degree. C. In this manner an optical compensation film
5-A, in which an optically anisotropic layer B1 was laminated on
the cellulose acetate film T1, was prepared. TABLE-US-00016
(Composition of coating liquid containing rod-shaped liquid crystal
compound) following rod-shaped liquid crystal compound (I) 100
parts by weight photopolymerization initiator 3 parts by weight
(Irgacure 907 manufactured by Ciba-Geigy Ltd.) sensitizer (Kayacure
DETX, manufactured by Nippon Kayaku Co.) 1 part by weight following
fluorinated polymer 0.4 parts by weight following pyridinium salt 1
part by weight methyl ethyl ketone 172 parts by weight Rod-shaped
liquid crystal compound (I) ##STR46## Fluorinated polymer ##STR47##
Pyridinium salt ##STR48##
[0294] From the prepared optical compensation film 5-A, the
optically anisotropic layer B1 alone, containing the rod-shaped
liquid crystal compound, was peeled off and subjected to a
measurement of optical characteristics with an auto birefringence
meter KOBRA 21ADH (manufactured by Oji Scientific Instruments
Ltd.). In a measurement at 590 nm, the optically anisotropic layer
B1 alone had Re of 0 nm and Rth of -260 nm. It was also confirmed
that an optically anisotropic layer, in which the rod-shaped liquid
crystal molecules were substantially vertically aligned to the film
surface, was formed.
[0295] (Preparation of Optical Compensation Film 5-B)
[0296] Heat-shrinkable films were adhered, by acrylic tacky
adhesive layers, on both surfaces of a polycarbonate film, which
was then stretched with a stretching apparatus under heating to
cause shrinkage of the heat-shrinkable films, and the
heat-shrinkable films were then peeled off. In this manner an
optical compensation film 5-B was prepared with Re of 268 nm, Rth
of 1 nm and a thickness of 60 .mu.m.
[0297] (Preparation of Optical Compensation Film 5-C)
[0298] Heat-shrinkable films were adhered, by acrylic tacky
adhesive layers, on both surfaces of an Arton film (manufactured by
JSR Corp.), which was then stretched with a stretching apparatus
under heating to cause shrinkage of the heat-shrinkable films, and
the heat-shrinkable films were then peeled off. In this manner an
optical compensation film 5-C was prepared with Re of 195 nm, Rth
of -20 nm and a thickness of 135 .mu.m.
[0299] (Preparation of Optical Compensation Film 5-D)
[0300] An Arton film (manufactured by JSR Corp.) was monoaxially
stretched to obtain a film A1 with Re of 170 nm, Rth of 85 nm and a
thickness of 70 .mu.m.
[0301] A surface of the Arton film A1 was subjected to a corona
treatment, and an alignment film was formed thereon in the same
manner as described above. Then an optically anisotropic layer B2
was formed with a coating liquid containing the aforementioned
rod-shaped liquid crystal compound. The optically anisotropic layer
B2 alone had Re of 0 nm and Rth of -135 nm. It was also confirmed
that an optically anisotropic layer, in which the rod-shaped liquid
crystal molecules were substantially vertically aligned to the film
surface, was formed. In this manner an optical compensation film
5-D, in which an optically anisotropic layer B2 was laminated on
the Arton film A1, was prepared.
[0302] (Preparation of Polarizing Plate 5-A)
[0303] A polarizing film was prepared in the same manner as in
Example 9. A surface of the prepared optical compensation film 5-A,
not bearing the optically anisotropic layer B1 (namely a rear
surface of the cellulose acetate film T1) was adhered to a surface
of this polarizing film, while a cellulose triacetate film (FUJITAC
TD80UL, manufactured by Fuji Photo Film Co.) having a saponified
surface was adhered to the other surface, with a polyvinyl
alcohol-based adhesive, whereby a polarizing plate 5-A was
prepared. In this operation, the absorbing axis of the polarizing
film and the phase retarding axis of the cellulose acetate film T1
were made perpendicular each other.
[0304] (Preparation of Polarizing Plate 5-B)
[0305] The optical compensation film 5-B prepared above and the
polarizing plate 104 of Example 9 were adhered with an acrylic
tacky adhesive. In this operation, the absorbing axis of the
polarizing film and the phase retarding axis of the optical
compensation film 5-B were made parallel each other. In this manner
a polarizing plate 5-B with an optical compensation film was
prepared.
[0306] (Preparation of Polarizing Plate 5-C)
[0307] A polarizing film was prepared in the same manner as in
Example 9. On both surfaces of the polarizing film, cellulose
triacetate films (FUJITAC T40UZ, manufactured by Fuji Photo Film
Co., Re=1 nm, Rth=35 nm, thickness 40 .mu.m) having a saponified
surface were adhered with a polyvinyl alcohol-based adhesive,
whereby a polarizing plate 301 was prepared.
[0308] The optical compensation film 5-C prepared above and the
polarizing plate 301 were adhered with an acrylic tacky adhesive.
In this operation, the absorbing axis of the polarizing film and
the phase retarding axis of the optical compensation film 5-C were
made perpendicular each other. In this manner a polarizing plate
5-C with an optical compensation film was prepared.
[0309] (Preparation of Polarizing Plate 5-D)
[0310] The optical compensation film 5-D prepared above and the
polarizing plate 301 were adhered with an acrylic tacky adhesive.
In this operation, the optically anisotropic layer B2 contained in
the optical compensation film 5-D was positioned at the side of the
polarizing plate 301, and the absorbing axis of the polarizing film
and the phase retarding axis of the optical compensation film 5-D
were made parallel each other. In this manner a polarizing plate
5-D with an optical compensation film was prepared.
[0311] (Mounting Evaluation on IPS Panel)
[0312] Evaluation of mounting on an IPS panel was conducted in
following four classes A to D, according to the type of the optical
characteristics of the optical compensation film employed on the
liquid crystal display.
(Class A)
[0313] In a structure shown in FIG. 5, there were employed the
polarizing plate 5-A as an optical compensation film 4 and a
polarizing plate 1, an IPS liquid crystal cell as a liquid crystal
cell 3, and the polarizing plate 104 prepared in Example 9 as an
optical film 5 and a polarizing plate 2, and these were adhered
with a tacky adhesive material. The adhesion was made in such a
manner that the optical compensation film 5-A of the polarizing
plate 5-A was positioned at the side of the liquid crystal cell,
and that the optical film 004 of the polarizing plate 104 was
positioned at the side of the liquid crystal cell. The absorbing
axes of the upper and lower polarizing plates were made
perpendicular each other, and the absorbing axis of the lower
polarizing plate was made perpendicular to the direction of the
molecular longer axis of the liquid crystal cell (namely the phase
retarding axis of the optical compensation film 5-A being parallel
to the direction of molecular longer axis of the liquid crystal
cell). A liquid crystal cell was taken out from a liquid crystal
television TH-32LX500 (manufactured by Matsushita Electric
Industrial Co.), and was used as the liquid crystal cell 3, after
removing the polarizing plates provided at the observing side and
at the backlight side, and the optical film. In this liquid crystal
cell, the liquid crystal molecules were substantially parallel
aligned between the glass substrates in a state without voltage
application and in a black display state, with a phase retarding
axis parallel to the imaging surface. Also a mounting was executed
with a similar layered structure, employing each of the polarizing
plates utilizing the optical films of Comparative Example 1, 2,
obtained in Example 9, instead of the optical film of the
invention.
(Class B)
[0314] In a structure shown in FIG. 5, there were employed the
polarizing plate 5-B as an optical compensation film 4 and a
polarizing plate 1, the IPS liquid crystal cell as a liquid crystal
cell 3, and the polarizing plate 104 prepared in Example 9 as an
optical film 5 and a polarizing plate 2, and these were adhered
with a tacky adhesive material. The adhesion was made in such a
manner that the optical compensation film 5-B of the polarizing
plate 5-B was positioned at the side of the liquid crystal cell,
and that the optical film 004 of the polarizing plate 104 was
positioned at the side of the liquid crystal cell. The absorbing
axes of the upper and lower polarizing plates were made
perpendicular each other, and the absorbing axis of the lower
polarizing plate was made perpendicular to the direction of the
molecular longer axis of the liquid crystal cell (namely the phase
retarding axis of the optical compensation film 5-B being
perpendicular to the direction of molecular longer axis of the
liquid crystal cell). The liquid crystal cell employed was a
parallel alignment cell, same as in the class A. Also a mounting
was executed with a similar layered structure, employing each of
polarizing plates utilizing the optical films of Comparative
Example 1, 2, obtained in Example 9, instead of the optical film of
the invention.
(Class C)
[0315] In a structure shown in FIG. 5, there were employed the
polarizing plate 5-C as an optical compensation film 4 and a
polarizing plate 1, the IPS liquid crystal cell as a liquid crystal
cell 3, and the polarizing plate 104 prepared in Example 9 as an
optical film 5 and a polarizing plate 2, and these were adhered
with a tacky adhesive material. The adhesion was made in such a
manner that the optical compensation film 5-C of the polarizing
plate 5-C was positioned at the side of the liquid crystal cell,
and that the optical film 004 of the polarizing plate 104 was
positioned at the side of the liquid crystal cell. The absorbing
axes of the upper and lower polarizing plates were made
perpendicular each other, and the absorbing axis of the lower
polarizing plate was made perpendicular to the direction of the
molecular longer axis of the liquid crystal cell (namely the phase
retarding axis of the optical compensation film 5-C being parallel
to the direction of molecular longer axis of the liquid crystal
cell). The liquid crystal cell employed was a parallel alignment
cell, same as in the class A. Also a mounting was executed with a
similar layered structure, employing each of the polarizing plates
utilizing the optical films of Comparative Example 1, 2, obtained
in Example 9, instead of the optical film of the invention.
(Class D)
[0316] In a structure shown in FIG. 5, there were employed the
polarizing plate 5-D as an optical compensation film 4 and a
polarizing plate 1, the IPS liquid crystal cell as a liquid crystal
cell 3, and the polarizing plate 104 prepared in Example 9 as an
optical film 5 and a polarizing plate 2, and these were adhered
with a tacky adhesive material. The adhesion was made in such a
manner that the optical compensation film 5-D of the polarizing
plate 5-D was positioned at the side of the liquid crystal cell,
and that the optical film 004 of the polarizing plate 104 was
positioned at the side of the liquid crystal cell. The absorbing
axes of the upper and lower polarizing plates were made
perpendicular each other, and the absorbing axis of the lower
polarizing plate was made perpendicular to the direction of the
molecular longer axis of the liquid crystal cell (namely the phase
retarding axis of the optical compensation film 5-D being
perpendicular to the direction of molecular longer axis of the
liquid crystal cell). The liquid crystal cell employed was a
parallel alignment cell, same as in the class A. Also a mounting
was executed with a similar layered structure, employing each of
the polarizing plates utilizing the optical films of Comparative
Example 1, 2, obtained in Example 9, instead of the optical film of
the invention.
[0317] In the liquid crystal display thus prepared, a light leak
rate and a color shift in a black display state were evaluated in a
direction with an azimuthal angle of 45.degree. and a polar angle
of 60.degree. from the frontal direction to the apparatus. Results
are shown in Table 4. The liquid crystal displays employing the
polarizing plate 104 utilizing the optical films of the invention
showed no color shift and little light leakage when observed from
an inclined direction, while the liquid crystal displays employing
the polarizing plates utilizing Comparative Examples 1, 2 showed a
large color shift and a large light leakage.
Example 13
[0318] (Evaluation of Mounting on OCB Panel)
[0319] The optical film 001 of the invention obtained in Example 1
was evaluated utilizing a liquid crystal display described in
Example 1 of JP-A-10-48420, an optically anisotropic layer
containing discotic liquid crystal molecules described in Example 1
of JP-A-9-26572, an alignment film formed by coating polyvinyl
alcohol, and an OCB-mode liquid crystal display described in FIGS.
10 to 15 of JP-A-2000-154261, and provided a saisfactory
performance in the viewing angle-dependent contrast, and a
satisfactory result was obtained in the color shift in an
evaluation as in Example 10. The optical films of Comparative
Examples 1, 2 were inferior, in a similar evaluation, to those of
the invention. These results are shown in Table 4.
[0320] As explained in the foregoing, the optical film of the
invention, and the optical compensation film and the polarizing
plate utilizing the same are identified as an optical film which is
capable of suppressing a color shift and providing a high contrast
ratio over a wide viewing angle.
[0321] It will be apparent to those skilled in the art that various
modifications and variations can be made to the described
embodiments of the invention without departing from the spirit or
scope of the invention. Thus, it is intended that the invention
cover all modifications and variations of this invention consistent
with the scope of the appended claims and their equivalents.
[0322] The present application claims foreign priority based on
Japanese Patent Application Nos. JP2005-262304 and JP2006-63026,
filed Sep. 9 of 2005 and Mar. 8 of 2006, respectively, the contents
of which are incorporated herein by reference.
* * * * *